Worksheet 3.6 Solving Numerical Problem Part A 1. Pb(NO3)2 compound decomposes when heated as shown in the following equation.

2Pb(NO3) 2PbO +4NO2+O2 If 6.62g of the compound is heated. Calculate the mass of PbO and 2Pb(NO3) 2PbO + 4NO2 + O2 From equation: 2 mol 2 mol 4 mol 1 mol, 22.4dm3 From question: 6.62g x mol y dm3 Use ratio : Find the no. of mole of Pb(NO3)2 :6.62 g / 331(RMM of Pb(NO3)2 = 0.02 mol From the equation, 2 mol of Pb(NO3) decompose to form 2 mol PbO Thus, 0.02 mol Pb(NO3)2 x mol PbO Therefore, mol of PbO = 0.02 mol Pb(NO3)2/2 mol Pb(NO3)22 mol PbO = ___________ mol Mass of PbO = 0.02 mol 223 (RMM of PbO) gmol = ________ g ii. Use ratio volume of oxygen at stp that is produced (1 mol of gas occupy 22.4dm3 at s.t.p.) : From the equation, 2 mol of Pb(NO3) decompose to form 1 mol O2 Thus, 0.02 mol Pb(NO3)2 y mol Therefore, mol of O2 = 0.02 mol Pb(NO3)2/2 mol Pb(NO3)21 mol O2 = ___________ mol Volume of oxygen = 0.01 mol 22.4 dm3mol (s.t.p) = ____________ dm3 2Fe2O3(s) + 3C(s) 4Fe(s) + 3CO2(g) The reaction between iron (III) oxide and carbon is represented by the above question. Calculate the maximum mass of iron obtained when 20g of iron(III) oxide is reduced by carbon. (RAM: O:16 Fe:56) i.

2.

Solution:

3. 10g of excess copper(II) oxide powder is reacted with 0.1 mole of sulphuric acid to produce copper(II) sulphate and water. (a) Write a balanced chemical equation for the reaction (b) Calculate the excess copper(II) oxide left after the reaction.

(c) Calculate the maximum mass of copper(II) sulphate formed. (RAM: O:16, S:32, Cu:64)

Part B Answer the following question: 1. Calculate the maximum mass of magnesium oxide formed when 6 g of magnesium is completely burned in air. (RAM O:16, Mg: 24) 2. Table 2 shows the positive and negative ions in the three salts solutions. Negative ion Chemical formula of salts 3NO SO42ITable 2 a. Complete Table 2 by writing the chemical formulae of the three salts b. Write a chemical equation for the reaction between lead nitrate solution and potassium iodide solution. c. What is the mass of the precipitate formed if 0.5 moles of an aqueous solution of potassium iodide is added to excess lead(II) nitrate solution? (RAM:Pb: 207, I:127) Positive ion Pb2+ Cu2+ K+