Midterm 2 potentially useful information

Indefinite integrals
Z
x 1 Definite integrals
sin2 (ax)dx = − cos ax sin ax
2 2a ∞
r
1 π
Z
−ax2
Z
x 1 e dx =
cos2 (ax)dx = + cos ax sin ax 0 2 a
2 2a Z ∞ r
(2n − 1)!! π
2n −ax2
Z
sin2 ax x e dx = , a, n > 0
sin ax cos axdx = 2(2a)n a
2a Z ∞0
2 n!
Z
sin (m − n)x sin (m + n)x x2n+1 e−ax dx = n+1 , a > 0, n < −1
sin mx sin nxdx = − , m2 6= n2 0 2a
2(m − n) 2(m + n) Z ∞
√ −ax
r
1 π
sin (m − n)x sin (m + n)x xe dx = , a>0
Z
cos mx cos nxdx = + , m2 6= n2 0 2a a
2(m − n) 2(m + n) Z ∞ −ax r
e π
cos (m − n)x cos (m + n)x √ dx = , a>0
Z
sin mx cos nxdx = − , m2 6= n2 0 x a
2(m − n) 2(m + n) Z ∞ √
2 2 π −b2 /4a2
sin ax x cos ax e−a x cos (bx)dx =
Z
e , ab > 0
x sin axdx = − 0 2|a|
a2 a Z b
√
r
Z
2x sin ax 2 − a2 x2 −ax2 1 π
x2 sin axdx = + cos ax e dx = erf(b a), a > 0
a2 a3 0 2 a
xm
Z Z
m
xm sin axdx = − cos ax + xm−1 cos axdx Trig identities
a a
cos ax x sin ax
Z
x cos axdx = + sin 2a = 2 sin a cos a
a2 a
Z
2x cos ax a2 x2 − 2 cos 2a = 2 cos2 a − 1
x2 cos axdx = + sin ax sin 3a = −4 sin3 a + 3 sin a
a2 a3
xm cos 3a = 4 cos3 a − 3 cos a
Z Z
m
xm cos axdx = sin ax − xm−1 sin axdx
a a
x2 1
Z
x
x sin2 axdx = − sin 2ax − 2 cos 2ax Spherical coordinate transformation
4 4a 8a
Z
x 2 x 1
x cos2 axdx = + sin 2ax + 2 cos 2ax x = r sin θ cos φ y = r sin θ sin φ z = r cos θ
4 4a 8a
Z
x 3  2
x 1

x Error function table
x2 sin2 axdx = − − 3 sin 2ax − 2 cos 2ax x erf(x) x erf(x) x erf(x)
6 4a 8a 4a
3  2  0.0 0.000 0.7 0.678 1.4 0.9523
1
Z
x x x 0.1 0.112 0.8 0.742 1.5 0.9661
x2 cos2 axdx = + − 3 sin 2ax + 2 cos 2ax
6 4a 8a 4a 0.2 0.223 0.9 0.797 1.6 0.9763
Z
eax
0.3 0.329 1.0 0.843 1.7 0.9838
xeax dx = 2 (ax − 1)
a 0.4 0.428 1.1 0.880 1.8 0.9891
Z
x m eax m
Z
0.5 0.520 1.2 0.910 1.9 0.9928
xm eax dx = − xm−1 eax dx 0.6 0.604 1.3 0.934 2.0 0.9953
a a

Constants
h̄ = 1.05×10−34 J s h̄2 = 1.11×10−68 J2 s2 h̄π = 3.31×10−34 J s h̄2 π 2 = 1.10×10−67 J2 s2
µ2 Z 2 e4 1 Z2 4π0 h̄2
En = − = −13.6 eV a0 = = 0.529 Å
(4π0 )2 2h̄2 n2 n2 µe2
 Other potentially useful information
Spherical Harmonics
` m Y`m (θ, φ)

1 1/2
 Hydrogen wave functions
0 0
4π
 1/2 n ` m ψn`m (r, θ, φ)
3
1 0 cos θ 1
 3/2
1
4π 1 0 0 √ e−r/a0
 1/2
3 π a0
1 ±1 ∓ sin θe±iφ  3/2 
8π

1 1 r
2 0 0 √ 2− e−r/2a0
5 1/2
 
2 0 (3 cos2 θ − 1) 4 2π a0 a0
16π 1
 3/2
1 r −r/2a0
 1/2
15 2 1 0 √ e cos θ
2 ±1 ∓ sin θ cos θe±iφ 4 2π a0 a0
8π  3/2
1 1 r −r/2a0
15 1/2 2 ±2iφ sin θe±iφ
 
2 1 ±1 √ e
2 ±2 sin θe 8 π a0 a0
32π  3/2 
r2

1 1 r
3 0 0 √ 27 − 18 + 2 2 e−r/3a0
Hydrogen radial wave function 81 3π a0
√  3/2  
a0 a0
2 1 r r −r/3a0
n ` Rn` (r) 3 1 0 √ 6− e cos θ
81 π a0 a0 a0
 3/2 √  3/2 
1

1 1 r r −r/3a0
1 0 2e−r/a0 3 1 ±1 √ 6− e sin θe±iφ
a0 81 π a0 a0 a0
1 3/2
   
r 1
 3/2 2
1
2 0 2− e−r/2a0 3 2 0 √
r −r/3a0
(3 cos2 θ − 1)
2a0 a0 a a 2e
81 6π 0 0
1 3/2 1 r −r/2a0
 
 3/2 2
2 1 √ e 1 1 r −r/3a0
2a0 3 a0 3 2 ±1 √ e sin θ cos θe±iφ

1
3/2 
4 r 4 r2
 81 π a0 a20
3 0 2− + e−r/3a0 1
 3/2 2
1 r −r/3a0 2 ±2iφ
3a0 3 a0 27 a20 3 2 ±2 √ e sin θe
2 3/2 1 162 π a0 a20
   
1 r r −r/3a0
3 1 √ 2− e
9a0 3 3 a0 a0
3/2
1 r2

2
3 2 √ 2 e−r/3a0
27a0 5 a0