MODEL HOME WORK: 3

Term : II Course Code : CHE101 Course Title: Chemistry Max. Marks: 7

Name of the planner: Dr.Harmanjit Singh ID of the planner : 13688

Part A

Q.1 Write down IUPAC name of following complexes:

i) [Pt(NH3)5Cl]Br3 v) [CoCl(NH3)5]Cl2

ii) [Co(NH3)5 Cl]Cl2 vi) Na2[NiCl4]

iii) K4 [Fe(CN)6] vii) [Co(SO4)(NH3)5]+

iv) (NH4)2[Ni(C2O4)2(H2O)2]

Q.2 a) By metal plating of iron how can we prevent it from corrosion? Which things we need to
keep in mind for selecting these coating metals?

b) Sc, Ti can have both +2 and +3 oxidation state easily but why it is not possible for Ni and Cu
to have +3 oxidation state?

Q.3 Write the formula of each of the following complexes:

i) hexaammineiron(III) hexacyanochromate (III) ii) potassium tetracyanocuprate(II)

iii) pentaaquahydroxoiron(III) ion iv) potassium trioxalatoaluminate(III)

v) sodium monochloropentacyanoferrate(III) vi) pentaamminebromocobalt(III) sulfate

vii) tris(ethylenediamine)cobalt(III) sulfate

Part B

Q.4 a) As we move from scandium to copper, atomic radii are decreasing very gradually but
when we move from sodium to argon atomic radii are decreasing very rapidly. Explain your
reason.

b) Write electronic configuration of following transition metal ions:

Cu+, Fe2+, Mn2+, Cr3+, Ni2+, Sc3+, Co2+

Q.5 a) The [Ni(CN)4]2- ion is having square planar geometry, whereas [Ni(Cl)4]2- ion has
tetrahedral geometry. On the basis of crystal field splitting diagram of both these complexes
explain their magnetic nature.

b) Predict the number of unpaired electrons in the following complex ions:

i) [Cr (H2O)6]3+ ii) [Cr (H2O)6]2+, iii) [FeF6]3-

Q6. Calculate the CFSE for the following complexes:

i) d5 high spin octahedral v) [Cr(CN)6]4-

ii) d6 low spin octahedral vi) [Co(NH3)6]3+

iii) d7 tetrahedral vii) [CuCl4]2-

iv) d3 tetrahedral

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