QCS/52/09/PR/MA/NA/001 Rev.

C2

Appendix 12.10
Laboratory Schedule

SAMPLING METHOD
For detailed sampling connections, refer to Appendix 12.3 P&IDs
P&ID LEAD SHEET: Dwg. No. QCS/50/00/PR/DR/PI/012 & 012A
P&ID Unit 09: Dwg. No. QCS/.52/09/PR/DR/PI/211, 211A, 211B & 211C
LABORATORY SCHEDULE FOR SULFUR RECOVERY UNIT (UNIT 09) LEGEND: SO: Start up operation A:1/Shift D: 1/Month
NO: Normal operation B:1/Day E: On Request (at least D)
C: 1/Week F: 1/6 hours
* : On-line Analyzer Provided G: 1/4 hours

NOTE: Frequency shall be increased when operating condition is changed.

Indication of “mo1%“ is based on “Dry” condition unless otherwise
specified.

SAMPLING POINT TESTING ITEM FREQUENCY

&
NORMAL FIGURE
No. STREAM NAME 1) Sampling Type & No. Test Item Normal Figure SO NO TEST METHOD SAMPLING SAMPLE REMARKS
2) Location (Note 1) METHOD CONTAINER
3) Related Line No.
4) Related Dwg No.
9.1 AGE Backwash 1) S5-520921 CO2 SMS 2239 S5
Recycle Water to 52- 2) Discharge of 52-P0911A/B H2S SMS 2239 52-09-PR-
P0905A/B DR-PI-211
3) SV5209028-6” H2O SMS 1608
4) 52-09-PR-DR-PI-104
9.2 Lean solution from 1) S5-520931 H2S 0.04 mol % 3/wk. SMS 2239 S5
52-E0904A-C 2 Inlet to 52-C0903 CO2 0.10 mol % E SMS 2239 52-09-PR-
3) SV5209053-16” MDEA (RFB) C SMS 2236 DR-PI-211

4) 52-09-PR-DR-PI-105 MDEA (ATB) D SMS 2236

MDEA (TB) D SMS 2235
Total N2 E SMS 1385
pH 3/wk. ASTM E70/90
Foaming C SMS 1327
Tendency
H2O E SMS 1608

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 SAMPLING POINT TESTING ITEM FREQUENCY
&
NORMAL FIGURE
No. STREAM NAME 1) Sampling Type & No. Test Item Normal Figure SO NO TEST METHOD SAMPLING SAMPLE REMARKS
2) Location (Note 1) METHOD CONTAINER
3) Related Line No.
4) Related Dwg No.
9.3 Age Off Gas from 1) S3-520901 HC C GPA 2261 S3B *52AI090041
52-C0903 2) Downstream 52AP090041 H2S, 0.02 mol % C C* SMS 1318 52-09-PR-
3) P5209038-32” CO2 (Dry basis) 98.42 mol % E ASTM D 5504 DR-PI-211

4) 52-09-PR-DR-PI-106 RSH / COS E SMS 2236

RSR E SMS 1918
Total sulfur ASTM D6667
9.4 AGE rich solution to 1) S6-520932 H2S 24.93 mol % E SMS 2239 S6
52-E0906A-C 2) Discharge 52-P0905A/B CO2 13.98 mol % E SMS 2239 52-09-PR-
3) SV5209043-16” MDEA(RFB) E SMS 2236 DR-PI-211

4) 52-09-PR-DR-PI-107 MDEA(ATB) E SMS 2236

MDEA(TB) E SMS 2235
Total N2. E SMS 1365
Foaming E SMS 1327
Tendency
H2O E SMS 1608
9.5 Blowdown water from 1) S2-520941 pH ASTM D 1293 S2
52-E0911 2) Blowdown water to52-V9221 Cl– ASTM D 512 52-09-PR-
3) BD5209303-3” Conductivity ASTM D 1125 DR-PI-211

4) 52-09-PR-DR-PI-120 PO4 ASTM D 515

SO3 ASTM D4327
Silica ASTM D 859
TDS ASTM D 18880
9.6 Process gas from 1) S-520903 H2S 4.6 mol% E C/E ASTM D 6228-98 S (Note 3) Customized
52-E0911 2) Inlet of 52-V0911 SO2 3.1 mol% E C/E ASTM D 6228-98 Gaschromatograph
3) P5209005-52” COS 1.45 mol% E E ASTM D 6228-98 With capillary column &
4) 52-09-PR-DR-PI-121 CS2 0.18 mol% E E ASTM D 6228-98 PFD. (Note 2)

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 SAMPLING POINT TESTING ITEM FREQUENCY
&
NORMAL FIGURE
No. STREAM NAME 1) Sampling Type & No. Test Item Normal Figure SO NO TEST METHOD SAMPLING SAMPLE REMARKS
2) Location (Note 1) METHOD CONTAINER
3) Related Line No.
4) Related Dwg No.
9.7 Process Gas to 52- 1) S-520904 H2S 1.9 mol% E C/E ASTM D 6228-98 S (Note 3) Customized
E0912 2) Outlet of 52-V0911 SO2 0.96 mol% E C/E ASTM D 6228-98 Gaschromatograph
3) P5209008-52” COS 0.15 mol% E E ASTM D 6228-98 With capillary column & PFD
4) 52-09-PR-DR-PI-121 CS2 0.03 mol% E E ASTM D 6228
9.8 Blowdown water from 1) S2-520942 pH E ASTM D 1293 B
52-E0912 2) Blow down water to 52-V9221 Cl– ASTM D 512
3) BD5209003-2” Conductivity ASTM D 1125
4) 52-09-PR-DR-PI-122 PO4 ASTM D 515
SO3 ASTM D4327
Silica ASTM D 859
TDS ASTM D 18880
9.10 Process gas from 1) S-520906 H2S 1.95 mol% E C/E ASTM D 6228-98 S (Note 3) Customized
52-E0913 2) Inlet of 52-V0912 SO2 0.98 mol% E C/E ASTM D 6228-98 Gaschromatograph
3) P5209010-52” With capillary column &
4) 52-09-PR-DR-PI-123 PFD. (Note 2)

9.11 Process gas to 1) S-520907 H2S 0.44 mol% E C/E ASTM D 6228-98 S (Note 3) Customized
52-E0914 2) Outlet of 52-V0912 SO2 0.22 mol% E C/E ASTM D 6228-98 Gaschromatograph
3) P5209013-52” With capillary column &
4) 52-09-PR-DR-PI-123 PFD.

9.12 Process gas from 1) S-520908 H2S 0.44 mol% E C/E ASTM D 6228-98 S (Note 3) Customized
52-E0914 2) Inlet of 52-V0913 SO2 0.22 mol% E C/E ASTM D 6228-98 Chromatograph
3) P5209014-52”
4) 52-09-PR-DR-PI-125
9.13 Process gas to 1) S-520909 H2S 0.44 mol% E C/E ASTM D 6228-98 S (Note 3) Customized
52-F0901 2) Outlet of 52-V0913 SO2 0.22 mol% E C/E ASTM D 6228-98 Chromatograph
3) P5209015-52”
4) 52-09-PR-DR-PI-125

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 SAMPLING POINT TESTING ITEM FREQUENCY
&
NORMAL FIGURE
No. STREAM NAME 1) Sampling Type & No. Test Item Normal Figure SO NO TEST METHOD SAMPLING SAMPLE REMARKS
2) Location (Note 1) METHOD CONTAINER
3) Related Line No.
4) Related Dwg No.
9.14 Process Gas from 52- 1) S-520910 H2S 0.43 mol % SMS 2254 S (Note 3) Customized
F0901 2) Inlet to 52-V0901 SO2 0.22 mol % Chromatograph
3) P5209016-64” CO2 37.66 mol % SMS 2254
4) 52-09-PR-DR-PI-130 H2O ASTM D5454
9.15 Process Gas to 52- 1) S-520911 H2S 1.01 mol % SMS 2254 S (Note 3) Customized
E0901 2) Outlet of 52-V0901 SO2 0 Chromatograph
3) P5209019-64” CO2 39.28 mol % SMS 2254
4) 52-09-PR-DR-PI-130 H2O ASTM D5454
9.16 Blow down water to 1) S2-520943 pH E ASTM D 1293 S2
52-V9221 2) Blow down water from 52- Cl– ASTM D 512 52-09-PR-
E0901 Conductivity ASTM D 1125 DR-PI-211A
3) BD5209005-2” PO4 ASTM D 515
4) 52-09-PR-DR-PI-131 SO3 ASTM D 4327
Silica ASTM D 859
TDS ASTM D 18880
9.17 Process Gas from 1) S3-520912 HC 0.24 mol % E* GPA 2261 S3B *52AI090011 (H2s,H2)
52-C0901 2) O/H outlet of 52-C0901 N2 56.04 mol % E SMS 1318 52-09-PR-
3) P5209021-56” H2 3.21 mol % E ASTM D 5504 DR-PI-211

4) 52-09-PR-DR-PI-141 H2S 1.01 mol %

CO2 39.28 mol %
RSH/COS 0.01 mol %
9.18 Circulation water from 1) S5-520923 pH E* SMS 1350 S5 *52AI090012
52-E0902A/B 2) Circulation water inlet to 52- Turbidity E Visual 52-09-PR-
C0901 Total Sulfur E SMS 600 DR-PI-211A
3) PW5209005-14” H2S E SMS 2239
4) 52-09-PR-DR-PI-141 Elemental E SMS 1897
Sulfur E SMS 2239
CO2 SMS 2239

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 SAMPLING POINT TESTING ITEM FREQUENCY
&
NORMAL FIGURE
No. STREAM NAME 1) Sampling Type & No. Test Item Normal Figure SO NO TEST METHOD SAMPLING SAMPLE REMARKS
2) Location (Note 1) METHOD CONTAINER
3) Related Line No.
4) Related Dwg No.
9.19 TGT backwash water 1) S5-520922 CO2 SMS 2239 S5
to 52-C0902 2). Discharge from 52-P0910A/B H2S SMS 2239 52-09-PR-
3) SV5209003-6” H2O SMS 1608 DR-PI-211A

4) 52-09-PR-DR-PI-146
9.20 TGT Tail Gas to 52- 1) S3-520913 CO2 38.12 mol % SMS 2239 S3B *52AI090014 (H2S)
X0921 2) O/H from 52-C0902 H2S 0.01 mol % SMS 2239 52-09-PR-
3) P5209024-60” H2O SMS 1608 DR-PI-211A

4) 52-09-PR-DR-PI-147
9.21 TGT rich solution to 1) S6-520933 CO2 14.68 mol % SMS 2239 S6
52-E0906A/C 2) Discharge from 52-P0902A/B H2S 5.89 mol % SMS 2239 52-09-PR-
3) SV5209015-10” H2O SMS 1608 DR-PI-211A

4) 52-09-PR-DR-PI-148
9.22 Blowdown water from 1) S2-520944 pH E ASTM D 1293 S2
52-E0921 2) Blowdown water to 52-V921 Cl–
ASTM D 512 52-09-PR-
3) BD5209007-3” Conductivity ASTM D 1125 DR-PI-211B

4) 52-09-PR-DR-PI-156 PO4 ASTM D 515

SO3 ASTM D4327
Silica ASTM D 859
TDS ASTM D 18880
9.23 Waste gas from 1) S-5209014 H2S <10 ppm vol E 3B/C ASTM D 6228-98 S Customized
52-E0921 2) Inlet to Incinerator Stack SO2 0.03 mol% E 3B/C ASTM D 6228-98 Gaschromatograph
3) P5209027-80” (Note 4) With capillary column &
4) 52-09-PR-DR-PI-157 PFD. (Note 2)

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 SAMPLING POINT TESTING ITEM FREQUENCY
&
NORMAL FIGURE
No. STREAM NAME 1) Sampling Type & No. Test Item Normal Figure SO NO TEST METHOD SAMPLING SAMPLE REMARKS
2) Location (Note 1) METHOD CONTAINER
3) Related Line No.
4) Related Dwg No.
9.24 Blowdown water from 1) S1-520945 pH E ASTM D 1293 S1
52-E9241 2) Blow down water to 50-T3302 Cl– ASTM D 512 52-09-PR-
3) BD5209141-3” Conductivity ASTM D 1125 DR-PI-211B

4) 52-09-PR-DR-PI-158 PO4 ASTM D 515

SO3
Silica ASTM D 859
TDS ASTM D 18880
9.25 Lean solution to 52- 1) S5-520934 H2S 0.04 mol % 3/wk. SMS 2239 S5
P0903A/B 2) Outlet of 52-S0902/52-S0904 CO2 0.10 mol % E SMS 2239 52-09-PR-
3) SV5209084-10” MDEA(RFB) C SMS 2236 DR-PI-211B

4) 52-09-PR-DR-PI-164 MDEA(ATB) D SMS 2236

MDEA(TB) D SMS 2235
Total N2 E SMS 1365
pH 3/wk. ASTM E 70/90
Foaming C SMS 1327
Tendency
Total Sludge D SMS 1615
H2O E SMS 1608
9.26 Condensate from 52- 1) S2-520946 S2
V0905 2) Suction of 52-P0914A/B 52-09-PR-
3) SC5209202-10” DR-PI-211B

4) 52-09-PR-DR-PI-170A
9.27 Rich Acid Gas from 1) S3-520902 CO2 39.61 mol % SMS 2254 S3B *52AI090015 (H2S)
52-V0903 2) Rich Acid Gas to 52-V0914 H2S 60.34 mol % SMS 2254 52-09-PR-
3) AG5209001-28” H2O ASTM D 5454 DR-PI-211B

4) 52-09-PR-DR-PI-171

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 SAMPLING POINT TESTING ITEM FREQUENCY
&
NORMAL FIGURE
No. STREAM NAME 1) Sampling Type & No. Test Item Normal Figure SO NO TEST METHOD SAMPLING SAMPLE REMARKS
2) Location (Note 1) METHOD CONTAINER
3) Related Line No.
4) Related Dwg No.
9.28 Sour water from the 1) S5-520915 MDEA (ATB) E SMS 2236 S5
discharge of 2) Sour water to 50-V3304 H2S E SMS 2239 52-09-PR-
52-P0904A/B 3) PW5209036-6” CO2 E SMS 2239 DR-PI-211B

4) 52-09-PR-DR-PI-172 NH3 C SMS 1381

9.29 Flexsorb Solution 1) S5-520935 CO2 SMS 2239 S5
from 52-V0904 2) Make up solution to 52-S0905 H2S SMS 2239 52-09-PR-
3) SV5209149-4” H2O SMS 1608 DR-PI-211C

4) 52-09-PR-DR-PI-174

Notes:
1) Water & sulfur free.
2) Customized gas chromatograph with column switch, capillary column, FPD detector (flame photometric detector)
& split/splitless injection.
3) Strahman valve or equal, jacketed with 1/2 “ steam & condensate connections.
4) 3B/C = Normally every 3 days unless otherwise specified by authority regulations.

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