CHEMCAD 6.3.

0 Page 1

Simulation: 30 mart son simulation Date: 03/30/2011 Time: 21:20:45

EQUIPMENT SUMMARIES

Shortcut Distillation Summary

Equip. No. 12 13 14
Name
Mode 2 2 2
Light key component 1.0000 3.0000 5.0000
Light key split 0.9990 0.9990 0.9900
Heavy key component 3.0000 5.0000 6.0000
Heavy key split 0.0010 0.0100 0.0050
R/Rmin 1.5000 1.5000 1.5000
Number of stages 18.6331 21.0818 16.2001
Min. No. of stages 8.2513 9.8590 7.5421
Feed stage 9.8165 9.0387 9.1289
Condenser duty -7.1733 -5.8127 -0.3485
(MMBtu/h)
Reboiler duty MMBtu/h 9.2927 5.4850 0.3986
Colm pressure bar 1.0000 1.0000 1.0000
Reflux ratio, minimum 0.2719 0.3820 0.3715
Calc. Reflux ratio 0.4079 0.5729 0.5572
Colm pressure drop 0.5000 0.2000 0.5000
(bar)
CHEMCAD 6.3.0 Page 1

Simulation: 30 mart son simulation Date: 03/30/2011 Time: 21:21:47

EQUIPMENT SUMMARIES

Kinetic Reactor Summary

Equip. No. 6
Name
Reactor type 2
Reaction phase 2
Thermal mode 1
Pressure In bar 32.0000
Tout C 170.0000
Q MMBtu/h -8.5534
Reactor volume ft3 116920.0547
Specify calc. mode 1
Conversion 0.9997
Key 2
No. of Reactions 2
Rate equation type 2
Overall IG Ht of Rxn -9.8223
(MMBtu/h)
Overall Liq H of Rxn -9.5511
(MMBtu/h)

Reaction Stoichiometrics and Parameters for unit no. 6

Reaction 1
RateConst = 2.4000e+000 Act.E = 0.0000e+000 Hrxn = 0.0000e+000
Comp Stoich. Exp.factor AdsorbFac. AdsorbE AdsorbExp.
1 -1.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000
2 -1.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000
3 1.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000

Reaction 2
RateConst = 1.5000e+000 Act.E = 0.0000e+000 Hrxn = 0.0000e+000
Comp Stoich. Exp.factor AdsorbFac. AdsorbE AdsorbExp.
1 -1.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000
2 -2.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000
5 1.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000

Plug Flow Profile for unit no. 6

Vol Temp Press Total Mole frac Mole frac

ft3 C bar kmol/h Benzene Propylene
0.00 170.00 32.00 391.54 7.093E-001 2.682E-001
5846.00 170.00 32.00 291.90 6.241E-001 1.838E-002
11692.00 170.00 32.00 286.82 6.175E-001 9.837E-004
17538.00 170.00 32.00 286.55 6.171E-001 5.205E-005
CHEMCAD 6.3.0 Page 2

Simulation: 30 mart son simulation Date: 03/30/2011 Time: 21:21:47

EQUIPMENT SUMMARIES
 23384.00 170.00 32.00 286.54 6.171E-001 2.753E-006
29230.00 170.00 32.00 286.53 6.171E-001 1.456E-007
35076.00 170.00 32.00 286.53 6.171E-001 7.698E-009
40922.00 170.00 32.00 286.53 6.171E-001 4.069E-010
46768.00 170.00 32.00 286.53 6.171E-001 2.144E-011
52614.00 170.00 32.00 286.53 6.171E-001 1.130E-012
58460.00 170.00 32.00 286.53 6.171E-001 6.039E-014
64306.00 170.00 32.00 286.53 6.171E-001 3.227E-015
70152.00 170.00 32.00 286.53 6.171E-001 1.724E-016
75998.00 170.00 32.00 286.53 6.171E-001 9.212E-018
81844.00 170.00 32.00 286.53 6.171E-001 1.583E-018
87690.00 170.00 32.00 286.53 6.171E-001 1.583E-018
93536.00 170.00 32.00 286.53 6.171E-001 1.583E-018
99382.00 170.00 32.00 286.53 6.171E-001 1.583E-018
105230.00 170.00 32.00 286.53 6.171E-001 1.583E-018
111070.00 170.00 32.00 286.53 6.171E-001 1.583E-018
116920.00 170.00 32.00 286.53 6.171E-001 1.583E-018

Vol Temp Press Total Mole frac Mole frac

ft3 C bar kmol/h Cumene Propane
0.00 170.00 32.00 391.54 5.332E-005 1.731E-002
5846.00 170.00 32.00 291.90 3.135E-001 2.322E-002
11692.00 170.00 32.00 286.82 3.367E-001 2.363E-002
17538.00 170.00 32.00 286.55 3.379E-001 2.365E-002
23384.00 170.00 32.00 286.54 3.380E-001 2.365E-002
29230.00 170.00 32.00 286.53 3.380E-001 2.365E-002
35076.00 170.00 32.00 286.53 3.380E-001 2.365E-002
40922.00 170.00 32.00 286.53 3.380E-001 2.365E-002
46768.00 170.00 32.00 286.53 3.380E-001 2.365E-002
52614.00 170.00 32.00 286.53 3.380E-001 2.365E-002
58460.00 170.00 32.00 286.53 3.380E-001 2.365E-002
64306.00 170.00 32.00 286.53 3.380E-001 2.365E-002
70152.00 170.00 32.00 286.53 3.380E-001 2.365E-002
75998.00 170.00 32.00 286.53 3.380E-001 2.365E-002
81844.00 170.00 32.00 286.53 3.380E-001 2.365E-002
87690.00 170.00 32.00 286.53 3.380E-001 2.365E-002
93536.00 170.00 32.00 286.53 3.380E-001 2.365E-002
99382.00 170.00 32.00 286.53 3.380E-001 2.365E-002
105230.00 170.00 32.00 286.53 3.380E-001 2.365E-002
111070.00 170.00 32.00 286.53 3.380E-001 2.365E-002
116920.00 170.00 32.00 286.53 3.380E-001 2.365E-002

Vol Temp Press Total Mole frac Mole frac

ft3 C bar kmol/h P-Diisopropylben 1-Hexadecene
0.00 170.00 32.00 391.54 3.006E-011 5.108E-003
5846.00 170.00 32.00 291.90 1.396E-002 6.852E-003
11692.00 170.00 32.00 286.82 1.426E-002 6.973E-003
17538.00 170.00 32.00 286.55 1.427E-002 6.980E-003
CHEMCAD 6.3.0 Page 3

Simulation: 30 mart son simulation Date: 03/30/2011 Time: 21:21:47

EQUIPMENT SUMMARIES

23384.00 170.00 32.00 286.54 1.428E-002 6.980E-003

29230.00 170.00 32.00 286.53 1.428E-002 6.980E-003
35076.00 170.00 32.00 286.53 1.428E-002 6.980E-003
 40922.00 170.00 32.00 286.53 1.428E-002 6.980E-003
46768.00 170.00 32.00 286.53 1.428E-002 6.980E-003
52614.00 170.00 32.00 286.53 1.428E-002 6.980E-003
58460.00 170.00 32.00 286.53 1.428E-002 6.980E-003
64306.00 170.00 32.00 286.53 1.428E-002 6.980E-003
70152.00 170.00 32.00 286.53 1.428E-002 6.980E-003
75998.00 170.00 32.00 286.53 1.428E-002 6.980E-003
81844.00 170.00 32.00 286.53 1.428E-002 6.980E-003
87690.00 170.00 32.00 286.53 1.428E-002 6.980E-003
93536.00 170.00 32.00 286.53 1.428E-002 6.980E-003
99382.00 170.00 32.00 286.53 1.428E-002 6.980E-003
105230.00 170.00 32.00 286.53 1.428E-002 6.980E-003
111070.00 170.00 32.00 286.53 1.428E-002 6.980E-003
116920.00 170.00 32.00 286.53 1.428E-002 6.980E-003

Equilibrium Reactor Summary

Equip. No. 7
Name
Thermal mode 2
Temperature C 220.0000
Heat duty MMBtu/h 0.4469
Reaction phase 2
Calc. mode 2
No of Reactions 1
Calc IG Ht of Rxn 0.0103
(MMBtu/h)
Calc Liq H of Rxn 0.0135
(MMBtu/h)

Reaction Stoichiometrics and Parameters for unit no. 7

Reaction no. 1
Base component 5
Frac.conversion 0.9900
Comp 1
Stoic. coeff. -1.0000
Comp 5
Stoic. coeff. -1.0000
Comp 3
Stoic. coeff. 2.0000
CHEMCAD 6.3.0 Page 1

Simulation: 30 mart son simulation Date: 03/30/2011 Time: 21:23:38

FLOW SUMMARIES:

Stream No. 1 5
Stream Name
Temp C 25.0000* 25.0000*
Pres bar 1.0000* 1.0000*
Enth MMBtu/h 10.723 1.3024
Vapor mole frac. 0.00000 1.0000
Total kmol/h 245.6000 111.6500
Total kg/h 19477.4300 4711.7439
Total std L ft3/hr 780.0093 319.3210
Total std V scfh 194399.89 88374.38
Flowrates in kg/h
Benzene 19028.5702 0.0000
Propylene 0.0000 4418.5053
Cumene 0.0000 0.0000
Propane 0.0000 293.2384
P-Diisopropylben 0.0000 0.0000
1-Hexadecene 448.8600 0.0000
CHEMCAD 6.3.0 Page 1

Simulation: 30 mart son simulation Date: 03/30/2011 Time: 21:24:09

FLOW SUMMARIES:

Stream No. 11 12 20 23
Stream Name
Temp C 20.0000 75.8541 151.8009 298.7643
Pres bar 0.0859 1.0000 1.0000 1.5000
Enth MMBtu/h 0.87377 6.3342 -1.0243 -0.31536
Vapor mole frac. 1.0000 0.00000 0.00000 0.00000
Total kmol/h 25.7882 120.0014 104.4067 2.0535
Total kg/h 1825.5939 9361.7230 12544.1484 457.5443
Total std L ft3/hr 81.0567 374.4090 511.3528 20.5409
Total std V scfh 20412.17 94984.77 82641.11 1625.43
Flowrates in kg/h
Benzene 1488.5770 9333.3142 13.3464 0.0000
Propylene 0.0000 0.0000 0.0000 0.0000
Cumene 63.0906 8.7830 12522.0278 0.0002
Propane 273.6125 19.6261 0.0000 0.0000
P-Diisopropylben 0.3118 0.0000 8.7742 8.6864
1-Hexadecene 0.0022 0.0000 0.0000 448.8577