MODELO

Sustancia incompresible Gas Perfecto Gas Ideal Sustancia Real

PROPIEDAD

v v = cte V = [R T / P] V = [R T / P] Tablas

u u = u(T) u(T) = a + bT u(T) u = u(T,v) ; Tablas

h h = u + Pv = h(T,P) h(T) = a’ + b’T h(T) h = h(T,P); Tablas

Cv Cv = du/dT = cte Cv = du/dT = cte Cv = du/dT = Cv (T) Cv = ( ∂u/ ∂T) v

Cp Cp = Cv = cte Cp = (dh/dT) = cte Cp = (dh/dT) = cte Cp = ( ∂h/ ∂T) P

ΔU = ∫ cv dT;
Δu Δu = C ΔT Δu = Cv ΔT Tablas: u2 – u1

Δh = cp ΔT; Δh = ∫ cp dT;
ΔH Δh = C ΔT + v ΔP Tablas: h2 – h1
 MODELO SUSTANCIA
ECUACIÓN GENERAL (Gases) GAS IDEAL GAS PERFECTO
INCOMPRESIBLE

Térmica de estado P = P(T,v) P.V = N.R.T P.V = N.R.T V = cte

Pvn=K [T 2 / T 1] = [P 2 /P 1][h-1/h] T2 = T1 [P 2 /P 1][h-1/h]

Proceso politrópico -------
(P v n )1 = (P v n) 2 [T 2 / T 1] = [v 1 /v 2][h-1] T2 = T1 [v 1 /v 2][h-1]

Trabajo de
expansión [P1 v1 – P2 v2] / [h-1] [N R ( T 1 – T2)] / [h-1] [m r ( T 1 – T2)] / [h-1] -------
politrópico
dU = ( ∂u/ ∂T) v dT
ΔU = ∫ ce dT;
dU/dT = ( ∂u/ ∂T) v = cv ΔU = ∫ cv dT;
Energía de estado du = (∂u/∂T)v dT + (∂U/∂v)T dv U1 – U1 = ce ( T2- T1 )
∫ dU = ∫ cv dT = ΔU U2 – U1 = cv ( T2- T1 )
ce = cte

Balance de energía ΔU = Q – Wext. ΔU = Q – Wext. ΔU = Q – Wext. ΔU = Q – Wext.