Scrubbed GAS 100-VLV-003 Process Water In

100-T-001 Convergence Number of Trays Molar Flow (W2) Molar Flow (VAP-HCl) Molar Flow (Scrubbed GAS) Converged 10.00 1.256e+005 156.9 131.2 1.256e+005 kgmole/h kgmole/h kgmole/h kgmole/h

300-CRV-001 Separator Type Vessel Temperature Vessel Pressure Vapour Molar Flow Liquid Molar Flow Heat Flow 75.01 91.32 13.09 509.1 0.0000 C kPa kgmole/h kgmole/h kJ/h CSTR-Feed Temperature 75.01 Pressure Molar Flow 91.32 509.1 C kPa SPRDSHT-1 SPRDSHT-1

A3: pH of CSTR Feed 11.04 kgmole/h

Process Water Air* MIX-100 Slurry-Vap Air 100-VLV-004 VAP-1 200-FCV-001 Lime Slurry* 200-V-001

Combined Vapour 100-T-001

Molar Flow (Waste Liquid) Waste Liquid

R
Neutrl-Vap* RCY to Heat Recovery Lime Feed Lime Feed to Neutrl Cold Formose Feed Neutrl-Vap VLV-Vap-Neutrl 200-VLV-002 300-CRV-001 300-PFR-001 Pressure Drop 20.00 0.0000 1.0000 kPa kJ/h m3 Heat Flow CSTR-Vap Bed Voidage RCY-1 PFR-Rcy 1

Slurry from Tank

200-P-001

L-Duty

A
Temp-ADJ

Reactor Volume 0.1311

Lime Slurry Formose Feed

100-VLV-001

Fresh Feed 100-V-001

Feed from Buffer

Feed from 100-VLV-002 Buffer* 100-P-001

300-E-001 Hot Feed to CSTR-Neutr 300-E-002

300-PFR-001 E-DUTY CSTR-Feed Neutr-Feed 300-CSTR-001 PFR-Duty Steam RCY to CSTR Effluent-Vap CSTR-Product 300-P-001 PFR-Feed PFR-Prodct 300-TEE-001

A
Lime Slurry-ADJ

B-Duty

R
RCY-2

PFR-Rcy 2

Treated Effluent 300-E-001 Duty 200-V-001 Vapour Molar Flow Lime Slurry Temperature Pressure Molar Flow 40.00 150.0 0.5209 C kPa kgmole/h Liquid Molar Flow Vessel Temperature Vessel Pressure Liquid Percent Level 0.0000 0.5209 40.01 101.3 75.00 kgmole/h kgmole/h C kPa % 100-V-001 Vapour Molar Flow Liquid Molar Flow Vessel Pressure 6.887 521.7 101.3 kgmole/h kgmole/h C kPa % Tube Side Feed Mass Flow Shell Side Feed Mass Flow Tube Inlet Temperature Tube Outlet Temperature Shell Inlet Temperature Shell Outlet Temperature 6.507e+005 9615 9557 29.94 45.00 96.55 80.25 kJ/h kg/h kg/h C C C C

300-MIX-001

Effluent to Neutrl*

300-CRV-002 HCl

300-CSTR-001 Separator Type Vessel Temperature Vessel Pressure Vapour Molar Flow Liquid Molar Flow Heat Flow Liquid Volume Flow 96.84 91.32 180.7 1052 0.0000 19.19 C kPa kgmole/h kgmole/h kJ/h m3/h

SPRDSHT-2 A3: Effluent pH C3: Formaldehyde (ppm) A7: CSTR-Conversion (%) C7: PFR-Conversion(%) C10: Overall Conversion (%) 9.010 7.048e-002 86.40 99.53 99.94 SPRDSHT-2

Vessel Temperature 29.93 Liquid Percent Level 75.00

A
HCl-Adjust

Final treated Effluent to Sea

Sat Mar 12 16:52:28 2011 \\FS-WEBDAV.CRANFIELD.AC.UK@SSL\DAVWWWROOT\USERS\SOE\S146289\PROCESS SIMULATION OF THE FORMOSE PLANT.HSC Case: Flowsheet: Case (Main)