DK-2800 Lyngby, Denmark

Petrobras - Petrleo Brasileiro S.A. Refinaria do Nordeste - RNEST Hydrogen Generation Unit - U-35

No. 4307085 Rev. 0 Job S-01411 Page 1 of 2 Clients Doc. No. I-FD-5290.00-2311-941-HTP-007 WBS 44

Job S-01411

Specification for Catalyst

Rev.

Description

Date

Made by

Chd.

Appd.

First issue

11-SEP-2007

KRLI

SKA

ORJ

Information contained herein is confidential and must not be used by or conveyed to any third party without our written authorisation - Haldor Topse A/S

DK-2800 Lyngby, Denmark

Petrobras - Petrleo Brasileiro S.A. Refinaria do Nordeste - RNEST Hydrogen Generation Unit - U-35

No. 4307085 Rev. 0 Job S-01411 Page 2 of 2 Clients Doc. No. I-FD-5290.00-2311-941-HTP-007

1. Specification for Catalyst This specification covers the catalysts required for the hydrogen production unit.
Service of Equipment Reactor No. Topse Catalyst Type Hydrogenation Sulphur absorber Pre-reformer Steam Reformer MT Shift Converter R-35001 R-35002 R-35003 R-35004 R-35005 TK-250 HTZ-5 RKNGR R-67-7H LK-811 LK-813 LK-811 Particle Size, mm 5, rings 4, extr. 11 x 6 20 x 18 4.5 x 4.5 4.5 x 3.4 4.5 x 4.5 Catalyst Loaded, m
3

Expected Lifetime, Years

1)

Guaranteed Lifetime, Years 1) 3 3 3 3

14.0 45.3 23.6 37.5 4.8 29.6 39.6

2) 3)

6 3 4.5 10

1)

8,500 operating hours per year. The hydrogenation catalyst volume has been calculated based on hydrotreated naphtha feed with maximum organic sulphur content of 10.1 ppm wt. (28.4 ppm vol., calculated as sulphur). The sulphur absorber catalyst volume has been calculated based on deaerated hydrotreated naphtha feed with an average sulphur content of 15 ppm wt. (42.2 ppm vol., calculated as sulphur).

2)

3)

Information contained herein is confidential and must not be used by or conveyed to any third party without our written authorisation - Haldor Topse A/S