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AP Chemistry - Kinetics of A Reaction Lab
AP Chemistry - Kinetics of A Reaction Lab
Background:
This experiment in designed to study the kinetics of a chemical
reaction. The reaction involves the oxidation of iodide ions by bromate ions in
the presence of acid:
The reaction is somewhat slow at room temperature. The reaction rate depends
on the concentration of the reactants and on the temperature. The rate law for
the reaction is a mathematical expression that relates the reaction rate to the
concentrations of the reactants. If the rate of the reaction is expressed as the
rate of decrease in concentration of bromate ion, the rate law has the form:
where the square brackets refer to the molar concentration of the indicated
species. The rate is equal to the change in concentration of the bromate ion.
-∆[BrO3-], divided by the change in time for the reaction to occur, ∆t. The term
"k" is the rate constant for the equation, which changes as the temperature
changes. The exponents x, y, and z, are called the "orders" of the reaction with
respect to the indicated substance, and show how the concentration of each
substance affects the rate of reaction.
The total rate law for the process is determined by measuring the rate,
evaluating the rate constant, k, and determining the order of the reaction for
each reactant (the values of x, y, and z.)
To find the rate of the reaction a method is needed to measure the rate
at which on e of the reactants is used up, or the rate at which one of the
products is formed. In this experiment, the rate of reaction will be measured
based on the rate at which iodine forms. The reaction will be carried out in the
presence of thiosulfate ions, which will react with iodine as it forms:
I2(aq) + 2S2O3-2(aq) 2I-(aq) + S4O6-2(aq) Reaction 2
Materials:
5mL 0.1M cupric nitrate Analytical balance (0.001g
solution, Cu(NO3) precision)
5mL distilled water, (1) 10ml beaker
5mL 0.10M HCl solution (7) Beral-type pipets with
5mL 0.010M potassium microtip
iodide, KI solution Cotton swaps
5mL 0.040M potassium Toothpicks
bromate, KBrO3solution Thermometer, 0◦-100◦C
5mL 2% starch solution (2) 12-well reaction strips
5mL sodium Trough
thiosulfate,Na2S2O3 solution 7 different colors of label
Cassette tape case tape
Timer, seconds
Procedure:
Part 1 – Find the Volume of One Drop of Solution
1) Obtain a microtip Beral-pipet. Fill the pipet with approx. 3mL of water.
2) Mass a small beaker using an analytical balance. Record the mass.
3) Holding the pipet vertically, deliver 5 drops of water into the beaker, nad
find the total mass. Record the data.
4) Add an additional 5 drops of water into the beaker, and again determine the
mass. Record the value.
5) Deliver 5 more drops and again find the mass. Record the data.
Part 2 – Determine the Reaction Rate and Calculate the Rate Law
1) Obtain 6 microtip pipets and fold an adhesive label around the stem of each
pipet. Label the pipets KI, H2O, Starch, Na2S2O3.
2) Fill each pipet with about 2mL of the appropriate liquid.
3) Place the pipets in an opened cassette case for storage.
4) Obtain 2 clean, 12-well reaction strips and arrage them so that the numbers
can be read from left to right.
5) Record the temperature of the one of the reaction solutions.
6) Using a provided table, fill each numbered well in the first reaction strip
with the appropriate number of drops of the reagent listed. Mix the solution in
each well with a new toothpick. Each experiment will be run in triplicate.
7) To wells 1-9 in the second reaction strip, add 2 drops of 0.040M KBrO3.
The timer should start immediately when the first drop of KBrO3 is added.
8) Record the time when the solution in each cell turns blue.
9) Rinse the contents of the well strips with warm water. Use a cotton swab to
dry the inside of each well.
12) Repeat the entire process (steps 4-11) for the following combinations that
cover experiments 4 and 5 and experiments 6 and 7, respectively.
Observations:
As thiosulfate ion was reacted, the solutions began turning blue. After
four minutes, the solutions reached a deep blue/indigo hue.
Analysis:
The average masses of 1 drop of water was calculated by averaging the
average mass of 1 drop of water calculated in the 3 trials, in which the mass of
a beaker plus 5 drops of water was subtracted from the mass of the same
beaker when empty. The volume of one drop of solution was calculated
through dimensional analysis by multiplying the average masses of 1 drop of
water by the conversion factor of the weight of 1mL of water, 1.0g, and then
dividing the product by 1000mL to calculate the volume in liters.
The mols of S2O3-2 was calculated by multiplying the mols of Na2S2O3
by 1, as there is a 1:1 stoichiometric ratio between mols of Na2S2O3 and mols
of S2O3-2. Mols of BrO3- was calculated by dividing mols of mols of S2O3-2 by 2
to calculate the mols of I2 because there is a 2:1 stoichiometric ratio between
mols of S2O3-2 and mols of I2, and then dividing the quotient by 3 because there
is a 3:1 stoichiometric ratio between mols of I2 and mols of BrO3-. The value of
-∆[BrO3] was calculated by dividing the mols of BrO3- reacted by the volume
of 12 drops. The rate of each reaction was found by dividing -∆[BrO3] by the
number of seconds for the reaction to occur.
The initial concentration of each reactant for each experiment was
calculated by using the proportion Vconcentrated X Mconcentrated = Vdilute X Mdilute,
where Vconcentrated and Mconcentrated are the volume and molarity of the starting,
concentrated solutions, and Vconcentrated and Mconcentrated are the volume and
molarity of the diluted reaction mixtures. Since volumes will be proportional to
the number of drops of solution used, the number of drops substitute for
volumes.
To calculate the order of iodide ion, “x,” Experiments 1 and 2 were
compared so that the concentrations of the species of the reaction were
substituted in the differential rate law equation, R = k[I-]x[BrO3-]y[H+]z
To calculate the order of bromate ion, “y,” Experiments 1 and 4 were
compared so that the concentrations of the species of the reaction were
substituted in the differential rate law equation, R = k[I-]x[BrO3-]y[H+]z
To calculate the order of hydrogen ion, “z,” Experiments 1 and 6 were
compared so that the concentrations of the species of the reaction were
substituted in the differential rate law equation, R = k[I-]x[BrO3-]y[H+]z
Once the order of each species involved in the reaction was determined,
the rate constant of each experiment was calculated by substituting data from
each respective experiment into the rate law equation, R = k[I-]x[BrO3-]y[H+]z
The rate of each reaction was calculated by dividing -∆[BrO3] by the
average reaction time.
The activation energy was calculated by graphing the natural log of the
rate constant on the y-axis versus the inverse of the temperature in Kelvins on
the x-axis to determine the slope of linear regression, and then equating the
slope to –Ea/R, where Ea is the activation energy and R = 8.31 J/mol X K.
Post-Lab Questions:
1) Why does the reaction rate change as concentrations of the reactants
change?
The reaction rate changes as concentrations of the reactants change
because of the direct relationship that exists between the concentrations of the
reactants and the reaction rate through the differential rate law.
6) Comment on the effect of the catalyst. Predict how the activation energy
changes when a catalyst is added to the reaction.
The addition of a catalyst increased the rate of the reaction. This is
because the function of catalysts in chemical reactions is to effectively lower
the activation energy barrier that a reaction must overcome to take place.
Conclusion:
The volume of one drop of water was experimentally determined to be
1.1 X 10-5 L. This value was achieved through the mathematical principle of
averaging multiple values by adding values and dividing the sum by the
number of values.
[I-] was experimentally determined to be 1st order; [BrO3-] was
experimentally determined to be 1st order; and [H+] was experimentally
determined to be 2nd order. Varying the concentration of one reactant
individually at any particular time while keeping the concentration other two
reactants constant enabled the mathematical calculation of the order of each
reactant.
The average reaction rate was experimentally determined to be 2.0 X
-7
10 M/s. This value was calculated by averaging the quotients of the -∆[BrO3]
divided by the number of seconds for each of the 7 reactions to take place.
The activation energy of the reaction at was experimentally determined
to be 28 kJ/mol. This was done by equating the slope of the best-fit linear
regression (-3393K) to –Ea/R, where Ea is the activation energy and R = 8.31
J/mol X K. Repeating the experiment at several different temperatures allowed
for the calculation of these values of energy; whereas at lower temperatures
molecular particles collide with less energy than required to overcome the
activation energy barrier and therefore bounce apart, resulting the lack of a
reaction, or result in a reaction that does take place but proceeds relatively
slowly, higher temperatures cause molecular particles to collide with energies
equal to or greater than the activation energy, which result in a rapid reaction.
One of the postulates for the Kinetic Molecular Theory is that the
average kinetic energy of the gas particles depends only on the temperature of
the system; thus, temperature is directly related to the rate of the reaction.
The rate constant was experimentally determined to be 22 M-3s-1. This
value was calculated using the differential rate law and equating the
experimentally determined rate of the reaction to the product of k and the
concentrations of each reactant raised to their respective orders, and then
averaging the calculated rate constants for each trial.
The total rate law of a reaction involving the oxidation of iodide ions
by bromate ions in the presence of acid was determined to be
R = k[I-][BrO3-][H+]2. This equation was determined by calculating the
individual order of each reactant and the rate constant k of the reaction and
relating them using the mathematical relationship stated by the differential rate
law.
The addition of a catalyst increased the rate of the reaction; the reaction
time decreased 36 seconds from 111 seconds uncatalyzed to 75 seconds
catalyzed. This is because the function of catalysts in chemical reactions is to
effectively lower the activation energy barrier that a reaction must overcome to
to initiate.