Here is how you can start with.

1. Install Loadrunner
2. Focus in Virtual User Generator. This is the component where scripting it done.
3. Use inbuilt Task pane in Loadrunner which instructs the steps in developing
Loadrunner test script.
4. Use demo application or any other available to you
5. Start Recording scripts, running scripts, correlating scripts, parameterizing
data values
6. Open Loadrunner Help and refer when you get a doubt.
7. If you have a little of c lang. progg. experience it is an advantage. But not
necessary.
8. Once your Script is running without errors in Virtual user generator, run it
through Controller and analyze in Analysis. Follow Help here also. They are
relatively much easier.

Please consult me if you still have questions or trouble in following this approach.
Note: Focus on correlation techniques, this is very important topic for you to succeed
in scripting. Wish you All the very Best!!!