Flash photolysis is a laboratory technique where a sample is excited using a strong light pulse from a laser or flash lamp. This starts a chemical reaction or changes the energy levels of atoms and molecules in the sample. The absorption of light by the sample is then measured over short time intervals using test pulses to monitor the relaxation or reaction initiated by the pump pulse. Flash photolysis was developed after World War II to photograph missiles and has since become more sophisticated using optics and lasers. It is now used extensively to study light-induced processes in various materials and biological systems.
Flash photolysis is a laboratory technique where a sample is excited using a strong light pulse from a laser or flash lamp. This starts a chemical reaction or changes the energy levels of atoms and molecules in the sample. The absorption of light by the sample is then measured over short time intervals using test pulses to monitor the relaxation or reaction initiated by the pump pulse. Flash photolysis was developed after World War II to photograph missiles and has since become more sophisticated using optics and lasers. It is now used extensively to study light-induced processes in various materials and biological systems.
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Flash photolysis is a laboratory technique where a sample is excited using a strong light pulse from a laser or flash lamp. This starts a chemical reaction or changes the energy levels of atoms and molecules in the sample. The absorption of light by the sample is then measured over short time intervals using test pulses to monitor the relaxation or reaction initiated by the pump pulse. Flash photolysis was developed after World War II to photograph missiles and has since become more sophisticated using optics and lasers. It is now used extensively to study light-induced processes in various materials and biological systems.
Copyright:
Attribution Non-Commercial (BY-NC)
Available Formats
Download as DOCX, PDF, TXT or read online from Scribd
sample is firstly excited by a strong pulse (called pump pulse) of light from a laser of nanosecond, picosecond, or femtosecond pulse width or by a short-pulse light source such as a flash lamp. This first strong pulse starts a chemical reaction or leads to an increased population for energy levels other than the ground state within a sample of atoms or molecules. Typically the absorption of light by the sample is recorded within short time intervals (by a so-called test pulses) to monitor relaxation or reaction processes initiated by the pump pulse. Flash photolysis was developed shortly after World War II as a result of the military's attempts to build cameras fast enough to photograph missiles in flight. The technique was developed in 1949 byManfred Eigen, Ronald George Wreyford Norrish and George Porter, who won the 1967 Nobel Prize in Chemistry for this invention. Over the next 40 years the technique became more powerful and sophisticated due to developments in optics and lasers. Also, the interest in this method grew considerably as the practical applications expanded from chemistry to areas such as biology, materials science, and environmental sciences. Today flash photolysis facilities are extensively used by researchers to study light-induced processes in organic molecules, polymers, nanoparticles,semiconductors, photosynthesis i n plants, signaling, and light-induced conformational changes in biological systems.