Corrosion Resistant Materials Handbook

CORROSION RESISTANT MATERIALS HANDBOOK
Fourth Edition
Edited
by
D.J. De Renzo
NOYES
DATA
CORPORATION
New Jersey, U.S.A.
Park Ridge,
Copyright G 1985 by Noyes Data Corporation No part of this book may be reproduced in any form without permission in writing from the Publisher. Library of Congress Catalog Card Number: 854872 ISBN o-8155-1023-3 Printed in the United States Published in the United States of America Noyes Data Corporation Mill Road, Park Ridge, New Jersey 07656 1098765432 by
Library of Congress Cataloging Main entry under title: Corrosion
in Publication
Data
resistant materials handbook.
Rev. ed. of: Corrosion resistant materials handbook I lbert Mellan. 3rd ed. 1976. Includes indexes. 1. Corrosion resistant materials--Handbooks, manuals, etc. I. De Renzo, D.J. II. Mellan, Ibert. Corrosion resistant materials handbook. TA418.75.C67 1985 620.11223 85-4872 ISBN o-8155-1023-3
NOTICE
To the best in this does of our not knowledge is assume any the information however, conthe
tained publisher for
publication
accurate; liability
whatsoever
the accuracy or completeness of the suitability for
of such information. of any information by any user, and of the in this to rely on
Final determination or product user. any
the use contemplated that anyone of materials himself
the manner of that use, is the sole responsibility We recommend recommendation should intending mentioned
publication and that standards. structions
satisfy
as to such suitability, and health current inthat users seek and
he can meet all applicable safety We strongly recommend manufacturers or suppliers
adhere to the
for handling each material they use.
Contents
SYNTHETIC 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 1.10 1.11 1.12 1.13 1.14 1.15 1.16 1.17 1.18 1.19 1.20 1.21 1.22 1.23 1.24 1.25 1.26 1.27 1.28 1.29 1.30 1.31 1.32 1.33 1.34 1.35 1.36 1.37 1.38
RESINS ABS Jackets ABS/PVC
AND Alloys-A.
POLYMERS. Schulman
................................................ .............................................
.1 .I
and Covers-CEEL-CO
................................................ Acetal Copolymers-Celanese Plastics ............................................ Acrylic Resins-Rohm and Haas. ...............................................
Acrylic Cellulose Chlorinated Epoxy Epoxy Epoxy Epoxy Resin-Sohio Acetates, Polyvinyl Chemical. Butyrates, Chloride ................................................ Propionates-Eastman Pipe and Fittings-B.F. ................................................. Chemical. Goodrich ...........................
.2
.3 .6 .9 10
.........................
.27
.32
Compounds-Devcon Pipe and Fittings-Ameron Resin-Duriron Resins-Shell Reinforced Reinforced Reinforced Reinforced
............................................. ..................................................... Chemical ................................................

Epoxy Furan and Vinyl Ester Piping and Vinyl Systems-A.O. Ester-Morrison Plastics. Smith-Inland .......................... Molded Fiber Glass.
Fiberglass Fiberglass Fiberglass Fiberglass
.............. .......
.33 .34 .35 .37

.39 .47
Polymer-Quaker Polyester
Oats Chemicals.
lsophthalic Polybutylene
...................... .................................... Fiberglass Reinforced Polyester Panels-Resolite Fluoropolymer-Allied Engineered Plastics. ........................................ ............................ Furan Resin-Koch Engineering, Maurice A. Knight Division .......................................... lsopolyester Resins-Amoco Chemicals Nylon 6/6 Resins-Celanese Plastics ............................................ .................................................... Nylon 11 Resin-Rilsan .......................... Nylon Reinforced Vinyl Hose-Sethco Division, Met Pro Corp. .............................. Oxirane Oligomer of Resorcinol-Plastonics International
Terephthalate-Celanese Phenolic Phenylene Resins-Occidental Oxide-Based Chemical. Resin-General .......................................... Electric.
.52 .53
54
.60 .61
.63 .65 .67 .68 .95 102 104 106 107 108 110 111 112
.................................... ........................................ Polyallomer-Eastman Chemical Products .............................................. Polycarbonate-Mobay Chemical ...................................... Polyester Engineering Resin-Dart Industries Polyester Laminates-Haysite Reinforced Plastics ...................................
Polyether Block Amides-Rilsan. Chemical Ethylene-Vinyl Material-Nalge. Polyethylene-Eastman Polyethylene-Himont Polyethylene-Lined Polyethylene Polyethylene Polyethylene Polyphenylene Tank .............................................. ....................................... Products. Acetate Tubing-Thermoplastic Scientifics Inc
..................................................... ..............
Chemicals.
113 114 116
Resins-U.S.I.
..........................................
Chemical Products .................
............................................ Copolyester-Eastman
Terephthalate-Based Sulfides-Phillips
116 118 120
Polymethylpentene-Westlake
Plastics.
.......................................... Chemical ........................................

vii
VIII
Contents
1.39 1.40 1.41 1.42 1.43 1.44 1.45 1.46 1.47 1.48 1.49 1.50 1.51 1.52 1.53 1.54 1.55 1.56 1.57 1.58 1.59 1.60 1.61 1.62 1.63 1.64 1.65 1.66 1.67 1.68 1.69 1.70
.................................... ........................................ ......................... Polystyrene Resins-Huntsman Chemical ............. Polysulfone-Union Carbide ............................................... Polyvinyl Chloride Ducts-Dayco ............................................ Polyvinyl Chloride Jackets and Covers-CEEL-CO ................................. Polyvinyl Chloride Liners-Fabrico. .......................................... Polyvinyl Chloride Pipe and Fittings-Thermoplastic Processes. ........................ ................................ Polyvinyl Chloride Tank Liners-Peabody Tectank.
Polypropylene-Eastman Chemical Products. Polypropylene Resins-Shell Chemical. Polyvinylidene Tetrafluoroethylene Fluoride-Rilsan. Hose-Everflex ............................................ Products
120 122
. 142
147 . 149 151
. 152 . 154 . 155

155
.................................... Tetrafluoroethylene Resins-Du Pont ......................................... Vinyl Ester Resins-Interplastic Corp. ......................................... Epoxy and Polyester Pipe and Fittings-Ameron ..................................
Phenol-Formaldehyde Polyester Acetal, Epoxy, and Vinyl Nylon Polypropylene and Furfuryl Ester Alcohol-Formaldehyde Fluoride Lined Piping Resins-Ametek, Systems-Resistoflex. Haveg Division.
. 156 . 157
. 159 . 170
....
174 179
Resins-Ashland. Resins-Du and Bisphenol
..................................... ............. Pont .................................... ........................... Resins-Duriron.

A Polyesters, and Vinyl Ester Resins-Amoco Chemicals . .................................. Fabrications-Atlas.
and Polyvinylidene and Polyester Halogenated SAN
Fluoropolymer
and Polyethylene
Isopolyester, Polystyrene, Polyvinyl Vinyl, Various Various Various Various Various Various Various Various Various Silicone
and ABS Plastics-Monsanto. Polypropylene Tubing-Barnant
Chloride,
and Polyethylene
.................
and Fluoroelastomer
Glass-Reinforced Polymers-Westlake Resins-General
.............................. Resins-Celanese Plastics ................................ Plastics ..........................................

............................................ for Linings and Membranes-Atlas. Chemical
. 218 . 220 .221 . 223 . 225 . 236 . 238

. 239 239 . 240
Electric
Resins and Elastomers Resins for Membrane Resins for Plastic Thermoplastic Thermoplastic
Resins and Metals-Phillips Lined
...................... .................................... ................................ Linings-Watersaver.

Piping for Products-Dow Piping Chemical Rubber ....................... ....................... Materials-Nibco.
. 242 . 247
250
and Elastomeric Polymers
Hose Stocks-Gates
....................... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... . . .
. 251 . 263 . 272

284 284
RUBBERSANDELASTOMERS 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 2.10 2.11 2.12 2.13 2.14 CEMENTS, 3.1 3.2 3.3 3.4 3.5 3.6 3.7 Acrylic
.......................... Cyanamid
.............. .................. Fluoroelastomer-Elkhart Rubber. ............... Fluorosilicone Rubbers-Dow Corning. ................ Polysulfide Rubber-Morton Thiokol
Elastomer-American Polysulfide Synthetic Elastomer Rubber Cyanamid Sealant-Stonhard. Chemicals Linings-Huron ............................ Limited. Cyanamid. Pont.
.285 . 287
. 290 . 293 294 . 296 . 297 . 297 .298 . 299 . 302
Silicone
........ Ltd ........
Urethane-American Urethane-Devcon. Urethane Various Various Various Various Various
.................... ..............
.............
Membrane-Sternson Elastomers-American Elastomers Elastomers Elastomers Rubber
and Rubbers-Du and Rubbers-Exxon and Rubbers-Minor Tank
............ ...... Co. ......
Chemicals. Rubber
and Elastomeric AND ASPHALT Surfacing
Linings-Acme-Fisher.
.355 . 367 ..........

.......... .......... 369 369
373 375 379 382 383 383
MORTARS, Epoxy-Base Epoxy Epoxy Epoxy Furan Furan Mortar Flooring
Floor
Systems-Stonhard
Compounds-Atlas. and Floor Cements-Sternson.
. .. . . . . . . . . . . . . . .. . . . . . . . .
. .
.. .. . . . . .. . . . . . . . . . .. .. .. . . .
Toppings-Pennwalt
.......... .......... ..........
Surfacing Grout-Atlas Polymer
. . . . . . . .
Concrete-Quaker
Oats Chemicals
. . .
. .. . . . . . . . . . . .
.......... ..........
Polyester
Grout-Radiation
Technology.
. .
. .
Contents
ix
3.8
3.9 3.10 3.11 3.12 3.13 3.14
Sulfur
Concrete Asphalt
and Coating-Sulcon Membrane-Pennwalt. Flooring
Systems.
......
Urethane Polyester Various Various Various Various
.......... ....
and Epoxy Cements-Atlas
Compounds-Atlas
..................... ............. Mortars-Koch Engineering Mortars-Pennwalt ................... Mortars-Sternson ...................

........................................... Alloy-Allegheny Stainless Stainless Ludlum. Steels-Jessop Stainless Wrought Stellite
...... ...... ...... ...... ...... ...... ......
. . . . . . . . . .
. . . . . .. . . . . . . . . . .
....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... . . . . ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... ....... .......
. . . .. . . . . .. . .
384 387 388 389 391 399 406
FERROUSALLOYS 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9 4.10 4.11 4.12 4.13 Austenitic Austenitic Ferritic
Steels-Allegheny
......................... Steel. ....................... Ludlum .....................

Wrought Products
Ferritic-Austenitic Iron Alloy-Cabot Iron ironAlloys-Cabot
Steel-Cabot Products. Division
..........
. . . . . . . . . . .
. . .
412 412 413 414 420 424 425 426 428 429 431
......................... ..........................
Foundry & Engineering .................. Molybdenum
and Nickel-Base Steel-Armco Duplex Stainless Stainless Stainless Stainless METALS
Alloys-Stainless Stainless Stainless
........ ....
Stainless Various Various Various Various Various
Steel Products. Iron and Steel Technology.
. . . . . . . . . . . .
and Austenitic Steels-American Steels-Carpenter Steels-Cyclops
Steels-Climax
Institute.
..........
.................. ............................
Nickel Alloys-Climax Molybdenum.
Steels and High AND ALLOYS.
...
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . ..
433 440 444
NONFERROUS 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 5.10 5.11 5.12 5.13 5.14 5.15 5.16 5.17 5.18 5.19 5.20 5.21 5.22 5.23 5.24 5.25 5.26 5.27 5.28 5.29 5.30 5.31 5.32 5.33
Aluminum Aluminum Aluminum Aluminum
....................... ............................ ................ Alloys-Aluminum Association.

Alloy-Alcoa. Bronzes and Nickel-Aluminum Bronzes-Ampco Metal
Aluminum-Zinc
........................... Steel ................. Beryllium Copper Alloy-Brush Wellman .................. ...................... Cobalt-Base Alloys-Cabot Stellite
Coating-Alcoa Coating-Bethlehem Alloy-Cabot Alloys-Wall Wrought Colmonov Products. ...............
Cobalt-Base Cobalt-Base
..................... Columbium-Cabot KBI ............................. ................ Columbium-Teledyne Wah Chang Albany. Copper Alloys-Revere. .............................
Copper and Copper Alloys-Arco Chemical Metals, Industries American Association. Alloys Brass Lead and Lead Alloys-Lead Magnesium-Dow Nickel Nickel-Base Nickel-Base Nickel-Base Nickel-Base Nickel-Base Nickel-Base Tantalum-NRC Tantalum Titanium-Industrial and High-Nickel Alloy-Teledyne Alloys-Cabot Alloys-Stainless Alloys-Wall and Other Rods,
. . . . . . . . . . . . .
....... ..........
........................... ...........
Allvac Wrought Foundry
Alloys-Huntington Products
.....................
............... & Engineering.
. . . . . . . . . . . . . . . .. . . . . .. . . . . . . . . . . . .. . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . .
.........
Industries
Colmonoy High Alloy
.....................
Pipe and Tubing-Colt Stellite. KBI
Electrodes
and Wires-Cabot Alloy-Cabot
........ ........
..................................
Titanium.
and Tantalum-Columbium
........................ ................... Titanium and Titanium Alloys-Timet. Zinc Alloy-New Jersey Zinc. .........................
Zinc Coating-Alcoa. ............................... Wah Chang Albany. Steel Alloys-Cabot Alloys-Carpenter Zirconium Alloys-Teledyne Nickel Steel, and Stainless Nickel
. . . . . . . . . .
............
Stellite.
Tungsten Cobalt, Stainless Titanium,
and Molybdenum-Schwarzkopf and Copper
Development.
....... ....... . .......
Technology.
.. . . . . . . . . . . . . . . . . . . . . . . . . .
.. . . . . . . . .
Zirconium
and Tantalum-Astro
Metallurgical.
609 609 610 632 633 638 639 643 644 645 646 647 648 649 655 663 664 665 666 725 728 729 730 731 732 735 736 742 744 749 756 756 757 764
Contents
5.34
5.35 5.36 5.37 GLASS, 6.1 6.2 6.3 6.4 6.5 6.6
Tungsten, Various Various Various CERAMICS,
Tantalum Metals Metals Metals AND
and Titanium
Carbide
and Alloys-Duriron and Alloys-General and Alloys-Walworth CARBON-GRAPHITE. Graphite.
Alloys-Kennametal ............. ............................... Metals Technologies. ................. .............................. . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . .. ..
. .
. 771 . 773 ,777
. . . . .. . . . . . . . . . . . . . . . . . . . . . .
. . .781 . . . 786 . . 786

. . . 790 .791 . 792 . . . 792 . 793 .796 796
..... ........ Ceramic Fiber Products-3M. ......... Ceramic Linings-Abresist. ...... Foamed Glass Block-Pennwalt .............. Glass Pipe-Corning ........... Glassed Steel-Pfaudler.
Carbon-Graphite-U.S. RESISTANCES Aluminum and Steel Carbon, Institute. Ceramic, OF MATERIALS
. . .. . . . . . . . . .
COMPARATIVE 7.1 7.2 7.3 7.4 7.5 7.6 7.7 7.8 7.9 7.10 Steel, Iron Metal, Rubber, iron, Iron,
OF CONSTRUCTION Plastic Tank
........................ Materials-American
and Glass Fiber Rubber,
Reinforced Plastic
Construction
................................................... and Wood Construction and Wood Materials-ITT Aluminum and Brass Couplers-Gates Pump ............ Materials-Corning ................... Rubber. Lining Cylinder Materials-Gates ................ Rubber. Jabsco.
797 809
Polymeric
Hose and Steel, Resin, Steel, Steel,
Aluminum, Synthetic Alloys
Lead, Glass, Concrete Resin and Rubber for Castings
.. 821
839 846 848 854 882
Bronze, Nickel
.................. ............................. Various Resin, Elastomer and Steel Tank Materials-Nalge. .............................. Metal, Elastomer and Plastic Pump Materials-Oberdorfer ...................... Glass, Metal and Plastic Piping Systems-0-I/Schott Process Systems.
and Copper and Forgings-Janney Natura! and Synthetic Alloy, System Fibers, Titanium, Porous Ceramic, Stone or Porous Natural Carbon Filter Tube Materials-Sethco. Pump and
......
884 885 889
7.1 1 Resin, Steel, Filtration 7.12 7.13 COMPANY Plastic
Rubber,
and Synthetic ............................... Heating
Fiber
Materials-Sethco Columbium LISTING
...........................................
and Tantalum . . and Cooling . . Coils-Vulcanium . . . .....
and Steel Pump
Materials-Thompson-Chemtrol.
Steel, Titanium, NAME AND
Zirconium, ADDRESS
891
. . . . . .
. . . . . . . .
. . . . . . . . . . . .892
TRADENAMEINDEX CORROSIVE MATERIAL
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...897 INDEX. . . . . . . . . . . . . . . . . . . . . . . . . . . . .900
Foreword
The ful the cially to ment
fourth reference concerned
edition expanded, volume,
of the first
Corrosion published resistant
Resistant in 1966, to cut materials for
Materials technical will provide
Handbook data. useful
has been completely information by choosing which suitable materials will
revised enable
and vastly
based on the latest available or manager and others
This well-established
and successcommerfor equip-
engineer corrosion designers specific
losses due to corrosion a particular screening guide
available having
application.
It would
also be useful
equipment
as a valuable
in choosing
corrosion
resistance
requirements. work tables Index to lies in the extensive in the book is organized by cross-indexing of thousands and other A separate
The great value of this outstanding of substances. resistant corrosive Trade The alloys; presents mercial sent from, The more The than materials. substances. Corrosive the
reference Material reader
160 detailed
are arranged corrosive
by types of corrosion chemicals
It refers
specific
recommendations
in the tables.
Name various
Index and a Company sections resins of taken in the book
Name and Address cover rubbers selected
Listing are also included. of corrosion cements, resistant materials, such ferrous section of comrepreinfluence
categories
as synthetic
and polymers; metals 13 tables directly
and elastomers; the
mortars,
and asphalt; A separate in the book to, nor
nonferrous a group engineering the makers
and alloys; which from
and glass, ceramics, compare materials essential
and carbon-graphite. merits made to industry. The tables at no cost
anticorrosive literature
of a cross section
and construction or distributors of information
selections
manufacturers
of these materials. contained indexes. in the book is evidenced at once in the extensive table
The vast amount of contents
and the exhaustive
Advanced composition and production methods developed by Noyes Data Corporation are employed to bring this durably bound book to you in a minimum of time. Special techniques are used to close the gap between manuscript and completed book. In order to keep the price of the book to a reasonable level, it has been partially reproduced by photo-offset directly from the original material and the cost savings passed on to the reader. Due to this method of publishing, certain portions of the book may be less legible than desired.
Synthetic
Resins and Polymers
TABLE
1.1:
ABS JACKETS
AND
COVERS-CEEL-CO
Typical
Resistance
Features
of CEEL-TITE
100 Series
Acetrc Acrd. I %, 30 days Acetic Acrd. 50%. 30 days Acetrc Acrd. concentrate Acetone, 10% Alummum Sulfate, 25% Ammonra Gas Ammonrum Hydroxrde Beer (over 3 2% alcohol) l Benzaldehyde Concentrate *Benzene l Benzyl Ether Bromrne l Bromoethane Butane Butyrrc Actd Calctum Chloride. 25% Calcrum Sulfa!e, 25% solutron Carbon Droxrde Carbon Tetrachlonde l Chlorobenzene Chloropropane Chromrc Acrd, 30% Citrrc Acrd, 25% Cod Lrver 011 Collordal Sulfur, 30 days, 140F Corn 011 Cyciohexanol l Cyciohexanone Detergent Drethanolamtne. 30 davs. 140F Dtethylene Glycol Diethyl Ether Drethyl Ketone Ethyl Acetate Ethyl Alcohol. 50% Ethylene Gfycol. 30 days, 140F Ferrol 1s Sulfate, 25% Form: Ildehyde, 30%. 30 days *Freon 11 Freon 12
S
U S
Gasorne Glucose, 30 days. 30% 146F Gfycerrn, 30 days, 140F Grapefrurt Jutce 30 days Heptane. 30 days l Hexane Hydrochlonc Acrd, 30 days Hydrogen Peroxide. 3% Kerosene, 30 days Ltght Process Ori. 30 days : 40F Liquid Wrench *Methyl Ethyl Ketone Mrnerai Spirits. 18 months Motor 011. 6 months Naphtha (lighter fiurd) 3 months Paratftn, 30 days l Pentane *Phenol Phosphonc Acid. 30 days Phosphonc Acid, 30 days 140F Potassium Chloride, 25% Potassrum Hydrox\de. Saturated sol&on 30 davs. 146F Red Copper Oxrde. 30 days 140F Sodrum Brcarbonate Solutton 30 days, 140F Sodrum Chlonde Solutron, 30 days. 140F Sulfunc Acid, 50% 30 davs Syrup. SrmpleSugar Tomato JUICP Tnsodrum Phosphate Ucon M-l@ Hydraulic Flurd 7 days. 160F Unc Acrd. 30 davs Vtnegar Frim Remover
z
S ; :
s
U s S S il U S U S
S S S S
s s
Z Z
S -Satisfactory U - Unsatfsfactory Test Method ASTM D 543 72
l Satisfactory
atmospheric @-
for use under conditions Trademark
Regtstered
Corrosion Resistant Materials Handbook
TAB.LE 1.2: ABSIPVC ALLOYS-A.
SCHULMAN
A special outdoor rigid polymer alloy, POLYMAN 507 retains more impact strength after UV exposure than any competitive material according to UL recognition tests. It is rated UL Bulletin 94 V-O and carries 95C continuous use temperature rating. In addition it offers the good electrical properties and tensile strength needed for wiring devices and small tool housings. A rigid polymer alloy, POLYMAN 509 exhibits low shrinkage (0.0045 in/in) and combines a 212F heat distortion temperature with a superior 430,000 flexural modulus to mold and hold strict dimensional tolerances in critical fit applications such as printed circuit card holders. Its high arc track resistance and compressive strength, along with a good balance of other properties, qualifies for applications in severe electrical service such as junction boxes and connectors. POLYMAN 511 offers the highest impact strength (83.5 tensile impact; 320 in lb Gardner impact) of the POLYMAN UL V-O rated rigid polymer alloys. It also has excellent UV color stability along with the exceptional stiffness and flatness required for large business machine and consumer appliance housings.
POLYMAN
507, 509, 511 Chemical Resistance
Class S-Satisfactory (only minor absorption) Class A-Surface affected only slightly; still performs mechanically Class P-Poor resistance; not recommended exposure
CLASS
Linseed Oil Mineral Oil Motor Oil Nitric Acid, 40% Olive Oil Potassium Hydroxide, 50% Sodium Carbonate Sodium Hydroxide, 50% Sulphuric Acid, 97% Ammonia, 30%
s
Brine Solution Clorox Citric Acid 2N Gasoline Glacial Acetic Acid Hexane Hydrochloric Acid, 30% Hydrochloric Acid 2N lgepal Lactic Acid 20%
CLASS A Chloroform Chromic Acid 30% Ethyl Alcohol Formaldehyde, 35% Formic Acid (Anhydrous) Glycol Isopropyl Alcohol Oxalic Acid 50% Phosphoric Acid, 85% Silicone Oil Turpentine
CLASS P Acetone Benzene Carbon Bisulfide Carbon Tetrachloride Ethyl Acetate Methyl Ethyl Ketone Toluene Xylene
NOTE: For solvent welding, use such solvents as: Perchlorethylene with Cyclohexanone Tetra Hydrofurane with M.E.K. For vapor degreasing, use such agent as: Freon TE with Alcohol
Synthetic
Resins and Polymers
TABLE
1.3: ACETAL
COPOLYMERS-CELANESE
PLASTICS
CELCON trioxane.
is a registered trademark of the Celanese Corporation used for its crystalline CELCON acetal copolymer can be injection molded, blow molded, extruded,
acetal copolymer
based on
machined. CELCON acetal copolymer offers high mechanical strength through broad ranges of temperature and environment. Celcon Grade Formulation
UlO-11
strength,
stiffness,
rotationally cast and easily toughness, and practical impact
Range Application
Melt Index
Description
1.0
Excellent processabillty in extrusion blow moldtng. injection blow molding and extrusion. High melt strength. Low odor grade for aerosols.
Aerosols, containers, industrial articles, rod, tube, slab, profiles.
M25-01
2.5
Excellent processability Not lubricated.
in extrusion.
Rod, tube, sheet, slab, wire coating
M2504
2.5
Good processability for injection molding in easy-to-fill molds. Possesses greater toughness and elongation than materials with 9.0 melt index. Same as M25-01 except that it is internally lubricated.
Injection molded parts requiring timum toughness and elongation.
op
M90-04
9.0
Excellent moldability due to high flow characteristics and stabtlity in processing High surface gloss and good dimensional stability. Internally lubricated. Ultraviolet stabilized. Good maintenance of physical properties and resistance to chalking in outdoor exposures.
General injection molding.
M90-08
9.0
Injection molded plications.
seasonal
outdoor
ap-
M270-04
27.0
Highest flow. Superior moldability for hard to fill molds with somewhat less toughness than M90. Internally lubricated. Celcon color Concentrates are provided in a wide range of standard colors for letdown into natural Celcon via extruinjection molding sion or screw machines. M90 Resin reinforced with 25% by weight of glass fibers together with a unique coupling agent. Provides increased stiffness, tensile strength and creep resistance.
H.igh speed injection cavity parts.
molding
for multi-
M90-07
To obtain body colored injection molded or extruded products at cost savings.
GC-25A
2.5
Windshield wiper pivots, gears, pulleys and other parts requrring the maximum in stiffness and strength.
(continued)
TABLE 1.3: ACETAL
COPOLYMERS-CELANESE Chemical
Time
PLASTICS of Celcon
Yield
(continued) M90, M25, M270 o:c Change Vwble Effect3 N.C. Disc. DISC. Disc. N.C N.C.
Resistance
Temp
Matenal Control (Air) INORGANIC 10% Ammonium CHEMICALS Hydroxide
Months 12 6 12 6 6 12 6 6 6 12 : 12 6 6 6 12 6 12 6 6 6 6 6 12 6 6 4 6 12 12
F 73 73 73 180 73 73 73 73 73 73 180 73 73 180 180 73 73 73 73 180 180 73 180 73 73 73 180 180 180 73 73 180
Strength 0 0 0.7 -0.3 : X X 2 3 4 0 6 3 3 1 2 1 -2 -3 -3 -6 3
Tensile Modulus 0 0 -16 -12 -15 -12 X X -12 -15 -10 -9 -9 1; 2 2 -8 1; -6 -7 -12 -8 -14 X -15 -12 X -12 -12 -18
Length 0 0.3 0.3 0.4 0.3 0.3
Weight 0.22 0.88 1.03 0.74 0.97 0.88 X X 0.59 0.71 0.49 0.77 0.78 0.96 0.61 0.80 0.84 0.49 0.73 0.83 -0.18 -3.29 0.61 0.81 0.82 X 0.94 0.89 X 0.83 0.84 -3.32
3% Hydrogen Peroxide 10% Hydrochloric Acid 10% Nitric Acid 10% Sodium Chloride
2% Sodium Carbonate
20% Sodium Carbonate 1% Sodium Hydroxide 10% Sodium Hydroxide
60% Sodium Hydroxide 4-6% Sodrum Hypochlorite 26% Sodium Thiosulfate 3% Sulfuric Acid 30% Sulfuric Acid Buffer, pH 7.0 Buffer, pH 10.0 Buffer, pH 4.0 Water (Distilled)
0.2 0.2 0.2 0.2 0.2 0.4 0.2 0.2 0.2 0.2 0.2 0.2 -0.1 0.1 0.2 0.4 0.2 X 0.3 0.3 X 0.2 0.2 -0.1
N.C. SI. Disc. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. SI. Disc. St. Disc. Pitted N.C. N.C. N.C. SI. Disc. SI. Disc. N.C. N.C. Disc.
ORGANIC CHEMICALS 5% Acetic Acid Acetone
Aniline Tint Benzene Carbon Tetrachloride
6 12 6 12 6 6 6 6 12 : 12 6 6 6 12 6
3: 73 73 120 180 120 73 73 120 73 73 73 180 73 73 120
-1 0.6 -4 -17 -19 -26 -17 -1 2 -11 0 3 -15 -19 -5 -17 -22
-15 -16 -20 -48 -48 -73 -43 -4 -6 -32 -12 -10 -26 -63 -20 -46 -50
0.3 0.2 0.7 1.6 2.1 4.8 1.8 0.2 0.1 1.2 0.3 0.2 1.1 3.1 0.6 1.6 2.1
1.05 1.13 3.60 3.68 4.45 12.1 3.93 0.86 1.39 5.23 0.74 1.93 2.09 7.7 3.62 4.25 5.23
N.C. N.C. N.C. N.C. N.C. Reddish N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. (continued)
10% Citric Acid Diethyl Ether Dimethyl Formamide Ethyl Acetate
Synthetic
Resins and Polymers
TABLE 1.3: ACETAL
COPOLYMERS-CELANESE Time Months 6 6 6 12 6 6 12 6 6 12 6 6 12 6 6 12 6 12 6 Temp F 120 180 73 73 120 73 73 120 73 73 180 73 73 180 73 73 73 73 180
PLASTICS Yreld Strength -23 0 1; -17 -4 -5 -13 -2 3 -6 -1 3 0 -15 -10 -7 -7 -14
(continued) __~ O0Change TenslIe Modulus -68 -18 -19 -35 -31 -24 -32 -34 -13 4 -9 -15 -i -45 -46 -17 -19 -43 Length 3.2 0.4 0.6 0.7 1.3 0.6 0.7 1.0 0.2 -0.07 0.2 0.3 -0.04 0.5 2.1 1.4 0.4 0.7 16 Wetght 10.05 1.33 1.43 2.19 2.54 1.62 1.98 2.27 0.04 0.09 0.35 1.05 -1.26 1.04 9.34 4.70 1.12 1.87 3.80 Vwble Effect3 N.C. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N C. N.C. N.C. N.C. N.C. N.C. N.C. Disc. N.C. N.C. N.C
Materral Ethylene Dichloride 50% Ethylene Glycol 95% Ethanol
50% Ethanol
Heptane
Oleic Acid
5% Phenol Toluene
OTHER
MATERIALS Fluid 6 6 6 12 6 12 6 6 6 6 : 12 6 : 6 6 6 6 6 6 6 12 6 6 12 6 180 180 73 73 73 73 180 180 180 180 180 73 73 180 180 180 120 120 120 180 180 180 73 73 180 73 73 180 5 0 0 3 -3 -0.5 -11 -5 2 3 3 18 3 0 I;
-11
Automatic Transmission Anti-Freeze (Telar) Brake Fluid, Super 9
Brake Fluid, Lockheed 21
Brake Fluid, Delco 222 Detergents Acclaim Calgonite Electra-Sol 50% lgepal
5 -23 -12 -1 -13 -9 -41 -33 -11 -15 -10 -14 -15 -18 -20 -15 -12 -12 -10 -7 11 3 -14 -1 7 -9 7 0
-0.07 0.6 0.3 0.2 0.3 0.2 1.4 1.3 0.2 0.3 0.3 0.4 0.4 0.7 0.4 0.5 0.7 0.7 0.7 0.3 0.2 0.2 0.2 -0.06 0.0 0.2 -0.06 -0.06
-0.15 1.53 0.34 0.53 0.70 1.05 3.60 3.18 0.85 1.00 1.04 0.75 0.84 1.62 1.04 1.32 1.30 1.50 1.43 0.34 -0.13 -0.03 -0.03 0.05 -0.18 0.02 0.04 -0.14
N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. SI. Disc. SI. Disc. N.C. N.C. N.C. N.C. SI. Disc. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C. N.C.
Detergent Solution2 1% Soap Solution Gasolines Mobil Regular (9315 Octane) Mobil Hi-Test (99.0 Octane) Sunoco 280 (103 Octane) Kerosene Linseed Oil Lubricating Grease Mineral Oil (Nujol)
Motor Oil (1 OW30)
-12 -6 0 8 4 -3 3 8 -1 5 5
1. Type 1 TenslIe bars used nnthese tests measure 8!5 x % x / Inches. rutlal yleld strength IS 8800. tenslle modulus 410,000. weight 13 grams 2 Cowsts of 0 5 grams of an alkyl sulfonate + 0 20 grams of trisodlum phosphate per liter of water N C. = No Change; DISC = Dlscoloratlon. SI DISC = Slight discoloration
3 X = Not recommended,
TABLE
1.4: ACRYLIC
RESINS-ROHM
AND HAAS
0,
PLEXIGLAS is the registered trademark for acrylic plastic sheet produced by Rohm and Haas Company. In its natural tically clear, transparent, lightweight material having outstanding weatherability, high impact resistance, good chemical ity and machinability. Chemical Resistance of PLEXIGLAS Sheet*
form, PLEXIGLAS acrylic sheet is an opresistance, and excellent thermoformabil-
2 q
o I. 2
PROPERTY 1 Thickness CHEMICAL RESISTANCE 0543 NEGLIGIBLE) CONCENTRATION. % 100 5 40 10 Acid Acid Acid Concentrated Concentrated 30 10 40 70 40 10 R-S 04 0.2 03 0.2 0.3 8 SE A-D 20 0.3 0.0 Concentrated 96 30 3 20 10 20 2 60 10 D-R-S 0.2 0.4 0.2 0.4 0.2 0.4 -0.2 0.3 0.4
R-S
04
1 inches
.0250
WEIGHT GAIN AFTER 7 DAYS IMMERSION AT 77F. (WEIGHT GAIN OR LOSS OF 1% OR LESS IS CONSIDERED
COMPOUND ACIDS
CLASS Acetic Acid Acetic Acid
NAME Glacial
TYPE
R-S 05 0.2
0.4
04 -_ 0.3 0.3 03 00 0.2 0.4 0.3 0.3 0.3 0.4
DL 0.5 4-D 0.4 A 04 A 5-A 04 -0.1 DL 03 0.5 0.3 0.5 0.3 0.5 -0.4 04 0.5
Chromic Acid Citric Acid Hydrochloric Hydrochloric Hydrofluoric Nitric Acid Nitric Acid Nitric Acid Olelc Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid BASES Ammonrum Ammonium Hydroxrde Hydroxtde
0.2 0.3 02 03 0 SE A-D 2.8 03 00 D-R-S 0.2 0.4 0.2 0.3 0.2 0.4 -0.2 0.3 0.4
A-D-S 0.4 13E D-R 5.3D 0.4 0.0 D-R-S 0.3 0.5 0.3 0.5 0.3 0.5 -0.2 0.4 0.5
Concentrated
Sodrum Carbonate Sodwm Carbonate Sodrum Hydroxrde Sodwm Hydroxrde Sodrum Hydroxrde
(continued)
TABLE
1.4: ACRYLIC
RESINS-ROHM
AND HAAS
(continued)
I
CONCENTRATION. %
TYPE Plexrglas G II UVA. II-UVT. G-UVT er0.1
OF ACRYLIC
PLASTICS
I
Plexrglas IA UVA Plexiglas MC 0.1 0.5 0.1
COMPOUND COMMERCIAL
CLASS PRODUCTS Cottonseed Detergent Kerosene
NAME 011 Solution
TYPE Edrble Grade Heavy Duty
Plexrglas K -rO.l 0.3 -;O.l
Plexiglas 55 to.1 0.4 c:.o. 1
DL -
0.25
0.3 -:o. 1
NO. 2 Fuel Oil (ASTM 0396) Thinner Oil White, Edible Whrte 011 (ASTM USP Grade Flakes 01040) 1
Lacquer Mrneral Olive Oil Soap
DL c.o.1 ..O.l 0.3 to.1 <O.l
DL to.1 co. 1 0.3 co.1 <O.l
0.3 co.1 <O.l 0.4 <O.l 0.1
DL 0.1 0.1 0.5 0.1 0.1-c
Sotutton
Transformer Turpentrne
Distilled Spirit (ASTM 013)
INORGANIC
COMPOUNDS
Distilled Hydrogen Hydrogen Sodium Sodium
Water Peroxide Peroxide Chloride hypochlorite 26 3 10 5
0.4 0.4 0.4 0.3 0.3 DL DL DL
0.4 0.4 0.4 0.3 0.3 DL DL DL
0.5 ct.7 0.6 0.4 0.3 R-S 12R-S 0.1 0.0 0.0 -0.1 A-S R-S 1.1 1.7
0.4 0.4 0.3 DL -
0.6 0.8 0.6 0.5 0.4 DL DL DL
ORGANIC
COMPOUNDS
Acetone Aniline Benzene Carbon Tetrachloride
--0. 1 -0.1 cro. 1c DL DL 95 1.4 0.8
0.1
-3.0 0.0 DL 7.5 2.2
-5-A-E 0.1 R-S DL DL 4.0 2.0
Drbutyl Sebacale Dlethyl Drmethyl Ether Formamrde
-0.1 I: O.lC DL DL 1.4 0.6
Ethyl Acelate Ethyl Alcohol Ethyl Alcohol
50
(continued)
TABLE
1.4:
ACRYLIC
RESINS-ROHM
AND
HAAS
(continued)
TYPE OF ACRYLIC Plextglas G II UVA.

II-UVT. G-UVT DL
PLASTICS
z. s Plextglas
K DL Plexrglas 55 Plexrglas IA UVA Plexrglas MC 4 2 2
COMPOUND ORGANIC
CLASS Ethylene
NAME Dichlorrde Sebacate
TYPE
CONCENTRATION. %
COMPOUNDS
R-S co.1 0.0 <O.l -0.2 14s A-C 0.0
DL 0.0 -0.1 A-C DL
DL 0.1 0.1 0.1 C A A DL
s $ ? 5 z x % 8 8 h
P-Ethylhexyl Heptane lsooctane Isopropyl
q.o.1 0.0 -rO.l
s-o.1 0.0 co.1 0.1 5.8s A-C DL
Alcohol
99
Methyl Alcohol Phenol (Aqueous) Toluene Chemical Resistance Code: A C 0 DL E R S = = = = = = = Attacked Crazed Discolored Dlssolved Edge Swellmg Rubbery Swollen 5
0.1 5.5s A-C DL
*Weight change is affected by the thickness of the material. Values given are for the thickness noted in the column heading. *Although carbon tetrachloride causes negligible weight change in contact with PLEXIGLAS sheet, it does cause optical distortion used with PLEXIGLAS.
of the surface. Carbon tetrachloride
should not be
TABLE BAREX
1.5: 210
ACRYLIC Resin
RESIN-SOHIO
CHEMICAL acrylate-butadiene polymer.
is an acrylonitrile-methyl
Chemical Resistance of Barex 210% Resin

F/T Observed Change FiT Observed Change
ACIDS
1090 30% 100% Hydrochloric Sulfuric
Carbon Tetrachioride 73123 100138 73123 100138 73123 100/38 73123 lOdl38 73123 100138 Hydroxide 73123 100138 73123 100/38 73123 100138 73123 100/38 73123 100138 73123 100138 73123 100138 73123 100/38 None None None None None Frosted, Softened None None None Yellowed None Softened None None None
None Slight Frost
1 ,l ,l,
73123 100138 73123 100138 73123 100138 73123 100138
Trichloroethane
Trichloroethylene Methylene Chloride
Acetic
30% Phosphoric 10% Nitric
None None None None None None Frosted, Rubbery Frosted, Rubbery Softened Softened Frosted, Softened Frosted, Softened None None None None None None None None None None None None None Frosted, Softened
KETONES
Acetone Methyl Ethyl Ketone Methyl lsobutyl Ketone
73123 100138 73123 100138 73123 100138
BASES
10%
Ammonium
Barium Hydroxide Calcium Hydroxide 10% Potassium Hydroxide 10% Sodium Hydroxide
ALCOHOLS
Ethyl Alcohol Isopropyl Alcohol Glycol
73123 100/38 73123 100138 73123 100138
Frost, Softened Slight Frost Frost, Softened None None None None None None
HYDROCARBONS
Benzene Toluene Xylene
ESTERS
Butyl Acetate Cellosolve Acetate Ethyl Acetate
73123 100/38 73123 100138 73123 100138
Exposure time in all testing was one year.
TABLE 1.6: CELLULOSE
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
TENITE esters are cellulose derivatives of acetate, butyrate, and propionate. Tenite plastics for molding and extrusion are supplied in the form of pellets. These resins have good processability and finished articles may be resoftened by heat and reshaped by the application of suitable forces. thermoplastic
Effect of Various
Material CHEMICALS Acids Tested
Chemicals and Reagents on TENITE@

Material Alcoholr. Tested
Acetate
Tim0 Exposed
Percent
Increase
l-
hicknes!
Observed Condition of Plastic
l-
Percent Wai#n
Increase licknen
-r
Obsmad of
Plastic
Condition
monohydric
Acetic. 590 Acetic, 10%
I year 1 week 1 week 6 days (100F 1 year
5 53 5 44 17.03
3 19 3 03 22 57 1.67
Shghtly
softened,
surface
Acetic. 30% *Chromic. 6% Citric, 10% Citric. 10% Citric, 30% Fluosi!iclc, 10% Fluosillclc. 28% Formic, 3% Hvdrochlorlc. +Hydrochlorrc, l Hydrochloric, Hydrofluoric, Hydrofluoric, Lacttc, 10% Lactic. 50% N~rrlc, 10% Ol0C Phosphoric. 30% Phosphoric, 50% *Phosphoric, 75% Pyrogallic. 4% sreanc Sulfuric, 3% Sulfuric, 10% Sulfuric. 20% Tannic. 10% Tartaric Trichloroacetlc 6% 6% 10% lo?/, 48%
)
2 63
attacked Shghtly softened, surface attacked Softened Softened and swollen Unchanged Decomposed Decomposed Slightly warped Slrghtly warped Unchanged Unchanged Softened Softeled and swollen Softened and swollen Decomposed Unchanged Shghtly softened, surface atracked Decomposed Unchalged Unchanged Brittle, surface attacked Decoliposed Stamed yellow Unchanged Softened Decomposed Decomposed Softened Unchanged Decomposed
n-Am+ tert.Amyl n-Bury1 seeBury tert-Butyl *Drawtone Ethyl *Ethyl, 50% 2.Ethylhexyl lroamyl lsobutyl *Isopropyl Methyl *Methyl, 5% vvPropyl l Tetrahydrofurfuryl
Alcohols, Glycerin di. and tri-hydric
2 days 2 days Z days 2 days Z days
-0.36 -0.17 1.41 0.36 -2.00
0.26 0.19 1.40 0.76 0.26
Jnchanged Jnchanged Jnchanged Surface bleached slightly Unchanged Dissolved Swollen and softened Swollen and softened Unchanged Unchanged Unchanged Swollen Blushed. softened, and swollen Blushed and softened Blushed Softened and swollen
2 months l14OF) 1week (140F) 2 monrhs 2 months 20 days 2 days 2 days 1 month 1 month 1month 2 days 2 days 1 week 1 year 2 months 2 months 1week 1 week 1 week 1 month 1 year 6 months 4 months (14OF) 2 days 1 month
2 days 1week 1 week 2 days 2 days 2 days 2 days I year 2 days 3 days
12.70 14.46 -0.36 -1.70 10.90 22.60 3.96 2.20
27.90
0.14
-1.30 -1.67
2.03 0 00
1.26 0 06 2.06
0.05 -0 61 1 49
0.42 16.40 51.00 2.59 4.22
3 14 6 80
1 50 4 34
Ethylene Glycol Oiethylene Glycol Triethylene Glycol
1 year 1 year 4 months 4 months 2 days
-0.66 1.29 20.76 25.40 0.39
-0.15 1.39 15.94 22.69 0.42
-3 33 2 03 1 63 7.60 304
-0 83 0.63 -0 42 3 55 2.19
Propylene Glycol Bases Ammonium Hydroxide, 10% Sodium Hydroxide, 1% Sodium Hydroxide. 10% Trimethylbenzyl Ammomum Hydroxide. 5%
EltW
Unchanged Very slightI\ softened Warped and softened; surface attacked Warped and softened, surface attacked Unchanged
1 month 1 month I week 17 days
12.41 -0.12 -4.07 5.85
Softened; surface attacked bftened and warped I&composed iwollen and checked
7.62 2.93
1 63 1.60
Acetate sec.Bury1 Acetate Ethyl Acetate Ethyl Lactate

n-Rutyl
! days ! days
7.24 3.74
9.75 3.62
iurface attacked iurface attacked Irnolved Irssolved
(continued)
ACETATES,
BUTVRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)
Effect of Various
Material Tested &err *Ethylene Acetate Acetate, Ethylene Acetate Acetate; Acetate) klsoamyl Isobutyl *Isopropyl Methyl Acetate Acetate Acetate Acetate silicate 1 month (122F) 2 days 2 days 2 days 1.89 7.82 1.32 0.61 4.32 a.44 fCont) Glycol Monoethyl Ether EE 2 days Time Expord Pornon Weidtt
WOOS?

Material Hydrocarbons Tested
Acetate
Trme Pann Wei& hicknos Observed Condition of Plastic
l-
hlckna
Otnervad Condition of Plastic
Expoad
46 hours flOOF, 60% R If.1 24 hours f14OF. 88% R.H.) 2 months 1 month 1 year
(Cont.) (Moth (Moth balls) balls) 094 2.02 0.00 0.00 a.92 2.12 Showed Showed considerable considerable plasticizer plashcizer exudatron exudation Unchanged Unchanged Swollen and slightly softened Unchanged
Surface attacked
Naphthalena
(EKTASOLVE= Cello~olve Glycol Methyl (EKTASOLVE Monomethyl
Acetate) Ethel Oraolved EM
l Naphthalene
Propane, Propane, gas
Cellosolve Surface attacked Surface attacked Surface Dissolved attacked
liqurd
l Toluene
Xylene Hydrocarbons, *Carbon Chlorobenzene Chlorobromomethane Chloroform Halogenatad
1year
Tetrachloride 2 months
14.92
4.12
Unchanged Orssolved Dissolved Dissolved
Tetra(2ethylbutyl)
-2.39
-0.83
Unchanged
EUWS
Oiethyl Ether Ether 2 days 2 days 1.38 -9.31 11.20 -0.15 Blushed and swollen Unchanged Dissolved Oi-Isopropyl 1.4.Oioxane Ethar Alcohols Oiethylene Ether Diethylene Glycol Monobutyl 06; Ether 2 days 11.20 12.30 Swollen, Dissolved surface attacked 2 days 1.02 1.63 Surface attacked slrghtly (EKTASOLVE Glycol Glycol Carbitol) Glvcol Monobutyl EBButyl Monoethyl Monomethyl EM, Ether 2 days 23.10 25 30 Swollen Dissolved and slightly softened Ether 2 days 1.95 2.64 Surface attacked shghtly
l o-Oichlorobenzene
p_Orchlorobenzene p-Oichlorobenzene *Ethylene Chlorrde Chlorrde Chlorrde
3 days 3 days 3 days (100F. 80% R.H.)
9.80 2.24 6.57
4.44 0.73 4.03
Slightly
swollen
Unchanged Showed Orssolved Dissolved some plasticizer exudation
l Methylene
Propylene
2 days 3 days 2 weeks 16 hours
25.30 5.36
2.06 3.45
Blushed and blistered Shghtly Orssolved Unchanged swollen
Bury1 Carbitol) Monoethyl DE. Carbitol) Monomethyl OM; YTetrabromoethane (EKTASOLVE
l Diethylene
Ether Methyl Ethylene
l Tetrachloroethane
Tetrachloroethylene Trrchloroethylene Ketones Acetone Cyclohexenone Oi-Isopropyl Methyl Methyl Methyl Methyl Ethyl Ketone Ketone Ketone Ketone Ketone 2 days 2 days 2 davs 40.40 51.30 0.64 2 days 2 davs 0.04 13.40 0.31 16.20 32 20
(EKTASOLVE
Surface attacked
(EKTASOLVE Cellosolve) Ethylene Ethylene Ether Methyl Glycol Glycol (EKTASOLVE
Dissolved Dissolved Unchanged Swollen, Dissolved surface attacked
EE. Cellosolve)
n_Butyl
(EKTASOLVE Cellosolve
lsobutyl n-Propyl
7.39
78.50 0.24
Swollen, Swollen
surface attacked and warped, surface
Hydrocarbons Benzene Butadiene-1.3. Butadiene-1.3, Heptane Vndtcotu rc,,. that material ir generally liqurd gas
attacked
I week I year
I month
5.94 -9.42 4.21 -5 Jar YIC in conmcr 36
17.47 a.85 2.77 -1.20
Softened tiarped
and swollen and shrunken
Phorone
Stained yellow
Showed exudation Unchanged Acetalc under thr condimnr of rhu
I year
unr0rirfacrar-y
with TENITE
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)
Effect of Various Chemicals and Reagents on TENITE@

Material Tested Time Expo&?d Percent Weight Increase Thickness Obsetwd Condition of Plastic Material salts (Cant) Acetate, Chloride, Chloride, solution Sulfate, solution Chloride, solution Nitrate, Nitrate, Sulfate, Sulfate, sohd 10% solid 16% 30% 3 months 2.95 3.56 2.00 Unchanged Slightly bleached &fluoride, Basic, 19% 2 months 2 months 2 months 3 97 3.25 0.34 2.07 1.65 0 00 Unchanged Unchanged Unchanged Potassium *Potassium *Potassium solution Potassium solution Potassium solution Permanganate. saturated Iodide, saturated Chloride. Cyanrde. Cyanide. 10% 19% saturated Tened
Acetate
Time EXpOnd Percent Weight Increase Thickness Obwwd Condition of Planlc
salts
Aluminum Aluminum Aluminum saturated Aluminum Ammonium saturated Ammonrum saturated Ammonium Ammonium Ammonium Ammonium Calcium Calcium Calcium Calcium Calcium solid Calcium Calcium Calcium Cupric Cupric Cuprous solution Ferric Ferric *Ferric Chloride, Chloride. Chloride, 5% 20% 46% saturated solid sohd 5% Sulfate, sohd 21% solution 2 months 2 months 2 months 2.93 2.50 2.61 2.12 1.91 046 Unchanged Unchanged Unchanged Surface 2.93 3 12 5.66 (lOOoF) 3.89 0.02 I .64 1.94 tacky Phosphate, Phosphate, Sulfate, Sulfate, Sulfate, 10% saturated solution Dibasic, Tribasic, solid soled 1 year 1 year 1 year 2 months 2 months 1 week -3.27 -3.74 -0.20 3.50 3.07 2.26 -0.6 -0.87 0.42 1.76 1.66 2.75 33% water slurry
1year
2 months 2 months 3 days 2 days
3.29 -5.84 -1.15
I.34
-4.64 -2.66
Unchanged Discolored Discolored Stained and softened and softened
yellow black
I month I month I week

1 week 1 year 1 year 2 days
3.27
1.39
Stained
1.43 0.14 2.91 0.0 3.66 2.91 2.93 0.61 2.94 -1.09
0.36
Unchanged Unchanged Unchanged Unchanged Unchanged
Potassium Potassium
Sulfate, Sulfate, 3%
sohd 10% solid
1 year
0.06 2.60 1.97 2.96 4.03 2.66 -0.10 -0.74 2.52 1.26 (140F) 1 03 -4.20 -0.64 0.37 3.60 0 65 -0.26 2.56 -0
0.40 1 46 0.61 1.60 2.37 1.56 06 1.53 0.54 -0.52 -5.60 -2.59 0 -2.25
Unchanged Unchanged Slightly softened Unchanged Unchanged Unchanged Unchanged Slightly softened Unchanged Unchanged Unchanged Drscolored, Discolored, Unchanged Unchanged softened softened
008
156
I year
2 days 2 days 1 week 2 days 4 days 1 year 1 year solution solution solution 2 months 2 months 2 months 2 months 1 week 1 month 5% 2 days 2 months solrd
Srlver Nitrate, Sodium Sodium Sodium
Bicarbonate, Bisulfrte, Borate, 20% 2.5%
055 1.64 0.61 2.10 0.16 1.96 1.38
Chloride, Chloride, Chloride, Phosphate,
solid 2.5% 40% 6% Monobasic.
Unchanged Unchanged Unchanged Slightly Brittle, softened surface attacked
Sodrum Sodium Sodrum Sodium Sodium
Carbonate, Carbonate, Chlorrde.
solid 2.5% 10%
1year
2 months 3 months 1 year
Hypochlorite,
Chloride,saturated Chloride,saturated Cyanide. Cyanide, Fluoride, 10% saturated 4%
Sodrum Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged *Sodium Sodium Sodium Sodium Sodrum Sodium Sodrum *Sodium Sodrum Sodrum Sodrum
Ferrocyanrde,
solid
Hypochlorite, Nrtrate. Nitrate, Nrtrate. Nrtrite, Nitrite, Srlicate, Srlicate, 5% hydrous saturated solrd 10%
0 35 -0.23 145 0 65 -0.36 0.27 0.19 -2.60 3 20 0 00
Softened. Unchanged Unchanged Unchanged Unchanged Unchanged Etched Softened Unchanged Unchanged Drssolved
wface
attacked
Chlorrde,
saturated
1year
solutron 2 months 2 months solutron solution 2 months 2 months 2 months 17 days 1 weak -0
sarurated soltd saturated solid saturated Ammonium salt
1.46
42 0.76 0.57 -0.34 0.59 0.96
Ferric Chloride,
1week
2 days 2 days 2 days 4 months
Magnesium Magnesium Mercuric Potassium Potasswm
Chloride, Sulfate, Chloride, Aluminum Chloride,
Unchanged Unchanged Unchanged Surface attacked slightly Unchanged
Trimethylbenzyl Chloride, Zinc Chloride, Zmc Chlorrde,
I.75
2.61 075
solution
I year
1week
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Materiel Tested
Miscellaneous Compounds. Ammoniated Alllne Carbon Carbon Chlorine. Chlorme, *Chlorine, *Ethylene Eugenol Formaldehyde. Hydrogen Hydrogen Hydrogen Solution Hydroquinone, lodme, saturated 20 g/gal solution 1 week 2 days 35% Sulfide, Sulfide, Sulfide. dry moist saturated Dwlflde Disulfide. dry moist saturated Oxide, gas solution saturated Chemicals, and Gases Mercury 1 Time EXpOpd ,creas.? Wei&1
Acetate
rhicknm 5
Material Te~ed Aeronautical and Automotive Item! (Cont.)
lOctane 011
Time EXPOred
Obreweci Condition of P1asttc
week (60C) 0.59 5 85 3.58 2.96

1.86 2.39
Unchanged Dissolved Unchanged Unchanged Crazed and brittle Crazed and brittle Softened swollen and conslderably
Gasolines Aviarlon. (Soconv Company) Eao Extra High-Test Regular Fire Chief Sky Chief Esso Regular Shell Shell Texaco and swollen and swollen Texaco Hydraulic Skydrol Skydrol 500 Fuel 3 Oil Company) Jet Propulsion (Humble Kerosene 011s Aeroshell Purol and badly Shell Socony Dlala No 12 1 VfA3l 115145 Vacuum
-5 56
Slightly
statned
1 month 2 days 1 week I week 1 week 1 day 1 week 1 month

2 months 2 months
atmosphere
0.77 0 12
-2 58 -2 33 -2 29 -1.90 -2 49 -3.35 -1.07 1.15 -6.00 -084 -0 24 0.42 -1.64
Stamed yellow Stamed yellow Stamed yellow

Stained Stamed Stained yellow yellow light yellow
18.54 11.82 1 05 3.95 1.58 5 58 2.48
39 70 0.94 0.75 2.29 2.22 3 11 0 82
Softened Dissolved Softened Unchanged Unchanged Unchanged Stained Stained Softened, warped
FluIds Unchanged Surface dulled Unchanged Unchanged
hght yellow hght brown swollen,
-5.95
-0.31 -1 -0 -1 72 08 92
-2 01 -0 82 -0 12 -0.30
Unchanged Unchanged No change Unchanged
HO. SAE Oil OTE Spew A50,
10
Hew
Nitrobenzene *Phenol, Sulfur Sulfur Sulfur 5% Dioxide. Dioxide, Dioxide. dry moist saturated solution
3 days 1 week 2 months 2 months 2 months
011 AX
6 months 2 months 3 days 4 weeks (122F)

011,
Decomposed
Mrdlum Texaco
17.30 13 50 10.60
11.60 9.71 13.50
Swollen Swollen Swollen warped
and warped and warped and conslderably
1692
Low-Temperature MIL-L-644B Nonautomotive
Greases and Oils Almonds 50% I n-Buranol O&solved
Titanium
Tetrachloride 10%
Triethanolamine Triethanolamine,
3 days I week I week
Very brlrtle 11.72 -5.16 24.90 Badly softened 0.69 Softened. surface attacked
Essential Bitter
Oils
Borneol. CItronella ClOVes
2 days 2 days 21days 21days 21days 21days 21days 71jays
0 10 0 56 0.28
033 0 33 0.14 0 09 0 19 0 51
062
Unchanged Unchanged Dtaolved Unchanged Unchanged Unchanged Uncianged Unchanged Unchanged
COMMERCIAL AND NATURAL PRODUCTS Aeronautical and Automotive Items

Gasolines,
Amoco Regular Amoco Premium Aviation, 100 Octane (Standard Oil Company)
I year
I year
I year
-2 80 -2 92 -4.41
-0.19
08 -1 12
-0
Eucalyptus Lemon Menthol, Palmarosa Pennyroyal Spea!mtnt 50% I n-Butanol
Stained ltght yellow Unchanged Slighrly stained
0.26 004 0 98 1.03
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Material Nonautomotive (CotIt) Essenttal Oils 2 days (White) 2 days 1 year 2 days 4 months 011 Oil. G.E., 011, Pyranol Items Odor Neutralizer 2 months 3 weeks Halt Dressing 3 days 2 days 3 days Acid. Solution Grounds Dental Sticks Barb Salts LIpstIck Lipstlck Frozen Pomade Pineapple 5% Insect Fly Killer Killer Concentrate Cream 5% 1 week 1 week 2 days 3 days 2 days (in 0.00 refrigerator) Brilliantine Burma Butter Carbolic Catsup Clorox Coffee Colgate Cologne Coty Coty Coty Dole Dreft Dwin Dwin Glim Glim Unchanged Slightly swollen Lysol Marie Earle Talcum Powder Powder Base Cream Max Factor Decomposed Slightly Badly stained softened Mercurochrome Milk Minute Maid Frozen Grapefruit Orange Tangerine Lemonade Mustard Oleomargarine Detergent. Household Stamless Detergent Detergent, 10% 2 months 1 week 1 week 2 months 2 months 0.93 -0.02 0.24 -0.99 1.99 1.31 0.00 0.00 1.80 1.49 Unchanged Unchanged Unchanged Slightly warped, showed surface Pine Bath Oil Port-a-Fount Liquid Dentifrice spots on drying Unchanged Orange Juice Concentrate Peanut Butter Powder Pebeco Tooth and slightly Concentrates: Mayonnaise Mennen Shave Cream Shave Cream -0.72 5.65 Unchanged Unchanged No 10-C 0.06 0.37 -0.85 2.74 -2.18 -3.20 (194F) -4.03 -2.94 -3 58 0.09 0.05 0 16 1.58 -0.95 -1.25 0.00 0.56 0.00 Unchanged Unchanged Unchanged Surface attacked shghtly iced Coffee Mmeral Sour Sperm Oil 011 Unchanged Shghtly Slightly stained warped Iced Tea *Joy Joy Detergent Detergent, Soft 10% OrInk Lipstock MIX Crude Terpineol Thyme Turpentine Wintergreen Tsned Greases and Oils Time EXpored Percent Wei&t IncreaLe Thickness Observed Condition of Plastic Howhold Hersheys Hinds *Hydrogen Hydrogen Horseradish Peroxtde. Peroxide, 3% 5% Material Items Honey Tested (Cont) Syrup Cream
Acetate
Time
Percent Wei$t
bxreaLe 1hickne!
lLI
EXpoad
Chocolate
1 week
167 1.80 4.46 3.10 1.87 1.98 -3.27 -0.32
0.74 4.30 2.95 1.73 0.86 1.04 10.05 1.82
Unchanged Slightly Bleached Shghtly Stained Unchanged Swollen Surface Stained Unchanged and slightly attacked warped Unchanged slightly warped and softened bleached Unchanged
& Almond
I week
3 days 1 year 2 days 1 week 1 week 2 months 2 months 3 days 3 days 3 days 1 week 1 week
I year
1 week 1 week (180F) 1 week (194F)
Transformer Transformer Household Air-Wick Bacon
Unchanged Unchanged
Kool-Aid Lady Lard Lemon
Esther Juice
4.30 2.47 0.97
4.00 1.37 1.24
Unchanged Unchanged Unchanged Badly softened
Lemonade Lever Tooth Paste
4 days (lOOoF) 1 year 3 days 3 days 3 days 2 days 2 days 3 days 1 week 1 week
Unchanged
2.61
-0.73
Unchanged Unchanged Unchanged Unchanged
Unchanged Unchanged Badly Slightly stained warped and swollen brittle
3 26
1.46
Stained
light pink
Unchanged 1.94 2.01 1.87 0.62 0.92 0.72 0.86 Unchanged Unchanged Unchanged Unchanged Stained Unchanged Unchanged Unchanged 2.65 2.00 1.17 Unchanged Stained light green Softened and slightly swollen
I day I day
40 days 28 days 1 week 1.92 1.04
Softened
I week 1week
2 days 3 days 3 days 3 days 3 days (100F) 1 week 2 days
1.77
2.78
Unchanged Unchanged
1.44
1.38
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)
Effect of Various
Percent Wei& Increase hicknes
Acetate
Matwial liousahold Powder Amolin Spiro &lest Rad Household Hudnut Lotion ltamr Deodorants
Tested (Cont.)
lime
EXpOpd
Obsewed Condition of Planic
Material Tested Miscellaneous Caultmg (Coot) (average of
Time EXpOred
hicknes
Compound Smash Syrup
I week I year
3 days
~l40F)
-2
68 2 58 1 83 0 32
-0 05
1.36 3 20
Unchanged Unchanged Unchanged Statned sllghfly Unchanged Swollen, Very Unchanged Unchanged VerY slightly softened softened, and warped
1 week 1 week 1 week Cleaner Cteme Waving
Unchanged Unchanged Unchanged (16OFi 3.57 4 90 2.15 Swollen and showed exudation Unchanged
five brands) Cherry CowCola Creosote 2.4.0 (Amme solld 6% in Flit Insect Spray (Ester Weed Killer 12.7% free acid) Weed Killer, addeN 2 months 1 week 4 days No 10856 Bail Porn (for 2 months 2 weeks and Oenison 1 48 0 38 069 2 06 204 1.41 0 39 0 00 5 12 0 62 Very slightly softened Type. 14% free acid) Concentrare Chlordane, 20% Syrup Concentrate
1day
I year
8 months 2 months 2 months -2
132
0.73 2 96 I 94 0 00 039 -045
Richard
1 day (lOOoF
59 I 59 2 82 0 17 0.38 2.80
Ronronol Servac Shoe Polish Kllafl
Lighter Detergent
Fluid
1year
1 year 3 daYs
-5.85
-1.32
Softened
and etched
2.4-O. DOT. DOT.
4 tablespoons/gal
slightly
softened
Decomposed 0.15 (19OFl 1.0 2.50 0.08 2.06 4.72 3.24 0.00 4 13 Stained Stamed
I week
1 week 2 months
End-O.Weed Type.
Shinola Soap, *Stanlay Stokelyr Tamp Tide Tomato Toni Toni Vicks Vitalis Watkins Welchs Welchs Wildroot Mioallaneour Blood Budweiser Canada Carboseal liquid Carboreal vapor Gas Antileak Compound, 2 months 000F) 2.76 0.81 Lager Beer Balsam Gas Antileak Compound. 1 week lweek 3 weeks 2months(100F) 5.28 -0.01 26.60 10% Floor Cleaner Detergent, Juice 5% (Campbells) Cleaner Juice
I dav
1 week I week
1 day
End-O-Weed 0.07 1.36 1.24 1.52 0 86 1.28 2 16 37.30 -1.34 1.74 2.25 0.04 1.02 1.03 1.30 Softened Unchanged Unchanged Shghtly warped Unchanged Unchanged Unchanged Badly stamed swollen Orange
4 tablespoons!gal Flit Insect Spray with &DOT Inks Cado Caners Cushman Shghtly Stamed stamed blue Unchanged
2 months
I week
3 daYs 3 days 2 days
Unchanged
Wave Lotion Wave Lotion Oecongestant Hair Tonic Fly Spray Frozen Grape Juice Neutraluer
felt tip pens) Oiagraph-Bradleys E-Z Brite Parker Sanfords Sanfords Marking Sheaffars Latex Mmeral Em&Ion Spmts Insecticide. Industrial liquid Edge Black Ori.Line Skrip Larkmg Black Superchrome Stencil 2 months
(122F )
1.08
-4 49
3 52
Stamed StaIned Swollen, Very Stained
black amber stamed sramed red slightly
3days
2 months
Considerably Unchanged Unchanged Unchanged Unchanged
1week
2 days 1tOOF) 3 days 3 days
1week
I week 3 days
Concentrate Grape Juice Cream 011
1month
1 Year IO days 2 months -6 -6 -3
112 00 5 1 69 24 -0 -2.23 -1.4 0.68 82
StaIned Unchanged Unchanged Unchanged Unchanged
Unchanged
Mortemoth Naphfha. softened, and stained Pamts
3.93 0.00
22.50
Swollen Swollen, Shghtly
I month
Outside 1011 base) 1 week
Ou Poor stamed Yellow Kemtone
Oulux
-1
52
-0.26
Unchanged Unchanged
Enamel
I day
*Indarer ,111.
rhor marenal
is~encrolly
unkvisfacrory
for YIC tn conr~cr
with
TENITE
Acrurc
under
rhr condtrlonr
of rhrl
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Material Miscellaneous Pamts Luminall L402 Pittsburg One-Coat Peach (water Semt-Gloss White 1 week -1.20 -0.42 UnchangedInterior. 1 week 331 1.61 Unchanged Tested Time Enpored Percmt Wei& increase Thickness Observed Condition of Plastic Material Miscellaneous Weed-B-Gon Weedone Weedone Tested
Acetate
Time
Percent Weight
Increase hicknw
EXpored
(Cont.)
(Cont.) Weed Killer, I month Tvpe. 2 months 2 months 3.32 2 88 2.56 160 1.66 1.62 Unchanged very very slightly slightly swollen swollen
2% tablespoons/gal Weed Killer Weed Killer, (Ester 9% free acid) 5 tablespoons/gal
emulsion1 (011 base) Photographic (All KODAK Acid *o-72 OK.50 Products Brand) Fixer Oweloper Developer 1 week 1 week 1 week 4 46 3.43 4.58 2.56 2 53 2.89 Unchanged Shghtly Stained softened light amber (Polycarbonate cracked when
Polycarbonate
Plastic
(Laxan)
3 days (lOOoF, 80% R.H.)
Unchanged softened, flexed) Unchanged Showed 0.32 -3.37 2.68 0.38 0.55 -1.30 -0.05 0.12 -3.59 1.94 3 00 -1.60 3.09 1.90 -1 0.16 -1.11 0.74 0.12 0.56 01 0 00 0 00 7.98 2 50 1.45 -0.28 1.96 1.74
Ouinine Refrigerants. Freon Freon Freon Freon Freon Freon Freon Solvex Stoddard Super Taxite Tincture Toxaphine, Ultra Solvex 22, gas 22, liquid 114, gas 114. liquid Scale gal 11 12. gas 12. liquid
2 days (120F) 2 hours 1 month 1 month 1 month 1 month 1 month 1 month 3 days 1 week Remover U.S.P. 1 day 2 months 3 days 1 month 1 week I year Weed Killer 13 8% free acid) (Ester 1 month
exudation
Unchanged Unchanged Unchanged Dissolved Unchanged Unchanged Unchanged Unchanged Unchanged Swollen, Swollen, Unchanged Unchanged Unchanged Unchanged Unchanged partially slightly dissolved softened
Mamtenance 2 lb/l0 Solvent
Retarder. Market Paint
Fly Spray and Varnish
of Green Soap.
61% (12%solution) Oescaling Agent.
(100F)
i Tl ?NITE,
Most tests were conducted
by
3 lb/IO gal Varsol No. 2 Solvent water Weed-B.Gon Type,
placing dry, injection-molded
specimens
of TENITE Acetate
in contact with the other material for the period of time shown.
Most figures given are the are reported exasrly,

(23C) and solu-
result of a single test, and the measured gains in weight and thickness without
tions
rounding.
aqueous.
Unless
stated
otherwise,
tests
were
conducted
at 73F
were
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Material Tested Time Exposed Percent Werght Increase Thickness Observed Condrtion of Plastic Alcohols, n-Butyl 5% 10% 30% 5% 6% 10% 10% 69% 10% 28% 3% 10% 10% 48% 2 days 8 months 1 year 30% 50% 75% 4% 3% 10% 20% 2 months 2 months 2 months 1 week 1 wek 1 year 1 year 1 year 1.60 1.50 0.91 0.97 0.74 0.31 2 56 1.08 2.31 1.26 1.58 1.53 0.80 0.75 1.60 0.50 1 year 3.59 Material Tested (Cont.)
Butyrate
Time Exposed Percent Increase Thickness Observed Condaion of Plastic
Weight
CHEMICALS
Acids Acetrc, Acetic, *Acetic, Boric, Chromic, Citric, Citric, *Citric,
Monohydric
2 days 2 days 2 daqs 2 davs 1 weak 1 week 2 days 2 days
6 45 7 20 3.62 23.00 13.40 2 02 23.40
7.20 1070 3.30 24.70 11.60 2 12 25 10
Swollen SWollen Shghtly Drssolved Softened Softened Swollen Very slightly softened Softened, Drssolved tacky softened
2 months
2 months 2 days 8 days (100F) 4 months 1 year 4 months 2 months 2 months 20 days 1 year 1 month (140F) fl4OFl
5.22
13.60 1.25 2.00 1.64 1.38 4.45 4 69
2.07 2.38
0 58 0.00 0.13 0.78 0.62 1.20 3.57
Slightly Slightly Softened
softened softened and wollen stained
sec_Butyl
l tert.Butyl
Oracetone Ethyl Ethyl. (denatured) 50%
Unchanged Slightly Slightly Surface
softened attacked
t.Ethylhexyl Isoamyl *Isopropyl Methyl Methyl. 5%
Unchanged Unchanged Unchanged
Fluosilicic, Fluosilicic, Formic,
1 year 2 days
2.02 1500
1.24 4.40
Shghtly Slrghtly Orssoived
softened softened
Unchanged 0.86 10.30 0.53 5.47 Surface Slightly Drssolved Unchanged Decomposed Unchanged Unchanged Unchanged Partially Stained Slightly Slightly Slightly attacked decomposed slightly swollen attacked and softened
n_Propyl
Hydrochloric,
l Hydrofluoric,
Hydrofluoric, Lactic, *Nitric, Oleic Phosphoric, Phosphoric, *Phosphoric, Pvrogallic, Stearic Sulfuric, Sulfuric, *Sulfuric, 50% 10%
l Tetrahydrofurfuryl
Alcohols, Drethylene 2-Ethyl Ethylene Glycerin Propylene Triethylene Bases Glycol Glycoi Di. and Tri-hydric Glycol Hexanedrol.1.3 Glycol 2 months 2 days (lOOoF) 1 year 1 year 2 days 2 months 4.24 0.03 0.44 8.61 2.10 0.4 1 0 00 6 70 8 24 6.10
Softened Unchanged Unchanged Unchanged Unchanged Softened
yellow drscolored discolored softened, surface
Ammonium Calcrum saturated Sodrum *Sodium
Hydroxide, Hydroxide. solutron 1% 10% Hydroxide, Hydroxide. 5%
10%
2 months 1 week 1 year 8 months 17 days
21.87 1 72 0.95 3.19 1.13
12.93 0.65 0.61 2.20 0.00
Softened Unchanged Unchanged Brittle Unchanged
Unchanged
Trimethylbenzyl Hydroxrde.
Ammonium
*Sulfuric, Sulfuric, Tannic.
3D% 94% 10% 1% 5%
1 year 4 months (lOOoF)
-0.42 2 75 3.28 9.25
-0.29 1.20 0.50 3.07
Surface
attacked EStWS n-Buy1 sec.Butyl Dioctyl Acetate Acetate Adipate 1 year 1 month (122F) 0.91 Small gain Dissolved 0 32 Phthalate Acetate Dissolved Dissolved Unchanged
Disintegrated Unchanged Unchanged Softened
Trichloroacetic, Trichloroacetrc,
1month
1 month
Dr-2.Ethylhexyl Ethyl
Alcohols, Monohydric
n-Amy1 tert-Amy1 2 days 2 days 3.06 14.00 3 00 11.30 Unchanged Softened, tacky
Vndicarcr ICII.
rhot material
isgencr4lly
unsatir/ncrory for use in conr4cr
wth
TENITE
Burpore
under the condrrionr
o/this
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Mearia Tened Esters (Cont.) Ethyl Ethyl Ethylene Acetate Acetate; Ethylene Acetate Acetate; Acetate) Lactate Propionate Glvcol Monoethyl Acetate) Ether Drssolved Hydrocarbons, Carbon Chlorobenzene Chlorobromomethane Acetate Acetate Acetate Acetate Acetate Dissolved Dissolved Dissolved Dissolved Dissolved Halogenated EM Tetrachlorrde Ether EE lEKTASOLVEQ Cellosolve Glycol Methyl (EKTASOLVE Monomethyl Cellosolve Drssolved Drssolved Dissolved Time EvJ=-t Percent Wei&t Increase Thickness Observed Condition of Plastic Material Hydrocarbons Propane, Propane, Toluene Xylene ga: liquid Tested
Butyrate
Tnme Exposed Percent Weight Increase Thickness Observed Condition of Plastic
(Cont.) 2 months 2 months 2 days 0 34 1.42 39.30 41.52 0.64 4 55 54.90 33.17 Unchanged Unchanged Softened Softened
1week
2 days
14 80
6 80
Surface Drssolved Drssolved Drssolved
shghtly softened
l ,lsoamyl l Isobutyl
Isopropvl Methyl n-Propyl Ethrfl Orchloro Diethyl
l Chloroform
o-Drchlorobervene 3 days 3 days 11.14 11.70
Softened Swollen Drssolved Drssolved Dissolved
end swollen
l p-Dichlorobenzene
Ethylene Methylene Propylene Chloride Chloride Chlorrde
s-Tetrabromoethane Oiethyl Ether Ether Ether 2 days 2 days 46 00 0.78 50.00 Dissolved Considerably Unchanged swollen Tetrachloroethane Tetrachloroethylene Trichloroethylene
3 days
Softened, Dissolved
swollen,
and tacky
Di-Isopropyl Etbn-Alcohols Ethylene Ethylene Cello&e) Hydrocarbons Benzene Gas, Natural,
1.06
12 days
Badly swollen Badly swollen
1day
Glycol Glycol
Monoethyl Monomethyl EM; Methyl
Ether Ether
Dissolved Dissolved
Ketones *Acetone Cyclohexanone Di-Isopropyl *Methyl Methyl *Methyl Ethyl n-Butyl lsobutyl Ketone Ketone Ketone Ketone Dissolved Drssolved Dissolved Dissolved Dissolved Dissolved Dissolved
(EKTASOLVE (EKTASOLVE
EE; Cellosolve)
Orssolved aromatic-free
Phorone slight decrease in and increase Salts Aluminum 33% water Aluminum Aluminum saturated Alvninum Ammonium saturated Acetate, slurry Chloride, Chloride, snlutron Sulfate. solutron solid 3 months 1 month 1.68 2.34 1.07 10% 2 months 2 months 1.48 0.10 0.71 0.00 Basic, 2 months 1.83 0.56 strength
1year
23 days
Showed
tensile strength in impact Gas, Natural, aromatic Heptane Hexane 5% content Showed
Unchanged Unchanged Unchanged Unchanged Slrghtly bleached
slight decrease in strength
tensile strength and rncrease in impact
1year
1 week
1.60
2.40
Unchanged Unchanged
Bifluorrde.
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Material Tested
Butyrate
Time Exposed Percent Weight Increase Thickness Obwved Condttion
salts Clnt.)
I
1 year 1 year 1 year
Tume Exposed
Percent
Increase Material 1 rh,cknes salts nMlt.) Tested
Weight
of Plastic
Ammonium saturated Ammonwm Ammanurn Ammomum Ammonium Calctum Calcwm Calcium Calcwm Calcwm
Chlarlde. solwon Nitrate, NItrate. Sulfate. Sulfate. Chloride, Chloride, Hypochlonte. Hypochlorlte, Phosphate, salld Dlbaslc, lrlbaslc, 10% solution solld solid soled solid 10% solid 10% 2.5% 40% 6% 30%
1 month 1 week
2.11 0 16 1 65 011 1 30 1 49 0 44 6 00 0 77 1.73 -3
0 78
Unchanged Unchanged Unchanged Unchanged. Unchanged Unchanged Unchanged Softened Unchanged Unchanged and cracked
Potaswm saturated Potassium Potassium Potaswm Sliver Sadlum S&urn Sodium Sodturn Sodium
Cyanide. solution Ferrlcyanlde, Sulfate. Sulfate, 2 5% 3% Sulfate, 2 5% solId 1% 20% 2 5% solid 2 5% 6% 10% 2 54L 10% saturated saturated solution soiutlon solid solid 10% 10%
2 months 4 days 1 year 1 year 2 days 3 days (lOOoF) 1 week 2 days 1 week 80XR (100F. H.)
046
0.04
Slightly
discolored
(brown)
0.23 0 75 0 58 0.52 0 88 0 00 75 0 00 0 54
Unchanged 0 12 1 36 1.46 1 30 1 64 1 68 010 1.25 2.14 1 53 1100F. 3 90 1 28 118 0 93 0 80 0.52 0.44 0 53 0 57 0 37 0 00 Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchailged 1 33 0 79 (140F) 0 89 0 57 1 02 -0 18 0 84 245 111 0 08 1 23 0 92 0 30 -2 09 0 12 0 42 0 39 0 20 -0 0 54 0 31 0 89 0 20 0 28 44 Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
1week
Nitrate. Acetare,
2 months 1 year 13 days 1 year
Aluminum Bicarbonate. Bwlfate. Bulfate, Blsulflte, Borate, Carbonate. Carbonate. Carbonate. Carbonate. Chlorlda, Chloride, Chloride. Chloride. Chromate, solution Cyanide, Cyantde. Fluoride.
Monobaw, Calwm Calcium Calcwm copper Copper Cuprous Ferric Ferric Few Ferric Fernc Llthwm Ltrhlum Magnesum Potasswm (alum). Potawm Potasswm Potassium 3otassium 3otasswm
3 days (lOOoF) 1 week 2 days 1 week 1 year 3 days (lOOoF) 1 year 1 year 80% R H.)
Phosphate, Phosphate, Sulfate Sulfate Sulfate. Chloride, Ammomum Chloride. Chloride, Chloride. Chloride, Bromide, Bromide. Aluminum 21% Brcmlde. Chloride, Chloride, Chrome Cyanide. 5% 2G?h 40%
1 year 1 year I year 2 months 2 months 1 week
-0 -0 -0
58 63 10 1 67 1 66 1 50
0 58 0 60 0.55 0 64
0 93
Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
Sodium Sodium Sodium Sodium Sodium
(Gypsum). (CuprIcI, saturated solld Sulfate,
solid
1 week 2 months 2 months 2 months
(lOOoF,
025 2 00 1 73 1 34 0 88 -0 -0 68 04 -0 0 75 0 96 043 0 30 04 0.00 1 00 084
Sodturn Sodium Sodium Sodium Sodurn Sodium Sodium Sodwm Sodium Sodium
80% R H
1
Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
I year
2 months 2 months 1 week
saturated solid 50%
solution
1 month 1 week 1 week
saturated
10% saturated solId 4% 30% solution
2 months 2 months 1 week 1 month 13 days 2 months 1 year soiut1on 2 months 2 months
Carbonate,
2 5% Sulfate
2 days 4 months l1OOF
155
1.94
Ferrocyanlde,
3% solId 10% Alum. 10% 10%
3 days (100F) 1 year 1 year 3 days (100F) 2 months
1.30 0 09 1 66 1 33 1 40 0 32 0.47 0 44
Unchanged Unchanged Unchanged Unchanged Shghtly discolored (brown)
Sodium Sodium Sodium Sodiurr Sodium
Hypochlorlte, NItrate, Nltrate, N~rrafe, solld 10%
saturated
S~hcate. solid
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)
Effect of Various Chemicals and Reagents on TENITE@ Butvate

Material
fasted
Time
-r
Percent I crease Weight thickne!
l-
Expnred
Material Miscellaneous
Tested end Gases
Time Exposed
Percent Weight
Increase Thickness
selts (Cont.)
Sodium Sodium Sodium Sodium Tetra Silicate, Sulfite, saturated 10% 20% 24% Silicate Ammonium solution 2 months 1.16 2.08 1.10 flOOFj f122OF) 1.22 -0.74 1.13 0.53 1.37 0.13 Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Slightly etched Unchanged
Chemicals
Kant.) Hydrogen saturated *Methyl Ozone. Ozone, *Phenol StYrene Sulfur, *Sulfur Monomer solid Dioxrde, Dioxide. Dioxide. Dioxide Dioxide dry moist saturated solution Sulfide. solution 20 g per gallon Monomer 45 daYs (outdoors) 45 daYs (120F) I week 1 week 2.39 0.99 Slightly Dissolved Dissolved ppm Unchanged Yellowed Decomposed Dissolved Unchanged 19.40 31.90 23.20 19.20 8.60 10.20 I6 10 11.50 Swollen, slightly warped swollen and stained yellow 2 months 5.87 2.34 Unchanged
1week
13 daYs 3days
Thiosulfate, Thiosulfate, (2Ethylbutyl) Benzyl 5%
0.88 0.00 -0 1
Hydroquinone. Nitrobenzene
1month I7daYs I week

1 week
Methacrylete 0.05-0.15 0.7 ppm
Trimethyl Chloride,
0.06 0.00
0.78
Zinc Chloride Zinc Chloride, Zinc Oxide, Mii&neous Ammoniated *Aniline Benzeldehyde Butedrene-1.3, Butedrene*Carbon *Carbon Chlorine, Chlorine, *Chlorine,
(hYdroussalt) saturated sohd solution
1week
I week (60C)
I week
2 months 2 months 2 months 2 months 3 days water NATURAL Hems 3 weeks (122F) slurry 4 weeks
Chemicals and Gases

Mercury Unchanged Oissolved Dissolved liquid S months 1925 2.72 25.62 1740 8.60 26.40 2.34 1.56 11.75 2.22 0.14 Swollen end softened
Sulfur *Sulfur Sulfur Sulfur Vapor Trtanium
Consrderably warped Swollen Drssolved Swollen Very brittle
and warped
I,3,
gas
1month
1 week ? days
Unchanged Softened Warped Crazed and brittle Crazed and brrttle Consrderably swollen softened and and swollen
in Hydrocarbons and Hydrocarbon
Oisulfide Oisulfrde, atmosphere dry moist saturated solution
Tetrachloride (TNT). AN0
saturated
Trinitrotoluene
Stained
I week I week I week
7.77
COMMERCIAL PRODUCTS Aeronautical
and Automotive Sealer
Dane Head Radiator
Unchanged
l 1,4-Oioxane
Ethylene Oxide. Oxide, gas gas 4% 35% IO minutes (105FI 20.85 0.24 12.96 6.74 25.60
Drssolved Unchanged Swollen and softened Unchanged Swollen Dissolved Peroxide, Peroxide, Sulfide, Sulfide, 3% 5% dn/ moist and softened Gasolines, *Amoco Amoco Aviation Avtation Regular Premrum 100 Octane Oil Company) Octane Oil 1 Year 13.9 5 19 11.9 9.9 9.8 5.77 7.5 8 1 Swollen Swollen Swollen Swollen and stained pink and stained pink and stained pink end stained Yellow 1 Year 5.21 6.06 Slightly stained Vacuum 115145
l EthYlene
I daY
IO min per day for 5 days
Formaldehyde, Formaldehyde, Furfural Hydrogen Hydrogen Hydrogen Hydrogen
1Year 1Year
1 Year
7.7 18.4 3.03
5.5 9.5 3.20
Swollen Swollen Slightly
and stemed Yellow discolored
! months
I year
(Standard (SoconY Company) Exxon Exxon *Shell *Shell Extra
1.72 1.40 2.26 3 04
1.07 1.30 0.81 1.65
Unchanged Unchanged Unchanged Unchanged
! days ! months ! months
Regular High.Test Regular
1Year
I Year
I Year
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)
Effect of Various Chemicals and Reagents on TENITE@ Bun/rate

Material Aeronautical (Cont.) Texaco Texaco Hydraulic Fire Chief Sky Chief Fluids: Super 3 Brake FluId 1 week Screwdriver allowed requirement GGG-S-12ld. *Indian Head Brake Fluid Hydraulic 21-6 Brake Fluid Fluid 1 weak 8 months 6 months 1 year 6 months 8 months 3.42 3.87 1.41 3.39 0.29 3.01 3.22 1.32 3.22 0.32 Fluid 500 Hydraulic 1 week Swollen Dissolved Dissolved Swollen and softened and stained handle dipped of Federal in iluid and to stand 3 days passed torsional Specificatmn Nonanomotive Essential Bitter 011s. Almonds 2 days 2 days 2 days 2 days 2 days 6.10 0.45 0.69 041 5.40 4.20 1.01 0.51 0 00 4.50 Dissolved Slightly Slightly softened softened Greases and Oils Swollen Dissolved and softened Pant No. 7 Heavy-Duty Brake Fluid (VV&860) 1 year I year 9.7 15.0 7.0 12 1 Swollen Swollen and stained yellow and stained pink Tatted Time EXPOrag Percent Weight Increase Thickness Observed Condition of Plastic Matenal Aeronautical (Cont.) Purol STP Texaco No. 50, 1692 Low HD, SAE IO 6 months 2 months 2 weeks 4waeks (122F) (15OF) -1.09 -0.09 Oil, MIL-L.6448 30 minutes 011 Unchanged Unchanged 5 weeks (140F) -0 -0.08 -0.16 0.00 10 0.00 0.09 0.17 Unchanged Unchanged Shell DIala 011 AX Tested Items Time ExP=d Percent Weight Increase Thickness Observed Condition of Plastic
and Automotive
Itams
and Automotive
l Oelco
Do
Temperature Winsorlube Zerolene
l Skydrol
Skydrol Wagner Jet Propulsion Jet Propulsion (Eao
Citronella Eucalyptus Lavender Lemon
Unchanged Unchanged Slightly Dissolved Dissolved softened
Fuel IA Fuel 3 Oil Company) Fuel 3 Fuel 4 Oil Company) Fuel 5
(Shell Oil Company)
l Palmarosa
*Pennyroyal Spearmint Sweet Orange
Standard
Jet Propulsion (Humble (Eao Jet Propulsion Standard Jet Propulsion
Oil Company)
2 days 2 days
0 26 0.56
0.88 0.00
Unchanged Unchanged Dissolved
Terpineol Thyme Turpentine
(Shell Oil Company) Kerosene Oils: Aeroshell Aeroshell Aeroshell Bearing DuoDrive Houghton MIL-L-7808 No. 2 No. 12 Turbine Guard Oil Oil Safe 1120 Oil Oil Screwdriver allowed requirement GGG-S-121d. handle dipped of Federal in oil and to stand 3 days passed torsmnal Specification Oil No. 300 2 months 1 year 3 days (12OF) 4 weeks 4 waeks (122F) 1 week <1 <1 0.27 0.60 0 0.04 0.00 0.34 0 Unchanged Unchanged Unchanged Unchanged Unchanged 1 week 0.41 1.32 Unchanged
1 year 2 days
99.20 11.80
62.62 9 70
Softened, attacked Unchanged Dissolved
swollen,
surface
Vanilla
(Imitation)
Wmtergreen Fuel 011 iL1 Fuel 011 f2 Heavy Linseed Mmeral Neatsfoot NO.OX-IO Sihcone Machine 011 Oil 011 Grease 011. Dow-Corning #200 Oil 011 Light Machme 1 week
Unchanged Unchanged Unchanged Unchanged Unchanged -0.40 -0.16 Unchanged Unchanged Slightly 3.87 0 77 3 10 0.16 stamed Unchanged Unchanged
1week
1 day 1 day I month 4 months 6 weeks 3 days (14OF) 1 week 3 months
Lubricating
Pme Bath 011
(continued)
TABLE
1.6:
CELLULOSE
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Time Exposed Nonsutomotive (Cont.) Sdicone Grease No. 44 (Dow) Oil Greases and Oils
Butyrate
Tame Exposed Percent Weight Increase Thickness Observed Candlt,on of Planic
l-
Percent Weight
Increase hicknes
-r
Observed Cnndltion of Plastic Hotwhold Dreft Items (Cont.1 5% Insect Fly Spray 10% Detergent Syrup Cream and Almond Killer
Detergent. Household Stainless Detergent Detergent, Andy Honey
2 months
131 018 0.51 2 54 147 1.97 1 30 1 20 1 46 1 50
0.50 00 0 38 1.31 0 60 1.50 048 1 50 0.80 1.05 4.07 0 82
Unchanged Unchanged Unchanged Slightly warped Unchanged Slightly yellowed
IO days (16OF)
6 months 1 week 1 week 1 week (194F) -0.78 -0.48 0 00 0 00 0.22 0.00 0 00 3.56 0 00 6 40 2.24
StaIned
yellow,
properties
Dwin Dwin Glim Glim Handy Hinds
I week
1 week 2 monrhs 2 months 1 year
unaffected Sour Crude Soya 011 Sperm Sperm Oil Oil Oil, G. E No. 10-C Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
Hersheys Transformer Transformer Transformer Wesson 5in-1 Oil Oil Items Odor Neutralizer (694) Mioma Pumex Flotilla Soap Soap Soap Flakes 4 days 4 days 4 days 4 days 3 days (lOOoF) Cake solution 1 day (100F) 2 days 2 days DIsinfectant Oressmg 1 week 3 days 1 week 3 days Tomato Acid, 5% Juice 1 week 1 77 1.36 1.67 saturated 0.10 012 1 42 1 53 0 78 049 0 52 12.55 1240 Swollen and shghtly softened 1 week (180F) Oil, Pyranol Oil, Pyranol
Chocolate
1week
1 week 3 days 1 week 1 week
Unchanged Unchanged Unchanged StaIned Unchanged Unchanged Slightly Slightly warped stained
I week
1 week 1 week 2 days
(77F) (194F)
-0.90 -0.92
-0.74 0 19 0.12
HorseradIsh Iced Coffee Iced Tea insect Repellent 6-12 10% Lipstick Joy Joy Lady Lard Lava Soap, saturated Lemonade Lemon Lighter Juice FluIds solution Detergent Detergent, Esther
Zdays
IlOOF) 3 48 1 67
Household Air-Wick Armour Armour Armour Armour Atabrine Avon Borax, Breath Cream Bon Ami.
2 months 2 months 3 days 3 days 2 days 1 week 2 days
Unchanged
Unchanged Unchanged Unchanged Unchanged Unchanged StaIned Unchanged Unchanged Badly swollen
No. 99 Soap
Unchanged 1 36 1 63 240 0 00 1.01 021 Unchanged Unchanged Unchanged
2 5% OPine
AMR Energene Exxon Kwik-Lite Ronsonol ZlPPO Lighthouse Lighthouse Lysol Cleanser Soap, saturated of water Insecticide. to 0 5% Powder 50% spray solution 5 tablespoonsful
2 months 2 months 2 months 2 days 1 year 2 months 2 days 2 days 2 months
3 03
2 69 3 18 1.28 00 0 95 2 05 0 00 0 00 4.37 4 53 2 36
Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Slightly Softened, pitted, Unchanged Unchanged Unchanged softened swollen, cloudy surface when wet
144
1 83 044 0 25 2 17 1 38 1 28 6.97 8.73 2 93
Brilliantine Bubble Butter Campbells Carbohc Catsup Clorox Coffee Cologne Cotv Dart Bath
Hair Oil
0 00
0 54
Unchanged Unchanged Unchanged Unchanged Decomposed Slightly discolored
I week
I week
Disinfectant.
Solution Grounds Sticks Lipstlck Furniture Polish Pineapple (Kress) Juice
j weks 3davs
12 days
Unchanged Unchanged Dissolved Stamed Very 1.45 0 54 slightly stalned
per gallon Malathion diluted Marie
I week
3 days 3 days 3 days
Earle Talcum
I days
week
Mayonnaise Milk
Dole Frozen Concentrate
Unchanged
l btdrcarer rhm morerlol rsgrnrrally *cl,.
unror~sf~crory for USCin cmmct
wrrh TENITE
Buryrrrre under rhr condirmnr
of thtr
(continued)
TABLE
1.6: CELLULOSE
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Material Tested Household Minute Maid Orange GrapefruIt Lemonade Tangerine Mr. Clean Mustard OCedar Old Dutch saturated Oleomargarine Peanut Pebeco Penicillin *Perfume Pme Bath Pan-a-Fount Powder Amalin Spiro cluest Pride Wax Ouinine Rad Household Radiant Richard Lotion Sane-Genio saturated Servac Stanley Stokelys Temp Tide Cleanser, solution 1 year 1 week 1 week 1 5% Julce 104 1.8 1.66 1.58 -0.24 0.06 0.69 0 20 Unchanged Unchanged Unchanged Unchanged Unchanged i days Polish Hudnut Cleaner (Woolworth) Cream !vavlng Oil Liquid Denttfrlce Butter Tooth Powder (powder) Furniture Cleanser, solution 3 days 3 days 3 days (lOOOF) 1 week (100F. 80% R H.) 2 days 1 week ! days 34 80 3 87 29 10 3 10 16.70 Swollen Unchanged Polymers Swollen, Unchanged Unchanged Unchanged 3 01 2 25 Shghtly softened Vinyl Vmyl Plastlsol Plastic. (cured) semwtgid shghtly crazed Deodorants and Plastics 4.00 6.00 Unchanged Unchanged Unchanged Unchanged Wesson Wildroot Wisk Oil Cream Oil Polish Juice Items Jwce Juice (Cont.) Concentrates 1 week 1 week 1 week 146 1.34 1.36 1.41 3.42 2.30 0.12 1 30 TlWX Exposed
Butyrate
Tbme Exposed
Percent InneaSe Wei*t hickne
-I-
Observed Condition of Plastic Household Tmcture
Materml Tested
-r
Percent Increase hickner
Weight
Items
(Cont.) LISP 2 monrhs 3 days Neutralizer Solut~anl 2 days 1122F) 2 days 2 days 3 days 2 months 1 week 1 week 217 1 30 1 52 0 13 0.14 0 00 Swollen and stalned Unchanged Unchanged Swollen and softened Unchanged Unchanged Unchanged Unchanged Unchanged 1.10 0.98 DIscolored 3 days 9 82 6 56 0 62 0 78 Shghtly Slightly softened stained yellow
Frozen
of Green Soap, Wave Lotlon Wave Lollon Decongestant VapoRub Va.Tro.Nol Hair Tome Fly Spray Frozen Salve Solution Bromate
0.64
0 62 0.56 0.46 2.74 0.50 0.45 0 00
Unchanged Unchanged Unchanged Unchanged Slightly Stamed Unchanged Unchanged yellowad
(30% alcohol) Toni Toni Vicks
173
2 23
Unchanged
1week
1 year 11 days 2 days 2 days
(Potassium Vicks Vicks Vitalis Watkins Welchs Welchs
Detergent
0.00
33 90
108
0.53 0 64 3 56
Grape Jwe
Concentrate Grape Juice
1 week 3 days 1 year
0.19
Detergent
Polycarbonate Polyurethane Foam
3 days (lOOoF. 80% R H.) 3 days 1100F. 80% R. H.) 2 days (140F) 3 days (lOOoF. 80% R H
Unchanged Unchanged Softened Unchanged and distorted
I week I week I week I week

1 days (120F)
i
Unchanged 32 6 2.71 0 85
I I
Unchanged 0.70 1.65 0.22 1 60 0.22 Unchanged Slightly stained Unchanged Unchanged Miscellaneous Amway Bitumastic Blood Budweiser Canada Carboseal liqwd Carboseal vapor Caulkmg (Average Compound of five brands) Gas Anti-leak Compo; md, Lager Beer Balsam Gas Am-leak Compot rnd. L.0.C No Detergent 50 Cone 30 days il22OFi 3 days 1 week 1 week 3 weeks 0.77 0.34 23 20 8.80 0 80 Softened, Slightly swollen, statned and stalned
1 day (16OF) 4 days 1 day (lOOoF)
24.9
Softened, Unchanged Unchanged
swollen
Detergent Floor Cleaner Detergent, Cleaner Orange
:2 months :!
months
(100F) (1OOFl
26.90
9.56 0 97
dw
2 months
I week -
Unchanged
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

PfXCWl Exposed Weight .hieknr Observed Condition of Plastic Material Tested
Butyrate
Time Exposed Percent Weight IncreaSe Thickness Observed Condnion
of Plastic
Miscellaneous Chlordane, Creosote 2.4-D 2.4-D. (Amine four
(Cont.) 20% Type). tablespoons Weed Killer (12.7% Undiluted per gallon (Ester Type). 3 days 1 year 4 months 4 months 4 months 3 33 11.65 5 02 1.53 19.50 2 42 5.45 3.60 7.61 8.19 Unchanged Softened Slightly Very swollerl sllght& and soitened
Miscellaneous inks Carters Cushman (For swollen and dw Dyna-Flo Parker Cluick
(Cont.) No 4,715 & Denison Felt-TIP Pens) 3 days (100F) Stencil Ink Inc, Ink Unchanged 60.65 30 50 Softened. Slightly 20 05 Stained 4.09 1.11 (lOOoF. 2.0 26 45 3 56 175 bymanufacturer 2 88 2 45 21 1668 2 73 2 40 0.31 Unchanged Unchanged Surface etched swned stained Pen Ink Superchrome Drying Ink 1 week IO days 38 40 21.8 32 00 159 Softened Softened, swollen
(14% tree acid) of water Endoweed Undiluted Endowed spoons Epoxy Epoxy Fertilizer Fertilizer, Fountain Cherry Cherry Grape Lemon Maple Orange Pepsi-Cola Pineapple Root Beer Smash Concentrate Coca-Cola Concentrate Softened, colored swollen, as free acld) 4 table4 months 3.47 1.31
Diagraph-Bradley
I week
2 days (100F) 18 days 3 days 1 month
(Formulab. Black Ink
Weed Killer. per gallon Hardener Resin (20% Disodium Liquid Syrups.
Slightly Dissolved
softened
and swollen
Blue No. 353) Sanfords Marking Dri.Line Ink
of water 1 month Phosphate, 3 days (122F) -0 07 StaIned 1.44 1.56 ye!low Latex Unchanged
SheaffersSkrip Emulsion 250 Spirits Insecticide. Industrial Yarn Size
3 days (lOOoF)
1year
Insecticide 48 hours 10 days liquid 80% R. H.)
Malaphos 1 year 1 year 1 year Mineral Mortemoth yellow Naphtha, Dnhocryl Pamt 1 year 1 year 1 year 1 year 1 year 1 year 1.31 340 3.87 118 5.02 2 04 1.70 0.14 1.40 3.10 021 1.15 0 66 0.28 Unchanged Unchanged Unchanged Unchanged Dwzolored Unchanged Unchanged Badly Badly Badly swollen swollen swollen Penetrox (All and blistered Paints
2.96
2.08 1.69 1.61 3.34
1.84 1.04 1.15 0 00 1.14
Unchanged Unchanged Stamed shghtly Unchanged Unchanged
Unchanged Softened Unchanged Unchanged Distorted. Unchanged Unchanged surface attacked and swollen
1week
1 month 3 days (100F) Used as suggested 1 week 1 day
I year I year
, 073
Remover Do Pant yellow Kemtone Luminall, paint Pittsburgh 011 base
(CPC 400) Dulux enamel, (outside 011 base)
one coat intenor L-402 (water emulsion) White, Semi-Gloss
1 week
3.11 0.75
1 .B9 0 62
Unchanged Unchanged
Strawberry Vanilla Gas Odorizers, Pentalarm *Spotleak Spotleak Inks: Cado *Carters Ink *Carters No. 10.656 Ball Point No. 10,856 Ball Point 86 (Concentrate) 1OOB (Concentrate) 1009 (Concentrate)
I week
4 weeks (122F)
1year
1 week 1 week
A Lobwant Products Brand) Fixer O-72 DK-50 Kodak
-0.9
-0
I
0 85 0.91 0 80
Unchanged
Photographic Acid
1week
4 days 10 days (140F) 2 months 5 09 1038 12.85 5.37 6.10 7 00
1 week 1 week 1 week
2 I6 2 20 2 33
Developer StaIned Stamed Stamed Developer
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)

Material Mivxllaneour Photographic Tested Time Exposed Percent
Weight
Butyrate
Observed Condnion of Plastic
lncreare Thxkness
Obwved Condttton of Plasttc
Material
Tested
(Cont.) ProductsProcessing K!t 1 week 1 week 1 week Solution 1 week 1 week 1 week and Fixmg 3.05 1.56 1.56 1.56 1 45 2.30 0 55 0.28 0 82 0.28 0.28 0.28 Stamed StaIned StaIned yellow dark amber hght amber
Miscellaneous Ultra l/3 Urine Varsof Water. Weedone Undiluted Weedone Weed-B-Gon 1 month 1 month 1 month 0 88 1875 4 28 0 20 9 50 1 20 Unchanged Type). Weed.B-Gon tablespoons Wine 245 02 0 00 2 37 1.20 062 / 0 58 1 .OB 0 38 Unchanged Unchanged Unchanged Solvex
(Cont.) Dercallng Agent, 1 month 1 week 1.70 1.50 1.14 1.66 27.32 0 54 040 0 94 0 74 14.00 Unchanged Unchanged Unchanged Unchanged Softened, swollen, dlscalored, and warped 2 months 1 month 1.98 1343 0.55 6 58 Shghtly Softened, swollen swollen. dlscafored. of water 1 week 1 year (Ester Type). 2 months (9% free acldl
Ektachrome@
lb per gallon No. 2 Solvent dlstllled
No. E2 First Developer Hardener Color Clearing Bleach Stabliizer Developer
Weed Killer.
Weed Killer, of water
5 tablespoons (Ester
per gallon Refrtgerants Freon 12. gas *Freon 12. ltquid Freon 22. gas
Weed Killer, Undlliited
(13.8% as 2% of water 2 months 7 BB 1 month 2 67 1.06
and warped Softened, Unchanged swollert, dtscolored.
Slightly
swollen
free acid) Weed Killer, par gallon Alcohol) and warped
Unchanged
OiSSOlbFd
Freon 22, liquid

Fraon
113
3 days 49.3 0.5
S2 Flow
112% Ethyl
H3 Flow Freon Freon Showersan Solvex 114. gas 114. I,qutd Disinfectant Scale Retarder, of water 1 year 1 year (140F) 1 year and B months 3 days 2 months 1 week Remover 3 days 3 13 1 57 (lOOoF 116OF) -585 048 956 047 1 60 1 52 1.46
I month
1 month 12 days 1 month
0.84 7.76 1 BB 1 58
Most tests were conducted
by placing dry, injection-molded
specimens of TENITE Butyrate Most figures given are the
in contact with the other material for the period of time shown.
Maintenance Bath
! !
Unchanged Unchanged Slightly softened
result of a single test, and the measured gains in weight and thickness are reported exactly, without rounding. Unless stated otherwise, tests were conducted at 73F (23C) and soluof acetic acid in water the information given
115 lb per gallon Steel Picklmg
tions were aqueous, i.e., Acid, Acetic, 5% indicates tested at 73OF. Unless other characteristics under Observed Condition specimen.
a 5% solution
(3% Sulfurtc Acid and 8% Ferrous Sulfate) Steel Plckhng (8% Sulfuric 14% Ferrous Stoddard Stoddard Super Bath Acid
are specifically
mentioned,
Unchanged Softened Unchanged Slightly Slightly Dissolved Unchanged stamed stalned
of Plastic refers only to the appearance
and feel of the plastic
Sulfate) liquid vapor
I -451 1
1 000 880 043
Solvent, Solvent,
Market
Fly Spray
Taxi@ Pamt and Varnish Toxaphene Insecticide. 12% sOlUtlOn
(continued)
ACETATES,
BUTYRATES,
PROPIONATES-EASTMAN
CHEMICAL
(continued)
The
Effects
of Various
:hange Thlckr
Chemicals
and
Reagents
on TENITE*@, Propionate
Percent Weight Change Tfucknerr
Obretved
Cond,tion
of Plss,,c
Time Exposed
Observed
Condition
of Plasttc
Slightly
softened
Dissolved Sligfwy swoiie Dissolved changed Carbon Carbon C,trtc Citric Chioroform acid, IO. acid (tablets1 1 dlsullde tetrachlorlde Softened, Softened. Snftened, swoilen swolien wolien Gasoline, Amoco Amoco
Premum Regular
1 year 1 year I year 1 year 1 year 1 year i year 1 year
6.28 2 25 4.81 2.44 4.81 3.58 3.22 6 96
12.16 5.38 5.33 5.08 7.03 5.48 6.91 23.25
swo,ien.
*avy
svrface
Esso Prenvum Esso Regular Shell High-Test
Brownish yellow Pmk, wollen, and warped Dark yellow P,nk and warped Yellow. Yellow Swollen slightly warped
month
F)
Vnchangrd Upchanged
I122 Ethyl Ethyl Eulyi acetate aicohol. aicohoi. 50% 95%
*Shell Regular Texaco Regular Texaco swolie swoiie Ink, Quick drymg Blue No. 353; Sky Ch,ef
Dssolved Softened. Softened. Unchanged Dissolved
and pink
Ethylene giycol Ethylene g,yco, monoethyl ether (EKTASOLVE EEI *Ethylene acetate glycol monomethyl ether (EKTASOLYE ERA Acetate1 35%
18 days 1 week
2.2 9.36
-5.6 8.15 Softened, swollen. surface p,tted and cloudy when wet
Formulab. Inc. *Malath,on, 50% spray diluted wth water to 0.5% Malathion
Dissolved Softened. swoIIe11 Dark yellow n:haged nchanged Dlsmteglated I year 1 year i year Unchanged Unchanged Dlssoived Dssoived Dlssnlved DISIntegrated changed Unchanged changed
Formaldehyde.
011: Bard& Bardah, Crude oil Purol
011 011
1 week (122 Fl 4 weeks ,122 F) I year 10 motor 011 2 months 6 months 1 week (122F) 4 necks (122-F) 1 month (122F) 2 days (122F)
-0.92 -196 Unchanged -0 10 -030 -2.04 -3.38 changed 0.03 -0.64
Gasolme, Regular Glycerin tieptane Hydrochlor,c acid.
10%
HD SAE =50
Hydrogen peroxide, 3% Methanol. 5% Methanol, 100% Methyl ethyl ketone *Methyl lsoamyl ketone Nitric acid Oie~c acid Dzone. 5-l 5 pphm ozone. 70 pphm
Texaco Co temperature Texaco Co temperature Sachet Wcks powder
011 1692 low oil, MIL-L-644B =50 011 1692 low 01,. MIL-L-6440
1 year 1 year 45 days ,otdoars) 45 days (12OF) 1 1 1 1 i year year year year year
Unchanged Badiy stained. sottened
decongestant
Phenoi. 5% Propane (gas) Propane U,qu,di soap 501tK. LISP Sodturn carbonate. 2.5% Sodium Sodzum S&urn *Sodium Sulfuric chlorade, 10% ferrocyantde Idry crystals1 hydroxide. 1% hydroxide, 10% aad. 3%
Dlslntegrated Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Drs,ntegrated Unchanged Shghtiy warped Softened. swollen Unchanged Unchanged Softened, saoiien
Most
tests
were
conducted wth the IS shown
by placmg other were conducted
dry, at
mjectmn-molded losted 73F for the (23GCl.
specimens perpod 01 tome
ot TENITE shown
Proplonate Tests for whxh
an ontomate nc temperature
contact
material
1 year 1 week 1 year 1 year 1 year 1 1 1 1 1 year year year year year
080
0 9t
Sulfurs ac,d. 30% TDlelle Turpentine Water *Xylene
TABLE 1.7: CHLORINATED
POLYVINYL
CHLORIDE
PIPE AND FITTINGS-B.F.
GOODRICH
CPVC PIPE/FITTINGS CKEMICAL RESISTANCE Chemical company A company B
NR
The attached list is a compilation of chemical resistance data from three companies involved in the CPVC pipe, fittings and accessories market. Since each company has used a different scheme to report their findings, the following key will be needed to interpret the data.
Company
C
739 Acetaldehyde Acetate Solvents, Crude Acetate Solvents, Put-e Acetic Acid, 10% Acetic Acid, 20% Acetic Acid, 50% Acetic Acid, 80% Acetic Acid, Glacial Acetic Anhydride Acetone Acrylonitrile Adipic Acid Ally1 Alcohol Ally1 Chloride AlUUl Aluminum Chloride Aluminum Fluoride Aluminum Hydroxide Aluminum Oxychloride Aluminum Nitrate Aluminum Sulfate Punaonia, Aqueous Ammonia, Dry Gas Ammonia, Liquid Anrnonium Bifluoride Anaoonium Carbonate Ammonium Chloride Ammonium Fluoride, 25% Ammonium Hydroxide Arrmonim Hetaphosphete Anxnonium Nitrate Anrnonium Persulfate Anrnonium Phosphate Anreonium Sulfate Anmoniom Sulfide Atnaonium Thiocyanate Amy1 Acetate Amy1 Alcohol Amy1 Chloride Aniline Aniline Chlorohydrate Aniline Hydrochloride Anthraquinone Anthrequinone Sulfonic Acid Antimony Trichloride Aqua Regia Arsenic Acid Arylsulfonic Acid Asphalt Barium Carbonate Barium Chloride
1859
u u
U
S
R R R NR NR NR R
NR NR NR NR NR NR R
Company A
E - Excellent to operating limit of material GExcellent to 80'F; material Good to BO'F. Limited; may be used under certain conditions Unsatisfactory; not recommended for pressure applications; for "on-pressure applications Good to maximum operating limit of
L L IJ u c S U E
E E
SLu-
R R R R R R R R R R R
R
R R R R R NR R R R R R NR R
Maximum operating limit is 18O'F 225'F
E E E E E E E E E E E E E E
E
Company B
1 - Good for 200F 2 - Good for 185'F 3 - Good for 140'F 4 - Good for 70F
(93C) (85'0 (6O'C) (21%)
Q - Questionable NR - Not Recommended
Company c
R - Recommended NR - Not Recommended R* - Reconrmended to 21O'F
E E E IJ S U II U u E E e L E L E E E
R NR
ti? NR
9 1
R R
NR R
(continued)

Chemical Barium Aydroxide Barium Sulfate Barirnn Sulfide Beer Beet Sugars Liquors Benzaldehyde Benzene Benzene Sulfonic Acid, 10% Benzene Sulfonic Acid Beotoic Acid Bismuth Carbonate Black Liquor Bleach, 12.5% Active CL2 Borax Boric Acid Boron Trifluoride Breeder pellets, fish Brine Brwic Acid Bromine, Liquid Bromine Water Butadiene Butane Butanol, Primary Butanol, Secondary Butyl Acetate Butyl Alcohol Butyl Amine Butyl Phenol Butyl Phthalate Butylene Butynedial (Erythrital) Butyric Acid Cadmium Cvanide Calcium Bisulfite Calcium Carbonate Calcium Chlorate CaIcium Chloride Calcium Aydroxide Calcium Hypochlorite Calcium Nitrate Calcium Phosphate Calcium Sulfate Cane Sugars Liquors Carbon Bisulfide Carbon Dioxide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Casein Castor Oil Caustic Potash Caustic Soda
A
POLYVINYL
CHLORIDE

C
GOODRICH
Chemical
(continued)
canpany A company B canpany C 185Q 73Q
canpany
Cwpany B
Company
73Q
E E
185Q Cellosolve Chloracetic Acid Chloral Hydrate Cblaric Acid, 20% Chlorine Gas, Dry Chlorine Gas, Wet Chlorine, Liquid Chlorine Water Chlorobenzene Chloroform Chlorosulfonic Acid Chrome Alum Chromic Acid, 10% Chromic Acid, 30% Chromic Acid, 50% Citric Acid Coconut Oil Copper Chloride Copper Cyanide Copper Fluoride Copper Nitrate copper Sulfate Core Oils Cottonseed Oil creso1 Cresylic Acid, 50% Croton Aldehyde Crude Oil Cyclohexane Cyclohexanol Cyclohexanone Decalin Demineralized Water Detergents Dextrin Dextrose Diazo Salts Diesel Fuel Diglycolic Acid Dimethylemine Dimethyl Formamide Dioctylphthslste Disodium Phosphate Dowtherm Ethers Ethanolamine Ethyl Acetate Ethyl Acrylate Ethyl Alcohol Ethyl Chloride Ethyl Ether Ethylene Bromide Ethylene Cblorohydrin E S E E S II E u U L E E E E E E E E e E E E S G U E U U
1 1
Q 4
E E E u U E E E
E
NR NR NR 1
NR
NR
2 NR NR 4 3 4 2 1 1 1 1
NR R NR
NR NR NR
R R
E E E E E E E u L S L S S u S S
R R R
1 1
R R R R R R
R* R* R* R R R
4
R R R NR NR NR NR
R R
R R
Q i tm
Q
1 NR R R
R R
S S L E E E E E E E E E u E E E
E
NR
NR R* R
NR 1
1
Q
G 1 E E E 1 E u 0 II E u U u E U U U U 1 I : 3 R R
NR NR
R
R
R R
1 1 1 1 1 NB
R R R
NR NR R
4 1
R R R R R R
E E E E
-.
(continued)

Chemical
POLYVINYL
CHLORIDE
C
GOODRICH
(continued)
Cmpany
cwpa*y A
Company A u E u E E E E E E E L E E S s S E E E u E G E S S E E E E E E E S S S E G G E S S L L S E 6
Company B 739 NR 1
Cwpsny Chemical 1859 R Rydrogen Peroxide, 50% Hydrogen Peroxide, 90% Hydrogen Phosphide Rydrogen Sulfide, Aq. Sol Hydrogen Sulfide. Dry Rydroquinone AydroxyIsmine Sulfate Rypochloraus Acid Iodine fin Alcohol) Isopropyl Alcohol Jet Fuel, JP-4 Jet Fuel, JP-5 Kerosene Ketones Kraft Liquor Lacquer Thinners Lactic Acid, 25% Lard Oil Lsuric Acid Lauryl Chloride Lsuryl Sulfate Lead Acetate Lime Sulfur Lineolic Acid Linseed Oil Liquors, Liquers Lubricating Oils Magnesium Carbonate Magnesium Chloride Magnesium Hydroxide Magnesium Nitrate Magnesium Sulfate Naleic Acid Yalic Acid Mercuric Chloride Mercuric Cyanide Mercurous Nitrate Mercury Methyl Alcohol Methyl Chloride Methyl Ethyl Ketone Methyl Isobutyl Ketone Methyl Sulfate Methyl Sulfuric Acid Methylene Chloride Milk Mineral Oils n01ssses Motor Oil Naphtha Nsphthslene Nickel Acetate Nickel Chloride
B 3
Canpsny C 185op 739 R R
Ethylene Dichloride Ethylene Glycol Ethylene Oxide Fatty Acids Ferric Chloride Ferric Rydroxide Ferric Nitrate Ferric Sulfate Ferrous Chloride Ferrous Sulfate Fish Solubles Fluorine Gas Fluoroboric Acid Fluorosilicic Acid Formaldehyde, 35% Formaldehyde, 37% Formaldehyde, 50% Formic Acid Freon - 11 Freon - 12 Fructose Fruit Juices, Pulp Fuel Oils Fuel Oil with R2SOh Furfursl Gsllic Acid Gas - Coke Oven Gas - Manufactured Gas - Natural Gasoline - Refined Gasoline - Sour Gelatin GllXClse Glycerine (Glycerol) Glycol Glycolic Acid Green Liquor Aeptsne Rexsne Rexanol, Tertiary Rydrobrmic Acid, 20% Rydrochloric Acid, 0-25X Hydrochloric Acid, 25-372 Rydrocysnic Acid Aydrofluoric Acid, fOX Hydrofluoric Acid, 30% Rydrofluoric Acid, 50% Hydrofluoric Acid, 60% Rydrofluorosilicic Acid Rydrogen Hydrogen Cyanide Hydrogen Fluoride, Anhydrous Rydrogen Peroxide, 30%
u
S S
1 1 1 1 1 1
R R
R R
E E E S U G
3 3 3 4 3
R R R R R R R R
NR NR NR NR NR NR
G G L G G G S E e E G S E G E E E E E E E E E E S U U S S U S E E S U E E
2 NR
R R R R
R R
9 R R
4 NR R
NR
R 1 1 1 1 1 R
R R
R R
R R R
2 2 2 2 2 4 4 4
R 3 NR NR
R R R R R NR
NR R*
NR NR
NR NR
R* NR NR NR
NR R R R R R R
R NR 3
NR
(continued)

Chemical Nickel Nitrate Nickel Sulfate Nicotine Nicotinic Acid Nitric Acid, 10% Nitric Acid, 20% Nitric Acid, 30% Nitric Acid, 40% Nitric Acid, 50% Nitric Acid, 60% Nitric Acid, 68% Nitric Acid, Anhydrous Nitrobenzene Nitropropane Nitrous Oxide OCWD3l Oils and Fats Oleic Acid Oleum Oxalic Acid Oxalic Acid, 50% oxygen ozone Falmitic Acid, 10% Palmitic Acid, 70% Paracetic Acid, 40% Perchloric Acid, 10% Perehloric Acid, 70% Perchloroethylene Phenol Phenylhydrazine Phenylhydrarine Hydrochloride Phosgene Gas Phosgene Liquid Phosphoric Acid, O-501 Phosphoric Acid, SO-752 Phosphoric Acid, 85% Phosphorous, Yellow Phosphorous, Red Phosphorous, Pentoxide Phosphorous, Trichloride Photographic Solutions Picric Acid Plating Solution, Brass Plating Solution, Cadium Plating Solution, Chromium Plating Solution, Copper Plating Solution, Gold Plating Solution, Lead Plating Solution, Nickel Plating Solution, Rhodium Plating Solution, Silver
POLYVINYL
CHLORIDE
GOODRICH
Chemical
(continued)
Cwpany A E E E E E E E E E E E E E E E E E E E E E L E E E E E E E S E S u G E E E E E E E E R E E E
E
company A
E
Company B
CCQKLXbV
c .
185oF R
Ccmpany B
73oF E E E G G 2 G G U U S E E E U E E E S S U E U S U E G u 6 6 S S L U E U E E E E E E E E 1 3 2 R
company C 739 185oF R R R* R
2 2
R R R R 1 R R* R* NR NR
NR NR
1 1 1
R R R R R R R R R R R R
2 2
R R
R* NR
R R R R R R R R R R
R R R R* R* R R* R* R* R
Plating Solution, Tin Plating Solution, Zinc Potassium Acid Sulfate Potassium Antimonate Potassium Bicarbonate Potassium Bichromate Potassium Bisulfite Potassium Borate Potassium Bromate Potassium Bromide Potassium Carbonate Potassium Chlorate Potassium Chloride Potassium Chromate Potassium Cuprocyanide Potassium Cyanide Potassium Dichrmate Potassium Ferricyanide Potassium Fluoride Potassium Rydroxide, 0-20X Potassium Rydroxide, 35% Potassium Rypochlorite Potassium Nitrate Potassium Perborate Potassium Perchlorite Potassium Permanganate Potassium Persulfate Potassium Sulfate Potassium Sulfide Propane Propargyl Alcohol Propyl Alcohol Propylene Dichloride Rayon Coagulating Bath Selenic Acid Salicic Acid Silver Cyanide Silver Nitrate soaps Sodium Acetate Sodium Acid Sulfate Sodium Antimonate Sodium Arsenite Sodium Benzoace Sodium Bicarbonate Sodium Bisulfite Sodium Chlorate Sodium Chloride Sodium Chlorite Sodium Cyanide Sodium Dichromate Sodium Ferricyanide Sodium Ferrocyanide
NR
1 1 1 1
1 1
R
R
R R
1 1 1
R R
R R
1 1 R 2
1 1 1
R R R R
R R R R
1 1 1 1
R R R R R R R
R R R* R R R
E E E E
(continued)

c=vny
POLYVINYL
Ccmpany A B
CHLORIDE
C
GOODRICH
Chemical
(continued)
Ccmpany A Cwpany B 739 Company
Company
Chemical
1859 Sodium Fluoride Sodirnn Rydroxide, Sodium Rydroxide, Sodium Rydroxide, Sodium Hydroxide,
Sodium Sodium Sodium Sodium Aypochlorite Nitrate Nitrite Phosphate
1859 R
15% 30% 50%

70%
R R* R* R R
Acid
Sodium Silicate Sodium Sulfate Sodium Sulfide Sodium Sulfite Stannic Chloride Stannoua Chloride Stearic Acid Stoddards Solvent Sulfur Sulfur Dioxide, Dry Sulfur Dioxide, Wet Sulfuric Acid, O-10% Sulfuric Acid, 10-50X Sulfuric Acid, SO-752 Sulfuric Acid, 80% Sulfuric Acid, 75-902 Sulfuric Acid, 90% Sulfuric Acid, 93% kulfuric Acid, 94% Sulfuric Acid, 95% Sulfuric Acid, 96% Sulfuric Acid, 98% Sulfuric Acid, 100% Sulfurous Acid Sulfur Dioxide, Liquid Sulfur Trioxide Tamic Acid
R* R* R* R* NR NR NR NR NR NR NR
Tanning Liquors Tartsric Acid Tetraethyl Lead Tetrahydrofurane Tetrahydrofuran Thicmyl Chloride Titanic Tetrachloride Toluol, Toluene Tributyl Phosphate Trichloroethylene Tricresylphosphate Triethanolamine Triethylamine Trimethylpropane Trisodimn Phosphate Turpentine urea and Urine Vinegar Vinyl Acetate Water Water, Acid Mine Water, Demineralized Water, Distilled Fresh Water, Potable water, Salt water, Sea water, Sewage WI iskey
White Wines Xylem Zinc Zinc Zinc Zinc or Xylol Liquor
E E S U U S U U U U L S G E S E E U 4 1 1 NR NR NR 1
NR
NR
NR NR
NR NR
R R R R R
R R NR R* R R* R* R* R* R* R R R R NR R
G G G G G E E U E E E E
2 2 2 2 2
R R R R R R R R R R
Chloride Chromate Cyanide Nitrate Sulfate
NR 1
NR R
Zinc
32
Corrosion
Resistant
Materials
Handbook
TABLE
1.8:
EPOXY COMPOUNDS-DEVCON
Somple Size: l/2 x % x I Cure: 7 days at room temperature. Immersion: 30 days
Chemical Resistance of Devcon Epoxy Compounds
Product Name Plastfc Steel Putty Plastic Steel Lfqurd Piastrc Steel 5-Mtn Putty / Alumtnum / Alumfnum Puttv Lrqutd VG VG VG VG p VG VG 1 Carbrde Putty 1 Wear Reststant Puttv / Wear Resstant Lraurd VG VG VG VG VG VG VG VG VG VG Lrqurd Putty VG VG VG VG VG F Epoxy Sealer 100 1 All products _ are Vti In Water, SOtUrOted VG
son SOIuftOn. leOOf
VG
/
i
VG VG VG VG F
/ /
U VG VG F VG
1 1 j
VG VG VG VG U VG F U
/ /
U F F F F U VG F F
VG
1 /
VG VG F VG VG VG
/ /
1 1 ~ /
VG VG VG VG VG VG VG VG
1 1 1
VG
U
F VG VG VG
VG F F F F VG
i t
VGF
VG VG VG
VG VG VG
VG VG F F VG
Ceramfc Wear Compound Tile Adhesrve Pump Repour Compound Hfqh Temp Wear ResIstant Putty HrahTemp Ceromfc Puttv
F F VG
F F
U U F
j / / 1
1
VG VG VG VG VG VG VG VG VG VG
/ /
VG VG VG VG VG VG
/ I
VG VG VG F
Hugh Temp Mold Maker Tonkfte II Backfng Compound 1 Bocktnq Compound / Hfah lmpoct Bockma / Wet Surface Reparr Puttv
/ 1 1 1 I /
VG VG VG VG VG
/ /
VG VG VG F U U
1
/
VG VG VG U
j i ] 1
1
VG VG VG VG VG VG VG VG
, 1
U F VG U VG II VG
u
U F U VG F VG
/ / I I
u
U F U u U U
F F VG F VG
U U F VG F
VG VG VG F VG
/ /
VG VG VG VG F VG
gasolrne, mtneral spwts, ASTM 3 011and propylene glycol Key. VG-Very Good; F-Fas U-Unsdsfoctory
CAUTION: Epoxres ore generally not recommended for long term exposures to concentrated ocfds and orgonfc solvents
TABLE
1.9:
EPOXY
PIPE AND
FITTINGS-AMERON
BONDSTRAND Series 1200 and Series 1600 are unlined epoxy products produced by the filament-winding process. Series 1200 piping offers the user a locked Q-ring joint for quick, reliable joining of either suspended or buried pipe systems, even under adverse weather conditions. For those users who prefer the rugged strenqth and performance of the QUICK-LOCK@ adhesive bonded joint, Ameron offers Series 1600 piping with its heavier pipe walls, longer spans and greater ring stiffness..
Chemtcal Solution
C
1,
Chemical Solution
oncen-
-L
F C 24 G 99 66 99 38 66 36 93 4R 24 dR JR ilR 66 JR 66 43 43 93 99 77 99 77 93 99 66 77 39 39 r* v 1/ NR NR NR _ lr NR Phosphoric Acid NR v NR NR rr Y NR NR NR w Magnewm Magnesum Male~c Actd Maleic AnhydrIde Mefhyl Alcohoi Methyl Chlor,de Methyl Ethyl Ketone Methyl lsobutyl Ketone Methylene Chloride Mineral Oil Monochlorobenzene Naphtha Natural Gas Nickel Chloride Nlckei N~frale Nickel Suitate N,,ric Acid? NI!~ Aod Oil (crude) Ole~c Acid Perchloric Acldl Perchlowthylene Phenol
<l% >I%
.3t10lY
--F Acetic Acid

1
C 66 NR 24 NR 99 99 99 93 99 66 49 36 66 99 99 24 93 49 66 93 66 99 66 93 93 24 66 24 YR 24 Chloroform Chlorine Gas wet Chlorinated Bwe Chlowated Wale? I-50 ppn >50 pprr O-IO%
F NR NR NR 150 NR NR 210 2w 200 210 210 100 120 120 150 200 NR 150 120 120 100 100 NR 100 NR 210 100 170 150 210 -
C NR YR VR 66 VR UR 99 93 93 99 99 38 49 49 66 93 VR 66 49 49 38 38 \iR 36 \iR 99 36 77 66 39 V NR rr V NR 1/ V V r/ NR r/ w _ V NR NR I/ NR NR Hydrofluoric Hydrofluosillc Acid Acid O-25 ~ Formaldehyde Formc Acid Fuel O,i Gasoi~ne Glycerin Green Liquor (paper) Heptane Hexane Hydraulic 011s Hydrobromlc Hydrochloric Aced Acid
F NItrate Sullate 200 210 770 150 1w NR 100 100 NR 210 1W 210 210 210 160 210 1.10% 10.70% 75 NR 210 2cc 0.70% 75 100 75 NR 1W 75 75 NR 103 210 I
C 93 99 77 66 38 \IR 36 38 \1R 99 36 99 99 99 62 99 24 QR 99 33 24 36 24 \lR 38 24 24 m 38 99 NR NR NR NR NR NR NR NR NR v w w w NR rr NR NR v
150 NR 75 NR 210
75 NR 210 150 210 100 150 100 200 NR
ACelOne Acrylic Acid Air A,rnlrn Potassium Sulfa te
Chlorinated Water Chrome ACIC C~tw Acid Copper Chlwde Copper N~tra:e Copper Sulfa% Crude Oil (sweet 8 sour) Cyclohexano Detergents D~ailylpnthalate 0-Dichlorobe?zene Diesel Fuei Diethylene Tr,anine D,prooylene Gyco! Ethyl Acetate Ethyl Acrylatf Ethyl Alcoho, Ethyl Benzene Ethy: Chloride Ethyl Ether Ethylene Dlch,ortde Ethylene Glyco Fatty Acids Femc Chloride Ferric Nitrate Femc Sulfate
210 210 200 210 150 120 100 150 210 210 75 200 120
klum~num Chloride Aluminum Alumuum Nitrate Sulfate
Ammonla Gas Dry Ammonium Ammonium Ammomum Ammontum Ammonium Al?lllX? Barium Chloride Benzene Black Liquor (paper mfg Chloride Hydroxide Phosphate Sulfate Nitrate
% IX or
Z-1
75 NR NR NR 150
Hydrogen Chiortde Gas Hydrogen Peroxide Hydrogen Sulllde lodlne (Sal @ R T) Isopropyl Alcohol Jet Fuel Kerosene Lactic Acio Latex Solulions Lead Nitrale Linseed 011 Lllhium Chloride L,thum Hydroxide Magnesium Magnewm Magnestufr Carbonate Chloride HyOroxlde O-30
NR 150 120 120 200 210 170 210 170 200 210 150 170 210 210 -
150 200 150 210 150 200 200 75 150 75 NR 75 -
Born Acid
Bromine Water Calctum Chlonde Calcium Hypochlonte Calaum Nitrate Calcum Sulfate Carbon Dlsulflde Carbon Tetrachlorzde Chloroacetlc Acetic Chloroacellc Acid-Glac\a
0.2% 2.25% !5-50% jO-65%
_ _
v
rr Polyvinyl Alcohol Em&Ion Potaswm Chlonde
_
I/
Chlorobenzene
on- lued)
TABLE
1.9:
EPOXY PIPE AND FITTINGS-AMERON

Chemical Solutton
(continued)
F Po:aswrr Potaw~m Potassium Potaswm Polaswm Propylene Cyanide Fluortde Hydroxide Nitrate Sulfate Glycol 0.30% 0.50% 210 150 1cO 210 210 T 210 210 200 c-10% 0.50% S&urn Chlorate 210 150 210 210 I
C 99 66 36 99 99 99 99 93 99 66 99 99 Sodurn Cyanide S&urn Hydroxide
B
SL
bll
Chemical
Soiut~on
Chemvzal
Solution
Concen-
Temperature
Gasket
;.,.;.~
Tanmc Acld .Tartaric Acid
Sodturn Bromide SDd~um Blsulfate Sodium Carbonate
TABLE 1.10:
DURCON
EPOXY RESIN-DURIRON
epoxy which is silica filled.
1
Tetrachlorwthylene Toluene Tr,chlorcethylene Trlethanolam!ne Vinegar water (salt) Water (fresh) Xylene Ztnc Chloilde
v
rr i,
Y
I I I I Where no concentration is shown, recommendations apply to any concentration up to 100% or to saturatton. %enes 5000 pipe can be expected to provide a ionger service life in thts environment. JGeneral fluid compatibility of standard polymer used in O-ring gasket for Bondstrand Series 1200 piping. Vor water contaminated with oil or fuel, standard polymer provides suitable performance at temperatures up to 180F (82C). ti Standard Gasket OK NR Not Recommended - Not Tested
4 8 9. 9 $ P 6 w x
Water (dlslllied or delorwed:
v
NR ,,
3
3 8 *
6 js a solid, cast thermosetting
The following
is a list of typical
applications
for DIJRCON
6. Sodium Thiosulfate, 200~ F Stannic Chloride. 200 F Sulfite Liquors. I5OF Sulfur Chloride. 15O.F Sulfuric Acid, 305, 200 F Sulfuric Acid, X-r, 150-F Sulfuric Acid, PO%, 125 F Tannic Acid, 2&I F Tartaric Acid, 200-F Thiophenol, 200 F Toluene, 175 F Trichloroacetic Acid. 125F Trichloroethylene, boiling Urea, 200F Linegar, 200 F Water, boiling Zinc Chloride, 200F Zinc Sulfate, 200F
Acetic Acid, 7O?, 200F Acetic Acid, Glacial, 200-F Acetone, boiling Acetyl Chloride, boiling Alcohol, 175F Alum, 2OOF Aluminum Chloride, 2@IcF Ammonium Bisulfite, 150F Ammonium Chloride, 200-F Ammonium Sulfate, 200F Amy1 Acetate, 2OOF Amy1 Alcohol, 175F Amy1 Chloride, 200cF Aniline, 15OF Anod zing Solutions, 200 F Antimony Trichloride, 150-F Benz;Idehyde, 200. F Benzene, boiling Benzene Hexachloride, I75* F Black Liquor, 200~F Brine, 200-F
Butvric Acid, 200F Calcium Chlorate. 150 F Calcium Chloride. 200 F Carbon Tetrachloride, boiling Chloracetic 4cid 1 . 125F Chlorinated \Vater, IFiOF Chlorine Dioxide. 150 F Chlorine, IYet, 150 F Chlorobenzene, 175-F Chromic Acid, 305, ambient Citric Acid, 2OOF Copper Sulfate, 2OOF Cupric Chloride, 200 F Dichlorobutane, 2OOF Dimethyl Formamide, 200-F Diethyl Sulfate, 200F Ethyl Alcohol, boiling Ethyl Ether, boiling Ethyl Nitrate, boiling Ethylene Dichloride, 150 F Fatty Acids, 2OOF
Ferric Chloride, 150. F Ferric Nitrate, 2OOF Ferric Sulfate, 200cF Formaldehvde, boiling Formic Acid, boiling Hydrobromic Acid, 40$. 200F Hydrochloric Acid, IO?, 200F Hydrochloric Acid, 205, 200 F Hydrochloric Acid, 305, 2OQF Hydrochloric Acid, cont.. boiling Hydrocyanic Acid, 125F Hypochlorous Acid, 125-F Lactic Acid, 200-F .Ilagnesium Chloride, 2OOF Magnesium Sulfate. 200 F ?rlaleic Acid, 200 F Malic Acid. 200 F Mercuric Chloride, 200 F hletal Plating Solutions, 150-F hlethyl Alcohol. boiling Methyl Ethyl Ketone, boiling
Nickel Chloride, 200 F Nickel Sulfate, 2OOF Nitric Acid, IO%. 175-F Nitiic Acid, 5O%, ambient Nitrobenzene, 150-F Oleic Acid, 2OOF Oxalic Acid, 200F Perchloroethylene, 200-F Phenol, 125-F Phosphoric Acid, 85%, 2OOF Phosphorous Oxychloride, 150F Phthallc Acid, 2OOF Potassium Nitrate, 200F Rayon Spin Bath, 200-F Sea RBter, 200-F Sodium Bicarbonate, li5F Sodium Bisulfate. 200 F Sodium Chloride, 200 F Sodium Nitrate. 200 F Sodium Perchlolate, 100 F Sodium Sulfate. 200 F
Synthetic
Resins and Polymers
35
TABLE
1.11:
EPOXY
RESINS-SHELL
CHEMICAL
These amine-cured EPON resin coatings are unique because they cure at room temperature. They are outstanding for their resistance to heat, solvents, salt water, and most other corrosive materials, and have notable resistance to mechanical shock and abrasion. EPON resin coatings exhibit excellent adhesion and flexibility over wood,.ferrous and nonferrous metals, and green or dry concrete. These coatings have outstanding weatherability and the high solids content which is possible at application viscosity. Applications for these coatings are as finishes for wood, metal, and environment, as chemical resistant finishes for installed equipment Coating formulations must be supplied as two-package systems, i.e., base component containing the EPON resin. The usable working life concrete in marine and other severely corrosive where high-temperature baking is impractical. the curing agent packaged separately from the
is a 10 to 15 hour period after the curing agent
is added.
A high solvent portant coating
degree of cure is obtained
overnight, but about five to seven days are required for maximum chemical and resistance properties to develop. More rapid cures can be obtained by forcedrying or baking. The most imreaction involves the crosslinking of the EPON resin with the polyfunctional amine curing agent. The epoxy systems referred to below are as follows: System 1: A fourcoat Svstembased on two coats of a long oil linseed ester red lead
primer Plus two Coats of a long oil soya ester topcoat for a total film thickness of 6 to 6 mils. SWem 2: A fourcoat swtem based on two coats of EPON resin lOOl/EPON curing agent C-l 11 red lead primer plus two coats of the EPON resin 1001/C-l 11 topcoat for a total film thickness of 6 to 6 mils. Swtem 3: A four-coat system based on two coats of EPON resin lOOl/EPON curing agent V-15 red lead primer plus two coats of the EPON resin 1001/V-15 topcoat for a total film thickness of 6 to 6 mils. System 4: A two-coat n/stem based on EPON resin 815/EPON curing agent H-2 applied to a total film thickness of 8 to 10 mils. Code: R = Recommended for immersion service R(S) = Recommended for spillage only NR = Not recommended
Coating Systems 1 Oxidizing Agents

NR NR R R NR NR R R Hydrogen peroxide, 30% Sodium hypochlorite, 5% Calcium hypochlorite, 5% Chromic acid, 40% Chromic acid, 5% Sulfu dioxide solutions Chlorine water
3
NR R R NR NR NR R
4
NR R R
NR NR R R
R(S)
R(S)
NR NR R(S) R(S)
Gases (Moist)
Carbon dioxide Sulfur didxide Chlorine Hydrogen sulfide R NR NR NR R R NR R R R NR R
R R
NR R
Acids
Sulfuric, 10% Sulfuric, concentrated Hydrochloric, 10% Hydrochloric, concentrated Nitric, 10% Nitric, concentrated Phosphoric, 10% Phosphoric, concentrated
R(S)
NR R(S)
NR
R(S)
NR R R(S) R(S)
NR
NR NR R(S) R(S) R(S) NR R(S) NR
R NR R R(S) R(S)
NR R NR (continued)
R(S)
NR
R(S) NR
R(S) NR
36
Corrosion
Resistant
Materials
Handbook
TABLE
1.11:
EPOXY RESINS-SHELL
CHEMICAL
(continued)
Coating Systems 1
Hydrofluoric, 10% Hydrofluoric, 30% Lower fatty, e.g., acetic, 20% Lower fatty, e.g., acetic, concentrated Higher fatty, e.g., oleic Organic food, e.g., citric Alkalies Sodium hydroxide, dilute Sodium hydroxide, concentrated Calcium hydroxide Ammonium hydroxide, dilute Ammonium hydroxide, concentrated Ammonium salts Sodium carbonate Salt Solutions (5%-l Alum Ferrous sulfate Copper sulfate Sodium chloride Calcium chloride Sodium sulfate Sodium phosphate Sodium acetate R(S) R 61 R R R(S) P R R R R R R(S) R R R R R R R(S) R R
2
R(S) NR NR NR R R
3
R(S) NR NR NR NR R
4
R(S) NR NR NR R R
NR NR NR NR NR
R(S)
0% concentration)
R R(S) R(S) R R R R R
Water Tap
Distilled Sea Solvents Chlorinated hydrocarbons (except methylene chloride) Aromatic hydrocarbons Aliphatic hydrocarbons Alcohol (methyl, ethyl, and butyl) Ethers Esters Ketones Phenol Furfuryl alcohol Furfural NR NR NR R NR R R NR R R R R
NR R(S) R(S) R(S) R(S) NR NR NR NR NR
R R R R R R(S) R(S) R(S) R(S) R(S)
R(S) R R R R R(S) R(S) R(S) R(S) R(S)
R R R R R R R
l
R(S) R(S) R(S)
Fats and Oils

Mineral Animal Vegetable
R(S) R(S)
R(S)
R R R
R(S) R(S) R(S)
R R R
Halogens (Moist)
Chlorine Bromine lodi ne NR NR NR NR NR NR NR NR NR MIBK NR NR NR and above.
*Esters are not recommended for continuous immersion service, only limited service.
Synthetic
Resins and Polymers
37
TABLE
1.12:
FIBERGLASS INLAND
REINFORCED
EPOXY
AND
VINYL
ESTER
PIPING
SYSTEMS-A.O.
SMITH-
RED THREAD II Pipe: An unlined fiber glass reinforced epoxy resin pipe with the ability to solve corrosion problems in light chemical service at temperatures up to 21OF. GREEN THREAD Pipe: Fiber glass reinforced epoxy resin pipe with a glass mat reinforced epoxy resin liner. Provides superior corrosion resistance at temperatures up to 225F. POLY THREAD Pipe: Fiber glass reinforced vinyl ester resin pipe with a glass mat reinforced vinyl ester re.sin liner intended for use in corrosive services at temperatures to 200F. Final liner thickness not less than 20 mils. Vinyl esters have better chemical resistance than epoxies in high acid concentrations and to oxidizing agents.
Chemical Resistance
MAXIMUM CHEMICAL RECOMMENDED TEMPERATURE F FOR PRODUCTS LISTED Red Green Thread II Thread Thread MAXIMUM CHEMICAL
N.R.-Not
Recommended
N.T.-Not
Tested
RECOMMENDEDTEMPEFIATUAE
pw
F FOR PRODUCTS LISTED Red Green POIV rhread II Thread Thread
Acetic Acrd, 10% Acetic Acid, 25% Acetrc Acid. 50% Acetlc Acid, 75% Acetic Acid. Glacial Acetone Acryhc Acid, 95% A&r(Wet or Dry)
Alummum Chloride. 1% Alumtnum Potasstum Sulfate, 56% Aluminum Sulfate, 50% Ammonia Gas-Dry*** Ammonium Hydroxide. 10% Ammontum Hydroxide. 26% Ammontum Persulfate. 30% Ammontum Nrtrate, 25% Anolyte Beer Benzene Benzene Sulfonic Acid, 5096 Benzene Sulfonic Acid, 75% Benzene Sulfonic Acid, 100% Black Liquor (Pulp Mill) Boric Acrd. 4% Bone Acid, 20% Bromoform Bromme Water, 4% Butyl Acetate Bury1 Cellosolve Calcrum Chloride, 37.5% Calcrum Hypochlorite, Satd. Carbon Disulfrde Carbon Tetrachloride Chloroacetic Acid, 10% Chloroacetic Acid, 25% Chloroacetrc Acrd, 50% Chloroacetrc Acrd, Glacial Chlorobenzene Chloroform Chlorothene Chlorine Gas, Wet t l ** Chlorine Saturated Brine d Chlorinated Water-G100 ppm Cl, Chlonnated Water-1~2CQ+mCI Chlorinated Water - Saturated $ Chromic Acrd. 5% Chromic Acid, 10% Chromic Aod. 30% Citric Acrd. 32% Coca-Cola (Syrup) Copper Sulfate, 17% Cresol 5% Cresol 10% Dichlorobenzene (Ortho) Drethylene Triamine Drmethyl Formamide
150 N.R. N.R. N.A. N.R. N.R. N.R. 210 210 210 210 150 lo0 100 N.T. 210 N.R. 210 120 N.T. N.T. N.T. 150 210 200 N.R. N.R. 75 150 210 N.R. 120 150 100 N.T. N.T. N.R. 100 N.R. 100 N.R. N.R. 150 N.R. N.R. N.R. N.R. N.R. 210 100 210 75 N.T. 150 N.R. N.R.
200 120 120 120 75 120 100 225 225 225 225 225 150 100 75 225 150 225 150 N.T. N.T. N.R. 225 225 225 N.R. N.R. 150 150 225 N.R. 120 150 120 N.T. N.T. N.R. 150 N.R. 120 N.R. N.R. 225 200 N.R. N.R. N.R. N.R. 225 150 205. 120 75 150 N.R. N.R.
200 200 150 150. 75 N.R. N.R. 200 200 N.T. 200 N.T. 120 150 200 2oD N.T. N.T. 75 150 150 N.R. N.T. 200 200 N.T. N.T. N.T. N.T. 200 150 N.T. 150 N.T. 120 150 N.T. N.R. N.T. 75 150 150 200 200 156 150 150 N.R. N.T. N.T. 200 N.T. N.T. N.T. N.R. N.T.
Dioxane Distillery Stillage Distillery Syrup Divinyl Benzene Dowanol EE Dowanol EM Dovviax BNB-Surfactant (NonylPhenol-Ethylene Oxde Condensate) Dow Latex 560 Dow Latex 700 Dow Latex 2144 Ethyl Acetate Ethyl Acrylate Ethyl Alcohol Ethyl Benzene Ethyl Ether Ethylene Glycol. 100% Ethylene Glycol-50% in Water Femc Chloride, 10% Ferric Chlonde 40% Ferric Sulfate, 10% Ferric Sulfate, 40% Formaldehyde Formic Acid, 88% Freon 12 OT 22 (Gas or Liquid) Gasolrne, 100 Octane Glycerine Glyoxal Green Liquor (Pulp Mill) Hexane Hydrdwomic Acid, 10% Hydrcbrornic Acid, 20% Hydrobromic Acid, 51% Hydrochloric Acid, 1% Hydrochloric Acid, 10% Hydrochlonc Acrd. 20% Hydrochloric Acid. 36.5% Hydrofluoric Acid, 1% Hydrofluoric Acid, 5% Hydrofluoric Acid, 10% Hydroflweilicic Acid, 25% Hydrogen Chloride-Gas, Dry*** Hydrogen Peroxide, 10% Hydrogen Pemxide, 27.5% Hydrogen SuHie Gae** Iodine (Satd. at Room temp.) Isopropyl Alcohol Jet Fuel (Super Refined Kerosene) Kerosene Lactrc Acid, 50% Lithium Chloride (Satd at Room Temperature) Lithium Hydroxide (Said. at Room Temperature) Magnesium Chloride, 24% (Mp Cf,6H,D)
N.R. 150 150 100 75 N.R. 100 210. 210 210. 75 120 75. 120 100 210 210 150 150 210 210 75 N.R. N.T. 210 210 N.T. 100 100 N.R. N.R. N.R. 75 N.R. N.R. N.R. N.T. N.T. N.R. N.R. 150 N.R. N.R. 150 120 100 150 210 120 210 150 210
75 150 150
N.T. N.T.
N.T.
N.T. N.T. N.R. N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. N.T. 200 2clo 200 200 N.T. 75 N.T. 75 N.T. N.T. N.T. 75 2Dct 200 150 200 2cxl 200 150 150 150 75
100.
75 N.R. 100 225 225 225 120 120 120 150 100 225 225 205 205 225 225 120 N.R. 75 225 225 120 205 loo
15Ql) 15ql) loQ1,
15Ql)
15Ql) 1541)
75.11 N.T. N.T. 7541) loql,
150 N.R. N.R. 150.

150 120 150 225 225 225 205. 225
200 N.T. 75 75 N.T.

N.T. N.T. N.T. N.T. N.T. 200 N.T. 200
(continued)
TABLE
1.13:
FIBERGLASS
REINFORCED
FURAN
POLYMER-QUAKER
OATS CHEMICALS
QUACORR MEDIA GUIDE
QUACORR is the trademark for furfuryl alcohol based resin/catalyst systems developed by the Quaker Oats Company for the manufacture of fiberglass reinforced plastic (FRP) equipment. QUACORR laminates exhibit a broad range of solvent and chemical resistance combined with excellent physical, flame spread, and smoke development properties. The QUACORR@ Media Guide provides guidelines QUACORR FRP equipment in corrosive media. for the proper application of
MEDIA
CONCENTRATION
TESTofEMP.
s u R.T. I50 B.P.(214) R.T. I50 B.P. 150 (240) X X X X X X X
ACETIC
ACID
25% 25% (GLACIAL) 25% 100% 100% 100%
ACETIC
ACID
ACETIC
ACID,
SODIUM XYLENE, METHANOL, ACETIC
CHLORIDE, DICHLOROPHENDL, ANHYDRIDE,
POTASSIUM BROMOSODIUM
Unknown
The data in this bulletin have been compiled from laboratory testing of QUACORR 1001/2001 laminates prepared in accordance with U.S. Department of Commerce Product Standard 15-69. Laminates were evaluated using the ASTM C-581 test method which requires total immersion of the laminates in test media. Data were obtained from coupons exposed to media for a minimum of three months and, in most cases, one year and compared to unexposed control laminates. Recommendations are based on an evaluation of the following properties: weight change, thickness change, visual appearance, flexural strength, flexural modulus, and Barcol hardness. Based on the results of one year testing in the media specified in ASTM Test C-581, this corrosion guide can also be used for QUACORR 1500 FR.
CHLORIDE, HYDROXIDE, ACETIC ACETIC POTASSIUM HYDROXIDE, ACETONE ACETONITRILE ACRYLIC ACRYLIC METHANOL, ACRYLONITRILE ALCOHOLS
DICHLOROPHENOL,
TRICHLOROBENZENE 100% SODIUM XYLENE, ACETIC CHLORIDE, DICHLDROPHENOL, ACID, SODIUM Unknown I50 150 X X
ANHYDRIDE ANHYDRIDE, CHLORIDE, METHANOL,
BRDMODICHLCROPHENOL,
TRICHLOROBENZENE 100% 100% I 501. R.T. R.T. 176 X X X X
ACID ACID, SULFURIC ACID, METHACRYLATES,
100% 6:60:5:5:24
WATER2. 100% (HEAVY), MALEIC (pH I-12) 100% (TRACE), HYDROCHLORIC Unknown R.T. R.T. X X ACID, SODIUM FUMARIC BISULFITE, Unknown I50 190 X X
-KEY s U R.T. Satisfactory
ACID, HEPTANE, ALKYD
SODIUM
HYDROXIDE,
HEXANE RESIN CHLCRIDE
Unsatisfactory ALKYL Rcnrr (70F Temperature to gOoF) ALLYL CHLORiDE FLUORIDE POTASSIUM SULFATE 100% Sat. 5% 5% 5% AMINES (ORGANIC), ACID NITRO COMPOUNDS, Unknown B.P. R.T. R.T. 150 R.T. I50 (212) ACID (AQUEOUS1
X X X X X X
@.P. SAT. CONC.
Boi
I Ing
Point ALUMINUM
Saturated ALUMINUM
Concentrated
HYDROCHLORIC
::
Tested under Recommendation
pressure. based
on
successful
case
histories.
(continued)
TABLE 1.13:
FIBERGLASS
REINFORCED
QUACORR MEDIA GUIDE
FURAN
POLYMER-QUAKER
EST TEMP OF
OATS CHEMICALS
(continued)
QuACCRR MEDIA GUIDE
MEDIA
QNCENTRAT
I oh
Af+!CNIUM
ACETATE
Sat. Sat. SULFATE, SULFURIC ACID 01 lute 20% 100%
R.T. 150 250 R.T. 150
X X CARBCN TETRACHLORIDE, ACETATE SOLVENT ALCOHOLATE AROMATIC SOLVENT CHLOROFORM, WATER X CELLOSOLVE X CELLOSOLVE X CHLORAL X CHLORINATED
AMMON I UM BROM I DE AfwINILIM At+t0JIUM ANILINE AQUA REGIA HYDRDSEN HYDROXIDE
BENZALDEHYDE BENZENE BENZYL CHLORIDE
100% 100% 100% 100% 100% 100% LIQUOR2
150 150 R.T. 150 R.T. 150 R.T. 150
X X X X X X X X CrlLOROFORM, CARBON (MIXED TETRACHLORIDE, ISOMERS) 100% p-c%lLOROPHENOL 95% 95% CHLOROSULFQNIC CHLCROTHENE N.U. ISOMERS) ACIDI. 100% 150 R.T. 150 R.T. R.T. 150 150 150 B.P. (312) 150 R.T. 150 B.P.f212) 150 X X X X X X X X X X X X X X WATER X CHLOROPHENOL X CHLOROACETIC CHLOROFORM ACID (TRI) MLCRINATED CHLDROETHANE, CHLORINE CHLORDACETIC SOLVENTS (TRACE). TRIHYDROCHLORIC ACID (DILUTE) (FREE?. ACID (MONO)
0-BENZYL-p-CHLOROPHENOL
BLACK
PULP
MILL
BORAX BROMINE
SOLUT
Icd*
Sat.
150
(FREE13 SODIUM XYLENE, ACID, ACETIC METHANOL, CHLORIDE, DICHLDRCANHYDRIDE, TRICHLOROUnknown 150 X
BRCMODICHLOROPHENOL, POTASSIUM PHENOL, SCDIUM BENZENE CHLORIDE, ACETIC HYDROXIDE,
100%
100% 100% 100% 100%
BUTYL BUTYL
ACETATE ALCOHOL
100% lOO% 3.P.
I I3 (243)
X CRESOL X CYCLMEXANE X CYCLCHEXANONE X (MIXED
BUTYRALDEHYDE CALCIUM CARBON HYPQCHLORITE DISULFIDEA
100%
150
100%
3.P.fll5)
CYCLOHEXYLAMINE DEMINERALIZED WATER
100s 100%
100% 100%
1. 2. 3. 4.
QuaCorr Consult Maxlmum loh
service Technlcal allowable
In
thls Servlce
media on be on
should temperatures have
be not
dlscussed higher been Testing historles.
with than deftned. Is
Technical 15OF. QuaCorr
Service. servlce at
concentrations may based satisfactory. successful
concentrations
recommended.
Recoranendation
case
DICHLDRETHANE
(1.2)
IOOl
concentrations may be satisfactory. have not
1.
Maximum low
allowable
concentrations
been defined. QuaCorr Test 1 ng is reccminended.
servlce
at
(continued)
TABLE 1.13:
FIBERGLASS
REINFORCED
@JACDRR MEDIA GUIDE
FURAN
POLYMER-OUAKER
OATS CHEMICALS
(continued)
QJACORR MEDIA GUIDE
MEDIA
DNCENTRAT
IO
:EST TEMP OF 100-120 190
DICHLOROBENZENE1 o-DICHLOROBENZENE, (DILUTE), SODIUM FUMARIC ACID, HYDROCHLORIC ACID bYDROXlDE, MALEIC ACID, ALCOHOL SODIUM
98% Unknown
X X
Z-ETHYL ETHYLENE WATER
BUTYRIC
ACID HYDROCHLORIC ACID,
CHLOf?OtiYDRIN,
ISOPROPYL 513% 7 IO) SODIUM MALEIC
0-DICHLOROBENZENE, HYDROXIDE (pH
Unknown
ETHYLENE
DIAMINE
o-DICHLOROBENZENE, ISOPROPYL ALCOHOL, ACID DICHLOROPHENDL DICHLOROPHENOL, ACID, XYLENE, ANHYDRIDE, CHLOROBENZENE DIESEL DIETHYL FUEL CARBONATE POTASSIUM SODIUM (2.4)
HYDROXIDE, ACID, FUMARIC
Unknown
ETHYLENE ETHYLENE
DIBROMIDE DICHLORIDE GLYCOL ACIDl ACID
100% CHLORIDE, METHANOL, ACETIC TRIACETIC Unknown
UHYLENE FLUDE0RlC FLUOSILICIC
SDCIUM CHLORIDE,
BROMODICHLOROPHENOL, HYDROXIDE,
FDRMALDEHYDE
IO05 100% 100%
150 B.P.(257) R.T. R.T. 300 I50 150 3.P.(212) R.T. I50 3.P.(l71) II3 R.T. R.T. I50 3.P.(l73)
X X X X X X X
FDRMALIN FDRMIC ACIDl
DIETHYLAMINE DIMETHYL DIMETHYL FORMAMIDE*. PHTHALATE
FUEL OIL FUMARIC ACID, HYDROCHLORIC ACID (DILUTE), SODIUM HYDROXIDE, MALEIC ACID, ISOPROPYL ALCOHOL, o-DICHLOROBENZENE FUMARIC ACID, MALEIC ACID, HYDROXIDE, SODIUV BISULFITE, HEXANE, HEAVY ALCOHOLS (pH SODIUM HEPTANE, l-12)
100% 100% 100% 100% 100% 100% 100% 100% sat. 100%
DIMETHYL DISTILLED
PROPANOLAMINE WATER
X X
X X
ETHYL ACETATE
FUMARIC ACID, SOOIUM HYDROXIDE, MALEIC ACID, o-DICHLORDBENZENE, ISOPROPYL ALCWOL FUNDAL
ETHYLACFTOACETATE ETHYL ACRYLATE

ETHYL ALCOHOL (ETHANOL)
*
METHYL PARATHION ALCOHOL RESIN SPIRIT, KEROSENE,
FUNDAL, X FURFURYL
X X X
951 95% 95%

with concentraticns may be otter media. have satisfactory. not been Testing defined. Is
GAS OIL, MINERAL PENlACHLCi?Df+lENOL 1.
1.
2.
Tested Maxlmum lower
in
combination
f+!axlmum allowable
lower COnCentratlOnS Fundal to 7 I part
concentrations may parts be water.
have sailsfactory.
not
been Testlng
defined. Is
QuaCorr recomnended.
ser~lce
a+
allohable
concentrations
QuaCorr recommended.
servlce
al
2.
(continued)
TABLE 1.13:
FIBERGLASS
REINFORCED
QUACORR MEDIA GUIDE
FURAN
POLYMER-QUAKER
OATS CHEMICALS
(continued)
rEST
__. .__.. __ s
X X X X X HYDROCHLORIC CHLORIDE, HYDROFLUDRIC HYDROGEN HYPOCHLOROUS MEDIA
__ __
TEST CONCENTRAT ION TEMP. OF s u
MEDIA GLYOXAL GREEN PULP MILL LIQUOR.
IC DNCENTRAT
IC+
TEMP OF
40%
150 R.T. 150
ACID WATER ACI D1 PEROXIDE ACID
(DILUTE),
VINYL
Unkrow
R.T.
15% I%
R.T. R.T.
X X X
n-HEPTANE
100%
100% 100% B.P.
R.T. I50 (208 199
X X
HEPTANE, SODIUM HEXANE, HEXANE, SODIUM ALCOHOLS HYDROBRmlC HYDROCHLORIC
MALEIC HYDROXIDE, HEAVY MALEIC BISULFITE, (pH
ACID, ALCOHOLS ACID, I-12)
FUMARIC (pH l-12)
ACID,
Unknown
SODIUM
BISIJLFITE,
I SOPHORONE
ISOPROPYL (DILUTE), FUMARIC ISOPROPYL ALCOHOL, HYDROCHLORIC ACID SOOIUM HYDROXIDE, MALEIC ACID, ACID, o-DICHLDROBENZENE MALEIC SODIUM MALEIC ACID (DILUTE)
100% Unknown
II3 190
X X
FUMARIC ACID, HEPTANE, HEAVY
Unknown
190
ALCOHOL, ALCOHOL,
Unknown Unknown
190 190
X X
ACID ACID
48% 15% 15% 25%2. 30%2.
R.T. R.T. I50 150 I50 R.T.
ISOPROPYL ACID I SDfRDPY ISOPROPYL KELEX
HYDROXIDE, ACID, FUMARIC
o-DICHLORDBENZENE,
L ETHER MYRISTATE. ( SOLVENT KEROSENE SULFURIC EXTRACT ACID I O+J 1,
100% 95:5 U know
II3 185 75
X X X
HYDROCHLORIC ACID CHLORIDE (TRACE) HYDROCHLORIC WATER HYDROCHLORIC AMINES (ORGANIC) ACID, ACID,
CAQUEOUS,,
ALKYL
Unknown
L I GANC ACID,
ETHYLENE
CHLOROIYDRIN,
20:5:75
160-180
SULFURIC KEROSENE
ACID,
NITRO
COMPOUNDS,
Unknown
R.T.
100% 100% 100% OIL, MINERAL SPIRIT, 32:31:32:5
R.T. 150 B.P. 150 (266)
X X x X
HYCJROCHLORIC WATER HYDROCHLORIC WATER HYDROCHLORIC HYDROXIDE, o-DICHLDROBENZENE, HYDROCHLORIC MONCCHLORIDE
PHOSPHOROUS
6:75:
19
R.T.
KEROSENE, GAS PENTACHLORCPHENOL KEROSENE, LIGAND,
ACID,
PHOSPHOROUS
ACID,
6:75:
19
150
SULFURIC KELEX ACID; CHLORIDE ACID PULP
ACID,
KELEX EXTRACTION);
LIGAND
Unknown Unknown
75 75
X X
(SOLVENT KEROSENE
ACID MALEIC
(DILUTE), ACID, ISOPROPYL
SODIUM FUMARIC ACID, ALCOHOL SULFUR
Unknown
190
SULFURIC LITHI,UH MAGNEFITE
34% MILL LlpUOR3.
B.P. R.T. I50
(280)
X X X X
ACID, SULFUR, (VAPORS) (DILUTE), SOLVENTS
Unknown
200
HYD7OCHLORIC ACID ETHANE, CHLORINATED
TRICHLORO(TRACE)
Unknown
R.T.
t4ALElC HYDROXIDE, HEXANE,
ACID, HEAVY
FUMARIC SODIUM ALCOHOLS Technical allowable TechnIcal
ACID, (pH Servlce
SODIUM HEPTANE, l-12)
Unknown
190
BISULFITE,
1. 2. Consult Technlcal
Service OTT temperatures
1 1. 2. 3. Consult Maximum
low
higher hlstorles.
than
150F.
on
hydrofltiorlc not
acid been Testing higher
appltcatlons. defined. QuaCorr is recommended. than 15DoF. service at
Recorrnendatlon
based
on
successful
case
COnCentratiOnS
concentrations have my be satlsfactoy. Service on temperatures
Consult
(continued)
TABLE 1.13:
FIBERGLASS
REINFORCED
~ACDRR MEDIA
FURAN
POLYMER-QUAKER
OATS CHEMICALS
(continued)
QUACORR MEDIA GUIDE CNCENTRAT 50:50 I 005 ACIDl KEROSENE, 32:3l 70s :32:5 EST TEMP. OF 120 150 150 150
X
GUIDE CONCENTRAT I ON Unknown TESTo:EHP. 190 s X IJ MEDIA METHYL PAP.ATH I ON, FUNDAL
MEDIA
ION
S
X X
MALEIC ACID, HYDROCHLORIC ACID (DILUTE), SODIUM HYDROXIDE, FUMARIC ACID, o-DICHLOROBENZENE, ISOPROPYL ALCOHOL MALE~~ ACID (DILUTE), ISOPROPYL ALCOHOL
METHYL
SULFATE
METHYLSULFONIC U know Unknown 190 190 X X
MALEIC ACID, SODIUM HYDROXIDE, FUMARIC ACID, o-DICHLOROBENZENE, ISOPROPYL ALCOHOL METHACRYLATES, SULFURIC ACID, METHANOL, WATERI* METHALLYL CHLORIDE ACID, ACRYLIC
MINERAL SPIRIT, GAS OIL, PENTACHLOROPHENOL MONOCHLORCBENZENE
5:60:6:5:24
176
X l.QNOETHANOLAMINE loos loos 100% ACID 2. 52 51 975 (ORGANIC), Unknown
R.T. 150 I.P.(27D) II3 150 150 R.T. 150 150 R.T.
X X X X X
Crude Un know
185 170
X MORPHOLINE X NAPTHA NITRIC
METHALLYL CHLORIDE, SODIUM CARBONATE, TRIETHYLAMINE SALTS, METHALLYL ETHER OF o-NITROPHEYOL, WATER METHALLYL ETHER OF o-NITROPHENOL (CRUDE), METHALLYL CHLORIDE, SODIUM CARBONATE, TRIETHYLAMINE SALTS, WATER METHANOL METHANOL, ACETIC ACID, SODIUM CHLORIDE, POTASSIUM CHLORIDE, XYLENE, ACETIC ANHYDRIDE, DICHLOROPHENOL, SODIUM HYDROXIDE, BRDMODICHLOROPHENOL, TRICHLOROBENZENE METHANOL, SULFURIC ACID,.ACRYLIC METHACRYLATES, WATERl. METHYLATED SPIRIT, INWSTRIAL ACID,
X
X X X X
Un know
170
X NITRCBENZENE
100x Un know
9.P.f
150) 150
X X
NITRC COMPCUNDS, AMINES HYDRCCHLORIC ACID OLEUM (CONC. H2S04)
PENTACHLDROPHENOL, MINERAL SPIRIT PERCHLOROETHYLENE 5:60:6:5:24 176 X
GAS OIL,
KEROSENE,
5:3l
:32:32 loos 100s loos IO01
150 R.T. 150 235-250 l.P.(250) 150
X
X
X
X X X
100% 100% 100% 100% 100% 100% 100%
R.T. 150 II3 100 R.T. 150 B.P.fl76) R.T. 200
X X X X X X X X X
PESTICIDE P+lENOL PHENOLIC
fFUNDALj3 52 SOS4 RESIN ACID 100% I51 15% 15% 90s
METHYL CELLOSOLVE METHYLENE CHLORIDE1 KETONE
I50 150 R.T. R.T. I50 l.P.(214) 150
X X X X
METHYL ETHYL
PHOSF+lORlC
METHYL
I SOBUTY L.
KETONE
100s
100%
1. 2. 3. 4.
1.
Recomndatlon
based
on successful
case
hlstories.
Maxlmum allowable concentrations have not been defined. DuaCorr service at lower concentrations may be satisfactory. Testlng Is recommended. Not remmended for concentrations over 51. I part Fundal to 7 parts water. Not recmnded at hlgh concentrations or hlgh temperatures. Consult Technical Service for concentrations above 5% and temperatures In excess of 15OOF.
(continued)
TABLE 1.13:
FIBERGLASS
REINFORCED
QUACORR MEDIA
FURAN
POLYMER-QUAKER
EST TEMF OF 200
OATS CHEMICALS
(continued)
&JACORR MEDIA GUIDE
GUIDE ONCENTRAT ION S

X
MEDIA PHOSPHORIC ACID SCRAP LIQUOR SODIUM PHOSPHATE PHOSPHOROUS ACID, HYDROCHLORIC (pH t-3).
U QUATERNARY At+4044 IUM SALTS LIQUORl.
Unknown WATE
ACID,
75:6: 75:6:
19 19
R.T. 150
RED PULP MILL

X
X X SILICON SLIMETROL
X
PHOSPHOROUS BROMIDEl* PHOSPHOROUS CHLORIDE PHOSPHORUS OXYCHLORIDE CHLORIDE) POTASSIUM CARBONATE (PHOSPHORYL
Sat.
TETRACHLORIDE
150 R.T. 150 150 150
100% 100% Sat. Unknown
SLIMICIDE
X X X X
SODIUM EISULFITE, MALEIC ACID, FUMARIC ACID, SODIUM HYDROXIDE, HEPTANE, HEXANE, HEAVY ALCOHOLS (pH l-12) $00
POTASSIUM CHLORIDE, SOCiUM CHLORIDE, XYLENE, DICHLOROPHENOL, ACETIC ACID, BRCh4ODIWLOROPHENOL. ACETIC ANHYDRIDE, SODIUM HYDROXIDE, METHANOL, TRICHLOROBENZENE WTASSIUM POTASSIUM FERRICYANIDE HYDROXIDE
I UM
CARBONATE
Sat. 50% 50% Sat.
150 R.T. 150 I50
X X X
SODIUM CARBONATE, METHALLYL CHLORIDE, METHALLYL ETHER OF o-NITROPHENOL, TRIETHYLAMINE SALTS, WATER SODIUM (2.5%), SODIUY CARBONATE, SULFUROUS CHLORIDE SODIUM HYDROSULFIDE ACID
POTASSIUM POTASSIUM POTASSIUM
PERMANGANATEI PEROXIDEl* PYROPHOSPHATE (TKPP)*
X X
60% 60%
R.T. 150 R.T. 150
X X X X X X X X X X X
PULP MILL
Ll&OR
(GREEN13
R.T. 150 R.T. 150 R.T. 150 150 150 R.T.
SODIUM CHLORIDE, POTASSIUM CHLORIDE, XYLENE, DICHLOROPHENOL, ACETIC ACID, BROMODICHLOROPHENOL, ACETIC ANHYDRIDE, SODIUM HYDROXIDE, METHANOL, TRICHLOROBENZENE SODIUM CHROMATE SODIUM HYDROXIDE
PULP MILL
Licx~o~
(RED)~.
PULP MILL
LiwoR
(wHITE)~.
PYRIDINE
X X service at
SODIUK HYDROXIDE (3-13%), BENZENE (pH 7 10)
o-DICHLORO-
1. 2. 3.
QuaCorr Maximum allowable concentrations have not been define low concentrations may be satisfactory. Testing Is recommended. Tested in comblnatlon with other media. Consult Technical Service on tervperafures higher than 150F.
1.
Consult
Technical
Service
on temperatures
higher
than
15DF. (:.ontinued)
TABLE 1.13:
FIBERGLASS
REINFORCED
FURAN
POLYMER-QUAKER
OATS CHEMICALS
(continued)
@lACORR MEDIA GUIDE :DNCENTRAT lo1 25% 25% 25% 5@%1. 5Obl. 60%** ACRYLIC WATERI* ACID, METHANOL, 60:6:5:5:24
MEDIA SODIUM HYDROXIDE, o-DICHLOROBENZENE, ISOPROPYL ALCOHOL, MALEIC ACID, FUMARIC ACID SODIUM HYDROXIDE, HYDROCHLORIC ACID (DILUTE, MALEIC ACID, FUMARIC ACID, o-DICHLDROBENZENE, ISOPROPYL ALCOHOL SODIUM HYDROXIDE, MALEIC ACID, FUMARIC ACID, SODIUM BLSULFITE, HEPTANE, HEXANE, HEAVY ALCOHOLS, (pH I-12) SODIUM HYDROXIDE, SODIUM CHLORIDE, ACETIC ACID, POTASSIUM CHLORIDE, XYLENE, DICHLOROPHENOL, BROMODICHLOROFHENOL, ACETIC ANHYDRIDE, METHANOL, TRICHLOROBENZENE SODIUM SODIUM LIQUOR SODIUM HYPOCHLORITE PHOSPHATE, (pH l-3) SULFIDE PHOSPHORIC ACID SCRAP
CCNCENTRAT I ON Unknown
TESTO:EHP*
s u 190 X SULFURIC ACfD
MEDIA
~EST4EHF
S
X
Unknown
190
R.T. I50 3.P.f216: 150 250 150 I76
X
X X
X
X X
Unknown
190
SULFURIC ACID, MEMACRYLATES, SULFURIC ACID, ACID, ACID,
ISOPROPYL KEROSENE, SULFONIC
MYRISTATE KELEX LIGAND ACID, SULFUR
5:95 Unknown Unknown
185 75 160-180
Unknown
150
SULFURIC SULFURIC DIOXIDE
X
X
.lS Unknown
R.T. 200
X X
SULFUROUS ACID, SODIUM HYDROSULFIDE SODIUM CARBONATE TETRAHYDROFURAN TETRAHYDROFURFURYL ALCOHOL
(2.5%
Unknown
176
100% 100% 60% 60% 100% 100%
R.T. R.T. R.T. 150 R.T. R.T. 150 1.P. (230) R.T. R.T. R.T. R.T. 180 R.T. 150
X
X X X
(HYDRO) (2.5). ACID SODIUM
2% Unknown
176 176
X X
SODIUM SULFIDE-HYDRO CARBONATE, SULFUROUS STANNIC STYRENE CHLORIDE
TETRAPOTASS I UM PYROPHOSPHATE
I oog 100% SULFURlC Unknown
I50 R.T. 160-180
X X X
THICNYL TOLUENE
CHLORIDE
X
X X X X X X X
100%
100% DIISOCYANATE SULFONIC ACID (IN WATER) 100% 70% 85% 70%
SULFONIC ACID (CONCENTRATED), ACID, SULFUR DIOXIDE SULFUR, MOLTEN
TOLUENE 300 SULFUR Unknown 200 X X TOLUENE 100% 150 160-180 X X TOLUENE TOLUENE
SULFUR, HYDROCHLORIC ACID, MONOCHLORIDE (VAPORS) SULFUR CHLORIDE SULFUR DIOXIDE, SULFURIC ACID (MONO) SULFONIC
SULFONIC SULFONIC
ACID ACID ACID
(IN
METHANOL)
(PARA)
100%
50% Unknown
X
X X
ACID,
Unknown
TRIMLOROACETIC
SULFUR MONOCHLORIDE HYDROCHLORIC ACID SULFUR TR10XlDE2 1. 2. Not recomnended Maximum allowable low concentrations
(VAPCRS),
SULFUR,
Unknown
200
X at higher concentrations. concentrations have may be satisfactory.
TFI I CHLOROBENZENE , ACET I C AC ID. SOD I UM CHLORIDE, POTASSIUM CHLORIDE, YYLENE, DICHLOROPHENOL, BROMODICHLWOPHENOL, ACETIC ANHYDRIDE, SODIUM HYDROXIDE, METHANOL 1. _ Reconmwndatlon _ . . acla SdlterIc based on successful case recomnenaea to maxlmum of
not
been defined. QuaCorr Testing is reccnmended.
service
at
2.
hlstorles. 50% concentration
and 250F. (continued)
TABLE 1.13:
FIBERGLASS
REINFORCED
FURAN
POLYMER-QUAKER
OATS CHEMICALS
(continued)
WACORR MEDIA TRICHLOROETHANE TRICHLOROETHANE (l,l,l) (MIXED ISOMERS)
MEDIA
GUIDE TEST CONCENTRAT I ON 100% 100s Unknown TEMP. OF
5 X X X
R.T. R.T. R.T.
TRICHLOROETHANE, CHLORINATED SOLVENTS (TRACE), HYDROCHLORIC ACID (DILUTE1 TRICHLOROETHYLENE
100s 100s 100% Unknown
150 B.P.(lB9) II3 170
X X X X
TRIETHANOLAMINE TRIETHYLAMINE SALTS, METHYL ETHER OF o-NITROPHENOL, METHALLYL CHLORIDE, SODIUN CARBONATE, WATER TRISODIUM PHOSPHATE ACID
sat. Unknown
150 R.T.
X X
VINYL CHLORIDE, HYDROCHLORIC (DILUTE), WATER WATER (DEMINERALIZED)
loos loos IO01 100% 100%
R.T. 150 B.P.(ZlZ) 150 B.P.(212) R.T. 150
X X x X x X X X X
WATER (DISTILLED)
WdlTE
PULP MILL
LIQUOR.
XYLENE
(MIXED
ISOMERS)
100% Unknown
B.P.(284) 150
XYLENE, SODIUM CHLORIDE, POTASSIUM CHLORIDE, DICHLORORIENOL, ACETIC ACID, BROMODICHLORO~ENOL, ACETIC ANHYDRIDE. SODIUM HYDROXIDE, METHANOL, TRIMLOROBENZENE ZIRCONIUM RAFFINATE (ZIRCONIUM DXYCHLORIDE, HCI, MIBK, THIOCYANIC ZIRCONIUM RAFFINATE (ZIRCONIUM 3XYCHLORIDE. HCI, MIBK, THIOCYANIC ACID)
100%
R.T.
100% ACID)
150
Synthetic
Resins and Polymers
47
TABLE 1.14:
FIBERGLASS MOLDED
REINFORCED
ISOPHTHALIC
POLYESTER
AND VINYL
ESTER-MORRISON
FIBER GLASS
EXTREN is a proprietary combination of fiberglass reinforcements and thermosetting polyester or vinyl ester resin systems produced in standard structural shapes and sheets by Morrison Molded Fiber Glass Company. EXTREN is widely used in industrial construction and maintenance, commercial construction, and as components of industrial equipment and commercial products. The information below is based on data collected from several years of actual industrial applications. In addition it is based on conservative evaluation of the changes which occur in certain properties of replicate laminates after exposures of one year or longer, both in the laboratory and the field, according to the American Society for Testing Materials (ASTM C-581). These properties include hardness, flexural strength, and flexural modulus. Surface stability is also a major characteristic and must be evaluated.
Series 500 and 525-lsophthalic Series 625-Vinyl ester
CHEMICAL polyester
RESISTANCE -
EXTREN NR = Not resistant R = Resistant SERIESso&525

RT 160F SERIES 625 RT 16c)F
SERIES500525
RT 160F
SERIES 625 RT 160F
CHEMICAL Acetaldehyde Acetlc Acid O-25% Acetic Acid 25-50% Acetic AnhydrIde Acetone Acrylonltrile Alcoho!, Butyl Alcohol, Ethyl 10% Alcohol, Ethyl 100% Alcohol, Isopropyl Alcohol, Alcohol, Alcohol, Isopropyl 10% 100% NR R R NR NR NR NR NR NR NR NR NR NR NR NR R Chloride Hydroxide Nitrate Potassium Sulfate Aqueous Gas Bicarbonate Bisulfite Carbonate Citrate Flouride Hydroxide Hydroxide Hydroxide Nitrate Persulfate 5% 10% 20% O-10% 5% R R R R NR NR R NR NR R NR R R NR R NR NR R NR NR NR NR NR NR NR NR NR NR NR NR NR R R NR R R NR NR NR NR NR NR NR NR NR NR R NR NR R R NR NR NR R R R R R R NR R R R R R R R R R R R R R R R R R R R NR R R NR NR NR NR 150 NR 150 NR 150 NR 150 150 R R 120 fl R 100 100 120 120 120 120
100
CHEMICAL Ammonium Ammonium Arsenious 0-Benzoyl Phosphate Sulfate Acid Bentoic Acid NR R R NR NP R R NR R NR R NR in Kerosene R R R NR NR NR NR R NR NR NR NR NR NR R NR NR NR NR R NR NR NR NR R R R R R R R R R NR R R R R NR R R 120 R R R R R R 120 R R 120 NR R R R R NR R
Barium Acetate Barrum Carbonate Barium Chloride Barium Hydroxide Bawm Beer Benzene 5% Benzene Sulfate
Barium Sulfide
Alcohol, Methyl 10% Methyl 100% Methyl lsobutyl Butyl
Benzene Sulfonic Acid Benzoic Acid Benzyl Alcohol Benzyl Chloride Brass Plating Solutton.
(3% 6% 1% 3% Copper Cyanide Sodum Cyamde Zinc Cyangde Sodum Carbonate)
Alcohol, Secondary Alum Aluminum Aluminum Aluminum Aluminum Ammonia, Ammonia, Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium
Bury1 Acerate Butyric Acid 040% Butylene Glycol Cadmium Cadmium Chloride Cyanide
NR R R R Plaling Solution: NR R R R R
NR NR R NR
NR R R R
NR R R R
(3% Cadmwn Oxide 10% Wum Cyantde
NR R NR R R
R R R R
120 R R R
120 120 120 R 120
1% Causticsoda) Calcium Bisulfite Calcium Carbonate Calcium Chlorate Calcium Chloride
R R (continued)
48
Corrosion
Resistant
Materials
Handbook
TABLE 1.14:
FIBERGLASS MOLDED
REINFORCED
ISOPHTHALIC
SERIES 625 RT 160F
POLYESTER
AND VINYL
ESTER-MORRISON
SERIES 625
RT 16O'F
FIBER GLASS
SERIES 500-525 RT 160F
(continued)
SERIES MO-525
RT 160ct-
CHEMICAL Calcium Hydroxide Calcium Hypochlorite Calcium Nitrate Calcium Sulfate Calcium Sulfite Caprylic Acid Carbon Dioxide Carbon Disulfide Carbon Monoxide Carbon Tetrachloride Carborw Acid Castor 011 Carbon Methyl Cellulose Chlorinated Wax Chlorine Dloxlde;Alr Chlorine Dloxlde, Chlorine. Dry Gas Wet Gas R R R R R R R NR R NR R R NR NR R NR NR NR NR NR NR NR NR Acid NR NR NR R d R R NR NR R NR NR NR R R R NR R NR R NR NR R NR NR NR NR NR NR NR NR NR NR NR NR NR NR R R NR R NR NR R NR R R R R R R R NR R R R R R R R R R R NR R R NR NR NR R NR R R R R R R R R 120 120 R R R R R NR R loo R R 120 R R R R R NR R 100 NR NR NR R NR R R R R R R R R
CHEMICAL Copper Pickling Bath. NR R R R R 011 R R R R R NR NR NR NR NR R Glycol Phthalate R NR NR R NR R NR NR NR R NR R R R R R R R R

NItrate) (10% Ferric Sulfate 10% Sulfuric Acid)
NR R NR NR R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR R NR NR NR R NR R R R R R R R NR NR NR NR NR NR NR
R R R R R R R R R R R NR R NR NR R R R R R R R NR NR NR R NR R R R R R R R R R R R R R R
R R R R R R R R R R R NR NR NR NR R R R R R R R NR
NR
Copper Corn Oil
Sulfate Slurry
Corn Starch Corn Sugar Cottonseed
Crude Oil, Sour Crude Oil, Sweet Cyclohexane Detergents, Sulfonated Di-Ammonium Phosphate Dibromophenol Dibutyl Ether Dlchloro Benzene
Dichloroethylene Diesel Fuel Diethylene Dimethyl
Chlorine, Wet Gas Chlorine, Llquld Chlortne. Water Chloroacetlc Chlorobenzene Chloroform Chlorosulfonlc Chromic Acid 20% Chromic Acid 30% Chromium Cltrvz Acid Coconut 011 Copper Chloride Copper Cyanide Copper Copper Copper Fluoride Nltrate Plattng Solution Sulfate Acid 040%
Dioctyl Phthalate Dipropylene Dodecyl Glycol
Alcohol
Esters, Fatty Acids Ethyl Acetate Ethyl Benzene Ethyl Ether Ethylene Ethylene Glycol Dichloride
NR R NR R R R R R R R R 120 R 120 R R R
Fatty Acids Ferric Chloride Ferric Nitrate Ferric Sulfate Ferrous Chloride Ferrous Nitrate Ferrous Sulfate 8-8-8 Fertilizer
(Copper Cyanide 10 5% Copper 14% Copper Cyantde 6% Rochelle Salts)
Copper
Brite Platmg
NR
NR
120
Fertilizer
(Urea Ammonium
(Causttc Cyanide)
NR NR
Copper Plating Solution. (45%Copper Fluoroborate

19% Copper Sulfate 8% Sullur~c Acid)
NR
NR
Flue Gas Fluoboric Acid Acid O-20% Fluosilicic
NR NR R R
Copper
Matte Dipping
Bath NR NR R R
(30% Few Chloride 19% Hydrochloric)
Formaldehyde Formic Acid
(continued)
Synthetic
Resins and Polymers
49
TABLE 1.14:
FIBERGLASS MOLDED
REINFORCED
500-525
ISOPHTHALIC
SERIES 625
POLYESTER
AND VINYL
ESTER-MORRISON
500525 160F SERIES AT 625 160-F
FIBER GLASS
SERIES RT
(continued)
SERIES RT
16oF
RT
160F
CHEMICAL Fuel Ott Gas. Natural Gasoline, Gasoline, Gasoline, Gasoline. Gluconic Glucose Glycerine Glycol. Ethylene Glycol. Propylene Glycolic Acrd Auto Aviation Ethyl Sour Acid R R R R R R R R R R R R NR NR NR NR NR NR NR NR R R R R NR NR R R R R R R R R R R R R R R R R R R R R R R R R R R
CHEMICAL Kerosene Lactic Acid Laura1 Chloride Laurlc Acid Lead Acetate Lead Nitrate Lead Plating Solution. R R NR R R R
Actd Acid)
NR NR NR NR NR NR NR NR R R R NR NR R NR R R NR NR NR NR NR NR NR NR R NR NR NR R -
R R R R R R R R R R R R R R R R R R R NR NR NR R NR NR R R NR NR R R
R R R R R R R R R R R R R R 140 R R R R NR NR NR R NR NR R R NR
NR
(II% Fluoborlc
.4% BOW
NR R R R R R R R NR R R R R NR NR NR R NR NR R R NR NR R R R R R
Levulinlc
Acid
Linseed 011 Lrthium Bromide Lithium Sulfate Magnesium Magnesium Magnesium Magnesium Magnesium Maleic Acid Mercuric Mercurous Methylene Chloride Chloride Chloride Blsulflte Carbonate Chloride Hydroxide Sulfate
Gold Plating Solution:

(63% Potasswm Ferrocyanlde .2% Potassum Gold Cyanide .0% Sodurn Cyanide)
Heptane Hexane Hexylene Hvdraulic Glycol Fluid Acid O-25% Acid O-37% Acid Acid 10% Acid Hot Stack Gasses
R R R R R R R NR NR Wet Gas NR Dry Gas NR Wet Gas NR NR R R NR NR NR
NR NR R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR -
R R R R R R R R R R R R R R R R R R
R R R 340 R R R R 120 R R R R 120 A R R 120 R
Hydrobromic Hydrochloric Hydrocyanic Hydrofluoric Hydrofluosilicic Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Hydrosulfite Hypochlorous
Methyl Ethyl Ketone Methyl lsobutyl Methanol Carbitol (see alcohol) Ketone
Methyl lsobutyl Methyl Styrene Mineral

Oils
Bromide, Chloride, Chloride, Peroxide
Molybdenum Monochloro
Disulfide Acetic Acid
Sulfide Dry Sulfide, Aqueous Fluoride, Bleach Acid O-10% Vapor
Monoethanolamtne Motor 011 MyFIstic Acid Naphtha Naphlhalene Nickel Chloride
R R R R
R
R NR R R
R R R R
Iron Plating Solutlon:

(45% FeCIz. 15% CaCI, 20% FeSOa 11% (NH.) zSO,)
NR NR NR R R
NR NR NR R NR
R R R R R
Iron and Steel Cleaning

(9% Hydrochloric 23% Sulfuw)
Bath
R Nckel Nltrate Nickel Plattng. (6% Lead R NR
9% Fluobortc Acld 4% BOK Acld)
NR
NR
Isopropyl Isopropyl Jet Fuel
Amtne PaImItate
R Nckel Plating. (11% Nckel Sullate 2% Nlckei Chlortde R

1% BOW Acid)
NR
(continued)
50
TABLE 1.14:
FIBERGLASS MOLDED
REINFORCED
SERIES 500525 RT 160F
ISOPHTHALIC
SERIES 625 FIT 16oF
POLYESTER
AND VINYL
ESTER-MORRISON
SERIES 625 RT 16oF
FIBER GLASS
(continued)
SERIES M&525 RT 160-F
CHEMICAL Nickel Plating:

(44% Nfckei Sulfate 4% Ammonium Chlorfde 4% Bone Actd) R
CHEMICAL Potassium Permanganate NR R R Potassium Propionic Propylene Persulfate Acid Glycol 150% 50-100% Potassium Sulfate R R NR NR NR R R R R NR R R R R NR NR NR NR R R R NR R R R R R R NR R R R R NR R R R R 120 R NR R R R R NR R R R R R NR NR R R NR NR NR NR R NR NR R NR NR R NR NR NR NR NR R R R R R NR R R NR R R R R 140 R R 120 NR R R NR R R R R
Nckel
Sulfate
Nrtrrc Acrd 05% Nrtric Acid 20% Nrtric Acid Fumes Nrtrobenzene Octanorc Acrd 011. Sour Crude Oil. Sweet Crude Oleic Acid Oleum (Fumrng Sulfuric) Olrve Oil Oxalic Acid Peroxrde Bleach
(2% Sodium Peroxlde 96% .025% Epsom Salts 5% SodturnSlllcate. 4TBE 1.4% Sulfurtc Acid. 66-BE)
Pulp Paper Mill Effluent Pyridine Salicylic Acid Sebacic Selenous Acid Acid
Silver Nitrate Srlver Plating Solution:

(4% Sher Cyanide 7% Potawum Cyanide 5% Sodium Cyanide 2% Potasswm Carbonate)
NR
NR
Soaps Sodium Acetate Sodium Benzoate
R R R R R R R R R O-25% R R R R R R R R R R NR NR NR NR NR
NR NR NR R NR R R R R NR NR R NR R NR R R R R NR NR NR NR NR NR
R R R R R R R R R R R R R R R R R R R R R R R R R
R R R R R R R R R R R R R R R R R R R 120 120 120 120 120 NR
Phenol Phenol Sulfonic Acid Phosphoric Phosphoric Phosphorous Acid Acid Fumes Pentoxide
NR NR R R R NR .R R R R R Latex w/35 NR Sulfate R R R R R R R R NR R
NR NR R R R NR R R R NR NR NR R NR NR NR R NR R R NR R
NR j\lR R R R NR R R R R R R R R R R R R R R R R
NR NR R R R NR R R R R R 120 R 140 R 140 R 140 R R

120
Sodium Bicarbonate Sodium Bifluoride Sodium Bisulfate Sodium Bwlflte Sodium Bromate Sodium Bromide Sodium Carbonate Sodium Chlorate Sodium Chloride Sodrum Chlorite Sodium Chromate Sodium Cyanide Sodium Dichromate Sodium Di-Phosphate Sodium Ferricyanide Sodium Ferrocyanide Sodium Fluoride Sodium Fluoro Silicate Sodium HexametaphosphatesNR Sodium Hydroxide Sodium Hydroxide Sodium Hydroxide O-5% 5-25% 50%
Phosphorous Trichloride Phthalrc Acid Pickling Acids

(Sulfuric and Hydrochloric)
Picrrc Acid, Alcoholtc Polyvinyl Acetate Polyvinyl Alcohol Polyvinyl Chloride (Parts DOP) Latex
Potassium Aluminum Potassium Brcarbonate Potassium Bromide Potassrum Carbonate Potassium Chloride Potassium Potassium Potassium Potassium Drchromate
Potassium Ferricyanide Ferrocyanide Hydroxide Nitrate
R (continued)
Synthetic
Resins and Polymers
51
TABLE 1.14:
FIBERGLASS MOLDED
REINFORCED
SERIES 500-525
RT 160F
ISOPHTHALIC
SERIES 625
RT 160F
POLYESTER
AND VINYL
ESTER-MORRISON
SERIES
RT
FIBER GLASS
(continued)
SERIES 5Ob525 RT 160F 625 160F
CHEMICAL Sodium Hydrosulfide Sodium Hypochlorite Sodium Lauryl Sulfate Sodium Mono-Phosphate Sodium Nitrate Sodium Silicate Sodium Sulfate Sodium Sulfide Sodium Sulfite Sodium Terra Borate Sodium Thiocyanate Sodrum Thiosulfate Sodium Tripolyphosphate Sodium Xylene Sulfonate Sorbitol Solutions Sour Crude Oil Soya Oil Stannic Chloride Stannous Chloride Stearic Acid Styrene Sugar, Beet and Cane Liquor Sugar, Sucrose Suifamic Acid Sulfanilic Acrd Sulfated Detergents Sulfur Dioxide, Dry or Wet Sulfur Trioxide/Arr Sulfuric Acid O-30% Sulfuric Acid 3040% Sulfuric Acid 50-70% Sulfurous Acid Superphosphoric
(76% PaOs)
R R R R R R R R R R NR R R R R R R R R R NR R R R R R NR NR R NR NR NR R
NR NR NR R R NR R NR NR R NR NR NR NR NR R R R R R NR NR R. NR NR NR NR NR R NR NR NR NR
R R R R R R R R R R R R R R R R R R R R NR R R R R R R R R R R R R
R 120 R R R R R R R R R R R R R R R R R R NR R R R R R R R R R 120 100 R

140
CHEMICAL Ttn Plating

(16% 7% 9% 2% Stannous Fluoroborate Tin Fluorobonc Ac!d Bow Acrd)
NR
NR
Toluene Toluene Sulfonic Acid Oils: Transformer
NR NR
NR NR
NR R
NR R
(Mneral 011 Types Chloro-Phenyl Types)
N: R NR NR NR R R NR R
N; NR NR NR NR NR NR NR NR R R NR
N: R NR NR R R R R R R R NR
NE R NR NR
Trichlor Acetic Acid Trichlorethylene Trichlorophenol Tricresyl Trisodium Turpentine Urea Vegetable Vinegar Vinvl Acetate Water Deronized Demineralized Distilled Fresh Salt Sea White Liquor (Pulp Mill) Xylene Zinc Chlorate Zinc Nitrate Zrnc Plating Solution. (9%21ncCyamde
4% Sodwn Cyantde 9% Sodtum Hydrowde)
Phosphate Sulfonate Phosphate
100
R R 100
140
Tridecylbenzene
011s
R R NR
R R NR
R R R R R R R NR R R
R R R R R R NR NR R R
Acid
NR
NR
120
Tall Oil Tannic Acid Tartaric Acrd Thronyl Chloride
Zrnc Platrng Solution: R R R NR NR NR R NR R R R NR 120 R NR

(49% Zvnc Fluoroborate 5% Ammontum Chlonde 6% Ammonium Fluoroborate)
NR
Zinc Sulfate
52
TABLE 1.15:
FIBERGLASS
REINFORCED
POLYBUTYLENE
TEREPHTHALATE-CELANESE
PLASTICS
A series of thermoplastic polyesters, polvbutylene terephthalate, was developed by Celanese and introduced under the trademark CELANEX. CELANEX@ resins are highly crystalline, and exhibit a unique combination of properties including high strength, rigidity and toughness, low creep even at elevated temperatures, minimal moisture absorption and exceptional dimensional stability, resistance to the effects of a wide range of chemicals, oils, greases and solvents, excellent electrical properties and outstanding processing characteristics. Chemical Resistance of CELANEX
Yo Change Time Temp. Tensile % Change % Change (Days) F Strength Weight Diameter* 73 73 73 180 180 73 73 73 180 73 73 73 73 73 73 180 180 73 73 73 180 180 73 73 73 73 73 73 100 :: 73 73 73 73 73 73 73 180 :; 73 120 73 73 73 120 73 73 73 180 180 73 73 73 :il 73 180 180 -40 -Z -15 -20 -27 -32 -35 -8 -7 -8 -36 -39 I; -10 -4 1; -14 -17 -13 -58 -73.5 -92 -99 -47 -72 -84 -96 1; -4 -4 -12 -20 -24 -68 -7 -10 -8 -25 -65 -2 -4 -4 -5 -3 -5 -3 -6 1; -4 -7 -8 0 -5 -55 -77 -41 -4 -4 +0.6 +03 +09 +2.1 -4 2 +oe +0.5 +03 -1.9 +03 +0.2 +0.4 -0 1 +o 1 +02 -06 -24 +02 +0.2 +0.2 +0.2 +02 +0.4 +o.o +o 1 -0.3 +03 +0.3 +03 0.0 +07 +0.3 +0.3 +0.4 +03 +0.3 +0.2 +11 +0.7 +0.5 +0.4 +08 +5.9 +4.4 +1.0 +2.0 +2.4 +3.6 +3.4 +0.4 +4.2 +4.3 +0.4 +0.5 +0.2 +0.1 +05 +06 +0.3 0.0 +06 +0.3 +01 +0.6 +o.,i +0.7 0.0 +0.2 +0.1 +02 +0.2 +0.1 +01 0.0 -10 +0.2 -0.1 +o 1 +0.1 +o 1 0.0 +o 1 +o.r +o 1 +o 1 +0.1 +0.1 +0.2 +02 +0.1 +0.1 +0.1 +02 +0.1 +0.2 +0.2 +0.1 +0.1 +02 +0.9 +0.5 +0.2 +02 +0.6 +0.7 +0.1 +0.1 +0.1 +0.8 +0.8 +0.1 +0.1 +0.1 +oo 0.0 00 +o 1 +02
Glass-Reinforced Resins
x Change Time Temp. Tensile % Change % Change F Strength Weight Diameter (Days) 90 73 0 +o 1 00 180 73 +o 1 00 360 73 +o 1 +0.1 90 180 360 90 180 360 24 90 180 360 60 180 180 51 360 180 360 135 240 180 360 30 48 180 360 30 48 180 360 60 100 180 360 60 100 180 360 60 240 18G 360 180 360 180 360 180 360 180 360 180 360 180 360 180 360 73 73 73 73 73 73 180 73 73 73 180 180 73 73 73 73 140 140 73 73 200 200 73 73 200 200 73 73 200 200 73 73 200 200 73 73 180 180 73 -17.3 73 73 73 :; 73 73 :z 73 73 73 73 -6 -: -3 -3 -3 -50 -3 -6 -5 -30 -32 -2 -1 -3 -1.6 -2.2 -74 -164 1; -31 -51 +1 -1 -43 -60 -3 -3 -43 -61 -6 -4 -34 -64 0 -1 -2 -55 -05 Cl -167 -5 -24 1: 1; 1; -3 -23 -4 -24 +0.3 +03 +0.5 +0.3 +0.4 +03 +2.4 +0.2 +0.3 +04 +65 +67 -0 1 +0.1 -0.1 +0.2 +0.2 +1.4 +19 +o 1 +03 +04 00 +20 -22 +o 1 +02 +0.2 +01 +o 1 +03 0.0 +03 +05 -0 1 00 z r +03 +03 +1.3 z +o 1 +o 1 +o 1 +o 1 +o 1 co 1 +0.4 +0.1 +0.3 +o 1 +0.6 +06 :: 00 0.0 +o 1 +03 +03 +o 1 + 1 00 + 1 00 + 1 co3 + 4 +01 +o 1 00 -0 1 +02 +01 -0 1 -0 1 00 +o 1 +0.1 co 1 +0.1 +0.1 00 00 +0.1 +0.1 +o 1 +0.1 +o 1 +0.2 0,
Material
Material Carbon Telrachlorlde
InorganIc Chemicals 10% Ammomum 90 Hydroxide 180 360 9 24 1% Sodium Hydroxide 90 180 360 24 90 180 360
Dlefhyl Ether
50% Ethylene GlycollWater 95% Ethanol/Water
10% Sodtum Chloride
10% Hydrochloric 90 Acid 180 360 24 64 3% Sulfunc Acid 90 180 360 24 64 90 180 360 90 180 360 60 90 180 360 90 180 360 90 180 360 :z 90 180 360 2:: Acetone 90 180 360 2:: Toluene 90 180 360 60 240 90 180 3M) 90 180 360
Perchloroethylene
Freon 113 Gasoline (Amoco. Unleaded) Aulomatlc Transmlsslon Flwd. (Type 6) Delco 222 Brake Fluid
40% Suifunc Acid Water (Tap)
Buffer, pHl0
Motor 011 (10-20-40)
Buffer, pH 4
Organic Chemicals 5% Acetlc Actd
Lubncatcng Grease
Hydraukc FluId (Skydrol 500s)
Benzene
Turbine Lubncattng Oil (Texaco Sate 15) Houron - Cosmo Lubnc 2425 1% Soap Solwon
Presoak Sol. (AxIon) Calgon Water Softener Sol. Bufler. pH7 Calgomte Dishwasher Sol. Laundry Detergent
l
BTX
Heptane
l/B x 2 diameter discs.
Synthetic
Resins and Polymers
53
TABLE
1.16:
FIBERGLASS
REINFORCED
POLYESTER
PANELS-RESOLITE
RESOLITE tions. The application.
CR panels are fiberglass-reinforced, polyester resin used in RESOLITE
polyester CR panels
sheets in flat and various corrugated and ribbed configurawas developed to withstand chemical abuse in heavy-duty
Acids
AC&C 5 o-75 o-50 50-75 100 S S S
:
S S S
T
Arrenoter
Aqua Reglo Benzene Sllonlc Benzolc Bone Butyric Chloroocetlcs. Mono. di ond +r,
5 5 5 S S
T T S : S
Chromic
Hydrobromac Hydrochlorx Hydrocyonlc Hypochlorous Hydrofluow Loctlc MOlelC N,trnc*
OklC
OXOllC
Nl,,OS
Perchlorlc Phorphotuc steonc Slf,l<

TOrtON
IOIC
o-100 o-50 50 100 o-30 30.50 oil 011 o-30 o-25 O-50 oil 011 011 o-10 O-20 011 011 0 35 35-60 over 60 O-10 oil 011 ol! 011 011 0-80 over 80. 011 011
S 5 S S : 5 : S S S S S z S 5 5 T S S S S : S T S S
T U S T 5 S S 5 T S S S S T s s S T T S 5 5 T : S T S S
Bicorbonoter B,tluorvder B,rulfoter B,rulf,tes Borotes Bromldel Corbonotes Chlorates Chlorlder Chromate! D8chromotei Fluorlder Hydrorulf,des lodfder Ntt,oter Perchlototer Perrvlfoter Phosphates Phorphfter SillColel Slhco-fluor,der wtoter Sulflder Sulf,ter
011 OII 011 011 011 011 011 011 011 all oli 011 011 011 011 011 011 011 011 011 011 OII all oil all
S S S : S S S 5 : S S S 5 S S S S T S
S : T T ; S S S : S 5 T S
S S S
S S
Amll?olm Hydroxide. Borlum Hydrwde Coiclum Hydronde POtorrlm Hydronde Sodium Hydrcwde
10 o-30 10 o-50 O-50 O-10 o-50
S S 5 5 S S 5
S T T T T S T
Mlscelioneous
COlCllV Hypochlonte* Chlorine Water Chlorine Dmxlde Hydrogen Peroxade Sodturn Hypothl?r,te Underaround Wafer-D,rtilled M,ne Wo1err Se0 Water Coohng Tower Water Metal Plotmg Solt~oni P,cklmg Soltlonr Metal Plotlng Solutlonr Phorphow Oxychlonde Phosphorur Trichlcrgde Plrkling Solvt,ons Strlpplng SOltlOr Petroleum Ether Moune Atmosphere Hum,d,ty, 100% Chlonter Cyclohexone Coprylic Acid Polrmtic Ethyl Acetate Cool Dust. moist lodrne Vopar Nut 0~1s Olw? Ollr Weed Killers, organic Fung,c,dei organic Insect,c,del, orgon,c Anthrocene 011 Sulfur, wenoble DDT
l
20 SAT 011 3 011 15
S S 5 S 5 S S S S 5
S S S 5 T T S S S S S S S T T T T
Solvents
Acerone
and Orgomcs
100 100 100 100 100 100 100 100 100 100 100 37 100 100 100 100 100 100 n rn v,v 100 100 011 100 100 100 100 100 100 100 100 100 100 S S S : S S S S S 5 S S S S S S S S S S T S z : S S S 5 S T S S T T S T S T T T S S 5 S S S T S : T : T S T : S T T
(acid) (ocvd) (olkollnei 011 011 (olkollne)
S S S S S S
Wet
Gases
and Fumes
S S S 5
Alcohols (all] Benzene Benzoldehyde Benzoyl Chlor,de Carbon Tetrochlorlde Chlorobenzerer Chloroform l Ethers Acetone, Ethylene Chlonde Formaldehyde Gorol,ne Glyc&
: S S S S : S
: _ _ : : T S
ep,one
Herone Kerosene Methyl Ethyl Ketone Naphtha Nophtholene Phenol l Perchlorethylene Tvchlorethylene Thnonyl Chloride StyretIe Sulfuryl Chlonde Toluene Xylene OllS Ethylened,chlot,de Ethylocetote
Carbon Dioxide Carbon Monor,de Chlonne Ammomo Bromine Flwwne Hydrogen Hydrogen Chlonde Hydrogen Fluoride* Hydrogen Bromde Hydrogen Sulfide Owdamg Gores Redvcmg Gores SteOlIl Sulfur D,ox,de Svlfut T&oxide Chlorine Dioxide Svlfur
z
S S S
S T T
LEGEND S = Sof,sloctory w,th expected long and econom,c 1116 T = Tests suggested. Under some conditions materials moy not be sultoble. U: Unrotirfoctory for continuous service.
TABLE
1.17:
FLUOROPOLYMER-ALLIED
ENGINEERED
PLASTICS
HALAR ECTFE is a melt processable fluoropolymer from Allied Corporation. It possesses a unique combination of properties as a result of its chemical structure-a 1: 1 alternating copolymer of ethylene and chlorotrifluoroethylene. HALAR fluoropolymer offers excellent chemical resistance, good electrical properties, broad use temperature range-from cryogenic to 34OF, and meets the requirements of the UL-94 V-O vertical flame test in thicknesses as low as 7 mils. It is a tough material with excellent impact strength over its broad use temperature range. HALAR ECTFE also maintains useful properties on exposure to cobalt 60 radiation at dosages of 200 megarads. It is one of the best fluoropolymers for abrasion resistance. HALAR fluoropolymer is a thermoplastic which can be processed by virtually any technique applicable with polyethylene. It can be extruded, injection molded, blow molded, rotomolded, and applied by ordinary fluidized bed or electrostatic coating techniques. It is available in a range of viscosity grades for extrusion and molding applications. HALAR ECTFE powders are available in three different particle sizes optimized for specific coating processes.
HXARB ECTFE R - Recommended NR - Not Reco,'m,ended -- _ NO Avalla~la Data Chen;cal Ammonium Carbonate Armnonium Chloride Ammonium Dichromate Ammonium Fluoride, 10% Ammonium Fluoride, 25% Ammonium Hydroxide Ammonium Metaphosphate ArmnoniumNitrate Ammonium Persulphate Ammonium Phosphate Anlmonlum Sulfate Ammonium Sulfide Pmyl Acetate Amy1 Chloride Aniline Anthraquinone Anthraqulnone Sulfonic Acid Antimony Trichloride Aqua Regia Arsenic Acid Barium Barium Barium Barium Barium
Barium
s 7 g 5 $ v) 5
$ q h. fi x $
CHEMICAL RESiSTANCE Temperature 15O'F 250'f --R R R R R -_ R R R R __ R R R R R R R _R R R R R R R R R R R R R R R R R R R R R R --__ NR -_ __ _-_R R R R NR R -R R R R R R -R R R R R __ R R R __ R R
Chemical Acetic Acid, 10% Acetic Acid, 20% Acetic Acid, 50% Acetic Acid, 80% Acetic Acid, Glacial ~ Acetic Anhydride Acetone Acetyl Chloride Acetylene Acetyl Nitrile Acrylonltrile Adipic 105 Acid Alcohol, Amy1 Alcohol, Benzyl Alcohol, Butyl, Primary Alcohol, Butyl, secondary Alcohol, Diacetone Alcohol, Ethyl Alcohol, Hexyl Alcohol, Isopropyl Alcohol, Methyl Alcohol, Propyl Ally1 Chloride Alum Alum, Ammonium Alum, Chrome Alum, Potassium Aluminum Chloride Aluminum Fluoride Alurcu~um Hydroxide Aluminum Nitrate Aluminum Oxychloride Aluminum Sulfate Ammonia, Gas Ammonia, Aqua, 10% AmmonilnnAcetate Ammonium Bifluoside Ammonium Bisulfide
73OF R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
3OO'F
73F --R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
R
Temperature 150F 250F

R R _R
XF
R R -_
__ ___ -_ -__
NR ___ _-_R R R R NR R _R R R R R R -R R R R R __ R R -__ R R
R __
c
*
R R R R R R R R R
R
R NR R R __ R R R R R -R
R R R R R __ R R R NR R NR _--R R R R R -_ R R _-NR NR NR NR R __ R R R
R R R R R -R R R NR R NR ___ -_ -_ R R R R R R ___ NR NR NR NR --_ R R R
Carbcnate Chloride Hydroxide Nitrate Sulfate Sulfide
Bt?WZ Beet Sugar Liquors Benzaldehyde, 10% Benzaldehyde, Above 10% Benzene, Benz01 Benzene Sulfonic Acid, 10% Benzoic Acid Bismuth Carbonate Black Liquor Bleach, 12.5% Active Cl2 Bleach, 5.5% Active Cl2
R R
R R R R NR R R R -R R R
(continued)
TABLE 1.17:
Chemical
73OF __--R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
ENGINEERED
Temperature 150F 250'F R R R R R R R NR R R R R R -_ R R __ R R R R R R R R R R R R R R R R -R R R R R R -R R -_ R R R R R R R R R R _NR R NR NR R R' NR R _R R _R -_ R R R R R R R R R R -_R R -__ R R R R R -R __ -_ NR R R R R NR
PLASTICS
300F
R
(continued)
Chemical Chlorobenzyl Chloride Chloroform Chlorosulfonic Acid Chromic Acid, 10% Chromic Acid, 30% Chromic Acid, 40% Chromic Acid, 50% Citric Acid coconut 011 Coke Cven Gas Copper Carbonate Copper Chloride Copper Cyanide Copper Fluoride Copper Nitrate Copper Sulfate Corn syrup Cottonseed Oil creso1 Cresylic Acid, 50% Croton Aldehyde Crude Oil Cupric Fluoride Cupric sulfate Cuprous Chloride Cyclohexane Cyclohexanol Cyclohexanone Detergents Detergent Solution (Heavy Duty) Dextrln Dextrose Dichlorobenzene Dlchoroethylene Diesel Fuels Diethylamine Diethyl Cellosolve Diethyl Ether Diglycolic Acid Dimethylamine Dimethyl Hydrazine Dioctyl Phthalate Dioxane Dioxane,1.4 Disodium Phosphate Divinylbenzene Epsom Salt Ethyl Acetate Ethyl Acetoacetate Temperature 150F 25O'F -NR R _R R R R R R R R R R R R R R R R R NR R R R R R R NR R R R R NR NR R NR R --NR NR NR R R R NR R R _NR R _R R R R R R R _R R R R R R R NR NR NR R R R R R NR NR R R R R NR NR R NR R --NR NR
NR NR NR R -R --_
73'F R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
XF NR _-_____ R R __ _R R R R R R R NR NR NR R R R R NR NR R R
BOrZlX Boric Acid Brine, Acid Bromic Acid Bromine, Liqud Bromine, Vapor 25% Bromine, Water Bromobenzene Bromotoluene Butadiene BUtme Butyl Acetate Butyl Alcohol Butyl Cellosolve Butylene Butyl Phenol Butyl Stearate Butyrx Acid Cadmium Cyanide Calcium Bisulfide Calcium BisulfitC Calcium Carbonate Calcium Chlorate Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Calcium NItrate Calcium Oxide ca1c1um Sulfate cane Sugar Liquors Caprylic Acid Carbon Dioxide, Wet Carbon Dioxide, Dry Carbon Disulfide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Castor Oil Caustic Potash Cellosolve Cellosolve Acetate Chloracetic Acid Chloral Hydrate Chloramine Chlorine Gas, Dry Chlorne Gas, Wet Chlorine, Liquid Chlorine Water, Saturated Chloracetic Acid Chlorobenzene
R R
NR
NR NR
NR
R
__
R R
R R R R R R R R
R R
NR
-NR
NR R NR R -_NR NR NR NR NR R -R _-_
3 "s 9 w. 4 2 5 D "s Q ? 3
NR
(continued)
TABLE 1.17:
ENGINEERED lkmperarure
PLASTICS
(continued)
TWperatUIe
Chemical Ethyl Acrylate Ethyl Chloride Ethyl Chloroacetate Ethyl Ether Ethylene Bromide Ethylene Chloride Ethylene Chlorohydrin Ethylene Diamine Ethylene Dichloride Ethylene Glycol Ethylene Oxide Fatty Acids Ferric Chloride Ferric Nitrate Ferric Sulfate Ferrous Chloride Ferrous Nitrate Ferrous Sulfate Fluorine Gas, Wet Fluoboric Acid Fluoslliclc And Formaldehyde, 35% Formaldehyde, 37% Formaldehyde, 50% Formic Acid Fornnc Acid (Anhydrous) Freon F-11 Freon F-12 Freon F-21 Freon F-22 Freon F-113 Freon F-114 Fruit Juices, Pulp Gallic Acid Gas, Natural Gasoline, Leaded Gasoline, Unleaded Gasoline, Sour Gelatin Gin GlUCOSZ Glycerine, Glycerol Glycolic Acid
73'F -R
R R
150F R R __ R R R NR NR NR R R R R R R R R R __ -R R R -R R R R R R R R R R R R R R R R R R R
250F NR R __ __ R R NR
NR
3OOF
Chenlcal Glycols Fkptane Hexale Hydrobromic Acid, 20% Hydrobromlc Acid, 50% Hydrochloric Acid, Cone 37% Hydrocyanlc Acid Hydrocyanuz Acid, 10% Hydrofluoric Acid Dilute Hydrofluoric Acid, 30% Hydrofluoric Acid, 40% Hydrofluoric Acid, 50% Hydrofluosiliclc Acid Hydrogen Hydrogen Cyanide Hydrogen Peroxide Hydrogen Peroxide, 50% Hydrogen Peroxide, 90% Hydrogen Phosphlde Hydrogen Sulfide, Dry Hydrogen Sulfide, Aqueous Sol. Hydroquinone Hypochlorous Acid Iodine Iodine Solution, 10% Isopropyl Ether 1sooctane Jet Fuel, Jl'-4 Jet Fuel, JP-5
73'F R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
150F -R
25OOF
R
3ooF
R R R R R
R R R
NR R R R R R R R R R _-_ R ___R R __ -_ __ __ _--__ R R R R R R R R --
NR R __ __ R R NR NR NR R R R R R R R 11 R -_R -_ __ _-_ --_--__ _-_ _R R R R -_ R R R --
R R R R R R R R R ---R R R ---_ -R -_ -_ R ---_ -R R R __ __ R -_ R R R R
R R R
R R R R R R R
R R R R R R R R R R R R R R R R R R R R R
R R R R R R R R R R R R R R -_ R R R R R R R R R -_ __ R R R R __ R R R R R R R
R R R R R R R R R R R R R R --_-R _R
R
R R ___ R R R --R R R R R R R
Lactic Acid, 25% Lactic Acid, 80% Lard Oil Laurie Acid Lauryl Chloride Lead Acetate Lead Chloride Lead Nitrate Lead Sulfate
R R R R R R R R R
(continued)
TABLE
1.17:
ENGINEERED
PLASTICS
!continued)
Ten-eratce
Chemical
73'F -R R R
15O'F
R R
2SOOF
R _-
_)L-*
Chemical Naphthalene Natural Gas Nickel Acetate Nickel Chloride Nickel Nztrate Nickel Sulfate Nicotine Nlcotinic Acid Nitric Aad, 10% Nitric Acid, 30% Nitrx And, 40% Nitric Acid, 50% Nitric Acid, 70% Nltrlc Acid, 100% Nitrobenzene Nitrous Aad, 10% Nitrous Oxide Oils, Vegetable Oleic Acid 0lelL-J Oxalic Acid Oxalic Aad, 50% Oxygen, Gas OZOIUZ Palmit-c Acid Palmitlc Acid, 10% Parhfflrl Perchlorlc Acid, 10% Perchlorlc Acid, 70% Pa-phosphate Petroleum Oils, Sour Petroleum 011s. Refined Phenol Phenyl hydrazine Phosphoric Acid, 10% Phosphoric Acid, 50% Phosphoric Acid, 85% Phosphorus Yellow Phosphorus Pentoxlde Phosphorus Trlchloride Photographic Solutions
73OF __--R
R
15O'F
R
25O'F
31)0OF
Lemon Oil Lime Sulfur Linoleic Acid Llnoleic Oil Linseed Oil Linseed Oil, Blue Lithium Bromide Lubrlcatinq 011, ASTM #1 Lutxicatinq 011, ASTM #2 Lubrlcatlnq 011, ASTM #3 Maqneslum Carbonate Maqneslun Chloride Maqneslum Hydroxide Magnesium Nitrate Maqneslum Sulfate Malelc Acid Mallc Acid Mercuric Chloride Mercuric Cyanide Mercuric Sulfate Mercurous Nitrate Mercury Methane Methoxyethyl Oleate Methylamine Methyl Bromide Methyl Cellosolve Methyl Chloride Methyl Chloroform Methyl Ethyl Ketone Methyl Isobutyl Ketone Methyl Methacrylate Methyl Sulfate Methyl Sulfuric Acid Methylene Bromide Methylene Chloride Methylene Iodine Milk Mineral Oil Molasses Motor Oil Naphtha
-___-__-
R
R
R R R R R R
R
R R R R R R
R R R R R R R R R R R R R R R R R R R -NR R R R R R R _R R NR NR NR R R R R R
R R R R -_ R R R R R R R R R R R R R R R R _NR R R R NR NR NR _R -NR NR NR R R __ R R
R R R R R R R R _--_ _--_ R __ -NR R R R NR NR NR -_ R _NR NR NR -R -_ R R
R R R R R R R R R R R R R R R
R
R __ R R R R R R R R R R R R R -R R NR R R R R R R R R R -R R R -R R R _R R R
__ -R R R -R R R R NR NR NR NR R -R R NR NR NR R R R R _-
__ __-_
R R R __R -_ -NR NR NR NR -_
R
R R R R R R
R R R R R R R R R R R R R R R R R R R R R R R
R __ NR NR NR R R ___ _-
R
R R R
R
R
R R
R
_NR __ R R R _R R -_
-NR _R ---_ -_ -_ -_
R R R R R R R R R
(continued)
TABLE 1.17:
Chemical
ENGINEERED
72F
I? R R II R
PLASTICS
330'F
(continued)
Chemical Silicone Oil Silver Cyanide Silver Nitrate Silver Sulfate
SOSPS
Temperature ,=,oc 250F --
73F R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
Plcric Acld Plating Solutions, Brass Plating Solutions, Cadmium Plating Solutions, ChrCJUE Plating Solutions, copper Plating Solutions, Gold Platrng Solutions, Lead Plating Solutions, Nickel Plating Solutions. Rhodium Plating Solutions, Silver Plating Solutions, Tin Plating Solutions, zulc Potash Potassium Alum Potassium Alur;inun Sulfate Potassium Bichromate Potassium Blsulfate Potassium Berate Potassium Bromide Potassium Carbonate Potassium Chlorate Aqueous Potassium Chloride Potassium Chromate Potassium Chlorate Potassium Cyanide Potassium Dichr9mate Potassium Ferricyanlde Potasslun Ferrocyanide Potassium Hydronde Potassium Iodide Potassium Nitrate Potassium Pa-chlorate Potassium Permanganate, 10% Potassium Pennanganate, 25% Potassium Persulfate Potassium Sulfate Propane Propylene Oxide Pyrldine Pyrogallic. Acld Salicylic Acid Salicylaldehyde Silxlc Acid
__
R
R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R NR NR R R R R
R R R R R R R R R R R R R R R R R R R R R R R R R R R R R -R R R R R NR NR R R NR --
__ -___ ___ __ _--i_ -R R R R R -R R R R R R R R R R -R R _R R -_ R R NR NR -_NR -_
-_ --_
__
R R R R R R R R R R R R R R R R R R R R R R R R R R R __ R R R R R R R R R R R R R R R
__
R R R _R R R R -R R R R R R R __ R R R R -R -R R R -R R R R R R R R R R R R -_R
-R R __ _R R R R _R R R R R R R -R R -_ -_ -R -R R R -_ R R R R R R R R R R R R _-_ R
-_
R R R -_
__
R R R R
R R R R R R __ -_ R -_ R R -R R
NR NR
NR
Sodian Acetate Sodium Alum Sodium Benzoate Sodium Bicarbonate Sodium Bichromate Sodium Bisulfate Sodium Sisulfite Sodium Bromide Sodium Carbonate Sodium Chlorate Sodium Chloride Sodium Cyanide Sodium Dichromatc Sodlun Fluoride Sodiu Hydrande, 15% Sodium Hydroxide, 30% Sodium Hydroxide, 50% Sodium Hydroxide, 70% Sodium Hypochlorite Sodium Iodide Sodium Metaphosphate Sodium Nitrate Sodium Nitrite Sodium Perchlorate Sodium Peroxide Sodium Phosphate, Alkaline Sodium Phosphate, Acid Sodium Phosphate, Neutral Sodium Silicate Sodium Sulfate Sodium Sulfide Sodium Sulfite Sodium Thiosulfate Sour Crude 011 Stannlc Chloride Stanncus Chloride Starch Stearic Acid Stoddard's Solvent
(continued)
TABLE 1.17:
ENGINEERED
Tern eratme
PLASTICS
(continued)
Temperature 250F 150F R R NR R R NR R R R R R R R R R
R
Chemical Succinic Acid sulfate Liquors Sulfite Liquor Sulfur Sulfur Chloride Sulfur Dioxide, Dry Sulfur Dioxide, Wet Sulfuric Acid, 10% Sulfuric Acld, 30% Sulfuric Acid, 50% Sulfuric Acid, 60% Sulfuric Acid, 70% Sulfuric Acid, 80% Sulfuric Aad, 90% Sulfuric Acid, 93% Sulfuric Acid, 94% Sulfuric Acid, 95% Sulfuric Acid, 96% Sulfuric Acid, 98% Sulfuric Acld, 100% Sulfurous Acid Tall Oil Tannic Acid Tanning LiqUOrS TX Tartaric Acid Tetraethyl Lead Tetrahydrodurane Tetrahydrofuran Thlonyl Chloride Thread Cutting Oils Toluene, Toluol Tomato Juice
73'F ---R R
15O'F R ___ R -_ R R R R R R R R R R R R R R -_ R R R R R R R NR NR R R R R
250'F R __ _R __ R -R R R' R R R --_ __ -_ -_ -__ R R R R R R R NR NR -R NR R
303'F
Chemical Transformer 011 Transformer Oil DTE/30 Tributyl Phosphate Trlchloroacetic Acid Trichloroethylene Triethanolamlne Trlethylamine Triosodlum Phosphate Turpentine
X-E!.3
73F _~____
300F
R R R R R R R R R R R R R R R R R R R R R R R R R NR KR R R R R
__ -_ ___ --_-_ ___ __ __ -_ __-__ --_ -_ __

R -_ -R __ R NR NR _R NR __
R _NR NR R NR NR R R R --_ R R R R R R R R R R R R R -R R R
--NR NR R
NR
NR R R __ __ -__ _--
Urine vase11ne VUlegar Vinegar, White Vinyl Acetate water water, Acid Mine water, Demineralized water, Distilled or Fresh water, Salt water, sea water, sewage Whiskey White Liquor WlilES xy1ene (xylol~ Zinc Chloride Zinc Nitrate Zinc Sulfate
R R R R R R R R R R R R R R R R R R R R
R R R R R R R R R R R R R
-R R R
60
Corrosion
Resistant
Materials
Handbook
TABLE
1.18:
FURAN
RESIN-KOCH
ENGINEERING,
MAURICE
A. KNIGHT
DIVISION
CHEMICAL
RESISTANCE
Meaning
OF PERMANITE
of Symbols
E-Excellent
all concentrations
r&stance;
uitable for general an d temperatures.
service most
Ga
resistance; suitable for most servicesconcentrations and temperatures to 2 12 F.
F-Fair resistance; suitable for some services-dilute concentrations and temperatures to 90F. NR-Not recommended for this service under most conditions.
Resistance Chemicd Resistance Chemical Chemical Rerirtrnce ...... E Coconut Oil Acetic Acid (to 85%) ....... ... E Nitric Acid ,.. ,,.... NR G Copper Cyanide Acetic Acid, Glacial ............... ........ E Oleic Acid E .......... G Copper Sulfate .............. Acetic Anhydride E Oxalic Acid . ...E I..... . Acetaldehyde ................. ................................ Corn Oil ...... E Paraffin .._ ..,. ,. E E Cottonseed Oil Acetone ............................................................... ................ E Petroleum Erher .,.,,....... E .E Aluminum Chloride ...................................... Cresylic Acid ........... ...... .... NR Phenol ,.,.,........... E E Cupric Chloride Aluminum Sulfate ... ...... ....... E Phosphoric Acid (to 7% cone.) E ........ E Dibutyl Phthalate Ammonium Bromide ........ .._......_ .. .: .... ...... ........ Phosphoric Acid (70 to E E Ethyl Acetate .............. ................. E 85% cont.) _ G Ammonium Carbonate ........ Bisulfate E ................. E Ethyl Alcohol .I.. ....... Ammonium Chloride E ............ ...................... Potassium E E Eth;l Ether Amnionium Fluoride ................... E Potassium Carbonate ______...._._____~ E Potassium Chloride ._......... E .................... E Ethylene Dichl&i& Ammonium Hydroxide ...................... E Ferric Acid Salts (to 45% cont. ) Ammonium Nitrate .... .._ E Potassium Hydroxide EE ................... ... E Ferric Salts ....... ................................. Potassium Iodide Ammonium Phosphate E E Ammonium Sulfate ........................ E Ferrous Salts .................... .E Potassium .Sulfate . ...._________...__._........................ F Pyridine E Formaldehyde Amy1 Acetate ........................................................ ................. ... ..... ..... E Pyridine Sulfate __._.._._____.._.___........... G ................................ F Formic Acid .......... Aniline ___......_....._..._ E Sodium Bicarbonate E E Sodium Bisulfate ......................... G Fuel Oil ................. Aniline Hydrochloride E _ .....___________ ._..._ ::....:I................... . Sodium Carbonate NR Aqua Regia ....................................................... Furfural .E E Barium Chloride .............................................. Furfuryl Alcohol .................................... E Sodium Chloride E .......................................... Gasoline ................... .E Barium Hydroxide ...........E Sodium Chlorite, Acid Soln. I _...E Glycerine Beer .......................................................................... E ................. Sodium Hydroxide .......... E Hydrobromic Benzene ........................................................................ Acid .................................Sodium Hypochlorite E E E Benzene, Monochlor ...................................... Hydrochloric .E Sodium Iodide Acid ................................. Sodium Sulfate E ...................................... .E Hydrofluoric Ben-e, o-Dichlor Acid (to 50% cont.) E Sodium Sulfide ,...,.. E .................... Hydrofluoric Acid (50 to .E Benxene, 1, 2, &Trichlor Sodium Sulfite ,. E G E Benxoyl Chloride .................. ................... 70% cont.) ....................................................Sodium Thiosulfate E E Acid .................................... Stearic Acid G Hydrofluosilicic Benzyl Alcohol ................................................... E E Hydrogen Peroxide (to 3% cont.) ... F Sulfur Monochloride E Borax ............................................................................ Sulfuric Acid (to 5096 cont.) E . Boric Acid ........ Hydrogen (over ....................................................... Peroxide G ....................................... NR Sulfuric Acid ( 50 to 60% cont.) .NR Bromine ............................................................... 3% cont.) F E Sulfide .......................................... Sulfuric Acid (over 60% cont.) G Bromine Water ................................................. Hydrogen ,, E NR Sulfurous Acid ... Butyl Alcohol ................................... E Iodine ... .................................................................. .,,.... E E . Calcium Bisulfite ...............................................Isoamyl Alcohol ..............................................Tannic Acid E E Tartaric Acid Alcohol .......................................... .......... Calcium Chloride .................................. E Isopropyl Tin Chloride ..,................ E E Trichlorethylene .................................................................. _. ............................ Kerosene E Calcium Hydroxide .............. __........_..._.._.................E E ..................................... ................. Trisodium Phosphate .....................................lactic Acid ........ P Calcium Hypochlorite E E Toluene E Lead Acetate ........................................................ Carbon Bisulfide ................................................. .,, E E Magnesium Chloride ........................._...... Turpentine E ....... ......... ............ E Carbon Tetrachloride E Vegetable Oils ..,.. ,._.... E .._.... ......................... E Magnesium Sulfate ...................................... Castor Oil .................................. E ., .E Vinegar ................................................. G Maleic Acid ............................................................ Chlorine (dry) E E Water. Distilled G Chlorine (wet) ................................................Manganese Sulfate ............................................. . .._............... E E Water, .............................................. Salt G Methyl Alcohol Chlorine Water ......................................... ,_......... . . E _ S ,Wine ......................................... Methyl Ethyl Ketone ..................................... E Chloroform Whiskey ............. ...................... ...................... E E Xylene Mineral Oils ........................................................... ................................ P Chromic Acid (dilute) ...... ..... .......................... ... ...................... Nickel Chloride ...................................... E z.mc Chloride .............. ........ NR Chromic Acid (concentrated) .. ................. .............................. E E ...... E Nickel Sulfate ................................................. 2rnc Sulfate ............................................ E Citric Acid ..... .......................................................... _.
Synthetic
Resins and Polymers
61
TABLE
1.19:
ISOPOLYESTER
RESINS-AMOCO
CHEMICALS
Corrosion resistant isopolyesters are characterized among resin suppliers and users by the molar ratio of the aromatic to the unsaturated acid and by the glycol used in synthesis. In this nomenclature, Amocos recommendation for a cost-effective resin with outstanding corrosion resistance to a broad range of liquids over a wide temperature range is a 1 : 1 propylene glycol isopolyester. That is, the resin is made with equal molar amounts of maleic anhydride and isophthalic acid and reacted with a sufficient excess of propylene glycol to ensure esterification to a high molecular weight. While the basic basic formulation three laboratory The resin stability. than the desirable corrosion suitable variations resistant resin offers the most versatile range of resistance properties, variations of the for specific applications are available from many resin suppliers. The second table shows of the recommended formulation.
with higher levels of maleic anhydride has greater crosslink density and thus offers very good temperature It should maintain mechanical properties up to 100C. It also shows better resistance to aromatic solvents basic formulation, although its resistance to mineral acids is not quite as good. Its brittleness may be unin some applications. and neopentyl glycol improves caustic resistance, The gasoline resistance of these as that of the other formulations shown in the second table. Adipic acid generally
Adipic acid improves flexibility formulations is not as consistent lowers resistance properties.
Chemical
Medium Saturated
resistance Temperature,
of laboratory C
synthesized Rating
resin* Applications Marine, bnne handling
Composite Acceptable Excellent Excellent Acceptable Excellent Acceptable Good Excellent Excellent Good Good Good Acceptable Acceptable Excellent Good Acceptable* Good
l l
NaCl H,O
93 71 71 49 49 93 71 71 71 49 71 71
Distilled
Pipe, water
10% Na,CO, 25% H,SO,
Chemical Chemical Descaler Fertilrzer, Chemical Chemical
storage handling handltng food handling handlrng handling handling handling
5% HCI 15% HCI 15% H,PO, 85% H,PO, 5% HNO, 25% Acetic Acrd Acid) Vinegar (5% Acetic
71 71 38 38 38 23 23 49 Bleach 49 49 71 71 71 In Water lsooctane lsooctane 49 23 23 23 23
Food storage,
Food processing, Burial conditions Fertilizers Chemical Failure Fertrlizers
pH, Soil Slurry pHlo Soil Slurry 1N NH,OH 2% NaOH 5% NaOH 38% Urea 100% Household Saturated Alum 100% Corn Syrup 50% Citric Acid 50% EtOH 50% 34-5-5 Fertilizer Lead Free Regular 50% 75% Toluene/50% Toluenel25%
Complete Acceptable Excellent Excellent Excellent Excellent Good Acceptable Excellent Good Good Good
Food handling Food handling Food, beverage Fertilizer Gasoline Petroleum Chemical ASTM C581, one year rmmersron. (continued) storage storage
Gas
Benzene 1:l
l l
Propylene
glycol
rsopolyester
cooked
to less than 15 acid number
Blistering
was apparent.
62
Corrosion
Resistant
Materials
Handbook
TABLE
1.19:
ISOPOLYESTER
RESINS-AMOCO
CHEMICALS
(continued) resistant 1 :2 performance 1 :l neopentyl 45 2.4 105 17.6 (121) 0.843 (5810) 50 from one year data excel lent excel lent good excel lent unacceptable excel lent excel lent unacceptable unacceptable unacceptable good unacceptable good unacceptable excellent unacceptable excellent unacceptable 0.7:1 0.3 neopentyl 45 2.7 103 18.6 (128) 0.795 (5480) 53
Resin formulations Isophthalic/Maleic Adipic Glycol % Styrene Clear Casting % Elongation Heat Distortion Laminate Flexural Flexural Barcol Properties Acid, Moles Ratio, Moles
for corrosion 1 :l propylene 45 1 .6
propylene 45 1 .3 132 14.8 0.887 (102) (6110) 53
Temp., IOpsi
C ASTM C581 (MPa) (MPa)
116 19.5 (134) 1.074 (7400) 56
Properties, Strength, Modulus, Hardness
106psi
Corrosion Distilled Water at 71 C
Resistance, excellent good excellent excellent complete excellent excellent excellent good
Composite
ratings
excellent good excellent failure acceptable complete failure excellent excellent excellent excellent
5% HNO,at
71 C
5% HCI at 71 C 25% H,SO, at 71 C 5% NaOH at 71 C #2 Fuel Oil at 23C Ethyl Gasoline Unleaded Benzene at 23C at 23C Regular at 23C
A partial Acetic Acidic Acrylic Alcohols Alum Ammonia Beer Brine Cheese Chlorine Chlorinated Coconut Cod-Liver Crude Distilled Ferric Oil H,O Chloride Oil Oil Dioxide Lye Acid Fumes Emulsions
list of materials
handled
and stored
in corrosion
resistant
isopolyesters Gasoline
Gasoline GI\,cols Grain Grapes HCI Solutions Hs (NH.) H NO, Hydrogen H, PO. Lye Manganese Meat Milk Monomeric Plasticizers Solution PO, Sulfide Chemicals
Premium Sa It Spray Seawater Sewage Soap Curd Soil
Salt Solution
Agricultural
Sour Crude Soybean Sulphur Vegetable Vinegar Vinyl Water Acetate Oil
Oil
H,SO, Solutions
Sugar Solution Dioxide Oils
Treatment Smelting
Chemicals
(NH.)z SO,
Solutions (NH,) Pasta Peanut Pickles Potable H,O NO, Oil
Wet Gases from Copper Whey Wine Zinc Chloride
Fatty Acids Fertilizers Fruit Juices Fuel Oil
Synthetic
Resins and Polymers
63
TABLE 1.20:
NYLON
6/6 RESINS-CELANESE
PLASTICS
CELANESE
reduced stantially
1000 series nylons are of the 6/6 type polyamides. They are used in the replacement weight, corrosion resistance, self-extinguishing properties, self-lubricating qualities and lower cost. Chemical
CHEMICAL
of metals, colorability
offering at sub-
Resistance
Of Cklanese
Nylons
1000
& 1003
EFFECT
Acetaldehyde. Acetamrde. Acetrc acid, Acetone,

Alcohols, aliphatic.
A/B t
D A
Dimethyl formamide, Dioctyl phthalate. Droxane. [h;;o;ats and oils,
lOC% 960/,
; A A;B : A A:B A/B AIB A/B BBC ; A0
Alcohol, benzyl, Alcohol, phenyl ethyl,

Ally1 chlorrde. Alummum chloride, Aluminum sulfate,
Ammonia, Ammonra.
gaseous,
Ammonrum~carbonate. Ammonrum chloride, Amvl acetate.
10%
10%
Ether, Ethyl acetate, Ethyl butyrate. Ethylene chlorhydrin, Ethylene chlorrde. Ethylene dramine. Ethylene dichloride. Ethylene glycol, Ferric chloride, Ferrous chloride, Ferrous sulfate, Fluorrne. Fluorosilrcic acid, Fluothane, Formaldehyde, Formic acrd. Fruit juices, Gasoline Gasolrne/Benzene Glycerine, E/;:;ol. Heptane, Hexane. Hydrobromic Hydrochloric Mixture
100%
100% 1OFh 100% 10% 10% 10% 10Yo 400/, 3% 10% 80:2Gj ;
Aniirne. Antrmony trichloride, Asprrin.
1009; 100% 10%
Barium chloride, Barium sulfide, Benzaldehyde. Benzene, Benzene sulfonic acid, Benzoic acid, Bdumen. Bleaching lye, Boric acid, Boron trifluoride. Bromine, Bromine water, Butanol. Butvl acetate. Butilene glycol.
Butyric acid, Calcium chloride, Calcium chloride in alcohol, Calcium hypochlorite. Camphor, Carbon disulfide, Carbon tetrachloride, Carbontc acid Chloracetic acid, Chloral hydrate, Chlorine, Chlorine water, Chlorobenzene, Chloroform, Chlorosulfonic acid, Chromic acid, Citric acid, Creosote, Cresols. Cresylic acids, Cupric chloride, Cupric sulfate, Cyclohexane, Cyclohexanol, Cyclohexanone. Decalin, Detergents, Dibutyl ohthalate. Drchlordrfluoromethane, Dresel 011. Drethylene glycol, Dimethvl carbinol.
10% 100% 100% Saturated
10%
: AD A A ; A/B
10% lo&&
30% 100% 100% 100% 20%
acid, acid,
10%
20%
Hydrofluoric acid, Hydrogen peroxide, Hydrogen sulftde, Hydroquinone, Iodine Iodine in alcohol,
10% 2% 10% 4% 0.5% 3% Saturated -
CD : Bl? A/B A
100%
100% 10% 10% 10% 1OFh 100% lo-100% 1% 10% 10%
in KI solution. Iso.octane,
GJ 10% 10% 10% 10% 8% 1osj 100% 100% 100% -
i! A BgC
; : : AC A/B : AC A ;
Lactic acid, Lead acetate. Lead stearate. Linseed oil,
::
B/C
D B/C A
Magnesium chloride, Magnesium hydroxide, Magnesrum sulfate, Manganese sulfate, Mercuric chloride, Mercury, Methanol, Methyl acetate, Methyl ethyl ketone, Methylene chloride, Mrlk, Mrneral oils. Naphthalene. Nickel sulfate, Nitrrc acid, Nitro-alcohols. Nitrobenzene. 011s of vegetables Olerc acid, and spices,
9Gh -
10% lo@) 100% : C A A
(continued)
64
TABLE 1.20: NYLON 616 RESINS-CELANESE
PLASTICS
(continued)
CHEMICAL Oleum. Oxahc acid. Paraffin, Perchlorethylene. Perchloric acid. Petroleum ether, Phenol, Phosphoric acid, Phthahc acid. Potasswm bicarbonate. Potassium bromide. Potassium carbonate, Potassium chloride. Potassium dlchromate, Potassium ferrlcyanlde. Potassium ferrocyanlde. Potaswm hydroxide. Potassium Potassfum Potassium Potassium Pyrldlne. Resorcinol. Sallcyhc acid. SIllcone flulds, Sliver nttrate. Soap solution. Sodium acetate, Sodlum benzoate. Sodturn bicarbonate. Sodium blsulfate. Sodlum blsulflte. nltrate, permanganate. sulfate, sulftde.
EFFECT
CHEMICAL Sodbum perborate. Sodwm phosphate, Sodium skate. Sodturn sulfate, Sodium sulhde. Sodium thlosuifate. Stanmc chloride. Stannlc sulfate, Stearic acid, Styrene. Sulfur, Sulfur dioxide. Sulfuric acid. 5% Sulfurous acid. Tallow, Tar, Tartaric acid. Tetrachlorethylene, Tetrahydrofuran. Tetralm. Thlonyl chloride, Toluene. Transformer oil. Trlchlorethylene. Triethanolamine. Urea. VaselIne. Vegetable oils. Vinegar, Vinyl chloride. Water, cold, Water, hot, Wax. molten, White spirit. Wmes and splrlts, Xylene. Xylenol. Zinc chloride. Zmc oxide, Zinc sulfate, 90.10&+, 10.9oqo 2590% 10% 100% 2% and alb&e
0
EFFECT A/B ; 2 ; : A : C
ii
10% 100% 10% 10% Saturated 60% 10% 60% 90% 5% 30% 30% 10% 50% 10% 1% 100% 90% 100% 100% 6&$ 50% 10% 10% 10.50% 10.9oq/, 10% 50% 15% Cl 10.50%
: 10% 1oGj 1oG$o AB A 1 A A?* A A ;
B/C
A ; A A$ ; AC A
Sodium bromtde.
Sodium Sodbum Sodium Sodbum Sodturn Sodium Soolum carbonate. chlorate, chloride. cyanide. hydroxide. hypochlorite. nitrate.
4. No attack, little or no absorption, little or no effect on mechanical properties. 3. Liile or no attack, some absorption causing slight swelling and slight reduction in mechanical properties at 73F (23C) C. Some attack or considerable absorption at 73F (23C) material not suitable for contact unless limited product life is acceptable. D. Material decomposes at 73F (23C) in a short time.
TABLE 1.21:
NYLON
11 RESIN-RILSAN
RILSAN RATING NYLON 11 CHEMICAL RESISTANCE RATING BESN BLACK T 194pF 9OC CHEMICAL Dwlhyl Ether CONCENTRATiON WF & A A A PW A+ A X A+ A A X A X A A A A A A A A PW A A A A A Peroxde Ac,d Ac,d 20% 2% A A B A B A A A A 50% A A A PlJre AI A A A A A A A A A B A A X A A E A X At A A X B X A A A A A+ A A A A A A A A B B X B lOJ=F 203 140~1 - (,Oi BESN BLACK T
CHFMICAL AWIafd&lde Acettc Acid Acetoc Ac,d Acetoc Aud Ace,,c AnhydrIde ACetOW ACZ?tlee Aluminum AllllIWl~ Amonwm Ammonium Ammo,m Hydrorade Nllrate Sulfate SuItate
CONCENTRATION
6aoF
20-c a
104OF 4o=c 6
14ooF 60C x A B X
194OF 9OC
5% 10% 50%
A A B El
A A
D,octylphosphate D,ocrylphd,alare Ethanol Ethyl AceWe Ethylene Chlorhydrtn Ethylene Ethylene Glycol Oxade Esrers
X At A A A A A A A
X B A AA A A B A
Pure
A A A A A A
Fatty Aad FlOrll-le
Formaldehyde Formic Actd Freon 12 Freon 22
sat. sol.
A A A
Amy1 Acetate Anethola Aniline Barun Beer Benzaldahyda BeWe* Benzyl Alcohol Bromine Blxx But, Alcohol Calcwm Arsenate Calcium Chloride Ca,cum NIlrate
Concenlrated
Pure Chloride
B+ A A A A n X A At A A A A+ D X B
X A
X A
X A
Freon 502 Fru,t Jutices Furfuryl Alcohol
B A+ X X A B A A
X B X
X
Gas (Coal) Gasolme (High Octane) Glucore Glycerine
A X A A
A
GlCOl Gr.?aSl?s Heplane Hydrogen Hydrogen
sat
sol.
Carbon D,rult,de Carbon Tetrachk,r,de Chlorane Chloroform Chromtc Actid Coder Citrtc Actd Copper Sulfate CWSOl Cyclohexane CClOhe~.3~Ol Cyclohexanone D D. T. Preparat~onr D,ammonum Phosphate 10%
a+ X X X X
Hydrochlortc Hydrochlor,c
x
X
X X X
Hydroxy
Oumolme
IY)cyanaleS Isopropyl Kerosene Alcohol
X A A A X A A A A A I3
B A X 0 X X
Lacttc Acid Lmseed Cake Magnesrum Chloride Mercury Methane Methanol Methyl-Cellosolve
a
A A
A X
B Methyl Mrthyl Acetate Bromtde
D,cnloroerhylene Dnrthanolammc 20%
A+
A+
(continued)
TABLE
1.21:
NYLON
11 RESIN-RILSAN
(continued)
RATING RATING BESN BLACK T CONCENTRATION WF 7GC -A A 104OF 40C B A
A Ai X A X A
CHEMlt34
CONCErJTCATlQW
WF - 20C
A
lWF 4oc X a A A A X
14OOF GOC
194OF 9O*C
14WF 6LlC B A A
Methyl Chloride Methyl Sullale Melhy tthvl Ketcne Krrone
A A A A B A A A
All Concenrration
x
X A X
A A
Methyl Isobutvl Milk
B
A
Monochiorobanlene Mustard Naphtha Ndphthalene Ntrrbc Ac\d Otis Crude 011 Refw2d Ole,c Actd Oxalx Oxygen Perchloroerhylrne Phenol Phosphoric Acid P,cr,c Ac,d PJ,ars,m Potauwm Potai,um Potrwum Pa,arsim Propane Pydraui F9 Pyr,d,ne Soap Solution Sodum Sodum Sodurn Sodurn Carbonate Chlortde Hydroxide Hvpochlwtte Concenxaied Saturated SC% Concentrrred Dduw Commrrcnl Grade Pure Cdrbcnate Hydroxade N,rrats Parmmp~rl*lu Sll~l.
bl.
A A A X A A A A A X X B X A 6 Fit X A A A X A A A X X A X X X B X X X X X A+ A X At A A B B A B X X 6 X
A A
A 0
B A A A A A A
A7
X X A A
X A A A A A B X
A
A A A
A A n Ai 8 A A A A A
Acud
A A A
A
401
A t3 A
A A
A A A A
lro??
A At X A A A 0 A A A A B A
A
A
A A
A+ A
6 B
A A 0 X 5
B A X X X
X A X
Sodwm Hypochlorlte
Synthetic
Resins and Polymers
67
TABLE
1.22:
NYLON
REINFORCED
VINYL
HOSE-SETHCO
DIVISION,
MET PRO CORP.
Sethcos NRV (Nylon Reinforced Vinyl) grade hose may be used at working pressures ranging from 100 to 250 psi (depending upon size). Its flex life exceeds that of rubber and its characteristic inertness satisfies requirements for a wide range of industrial and laboratory applications. The reinforcing nylon mesh is encapsulated in the walls of the clear vinyl, providing a high strength, smooth surface hose. The imbedded mesh is never in contact with fluid or atmosphere. Working temperatures range from 20 to 175F as discharge hose and 20 to 140F as suction hose. The vinyl is fire resistant and self-extinguishing.
Sethco Nylon Reinforced Vinyl Hose Chemical Resistance Guide

Excellent Chemical Resistance for:
Essential Oils Ethgl Alcohol Ethyl Chloride Ethylene Glycol Fatty Acid Ferrtc Chloride Ferric Sulphate Fluoborlc Actd Flue SI~ICIC Acid Formic Actd Formaldehyde Freon Galhc Actd Gas (Natural) tS;sa;;;e (NonA:omattc) El;S;i?pendtng on type) Oxahc Acid Oxygen Palmmc Actd Picrtc Acid Phosphoric Acid Potassium Chloride Potassium Sulphate Propane Pyrethrum Sodium Btsulflte Sodturn Bicarbonate Sodturn Borate Sodium Carbonate Sodium Chloride Sodium Cyanide Sodwm Hydroxtde Sodium Hypochlorlte Sodium Nitrate Sodium Phosphate Sodtum Slltcate Sodium Sulohlde Sodhum Sulphate Sodturn Thlosuiphate Steanc Acid Stannous Chloride Sulphur Dtoxtde Sulphurlc Actd (DII Sulphurous Acid Tanmc Acid Tartartc Acid Tar 011 Turpentine Urea Uric Actd Vinegar Water Whiskey Wine WOOI 011 Zinc Chloride Zinc Hydrate Zinc Sulphate Acetic Acid Air Alcohols Aluminum Chloride Aluminum Sulfate Alums Ammonia Gas Ammontum Chloride Ammomum NItrate Amnlonlum Phosphate Ammomum Sulphate Amy1 Alcohol Animal 011s Ant:mony Salts Arsemc Salts Barium Salts Basic Copper Arsenate Beer Benzolc Acid Benzyl Alcohol Boric Acid Basic Copper Sulphate Bordeaux Mixture Butanol Butter Calcium Hydroxide Calcium Hvnochlorlte Calcium .&its Carbolic Acid Carbon Monoxtde Caster Oil Corn 011 Cottonseed 011 Caustic Potash (-20%) Caustic Soda (-20%) Chloroform Chromic Acid Chlortne IDrvt Chlortne (Water) Chromium Salts Copper Chloride Copper Sulphate Cltrlc Acid Cresvllc Actd Cupric Sulphate
Glycerine Hydrochloric Acid Hydrocyantc Acid Hydrofluonc Acid Hydraulic 011 Hydrogen Gas Hydrogen Peroxide (DII.) Hydrogen Sulphlde Lacttc Acid Lard Lead Arsenate Lead Sulphate Lime Linseed 011 Magnesium Chlonde Magnestum Hydroxide Magnesium Sulphate Malelc Acid Milk MIneral 011 Molasses Ntckel Chloride Ntcottne Nttnc Acid 20% Nitrogen Oxtde Nitrous Actd 011
Also
Recommended
for
Causttc Soda (+ 20%) Chlordane :t7zot e Gasoltne (AromatIc) Hvdroaen Peroxlde Icon.) K&o&e Mercunc Chloride Methyl Chlonde Olelc Actd Pentane Perchlortc .Actd Perchlorethylene Phw?olates Ph Jnols Stoddard Solvent Sulphurtc Acid (Cont.) Trtchlorethylene Trichloracetlc Acid
Aniltne Benzlne Benzol Borax Butane Bromine Calcium Btsulphlde Calctum Chlonde Carbon Tetrachlonde Caustic Potash (+ 20%)
Check with
manufacturer
or test in your plant

Chloracetlc Acid Cresols Cyclohexanone Ethyl Acetate Ethylene Dlchlorlde Fuel 011 (AromatIc Gas) 100 octane Fuel 011 Isopropyl Acetate Ketones Laquer Solvent Naphtha Nltrobenzene Paint Solvents Pyridlne Toluene Toluol xylol Xyiene
Acetlc Anhydrtde Acetone Acetyl Bromide Acetyl Chlortde Ammonium Hydroxtde Amy1 Acetate Aromabc Hydrocarbons Butyl Acetaie Carbon Bisulfide
68
Corrosion
Resistant
Materials
Handbook
TABLE 1.23:
OXIRANE
OLIGOMER
OF RESORCINOL-PLASTONICS
INTERNATIONAL
KEY PROPERTIESOF PYROITE ll

1) Corrosron
chemrcals resistance to most solvents (See compatibMy chart.) resistance and toughness. 6) from -80F to over 500F. 7) strength and corrosive 5) Excellent bondrng characterrstrcs. Bonds to metals, glass. concrete, glass. plastics, etc. High resistance Non-galling to thermal cycling. fiber
2)
3) 4)
Erosion Stability
High dielectric
to temperatures
capability.
M ETALS
*
4
DATA INTERPRETATION
/
RESULT
A (4 05
DEPTH OF CORROSION PER SURFACE 002 In. per year mm. yr.) 020 In per year (4 050 In per year (4 5 mm. yr ) 1.27 mm. yr.) Not recommended
B C NR cl
4 )
050 In per year or exploswe
No data
To convert
Questronable rate to mrlllgrams per
decimeter
per year
(mdd)
mdd
= I
yr
,695
specific
gravity
of metal
PLASTICS
SWELLING OR DIMENSIONAL CHANGE. (ANY DIRECTION.) WHICHEVER IS GREATER. 4 1000 4 1500 42000 ,2000 No data Ouestlonable Note When botllng IS tndlcated. boiling temperature varies with concentrahon of corrodent LOSS OF TENSILE STRENGTH 4 1500 4300 45000 ,5000 No data Good Ltmlted DESCRIPTION CHEMICAL ATTACK LIttIe or none resistance resistance (Manor attack) (Moderate attack) RESULT A B C NR -
Attacked or dissolved wlthln minutes or years (Not recommended) No data
EXAMPLES OF TYPICAL CALL-OUT METALS

w 1 I 4 * ) 002 002 002 010 050 050 I I yr yr I any al 200 concentration concentratnn at 70F between 200 and 50. 0.20% from 70F lo 212F A to 200 A at 200 A to 212F at 212F a1 212F an yr I I I 050 yr yr yr in can saturated I any
concentration at 70F concentration
between 70F
and
140F
B 20.500 NR
70.140F
saturated I any yr
at 70F Just a few degrees of temperature dtfterence (or percentage points of con.
NR any
concentration A NR
0 to w
saturated eftect
at 70 F corrosion
CentratIon)
greatly
Comblnattons
marked
A NR are crltlcal
as to concentration
or temperature
PLASTICS
Llttle 200F Ltttle 200 Good from to no chemical (temperature to no chemical F (temperature resistance 70F lo attack 4 lo00 swelling or 415O D loss of tensile strength at lOOn concentration at 70F or A or 4 15 o loss Swelltng ot tenslie strength from 0 to 200 concentration at 70F or A to 200 4 150 or *30 o loss 01 tenstle strength lrom 20 at top of column) attack 4 10O0 swelling
at top of column) chemical attack)
(minor 140F
to 500 concentration
B 20.50e 70.140F
Attacked
or dissolved
W200
swelling 1
01 b50
I) loss
of tensle
strength
I concentrated
at 70F
or 200-F NR
~twnm=rati~re
at too 01 column
(continued)
ABLE
1.23:
OXIRANE
OLIGOMER
200F
KVNAR 200F STAINLESSSTEEL 316 70F
INTERNATIONAL
TEFLON FEP 70F EPOXV 70F
(continued)
HASTELLOV 6 70F THERMOSET 70F
CHEMICAL Acetamide Acetate Solvents Crude
PYROITE II
VINVL ESTER
TEFLON PFA 200F
PYtlgrE
Acetic Acid Vapors 100% (hot) Ace& Anhydride 100% (boilng) Acetic Acid Glacial 70F Acetone 100% Acetonilrik
Akohol, Aminoethanol 2
(continued]
TABLE
CHEMICAL
1.23:
OXIRANE
OLIGOMER
I
KYNAR 200F I I STAINLESSSTEEL 316 7O'F I
INTERNATIONAL
TEFLON FEP 7O'F I EPOXY 70F
(continued)
tlASTEl.LOY C 7O'F I I VINYL ESTER THERMOSET 70F I TEFLON PFA ZOO'F I
PYIl#$E II
PYROITE I
70F
Aluminum Sutphata 10% Aluminum Sutphata 410% Aluminum Sulphate ~10% hating boiling A 1 Ia 1 I. 201'F as
h "I B I h A* to50% I#200F
Aluminum Chbrohydroxtde (wet) Amines
L I, 70F
Lb 7D'F
AC Ia50% ,a210F
Ammonium Chloride 10% Ammonium ChMde 410% baiting hoiting 1 I 1E fn11 6qIl?q w I
Ammonium Chhnide blO%
(continuec
(continued)
TABLE 1.23:
CHEMICAL
Bromine Moist Gas
OXIRANE
OLIGOMER
200F
KVNAR 200F STAlNLESS STEEL 316 70F
WI "Rh* wit"
INTERNATIONAL
TEFLON FEP 70F
A ,a 200-F
(continued)
NASTELLOV 70F
A A BR.im WIk
PYROITE II
A BI,llli(le WIIC 50% II 212-F
EPOXY 70F
WA II VJ'F 0c Broannr water
VINVL ESTEA TNEAMOSET 70 F

AC ID 100% to 80F IdAliquid
TEFLON PFA 200F

A A 25% 8w"m.e Wll" la 200F
PYFly\TE 1 0
"R to 70F Bc Bmnlm wt.3
1Bromine watt,
25% to 212F A to 212'F
Butane
100%
Buttermilk
Butykne
Bulyl
Phthalate
A II 15'F
A,. 125'F
AC D WJ'F I I I
A I
A I
Cakium
Carbonate
Cakium
Chloride
(saturated)
Cakium
Chbride
(dilute)
Cakium
llypochbrile
100%
74 Corrosion Resistant Materials Handbook
v s
Y t Y
N N
I <
-0 a
I f < -
<
< <
Y ::
N
Y 0
N
D 0 ::
Ye
a;
s
N f <
:a
P *
-0 <
Pr
E;
:r
a c
<
TABLE 1.23:
OXIRANE
OLIGOMER
INTERNATIONAL
(continued)
Copper Flumtdc Copper Nitrate (hot, concentrated) Copper Sulfate (hot, concentrated)
Coltonreed oil
(continued)
TABLE 1.23:
CHEMICAL
OXIRANE
OLIGOMER
I
KVNAR ZOO'F I I STAINLESSSTEEL 316 70F I
INTERNATIONAL
TEFLON FEP 70F I EPOXY 7O'F
(continued)
NASTELLOV C 70F I I THERMOSET 70F
PY?tI$E II
VINVL ESTER
I
TEFLON PFA 200F I
PYROITE I
70F
Oebqcnts(general)
D*IAybther
Olbobutybne
DinethylAnillee
AI * 70F
BDlrz"F
7@"F Kd,L*'F
A.
Ah300"F
Mmelbyl Fomumlde IAmelbyl Pbthalate Mnw?tbyl SuSexlk
(continued)
ABLE 1.23:
CHEMICAL P-Dioxanc Dow Therm
OXIRANE
OLIGOMER
200F
KYNAR
INTERNATIONAL
TEFLON FEP 70F EPOXY 70F
(continued)
HASTELLOY C 70F VINYLESTER TNERWOSET 7O'F
PYROITE II
1
200F
STAINLESSSTEEL 316 70F
TEFLONFTA
200F
PYll)bFTE I
1 ,a 70F
WI II 151F ws ls0l.r 1.1
Ch lZ2"F
Ill
WDF
(I
Ethyl Benzene
Ethyl Ether
Ethyione Diamine
(continued)
TABLE 1.23:
CHEMICAL
OXIRANE
OLIGOMER
PYIN$E
II
KVNAR 200F STAINLESS STEEL 316 70F
INTERNATIONAL
TEFLON FEP 70F EPOXY 70 F
(continued)
NASTELLOV 70F C VINYL ESTER TNERMOSET 70 F TEFLON PFA 200F
PYI$ITE
Hexamine
Hydraulic
Fluid (Petroleum)
Hydraulic
Fluid (Synthetic)
Helium
Hydrochloric
Acid
l-20%
Hydrochloric
Acid
41%
Hydrochloric
Acid
1%
175 F
Nydrochlodc
Acid
h-2%
175F
Hydrochloric
Acid
,2%
175F
(continued)
TABLE 1.23:
CHEMICAL
OXIRANE
OLIGOMER
PYROITE
I 200F
II
I KYNAR 200F I STAINLESSSTEEL 316 70F I
INTERNATIONAL
TEFLON FEP 70F I EPOXY 70F
(continued)
NASTELLOY C 70F I VINYLESTER TNERMOSET 70F TEFLON PFA 200F
PYROITE I
70F
(continued
TABLE 1.23:
CHEMICAL
OXIRANE
OLIGOMER
I
KVNAR 200F I I STAINLESS STEEL 316 70F I
INTERNATIONAL
TEFLON FEP 70 F I EPOXY 70F
(continued)
NASTELLOY 70aF I C I VINYL ESTER TNERMOSET 70 F I TEFLON PFA 200 F I
PYIl$-f$E II
PYROITE I
7OF
Lime-Sulpher (Cakium Sullide) Linokk Acid Linseed Oil Lithium Chloride 30% al 200F Lithium Hydroxide 10% al 200 F I 1
ABLE 1.23:
OXIRANE
OLIGOMER
STAINLESS STEEL 316 70F
INTERNATIONAL
TEFLON FEP 70F EPOXY 70F
(continued)
HASTELLOV 70 F C VINYL ESTEA TNERMOSET 70 F TEFLON PFA 200F
PYROITE I
70F
Mineral Oil
Morpholhw
Nickel Chloride Nickel Nitrate
(continued)
TABLE 1.23:
CHEMICAL
OXIRANE
OLIGOMER PYllIfTE 0
OF RESORCINOL-PLASTONICS II
INTERNATIONAL
TEFLON FEP 70F
(continued)
KYNAA 200F
STAINLESSSTEEL 316 70F
1111U,.,I,F I
EPOXY 70F
NASTELLOY C 70F
VINYLESTER TNEAMOSET 70F
TEFLON PFA 200F
PYI$j~E
With Acid Fuming
(70% cont.)
*s*,t2~F CnM rh@nur 70F
Ab125"F "(Id 212'F

A OS% B SO% II me.
170% ,#L,)"F
"II
M k 70-F "II,! 212'F

I) 10% 20%
ml funllnp C/M SO'% IO'F a MD 50% a,l.l'F

Cnl sx AC 2x s-ox
A * 248'1 1.90% c 73'F
HiIrk ACM
Wobmuene
(Suflng)
soxm2~F
II IS%
A 2540K Alw CUT.
0 SC 10 70F
A 70%
WA
AsI0 212F
A ,470-r sC w*-t,*'F A
A 100% ,040D"F
A,. 300F
C,@ 122'F nn * Z,?OF
s 100% b 211F
CnM I0100% Is100F
M 10IO'F C 10122-F WR I,212'F A
-en
1 II600F
A,# 300-F
A to600F
Ail -3ZO'F II
Nitmmethanc
A I,1,2*F
I b 122'F
A s 1sX II212'F Is 10% ,I150F AI 10.100x bIO"F s 100%
A,#IOO'F
A ID100F
NAnus Acid
Ati Z,t"F
I I.212"F
A,# too-F
AC I#10% ID150F
A ,a,OODF
Nllmus
Oxtdc
A
A
YII., 70-F
Al4 176F
A ,,7DDF
s 100%
N-octane
Atl,ZS"F
MIS Animal
I IIO"Ftr M UlrPx A 7)'FU b,
A I.IO'F
1s* 140F xs,# 100% ,a210F ,ma*HUr) AB,a ,sOX 1sl,O"F
OilsCrude
A
A
Ah 28s'F
k,, Z75"F
)IhZDO"F
Mb
Mineral
A IO2ss"F
MkMve
A,4 7O'F
Ash ,OOK b 210F
)1
OlisVegetable
A
A
A,,17I"F
AD 248F Ah 12O'F CW 200F UI ti211-F A 11FzlS'F
A 70170F LB IO"F,#500F 080% ti120F s te4ox WR cute. IM ,040# * 212F A W+s# 11100F A
A,. 70F
A A ,005 IO160-F B,OOW ,ss"Fh 212-F s,O~OOX 70-F IO21*-F
Ash ,OOK h 210F
Okk
Acid (redo/l)
A ,a200F
Mb
,00x h 21O'F
Oxalk Ac!d
A ,,2OO'F
1 I#112-F
As 1, ,OOK m 210F
A IO212F
Oxygen
A * 1W"F
Asb75DF
&
Ozone
AD t7s'F
Antardq 1 I.70F AClrWO"F A Is'F,.Wn C C r.Fwa*,,S*F
A I.,*s'F
AII,%?ll'F
palmltk ACM
A ,It,.'F
A ,eIDO'F
As,~,sox I#12O'F It) Cmm,Nld v.1 I.(50F
PWMII
A ,a70F
Pentane
AIUO'F
(continuec
rABLE 1.23:
CHEMICAL
Plating Solutions
OXIRANE
OLIGOMER
KYNAR 200F A 3TAlNLESS STEEL 316 70F A to IllF AC IO 14OF wa ckt,rnk** A 10 IZDF
INTERNATIONAL
TEFLON FEP 70 F A !0 70F EPOXY 70F A 10 170F
(continued)
HASTELLOV 70F C VINYL ESTER THERMOSET 70 F biB 10 180F TEFLON PFA 200F A
PYIH$E II D
Nickel A
PYROITE I
70 F L IO 180F
A 10 1OF Slqif ~ktf,Dk*I A ,a 120F
Plating
Solutions
Silver
A I0 120F
1 ID 70F
1 I0 12DF
As IO 1.30F
A 10 70F
A 10 lWF
Plating
Solutions
Tin
Aa
c 11 10s F 1 Syllidt II 7s F aa Chhlrld~L obofltr AB 10 IeoF
A ID 70F
A 10 100F
110 100F A 10 150F rlclpl 1cld Chbnidl
1s II *IO-F YR rylnldr 11 180 F As 10 160F
110 210F
Plating -
Solution
Zinc
1s
A 10 10F
L l0 150F
&
A 10 *se F
Potassium
Acetate
A 10 70 F
Potassium
Aluminum
Sulphate
(alum)
A 10 275F
A8 10 15OF a 10% I0 21ZF e WOY. 10 IOF A *a.sox I0 212F a CMC. I0 1WF s I0 70% 1D 212F (pit,) A l1lY tt I(15F A I, 17% 10 240F a 2o.lash II 70F *20-70x II 211F A 104llK I@ 212F s Io.1eeh ID 7OF As lwh to 70 F A 10~30K 10 212F I IO-40% I# ?1?F e 10~100% II 70F II II lOOK l0 2,2F a le.,oo% 10 70F a 10.30% ,D 212F A 10-60~ I# 212F a OOIU. 10 150F a IO-WY. IO 212F a 10.100% I0 7OF s IO-100% ,a 212F A 5% 170F Aa 10 130F
I ,a 200F
AE 10 30s F a 10% ,D ZlZF a 100% 10 70F a 100% a 70F e lll.wh IO 212F a 1OfJ% II 1501F A 1* 30% 11 IOF a 100% IO 212F A lee% 11 1500F A lo-es% ID 21zv a 100% d 70F s 30% I0 21ZF c se.7e% I, 212F A loll% It 350F a 100% IO 7OF A8 10.sclx (0 212F A 1040% I0 212F a ID-JO% 1. Z12F e 100% II 70F e 100% II 7OF a 1e.eex IO 212F II 100% aI 1500F a wwh 10 Z12F
?.e 10 100% 10 220F Aa I0 50% I# 150F 1s 10 100% 10 l,OF Ia 10 lee* 10 212F
Potassium
Bicarbonate
1s IO ZISF
A I# 7OF
A 1 10% c 100% A
L.
Potassium
Bichromate
A ID 27SF
A 10 2eev
Potassium
Bromide
A 1v 275F
A I# 200 F
Ia lo 100% 11 110F AC 10 IelI% 10 110F As 10 sex IO 150F
Potassium
Carbonate
A to 275F
A II 200F
Potassium
Chlorate
A to 27SF
1 e 200F
AB I0 lluJ% (0 110F
Potassium
Chloride
Ah 275F
A 10 250F
Aa 10 100% 10 21OF
Polassium
Chromate
AI II 275F
A 10 7OF
Aa lo 10% 10 IlOF
A ID 70F
Potassium
Cyanide
A I@ 275F
A lo 200F
A A ID% c 100% A
AI 10 loll% I0 14ev
Potassium
Dichromalc
ii
A lo 275F
A 10 2OOF
Ae 10 100% I# 2WF
II
Potassium
Ferricyanide
AD 275F
A 30% I@ 70F
As 10 100% 10 210F
A JO,. 10 70F
Potassium
Fetrocyanide
AC 275F
A 10 2OOF
a 10-w,.
IO 212F
Aa to 1Oil% 10 210F
Potassium
Hydrate
A II 212F Ah ,s7v I IO 212F c e 230F A*
A A *ox l0 250F A 1alw I0 125OF A IO 70F a 10-6ax 10 3DOF a 100% II 7llF a 10.1!wh 7DOF I# 212F 1a I0 lo**/, 10 ZOOF a lw/. II IDF e IO-soy* 70F ,a 212F
A b 70F
I,0
1aaF
Potassium
Hydroxide
A loax 11 70F a lll~ssx t. 211F we IODK #I 5DOF I so.*w. I, 212F c 10% II 70F II 100% n 7ev II 30% d 70F A a 10~1wh 7OF I# ssev
eme ID wh
I( IIIDF
Potassium
Hypochlorlte
1 IO 70F
Potassium
iodide-iodine
A II 70F
Potassium
Nitrate
11027SF
I\ so 200F
18 10 100% ID 210F
A (continuec
(continued)
TABLE
CHEMICAL
SIlCyklddlVlb
1.23:
OXIRANE
OLIGOMER
INTERNATIONAL
TEFLON FEP 70F 1 In ,lsF EPOXY 70F
(continued)
NASTELLOV C 70F VINYL ESTER TNERMOSET 70F TEFLON PFA 200F 1
PYIi$JE
I
II
KVNAR 200 F 1 H 122F s 8, 15sF E ., 211F
STAINLESS STEEL 316 70F
PYl$$TE
).
ssll Arhle (Sodium Chbrkb
Solution)
Sinconc Oil
Silver Bromide
Ah
70F
)1
x a=*h 1 1 @MIs-100% 1
1 h 70F
Wlvcr Chbrlde
lk125F
Sodium
Aluminum
Sulfate
A,CWX 211F a,
1 h rOF
s t. (0% I0 r,ZF
1s 10 ,usx
10 120F
Sodium Bcnzoate
Sodium Rkrrbonate
Sad&m Bichmmale
Sodium Aisulfate
Sodium flisulSte
Sodium Borate (Borax) x b 27sF xs ,, ,WF 1 U 2sVF 1 1 xs 10 ,DO# I, 1,DF 1 I
(continued)
YABLE 1.23:
CHEMICAL
Salbm Bfomtda
OXIRANE
OLIGOMER
PYlgl_F
II
II
KVNAR
INTERNATIONAL
7ERON FEP 70F
AO2SO'F
(continued)
NMIELLOY 70F
SIC5.K
2OOF 1 U 275-F
STMLEI WEE1 316 70F

B 1CSSU AuPr*I 11,155X b212'F S IWX 8,500"F MS.15.WX S1CIWX Y 212'F U7O"F "175F
EPOXY 7OF
YtNYL ESTER lNEttMO3E7 70F

ASUIOOI to ZIO'F
7EFLON FFA ZOOF

A
PYilfjFFTE I
AS t, 1SO'F
ta212"F
sodium
CSf&onale(Sodx
ash)
A II 27S'F
At, 20.-F
A 20% t. 122-F C ~1.b 7S"F YIIul. aI 122-F At.212'F
A 101WX1121ZF S 1WY.U 15W'F SlOTOK SIOX II 212'F aI 7O'F
AS10~2SX
10 1W 'F
A 5SX ,, 122OF D55H .I ISO'F
sodbnl chbrate
Sodtum CtMdr (brbe)
A,4 27s"F
AD
200-F
AS WX to *IS-F AS 100% t.22)'F
AUZ12'F
275-F
"SISK II 12S'F S 2030% b 212F A IWX ta 71.212-F bMSt%.7SF I,lCWK 71.ZIZ'F .lSOX"IS'F S 15%,.212*F Sl,lSS%at7S'F ChsdatlZSZF A IS% @212-F AlCIW(X,!7SDF Yt3SX al IllOF
A 10X N 2W"F A t,c11.t,20O~F
A IaZlZ'F
At, tWX
t. 212-F
AS!4 IDS% t# 1SO"F
A II 212'F
Sodbm
Chmmate
AOXl.ZW"F
Al0IWX 7C212'F SlSaOX A 1OSX
AIH
50% Ia 215-F
ASb SSK t. 215-F ASI8 50% blW"F
So&m CNfab
Sodium
Ata7O'F
ASb2SX
l012O'F
AU71'F
Cyantde
1,.
275-F
At4 71'F
AS,. ,00X t. IIS-F
Sodium
Dkhmmab
Aa
xc
A5X*lAny SICIWK 4l771'F CM .X al l.0.F AS%#bNh*c A lCZOX Ia 212F I "MD%~~2~F SC,OS%.45S*F
lit,
71-F
AS,, ISSOX b 21,-F
AIt4 210-F
Sedbm
Fafttcyantds
xab
275-F
At, 7,'F
A tS5X lO.llS*F I ISX
AS,, lWX
II 21,-F
Aw7O'F
ASt.2lO'F
Sodium
Fluodde
,I*dLi, A
Ata27S*F
Ab2OSQF AbIO'F A SK UIZZ'F 14OU b 122'F C4,X ., 212F
A.taISSX"lSS'F l--w 0 1,70X11 212-F A 100% "IS-F AA-." 7S'F 2X 45-W% al 210-F Uils-25% til25'F AS5X121SDF
A.U
2lS"F
(mkwvb : z;::: Ai:w9:
Sodium
Hydroxide
(cruxliC Sodldp)
A WY. I, 212-F &".r-M25S.F
Al.lOOX Ia 12S'F ASSXt.2W~F
A YX )I 241F A ".&,a 7.-F
Sodium Hydroxide (mette11)WKt4 :F Sadbm Hypochbrtte (sobtbn)
YI
as
w x k%2;170 F
m
12OXt.2W'F A IS% ,a 2SO'F
xa
IIs
A 1X AIlSOX
xn
lln
Lt.
275'F A.,%,. ul-Y5x 12F
C 20% SS-
AS5X.tl2S'F SC S.lSX .tlSO"F
AZSXtr2W'F
ASU 20% I, ,.0-F LSD 20X at210'F
Sodium HyposulAta
Sodium Metaphospbate
M
1
I,,
24,-F
ASlWX r2sx5aa2
A Ia 70F
AS"
20% U 210-F
1 * lOOF
Sodium
Metasltbate
A l&SO% U 212'F S 1204L d 70-F S 15~00% at 251F A
A 1&1OOX 70212F S 30~1OOX 1,.20X
I
AS!, IWX 1.2tS'F A A 111 SS xn
Sodium
Nitrate
Ata 2759
A II 2SO'F
Sodium
Nitrate
(motten)~5S6F
KS
"I1
AS
Sodium
Nttttte
A
A
A k 275-F
AStl2OX AC-. A ,00X at 70F 510% U 212-F
AII2WO"F
ASI0 100% I. 210-F
A I
So&urn
Perborate
At,7.'F
AS
S 10% I. 212'F
AS
Sodium
Pemxtde
AU
275F
A 70.212'F
Ab2W'F
1,.50X AIcCW&. A 1&100X 70.212F
AS*
SO-F
A Ia SD% h 150-F
Sodium
Phosphates
At. 275F
AS 10.100X 70212F
ADIW'F
AS,4 IWX 10 210-F ru#pl rlJdilJ8 *I.mMa**tM*
~~
(continued)
TABLE 1.23: OXIRANE
OLIGOMER
INTERNATIONAL
(continued)
Slrnnk Chbrkb Stannous Chloride
Steam
liti SSO'F
PdSSS'F
)rb,IOO'F
At.2SO"F
At. SSO'F
ABt,tZO'F
At,,SO'F
Sutphate Bbck Liquor Sulphate 6mn liquor

Sumnol
A
1
A
Ah27S'F
It, 212'F Ek,SS'F
A.Z"'F
At,212-F
It, 175F
AOh
100% U 20.-F
A
A
)I, 212F
A A
Al, 70F
AStelOOX
te2OO'F
Al978~F
SUlphll l.kplu (100% soktion 10% SO,) wtth
AI)II 212F
At.,O'F
ABM
212F
AIt. 100% WZOO'F
Ata7ST
ASleIOOK II 220F
(continued)
TABLE
1.23:
OXIRANE
OLIGOMER
ZOOF
KYNAR 200 F m It 70DF STAINLESS STEEL 316 70F 1
INTERNATIONAL
TEFLON FEP 70F A ,I 125-F EPOXY 70 F
(continued)
NASTELLOY 70F C WY1 ESTER TNERMOSET 70 F we
*uil * war
CHEMICAL
Thioey( Chloride
PYROITE II
As * MF
TEFLON PFA 200F A
PYROITE I
70 F C
Tb
Mottrn
,449F
ne
ee
WR AC tnnw*
MR
IIR
Tnchbromoneiberoatham
(Freon
17)
Triethykne
Glycol
I
A
I
A
A* 125F
A I. 200F
YII
!
AS ID 100% IO 2OPF
I
A
R
1 IO 2OOF
Ttiethyl
Phosphate
Trtphenyl
Phosphite
(continued)
ABLE
CHEMICAL
1.23:
OXIRANE
OLIGOMER
PYIttI;E
II
KYNAR 200F STAINLESS STEEL 316 70F 1
INTERNATIONAL
TEFLON 7OF FEF EPOXY 70F
(continued)
I I HASTELLOY 70 F C VINYL ESTER THERMOSET 70F I TEFLON PFA 200F I I
PYl$ltE
D
Trisodium Phosphate Tung MI (china wood oil) Turponline
Vinylkline Chbride (Resb)

Water. Acid
Mine
Water. Boibr Feed

Water.
Uirtllbd
Water. Fresh Water. Ueknlzed Water. lb-mineraLed Water. Brackish Water. (salt) See ah0 Sea Water Wax Whiskey
(continued)
TABLE 1.23:
CHEMICAL
OXIRANE
OLIGOMER
200F A
KVNAR 200F A Ia70F STAINLESSSTEEL 316 70F A
INTERNATIONAL
TEFLON FEP 70F Al4 7D~F EWXV 70F A
(continued)
HASTELLOY C 70F 1 THERMOSET 70F mm 1ml"F
PYROITE II
VINYL ESTEA
TEFLON PFA 200F A
PYliy\TE D
1
WhHc Liquor(PulpMill)
TABLE 1.24:
PHENOLIC
RESINS-OCCIDENTAL
CHEMICAL
Durez 13856 Black CHEMICAL % Change Chemical Acetic Acetic Acetone Ammomum Ammoxuum Anll~ne Benzene Carbon Chromic Citric Tetrachloride Acid Acid Ether FormamIde Water (95%) (50%) (40%) (0.25%) (10%) Solution Hydroxide Hydroxide (cont. (10%) Acid Acid (Glacial) (5%) in RESISTANCE l/8 x 2 bsk Thickness -0.72 1.60 0. 56 5. 60 2.50 1.50 -1. -0.37 -0.55 0.68 0.68 -0.99 -0.44 1.10 -0.31 0.26 1.20 -0.29 0.21 9.21 6.40 8.00 I 1.10 0.01 (#Z Oil, Acid Acid Acid Acid Solution Solution Carbonate Carbonate Chloride Hydroxide Hydroxide Hydroxide Hypochlorite Acid Acid Acid (cont. (30%) (3%) Oil (5%) (1%) (20%) (2%) (10%) (60%) (10%) (1%) (4-a%) 1.90 0.06 I 3. 30 0.94 0. 16 0.04 0.00 5.50 1.50 -0.02 1.00 -1.00 fuel White (cont. (40%) (10%) 0.20 0.99 1.10 0. a2 1.10 1.00 I I 2.70 -7.90 I 13.00 4.90 0. 61 0.02 -0.05 ) oil) USP 0.04 0.05 I I I 0.04 0.60 0.49 0. a1 1.40 1.40 I I 10.30 13.00 I 1.70 -0.39 -0.66 0.13 I I I 1.30 5.40 5.30 4.50 5.90 5.50 I I I 0.21 0.30 0.39 I I I 32 Weight -0.03 5.50 -0.39 12.00 8. 30 0.98 0.29 0.14 -2.29 5.05 5.29 1.17 -0.61 4.70 0.66 0.87 4.40 0. 36 2.10 11.11 8.20 14.00 I 5. a0 One-Year Exposure ASTM at 23-C. D 543-60T
The following chemical resistance data was obtained by exposing several DUREZ materials to common known chemical contaminants for variable periods of time and then calculating the percent change in specimen dimensions and weight. The specimens were either 2 diameter discs by l/6. thick; or X by I$ bars, 5 long. The appearance of the afterexposed specimen was graded according to the following codes: A - Smooth, glossy G -Wrinkled B - Slightly dull H - Swollen C - Dull I - Cracked D - Fiber shows J - Warped E - Pimpled K - Blistered F - Mottled or unsigned values indicate specimen growth or weight values indicate specimen shrinkage or weight loss.
791 Black CHEXICAL % Change Chemical Aretic Acetone Ammonium Aniline Carbon Cztric Dimethyl DistIlled Ethyl Ethyl Ethyl Heptane Hydrochloric Hydrogen Nitric Oleic Phenol Soap Sodium Sodium Sodium Sodium Sodium Sulfuric Sulfuric Toluene Transformer Turpentine Oil Acid Acid Solution Solution Chloride Hydroxide Hydroxide Hypochlorite Acid Acid (30%) (3%) 2.70 0.14 0.02 0.01 Carbonate (5%) (1%) (2%) (10%) (10%) (1%) (4-b%) 3.20 I I 9.90 -0.05 -0.75 -1.20 Acid Peroxide (10%) 0.15 2.70 2.30 1.90 1.60 I 7.00 I I 17.00 0.51 0.05 0.10 (10%) (3%) 2.10 I 0.45 5.40 4.50 3.80 3.00 I 13.00 I I Detergent Tetrachloride Acid (10%) Solution Formamide Water Acetate Alcohol Alcohol (95%) (50%) (0.25%) Hydroxide (10%) Acid (5%) in RESISTANCE 118 x 2 Disk Thickness 6.00 -0.35 5.00 -1. -0.22 4.60 3.90 0.21 3.20 -0.18 -0.11 2.30 -0.25 0.25 I 4.60 I 0.90 11.00 9.80 I I 32 One-Year Exposure iS.TM
Diameter -0.21 1.10 -0.04
Appearance B B E H B A B A F F A A G A E C G A A E E H I B A A A I I I A A A B A A I I F F I E F A A A
3.90 1.80 0. -0.02 0.65 1.00 1.00 18 0.06
Positive negative IIurez
gain;
Detergent Dlethyl Dimethyl
0.12
-0.16 0.95 0.09 0.20 0.98 0.02 0. Acid Acid Acid (cont. (10%) (40%) (28%) (3%) 38
at 23-C. D 543-601
DIstilled Ethyl Ethyl Ethyl
Acetate Alcohol Alcohol
Diameter 2.90 -0.23 2.40 -0.29 0.00 2.40 2.10 0.18 1.80 0.09 0.09 1.20 0.03 0. 36
W+ight
12.00 -1.10 9.00 1.20 -0.03 9.70 a. 70 0.63 a. 10 0.54 0.49 5.00 0.06 1.80 I
Appearance G c G
Ethylene Heptane Hydrochloric Hydrochloric Hydrofluoric Hydrogen Hydragen lsooctane Kerosine Mmeral Nltrtc Nitric Nitric Oleic Phenol Soap Sodium Sodium So&urn Sodium Sodium Sodium Sodium Sulfuric Sulfuric Sulluric TClhleIle Trauaformer Turpentme
Dichloride
2.71 2.70 3.00
A C G G
E G G G G c A I G I C
Peroxlde Peroxide
Ethylene
Dichloride
9.20
a. 50 7.10 I
F G G
A I G I I G C A A
(continued)
TABLE 1.24:
PHENOLIC
RESINS-OCCIDENTAL
CHEMICAL
(continued)
Chemical
Resistance
Chemical
Resistance
Exposure
to
Various
Chemicals
for
1 Week
Exposure
to
Various
Chemicals
for
1 Month
Material Condition
and
X Change Length
X Change
Thickness
X Change Width
2 Change
Weight
Uaterial Condition
and
X Change Length
X Change Thickness
X Change Width
X Change
Weight
23570 BoillnR Water

l
23570 .12 +1.34 + .78 + .8b Boiling Water
10% E2SO4
.04
l1.20
.60
.88
10% H2SO4
.12
+2.73
+1.42
+2.64
10% NaOH
.I3
+3.5a
+I.85
+2.24
10% NaOH
10% WOH
.02
.I5
.13
.lO
10% N-&+OH
.03
.28
.18
.23
Leaded
Gasoline
.16
.lO
Leaded
Gasoline
.13
.I0
lo-30
Motor
Oil
.12
.lO
lo-30
Motor
Oil
.07
.09
.Ol
Transmission
Fluid
-14
.I1
.Ol
Transmission
Fluid
.Ol
.14
.ll
.09
Brake
Fluid
-1.23
.43
.03
Brake
Fluid
.98
.47
.07
50% Glycol
.Ol
.a7
.40
.09
50%
Glycol
-02
.90
.41
.20
5% NaCL
.o:
.91
.46
.11
5% NaCl
.03
.94
.44
.24
50% Alcohol
.Ol
.93
.45
.09
50%
Alcohol
.07
.63
.42
.20
Not
Available
Deteriorated
(continued)
TABLE
1.24:
PHENOLIC
RESINS-OCCIDENTAL
CHEMICAL
(continued)
Chemical
Resistance Chemical Resistance
Exposure
to
Various
Chemicals
for
6 Months Exposure to Various Chemicals for 1 Week
Material Condition
and
Change Length
% Change -Thickness
X Change - Width
X Change Weight
Material
Condition
and
X Change Length
X Change Thickness
X Change Width
%Change
Weight
23570
29502
Bolllng
Water
Boiling
Water
.08
+1.09
.64
.55
10% B2S04
-34
+5.66
+2.56
+7.11
10% H2S04
.25
+6.95
+3.06
+4.56
10% NaOH
10% NaOH
.16
+2.54
+1.27
+2.48
10% NH40H
.09
.28
.24
.5fJ
10% NH40H
.90
.46
.Ol
Leaded
Gasoline
.11
.08
.02
Leaded
Gasoline
.77
.46
lo-30
Motor
Oil
.06
.04
.04
lo-30
Motor
Oil
.BO
.43
.06
Transmission
Fluid
.14
.11
.Ol
Transmission
Fluid
.64
.44
.02
Brake
Fluid
.02
.98
.50
.17
Brake
Fluid
.79
.39
.Ol
50% Glycol
.06
.83
.33
.47
50% Glycol
.01
.92
.41
.lO
5% NaCl
.08
.83
.36
.61
5% NaCl
.80
.46
.06
50% Alcohol
.06
.82
.22
.47
50% Alcohol
-01
.92
.40
.05
Not
Available
Deteriorated
(continued)
::
0; +
2 +
0
z +
8
l
0 +
:: +
2 +
x
Y; +
1.
1
8
A
4 +
2 +
0
0
a
+
z +
z +
TABLE 1.24:
PHENOLIC
RESINS-OCCIDENTAL
Chemical Resistance
CHEMICAL
(continued)
Chemical 96 Rours In Resistance Boiling X Change Thickness 5.72 4.45 6.03 1.13 2.33 4.05 .92 1.46 .60 3.61 4.49 1.70 1.21 1.65 3.13 3.47 3.35 5.11 4.02 .22 5.03 1.30 .32 .59 1.20 .9O Water Change Diameter 1.71 1.23 1.26 .63 1 .oo 1.19 -48 .76 .33 1.64 1.67 .91 .60 .64 1.60 1.76 1.88 1.00 1.63 .I5 1.19 .69 .21 .34 .80 .80
10
Days
in
25OF
Vapor
at
16 psls
Pressure
X Change
Material 111 118 123 145 Weight 7.24 7.68 5.14 2.36 4.13 5.00 2.09 3.39 1.62 6.24 6.42 3.80 2.82 3.39 6.17 6.79 6.44 7.52 7.08 1 .oo 6.20 2.77 .a9 2.14 3.00 3.20
Appearance Code 8. B. B. B. A C. B, B, B B, A A B, B. A B B, A B B B. B. B B A. A B. D D, K F D E E E E E f F R R E
Material
X Change Weight
Change
-Thickness
X Change -Diameter
Appearance Code
156
1.72
.76
.50
165
2.17
1.19
.73
B, E. K
152 153 156
13856
2.64
1.24
.05
22829
1.98
.92
.66
161 165 791
30169
3.27
2.55
1.22
30698
1.74
.a7
.57
3948 3856 14900
Chemical
Resistance
16378~ 18420
10
Days
in
25OF
Water
ilt
16
psis
Pressure
18441 Appearance Code 21210 B 22257 21028
X Change H.3teria1 156 Weight 2.67
2 Change -Thickness 1.55
2 Change Diemeter 1.03
165
3.00
1.74
1.. 09
B, E, K
23570 29237
13856
3.56
1.11
-95 30270
22829
2.20
.77
.59
30614 30645
30169
3.75
2.59
1.28 30698
30698
1.97
.80
.52
30806
(continued)
TABLE 1.24:
PHENOLIC
RESINS-OCCIDENTAL
Chemical Resistance Sulphuric Acid
CHEMICAL
(continued)
Chemical Resistance Caustic (.5% NAOH)
96
Rours
in
BoilinR
(H2S04)
96 Appearance Code C. C. B. F. D. H, C H J Flaterial
Hours
In
Boiling
X Change
Naterial
111 118 123 145 152 153 156 161 165 791 3948 13856 14900 16378A 18420 18441 21028 21210 22257 23570 29237 30270 30614 30645 30698 30806
We IRh t 18.49 24.53 16.46 7.92 15.14 11.58 11.17 4.71 1.63 17.66 10.20 7.10 8.76 16.75 6.05 8.84 26.67 12.03 16.76 7.41 22.03 5.21 4.91 25.75 3.91 7.10
X Change Thickness
15.58 14.15 15.29 12.76 12.39 11.14 10.36 3.74 1.25 13.93 7.31 4.55 8.01 11.37 3.55 4.98 16.66 10.57 12.92 8.84 15.80 3.73 8.08 2?.56 2.73 3.53
X Change
Diameter 2.72 2.59 2.80 1.25 2.25 2.19 1.27 1.02 .61 7.20 2.43 1.56 1.13 .60 1.78 2.27 4.89 2.39 2.53 .86 3.30 1.33 .94 3.59 .93 1.66
X Change
Weight 9.41 12.88 7.36 4.89 4.64 6.38 1.51 3.96 2.14 7.16 7.29 3.91 2.87 3.69 6.64 7.27 7.68 9.36 8.16 1.05 5.76 3.65 .99 2.23 3.12 3.70
X Change
Thickness 7.88 4.32 6.54 1.17 2.57 5.54 1.18 1.79 .81 4.39 4.75 1.80 1.38 1.90 3.89 3.84 4.21 6.31 5.84 .31 .57 2.05 .55 .59 1.32 1.12
X Change Diameter
.90 1.26 1.44 .77 1.19 1.47 .63 1.00 .49 1.87 2.10 .94 .62 .79 1.71 1.84 2.10 2.27 1.88 .22 1.22 .90 .24 -33 .82 .91
Appearance Code C. B, R, R. B. C, B. R, B B, B R, B, B, B B. C. B B B C, C R. B R. B K E D, E D D C E E E E D R E E E E F
111
118 123 145 152 153 156 161 165 791 3948 13856
C.F C. F C. F C. E. F C. F C. F C, D. H
B,F.R.J B C. D, B, R, C, E F J D, D. J H
14900 16378A 18420 18441 21028 21210 J F F J I 22257 23570 29237 30270 30614 30645 30698 30806
B.C.H,J C. C. C. B. B, H. E. D, E. E.
C.R.C.R.1 C. B K
(continued)
TABLE 1.24:
PHENOLIC
RESINS-OCCIDENTAL
CHEMICAL
(continued)
Chemical 96 2 Material Hours In Boiling Resistance Soap (5% Ivory) X Change Diameter 1.79 1.49 1.51 .52 .99 1.37 .37 .88 .43 1.93 1.99 .80 .62 .73 1.93 2.01 2.12 2.36 1.95 .19 1.55 .88 .24 .33 .a3 .80 Appearance Code C, C C. C. C C C. C C, S. C. B, 8, B. C. B, C, B. C. B C, C C B S. B. K D D. F F D D D E E J D D D D E K S E
Change Weight 8.05
2, Change Thickness
6.16 5.48 6.72 1.24 2.65 4.58 1.09 1.73 .64 4.45 5.76 1.70 1.37 1.78 4.11 4.07 3.90 6.66 6.30 .26 8.02 1.61 .39 .49 1.10 1.10
chemical 168 Hours (7 Days) in Sodium
Resistance 111 Aypochlorite (52 NeOCl at 50-c 118 11.46 2.96 2.26 4.45 5.77 2.11 3.51 1.92 7.43 8.13 3.70 2.94 3.47 7.40 7.59 7.44 9.34 8.58 1.01 7.39 3.34 1.00 2.34 3.21 3.50
2 )lateria1 118 123 165 791 3940 13856 14900 18420 18441 21028 21210 22251 30270 30614 30645 30698 30806
Change Weight 6.08 4.22 1.6C 3.18 4.05 2.90 1.18 4.26 4.89 1.46 4.58 2.92 2.65 1.28 1.41 .83
X Change Thickness
1.80 1.99 .55 1.65 2.02 1 .Ol .41 1.93 2.39 .67 2.70 1.95 1.32 .03 .31 .02 .50
2 Change Diameter .84 .83 .47 1.01 1.21 .71 .27 .14 1.28 .93 1.47 .93 .76 -07 .33 .50 .43
Appearance Code C
123 145 152
C 153 C. C, C. C. C. C, C. C. C, C, C 21028 C, C. C, C. D 21210 D 22257 D 23570 D, F 29237 30270 30614 30645 30698 30806 D. D 161 D 165 D 791 D 3948 D 13856 D 14900 D 16378~ D 18420 D 18441 f 156
1.61
TABLE
1.25:
PHENYLENE
OXIDE-BASED
RESIN-GENERAL
ELECTRIC Introduction
COMPATIBILITY
TESTING
PROCEDURE
NORYL resins are especially noted for their outstanding hydrolytic stability. The water absorption rate of all NORYL resins, both at room temperature and at elevated temperatures, are among the lowest of any engineering thermoplastic, which contributes to the retention of properties and dimensional stability in the presence of water, high humidity and even steam environments. In addition,NORYL resins are also virtually unaffected by most aqueous solutions, detergents, acids, and bases.
This test is used as a method for predicting the longterm effects of contact materials or environments on the physical properties of Noryl. The test uses specimens which are exposed under strained conditions at various temperatures duplicating as closely as possible the effect of residual and induced stresses in a fabricated part. By measuring the loss of certain physical properties we can estimate the effects of exposure to the environment on a Noryl application. Test Procedure 1. Place the tensile bars in the strain jigs which dupliFor a standard cate the stress levels to be checked. test use 0%. l/2% and 1% for unfilled grades and O%, l/4% and l/2% for glass-filled grades. Test a minimum of 3 tensile bars for each stress level.
Nom-l. QFNZ Ream
NORYL 731,831 Resin
NOSYI QFN3Rssti
TwsEl
NORYL Resin
2. 3.
APPUd%WS.Pl
0 8.ooO 0 WC0 N N N N N N N N N N N N N NN N N N N N N x NN x x x x N N N Ii N N N N N
0 3aOO N N N N N N N N N N N N N A N NX N N
0 38ooApplied~,pSi N N N NA BA N N N N N aEcade(lB) OlelcAcld MamiacQmo11 Unssedoli Unenrloil vammle
0 8Dw NNNNNNNN N N N
0 6,CM
0 3800 0 3800
HJdEdl0mACid(lcrrs) IiJdmao~Acid(mnc.) -Aud(lc%) -And(m) -Aua(m) IU?MCAdd(lulb) NoiricM(lm) -emc@Jm> KTdmfmo*Add(m)

-UtUEi Ammonia
NNANNNA NNANANA N x x x xxx
Apply the contact material to the tensile bars making sure the material is in direct contact with the bars. If the material is a piece of tubing or gasket material, it may be secured by using a copper wire to tie it to If the material is a liquid, the tensile the tensile bar. If the bars and strain jigs should be totally immersed. material is a grease or paste, coat the tensile bars. Place the specimens in suitable containers and place one set in an oven for 3 days at 185'F and the other leave out at room temperature for 7 days. Example: If testing a material with NORYL number of specimens would be: 0% 3 days 7 days @ 185O~ @ RT 3 3 l/2% 3 3 1% 3 3 =9 =9 731 the
4.
NNNNNNNA NNNNNNNA N AAANALXX
xliaptane x x x x bm,haml Impropanoi

EthylcmeQlycai Qulf_~Ofi Ryhon 2EP
NNNANNNN N N N N N N N N
W(lW)
NNNNNNN
NNNANNNA NNNNNNNN
NNXXXXXX NNNNNNNN
-w(lm) -ImF=Jdee(mno.)
dmmonflno
NNNNNNNN
N N
phosphate(~)
NNNNNNNA NNNNNNN N
N NNNNNNN
GE.6lllmneC)-e87
Hcw&tm6&6SO LlcmeaQmao
NNNNNNN
NNNNNNN
--(sat) --(eat)
-O-illoIlds(Bat) QOKIX
NNNNNNNX NNNNNNNN
Total 18 5. At the duration of test, remove the specimens from the oven and leave at room temperature for a minimum of 30 minutes. Then use the Instron to determine tensile strength and % of elongation. Results
NNNNNNNN
NNNNNNNN
NNNNNNNN
lnm6cm/m BesterNo. NesterNo 13.5

164
NNNNXXNN NNNNXXNN
Lesml(28)
NNNAXXXX
Reporting
The contact material is considered compatible if there is no cracking, embrittlement or less than 10% loss in tensile properties. The material is considered marginal if there is no cracking, crazing or less than 20% loss in tensile properties. An incompatible material is one which cracks, crazes or loses more than 20% of its tensile properties. (The above are compared against a control). (continued)
TABLE 1.25:
PHENYLENE
OXIDE-BASED
RESIN-GENERAL
ELECTRIC
(continued) TESTING RESULTS
COMPATIBILITY
Effect en
731 Aggres siveness* -
Norvl Aggres731
Effect
Aggres -
en
Nor!1 A5grcs-
N-190
N-190
siveness'
Craze S S S S Ethy~ne Ethyltncdiamine No
siveness*
siveness'
n-PtntAne n-IItxk7e CctAne Dodccane
Qlase Craze Cr*se Cr*ze
S S S S
craze
Qaze Craze
Effect
NC
Effect
No Effect
SW811 V V V
No Effect
Swell swell Crack v
M
Diethylamine n-Amylarome
Qack Crack
Aromatic
hiethylamine
Toluene Xylem
Solvent swell
n
V
Solvent Swell
n
V
Ketones
Acetone
Craze Well SW11 Crack Craze Crack Solvent
V V V
V
Craze
Methyl ethyl ketone Alcohols Hethyl propyl Ketone mtiyl Methan Et!!nol Isopropanol n-Butin Pentan Isohexanol OCtanOl 2-Ethyl B-01 Trimethyl-3.5, 5-3-huancl
No NO
swell swell Crack
V V
V V
iscbatyl ketone
Effect
Qare
Methyl phenyl ketone Iscphorone Cyclohexmone
V V M
Effec?
craze
U-are Q*2.S S
aazt= QaZe
Swell
V V V
No Effect No Effect Craze No L=fcct NO Effect Craze Qaze

S S
craze
Craze Craze
Craze
Swell
SVISll
!4
Qate
Acetates
Methyl
acetate
Crack
Qack SW11
V V
Swell Swell Swell we11
Chlorinated
Ethyl
acetate
n-Propyl acctAt-e Methylem

Chloroform
v v
Chloride
Solvent Solvent Solvent Craze Solvent Solvent
V V V V t4 n
Solvent Solvent Solvent Craze Solvent Solvent
isopropyl acetate
Crack
Trxhloroathylene l,l,l-hichloroethme 1.1,2-hichloroethane Chlorobentcne
Anhydrides Acetic anhydrlde Propionic anhydride No Effect Crack _

V No Effect S
Craze
AggressivencsS:
S-Slight, M - Moderate. V - Veri
104
Corrosion
Resistant
Materials
Handbook
TABLE
1.26:
POLYALLOMER-EASTMAN
CHEMICAL
PRODUCTS
The effects of various chemicals on TENITE Polyallomer Formula 5020 were determined by and measured injection-molded samples of the plastic in the chemicals and maintaining them 73F (23C) for one year. After one year, each sample of plastic was removed from the jar in wiped dry, and quickly weighed and measured. The appearance of the sample after exposure was also recorded.
immersing weighed at a temperature of which it was tested, to the test medium
The shelf-life tests were conducted using 50 ml capacity, 0.010 inch (0.25 mm) wall thickness blow-molded bottles of TENITE Polyallomer 5020 filled with selected household items. The filled bottles were stored at temperatures of 73F (23C) and 140F (60C) for one year. Changes in bottle weight and appearance were determined at the
end of the test period.
Polyallomer is highly resistant to chemical attack and to stress-cracking. and attack the surface slightly. These chemicals are mainly chlorinated the higher aliphatic hydrocarbons, such as gasoline.
However, a few chemicals produce swelling compounds, aromatic hydrocarbons, and
Resistance
of TENITEE
[Exposure:
Polyallomer One Year
5020 at 73F
to Various (23(Z)]
Chemicals
Reagent Ace:~c Acid Acellc Ace;one Aicorrox Ammonium Ammomum Benzene Brake Carbon Chromic Citric Coffee Cottonseed Dibatyi Dlerhyl Dlme:hyl Delomzed Ethanol Ethanol, Ethylene Gasolme. Gasolme. Hexane Hydrochlonc Hydrochloric Hydrogen Hydrogen lodme Aud, Acid. PeroxIde. Peroxide, cone 10% 28% 3% 011 Sebacafe Ether Hexyl Water 100% 50% Dichlortde Regular High Test Pn!halate Folmarmoe Fluid Tetrachlorlde Acid. 40%. 10% Acid. Decrgent (0 25,L! cone 10% Hydroxide Hydroxide Acid 5L< cone Cl 04
Change in WeIghI. 0i0 Thickness. 4, Appearance Nc Ciange NC Change NC, Change Nc Change Sli;htly Slqhtly Swollen NC Change Swollen Sl~;h!ly DIscolored No Change No Change No Change No Change Sfiollen No Change No Change No Change No Change No Change No Change Si4ollen BlIstered, Swollen Swollen No Change No Change No Change No Change Stalned Swollen D~scolore:! D~scolorec lsooctane Kerosene lysol Methyl Mmeral Molasses Mouthwash Mustard Nltrlc Nltrlc Nltnc
Raagenl
ChaII#E WeIghI, % Thicknass. 6 30 15 90 1750 0 11 0 12 0 59 0 03 0 35 6 04 4 70 0 79 0 02 0 51 0 04 cl 05 0 04 5 50 0 12 0 08 0 12 0 28 0 16 0 12 0 45 0 16 0 08 0 12 0 08 0 04 0 08 0 04 0 00 0 04 0 24 0 00 0 04 0 12 0 04 0 12 0 08 6 20 0 08 1 50 7 50
ifl
B.lt.stered. Discolored. BlIstered, No Change No Change No Change No Change No Change No Change Badly DIscolored Slightly Slightly DIscolored DIscolored DIscolored, Swollen Swollen
% Appearance
c 28
i ^ 33 c 74 0 04 c 04 0 20 5 70 0 12 11 20 c 04 0 08 0 12 0 08 0 29 5 so 0 08 0 20 0 04 0 12 G 21 1 60 1 90 7 60 6 80 6 70 0 24 0 08 0 08 0 16 0 08
? ?8
1 94 0 01 0 37 0 13 15 10 c 38 6; 50 -0 08 (1 08 0 03 c 05 1 51 14 10 0 20 0 37 0 01 0 26 0 07 5 20 10 60 19 40 17 60 16 90 0 11 0 01 0 01 -0 01 011
DIsInfectant Alcohol 011
Acid, cone Acid. Acid, 40% 10%
Olelc Actd, 03% Ohve 011 Orange Phenol, Sodium >odlum Sodium Sodtum Sodium Sodium Sulfuric Sulfuric Sulfunc Toluene Tomato Juice 011 Transformer Turpentme Drink 5% 1% 10% 2090 2% 10% 1% 3 5% Chloride, Cabonate. Carbonate, Hydroxide, Hydroxide. Hypochlorite, Acid, cone Acid. Acid, 30% 3%
No Change No Ghange No Change No Change No Change No Change No Change No Change No Qlange No Change Discolored DIscolored No Change No Change BlIstered. No Change No Change Blrstered. Swollen Swollen
DI 2-Ethyl
Soap Solution,
0 01 -0 01 0 04 0 ia -0 03 -0 01 0 08 -0 03 -0 005 -0 008 19 50 0 07 3 50 23 70
Ethyl Acetate
(continued)
Synthetic
Resins and Polymers
TABLE 1.26:
POLYALLOMER-EASTMAN
CHEMICAL
PRODUCTS
(continued)
Shelf-Life
Data on Blow-Molded Bottles of TENITE@ Polyallomer [Exposure: One Year at 73 F (23 C)]
Change In Weight. %
Appii~llC8
5020
Mustard Molasses Orange Ormk Mouthwash Tomato Jurce Coffee Lysol Drsinfectant lodme ivory Detergent, Shoe Polrsh Margarme Grape Jurce Cheese Spread Grape Jelly Peanut Butter
-0 33 -0.13 -1.66 -1 14 -1.06 -0 61 -0 14 -1.69
No Change No Change No Change No Change No Change No Change No Change No Change No Change No Change No Change No Change No Change No Change No Change
1%
-0 12 -0.29 -0 07 -1.00 -0.32 -0.42 +o 14
Shelf-Life
Data on Blow-Molded Bottles of TENlTE@ Polyallomer [Exposure: One Year at 140 F (60 C)]
fleapent Walght. %
5020
Changs In Appanncs
No Change No Change No Change No Change No Change No Change Bottle Stained Bottle Stained No Change No Change
Mustard Molasses Orange Drink Mouthwash Tomato Juice Coffee Lysol Disinfectant iodine ivory Detergent, 1% Shoe Polish Margarine Grape Juice Cheese Spread Grape Jelly Peanut Butter
-4.2 -3.9 -10.8 -24.0 -5.0 -9.1 -6.0 -31 .l -4.0 -4.1
Bottle cracked at seams in -5.0 -6 7 -6.5
1 day
No Change No Change No Change
Bottle cracked at seams in four weeks
706
Corrosion
Resistant
Materials
Handbook
TABLE 1.27:
POLYCARBONATE-MOBAY
CHEMICAL
The combination of mechanical and optical properties offered of the characteristics of a transparent metal. It is a thermoplastic toughness, and a temperature capability up to 250F. Because of a combination bonate sheets are finding is resistant of optical application
by MERLON gives the designer a material with many which provides good optical properties, exceptional
characteristics, impact strength, and dimensional stability, MERLON as glazing, especially in those areas where glass breakage is high. to:
Industrial Petroleum Products Petrol Refined oil Spindle oil Transformer oil Vacuum pump oil to: Milk of lime Nitric acid :conc.) Sulfuric acid (cont.) to:
polycar-
MERLON Chemicals
at room temperature
Nitric acid Nitric acid Dleic acid ~,xxa$$id (10%) (20%)
Acetic acid (20%) Aluminum chloride Aluminum sulphate Ammonium ctiloride Ammonium nitrate Ammonium sulphate Antimony trichloride Arsenic acid (20%) Butyl alcohol Calcium chloride Calcium nitrate Chlorinated lime paste Chlorinated lime solution Chrome alum Chromic acid (20%) Citric acid (40%) Copper chloride Copper sulphate Cuprous chloride Cyclohexane Decahydronaphthalene Ethyl alcohol (96%) Formic acid (10%) Formalin (30%) Glycerine Glycol Hydrochloric acid (10%) Hydrochloric acid (20%) Hydrogen peroxide (30%) Hydrofluoric acid (20%) Iron chloride Iron sulphate Isoamylalcohol Lactic acid (20%) Magnesium chloride Magnesium sulphate Manganese sulphate Mercuric chloride Nickel sulphate Common Beer Borax Cocoa ~~Z;;;il Chocolate Cinnamon Cod tiver Household
Axle oil Brake fluid (room temp.) Compressor oil Diesel oil Gasoline (low aromatic)
MERLON
(2%)
Petroleum ether Phosphoric acid, cont. Propyl alcohol Potassium aluminum alum Potassium bichromate Potassium bromate Potassium bromide Potassium chloride Potassium nitrate Potassium perchlorate Potassium permanganate Potassium persulphate Potassium sulphate Propargyl alcohol Propionic acid (20%) Silicone oil Silver nitrate Sodium bicarbonate Sodium bisulphate Sodium bisulphite Sodium carbonate Sodium chlorate Sodium chloride Sodium hypochlorite Sodium sulphate Stannous chloride ~~!$~:ic acid (10%) Sulphuric acid (50%) Tartaric acid (30%) Trichloroacetic acid (20%) Zinc chlorrde Zinc sulphate
has
limited
resistance
Cycloheranol Gasoline (high aromatic) Hydrochloric acid (cont.) M~RLOW is not Acetaldehyde Acetic acid Acetone Acrylonitrile Ammonium ;;nyz;$rn resistant
(cont.)
fluoride sulfide
Benzoic acid Benzyl alcohol Bromobenzene Butyric acid Carbon tetrachloride Carbon drsulfide Carbolic acid Caustic potash solution (5%) Caustic soda solution (5%) Chlorobenzene Cycle hexanone Cyclohexene Dimethyl formamrde
Ethane tetrachloride Ethylamine Ethyl ether Ethylene chlorohydrin Formic acid (cont.) Freon* (refrigerant & propellant) Nitrobenzene ;;t;o;fllulose lacquer Phosphorous hydroxy chloride Phosphorous trichloride Propionic acid 5$cJr~n~ sulfide Sulfuryl chloride Tetrahydronaphthalene ;f$.x$~ne Xylene Freon 113, temperature. which may be used on
lDupont
unstressed MEaLon
trademark, MERLON
except at room by:
is dissolved
Materials Mineral heating zvtse$water $$ar~il Orange jurce Orange peel Paraffin oil pepper Rapeseed 011 Rum Salad oil Salt solution (10%) Soap (soft and hard) Table vinegar Tincture of iodine (5%) Tomato concentrate Tomato juice Turpentine Vodka ;;&ng soap Wine oil
Chloroform Cresol Dioxane
Ethylene Methylene Pyridine
dichloride chloride
Dimensional
Water A$sorption
n
Change
vs. Per Cent Water Absorption
DimenGo,~nChartge Conditions
oil
%z!
Detergents (nonionic Fish 011 Floor polish Fruit syrup Glaziers putty Grapefruit iuice gcps;f~tt peel Ink Insulating tape Linseed oil Linseed oil standard and anionic)
I
I
MERLON
0.0
0.0008
0.0013
0.0003
50% Room Boiling
R.H. Temp Water
Samples
Aged in Hot Water for 6 Months
(212F)
varnish
Original
Dimension (Inches) 1.3373 1.3374 0.8735
Dimension after 6 months immersion (Inches) 1.3382 1.3390 0.8740
Synthetic
Resins and Polymers
107
TABLE 1.28:
POLYESTER
ENGINEERING
RESIN-DART
INDUSTRIES
XYDARM RESINS
CHEMICAL TENSILE STRENGTH AND ELONGATION RESISTANCE BEFORE AND AFTER EXPOSURE(*) XYDAR.
Original Value 60% RH (5 wks. @ Rm. Temp.) Water (200 Hrs. @ llOC) Water (30 days @ 82'C) Acetic Acid (1 week @ reflux) Ethyl Acetate (1 week @ reflUX) Bleach (1 month @ 5O'C) Brake Fluid (1 month @ 50C) 10% NaOH (1 month @ 5O'C) Transmission Fluid (1 month @ 50Cl Motor Oil (1 month @ 5O'C) Skydrol (2 weeks @ 71'C) Antifreeze (1 month @ 5O'Cl 20% ~~S04 (1 month @ 50C) 37% ~~S04 (1 week @ 50C) 100% H2S04 (1 week @ 5O'C) 20% HCl (1 month at 50C) 70% HNO~ (11 days @ Rm. Temp.) Gasoline (Leaded) (1 month @ 50C) MEK (1 week @ reflux) Isopropyl Alcohol (1 week @ reflux) JP-4 (1 month @ 5OC) Detergent (1 month 4 5O'Cl Trichloroethylene (1 week @ 5O'C) (*l % Decrease in tensile 30%; D = >30%. strength
XYDAR- SRT-300 Tensile Elong Rating (%l_ (psi) 16810 4.9 16900 A 3.0 13770 B 4.9 15900 A 3.3 17290 A 3.9 16290 A 3.1 16640 A 3.9 16390 A 3.8 16010 A 3.4 17320 A 3.6 17090 A 4.7 17940 A 3.9 17990 A 4.2 17230 A 3.9 15600 A 3.2 ----Disintegrated---16520 A 3.6 16400 A 2.8 16840 A 4.3 16200 A 3.2 17680 A 4.4 16860 A 5.1 17800 A 5.1 19000 A 4.0 after exposure
Tensile (psi) 17730 17000 13380 17100 15420 18160 16920 17540 16490 17220 17580 17280 17700 17600 11080 17410 16840 18150 19420 17030 16840 19900
SRT-500 Elong.
Racing
A C
(%C
4.8 3.1 4.2 3.4 3.2 4.0 3.1 3.8 3.3 4.0 4.6 3.7 2.8 3.8 3.6 3.5 4.9 5.4 6.0 4.8 4.9 4.1
B A A A A A A A A A D A A A A A A A
- A = 0 to 10%; B = 11 to 20%; C = 21 to
108
Corrosion
Resistant
Materials
Handbook
TABLE
1.29:
POLYESTER
LAMINATES-HAYSITE
REINFORCED
PLASTICS
HCR-191 is a chemical resistant polyester laminate produced by the match metal molding of fiberglass mat, inert fillers and HETRON@ 197 resin. HCR-191 laminate when compared to other corrosive resistant materials offers excellent weight to strength ratio (specific gravity of HCR-191-1.9 . . stainless steel-8.0) and ease of handling and fabrication. HCR-196 is a chemical resistant polyester laminate produced by the match metal fillers and DERAKANEB470 resin. The DERAKANEB470 is a vinyl ester resin. HCR-197 is a chemical resistant polyester laminate produced by the match fillers and ATLAC 382 resin. The ATLAC 382 system is bisphenol A fumarate molding of fiberglass mat, inert
metal molding resin.
of fiberglass
mat,
inert
CHEMICAL
Materials Acetlc Acid Acetic Acid Acetlc Acid. Glaclai Acetlc Acid. Vapor 8 C :ondensate Acetophenone Aluminum Tnchlonde Aiumlnum Fluonde 2.Ammoethanol Ammoma Aqulous Ammomum Chlonde Ammomum Fluonde Ammomum Hydroxide Ammomum Nltrate Ammowm Persulfate Ammomum Phosphate, Monobasic Ammorwm Salt of Pnmary Alcohol Glycol Ether Sulfate Ammomum Sulfate Ammomum Thiosulfate Amy1 Acetate Amy1 Alcohol AnlIme Antimony Pentachlonde Antimony. Tnchlonde Antimony. Tnchlonde Banum Carbonate Banum Chlonde Benzene Benzene Disulfonic Acid Benzene, Sulfontc Acid Benzolc Acid Bromme, Dry Gas Butyl Acetate Butyl Carixtol Butyl Phthalate Butyric Acid Calwm Chlorate Calcium Chloride Calccum Sulfate Caprylic Acid Carbon Dioxide Carbon Tetrachlonde Chlorine Gas, Dry Chlonne Gas,Wet Chlorofluocarbon % 25 10 100 25 100 40 100 100 28 45 40 20 45 25-100 65 100 60 60 100 100 100 100 50 100 100 100 100 100 25 100 100 100 100 100 20 All All 100 100 100 100 100 100 100
RESISTANCE Test
ReSUI1S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S F. 210 65-95 100 180 75 210 75 05 80 200 150 150 200 150 225 100 250 100 75 200 125 75 200 75 250 250 75 194 200 250 75 75 85 100 200 250 250 250 140 250 120-122 40 220 158
DATA OF HEIRONe
Materials
197
Concentration % Temp. F. 140 150 250 250 140 100 75 75 100 100 85 80 120 80 150 75 200 250 250 250 150 194 250 120 230 392 250 250 250 200 85 75 250 200 125 80 80 100 122 75 00 100 300-310 160 250 Test Results S S S S S S S S S S S S S S S S S S S S S S S S S S S S
Concentration Temp.
s
S S S S
32 Chromic Acid Sat Chromous Sulfate All Copper Chloride All Copper Cyamde Sat Copper Nltrate 100 Dtbuty Phthalate 100 Diesel Fuel 1iW DIethanoI Amme 100 Dlethyl Sulfate 100 Dlethylene Gycol Dlethylene Gycol N-butyl Ether 100 100 Dilsobutyl Phthalate 100 Dodecene. trace WI Sat Ethyl Acetoacetate Ethyl Alcohol o-95 Ethyl Chlonde 100 Ethylene Chlorohydnn 100 Femc Chlonde 100 Fernc Nttrate 100 Ferrous Sulfate 100 37-44 Formaldehyde Gasoltne 100 Glycenne o-75 100 Heptane. Vapor 8 Condensate Hydrochlonc Acid O-20 Hydrogen Chlonde Gas 100 Lead Acetate All Magnestum Carbonate TM) Mercury 100 35% So Vapor Nitric Acid Perchlonc Acid O-72 Stanmc Chlonde 100 Steanc Acid 100 Sulfunc Actid O-50 Tetrapotassium Pyropl losphate 60 1.l .l-Tnchloroethane 100 100 Trimethyl Carbinol 100 Tnphenyl Phosphite 100 Trisodium Phosphate O-50 Urotroptne 28 Xylene 100 21nc Chlonde 70 Zinc Hydrosulfite Sat. Zinc Sulfate All
S
S S S S 3 S S S S S S S S S
S
S
Note: S -
Satisfactory
(continued)
Synthetic
Resins and Polymers
109
TABLE
1.29:
POLYESTER
LAMINATES-HAYSITE
REINFORCED
PLASTICS
(continued)
Chemical Resistance of Dow DERAKANE

MAXIMUM SERVICE TEMPERATURE VS CHEMICAL
470 Resin
ENVIRONMENT
CHEMICAL ENVIRONMENT Acebc Acld Acebc Acld Acetlc AnhydrIde Acetone Ac,d Cleaner hydrochloric acld Acrykc Acid Ally1 Chloride Alkyl Benzene Sulfow Acld Alummum Chlonde Alummum Chlorohydroxld.? Aiummum Nitrate Alum~nw Sulfate Ammo,um Chlortde Ammonun Phosphate. dlbaslc Ammomum Thlocyanate Ammonium Thwxulfate Barlum Sulfate Benzaldehyde Benzene Benzene, Ethyl Benzene Basulflte I Scrubber Black Liquor recovery
CONCENTRATION % 25 50 100 10 _ 25 A,, 92 All 50 10 All All 65 50 60 A,, 100 100 I/32/3 Gases _
MAXIMUM F/C
210199
CHEMICAL ENVIRONMENT Dethano, Amine Dlethylene Glycol Dwobuty Phthalate Ethanol Ethyl Alcohol Ethyl Benzene Benzene Ethylene Chlorohydrln Erhy, Sulfate Femc Chloride Hydrochloric Acld Formic Acid GaSOllne HeptZle Hydrobromlc Acld Hydrochlonc Acld ,sopropy, Myrlstate Jet Fuel (JP-4) Lead Acetate M&c Acld Morphollne Naphtha N,tr,c Acid Oxakc Acld Phenol S,fo,c Acid Pla,lm Piatlng Solution Propvavc Acld Sodium Chromate Sodlum Hydronde Sod,m Lauryl Sulfate Stvrene 80 F Bath
CONCENTRATION % 30 100 100 95 All 213 l/3 100 100 29 185 All 100 100 62 37 _ A,, 100 100 40 Ali 65 100 50 10 Ail 100 _ 75 Ail _ 70 Al,
MAXIMUM FIC 120149 210199 150/65 100138 W/38 120149 100/38 100138
31.
180/82 loo/38 180/82 190188 100138 80127 120149 2501121 210199 180182 2501121 210/99 210199 100138 100/38 250,121 70/21 100138 100/38 350,177 3501177 200193 210/99 210/99 120149 210/99 180182 250/121 2501121 150165 150165 200/93
Bow Acld Brine Butrylc Acid Capryl~c Acid Carbon Tetrachlortde Chlonne dry gas Chlorine. wet gas Chloroacetlc Aod Chromic Acid Copper Matte Dtpping Bath 3Oo FeCI3. 19% Hydrochloric
100 All A,, 100 A,, 100 100 100 50 20 _
/1)
_,
Transformer 011s Z,nc Chloride Zinc Sulfate
180182 100/38 180/82 210199 100138 180/82 2301110 180/82 230/110 2501121 80127 210199 80127 210199 80127 180182 100138 210199 180182 160171 120149 3001149 100138 100138 3001149 3101154 2501121
CHEMICAL
RESISTANCE
OF ATLAC
382
The data below represknt the current knowledge of corrosive envlronmental conditions which Atlac 382 blsphenol A fumarate resin will withstand when properly used In relnforced olastlc laminates:
CHEMICAL Acetic Aad Acetic Acid Acetic Acld Ammonium Hydroxide Ammomum Chloride Ammonum Sulfate Amvl Alcohol B&l Alcohol C&urn Chloride Calaum Sulfate Chlonne Dlox,de Chlorme Dry Chlorme Wet Chloroacetlc Acld Chloroacetu Acld Chromic Acad Ethyl Alcohol Ethylene Glycol Ferric Sulfate Ferrous Nltrate Fluos~luc Aod Gylcerm Hydrochlonc Acld Hydrochloric Aad Hydrochlonc Acld Hydrogen Peroxtde Hypochlorous Acld Lactic Acid CONCENTRATION %
10
MAXIMUM OF 220 220 140 140 220 220 220

180
CHEMICAL Magnesum Sulfate Metal Plating Solubon Methyl Alcohol Napthalene N,tr,c Acld N,tr,c Ac,d Perchlorlc Acld Phosphoric Acld Potassum Carbonate Potassum Carbonate Potassium Hydroxide Scdlum Blcdrbonate Sodurn Carbonate S&urn Carbonate Sodium Chlonde ?&&urn Hydroxade Sodium Hydroxide Sodurn Hvdroxlde Sodurn H&chlor& Sullonated Detergents Sulfur Dloxlde Drv Sulfur Dloxlde, Wet Sulfunc Acld Sulfwc Acid Sulfunc Ac,d Trtchloroacetlc Acld Zinc Chloride
CONCENTRATION %
All
MAXIMUM OF 220 180 140 220 200 80 160 220 140 100 160 180 140 80 220 220 180 80 180 160 220 220 220 220 160 220 220
25 50 20 All 20 All All A,, All 5 _ _ 25 50 5 All A,, All All 10 too 10 20 37 30 20 All
220 220 220 220 220 220 140 200 180 220 220 220 80 220 220 160 160 160 220 220
loo All 100 5 20 10 50 10 25 10 10 10 25 A,, 5 10 25 15 100 _ _ 25 50 70 50 A,,
110
TABLE
1.30:
POLYETHER
BLOCK
AMIDES-RILSAN
PEBAX is ATOCHEMs registered trade name for a family of polymers known as polyether block amides (PEBA). The structure of all PEBAX products comprises linear and regular chains of rigid polyamide segments and flexible polyether segments. In addition to their copolymeric structure, the various grades of PEBAX show other original characteristics: very wide range of flexibility; absence of any plasticizer; excellent impact resistance, even at low temperatures; little variation in flexibility between -40C and +8OC; low density; very high elastic memory; excellent mechanical properties; and good chemical resistance.
Chemical
Resistance
Change Change Chonge
of PEBAX
in stress I volume ,n elongation
Polymers
ot break in %
ot break m % m %
Chemicals
Test
Time Temperatures 0 - 15 - II -;2
5533 SN 00 0 - 20 - 20 -32 + + + + + 0 1.2 1.2 1.5 1 1,2
T
0
+ 7 5
4033SNOO
T
3533 SN 00
SulphuracAcid. 100/O Sc&m Hydroxade. 10% Z,nc Chloride. 5090 Water Bo,lmg Writer
7 days/23 C I. ,. ,. 7 days/100 oc 7 days/l21
- 24 - 64 DiSSoiVeS
I
I
Lockheed H 55 Skydrol
I
ASTM No I 011 3 days/IQ3 oc 7 days1121 C 3 days/ 100 C 7 days1121 oc 7 days/95 OC 7 days/79 OC
I 0
I 0
I + + 4.7 1.8 - 14 47
ASTM No 3 011
SKIP Detergent 30 g/l Potasswm 34O Boume
0 0
12.5 0
+ 2.4 + 1.5
- 12.5 20
Lrxkheed H 55 Skydrol
ASTM No 1 01
3 dqs/lcn 7 dqS/l21
oc oc
- 55 - 92 -50 - 49
+ 17.7 + 40 + 135 + 51
ASTM No 3 011
3 doys/lLm oc 7 days/l21 DC 7 days/95 =C 7 days/79 C
SKIP Detergent 30 g/l Potosrlum 34 Baume
Chemicals
Tests Time Temperatures
5533 SN 00
4033 SN 00
3533 SN 00
2533 SNOO
6312 MN00
5512 MN00
Ethanol Propnol Butanol
7 do&23
OC
+ 7 + 21 + 31 +fJ.5 + I8 + 32 + + 16 5
~+27~+45~+60~+22~+33~ + 30 + 54 + 54 + 51 + 128 + 405 + 9 + 44 + 64 + 27 + 15 + 21 + 110 _ + 48 + 26 + 28 + 110 _ +A8 + 26
+ 20 + 25 0 + 3.5 _ +5 + j.5
+ 32 + 37 0 14
lsooctane loo OCtonepetrol M 15 luel Kerosene Poraffm
7 days/23 OC 2 days/50 OC 7 days/23 OC
+74 + 2:6
(continued)
Synthetic
Resins and Polymers
111
TABLE 1.30:
POLYETHER
BLOCK AMIDES-RILSAN
(continued)
Tests
Chemicals Time Temperature
5533 SN 00
4033 SN 00
3533 SN 00
2533 SNOO
6312 MN00
5512 MN00
0 7 days/23 2 days/50 2 days/50 OC OC C +a + 21 t 27
0 tt3 + 41 t 41
0.
ASTM Fuel B ASTM Fuel C Benzene ACHOW Me?h leth
+ 33 + 4.2
I ketone
t 60 t 42 + 4.5
t 182 + 45 t 4,5
t t t
210 a n,5
t 12 +a +4,5
t 22 + 45 +a
TABLE 1.31:
POLYETHYLENE-EASTMAN
CHEMICAL
PRODUCTS
Two-inch diameter by /s-inch thick disks injection molded from a 0.918 density TENITE Polyethylene formulation were immersed in the chemicals listed in the tabulation and stored under a constant temperature of 73OF for one year. The disks were weighed and measured at the beginning of the test period and again at the end. The percent change in weight and thickness was calculated for each chemical at the end of the test. The change in appearance was also noted. Chemical resistance of polyethylene is density related-improving with increasing density. Therefore, the lowest density formulation of the TENITE Polyethylene family was tested to represent the greatest change that would be expected from contact with the various chemicals.
The Effect of Various Chemicals on TENITE@ Polyethylene (Exposure:
One Year)
K Change In Thickness 0.2 00 -01 01 0.6 14 05 00 00 00 00 0.0 0.0 -01 00 -01 2.9 3.3 0.0 00 31 Appearance NO change No change No change No change No change Yellowed No change No change No change No change No change No change NO change No change No change No change Swollen Swollen No change No change Swollen
%Change
Chemical Acetone Acellc Acid Ammomum Weigh! 1.2 5% Hydroxide 08 10% 0.0 41 00 36.6 37.9 25 1 10% 00 0.1 00 2.6 6.9 Ether 0.0 0.3 0.1 13.5 15 1 0.0 00 10.0
In Appearance No change No change No change No change No change Swollen Swolien Swollen and warped Chemical Hydrochloric Hydrogen Methanol Acid PeroxIde 59~ 10% 30%
Thickness 0.2 00 00 08 01 7.7 4.3 2.6 0.0 01 00 0.6 09 0.0 0.0 0.0 3.2 3.0 0.0 03 2.5
Welghc -02 00 0.0 00 05 ) 48 24 0.3 02 10% 2% lOoa 1% Solution 5% 00 00 01 00 0.0 00 00 15 1 14.5 00 0.2 15.4
Butyl Acetate Calcium Chloride Carbon Carbon Dlsulflde Tetrachlonde
2-_0%
Methanol 100% Motor 011 Nltrtc *Oleic Acid Acid (COW
Chloroform C,trlc Acld Ethanol
No change No change No change No change Swollen No change No change No change Swollen, Pink Swollen No change No change Swollen
vmOlli,e 011 -Phenol 5% Sooturn Sodium Sodium Sodwm Sodium Sulfwc Chloride Carbonate Hydroxide tiydrowde Hypochlorlte Acid 30% 3%
5040
Ethanol 95% Ethyl Acetate Ethylene Ethylene Ethylene Formaldehyde Gasolme Gasolme Glycerme Green Heptane Soap Solution Dlchlorlde Glycol Glycoi (Regular) (Awatlon) Monoethyl 35%
Sulfuric Actd Toluene Turpentme Water Wesson Xyiene Oil
Listed as a stress-cracking agent. Believed likely to be a stress-cracking
agent, but not tested for this characteristic.
112
Corrosion
Resistant
Materials
Handbook
TABLE
1.32:
P~LYET~~YI_ENM~IMoNT
1900 UHMW Polymer is an ultrahigh molecular weight, high density polyethylene resin having a molecular weight range between 3 and 6 million. The extraordinary wear properties of parts manufactured from 1900 UHMW Polymer result in superior replacement parts or long-performance components on original equipment. Used either way, they offer outstanding resistance to impact, abrasion, and chemicals, plus high energy absorption and self-lubricating properties.
Test
pieces,
0.040
x 1 x 2
inches,
immersed
in
reagent from
under reagent
conditions and wiping
given: dry.
Appearance
and weight
change
reported
on removal
Synthetic
Resins and Polymers
713
TABLE 1.33:
POLYETHYLENE-LINED SCIENTIFICS INC.
ETHYLENE-VINYL
ACETATE
TUBING-THERMOPLASTIC
BEV-A-LINE, translucent, tate shell and a polyethylene

The shell excels in durability A-LINEIV retains flexibility from -60 to 200F.
flexible liner.
tubing for purity systems, combines two tubings Liner and shell are merged by a patented extrusion
in one: an ethylene process.
vinyl
ace-
with superior at temperatures
aging characteristics. Tubing burst strength surpasses that from -60 to 160F and BEV-A-LINE V HT withstands
of PVC. BEVtemperatures
The liner is ideal for use where purity must be maintained and good resistance to alcohols, acids, caustics and solvents is required. This tubing will resist stress-cracking. Its inert and neutral contact surface provides a stable environment in which the pH of the content is essentially maintained. The interior is exceptionally resistant to stains and it resists absorption of liquids, stays translucent and cleans easily.
Chemical and Environmental Properties of BEV-A-LINE

Chemical or Solvent Concentration lo?& COK 103% Dilute COC COC COC 521 d Sa d Sa 2 Sa d Sa d 100% 1 00% 1 00% Sa, d 100% Sa d Sal d Sa d Sa d 100% Sa! d Sa d COC Dlill:E 100% 60% 10% Sa! d Sat d Sa! d Bleach sot n Sal d Sa! d 100% 50% Sa 0 Sa! d Sal d Dilute 100% 100% 100% 100% Sat d Sa d EV-A-LINE IV Outer Shell __-i, S Cl 5 S S s s S S S s U U 0 S S S S S 5 u 0 S S S S s S S S S S S S U U S S S S U U U S S S S S 0 U S S U U 0 0 S S S IS = satlafacfory (no attack) 0 = sflghf &tack U = unsatisfactory
--__
B-IV _iner
IV and V HT Liner and Shell at Room Temperature (73F)

Chemical L:uCtoSf Sa!lrc Acid GyCeWe Glycol~c AC<? Hepiane Hydrobronlc Acid or Solvent
B-V Liner
ConccntratiooBEV-A-LINE Outer Shell

52 d Sa 0 OOC 30% 1004. 50% COC 31 1% 309 90% 100% Sal d Sa* d Sa: d Sat d Sa! d Sat d Sa d Sa: d 100% 100% 100% Sat 0 COC Sal d 30.50% C0C Sal d 85?0 1% Sa! d 1% 10% Sat d COC Sal d 40% Sat d 20% Sat d Sal d 20% COC COC 100% Sa! d Sal d COIX Cone Sal d 50% COC 70% 98% 100%
IV
S-IV Liner 5 5 S c L 5 c S S 5 S S S S S S S S S .I 0 S s 5 S S S 0 S S S S 3 S S S S S S S S S S S S S S S S S S S S S 0 i: U U U U S
7-
B-V LItlet __ c S c S 0 S S S S S S S S S S 5 S S S 0 S S S s S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S 0 0 S S shell
Ace:aloa+de A-E c Acid (Glacial) ACelOW Alumnurr Chloride Al~mium Hyaoxlde Al!,rr,rurr~ Sula!e Ammo;un~ Carbowale Ammonwm Chlor,ae Ammon~u~,Ntlrafe Ammonium Persulla?a Ammowm Suliare Ammonlurr TWxyanate Amyl Ace:ate Amyl Chloride Allle Antimony Chloride Arsenic Acid Bawm Carbonate Bawm Chior!de BarNurn Hydroxide Barturn Sulfa!e Benzene Benzo~c Acid Borax Botlc Acid Bow Acid Butanediol Bu:aedlol Butanedzol Calcwm Calcium Calcium Calcium Calcium Calwm Carbonate Chlwde Hydroxide Hypochlorw NItrate Sulfate
0 0
II S S S S S
s
S
s
s
S
s
S S S S S
u
0 S S S S S S S S S S S
I /
S S U S S S S S S S U s S S S S S S S S S S
s
S S
hidroger
Pcroxde
s
S
Laclic Acid La:ex Lead AceWe Magnesium Carbonate Magnewm Magnesium Magnesluv Chlortde Hydroxide Nitra:e
s : s
s : s
I
S S S
1
Magnewm SLllfa!e Male~c Acid MecurIc Chloi~oe Melhylene Chloride MIneral 011 Naphtha Nickel Chloride Nickel Nttrate Nickel Sulfate N,cotlnlc Acid NI!W Acid 01.x Acid Oxalic Acid Pnosphorlc Acid PICK Acid Po!assium Poiassium Pcxass~um PoiassiuV Po!aswm Po!asswm Potassun Po:asswr Polaswm Polasswm Poasslum Polassu~ Puassium Potaswm Propylene Blcarbow!e Boraie Broma!e Bromide Carbonate Chloride Dlchromale Ferrtcyaplde Hydroxide N!tra!e Perchloiale Permangdnale Sulfate Sul!tte Glycol
s
0 0 S
S S S
s s
S S
s s
s
S
100%
s s
S
S
S S S
S S 0 S S
S
Castor Oil Chromic Acid C~lric Ac!d Copper Copper Chloride N~!r.ale
S S S S S S S S S II U S S S S S 0 0 S S 0 U S S S S S
S
S S
I s
s /
i
s s
S
S
S S S S U S S S S S S S S S S U U u u U u U S V HT
CoDpe Sulfaw Cottonseed 011 CresOl Cyclohexane Cyclohexanol Dexwl DeXtKJse D6odlu-m Phosphate Dlethylene Glycol D~octyl Phthalale Ethyl Ace!& Ethyl Alcohol Ethyl Alconol Ethyl Buryrate Ethyl Ether Ferc Chloride Femc Nl!ra!e Few Sulfate Ferrous Chloride Formaldehyde
S
s
S
s
S 5 i
100% 100% 100%

100% 35% 100% 100% Sa! d Sal d Sal d Sal d 40%
Sat d
!
i
s
s
S g
SI~ICIC Acid Sodium Blcarbonale Sodium Borate Sodium Carbora!e Sodwm Sodurn Sodwm Sulfuw Sul:ur!c Chloride Hydw.!de Sulfaw Acid Acid
i
!
s s
s I s I s
/ : / s
I
7OF = 21C
Tetrahydroturan roluene le!rachloroethylee rnchloroethylene Kylene 7.1-c Sulfate For chemvzal reststance
100%
100%
100%
100% S&d charactenstlcs Sclentiflcs. Inc.
of Bev-A-Ltne
outer
contact
Thermoplastic
114
TABLE
1.34:
POLYETHYLENE
RESINS-U.S.I.
CHEMICALS
PETROTHENE density appear marked. There density may be
resins are available across the entire range of polyethylene densities 0.91 to 0.96. The variations in very small, but the effect of even a very small change in density on certain essential properties is very are many applications for which resins of higher density and many others for which those of lower preferable. The three density ranges of polyethylene are: Low density Medium density High density (linear) Chemical Resistance of Low and Medium Density 0.910-0.925 0.926-0.940 0.941-0.965 Polyethylene g/cc g/cc g/cc Reagents
to Various
Reagent Acetaldehyde Acetic Acid Acetic Acid Acetic Acid Acetic Anhydride Acetone Acrylic Emulsions Ally1 Alcohol Ally1 Chloride Aluminum Chloride Alummum Chloride Alummum Fluoride Aluminum Sulfate Alums tall typesl Ammonia, 100% Ammonium Carbonate Ammonium Chloride Ammonium Fluoride Ammonium Hydroxide Ammonium Metaphosphate Ammonium Nitrate Ammonium Persulfate Ammonium Sulfate Ammonium Sulfide Ammonium Thiocyanatc Amy1Acetate Amyl Alcohol Amy1Chloride Aniline* Aniline Hydrochloride Antimony Chloride Aqua Regia Arsenic Acid Barium Carbonate Sariurn Chloride barium Hydroxide Barium Sulfate Barium Sulfide Beer 6enzenc Benzene Sulfonic Acid Benzoic Acid Bismuth Carbonate Slack Liquor @leach lye Soras Soric Acid Boric Acid Bromic Acid Bromine Liquid Bromine Water Butanediol Butanediol* Sutanediol Butyl Alcohol Butyric Acid Calcium Bisulfide
Concen
tration 1 1 i I I
gjTz=
I , I I
Calcium Carbonate Calcium Chlorate Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Calcium Nitrate Calcium Sulfate Camphor Oil Carbon Dioxide Carbon Dioxide Carbon Dioxide Carbon Oisulfide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Castor Oil Chloracetic Acid Chlorine Dry Gas Chlorine Moist Gas Chlorine Liquid Chlorine Water Chlorobenzent Chloroform Chlorosulfonic Acid Chrome Alum Chromic Acid Chromic Acid Chromic Acid & Sulfuric Acid Cider Citric Acid Coconut Oil Alcohols Cola Concentrates Copper Chloride Copper Cyanide Copper Fluoride Copper Nitrate Copper Sulfate Copper Sulfate Cottonseed Oil Cresol Cresylic Acid Cuprous Chloride Cyclohexanol Cyclohexanone Detergents, Synthetic* Developers, Photographic Oertrin Dextrose Dibutylphthalate Disodium Phosphate Oiazo Salts Oiethylene Glycol Diglycolic Acid Dimethylamine Dioctyl Phthalate Emulsions, Photographic
Conccn.
tram
1
7 t ,
Concen-
ry L
II
100% 1.10% IO-SO% 80.IDOX
Satd. Sat-d. Satd. Bleach Sot? SO%
! ! U I s uI S U S S U 0 0 U S U U U S S S s S s s : f E 5
Dilute Cone. Cont. Cont. Cont. Dry Gas Satd. 20% 0,880 s.g Satd. Satd. Satd. Satd. Satd. Satd. 100% 100% 100% 100% Satd.
100% dry 100% wet Cold Satd.
Cont. 100% 100%
_..I S S S S S S SU S S S U s U :S S Iu
I
tration 100% 100% 35%
p .tC f
IS s U U U u U U S S s S S S S U s , 0 s s s 5 S
( 4 ! a , ! I s I
1 S 1
I% Satd. So
100% Satd. 20% up to SO%
i S !i
I! Iu 3 IJ IJ IJ < i
Satd.
100% Satd. Satd. Satd. Satd.
: : : : S S S S : : S U U S S : U S
Satd. Satd. 2% SaYd. Dilute Satd. 100% 50% Satd.
b C d1 1 S 5, 51 s S
: S S S UI s S U S
All Cont. Satd. 10% Cold Satd. Dilute 10% 100% 10% 60% 100% 100% Cont.
i i I i i , I i
Satd. Satd.
s S s S S S : S
Ethyl Acetate Ethyl Alcohol Ethyl Alcohol* Ethyl Butyrate Ethyl Chloride Ethyl Ether Ethylene Chloride Ethylene Chlorohydrin Ethylene Dichloride Ethylene Glycol Ferric Chloride Ferric Nitrate Ferrous Chloride Ferrous Sulfate fish Solubles fluoboric Acid Fluorine fluosilicic Acid fluosilicic Acid Formaldehyde Formic Acid Formic Acid Formic Acid Fructose Fruit Pulp Fuel Oil Furfural Furfuryl Alcohol Gallic Acid Gasoline Gin Glucose Glycerine Glycol Glycolic Acid Grape Sugar Heptane Hexanol. Tert: Hydrobromic Acid Hydrocyanic Acid Hydrochloric Acid Hydrochloric Acid Hydrochloric Acid Hydrochloric Acid Hydroftuoric Acid Hydrofluoric Acid Hydrofluoric Acid Hydrogen Hydrogen Bromide Hydrogen Chloride Gas Hydrogen Peroxide Hydrogen Peroxide Hydrogen Phosphide Hydrogen Sulfide Hydroquinone Hypochlorous &id Inhs Iodine tin KI Soln.)
7 I 5 ,j (1 1I 1I 1I 1I !, s1 s, : S S S S S S S S S S S 0 U U S U U S S S S S U S S : s S s S : S ! S S : s
II
Satd. Satd. Satd.
32% Cont. 40% O-20% 20.50% 100% Sat-d.
100% Satd.
j IJ tJ IJ c i
J
30% Sard. Aq.
I1 > < , < b 5 s

1I S s s s S S S S S D S S S 0 U S S S S S U
50% Satd. 10% 30% 35% Cont. 40% 60% 75% 100% 10% 3Z 93% lW%
Corn. Cont.
(continued)
Synthetic
Resins and Polymers
115
TABLE 1.34:
POLYETHYLENE
RESINS-U.S.I.
CHEMICALS
(continued)
Reagent
Lactic Acid Lactic Acid Latex* Lead Acetate Lead T&a-Ethyl Linseed Oil Lube Oil Magnesium Carbonate Magnesium Chloride Magnesium Hydroxide Magnesium Nitrate Magnesium Sulfate Maleic Acid Mercuric Chloride Mercuric Cyanide Mercurous Nitrate Mercury Methyl Alcohol Methyl Bromide Methyl Chloride Methyl Ethyl Ketone Methylene Chloride Methylsulfuric Acid Milk Mineral Oils Molasses Naphtha Naphthalene Nickel Chloride Nickel Nitrate Nickel Sulfate Nicotine* Nicotinie Acid Nitric Acid Nitric Acid Nitric Acid Nitric Acid Nrtrobenzena Ocfyl Cresol Oils and Fats Oleic Acid Oleum Orange htract Oxalic Acid Oxalic Acid Oxygen Ozone Perchioric Acid Petroleum Ether Phenol Phosphoric kid Phosphoric Acid Phosphoric Acid Phosphorus (Yellow1 Phosphorus Pentoxide Phosphorus Trichlorida Photographic Solutions
400
F II
I
Reagent Pickling Baths Hydrochloric kid Sulfuric Acid Sulfuric-Nitric* Picric kid Plating Solutions Brass Cadmium Chromium* Copper Gold* Indium Lead Nickel Rhodium* Silver Tin* Zinc Potassium Bicarbonate Potassium Borate Potassium Bromata Potassium Bromide. Potassium Carbonate Potassium Chlorate Potassium Chloride Potassium Chromate Potassium Cyanide Potassium Oichmmate Potassium Farril ferro Cyanide Potassium Fluoride Potassium Hydroxide Potassium Hydroxide Potassium Nitrate Potassium Parborate Potassium Parchlorate Potassium Permangamte Potassium Persulfate Potassium Sulfate Potassium Sulfide Potassium Sulfite Ropargyl Alcohol Propyl Alcohol Propylene Dichloride Propylene Glycol Rayon Coagulating Bath Sea Water Selenic Acid Shortening* Silicic Acid Silver Nitrate Soln. Soap Solution Sodium ketate Sodium Benzoate Sodium Bicarbonate
Conccn-
tration Sodium Elsulfate Sodium Bisulfita Sodium Borate Sodium Bromide Sodium Carbonate Sodium Chlorate Sodium Chloride Sodium Cyanide Sodium Dichromata Sodium Farricyanida Sodium Farrocyanide Sodium Fluoride Sodium Hydroxide Sodium Hypochlorite Sodium Nitrate Sodium Sulfate Sodium Sulfide Sodium Sulfide Sodium Sulfite Stannic Chloride Stannous Chloride Starch Solution Stearic Acid Sulfur Sulfur Dioxide Sulfur Dioxide Sulfur Trioxidc Sulfuric Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid, Fuming Sulfurous Acid Tallow lannic Acid Tanning Extracts Tartaric Acid Tartaric kid Tetrahydrofurane Titanium Tatrachloridc Toluena Transformer Oil Trichloroathylene Triethanolamine Trisodium Phosphate Turpentine Urea Urine Vinegar Vanilla Extract Wetting Agents* Whiskey* Wines Xylene Yeast Zinc Chloride Zinc Sulfate
Concen-
tration Safd S&d.
1t
F
3
3
S&d. 100%
1%
Satd. Satd. Satd. Satd. Satd. Satd. Satd. Satd. S&d. 100%
U S S : S S S S s S s s S S S S s S S E 5
Dil. S&n. Cont. Satd. S&d. Satd. Satd. Satd. Satd. Cent.
s s
S i
S i S : :
25% Satd. Soln. Satd Satd. Tatd. Sofn. Satd. 100% Colloidal Dry, 100% wet. 100% 0.50% 70% 80% 96% 18% LConcJ
:
S
S
100% lDG%
SaFd. 1% 10% S&d. Sagd. S&d. 40% SaYd. 40% Satd. 20% corm. Satd. SaFd. 10% 20% S&d. Cont. Cont. Cone.
Comm.
wd. Cont. Satd. Dilute 0.30% 30.50% 70% 9198% 100%
; E E i 5 I i i i i i i 1 i i i i , i i ; 1 , 1
O-some attack
S S S S S S S S S S S 0 3 :
S
0
S
10% Comm. 10% Satd. Satd. S S S J J J ; J i E S S S 5 i ; S I i i i
Cont. Cont. Dilute Satd. 100% 100% 10% 90% up to 30% 309D% 90% lW% 100% 100%
100%
100% Satd. rp to 30% Comm.
U U S 0 S S S U U U U U U u S U S S S S S
u u
Any Concn. Saw. 35%
s&d.
Satd. Satd.
7OCf = wc,
14w
= 60OC
Kay: S-satisfactory
U-unsatisfactory
*The values are obtained from tests made under static conditions and using nonstressed specimens. Reagents marked with an asterisk (1 may, under certain conditions, cause environmental stress cracking if the polyethylene products are improperly designed or not made of the best suitable resins.
116
Corrosion Resistant Materials Handbook 1.35:
TABLE
POLYETHYLENE
TANK
MATERIAL-NALGE
The XL-200 D.O.T.-exempted mini-bulk tank is a reusable, lightweight 200 gal tank system for hazardous liquids. Rotationally molded of cross-linked high-density polyethylene (XLPE), the XL-200 has superior resistance to impact and stress-cracking and is compatible with a wide range of chemicals (see chemical resistance summary). Its strong over a wide temperature range, from -20 to +16OF (-29 to +71C). Chemical Rcslstance Summary Class of Substances at 20C Acids, dilute or weak Acids*, strong and concentrated Alcohols, Aliohatic Aldehydes Bases Esters Hydrocarbons, Aliphatic Hydrocarbons, Aromatic- Hydrocarbons, Halogen&d Ketones Oxidizing Agents, strong
l
Excellent -Excellent Excellent Good Excellent Good Good
Good Fair Good Fair
This Chemical Resistance Summary IS mrended as a genera/ guide only.
Except for ox:dizmg acids; for oxidizing sods, see Ox/d,z,ng Agents, strong.
TABLE
1.36:
POLYETHYLENE PRODUCTS
TEREPHTHALATE-BASED
COPOLYESTER-EASTMAN
CHEMICAL
KODAR PETG Copolyester 6763 is a clear, amorphous polymer based on poly(ethylene terephthalate) and has a number average molecular weight (Mn) of about 26,000. To obtain the data shown below, sections of unstressed injection-molded tensile bars l/s inch (3.2 mm) thick were weighed and measured and immersed in the chemical or reagent shown and stored at 73F (23C) for a period of one year. At the end of the test period, each sample of plastic was removed from the jar in which it was tested, wiped dry, and quickly weighed and measured again and the to the test medium changes in weight and thickness were calculated. The appearance of the samr !e after exposure was also recorded. Ordinarily, a plastic would not be suggested for continuous immersion in a reagent that causes an increase of 5% or more in weight or thickness. This does not imply that a change in weight or thickness of less than 5% necessarily indicates suitability for immersion. The results of these tests showed that KODAR PETG Copolyester 6763 is resistant to a variety of chemicals, highmolecular-weight esters, aliphatic hydrocarbons, and dilute solutions of acids and salts. PETG 6763 was significantly affected by concentrated acetic acid, acetone, benzene, toluene, carbon tetrachloride, dimethyl formamide, and phenol and was completely deteriorated by concentrated nitric and sulfuric acids and by ethylene dichloride.
(continued)
Synthetic
Resins and Polymers
117
TABLE 1.36:
POLYETHYLENE PRODUCTS
Reagent
TEREPHTHALATE-BASED
COPOLYESTER-EASTMAN
CHEMICAL
(continued)
%Change
Weight 0.5
,n
Thickness
I ! I ~ I
Dwolored Dwolored
Appearance of Plasrlc After Exposure Verv sllqht vellowmq and swollen (brown). swollen, rubber-like
Acettc Acid. 5%
A cct~c Acad. cone

Acetone Ammonum Hvdroxlde. cont. 10%
192 15.6
! / 1
0.2 18.5 234
A;r.:r:on~um HvdroxIde.
Turned white - outslde crumbling off ~--.___ DIscolored (pInkI - surface has blisters
Cttrlc Acid, 10% Cottcnseed 011 Detergent, Alconox Demnlzed Water Dlbutvl Dlmethvl Ethanol, Sebacate Formamlde I 21.9 05 06 !
(0
25%)
100% _ Ethanol, 50% Ethyl Acetate -___ Ethylene Dlchlortde Gasolme. High Test Gasoline, Regular Hexane Hvdrochlortc Hvdrochlorlc Acid, cont. Acid. 10%
I : / /
38.6 0.7
202 _ 1.3 0.8 01 11
I 05 / __-___ 24.5
_
/ ~ ;
!
Badly discolored and dtstorted ____Very slight vellowlng
_~--~
Slight vellowng Badly dtscolored and swollen - rubber llke Completely Cloudy deteriorated -__ !n one week
___-
0.9
0.8 02 I 0.9 0.3 04 0.3 0.2
: / / I j
/
-_____Sltght vellowmq .__L__ S!lght vellowlng Badly dlrcolored Slight veliowlng Sltqht vellowmg Sllqht yellowlnq Very slight vellowng _~___ Very sltght vellowng Very slight vellowlng. crazing - blisters under surface
_~._____
I / I I I !
I
0.2 0.6
04
1 Hydrogen PeroxIde, 28% 1 Hvdrogen PeroxIde. 3%
I / i ; ~
i
I I
lSOOctane
Kerosene Methyl Alcohol Mineral 011 Nltrlc Acid, cone Nltrlc Actd. 40% Nltrlc Acid. 10% 1 Oleic Acid, 83%
0.3 0.3 05 02
0.2 0.7
0.1
jvsllghtvellowlng
_
14
0.5
0.1
! : I
/
_
0.8 0.3 0.2 0.2 14.3
[ / / 1 I / j
i
Completelv Turned%hlte
detertorated
after one week __-
Slight vellowng Verv shqht vellowinq Verv sltaht vellow~nq Turned black Slight vellowmg Slight vellowmg Sllqht vellow~ng Sllaht vellowina Sliaht vellowinq Slight vellowmg Shght vellowng Completely deteriorated in one week
I Olwe011
Phenol, 5% Soap Solution, -__ 1% 10%
02 13.2 0.5 0.3 0.4
I j I i I
i
0.2
01 0.2 0.4 6.4 0.2 0.6
Sodwm Chloride,
Sodturn Carbonate. 20% 1 Sodium Carbonate, 2% 1 Sodium Hvdroxlde. Sodwm Hydroxide, Sodium Hvpochlorite, Sulfurtic Acid, cont. Sulfuric Acid, 30% I Sulfuric Acid, 3% Transformer Toluene Turpentine Oil 10% 1% 3.5%
I I
0.5 8.0 0.8 0.8
I
I
1 j
j
0.3 I 0.2 0.2 0.2 31.0 0.2

Sisn.
/ I I
/ Slight yellowing Slight vellowing Very sltght vellowng Turned white - rubber-llke Slight vellowng
0.5 0.4 25.9 0.3
l C!wtgesshown
were
increases
unkn
rhe/igure
h precede
b.v (I nfFtti
118
TABLE
1.37:
POLYMETHYLPENTENE-WESTLAKE
PLASTICS
The high resistance of TPX (polymethylpentene) to chemical attack, combined with its excellent transparency and high temperature performance, makes it particularly suitable for a wide range of applications. TPX polymers are highly resistant to inorganic environments, are not attacked by aqueous solutions of inorganic salts nor by most mineral acids or alkalis even in a concentrated form. They are, however, affected by oxidizing reagents. TPX polymers show good resistance to many organic chemicals although, as with other polyolefins, absorption does occur in certain cases leading to a loss of rigidity and a decrease in yield stress. Tests on injection molded samples at 20C (68OF) and 60C (140F) over a period of 3 months are listed and give an indication of the behavior in practice.
2oc
60C
2oc
6OC
Acetic acid (glacial) Acetic acid (dilute) Acetone Aluminum chloride Aluminum fluoride Aluminum sulfate Ammonia Ammonium carbonate Ammonium chloride Ammonium fluoride (20%) Ammonium hydroxide (10%) Ammonium nitrate Ammonium sulfate Ammonium sulfide Ammonium thiocyanate Amy1 acetate Amy1 alcohol Amy1 chloride Anisole Barium carbonate Barium chloride Barium hydroxide Barium sulfate Barium sulfide Beer Benzaldehyde Benzene Benzoic acid Benzyl alcohol Brake fluid Bromine liquid Bromine water Butylacetate Calcium carbonate Calcium chlorate Calcium chloride Calcium hydroxide Calcium hypochlorite Calcium nitrate Calcium phosphate Calcium sulfate Calcium sulfite Carbon dioxide Carbon tetrachloride Carbonic acid Chlorine water Chlorobenzene Chloroform Chromic acid
B A B A A A A A A A A A A A A B B C B A A A A A A A C A A A D D C A x A A A A A A A A c A D C C A
B A B A A A A A A A A A A A : C C C A A A A A A B C A A ; D C A A A A A A A A A A C A D C D A
Citric acid Copper chloride Copper cyanide Copper fluoride Copper nitrate Copper sulfate Corn oil Cuprous chloride Cyclohexanol Cyclohexanone Decalin Diesel Oil Dimethyl formamide Dioctyl phthalate Ether Ethyl acetate Ethyl alcohol Ethyl oleate Ethylene glycol Ferric chloride Ferric nitrate Ferric sulfate Ferrous chloride Ferrous sulfate Fluosilic acid Formaldehyde Formic acid (100%) Fruit juices Gear box oil Gin Glycol Hexane Hydrochloric acid (50%) Hydrochloric acid (30%) Hydrochloric acid (20%) Hydrochloric acid (10%) Hydrofluoric acid (60%) Hydrogen peroxide (70%) Hydrogen peroxide (35%) Hydrogen peroxide ( 10%) Isopropyl alcohol (100%) Iodine in ethanol solution Lead acetate ( 100%) Lemon oil (concentrated) Linseed oil Lubricating oil Magnesium carbonate
A A A A A A A A A B C B A A C B A B A A A A A A A A A A A A A C A A A A A A A A A A A C A B A
A A A A A A A 4
B 6
D A A C C B C A A A A A A A A A A B A
A C
B A A A A B B A B A A C A C A
(continued)
Synthetic Resins and Polymers
119
TABLE 1.37:
POLYMETHYLPENTENE-WESTLAKE
PLASTICS
(continued)
2oc Magnesium chloride Magnesium hydroxide Magnesium nitrate Magnesium sulfate Magnesium sulfite Mercuric chloride Mercuric cyanide Mercurous nitrate Mercury Methyl alcohol Methyl ethyl ketone Methylene chloride Milk Mineral oil Motor oil Nickel nitrate Nickel sulfate Nitric acid (fuming) Nitric acid (70%) Nitric acid (50%) Nitric acid (10%) Nitrobenzene Oleum Olive oil Oxalic acid (50%) Paraffin ozone Paraffin wax Paraldehyde Petrol Petroleum ether Phenol Phosphoric acid (50%) Photographic developer Potassium bicarbonate Potassium bromide Potassium carbonate Potassium chlorate Potassium chloride Potassium chromate Potassium cyanide Potassium dichromate Potassium ferricyanide Potassium ferricyanide Potassium fluoride Potassium hydroxide Potassium nitrate Potassium perborate Potassium perchlorate Potassium permanganate Potassium sulfate Potassium sulfide Potassium sulfite Pyridine Resorcinol (saturated)
A
60C A A A A A A A A B B A B B A A D B A A B D A B A A C C C A A A A A A A A A A A A A A A A A A A A A A B A Rum Silicone oil Soap solution (concentrated) Sodium acetate Sodium bicarbonate Sodium bisulfite Sodium borate Sodium carbonate Sodium chlorate Sodium chloride Sodium chlorite (20%) Sodium cyanide Sodium dichromate Sodium ferricyanide Sodium ferrocyanide Sodium fluoride Sodium hydroxide (50%) Sodium hypochlorite Sodium nitrate Sodium nitrite Sodium silicate Sodium sulfate Sodium sulfide (25%) Sodium sulfite Stannic chloride Stannic sulfate Stannous chloride Sulphamic acid Sulfuric acid (98%) Sulfuric acid (60%) sulfuric acid (30%) Sulfuric acid ( 10%) Tannic acid Tartaric acid Tetrahydrofuran Toluene Transformer oil Trichloroacetic acid (10%) Trichloroethylene Turpentine Vaseline Vinegar Vodka Water Whisky White paraffin White spirit Wines Xylene Zinc chloride Zinc oxide Zinc sulfate A = B= C= D = Negligible effect Limited absorption or attack Extensive absorption Extensive attack
20c A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A C C A A C C A A A A A A C A C A A A
60C A A A A A A A A A A A A A A A A A A A A A A A A A A A A B A A A A A C C C A C C A A A A A B C A C A A A
A A A A A A A A A B A A A A A A D A A A A D A A A A B B C A A A A A A A A A A A A A A A A A A A li A A B A
120
TABLE
1.38:
POLYPHENYLENE
SULFIDES-PHILLIPS
CHEMICAL
RYTON polyphenylene sulfide resins and compounds are engineering thermoplastics developed by Phillips Petroleum Company. Available in both molding and coating grades, these materials feature excellent dimensional stability, inherent flame retardancy, thermal stability, chemical resistance, desirable electrical properties and ease of processing. RYTON resin compounds are resistant to a very broad range of chemical materials and at elevated temperatures are considered second only to PTFE in overall resistance to corrosive and hostile chemical environments. Environments to which RYTON compounds do not have adequate resistance include oxidizing environments such as 50% nitric acid, 30% sulfuric acid, sodium hypochlorite, bromine water, etc., all at 200F (93C) or above.
ENVIRONMENTS
COMPATIBLE
WITH RYTON COMPOUNDS
Room Temperature
200F (93C)
Hydrocarbons Esters Ketones Alcohols Chlorinated Hydrocarbons Bases Amines

Acids
Hydrocarbons Esters Ketones Alcohols Chlorinated Hydrocarbons Bases Dilute Acids
TABLE
1.39:
POLYPROPYLENE-EASTMAN
CHEMICAL
PRODUCTS
Resistance
of TENITE
Polypropylene
4231
to Various
Chemicals*
Change in Thickness 1 .o 0.1 -0.1 1.8 -0.4 No change Slightly Slightly Slightly Slightly bleached bleached bleached yellov.
Chemical Acetone Acetic Acid 5% Ammonium Bury1 Acetate Calcium Chloride 212% Hydroxide 10%
Appearance
Wwght 2.2 0.1 0.0 6.3 0.1
(continued)
121
TABLE
1.39:
POLYPROPYLENE-EASTMAN
CHEMICAL
PRODUCTS
(continued)
*Injection-molded disks 2 inches in diameter and %-inch thick were immersed in the chemicals and stored under a constant temperature of 73F for one year. Polypropylene is highly resistant to chemical attack and to stress-cracking. However, a few chemicals produce swelling and attack the surtace slightly. These chemicals are mainly chlorinated compounds, aromatic hydrocarbons, and the higher aliphatic hydrocarbons, such as gasoline.
122
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
EXPOSURE
Temp., OF
Time, days
CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U= Unsatis.
PERMEABILITY (gm./24 hr./ 100 rq. inlmil)
Acetaldehyde Acetate solvents, pure Acetic Acid (5%) Acetic Acid (10%) Acetic Acid (20%) Acetic Acid (50%) Acetic Acid (Glacial) (100%)
68 122 73 73 140 70 140 73 72 176 68 122 140 68 68 122 140 73 73 68 176 68 140 68 140 73 68 140 212
180 180 365 30 100 100 30 30 180 180 100 30 100 180 100
M M M S S S M S S M S S M S M M M S S S S S S M U
39.6
1.06 6.4 4.2
Acetone
(DMK)
Acetophenone Acetylene Acriflavine (2% aq. soln)
Acrylic emulsions Ally1 chloride Almond Oil Aluminum chloride
117
S S S S S S S S S S S S S S S S S S
0.0
Aluminum Aluminum Alums Ammonia Ammonia
fluoride Sulfate
68 140 73 73 72 73 140 73 73 73 73 68 140 73 30 180 180 365 100
(15% sol.)
(25%)
9.5
17.4
Ammonia (30%) Ammonia, concen. Ammonia (gas-liquid) Ammonium Acetate Ammonium Bicarbonate Ammonium Carbonate
(continued)

TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued)
123
REAGENT ,Soldr onsaturated ~ol~tton unlessandncated orherwsel
EXPOSURE
CHEMICAL EXPOSURE PERFORMANCE

S = M=
Saris.
Temp., OF Ammonium Ammonium Chloride fluoride 73 68 140 212 Ammonium Ammonium Hydroxide 73 68 140 212 Ammonium Ammonium Nitrate persulphate 73 68 140 212 73 73 68 140 212 Amy1 Acetate Amy1 Alcohol 73 68 140 212 Amyl Chloride Aniline 68 140 68 122 140 Anisole 68 140 212 Anti-freeze Antimony Chloride, satd 68 122 68 140 212 Apple Juice Aqua regia 73 68 140 212 73 73 68 140 (10% aqueous sol.) metaphosphate
Time, days
Marginal
PERMEABILITY (gm.124 hr.1 100 sq. inlmil)
U= Unsatir. S s s S
365
S S S S S S S S S S S S S S S S S M M
Ammonium Ammonium Ammonium
Phosphate Sulfate Thiocyanate
180 180 30
S M S S M U
0.165 2.77
180 180
S S S S M
0.0 0.45
43
S S M U U U S S
1.78
Aromatic Asphalt
Hydrocarbons
Barium Carbonate
(continued)
124
TABLE 1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
(Sohdr m saturated solution unlessmdicated otherwKl
EXPOSURE
Temp., F Barium
Time, days
PERMEABILITY (gm.124 hr.1 100 sq. inlmil)
Carbonate
212 68 140 212 68 140 212 73 68 140 212 68 140 212 72 73 73 68 68 140 73 73 68 122 68 140 212 73 73 73 73 73 68 140 68 140 73 73 73 73 73 72 176 365 180 180
S s s S s S S S S S S S S S S S M U M M S S S S S S S S S S S M M U M M M M S S S S S 0.22 1.0
Barium Chloride
Barium Hydroxide
Barium Salts Barium Sulfate
Barium Sulfide
Beer Beet Juice Benzaldehyde Benzene/Benz01 Benzene Sulfonic Acid Benzoic Acid Benzoyl Chloride Benzyl Alcohol Bismuth Carbonate
30
180
100% loss
Bluing Borax Boric Acid, Brandy Brine Solution Bromine Gas (weak) Bromine Liquid
Bromine water, satd Butane Butanol Butter Butyl Acetate Butyl Phthalate
365 80 30
Synthetic Resins and Polymers TABLE 1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued)
125
EXPOSURE
1
Temp., OF Calcium Bisulfite Calcium Carbonate Time, days
CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U = Unsatir.
PERMEABILITY (gm.124 hr./ 100 sq. in/mill
73
68 140 212 68 140 212
S
S S S S S S 365 30 30 S S S S S S S S S S S S S S S S S 86 365 S U S U S S S S 365 S S S U U S S S 3.64
Calcium Chlorate
Calcium Chloride (2.5% aqueous solution) Calcium Chloride (50% Solution) Calcium Hydroxide 73 72 176 68 140 212 Calcium Hypochlorite Calcium Nitrate (50% soln.) 73 68 140 Calcium Phosphate Calcium Salts Calcium Sulfate 212 68 73 68 140 212 Calcium Sulfite 68 140 Camphor Oil Cane Sugar Liquors Carbon Bisulfide Carbon Dioxide, dry Carbon Dioxide, wet Carbon Dioxide Solution Carbon Disulfide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Carrot Oil Castor Oil 212 73 73 73 73 73 68 140 73 68 140 73 140 68 140 73
365 106
73
143
0.0
(continued)
126
Corrosion
Resistant
Materials
Handbook
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
(Sol,dr ,n salurated $oIlm unless indtcated othenwe)
EXPOSURE
PERMEABILIT)
Castor Oil Caustic Soda, cont. Caustic Soda, dil. Cellosolve@ Cetyl Alcohol Char-co-sol Chlorobenzene Chlorine Chlorine Gas Liquid
Chlorine Water Chlorine Chlorine (wet) (dry) Hydrocarbons Acid 73 73 73 68 140 212 73 73 73 73 140 73 68 140 68 122 140 sitric Acid, 2 N Zitrondropar (Lemon) Zlove Oil Zoconut Oil Zod Liver Oil Coffee Zoke Oven Gas 73 68 122 73 140 73 73 73 73 180 180 30 365 109 109 302 159 162 96 365 30 30 365 365 U U S S S S S S S S S S S S S S S S S S M M S S S S 6.43 22.77 0.0 5.35 0.0 0.0 0.48 2.3
Chlorinated
Chloroform Chlorosulfonic Chlorox Chrome Alum
Chocolate Syrup Chromic Acid (10%) Chromic Acid (30%) Chromic Acid (40%) Chromic Acid, 2 N Cider Citric Acid (10%)
(continued)
Synthetic
Resins and Polymers
127
TABLE 1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
ISohds I saturated solutmn unless,nd,cated otherwsel
EXPOSURE
Temp., F
Time, days
CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U = Unratis.
PERMEABILITY (gm.124 hr.1 100 sq. in/mil)
Copper Salts Copper Sulfate Core Oils Corn Oil Cottonseed Oil Creosote Cresal Cresol Cupric Chloride Cupric Cyanide Curpic Fluoride Cupric Nitrate Cupric Sulfate Cuprous Chloride Cyclohexane Cyclohexanol Cyclohexanone DDT Spray Decalin Detergent Solution (Heavy Duty) Developers (Photographic) Dextrine Dextrose Diacetone Alcohol Diazo Salts Dibutyl Phthalate
73 73 73 73 140 73 140 73 73 68 68 140 68 140 68 140 68 140 68 140 68 140 68 122 68 122 68 122 68 73 73 140 68 140 68 140 68 140 68 122 68 140 73 180 189 30 30 180 180 180 180 189 180 158 167 191 113
S S S S S S S S U S S S s S S S S S S S S S M M S S M M S U S S S S S S S S S S s S M 0.21 3.94 194.0 100% loss 0.13 1.63 0.22 13.4 0.0 0.0 0.0 0.0
(continued)
128
Corrosion Resistant Materials Handbook POLYPROPYLENE RESINS-SHELL CHEMICAL
TABLE 1.40:
(ccIntinued)
REAGENT
(Solids an rarursted solution unlessmdicated ocherwise~
EXPOSURE
Temp., o F
Time, days
PERMEABILITY (gm./24 hr./ 100 sq. in/mill
Dichloroethylene Diethanolamine Diethyl Carbonate Glycol Phthalate Ether Formamide
73 68 140 68 140 68 140 68 140 68 140 73 140 68 122 70 140 73 30 30 180 180 100
S S S S M S S S S M M S S S M M M M S 78 160 S S S S 180 180 180 180 365 365 S S S S S S S S S S S 365 180 100 M M M M M S S S 7.0 100% loss 0.0 0.40 1.42 17.9 0.55 5.03 1.1 10.6
Diethylene Di-iso-octyl Dimethyl Dimethyl
Dimethylamine Dioctyl Dioxane Disodium Phosphate Phthalate
(DOW
Distilled Water Dobanic Acid Donax 8 Dye (Rit) Epichlorohydrin Ethanol (50% Aqueous
68 140 73 140 68 140 68 122 73 68 122 73 73 68 140 73 73 122 140
Solution) Ethanol (95%) Ethanolamine Ethers Ethyl Acetate
Ethyl Acrylate Ethyl Alcohol Ethyl Alcohol (50%)
68 140 73 140 68 365 100 30
(continued)
Synthetic
Resins and Polymers
129
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
EXPOSURE
Temp., OF
Time, days
CHEMICAL EXPOSURE PERFORMANCE S = Satis. M= Marginal U-i Unsatis.
PERMEABILITY bnJ24 hr./ 100 tq. in/mill
Ethyl Alcohol Ethyl Alcohol Ethyl Chloride Ethylene
(50%) (95%)
140 73 140 68 140 68 140 68 70 73 50 68 140 212 68 140 73 68 140 73 73 73 68 68 140 73 72 73 72 73 73 68 140 68 140 68 140 73 68 140 73 68 122
30 100 30
s S S M M M M
Chloride
Ethyl Ether Ethylene Di-chloride Ethylene Glycol Ethylene Oxide EthYl Oleate
180 30 365
M M S M S M M S S S S S S S S S S S S S S S S M S S S S S S U M M S
Fatty Acids, Ce Ferric Chloride Ferric Nitrate Ferrous Chloride Ferrous Sulfate Fish Flit Insecticide
Fluosilicic Acid Fly Spray (Ortho) Formaldehyde, (35% Solution) Formaline, (40% Solution) Formic Acid (85%) Formic Acid (Anhydrous) Freon@ Fructose Fruit Juice Fruit Pulp Fuming Nitric Acid Furfural Furfurol Gas Oil
90 30 365
0.31 0.31 24.7
180 180
S S
(continued)
130
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
LSolldr I saturated solution unlesstndacatedofherwsel
EXPOSURE
Temp., OF
Time, days
CHEMICAL EXPOSURE PERFORMANCE S = S8tis. M= Marginal U= Unutis.
PERMEABILIT? I (gm.124 hr./ 100 sq. in/mill
Gasoline
73 73 140 73 73 68 140 73 73 73 68 140 68 140 68 122 68 140 68 73 73 73 73 73 70 140 Solution 73 73 68 140
100 365 100 365
M M M M M S M S S s S S S S S S S S S S S S M M S S S S S S
100% loss 100% loss 100% loss
Gasoline (Aviation) Gasoline (Sour) Gearbox Oil Gelatin Glucose Glue Glycerine Glycolic Acid (30%) Glycerol Grape Sugar Grease Green Soap Solution Heavy Duty Detergent (OMO) Heptane Hexane Household Detergent Household Ammonia Household Soap Hydrobromic Hydrochloric Acid Acid Solution (5%)
180 180
-0.14 -0.86
365 30 100 180 365 100 100
100% loss
(Cont.) (38%) -lydrochloric Acid (10% aqueous solution) iydrochloric hydrochloric Acid (30%) Acid (35%)
73 73 140 73 68 73 140
100 365 100 365 180 100 100 90 10 365
S S S S S S M S S S S .35
iydrochloric iydrochloric iydrochloric
Acid (36%) Acid (50%) Acid, 2N
72 176 73 73
(continued)
131
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
IWads m saturated solution unlerrmdxated otherw84
EXPOSURE
Temp., o F Hydrocyanic Hydrolfluoric Hydrofluoric Hydrofluoric Hydrofluoric Hydrofluoric Acid Acid, Dil. Acid (38%) Acid (40%) Acid (50%) Acid, Techn. 73 73 73 140 73 72 68 140 68 140 73 73 73 73 73 140 73 73 68 140 lgepal Ink, Washable Iodine Solution Iodine (in alcohol) losan lpana Plus Isopropyl Alcohol Isopropyl lsooctane Kardemommudropar (Cardamom Karo Syrup Kerosine 68 122 73 68 122 140 73 Ether 73 73 73 73 140 73 68 122 68 122 73 140
Time, deys
CHEMICAL EXPOSURE PERFORMANCE S = Setir. M= Marginel U= Unsetis. S s
PERMEABILITY (9mJ24 hr./ 100 sq. inlmil)
30 30 90
S S S S S S S S S S
Hydrogen Bromide (10%) Hydrogen Chloride Gas, dry Hydrogen fluoride Hydrogen Hydrogen Peroxide (3% Solution) Hydrogen Peroxide (28% Solution) Hydrogen Sulfide, dry Hydrogen Sulfide (wet + aqudbus solut&n) Hydroquinone
100 365 30 30
S S S U S S S S
365
S S S S S S S S M M M M S S S S M M M 0.110 2.89 4.27 59.0 0.25 3.74 48.0 100% loss 5.10
365 30 30 180 180 186 80 30 30 109 86 180 180 106 30
Kerosine (No. 2 fuel oil)
132
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
ISohdr I saturated solutcm unless tndicated otherwise)
EXPOSURE
CHEMICAL EXPOSURE PERFORMANCE S = Satis. Time. days U= Unsatis.
Temp.. OF Kerosine (No. 2 fuel oil) Kleenezy Kleenosan Kleer-View Kresol Lacquer and Lacquer Solvents Lactic Acid Lactic Acid (20%) Lanolin Lead Acetate Lemon Oil Ligroine Lime Sulfur Linseed Oil Linseed Oil (blue) Lubricating Windshield Washer Solvent 140 140 140 73 140 68 122 73 73 73 68 140 73 73 140 68 122 73 73 73 73 140 73 73 68 140 73 68 140 212 73 140 212 Magnesium Sulfate 73 140 212 Magnesium Sulfide 68 140 212 73 73 73 68
M= Marginal
PERMEABILITY kgn.124 hr.f 100 sq. inlmilb
30 30 30 69 68
180 180
U S S S S S S M S S S S
4.62 5.38 0.85 4.53 0.23

1.56
365
65 14 180 180 365 30 100 100 303
S M M M M S S M M M S S S S S S S S S S S S S S S S S S S S
23.5 258.0 100% loss
Oil
be
Machine Oil Magenta Dye (2% Soln.) Magnesium Chloride Magnesium Carbonate
Magnesium hydroxide
Malic Acid Manganese Salts Mayonnaise Meat Sauce
180
0.29
Synthetic
Resins and Polymers
133
TABLE 1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
(Sol& I saturated solution unlesstndlcated otherwtre)
EXPOSURE

s *
Satir.
M= Marginal
PERMEABILITY (gmJ24 hr./ 100 sq. in/mill
Temp., OF
Time. days
u - Unsatir.
Meat Sauce Mennens Skin Bracer Mercuric Cyanide Mercurochrome Mercuric Chloride Mercurous Nitrate Mercury Methyl Alcohol Methyl Methyl Methyl Methyl Bromide Ethyl Ketone lsobutyl Carbinol lsobutyl Ketone (100%)
122 73 140 68 140 73 73 68 140 73 73 140 68 140 68 122 68 122 70 140 73 73 73 140 73 68 122 68 140 73 68 122 140
180 23 23
S S S S S S S S S S
1.3 0.68 6.8
365 30
S S M U M M S S S U M S M M S S S S S S S S S S 0.16 1.29 3.5 84.0 0.21 2.7
180 180 180 180 100 100 30 30 30 109 86
Methylene
Chloride
Milk Mineral Oil (White) Molasses Mondludropar Monochloracetic
(Almond) Acid
MothSpray (Black Flag) Motor Oil (Shell X-100)
180 180 100
0.031 0.26
Mustard Paste n-Heptane Naphtha Naphthalene
73 140 68 68 140 212 73 73 140 73 100
M M M M M S S S S
Natural Gas Neatsfoot Oil Nickel Chloride
103 110
0.0 0.06
(continued)
134
TABLE 1.40:
PGLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
T
Nickel Nitrate 68 140 212 Nickel Salts Nickel Sulfate Nitric Acid, Cont. 73 73 73 122 140 70 140 73 73 (50%) 140 70 140 Nitric Acid (75%) Nitric Acid, Fuming Nitrobenzene 68 73 68 122 140 Nitrogen Oxides Vitrous Acids Vutmeg Oil DPC 60 Solution 3ils. Vegetables 3leic Acid (21%) 73 73 73 73 73 68 122 140 68 140 212 3live Oil 3xalic Acid Oxalic Acid (50%) Oxygen Gas almitic Acid araffin Wax 73 140 68 122 73 73 73 68 140 68 140 )eanut Oil 73
EXPOSURE
Temp.. OF
Time, days
CHEMICAL EXPOSURE PERFORMANCI S = Sstir. M= Marginal U- Unratcs.
PERMEABILITY (gm.124 hr.1 100 $9. idmil)
S S S S S 365 180 30 100 100 100 365 30 100 100 180 365 180 180 100 S S U S M tvl M U M U M U S S U S S 82 100 180 180 30 U S S S S U U U 365 152 180 180 365 U S S S S S S S S S M M 133 S 0.0 0.0 0.28 2.3 0.076 0.27 1.25
0.42
Nitric Acid, Oil (10%) Nitric Acid, (30%) Nitric Acid (40%) Nitric Acid, Cont.
0.42 0.40 8.4
Ileum
araldehyde
(continued)
Synthetic
Resins and Polymers
135
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
lSol,ds on saturated solution unlessmdlcated otherwsel
EXPOSURE

s = Satis. M=
PERMEABILITY (gm J24 hr./
Temp., OF Peanut Oil Peppermint 140 73 120 73 73 73 73 140 (5%) 73 140 73 73 70 140 Phosphorous Oxychloride Picric Acid Plating Solutions: Brass, Cadmium, Chromium, Copper, Lead, Gold, Indium, Nickle, Rhodium, Silver, Tin, Zinc. Potassium Bichromate/ Sulphuric Acid/Water (5/l 00/5) Potassium Bicarbonate Potassium Borate Potassium Bromate Potassium Bromide Potassium Carbonate Potassium Chlorate Potassium Chloride Potassium Chromate Potassium Cyar.ide 68 73 68 140
Time, days 73 196 95
Marginal lJ= Unsatis. S S M S M S
100 sg. inlmil)
Oil
0.07 0.14 39.3
Perchloric Acid Petroleum Oils, Sour Petroleum Phenol Phenol Solution Oils, Refined
100 loo 365 30
S S S S S S
Phosphoric Acid (25%) Phosphoric Acid (25-50%) Phosphoric Acid (85%)
109 108
S S M M S S
70 140 68 140 68 140 68 140 68 140 73 73 73 68 140 68 140 212 68 140 68
106 108
M M S S S S S S S S S S S S S S S S S S S
Potassium Ferricyanide Potassium FerrVFerrocyanide
(continued)
136

1.40: POLYPROPYLENE RESINS-SHELL CHEMICAL (continued)
TABLE
REAGENT
(Sohdr m saturated solution unlerr mdicated otherwsel
EXPOSURE
Temp., OF Potassium FerrVFerrocyanide Potassium Fluoride 140 212 68 140 212 68 (50%) 122 73 73 68 140 Potassium Perborate Potassium Perchlorate Potassium Persulphate Potassium Permanganate Solution Potassium Sulfate Potassium Sulfide 70 140 73 68 140 212 68 140 Propane Propionic Acid Propylene Dichloride Pyridine Rice Barn Oil Rosin (light) Safflower Oil 212 73 68 140 68 140 73 73 140 73 73 140 73 68 122 Shellac 73 (10%) 212 68 140 68 140 68 140
Time, days
S = Satis. M= Marginal
u= Unsatir.
PERMEABILITY (gm./24 hr./ 100 sq. inlmil)
S S
S S S S S S S S S S S S S S S S 100 100 M M S S S S S S S M S M M M 106 111 161 63 180 180 S S S S S S S S S S 0.0 0.0 0.031 0.26 0.0 0.0
Potassium Hydroxide Potassium Hydroxide Potassium iodide Potassium Nitrate
180 180 365
0.0 0.48
Potassium Sulfite
Sauerkraut Shell X-100
(continued)
Synthetic
Resins and Polymers
137
TABLE 1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
EXPOSURE
Temp., OF
Time, days
CHEMICAL EXPOSURE PERFORMANCE S = Sotis. _ M= Marginal U= Unsatis.
PERMEABILITY (gm.124 hr./ 100 sq. in/mil)
Shoe Polish (liquid) Sea Water
73 68 140 212 68 140 212 73 73
S S S S S S 365 30 30 100 100 S S S S S S S S S S S S S S S S S S S S S S 365 30 30 30 30 365 30 30 90 30 365 30 S S S S S S S S S S S S S
Silica Gel
Silicone Oil Silver Nitrate Soap Solution Soap Solution
(1%)
(5%)
73 140 70 140 73 68 140 212 68 140 2t2
Soapless Detergent Sodium Acetate
Sodium Benzoate (35%)
Sodium Bicarbonate Sodium Bisulfate Sodium Bisulfite Sodium Borate Sodium Bromide Sodium Bromide Oil Soln Sodium Carbonate Sodium Carbonate, Satur. Solution Sodium Carbonate Sodium Carbonate aqueous solution) sodium Carbonate (20% Solution) Sodium Chlorate sodium Chloride, Solution Sodium Chloride (10% Solution) (2% Soln) (2.5
73 73 73 73 68 140 68 140 73 72 176 73 140 73 73 140 73 72 176 73 140
(continued)
138

(continued)
TABLE 1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
REAGENT
Gollds &n saturated solution unlessindicated otherwse)
EXPOSURE
Temp., OF
Time, days
Sodium Chlorite Sodium Chlorite Sodium Chlorite Sodium Chromate Sodium Cyanide
(2%) (20%) (30%)
68 140 68 140 68 140 68 140 73 68 140 212 68 140 212 68 140 212
S S s M S M S S S S S S S S S S S S 365 30 90 30 365 100 30 30 180 180 30 30 30 100 100 100 S S S S S S S S S S S M M M M M S S 30 100 S S S S S S S 0.58 1.92
Sodium Dichromate
Sodium Ferricyanide
Sodium Ferrocyanide
Sodium Hydroxide (1% Solution) Sodium Hydroxide (30% Solution) Sodium Hydroxide, (50%) Sodium Hydroxide (60% Solution) Sodium Hypochlorite Sodium Hypochlorite Sodium Hypochlorite sodium Hypochlorite sodium Metaphosphate sodium Nitrate sodium Palmitate (5% Solution) sodium Perborate Godium Phosphate, Alkaline sodium Phosphate, Acid sodium Phosphate, Neutral Aodium Silicate (5%) (10% Soln) Soln Cont.
73 140 72 176 70 140 73 140 68 122 73 140 73 73 70 140 73 73 73 73 73 73 73 73 73
(continued)
Synthetic
Resins and Polymers
139
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
(Solids in saturated solution unless indicated otherwise)
EXPOSURE
PERMEABILITY
Sodium Sulfate Sodium Sulfide Sodium Sulfite Sodium Thiosulfate Soybean Oil Spindle Oil Stannic Chloride (hype)
Stannous Chloride Starch 140 212 Stearic Acid Succinic Acid Sugars and Syrups 73 73 68 140 212 73 73 68 176 68 73 (dry) (wet) 73 73 73 140 70 140 Sulfuric Acid (30%) Sulfuric Acid (50%) Sulfuric Acid (96%) Sulfuric Acid (97%) Sulfuric Acid, cont. (98%) 73 140 72 176 72 176 73 68 365 30 100 100 30 30 90 10 90 10 365 180 S S S S S S S S S S S S S S S S S S S S S S S S S S S -1.01
Sulfate Liquors Sulfur Sulfamic Acid Sulphur Dichloride Sulfur Chloride Sulfur Dioxide Sulfur Dioxide
Sulfuric Acid (3%) Sulfuric Acid, Dil. (10%)
(continued)
140
TABLE
1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
(Solids m saturated solution unlesslndlcsted othmwr~~
EXPOSURE
Temp., OF
Time, days
CHEMICAL EXPOSURE PERFORMANCE S = Satir. T M= Marginal U= Unsatis.
PERMEABILITY (gm.124 hr.1 100 sq. in/mil)
Sulfuric Acid, cont. (98%) Sulfurous Acid Super Shell Tallow Tannic Acid Tar Tartaric Acid Tea Teepol 514 Solution (27%) Tetrahydrofurane Tetralin Thiopen Toluene Tomato 2T Oil Transformer Transformer Oil Oil, DTE/3D
122 140 73 68 122 68 140 73 73 73 73 73 73 73 73 73 140 73 68 122 73 140 72 176 73 73 68 140 73 73 140
180 100 180 180
S M S M M S S s S S S
-1.44
100% loss 100% loss
100
S S M
365 100 180 180 30 30 90 30
S M M S S S M U M M S U S S S M U S M S S S S S S S S S S 0.64 2.81 0.0 4.1
Trichloracetic Acid, 2N Trichloroethylene Triethanolamine Tri-sodium Turpentine Two-stroke Urea Vanillindropar Varnish Vaseline Vaseline Oil Vinegar (Vanilla) Oil Phosphate
365 30 100 100 109 86 180 180 90 30 180 180
70 140 73 68 122 73 68 122 72 176 68 122
1.99 0.0 0.073
(continued)
Synthetic
Resins and Polymers
141
TABLE 1.40:
POLYPROPYLENE
RESINS-SHELL
CHEMICAL
(continued)
REAGENT
(Sol,dr I saturated solutmn unlesslndacated otherwml
EXPOSURE
Temp., OF
Time, days
CHEMICAL EXPOSURE PERFORMANCE S = Satir. M= Marginal U = Unsatis.
Water Water (brine) Water (fresh) Water (potable) Wax Crayon Wedac Wesson Oil Wheat Germ Oil Whiskey White Paraffin White Spirit (low aromatic content) White Spirit (high aromatic content) Wines Xylene
73 140 73 73 176 73 140 72 73 140 73 68 176 73 73 73 68 73 122 140
365 14
S S S S
30 30 30 160 58
S S S S S S S S S 2.46 0.10 0.01 0.0
100 100 30 180 365 180 100
U U S M M M M S S S S S S 100% loss 100% loss 100% loss 100% loss
Yeast Zinc Chloride Zinc Oxide Zinc Sulfate
68 140 73 68 140 73
142
Corrosion
Resistant
Materials
Handbook
TABLE 1.41:
POLYSTYRENE
RESINS-HUNTSMAN
CHEMICAL
to suit a wide variety of molding or injection but
These thermoplastic resins are crystalline, rigid and of brilliant clarity. They are formulated applications. All the polystyrene resins are processed by extrusion, thermoforming, blow only the rubber-modified impact polystyrene or ABS can be thermoformed.
REAGENT
(Solodr 4 saturated solutm~ unless indscated otherwtsee)
EXPOSURE

s =
SOLVENT
(X lndtcater that the reagent acted as
Satis.
S M U U U S M U
Temp., OF
Time. days
M= Marginal U= Unsatis.
a SolventI
Acetic Acetic Acetic Acetone
Acid 5% Acid Acid 10% 100%
77 77 77
365 365 365
Acetophenone Adrenalin Hydrochloride Adrenalin in oil Ally1 Alcohol Aluminum Aluminum Ammonia Ammonium Amyl Amyl Alcohol Acetate-n Chloride Sulphate Hydroxide (Sat.) (Sat.) 122 122 122 365 365 365
S S S S U U U U Z S S U S U S U S S U U U U X X X
Amy1 Phthalate Amseed Oil Aspirin (pwd) Atropine Sulphate Barium Carbonate Beef Benzaldehyde Benzedrine Benzene Benzoic Benzyl Acid Acetate 122 122 365 365 122 365
(pwd)
122
365
Borax (Sat.) Boric Acid Bromine Butter Butyl Butyl Butyl Acetate Acetate Alcohol iso n iso Liquid
77
365
S S U S M U M U M U U S (continued) X
Butyl Alcohol n Butyl Phthalate Caffeine (Sat.) Calcium Hypochloride Calcium Hypochlorite Camphor Carbon Tetrachloride Carbolic Acid 50% 100% Carbolic Acid Cassia Oil Castor Oil
15%
144
TABLE
1.41:
POLYSTYRENE
RESINS-HUNTSMAN
CHEMICAL
(continued)
REAGENT
(Soltdr in saturated solution unless md~cated otherwant
EXPOSURE
CHEMICAL EXPOSURE PERFORMANCE S = Satir.

M=MargiMl
SOLVENT
(X lndoutn that the r+gent acted *I
a 5ob4ent)
Temp., OF ;lucose
Time. dayr
U- Unutir.
30% jlycerine ieptyl Alcohol-n fexane iexyl Alcohol-n horseradish ioney hydrochloric Acid iydrochloric Acid iydrofluoric Acid iydrogen Peroxide iydroquinone odine Tincture so-propyl Alcohol (erosene .actic Acid 16%
77
240
s S s M S S M U S M M M U U S U S M
10% 38% 10% 30%
77
365
77
365
_anolin _ard .auryl Alcohol .ead Arsenate _ead Nitrate _emon Juice _ime Water _ipstick Aagnesium Carbonate Aaleic Acid 10% dercuric Chloride 5% Jlesityl Oxide vlethyl Acetate wlethyl Alcohol wlethyl Chloride vlethyl Ethyl Ketone Methyl lsobutyl Ketone (Oil of Methyl Propyl Ketone Methyl Salicylate Wintergreen) Methylene Milk Mineral Oil Mono-Chloro Benzene Chloride
77
365
122
365
S U S M S S S U U M U U U U U U X
122 77 122
365 365 365
X X X
77
14
S S U M M U S X
Motor Oil Mustard Nitric Acid 20% Nitroglycerine
(continued)
146
TABLE
1.41:
POLYSTYRENE
RESINS-HUNTSMAN
CHEMICAL
(continued)
EXPOSURE
Tannic Acid 2% Tartaric Acid Alcohol Tea (Sol.) Tetrahydrofurfuryl
Tetralin Thionyl Chloride Titanium Tetrachloride Toluene Trichloroethylene Trisodium Phosphate (Sat.) Triethylene Triethylene Turpentine Water Water Carbonated Witch Hazel Distilled Worcestershire Zinc Carbonate Zinc Chloride Zinc Stearate 50% Sauce Glycol Tetramine
Synthetic
Resins and Polymers
147
TABLE
1.42:
POLYSULFONE-UNION
CARBIDE
UDEL Polysulfone is a high performance thermoplastic known for its high temperature resistance [3OOF (149C) UL listing for continuous use], hydrolytic stability, and excellent close tolerance moldability. Polysulfone also possesses good resistance to a wide variety of aggressive environmental conditions. In the most general terms, POlYsulfone is highly resistant to aqueous mineral acids, alkali, and salt solutions. Resistance to detergents and hydrocarbon oils is good, even at elevated temperatures under moderate levels of stress. In polar organic solvents such as ketones, chlorinated hydrocarbons, and aromatic hydrocarbons, polysulfone will swell, dissolve, or stress-crack. Chemical
Inorganic Acids Chromic Chromic Acid, Acid, 12% 60% Acid, Acid, Acid, Acid, Acid, Acid, 20% 10% 15% 20% 37% 50% Chemicals (22C.)600C.)(tt50C.)(990C.) 730F: i40F: ittSF.ilOOF. NR NR R R R R R LR NR NR R R R R R * LR LR LR * R R R NR NR R R R R LR * * NR NR NR R * + * NR * NR NR
Resistance
Key R LR NR *
IO
Chart
rarrngs
Recommended LImIted Recommendation (many appllcatmns possible depending on stress level) Not Recommended No data
(121C.)(1490C.) .25OF. 300F NR NR R * * * NK * UK UK NR NK R * * * NR * NR NR
Hydrobromic Hydrochloric Hydrochloric Hydrochlonc Hydrochlorw Hydrofluoric Nltnc Nitric Nifric
Organic Acetic Acetic
Chemicals Ar,d 10%
(22C.)(600C.~(850C.)(990C.~ 73F. 140F. lBSF. 210F. R R R LK \K R R R \K R R R R R R
(149Y.J 300F. * YR NR NK hK
Actd. 20%
Acid, 10% Acid, Acid, 20% 40% 71% Acid, 20%
*
R R NR R R K R K K R K NR R K 20% 35% 5% 10% 25% 50% R I? K K R K R K
Acetlc Acid. .50% AC~IIC Acid. Acetic Glacial
*
UK
*
UK
.
R R R
* R R K
. K K R
*
_ R R YK
Anhvdrlde
N#tr!c Acid, Phosphoric Phosphoric Phosphoric Phosphoric Sulfuric Sulfuric Suifwc Sulfunc Sulfuric Bases Ammonia. Ammonia. Potawum Potawum Sodium Sodium Sodium Sodium
Arc=tnnl=
lo%
YR 100% JR UK LR 100% Solvent. i\n~sole. Toluene, 100% lOO6 100% \K R LR R K 100% 100% 100% R R R UR UK R 100% 100% R R R NK \iK 100% 100% \K R
UK UK UK
YR UK YK
\R UK NK
NK NR NK
Actd, 50% Acid. 85% Acid, 40% 100%
Aceton~trtle. Benzene. Butanol, Butvl Butyl
100% 100%
*
K R R K YK
R R K R YK
R R K R UK K K K \K 1K
*
R R NH NR \K
.
YR
NK
NR
NR
Acid,
Acetate.
Actd, 65% Acid. 75% Acid. 85% Acod. 95% 15% 29% Hydroxide, Hydroxide, Hydroxide. Hydroxide, Hydroxide. Hydroxide.
CELLOSOLVE Hvdroxy Hydroxy Prop~onate Solvent Tetrachlorlde.
Butvlated Butylated Calcium CARBITOL
.
f *r
.
R R k R R R R K
.
K KK R K K R K
___K K K K
Carbon
1
* YK rK
* . . . *
UK UK
CELLOSOLVE Chlotobenzene. Chloroform, III~IC 4cld.
Solvent, 100% 100% 40% Oil.
* . . 1 f * f
NK CK
* + . * f .
NK YK
\R UK UK
Cottonseed Crude
011. Texas.
C!clohexane. Cvclohexanone,
100%
. . . .
ZiK LK \K
f . . r
UK vuK \K
f * . .
UK \iK *K
. . . .
NK UK \K
Other Ammonium Ammonium Antimony Black
100% 100%
Persulfate. Persulfate, Tnchlorlde,
24% 40% Sat.
Liquor Chloride, Sat.
* *
R R
. *
R R
* * . .
R R NR
. I
R R R *
* *
K K *
*
NR NR R R *
Dwthyl
ether,
Dwopropyl Dtoctyl Ethanol,
ether,
Phrha!ate, 100%
.-
Calcium Calcium Chlorine,
Ethanolamlne. Ethyl 2.Ethvl Ethylene Ethylene Acetare, Butvrtc
100% 100% Acid. 100%
Hypochlorlte 100% Wet
D~am~ne, 92% Glycol. 100% 100% LR LR LR UK NK loo& LR R 100% 100% 100% R R R
Green Liquor -Hydrogen Peroxide, Oxygen
R 100% R K R
K * K
R K
R K
K *
R *
Formaldehyde, Freon
Ozone
Potawum Sodium Sodium Sodwm Sodium Narrate, Carbonate, Hypochlortte. Hypochlorite, Stl~cate, 1.7% Sar. 1.7% 5X% 17%
*
K
R LR K R LR
*
K
*
R
11 , lOOo/ 0 Freon22. 100% Freon: Freon Furfural Gasoline, Glucose Clvcerlne. n-Heptane, BF, TMC 100%
*
. UK NK

. YK NK
*
* NK NK
*
.PUK NK
I
K K
.
K K
.
R R
, 1007
*
R K
R R
*
* .
I
K
r
K
1
R
*
R
* *
1
* * *
.
* *
*-
Zinc
Chloride,
S.U.
n-Hexane,
(continued)
148
TABLE
1.42:
POLYSULFONE-UNION
Organic Irooctae, Iropropanol. Kerosene, Lactac Acid, Laurie Linseed Malomc MEK, Acld Oil, 100% Chemicals 100% 100% 100% 60%
CARBIDE
(continued)
(22OC.)(6OOC.) (85~C.J(9s~C.)(149~C.) 73OF. 140F. 185OF. 210F. 300F. R LR 1.R R * K R NK * * * * * +
(continued)
*
R f * 1 NK * NR NR * * NR * UK UK NR
*
R * * * NK * NK NR * NR
*
R
* *
R SR * . NR
.
* . YR r UK NR *
Acid,
100%
100% 100% Chloride, 100%
Methanol, Methylene Morphoiine Oletc Aad,
R NR NR
*
zrK NR *
100%
R R NR R UK NR NR
Oxahc Actd, 20% Pyrtdine Sorbx Acid, 100%
*
UR
*
hR
UK UK NK
*
4K .R uK
+
hK iK \R
,,,.2.2-Tetrachloroethane. 100%
Tetrachloroerhylene. Tnl,apn.Inns. 100%
Trlchloroethylene, Tributyl Phosphate 100%
100%
JR NK IR
\K NR
UK UR
QK NR
4iK hiR
Turpentine,
VM&P Xvlene.
Naphtha, 100%
100%
Pipe 5eal Compounds Lot-Tote Lx-Tire Lx-Tire Masters Permatex Trtion AV 100% FJ, 100% E. 100% Metallic, n2. 100% TF-15. 100% Commercial Products 100% NK NK NK K K R UK *K NK CK UK NK LK VK rK \K \K \K
miscellaneous Clobber Acldlc Drain
Cleaner, Copper
100% Cleaner, 100%
LR R LK K K K R
Copperbwe Duckreal
Sealant.
100%
* *
K K IK K
*
R K IK K
.
K K IK K
Odr:
ASTM ASTM ASTM A,TM Slllcones. SlidstIr RTV 140. lOO%I lOOY, K LR R R 100% K Oil W, 100% 011 82. loo<. 011 #3, lOo%a 011 #lO 100%
. 1 * * * *
to many envwonm?nts. other than 100%
88 (GE). (GE) (GE)
* *
R R *
*
R R
RTV-106 RTV-109 Zephlran
Dwnfectant.
*
practice
* * *
Thrs
refers
speclfrcaiiy as chlorine
to 100% expocure
chlorme
(wet),
It IS recognlred environmentr,
that
WIdespread polysulfone
mdustry
IS to refer corrwon
chlorine.
In many
of these
can provide
excellent
protection
Synthetic
Resins and Polymers
149
TABLE 1.43:
POLYVINYL
CHLORIDE
DUCTS-DAYCO
PLIADUCT is a continuous, all plastic extruded strip, so shaped that when coiled, the edges interlock to form a rigid duct. It is flexible. Hand bend it to any position. It will remain in that position until bent again. Lightweight and durable, PLIADUCT has no wire or metal reinforcement. It will not corrode or oxidize. PLIADUCT is self-extinguishing. Service temperature range is -10 to 150F. Chemical Resistance Chart*
CHEMICAL TEMlEFR^rTR; 0 0 NR NR R R R NR R NR NR NR NR NR A R -R R R NR NR NR A R R A A R NR NR R NR R R R R NR NR R NR NR NR NR NR R R R R R R NR NR R R R R R R R R R R R R NR NR NR NR A R R R R R R R R R R R fl R NR R R R R R R R R R R R NR R R R R NR NR R NR CHEMICAL Butyne Diol Butyric Acid Cadmium Saks Calcium Salts Carbon Bisuffide Carbon Dioxide Carbon Monoxide Carbon Tetrachloride Carbonic Acid Castor Oil Caustic Potash Cellosolve Caustic Soda Chloracetic Acid Chloral Hydrate Chloric Acid, 200~ Chloride (water) Chlorine (dry) Chlorine, Gas (dry) Chlorine, Gas (wet) ChlorineMater Chlorobenzene Chloroform Chlorosulfonic Acid Chrome Alum Chromic Acid, 10% Chromic Acid, 5090 Citric Acid Copper Salts Corn Syrup Cottonseed Oil Cresol Cresylic Acid, 50% Crotonaldehyde Crude Oil Cyclohexanol Cyclohexanone Detergents Dextrin Dextrose Diazo Salts Digtycolic Acid Dimethylamine Dioctylphthalate Disodium Phosphate Distilled Water Esters Ethers Ethyl Acetate Ethyl Acrylate Ethyl Alcohol Ethyl Chloride Ethyl Ether
TEMPERATURE
72F 140F
CHEMICAL
Acetaldehyde
Acetic Acid, to 80% Acetic Acid, over SO% Acetic Acid, glacial Acetic Anhydride Acetone Acetylene Adipic Acid Allyl Alcohol, 96% Allyl Chloride Alum Aluminum Saks .Ammonia (gasdry) Ammonia (liquid) Ammonium Fluoride, 25% Ammonium Hydroxide Ammonium Salts (other) Amy1 Acetate Amyl Alcohol Amy1 Chloride Anilineand Salts Anthraquinonesulfonic Acid Antimony Trichlonde Aqua Regia Aromatic Hydrocarbons Arsenic Acid, 80% Arylsulfonic Acid Barium Salts Beer Beet Sugar Liquors Benzaldehyde, 10% Berualdehyde, above 10% Benzene Benzoic Acid Bismuth Carbonate Black Liquor Bleach (12% Cl) Borax Boric Acid Breeder Pellets (fish derivative) Bromic Acid Bromine, Liquid Bromine. Vapor (25%) Bromine Water Butadiene Butane Butanol, Primary Butanof, Secondary Butyl Acetate Butyl Alcohol Butyi Phenol
R R R R NR R R R R R R R R R R R R NR NR NR R NR NR R R R NR R R R R R R NR R NR NR R R R R R R NR R R NR NR NR NR R NR NR
NR NR A R NR R R NR R R R NR R R R R R NR NR NR R NR NR R NR NR R R R R NR R NR R NR NR R R R R R R NR R R NR NR NR NR R NR NR
T~~PERITuRE 72-F 140F
Ethylene Bromide Ethylene Chlorohydrin Ethylene Dichloride Ethylene Glycol Ethy!ene Oxide Fattv Acids Ferric Salts Fish Solubles Fluboric Acid Fluorine, Gas (wet) Fluorine, Gas (dry) Fluorcsilicic Acid, 25% formaldehyde Formic Acid Fructose Fruit Juices and Pulp Furfural Gallic Acid Gasoline Gasoline, High Octane Gasoline, Jet Fuel, JP4 Gasoline, Jet Fuel, JP-5 Glucose Glycerine Glycol Glycolic Acid Grapesugar Hsptane Hezane Hexanol, Tertiary Hydrobromic Acid, 20% Hydrochloric Acid, to 25% Hydrochloric Acid, over 35% i-iyfiocyanic Acid Hydrofluoric Acid, to 50% Hydrofluoric Acid, over 50% Hydrogen Hydrogen Peroxide, to 93% Hydrogen Fhosphide Hydrogen Sutfide Hydroquinone Hydroxylamine Sulfate Hypochlorene Acid iiypochlorous Acid Iron Salts Jodine Kerosene Ketones KraR Liquors &tic Acid, 25% Lard Oil Laurie Acid Lauryl Chloride
NR NR NR NR NR NR R R NR NR R R R R R R R R R R R NR A R R R R NR R R R A NR NR R R R R R R R R R R A R R R R R R R R R R R R R R R R R R NR NR R R NR R R R R R R R R R NR R NR R R R R R R NR NR R R R R R R R R fl NR fl NR R R R R
(continued)
150
Corrosion
Resistant
Materials
Handbook
TABLE
1.43:
POLYVINYL
CHLORIDE
DUCTS-DAYCO CHEMICAL
(continued)
TEMPERATURE 72-F 140F
CHEMICAL Lead Salts Linoleic Acid Linoleic Oil Linseed Oil Liquers Lithium Bromide Lubricating Oil, ASTM #1.#2. u3 Machine Oil Magnesium Salts Maleic Acid Malic Acid Manufactured Gas Mercury Salts Mercury Methyl Alcohol Methyl Chloride Methylene Chloride Methyl Ethyl Ketone Methyl Iso-butyl Ketone Methyl Sulfate Methyl Sulfuric Acid Milk Mineral Oils Mixed Acids Molasses Muriatic Acid Naphtha Naphthalene Natural Gas Ntckel Salts Nicotine Nicotine Acid Nitric Acid. Anhydrous Nitric Acid, to 66% Vitric Acid, over 68% Nitrobenzene Nitrous Oxide OCHlOl Oils and Fats Oil, Sour Crude Oleic Acid Oleum Oxalic Acid Oxygen Ozone Palmitic Acid, to 70% Palmitic Acid, over 70% Paraffin Perchlotic Acid, to 10%
TEMPERATURE
72F 140F R R R R R
CHEMICU Rayon Coagulating Rochelle Salts Sea Water Selenic Acid Sewerage Silicic Acid Silver Safts Bath
mCFm2T
R R R R R R fl R R R R R NR NR NR NR R R R R R R R R NR R R R R NR R NR NR R R R A R NR R R R R R R R
R R R R R R R R R R R R R NR NR NR NR NR R R R R R R NR R R R R NR R NR NR R R R R R NR R R R R NR R R
Perchloric Acid, to 70% Perchloric Acid, over 70% Petroleum Liquefier Phenol Phenylhydrazine Phenylhydrazine Hydrochloride Phosgene. Liquid Phosgene. Gas Phosphoric Acid, to 85% Phosphorus (yellow) Phosphorus Pentoxide phosphorus Trichloride Photographic Solutions: DK#3 Dektal Developer Kodak Fixer Kodak Short Stop Picric Acid Potassium Alum Potassium Bicarbonate Potassium Bichromate Potassium Borate Potassium Bromate Potassium Bromide Potassium Salts Potassium Hydroxide Potassium Pemanganate, 10% ,Potassium Permanganate, 15% Propane Propane Gas Propargyl Alcohol Propyl Alcohol Propylene Dichloride Plating Solutions: %rass Cadmium copper Gold lndium Lead Nickel Rhodium Silver Tin Zinc
R NR A R NR R NR R R R R NR R R R R NR R R R R R R R R R R R R R R NR R R R R R R R R R R R
NR NR R NR NR NR NR A
R R R R R R R R A R R R A A NR R R NR R R NR R R R R NR NR NR R NR NR NR NR A R R R z NR R R A R R R R R NR R
NR R R R R NR R A R R R R R R R
NR above 125.F
R R R R NR R R R R R R R R R A R
KEY. R-fiecommsndod NR-NU Recommended BLANK SPACES lodie kslr ofmfic tacommwodatcms
Soaps Sodium Acetate Salts Sodium Hydrox!de Sour Crude Oil (west Texas) StannicSalts R Stannous Salts R Starch R Blearic Acid R Btoddards Solvent NR Sulfur R Sulfur Dioxide, dry R Sulfur Dioxide, wet R Sulfur Trioxide R Sulfuric Acid, to I%% R Sulfuric Acid, over 8096 NR Sulfurous Acid R fall Oil R Tannic Acid R Tartaric Acid A fetraethyl Lead R Tetrahydrofurane NR Thionyl Chloride NR Tirpineol R Titaniumfetrachloride NR Tanning Liquors R TOluol or Toluene NR Tri Butyl Phosphate NR Trichloroethyiene NR Triethandamine R Trimethyl Propane R Trisodium Phosphate R Turpentine Fi Urea R Urine Fl Ymegar NR Vinyl Acetate R Water Acid Mine R Water Deionized R Water Demineralized R Water Distilled-water trash R Wprer Saft R Whiskey R White Liquor R Wines Xylene or Xylol NR Zinc Satts R
Synthetic Resins and Polymers TABLE 1.44: POLYVINYL CHLORIDE JACKETS AND COVERS-CEEL-CO
751
Typical Resistance Features of CEEL-TITE
300 Series PVC-UVR
and 500 Series PVC
Acetrc Acrd 20% Acetone *Alcohol, Ethyl Alumfnum Chloride Alumnum Sulfate Ammonia Gas Ammomum Chlonde Ammomum f-tydroxde A-nmontwn Sulfate *Amy1 Chlonde AntIme Barium liydroxrde Barium Sulfate Barium Sulfide Beet Sugar Lrquors *Benzene Benzorc Acrd Black Lrquor Bleach 12.5% acttve Cl, Bone Acid Bromrc Acid Calcrum Carbonate Calcrum Chlonde Calctum ttydroxrde *Carbon Btsuffide Carbon Morwxrde Carbon Telrachlorrde Carbonrc Acid Caustrc Soda Caustrc Potash Chlorrne Waler Chlonne l Chlorobenzene Chrome Ac!d 10% Chromrc Acid 30% Cttnc Acrd l Ccke Dven Gas Copper Cyanrde Copper Sulfate l Creosol l Cvclohexanol Cjclohexanone Drmethvlamrne Droctylphthalate Drsodrum Phosphate Ethers Ethylene Glycol Fatty Acrds Ferrtc Chlonde Ferrous Sulfate Fluonne (gat-wet) Fluoailicic Acid Fomaldehyae Formrc Acrd Fruit Jutces + PUID *Furfural Qasokne (refined) Glycenne Hydrochloric Acrd t-tydrocyanrc Acrd l ttydroiluorrc Acrd 50% Hydrogen Sulfide (dry) Hydroqurnone Hypochlorous Acid lodlne Trncture Kerosene Magneswm Chlorrde Malerc Acrd Metnyl Alcohol *Methyl Ethyl Ketcne *Methyl Chloride Mrxed Acrds Nickel Chlonde Nrckei Sulfate
l Nrtnc Acrd Anhydrous

Nttnc Acrd, 10% Nrtrtc Acrd. 63% Nitrous Oxrde 011sand Fats Olerc Acrd Oleum Cxalrc Acrd Palmrtrc Acrd, 10% Perchlonc Acid, 10% ?eFe;;um 011s (sour) Phosgene Gas Phosphonc Acrd, 25% Phospnorrc Acid. 50% *Phosphorous Trichlonde Phthalrc Anhydrrde Plattng Soltirons Potassrum Chlonde Potassum Cyanide Potasscum Drchromate &w;ss; Hydroxide Permanganate. 10% Propy Alcohol *Propylene Drchlonde Sea Water Stlver Cyanrde Silver Platrng Solutron Srlver Nrtrate Sodrum Brsulffte Sodrum Chlonde Sodrum Cyantde Sodturn Ferrocyanrde Sodrum ttydroxrde Sodrum l-typcchlonte, 125% Sodrum Sulfate Sodrum Sulfite Sodium Throsulfate Sour Crude 011 Stannrc Chlonde Steanc Acrd Stannous Chlonde Sulfur Sulfur Dfoxide (dry) Sulfur Droxfde (wet) Sulfunc Acid, Ib% Sulfuric Acrd. 70% Sulfurous Acid Tannrc Aced Tartanc Acrd Tetrahydrofuran l Toluene l Tnchloroethylene Triethanolamine Trisodtum Phosphate Turpentine Urea Vinegar Vl$ter (acrd mane water) Whtskey and Whrte liquor Xylene Zfnc Chloride Zrnc Sulfate S-Satrsfactory U-Unsatisfactory Test Method ASTM -
D - 1784
Satrsfactory for use under atmcephenc condrtrons
752
TABLE
1.45:
POLYVINYL
CHLORIDE
LINERS-FABRIC0
CHEMICAL
RESISTANCE CHART
R-Recommended RT-Room Temp.
IN0 Chemical Reagent
ANIC
ACIDS
INORGANIC Id .t P. 26990
SAL
- co
&
DUNDS
(Contd.1 at
he.
x;i 0
Chemical
Reagent
:onc.
0
Material recommended max. Costat twnp. BORN R-130 R-130 R-130 R-130 R.130 R-130 R-110 R.l10 R.l10 R.l10 651 R-150 R-150 R-150 R-150 R-150 R-150 R-130 R-130 R.130 R-130 R-110 R-RT R-130 R-140 R-140 R.140 R.140 R.130 R-130 R.150 R-110 R-110 R.150 R-150 R-150 R-150 R-130 R-150 R-130 R-150 R-150 R.130 R-150 R-140 R.150 R-150 R-150 R.150 R-150 R-150 R.150 R-150 R-150 R-150 R-150 R-150 R-150 R-150
2699 R-RT R-RT R-AT R-RT R-RT R-RT R-RT R-RT R.RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R.RT R-AT R-RI R-RT R.RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-AT R-AT R-RT R-RT R-RT R-RT R.RT R-RT R-RF R-RT 9.RT 7.RT =I-RT 9.RT
@I
Aqua
Regaa R-130 10 30 R.120 R-l 10 30 20 20 40 30 Acld 75 10 40 R-100 R-RT R-100 R-110 R-130 Aad Acld Trloxade Acjd Acid @ Acad@ Acad
R-RT R-130 R-l 10 R-130 R.140 R-140 R-130 R-130 R-RT R-130 R-110 R-100 R-110 R-150 R-RT R-RT R-l 10 R-100 R-RT R-RT R-RT R-120
Chrome Copper Copper Copper Cuprous Dlsodwm Fernc Ferrous Ferrous Hydrogen Hydrogen Hydrogen
Alum Chloride Nitrate Sulfate Chloride Phosphate
6or1c Acld Brom~c Acid Carbonic Chromac Chromium, Hydrobromlc Hydrochlonc Hydrochlortc Hvdwluonc Nnrlc Acid Nttrwz Ac,d
PhosPhOrlC
Fluor~l~c~c Acid
Fcrr~c Chloride NItrate Chlorade Sulfate PeroxIde@ Peroxnde@ Sultade Carbonate Chlorade Nitrate Sulfate Chloride NItrate 3 10
R-l 10 R-RT R-l 10 R.120 R-120 R-120 R-120 R-110 R-110 R-130 R-100 R.lOO R.130 R-130 R-130 R.130 R-110 R-130 R.l10 R-130 R-130 R.130 R-130 R-120 R-130 R-130 R-130 R-130 R-130 R-130 R-130 R.130 R-130 R.130 4.130 q-130 q-130 q-130
Magnestum Magnesum Magneswm Magnerwm Mercuric Mercurous Mercurv Phosphorus Phosphorus Potasr~um
Sulfuric Sulturlc Sulfurous Mw.ed
Acld Acld Acid Aclds for 7%HF
Sta~nlesr Steel plcklmg 20% HN03 R.140
(Yellow1 PentoxIde B+carbonate Carbonate Chloride Chromate Cyamde Nitrate Perchlorate Permanganate Sulfate
INORGANIC
ALKALIES d
at
@
Potasswm Potassium Potarswm Potasswn Potaswm Potaswm Potasrlum Potassium
L
2699 ~ R-RT R-100
INORGANI(
4LT.S :onc.
Chemical
Reagent
:DMPOl JNI >s &tori al r ecommendad tenw. nwx I. E,,nrtmt BORN R.130 R.120 -IR-150 R-140 R-150 R.150 R-150 R-130 R-150 R-150 R-150 R-150 R-150 R-150 R-15P R-150 R-150 R-150 R-150 R-150
Salver Nitrate at Sodun Sodum Sodwm Sodium Bicarbonate Bwltlte Borate Carbonate Chlorate Chlorado Dachromate Ferrocyanlda Fluoride Hypochlorite Nwate Sulfete Sulfite Phosphate
0
Alunvnum Aluminum Alummum Ammomum Ammomum Ammonium Ammonwm Ammonwm Antwnony 6srlum Barurn Bismuth Calcium Calcium Calcwn Calcrum Calcaum Calcwm Chloride Fluoride Sulfate Carbonate Chloride Fluorldc Nnratt Sulfide Chlonde 20 50
2699@ R-RT R.RT R-RT R.RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R-RT R.RT R-RT R-RT R-RT R-RT
Sodium Sodtum Sodium Sodum Sodium Sodium Sodium Sodium Sodium Trisodium
R-130 R-130 R-130 R-130 R-130 R-130 R-130 R-130 R-130 R-130 R-1JO R-130 R-130 R-130 R-130 R-130
csrhvlate Sulfate Carbonate Btsulfatc Carbonate Chloride Hyoochlorlte NItrate Sulfate
Zinc Chlonde Zinc Sulfate
(continued)
Synthetic
Resins and Polymers
153
TABLE 1.45: PoLYvlNYL

PLATING I
CHLORHDE LINERS-FABRIC0
SOLUTIONS 1 Material recqmmded at
(continued
ORGANIC COh WNC IContd.) Material recomm en ded at m;r: K. CO,,P, te mp. BORN NR NR R.120 R-l 20 NR 00 NR NR R-100 R-100 @ Ketone 00 NR NR NR NR R-RT R.lOO NR NR R-100 R-100 R-100 NR NR R-100 jrocarbonr r Alcohol@ 661 NR NR R-150 R-150 NR NR NR R-100 R-100 rvR NR NR NR R-RT R-110 NR NR R-RT R-110 R.l10 R.130 NR NR BOEE
Chemiul
Reagent
rJnc.?i @I
Furfural Gallx Acid GhXqse Glvcertne Hvdroqulnone Note: 3/32 & l/8 PVCType 651 are the materials abuse drctates this. of choice for lswropvl Lactic
plating and rinse tanks. The combinatton

sol~t~qn strength and mechamcal Electroless Solutions
of temperature.
Acid Acid Alcohol Ethvl
I
29L9
Lead Acetate Mallc Methyl Methyl
8 mil PVC Type (dIsposableI
I
led at RP. BOEE
Naphthalene Nltrobenrene Olefc Acid Oxalic Phenol Acid Acid Acetate Acetare Acid
ORGANIC
COMPOUNDS
Chemical
Reagent
Phev)hvdrazle Acetaldehvde Acetic Acetic Acetlc Acetone Alkvl Alkvl Amvl Amvl Amvl Allle Benzene 8enro1c Eutvl Butvl Carbon Carbon Acid Alcohol Phenol Acid Dwlfrde Tetrachlor!de Acid Alcohol Chloride Alcohol Acetate Chloride Acid Acid AnhydrIde 100 80 10 NR NR R-130 NR NR NR NR NR NR NR NR NR R-100 NR NR NR NR NR NR NR NR Acid NR R-110 NR NR R-130 NR NR NR NR 100 NR NR NR NR 40 R-RT NR NR NR R.130 NR NR NR NR NR NR NR NR NR R-110 NR NR NR NR NR NR NR NR NR R-130 NR NR R.150 NR NR NR NR NR NR NR NR R-UT NR Wet strength Kvmene Kvmene 557 709 IR l-95 resins: Dtrtllled Fert~llrer Fruit Grape Dakjre Peanut Water Solutions l-150 I-RT Chemrcal Reagent 0C. 9 0 IORN MIS< LANf R.130 Polvv~nvl Sodwm Stearlc
Tann~c Acid Tetrahvdrofuran Trlethanolamlne Urea Crude 011. fuel 011s and other allphatx h use wth PVC Type 3134. an 011 res~sta~
R-130 are s#t ab le for
IS COMPOUNI Matenal r max. c, 651 R.150 R-RT R-150 R-110 R.150 R-100 R.RT ed ,P. 2699 @
Butvr~c
Chloracetlc Chloroform Chlorosulfonw Cltrlc Acid
Chlorobenzene
Juicer Sugar No. 31 Solut~or I-RT IR l-130 011
Mustard Photographic R-RT NR R-150
Cvclohexanol Cvclohexanone DeXtrl Dlbutvlphthalate Dlethvl Ethyl Ethyl Ethyl Ethyl Ethyl Formtc Ketone Acetate Alcohol@ Bromide Chloride Ether Acid Dimethvlsmine
Sea Water sugar Salutlo VlBgH Water Yeast (Potable) Wine (non-fortifIedI
R-150 R-140 R-150 R-150 A-RT R-150
R-95 R.70 R-95 NR
Formaldehvde
Perez Rcs~ns
The above ratjngs are based on the consideration of chemical resistance only. Potable water will not attack flexible vinyls, but to store it safely from the standpoint of toxicity, a specially formulated vinyl must be used. This would also apply to any material that is intended for human consumption. In this latter category, the possibility of the migration of very small amounts of plasticizer having an effect on the taste of the stored liquid should be considered. @Hydrochloric Acid must not be contaminated with organic chlorides (500 ppm max. concentration) @Applies only to inhibited hydrogen peroxide. Unrnhibited 10% H202 will not deteriorate lining, but lining will contaminate Solution. 02699 material is specially formulated for pit 81 pond lining applicationsand is generally serviceable after installation between -20 deg. and +150 deg. F. It has a bacteriostat which resists attack by soil microorganisms. Some of the recommended uses for particular compounds are shown above, however specific applrcations should be checked with the factory, particularly those containing mixtures of the compounds mentioned above. @Concentrations of 10% or less are suitable with all vinyls listed at right for non-food use. @All concentrations left blank are 100% or Saturated solution.
154
Corrosion
Resistant
Materials
Handbook
TABLE
1.46:
POLYVINYL
CHLORIDE
PIPE AND FITTINGS-THERMOPLASTIC
PROCESSES
Chemical Resistance of EXCELON
R-4000 Pipe and Fittings

LUBRICATING OIL, ASTM X3 METHYL SULFATE hlAPTU& NITRIC ACID. 10% NITRIC ACID. 30% NITRIC ACID, 60% PHENYLDHYDRAZINE HYDROCHLORIDE PHOSPHORUS (YELLOW) PHOSPHORUS PENTRIOXIDE POTASSIUM PERMANGANATE. 25% @ 125F PROPARGYL ALCOHOL PROPYL ALCOHOL TETRAETHYLLEAD TRIETHANOLAMINE TRIMETHYL PROPANE
.I . . .I.
RECOMMENDED (tested72F. 140F) @

ACETIC ACID. 10% ACETIC ACID. 20% ACETYLENE ADIPIC ACID ALUM ALUMINUM ALUM ALUMINUM CHLORIDE ALUMINUM FLUORIDE ALUMINUM HYDROXIDE ALUMINUM OXYCHLORIDF ALUMINUM NITRATE ALUMINUM SULFATE AMMONIA (GAS-DRY) AMMONIUM ACETATE AMMONIUM ALUM AMMONIUM BIFLUORIDE AMMONIUM CARBONATE AMMONIUM CHLORIDE AMMONIUM HYDROXIDE AMMONIUM HYDROXIDE. 10% AMMONIUM HYDROXIDE, 28% AMMONIUM METAPHOSPHATE AMMONIUM NITRATE AMMONIUM PERSULFATE AMMONIUM PHOSPHATE AMMONIUM SULFATE AMMONIUM SULFIDE AMMONIUM THIOCYANATE AN~~H;AOUINONESULFONlC
ANTIMmd
COPPER NITRATE CORN SYRUP c&PER SULFATE COTTONSEED OIL CUPRIC FLUORIDE CUPRIC SULFATE CUPROUS CHLORIDE DETERGENTS DEXTRIN DEXTROSE DIAZO SALTS DIGLYCOLIC ACID DISODIUM PHOSPHATE DISTILLED WATER ETHYLENE GLYCOL FATTY ACIDS FERRICCHLORIDE FERRIC HYDROXIDE FERRIC NITRATE FERRIC SULFATE FERROUS CHLORIDE FERROUS SULFATE FISH SOLUBLES FLUOBORIC ACID FLUORINE GAS (WET) FLUOROSILICIC ACID, 25% FRUCTOSE FRUIT JUICES 8 PULP FREON 11 FREON 12 GALLIC ACID GASOLINE. JET FUEL IP.l
METHYL ALCOHOL METHYL SULFURIC MILK MOLASSES MURIATIC ACID NATURAL GAS NICKELCHLORIDE NICKEL NITRATE NICKEL SULPHATE NICOTINE NICOTINE ACID NITROUSOXIDE OILS 8 FATS OIL, SOUR CRUDE OLEIC ACID CI$$lC$CID
ACID
k.i
._.. ._
GLUCOSE GLYCERINE GLYCOL GLYCOLIC ACID GRAPESUGAR HYDROBROMIC ACID. H:gOCHLORIC ACID. 10. 30. 35% HYDROCYANIC ACID HYDROGEN HYDROGEN PEROXIDE, 30% 50% H::;OGEN SULFIDE HYDROQUINONE HYDROXYMMINE SULFATE HYPOCHLORENE ACID HYPOCHLOROUS ACID KEROSENE KRAFT LIOUORS LACTIC ACID. 25% LAURIC ACID LEAD ACETATE LEAD CHLORIDE LEAD SULFATE LINOLEIC ACID LINSEED OIL LITHIUM BROMIDE LU[c;;A;;NG OIL ASTM C2 MACHINE OIL MAGNESIUM CARBONATE MAGNESIUM CHLORIDE MAGNESIUM HYDROXIDE MAGNESIUM NITRATE MAGNESIUM SULFATE MALEIC ACID MALIC ACID MANUFACTUREDGAS MERCURIC CHLORIDE MERCURIC CYANIDE MERCUROUS NITRATE MERCURY 7OY mm h?mperature
TRICHLORIDE AkSENlC ACID, 80% BARIUM CARBONATE BARIUM CHLORIDE BARIUM HYDROXIDE BARIUM SULFATE i;,bM SULFIDE
-_-.
BEET SUGAR LIQUORS BENZOIC ACID BISMUTH CARBONATE BLACK LIOUOR BLEACH112%CLI BORAX BORIC ACID BREEDERS PELLETS ,d~;p,fc~~ CADMIUM CYANIDE CALCIUM BISULFIDE CALCIUM BISULFITE CALCIUM CARBONATE CALCIUM CHLORIDE CALCIUM HYDROXIDE CALCIUM HYPOCHLORITE CALCIUM NITRATE CALCIUM SULPHATE CARBON DIOXIDE CARBON MONOXIDE CARBONIC ACID CASTOR OIL CAUSTIC POTASH CAUSTIC SODA CHLORAL HYDRATE CHLORIC ACID. 20% CHLORIDE (WATER) CHLORINE WATER CHROME ALUM CITRIC ACID COPPER CARBONATE COPPER CHLORIDE COPPERCYANIDE COPPER FLUORIDE Unless specified,
OZONE PALMITRIC ACID, 10% PERCHLORIC ACID. 10% PETROLEUM LIOUIFIER PHOSGENE. GAS PHOSPHORIC ACID. 10% PHOSPHORIC ACID. 25% PHOSPHORIC ACID. 75% PHOSPHORIC ACID, 85% PHOTO SOLUTIONS DK #3 DEKTAL DEVELOPER KODAK FIXER KODAK SHORT STOP POTASSIUM ALUM POTASSIUM BICARBONATE POTASSIUM BICHROMATE POTASSIUM BORATE POTASSIUM BROMATE POTASSIUM BROMIDE POTASSIUM CARBONATE POTASSIUM CHROMATE POTASSIUM CHLORATE POTASSIUM CHLORIDE POTASSIUM CYANIDE POTASSIUM DICHROMATE POTASSIUM FERRICYANIDE POTASSIUM FERROCYANIDE POTASSIUM FLUORIDE POTASSIUM HYDROXIDE POTASSIUM NITRATE POTASSIUM PERBORATE POTASSIUM PERCHLORATE POTASSIUM PERMANGANATE. 1046 POTASSIUM SULFATE PROPANE PROPANE GAS PLATING SOLUTIONS BRASS CADMIUM :zlER INDIUM LEAD NICKEL RHODIUM SILVER TIN ZINC RAYON COAGULATING BATH SEA WATER SEWERAGE SILICIC ACID SILVER ZYANIDE SILVER NITRATE SILVER PLATING SOLUTION :A:;: SULFATE
SODIUM ACETATE SODIUM ALUM SODIUM BENZOATE SODIUM BICARBONATE SODIUM BISULFATE SODIUM BISULFITE SODIUM BROMIDE SODIUM CARBONATE SODIUM CHLORATE SODIUM CHLORIDE SODIUM CYANIDE SODIUM DICHROMATE SODIUM FERRICYANIDE SODIUM FERROCYANIDE SODIUM FLOURIDE SODIUM HYDROXIDE. 10% 30% 50% SODIUM HYPOCHLORITE SODIUM NITRATE SODIUM SUl~rlTE SODIUM SilLI IDE SODIUM SULFITE SOUR CRUDE OIL (WEST TEXAS) STANNICCHLORIDE STANNOUS CHLORIDE STARCH STEARIC ACID SULFUR SULFUR DIOXIDE. (DRY) SULFUR TRIOXIDE SULFURIC ACID 3.
10%
ETHYLENE DICHLORIDE ETHYLENE OXIDE FLUORINE. GAS FURFURAL HEXANE HYDROFLUORIC ACID. _.
0
IOZE
20% 33. 50% SL?&ROUS ACID TAN OIL TANNIC ACID TARTARIC ACID TANNING LIOUORS TRISODIUM PHOSPHATE UREA URINE VINEGAR WATER. ACID MINE WATER. DEIONIZED WATER, DEMINERALIZED WATER, DISTILLED WATER, FRESH WATER, SALT WHISKEY WHITE LIOUOR WINES ZINC CHLORIDE ZINC SULFATE ZINC NITRATE
::aTuooNAEss METHYL CHLORIDE METHYLENE CHLORIDE METHYL ETHYL KETONE METHYL ISO-BUlYL KETONE NAPHTHALENE NITRIC ACID, ANHYDROUS NITRIC ACID. 68% NITROBENZENE OLEUM PALMITRIC ACID, 7090 PERACETIC ACID. 40% PERCHLORIC ACID, 15. RECOMMENDEDPERCHLORICACID. 700. PHENYLrlYDRAZINE ACETALDEHYDE PHOSGENE. LIOUID ACETIC ACID. PURE PHOSPHORUS ACETIC ACID. 80% TRICHLORIDE ACETIC ACID. GLACIAL PICRICACID ACETIC ANHYDRIDE PROPYLENE ACETONE DICHLORIDE ALLYL ALCOHOL, 96% STODDARDS SOLVENT ALLYL CHLORIDE SULFUR DIOXIDE. (WET) AMMONIA (LIQUID) SULFURIC ACID. AMMONIUM FLUORIDE, 60% 25% 85% AMYL ACETATE 940. AMYL ALCOHOL 95% AMYLCHLORIDE TETRAHYDROFURANE ANILINE THIONYL CHLORIDE ANILINE TITANIUM CHLOROHYDRATE TETRACHLORIDE ANILINE TOLUOL OR TOLUENE HYDROCHLORIDE TRI BUTYL PHOSPHATE AQUA REGIA TRICWLOROETHYLENE AROMATIC TUHPENTINE HYDROCARBONS VINYL ACETATE BENZALDEHYDE. 10% XYLENE OR XYLOL BENZALDEHYDE.ABOVE ._.
NOT
I%
RECOMMENDED
(@72F) ANTHRAOUINONE ARYLSUFONlC ACID BUTYL ALCOHOL BUTYL PHENOL CELLOSOLVE CHLOROACETIC ACID CRESYLICACID, 50% CRUDE OIL ETHYL ALCOHOL FORMALDEHYDE FORMIC ACID GASOLINE HEPTANE HEXANOL. TERTIARY HYDROFLUORIC ACID. 46% LINOLEIC OIL
BENZENE BROMINE, LIOUID BROMINE WATER BUTADIENE BUTANE BUTANOL. PRIMARY BUTANOL.SECONDARY BUTYL ACETATE BUTYNE DIOL BUTYRIC ACID CARBON BISULFIDE CA.RI-mN TETRACHLORIDE CHLORINE (DRY) CHLORINE. GAS CHLORINE GAS (WET) CHLOROBENZENE CHLOROFORM CHROMIC ACID, 10% &l;g;c ACID, 50%
_. __..
CROTONALDEHYDE CYCLOHEXANOL CYCLOHEXANONE DIMETHYLAMINE DIOCTYLPHTHALATE ESTERS ETHERS ETHYL ACETATE ETHYL ACRYLATE ETHYL CHLORIDE ETHYL ETHER ETHYLENE BROMIDE ETHYLENE CHLOROHYDRIN
deta 6 basedon
155
TABLE 1.47: POLYVINYL
CHLORIDE TANK LINERS-PEABODY

a wide variety
TECTANK
of chemicals. A partial guide to chemicals
TECLINE TL990 liners are suitable for the storage of which TECLINE TL990 liner will safely store includes:
Acetic Acid (10%) Ammonium Hydroxide (30%) Ammonium Phosphate Ammonium Sulfate Antifreeze (Ethylene Glycol) Animal Oil Boric Acid Bromic Acid Calcium Chloride Solutions* Calcium Hydroxide Chlorine Solution (20%) Chromic Acid (10%) Clorox Crude Oil Diesel Fuel Ethyl Alcohol Fertilizer Solutions*
l l
Gasoline* Glycerine Hydraulic Fluid Hydrochloric Acid (60%) Hydrofluosilicic Acid (30%) Hydrogen Peroxide (30%) Isopropyl Alcohol Jet Fuel (JP-4) Kerosene Magnesium Chloride Magnesium Hydroxide Methyl Alcohol Mineral Spirits Naptha Nitric Acid Phenol Formaldehyde Phosphoric Acid (75%)
l l
Potassium Chloride* Potassium Sulphate Salt Water* Sea Water Sodium Acetate Solution Sodium Bisulfite Solution Sodium Hydroxide (60%) Sulphuric Acid (40%) Tannic Acid (50%) Turpentine Urea* Zinc Chloride*
May be stored in Peabody TecTanks TherrnoThane 7000, factorycoated bolted tanks.
TABLE 1.48: POLYVINYLIDENE

FORAFLON@
FLUORIDE-RILSAN
However, solutions.
in general resists mineral acids, bases, saline solutions, oxidizing agents, and halogens. it is attacked by concentrated hot sulphuric acid or nitric acid and very concentrated alkaline resists alcohols, chlorinated solvents, aliphatic and aromatic hydrocarbons and crude oil.
FORAFLON
It swells in certain dimethylacetamide,
polar solvents like ketones and esters and dissolves in aprotic solvents like dimethylformamide and N methylpyrrolidone. It is also attacked by hot amines. of FORAFLONQD immersed under stress
As an indication, the following table shows the good resistance in some particularly aggressive reagents.
Test pieces are cut according to ASTM D 1708 from an extruded plate 0.7 mm thick, and either unbent or bent by the device recommended in standard ASTM D 1693: the.y are immersed in a reagent at the temperature indicated. The tensile properties are checked periodically.
For the reagents indicated, the yield strength of both bent and unbent test pieces varied by at least 10% after one year, as compared with that of a control left in the air at the same temperature.
Reagents Concentrated hydrochloric acid, 36% Sulphuric acid 80% Nitric acid 32% Chromatosulphuric mixture (CrO3, 50%, H2SOq. 15%, H20, 35%) Acetrc acrd 50% Caustic soda 45% Sodium carbonate 40% Ethylene glycol, pure Perchloroethylene Crude 011 Temperature 130 :: 90 130 :: 90 130 90 90 130 C
156
TABLE
1.49:
TETRAFLUOROETHYLENE
HOSE-EVERFLEX
PRODUCTS
PARTIAL
LIST OF CHEMICALS
AND MATERIALS
COMPATIBLE
WITH TEFLON
HOSE
Teflon@ TFE fluorocarbon resin is so broadly chemically resistant that factors such as temperature, pressure and their fluctuations are usually the primary influence on the serviceability of this material in a specific application. Solvents and gases known to require special consideration due to these factors are indicated by asterisk(*). Also, selection of material for fittings is influenced by reagent, concentration, duration of exposure and other considerations. For guidance only, our preliminary recommendations for coupling material are indicated by letter following the reagent, thus: (B) brass; (Cl carbon steel; (S) stainless steel; (M) monel.
Teflon is attacked bv only two classes of chemiulr: al Molten alkali metals rueh as sodium 11 potassun bi Fluorahemicals rush as chlorine tnflwride ICIF,
._-
I and oxggnn
157
TABLE 1.50: TETRAFLUOROETHYLENE
RESINS-DUPONT
Table I-Tvoical
Abietic acid Acetic acid Acetic anhydride Acetone Acetophenone Acrylic anhydride Ally1 acetate Ally1 methacrylate Aluminum chloride Ammonia, liquid Ammonium chloride Aniline Benzonitrile Benzoyl chloride Benzyl alcohol Borax Boric acid Bromine n-Butyl amine Butyl acetate Butyl methacrylate Calcium chloride Carbon disulfide
Chemicals with Which TEFLON Resins Are Comoatiblel

Ferric chloride Ferric phosphate Fluoronaphthalene Fluoronitrobenzene Formaldehyde Formic acid Furane Gasoline Hexachloroethane Hexane Hydrazine Hydrochloric acid Hydrofluoric acid Hydrogen peroxide Lead Magnesium chloride Mercury Methyl ethyl ketone Methactylic acid Methanol Methyl methactylate Naphthalene Naphthols Nitric acid
points swelling. of the liquids Note Values Itsted.
Cetane Chlorine Chloroform Chlorosulfonic acid Chromic acid Cyclohexane Cyclohexanone Dibutyl phthalate Dibutyl sebacate Diethyl carbonate Dimethyl ether Dimethyl formamide Di-isobutyl adipate Dimethylformamide Dimethyl hydrazine, unsymmetrical Dioxane Ethyl acetate Ethyl alcohol Ethyl ether Ethyl hexoate Ethylene bromide Ethylene glycol
Nitrobenzene 2-Nitro-butanol Nitromethane Nitrogen tetroxide P-Nitro-2-methyl propanol n-Octadecyl alcohol Oils, animal and vegetable Ozone Perchlorethylene Pentachlorobenzamide Perfluoroxylene Phenol Phosphoric acid Phosphorus pentachloride Phthalic acid Pinene Piperidene Polyacrylonitrile Potassium acetate
Potassium hydroxide Potassium permanganate Pyridine Soap and detergents Sodium hydroxide Sodium hypochlorite Sodium peroxide Solvents, aliphatic and aromatic2 Stannous chloride Sulfur Sulfuric acid Tetrabromoethane Tetrachloroethylene Trichloroacetic acid Trichlorethylene Tricresyl phosphate Triethanolamine Vinyl methacrylate Water Xylene Zinc chloride
1. Based on expenmenls
with TEFLON 2. Some resns. halogenated
conducted
up lo the bolllng moderate
Absence of a speclflc chemical does not mean that 11 lncompatlble is

only and not for speckatlon purposes.
solvents
may cause
are averages
Table II-Exposure of TEFLON Resins to Acids and Bases. Exposure

Reagent Hydrochloricacid 10% Temp., C (F) 25 (77) 50 (122) 70 (158) 100 (212) 200 (392) 25 (77) 70 (158) Exp ,s;re Weight Increp&
12 mo. 12 mo. 8 hr. 8 hr. 12 mo. 12 mo.
0 : 0 0 E.1
20%
Nitric acid 10%
Sulfuric
acid 30% 25 (77) 70 (158) 100 (212) 200 (392) 12 mo. 8 hr. 8 hr. : 0 0.1
Sodium hydroxide
10% 50%
25 (77) 70 (158) 100 (212)

25 (77) 70 (158)
12 mo. 12 mo. 8 hr.

12 mo. 12 mo.
0 0.1 0
0 0.1
Ammonium hydroxide
10%
(continued)
158
TABLE 1.50: TETRAFLUOROETHYLENE
RESINS-DU
PONT (continued)
Table Ill-Exposure of TEFLON Resins to Solvents. Exposure $rng;; Solvent Acetone 25 (77) 50 (122) 70 (158) 78 (172) loo (212) 200 (392) 25 50 70 loo 200 25 50 70 loo (77) (122) (158) (212) (392) (77) (122) (158) (212) 12 mo. 12 mo. 2 wk. 96 hr. 8 hr. 8 hr. 12 mo. 12 mo. 2 wk. 8 hr. 8 hr. 12 mo. 12 mo. 2 wk. 8 hr. 8 hr. 12 mo. 12 mo. 2 wk. 12 mo. 12 mo. 2 wk. 0.30 0.4 0 0.5 0.6 1.0 0.6 1.6 ::95 3.7 0 0 0
0.1
Table II and Table Ill Notes: Many of the laboratory evaluations were run at the boiling point of the chemicals listed. This should not be considered the upper use temperature for TEFLON resins in such environments, which can be considerably higher. l These are essentially equilibrium test values: additional exposure times would not increase the values significantly. l Weight changes less than 0.2% are not considered to be experimentally significant. l Values are test averages only and are not for specification purpfxes. l Tests at over the boiling point of the reagent were in an enclosed chamber, hence at its vapor pressure.
l
Exyzre
InCZF,
Benzene
Carbon tetrachloride
Ethyl alcohol (95%)
200(392)
0.3 0.5 0.70 0.7 0.3 0.6 0.6
Ethyl acetate
25 (77) 50 (122) 70 (158) 25 (77) 50 (122) 70 (158)
Toluene
Table IV-Absorption of Representative fluorocarbon resins(l)
Liquids In TEFLON@ 160 FEP and TEFLON@ 350 PFA
168 Hour Exposures to Solventsat Their Boiling Pointsm Range of Temperature Weight Gains C F % __ 185 (365) 0.3-0.4 Aniline 201 (394) 0.6-0.8 Acetophenone 179 (354) 0.4-0.5 Benzaldehyde 204 (400) 0.3-0.4 Benzyl Alcohol 78 (172) 0.3-0.4 n-Butyl Amine 78 (172) 2.3-2.4 Carbon Tetrachloride 190 (372) 0.1-0.2 Dimethyl Sulfoxide 1.2(3) 47 (117) Freon@113 99 (210) 0.7-0.8 Iso-Octane 210 (410) 0.7-0.9 Nitrobenzene 121 (250) 2.0-2.3 Perchloroethylene 68 (154) 1.7-2.7 Sulfuryl Chloride 110 (230) 0.7-0.8 Toluene 200()(392) 1.8-2.0 Tri-Butyl Phosphate
166 Hour Exposure to Acidic Reagent Temperature C F Bromine (anhyd.) Chlorine (anhyd.) Chlorsulfonic Acid Chromic Acid, 50% Ferric Chloride, 25% Hydrochloric Acid, 37% Phosphoric Acid (Cone) Zinc Chloride, 25%
Table IV Notes: (1) No significant differences between FEP and PFA resins in these tests. (2) These are essentially equilibrium values; additional exposure times would not increase the values significantly. (3) PFA data only. (4) Not boiling. (5) Values are test averages only and are not for specification purposes.
Range of Weight Gains %

0.5(3' 0.5-0.6 0.7-0.8 0.00-0.01 0.00-0.01 0.00-0.03 0.00-0.01 0.00-0.03
22 120 150 120 100 120 100 100
(-5) (248) (302) (248) (212) (248) (212) (212)
TABLE 1.51:
VINYL
ESTER RESINS-INTERPLASTIC
Maximum
CORP.
Temperature OF Concentration Chemical
Ammonium Slcarbonate Slsultlte Carbonate Chlorlda Citrate Fluoride Hydroxlda
Chemical Resistance Co-Rezyn3 Vinyl Ester Resins*

Concentratlor Chemical A
Acataldehyde Acetlc Acid All O-25 25-50 50-75 Acetlc Anhydrlde ACetOm Acrylic Acid All 100 25 All All 10 100 Alcohol, teopropyl 10 100 Alcohol, Methyl 10 100 Atcohol, Alcohol, Methyl lrobutyl Sutyl 10 10 All All Chloride Fluorlde Hydroxtde Nltrate Poteulum Aqueous Gas Ltquld Acetate 65 Sulfate All All All All All O-20
% by Weigh
1
1 t \IE \IE
Recommended
Maximum VE 8100 VE 8300

150 150 150 210 150 150 180 150 150 100 180 180 210 210 NR NR 150 210 180
Recommended
Temperature
OF
8100 8300
VE 8440
VE 8710
VE 8520
% by Weigh
O-50 All All All All All 5 IO
VE 8440
150 150 150 210 150 150 180 150 150 100 180 180 210 210 NR NR 150 210 180
VE 8710
150 150 150 210 150 150 180 180 180 150 180 180 210 210 NR NR 180 210 180
VE 8520
150 150 150 210 150 150 150 150 150 100 180 180 210 210 NR NR 150 210
NR 210 180 150 NR NR 100 NR 100 156 SO 156 100 150 NR 150 150 NR 210 210 80 180 160 210 140 100 NR 80
NR 210 180 150 NR NR 100 NR 160 150 SO 150 100 150 NR 150 150 NR 210 210 80 180 160 210 140 100 NR 60 150 150 NR 220 210 80 200 180 220 140 180 NR 60 100 NR 120 150 100 150 120 150 210 210 180
NR 150 150
Ammonium Ammonium Ammonium Ammonium
NR NR
Ammonium Ammonium
AcfyIonltrlle Alcohd. Alcohol, Butyt Ethyl
NR
20 29
150
Ammonium Ammonium
Nitrate Persulfate Phosphate Sulfate
All All 65 All 100 All
t50
Ammonium Ammonium Amyl Acetate
NR 150 150 NR 210 210 80 150 150 210 140 100 NR
Anlllne Anlllne Anlllne Hydrochloride Sulfate Acid
All All All
Secondary
Ally1 Chloride Alum Aluminum Aluminum Aluminum Aluminum Atumlnum Ammonia. Ammonia, Ammonia, Ammonium
Arsenlous
0
0-Benroyl Barium Earlurn Barlom Sarlum Barium Earlum Seer Benzolc Acid All All All All O-IQ All All 780 210 210 210 150 210 180 120 180 210 210 210 150 210 180 180 210 210 210 180 210 180 210 210 210 15r 210 180
Acetate Carbonate Chloride Hydroxlda Sulfate Sulfide
(continued)
TABLE
1.51:
VINYL
ESTER
RESINS-INTERPLASTIC CORP. (continued) Maximum Recommended Temperature OF VE 8100 VE 0300

NR 210 VE8440 VE
I
Concentratio Chemical
Csdmlum Cysnlde Plrtlng 3% Cadmium Oxide 10% Sodium Cyanide 1% Caustic Soda Calcium Csiclum Calcium Calcium Calcium Cslclum Blsulflte Carbonate Chlorate Chloride Hydroxtde Hypochlorlte Nltrate Sulfate Sulfite
Maximum Recommended Temperature OF IE 8100 IE 8300

180 VE 8440
Concentratio Chemical % by Weigh

100
8710
NR 210 210 210 1.90
VE 8520
NR
% by Weigh
Sotn.:
VE 8710
200
VE 8520 9
senrene
5% Benzene Benzene
NR 210 210 210 NR NR
180
in Kerosene
Acid All All 100 100
Sullonic
210 210 NR NR
210 210 NR NR
All All All All All All All All All All 100
180 180 210 210 180 160 210 210 180 180 180 210 NR 210
180 180 210 210 180 180 210 210 180 180 180 210 NR 210 100 150 100 210 150
180 180 210 210 210 180 210 210 180 180 210 240 NR 240 150 150 100 210 150
180 180 210 210 180 160 210 210 180 180 180 210 NR 210
Bcnzolc Acid Benzyl Alcohol Benzyl Chloride Black Liquor Recovery, (hrrnace gasses)
325
32.5
350
Brass PIstIng 3% 6% 1% 3%
Solution:
180
180
180
Calcium Calcium Calcium
Copper CyanMe Sodium Cyanide Zinc CyanIda Sod& Carbonate Llquld NR NR NR NR
Sromlne,
Cane Sugar Llqwr Capylic Acid Dloxlde Dlsulflda Monoxide Tetrachlorlde Acid
180
180
190
Carbon Carbon Carbon Carbon Carbon
Bronze Plating 4% 5% 3% 4.5%
Solution:
180
180
190
Copper Cyanlde Sodium Cyanide Sodlunl carbonate Rochelle Salta 100 O-50 100 NR 210 NR 210 NR 210 100 NR
100
100 150 100 210
Bulyl Acetate Sutyrlc Acid
Carbowsx Castor Carboxy 011 Methyl Cellulose 10
210 150
150
Sutyl Senzyl Butyl Carbltol
Phthslate
100 100 100 100
150
150
150 100 100 Chlorinated (caustic Chlorinated Chlorine Chlorine Chlorlne, Brine Liquors chlorine cell) Wax All 15 Satd. 100 100 180 200 160 210 210 NR 180 200 180 210 210 NR 190 180 200 180 210 210 NR 180 210 210 NR 180
Sutyl Cellosolve Eutylene Glycol
160
160
180
DIoxIdelAIr Dloxlde, Dry Gas Wet Gas Llquld Wet Gas
c
Cadmium Chorlde All 180 180 180 180
Chlorine. Chlorine,
(continued)
TABLE
1.51:
VINYL
ESTER
RESINS-INTERPLASTIC fE 8100 fE 8300

160 120 100 NR NR NR NR
CORP.
(continued)
Maximum Recommended Temperature OF
Maximum Recommended Temperature F Concentratio Chemical

Chlorine Wsbr Acid
Concentratio VE 8440
180 120 100 NR NR NR NR
IE 8100 IE 8300
200
% by Weigh
All 25 50 Con.
VE 8710
190 120 100 NR 100 NR NR 140
VE 8520
Chemical
Copper Pickling Bath: 10% Ferrk Sulfate 10% Sulturlc Acid copper Sulfate
% by Weigh
VE 8440
200
VE 8710
200
VE 8520
Chioroecetk
All
210 210
210 210 210 210 210 NR 210 210 120 100
210 210 210 210 210 NR 210 210 120 120
210 210 210 210 210 NR 210 210
NR NR NR NR
Corn Oil Corn Starch Corn Sugar Cottonseed Cresyllc Crude Crude Oil 100 100 100 100 100 Slurry All
Chlorobenxene Chloroform Chloraulfonk Acid
100 100 100
210 210 210 NR 210 210 120 100
Chrome PIstIng 60th: 19% Chromic Acid Sodium Fluoroslllcats
Acid 011, Sour 011, Sweet
sunate
Chromic Acid 20 30 150 NR 150 NR 150
Cyclohexene 140 NR Cyclohexenone 150 210 210 All All All 210 210 210 150 210 210 210 210 210 190 210 210 210 210 210 210 210 210 210 210 210
Chromium Cltrlc Acid
SuMate
All All
D
Detergents, Diallyl Sultonated All All Phosphate 65 100 100 100 100 100 100 100 100 100 100 100 100 210 150 210 NR 100 NR NR NR NR NR 160 60 NR 60 NR 210 150 210 NR 100 NR NR NR NR NR 160 60 NR 60 NR 210 190 210 NR 150 120 NR NR NR NR 200 120 NR 100 NR NR NR NR NR NR NR NR 160 210 NR
Coconut Copper
011 Chloride
phthalate
CopperCyanide
Copper Fluoride
Di-Ammonium Dlbromophenol Dibutyl Dlchloro Ether
Copper
Nitrate
All
210
210
210
copper Plating Sokls. Copper Cyenlde 10.5% CopPer 14% Sodium Cyenlde 6% Rochelh Bells
Benzene
160
150
190
Dichloroethylene Dichloromonomethsne Dichloropropane
Copper Brlts Plellng Csustlc-cyenlde
160
160
190
Dlchloropropene Diesel Fuel Amine
Copper Plating Boln. 45% Copper nuoroborate 19% copper Sulfate 8% Sulturk Acid Copper Matte Dlpplng Beth: 30% Ferric Chloride 19% Hydrochloric
160
160
200 DIethanoI Dlethyl
Amlne Benzene Carbonate
160
160
200
Diethyl Dlethyl
(continued)
TABLE 1.51:
VINYL
CORP. (continued)
Temperature OF Concentratio Maxlmum WE 8100 VE 8300 VE 8440 VE 8710
100 80 80 100
Concentration 1 \IE 8100 Chemical Oiethytane Glycol Diethylhexyl Phosphoric Acid (in Kerosene) Diethyl Sulfate Diisobutylene Oiisobutyl Phthalata Dllsopropanol Amlne Dlmethyl FormamIde Olmethyl Morpbollne Dimethyl Phthelate Dioctyl Phthalate Dlpropylene Glycol DMA 4 Weed Killer 2,4D DMA 6 Weed Killer Dodecyl Alcohol % by Weigh t 100 20 100 100 100 100 100 100 100 100 100 100 100 100 150 150 \{E 8300 150 VE 8440 150 120 NR 100 100 100 NR NR 150 150 150 180 150 150 120 120 180 150 150 150 NR NR NR F Fatty Acids Ferric Chloride Ferric Nitrate Ferric Sullate Ferrous Chloride Ferrous Nltrate Ferrous Sulfate 8-8-8 Fertllirer FertillzerUrea Ammonium Nitrate E Electrosol Epichlorohydrin Epoxidlzed Soybean 011 Esters, Fatty AcIda Ethyl Acetate Ethyl Acrylate Ethyl Benzene Ethyl Sromlde Ethyl Chloride Ethyl Ether Ethylene Chlorohydrln Ethylene Glycol 5 100 100 100 100 100 100 100 100 100 100 All 210 210 150 NR 150 180 NR NR NR NR NR NR 150 NR 150 180 NR NR NR NR NR NR NR NR NR 100 210 210 150 NR 150 180 NR NR NR NR NR NR NR NR Freon 11 Fuel Oil Furfural Formaldehyde Formic Acid 150 NR 150 Flue Gas Fluoborlc Acid FluosillclcAcid VE 8710 200 150 120 VE 8520 Chemical
1
NR
Maximum
Recommended
Recommended
Temperature
OF
% by Wefgt All 100
VE 8520
EthyleneGlyeolMor&utyiEttw Ethyl Sulfate
120
NR
100 100 100 NR NR 150 150 150
All All All All All All All
210 210 210 210 210 210 210 120
210 210 210 210 210 210 210 120
210 210 210 210 210 210 210 120
210 210 210 210 210 210 210
120
120
120
340 All 10 20 All 10 All 180 210 180 150 180 100 100 100 5 10 100 180 120 100 NR
340 180 210 180 150 180 100

100 180
340 210 210 180 15c 180 100 100 180 150 120 NR NR
180 180
210 180
100
120 100 NR
(continued)
TABLE 1.51:
VINYL
Maximum Concentratio VE 8100 VE 8300 VE 8440
CORP. (continued)
Temperature OF Concentration VE 8710 VE 8520; Chemical Hydrobromlc Acid % by Weight O-25 25-50 Hydrochloric Acid Hydrochloric Acid saturated wlth Chlorine gse Hydrocysnlc Acid O-20 20-37 30 Maximum IIE 8100 1IE 8300
180
Recommended
Recommended
Temperature
Chemical G
% by Weigh
VE 8440
180 100
VE 0710 200 200 210 180 190
VE 8520
Gas. Natural
Gasoline, Auto Gsrollne, Avletlon Gssollne, Ethyl Gssollne, Sour Gluconk ACM Glucoee Gluteraldehydc Gluterk Acid Glycertne Glycol. Ethylene Glycol, Propylene Glycollc Acid
50 180
210 190 150 190 180 150 210 120 120 210 210 210 190 80 90 190
210 180 150 190 190 190 210 120 120 210 210 210 150 90 80 190
210 190 190 190
210
100 210 190 190
210 190 190
210 180
All 10 20
180 150 100 180 160 210 210 150 210 210 190 190
150 150 100 190 190 210 210 150 210 210 190 190 150 150
180 150 100 190 190 210 210 150 210 210 190 150 100 150
190 150 100 190 190 210 210 150 210 210 190 180 150 150
190 Hydtolluwlc Acid 190 210 120 Hydrogen Sromlde, Wet Gas 100 100 100 O-30 All All 120 Hydrogen Chlortde, Dry Gas 210 210 210 200 Hydrogen Sulfide, Aqueour 100 Hydrogen Fluorlde, Vapor 80 Hydroeultlte Bleach 180 190 Hypochlorous Acid 10 20 190 150 210 Hydrogen Chlortde, Wet Gas 210 Hydrogen Peroxlde 210 Hydrogen Sulflde, dry 150 210 HydrotluoslllclcAcid 10
All SO 50 All All All 10 70
Glyoxal Gold Plating Solution: 63% Potserlum Ferrocysnlde 2% Potarrlum Gold Cysnlde .8% Sodium Cyantda
40
H
troll
HOptllll~ liexane Hexylene Glycol Hot Stack Gerres Hydraulk Fluld Hydrerlna
150 i50 150 340 210 NR
150 150 150 340 210 NR
150 150 150 340 210 NR
150 150 150
PtathIg Solutton: 45%FeCl : 15%CeCl 20FeSO,:ll%(NH,),SO~
190
180
180
Iron end Steel Clesnlng Seth: 9% Hydrochlork 23% Sulturk
190
180
190
210 NR
isopropyl Amlno lropropyl Palmltate
All 100
100 210
100
120 210 210 (continued) z
210
TABLE
1.51:
VINYL
ESTER
RESINS-INTERPLASTIC
Maximum
CORP.
(continued)
OF Concentration Maximum fE 8100 IE 8300
210 210 NR NR NR NR NR 210 Dlsulflde Acetlc Acid
Recommended
Temperature
Recommended
Temperature
OF
Concentration Chemical
J
Jet Fuel
ilE 8100 fE 8300

VE 8440
% by Weigh1
VE 8710
VE 8520
Chemical
Mercuric Chloride Chloride Chloride
% by Weigh1
All All 100 100 100 100 100
VE 8440
210 210 NR NR NR NR NR 210 200 NR NR 210 210
VE 8710
210 210 NR NR NR NR NR 210 200 NR NR 210 210
VE 8520
210 210 xI( NR NR NR NR 210
180
180
180
Marcurous Methylene
K
KeImene
Methyl
Ethyl Ketone lsobutyl Isobutyl Styrene Ollr Carbltol Ketone
180
180
180
180
Methyl Methyl
L Lactic Acid Lasso (50% Chlorobenzone) titex Laura1Chtorlde Laurie Acid Lead Acetate Lead NItrate Lead Pletlng Solution: 6% Lead .8% fluorborlc Acid .4% Boric Acid LevullnlcAcid Linseed 011 Lithium Bromide
Llthlum Sulfate All All All
All
210 Ntt
210 NR 120 210 210 210 210 180
210 120 120 210 210 210 210 IS0
210 NR
Methyl Mineral
All 100
Ail All All
120 210 210 210 210 180
Molybdenum 210 210 210 210 Monochloro
100 100 100
200 NR NR 210
NR NR 210 210
Monoethynolamlne Motor 011 Myrlstlc Acid
100
210
210 210 210 210
210 210 210 210
210 210 210 210
210
N
210 Naphtha 210 Naphthelene 210 Nickel Nickel Chloride Nltrate All All 100 100 180
180
180 210 210 180
180 200 210 210 180
120 180 210 210 180
180
210 210 180
M
Magnesium Magnesium Magnesium Magneelum Magnesium Malelc Acid Slrulflte Carbonate Chloride Hydroxide Sultate All All All All 180 180 210 210 210 210 IS0 180 210 210 210 210 180 180 210 210 210 210 180 180 210 210 210 210
Nickel Platlno 8% Lead .S% fluoborlc Acid .4% Sorlc Acid Nickel Plating 11% Nickel Sulfate 2% Nickel Chloride 1% Sorlc Acid Nickel PLetlng 44% Nickel Sulfate 4% Ammonium Chloride 4% Sorlc Acid Nickel Sulfate
180
180
180
180
180
180
180
180
All All
All
210
210
210
210
(continued)
TABLE 1.51:
VINYL
Concentration
CORP. (continued)
Temperature OF Concentratior Maximum VE 8100 VE 8300
210
Chemical
Nitric Acid
% by Weigh1 I
5 20 52
1
I
Maximum
Recommended
Recommended
Temperature
QF
vE 8100
\iE 8300
150
VE 8440
150 120 NR 160 NR
VE 8710
150 140 120 160 NR
VE 8520
150 120 NR
Chemical
Phthallc Acid
% by Weighi
All
VE 8440
210
VE 8710
210
VE 8520
210
120 NR 160 NR
Pickling Acids, Sulfurlc and tiydrochlorlc Picrlc Acid, Alcoholic 10 All 100
210 210 210 120 120
210 210 210 120 120
210 210 210 120 120
210 210 210 120 120
Nitric Acid Fumes
160 Polyvinyl NR Polyvinyl Alcohol Acetate Latex
0
Oaklte Rust Stripper Oclanoic Acid 100 100 100 All Sulfuric) 100 All 160 160 210 210 210 NR 210 210 160 160 210 210 210 NR 210 210 160 210 210 210 210 NR 210 210 160 160 210 210 210 NR 210 210
Polyvinyl Chloride Latex with 35 parts DOP Potassium Potassium Potssslum Potassium Potassium Potassium Potassium Potassium Polarslum Alum Sulfate Blcsrbonate Bromide Carbonate Chlorlde Dlchromate Ferricyanlde Ferrocyanlde Hydroxlda Nltrate Permanganate PersuIfa1e Sulfate Acid All O-50 All All All All All All All All All All All 20 60 100 100 Acid 100 All Fumes o-54 100 NR NR 210 210 210 NR NR NR 210 210 210 NR NR NR 210 220 210 NR NR NR 210 210 210 NR Propylene Gtycol All
210 150 210 150 210 210 210 210 150 210 210 210 210 200 160 NR 210 160
210 150 210 150 210 210 210 210 150 210 210 210 210 200 160 NR 210 160 NR
220 150 210 150 210 210 210 210 150 210 210 210 210 200 160 NR 210 160 NR
210 150 210 150 210 210 210 210 150 210 210 210 210 200 160 NR 210
Oil, Sour Crude Oil, Sweet Crude Oleic Acid Oleum (Fuming Olive 011 Oxalic Acid
P
Perchlorathylene Perchlorlc 100 10 30 Peroxide Bleach 2% Sodium Peroxlde g6% .025% Epson? Salt& 5% Sodium Sillcrfe, 42BE 1.4% Sulhirlc Acid, 86Be Phenol Phenol Sulfonlc Phorphorlc Phosphoric Phosphorous Phosphorous Acid Acid PentoxIde Trlchlorlde 100 150 100 210 100 150 100 210 100 150 100 210 100 150 100 210
Potassium Potassium Potasrlum Potassium PropIonIc
Acid
Pulp Paper Mill Effluent Pyrldlne 100
NR
NR
R
Rayon Spln Bath 150 150 150
(continued)
TABLE 1.51:
VINYL
Maximum Concentration WE8100 rlE 8300
VE 8440
CORP. (continued)
Temperature F Concentration
VE 8710 VE 8520 Maximum
Recommended
Recommended
Temperature
OF
1IE 8100 IIE 8300 VE 8440 VE 8710

210 210 210 180 130 120 200 200 200 200 210 180 150 180 210 210 210 130 210 210 210 210 200 160 180 210 210 150 210
Chemical
% by Weigh
Chemical
% by Weigh
All All All All All All 5 10 25 50
VE 8520
210 210 210 180 150 120 160 150 120 180 210 160 130 180 210 210 210 130 210 210 210 210 200 180 180 210 210 130 210
S
Selkylk Seback Selenlus Acid Acid Acid All All All All 160 210 210 210 200 160 210 210 210 200 160 210 210 210 200 160 210 210 210
Sodium Sodium Sodium Sodium Sodium Sodium Sodium
U-Phosphate Ferrkyanlde Ferrocyanlde Fluoride Fluoro Silicate Hexametaphosphetes Hydroxide
210 210 210 180 150 120 180 150 130 180 210 180 130 180 210 210 210 130 210 210 210 210 200 180 180 210 210 150 210
210 210 210 180 150 120 180 150 130 180 210 180 150 180 210 210 210 130 210 210 210 210 200 180 180 210 210 150 210
Silver Nltrete Sllvar Plating Solution 4% Silver Cvsnlda 7% Potas&m Cyanide 5% Sodlum Cyenlde 2% Potassium Cerbonete
-eP* Sodium Sodium Sodium S&urn Sodium Sodium Sodium Sodium Sodium Sodium So&urn Acetate Alumlnete Alkyl Afyl Sulkmates
All All All All 100 All All All All 10 All o-25 35
210 210 120 150 160 160 120 210 210 210 210 160 160 210 210 150 210 210 210
210 210 120 150 180 160 120 210 210 210 210 160 160 210 210 150 210 210 210
210 210 120 150 210 160 120 210 210 210 210 180 180 210 210 210 210 210 210 210 210 150 210 210 210 210 210 120 150 180 180 120 210 210
Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sorbltol
Hydrosulflde Hypochlorlte liypochlorlte Lwryl Sullste
All o-5 5-15 All All All All 20 All All All All All 37 All All All All 100
Benmate
Skarbonste Bllluorlde Elsulfata Slsulflta Bromste Sromlde Co&mete
Mono-Phosphate Nltrate Nltrlte Persulfate Silkate Sulfate Sulfide Sulllte Tetra Borate Thlocyenste Thlosulfste Trlpolypho8phste Xylene Sullonate Solutlonr,
Sodium Sodium Sodium Sodium Sodium Sodium
Chlorate Chloride Chlorite Chromate Cyenlde Dlchromete
All All All 50 All All
Sour Crude 011
(continued)
TABLE 1.51:
VINYL
Maximum VE 1 8100 bE 8300
210
CORP. (continued)
Temperature OF Maximum Recommended Temperature OF
Recommended
Concentratia n Chemical
soya Oil Chloride Chloride
Concentratia
VE 8440
210 210 210 210 NR 100 160 210 210 210 210 210 210 210 160 120 NR 100 210 100 160 210 210 210 210 210 210 210 160 120 NR 100 210 210 NR 210 160 160 160 210 210 210 210
VE 8100 WE 8300
100 NR 200
% by Weigl 1t
All All All All 100 Ail All All O-26 All All
VE 8710
210 210 210 210
VE 8520
210 210 210 210 NR
Chemical
Thioglycolic Thionyl Acid
% by Weigl
10 100
VE 8440
100 NR 200
VE 8710
100 NR 200
VE 8520
Stannk Slsnnous Slasrk StyWe
210 210 210 NR 100 160 210 210 210 210 210
Chloride
NR
Acid
Tin Plating 16% Stannous Fluoroborate 7% Till 9% Fluorborlc Acid 2% Boric Acid Tolusne Toluene Solfonlc Acid 100 All
succlommltrlle Sugar, Sugar, Sullamk SultanIlk Bee1 and Cane Liquor sucrose Acid Acid
NR 210
NR 210
100
210
NR 210
Transformer Oils: Mineral 011 Types Chloro-Phenyl Types Trichlor Acetlc Acid 50
210 NR 210
210 NR 210
210 NR 210 100
210 NR 210
S&sled Detergents Sulfur Dloxlde, Dry or Wet Sulfur Trloxlde/Alr Sulturlc ACM
Trkhloroethane Trlchloroethylene Trlchloromonofluoro-Methane Trlchlorophenol Trkresyl Phosphate Sullonate
100 100 100 100 NR 60 NR 100 All 100 Chlorobromlde 100 All 100 All 210 120 NR 210 100 150 NR 60 NR 100 210 120 NR 210 100 150
NR 100 NR 120 210 120 NR 210 150 150
NR
All O-50 SO-70 75 Over 75
210 210 160 120 NR 100 210
NR
Tridecylbenzane Trlethanolamlne Trimethylene Trlsodlum Turpentine Tween Surfactant
210
Sulfurous
Acid Acid
All 105% H, PO,
NR 210
SuperphosphorIc 76% Pz 0,
Phosphate
150
T
Tall Oil Tsnnk Acid Tartsrk Acid Tetrschlorosthylene Tetrasodlum EthylensDlemlns Textone- 50% Aqusous Sodium Chlorete
All All 100 160 100 210 60 150 100 210 60 150 100 210 100 210
U
Urea O-50 150 150
All
120
120
120
V
Vegetable 011s 210 210 210 210 210 210
210
210
210
Vhwgar
(continued)
TABLE
1.51:
VINYL
ESTER
RESINS-INTERPLASTIC
CORP.
(continued) *Co-Rezyn Vinyl Ester Resins
Maximum
Recommended
Temperature
OF VE 6300 The most versatile of all Ihe vinyl esters with excellent corrowon resistance from acids lo alkalies and oxldlzmg chemicals The m0S.t wdely used rest of the family of vinyl esters lor filament hand lay-up winding remforced and custom plastic fabricated tanks, pipe, as VE 6440 The fire reslstanl brommated counterpart 01 Ve 6300. When used with 3% antlmonv InoxIde. has a flame spread rate of less than 25 per ASTM E 64 Tunnel Test. Excellent physlcal properlles and corrosion reslstance I a Vinyl Ester resm Lower halogen content and cost than VE 6400 and same competitive materials. VE 6710 A higher cross ilnk giving hlgher heat chemical This causllc excellent adheswe for reliable seconsolvent IS resistance demonstrated resistance reswance, as density rest than VE 6300 dIstortion and exceprlonal and hydrolytic by an the stablll(y. excephonal Altalns good IS un-
Concentration Chemical
Vinyl Vinyl Acetate Toluena
ES100 EE300 VE 8440 VE8710 VE8520
% by Weight
100 100
NR 60
NR 60
NR 60
NR
and process equipment. toughness and fatigue
Outstanding propertles
W
water Defonlzed Demineralized Dlstlllcd Fresh satt Sea Whfte Liquor (Pulp HI) All
demonstrated by high cycle pressure on lhin wall filament wound pipe. By suitable control of promoter levels, 210 210 210 210 210 210 160 210 210 210 210 210 210 160 210 210 210 210 210 210 160 and Co-Rezyna VE 6300 can wlthout mlo thick sections 210 210 210 210 210 210 VE 8300 excess This resin properties dary Used I: cracking
values Catalyst
be fabricated or crarlng
warping. demonstrates which makes

OperStlOnS.
of VE 6710.
example.
bonding
affected by temperatures some sacrlflce 6300
chlorobenrene Although a tough I this property
at amblent rest there IS versus VE
Filament Hand
wmdlng and spray melal die lay-up molding
lay-up
SMC match Pullruslon Tank linmgs Coatmgs has a v~scoslty
of 500 cps and CO-
VE 6520 An extremely tough epoxy based vinyl ester havmg 20% elongation This IS a non-rubber resin, developed for SPI Lmer appltcallons to m~nlmlze crackmg or crazmg due to thermal or mechanlcal shock and physlcal abuse. Relalns very good chemical reslstance. Is 100% compatible wth the other Co-Rezyn@ Vmyl Other Esters uses to add addItIonal toughness.
lams 45% styrene. VE 6100 A lower cham length version of VE 6300 havc0s111e.5. mg lower lnlrmsic and ewdent ~1st llsco?.lty Contains 50% styrene wlh a nommal of 100 cps. HSS eSSentlSlly the Sam e cured
X
Xylane 100 NR NA 100 NR
properties
as VE 6300. Cenlrlfuaal
Used casting
for.
Coatmgs Tank lmmgs Primers Adheswes
Co-Rezyn@ MVR-Modified
All All 210 210 I60 210 210 160 210 210 160 210 210 MVR 6000 - Good where MVR spread the optimum 6040 - Fire conoslon resistance resin and physical Nitrate vinyl ester retardant. properties
Vinyl Ester Resins

properties. A ecOnomlc choice are nof required. Vinyl Ester - No fire retardant. Resm with a flame
Zinc Chlorate Zinc
21C Plating Solutlo: 9% Zinc Cyanide 4% Sodium 9% So&urn Cyanfde Hydroxide
brominated
Modilied
of IeSs than
25 per ASTM
E 64 Tunnel
Test.
when
used with 3% antmony and corrosion resistance
trioxlde. DOeS not slfsl the optimum physical proprrttrs associsled with the Vmyl Ester Resm. VE 6440
MVR 6050 - Fire retardant. brominated Modlfled Vinyl Ester with a flame spread rate of less then 25. per ASTM E 64 Tunnel Test, when used wlth 3% antimony 21C solutto: 49% Zinc fluoborat* 6% Ammonium Chloride 6% Ammonium Ftuoroborate
PMng
!OO
200
200
trloxlde An economic propertles are required
choice where superior corrosion resistance and over fire relardanl lsophthallc polyester resins bromfnated Modlfled Vlnyl Ester trloxlde or other flame retardant rstlng of less than 25 Only a small from the unmodified vlnyl
physical
MVR 6060 - Ffre retardant require the use of SntlmOny the ASTM resfstance E 64 Tunnel and physical Test
resin which does chemicals lo achieve sacrifice ester of chemical VE 6400.
not
propertles
21C Sulfate
All
IO
210
210
210
(continued)
TABLE 1.51:
VINYL
CORP. (continued) Chemical Resistance Co-Rezynr MVR Reslns

Concentration % by Weight
All All Acid O-20 20-37 10 20 All
Chemical
Acetic Add
Concentration % bv Weight
O-25 50
MVR 8000
170 150 NR 80 150 NR 150 170 140 100
Maxlmum Temperature MVR 8040 MVR 8050

!70 150 NR 60 150 NR 150 170 140 100 NR 150 150 100 NR 200 NR 170 200 180 NR 150 180 150 120 180 200 180 180 180 170 150 NR 80 150 .NR 150 170 80 100 NR 120 80 80 NR 200 NR 170 200 180 NR 100 180 NR 80 180 80 180 180 180
MVR 8060
200 180
Chemlcel
Glycol, H9X4M Ethylrne
MVR 8000
200 150 180 150 150 100 200 180 180 180
Maximum Temperature MVR 8040 MVR 8050

200 150 180 150 150 100 200 180 180 180 150 120 80 200 200 200 200 150 150 120 150 100 200 180 180 180 120 100 NR 200 200 170
MVR 8060
210 150 210 180 150 100 200 180 180 180 150 120 NR 210 210 210
ACetOll* Alcohol, Ethyl
100 100 10
NR Hydrochloric 80 150 Hydrolluorlc Add NR 150 Hydrogen Suttlde 210 Jot Fuel 140 KerrnOn* 100 Naphtha NR Nltrlc Acid 150 150 100 NR 210 NR 180 Potsulum Hydroxide 210 210 NR 180 180 150 120 210 200 180 180 180 Toluene Water, Dlrtlllcd or Sea Sodium Hypochlorlte Sodium Sodium Carbonate Hydroxldo 10 25 o-25 O-10 10-25 50 o-15 150 120 180 140 120 180 150 150 120 180 140 120 180 150 120 100 120 NR NR NR NR 150 150 150 160 140 180 150 5 20 50 150 120 60 200 200 Acid All 200
Alcohol,
Methyl
100 10
Alum Ammonls, Ammonla, Ammonia, Ammonium Ammonium Aqueous Oar Llquld Carbonate Hydroxide
All o-20
NR All O-20 29 100 All
NR 150 150 100 NR 200 NR
011, sour 011, Sweet Phorphorlc
Senzene SrllN Sromln., Calcium Cslclum Chlorine Chtorlna, Chlorine Chlortna Chromic Ltquld Carbonate SuItate Qar, Wet or Dry Ltquld Dloxlde Water Acid
Plckllnp A&b, Sulfudc 6 Hydrochloric
200
200
170
210
All All 100
170 200 180 NR
All Ail 20 All Atl 10
150 180 150 120 180 200 180 180 180
Sultur Dioxide, Dry or Wet Sultur Trloxlds/Alr Sulturlc Acid All Alt O-50 50-70 75 200 200 200 100 120 NR 200 200 200 200 160 120 NR 200 170 170 150 80 80 NR 200 210 210 210 180 120 NR 210
Cycloh*xane Ethylene Fluailicic Gasoline, Glycol Acid Auto Avletlon Ethyl
TABLE
1.52:
EPOXY AND POLYESTER
PIPE AND FITTINGS-AMERON
BONDSTRAND
CHEMICAL
RESISTANCE CHART
TEMPERATURE CHEMICAL SOLUTION
LIMIT
Acetic Anhydride ACNOIX Acetonitrile Acrylic Acid Acrylonitrile Air Alcohol, Amyl Alcohol, Butyl Alcohol. Ethyl Alcohol. lsobutyl Alcohol. Isopropyl Alcohol, Methyl Alcohol, Polyvinyl _ ^
II !I
-I/ 120 11 120 NR 100 3004 200 200 180 180 150 180 150
I 1
49 49 NR 38 14Q4 93 93 82 82 66 82 66
l I 1
-120 120 N loo 3004 203 200 180 180 160 180 150
I I 1
--49 49
I I
NH NR
I I
NR
---
1 NR 1 NR 1 -NR NR 1 -NR NR I -14Q4) 200 93 / RP-34 93 100 38 / UP-34 93 100 38 I RP-34

NR 38 82 82 82 66 66 __ loo 100 -loo __ 38 _38 38 __ RP-34 RP-34 -RP-34 -
.M
I
II Eutadiene I/ 150
NH , NM , NH 1 N N , --
66
150
66
I --
1 --
1 --
J,
Amy1 Acetate Amy1 Chloride Aniline Antimony Pentachloride
100 100 NR -220
38 38 NR -104
100 100 NR -220
38 38 NR -104
NR NR NR 100 150
NR NR NR 38 66
---RP.34 RP-34
Carbon Disulflde Carbon Monoxide Carbon Tetrachkwde Carbonic Acid Castor Oil
-2OiI 150 180 220
-93 66 82 104
-200 150 180 220
-93 66 82 104 NR 180 200
NR 93 NR 82 93
-RP-34 -RP-34 RP-34
(continued)
TABLE
1.52:
EPOXY AND POLYESTER
(continued)
CHEMICAL SOLUTION
Formic Acid
0.10
NR
Dcalc~um Phosphate-_
(continued)
TABLE
1.52:
EPOXY AND POLYESTER
(continued)
TEMPERATURE CHEMICAL SOLUTION

COflCWl
tration
LIMIT SERIES 5000
TEMPERATURE
LIMIT SERIES 5000
tlvowhlorour wine Jet Fuel KWOWW Lactic Acid Latex Louric Acad Lead Acetate Lead NItrate Levulinic Acid
Acid
Lime Linseed Oil Lithium Chloride Lube 011 Magnesium Carbonate Magnesium Chloride Magnesium Hydroxide Magnestum Nitrate hlagneswm Sulfate Maleic Acid Mercuric Chloride Mercurous Chloride Mercury Methacrylic Acid, Glacial Methyl Chloride Methyl Ethyl Ketone Methyl Isobutyl Alcohol Methyl lrobutyl Cdrbitol Methyl Isobutyl Ketone Methyl Methaaylate Methyl Sulfonic Acid Methylene Chloride Mineral Oil Naphtha Naphthalene Nickel Chloride Nic!xel Nitrate Nickel Sulfate Nitric Acid Nitnc Acid Nitrobenzan hlitrogen Solutions 31, Sour Crude
(continued)
TABLE
1.52:
EPOXY AND POLYESTER
(continued)
TEMPERATURE CHEMICAL SOLUTION 2000 SERIES 4000 IEDcd

OF OC
LIMIT SERIES 5060 ,Pds,W,

OF OC Adhesive tm
---1--
___ ._
TEMPERATURE LIMIT --II
NR
NOTES:
Sugar Solutions
Sulfite Liquors Sulfur Chloride
I! II
2204 150 NR
( I
1.
104 66 NR
1 150 1
NR
66 NR
200 NR
93
RP-34
1 NR j
--
Concentration Where no concentration is shown, recommendations apply to any concentration up to 100% or saturation. Where a concentration range is given, recommendations apply to any concentration within that range. Where a single concentration is given, only that specific concentration has been tested. Use RP-34 adhesive for all applications food applications up to 200F (93C). Use adhesive shown for field installation RP-GA adhesive for food applications. except except use RP-GA for use RP-105 or
2. 3. 4.
Use Bondstrand filament-wound fittings and flanges. flanges may be used in Series 5000 systems. Recommended
Molded
II
NR
NR
NR
NR
NR
NR
--
,,
NR-Not
TABLE 1.53:
PHENOL-FORMALDEHYDE
AND FURFURYL
ALCOHOL-FORMALDEHYDE
RESINS-
AMETEK,
HAVEG DIVISION
Mmmum
Haveg 41 NA is a lhermosetting
of phenol-formaldahyde fillers. salts It is generally and chlorinated resin aromatic recommended
plastic, end inert
based
on a composition silicate mineral acid, with
Chemical Service Acetaldehyde. 90%
Grade 4i NA c, Mb
sO*F I NR UEI
..I.
160F I
TWllperatUre F
non-asbestos
for service
y,..^
hydrocarbons.
41 NP
E E E E Trot .__. 1 1 I G NR G F G NR Tl?st G E F G E E E E NR E E NR F E E E E NR F E G F
E.120 NR.120 E-212 G.212
61 NA .1 NA
Haveg 61NA
of furfuryl silicate dilute carbons. fillers. acids,
is a thermosetting.plastic It Is generally alkaline reactions
based
on a composition with hydro ACelOl-te Acetonltrile. 201 Acel~c anhydrIde
61 NA dl NC 51 NA 01 NA R,NA 41 NA 61 NA 11 NA Acelyl chloride Acrylic acid. Bosh 61 NA 41 NA 61 NA 41 NA 61 NA 41 NA Alurmnum chloride Aluminum sulfate hydroxide. 26% 61 NA 41 NA 61 NA 41 NA Ammonium 61 NA 41 NA n-Amy1 alcohol 61 NA 41 NA 61 NA 01 NA Anilmt hydrochloride 61 NA 91 NA Aqua regm 61 NA 41 NA 61 NA
alcohoLformaldehyde
resin and inert non.asbestos recommended for service aromatic and chlorinated
_ .
1
I
NR.212 F.133
Haveg 46 is a phenol-formaldehyde Its primary fluosilicic consideration acid, and related
resin
with
a graphite
filler
is for use with fluorinebearing
hydrofluoric
acid,
compounds.
Haveg 66 is furfuryl
filler. Haveg In addition
alcohol-formaldehyde resistance
resin
with
a graphite compounds, 61 NA.
Acrylonltrile
to its resistance
lo HF and related to alkalies
E-300 E-300 E-2.W
66 has the same
as Haveg
KEY: E = Excellent. Can be used generally, and is to all intents affected at all by chemicals at the test temperature. G = Good. Can be used quite generally. Satisfactory F = Fair. Can be used for some purposes. sample or discolor solution. NR = Not recommended. and purposes not
E
E F G E Test NR NR TeSt G
E
E NR NR E
NR-212 G-278
in most se&ices. to swell
AflillfW
May involve some tendency
SODIUM For alkaline service,
HYDROXIDE
(NaOH) AND HAVEG

grade.
Ally1 chloride
G-100
Haveg 61 NA is the recommended
Haveg 61 NA can be used with varying concentrations of NaOH, even concentrations up to 60% at elevated temperatures; however, it is affected . There is a surface effect that can contribute to contamination of the solution. Haveg 61 NA should be considered only where NaOH is used to neutralize conditions or as a reactant in a particular process.
Haveg 41
acidic
overnight.
NA, when exposed to 0.5% NaOH in water, will be seriously 1% NaOH will begin its attack immediately.
attacked
(continued)
TABLE 1.53:
PHENOL-FORMALDEHYDE
AND FURFURYL
RESINS-AMETEK,
HAVEG DIVISION
(continued)
Maximum
Temperature Chemical Serries Benzotrachlonde ______ 61 hC 41 luc hl hL

41 h' *I h
Chemical Service Chlorosulfornc E G Test F E E E E

,
Grade 1 NA
80F E 1es1 NR NR NR NR NR NR E E E E E Test E
l&F hR
Maximum Temperature F
ac,d 30% 10% ac~dl
NR F F.9a-Y G E.140 E E E E-300 E.3W Copper lullate Cupw chlorfde chlonde Em0 __.. Chromic BCX!. 2% (with sulfuric Chromic acts
6 NA 4: NA 61 NA 41 NA 61 NA 41 NA 61 NA 41NA 61 NA Al NA 61 NA 41 NA 61 NA 41 NA
Chromic acid
een2yl chloride Bow acid _~
I IWL 41 NL 61 NC
41N
E E E E E E
E-300 E.3W.l E.300 E-300
Bromine, 3% maximum n_Bulyl alcohol ~Butyl n-Bulyric Calcium chloride, acid chlorlde sec.butyl chlor#de
61 N 41NF r. .I, 41 NC ___ 61 NP 41 NL 61 NA 41 N 61 NF dl ML . 61 NC 41 NC Al&J
I 1 I
F E
Test E E E E E NR ,..
F I
E E E E E E
F.-&n -1
NR-212 E-212
Cyano,en
G.266 G.266 E-300 Dibutyl phthalate Dabutyltin dichloride Dibutyl ether
41 NA 61 NA 4, NA 61 NA 41 NA 61 NA
E E E E F
E
E E E E
1 E I
E-212 E-212 E.212 E-212
Calcium hypcchlorile Carbon disulfide Carbon letrachlonde Chloral Chlorel. 32% and MCB, 64% Chloral. 40% and MCB, 59%
1 1
NR E E
F
E E E c
F
E E E F G-257 4, NA Dlethyl ether Dlethylkelone Dtethylene ~lycol 61 NA 41 NA 61 NA 41 NA 61 NA dl . _. +.I& 61 NA 41 NA Dimethyl phfhalate 61 NA 41 NA Eplchlorohydrln Ethyl acetate Ethyl alcohol 61 NA 41 NA 61 NA 41 NA kl NA E E E E I G E E G TM E E E-23C I=.,,, G-212 E.212 E.212 E G G-212 G-212 E-212 G.212
41 NA 61 NA 41 NL kl NL
I.
..r
&
41 N& 61 NL. 41 NA 61 NC dl NL Chloral hydrate Chlordlne 61 NL 41 NA 61 NA E R ; E Test E E F E c. G E
E-257 NR.203 E.203
_._
Dusobutyl ketone
1
1
NR NR Tell G F F G NR r:
(continued)
TABLE 1.53:
PHENOL-FORMALDEHYDE
AND FURFURYL
RESINS-AMETEK,
HAVEG DIVISION
(continued)
Chemiul Methyl isobulyl Methylene
Servia
GWJ9 1 NA
80F NR
l&F
Maximum Temperature F G-212
Chemwzat Service FT,eol. 100% Penol, 65% Phenol. 9% Phenol. 6%
Grade 4: kA 61 NA 41 NA 61 NA 41 NA 61 NA 41 NA 61 NA
41 NA
8dF NR NR G NR E G E F NR E
160-F
Maximum Temperature F
ketone. 100%
6: NA P! NA G G T& NR Test G E E TCSl E E 6 NA 4: NA
F G NR E F
NW212 F.212 G.212 NW212
chloride acld 10%
Monochloroacelic Uonoch1oroacetoe. Hoochloroberet Uonoethanolamme. Monoethmoiamlne. Uwosodwm Naphthylene
6 NA 4, NA 61 NA 41 NA 61 NA 41 NA
E-212 E.212 G.l!U
Phenyl ether
PhOSpee
61 NA
7 NA
61 NA 41 NA 50% 61 NA .I Phosphorous orychlorlde Phosphorous Polasswn trlchloride NA 61 NA 41 NA 61 NA 41 NA bisullate 61 NA 41 NA 61 NA 11 NA Potasswm dlchromsle. 5% 61 NA 41 NA PolPssslum permangana1e Proplonic Ropiorw Pyrldlne Resorcinol. 46% Sodwm bisulfate Sodaurn bwltile 6, NA 41 NA 61 NA 41 NA aad, 30% 61 NA 41 NA 61 NA 41 NA 61 NA 41 NA 61 NA 41 NA 61 NA 1 Phosphoric awj.
F
Test E E G E E E E E
F
E E G E E E E E E
I 1 I
EP12 E.212 G.212 G.212 E.300 E-300 E.300 E-300
20% 50%
6, NA
41 NA
1
1
Test E E E F E E E F E NR
I F-212 E.233 E-223 E.300 l=.!aY 1 i
61 NA
41 NA
methyl arsenate
61 NA 41 NA 61 NA 41 NA 61 NA 61 NA 41 NA 61 NA 41 NA 61 NA 11 NA 61 NA 41 NA 61 NA 41 NA 61 NA 41 NA 61 NA 41 NA 61 NA 41 NA 61 NA 41 NA 61 NA
____
Nitric acid. 2% maximum (with sulturic acid not recommended) Ntlrilotriacetic Nitrobenzene Nitrophenol n.Octyl alcohol W3ctyl chloride aud
1
1
, G _ 11NA I NF) _ .
NR E E E E E E E E E E E E E E E NR r.
I
Potassium cyanide G E E E E E E E E G E E E E G F E E F-212 HR.212 F-2t2 E-265 F-212 E.212 E.212 E-212 E.265 G-265 G.xx) E.200 E-212 E.212 E.212 G.212
1
1
F E
I F 1 F
1 NR
1 I I I
E-212
_.
NR
E E E E NR NR G G E E E E G G E E E E F F G E
l #d. lCQ*A
E-212
Oleic acid Oxsl~c wad. 20% PlWil FetachloroethSe Pentan&ione Pwchloroethylene
Eaco E-300 E.303 E-300
_. .
Al NA 61 NA
E E
1 1
E-212 E-212
(continued)
TABLE 1.53:
PHENOL-FORMALDEHYDE
AND FURFURYL
ALCOHOL-F0
ALDEHYDE
RESINS-AMETEK,
HAVEG DIVISION
(continued)
Chemiul
Service
Grade
BOF
160-F
Maximum Temperature -F
Grads
4 NA
80F
1SOF
ND
Temperature F
-rest
E TfZ.1 E E E
61 NA
E Nfi E E F
E-212 E.212 G.212
PI NA 67 NA 41 kA 61 NA
Synthetic Resins and Polymers TABLE 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND
179
RESIN SERIES
CHARACTERISTICS
SUGGESTED APPLICATIONS
H-RON
92
Maximun fwe retardancy. Class I flame spread cm he achreved. Good corrosion resistance. Habganated polyester. Maxbtmn corrosbn and heat resistance. Class I or II flame spread can be achiiad.
Frimmily for severe fume handling equipment to 25OF.
HETRON 197
All eqwpment where maxrmum corrosron and heat resrstance are required - intemrittent service to about 600F: contrnuously rn 350F range. Excelbnt for hot wet chlorine and other hrghly oxidizing environments. General corrosbn resrstant equrpmant. linings, coatmgs. toppings, All corrosbn resrstant equipmmt except fume handhng systems to about 250F. Ideal for caustrc and hvwchbnte.
HETRON 72 HITRON 700 HETRON 900 I AROPOL 7240

Series (Includes 7241 and 7242)
Similar to HETRON 197 series. 9isphanol~A Fumarate resins. Excellent corm&on resistance. Non-fire retardant. Vinyl ester restns. Nonfire retardant. Excellent corrosron resistance. Isophthahc resins. Nonfire retardant. Moderate corrosbn resistance.
All equipment except fume handling systems to about 190 F. AFtOf 7242 can be used for FDA applicatrons.
AROPOL 7430
Series (Includes 7530 and 7532)
Resilient isophthahc resms. Nonfire retardant. Moderate corrosbn resrstance.
All equpment except fume handling systems to about 150F. Excaflent for filament winding applicatrons.
HETRON 99P
.
Fee retardantlisophthafic with grnrd mrrosbn resistance. Class I f&ins spread can be achiied.
For ftane handling equipment to 250F.
The following
definitions
will aid readers using this Guide. Asterisks - Resins marked with an asterisk indicate that it is preferable to use this resin over another resin even though both are resistant at the temperatures listed in the Guide. LS - Indicates that limited service life can be expected. This means that some chemical attack will occur but not enough to render the equipment useless. NRResin is not recommended.
Service Temperature - Temperature data is not

necessarily the maximum service temperature. It is the upper temperature at which a specific resin has been satisfactorily tested or used. AMB Refers to ambient temperature of 7!XOF.
Blank Space - Showing no service temperature recommendation indicates that insufficient resistance data was available. It does not mean that the resin is unsuitable for that environment.
I CHEMICAL ENVIRONMENT Acid: Salt CONCEN. TRATION %
I \
SERVICE
TEMPERATURE.
OF FOR RESIN TYPES
ACID: SALT ENVIRONMENT.
HETRON 92 SERIES LAMINATES.
GOOD FOR 25oF VAPORS FROM THE ACID: SALT SOLUTION. HETRON 99P recommended for fume service only.
THESE RESINS RECOMMENDED AT AMB. (AMBIENT 7540F) TEMPERATURE OR TEMPERATURE IN F SHOWN FOR ESTIMATED 10.15 YEAR LIFE. HETRON 197 SERIES RESIN PRE. FERRED AT 2UOF OVER HETRON 72 SERIES RESIN AT 2OOF. THESE RESINS MAY BE SUITABLE AT HIGHER TEMPERATURES BUT NO DATA IS AVAILABLE. HETRON 922 RESIN RECOMMENDED FOR LIMITED SERVICE. AT 100-F WITH ABOUT 5 YEAR SERVICE LIFE.
(continued)
180
Corrosion
Resistant
Materials
Handbook
TABLE
1.54:
POLYESTER
AND VINYL
ESTER RESINS-ASHLAND
(continued)
List of Trademarks and Product Names

Adogall* ... Aemsol . Allpal .......... Abdlrm ........ Am&em . Amerex . . . . . . . . Amine Salt Solutbns. 73g73 M-A, m-0, M-C Sherex Chemical Co. American Cyanamid Co. Chemical Div., GAF Corp. Amchem Products Inc. Amchem Products Inc. Drew Chemical Corp. W. R. Grace Co., Dewey 8 Almy Div. American Mineral Spirits Co. International Dioxide Inc. Wyandotte Chemical Co., J. P. Ford Div. Armak Co. Armak Co. Wyandotte Chemical Co., J. P. Ford Div. Velsicol Chemical Corp. Bet2 Laboratories, Inc. Drew Chemical Corp. Oxy Metal Industries Corp., Parker Div. Spartan Chemical Co., Inc. Colgate-Palmolive Co. Hooker Chemicals & Plastics Corp. Calaon Coro. Union Carbide Corp. Union Carbide Corp. Rowe Products Co. Ashland Oil, Inc. Dow Chemical Co. Peabody Engineered Systems Quaker Chemical Co. Drew Chemical Corp. American Cyanamid Co. American Cyanamid Co. W. R. Grace Co., Dewey 8 Almy Div. W. R. Grace Co., Dewey 8 Almy Div. Arapahoe Chemicals Huntington Laboratories Diversey Chemical Co. Dow Chemical Co. Drew Chemical Corp. Hooker Chemicals & Plastics Corp. Staley Chemical Co. Union Carbide Corp. Economics Laboratory, Union Carbide Corp. Ashland Oil, Inc. Stauffer Chemical Co. Ciba-Geigy Corporation Union Carbide Corp. Pennwalt Corp. 3M Co. Hooker Chemicals 8 Plastics Corp. Buffalo Color Corp. Rohm 8 Haas Spartan Chemical Co., Inc. Inc. Gbhrlte 15, X-200 ......... GokbnGb .............. Halao Sg Ashland Oil, Inc. Spartan Chemical Co., Inc. Hooker Chemicals 8 Plastics Corp. Chemical Div., GAF Corp. Ciba-Geigy Corporation Ashland Oil, Inc. The Richardson Co. Johns-Manville Hercules Powder Co. Monsanto Co. General Mills Chemicals, American Cyanamid Co. Huntington Laboratories Dye & Chemical Co. of Canada, Ltd. Shell Chemical Co. Oakite Products, Inc. Olin Chemical BASF Wyandotte Corp. Olin Chemical Oxy Metal Industries Corp., Parker Div. Oxy Metal Industries Corp., Parker Div. G. H. Packwood Mfg. Co. Spartan Chemical Co., Inc. Ashland Oil, Inc. Spartan Chemical Co., Inc. Borden Co. Uniroyal, Inc. Wyandotte Chemical Co., J. P. Ford Div. The Richardson Co. The Richardson Co. Ashland Oil, Inc. Envair, Inc. Spartan Chemical Co., Inc. Monsanto Co. Sherex Chemical Co. Tretolite Div., Petrolite Co. H. B. Fuller Company Dow Chemical Co. Union Carbide Corp. Olin Chemical Olin Chemical BASF Wyandotte Corp. Ciba-Geigy Corporation Staley Chemical Co. Atlantic Richfield Sherex Chemical Co. Sherex Chemical Co. Sherex Chemical Co. Exxon Company Dow Chemical Co. Gcoch Feed Mill Corp. W. E. Zimmite. Inc. Inc
................
Amsco BKOH Solvent

Anthlum Dbxtde
Igepal .................. lrgasd DA ............... Isocure ................. Isoprep ................. JM-235, JM-271
Apache Amlaal
...........
Kymene ................. Lasso .................. Lix 54N ................. Magnllbc .............. Matar .................. Mulsollne .............. Neodol ................. Oaklte ................. Olin ................... i%lD.. ................. OPM-i,OPM-2 ...........
Arquad Benteo
. .
Bmuoflu:Brominex
Betxsulllte3.. Blocida CWT.102. Bondarlte
Bowlcloanm
Build C-56 Calgun . .
carbitd
Celbeolve cell Putty Cham-Rex c2m5. C-2009, C-2075 Chbrothene Clhex clealler508..... CWTlM Cyaf cygon
. .
Parco...................
Pax Hyspeed ........ PD34 .............. PepSet.. .......... Plus 6 .............. Polyco ............. Pdywet ............ Raylene ................. Rkhamlde ............... Rkhonate ............... RJ.4 .................... Sam-Fresh
Darux ___.._..___..___,.. Daxad DFR.121 Dkrohe Diversey ..__....__..__...
Dowclem
DmwSpenN Durex DW-575
SD-20 ......... Skydrol ....... Softener B ..... SP-101 ........

Stackfas Mastic Telona .................. Tergitol ................. Textone ................. Thermolln ............... 35D.. .................. Tlnoflx OF ...............
Dynd
Electrasol Elvase EP 52.A55 Eptam Erbnal NW EVA Exalt _. FClW, 2w, 206A Fluomluhes Furbn 12.62
u-3400, U7ooo. ........... Ultrawet ................

Varlquat Varlsoft Vamx 155E Varsol . . vtdden VlvoZyne . Zlmmite
. ..
........ ........ ........ ........ ........ ........ ..
G.51 Glass Cleaner
..
(continued)
Synthetic Resins and Polymers TABLE 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND (continued)
181
HETRONandAROPOL ResinSelection Guide ior Corrosion Resistant RTPAPPliceti0n-s

SERVICE TEMPERATURE, OF FOR RESIN TYPES HETRON 920 sEmw9so NR 90 2101220 2101220 21w22u 160 lXU180220 NFUNR NR NWNR NR NR NR --/lSQ NR NR NR NR _ NR NR _
CHEMICAL ENVIRONMENT Acotaldehyda ................ Acotaldehyde, 1% In air ........ Acetaldehyde Fumes .......... Acetk Acid .................. Acetk Acid .................. Aoetlc Acid .................. Acetk Acid .................. Acetic Acid ............................ Aoetk Aotd. about 10% In Hydrocarbon, Liquor end vapor ..................... Acetic ACM. Glackl ..................... Acetk Acid. Gkckl ..................... Acetlc: Gkckl: 70% Nltrlc: 49% Hydrolluorlc AcetIc ACM: HCI ........................ Acetlc: HCI: H,O ........................ Aoetlc: H,O, ............................ Acetic Acid: Sodium Dkhromato ........... Acetlc Actd Vapor ............... Acetic Acid, Vapor 6 Condensate . . Acetic Anhydrtdo ............... Acetic Anhydrlde ......................... Acetone ................................. Acetone ................................. Acetone ................................. Acetona: Cyclohoxanc Hexane: Water ........ Acetorw Water ........................... Acetonltrtk .............................. Acetophenona ............................ Acetyl Chlorldo ........................... Awtyl Chkrlde ........................... Acid Rinse, PhotographIc .................... Acldlc Gaseous Atmosphem, Saturated, Weak Phoaphorlc, Hydrolluork. Sulfurous, Etc., at 3900 fpm .............. Aclda (Sullurk, Phosphork, Acetic), Soda Ash, Organk Salts, Dye Sulk, 2.5%Soll&,pH2-5.. .................... Acrykmlde .............................. Acrylk Actd .............................. Acrylk Acid .............................. Acrylic Acid .............................. Acrylic dlrperslon: Acryknltrlk ............... Acrylic dkpersion: Vlnylldene Chloride ........ Acrylic Emulrlon ........................... Acrylic, Glrclrl ............................ Acrylk Spray Liner, Water Reduolbk at 12OF(PPG Indwtrks) .................. Acrylic Stynne Emulsknst DW-975, U-3400, U.7091 ................... Acrylk Wet Ink Vamk h. Water Reduclbk at 120F(PPG Industrka) .................. Acrylonitrlk ............................... Actlvatad Carbon Bedr, Water Treatment ...... Adlpk Acid, Adipyl Chloride and Hydrochloric ACM ........................ Adlpyl Chlortde, Adlpk Aold and Hydrochkrk Ad0g.n~381: xylem ....................... .............................. AdottAdo9en449 .............................. Aemsolt, Wettlng Agent .................... Alr, Humid, Trace Sulfur Fumes ............... Air: Methyl Sulfide: Methanol; Smell Amounts H,O. H,S, Methyl Mercrptrn, Acetone, TurPentlne ............ Alcohol, Ethoxylatad, pH 8.5, C,,.C,, ...........
CONCENTRATION %
100 (40 Ibsm 10 15 25 50 75
NETRON 92/99P NRI490 90

150
HETRON 72/197119711 NR 210 210 210 125
MOP01 724017430 SERYS NR 170/150 170/150 17ol150 1541125
HETRON 700170Oc NR 2101200 21omo 21wW 150 16a150 -
125 125 AMBKJO
100 100 @ 120-F 3:5:1 @ 1WF 50:2U 50:16.5:315 95:1.5 la, 70:30 @ 212-F
10011ocu1w LYLSJNR NR AMB 66 AMB 160 160 loo LS/LS/NR NR NR NR AMB NR AI.40 NR NR NR NR NR NR NR NR 150
NR/AMB/66 AM0 NW1801NR NR NR
NR NR AMBlNR NR NR NR -
25 100 1W @ 12o.F 10 100 100 @ 133F 10:10:1:79 1090 100 1W 100 100 @ 13OF -
NR/-
90
Unknown 50 100 @ 1WF 25 10 96:2 9&2 loo NR _ -
-/to 165/--1wNR loo 100 AMB AM0 90 --I-/NR AM0 --I-/NR NR 2al lMYlW/NR 120 120 AMB 200
NR 100 120/NR NR NR 120/120 1201120 -
10 165/NR AM0 loo _ SAT SAT NR NR NR 120 120 -
lo 16YAMBllOO AMBilW _ SATISATINR _ 120/12W-
loo
NRI12W120/AMBI-
Unknown Unknown 25:75
652.56 100
165 120
_ 120
_ -
SAT under SERVICE TEMPERATURE = S.stisl.%tory With mlemnce to mcommendaNons under s ,gqyh;;;?l;gps. W_UT%Y= First two msrerials sat at 1 msisrance unknown 100/100 = Both mareriels sefislactoty, tirsl pn?lwr&, efc. 125 = Pmhrmd mahrial, a/thou h others sm suifabfe at 125 .R. 100150 = Temperalum varied w!I m hmlls shown tSee list of trademarks and product namt?s.
(continued)
182
TABLE
1.54:
POLYESTER
AND VINYL
SERVICE
bxntinued)
TEMPERATURE F FOR RESIN TYPFS HETRON 920 SEAIESI9.90
CHEMICAL ENVIRONMENT Algaecide, phenate based ............... Alipal C0433t ........................ Alkaline Film Stripper, Butyl Cellosolve: Monoethanol-Amine @ 136F ............ Alkaline Soak Cleaner ................. Atkanolamide, Fatty Acid ................... Alkanolamide Nonionic Surfactant ........... Alkyl Benzene Sulfonic Acid ............... Alkyl Dimethyl Benzyl Ammonium Chloride: Phosphoric Acid: Inerts .................. Alkyl Dimethyl Beruyl Ammonium Chloride: Tributyl Tin Chloride/Ethylene Oxide/Amine: Hydrochloric Acid: Inerts ................ Alkyl Ether Amine Oxide Surlactant .......... Alkylate, Substituted Benzene Type, Relinery Alkylate Sulfonates, Linear ................. Atkylrtion, Aromatk Hydrocarbon ........... Ally1 Chlortde ............................. AlmondOtt ............................... Alodine 461/45t, pti 2 ...................... Alpha Otefin Sulfonate ..................... Alum ................................... Alum ................................... Alum, Potassium .......................... Aluminum Chloride ........................ Aluminum Chloride: Fluosllkk AtId ......... Aluminum Chloride Spent Catalyst Solution, 1DWppmBenzene rB13tt.F .............. Alumlnum Chlorohydmte ................... Aluminum Chlorohydroxlde ................. Aluminum Citrate ......................... Aluminum Desmutter 6 Deoxidtzer .......... Aluminum Etchant. Phosphate Free ......... Aluminum Fluorlde ....................... Aluminum Hardening Fixing Bath, , .......................... Photographic Aluminum Hardening Raptd Fbtlng Bath, Photographic ...................... Alumlnum Hydroxide ..................... Aluminum Hydroxide ..................... Aluminum Nltrate ......................... Aluminum Oxide Drying .................... Aluminum Oxide Wet with HCI, Drying ........ Aluminum PIatlng,Sulfuric, Sodium Dlchromate ..................... Aluminum Potassium Sulhte ................ Aluminum Potassium Sulfate, Vepor & Condensate.. ........................... Aluminum Reduction Pot Plant Rooflng andSIdIng .............................. Aluminum Sulfate .......................... Aluminum Trkhloride ....................... Amchem 616t: Nitric ....................... Amemx 2Dlt .............................. Amerex 209t .............................. Amine Salt Solutions, 73673 MA, M.Band MCt ........................... 2.Aminoethanol ............................ Amlnoethoxy Ethanol rB 2TO.F ... , ........... Aminoethyl Piperezlne ...................... Ammonia, Dry ............................. Ammonla, Liquid ........................... Ammonia, Wet ............................ Ammonia: Ammonium Nitrate: Hydra fluosilkk: Nitric: Phosphoric 6 Sullurlc, Wet Vapor ......................
CONCEN. TRATION %
100
HETRON 9299P
HETRON 7211971197A 125 100 NR 100 120 100
AROPOL 724017430 SERIES 1251-
HETRON 7001100c 125 1w NR 160 120 -
28
57.30 10 ouga1 55 amtde 100 0.1125.75
NPJ-
NPJ160/-
NR NR
1W
loo/-
0 1:01:23.77 COtlC. Jnknown Q 10512O'F 100 100 100 10 Sat'd 5 All SlImy:2
100 120 AMW-I100
120 AMBI120
1001-
1201-
NIV120 120 2cu 160 125 210 210 1701150 1601150 160130 170/150 -
NR NR
NW30 -
2201200 2w/150 160' 2101150 2101220 2101220 2101220 2101220 16O/165/AM&--
-!120
NR 17ol150 170/120 2OOll50 2001150 2w/150 1651150 AM0
50 50 Sat'd
165
AMB 5oz/gal All AMBiW AMB 60 60 165!AMB
Satd 20 Sald -
220/2901220&?90/160 150 16wl40 1701150 -
AMB AM0 170/150 -
180/200 16W2W 160/160 -
All
-/lso
210 160 250 210 6595 125 125 65
17w150
2101220
5 FUllas
All 40 6:16 103 100
16OJ13Oi250 -
1601150 LS125 125 -
1701150 6595 125 125
210/230 -
100 100 100
NfU90 NFU-I90
65 NR NR 90 NR -
NR NR AMBINR AM&LYNR NR 90 601NR NWNWlW1160 lW/lM
Gas
100
Gas
15:5:2.5:2.5:Trace
250
NR
HETRON SSP for fums service only IGood fesf results a/far shon axoosum Synthehc suriacing WI/ recommended lor ax~mu msistance l3enzo / Peroxrde - D#methyl am/ins cum system recommended SaYISr sctory satwcc Post-cure racommendbd Solution may discolor Nonrh!xotroprc resms preleradle Unsetlslacro/y as /mmg
to assure
Acceptable ss to odor end tasfe Ior AROPOL 7242 type resm. SNamed 4 hours wirh atmospheric steam pnor to axposum *Three 3 hour exposures to 30% nitric at 1CiYF to simulate cksnin No dwxlorstion occurs af 5 lt/ga/. sod wrfh AROPOL 7242 and A ETRON 7W ryps construcfmn il surfaces are acid or steam cbanad *C veil on/ -AROPOL 7r 4OOnly *Apoears to be erosion/corms!on AROPOL 7240 SAT al 1ZOF 1See M 01 trademarks and oroducl names
(continued)
. .
:
. . 5:::..2..::::::: . . . . . .,.;jc:; ::::::::::::: . . : : . : : ::: 1:: : :::: ::: :::

a:. .p..,::::::::.::: . . . . . . . . . . . . . . . . . . .
::
::.
::
::::::::
::.:::
: G
184
Corrosion
Resistant
Materials
Handbook
TABLE
1.54:
POLYESTER
AND VINYL
ESTER RESIIN! j-ASHLAND

SERVICE
(continued)
TEMPERATURE, F FOR RESIN TYPES HETAON 920 SERIES1980 HETRON 72/197/197A 180 130/110/160 130/110/100/1w/AMB NR 200 140 -/LS/NR 65 125 AROPOL 724017430 SERIES HETAON 700/790c
CHEMICAL ENVIRONMENT Ammonium Thiocyanate: Hydrochloric Acid Ammonium Thiocyanate: Thiosuliate: Sulfate: Water ........................ Ammonium Thiosuliate ................... Ammonium Thiosuliate: Thiocyanate: Sulfate: Water ......................... Ammonium Tungstate .................... Amsco BKOH Solventt .................... Amyl Acetate ............................ Amyl Acetate @ 120F .................... Amyl Alcohol ............................ Amy1 Alcohol ............................ Amy1 Chloride @ 120-F ................... Anaerobic Sewage ....................... Aniline ................................. Aniline Hydrochloride ..................... Anlllne Hydrochloride, Substltuted: HB r. HCI: Br,: H,O ..................... Anlllne Sulfate ........................... Anionlc Polyelactrolytes, Blend ............. Anionic Suriactant ....................... Anodizing Solutions ...................... Anthium Dloxidet ........................ Anthracene Oil ......................... Anthraquinone Disulionic Acid Q 150F ..... Antimony Pentachloride ................... Antimony Trlchloride ....... ....... .... Apachet ............................... Apple Acid .............................. Aqua Ragia (Cont. Hydrochloric: Cont. Nitric, 33) ....................... Aqua Regia ....................... Aqua Ragla Fumes ................. Armeen Ct ........................ Armeen DMCDt .................. Aromatlc Hydrocarbon Alkylatlon ..... Aromatic Solvent: Tributyl Phosphate ArquadUSOt ...................... Arsenic Acid ....................... ArsenouoAcid ..................... Asphalt .......................... Atmosphere, Chemical Plant ......... Atmosphere. Coal Dust ............. Atmosphere, 100% Relative Humidity Axelaic Acid ....................... B Crude 011 ..................... Bacterlclde Phenate Based .......... Barlum Acetate .................... Barium Carbonate ................. Barium Chloride ................... Barium Hydroxide ................. Barium Hydroxide ................. Barium Sulfate .................... Barium Sulfide .................... .......... Beer Beer, BrewIn; I&i; &ei ......... Bwt Sugar Liquor .................. Bentact ......................... Berual Chloride .................... Benzaldehyde ..................... Benzene .......................... Benzene @ 120F .................. Benzene @ 2WF.. ................ Benzene, HCI (trace), Water ......... Benzene I Hydrogen Chloride Vapors Benzene, Vapor .................... Benzene, Wet Acid (HCI) ............. Benzene: Ethyl Benzene ............. Benzene Disulionlc Acid ............ Benzene Sulionic Acid .............. Benzene Sulionic Acid .............. Benzene Sulionic Acid ............. Benzene Sulionic Acid: Sulfuric: Water Benzoilex 9.SEt .................... Benzoic Acid .....................
tSee l!st of trademarks and product names
CONCEN. TRATION %
HETAON 92199P
4:5.5:2.3:68 60 5.5:4:2.3&I Satd lco All 100 All Vapor loo _ IM) loo 15:4.5:1.5:1:76 Satd 100 56 COllC 6 100 Satd 50 10 2iW150 AMBIAMBf90 2CO/l&l AMBI160 1oollOO/120/-
130/110 NR 130/110 lOO/NR NR IWNA 140 NR 65 NR NR LS12YNR AMB SATIAMB 1601150 NR NR NR NR 120 120 AMBI195/100 100 120 _ AMB 125 NR LSl6OINR 1601150 LS.AMB/NR NR 170/15u NR AMB 150 NR NR LS:AMB/NR NR NR AMB 15OlNR NR NR 140 120 170/150
130/110 130/110 LS/NR NR NR 1601120 140 NR 65 NR l&3/140 225l220 125 120 _ NR AMB AMB 130/NR NR NR 120 NR 120 160 100 100 120 _ 125 160 200 200 200/l 50 150 160 150/b AMBlNR NR NR NR NR 200 200 140 120 2201200
130/lCO/130 100 NW100 NRJ1w/200 NPJSAT 65 NW150/160 140/1601220 _ SATIWI2001220 NR NR 60/16O/100 100 120 lW210/220 210/1501160 150/2101160/AMBINR 16O/NR/NR/NRilOO NR NR _ 2 101220 SAT 210/220 140/120/210/-
-/NR AMBIW NR 200 140/NR 65 NW-
14011401Ls140 200 125 120 AMB 100 AMB --ISAT/NR AMB 200 150 95 130 AMB 120 120 120 AMB 120 180 100 100 120 AMB 125 160 200 200 _ 160 NR 150 160 NR AMB NR LS 176 65 AMB AMB 100 194 200 NR 100 140 120 250
Cont.@ 160F COW COW. COX. 65% COW. All 19 Be Satd 100
Satd All All 10 Satd All Satd 50 100 1W 100 100 100
-/NR 2ca160 200 NWNW--/150 -/NR NR 15WNFUAMBISO NR/NRIAMWAMBI160 NFUAM B/W 250
vapors
1/3:2!3 100 30 loO@ 16OF Satd 68715 1CO Satd
(continued)
Synthetic Resins and Polpm
185
TABLE
1.54:
POLYESTER
AND VINYL
SERVICE
(continued)
TEMPERATURE, F FOR RESIN TYPES HETRON Pm SIIIIFI~PI HETTROll 7211971197A
AM0
CHEMICAL ENVIRONMENT Benroic Anhydride ...... ..... Benzotnchloride Benzoyl Benzoic Acid to) ..... : : : ::: Benzoyl Chloride .... Benzoyl Chloride Vapors with HCI, H,O, Benroic Acid .................. ........... Benzyl Alcohol ........... Benzyl Benzoate ........................ Benzyl Chloride .......................... BetzSullite3t,pH5.5.. ................... ................. Biocidet 207 Biocidet 205 @ 125OF : : ................... Biocide: Chlorophenate, Organic Sulfur Type Biocide; Chlorophenol, Methylone Thiocyanate Blend @ 125F ............. Biodegradable, All Purpose Liquid Cleaner .......................... Biodegradable Detergent, Liquld ............. Biodegradable Detergent Ultrawrtt 5OK ....... Biodegradable Dotergent Ultrawott 4tiDS ..... Biodegradable Detergent Ultrawrtt BOL ....... BKOH, AmscoT. Solvent .................... Black Chrome Bath: Chromic, Acetic, Barium, Acetate ........................ Black Liquor, pti > 7 ...................... Black Liquor Recovery Fumaca Gases @ 210.325*F .......................... Black Liquor Room Flooring, Spills ........... Black Liquor, Spent Sulfite, Calcium Bass Mill pH 1.52 (Trace Formic & Acatate) ...... Blanch, Peanut, Hot Water, Detergent @ 16QF ...................... Bleach, Ferricyanide with K Bromide for Photography ......................... Bleach Reactor. 6% Sodlum Hypochlorlta .... Bleached Pulp ............................. Blow Gas Absorber ......................... Bonderitet 73 ............................ Bonderitet 722X? .......................... Bondarttrt K.7lCl-g 701-P .................... Bonderitet K.761. pH 56 .................... Bonderitet 37,3?S, 39 ...................... Bondoritet 721-S .......................... Bonderitet 1303 Makeup .................... Bonderitet 1303 Replenishing ................ Borax .................................... Bordeaux Mlxturo .......................... Bork Acid ................................ Boric Acid: Nickel Chlorlda Nkkrl Sulfate ...... Boric Acid: Sodium Sulfate with 0.25% Sulfuric Acid, 0.03% H,O,, 100 ppm Iron, 3OG3 ppm Chloride, Temperature Cycled .... Bottle Washer Solution ..................... Bowl Cleanset ............................ BowlCleanse,MildT ........................ Brake Fluid ............................... Brass Plating Solutton 3% Coppen 1% Zinc and 5.6% Sodium Cyanides, 3% Sodium Carbonate ............................. Brew Kettle Fumes ......................... Brine,CI,Sat.,pH2 ......................... Brine, Dechlorinatsd: pH 2-3, Free Chlorine (Traces) @ 2W~22gDF ............. Brine, Salt ................................ Broke Chest Fumes ........................ Bromine, Dry Gas .......................... BromineFumes ............................ Bromine, Liquid ............................ Bromine Water ............................ Bromine: Water ............................ Bromine, Wet Gas ......................... Bronze Plating, 4% Copper, 5% Sodium Cyanides, 3% Sodium Carbonate, 4.5% Rochelle Salts .............. Brown Stock Washer Hoods, Ducts .... : : : : tSee list Of tradem.wks and product names
*HETROf, c,d,,,dns rg, ,nd 700 IC,,CI w,,h Some crazmo
CONCEN. TRATION % loo loo All 100

Jnknown Gt 194-221 1W 100 100 ID0 100 100 IW
WETROM 92199P
AROKIL 7240/7430 SERIES
WETRON 7001700c
NFCNPJNR -/NR NRINR 200 125 LS/LYNR 125 LSiLYNR 100 NR
NR NR
NR
_
NW-
210:NRJ-
NPJNR NR 125 SAT 125 SAT loo 1tM AMBlNR NR 200 125 SAT 125 NW30 NW0 -
SAT
loo loo
loo/1001-
IO0 loo 100 loo
1w 150 130 100 lWfloo/115
lW/NR
LYNR 2201180 NR AMB
loo/21OQ20 NWSAT
NRINR --ISAT/NR
NR
@ ZlZF 80 140 190 185 1M 100 120 150 a5 NR NR -
NR NR -
NFU-
NR -
12wNR 100 loo loo/loo/210/210122u , -
Satd
Satd &I253 agal -/180 -
167mcVI67 140 200 180
1801140 1BoIlXl
22CV140 2W
1525 5.10
--12ow206 loo 1w -
-I206
loo
2061I ?O/twiloOiNFVIX)
IW
lXV300310 S&d Satd la, la3 Satd @ 75-F 5% 100 AM&W 180 SATi AMBFaO 14WNRIgpl
180 150 220 SAT 220 SAT AMB 140 NR
IM NR
180 2121200
IBOI2101220 NR,-
1801150 NR NR NR NR NR
200 AM0 NR
210/220 Boll00 AMBIIW NR SAT 180/2w 80
AMB
,es,ns rpprrr 10 DC unswtabk under but l e n?sisf&7f under SUIK CondmnS.
CyCllC
180SATISAT SAT 'D,Ssolvcd solids. 1574.2183 ppm PO.. 0.25 ppm: rota/ PO.. 1.3 ~ppm: CU. 0 7 pm. In. 3.4 pppm. Fe. 7.8 ppm: C&o, 4x) ppm mar.. Chromafr. hexa. 18.22 ppm Cl2 rosrduel.02045 p@n:NeCl. 527.02 pprn
(continued)
186
Corrosion
Resistant
Materials Handbook
TABLE
1.54:
POLYESTER
AND VINYL
CONCENTRATION %
1012'b sollos loo 100 100 HETROW' 92199P
(continued)
RESIN TYPES HETAON 920 SERIES,980 1:: .P 60 120 8G'?20 %3'120 NRIOO 21G,NR8C' 160'180 NR210*16C 160,N9100 _ 180,HETRON 721197;197A 120' a5 85 AM0 80 100 100 100 85 85 NR 80 AMB 100 120 NR 120 AMB AM0 200 180 90 90 AROPOL 7240:7430 SERIES HETRON 700 7ooc '20 _ _ AMB lCK!NR 220150 NR 80 NR 2001120 NR 120 200:150 150 AMB NR -
SERVICETEMPERATURE.'FFOR
CHEMICAL ENVIRONMENT Build? Detergent Solution. pli 9.10 Butadisne Latex ........... P.Butoxyethanol 2.2.Butoxvethoxvethanol : : : .. :. ....... B;tyl Acetate : ... Butyl Alcohol: Ethyl Hrxylacatate: Di4sobutyl Ketone ...................... Butyl Alcohol, Normal .................... Butyl Alcohol, Secondary ................... Butyl Alcohol, Tertiary ..................... Butyl Carbitolt ........................... Butyl Cellosolvet ................... Butyl Cellosolvet: Monoethanolamine Film Stripper Q 136F ................. Butyl Ether .... Butyl Ether. Phosphorfc: ~Hydr&lo& : : : :,I : : Butyl Phthalate ........................... Butylamlne .............................. Butylena Glycol ........................... Butylrne Oxide ........................... Butyric Acid ................. ......... Butyric Acid ............................. Butyric Acid .......................... Butyric Acid ............................. C56T .................................. C.56t.Crudo ............................. C56t; High Purfty ......................... C56T; Beg. P High Purfty Wet With H,O ....... Cadmium Cyanide Plating Bath, (3% Cadmium Oxide; 10% Sodium Cyanide; 12% Sodium Hydroxide) ............................ Calcium Bisulfide ......................... Calcium Bisulfite ......................... Calcium CarbonateJ ....................... Calcium Carbonate, 90%; Magnesium Hydroxide, 10%; Nickel & Iron Hydroxides . Calcium Chlorate ......................... Calcium Chloride ......................... Calcium Chloride, pH 5.5 ................... Calcium Chloride, pH 8.5 ................... Calcium Chloride: Phosphoric Acid ........... Calcium Chloride: Sodium Chloride: Magnesium Chloride .................... Calcium Hydroxide ....................... Calcium Hydroxide ....................... Calcium Hydroxide ....................... Calcium Hypochlorttea ................... Calcium: Magnesium: Sodium Chlorides ...... Calcium Nitrate ........................... Calcium Oxide ............................ Calcium Sulfate .......................... Camphene, Chlorinated 68%: Xylene ......... Camphor ............................... Can Cleaner, Acidic, pH 1.2, Sulfuric & Hydrofluoric, Aluminum 6 Oil Impurities ............................. Can Treatment, ChromeFree, pH 5-6 ......... Can Treatment, Chrome Phosphate, pH 2 ...... CaneSugar Liquor.. ...................... Canning Plant Waste ...................... Capric Acid .............................. Capric Acid .............................. Caprylic Acid ............................. Caprylic Acid ............................ Carbamide .............................. Carbon Beds, Water Treatment .............. CO,: SO,: N,: 0,: H,O Vapors ................ Carbon Dioxide, Wet. Acidic ................. Carbon Disulflde .......................... Carbon Dlsulfide Recovery Fumes ............ Carbon Disulfide Vapor ..................... Carbon Monoxide Gas ...................... Carbon Tetrachloride ....................... Carbon Tetrachloride, Vapor .............. Carbonic Acid .................... .......
AMBi90 -I93 -90 -1190 -ma NPJ801-/160 NW12OI150 -/150 --I150 AMBIwix%-
mLSAMB,luR 8OINR 80INR BOINR 851NR *0.:_ 1601140 NR 120 15oi130 1501NR -
5 10:85
100 100 100 100 100 5730 100 Unknown 100 IOU @ 75-F 100 100 25 50 70 100 100 100 99+
Sat'd Sal'd Sat'd 25 Sat'd Sat'd 55 35 2510 10:12:2 15 25 Sat'd Sat'd 10:2:12 Sal'd Sat'd Sat'd 90.10 100 @75-F -I170 -/160 25cf180 2M -
NR _ 250 250 --127e*/--12w100 150 175'/175/120 150
NR 16011701110 160!140 --ILSI20 1501120 lEo/15c 180193 160190 120/1801150 18OflM NR
220~200 1.60 210 200 225/220 27&23&_ 180 160 160 120 2201200 22012cO -
210~220 _ 180 210220 210>220 2101220 180,160,180 210'220 2101220 -
--/lM) --ilfxJ -/160 -I100 -llE!O
150 250/200 --INR 250 122 -
120 120 120
160 160 16C 160 160190 250/200 NR 160 NR NR AMB 21013ol NR 210,300 LSAMB150 AMB.150 AMB 180 NRBO 180200 NR80 !80:200 1601-
Sat'd 5 Satd 5 Sat'd 12zO0.1:70:5:14vol by 100 100 25 100 100 100 Sal'd 250 NR 140 NRI160/200 125/14OlAMB 160 --I160 --116O 140 140 160 200 120 250 NR 160 125' 140 160 AM0 160/120 1601120 16OllW 160/100 150190 2W/lYl NR NR NR 2001150 LS.AMB.NR AM0 16Oi130
tseellsl Of trademarksand "arnes product

(continued)
188
TABLE 1.54:
CHEMICAL ENVIRONMENT
POLYESTER
AND VI
L ESTER RESINS-ASHLAND
SERVICE
(continued)
TEMPERATURE. F FOR RESIN TYPES HETRON 920 SERIES!990 HETRON 721971197A 180
180
CONCEN. TRATION % 5.3 7 35.23 Satd Sald 25 50 COX 3040 Q 110-F 100 100 0 12OF 100 100
HETRON 92 99P
AROPOL 724017430 SERIES
NETRO 700700c
NR _ -
Chlorine Dioxide Process Generator Covers Chlorine Dioxide Retention Tower Chlorine Dioxide: Sodium Carbonate and Bicarbonate. pH 6 Chlorine Dioxrde: SodiumChloride .............. Chlorine Dioxide, Vapor Chlorine Dioxide-Washer Hoods, Ducts ... Chlorine Dioxide, We? .............. Chlorine Dioxide: Sulfuric (lO.Shl) .......... Chloroacatlc Acid ........................ ....... Chloroacetic Acid Chloroacetic Acid ......... : : : ::: Chloroacetic Acid Plant Water Scrubber :: Chlorobenzene .... .. Chlorobenzene Vapor 6 Condensate ... :: Chlorolluocarbon ........................ Chlorofon Alkaloids, HCI, Acetic, Sodium Chloride, Water Fume System ............ Chloroform, Llquid ....................... Chloroform: Methylsno Chlorida: Carbon Tetrachloride, Small Amount Methyl Chloride, ii,O, HCI @ lOOoF ............ Chloroform, Vapor .................. Chlorosulfonic Acid ...................... Chlorothene N.U.f ............... Chlorotoluene (0) .......... : : ........ : : Choline Chloride; Reactlon of Trtmethylamlne HCI and Ethylene Oxide ................. Chromate-Zinc Blend lnhlbltor Strbillzed ... Chrome Acid Plating Bath Vapor ............ Chrome Anodizing Solution .............. Chrome Barrel Plating Fumes ............. Chrome Bath, Black, Chromic, Acetic, Barium Acetate ....................... Chrome Bath, 19% Chromic Acid with Sodium Fluorosilicate and Sulfate ............... Chrome Frae Can Treatment, pH 6 .......... Chrome, Hard, Plating Baths ....... :. ...... Chrome Phosphate Can Traatmant, pfi 2 ..... Chrome Plating .......................... Chrome Plating Bath Vapors ............... Chrome Reduction Process ................. Chrome Raductlon Procass Liquor ......... Chromic Acid ........................... Chromic Acid ............................ Chromk Acid ............................ Chromic Acid ............................ Chromic Acid ............................ Chromk Acid ............................ Chromic Acid ............................ Chromic Acid ............................ Chromic Acid ............................ Chromic Acid ........................... Chromic Acid Evaporator, Vacuum, Recovery Units wlth 20% by Volume Concentrated Sulfuric @ 160-F ....................... Chromic Acid, Intermittent .................. Chromic: Nitric: Hydrofluork Acids .......... Chromic: Nitric Hydrofluork Acids .......... Chromic: Phosphoric: Hydrofluoric Acids ..... Chromic: Phosphoric: Hydrofluoric Acids ..... Chromic Acid: Sodium Fluoride. High Agitation ......................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................... Chrornlc: Sulfurk Acids .................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................... Chromic: Sulfuric Acids .................. Chromic: Sulfuric: Hydrofluosilicic Acids ..... Chromic: Sulfuric: Hydrofluosilicic (Chrome Plating) .. ... Chromic Oxide in 300F end 160FAir, ... Quenched with 1OOF Water, 5060 fps
t&e hsl of trademarks and product names
_ -
1201Qa 1301NR NR NR NR -
_ 200 150 lo(1 NWNRIN F&SO -
loo 120 200 SAT 140 120
NR
120 QO NR NR -
NR
NR NR NR
90 AM6 NR NR 156 At.46 NR
Nh15&NW-
NR
NR
NR
39:65:5 100 100 100 0 6OF 100 @ 200-F
NR NRNRNW-
NR NR NR NR NR NR
NR NR NR -
NR NR NR 160 LS125iNR -
NFUNPJNR -
100 12Ol-
125 200 150 115
125 -
NR-
200 1M 130 1M
NR -
NR NR
100 SAT lOQi120 601100 - 180 NW60 NR NR NR NR NR
Q 100-F @ 12OF 25
22@220/2301230/2w 1% LS2001LSXXllNR 150 140 NR 40 vapor/NR 140 140*11404150 1% 120 2Ockl&Y-
NR -
NR NR NR NR NR NR NR NR NR NR NR
5 10 15 20 30 40 M 6.5 ltwgal 60 Sat d
AMBINR NR NR NR NR NR NR
56 oz/gal 1520 5:2:3 62:1.5 7:40.2 9.3:6.5:11
NR
SAT/-/xx) 60 60 103 100 136
NR NR
NR NR NR NR NR NR
NR NR -
36:ppm
40:0.4 ougal 6353 oz/ga1 33:0.33 or/gal 530.53 odgal 3:16 x)s?g 12.5.16 2032 35.2:O 2:0 4 450305 <2 OUgal NO chemical 150-
NR NR NR NR NR NR
NR NR NR NR NR NR NR
153 140 140 177 16.5 180 225/225/QO 115 115 attack wth
197. not swtabie
due to abrawn
(continued)
189
TABLE
1.54:
POLYESTER
AND VII Ni fL ESTER RESI
S-ASHLAND
HETRON 92/99P
(continued)
AROPOL 724017430 SEAIES HETAON 700/700c HETAON 920 SERIES/980
Chromic: Phosphoric: Hydrofluoric Acids. .... Chromic: Phosphoric: Hydrofluoric Acids. .... ...... ................. Chromic Sulfate Chromium Hardening Fixing Bath, ........ Photographic .. .. Chromium Hardening Stop Bath; Photographic . ........................ Chromium Potassium Sulfate ................ Chromous Sulfate .......................... Citrate Process for SO, Removei .............. Citrext Process for SO, Removal ............. Citric Acid ............................... Citric Acid ............................. .......................... Citric Acid ..... Citric: Lactic Acids ........................ Citric AcidlSuifate/Chlorlde in Mixed Solvents-Minerel Spirlt Type @ 7S-220F .... Clay Slurry 20%, 20% Potash in . Sat.Brine@AMB.. Cleaner 508T .............................. Cleaner, Biodegradable, All Purpose Liquid .................................. Cleaner 8 Disinfectant, Pd 94t ............... Coal Dust Scrubber ........................ Coal. Med. Sulfur, Particulate Scrubber, pH 1.439, Ci560-1200 ppm, 300,ooO ACFM .... Coal/Water Slurry @ 8oF ................... Coatlngs, Water Reducible @ 120F Acrylic Wet Ink Varnish (PPG industries) ..... Polyester White Enamel (PPG industries) ..... Epoxy Spray Liner (PPG Industries) .......... Acrylic Spray Liner (PPG Industries) ......... Cobalt di (2 ethyl hexyl) phosphate: tri-m.butyl phosphate: Shells livestock spray base ...................... Cobalt Nitrate ............................. Cocamidopropyl Betaine .................... Cocamidopropyi Dimethyiamine .............. Coconut Fatty Acid Dlethanoi Amide .......... CoconutOil.. ............................. ............ Codliver Oil .................. Collee Roasting Fumes ................... Combustion Gases, Particulate, Cooling and Washing with Water .................. Condensable Liquor, pH 9, Pulp and Paper Mlii .............................. Cooling Tower Inhibitor, ChromateZinc Blend, stabilized ......................... Coollng Towers ............................ Cooling Water, ph 5.57 .................... ....... Cooling Water, 20 ppm Chromate ........... Copper Acetate ............... Copper Chloride ........................... Copper Chloride: Silver Nitrate ............... Copper Cyanide ........................... Copper Cyenide Plating ..................... Copper Cyanide Plating Bath, (10.5% Copper and 14% Sodium Cyanides; 6% Rochelie Saitsp @ 19tIOF ............................... Copper Cyanide, Potassium Cyanide, Potassium Hvdroxide Copper Electrolytic Cells Copper Extractant, Ion Exchange Oxime Type Copper Fluoride] CopperLeachTanks........................ Copper Matte Dipping Bath, 30% FeCI,; 19% Hydrochloric . . Copper Nitrate Copper Oxide: PbSO,: S: FeO: ZnSO,: Bi,(SOJr Dust ..__.... Copper Oxychloride Copper Oxychloride Copper Pellet Smelter Copper Pickle Bath, Sulfuric/Water _
J-
SERVICE TEMPERATURE, OF FOR RESIN TYPES

HETAON 7211971197A 100 too _ 60 80 150 140 140 160 BP 150
CONCEN. TRATION %
7:40 2
9.3:6.5:11 All _ Satd Satd 50 Satd Satd @ 265-F Unknown 40 Slurry 100 100 Liquor 1O/90 -
-1200 BP1200 _ SAT @ 12 fps
_
150
170/l 40 1601150 160/150 NR -
140 140 160 220 NR _
2101220 BP NR -
160 loo 100 150
Hetron
150 197-3 with abrasion -/-/NR -/--INA NR --I-/NR
resistant NR NW NR NR
Filler Satefactory SAT SAT NR SAT
at 7 fps SATISATINRISAT!-
150/loOI-
30:5:65 Satd 100 100 1W 100 100 100 Satd Satd 1533 Satd Fumes
176 -/140/120 120 100 100 130 125 AMB 160 360 250 AMB 200 160
120/120/14017YAMB -
140/120 120 140175 _ 130
140/120/120/15Ol160 _ _ 130/AMB 170 180 1601160 2101220 _ 2101220 -
125 AMB 1501130 1601130 160/1601150 WNR -
LS125INR AMB 180 2201200 200.
At.40 -/I20 250 200190 -
NW6:3:2 angal 1CHl Satd Q 75F --INR -
NR 175 150 115 150 160 140 200 300/3001175 _ NR 160/140 NR NR -
SAT 200 _ _ 220/200 -
1201_ _ zoo/210/220 _ _ _ -
Satd l&25:25 10.6 3 20 Satd Fumes 1 gal19 gal
1401160 _ 1401AMBI_ tSee
Dissolved so/Ids. 1574.2183 ppm: PO.. 0.25 ppm; tofal PO., 7.3 pprn; Cu. 0.7 ppm; Zn, 3.4 ppm; Fe, 7.8 ppm; CaCo, 450 ppm max.; Chromate, hexa. 18-22 ppm. C/, res,doal, 0.2-0.45 ppm: NaCI, 527.702 ppm.
list 01 trademarks
and product names
(continued)
190
Corrosion
Resistant
Materials
Handbook
TABLE 1.54:
CH.#lCAL ENVIRONMENT
POLYESTER
AND VINYL
SERVICE
(continued)
TEMPERATURE. F FOR RESIN TYPES HETROH 920 SERIES980 20 HETRON 72/1971197A 220 180 SAT I50 250 150 120 loo 100 100 AMB SO 130 AROPOL 7240:7430 SERIES HETRON 700!700c 22Ol220 _ 22o:zw 150 120 1eOllW 180rloo NR 130 2w 200 LS125iNR -
CONCEN. TRATION %
HETROW 92!99P
Copper Pickling Bath (Fe,(SO.),, &SO.) Copper Plating Solution(45% Cu(BF.),; 19% Copper Sulfate; 8% Sulfuric ..... Copper Refining Cells ................. Copper Smelter Fumes ......... CopperSullate ................ ::::...I:. Copper Sulfate: Sulluric ................... Copper Sulfate: Sulh~ric ................... Copper Sullate: Sulfuric Acid ...............
Corn Corn Oil ................................
_ Satd 5-18 50.xX1 1228 100 Slurry All 100 100 100 100 100 100 @ 75-F 100 12:5
f _ 250 15OllWl-/NR -/NR -/NR -/NR
_ 1801120 lM/100 NR NA NR NR
laa 2iOi250 120*:150200 20>22C 210 220 _ 50 200 NR IBOI_ 2101220 100 2101230 -
gpl
Starch .................. ........ Corn Sugar ........... ............. Corn Syrup, Acid, Decoloriring ............ Corn Syrup, Crude Acidic ..... CottonseedOil ............. 1: .:..:::: Cresol ................................. Cresol Fumes ........................... Cresylic Acid ............................ Cresylic Acid Fumes .. ................... Cresylic Acid: Sodium Hydroxide ........... Cresylics, Water, Neutral Oils, Mercaptans. H,S, Waste Liquor, pH 56 .... CrudeOil,B ............................. Crude Oil, Sour ......................... Crude Oil Storage Tank Bottoms ........... Crude Oil, Sweet ......................... Cupric Sulfate: Fe& Bulfair: Sulfurtc Acid .......................... Cutback Diluent, Refinery ................. cw-ft 102 .............................. CyafSlOlt.. ........................... Cyanoacetic: Methyl lsobutyl Ketone; 0.6 Sulfuric in Saturated Sodium Chlorfde @ lOOoF ...................... Cyanuric Acid Tank with 16% Sulfuric, Steam and Calcined Urea ................ Cyanuric Chloride Scrubbed with 6.26% NAOH Cyclohexanr ............................ Cyclohexane ............................ CyClohOxaM: Acetone: Hrxan: Watr ....... Cyciohexanono .......................... Cyclohexylamine: Hydrochloric Acid ........ Cycl~Octadlrne ......................... Cygont 400 ............................. Cygont 400 ............................. Darext46 ............................... Daxadt 30 ............................... DDT. Inrectlcide Bolutlon ................... Decanol ................................. Dechlorinated Brlnr pH 2.3, Fm Chlorine (fracre) ........................ Deionized Watep ......................... Deionized Water, High Purity, 1.5 )rmho/cm. .... Demineralized Water ...................... Depleted Na 6 K Brines .................... Deamuttor I Deoxidizer for Aluminum ..... , .. Desulfurtzer Feed/Rofiney ................. DosulfurIzing SO,, H,S wlth Monoethanolamlnr ..................... Detergent Alcohols ........................ Detergent Base-Tridecylbenrenr Gulfonatr Detergent, Biodegradable, Llquid ............ Detergent, Dimethyl Benzyl NmAlkyl Type with 23% HCI. 77% Inerts ................ Detergent, Dlmethyl Benzyl N-Alkyl Type with 25% Phorphorlc. 75% Inert r .......... Detergent, Dirhwrrhing. Llquld, Biodegradable .......................... Detergent, Organic pH l&11 ................ Detergent, Pax Hyrpwdt ................... Detergent, pH 6 ........................... Detergent Solution, Buildt pH 9.10, 1012% Solids ......................... Detergents, Germicidal .................... Detergents, Organic ....................... Detergents, Sulfated .....................
NO change m ware, at 0 1 tf z lammare/gal. AROPOL 7530 satslactory as m
134XAMB 180,150 1301110 18ollM AMBI125 90
10:1020 -
210 210 180 125 -
100 -
650
LSSAT 212 175 14WNFU175 140 NR NR 100 150 NR 180 14W180 -
212/NR 17Y1601NR 150/NR -
217J2w LS to 2lOiNR NR NR NR 150 150 -
Vapor 100 10:10:1:79 1W 955 Q 100-F 100 3 75 103
160 Kv120 NRNFLNRI2101220 2!0~220 NRI120/1&l 1201lW/:001-
2.5 100 Satd

loo loo 1w
IS0 loo 200 l&I 212 200 AMB AMBINFUNR 120 loo 100 loo 100 1w NR loo 1SO/w AMBINR 1801212
80 AMBINR 120 loo
Satd -
100 Satd 3 16LXI&l/-
1w -
lW/lW/-
160 I40
_ 1201100 -
120 Cone lank
NR 180,-
loo/-
120 -
100 -
2@3O.@JO gal
tSee
list of trademarks
and product names
(continued)
Synthetic
Resins and Polymers
191
TABLE
1.54:
POLYESTER
AND VII
L ESTER RESINS-ASHLAND
CONCEN. TRATION % All 65 10:10 100
100 @ HETRON 92199P
SERVICE TEMPERATURE. F FOR RESIN TYPES

HETAON 721197/197A AAOPOL 724017430 SERIES 16OllW HETAON 700/700c 2W 100 180 NR NR NR 80 15O/AMB HETAON 920 SERIES/980 2101220 _ lCOI1501180 I W/SAT NR NR NR 801150 1M/200 210/150 300 -/LSINR NR NR NR NR NR NR NR NR NR NR NR LS/NR NR NR NR NR NR NR NR NR NR LSlNR NR NR NR NR NR NR NR NR 120 NR NR NR NR NR NR 2M) NR NR LS AMB LSiNR LS/NR 120 120 NR _ NR NR LSI_ NR NRIlW NPJNRINR NR NR NRINR NR NR 120/1501200 804120 80 120 801120 NR NR NR NR NFVNFUIOO NR 1501200 so _ 1201150 NPJNRI120/100/l 50 AMBIlOO 801120 _
(continued)
CHEMICAL ENVIRONMENT Detergents, Sulfonated .................... Developer, Photographic, Caustic .......... Developer, Photographic, Moderately Alkaline ............................ Developers, Color ......................... DFR.lZlT ...................... ^. ....... Dialiylphthalate ........................... Di-Ammonium Phosphate @ 225OF .......... DFAmmonium Phosphate: Ammonium Sulfate Di.Ammonlum Phosphate Vapor ............. Dlbromophenoi ........................... 2,3Dibromopropanol Q 120F .............. Dibromopropanol; Small Amount Trim bromopropane & Brominated Organics ..... Dibutyl Ether ............................. Dibutyl Phthalate ......................... Dibutyl Sebacate ......................... Dlcalcium Phosphate gas: Llquid; ScrubbingpH54.. ....... . .............. 2. SDichioroJ-Aniline in 32% HCI @ 170F .... Dichloroacetaldehyde ..................... Dichioroacetic Acid ....................... Dichlorobenrene ..........................
1.2.Dichloroethane
80/80/60 80/80180 80180180 100 LS/LS/NR LSlLSlNR 80 Ah40
lW/IW 160/13a AM0 NR SO/Ah40
6%12OF
100 IW 100 -
Diesel Fuel............................... Diesel Fuel, Premium ...................... Diethanoi Amine .......................... Diethanol Amine .......................... Diethyl Benzene .......................... Diethyl Carbonate ......................... Diethyl Ether ............................. Diethyl Formamide ........................ Diethyl Ketone ........................... Diethyl Maleate ........................... Diethyl Maleaie: Water ..................... Diethyl Sulfate .......................... Diethylamine ............................ Diethylene Giycol ......................... Diethyiene Glycol Nebutyi Ether .............. Diethylene lmide Oxide .................... Diethylene Trlrmine ......................
Dichloroethene ........................... Dichloroethylene .......................... Dichloromethane ......................... Dichloropene: Dlchloropropane .............. Dichlorophenol ........................... Dlchlorophenoxyacetlc Acid ................ Dichloropropane .......................... Dichloropropane: Dichloropene .............. Dichloropropene .......................... Dichloropropionic ......................... Dichromate Bleach, Sulfuric, Photographic .......................... Dicoco Dlmethyl Ammonium Chloride ........ DiCrobe NNT, Germicidal Detergent .......... Dlcyclopantadiene ........................
........................
IWF 100 @ 265F 100

100 @ 100 100 100 100 Q 1WF IO0 2 100 @ 100-F 100 100 100 loo 30 100 IW 100 100 @ 75F 100 @ 75F loo 100 @ 75F 97~3 @ 212F 100 loo 100 100 10 100 10:10:10:70 20 loo 100 75:25 @5:10:5 100 100 100 loo 70 100 @ 75F
80 120 loo 100 175 110 110 120 NR NR 1w 100 85 100 NR -/SAT/NR NA 120 80 AMB IM) 150 NR
120112u 175040 AMBIAMBINR NR NR NR NR 1801150 NR 1201120 -
Diethylene Triamine: Ethylene Diamine: Sodium Hydroxide: Water ................ Dlethylhexyl Phosphoric Acid (In Kerosene) .... Digester Blow Down Vapors @ up to 220F .... Digester Room, Pulp Mill, Floors, Spills ....... DigiycolamineG 270F .................... Diglycolamine. Satd. with CO, and H,S @ 27OOF.. ......................... Dihydrcgenated.Tallow Dlmethyl Ammonium Chloride: Aqueous isopropanoi ............ Diisobutyl Ketone: Ethyl Hexyiacetate: Butyi Alcohol ........................... Diisobutyl Phthalate ................ ...... Diisobutylene ............................ Diisocyanate, Diphenyl Methane ............. Diisopropanolamine ....................... Dimethyl Acetamide ....................... Dimethyl Acetamide ....................... Dimethyl Benzyl N-Aikyl Type Detergents with 23% HCI or 25% phosphoric and rest inerts ..........................
tSee 11s of trademarks and product names
loo
lOOI-
(continued)
192
TABLE
1.54:
POLYESTER
AND VINYL
CONCENTRATION %
HETAON 92/99P
(continued)
HETRON 72119711971 AROPOL 7240/7430 SERIES HETAON 700170lc HETAON 920 SERIES/980
SEnVICE TEMPERATURE, F FOR RESIN T\ PES CHEMICAL ENVIRONMENT Dimethyl Distearyl Ammonium Chloride: Aqueous lsopropanol Dimethyl Formamide ........................: : : : : : : Dimethyl Formamide ..................... Dimethyl Formamide @ 9OF .............. Dimethyl Formamide: Terephthalic Acid: HCI: Water ........................ Dimethyl Morpholine Q 120F .............. Dimethyl Phthalate ........................ Dimethyl Phthalate: Methyl Ethyl Ketone: MEK Peroxide .................. ...... Dimethyl Sulfoxide ........................ Dimethyl Tin Dichloride. .................. Dimethylamine .......................... Dimethylamine ........................... DMP: MEK: MEK Peroxide .................. Dinitrobutyl Phenol in 25% Sulfuric Acid Weste @ 150F .................... Dloctyl Phthalate ......................... Dioxane ................................. Diphenyl Ether ........................... Diphenyl Methane Diisocyanate ............. Diphenyl Oxide ........................... Dipropylene Glycol ........................ Dipropylene Glycol Dibenzoate .............. Dishwashlng Detergent, Liquid, Biodegradable .......................... Dishwashing Liquid ....................... Disinfectant, Chlorinated Phenol Type ........ Disinfectant & Cleaner, Pd 84T .............. Dispersant, Anionic, Blend .................. Dispersant, Nonionic, Blend ................ Dispersing Agents ........................ Distilled Water ........................... Di-Syston ............................... Dlversey 514T ............................ Diversey808T ............................ Divinyl Benzene ........................... Dodecane ............................... Dodecene ............................... Dodecene, Trace HCI ...................... Dodecyl Alcohol .......................... Dodecyl Benzene Sullonic Acid: Sulfuric Acid: Water: Oil .................. Dodecylbenrene Sulfonic Acid Dolomite Kiln Gases, Wet .................. Dowclene ECt ............................ Drain Cleaner, Liquid (Spartan Chemical) Q 80F ............................... Drewsparse 732t .......................... Drewsperse734f .......................... Drewsperse735T Q 12SF .................. Drewsperse 738T @ 125OF .................. Drewsperse 74lT Q 125F ................. Drewsperse780f .......................... DW-875T, Styrene, Acrylic Emulsion .......... DXE: Xylene; Trace H,SO,; Flake Caustic ...... Dye Plant Water Treatment, pH 2-3 ........... EDTA ................................... Electrasolt Detergent ...................... Electronics Plant Waste .................... Electrostatic Precipitator Fumes, 11% Carbonate, 3% Sulfate, 1110% Fluorides, 1110% Bicarbonates ..................... Electrostatic Precipitators, S; H,S; SO, ........ Elvaset ................................. Emulsifier, Oil and Grease, Alkanolamide Type ................ EP52.A85t ......................... Epichlorohydrin ................ Epoxidized Soybean Oil .......... Epoxy Spray Liner, Water Reducible 0 120F (PPG Industries) ...... Eptamt, Herbicide .............. Erional NWf .................. Esters, Fatty Acid ..............
72~25
7.2 30 100 7:14:26:51 100 100 36:63:1 100 @ 75F 50 4 60 36:63:1
120/NPJ-/NR NR NRI-
120 100 go NR 100 LSILSINR --lLS65/NR NR 65.60 130 --ILSBO/NR --lLSWNR -
1201120 _ NR NR
120 _ NR -
120/NRINR NW00 120/150 _ _ -
NR NR NR -
NR 150 NR 150 NR _ NR _ 160 120 100 125 125 200 _ NR _ _ 125 125 SAT SAT SAT 125 NR AMB -
up to 16 100 100
100 @ 75F 100 1GfJ 100 100
NRI-/NR NR NR 160 -
-/NR NR NR 120 NR 16a120 120 100 125 125 1601140 NR NR NR -
120/150 NR 60/120 60/120 1504160 120/100 100 loO/_ 2101220 NW120 601150 _ 1501160 2101220 _ _ AMB 150 AM0
120 100
1M) 100 100 100 100 1 to 10 Dilutmn 14 ozlgal 5.3 ozlga1 1W 100 100 100 100 65:10:4:1 All 1W NR 15XNR/100 100 100 100 1CO 100 5050 @ to 165-F 36 5 NR/lW/-
120 100 100 125 125 125 210 120 &I 140 AMB AM0 120 100 150 150 60 NR 125 125 SAT SAT SAT 125 60 NR 180 AMB -
125 125 LS/NR LSlNR LS/NR 125 NR -
100 1M) 100 100
165 260/260/100 120 AM8 125 NR 120 AMB 120
1001100 AM0 NR _ 1801150
165 _ 100 120 AMB NR AMB 180
185/k loo/AMBINR 1201150 NPJAMB!160
COilC 1Cil loo
+~ee list
of
trademarks and productnames
(continued)
.......................... ::: ... ,,,:::
...
.............
194 TABLE
Corrosion
Resistant
Materials
Handbook
1.54:
POLYESTER
AND VINYL
CONCEN. TRATION 6.6.6 10340 26 5oL 16 % HETROW 92l99P 15w-
(continued)
TEMPERATURE, F FOR RESIN TYPES HETAOW 920 SERIES/990 HETRON 7U1971197A AROPOL 7240 1430 SERIES HETRON 7001700c
SERVICE CHEMICAL ENVIRONMENT
........ Fertilizer Scrubbing Fertilizer Solullon ................... Fertilizer Solution .................. Fertilizer Solution, Nitrogen ........... Fire Retardant Liquld (Osmose Co:) ........ Fish 011 and Meal Exhaust Gas .............. Flsh Tanks .............................. Flxlng Baths. Phologrrphy ................. Floor Wax Polymers ....................... Flue Gas @ 26&34O*F .................... Flue Gas @ 190.280F ................... Flue Gas, Bohr up to 45oF ................ Flue Gas, Chemical Incinerator .............. ............. FlurGas,CorlFlredupto350F Flue Gas, Garbage lnclnrrator ............... Flue Gas, llog Fuel, Some HCI, pli 3.7-7 ....... Flur Gas, Ruovery Bolla up to 400.F ........ Flur Gas Scrubbing, Ammonia Process ....... Flue Gas, Wet* ........................... Flue Gasn; Some Sulfuric Acid Fumos. Abraslvo Clay Partlcl~s .................. Fluoborlc Acid ........................... Fluoboric Acid ........................... Fluoride Salts + HCI ...................... Fluorinated. ChlorlnaI4 Acid Organlcs N@utralizad Wlth Limo. Effluon~ ........... Fluorlna ................................ Fluodnr Gas ............................ Fluorlnr: Phosphorus Pontoxkte ............ Fluorine Scrubber, Rocovr H,SIF, ........... Fluomlubos~, Ollr and Gnasoa ............. Fluoslllck Acid .......................... Fluosiliclc Acid .......................... Fluoslliclc Acld .......................... Fluoslllclc Acid .......................... Fluosillclc Acid Furnn, Wop ................ Fluowlfonk Acid .........................
Fly ASJl Sluny
175 60 80 SATlSATlNR SATISATINR SAT/SAT/NR 3m13m/SATISATINR lea 155 SATISATINR 125 120140 BP lx) 105 65
801
@Q
w175/AMB
175 -
12on50 _ 1751-
160
NR NR NR NR NR 1%X251AMB
SATiNR LSlSYNWNRINPJNPJ160 120 2101220 16012rn -
160 160 -
180 180 -
10 Sald 3O:10
BPil6O -rw
100 @ 75-F im
1.5:1.5
Nix-
NR NR twiAMB NR NR AMB 1501120 AMB AMB AMBJNR NR 150~1rn AMB AMB 150 -
100
10 25 35 S&d
AMBI-
160 AMB 160 180 160
150 1M 100 loo i 50~2m 801120 1m AMB loOi160 120 120 -
im
-IAMB NR
700
NWxx) --190 --190 -l9O NFUlx) NR AMB 2m 1x1 15c1 SAT
............................
im @ 80-F
to 25 2x37 5052 37M Unknown @ 200-F
Formaldahydo ............................ Formaldohydo ............................ Formaldohydo ............................ FormaldrhydeO 150F .................... Formaldehyde. Phenol, Sulfuric Fumos ....... Forrnsmlde .............................. Formk: Acetlc Acids ...................... Formic Acid ............................. Formic Acid* ............................. Formic Acid ............................. Formic Acid ............................. Formic Acid 60%, Satd with NACI: Unknown Organlcs ...................... Formic Acid Vapor ........................ Fourdrinier Drying Section Fumrs ........... Fourdrlnier Liquor .......................... Freon II ................................. Fruit Julus ............................. Fuel Oil, No. 1 and No. 2 .................... Fuel Oil, Naval, ML-F-669A ................. Fumigant, Sol1 ............................ Fumigants ............................... Fungicide, Phsnate Based .................. Fungus, 95% Relative Humidity MIL E4272C Aspergillus Flavus (lCl636) ................ Chaelomlum Globosum (6205) ............. Memenoniella Echinata (9597) ............. Ponicllllum Cltrinum (9649) ................ Furfural ................................. Furfural .................................. Furtural .................................. Furturyi Alcohol ........................... Furnace Oil ...............................
nAROPOL
2 vol.
im
10:10 10 25 50
im200 AMB AMB NR
im*iLs 15&W 1201NR NR
imks
150
200
140
150 AMB -
100 5350
10 -
100. im 40
194/13OiW
194 130 120
AMB -
75 120 -
100 300 im
COW. Gnlc.
17W17YNWNWAMBJw86/86/mlAMB NW-
170 175 NR NR 125 66 66 66 66 AMB
AMB 17w130
NR 125 86 66 66 66 NR AM&NR 125
1m 5
10
lx)/150 lm/wO NR 01 1.2%
50100 im
100 -
7343 SStr~lSclOy. 12.5: NI. 74.6. 0,. 4.9:
: SO,, 0.25: SO,. 0.03; CO,
rrO. 72% S0,5% O/12% C0,70% N,ll3 4% H,O; 5 pm7WlP 2.3&X7 burn HQ 1020 Pam HF. rus, 14h?1 t!See list of trademarks and product names
H,SC-.
H,O.
76. I/y ash. 5.0 9rrms
w. nlocrry60 IPS
VoI. I SO,. 0.25: SO, 0.003. CO,. 12.5. N1. 74 6. 0,. 4.9. H.O. 76 t/v ash. 1.2 WW7U I?: YCIOCI~Y 8 IDS
(continued)
195
TABLE 1.54:
POLYESTER
AND VINYL
I
CONCEN. TRATION % 100 Sat'd 100 100 100 SO:10 100 100 194/l% 1751loOIHETRON' 92/99P NR -
SERVICETEMPERATURE.FFOR HETRON 7211971197A NR 125 60 200 200 160 160 60 194 175 AM6 _ 100 &I AMBI-I100 AROWL 7240/7430 SERIES NR _ AMBI1W'YNR 1OO'YNR 1301100 1751100 AMB AMBI100 1601100 60 100 12Y125/100 160 100 125 160 16011CQ 100 125 1601150 160/150 -
(continued)
RESINTYPES HETAON 7001700c NR _ _ 100 NR 1601150 100 1M) 100 NR 160 HETRON 920 SERIES/980 NR _ __ 100 103 100 100
Fusion 12.62t Q 175OF .................... G.61T .................................. Gallic Acid ........................ Gallotannin ........... .... ............. Galvanizing Line Fumes ................. Garbage Incinerator Fumes ................. Garbage Incinerator Water Scrubber ......... Gas Oil. Dirty, Refinery ..................... Gasohol; 91.6% Unleaded: 6.2% Ethanol ...... Gasohol; 93.6% Unleaded: 6.4% Ethanol ...... Gasoline ................................ Gasoline, Aviation ........................ Gasoline: Benzene ........................ Gasoline Components ..................... Gasoline, Ethyl ........................... Gaaollne, Lead Free ....................... Gasoline, Martna ........................ Gaaollna. MS-08 ........................ GelstIne; ........................... Geothermal Water ................... Gamtlcidal Detergents ................ Geyser Water, Condensate ............ Glass Cleaner, Fortified with NH, (Spartan Chemical Co.) .............. Globrita 15T ......................... Globrite X2tMT ...................... Gluconic Acid ....................... Glucose ............................ Glycerin Still Talllnga with Small Amount Sulfuric to 330F ................... Glycerine ........................... Glycerine in Salt Satd. Water .......... Glycerol Dibromohydrln; Small Amount Tribromopropane & Brominated Organic8 ......................... Glycol.............................. Glycollc Acid ........................ Glycollc Acid ........................ Glyoxal ............................ Glyoxylic Acid @ 215OF ............... Glyoxylic Acid: SO, @ 215OF ........... Gold Pickling, Sulhuic ................ Gold Plating, pH 4.4 .................. Gold Plating Solution (23% Potassium Farrocyanide with Potassium Gold Cyanide and Sodlum Cyanide), ....... Gold Smelting Furnace Gas and Dust.Wetupto4CxYF ............... Golden.GloT .............................. Golf Ball ScouringCleaning Solution .......... Green Liquor ......................... Gypsum Slurry + 1% H,PO,, + Trace HF Gypsum Slurry Cooler (Fertilizer Plant) ..... HalsoSSt ............................. Hard Chrome Plating Baths .............. HAS (Hydroxylammonium Acid Sulfate): Sulfurlc: Water ...................... HAS (Hydroxylammonlum Acid Sulfate): Sulfuric: Water ...................... HCI: Methylimlno Ether. Methanol: Isobutyronitrile: Impurities ............. Heating Oil ........................... Helium, Liquid ......................... Heptana, Dissolved Heavy Organics. Traces H,O, ZNCI,, HCI .60% Methanol, H,O, HCI, ZNCI,, Organics .2 Phases ............. Heptane, normal ....................... Heptane, Traces Water, HCI; Other Heavy Organic8 ...................... Haptane, Vapor & Condensate ........... Herbiclda, Liquid* ...................... Herbicide Powder & Fumes .............. Hexachlorocyclopentadiene ............. Haxachlorocyclopentadiana, Crude ....... Hexachlorocyclopentadiana; High Purity ...
tSee hst ottrademarks and
loo/160/lOOI100/125 210/220 NPJ2101220
C0fh.Z. -
50 100 100 70 200 -020 160
200 7C-240
100 @ 60.12O'F All 35 70100 40 25 25:Sat'd 25 -
250/140 120 NWNFU-
250125012w 140 103 NR NR 150 -
16Oll50 14011x) 120 NR NR lW/-
NR 220/200 140 100 LS'INR LS"NR 150 125i-
NW200 16012cC AMBJlDO 80 Ls/LSi150 _
@2CO'F 100
NRIAMWNRJNR
200 SATlSATlNR 100 NR 100 190 NR 130
NR 100 NR AMBI-
200 NR 100 SATI_ NR _ -
180/NR loO/SAT _ NW-
20:60:20 11:75:14 23:74:2:0.3:1
100 100 -/77/HETRON
100
31 SAT, NO Ve!. to .452"F
140 1M) AMBi120 100 110 10 100 100 120 60/w2001200/206 120 120 100 2M) 180 90 ZOO/120 tlO/NR NR -
2ca150 NR -
160 120 _ 160 160 -
product names.
(continued)
196
TABLE 1.54:
POLYESTER
AND VII
L ESTER RESII
CONCEN. TRATION %
!3+ 100 28 100 1OU
;-ASHLAND
HETRON'
(continued)
HETRON HETAON AROPOL 727197119711724017430 SERIES 700179ac
90 86 80 WI56 120 155 9w--/200 120 160 100 NR 200 200 200
SERVICE TEMPERATURE, OF FOR RESIN TYPES 92/99P

90/86/80 120/100 100 RH 1M) 10 70 1058 18 25 46 50:5:Trace 100 Unknown Unknown 1.5 10 15 20 32 36 36.37 37.5 1.1:z.g Unknown 230 230 230 85190 85l90 8Y230 230 230 180 150 100 SAT/SAT/NR 160 160 77 120 NW-/160 -/WI 120
HETAON 920 SERIES/990
Hexachlorocyclopentadlene; Reg. & High Purity Wet With H,O ..................... HexachloroendomethyleneTetra. hydrophthalic Anhydride, Wet ............. Hexamethylenetetramine .................. Hexane ................................. Hexylene Glycol Ammonium Chloride ........ High Purity Water, 1.5 pmhdcm. ............. Hog Fuel Flue Gases, Some HCI, pH 3.707 ..... Huff, Misrourf, Okla. or Texas ............. Humid Air, Trace Sulfur Fumes ............ Humid Atmosphere ........................ Hydraulic Fluid, Skydrol SWT ............... Hydrazine ............................... Hydrazine ............... ............... Hydrfodlc Acid ........................... Hydrobromlc Acid ......................... Hydrobromlc Acid ......................... Hydrobromic Acid ......................... Hydrobromic Acid: Copper Oxide: Bromine ......................... Hydrobromlc Fumes Q 290F ............... Hydrocarbon Alkylation .................... Hydrocarbon With About 10% Acetic Acid, Liquor and Vapor ................... Hydrocarbons: Ferric Chloride Mist .......... Hydrochlorfc Acid ........................ Hydrochloric AcIda ........................ Hydrochlorfc Acid ........................ Hydrochlortc Acid ........................ Hydrochloric Acid ........................ Hydrochloric Acida ........................ Hydrochloric Acid ........................ Hydrochloric Acid ........................ Hydrochloric: Amine Q 2oOF .............. Hydrochloric: Ammonium Thlocyanate ....... Hydrcohlorlc Acid (12%) + Aqueous Ammonia to pH 0.3 ...................... Hydrochloric Acid, 2o Be: Amine ............ Hydrochloric Acid @ B.P. ................... Hydrochloric: Brighteners .................. Hydrochloric: Chlorinated Hydrocarbons ...... Hydrochloric (BZ%):Chlorinatsd Organic Contaminates (phase separation 213 acid: 113 organic) ..................... Hydrochloric Acid (32%): Chlorfnated Organlcs .................... Hydrochloric (32%): Chlorinated Organics: Trlchloroethylene ....................... Hydrochloric: Cl,; Aromatic Sulfonic Acid; H,SO. ............................ Hydrochloric Acid, Cl,. Water, Chlorinated Organics .................... Hydrochloric Acid: 2, &Dlchloro-4 aniline @ 170F ........................ Hydrochloric: Fluoride Salts ............. Hydrochlortc Acid + Free Cl, ............ Hydrochloric Acid, Fumea @ 22529oOF .... Hydrochloric: Hydrofluorlc: Nitrate ....... Hydrochloric Acid: Inerts: NoAlkyl Dimethyl Benzyl Ammonium Chloride: Tributyl Tin ChloridelEthylene Oxide/Amine ......... Hydrochloric: Methyl lsobutyl Ketone ...... Hydrochloric: Methyl lsobutyl Ketone; NH,CNS.. .......................... Hydrochloric: Nitric Acid ............... Hydrochloric: Nitric: Sulluric @ up to 225F Hydrochloric: Phenol: Aqua Regia ......... Hydrochloric: SW ppm Phenol; Ml ppm Octyl, Decyl, Butyl, Phosphorous Chlorides ........................... Hydrochloric Acid: Phenol: Water ........ Hydrochloric: Phosphoric Acids .......... Hydrochloric: Phosphoric: Butyl Ether ..... Hydrochloric Acid Pickling Tank Covers & Fumes ..................... Hydrochloric: Silicone Oils ...............
NO change m water at 0.1 It. laminate/gal. *AROPOL 7530 satmlactory.
80156!1201120 AMBVNR w2w120 130100 NR NR 160/100 160/100 16W_ -
_
80 80.156 120 LSlSY120 NA 2001160 ZOO/160 1W _
_ _ 100 120/20 1501180 _ NR _ 210/220 2M) 150 160.220/2101220 2101220 210/220 2101220 160 150 100 SATI180/NRI-
AMB SATlSATlNR 120 -iEa-
16Otl50 180/150 150 15OtlOO 125(90 125190 lCQ/NR
LS200 230/200 150 150 150 1501120 140/LSAMB/NR SATiNR 180 _ NR -
98.8:0.2w/w 20 10:30 32:<5 @ 60-F
88.3:11.7 @ 104F 99:1 @ 104F 68.1:0.9:14@ 25 Unknown 32 10:30 All 77:13:10 2al/104-F -
NR NR NR 80 60/60/NR -/LS/NR 120 200 -/SAT/NR 100
LS/NR LS/NR -
_ _ NPJLSI-
23:77:0.1:0.1 15:100 15 20:5 6 Mola~lWO:10 Conc:0.5:0.5
158-203/NW-
100 -/156-203JNR 203 2lot210/60
NR -
_ -
loo/NRI-
37 10:20:70 Unknown Unknown 30 21
NRttSee -00
100 NR 120 120 215/195
NR -
_ NR _ -
NRI_ -
as !n 2~3O.LWO gat. tank
list of trademarks
and product names
(continued)
Synthetic
Resins and Polymers
197
TABLE
1.54:
POLYESTER
CONCEN. TRATION %
1445
;-ASHLAND
SERVICE HETRON 92199P
(continued)
TEMPERATURE. OF FOR RESIN TYPES HETRON 920 SEAIESPBO HETRON 7tlPlI19lA 140 loo 90
CHEMICAL ENVIRONMENT Hydrochloric: Sulfuric ......... Hydrochloric: Sulfurk: Antimony Trioxide ...... Hydrochloric: Sulfuric: Nitric Hydrochloric: Teraphthalk Acid: DImethyl Formamida: Water Hydrochlork Acid, Trace Phanol; &yl, Decyl. Butyl Chlorldor 6 Phosphorous Trichlortde ............................. Hydrochlork (aqueous) + Organic Solvents .... ..... Hydrochloric wlth 2 6 Dlchlor4nltroanlllnr Hydrochloric, 10% by volume with Ferrk and Ferrous Chlorides, pH 1 .............. Hydrochloric, Satd. Ferrous Chloride ......... Hydrochloric. Small Amount Acetone .......... Hydrochloric, Traca Organks ................ Hydrochlork. Traca Phenol and Cresylic Acid @ 175*F .................... Hydrochlork, Trrca Toluena 6 Chlorotoluene ... Hydrcchlork Trfmathylamlno ................ Hydrochloric, 60% by Vol.: Hydrofluork, 20% by Wt.: Sulfuric, 29% by Wt.: Sodium Dlchromate, 3% by Wt.a ............ Hydrocyanlc Acid .......................... Hydrolluork Acid .......................... Hydrofluoric Acid .......................... tfydrofluork Acid .......................... Hydrofluoric Acid .......................... Hydrolluorlc Acid @ 195-F .................. Hydrofluork Acid Q 195.F .................. Hydrofluork Acid .......................... Hydrofluork Acid @ 1WoF ... .............. Hydrofluork: Chlorfne: Nitric Oxide Fumes ..... Hydrofluorlc: Chromic: Nitric Aclds ........... Hydrolluork. 49%: Glacial Acat!c: 70% Nltrk ... Hydrofluork, 49%: Glacial Awtic: 70% Nltrk ... Hydrolluork: Hydrochlorfe Nltrfc ............ Hydrofluork, 20% by Wt.: Hydrochloric, 80% by Vd.: Sulfurk, 29% by Wt: Sodium Dkhromato, 3% by Wt. ............ Hydrofluork Actd: Nltrk .................... Hydrolluorlc Acid: Nltrfc .................... Hydrofluorlc Acid: Nltrlc .................... Hydrofluork: Nltrlc Acids .................... Hydrofluoric: Nitric Acids .................... Hydrofluork: Nitric Acids .................... Hydrofluorlc: Nltrk Pkkllng ................. Hydrofluoric: Nltrk Pkkllng Solutfon ......... Hydrofluoric: Phosphork: Chromic ........... Hydrolluork: Phosphork: Chromic ........... Hydrofluork Acid: Stannous Fluorfde .......... Hydrofluosillcic Acid ....................... Hydrofluosilicic Acid] ... ................... Hydrogen ..... ........................... Hydrogen Bromide, Dry ..................... Hydrogen Bromide, Wet ..................... Hydrogen Chloride ......................... Hydrogen Chlorfdr, Absorber ................ Hydrogen Chlorfdo, Anhydrous ............... Hydrogen Chloride and Benzene Vapors ....... Hydrogen Chlorldo: Chlorfne Saturated with Trtrachlorocyclopentano, Ccl., Trace .................. Hexachlorocyclopentane Hydrogen Chloride, Cl,, CO,, CO, H,, N,, 0, .................................. Hydrogen Chloride Fumos @ 350F ........... Hydrogen Chlorfde Gas: Chlorine @ 392-F ..... Hydrogen Chloride Gas, Dry ................. Hydrogen Chlorlda Gas, Wet ................. Hydrogen Chloride. Steam .................. Hydrogen Fluorfde, Cl .. Nltrk Oxide Fumes .... Hydrogen Fluoride, Vapor ................... Hydrogen Fluoride, Wet .................... Hydrogen Fluoride. Wet .................... Hydrogen Iodide: Iodine Vapor ............... Hydrogen Iodide: Sulfuric ................... ......................... Hydrogen: Ozone ....... Hydrogen Peroxide ...........
uomt
72407430 SERIES
HETRON 7001700c
15355
302010 28 14:7:51
_ NR
1W
Unknown
37 @ 194F 32
80 NR 170
170
15 36 32 2s-30 37:1W NFLNW-
120 240/240/SO LSJLSINR 140 130 80 LYNR NR -
1201NFU-
120 Satd 5M @ BP BM @ BP 10 15 20 22 40 15 Unknown. 3-6:2 1:2:5 @ IlOF 1:X8 @ 1WF NPJNRI2w NFUNW100
lWNR NR 1OChNR wNR NR NR NR 200 NR NR 1w 93 100 LYNR NR --ILS NR lM/NR NR 153 1w loo LYNR SAT
2W NR NR AMB 90 SATlSATlNR SATlSATlNR AMB --I-/LS 80 NR NR loo
loo NR
Hot
SAT
13.77:10
120 515 2.57.5 23:20 24:12 Q BOF 4.15 @ 190-F 5:50 @ 120-F Unknown 3.520 24017 11%.59.3 X1:50 @ 220-F 10 35 1W 100 100 Cont. @ 210212F 36 100 23yz?Y250 250 85 NR loo NR 250 90 180 1M) 250 loo/NR AMB AMB NR NR AMB NR 15o/lW AMB 150 100 180 l&I NFUNRI165 165 135 NR NR HOI 105 loo 1w NR NR NR NR NR lOYNR NR lOY-
65.35 Unknown Ul-lknOWn 100 100 Unknown Uh-lOW~ 35 12 100 66 BP1 25 gPl 5 120 -
125 AMB SATlSATlNR SATISATINR lx) 120 2u)/24w95 90 90 150/not 95 l&3 150 158 loo 210
120 120 AMB 18OiNR
IBOIAMB NR 95 AMB
21w2u 21w22u 18012w AMB 150
fSee1st01 trademarks
and product names
(continued)
798

j-ASHLAND
HETROII' 92199P
TABLE
1.54:
POLYESTER
AND
VII
L ESTER
RESI
(continued)
FOR RESINTYPES "ETRON 7001700c HETRON 920 SERIES'980 1x LS:6of210 2 101220 104 AMBlNR AhlB/NR AMB AMB 1M 120 AMB loo AMB HETRON 72/197:19lA AROPOL 724017430 SERIES
SERVICETEMPERATURE.'F
CHEMICAL ENVIRONMENT Hydrogen Peroxide ........... ....... Hydrogen Peroxide .................... Hydrogen Peroxide ..................... Hydrogen Peroxide: Sulfuric: ZnSO,:NA,S:O, ............. ........ Hydrogen Peroxlde, Vapor 6 Condensete ...... Hydnqen Peroxide Vapon ................. Hydrogen Sulfide ......................... Hydroxyrcetic Acid ....................... Hydroxyecetlc Acid ....................... Hydroxyrcetlc: Phosphoric: Sullurlc Acids .... Hydroxylrmlne Acid Sulfate (Hydroxyl. ammonium Acid Sulfate) ................ Hydroxylrmine Acid Sulfate: Sulfurtc ......... Hydroxylrmmonlum Acid Sullate (Hydroxylamlne Acid Sultrto) .............. Hydroxylrmmonium ACM Sulfato: Proplonic Acid: Weter ..................... Hydroxylrmmonlum Actd Sulfate: Sulhrrk ...... Hydroxylrmmonlum Acid Sullrte: Sulturic Watep .......................... Hydroxylrmmonium Acid Sulfete: Sulfuric Watep .......................... Hypochlorour Acid ......................... Hypochlorous Acid ......................... Hypochlorour ACM ......................... Hypophoephortc Acid ....................... Hypophorphorour Acid ..................... l9eprlCO-B39t .......................... Ilmenite On: Sulfurlh SteernAb Agitation Q 220F ....................... Iminoethyl Alcohol ......................... Incinerator, Chemical ...................... Incmerrtor,Gerbege. Fumes ................. Incinerator Water Scrubber .................. lodlne: Hydrogen lodlde Vapor ............... IodlneKeroeoneBrtne ...................... lodlne Vapor .............................. lqjarol DAt ............................... Iron Porchlortdo ........................... Iron Perchloride ........................... Iron PlotIn Solution 45% FOCI,; 15% C&I,; 29% FeSO.; 11%; (NH.),SO. ............... Iron and Steel CleanIn Bath, 9% Hydrochloric; 23% Sulluric ............... lrobutyl Alcohol ........................... lrocunt 399 .............................. lsocuret 399 .............................. Irocuret 999 .............................. Ieocyanrte, Polymethykne Potyphoqt ........ IsoDecrnol ............................... Isoprep 33t .............................. Isoprep Ut ............................... Isopropyl Alcohol ....................... ._ Isopropyl Alcohol .......................... Isopropyl Alcohol: Sodium Xyhne Sultrte: OPhonytphmol: Potrulum Rlclnoteata Inertr .................................. lropropyl Amine ........................... Isopropyl PaImItate ........................ ltrconic Acid .............................. Itaconic Acid .............................. Jet Fuel A ................................ Jet Fuel (JP.4) ............................ Jet Fuel PFB .............................. JM.23E.t Adhe8lvo .......................... JM.27lt Adhoslvo .......................... JP.9 Fuel ................................. JP.10 Fuel ................................ Kaolin Slurry .............................. Kerosene ................................. Kerosene, 70%, 10% Irodecanol. 29% organicr: 39% Phosphoric ................. Kerosene: Vapor & Condenrate ............... Kerosene: Xylene: 85% Phosphoric ........... Knofler Fumes ..........................
Kymenet,Resin tSee Solution .................. names 1151 Irademarks of and oroducl
CONCEN. TRATION % 30 35 50
2.15.Trac.a 5 50 All 35 70 29:51:20 go S&d:70 go 6%1:10 Bwao:10 11:75:14 x):60:20 10 20 Gmc. 50 50 100 3&401(>20 100 Flue ge.s
105/120 loO'/1051105iNR loo':lm/12W-
Nfi 140 -
AMB NR 140 -
100
250 140 -
120 140 253 140 100 24Y24y212 125
212 175 160
100 100
104 AMB AMB 115 105
104 AM0 AMB -
NR"/110 300X0160 160 150 150 120 175 AMB
AMB AMBI-
100
100 20
1751180 -I140 14CV-
160 160 AMB' AMB AMB 120 160/1651150 NR 601NR 13ol60
2001-
All
AMB' AMB AMB 150 -ia 15&156llW156lAMB AMB AMB NR 165 160 AMB AMB
100/120
AMBIAM&AM&150160 165116016OiloO 80:100
100 im 100 100

All 50z@l lOoz/gal
100
10
lR10&6%7
100
AMB -/lBO 95 16O/AMBI22ol125 125 AMB -
imi100/120 2101220 1201210 1201210 120 -
im im
25 10
100
160/150 AM&-
100 17Y120
100 100 im 100

33:33:35 3&w
100 100 80
175 150
100
100 80 eel00
16Oll50
im 100 -
loo/imi-
150 -
150 -
120
120 103 160 90
(continued)
Synthetic Resins and Polymers -ASHLAND

HETRON' 92/99P 200 _ -
199
TABLE
1.54:
POLYESTER
AND VIN
L ESTER RESIP
CONCENTRATION %
All Sat'd lOO@ 140-F 100 1 to 10 Dllutlon All 62 All All Sat'd 100 100 100 100 10 All Sat'd Sat'd 25:25:16:10:6:3 Sat'd 100 100 100 w:10:29:1 --@ 212-F -
(continued)
HETRON 72l1971197A 200 160 NR 60 120 100 AROPOL 724017430 SERlES 1601130 160/130 160/130 120/160/160/AMW120' 120' _ HETRON 7001700c 2201200 NR 60 _ 100 22Ol200 120 120 160 220/2cil 22OuOo 200 160 103 100 2101220 120/1201_ _ _ 2101220 210/220 21w220 16O/210/220 NWNR NWHETRON 920 SERIES/980 2101220 NPJ601100 100
SERVICE TEMPERATURE, OF FOR RESIN TYPES CHEMICAL ENVIRONMENT Lactic Acid .............................. Lactic: Citric Acids ......................... Lasso ECT ............................... Lasso ECT ................................ Lassot Herbicide ........................ Latex, Acrylic ............................. Latex Dispersion in Water ................... Latex, Rubber ............................. Latex,Vlnyl ............................... Laurie Acid ............................... LauriclMyristic Monoethanolamide: Sodium Xylene Sulfonato Solution ..........
160 -
120' 120 212 212 120 155 160 -
LaurylAlcohol ............................. Lauryl Chloride ............................ Lauryl Chloride, Crude, Acidic ................ Lauryl Mercaptan .......................... Lauryl Pyrldinium Chloride ...................
Lead Acetate .............................. Lead Chloride ............................. Lead Nitrate .............................. Lead Plating, Acid: Fluobortc, Boric Acids* ..... Lead Plating, Alkaline, Pb (C&&O),, NaOH* ..... Lead: S: CuO: FeO: &SO,: Bi,(SO,), Dust ....... Lead Smelter Fumes, Duct ................... Leather Dyeing & Finishing .................. Leather Tanning, Drums ..................... Levullnic Acid ............................. Light Gas Cycle Storage ..................... Light Water, FC195T ........................ Light Water, FC203T ........................ Light Water, FCZOgAT ....................... Lignin: Crude Tall Oil: Spent Acid: Sulfuric, pH3 ............................ Lignosullonate, pH 1.5-2 .................... Ligno-Sulfonic Acid ........................ Lime Kiln Stack Gases ...................... Lime Neutralization Effluent; Chlorinated Fluortnated Organica. Chlorlder, Fluortdee, HCI, HF, H,O ........................... Lime Slurry ............................... Lime, Thiosorbic ........................... Limestone Injectlon, SO, Removal, Fossil Fuel, Mist After Scrubber, pH 2.12 ............... Linear Alkylate Sufonates ................... Linoleic Acid .............................. Linseed Oil ............................... Linseed 011, Chlorfnated ..................... Liquid Chlorine ........................... Lithium Bromide ........................... Lithium Carbonate3 ......................... Lithium Chloride .......................... Lithium Chloride ........................... Lithium Chloride ........................... Lithium Chloride ........................... Lithium Chloride: Methyl Alcohol ............. Llthium Hydroxld3 ......................... Lithium Sulfate ............................ Llvestock Spray Base (Shells)z cobalt di(2-ethyl hexyl) phosphate: tr-mbutyl phosphate .............................. Lix54Nt .................................. LPC ..................................... Machine Oil & Sulphur Fumes ................ Magnesite Mill Spent Liquor ................. Magnesite Recovery Boiler Blow-Down; Acetic: Sulfuric: Sulfurous: Formic Acids; Acetone .......................... Magnestum Bicarbonate .................... Magnesium Blsulfite ....................... Magnesium Btsulflte Acid Liquor, 5% SO,, Chlorides, pH 4.55 ................... Magnesium: CakYurn: Sodium Chloride Solution ........................ Magnesium Carbonate ...................... Magnesium Chloride ....................... Magnesium Chloride, Hexahydrate; Filter Aid; Activated Carbon ........................
+See lislollrademarks and Droduct names
NWSATI-
200 NR 200 SAT SAT SAT 160 120 120 200 AM6 300
120 120 2cxl NR -
160/NRINR -
105 Sat'd Sat'd 160 160 150 140 100 203 90 LS55 180 250/250/265l265i140 160 170 NR 170160 160/1601130 NR 140/160/2001150 -55 160 160 160'
170 _ 2101220 .55/2101220 150 2101220 2101220 2101220 2101220 150 210/220
COW. 108 100 100 All Sat'd 045 2840 4555 Sat'd 25175 Sat'd All 150/NWZMI140/160 NW-
65:5:30 100 10 -
176 115 155 HOT 150
_ _ -
Sat'd All 2:10:12 Sat'd Sat'd 66
--/150
212 180 150 160 220 31013101-
NR 160/130
212/200 180 150 2201200 -
160 160 _ _ 160 2101220 -
160 220 _
160/150 160/15a -
(continued)
200
Corrosion
Resistant
Materials
Handbook
TABLE
1.54:
POLYESTER
AND Vlh
_ ESTER RESII
CONCENTRATION % Cont. Q 275F lo 500F at limes
2:12:10 Satd Satd S&d
-ASHLAND
(continued)
TEMPERATURE, F FOR RESIN TYPES HETRON 920 SERIES.1980 HETRON 721197/197A AROPOL 724017430 SERIES HETRON 7001700c
CHEMICAL ENVIRONMENT Magnesium Chloride, Occasional HCI Vapors ........................... Magnesium Chloride: Sodium Chloride: Calcium Chloride ........................ Magnesium Hydroxide .................... Magnesium Nitrate ......................... Magnesium Oxide .......................... Magnesium Oxide Acid Condensate ........... Magnesium Oxide - Fluoride Mist and Fumes ............................. Magnesium Sulfate ........................ Magnifloc 509.Ct .......................... Magnifloc 573Xt .......................... Magnifloc E343t ........................... Maleic Acid .............................. Maleic Acid ............................... Maleic Acid, Trace Phthalic, Fumaric, Benzoic, Quinone ................ Maleic Anhydride .......................... Malelc Residue ............................ Maleic Residue, > 0.5% Phenol ............... Malic Acid ................................ Manganese: Ammonium Sulfates, pH5 ......... Manganese: Ammonium Sulfates: Sulfuric pH5 Manganese Sulfate ........................ Manganese Sulfate: Sulfuric ................. Manganese Sulfate: Sulfuric Acid ............. Marine Fouling ............................ Marine Gasoline ........................... Matart, Germicidal Detergent ................ MEK: DMP: MEK Peroxide ................... MEK, 100%: Sulfuric Acid, 50% ............... MEK: Toluene: Steam: Maleic Acid; Chlorides present ........................ Melamine Resin .......................... Mercaptan, Aromatic ....................... Mercaptan, Organic, H,S, H,O, Butanol ........ Mercapto-Ethanol .......................... Mercapto-Ethanol Tall Oil ................... MercapkkEthanol Tallate .................... Mercaptopropionic Acid ..................... Mercaptopropionic, Crude Acid ............... Mercuric Chloride .......................... Mercurous Chloride ........................ Mercury .................................. Metal Phosphate Salts ...................... Metal Phosphates, Trace HF. Hydrofluosilicic ......................... Metal SulfatsSalts: Sulfuric Acid ............. Methacrylic Acid ........................... Methacrylic Acid ........................... Methacrylic, Glacial ........................ Methallyl Chloride Q 165OF .................. Methanamide @ lOOoF ..................... Methanol 60%, H,O Trace, HCI, ZnCI,, Organic& Heptane, Dissolved Heavy Organlcs, Traces H,O, HCI, ZnCI,, 2 Phases ........... Methanol/Nitrogen Oxide Fumes, @ 220F ..... Methyl Acrylamlde ......................... Methyl Alcohol ............................ Methyl Alcohol: Lithium Chloride Methyl Alcohol: Methyl Chloride: Hydrochloric ............................ Methyl Alcohol: Turpentine .................. Methyl Alcohol: Water: Hydrochloric @ 150F .................... Methyl Bromide: Ethylene Dlbromide .......... Methyl Chloride ......... .................. Methyl Chloroform ......................... Methyl Ethyl Ketone ........................ Methyl Ethyl Ketone Q 120F ................ Methyl Ethyl Ketone: Dimethyl Phthalate: MEK Peroxide ........................... Methyl Ethyl Ketone, Vapor & Condensate ...... Methyl lsobutyl Ketone ..................... Methyl lsobutyl Ketone; 200 gpl Fluorides; 500 gpl Sulfuric Acid& 3 .................... f See
-I160 lW/-
150 _ 150 160 200 2W 1x)/120/165 NR 95 125 125 loo 203 1w 60 loo -/LS-BYNR 60. 80 60 65.60 65.60 65-W NR NR 212 212 250 60 80
_
-/NR 1601130 1601150 90 %I 90 16o/lW 154u120
NR _ 200 200 200 NR _ 60 _ NR NR 220/2w 22012w 22012w
2101220 _ 2101220 160 150 _ _ 2101220 _ 801_ NWNRI2 101220 2101220 -
Satd
200 -
5 Satd 16 100 @ 165F 10 13:156 gpl 13:135:40 Satd 9ozlO 50~~6 (gp0 100 Ccnc. 63:36:1 1o:w
2iwNFU125/125/lW/60112YNRJNRI212 212 250 -
125 125 60 60/NR NR NR 1601150 1601130 16O/-
gpl
100 100 100 100 100 100 Satd Satd 100 Satd 30 24:10 100 @ 145-F 10 100 IW 1W
NRI-
135 NR loo 90 --ILS/NR SAT
NR NR SATiLS
_ _ SATiLS LS
Unknown 48 100 75:25 94:0.4:0.2 o 65: lo 46 @ 150F 93:5:2 Vapor 3070 @ 75-F 100 100 100 IW 63:36:1 100 Q 120-F loo
AMB -
140 90 125 170 135 -/LS/NR NR 40 60 NR NR --/LS-65/NR 50 60
901NR -
NR 1501NR --INR --/NR NR NR -/NR NR -
NW120 -
NFVNR NR NR NR _
NRI40/NRINR NR/-
NR NR _ NR _
llsl 01 trademarks
and pmduct names
(continued)
201
TABLE 1.54:
POLYESTER
AND VI
L ESTER RESI
CONCEN. TRATION %
;-ASHLAND
(continued)
TEMPERATURE, *F FOR RESIN TYPES HETROH 920 SERBS990 HETRON 72.1971197A AROPOL 7240 7430 SERIES HETRON 700,700c
Methyl Isobutyl Ketone; 300 gpl Fluorides; 40 gpl Hydrofluoric Acida ............ Methyl lsobutyl Ketone: Hydrochloric Acid Methyl Methrcrylrte ....... ........ ...... Methyl Parathion Methyl Phenol Fume;. : : 1.......... : : 11: : : Methyl Styrene .......................... Msthylene Blsthiocyanrtr, Polychlorophenol Blend @ 125-F.. ...................... Methylene Chloride ....................... Methylene Chloride: Chlororcetic Acid ....... Methylone Chloride: Chlorotorm: Carbon Tetrachlorlde, Small Amount Methyl Chloride, H,O, HCI ..................... Methylene Chloride Distillate Bottoms; High Caustic, Water, to 212-F ............ Methylene Chiortde: Ethyl Acetate: Caustic, 50% .......................... Methylene Chloride: Toluene ............... Methylene Chloride: Toluene: Xylene: MEK 6 MIBK: Benrenes: TCE: Ccl, ........ Methylene Succinlc Acid .................. Methylimino Ether Methanol: Isobutyronitrile: HCI: Imputities .......... Methylisobutyl Ketone: Cyanc+acetic; 0.8 Sulfuric in Saturated Sodium Chlortde @ lOOoF ............................. Methylol Acrylamlde ...................... Milk & Milk Products ...................... Milk Wsgon Cleaner ...................... Milk Waste ............................. Mineral Oils .......................... Mineral Wool Slurry ...................... Moisture ............................... Molten Salt ............................. Mortal 6 Nickel Cleaning Baths; HCI, CuC4 ... Monel 6 Nkkel Cleaning Bathr; HCI, Fh(SOJ, .......................... Monochloroacetic Add ................... Monochloroaoetk ACM .................... Monochlororcetic Acid .................... Monochlorobenzeno ....................... Monoethrnolamine ....................... Monoethenolamine: Butyl Cellosolve Film Stripper @ 138OF ................... Monc+thrnolrmlne Dosulturtzlng SO .. H.S .... Monohydroxysuccinic Acid ................. Monosodlum Phosphate, pH l-3 ............. Morphollnr .............................. Morphollne @ 1zOF ...................... Motor Oil ............................ MS.08 Gasoline .......................... Mulsollnr 6WOt .......................... Murirtic Acid ............................. Mustsrd (3% Sodium Chloride, 5% Acetic Add) ............................ Myrlstic Acid ............................ MyristlclLaurk Moncethrnolrmidez Sodium Xylene Sullonate Sotution ................ Naphtha ................................. Naphthrlene ............................. Naphthenic Acid .......................... Naphthoquinone. 1,4 ...................... Naphthoquinone (scrubbing with water) ....... Naphthylamine Sullonic Acid ............... Neodol253St ............................ Neopentyl Glycol ......................... Nickel Anolyte Llquor (Into Metsls) ........... Nickel, Bright . . . . . .. Nickel Chlortde: Nickel Sulfate: Boric Acid . . Nickel Chloride NickeCCobalt + Solvent Extraction Circuit; pti 1.8~4.5.0.31.5gpl fluorides Nickel Electrolyte. Purified (Into Metals) Nickel 6 Monel Cleaning Bath; HCI, CuCI, Nickel & Monel Cleaning Bath; HCI, Fe,(SO.), tSee 161of trademarks and voduct
names
10015 1W @Zt75F
158203/-
60 --115&203/NR 80 NR --ILSINR NR -
NR NR SATINR NR
NR NR SAT NR -
_ NR NR NRNR NR NR-
100 100 100 100 NR NR NRI-
9x5
65.39:s
NR NR NR
NR NR NR
NR NR NR -
NR NR NR
NWNFUNR-
83:16:1 WM 33:39:9:2:36:, 25 74:2:0.3:23:1
rw
-l771-
603 46 -
LSSAT -Mio -
AMB ltW150
90 AM0 80 _ 220iAMB for a@tated tank

Amblenl
AM% ao/1801200:2 10
Acid 100
Unknown loo RH Splash h Spills
AMBll&l AMB Hetron@ 197.3 wth

120
120 750
lt3oll5c filler satisfactory -
7w-
180 l&l AMB NR

NR NR AM8 NR NR NR NR 95 203 100 NR NR AM&-I150
NRINPJ-
50 80 @ 1WF 100 0 145-F 100 loo 30:57 loo 10 510 10 1w loo
NR NR NR NR NR NR
NR NR NR AM0 NR NR
NWNWNR
NR75 NPJAMB NWNFU-
NR See Hydrochloric lWAcid
NR _ -
NRI2101220 -
21 o/220 120 1% 180 120/18012w 1BOiZW -
All
200 4MB1130 120 200 AMB 150 150 loBi-
1W
100 Satd Satd Unknown Satd 1w w 81 Nl etc. 12:53% ozlgal Satd
180/150 1501120 1801-
120
lW/-
;ia*
150 180 180 220 185 180
1801150 -
22012w 140/-
2101220
220
(continued)
180
202
Corrosion
Resistant
Materials
Handbook
TABLE 1.54:
POLYESTER
AND VIF
L ESTER RESI
CONCEN. TRATION % sa: M-3 5 5 07.&a
;-ASHLAND
SERVICE HETRON 92199P 220 -
(continued)
TEMPERATURE. F FOR RESIN rYPES HETRON 7ooi7ooc 220 200 1451200 2w 16celo 22G200 NR NR NR 160 150 AM0 NR NR NR 6595 lBO/l&J/210/220 ETRON 920 SERIES980 210,2X _ AROPOL 724017430 SERIES 100 150 -
HETRON 7U1971197A 220 150 150 200 -
Nickel Nitrate :: Nickal Plating; Electrorafining pH 1.5 Nickel Plating (Nickel Sulfamate: Magnesium Chloride: Boric Acid) pH 3.7 Nickel Plating Solution (11% Nickel Sulfate: 2% Nickel Chloride: 1% Eorlc Acid) ....... Nickel Plating Solution (44% Nickel Sulfate, 4% Ammonium Chloride: 4% Bortc Acid) Nickel Soap Catalyrt ....................... Nickel Sulfate ............................. Nickel Sullate: Nickel Chloride: Boric Acid ..... Nickel Sulfate: Nickel Chloride: Boric Acid: Brightener (Nickel Plating) ........... Nitrating Acid Spent ................... Nitrating Acid, Strong .................... Nitration, Spent Acid ....................... Nitric Acid ................................ NitricAcid ................................ Nitric Acid ................................ Nitric Acid ................................ Nitric Acid ....................... Nitric Acid ............................... Nitric Acid .............................. Nitric Acid ............................. Nitric: Amchem 616f ...................... Nltrlc Acid: Copper Salts .................... Nltrlc: Copper Salta ........................ Nitric, 70%: Glacial Acetic: 49% Hydrolluodc . Nitric. 70%: Glacial Acotlc: Is% Hydrofluoric Nitric: Hydrochlork ........................ Nitric: Hydrochloric Acids ................. Nitric: Hydrochloric: Hydrofiuorlc .......... Nitric: Hydrofluoric ........................ Nitric: Hydrofluorlc ........................ Nitric: Hydrofluorlc Acids ................... Nit&: Hydrofluorfc AcIda ................... Nltrfc: Hydrofluortc Acldr ................... Nltrlc: Hydrofluorlc Acids ................... Nitric: Hydrofluorlc: Chromic Aclds ........... Nltrfc: fiydrofluorlc Pickllng sdutton ......... Nitric: Hydrofluorlc Vapors .................. Nitrfc Acid: Phosphoric ..................... Nitric (34%): Phosphoric (65%) ............... Nitrtc: Phorphortc: Sulfuric: Nonionic Surfactant ..................... Nitric: Sodium Dlchromato ................... Nitric: Sodlum Dlchromate: Mqfybdlc Acid: ....................... Water @ 13DlWF Nltrlc: Sulfuric @ 210F ..................... Nitric: Sulfuric: Cbpfmr Saltr ................. Nitric: SulfurlcDlnitro-Toluene Fumes ......... Nitric: Sulfuric: HCI @ up to 226OF ............ _. Nitric: Sulfuric: Hydrochloric: Water ........ Nitric: Sulfuric: Hydrochloric ................. Nitric: Sulfuric: Na dichromate: Cr,(SOJ, ....... Nitric: Sulfuric 6&50 ........................ Nitric: Sulfuric: Water ....................... Nltrlc Acid Vapor ........................... Nitric Acid Vapor ........................... Nltrfc Acid Vapor ........................... Nitric Acid Vapor ........................... Nitric Acid Vapor ........................... Nitric Acid. Vapor 6 Condonsato .............. Nitric Acid: Wettlng Agent ................... NitricAmmonia Fumra ..................... Nltrtc, Gone.; Sulfurfc. Cont. ................. Nltrfc Oxldo, Cl,, HF Furnor ................. Nitric Oxldr. Chlortnr. Hydrofluorlc Fumes ..... Nltrfc, Rod Fuming ......................... Nltrlc. 70%: Sulfurk. 70% Pickling Acid ........ Nltrobenzene .............................. Nitrogen .................................. Nitrogen Fertilizer Solution ................. Nitrogen, Liquid .......................... Nitrogen OxideMethanol Fumes, @ 22OF .... Nitrogen: Oxygen ........................ N,: CO,: SO,: 0,: H,O Vapors ..............
AROPOL 7343 samlacmly
Satd 53126 orlgat 220 -
AMB 220 160 150 60/6O/NA 60160/NR -
40.6:6: Trace oz/gai @ 160-F 2 5 10 20 J5 a 50 52 4 166 15:lal gpl 2crlW gpl 521 Qp 110-F 6:3:1 0 1WF lo.10 5:x) 10.77 13 7.5.2.5 15:5 12:24 @ 60-F 154 @ 1Bo.F 2013 505 0 12QF 2z3.8 20x5 35:5 3:60 4:7 by vol. x):11:59.1 ?0?8oz/gal@80 2So.w:<o.1:75 %m 9.5:17:112 gpl 1020:10z6 molar 10:20:30.40 12:x):30 3.0:7.0:25 gpl 30 !m39 36% 10% 60% 24 @ 183-F 46 @ 1WF 5 2% ougal :S3 ty vol. @ 1OO.F UIllUlOW unknom not 100 0 75-F 1o.S:51 100 100 26 100 Unknown W5C 0.12 0.1:5 14 by VOI
NR NR
_
NRINR,210,220 160 1201140 1001150 NR NR -
NWNRI21w2@l 1401175
210 m 140 140 140 140 110 65.95 150 10160 NR NR 200 21w2101loo 165 165 NR 135 NR .Yl 105 203 125 120
160/120 AMWNR NR NR NR NR NR NR NR -
NWNWNW15&JNWNW-
zoo/NR
NRI-
NW-
NR
NR NR 105 60 NR
001NRI-
NW-
SAT/SAT/NR IO160 al 90 40180 180 WNRJNR 2cm 175 160 60 120
NR NR NR -
NRI-
NR/17Y95 -
NRIlM)il&l 1601180
NR
NR
NR NR NR
160/160 -
mlNR -
NR Hot
NR NR 60 NR 160/60 NR NR 60 NR NR &l/NR -
Go/t! jee 65 120 lisl of trademarks
Hetron 31 SAT also, no veil NR and product names
_
(continued)
Synthetic
Resins and Polymers
203
TABLE 1.54:
POLYESTER
AND VII
L ESTER FiESl
CONCEN. TRATION % 79 157 100
51 0649 1W
i-ASHLAND
SERVICE HETROn 92!99P
(continued)
TEMPERATURE. F FOR RESIN TYPES HETAOH 920 SERIES980 HETRON 72ll971197A 175 AM0 120 200 lx)/AM0 AM0 165 SAT 1M 120 110 loo lzolLSNR 12O llr! 110 loo AM0 NR 16Oirw NR AM0 lx, loo AMB/AM&AM&12aAM&AM&-AMBIliM~15O ZICUIM 16@15O AM0 AMBIAM&160 NR _ 200 2101150 200 AM0 120 xx) NR 130 122 14O AM0 180 180 leeJ130 NR lx) 1801130 200 NR 130 AM0 LSISAT 120 120 110 120.1 IO,100 1601200 NRlW 2001210 160.220/_ 210 210 210 NR200 200 200 200!210 NR 130.2wi210 _ AROPOL 7240:7430 SERIES HETRON 700~700c
Nitrogen: Oxygen: SO,, droplets 60% Sulfuric Nitromethane Nitromethane(tris, hydioxymethyl): Formaldehyde: Water, pH3 ........ Nitrophenol ..... : : : : .. pNitrololuene !&Ironic Acid .............. Nitrous Acid .......... : : .............. Nitrous Acid ............. Nonandioic Acid .......................... Non-Condenrrble P&P Mill GJe ............. Nonionic DispersJnt, Blend a 12SDF ......... Nonionic SurfJctrnt, Afkanolrmide ......... Nonionic SurfJctJnt, Alkyl Ether Amine ............ Oxide ............ NonylPhenol:::::::::::::::: .................. Nonyl Phenol, Ethoxylrted NonylphenoxytrfethoxyethJnol SulfJte, SodiumSJlt ............................ Nuclorr, RJd WJste ....................... NucloJr Swimming Pool ReJctor Liner ........ Nuclear Waste Ammonium Nitrate ..................... Fluoride Solution Nuclear Waste, Water, Low Level ........................ ionexchange.. ......................... NutOif,Ground Oakitet Cleaner, pH 11.12 @ 185F .......... Oakitet Strfpper SAt ...................... Octanoic Acid ............................ ........................ Odichlorobenzene Oil. Crude, B ............................. Oil, Crude Storrge Tank Bottoms ............ Off,Fumace. ............................ Oil. Gas, Dirty, Relinery .................... Oil, Heating .............................. Oil, Low Sullur Crude ...................... 011, Medium Sulfur Crude ................... Oil, Mid-Continent Sweet ................... Oil, Oxidized Petroleum Heavy Bottoms, 7.6 fbr/gJf with JbOUt 10% Acetic Acid ...... 011. Refinery WJste Eflluent ................. Oil. Slop, Refinery ......................... Oil, Sour Crude .......................... Oil, Sour Crude, Wyoming .................. Oil, Waste, Various Ketones, ArOmJtiCS ....... Oil, Water SepJration ...................... Oil, West Texas Sour ...................... Oil, West Texas Sweet ..................... Oilr:AnimJl.............................. MinerJl................................ Vegetable ............................. Olefin (JiphJ) Sulfonate .................... Oleic Acid ............................... OfeoparJthion ............................ Oleum (fuming sulfuric) .................... Oligomertc Dlspenunt ...................... Olint 58981 ............................... OliveOil.. ................................ 1gODt: VlnylidJne Chlorlde .................. OPM.lf .................................. opht.2t .................................. Ore Smelting Furnace Gas, Wet, with dust: 4O%NJ. 23% Cd, 6% Pb, 21%B, 6%Zn Jnd other Oxides to 400F .............. ..................... Orgrnic DJlJgJntJ Organic Solvents + Aqueous HCI ......... OrgJnotin, Quetemary Ammonium S~ltr, Amlne Selts Blended ............. Retardant Liquid Formulationr .......... Oxalic Acid ....................... ... .... Oxidizing Gases Oxygen: CO,: SO,: SO,: H,O, Trace; cl;.N, : : Oxygen: Nitrogen ................... Oxygen: Nitrogen: SO,; Droplets 8!% Sulfuric 0,: N,: CO,: SO,: H,O Vapors ........... ................ Ozone ....
tSee hsl 01 lrademarks and product ndnws OStnOSJ COmpJny PrJmix; Jnd Fir0 oil. SWJJt CNdJ .........................
_ NWAM0
NR
_ 120-
24
100 10 Satd 100 55 aInN% 100 100 26
100 loo SAT loo
loo -
100 Cone. 0 la, 12OF
14O/NFUNR/-
AM0
Satd
140 -/LS12QNR -
Unknown Unknown AMBI1W 100 100 1W 100 3 100 loo s&2 2w 140/NR 13W14tN-
AM0 210 210 AM0
SATISATINR pHl2 @ 75F Unknown @ 194-F 100 100; 5O L 16 All loo 21.1.5:o 9.0.2.5 5050 15 79:7 5.70:12:0 1.14 by vol 3 NR 125
NR NR
NR_ -
LSl2YNR 02-
125
216 220 _ _
220 AM0 -
220 AM0 200 65 175 120 100
180 140 -
2201200 AM0 -
_ _
(continued)
204 TABLE
Corrosion Resistant Materials Handbook 1.54: POLYESTER AND VINYL ESTER RESINS-ASHLAND
SERVICE
(continued)
TEMPERATURE, F FOR RESIN TYPES HETAON 920 SERIESi HETRON 7211971197A AMB 1cO1100/140 100 AMB 76-120 110 140 AMB AMB 65165/B516Y65/6=5/651851100 120 140 125 125 125 160 AROPOL 7240/7430 SERIES HETRON 7001700c
CONCEN. TRATION % Fumes
HETRON 92199P 0,
Ozone:Hydrogen
Ozone: Ozone Oxygen,
Ozone/Cyanide
..............
........................ Wet .................
20 Ibs/day 8 1% Unknown 1.5-2.5.0,
Sewage Treatment ..... 3 :. : ......... Ozone Treatment Condominium Waste ....... 4 lbslday @ 2% 0, Palmitic Acid ............................. Satd Paper Machine ........................... Fumes Paper Mill Liquor .......................... Unknown Parathion, Wet ........................... Parco 450/45t, pH 1, HF presenta ............. Parco Cleanert 556R ...................... 100 Pax Hyspeedt, Detergent ................... Satd Peanut Oil .............................. 100 Peel Oil .............................. 100 PepSet1505t.. .......................... 100 Pep Set2596 ............................. 1W Perchlorlc Acid ........................... 5 Perchloric Acid ........................... 10 Perchlortc Acid ........................... 30 Perchloric Acid ........................... to 70 Perchloroethylene ....................... 100 Perchloroethylene, Vapor & Condensate ...... 100 Petroleum Ether .......................... 100 Petroleum Oil 61Waxes, Water Emulsion ..... Phenate Based Algaeclde .................. 1M) Phenate Based Bactericide ................. 100 Phenate Based Fungicide .................. 100 Phenol .................................. 2 Phenol .................................. 5 Phenol .................................. 10 Phenol .................................. 65 Phenol .................................. 100 Phenol, Formalin, Sulfuric Fumes ............ Unknown Q 2CilF Phenol, Fumes ........................... Phenol: HCI : Water ....................... 20:10:70 Phenol Sulfonic Acid ...................... Satd Phenolic Resin. Urea Modllied (Durezt 24942) .......................... PH 78 Phenolic Spent Caustic, Refinery ............ Phenollc Spent Caustic, Refinery, Neutralized to pH 5-6 .................... Phenols, Some: Sulletes, H,S, Water, Waste Liquor, pH 5-6 .......................... 0.Phenylphenol: Sodium Xylene Sulfate: Isopropyl Alcohol: Potassium Rlcinoleate: 6:10:10:6:67 lnerts ................................. Phosphate MIX (NaOH + H,PO,) ............ PhosphatelPhosphoric Acid Waste 510 Liquor, pH 1-3 .......................... Phosphate Rock Dust Scrubbing ............. Unknown Phosphate Salts .......................... 25 Phosphonitrilic Chloride, Cl,, HCI, Benzene. H,OVapors .................... Phosphoric Acid .......................... 65 Phosphoric Acid: Calcium Chloride ........... lo:25 Phosphoric Acid, 26%, Some Fluorides, Fumes Ammonla; Reactor ...................... 40:7:2 Phosphoric: Chromic: Hydrofluorlc .......... Phosphoric: Chromic: Hydrofluorld .......... 8.5:9.3:11 Phosphortc: Fluorine: SIO, .................. 54:1.2:2 65 Phosphoric, Food Grade .................. 15:9 Phosphoric: HCI, Sat. with Cl, ............... 15:9 Phosphoric: HCI, Sat. with Phosphorous ...... Unknown Phosphoric: Hydrochloric Acids ............. Unknown Phosphoric: Hydrochloric: Butyl Ether ........ Phosphoric: Hydrochloric: HP .............. 65:1:5X ppm 50:2:7 Phosphoric: Hydrofluoric: Cr,O, ............. 6:11:9 Phosphoric: Hydrofluorlc: Cr,O, ............. Phosphoric: Hydroxyacetlc: Sulfuric Acids .... 5129120 Phosphoric, 36%: 70% Kerosene, 10% lsodecanol, 20% Organics ................ 35:33:33 Phosphoric 65%: Kerosene: Xylene .......... Phosphoric Acid: N-Alkyl Dimethyl Benxyl 25:0.1:75 Ammonium Chloride: lnerts ...............
tSee list of Irademarks and product namrs
_ 140/160
_ 160 1801120 175/120 AMB AMB NR NR NR NR NR _ 125 125 125 NR NR NR NR _ NR NR 130/130/130/-
_ _
2201200 _ AMB AMB NR _ 125 125 125 loOI-lOOINR NR _ _ NR 130 130 130
AMB 140/AMBJ120 120
1601AMBIAMBI1801150/SO/100 _
NRINFUNPJNFUNR/-
_ 8ollW
100 NR NR 80-110 NR AMB 130 130 130
NW30 NR/NR NFVNR
loo/1701-
100 200 SATIAMB 220 _ AMB 120 250/250/200 100 to 250 100 100 175 180 220 220 SAT SAT 230/230/100 100 243/243/150 100 100 100 _ NR AMB 1801150 -
_ 2201200 NR NR 1OOINR _ _ _ -
AMB
2101220 _
_ -
_ loo/-
(continued)
206
TABLE
1.54:
POLYESTER
AND VI
L ESTER RESI
CONCEN. TRATION %
25 sac d Sal C Q 265F All Sat d Sal d
;-ASHLAND
SERVICE HETRON 9299P AMB
NW90 -
(continued)
TEMPERATURE, OF FOR RESlh TYPES HURON 920 SERIES980 180 _ 210,220 HETRON 72i19lf197L 110
110 _
CHEMICAL ENVIRONMENT Potassium Carbonate Potassium Carbonate ...... Potassium Chlorate ............ ...... Potassium Chloride Potassium Chloride: Cl,, Br, Satd;. pH 2.4 Potassium Chloride, Mercury Grade ......... Potassium Chloride: Potassium Hydroxide: Hypochlorite with Treces Chloropicrin @ 194OF ........................... Potassium Chloride, Wet Vaporr ............ Potassium Cyenide Potassrum Cyanide: K Hydroxide: Copper Cyanide ...................... Potassium Dichromate .................. Potassium Ferrlcyenide .................. Potassium Ferrocyanlde .................. Potassium Fluoride2 ...................... Potessium Hydroxide .................... Potassium Hydroxide .................... Potassium Hydroxide .................... Potassium Hydroxide ................. Potassium Hydroxide ................. : Potassium Hydroxide: Potassium Chloride: Hypochlorite with Traces of Chloropicrin @ 194OF ....... .. .......... Potassium Hydroxtde: Potassium Cyanide: Copper Cyanide ................ Potassium Nltrate ......................... Potassium Oxalate ........................ Pota*sium Permanganrte .................. Potassium Peroxide ...................... Potassium Persultate ..................... Potassium Pyrophosphate ................. Potassium Ricinoleate: 0-Phenylphenol: Sodium Xylene Sulfate: Isopropylalcohot Inorta .................. Potessium Sulfate ........................ Power Plant Scrubber, Med. Sulfur Coal, pH 1.936 ......................... Power Plant Scrubber, Med. Sulfur Coal, pH 1.936 ......................... Premix Liquid (Osmose Co.) ................. Propenoic Acid See acrylic acid Propionic Acid ............................ Propionic Acid ............................ Proplonic Acid ............................ Propionic Acid @ 12CtvF .................... Propionyl Acid @ i2tJF .................... Propionyl Chlortde ........................ Propylene Glycol .......................... Pulp, Bleached ......................... Pulp and Paper Mill Bleach ................. Pulp end Paper Mill Condensable Liquor, pH 9 ....................... Pulp and Paper Mill Digester ................ Pulp and Paper Mill Recovery Boiler .......... P 6 P Mill Waste, Acidic .................... PulpStock.. ............................. Pulp Stock, Chlorinated, pH 4.5 .............. PVC Latex with 35 partr DOP ................ Pyridine ............................. Quaternary Ammonium Compound, In Isopropanol, Cationic .................... Quaternary Ammonium, Dialkyl, Dimethyl Type: Aqueous lropropanol ............... Ouatemary Ammonium Salts, Organotln, Complex Amine Selt Solution Q 125OF ..... Ouatemay, Dlcoco Dimethyl ................ Ourternary, Dimethyl, Dlrtraryl In Isopropenol .......................... Ouatemary, Dimethyl, Dlstearyl in Neutral Organic Solvent ................ Quaternary, Hexylene Glycol ................ Quaternary, Methosultate Type ............ Quaternary Softener, Difatty Complex ....... R.2 Solutions .... Rad Waste, Nuclear : : : : : : : : :
tSee 1151 trademarks 01 and product names
AAOPOL 7240 7430 SEPIES

AM6 -
ETROH 700 7OQC :5G

AM6 _
2w -
250 190 180
:60150 -
220,206 _ -
15:15:1 Satd 3.2 8 origai All Sald Satd AMBI-
AMB 175 200 200 150 NR 175
NR 1843!180,150 1801150 lM/NR -
200 22O~lt3C 2201180 150 150lAMB 15OIAMB AMB _ 1751-
NRINRJ_ 21ci22c 210220 210!220 150 150 150 150 150 150
200, -/zoo 200 NFUNFUNFU-
Sotd
10 25 45 50 2 oz/gat
15.15 1 2:3$
200 150 AMB 175 220 150 AMB loo
1801150 12YNR AMBI-
22012w 2w115l 200 100
NFL2
arlgal
All
101220
-
Satd All Sald Q 80-F All 100
2101220 2101220 1001-
6:0.10:10.%7 All Liquor Mist 8 Fumes 100 1 20 100 80 80

100 0
2W -
loo 220 150 150 80
180150 02J80 NR LSINA 1701150 _ AMB 120 NR 1201120 120~120 LS 1201120 1201120 190150 120 120 120 120 120 120 _ _
22012w 80 NR LSNR 2001180 130 AMB NR 120 120 SAT 120 120 1w 120 120 120 -
lW/2101220 80 2008NRINRINPi2101220 _ 1301AVB NR 12OI1201120/120/1901120 120 120 _ -
806 NRINWNR/lOOU70 AMBIAMBIAMBI-
NR NR NR 184 190 130 150 190 110 NR 120 120 SAT 120 120 190 120 120 120. 180 100
1WF All -
Fumes Fumes Fumes FUMS
100 75.25
NR 120 1201-
75
1X4120/1%X-
Sald -
120/12011201-
(continued)
Synthetic
Resins and Polymers
207
TABLE
1.54:
POLYESTER
AND VIP
L ESTER RESI
CONCEN. TRATION %
;-ASHLAND
SERVICE
HETRON'
(continued)
TEMPERATURE, F FOR RESIN TYPES
HETRON
92199P AMBI1671NRI140011W
HETRON 7219711971
AROPOL 724017430 SERIES
HETRON 700700c
920 SERIESI9EO
Radiochemical Hoods, Glove Boxes

Raylenet
....
: I. .... RayonSpinBalh ..... Rayon Spin Bath Evaporator/ Crystalizer to 16O0F Rayon Spin Bath Fumes C 195.2C13bF : ...... Rayon Spinning Fumes ............... Recovery Boiler Biow.Down; Acetic: Sulfuric Sulfurous: Formic Acids: Acetone ............................... Recovery Boiler Flue Gas to 400F ...... Recovery Boiler (Kraft), no contact rvap.; 59100 ppm SO,, 12.14% CO,, 19% by vol. .......... moisture, 37 lps to 4U0F Recovery Boiler Stack Gases 6 3&F ... .... RedLiquor ............................... Reformer Charge ......................... Renderlng Fumes, Ozone, Chlorine ........... Rhodium Plating, phosphate ................ Richamide CDAT .......................... Richonate 165Ot ......................... RJ-Qt Fuel ............................. Rock Wool Slurry ....................... Salicyiic Acid ......................... .I: Salt, Molten ........................ Sand, Dry, 60-70 Mesh, 350 cfm ...............
send, Slurry
50 -
150 180
1401-
--,LSSI140
NW-
212 SAT!SAT/NR
NR NR
21212W
NPJNR-
Fumes -
SAT/SAT/N,? SAT!SATINR -/MO/-
NR NA AMBIe-
NWNW-
100 100 100 Unknown Sal0 Splash 4 8 Spells
120 120 120 120 80 197.3 with llller
804Hetron
80 satlstactow for aaltaled
120 120 80 tank. Amblent 150 Restslant Liner
160,-
7501Hetron 31
750 Sallsfactoly
Sani-Fresht Soap Solution .................. Scrubber, Med. Suitur Coal, Particulate, pH 1.9 3.6, Cl560-1200 ppm. 309,ooO ACFM Gas ..... Scrubber, Med. Sultur Coal, Particulate. pH 1.9. 3.6, Cl560-1200 ppm. 300.9W ACFM Gas ..... Scrubber Sludge; 30% Solids (96% Ca SultetelO% Ca Sulfate), ..................... 15%FlyAsh,pHll Scrubber Sludge; 36% Solids (90% Ca Sulfate 10% Ca Sulfato). 15% Fly Ash, pH5. ......... Water ................................ See Water, Desalination, pti 7.5 @ 265.F ....... Sea Water, Desalination, pH 7.5 .............. Sea Water, Desalination, pH 7.5 .............. Selenious Acid ............................ Septic System ............................. Sequestering Agents ....................... Sewage, Anaerobic ......................... Sewage, Municipal, Treated 6 Untreated ....... Sewage Treatment ......................... Sewage Tmatment Fumes ................... Sewage Treatment, Ozone, 3% ............... Sewer Gas; H,S .......................... Shampoo, Carpet .......................... Shampoo, Liquid .......................... Silicone Oils: Hydrochloric Acid .............. Silver Cyanide ............................. Silver Nitrato .............................. Silver Nitrate: Coppw Chloride ............... Silver Plating Solution. 4% Silver; 7% Potassium and 5% Sodium Cyanides 2% Potasslum Carbonatti ................. Silver Refining Cells ........................ Single Vessel Chlorine Dioxide Process (Hooker) ........................ Skydroi 500t, Hydraulic Fluid Siimicide, Organotln Amine Blend r@125F ..... Slimlcide, Polychlorophenate organosulfur blend ....................... Slimicide, thiocyanatepoly&lorophenol blend @ 125OF.. ........................ Slurry, 20% Clay: 20% Potash In Satd. Brine .... Slurry, Coal/Water @ 6OF .................. Slurry, Lime ............................... Slurry. Mineral or Rock Wool ................. ............... Slurry, Sand/Water Q 60F Smelting Furnace Gas and Dust, Wet to 4OOF ........................
tSee swat SIa ...................................
.............................
kY%'Qai @8o.F
All NR wtth Abrasnn
120
150
150
120 120 100 180 --/LSINR 180 132 AM0 125 85 AMB AMB AM0 100 AM0 100 120 195 PO 80
loo 18WlM -
loo 180 -
AMB 85 AM0 AMB --IAMB -
IWi2101_ 2101AMB AMB AMB AMB AM0 lW/21012101-
NOrmal 175 x Normal 2.75 x Normal All 100 -
AMB 125 85 AMB AMB AMB AMB LSlWINR
AM0 125 AMB AM0 AMB AMB 1w 200
100 7921 Satd All x3:15
AMBI200
180/150
100 loo 100 100 40 Slurry @ 80-F 10190 Satd Unknown 4 lbsigai lEOIHetron Hetron Hetron etro -
NR SAT 197 SAT throughout 160 SAT 125 --ILS/NR 197 SAT @ 12 tps 197-3 with abrasion except
NR for absorption Ah48 LSiNR 125 SAT resistant 170180
200
2W/NaOH 150/1&l -
Of Cl, or ClO,m SAT 125 SAT
at 7 ips 170
180 197.3 wth t!ller satlsfaclory Hetron SAT.SATINR
Fuller Satisfactory for agitated
tank. Amblent
31 Satlsiactory -
hsl01 trademarks
and product
wmes
(continued)
208
TABLE 1.54:
POLYESTER
VINYL
CONCEN. TRATION % Unknown -
S-ASHLAND
(continued)
TEMPERATURE. OF FOR RESIN TYPES IiETROH 920 SEWS980 AROPOL 7240 7430 SERIES HETRON 700'7ooc
HETAON 721971197A
Smoke, Particulate, Cooling and Washing with Waler Soap Plant Fumes Soap Solution :::: :. Soap: Sulfuric .,.... Soap Tower Exhruat Fumer 1 : : : Soda Ash; Sodium Carbonate ....... .. Thickener Fumea .......... Sodium Acrtrte .......... Sodium Acid Sulfite ..... Sodium Alkyl Benzene Sulfonrte .......... Sodium Alkyl Xanthate Sodium Alkylaryl Sulfonate; pH 6 .......... .......... Sodium Aluminate Sodium Ammonium Phosphate Sodium Benzdate ........................ Sodium Bicarbonate ..................... Sodium Bicarbonrts ..................... Sodium Bichromate ...................... Sodium Bichromate: Sulfuric: Sugar .. Reaclion Product, pH 26 ............ Sodium Bisullaie ....................... Sodium Birullide ........................ Sodium Blsulfider ...................... Sodium Bisulfide ........................ Sodium Bisulflde: NaOH .................. Sodium Blsulflte ......................... Sodium Bisulflte: Sodium Sulfate: Sodium Sulfite ........................ Sodium Birulflte/Sulflte ................... Sodium Borate ......................... ... Sodium Bromide ..................... Sodium Carbonate ....................... Sodium Carbonate ...................... Sodium Carbonate Q 206OF. .............. Sodium Carbonale ....................... Sodium Carbonate ....................... Sodium Carbonatea ....................... Sodium Ca~otWt~: Soda Aah Thlckrner Fumoe ...................... Sodium Carbonate, Vapor & Condensate ..... Sodium Chlorate .. ...................... Sodium Chlorate ....................... Sodium Chlorate, Sodium Chloride .......... Sodium Chlorate: Sodium Chloride with .... 350ppmCr,10ppmCa,10,000Ampr.. Sodium Chbrato: Sulfuric: Chlorinr Dioxldr: Methyl Alcohol ................. Sodium Chloratr, Sulfuric. Methanol, Sodium Sulfate ......................... ......... Sodium Chloride ................ Sodium Chloride: Calcium Chloride: ................... Magnesium Chloride Sodium Chloride, Cl, Satd., pli 2 ............. Sodium Chloride, Cl, Satd .. pH 2.6 ........... Sodium Chloride: CIO, ..................... Sodium Chloride, Dechlorinated: pH 25 Free Chlorlno (Traces) ................... Sodium Chloride: HCI ...................... Sodium Chlorldo, Mercury Grad r ............ Sodium Chloride, pH 3 ..................... Sodium Chloride. pH 3, Cl, Satd ............. ....... Sodium Chloride. pH 3.5 ............ Sodium Chloride, pH 10.5, Cl, Satd ........... Sodium Chloride, pH 11, some Cl, ............ Sddlum Chloride. Satd. Chlorine ............. Sodium Chlorldo: Sodium Chlorate ........... Sodium ChMdo: Sodium Chlorate wlth 366 ppm CR. 10 ppm Ca. lO.WO Ampa ....... Sodium Chloride: Sodium Nltrate: Sulfuric ..... Sodium Chloride: Sulfuric Acid .............. Sodium Chloride: Sulluric. Chlorine + CIO, .... Sodium Chloride, Vapor & Condensate ........ Sodium Chloride, Wet NaOH. Chute .......... Sodium Chlorite ....................... .................. Sodium Chlorite ...
tSee list of lrademarks and product name8
lW/AMWlOO 14O/-
lee AMB AM0 1M) 160 2ao 165 100 120 NR 2cHl 176 140 140 140
AMB AMB -
AMB
AMB _ -
AM6 215!-
15OlNR 176l160/120 16012001150 120iAMB 150 160~160 16oi140
100 15 100 All 40 sat d Unknown Satd 10 Satd
2001150 NR 176 14Ol140 -I90
210/220 150'1201lie2101220 1601150/2101220 l40'1401140/210/220 2101220 2101220 1&J:1601160/l&I1601210:220 210!220 -
All 15 65 45 15% Satd 15:15:15 5CU53 Sald Sald All 2 10 10 25 32 6&d 170 220 120/12O/AMBIIWAMB lW160 -i90 200 200 -
1e01150
200 140 _ 140 140 2oa 22Of140 160116Q 16CllW 1801160 160 160
200 160 160 160 200 165 150 170 250 160/160/160/160/LS AM6 AM0 180 160 203 200 160
NR 16W90
16oirro 1601150 150,1601NR AMB AMB/-
130 NR -
2co 200 150
10 90 Satd 3.2M:3.4M 340%0 gpl
145 125
20:450 gpl:Sald:Trrce
160/150 200 212/200 NRILS ZlW2101NR 2101220 -
Sald 12:10:2 -310 QVI Satd 2335 Satd SstdJ Satd Sald Satd Sald Sald Satd Satd 3.4M:32M 2w:340 6:620 6.12 23:35 Sald 100150 tons/day 2 25 gpl
200
2M 1M 212 170 120 ZM) 160 210
NR -
NIU-
210 165 190 165 220 160
150 160 212 120 160 175 160 AM0 212 175 -
210:220 210~220
(continued)
Synthetic Resins and Polymers TABLE 1.54:

209
POLYESTER
AND VI
L ESTER RESII
CONCEN. TRATION % Sat d
Satd 43 Sat'd 50 10 Sald 30.70 Sat'd 40 100 Sat'd Sat'd All All Sst'd Unknown 15.65 45 15:15 0.5 %@14O'F-33%&3'F-I 1 5 10 15 25 50 Unknown @ 160-F 5:12 10:10:10:70 30.1.6
S-ASHLAND
HETROM' 92/99P
(continued)
FOR RESINTYPES HETRON 700 7ooc '50 200~180 180 210!2co 120 120 220/200 220'200 NR lcoNR LS125:NR 120'NR NR NR NR NR 140 140 LS2cO~120 212'150 2121150 212115a 2lZlM NR NR 14O/ldoi_ 150 150 120 120 180 18011M HETAON 920 SERIES!980 2101220 2101220 2101210,21012101210:220 2101220 180 1501150'/METROW 72119711971 150 AROPOL 7240!7430 SERIES ha 103 lx):1M 160 180'120' 120' 180150 180150
SERVICETEMPERATURE.OF
...... .... Sodium Chlorltr .... ......... Sodium Chromate ... Sodium Cumene Sullonate .... Sodium Cyanide ...... : .... : .. SodiumCyanide. .......... 1:::. ........ SodiumCyanides.. Sodium Dichromato ...................... Sodium Dkhromatr: Acetic Acid ............ Sodium Di-phoaphato ..................... Sodium Dodocylknzeno Sulfonata, pH 8 ..... .................... Sodium Ethoxyrullatr ..................... Sodium Forrkyanide Sodium FormcyanIde ..................... Sodium Fluoride ..................... ................... Sodium Fluororilkatr .............. Sodium Hoxamotaphasphate Sodium Hydmgon Phoaphato .............. Sodium IiydrcHulfldo ..................... Sodium Hydrosulfldoa ..................... Sodium Hydmsulflde: NaOH .............. Sodium Hydroxide ....................... Sodium Hydroxide ....................... Sodium Hydroxide ....................... Sodium HydroxIdea ...................... Sodium Hydroxide ...................... Sodium Hydmxido ....................... Sodium Hydroxldr ....................... Sodium Hydroxldo ....................... Sodium Hydmxldo: Ccl.: Alumlnum Chlorida . . Sodium Hydroxide Croaylk Acid ........... Sodium Hydroxldr: Ethylonr Dlamlne: Diethylena Triamlnr: Water ............. Sodium Hydroxldr: Gluconic Acid ........... Sodium Hydroxldr (10% l xpoauro time): H,SO, Paato (90% rxporun tlmo), sulf1da Roductkn Proco8aJ .............. ..... Sodlum Hydmxkk, Intomtlttont Smlo Sodium Hydroxldo: NaHS ................. Sodlum Hydroxide Noutmlizatlon of Acidk Organks ..................... Sudlum Hydroxide Nwtralizatkn of Acidic Totuono, Naphtha ................ Sodium Hydroxide Scrubbing Cl, Blow Gas ... Sodium Hydroxldo Scrubbing Cl,. CIO, ...... Sodium Hydroxldo: Sodium Thio4fate 6 Sulflde ............................. Sodium Hydroxldo Vapor & Condonsatti ..... .............. Sodium Hypochlortto34.47.. .............. Sodlum Hypochloftt&~47.. ............... Sodium Hypochlorlt&~*7.. Sodium Hypochloriter 4 5. 7 ................ Sodium Hypochloritr Reactor, 10% Excess Cl, ......................... Sodium Hypochlorlto Reactor, .................... 10% Excorr NaOH Sodlum Hypochlorlto Vapora ................ Sadlum Lauryl Sulfatr ..................... Sodium: Magn4um: Calcium ChlorIdr Solution ....................... Sodium mota~araonltr ..................... Sodium Mothacrylatr, pH 10.10.5 ........... ................... Sodium Monophoaphatr Sodium Nitrato ........................... SodiumNitritr.. .......................... Sodium Nlttitr: Sodium Chlorldr: Sulfuric ..... Sodlum Porsulfrtm ........................ Sodium Phoaphato. Mono, pH 1-3 ............ Sodium PhosphatePhorphotic Acid Scrap Liquor. pH l-3 ..................... Sodlum Polyactylatr. pH Oslo.5 ............. Sodium Silicate .......................... Sodium Silicate, pH 1223 ................... Sodium Sulfate ........................... Sodium Sulfate: Boric Acid with 0.25% Sulfuric. 0.03% H,O,, 100 ppm Iron, 3000 ppm Chlorldr, TomPoratun Cyckd"
+fETRO%
COndrt~onS
-/loo 9ot-
180 120 LSl60iLSl60iNR --ILSlSO~NR --ILSl2O/NR
220 --1220
250 180 150' 200 160 160
NW1401180 NRl1B.I NFUNIUNWNW-
155 LS/LYNR 140 LSAMS LSAMB NR NR NR -
80 -
520 15 15:15 @lO'F @W'F 2Q 5 302 5 5% 10 15 2 15 15 5% 1W 122:10 50 25 Sat'd Sat'd Sat'd B:8:20 20 510 --1150 220 18CNNW1Bo 125z'NR 1WNR NR 12Y-
150 140
NR
140 NR 1401 -
100 NR 180 125 120 110 125
NR NR NR 120 LSJNR NR
NR 120 120 loo 120 125 120 120 125 150 150 1M 150 10
100 150 130 180 180~150 250 180 180 200 200 180 160 2ao AMB 9CjNR NR 175150 l@OllM 1801150 -
100
120 150 180
2101220 2101220 210/220 120/-
2201180 22cul80 -
l&3160' 200' 220.200 150 2101220 2101220
25 6 All
AhW180
25:15
tsee lslol
--12061206 trademarks
-206
2ffi'f-
197
and
700
Some
Serk?S
CtsZ!g
r.?s!s
but
dogear
to be unsurrable under cyclic

under StaOc cond,t,ons
and product names
wtth
are res,stdnt
(continued)
Synthetic
Resins and Polymers
211
TABLE
1.54:
POLYESTER
AND Vlh
L ESTER RESI
CONCEN. TRATION %
;-ASHLAND
HETTRIJN 92199P
(continued)
TEMPERATURE. OF FOR RESIN TYPES HETRON 920 SERIES990
210
SERVICE
CHEMICAL ENVIRONMENT Sugar Solution

Sulfamic Acid
NETRON 721197!1971
AROPOL 724017430 SERBS

AM0
NETRON 7001700c
....
::
Sullanilic Acid : Sulfate: Ferrous Sullate ... 1. : : 1. Sulfate Recovery Boiler Gases ... ............. Sulfate Salts. Sulfurk ..................... Sulfated Detergents Sulfide Anolyte(NiS0 . . NiCI,. H,BO, @ pfi 1.5) for ekctro ............. nfinlng process ........... Sulfide Reduction Process Sullurk Acid Paste (go% exposure time): NaOH (10% exposure time) ... ....... ........ Sulfldic Spent Caustk. Petrochemical Sulfidk Spent Caustic, Petrochemical, .................... Nwtrallzod to pH S-6 SMte Liquors ............................. Sulfltr, Spent Liquor, Calcium Base MIII. pH 1.52 (trace lormk 6 acatk) ......... SSull4sophthalk Acid, Na Salt .............. Sulknate, Alpha Olefln .................... Sulfonated Allphatks. HCI, H.S. Butanol ....... Sulfonated Detergents Nwtrslization Fumes ... Sulfonated Detergents: Sodium Hydroxide: Sodium Trfpolyphosphate: Hypochlortte: Blsulflto Fumos .......................... Sulfonk Acid, Alkyl Benzene ................. Sullonk Acid, pnitrotolueno ................. Sullonyl Chlorfdo ......................... Sulfonyl Chlorfde, Aromatic .................. ..................... CSulfophthalic Acid CSullcphthalic Acid: Sulhwk Acid ............ Sulfur .................................... Sulfur Burner Gas Coolor. Wet to 3SOF ........ Sullur Burner Gas, Wet to 35OF .............. Sulfur Chlorfde ............................ Sulfur Chlortdr ............................ Sulfur: Cue: PbSO,: FsOz 2&O,: Bt,(SOJ, Dust ........................... Sulfur Dlchkrldo ........................... Sulfur Dichloride ........................... Sulfur Dioxldo, Ammonia Scrubber Process ..... SO,: Ammonia, Vapor ....................... Sulfur Dioxide Burner Gas, Cooler, Wet to 350*F .................... Sulfur Dioxide Burner Gss, Wet to 35O.F ....... SO,: CO,: N,: 0,: H,O Vapors ................. Sulfur Dloxtde, Dry or Wet ................... Sulfur Dioxldr. HF, H,S, F,H,SO. ............. Sulfur Dloxido; Oxygen: Nitrogen, droplets 80% Sulfuric .................... ........ Sulfur Dioxide Pulp Mill .......... SO, Removal by Cltroxt m Citrate Process ...... SO, Removal; Fossil Fuel; Limestone Injection Mist after Scrubber, pH 2.12 ........ Sulfur Dloxldr Satd. H,O: tracs HF, H,SO,, H.S. P ....................... SO,: SO, Fumos ........................... SO,: SO, Fumes, Watrr Spray ................ SO,: So,: HCI: H,SO,: Caustk It,0 Fumes ...... Sulfur Dioxidr: SO,, Wet @ 14gooF............. Sulfur Dioxidr, Trace Sulfur Trtoxide ........... SO,Vaportzatlon ........................... Sulfur Dioxide, Wet; Wet: CO .. N,, 0 .. .Dust to 350-F ................. Sulfur Fungklde ........................... SulfwHumld Ah. Fumos .................... Sulfur snd Machlne 011 Fumes ............... Sullur. Molton @ 250.28oF .................. Sulfur, Molten (H,S, SO,, H,O, SO, in ppm) @ 260~30CrF .................. Sullur. Molten, Vapors ................. Sulfur Trioxide, Dry ...................... Sulfur Trioxide: SO,, Wet 2 140-F ........... Sulfur Trioxide, Wet ......................
,See I,$., or lradrmarks and product nem~~
... : ......
50 Sal d
All
164 3003co/135
160~150 150 2001-
15 16 24.10 050
160~100 1601100
21012101_ 2101220
200
170
20:5
150 130 130 160
lx)/130/1601120
130 130 NR
2101220 2101220
4p 212-F 25 100 100. 1M 140 193 -
100 190
100 24 100 @ 75-F
190 100 200 a0 120 w SATlSATlNR SATlSATlNR NR
190 NR NR LSW/NR NR NR NR NR NR NR NR NR -
2101220 NR _ NRNPJNR NRI-
im
25 501.6 100 Vlpor @ 80-F
25:1&z!k10:83 Vaoor @ 60-F 100 0.06:0.02 by VOI
200 NR 115 120 SAT/SAT/N R
NR NR NR NR 160/150 -
NFVNR/NR/2101250 -
).1:1270:5:14 100 Water by VOI
SAT/SATlNR 120 250 170 175 --/10400/140 140 170
22Ol-
Sard
7.15:79 Fumes
1501120/NRI-
Unknown 7614 2 1W 6.10 100 100 100 100 24 76 100 190 -/LYNR 250 140 SATlSATlNR 200 HOT -/SAT/NR -/SAT/NR 30013cO/AMB -/LSiNR AMB
NR lEOINR NR NR NR
190 SAT/NR
NFUNPJ21OQ20 NRI-
(continued)
212
TABLE
1.54:
POLYESTER
AND VINYL
ESTER RESII
CONCEN. TRATION % 8 25 50 50 Q 250-F
70 75 80 93 30:6:10 30 125.13 gpl 7.6x.5 Unknown 60 5353 OzlQal 1613 a 155-F 20:20 16.12.5 3220 80 53:47byvol@ 1oO.F
;-ASHLAND
SERVICE HEmON 92 99P Iti230 2x NR150 looNR -
(continued)
TEMPERATURE, F FOR RESIN TYPES HETRON 920 SERIES,980
CHEMICAL ENVIRONMENT Sullur, Wettable. Fungicide .......... .... ........ Sulluric Acid Sulfuric Acid Sulfuric Acid . : 1::: . : Sulfuric Acid SulfuricAcid.. ... :.:.:::.:::.:..:::::::::. Sulfuric Acid .............................. Sulfuric Acid ............................. Sulfuric: Ammonium Blsulfste: Surfactrnt ...... Sulfuric Acid: Ammonium Sulfate: Manganese, pH 9 ................... ..... Sulfuric: Anodizing Solution Sulfuric: Benzene Sulfonic Acid: Water : ....... Sulfuric: Chlorate, Methanol, Sodium Sulfite .... Sulfuric: Chlorine Saturated .............. Sulfuric: Chromk .......................... Sulfuric: Chromk .......................... Sulfuric: Chromic Acid ...................... Sulluric: Chromk Acids ..................... Sulfuric: Chromic Acids .................... Sulfuric: 2% Chromic Oxide ............... Sulfuric (106N): CIO, ....................... Sulfuric, Cont.: Nitric, Cont. Sulfuric: Contaminated with Maganese Sulfate and Oxide ........................ Sulfurfc: copper Salts ...................... Sullurk: CopfJer Salts ....................... Sulfurtc: Copper Sullrte ..................... Sulfuric: Copper Sulfate ...................... Sulfuric: Copper Sulfate ..................... Sulfuric: Cu: Fe: Zn SlurryrThickener ........... Sulfuric: 1% Dodecyl Benxene Sulfonic Acid ............................ Sulfuric Evaporation ....................... Sulluric: FeO.TiOI Ore, Sterm.Air Agltrted @ 220-F ........................ Sulfuric: Ferric Sulfate: Cupric Sulfate ........................... Sulfuric Acid Fume Scrubber ................. Sulfuric Fumes In Steam .................... Sulfurk: HCI ............................. Sulfuric: Heavy Polymer, Trece Iron and Hydrocarbons .................... Sulfuric: Hydrochloric Acids ................. Sulfuric: Hydrochloric: Antimony Trioxide ...... Sulfuric. 26% by Wt.: Hydrofluortc, 20% by Wt.: Hydrocfrlorlc. 66% by Vol.: Sodium Dichromate, 3% by Wt. ............ Sulfurk: Hydrogen lodlde ................... Sulfuric: Hydroxylemine Acid Sulfate .......... Sulfuric: Hydroxylrmmonium Acid Sullrte ...... Sulluric: llmenite Ore, Steam.Air Agitation a 22OF ....................... Sulfuric: Llgnin: CrudeTell Oil, pH3 ............ Sulfuric: Manganese: Ammonlum Sulfates. pH, Sulfuric: Manganese Sulfate ................. Sulfuric: Manganese Sulfate ................. Sulfurk: 60%: MEK, 160% ................... Sulfurlc: Metal Sulfate Baits ................. Sulfurtc: Na, Mg, Zn Sulfrter ................. Sulfuric: Na Sulfate ........................ Sulfuric: Na SulfrteSatd. with Cl, ............ Sulfuric (10.6N), Na,SO,, 0.06 gpl NeCIO,, 0.2 gpl N&I ..................... Sulfuric: Nltrtc Acid 609 .................... Sulfuric: Nitric Acldr ........................ Sulfurtc Nltrk Acldr ........................ Sulfuric: Nitric Acids @ 160~200aF ........ , ... Sulfuric: Nltrtc Acids @ 210F ................ Bulfuric: Nltrtc: Copper Baltr ................. Sulfuric: Nitric: DinitroToluene Fumes. ........ Sulfuric: Nitric: HCI @ up to 22SF ........... Sulfuric: Nitric: Hydrochloric ............... Sulluric: Nitric: Na dichromrte: Cr,(SO.), ....... Sulfuric: Nitric: Phosphoric: Nonionic Surfactant ...................
tree !istof trademarks
HETRON 7211971197A 140 25025a200 200 LSLS:NR 190 175/175/NR 1M NR 110 --11001100 AM0 140 125 60 140
AnomL
724017430 SERIES
HETRDM 7001700c
1601120 1501NR NR NR NR NR NR NR -
_
22512oC 220:2co LSNR 190/16i AMB NR NR ?OfJNR NR NR NR NR 120 NR 120 -
210~220 210 226 NW160:120/NR NR _
NR60 NW-
160 NRNR225 90 165 120 NR 212 150 160 120 150 NRNRY160 -no 194 300/140 80 160 100 150 160 150 165
NR NR NR NR 1x1/-
a:31
10 gpi
33.31 gpl a12 l&5 200:50 gpl 10%.60 10:5gp1 70 to 70 1020:3&40 2a10:10 33 0.05 45 15 60 30.1 x15:5
NR
25 gpw QPI 70:Satd 10.86-W 1KU.3040 3OsO.10 40:13.135 gpl 1090 2650 gpl Kv90:10 lo:24 lo:24 35:23 35.23 NR 125 -
lh7 156 125 160 200 125 1W 203 60 135 135 160 130 130 160 16OF NRIMB/NWSATISATINR ppl molar NRI160 AMB
125 60/60 200 -
aoi-
NW-
30 56:26 8 f&:26 38a.5 20:s 179.5:112 10:1020:6
NR
NR NR NR 90 40160 60 8Ol-
NFV-
20 1030 7 013.6.25 gpl 5.20 11 0 1
andprod!Jcl
names
(continued)
Synthetic
Resins and Polymers
213
TABLE
1.54:
POLYESTER
AND VII
L ESTER RESI
CONCEN. TRATION % 51 10.5 5.399 75 2
;-ASHLAND
HETRON 9299P
(continued)
lF FOR RESlN TYPES HETRON 920 SERIES/980 aoNRHETROM AnomL 721197l1971 7240'7430 SERIES 80
80:&,/N R 160
SERVICE TEMPERATURE. CHEMICAL ENVIRONMENT Sulfuric, 70%: Nitric, 70% Pickling Acid Sulfuric: Nitric: Water :: Sulfuric: Organic (Alkyl Benzene) Sulfuric Acid Paste (90% exposure time): NaOH (10% exposure time), Sulfide ............. Reduction Process
HETRON 7001700c 80 NR -
NR-
NR _
Sulfuric, 93%: Phosphoric, 85% @ 160F .... .. ...... : : : Sulturic: Phosphoric Acid Sulluric: Phosphoric: Hydroxyacetic Acids .... Sulfuric: Phorphortc Acid: Sodium Hydroxide: Trisodium Phosphate: Water .... Sulfuric: Phosphoric Acid: Sodium Hydroxide: Trisodium Phosphate: Waler .... Sulfuric Acid, pickle liq. tank covers .......... ........... SuIturic: Soap ............... Sullurfc: Sodium Chlorate: Chlorine Dioxide: Methyl Alcohol ................. Sulfuric: Sodium Chloride .................. Sulfurtc: Sodium Chloride, Chlorfne and CIO, SuIturic: Sodium Chlorfde: Sodium Chlorate: Cl,: CIO,: Steam ................ Sulfuric: Sodium Dichromatr ................ Sullurlc: Sodium Dichromatr ............... SuIturic: Sodium Dichromate ..... : : .... Sulfuric: Sodium Dichromate ..... Sulfuric: Sodium Dlchromate: Chromic Sulfate Sulfuric: Sodium Dichromate Over Storm Coils ...................... Sullurfc: So&urn Nflralr: Sodium Chloride ..... Sulfurfc: Sodium Sulfate, H,S and CS, ........ Sulfuric: Soya Oil to 3WF .................. Sulfuric: Sullate Salts ...................... Sulfuric: CSulf~phthalic Acid ............... Sulfuric: Traca Dichlorides .................. Sulfuric: Trace Dichlorides @ 196OF .......... Sulfurk: Trace Nitrogen 6 Nltrobenzene ...... Sulluric: Trace Organiw .................... Sulfurtc: Trace Organic8 .................... Sulfuric: Traca Organics .................... Sulfuric: Trace Organic8 .................... Sulfuric: Trace Organics ................... Sulfuric: Trace Organics .................... Sulfuric Acid Vapor ........................ Sulfuric Acid Vapor ........................ Sulfuric Add Vapor ........................ Sulfuric Acid Vapor ........................ Sulfuric Acid Vapor with Trace Niltic ......... Sulfuric Acid, Waste, with up to 16% Dinitro Butyl Phenol @ lsOF ............. Sulfuric Acid, Waste, Leaching, pH 2-5 ........ Sulfuric Acid Waste with Metal Salts ......... Sulfuric Acid, wasle pickle Ilq. ................ Sulfuric Acid: Water: HAS (Hydroxylammonium Acid Sulfate) ........................... Sulfuric Acid: Watrr: HAS(Hydroxylammonium Acid Sulfate)* ........................... Sulfuric: lg20%: Xylene Derivative: T-Amine: Alkaline Metal Sal1 ............... Sulfurk: Zinc Sulfatr: Sodlum Sulfate ......... Sulfurfc: Zfnc Sulfatr: Sodium Sulfate ......... Sulfuric 134% Zn Sulfate 1.3% Na Sulfate 38%. CS,. Amines. Satd. with H,S .......... Sulfuric 5.10%. Zn Sulfate I-8%, Na Sulfate S-25% Satd. with H,S. Trace Amines ........................... Sulfurous Acid ............................ Sulfurous Acid ............................ Sulfuryl Chloride ........................... Sulfuryl Chloride ........................... Sulphidr Anoiyte. Nickel Plating Tank pH 1.5 .... Super Phosphoric Acid .............. ... Super Pnosphoric Acid ..... ::: Surfactants, Alkanolrmide .............. Surfactants. Amide Type ................. Surfactant. Anionic ..................... Surfactants, Linear Primary Alcohol Type
tSee
20:5 5050
lOso x)51:29
150 NIXL.YSATI160 243/243l100 loo 200 145 212 120 180 150 180 160 1M) 60 180 125 SAT/SAT/NR 135 100 166 -lLS/NA 166
NR -
2 14.2:0.5:82 2.5.20.2.0.5.75 25
Unknown 45X?ogpl.Sstd:Trace 12:a 35:23 4N 1M lM.Satd 30.3 30.5 ozfga1 32.4 42 5 oz/gal 952 gpl:Satd 22+?6:3.5-5 2cKa:a 10:20 10% lo:24 1.6:M 30 76 30 @ 160-F 30 47 @ 166-F 62 0 166-F 72 @ 166F 76 60 0 166-F 60 50 98 @ 1Bo.F 1520 65.70 25 177 gpl w:20:20 75:14:11 1.55:3:5 610:18:1wo 16YNW-
21512w
NR
NR NR NR NR SAT -
LSlMllNR NR NR -
140 140 NFU-
NR 166 140 140 NR 220 to xx) -/NR AM6 -/go 200 100 100 loo 1MYNR NR
l&7'/-
120 NR 1wJlsl
NR NR NR -
NR l&I NFU-
NR -
205/w-
165
10
M2wIAM0 NPJNW-
%2oo 150 150 NA NR lscl 300/3001160 120 120
NR NR NR NR AMWNR AMWNF AM6 NR NR 22012oo 2201200 120 120 120 120
1001loo/NR NR 210/22fl 210:220
Satd 99 @ 120-F
100 0 76% 75-F P,O,
loo 100 100 58 loo
120 120
lisl 01 trademarks
and product n.snes
(continued)
274
TABLE 1.54:
POLYESTER
AND VII
L ESTER RESI
CONCEN. TRATION %
;-ASHLAND
HETRON 9Zi99P
SERVICE TEMPERATURE.F FOR RESIN TYPES

HETROM 721197'197A AROWL 7240:7430SERIES HETROW 700 7ooc "ETRON 920
(continued)
SERIES!980
Surtactants, Linear Primary Alcohol Type-Ethanol Surfactant, Nonionic. Alkyl Ether Amine Oxide Surlactant, Nonionic, Tergitol 15&9t : : : Surtactant, Nonyl Phenoxytriethoxy Ethanol Type ........................ Surlactant, Polyethylene, oxy Derivative ...... Sweet Crude Oil .......................... Sweet Oil ............................... ... .... Sweetwater 35Dt: Acrylonitrile : : : ........... Tall Oil Tall Oil, Crude, ;.iO/.&en; hcid: Lien& &I 4:3 Tall Oil, 2% Spent Acid, pH1, Lignin Tall 011: Sulfuric: Llgnin, pH3 ........ : .. : : : Tannic Acid .............................. Tanning Leather, Drums .................... Tar Camphor ............................. Tariaric Acid ............................. Teller Scrubber, Wet Process P,O, Plant .... Telonett. Fumigant .. ............ Terephthalic Acid: HCI: Dimeth;; Formamide: Water .................. .......... Tergitol 15&9t .............. Tetrachlorocyclopentane Saturated with Cl, and Trace HCI. Ccl., Dlcyclopentadleno and Hexachlorocyclopentane .............. Tetrachloroethylenr ........................ 1.1,2, P.Totrachlorethylene : ................ Tetrachlorophenol, Sodium Salt .............. Tetrachloropyridino ....................... Tetrakls (Hydroxymethyl) Phosphonium Chloride .......... ....... Tetrakis (Hydroxymethyl) Phosphonium ........ Chloride, HCI, Ii,0 Vapors ................. Tetrapotasslum Pyrophosphatr .............. Tetrasodium Ethylenediamine Totraatate ..... Tetrasodlum Pyrophosphatr ................. Tetrasodlum Pyrophosphate ................. Textonet Bleach Thermolin RF-23Ot ......................... Thermolin RFe230t ....................... Thioglycol, Mono .......................... Thioglycolic Acid .......................... Thionyl Chloride ........................... Thionyl Chloride, Vapor ..................... Thiosorbic Lime ........................... Tin Fluoborate Pletlng Bath, 18% Stannous Fluobrate; 7% Tin, 9% Fluoboric Acid; 2% Boric Acid ......................... Tin, Molten, 7W*F, Fumes .................. Tinoflx DFt ............................... Titanium Sulfate Ftsduction Process ........... Tobias Acid ............................... Toilet Tanks, Aircraft ....................... Toluene .................................. Toluene @ 120F.. ........................ Toluene Dllsocyenete ....................... Toluene Sulfonic Acid ...................... Toluene Sulfonic Acid ...................... Toluene, Vapor ............................ Toluene, Vapor 6 Condensate ................ Toluene, Vapor & Reflux .................... Toluene: Xylene: Aromatic: Aliphatic .......... Tolyl Chloride (0) ........................... Toxaphene: Xyleno ......................... Transformer 011 ............................ Trensmlsslon Fluid, Automatic ............... Tributyl Phosphate Tributyl Phosphate: Aromatic Solvent ......... .................... Trichloroacetaldehyde Trichloroacetic Acid ........................ Trichloroacetic Acid ..... .... .........
1W 1W
14af200 6w220 -
12C 120 loo loo 105 210 140 AMB 200 200 2W 250 SAT 80 250 95 NR loo loo
12C -
120 120 100 200 2@J 2w 200 22a2w 22012w -
12011 210;230 180 1501NRINRINRI210/2101_ _ -
28 100 100 98.2 10:30:60 Satd 100 Satd Cone 14:287:51 100
16nilM
_ _ -
160/1w
1801150 -
100 100 loo 13 loo loo
12016s AMWNR NWloo --ILS12ChNR AM0 120 AMW17011701NR AMB 125 125
NR NR 120 -
ea1w NRI120/_
NR NR -
..........................
80 All 5 Satd @ 75-F Pure Impure loo 10 loo

loo
125 -/125 -/125 -
SO/NR 1ZYBOlNR -
130 22wOO -
lW/150/150/lW/210/220 _ lW/NR -
95 95 65-80 NR lYX1501NR 150
NR
NR NR
NWNW-
Satd
200
AMB -
50 All loo loo Satd 65 loo loo loo loo 86.3:5:6 100 @ 200-F 90:10 loo loo loo 35.65 100 @ 1WF o-50 50
SATI-
SAT AME 80 AM0
200 NR NR AM0 loo -
zoo/210/LS.AMBllW NR/.30/210/210/-
AMB NIV-/NR
AMBIAMBINR NR 150 loo 200
AMBINR NR -
12U/NR/-
120 230/230/901--iNR 122 AMB so/-AMB AM0lNR AMB
AMB NR 180 180
ZlOiNR 2101210/-
.........................
NRI2wiAMB
NR 200 AM0
AM&LSlBOrNR
tSee
hst of wademarks
and Droducl names
(continued)
Synthetic
Resins and Polymers
215
TABLE 1.54:
POLYESTER
AND VINYL
ESTER RESI
CONCEN. TRATION % loo
100 100 100 100 100 @ 120-F
;-ASHLAND
HE7RON 92199P
(continued)
HETROI 72119711971
SERVICE TEMPERATURE. F FOR RESIN TYPES AsomL

724017430 SERIES HETROW 700700c NETRON 920 SERIES980
Trichloroacrtonitrile. Trace Acetonitrile and HCI ................ Trichlorobenzene Trlchlorobenxene Vapors Wet wrth HCI : : ... 1, 1. l.Trichloroethane 1. 1, Z~Trtchloroethane ....... .. 1: : 1: : ... Trichloroethylene ...................... I, 1.2.Trichloroethylrne .................. Trlchlomethylene, 50%. .................. Trtchloroethylenr: Chlorinated Orpanics: ........ Hydrochloric (32%) ... ... Trichloroethylrne Fumes; 22% MI; 10% Cl,; 9% 0,; 6% CO; 4% H, ........... Trichloroethylene, HCI, Ct,, H,O Vapors ...... ..... Trtchloromethane ........ Trichloromonofluommethane ... : : 111: ..... Trtchlorophenol .......................... Trtcmyl Phosphate ...................... Trldecyl Benzene BulfonateDetergent Base Triethanol Ammonium Lauryl Sulfate ........ Trtethanolamine Llnaar Alkylate Sulfoneto ... Trlothylamine ........................... Triethylamine Hydrochlortde ............... Trlethanolamlne ....................... Trtethylene Glycol ................ Trtfluorovlnyl Chloride, Oils and G&ares ..... Trthydroxybenxoic Acid .................. Trtmethyl Borate In Methyl Alcohol* ......... Trlmethyl Carblnol ....................... Trimethylamlne Hydrochlodde ............. Trimethylamina Hydrochloride, pH 54 ....... Trlmrthylamine: HCI ..................... Trimethylamine HCI: Ethylene Oxide Reactlon Trtphenyl Phorphlte .................... Trtr (Hydroxymethyl) Nltromethane: Formaldehydr: Water, pH3 .............. Trtsodlum Phosphate ..................... Trtsodlum Phorphatr ...................... TunaOil ................................. Turpentlnr: Chlortno ....................... Turpentine, crude sulfate @ loOoF ........... Turpentine: Methyl Alcohol ................. Turpentine, Pure Gum .................... U-34EQt and U7000t. Styrene Acrylic Emulsions ....................... Ultraformer Fead, Reflnory .................. Ultralormer Faa&Xylena ................... Ultraformer Heavy Faed. Rrflnery ............ Ultrawett BOK Blodagrrdable Detergent ....... Ultrawet 46DS Btodegradable Detergent ...... Ultrawrt WL Biodegradable Detergent ........ Underground, Clay Soil ..................... URAN Ferlllizer~Ammonium Nitrate Composition; 44.3% Ammonium Nitrrtr. 35.4% Urea, 20.3% Water ............... Uranium Bxtraction ........................ Uranium Fluoride, KOH, HF, KF, K.0, K,UO., Cb, KCI, KOCI, KCIO,, KCIO., CO,, K,CO,, KHCO*, H,CO,, UO,CO,, F,, CIF,, DF, ....... Uranium SX Units ......................... Urea .................................... Urea: Ammonium Chloride: Ammonium Nitrate ................................ Urea: Ammonium Nitrate: Water ............. Urea: Ammonium Nitrate: Water ............. Una: Ammonium Nitrate: Water ............. Urea~Fonnaldehyde Resin .................. Urea Modified Phenolic Rerln (Durazt 24942) ... Urotropine ............................... Vanasol @ 6ClF .......................... Variquatt K-300 ............... .......... Varisottt 222-90 ...................... Varoxl6SET.. .......................... Varsolt @ 2G1F .................... Veneer Drying Fumes ..................
NWNPJ-
85 NR 212J212180 BOINWNR AMB NR
NR NR NR NR
NR NR NR NR NR 120 80 -
NR-
80 NPJNFUNRml/NFVBW120 210/15OI-
NPJNFU-I175 NRJ175l12uiNFUNRJ-
14:0.9:85.1 @ 104F 100 @ 80-F 1W 100 @I 175-F 100 loo SO loo Satd a 75-F loo loo loo &Id 98 loo too 1W loo.37 loo 51a8:49 2s Satd loo SC++*.3 @ 320-F to48:loB5Q 100 15O.F
NR 120 NR NR 120 80 loo
NR NR
NR -
AMBI180 AMB 80 lx) loo 130 -190 130 130 NR 122 120 AMBJNWLY-f90 150 AMB NR LS 120 en AM&--I-
NR 13W9O/NR
15C:-
130 180 -
130/lWi1201-
180 NR lSo/120 NR SATlNR AMBIAMB LS AMB AMBIAMBI-
2101210/160/NFVSATINRIAMBilW -
loo 1w loo AMBI-
150 130 1w AMB AMB AM0
AMB
120 SAT
loo -
Satd 38:2.5:20 2cK3o:50 354420 4oI10:50 100 80 @a12iX120/loo NWAMB 80 -/SAT/NR 120 120 120 SATISATI10 3w/3Wi-Do SAT 160 AMB
150190
loo SAT 1SOIAMB -
loo/SAT ll3011201-
120 SATI1201120 120/120 120 SATINR SAT 120 120 120 SATINA -
120/-
pli 78
28 1 -
SAR1201120/1201SAT,-
tSeeltst01 trademarks
and Droducl names
(continued)
216
Corrosion Resistant Materials Handbook POLYESTER AND VI NY L ESTER RESINS-ASHLAND

CONCEN. TRATION % COnC 100 100 Q 75-F
100 1OOGi BO'F 100 WETROW' 92 VVP
TABLE 1.54:
(continued)
HETRON 72:1971197A AROPOL 7240.7430 SERIES l.SOf1BOilM NR NR 100' NR 15OINR 1801150 12Y100 HETROh 700~700c HETRON 920 SERIES'900
SERVICETEMPERATURE.FFORRESINTYPES
Water, GoothomlJl........................
Vegetable Oils :. : ..... Viddbn Dt Fumigant Vinegar ....... : .... Vinyl Acetate ........ Vinyl Toluene : : : : : : : 1 : : : : : : 1. .. 11 : .. : Vlnyl Trkhlortde VlvoZynet ............................. Wash Solution. pli 13.6 ................... Washer Hoods, Ducts, Chlorination, CIO,. and Brown Stock .. , ................... Waste Oils, Gear. Cutting, etc., Treated with ............... Lime and 93% H,SO. Waste, Organic, H,O, HCI, Cl, Vapors ...... Waste Water Treatment Water: Acid: Organic contambtated : : : : : : . Water, City (t&69 pal) ..................... Water, Condonaate. pH 7.342 with NH,, NO,, SO., B, Cl, 0,, H,S ............. Water, Condensate, Buffered .............. Water, Condensate, Traa Amounts Mercaptan, H,S. Turpentine, Acetone .............. Water, Condensate, Zero Hardness, pH 8.595 @ 2W.210F ................. Water. Contaminated with Aromatic Solvents, Salts, Hydrocarbon Rosins, Organics; . Slightly Acid to Basic ................... .. wltaf, Cooling, ph 5.57 .................. Water, Cooling, 26 ppm Chromate ........... Water, Cooling lower ..................... Water, DelonLuP~ s ...................... Water, Doionized, High Purity 1.5 pmhdcm. ... Water, Deminerallzedd ................... Water, DistIllad ......................... Water, Drinking ........................ Water: Ethylene Glycol rg 212OF ............
_ _
AM&NW-
NR AM0 80
AME NR NR 100 150 NR -
2101220 NW8OlNW160/220
NR
-
NR
SAT NR 175 150/150/NR 180
96 5.2 1.5 100
NW-
-I103
l&X-
NWLS/-
@15O'F 100
SATISAT'I-
loo/100 103 100 loo %x0 loo/160/NWAM&-
100 180 180' 120 180 212/212/180 210/210/180 NR
180 120 18oiXl AMB"!NR" 1801120 1601140 AMB"/12Y180114O 2cK!l% AMBI700 NR as mola~ng cpd -
l&l 120 210/220 2101220 2101220 AM&-
Water, Geyser, Condensate ................ Water, Ground, Organic(1.310 ppm) Contaminated, Untreated, pH 5.7 ......... , .......... Water, lrrtgatlon ............... ......... Water, Light, FC195T ........... Water, Light, FC203t ...................... ...................... Water.09 Separation Water. Organic: acid contaminated @ 15rYF ... Watec pH3, pH7. or pH 10 .................. Water, pH 5 to 9 (1.13 at tlmos) with HCI: Cl,, Benzok Acld; Baruoyl, Bansal, Bonql Chlorldoa Praaent ................. Water, 13,ooO ppm l atk acid ............... Water, 6.ooO ppm chlorobenzeno ............. Water, 166 ppm methylone chloride .......... Water, 3,DW ppm 15ooctyl alcohol ........... Water, 56 ppm Phenol ...................... Water, 566 ppm sodium chlorldo ............. Water Satd. with 1.525% Ozone in Oxygen ... Water, Sea ............................... Water, Sea. dorrllnatlon pH 7.5 .............. Water, Sea, deaalinatlon pH 7.5 .............. Water, Saa, dosalinatlon pti 7.5 @ 265.F ...... Water, Steam Condanutaa ................. Water, Storm Condonsate, Steam; Buried ...................... Pipe B upto2Ul.F Water. Sulfuric: Aoatlc: Methylanr Chloride: Octyl Alcohol: Sodium Chlorlde: ......................... Chlorobenzrm Water, Tap ............................... Watr Treatment, Dye Plant, pH 2-3 ........... Watn Treatment, SoHonIng end Coagulating ......................... W8tar, Vapor 5 Condarwato~ ................
110 AMB 160 120 AMB SATlSATlNR 125
125l-
AMB 120' AMB SATiNR Ah48 120 NR AMB NW-
100 100 g&5:1.5.2 -
AM&160/NWAM&-
NW-
120 150 150' 150' 150' AMB 150' 140 1%3 180 132 -/LSINR
150'
150'/120 150 150 150 1Sc4u50
150 150 150 150 153 180
210/-
1.7xNormal 2.75xNormal Normal 100
lSou50 NR 180/-
2owNR
212' NR
41 3:0.3:1.3:0.01:0.3:0.5:0.8 180 AMB/18011
15011501NR l&I 180 AMB 212
1501NR 1801150
NR 180 -
NW180
AM0
"D~ssolvea SOCUS. 1574.21#~~m'f'O, 0.25Mm; fOra PD., 7.3pPm: Cu. 0 7ppm. zn.3.4ppm; Fe. l.Bpprn:CaCo, 450ppm mex.; Chromate. hexs. 1~22ppm. 0, resrdual. 0.20.45p~". NaQ 527.702wm '@NO change m waler a! 0 1 It' lammarelgal. as m "AROPOL 7430 Set~SIac~ory.
Such es mefhylene chloride. 50 ~,wn: chlorolorm. 2; tnchloroethylene 8 tncnloroelhane. 14: alcohols. 7W. MEK 8 MIBK. 2X Benzenes. 105. Acetone. 50 Phenol. 2 etc AROPOL 7242 safrslaclory
2p30.WOga~ tank
(continued)
Synthetic
Resins and Polymers
217
TABLE 1.54:
POLYESTER
AND VII
L ESTER RESI
CONCENTRATION %
;-ASHLAND
WETRON 9C99P
SESVICE TEMPERATURE. OF FOR

HETRON 721197!197A AROWL 7240 7430 SERIES
(continued)
RESIN
TYPES HETRON 920 SERIES990
HETRON 7001700c
Water, Waste with Pine Oil, Kerosene, Methoxychlor, Melathion, Xylene, Detergents, Chlorophyll, Surface Active Agents and Other Oils Water, Waste, With Solids. Oil, Grease Water, Waste, Trickling Filters ........... .......... Water, White .......... :: Wax, Chlorinated : : : : 1. ... :. Weed Killrrs ........................... Whey ................................... .............. Whiskry ................. White Liquor (Pulp Mill) .................. ............. White Water ........ White Water, Splash 6 Spills ................ ....................... Wine Fermentation Wine Storego ............................ Winery Waete ............................ Wire Pickling Fumes ....................... Xylone .................................. Xylone @ 120-F .......................... Xylene: Adogent 381 ..................... Xylene: Camphene. Chlorinated 68% ......... Xylene Derlvatlvr: T-Amine: Alkallne Metal Salt: 10.20% Sulturlc Acid ............. Xylene: DXE; Trace li,SO.; Flake Caustic Xylene: Koroaeno: 05% Phoaphortc .......... ........................ Xylene:Toxaphene Xylene/Ultraformor Fnd ................... .................... Zlmmltet, Mud Remover Zinc Casting Fumos ....................... Zinc Chloride @ 310F ..................... Zinc Chloride ............................. Zinc Chloride Plrting Bath; Zinc Chloride: Sodium Chlortde: Ammonium Chloride, pH 4.862 ...................... Zinc Cyanlde Plating Bath, 9% Zinc rnd 4% Sodlum Cyanides 9% Sodium Hydroxide ... ............... Zinc Dimethyidlthlocarbanate Zinc Electrolytic Collr ...................... ........................ Zinc Fluoborate* ZincFluoborste Plrting Bsth, 49% Zinc Fluoborate; 5% Ammonium Chlortde; 8% Ammonium Fluoborate .............. Zinc Hydrosulfite ......................... Zinc. Nick.1 Hydrophosphstr, HF rnd Fluoslliclc ............................ Zinc Nltrste .............................. Zinc Phosphate ........................... Zinc Smelter Fumes ....................... Zinc Sulfate .............................. Zinc Sulfite ..............................
Unknown -
AKBAMBI-
en
AM8
BT,PUB AMB
80
AM0
80 AM8 AM0 lBo12W -
100 @
AM0 AM0 -
AMB 180 AMB NR NR
BOF
NR 17YAMB/AMBIAMB
Bi:1501-
ll@-
AM0
110
140
NRllOO NWloO/-
100 100
-rw
NW-
lSo/lwISATINWNR 100 122 100 NR 100 122 AbIB/--/-
9YNR NR lt<)iNR NR -
75125
10:90
5050@185 333335 10% l-2 70 Satd
NR-
l@Y2al
100 cwYxwoJSAT/SAT/265 la5150 220/200 210/-
18.31:3 oLlga, NW90 14W-
AM0 NR 140 -
180
160/210/-
3.5 50
Satd S&d Sald Unknown All Sald -JlElO 160
2w 160 80 180 200 SAT 200 --153 250 NR l&w50 15C:100
200 lXU15O 180 2201200 -
2001-
210/210/lBO/-
tSe llsl 01 lrsdcmarks
and c)roducI names
=U/7SUtfSlUClO~
HETRON 99P tar turns service on/y Good hst nsutts 8tkr short exposure YJynmelic sudecing veil mxmmended for mrximum resistance BenZoyl PeIVXid8 - Dimefhyl uniline cure system recommended t0 8Ssur8 satist8ctOty cervice *Postcure recommended Solulion mry discolor Nonthixotropic ns@ prefenbk _....
US Ill7hlg
NO change in water at 0.7 ft. laminate/gal. gal. tank. AROPOL 7530 SatiStUCtOrj. MAROPOL 7343 SUtiSfUCtOrY
as in 20-30.000
Acceptuble 8s to odor 8mi Iusfe tar AROPOL 7242 fype resin. Steumed 4 hours with rtmospherlc steam prior to exposurs Three 3 hour exposures lo 30% nrtrlc 8t 100F to simukte cleenin NO discvlorution occurs et 5 rttfgul. ucid with AROPOL 7242 md A ETRON 700 type construction M SlJ1f8soSS 810 8cid or Steum C/UUned rYY veil an/v - . _ _ .. aA ROPOL 7$40 only uAppceIs to be eroslon/comXion AROFOL 724LSATut 12Q.F HETRON 197 and 700 series resins appear to be unsuitable under cychc conditions with some crazing but are resistant under static conditions. Dissolved solids, 1574-2163 ppm: PO,, 0.25 ppm; total PO, 1.3 ppm; Cu, 0.7 ppm; Zn, 3.4 ppm; Fe, 1.8 ppm; CaCo, 450 ppm max.; Chromate, hexa, 18-22 ppm. Cl, residual, 0.20.45 ppm; NaCI, 527.702 ppm.
Vol. % SO, 0.25; SO,, 0.03; CO, 12.5; N, 74.6; O,, 4.9; H,O, 7.6; f/y esh, 5.0 grams fr; velocity 60 fps. Vol. % SO,, 0.25; SO, 0.003; CO, 72.5; NI. 74.6; 0, 4.9; H,O, 7.8; t/y 8sh. 1.2 grams fr; velocity 8 fps. 0.12% Sop% O,ll2% CO,RO% NJ13.4% H,O; 5 grams/fr of 1.2% tf,.S@, 2-3ooo ppm HCI. 1020 ppm HF, rust water. z4Such as methylene chloride, 50 ppm; chloroform, 2; trichloroethylene 8 trichloroethane, 74; alcohols. 760: MEK 8 MIBK. 200; Benzenes. 105: Acetone, 50; Phenol, 2 etc. AROPOL 7242 satistactory.
TABLE
1.55:
POLYPROPYLENE
AND POLYVINYLIDENE
FLUORIDE
LINED PIPING SYSTEMS-RESISTOFLEX
Chemical
Resistance
Ratings for RESISTOFLEX-PP
(Polypropylene)
and FLUOROFLEX-K
(KYNAR)
Acetic Aad iGlacial Acehc Acld 150%) Acetic AnhydrIde Acetone Acetone (1 O%l 150%)
70 225 75 120t 120t
70 212 1 NR 120 NR
, Er1ne I BromtcAcld ,
225 NR NR NR
275 230t 170
Chromic Chromyl Coal
Acid (31!?, w!? 0 3:, H&O.1 Chlonde
qromme~Dvl
Water (25%)
I/ Bromine(Llqu!d) Bromme 1 Butadlene 1 Bufyl Acetate
170
212t 250
Citric Acld
Gas
011 4
: 160 ! / ; 140t / i I
140 140 140 140 140 __ 120 140
170 1201 275 2121 275 275 275 275 275 275 275 275 150 150 120
Ettylene Ethylene Ethylene
Dlamlne DIchlor,oe GlycO .EDCI NR 225 NR 140 :50:,; 225 225 225 225 225 225 140 140t NR
EthyleneOxIde Fatty Acids Ferric Chloride Ferric NItrate Ferric Sulfate Ferrous Ferrous -___. Ferrous Chlorloe NItrate Sulfate 137%)
Acetonttrife Acetoohenone Acetylchlonde ACWlOnltrlle Allyf Chfortde Aluminum Albmlnum Alummum Alummum Ammonium Chlortde Fluoride Hydrowde Nitrate Potassum Sulfate Sulfate (Alum1
/ I
I
70 NR 120 100 NR 225 225 225 225 225 225 140 150 225
j
;
NR
Cocoanut
120 NR
Copper Chloride 1Copper Copper Cyanide Fluortde NItrate Sulfate -___ 7
NR NR 70t 70t 7ot
75 75 275 275 275 NR 70 70 I 275 275 275 212t 230t I 275 275 275 275
j I I
I
i 120t , 70 1 212 ;;:

275 275 275 275 NR 212t 275 275
/ Butyl Acrylate / n-B&y Alcohol 1set-Butyl Alcohol j F;f;;$A;rhol ~sec.Butylamlne

1 tert-Butylamlne Butylene T___ Butyl Bromide
I Copper
1 copper
+
275 120t 250t 275 NR NR 70 275 275
corn 011 Cottonseed CreSOl I 011
i /
70
Formaldehyde Formx Acld Fuel Oil FUrane Furfural Gall~c Acjd GasGas-
I ,
1Alummum
Aluminum
AmmontaiDryGasi i
Ammoma Aqua (30%) Ammonium Blfluorlde Ammonium Carbonate Chloride Fluorlde(25%1 Hvdroxlde Nltrate Phosphate
/ , ~ / / 1 ( , I
I /
Cresyc ACd Crotonaldehyde

-T,,
NR NR 225
Butyl Chloride Butylphenol
Butyrlc
n-Bury
j Crude 011 ~iie( Cyclohexanol

Cyclohexanone ~ Dextrln /
t / I
70 NR 150t 120t 12vt
275 275 150 70 2301 70 275 70 275 70
NR Manufactured Natural Leaoed Unleaded Sour ---I--
Aud Mercaptan Blsulfate Blsulflde Carbonate Chlorate Chloride Hydroxide Hypochforlte(PO%l Hypochlorltef94%1 Nitrate Sulfate
225 225 225 225 225 225 225
! Ammonium
1 Ammonwm Ammonium Ammomum Ammonlum
1 275 I 275
212 275
1Calaum
Calcum Calcium Calcum Calclbm Calcium Calcium Calcium Calcwm Calcium
c
I
1
GasolineGasolmeGasolineGlUCOSe
225 225 225 225
, Dfesel
Dethyl
Dlacetone Alcohol ---/-Fuels Cellosolve + Dtethylamine
I :
NR NR NR 225 225 150t
275 275 275 275 275 275 70 275 275 275 275 275 275 275 275 275 250 212 212 275 275 275 275 212 757 120t 275
1 j I I /
Glyceme Glycol ~Glycol~c Aad Heptane HeXarle Hydrlodrc ACE 48$, Aced i50% Acid 12%) Acid flO%l Acid 120X,! Acfd Cone l3E%I Acid Hydrobromlc Hydrochlonc Hydrochlonc Hydrochlonc Hydrochlonc Hydrocyamc p-e
275 275 125 275 275 120
Ammorxum Sulfate Amyl Acetate Amyl Alcohol Amyl Chloride
4
120 225 275 275 275 275 225
Dlethyl Ether cDlethyleneTrlamme Dlglycollc Dllsobutyl Acid Ketone
120
i 1 NR (
140t 120 NR 70t 225 225 225 225 70t NR Acid 70
LAnlflne
AnttmonyTr!chlonde Aqua Regla Arsenrc Acld BarNurn Carbonate Barurn Chloride
/ /
c
(Wet1 (Dry)
70t 70t 275 275 275 275 275
Capryl~c Acid Carbon Dloxlde Carbon Dloxlde Carbon Dlsulllde CarbonTetrachlorlde castor 011 CellOSOlVe Chlorine L,qwd Chlorine (5% I Ccl.1 Chlor,neWater(Saturated) Chlorine Chlorine Gas [Wet or Drvi Dloxlde (15%i Acld !50%1
:
150t 15ot NR
150 275 275 70t 275 275 275 212 212t 212t
Dtabutylene DImethyl Amne I_ Dimethyl Formamtde Dlmethyianllme DImethyl p-Dtoxane Dtstllled Water Phthalate
i I I
__)
70
701 2121 275 NR NR 70 70 NR
/ 1 J
150t NR 75 140 150 225 185 175 150
120t 225 NR NR / : I j 225 _----t_ 120t i
Barwm f-lydroxlde Banurn Sulfide Benzaldehyde Benzene BenzeneSulfomc Benzac Acid Benzyl Alcohol Benzyl Chloride Black Liquor Borax Boric Aad --
I NR / -+ -120t 70t NR NR
~ 275
NR
/
1
140t 120t 100
Eplchlorohydrm
HydrofluorlcAc,d(35$1 Hydrofluorlc Hydrofluorlc Hydrofluoslllclc Yydrogen Yydrogen Chloride Cyanide Peroxtde 130%) (Dry1 Acid (70%) Aud I1 00%) Acid
; i
125 170 120 230 275 275 275 275 275
Esters Ether
150t
NR NR NR NR NR NR
1Ez;.srtate i Ethyl ~Ethyl

Alcohol Chloride Bromide NR 275 230 230
1 1
7. 140 140t 140 70
160t
70t 225 225
Hydrogen Hydrogen +iydrogen iydrogen ,ydroge
Chloroacettc Chlorobenzene Chloroform Chlorcsulfonlc
Ethylene
Acid
NR
/ EthyleneChlonde ! EthvleneChlorohydrln
NR NR 70
PerOxIde l90$1 Phosphlde Sulftde (Dry1
70
/ I
7o
140
(continued)
TABLE 1.55:
POLYPROPYLENE
AND POLYVINYLIDENE
FLUORIDE
LINED PIPING SYSTEMS-RESISTOFLEX

(OF
POW Chembc,l -
(continued)
,
Ck.ld
SE IRE
T
PVDF
PVDF
&y
D~0Pl-A
Ch.mul
It.,
Hydrogen
SulftdelWetl Acid NR 70t
275 275 150t 170 1 Sot 212t
Monochlorobenzene Morpholme Naphtha Naphthalene Nickel Nickel Nickel Chloride Nitrate Sulfate 70 225 225 225 225
Hywchlorous lodlne(Dryi IodmeiLiqutd) lodme (Wet; lodoform
150 NR 275 212 275 275 275 70 250t m 150 100 (70%~ 190%) 70 NR _NA_ 50 NR 120 70 140 NR NR 70 170 130 120 120 NR 120 70 170 120t 212t 275 275 250t NR 120 275 230 275 275 / i
Potaswm Potassium Potassium Potaswm Potasswm Potaswm Potaswm Potaswm Potaswm Potaswm Potassium
Chlorate Chlorlae Cyamde Dlchromate Ferrocyanlde Hydroxide Nttrate Permanganate Permanganate Sulfate Sulfide :20%1
225 225 225 225 225 225 225 140 225 225
275 275 275 275 275 212t 275 250 250 275 275 275 120 NR NR 120t
Sour Crude 011 Stanmc Chloride Stannous Stoddard Sulfur Sulfur Chloride Sulfur Sulfur Dxhlonde Dloxlde Chloride s Solvent Stearlc Acid
275 225 225 120t 275 275 275 250t 140 NR 250t 70t 70t 170 NR 225 225 200 175 150 140 125 70 IOleum) NR t50t 250 230 230 230 170 150 130 120 NR 212t 275 230t 250t 275 NR
Jet Fuel - JP4and Kerosene Ketones
JP5
NR NR 70
212 275 NR 125t 125
NlCOtlne
Lactvz Acid
Laur~c Ac!d
Nlcotlmc Acid
N~trlcAcld(Z%) NltrlcAcld(lO%) Nltrlc Acid !30%1 NltrlcAcld150%1 Nltrlc Acid - Cone Nltnc Acid NltrlcAc!d Nltrobenzene Nitrogen Dloxlde Actd N~tromethane Fummg
120%)
140
Sulfur Trloxide
Sulfuric Sulfuric Sulfuric Sulfuric Acid (5%) Acid (10%) Acid (30%) Acid (50%~ !60%1 i76%1
Lactx Acid ,60%1 Lard 011 Lauryl Chloride
70
275 230t 250t 275 250t 250t 275 275 275 275 275 275 275 250t 250t 275 250t 250t 250t
150
225 NR 140 011 Carbonate Chloride Hydroxide NItrate Sulfate 70 225 225 225 225 225 140 NR n-Butyl
Propane Propyl Alcohol Propylene Pyndlne Pyrogallol Refrlgewlts Sahcyl~c Ac!d Sea wzter Oxide
c Lead
Acetate
Sulfuric Acid
Sulfuric Sulfuric Sulfunc Sulfunc Sulfurous Tall 011 Tann~c Acld Tartar~c Acjd Tetraethyl
Lemon 011 L~noletc Acid Linseed 011 Lubncatmg Magnewm Magnesium Magnesium Magnewm Magnesium Malelc Acid Maltc Acld Mercaptan Mercuric Mercunc
I-
-Sulfuric
Acid 50
Acld (93%; Acid 196%) Acid (96%) Acld - Fuming Acid
11 12 8 22 120 225 225 225 225 225 225 225 225 225 225 225 225 225 225 225 225 150 150 225 225 225 225 225 225 225 225 150t
212t 120 212 275 275 275 275 275 275 275 275 275 275 275 275 275 275 120 NR 212 275 275 275 275 275 275 275 275 275
Sallcyl-aidehyde
;i NItros / i
Octane
Silver Cyamde
Sliver NItrate Sodturn Acetate Sodium Benzoate Bicarbonate Blsulfate Blsulflte Bromide Carbonate Chlorate Chloride Fluoride HydroxtdellO%l Hydroxide (50 x I*+ I1 7%1 Sodturn Sodwm Sodwm Sodium Sodwm Sodium -Sodium Sodturn S&urn Sodwm
Octane Olelc Acid Oleum Fuming Sulfuric Acldi NR 70 225 NR 225 NR _ 70t 70t 150 140 1 NR 225 ! ; 225 140 75t
Lead 150X, NR Phosphate Acid i tOh1 Acid NR NR 150t NR (50-501 225 NR NR 225 NR 140
Oxalic Acld Oxygen Ozone Paimltic Acid Perchlorethylene Perchlorlc Perchlorvz Phenol,lO%l Phenol llOO$, Phenylhydrazme Phosgene Phosphoric Phosphoric Phosphoric Phosphorus Phosphorus Phosphorus PentoxIde Trlchlorlde IGas 8 LIquIdI Acid 130%) Actd (52%) And 165%) Ac,d (lO%l Acld(72%) Gas
Telrahydrofuran Terramethyl Hydroxide TOlUerla Tnbutyl Trlchloroacetlc Trlchloroacetlc Tr~chloroethylene Trlethylamlne Trtsodlum Turpentine UDMH-Hydrazlne urea (50%) VarSOl Vmyl Acetate water White Acid (Ammonium Dtfluonde xytene Zinc Chloride Zmc NItrate zmc Sulfate 8 HCI; NR 225 225 225 Phosphate Ammonium
Chloride Chloride
(40%1
140 225 150t 225 70t (50%) 140 NR 75t NR 70 120 70 NR 225 70 __ ._
212t 170 70 75t 75 275 120 275 275 70 250t 250t 250t 275
Mercur~cCyan~de Mercuric Mercury Methane MethaneSulphonlcAc!d Nttrate
275 275 275 i12t 275 275 275 150 tzot NR 120 NR 70 212t
Sodturn Cyamde
Methyl Methyl Methyl
Alcohol Bromjde Cellosolve
275 250 230 212t
Sodaurn Hypochlorlte Sodium Sodium Sod!m Sodwm Sodium Sodium Sodwm Sodwm Sodium Sodium NItrate NItrIte Peroxlde Phosphate Sltlcate Sulfate Sulfide Sulfite Thlosulfate
Hypochlorlte(ZO%Y
Methyl Chlonde Methyl Chloroform Methyl Methyl Ethyl Ketone Sulfuric Acid Ketone
i-
-I--I
I i
212t 212 70t 275 275
Methylene Milk Mineral
Chloride
Methyl-isobutyl 011
jl
Phthallc AcldiOrthol PICNICAcid Polyvnyl potaswm Potawum Acetate Bromide Carbonate for se at htgher
I j I I
70t 140 75 225 225
250t 212t 275 275 275
Monoethanolamme t Maximum temperature
275 NR -
at publication in anhydrousconditlon I processes where
consult
275
factory
temperature? type reactlow
-_
___~ *** Polypropylene from NR Not the IS not recommended of sodium severely where tree chlorine IS present as a residual reactant
* Not ** Not
recommended recommended
as m Frledel-Craftsand mercury amalgam 1s formed
alkylatlon
formatnon
hypochlorlte
or from
deCOmDOSltlon
recommended
affected
220
TABLE
1.56:
ACETAL,
NYLON
AND
POLYESTER
RESINS-DU
PONT
DELRIN Resists weak Resists weak
Acetal
Resins in strong for strong ethers, acids. alkalies. oil, greases,
Acid
Resistance
acids (pH 4). Not recommended bases (pH 9). Not recommended
Basic Resistance Solvent Resistance
Excellent resistance to a wide variety of solvents, gasoline and other petroleum hydrocarbons.
ZYTEL Acid Resistance
Nylon
Resins
Base Resistance Solvent Resistance
Limited. Attacked by strong acids. General order of resistance 612>66> copolymers or 6. Excellent at room temperature. Attacked by strong bases at elevated temperatures. Generally excellent. Some absorption by such polar solvents as water, alcohols, and certain halogenated hydrocarbons causing plasticization and dimension changes.
RYNITE Acid Resistance
Polyester
Resin
Base Resistance Solvent Resistance
Good at room temperature. Attacked by strong and weak acids at elevated temperatures. Good at room temperature. Attacked by strong and weak bases at elevated temperatures. Excellent resistance to a wide variety of fluids such as gasoline, motor oil, transmission fluid, hydrocarbons and organic solvents. Some absorption by ketones and esters causes plasticization and small dimensional changes.
Synthetic Resins and Polymers TABLE 1.57: EPOXY, FLUOROPOLYMER AND POLYETHYLENE RESINS-DURIRON
221
DURCO Durco Designation DURCON DURCON

Olrrrn --.__ TFF
NON-METALLICS
Max. Service Temperature eooxv 215O 225O 400 400 F (102O C) F (1070 C) F (204O C) F (2040 C) F (93O C)
Durco Symbol DU6 D700

TFF
Description Silica filled epoxy Glass fiber reinforced

T~trnfltlnrnPthylene .
__._..I_.__...
6 700
polymer
Durco PFA Durcothene
PFA UMPE
1 1
1
I
*Most Durco equipment totally lined with TFE
Perfluoroalkox y polymer Ultra high molt ecular weight polyethylene

F (149OCI.
200
is limited to 300
__rr_.
. .
.._._
ynn-r
silver nitrate
IG&E Ic Is
IE
Ferrous sulfate
Formaldehyde
E
G
S
G
E E E E E
Formic acid Glvocrin. crude
E
E G E E
G E E E
s E E E
HCL waste pickle liquor cid>15~F65Ct
Hvdrochloricacidc150F&50CI Hvdrochloric
_.. ___.___ jW
/Lactic acid Lead acetate
r-1
IG IP
1G 1; IG 1;
Ii
IE IE
1:
IE JE
(continued)
222
TABLE 1.57:
EPOXY,
FLUOROPOLYMER
AND POLYETHYLENE
RESINS-DURIRON
(continued)
Sodium
bisulfate
E-1
E-1
_Mangawse chloride Mercur,c chloride Mercuric nrtrate Mercuric sulfate
E E G E 7-E
E E G EiE IE7ElF
E/E E E
E E E 1
I Mercuvcus sulfate
Nftric acid. all strengths Nitric acrd + 3%. Nitrobenzene Oleic acid Oleum Oxalic acid Phenol Phosphoric acid 1 +2%H,SOd.l%HF _ . c Phosphoric acid, all strengths Picric acid Phthalic acid Potassium bisulfate Potassium chloride Potassium hvdroxide 5% HF
G P S IP (P
SE P (E E E
SI G P 1P G P
jG(GjEjG IGIGIE iElPiE
I
G
I
S
I
E E E E E G E E E E E E I Tar and ammonia TSlSrEl El
tSlPlEtE1
GGE GGEE E E S
E = Excellent - Virtually unattacked under all conditions. G = Good - Generally S = Satisfactory - Suitable under Some conditions: not recommended for remainder. for details. P = Poor - Unsuitable under ah conditions.
acceptable with a few limitations. Consult The Duriron Company,Inc,
Synthetic Resins and Polymers TABLE 1.58: ISOPOLYESTER, RESINS-AMOCO

Comparison
223
HALOGENATED CHEMICALS
AND BISPHENOL
A POLYESTERS,
AND VINYL
ESTER
of commercial
corrosion
resistant
resins
after
one year
immersion
The lengths of the bars reflect the tested performance of the resins after one year in the indicated environments. The Composite Ratings are the ten year performances projected from the 1, 3, 6 and 12 month evaluations. All laminates were made according to ASTM Method C581 with a glass fiber content of 25f2%. To assure high quality, the ATLAC-based laminates were supplied by ICI United States. The other laminates were fabricated in the laboratory.
Flexural
psi 0
Strength
1 cl.000
Flexural
I
80
Modulus
600.000 I 4000
I I
MPa 0
I
20
5.000 I
I
60
15.000 I I
100
I
120
20.000 I I
140
I
160
25.000 I
3
3
40
200,000 400.000 I I I I I 1000 2000 3000
5000
800.000 1
6000
l.Ooo.oKJ I 7000
8000
224
TABLE
1.58:
ISOPOLYESTER, RESINS-AMOCO
HALOGENATED AND BISPHENOL CHEMICALS (continued)
A POLYESTERS,
AND VINYL
ESTER
Barcol Hardness
0 I 10 I 20 I 30 I 40 I 50 I 60 I
Composite Ratings
H,O at 71C 5% HNO,at 71C 5% HCI at 71 C 25% H,SO. at 71C X2 Fuel Oil at 23C Ethyl Gasoline at 23C Unleaded Regular at 23C Benzene at 23C/time to failure
excellent good good good excellent excellent excellent 1 year
H,O at 71 C 5% HNO, at 71 C 5% HCI at 71C 25% H,SO. at 71 C X2 Fuel Oil at 23C Ethyl Gasoline at 23C Unleaded Regular at 23C Benzeneat 23C/time to failure
good excellent good good excellent excellent excellent 3 months
HI0 at 71C 5% HNO,at 71C 5% HCI at 71C 25% H,SO, at 71 C #2 Fuel Oil at 23C Ethyl Gasoline at 23C Unleaded Regular at 23C Benzene at 23C/time to failure
good acceptable excellent excellent excellent excellent good 6 months
H,O at 71 C 5% HNO,at 71C 5% HCI at 71 C 25% H,SO, at 71 C X2 Fuel Oil at 23C Ethyl Gasoline at 23C Unleaded Regular at 23C Benzene at 23C/time to failure
good excellent good excellent excellent failure acceptable 1 month
H,O at 71C 5% HNO, at 71 C 5% HCI at 71C 25% H,SO, at 71 C X2 Fuel Oil at 23C Ethyl Gasoline at 23C Unleaded Regular at 23C Benzene at 23C/time to failure
acceptable good acceptable good excellent excellent good 6 months
1. ICI United States
2. Dow Chemical Company
3. Hooker Chemical Corporation
TABLE 1.59:
POLYSTYRENE,
SAN AND ABS PLASTICS-MONSANTO
The data shows results under Test Procedure ASTM D.543, h&tante of Plastics to Chemical Reagents. This method requires molded two-inch diameter disc specimens to be placed in a separate container and totally immersed for 168 hours (seven days) at 73.2F. Appearance, weight and dimensional changes are noted as evidence of chemical attack. To obtain information on chemical resistance at elevated temperatures, these immersion studies were repeated at 50C (122F) and the results are set forth under the column Heat Reduces Resistance.
The rating of certain reagents is followed by the designation ( t ). This designation indicates that the reagent was applied to a bar specimen which was then placed in a bending jig and held under constant 29& outer fiber strain at 23C (73F) for 72 hours.
TEST CLASSIFICATIONS 73 - Resistant. No visual change
MR X ModeratelV Not ReSiStSnt. Resistant Some WRS observed visual in the plastic for 1 duratoon of the test. (discoloration. crazmg. checking) occurred. by the end of the test.
change
The plastic was severely crazed. or was softened.
or was d6solved
Chemical Resistance of Lustrex and Lustran Plastics

~LUSTREX POLVSVYRENE~ LUSTRAN SAN lLUSTRAN ABS LlJSTREX*POLVSTVRENE 73-F Acids Acetic l-5% Acetic 25% Acetic 50% Acetic Glacial 100% Benroic Boric ButYric Carbolic 50% Carbolic 100% R MR MR x R R MR x A Yes Yes Yes Yes Yes Yes Yes R R R x R R x x R NO NO Yes NO NO No j R R R X R A X H#st Reduces Resistance LUSTRANa 73-F SAN LUSTRAN 73-F ASS tImat Redwas Rnistanw
!
!
X R
Chromic 20% Chromic Sulfwc Acid Mixture
Alcohols Ally1 n-AmVl Benzovl Benzyl Butoxyethanol n-Butyl SK-BUWI Ten.-Butyl MR R x R IR IR MR MR Yes
YSS
x R R A MR R IR R x IR -
Yes Yes Yes NO No Yes -iXI Yes -
X R X R R -
Yes Yes Yes Y%S Yes
Cetvl Cyclohaxanol Oecyl Diacetone
R R -
Octanoic Oleic 1 DO% Oxalic 10% Palmitic
MR R MR
Yes Yes NO
R R R
Yes NO NO
R R -
I 2.Ethoxvethanol Ethyl (denatured) Ethyl Formula 30 Ethvl 95%
X -
(continued)
TABLE 1.59:
POLYSTYRENE,
(continued)
Methylamyl Nonyl WOCtYl
R R R
Yes NO NO
R R
NO
Dlmethylformamade Dlphenylawne nl~thlrnrtrlmlne Dlephenylemmine (Carbazole) Ethylenedaamme lsopropylamlne Pel-WlFlm,ne Twhopropanolamme Trlethylenetetramme Cosmetics LallOlln Alkalies Ammonia Ammonia (cont.) (aqueous) Hydroxide R YeS R NO R R Yes R R Perfume Alcohol 5DA40
1 x
1 x Yea _ I MR MR _ -
Ix
IX I -
R -
NO No -
X X
/ 1
R -
1 /
1 MR 1
R MR X
Yes _
R -
No -
Cyclopsraffins Cyclohexane Methylcyclohexane R R No R -
(continued)
TABLE 1.59:
POLYSTYRENE,
(continued)
LUSTREXPOLVSlYRENE Group 73.F Peooer

_r
LUSTRAN 73-F Rt
SAN
LUSTRAN
ABS
nut Rsducaa Rssinsnsr
nut Rsdacss Flaaistsnu NO NO NO NO -
n-r
R R -
Foods
L
Black Butter Carrot
(fresh)
,
X R NO Yes Yes .__ R R _
R R R Pt
Juice
Catsup C*la#., C*l* Che...__ Chicken Glycol Dibutyl Mono&hyl Phthalate Ether) 1 x _ Ix jx X X Chicken Cinnamon, \~______I Graw SVYr pwd. fconc.l ,uv,vu.,
1
I-
Yes
I Ix
R R R
NO No
I -I
R R -
Clove 011 Coca-Cola Coca-Cola Cocoa Coconut Cod Liver Oil Oil Extract Butter
_ _.. _.
R R MR MR Yes Yes NO Yss Yes
1 MR
Ethyl Ethyl Ethyl Ethyl lsoamyl
Benzoate Chloroacetate Lactate Salicylate Acetate Acetate Acetate Benzoate Laurate (Bourbon) Oil Fat Gravy (Over I,*irm 3.2% alcohol)
x _ X x x MR R R -
_ _ Yes -
x x -
_ -
X X X X X ii R R R Crirco Fountam Chew, Syrups Chocolate, /hIA R R R MR Ale Ale Juice Extract Juice R R MA Yes Yes YeS NO NO -
Isopropyl Methyl Methyl Methyl Foods Alcohol Almond Bacon Beef Beer m-0,
1 I
R R R R Rt R R R
No -
1 I
I
R R R -
Orsnee, Root Bear, StraWbarrY, Vanilla Garlic Gin Ginger Ginger Grape Salt
R Fl R Rt R
NO NO -
Grapefruit
(continued)
TABLE 1.59:
POLYSTYRENE,
(continued)
(Curtis) Lard Lean Beef Lemon Emulsion Flavoring 1 IMR Ix
A R MR X
Yes NO -
R -
NO No -
R -
Lemon Juice, Fresh Lemon Oil and Peel
1
Ix
1 I
Leaves, Caraway Seed. Celery Seed. Cinnamon Coriander (Stick), (Whole).
Cumin Seed, Dill Seed, Fennel Seed (Whole), Marjoram. Mustard
[ Parsley Flakes
IRt
Synthetic Resins and Polymers 229
0
4
ZtL,
s ::
I I
ILrclElLLILl
UC=
I ==
t; 3
I
I
IIIlIIIIIIIII nflslll zol I
I I I zP
TABLE 1.59:
POLYSTYRENE,
(continued)
LllSYREX* , SMP Hydrocarbons. Chlok Ethanol 73-F
WLYSYYRENE nm nducm Raistanu -
LUSTRAN 73F x x x x -
SAN
LUSTRAN 73-F
ASS
Ihat Reduces tksistanu
Halogensted
x X X X X X X X
Chloroform a-Chloronaphthalene Chloropropane o-Dichlorobenzene P-Dichlorobenrene Dethylene Chloride (gas &
Ethyl Chlonde
Acetophenetldm Adrenalin Adrenalin Aspwn, Hydrochlonde m 011 pwd.
R R R R
NO Yes NO NO
Trichlorobenzene Trichloroethane Ttichloroeth,ylene Tnchloropropene Katonas Acetone Acetophenone 8 Ethers
x x -
x x -
X X Gum Acacia, pwd. R R U.S.P.) YES Yes ij -
Gum Tragacanth Iodine Iodine 83% (T~ncfure
1 IX _ -
X _
x x
x x
X X
Mentholatum Menthol Crystals
I
/x
(continued)
TABLE 1.59:
POLYSTYRENE,
(continued)
LUSTREX GWlp Pharmaceuticals Mercurochrome Mercury Merthiolate, Novocain Omtment. Ml? tincture (2% and 4%) MR R R R R MR R R Ammomated MR 13-F
POLYSTYRENE Flea1 Reduces Resistance
LUSTRAN 73-F
SAN
LUSTRAN 73-F
ASS
!LUSTREX
POLYSTYRENE, Haat Raducos Resistance _ NO NO Vnr Yes .1_ I -
LUSTRAN
SAN
LUSTRAN 73-F -
ABS
Hut Reduc@s Resistance
CKIUP
Salts
I
73F
1 : 73F
I
Heat Reduces,
Resistance NO
Yes NO Yes NO Yes NO Yes
R R
R -
Cadmium Calcwm Calcium Calc,,.Calcium Calcium Calcwm Ceslu -
Stearate Elromlde Chloride Y ..^^_ &.,^.,A^ nypocnlc ,rite Oxide Sulfate 25% Sol me. pwd
/ R R L0 R n n -
1 I ,1
1
R NO _ No R
I , 1
_
R R R R
, i 1
iR ,R R R I
Pectin, sat. Penicillm Petroleum P*trolaum G Jelly
0 n
R
&I^ I.
-
__ Jell I, _ ,bolated car n..;uullline rrra-hnin. .,.,...... S,df.dia.inP __ ___-. a,,, n .^._ _..* 1IIIIIITIII
C..I..-
Yes N .._ Yes

Nn
1 MR ..aq
I -
1 I /
.I
8 No
..
R -
Copper Copper Cupric Cupnc Cuprous Dlphenyl
xloe Sulphate Chloride Sulfate Oxide Oxide e..,... 25% 25%
n MR _ R X X D.
I.
_ No
I?
R R R
No V..*
1 I ;
R 1 -
Ethylene Oxide Ferric Amm__...Femc - Ferrous ~n,or,qe. Ferrous Sulfate Ferrous Sulfite Hydrogen Ammonium Salt. Sulfide sat.
sag. 25% n MR x R
MH ..n.
I0
NO Y8S
-
R R R -
,es NO Ye5
L,.
,
A
R R
Hydroqulnone.
Hydroqumone. Lead Acetate

LrdU -r>er1015
4%. sat
/_
__A A.____._
Bromide Carbonate Chloride
lllll
L.D..
R R R R
I0
-
j-
Lead NItrate Magneswm Magneswm Mercury 5% ov,d
Yes NO NO Yes Yes
I j
,_
1
1
R R
No No
IR
MR
No
I 1 I
_ -
(continued)
TABLE
1.59:
POLYSTYRENE,
(continued)
LUSTREX*POLYSlYRENE Group Salts Potasswm Sulfate. Potaswm Potasswm Potassum Potassium Potassium Potassium Potawum Potassium Potassium .zilt Aluminum sat. Bxarbonate Bwlfate, Bromate Bromide 3% Chloride Chrome Alum. Ferricyamde Iodide. sat Permanganate. MR NO sat. R MR R MR R R R Yes NO NO Yes Yes Yes 73.F Haat Rldua Resist*nu
LUSTRAN* 73-F
SAN
LUSTRAN 73F
ASS
Ifeat Reducn Rasistanu
R R R R R R
No NO NO _ NO NO Yl?S
R R _ R
Sodwm
NItrate
(continued)
TABLE 1.59:
POLYSTYRENE,
(continued)
LUSTREXPOLVSNRENE GKIUP Miscellaneous Benzomtnle Benzyl Benzoate 73f Heat Rduca Resirtuw.9
LUSTRAN 73F -
SAN
LUSTRAN 73F X X
ABS
LUSTREXaPOLVSNRENE Group Miscellaneous P-Cymene DDT Decahydronaphthalene Detergents Detergent Der0rn Diethyl Carbonate Joy (5%) x Rt _ Yes NO No NO Yes Ix I73-F HIat R#duces Rnistancs
LUSTRAN 73-F R R Ri R Y R -
SAN
LUSTBAN 73-F X Fit R
ABS
Heat RDducDs Rnistrncs -
Heat Roducm Resistmu Yes NO NO No -
1MR
R Flutd 4 R R x MnO. R 3%. sat. MR MR IX
X X X X Y R X -
NN-Diethyl-M-Toluidine DimethVl Sulfate N,N-D~methylaniline n,nrilnn Distalled Water Dow Corning Dowtherm A D~v Cell Solution and N&Cl Elan (Photoa.) Ethylcellulose N-Ethvlaniline Eugenol Flit, insecticide Freon II Dow Cornmg Fluid 200
1MR
1 -
Colloidal Sulfur Cottonseed Oil Cresolic Compounds
MR Ml7 MR
Yes -
R R -
NO NO -
R R X
(continued)
TABLE 1.59:
POLYSTYRENE,
(continued)
L
I
TVdOl Motor Mr. Oil-Sunoco
USTRAN
AB!
73'F
MR
NO
clean ..-.-_____
R R
IIFI
-
X X X R X R -
Nepnthslsne Base Gear O+Telachron lsobutyronitrile Ivory Soap Lactose, sat. Lestoil R Yes R R I X I Nitroglycerin Nitromethene m-Nitrotoluene Nitrous Oxide Nqol Oil of Anise Seed Clove Lilac (Aflificlal) Nutmeg Peppermmt Roses Rose Geranium. Sandalwooc Sassafras. Spearmint. Sweet
Ix
R R X
Yes I
Mesityl Metalltc Metalltc
Oxide Mercury Sodium (powder)
MR R -
X -
Almond, Oil-Light
Wrntergreen Machme
dl-Methionine
X WR R WR WR R 4R R HR _ HR
x x x x x x x
- I1 - - 1
iR -
/x
X
~1
1
-
/I-
Olive 011
Ozone (abs of light)
No _ No Yes NO Yes Yes NO
IR R R x -
No NO No -
Palm Oil Paraff I
Paraffl 011 Para 011 Pentasol Phenol 5% Morpholine Moth Flakes Yes IX -
X X -
Phenylacetomtrlte Phosohorous. White
1 MR
(continued)
TABLE 1.59:
POLYSTYRENE,
(continued)
LUSTREX Group Miscellaneous Pine Needle Oil Ix x 73F
POLVSTVRENE flea1 R&ms Resistmn IX
LUSTRAN 73-F x
SAN
LUSTRAN 73-F -
AES
Heat Reduces Rmsistanu -
Impact materials less resistant. Impact materials not tested. tTested under 2% constant strain. ttComposition
may vary, each formulation should be checked individually.
(White Sulfur Tenite
Spirits) (Moist)
x R R x x x x IR
Yes NO
R x x R -
NO No
R X -
Sucrose 30%
Dioxide Tetrehydrofuran Tetralin Texaco 3-In-One Thmyl Tobacco Motor Oil Chloride Tars Oil
Triethanolamine
ii
236 TABLE
corrosion Resistant Materials Handbook 1.60: POLYVINYL CHLORIDE, POLYPROPYLENE KEY

to
the
AND POLYETHYLENE
FABRICATIONS-ATLAS
c
H
80F.
p
R
C
RECOMMENDED CONDITIONAL may be suit_ able but ConsuIt Atlas before w3ng. NOT RECOMMENDED
temperature t~mta-
,,on 01 the material I cases where chern~~al bolls belowth,s IimItatIon. resistance 15 Intended to beshownuptothebolltng pomt
RIGID PLASTIC
FABRICATIONS
CHCHCHCH Acetaldehyde Acettc Acehc Alum Alumrnum Alummum Alumrnum Ammonrum Ammonrum Ammonium Ammonrum Amy1 Acetate Amy1 Alcohol Anrline Aqua Regra Barrum Chlorrde Barlum Barrum Hydroxrde Nrtrate Chlorfde Nrtrate Sulfate Chlonde Hydroxrde Nitrate Sulfate acrd. up to 10% acrd. glacral N R R R R R R R R R R N R N R R R R R N sulfonrc acrd R R N -A R R N i R;R C N N NtN N N R R N R N R N R N N C C acrd. 10% R N;N R ,R N R R.R R H RR R R A N:N R N R N R R R R R A R NC CiR N R,R R:R RR RR R R R R.R N~tN RI-R---N R + R R R A N,C RR N R Chlorrne Chlorrne gas, wet water acid
CHCHCHCH N R R N N acrd. up to 5% ~acrd. 10% actd. 20% acrd, 50% and over R R R R R R R R actd C N N _ NlN R C N N A R RR C RR R,R R RR N./C N N R N R A N N R R NON R.N C C N N.C R R.R R N RR R R R-R NN NNNNNN N N C NC N R R R N R C N;N N1.N N/C N-:C N[C NR NR N;R N +_f4 RR R:R RjR RiR N N N N N N N C N N N R R R R N
c -. . R i R R:R R R;R R RIR R:R R N C R R R R R R C R R R R N A R N C
Chloroacetic Chlorobenzene Chloroform Chromic Chromrc Chromic Chromrc
Crtrrc acid Copper Copper Copper Chlonde Nnrate Sulfates
R,R.N
Drchloroacehc Drch!orobenzene
RCNNNNN R R.R RIR C!R N R I~ N R R R:-R R-R R,R CR N R C N -. R,R RR R R N.C N N R A R R R R N N
Drethyl
ether
Ethyl Acetate Ethyl Alcohol Ethyl Sulfate Ethylene Ethylene Fluosiltcic Chloride Glycol acrd
N.pmmt N:N R N R C N: R
.R N R
N!N _ .___..~__.N -N:ti m-i
_. ~~~_ ~_~__~~R-.__R c-5
R.I__RJ I Rmc
C N R C N R N:C N. N N N
Barrum Sulfide Benzene Benzene Benzorc
R;R_R
Bone acid Bromrne Butyl Butyl Butync water
Formaldehyde Formic Gasoline Glycerine -~. --~ Gold Cyanide Hexane Hydrobromic Hydrochlonc Hydrocyanrc Hydrofluonc Hydrofluosrlicic Hydrogen Hydrogen Hydrogen acrd
Acetate Alcohol acrd Chlonde Nrtrate Sulfate Bwlfite Chlorrde Hydroxtde Nrtrate Drsulfide Tetrachlorrde
i N,N
R R R ~_ _.~. R..~ __. ~.. R_ ~R __.i R _ .R R R R R R C .R~ C R ._~ R _N? R-- R, ~~ R N G
~~ .~p-_~-_j ~~_. ___.._.

R;R ~_~. CIR C;R _~__~_-____-_ R .j ~__ R/R --it__.. R R/R +
R R ~~_.. - ~_._.._._- .-
R!R C;R
C _~ C R C
N,C
Cadmrum Cadmrum Cadmtum Calcrum Calcrum Calcium Calcrum Carbon Carbon
R -.._ .T .___~_.___ RsR RIR RIR __ 7m-m CR ~_ _____~~~ R - C.?.. N -_*- NI R /_.__... R acid, 20% acid acrd. 10% acid, 3040% acid 50% _. gas, dry R ._ A - R;R .._--. R R R __c R -_i_-__~~ RIR RIR C;R ~__---t---~ R;R RiR _._ R ~. .-R,R R R __---_-i_~-_i_---_- R:R R ~.
R R
RIR I-_-
R/R R/R -mIm__t__-__
R C R
Peroxide, Sulfide Sulfide
gas, wet
Iron Chlorides Chlorrne gas, dry Iron Nitrates
(continued)
Synthetic Resins and Polymers TABLE 1.60: POLYVINYL CHLORIDE, POLYPROPYLENE AND POLYETHYLENE FABRICATIONS-
237
CHCHCHCH
Iron
~Potassium Nitrate
CHCHCHCH _____-
- --
Sulfates
Isopropyl Ether ..__ N NLC_._N~LC_~mNPotassium Sulfate N + __ Kerosene _ R RR N:C N .._ ___.___ ~ ~_~~~_~~ mm_ ~~_ RC ----+--_. i.Lactrc acid, 25% R R; R/R R _~ ~~______--_c -R A-_iRIR ._._~~. Salrcylrc acrd Lead Acetate R R;R R,R RR R Lead Nrtrate Lrnseed Oil Magnesium Magnesium Magnesrum Magnesium Maleic acid Mercurrc Methyl Methvl Methyl Acetate Chloride Hydroxide .~~ Nrtrate Sultate R R R R R,R RR R R: R RiR ~~~~- 1. ~-R!R CCR RR R,R ~.~~ -__ R R R R C R _._ R Silver Nitrate Sodium Acetate
~~~~~-R N
RRR R R R R __.. ~~ ~_~_F~~!?! RIR ~~ R/R RR Rj_R__R
R ~
R;R R?R -_R/R RR R ,R .._
R .~~~_~ !R RIR R R !R
: R R
Sodrum Brcarbonate Carbonate Chlonde
__~~~~
..-
R R ~~._ R R RiR R
RRRRRR ...~~~~~~.__ R RRRRRR
~~.__~~Sodium
Sodium
1 RRI~R~_.RJ.
Acetate Alcohol Ethyl Ketone
R RR ~~ _~.__+_-R CR ~_r 1J--F, R - .~_+._ RIR R R R ~~_-___ RR N N/N NiN N;N N R R/R RR RIR R
Sodlum Sodium Sodium Sodium Sodium Sodium Sodium Sodtum Soya Oil
Hydroxide, Hypochlortte, Hypochlorrte. Nitrate Sulfate Sulftde Sulfite Thiosulfate
30% and over up to 3% 15% and over R R RIR RR R/R R
Nickel
Nitrate
R R R R
R/R R R
R/R RIR
Nickel _ _._._. Sulfate Nirtic acid, up to 5% Nitrtc acid, 20% Nrtric actd. 40% N!ric acid, 50% and~~~ over ~ Nrtrobenzene Oleic actd Oxalic acid acid. 10%
R R
R R
R R
Steanc
acid
Sulfur gas, ____.-. Dioxide __ ~__dry Sulfur Droxide gas, wet Sulfur Trioxide gas, dry
_~-------L--__--T~~~~~_
R R N:R _~_~_~ i CC ~,__ T ..~ N C mm-++ ~~~.. ~~ _ N : N N N NIC N ~~~~~~~~~~~._ N NN NIC NIC N R R:R
~+
R&_RRCR
C Sulfuric acid, over 93% N N/N N C N N N
Perchloric Phenol Phosphonc Phosphorous Phosohorous Phthalrc
acrd actd Trtchlonde Tin Sulfate Toluene Brcarbonate Carbonate Chloride Cyanide _~. ___.~ FerncyanIde Ferrocyanide Hydroxide. Hydroxide, UP to 30% 30% and over R -..R R;R R!R R/R R ~__-_~,~~______~~~~~~_ ~~ ids ~~~ R RIR ___~_, IR _-._ RJR -...-._ R R A_ , R RR ___ R -; _ R $_ R_i .R-_ Trrchloroethylene Trrsodtum Tung 011 Urea Phosphate
actd
Picrrc acrd Potasstum Potasswm Potassrum Potassium Potassrum Potasstum Potassium Potassium
f?
238
Corrosion Resistant tWaterials Handbook VINYL,

C
TABLE 1.61:
Legend: X = Satisfactory
SILICONE
=
AND FLUOROELASTOMER MASTERFLEX

testing
TUBING-BARNANT Tables
V = VITON (fluoroelastomer) tubing
(vinyl) tubing tubing
Tubing Compatibility
T
S
Use only after
= TYGON
= Silicone
N = Not satisfactory I
Fluld to be
1
= No data available
pumped+
N N X C N C N N N N N X X X X X X X X X X X N N N X X X X acid actd X X X X X X X
blng
v
x
X X N N
IFluldto be pumper
Aolybdenum dtsulftde
ArrI<~ldehyde /wetdIes IlOW mol WtI ?CCIIC acid [less Ihan 5%l Acellc ;1Cld (more than 5bl AcetIc nrlhydrlae Acrl0 ItrIle .itrtone Aceryl bromide .Aceryl chlorrae All
UWVJIS
Cresol :yClOhexane >clohexanone 3acetone alcohol 3methyl lormamrde Essentral 011s Ethers Ethyl acetate Ethyl alcohol (Ethanol) Ethyl bromtde Ethyl chloride Ethylarnme Ethylene Ethylene Ethylene Ethylene chlorohydrln dlchlonde glycol oxrae
x
N N N --
.4onoerhanolarnme daphtha datural gas Jrckel salts dltrtc acrd (drluted) rlrtric sod [med cone) \11trrc dcrd Iconc) Qtrobenzene Jltrogen oxides Qtrous acid 311s. animal 311s. mmeral 31s. vegetable 3lerc actd 3XdllC acid 3xygen lgasl erchlorlc acrd erchloroethylene henot hosphonc @rthol hthallc olyglycol sod
r v - _x
X C X
ru
Fluldto be pumped
;i
X X
NC C
x x
X N C N
;i
c
N N N
x x
X N X X
C X C X
Allphatlc hydrocnrbon\ ?~rn~num Alum~nurn Alurlls .Ammonld (gas. IlquldJ ~\mmon~m acetxe Ammorwm ?mmonwm carbonxe hyarOxlae Chl0rrae sulphdte
x
N
x
N
x
X N
C C
Y
X I X X ;i X
Farry acids Femc chloride Frrrrc sulrate Ferrous chloride Ferrous sulfate Fluoborate salts Fluoborrc acrd Flue-SI~ICIC acta Formaldehyde FormlC wd Frron Gdsolrne (nondromr)clcJ
c c c c c
---C
x x x x
acid
lattng solutrons N N C X X otasslum otaswum otaswm otasstum (COCl otasslum pdlne carbonate chlorate hydroxide
x
X -
x
X X X X X N X X
Xylene (Xyloll Zlrlc ihlorrde
N X
N -
X x
C
N N N
x
X -X X X -N
Uquehd food producu
Ty9on food
(med concl hydroxide Iodide
4n111rir h>arvchiorlae 4rlIlmon\ I&S A4d regra (75% hyarochlortc. 25% llll dCldJ ?rorrlatlc hydrocarbons hrsenlc Bnwm salts \rllts
Gasoline (hrgh aromatlcrtyj GlUCOSf? Glue Glycerme Hyarlourc dcrd
x x N N N N N N
x x x x
X X X X X X
~tlrcone flurds ;&one 011 jllver nttrate joap solutrons jodrum jordum jodwm jodrum Sodrum iodlum Sodrum iodtum Sodrum btcarbonate blsullate brsulrite borate chlorate chlorrde ferrocyantde hydrosulfite hydroxrde
c
x x
X X X X X
Hydr@bromlC Hydrochlorrc
x x
X X X X Milk ot maqnesra
Hydrochlonc acid (rned concj Hydrochlorrc (concJ dcla Hydrocyaw acrd acid
Berwldehyde Benzene ~erizenwlon~c Benzorc aCla Benlyl dliohol Bleichlng Ilquors Bow dcra BrOlnle Bullne
SOdrUm carbonate
Hydrofluorlc acid Hyarogen peroxlde Iail Hydrogen (COIILI Hydrogen peroxrde
x x
X -X -X X _C X X X X X
x x
N N N N N
x
X X -C X X
X X
N sulfide X X X N N N X X X _ chlorrde sulldte salrs X X X X X -
c
N X
Id4
Sodrum hydrcxlde (med concl Sodrum hydroxide lconcj Sodrum hypochlorrte Ibelow 5%) Sodrum hypochlorlte /above 5%) Sodlurn nrtrate Sodrum Sodrum Sodrum srlrcate sulhde sulphrte
IBuwr 101) HUlVllC dCld Calcium oxode (alluteal Cdlwm salt5 C3rbon brsulfrae Cdrbon arowde Carbon tetrdchlorrae Chlordceuc dcld Chlorine (wctj Clllorlne (dry1 Chlorooenrene C1110(obrornonlethdrle Chlotolwm Chlorosull0lc acrri Chromic acra Chrom8nl \dlts Copper S&S
Hypochloroul acid I0rJlne so1ut10ns Krrosrne Krrones Lacquer soIvents Ldctrc acrd Ledd acetate Lrnseed 011 Lrthrum hydroxrde 15%) Magnewm Maynewum M&c dcld
x
X N N
Uquclltd
hod
producu
x
N
Beer Butter Coca co13 syrup Coffee Lard hldzola
x
N
x
X
x
-ii X -
T 1
011
iManganese
,Mercry salts hlethdne
x x x N
x x x x x
X
X X
x x
Steam Iup to 40 pstl Stedrlc acid Styrene Sulrur Sulfur Sullur chlorrde dloxrde hexdlluorrde
Orange peel 011 Orange syrup Scotch whiskey Spry shortenmg Tdb concerltrdte Tla Marla liqueur Vegetable Vlegar 011 X
c
X -
x
2
1 Methyl
rhlorlde Mlxed dud (40% slphrlc. 15% rlllrlcJ
c f-
x xJ
Synthetic
Resins and Polymers
239
< .0 0
aueldaH
0 _._
auazuag
C <
uo!lnlos ap!xoJpAq wntpos

me 3lJOlWOJp~~
pawluasuog (%OL) PI= 3JlN

<
(~~86) P9
.
3lJnw-s
z, JWeAlOd
>,,q&lu,ec(l
wwwQwwww~www~ww~wwww~wwwcJwwQ-wQ-uwww~w
LOW
99 WAN SH B d.9
aw
wwaw
w
W waaw LLLWWLW
awwwaa
a
ww
waawwww
wwaw ww
aww
wuwaw
W=W~bd Odd PW euelAlS 0 c-9
u_ a
240
Corrosion
Resistant
Materials
Handbook
TABLE
1.64:
VARIOUS
RESINS-GENERAL
ELECTRIC
Comparison
of Chemical
Resistance
of Six Plastics Resins % tensile retaineda Noryl phenylene Poly- oxide based Polyphenylsulfone4 resin2 ene sulfide5 100 91 0 100 35 79 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 92 100 100 100 95 100 0 0 0 0 0 0 100 70 55 100 100 99 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 loo 100 87 100 62 84 27 100 0 51 0 0 0 0 100 98 100 100 100 75 100 100 96 100 100 100 100 100 loo 100 100 100 100 loo 100 loo 100 100 100 loo loo loo 100 loo 100 100 100 100 04 64 100 100 100 100 100 49 65 96 100 80 93
NylonChemical
616
Potycarbonate3 37 67 0 100 20 30 100 0 100 100 100 100 98 7 0 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 48 0 48 94 74 100 0 0 0 0 0 0
Phenolic
Acids i
!
Bases 1 / lnorgallic
10%
10% acetic Glacial acetic Acetic anhydride Lactic Benzene sulfonic 88% formic 10% WI 37% I-ICI 10% HNO, 30% H2S0, 85% H,PO, 10% chromic
30 0 74 22 0 0 0 0 0 0 0 67 69 89 85 66 33 62 76 90 60 94 73 82 86 74 19 13 47 29 76 80 57 39 44 8 93 07 87 84 96 91 78 85 100 93 74
98 4 83 13 73 63 99 100 85 loo 100 96 loo 100 -
15% NaOH 30% NaOH 28% NH,OH HID
A12(S%)3 WW2S0,
Na2S0, Na2SIO3 Na2S NaCl NH,CI CaCI, BaCI,

WCl2
aqueous solutlon
AICI, FeCI, NH,NO,
CaWW
NaHC03 Na2C0, Na2CriOj KMnO, NaOCl L Brl 2-Aminoethanol Amyl alcohol Butyl alcohol Cyclohexanol Ethylene glycol
Alcohols I
Amlnes
n-Butylamine c Ethylenediamine Aniline Dimethylaniline Morpholine Pyridine
(continued)
Synthetic
Resins and Polymers
241
TABLE
1.64:
VARIOUS
RESINS-GENERAL
ELECTRIC
(continued) 76 tensile retaineda

Noryl phenylene Poly- oxide based Polyphenylsulfone* resin 2 ene sullies 0 0
0
Chemical Acetophenone Cyclohexanone Methyl ethyl ketone Benzaldehyde 37% Formaldehyde Furfural Acetyl chloride Benzyl chloride Carbon tetrachloride Chlorobenzene 2Chloroethanol Chloroform 5% aq. chlorophenol Epichlorohydrin Ethylene chloride Amyl Butyl Butyl Ethyl acetate acetate phthalate acetate
Nylon6/6 87 07 07 98 77 81 0 80 76 73 12 57 41 a4 65 88 95 90 89 100 81 96 87 90 84 07 80 86 90 88 100 89 76 91 93 88 100 57 0 0 a4 07 95 66 a4
Poly-
1 carbonate3
0 0 0
Phenolic6
Aldehydes. ketones 1
0 100 0 0 0 0 0 0 0 42 0 0 46 0 46 0 61 78 0 0 75 100 100 99 100 100 100 99 0 0 0 25 0 0 0 0 0 0 0 0 62 16
0 100 0 0 0 17 0 0 0 0 0 0 0 32 63 0 100 0 0 0 99 100 100 100 100 100 100 100 0 0 0 0 0 0 0 0 0 0 0 0 55 77
0 0 0 0 100 0 0 0 0 0 53 0 57 0 0 0 0 19 0 0 47 0 0 0 36 36 0 0 100 100 100 0 0 0 69 0 0 66 0 0 93 100 19 0
100 99 100 84 100 100 100 100 100 100 100 07 100 74 72 100 100 100 100 100 89 88 76 100 91 100 100 100 100 100 100 100 96 100 96 100 100 71 100 100 100 97 100 100 100
100 100 100 100 100 100 100 100 92 98 100 100 100 100 100 100 94 -
Chlorinated organics
Esters {
Butyl ether Cellosolve
Hydrocarbons
Cyclohexane Heptane Diesel fuel Gasoline Stoddard solvent Mineral oil Motor oil Wesson oil Dowtherm Toluene Xylene
N&riles { Nltro compounds {
;f;z;.;$;
Nitrobenzene Nitro methane m-cresol Phenol Dimethyl sulfoxide Sulfolane N.N-dimethylformamide Cresyldiphenyl phosphate Triphenylphosphite
24-hr. l~powre at ZOOF. 1-Zytel 101, Du Ponc Co. 2-Noryl. General Electric Co. 3-Lexan 141. General Electric Co. CUdel. Union Carbide Corp. S-Ryton, Phitlips Pelroleum CO. G-Gcnal 4300. General Eleclric CO.
a--Alter
MibcdlalWOUS
(Reprinted
from
Modern
Plastics)
242
TABLE
1.65:
VARIOUS
RESINS
AND
ELASTOMERS
FOR
LININGS
AND
MEMBRANES-ATLAS
KOROSEAL ATLASTAFLEX NEOPRENE CHLOROBUTYL
is an extruded,
plasticized chloride
polyvinyl laminated
chloride
sheet lining material.
is a polyvinyl is a synthetic
sheet lining.
rubber-based rubber
sheet lining. lining material. rubber sandwiched between two layers of soft natural
is a synthetic
3-PLY is a sheet lining rubber. Atlas PVDF
consisting
of a layer of hard natural
sheet lining is a polyvinylidene
fluoride.
ATLASTIC 31 is a hot-melt asphaltic compound with a ball-and-ring softening point of 200 to 225F (93 to 107C). ATLASTIC 40 is a corrosion-resistant membrane system consisting of a layer of ATLASTIC 40 textile in the center of two layers of ATLASTIC 31. ATLASTIC 50 is a textile-reinforced, hot-melt asphaltic membrane with a ball-andring softening point of 250 to 275OF (121 to 135OC). CHEMPRUF linings are a series of heavy-duty monolithic systems based on epoxy, furan, polyester, and vinyl ester resins. The CHEMPRUF 1000 Series systems contain flake glass as filler and reinforcement. The CHEMPRUF 2000 Series systems contain fabric reinforcement which provides a lining with outstanding structural integrity and chemical resistance in broad thermal ranges.
Flake Glass Systems CHEMPRUF CHEMPRUF CHEMPRUF CHEMPRUF CHEMPRUF 1100 1200 1300 1301 1400 Resin Binder Furan Epow Polyester Polyester Vinyl Ester Fabric Reinforced CHEMPRUF CYEMPRUF CHEMPRUF CHEMPRUF CHEMPRUF Systems 2100 2200 2300 2301 2400 Resin Binder Furan Epoxy Polyester Polyester Vinyl Ester
Chemical R: N: A: C: X:
Resistance
Chart
Recommended Not recommended Silica filler will be attacked. Sealing the surface may prolong Conditional; may be suitable but consult Atlas before using Does not apply
life
2 = 0
5 = 4:
-
C Room Temn
Acetaldehyde
ti 150F
C H
NN CN NN A Ft _
Ct. I Hh I RR I RN I i-i I
( t P P F F
Acetic acad. up lo 10% Acetlc acid. glaClal Alum Alumwwm Alummum Alummum Ammomum Ammomum Chlortde Nitrate Sulfate Chloride Hydroxide
RR RR IRR RR
9R I
Ti I P 3R F F b
El 3A -
NRC
(continued)
Synthetic
Resins and Polymers
243
TABLE 1.65:
VARIOUS
RESINS AND ELASTOMERS
FOR LININGS
7-
AND MEMBRANES-ATLAS
(contd)
E = a
C Room Temp.
H 150F
z CH RP
Is ;i; 2
:li 3C 3C
JN 4N
CH 3N
CH
RR RR NN RC _ NN YN RR RR
, Ammomum ~Ammontum
Amvl Acetale ~ Amy1 Alcohol I Amhne , Aqua j Barwm Barwm Barurn Barium BeMerle Regba
Nltrale SuItate
RR Nh
RR Rh - I
RR
NhI r4N
r4N
Chlortde Hydroxide NltraIe Sulfide 3R I F I 1R RR F i-i I F - 1R IR RR I F UN I P JN acid. 10%
G UN UN UN UN
G 3R G UN G IR G JN UN UN UN G G 3R G 3R 3R G IN IN IN IN IN c IN IN N N N N
/ Benzene
sulfon~c
RR 4N __ cl FIC i-i FIR
-.
1 t 1
$ ?
-7i-c
F rUN f UN -
(:n
i-i -
t UN rUN f i-i -
1
t-3
54
T
8
z z yr
I
z
0
z :n i-z -
RR RR RR
:n c Fii
6 -
4
[
( FtR(RR 3R JN 4C JN JN 4R JN tR 3N 4N ;k IR 1-i IC 1N IC IN IR IA IR IR IR IN IH JN:NN RR NN RC NN CN RR AC RR RC NN RR RR R R NN CN RN AC RR RR RR RR RR RC RR F h c F F F F h R R R h C R RIC RIR R A R RIR A:R H h F
8 ;; i t
8 i Ii ii
c:n
l7
-6 -6
I
Ei
c
I
RI R RI R hIN hIN hIN hIN R R A R C.i R R NIN R R R R R R NIN NIN C N RR N Ni C C C C A C
F F h F h L F h F RINI n R RIR RIA R h R A R R C
FIR PIN 4N -
I I
F n n
L-i IN
IUN -
RR NN NN
in4N n 1N
FIR FIR
i-i -
IUN
nIN nIN -
IUN I9R
RR
RIR RIR
I 3R F IR -
I9C
RR cc RR AC RR RR RR NN RR RR RR RC cc
1
RIR NIN Rz NIN IN 6 IR Rc Rx R R NIN R R RR RIAR N IN N IN Ac Rc R 77 c RR R YR Y2 R ; z R RR h IN NIN RIR A -G -; R A R R N N i #N N
:I4 RIR -
2 % 6 -
Fz
:C -
Cz RIR h IN RIA RIR RIA NIN h IN C:H h IN RIC Cz RIC RIR IR IA #A -IN :N IN .N c N N N N K N
F1R 1N -
PIR -
IaC
r JN
L1N RIA -
IU Nj F
( 72 FIR PIN -
RIR RIR nIN nIN I!IN hIN RIR RE RIR -
I Etromme
~ Bulyl 1 Butyl
wear
Acetate Alcohol
z -
h1ri
I1C I3R IU N!
I I I
-7
--I
Nh I
rJN
RR rJN - I RR F,R - I
9R
JN JN 1N fE FIC P iN FK FIA FE L h4N
I 4N MN P 1 RR F3R
F4A F1N FIR F,R FIR NIN N N N N N N N N Rc N N N N N N N N N N N Ni N N A N R
1R 1C 1R 1R *R 1R 4C IN IN k :N IN IIN 6 IC .N f IN i c IN ;N
I- RR
F F
RR RR RR RR A AC
Calctum Calcium
B~sulftte Chloride
RR RR
Gi 9R
RI ? -_ RII4 -_ RIA RIA t il. . ..NIN NIN NIN N IN N IN Rc 1 C N N N L 7 4 f NI ;;7 ; iN
R t-R R R RR I- RR R R n R II r, R N R h R R R R R R C N R R R R
I
F F
Gi 9fi Carbon Carbon Chlorme Chlorine ,Chlorme /Chlorme Dlsulllde Tetrachlorlde Dloxlde. gas. dry water solution / !4 N NN ICC RC RC AC acid. 10% CN N N; I Chloroform Chromic ,Chromlc acid. acid. up to 5% 10% N U /R Ri IN IN IR IN IN IR
IN P hIN JN NIN 4N 4N IN IR IN NIN NIN R R N IN N IN N N i NN N N
JNI RR
NN CN NN R NN RR CR RR NN
NN
.-
IN hi C.N NIN C N C d C N C N N N N N C N N N N Ni N N
hlNiRR A R R R R N N -A C;NN R NiNN

t N NiNN
gas. wet water
I ,Chloroacellc
Chlorobenzene
c IN IN -ii.
;~
R R;
/Otric
j Copper
-F T -i-
NN NN RR
acld Chloride
IRRIRR
R R R A CI,,RRr;;;;j C
R/RR/
A RR _-_I
RR -
(continued)
244
TABLE 1.65:
VARIOUS
FOR LININGS
AND MEMBRANES-ATLAS
bntd)
--r
t
_.-
c
f
6 2
E al 6 :ti
8
:! i t
0:
5 z
i C Room
; Copper
2 i
( :n FtR FIR
2!
5 i
-6
( 1 f r r r r ( r P F F F F P C F h F F F C h R h C F F F Ir ININNIRCINN INj-&&lNIR~R
5
CH RR RR RN NN NN VN ?R 3N VN ?R UN ?R 3C 3R 3R 7R 2R ?C 3R 3R 4N JN 3C IR 1 1R IR 3R
Temp.
Ntlrale
H 150F
/ CM \RR
; CH RR
CM I UN I __ UN /
UN
~HlCH
tc
tR t JN:NN JN NN
CH
CM
cc
RR
cc
RR RR RR RR RR RR RR AC
5-i
t t 1
E6 ! ( I
z t
z
6 2 %
8 i
x
ri:
a8
t c 1, :k -
c1N c4N
h1N hIN :N C hIN hIN RIC AIA h IN hIN :c C hIN RIA RIN NIN NIN R C NIN NIN A N R R RIA h IN R1R RIR NIN _~
z UN UN -
Ii-ii
-6 CH -_
3R 3R 3N 4N UN 4N E :N 1N tR RR
I ii I i-i
I3NIRR ,YNlRR
IVNjRR IVN;RR
, ,
FIR FIR FIN -
UN Dlethyl Ethyl Ether Acetate NN NN UN UN -~ :N JN JN Ethylene Glycol RR RR RR CN NN RR RR NN IiydrObrOmlC Hydrochloric Hydrocyanlc acld acld rcad RC RC RR RC RR Hydrogan Hydrogwt Pwortdr Sulhd, gas. dry RR RR RR RR RR RR RN RR RR RR RR RR RR RR RR RR RR tC tC
r4N
I JN -
hIN hIN h IN RIR RIN NIN A R RIR R R Rc AR R Tt R R RR R C R R R A RIC R -c Rc AR RR R R R R R R N N IC,RC N;RR
dN/NN
UN UN -
r rrlN
F 1R E JN
I NN I-NN
rJN
IN F FK JN P FG r.IN FIN FIC FIN FIC PIR RIN RIR RIA RIR h IN NIN RIN RIC RIC RIR RIA RIA IN __.. X A kf p R T R
3R NN NN
I3C,RR (,NIRR
rqN/RC
F 3RRR
rJN
F 1R
FIUOSIIICIC acld Formaldehyde Formx Gasolme Glycsrme Gold nex*ne Cyrnlde aad
rrl
N / RR
P 4N
FtR r.,N FIC FIC
JN
.~ JN 4N tC tFt JN IC IC IC
1
F IAlAR
F F
6 3R!RR
F tR F 1R
C r- RR RlRR N r- RR R:RC
FIC/NN FtR FtR c1 N F1N
F
RR RR RR RC
FIR FIC C:N RIC RIC C: c hIN C.C R A RI nIC
t RR
:c
1N IN IN
JN
t- RC
FfI RC
FIClNN FlR:RA FlR;RR FIRIRR FtR IFtR]RR r.4NlRR I, , cIRIRR F F a R RR A R R RlRR t- RR .. CC
JN
:c
4N
4N Jr4
C:c. HIC hIN
4 Ni IQ
tR ARIAA tR IR CN IR IRRR I
:c
I R --+ NR -4 R!
!F 1C /R d c J W /R R R IR :i :N IA IC IC IC R5 IR R R R N -E R
:c
IN
ccb RR T-
/ Magnesium
Chloride Hydroxide Nitrate
~RRIRR RR RR RR RR
IN R R R
N
Magnesvdm
: Magneswn
__ + 3RtNN
Req,,es
Synthetic (continued)
Fabric
Synthetic
Resins and Polymers
245
TABLE
1.65:
VARIOUS
FOR LININGS
AND MEMBRANES-ATLAS
(contd)
cy -,i i
c
I?
It. [
C Room
Mercuric Methyl
Temp.
Acetate
H 150F
cl.41 CHjCH
NN RR!RC i---NN C NN CN RC+NG NNICN NN -NNIRC NN NNiRR.NNCNICN; -i--7 NN CCNNICN! RRIRRiRR C NN CC NN
cnicn -RRtCN
-t
I
c
F E
c
r
h
Acetate Alcohol
Ethyl
___-
Methyl
RRJCN NN.NN NNF RR RR RR RR Rta NN I- NN RC t RC
c
h ii IN FIR RIC
Methyl
Methyl
Ketone
NN--*- NN
-_-~
NN
NN
I--NN NN CN CN
F
FE~CNIAR;NNJCN F F F F F F~F~RRIRR;C/RR
Sulfate 011 Splrlts acid Chloride NItrate Sullate
NN/NN
CN RR RC t RR
MIneral MIneral Murlatlc Nickel Nickel Nickel
KilRRIRRR
[
NN
R!R F
R R N N N N N
N,lrtcac,d.20%1Nltrlc acld. 30%
,RC
+--RRINNlNN
+-
I
GJRR~NN NN t- NN
NNICN
NN NN
F F h h
t-NN
NN/RR
YN
N NI
INN NN t
NN
N N!
RR
h R RR R h R RR RR RC c RC i- NN NN R
Olelc Oxalic
acid acid acid
NN GR
I-
N N/ C N
NN CN
RC,RC NN
Perchlorx Phenol Phosphoric Phosphorous Phosphorous Phthallc
CN acfd acid Trlchlorlde ._i iRR /RR ?G~RR RRiRR ;;;;;R NNR N RR,C RR:C NN RC
R R
---I H
RR RR
RC,RR
_f---
R N
acld
--I
RR NNlNN H RR -.I
NN NN
RC
NN C
NNI
CN RR
N;;;~NN~NN/GNI R N R R R A
IRR RR
I NN NN
N N n R I, II
N
Potasswm Potawum
Carbonate -4 Chloride
!RRIRR/
t RR
Potasswm Potasswm Potasswm L-
Fetrtcyanlde Ferrocyamde Hydroxide. up to 30%
R R R R
CN tRR
Potassum Potaswm Pyrldlne Rochelle
Norate Sulfate
R RiRR N N NN
salt
R RRR R C 9R RR RC AC cc Ad RR RR RR
ICC/cc r--- c_
RRjRC -RR iA
1. R R R R .R C 1~
Sodium
Bicarbonate
(continued)
246
TABLE 1.65:
VARIOUS
FOR LININGS
AND MEMBRANES-ATLAS
kontd)
I-
I i
2
n A
C Room Temp.
Sodium Sodium Sodlum Sodium Carbonate Chloride Cyamde Hydroxide. Hydroxide. Hypochlonle. up to 30% 30% and over
H 150F
CniCnlcHlcnlcn
t;
c
cn cn i-i -
cn
CH
cn
1 ?R I3R I3R IG IGN -
j Sodium
Sodium
up to 3%
r4N
3R F I 3R I 3R I *R RCIRCIRR/RRRAI
Sodium
Sulfate
i Sodlum
i Stearlc / Sulfur 1 Sulfur 1 Sullur i Sulfur Sulfut~c , Sulfurx
Thwxulfafe
fG 14N 9R/RRti-Nm
acid Dioxide Dloxlde Trloxlde Trloxlde acid. acid. gas. dry gas. wet gas. dry gas. wet up to 50% 80%
I 1N -
?R!RCjRCk CN NN NN NN CN NN NN NN
n 4N
-
n1N n1N
hIN -
FIR hIN hIN hIN hIN h IN h IN NIN -
Tin Chlortde
~RRHCN~RRR
TinToluene Trxhloroelhylene Trlsodwm Tung Urea xylene Ant Zinc Ztnc Chloride Nitrate Sulfate 011 Phosphate
C:N :N IN IN R lk R N
Synthetic
Resins and Polymers
247
TABLE 1.66:
VARIOUS
RESINS AND METALS-PHILLIPS CORROSION
CHEMICAL GUIDE
RESISTANCE
2fvf
2wF ENTO,
2wF KINAR
2wF lEFLOh MtBOI STEEL
MEDIA
RYTOf
AIL. M,NM
wm)
I Acctaldehyde Acettc Acids Acetac Anhydride Acetone Acetonitrile Acetophenone Acetylene Acetyl Chloride (dry) Acid Mane Water Alcohol, Alcohol, Alcohol, Alummum Aluminum Amyl Butyl 2.Aminoethanol Chloride (dry) Sulfate (wet) Ac,d Acetlc Acid, Glacial A A A A A A A A A NR
A NR
A A A A A A A A A
A A
A NR A NR NR NR NR Nfl NR
A A A A A NR NR NR NR A NR A A A A A A
NR NR
Q
NR A NR NR NR
Q Q
NR A A A A NR NR :
A/Q
NR
Q
NR A A NR A A A NR NR -
Q Q
A A A A NR A A A A NR NR A
Q
A/NR AlA A A A
Q
NR NR
Chlorohydroxlde Ammonia, anhydrous Ammonium Chlortde Ammonium Ammomum Ammonium Aniline Asphalt Barium Barium Emulsions Hydrorlde Sulfate
A A A A A A A A A A A A A A A A A
AI-
Q
A A A A A NR A NR A A NR NR A -
Q
A NR NR
A A A A A A A A A A A A A A A NR NR A A A A NR NR
Al-
Q
A A A A
A A NR
Hydroxide Nitrate Sulfate
Q t Q
A A
Q
NR
Q
A A -
Amyl Acetate
Q
NR
Q Q
A A NR
Q
A A NR NR NR NR NR
A A A
A A A A A A A A A A A A A NR A A NR A NR NR NR NR A A A NR NR NR NR NR NR A A A A A A A A A A A A NR NR NR NR A A NR A A NR NR NR NR NR NR NR NR NR A A A NR A NR NR A
Bar&urn Chloride Benzene Benzaldehyde Benzene Benzyl Borax Bromine Butadiene Butane Butylene Butyl Acetate Butyl Amme Butyl Ether Butyl Phthalate Calcium Calcium Calcium Chloride NItrate Sulfate (wet) Sulfonic Acid Chloride Benzonitrile
A A NR A A NR A A A A A NR NR A A A NR
NR/C
A A A A
A/Q AlQ A/Q

A A A A A AjNR NR NR A
: A A NR NR A NR A A A A NR A A A A A A -
Q A A A NR -
NR NR NR NR NR
WQ
Al-
Q
NR :
Q
NR A A A A A A
A A A A A
Q
NR -
A/Q
NR NR P NR A A A NR A NR NR NR NR
A A A -
Q
A A A A NR NR A A A A AlA A A A NR A A A A A A pi NR A A A A A A A A A A A A
Carbon D&oxide Dlsulftde Tetrschloride Cellosolves Chlorobenzene 2-Chloroethanol Chloroform Chlorophenol, Chlorosulfonic Chlorme(dry) Chromic Acid Cottonseed Oil m-Crew1 (crude) Cresyldiphenyl Phosphate Crude Oil Copper Sulfate Cycloherane Cyclohexanol Cyclohexanone 5% Aqueous Acid (dry) (wet)
A A A A A
A/Q
Q
A A A NR A A A -
Q
A A A NR A A A NR
NR
Q
A A NR A A A NR
A A A
Q
NR NR NR A NR A NR P I\ P 9 NR
Q
NR
A/Q Q
A NR A A A
n
). h 4 4 4
Q
NR -
Q -
Q Q
A A NR NR A A
Q
NR
Q
NR A A A NR : A
Q
A NR A
Q
A Q NR A A A
Q A
Q
NR -
Detergents Dtesel Fuel
4 4
4 z 4
A A A NR
A A
A
(continued)
248
TABLE
1.66:
VARIOUS
RESINS AND METALS-PHILLIPS m

WF ENYD, Y
CHEMICAL
(continued) m
ZWF P&E:I m XROC
m
1W F KYNAR
m
MOF TEFLDf m A A A A A NR NR NR NR NR A
MOF
20s F
POLY LFOf
NYLON
STEEI A
ALMlNUM (3cQI)
Diisobutylene Dimethyl Aniline Dimethyl Dimethyl Dlmethyl Diphenyl Dioctyl p-Diorane Dowtherm Formamide Phthalate Sulfoxide Ether Phthalate A A A A A A A A A NR
m
A
A A A A
A/Q
NR
NR NR NR -
Q
A A
Q
NR NR
A A
NR NR
NR NR
NR NR
Q
A A A A A NR A A A
Q A
A
Eplchlorohydrin Ethanolamine Ethers Lthyl Acetate Ethyl Chloride Ethylene Ethylene Ethylene Ethylene
(dry)
A A A A NR
NR NR
A A A A A A A A A
NR NR NR NR A
NR
NR -
Q
A A NR :
(wet)
A A
Chloride Dlamine Dichloride Glycol Ethe
Q Q
NR NR
AIQ A/Q
A A A/NA A
NR NR NR A
NR NR NR A
Q
NR
Q
A A
Q AIQ
A A A A A A A
Q Q Q Q -
Q Q
FC-77 (Cyclic Fluormated Ferric Chloride Ferrous Chloride Flo-Cool lSO(SilicateEster) Fluorosilicic Acid, 25% Formaldehyde. Formic Acid Freon (dry) Fuel Oil FlWlll Furfural CaSOllne Glycohc Acid Heptane Hexane Hydrochloric Hydrochloric Hydrufluoric Hydrogen Hydrogen HydroSen KWOSel-le JP Fuels Ketones Lactic Acid LPC Lubricating Magnesium Magnesium Methyl Oil Chloride Hydroxide Acid, 20% Acid, 37% Acid, 5.75% 30% 37%
A A A A NR A :/NR NR A : NR AiA -
A A
NR -
NR NR
NR NR NR NR A A A
NR NR
A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A
A A
A/Q
A A A A A A A A NRIF NR/Q A : A A A A A A A A A A A A A
A A NR NR NR A A NR
Q
NR
A NR
Q
NR A A A A A
NR A A A A -
A A A NR NR
NR A A A A A A NR NR : A A NR
A A NR A A NR NR A NR
Q
A A NR NR A A A
Q Q
A A A A
Gas Peroxide, Sulfide (wet)
Q Q
A
Q
A A A NR A A
:
NR
A NR NR A A A
A A A A NR
A A A A A
Q
A
Q
A A A A A
NR
MethylenaChloride Ethyl Ketone Ketone Methyl lsobutyl Mmeral Oil Morphofme C9tor Oil Naphtha Naphthalene Nitric Acid, 10% 35% (Cont.) Nitrobenzene Nitrogen Nitromethane
: NR NR
A NR NR A NR A A iI R n
NR A NR A
NR A NR A
A A A A
NR A NR A
A A A A A A A
&IQ k n h WQ VQ 1 VQ \ VQ
Q -
Q A
A NR NR NR 4 4
NR
A )I 9
VQ 9
YR YR
NR
/4
(continued)
Synthetic
Resins and Polymers
249
TABLE 1.66:
VARIOUS
RESINS AND METALS-PHILLIPS
CHEMICAL
kontinued)
m
MO-r MEDIA 2W F 2M F KYNAR IWF TEFLON 2wf
m
ZWF
m
wF NYLON :ARBON ALUYINUY STEELoca1)
RYTON m
PENTON
POL. ULFONI
NORlL -
m
A A AIQ A A A A AIQ A A A A A A A A P A A A A A A A A Q A A NR Q NR Q NR NR NR : A A A A A A Q A A A A NR A A P A A A A A A A A/NR NR A A A A A A A A A A Q A A A A A A QINR A A AjNR
m
A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A NR NR A NR A A A A NR A
Perchloroethylene Phenol Phosphoric Phosphorus Potassium Polarslum Polarslum Propylene Pyrldlne Acid
(dry)
Nil A
m
NR NR A NR NR A NR A A A A A A A A A A A NR A A A A NR NR NR NR NR Q A A A z A NR : A _ A A NR A NR A A NR A A A A A NR
NR A -
Q
NR NR A P A Q A
A A NR NR NR NR Q A
Q
NR A Q Q Q A A A Q A A A Q NR A A A A A A A NA NR A A A : NR A
Trnchloride (dry: Chloride Hydroxide, Chlorohydrin So% Permanpanate
Sodium Bicarbonate Sodturn Carbonate Sodturn Chloride Sodaurn Chromate Sodium Hydroxide, Sodium Hydroxide. Sodium Hydroxide. Sodturn Hypochlorlte Sodium Sulfate Sodwm Sulttde Sodium Thlosulfate Steam-&IV F Stoddard Solvent Sulllnol SlfolUle Sulfur Sulfuric Sulfuric Sulfuric Dmxide And. 30% Acid, 50% Acid. 98% 15% 3D% 50% Soln.
: Q NR NR NR NR NR Q Q Q NR A Q NR NR A A A NR P NR A A A NR NR Q NR A Q A NR NR NR Q A A Q NR A
A A A/Q * A A A Al2 A A A A A A A A A A A
Tetrahydrofuran Toluene Tomato JUG Tnchlorethylene Trxhlorrcetic Trlethyl Trlphenyl Trlsodlum vmegar Water, Deionized Sea Tap Xykfle Zmc Chloride Actd Phosphate Phosphite Phosphate
NR A A A A A A A A A NR
NR A NR -
Turpentme(dry)
Ryton grades c~nta~nlng glass fiber and/or mineral fillers will be less chemically
reslstant
than indicated.
RYTON PENTON KYNAR TEFLON NORYL
polyphenylene sulfide poly-3,3-bis(chloromethyl)oxacyclobutane polyvinylidene fluoride polytetrafluoroethylene phenylene oxide-based polymer
250
TABLE
1.67:
VARIOUS
RESINS FOR MEMBRANE
LININGS-WATERSAVER
WATERSAVER MEMBRANE LININGS
HYPALON (Chlorosulfonated
OR CPE R Polyethylene) (Reinforced Chlorinated Polyethylene)
. ..provides excellent resistance to weathering and chemical attack. Hypalon is available only as a rein. forced membrane and does not require a protective cover for most applicatrons. Hypalon is approved for potable water containment.
. ..specifically formulated for resistance to oils. Offers all of the desirable characteristics of Watersaver CPE and in addition, provides greater strength and resistance to creep, sagging, and puncture where conditions of use are severe, such as steep slopes or other high stress applications.
PVC (Polyvihyl
Chloride) EPDM (Ethylene Propylene Diene Monomer)
. ..membrane offers good chemical resistance, sealability, and serviceability in unexposed applications. It has performed satisfactorily as a liner for recreational lakes, canals, evaporation ponds, sewage lagoons, brine ponds, etc. It is recommended that an earthen cover be provided for PVC to maximize its service life as a fluid barrier.
. ..he. ,sen used for roofing and lining applications for many years. Superior weathering and elongation characteristics have made EPDM the most widely used single ply roofing membrane in the U.S.A.
OR CPE (Chlorinated
Polyethylene)
EPDM
R (Reinforced
EPDM)
. ..specifically formulated for resistance to oils. Membrane features excellent weatherability, sealability, chemical resistance and long term durability. CPE does not require a cover material for most applications.
. ..has the superior weathering characteristics of the non-reinforced EPDM with additional strength and tear resistance required by some applications. Many potable water reservoirs are rehabilitated with EPDM R or Hypalon.
OIL RESISTANT
POLWINYL
CllLORlDE
(ORPVC)
ISOBUTYLENE
ISDPRENE
(BUTYL) 1
(IIR)
POLYCHLOROPRENE
(NEOPRENE)
(CR)
ETHYLENE
PROPYLENE
DIENE
MONOMER
(EPDY)
CHLOROSULFONATED
POLYETHYLENE
(HYPALON)
(CSMI
CHLORINATED POLWINYL
POLYETHYLENE CHLORIDE (PVC1
(CPE)
EXPOSED EXPOSED BURIED ACID
LINER SIDE SLOPE LINERS DH 2 to 7 LINER
NR NR R II
II RR I II
RR RR RR RR
III ii
IYR UR 9 P YR
II i i i UR i
i -
RESISTANCE
ALKALINE PETROLEUM POTABLE DOMESTIC ROOFING
RESISTANCE PRODUCTS
pH&VOW I
I .
i
1R I iii
WATER WASTE MEMBRANE
1 NR R NR
R R R
1 RR RR NR
I.
RECOMMENDED
II.
RECOMMENDED
ONLY WITH REINFORCING
YR _ NOT RECDMYENDED
TABLE 1.68:
VARIOUS
RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW
CHEMICAL
DOW plastic lined pipe, fittings, and valves are designed and manufactured specifically for safety with long service life and process integrity in handling corrosive media, either liquids or gases, The variety of lining materials in the line of DOW piping engineer designing a piping system to select components particular service. The complete line includes: SL piping products lined with SARAN* polyvinylidene PPL piping products lined with polypropylene resin. KL piping products lined with KYNAR** polyvinylidene PTFE piping products lined with polytetrafluoroethylene Trademark
**Trademark of The Dow Chemical Company of Pennwalt Corporation
Maximum Tsmperaturs-nF
PC)
products allows the best suited for that chloride fluoride resin. resin. resin.
Ratings of serviceability of DOW plastic lined pipe, in terms of resistance to corrosive attack by process media and maximum operating temperatures, are shown in the following table. Unless otherwise noted: Solutions of inorganic materials appearing in the listing are saturated solutions. Where concentration percentages are indicated, the percentages are by weight.
i L
:
: 1
:d -
#$ -
E : 9 2 g
. t ._
f i
E
iA -
6 -
64 -
1 -
Sd -
s -
2ci d
Eh -
E -
k -
5 x
d -
d -
d -
d -
P
d
d
h
zl
s z
- -
ir . .i
.I i
=
E I
E E
7
!i E
E; E - - ;
5
E -
h .t
3
; E g
I i
1
: ;
Y
J2
0
11
.-
3 f 5 ._
g i
5
e i
5 ._
i f
TABLE 1.68:
VARIOUS
CHEMICAL
(continued)
Maximum Temperature--7(T) 110
ml El
Cormsiw
Strsrm
*ls 11361
=
llnl
as
llm
19
11 2
1
04
Not Recom mended
Calcium chlorid*(rmunmdl Calciumchlwin
?m Pm
IL
PPt IL
St PPt St
Zd e -
2
$0 -
h
id 6d -
, : i -
;ris : =
ih -
i = -
$ -
r;
=
e =
If 2 -
E E - E E -
E i - -
a
5 I 8
=
D D
ij =
m y
?s
1
2 :
f
z
u
Y
f 0
D 6
1
0
7,
E
7
: il -i
-
d L : -
i -
i; -
i;
d -
i; ii -
id -
i -
i; . -
ti =
=
= =
EE - -
E 1
D
iz e
_O i
m 5
E -
;
.Y
i
0
I
s
.
0
0 f
f
B
6
.Y ;
.r d
TABLE 1.68:
VARIOUS
RESINS FOR PLASTK
LINED PIPING PRODUCTS-DOW
CHEMICAL
(continued)
z
KL SL PPL
PPL
i
IL
SL
SL
KL PPL PR SL
SL It
KL
PPL
St
PPL
St
IL
-t
KL
KL
PPL St
Corrosion
Resistant
Materials
Handbook
6 * $ iti ii
L =
$c4 i: =
ti =
i; =
E F ;
5
2 .Y
E E - $ f
t: t
E
2
a!
5
E
E
I H
E f
I
2 iit
iti ii = i; ii -
i -
2 ii -
c c - i h - c ii f G;
; -
is - -k - - L
1 d
ii =
f
-
b t
ii
: -
E 3
= = = E EE - - D f
= =
r -
EE - -
1 E - -
3 : :
,
j i
. I f: I: ; 2 f j B
0 Y
x
.Y
ij
.5
i i
z
Y
Y
.Y
$s
Z K
f d
:: i
TABLE 1.68:
VARIOUS
CHEMICAL
(continued)
Maximum Tempcrahln-*F PC)
IL Y
(continued)
TABLE 1.68:
VARIOUS
CHEMICAL
(continued)
(continued)
TABLE 1.68:
VARIOUS

Maximum Temperature--F PCI
CHEMICAL
(continued)
Maximum (60 11311 m 11351 lull 250 m Ilull Temper&m-*F :n: IC) El tzI ISI n WI NOt Recom mended
El
sodium uh
I =* II
St PPL
TABLE 1.68:
VARIOUS
CHEMICAL
(continued)
nff
Pm
II
II
WL
I
I
I
I
SL
I
St
PPL
nrf
Pnoriun chbrat llSWOPll
I(t
I KL Kt
wt
SL
I KL PPt i
nffll PrR nrf
I
I
PPLi
I St-3 I
I St
I
I
St
Pmusium chbrida Pauaium shmmtie ImIk~lin*~
?Pt
SL
nR
IL
IL
PPL-
nfi
nfi
PPL PPt
St St
lu
Pmubm
pwchbrn*
nrf whl PlFf Kt
It
PPt
Pmauium pwmangan.a
Pamssbm
dide
Iwfll
Pm
al
n
I M I sl* I
SL
PPL
Synthetic
Resins and Polymers
261
I
I a
% : c
a -
:L -
i: itI -
E I -
i 2
ti -
5 : -
ti -
z - c - -
=
zrE!!?E ?I = Z?
E _ E E _ -
E E E -
cE __
E t
Z ;
1
F .
.
e %
2
&l
z
g i$ g ; x .u .g 2H .g g
3
z 2
1
e
3
lz
ZZ
I I
A i; -
-t
-
i 1. :;:
i -
i 22 -
2 ti , -
L -
s i t -
+I -
f
L
kg -
rcs :i -
LYI -
z : -
z s - - - = =
E -E -
s ;
b =
;
x
=
=
=
;: =
E -
* =
E E E - - -
il =
E E - = k 6 z H i
3
E 4 :
E E - -.
E -
1 t
s
P
ep
P
.a
5 t
2
3 s
i I 3 3
k
OL
c
5
I 5 3
I d
.
1
s ::
.
5
L
5 f
c.
5
5 ,;
::
s f
2 ._ fi
e ;
P
B f
I i
E I
I ._
5 %
z ;
,x
TABLE 1.68:
VARIOUS
RESINS FOR PLASTIC LINED

Msximum Temperature--7 fTI
PIPING PRODUCTS-DOW
CHEMICAL
(continued)
Maximum
Comasire
Stream
263
TABLE
1.69:
VARIOUS
THERMOPLASTIC
AND ELASTOMERIC
PIPING MATERIALS-NlBCO
Chemical Resistanceof Industrial lhetmoplastics
R = Recommended NR = Not Recommended = No Data Available
Acetaldehyde Acetamlde Acetic Acid, Acetic Acid. Acebc Acebc Acettc Acebc
10% 20%
Acid. 50% Ackd. 80% Acid. Glacial AnhydrIde
I
3F NR R R R R R NR NR R NR NR NR R A NR NR R R R R R R R R NR R R R R R R R R R R R R NR R R A R R R R A R R R A R R R NR NR NR NR NR R Ester
PVC 140F NR R R R NR NR NR NR
CPVC 7 3F 185F
POLYPROPYLENE 3F R R R R R d R R R R R NR NR R 12OF R .R R R NR NR NR .R R R NR R R R R NR NR R R R R R NR NR NR R 15OF 18OF 3-F
PVDF 15OF 23OF 2BOF 3F UR UR UR UR UR UR UR UR UR UR R R UR UR R UR R R R UR UR R R UR R R R R R R R A R R UR R UR UR UR R
VITON 14OF NR NR NR NR NR NR NR NR NR NR R R NR NR R NR R R R NR NR R R NR R NR R R R R R R R R NR R NR NR NR NR 185F NR NR NR NR NR NR NR NR NR NR R R NR iR R NR R R R NR NR R R NR R NR R R R R R R R R NR R NR NR NR NR
R R
NR NR NR NR NR
R R R NR NR NR NR
F
7:3F R A R R R R R UR R UR R UR UR R R R R R R R UR R R R R R R R R R A R R R R
EPDM 14OF R R R R R R R NR R NR R NR NR NR R R R R R R NR R R R R R R R R R 210F R NR NR NR NR NR NR R NR R NR NR NR R R R R R NR R R R R R R R R R R NR R R
R NR NR
NR NR NR
ACetOne Acetophenone Acetyl Chloride Acetylene Acetyl Nltrlle Acrylac Acad. Ethyl Acrylonltrlle Adlplc 105 Acid Alcohol Alcohol Alcohol, Alcohol. Alcohol Alcohol. Alcohol. Alcohol AICOhOl. Alconol AlcnOl AlOtwl
R NR NR NR R NR NR NR R NR R R R R R R NR R R R R A NR R R R R R R NR R R R R R R NR R R R R R R R NR NR NR NR NR R NR NR R R
NR
NR R R R R R
NR R NR NR NR R R R A R R R R R R R R R R R R R R R R
Ally! Amy1 Benzyl Butyl. Pnmary Butyl. Secondary Dlacetone Ethyl Hexyl Isopropyl Methyl Propargyl Propyl
R R R R R R R R R
R R R R NR R R R
R R R R NR R NR R
R R R R NR R NR R R NR R R
Ally, Chloride Alum Alum Ammon,m Alum Chrome Alum. Potassium Alurmnum Chloride Alumnum Fluoride Aluminum Hydroxide Alum,num Alum,num Alum,num Ammoma Ammonia Ammonia. Ammonwm Ammon,m Ammonum Ammon,um Ammonwm Ammomum Ammon!um Ammomum Ammonium Ammonium Ammohlum Ammonwm Ammonwm Ammonum Nitrate Oxychlonde Sulfate Gas Aqua 10% Llquld Acetate Blfluorlde Blsulflde Carbonate Chloride Olchromate Fluoride. 10% Fluoride. 25% Hydrwde Metaphosphate Nitrate Persulphate Phosphate Sulfate
R R A R R
R R R R R
A R R R R R R R R R R R R R R R R
R R R R R R
R R R R R NR
R R A R R R
R R R RS
R R R R
R R
R R
R R R R R R R R R
R R R R R R R R R R R R UR R NR R Nk R NR R R R R R R R R R NR R R R NR R NR R R R NR R NR A R R R R R R R R R R R UR R R R NR R R R R R A R NR R R R R R R R R N NH R
R.
R R R R
R R NR R
R R R R
R R R R
R R R R
R R
A R UR R UR UR R UR R UR R R
NR R NR R NR NR R NR R NR R R
NR R NR R NR NR R NR A NR R R
Ammonum Sulfide Ammonwm Thmcyanate Amyl Acetate Amyl Chlorlde An,l,ne An,lme Chlorohyarate An,l,ne Hydrochloride Anthraqumone
Polyvmyl Chlorrde. Type 1. Grade : $hlonnated Polyvmyl Chloride R Recommended to 210F -
Data tp 210F
for other
chemxals
presently
not awlable
264
TABLE 1.69:
VARIOUS
THERMOPLASTIC
AND ELASTOMERIC
PIPING MATERIALS-NIBCO
(continued)
CHEMICAL
PVC 3F 140F R R NR R R R R R R R A R NR NR NR R R R R R R R R A NR R R NR NR R R NR A
CPVC 3F 185F
POLYPROPYLENE 3F R 120F R 150F A 18OF A 3F R R R R R R
PVDF 150F 230F 280F

7 3F
VITON 140F R R R R R 185F R R R R R

7 3F
EPDM 140F
R
210F
Slfonlc Ant,mony Trlchloride Aqua Aegla Arsenic Acid Aryl Sullon~c Acld
Anfhraq4one
ACld
R R NR R R R R R R R R R R R NR R NR R A R R R R R R R R NR R R NR NR R R NR R R
R R
NR R
f
R R R
R R R R R
R NR R
NR R
NR R
R R R R R
R R R R R
R R R R R
R A R A R R R
R R
R R VR NR NR R R NR R NR R NR R R R R R R R R R R R R R R
NR NR R NR R R R R R R R R R R R
NA NR NR NR R
NR NR NR NR
NR R R R
NR R R R
NR R R R NR NR NR NR R R R R R R NR NR NR NR NR NR NR NR R R R R R R NR NR NR NR NR NR R R R NR NR R NR NR NR NR NR NR R R R NR NR NR NR NR NR NR NR R NR NR NR NR
R R
R R R R R
R R R R R R
R R
R R
R R
NR NR R R R NR NR R NR R R
NR NR
NR NR
NR NR
NR R R
NR R R
NR R R
R R R R
R R NR R
R R NR R
NR R
R R NR NR NR R R R
R R NR NR NR NR R R NR
R R NR NR NR NR R R NR
NR NR R R R NR NR R
R R R R R
R NR NR NR R NR R R R
R R
R R
R R
R R R R R
R A
R R
R R
R R R R NR R
R R R R R R R R R R
R R R R R R R R R R
R R R R R R R R R R
R R R R R R R R R R
R R R R R R R R
NR R
NR R
NR R
R R R R
R R A R R R R
cane sugar Liquors Carbltol Capryllc Acid Carbon Oloxlde Wet Carbon Carbon Carbon Carbon Oloxlde Dry Otsulllde Monoxide Tetrachlorlde
R R R NR NR R R R R R R NR R R NR R R
R R R R NR NR R R NR NR R R R R R
R NR NR NR R R R
R NR NR NR R R R
R R R R NR R NR
R R R R NR R NR
R NR R R NR R NR
R R NR R R
R R NR R NR
R R R R
R R NR NR
Polyvmyl Chloride Type 1. Grade Chlorinated Polyvmyl Chloride + For dratnage apphcat~on only R Recommended lo 210F - Data to 210DF
for other
chemocals
presently
not avatlable
(continued)
Synthetic
Resins and Polymers
265
TABLE 1.69:
VARIOUS
THERMOPLASTIC
AND ELASTOMERIC
(continued)
CHEMICAL
PVC 3F R R R R 140F R R R NR R R R NR NR NR R R NR NR NR NR NR R A R NR A R R R R R R R R R R NR R NR R R R R NR NR NR R R R R R NR NR NR NR NR R NR
F
7 3F
CPVC 155F R A R
POLYPROPYLENE 3F 120F 150F 180Ft 3F R
PVDF 150F R R R R R 230F R R R R R 280F R R R A
R R R
VITON 14OF R R NR NR NR NR NR 185F R R NR NR NR NR NR 3F R R R R R
EPDM 140F R NR R R NR 210F R NR NR NR NR
7 3-F
R R NR NR NR NR NR
Chloracerlc Acid Chloral Hydrate
R R R R R R NR NR
NR NR UR A NR NR
NR NR
NR NR
NR NR
R R A R R
R R A R R NR R NR NR NR NR NR R R R R R A R R R R NR NR NR R R R R NR NR NR NR NR NR NR R NR
R R R R NR R R R NR R R R R R R R R R R R R R R R R R R R A R NR R R
R R R R NR R R R NR R R R R R R R R R R R R R R R R R R R R R NR R R R
A R R R NR A R R NR R R A A R R R R R R R R R R R R R R R R A NR R R R
NR NR NR R R NR NR NR R R R R R NR NR R R R A R R NR NR NR NR R R NR NR R R R NR
Water Saturated Chioracetlc Acld Chloroacetyl Chiorlde Chlorobenzene

Chlmne
R R R NR NR NR NR A R R R NR R R R R R R R R R R R NR R NR R R R A NR NR NR e II R R R R R R NR NR R NR NR R NR R R R NR NR
R UR NR NR NR R R R R R R R R R R R R
NR NR NR R R R R R
NR NR NR R R R R A
NR NR NR
R R
R R NR R R R R R R R
Chlorobenzyl Chloroform Chlorop,cr, Chlorosulfonlc Chrome Chromic CHromfc Chromfc Ac,d Acld Acld Acid
Chloride
Acid 10% 30% 40% 50%
NR R R
C~tr,c Acid Coconr 011 Coke Oven Gas Copper Carbonate Cooper Copper Copper Copper Chloride Cyantde Fluoride
Nitrate
R NR NR R R R R R R NR NR NR NR R R NR NR NR R R NR
R NR NR R R R R R R NR NR NR NR R R NR PUR NR R R NR
A R
R R
R R R R R R R R R R R R R R R R R R R R R R NR R NR R NR R R NR NR NR R R R R NR NR R R R R
R R R A R R R R R NR R R R R R NR
R R R R R R R NR NR NR R R R R NR NR
copper Sulfate Corn syrup

Cottonseed CISOl Cresylx Croton
Aad
R R
R R
011
50%
Aldehyde
UR R R
NR A R R R
R R
R R
NR
NR
NR R R
NR R R R NR NR NR NR NR
NR
NR
NR
NR R R R R R UR UR UR R NR R NR NR NR NR R NR R NR NR NR NR R NR R NR NR NR NR
R R NR NR NR R NR NR
NR NR NR NR NR NR NR NR
NR NR NR NR NR NR NR NR
R NR NR NR NR NR NR NR NR NR
NR R R NR NR R R
NR
NR
UR
NR
NR
NR
NR
Poiyv~nyl Chloride Type 1 Grade 1 2 Chlonnated Polywnyl Chlotlde + For dramage appl~caf~o only R Recommended 10 2:OF - Data lo 21OF
lor other
chemicals
presently
not available
(continued)
266
TABLE
1.69:
VARIOUS
THERMOPLASTIC
AND ELASTOMERIC
(continued)
CHEMICAL
PVC 3F 140F NR NR NR R
CPVC r3OF NR 185F NR
POLYPROPYLENE 3F NR R 120F NR NR 150F lEOoF NR NR NR NR
D~octyl Phthalate Dloxane D~oxane. 1. 4 Dlsodlum Phosphate Dwmylbenzene Epsom Salt Ethvl Acetate Eth;l Acetoacetate Ethyl Ethyl Ethyl Ethyl Acrylate Chloride Chloroacetate Ether Bromide Chloride Chlorohydrln Dlamme Dxhlorlde Glycol Oxide
NR NR NR R R NR NR NR NR NR NR NR NR NR NR R NR R R R R R R R R R A R R R R R A R R
t I
PVDF 150F NR NR NR R R NR NR NR R NR R R NR NR 230F NR NR NR R R NR NR NR R NR R R NR NR ZIJOF NR NR NR R R NR NR NR R NR R R NR NR R NR R R R R A R R R Nk R R R R R R R NR NR NR R R :: NR NR R R R R NR R R R R R R .R R R R R R NR R R R NR R R R NR R R R A R :: R R R 73F
VITON 140F NR NR NR 185F NR NR NR
7 3F UR UR UR R R UR R R R R R R R UR R R R
R NR NR
EPDM 140F NR NR R R NR NR NR R NR NR NR R R NR R R NR R R R NR NR NR NR R NR R R NR 210F NR NR R R NR NR NR R NR NR NR NR R NR R R NR
7 3F R R R
NR NR NR NR NR NR NR NR NR NR R NR R NR R R R R R
NR
NR
NR NR NR R NR R R NR R R NR R R. R. R
NR NR NR R NR R R NR R R NR R R. R R
NR NR NR R NR R R NR R R NR R R R R
R NR R
NR NR NR
NR NR Nk
NR NR Nk
Ethylene Ethvlene
Eth;lene
Ethylene Ethylene Ethylene Ethylene
YR R
NR R
NR NR
NR R
Fatty Acids Ferrac Acetate Fernc Chloride Ferrac Hydroxxde Ferric NItrate Ferrac Sulfate Ferrous Chloride Ferrous Hydroxkde Ferrous NItrate Ferrous Sulfate Fish Solubles Fluorine Gas Wet Fluoborlc Acld Formaldehyde. Formaldehyde. Formaldehyde. Formrc Ac,d Formic Acld Freon F-11 Freon F-12 Freon Freon Freon Freon F-21 F-22 F-l 13 F-114 35% 37% 50% (Anhydrous)
R R
R R
R R
R R
R R
R R R
R R NR R R R R R NR R R NR NR R R R R NR
R R
R NR NR NR NR NR R R :: NR NR NR R R R NR R R R R R R R R R R : R R R
R NR NR NR NR NR R R R R NR NR NR R R R NR R R R R R R R R R NR NR NR R NR NR R NR R NR NR NR R NR R NR NR NR R NR R
R R R R R R A R
NR NR NR NR NR NR R R R R R. d R R R R R R R R R R
R R NR YR R R R R YR
UR A NR R UR UR UR
tik ik
NR NR R R R
i&l idi
NR NR R R R
NR NR
NR NR R A R
UR R R R R R
NR NR R R R R
NR NR R R R R
NR NR R R R R
R R NR NR NR R
NR NR NR NR NR R R R R
NR NR NR NR NR R R R R
Gall~c Acld Gas. Natural Gasoline. Leaded Gasolme, Unleaded Gasolme. Sour GeMIn Glfl GlUCOSe Glycerme.
R R R R R R R R R R R R R R. R R R R R NR R R
R R R R R R R R R
Glycerol
Glycohc Acld Glycols Grape Sugar neptane Hydrobromoc Hydrobromx Hydrochloric Acld. 20% Acud. 5wb Acld. Cont.
ri E
R R R NR NR R R R
: 37%
R R R
NR R..
UR R R R R
NR NR R
NR NR kI R
NR NR
: R R R
NR NR R R NR
NR NR NR NR NR
1 Polyvmyl Chloride. Type 1. Grade 1 2 Chlorinated Polyvinyl Chlonde t For dramage application only R Recommended to 21OF - Data to 210F.
for other chemicals
presently
not avaalable
(continued)
267
TABLE 1.69:
VARIOUS
THERMOPLASTIC
AND ELASTOMERIC
(continued)
CHEMICAL WF Hvdrocvanc H;droc;an,c Hvdrofluorlc Hydroflurac Acld Aad. 10% Acid. Dalute Acod. 30% R R R R R A R R R NR R R R R R R R R NR
PVC 14OF R R NR N9 NR NR R R R NR R R R R R R R R NR NR NR
CPVC 3F 155OF
POLYPROPYLENE 3F R R R R R R R. NR R R. R R IZOF ISOF 15OFj
NR NR NR NR R NR R NR NR
R R A
R R
R. NR
F
13F R R R A R R R R A R R R R R R R R A
PVDF 230F 25OF R R R 7 3F
VlTON 140F R R NR NR NR NR A R Uk R R R NR R R R NR NR R R R R NR R R R R R R R 155F R R NR NR NR NR R R NR R R R NR NR R R R R NR R R R R R R R 3-F
EPDM 14OF
R R
1SOF
210F R R NR NR NR NR R R
NR NR NR NR R R
Hydrofluorlc Aad. 40% Hydrofluonc Acid. 50% Hydrofluos~l~ac Acid Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Cyamde Fluor!de. PeroxIde PeroxIde. Anhydrous 50%
NR NR R R R
R R
R R
R R R R R R R
UR UR UR R R R UR R R R R NR NR NR NR NA R R NR
NR NR NR R R NR R NR A NR NR NR NR NR NR NR NR
NR NR NR R NR
PeroxIde. 90% Phosphrde Sulfide. Dry Sulfide. Aqueous Sulfate Ac!d
.A
R R R
So
UR UR R
Hydroqumone Hydroxylamme Hypochlorous Hydrazme lodIne Iodine Solutton. Isopropyl Ether 1sooctane Jet Fuel JP-4 Jet Fuel. JP-5 Kerosene Kraff L,quor Lactic Acid Lactic Aad. Lard 011 Launc Acid
R R A NR R
10%
NR NR
NR NR NR NR NR NR NR NR NR
R R R R R R R R R R R R R A R R A UR R R R R R R A R R R
NR
iR
NR R R R R R NR NR R A R R R R R NR NR R R R R R NR NR R
R R R R R R
NR R R
NR R R
NR
R R R R R
25% 80%
R R R R R R R R R
Lauryl Chlonde Lead Acetate Lead Chloride Lead Nitrate Lead Sulfate Lemon 011 Llgrolne Lime Sulfur L~noletc Llnolelc Linseed Linseed Acld 011 011 011 Blue
R R
NR R
NR R
NR R
NR R
NR
NR
R R R R R R NR R R A A R R R R NR NR R R R R R R NR R NR NR NR R NR NR NR R NR NR
R R R R R R R R R A R R R R R R R R R R R R R R
R R R R R R R R R R R R R R R A R A R R R R R R
R R .R R R R
R R
R R R
R R R A R R R R
Llqers LIthum Bromide Lubr,cat,ng 011. ASTM Lubr!cat,nq 011. ASTM Lubncatm~ 011. ASTM MachIne 011 Magnesium Carbonate Magnesium Chloride Magnesium Magnesium Magnesium Magneswm Catrate Hydroxide NItrate Sulfate
dt UP 113
R R R R R R A R R R R A R R R R R R R R R NR R R R R R R A NR R R R R R R R R NR R R R R R R A R R
R R R
R R R
R R .R R R R R R
NR NR NR NR R R R R R R NR NR A R R R
NR NR NR NR R R R R R R NR NR R R R R
NR NR NR NR R R 9 R R R NR NR R R R R
R R R R R R R
R R A R R R R R
R R R R R R R R
Manganese Sulfate Male% Acid Mal~c Acid Mercurtc Chloride Cyamde Mercuric Sulfate Mercurous Nitrate Mercury
MB,CU,IC
R.
Polyvmyl Chloride. Type 1. Grade 1 2 Chlonnated Polyvmyl Chloride + For dramage applfcatlon Only R Recommended to 210F - Data to 210F
for other
ChemlCalS
Presently
not avaIlable
(continued)
268
Corrosion
Resistant
Materials
Handbook
TABLE
1.69:
VARIOUS
THERMOPLASTIC
AND ELASTOMERIC
bntinued
CHEMICAL BF Methane
~efhylene
PVC 140F R NR NR NR NR NR NR NR NR NR R NR NR NR R R R NR R R NA R R R R R R R R R R NR NR NR NR NR NR NR A R NR R R R R R NR R NR NR NR R R NR NR NR NR NR
Cplcrobromlde Methoxyethyl Oleate

Methylamlne
ik
R NR NR NR NR NR NR NR A R R NR NR NR R R R NR R R NR R R R A R R R R R R R R NR NR NR A
F
CPVC
7 3F
POLYPROPYLENE 120F 150F
3F 185F 1
18OFi I 7 3F
PVDF 150F 230F R 280F 1 3-F R
VITON 140F R 185F R
IR
f
R R R R R R R R NR NR R NR NR NR R R NR R R R R R NR NR R NR NR NR R R NR R NR R R R NR NR R NR NR NR R NR R NR NR NR R NR R NR NR NR R NR R NR NR NR
F
73F NR NR R NR R NR NR NR NR R NR R R NR NR NR NR R R R R
EPDM 140F NR 21OF NR
Methyl Methyl Methyl Methyl
Bromide Cellosolve Chloride Chloroform
NR NR NR NR NR NR
NR NR NR NR NR NR
NR NR
NR NR
R R
NR NR
NR NR
NR NR
NR NR R R NR NR NR R R NR
NR R R R R R R R
NR R R
NR
NR
NR
NR
NR NR
NR NR
NR
NR
R NR R NR
R R R R R R R R NR R R R
R R A R R R R R NR R R R
R R R R R A R R NR R R A
R NR R NR NR NR NR NR R R R R
R NR R NR NR NR NR NR R R R R
R R
NR
NR
NR R R
R R R R R R R R R R R R R R R R R R R R R R R NR R R R R R NR R R R R R NR NR NR R R R R NR R NR NR NR NR NR NR NR R R R R NR NR NR NR NR NR NR NR
R R R R R
R R R NR NR R R R NR NR R NR R R NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
R R R R R NR NR
R R R R R NR NR
R R NR NR NR NR NR
Nitrous Ox,de Nltroglycol
R NR R R NR R R R R R R R R R R R R R NR NR NR NR R
R R R NR NR NR A R R R R R R R R R R R NR R R R R R R R R R R R R R R R NR NR NR NR R NR R R R R R R R R R R R R R R R NR NR R R NR NR NR NR R R R R NR NR NR NR R NR NR NR R R NR R R R NR NR NR R R NR R NR NR NR NR NR R R NR R NR NR
0,lsVegetable Ole,c Acld

Oleum Oxalic Actd Oxalic Acid 50% Oxygen Gas OZOfl.5 Pai,f,c Palmittc Palm,,, Paraflln Peracervz Perchlorlc Perchlo,, Ac,d Acid Ac,d 10% 70%
R R R R R
R R NR R R R
R NR R R R R R
R NR R R R R R NR R
R NR R R R R A R
R NR NR NR R R R R
R NR NR NR R R R R
R R
R R R
Acid 40% Acid 10% Acid 70%
R R
R R
A R
Perphosphate Petroleum 011s Sow
NR
NR
NR
R R
NR
NR
NR NR NR NR
Phenylhydrazme Phenylhydranne Hydrochloride Phosgene Ltquld Phosgene Gas
Polyvmyl Chloride. Type 1 Grade 1 2 Chlor,nated Polyvinyl Chlortde + For dratnage appkatmn only R Recommended to 210F - Data to 210F
for other
chemxals
presently
not wallable
(continued)
Synthetic
Resins and Polymers
269
TABLE 1.69:
VARIOUS
THERMOPLASTIC
AND ELASTOMERIC
(continued)
PVC 1 3F R R R R R NA R NR A R
R R R R R R R R A R R R R R R R R R R R R R R R R R R R R R R R NR R R R R R R R R R R R R R NR R R R R 140F R R R NR R NR NR R NR R R R
1
7 3F
R R R R R R R R R R R R R A R
CPVC
185F R R NR
POLYPROPYLENE 3F
R R R
PVDF 18OFi
R R R
(20F
R R R
150F R R R
3F R
150F
R R R
230F
R R R
280F
R NR
VITON
140F R R R 185F R R R 3F
EPDM
140F R R R
13F R R R
210F
R
R R
R R R R R R R R R R R R R R R R R R R A R R R R R R R R R R R R R R R R R A R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
R R R R R A R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
R R
R R R
R R R R R R
R R R
R R
NR R R R R R R
R R
R A
R R R R R R R R R R R R R R R R R R 4 R R R R
R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R
R A R R A R R R A R R NR
A A A R R R R R R R R NR
R R
R R R R R R
NR
R R
R R R R R R R R NR
R R R R R R R R NR NR NR R R NR R R R R R R Polyvinyl : Chlonnated
R R R R NR R R R NR NR NR NR R NR R R NR R R R 1 R R R R R R R R R R R R R R R NR NR NR NR NR R R R R R R R R R R R R
R R R R
R R R R
R R R R R R R H R R
R R R R NR
R R NR
NR NR R R NR
NR NR
NR NR
NR NR
NR NR
NR NR
R NR NR NR
R NR NR R R
A R R
R R R
R R
R R R
R R R
Chloride Type 1 Grade Polywnyl Chlortde
(continued)
270
TABLE
1.69:
VARIOUS
THERMOPLASTIC
AND ELASTOMERIC
(continued)
CHEMICAL 73F soaps Sodaurn Sodwm Sodlum Acetate Alum Benzoate
PVC 140F
CPVC 3F R 185F R R
POLYPROPYLENE * 7 3F 120F R 150F R 18OF R UF 150F
PVDF 230F
280F :
VITON 140F 185F 7 3F R R R R R R R R R R R R R R R
EPDM 140F R R R R R R R R R R R R R R R 210F R R R R R R R R R R R NR R R R
7 3F R
ik
R
ik
R R R R R R R R
Nk i
R R R R R R R R
R R R R R R R R R R
R R R
R R R
R R R R R R R R R
R Sodium Sodium Sodium Sodium Sodium Sod,Sodlum Sodium Sodium Sodturn Sodium Sod,, Sodium Sodium Sodium Sodwm Sodturn Sodium Sodium Sod,um Sodlum Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Borate Bromide Carbonate Chlorate Chiorlde Chior~te Cyanide Dlchromate Ferrlcyanlde Ferrocyanide Fluoride Hydrox!de Hydroxide Hydroxide Hydroxide Hypochlorw lodlde Metaphosphate Nitrate Nitrite Palmttate Perborate Perchlorate PeroxIde Phosphate Phosphate Phosphate Silicate Sulfate Suillde Suif~te Thlosullate Solur~an 5% R R R Alkaline Acld Neutral R R R R R R R R R NR R R R R R R R R R R R NR R R R R R R R R R R R R NR R R R R R R R R R R R R NR R NR R R R R R R R R R
R R R R R R
R R R R R
R R R R
154. 30% 50% 70%
R R R R R R R R R
R R R R NR
R R R R NR
R R R
R R R R R R R R NR NR NR NR R R NR NR NR NR NR R R NR R R R R R R R R R R R R R R R A R UR R R R UR UR R R R R R R R R R R R R R R R R R NR R R R NR NR R R R R R R R R R R R R R NR R R R NR NR R R
R R R R
R R R R
R R R R
R 1 R R
R R
R R
R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R A R VR R R R R
R R R R R R R R R R NR R R R R
R R R R R R R R R R NR R R A R
R R R R
Sour Crude 011 Stannlc Chloride Stannous Chloride Starch Stearlc Acid Stoddard s Solvent SUCCIIC Acid Sul+amtc Acid. 20% Sulfated Detergents sui1ate Liquors Sulfite Liquor Sulfur Sullur Sulfur Sulfur Sulfur Chlotlde Dloxlde. Dloxlde Tr,ox,de Dry Wet
R R R
R R R
R R
R R
R R R R R R H R R R R R R
R R R NR R R R R R R R R NR NR NR
\1R rlR R R
NR NR
NR NR
NR NR
R R R R NR NR R R R R R R R
R R A NR NR R A R R R R R
R R NR NR R R R R NR NR NR NR NR
R UR R UR UR A R R R R R R R R
R NR R NR NR R R R A R R R R R
R NR A NR NR R A R R R R R R R
R UR R R
R NR R R
R NR R A
Sulfur Trloxlde Gas Suilur~c Acid 10% Sulfuric Acld. 30% Sullurlc Ac,d. 50% Sulfuric Sulfuric Sulfuric Sulfuric Acid, Acid. Acld. Aad. 60% 70% 80% 90%
R R R R R R NR
R R R R R R rlR
R R R R R NR NR
R R R R NR NR NR
R R NR NR NR NR
NR NR NR NR NR
R R R R R UR UR
R R R R R NR NR
NR NR
1 Polyvmyl Chloride. Type 1. Grade 1 2 Chlonnated Polyvinyl Chloride t For dra,age appllcatlo Only R Recommended to 21OF - Data to 21OF
for 3fher
chemicals
presently
not wallable
(continued)
Synthetic
Resins and Polymers
271
TABLE
1.69:
VARIOUS
THERMOPLASTIC
AND
ELASTOMERIC
PIPING
MATERIALS-NIBCO
(continued)
CHEMICAL
Sulfuric Sulfuric Suifur~c Sulfuric
Actd Acid Acid Acid
93% 94% 95% 96%
F
PVC
I 3-F
140F NR NR NR NR NR NR NR R R R R NR NR NR R NR NR NR NR R NR R NR NR R NR R R
NR NR NR
CPVC 185-F
NR
7 3F R R R R R UR
1
7 3F UR UR UR UR UR UR R R
POLYPROPYLENE 120F NR NR NR NR NR NR R R 150F NR NR NR NR NR NR R R NR lBOF1
NR
NR
NR NR NR
1
7 3F
PVDF 230F NR NR NR NR NR R R R R 28OF NR NR NR NR NR

7: 3F
VITON 140F 185F

7 3F
EPDM 140F NR NR NR NR NR NR NR R NR NR NR NR NR NR NR NR NR NR 210F NR NR NR NR NR NR NR
150F R R R NR NR
R R R R R R R
NR NR NR NR NR NR NR R
Sulfuric Ac,d 98% Sulfuric Acid 100% Sulfurous Ac,d Tall Oil Tann~c Acid Tanning Liquors TX Tartarlc Acid Tetraethyl iead Tetrahydrodurane Tetrahydrofuran Tetra Sodium Pyrophosphafe Thwnyl Chloride Thread Ctittlng 011s TlrplKl T,tan,m Te,rachlor,de Toluene Toluol Tomato Juice Transformer 011 Transformer 011 CITE/30 Trlbutyl Phosphate Tributyl Citrate Trvzhloroacetec Ac,d Trichloroethylene Tr~efhanoiam~ne Trtefhyiamlne Trimethyipiopane Trlsodlum Phosphate Turpentine
NR NR NR R R R R R NR NR A NR R NR NR NR R NR R R NR
R R R R
R R R
R R
R R
R.
R R NR NR
R R NR NR
R R NR NR A NR NR
R R R R R NR NR
NR NR NR NR NR
UR
NR
UR
NR
NR
NR
R UR NR UR R R NR R R NR A NR NR R NR R R R R NR NR R R R 4R 4R R 4R R R R R R R R R R R R R R R R R R R R R R R R R R NR NR R NR R R R R R R R R R R R R R R R R R R R R R R NR NR R NR fi R R R R R R R R R R R R R R R R R R R R R
NR NR NR NR NR NR R R NR R
NR NR NR NR NR NR NR NR NR NR
NR NR NR NR NR NR NR NR NR NR
R R UR R NR R NR R R R R R R R R R R UR R R R R R R R A R R R R R R VR R R R NR R R A R R R R NR R R R R R R R R R
NR NR R NR NR R R R
NR NR R NR NR R R R
NR NR R NR NR R R
UR
NR
NR
NR R R NR
NR R R NR R R R R R R R R R R R NR R R R
NR H R NR R R R
NR R H NR R a R
R R NR R NR
R R NR R NR R R R R R
NR
R R R R R R R R R R R R R R NR R R R R R R
R R R R R R R R R R R R R R R R R
R R R R R R R R R R R R R
R R R R R R R R R R R UR R R
R R R R. R R R R R R R NR R R
water Salt water Sea water sewage Whiskey White Liquor w,nes xyiene ,xylol, NR R R R
R R R R R R NR R R R
R R R NR R R
A R R NR R R
R R NR R R R
NR R R R
ZIC Chiorlde Zinc N~trale zinc Sulfate
I Polywnyl Chlorlde Type 1 Grade 1 7 Chlonnated Polywnyl Chloride t For dramage applatlon oniy R Recommended lo 210F - Data to 210F
for other
chemicals
presently
not available
VITON:
trade
name for vinylidene
fluoride-hexafluoropropylene
copolymer.
272
Corrosion Resistant Materials Handbook VARIOUS THERMOPLASTIO POLYMERS FOR HOSE STOCKS-GATES RUBBER
TABLE
1.70:
Stock Type G i!
Composition Plasticized Polyvinyl Chloride
Polyamide Resins (Nylon 610) Polyester Elastomer Polyurethane Special Material (Gates Tufflex Hose) (Hytrel) (EVA) Ethylene Vinyl Acetate
Y
E U cl
GATES CHEMICAL
1 Excellent Rcstrtance - This fluid is expected minor or no effect on the polymer. to have
RATING SYSTEM
The amount of discoloration that can be tolerated is usually established by the user on the basis of application. Obviously, products such as paint must be conveyed through a hose having very good nondiscoloring characteristics. If the product is not visually affected, then the hose is satisfactory. For some products, the discoloration may not be objectionable from a visual standpoint. However, the amount and makeup of the particles causing discoloration may be objectionable if they affect the final use of the product. Some of the more discoloration are: common methods of checking
polymer should give reasonably 2 Good Rerirtrnce -This satisfactory service. Due to the nature of this chemical and under prolonged continuous exposure, the stock may exhibit minor to moderate deterioration and/or solution discoloration. Environmental changes such as concentration, etc., temperature, may promote increased degradation. x Not Recommended - The stock is unsatisfactory this chemical and should not be used. - (Darh) - Insufficient or no data is available material. Testing is advised. Note for
for this Allowing the fluid to remain in a sample piece of hose for a given period, and then inspecting visually for discoloration. Testing fluid as in No. 1 above and then passtng it through filter paper to check foreign content. A more refined test can be made with a soectroohotometer. This instrument measures light transmission ihrough the fluid before and after immersron tests with the stocks. This ives a relative rating expressed in percent, the original uid being rated as 100%.
1: The above ratings as applied to the Chemical Resistance Tables are intended as guides only. They are compiled from the best data available to us. Ratings shown in the tables are based on a temperature of 70 F. and 100% concentrated or saturated solutions unless otherwise noted.
Note 2: If unusual conditions exist, a stock test in the fluid is suggested. Note 3: Where a chemical listed in the Resistance Tables is soluble in a solvent other than water, the solvent should also be checked for its suitability with the stock. Note 4: Discoloration of fluids conveyed in hose-There are no generally accepted standard tests for measuring or rating discoloration of fluids passing through a hose.
(continued)
Synthetic
Resins and Polymers
273
TABLE 1.70:
VARIOUS
THERMOPLASTIC
POLYMERS
CHEMICAL
FOR HOSE STOCKS-GATES

TABLE HOSE POLYMER TYPES
RUBBER (continued)
RESISTANCE
CHEMICAL A Acetaldehyde .................................. Acelamrde .................................... Acellc Acrds ................................... Acetone ....................................... Acetophenone ................................. Acetylene ..................................... Acrylonttrlle ................................... Aero-Safe 2?iOO................................ Aeroshell. 1A. 1AC. 4 .......................... Air, Ambrenl.. ................................. Atr, 150F ..................................... Air,1600F ..................................... Air. 200F. .................................... Awcratt Hyd 011 AA ........................... Alcohol, Amy1 ................................. Alcohol, Sutyl ................................. Alcohol, Furlural ............................... Alcohol.Ethyl ................................. Alcohol, Isopropyl ............................. Alcohol. Methyl (6%). .......................... Alcohol, Methyl (166%) ........................ ,Alkazene ...................................... Chlonde............................ 1alummum Alummum Fluortde ............................ 1 .......................... 1Mummum Hydroxrde
4
U 1
I C -
2(;[2 1 Use Chemrcal Hoses 1 2 I I Use Weldmg Hoses 1 X 1 1 1 1 1 1 1 : 2 2 2 1 1 1 1 1 2 X 1 1 No Hose Available 1 1 1 1 1 Use Chemical Hoses 1
X X -
1 1 2 X X -
X -
1 )
1 1 2 X -
1 -
1 2 1
,
; ) 2
1
1
1 -
2 2 2 -
:
1 2 1 1 1 1 1 1 1 1 1 1 1 2 1
2 1 -
1 1 1 1 1 2 2 1 2 1
Nitrate .............................. I kluminum Sulfate ............................. hIurn ........................................ 1 kmmonia. Anhydrous .......................... 1 4mmonia. Aqueous ............................ 1 Muminum 1 Acetate ............................ 14mmonium Bicarbonate ....................... I4mmonwm Carbonate.. ....................... I4mmonium Chlonde ........................... ......................... 14mmoniumkydroxlde 4mmonwm 1 Metaphosphate ...................... Nrtrate ............................ (Fertrlirer) \mmonium Nrtrite ............................. c I Immonium Persulfate .........................
14mmoma 14mmonium
1 1 1
2 1
1 1
1 1 1 X
1 1 X
1 1 2 2
1 1 2
1 1 2 2 2 X X
b4mmonwm Phosphate.. ....................... bmmonium Sulfate ............................ A bmmonium Bulfrde ............................ P \mmonwm Thiocyanate ....................... P Armyl Acetate .................................. Akmyl Borate ................................... Armyl Chloride ................................. Aimyl Chloronaphthalene ....................... ............................. A,myl Naphthalene Armyl Phenol .................................. Anathole ...................................... Aaniline ......................................... A&line Oils .................................... A,rrimal Fats ................................... A,nti-Fraaze (Glycol) ........................... A ntimony Chlorrde (50%) ...................... A ntimony Baits ................................ A qua Regra .................................... A rcq A T.F. Dexron ............................ Type2 ............................ A rco ATF ................................. A rcqc-2.100 A roclqr, Monsanlo ............................. A rqmatx Hydrocarbons ........................ A raemic Baits.................................. Aakarel (Transformer 011) ......................
2 1 1 1 1 2 2 2 -
2 2 1 X 1 1 1 1 1 1 -
X 1 2 1 X 1 Use Chemical 1 1 1 2 1
x Hoses -
X 1 -
X X 1 2 2 1
1 2 1
1 X
X (continued)
274
Corrosion
Resistant
Materials
Handbook
TABLE
1.70:
VARIOUS
THERMOPLASTIC
POLYMERS
G

HOSE POLVMER TYPES 2 v E
RUBBER bontinued)
U I 0
CHEMICAL
A-Continued
Asphalt, 18OF ................................ ASTM O,l No 1.. .............................. ASTM 011 No 2 ................................ ASTM 011 NO 3 ................................ ASTM Ref Fuel A ............................. ASTM Ref Fuel B ............................. ASTM Ref Fuel C ............................. 2 X X 2
B Baltic Types
100 150. 200 300. 500 ............ Banvel. Concentrated .......................... Barium Carbonate ............................. 3arwm Chlonde ............................... 3arlum Hydroxide ............................. 3arfumSulfate ................................ 3arlum Sulfide ................................ 3aslc Copper Arsenate ........................ 3aygon ....................................... 3eer .......................................... 3eel Sugar Lquors ............................ 3ellows. SO-20 Hydraulic Oil ................... 3enzaldehyde ................................. 3enzene ...................................... 3enzoic Actid .................................. 3enzyl Alcohol ................................ $lack Sulfur LlquOr ............................ )orax (Sodium Borate) ........................ {ordeaur Mxture ............................. Acld .................................... iorlc Copper Sulfate .......................... hake Flwd (Petroleum) ........................ lrake Flwd (Synthetic) ........................ lrme (Salt) ....................................
low
1 1 1 : 1 Use Chenvcal Hoses I 2 I 1 Use FDA Hoses -
:
X
X 1 2 1 1 X 1 1 2 1 2 Use Chemical Hoses 2 2 1 1 1 1 1 1 1 2 2 -
Elunker 011 .................................... Elutane. Gas or Liquid .......................... B#utter .......................................... t ebutyl Acetate ................................... 0 ,utyl Alcohol (ButanOl) ........................
1 1
I 2 I Use 20BHB Only Use FDA Hoses 2 1
X 1
C ...............................
Bisulfate ............................... Bisutflde ............................... ..- .................... Bisulftte ........ Carbonate ............................. Chlorite... ............................. 1
1
alcium Arsenate alcium al&m alcium alctum slcium slcium cc llcium cc
2 1 2 1 X
1 1 1 1 1 Use Chemical Hoses
2 1 1
1 1 1 1 1
Chloride. 1.. ........................... Hydroxide (Cont.) ..................... Clklcium Hypochlorite (5%) .. .................... Calcium HypochloftlO (15%). .._ . . . . ..__. .__._.. . Calcium Nitrate _.. . . . . . . ..... .... .... . .. Calcium Silicate . . . . . . . . _. . . . . . . . . . . _. . . . . Calcium Sutflde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cane Sugar Lquon . . . ._.. . . . . . . . . . . . . . . . . . . Carbohc Acid (Phenol) . . . . . . . . . . . . . . . . . . . . . . . . , Carbon Disufhdc . . . . . . . . . . . . . . . . . . . . . . . . . . Carbon Dioxide (Dry) . . ......... ........... Carbon Dloxicb (Wet) . . . . . . . . . _. . . . . . . . . _. _. . . : Carbon Totnchloride . . . . . . .._. . . . . . . . . . . . . _... Carbonic AIM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carter MotorDt1................................ 7
2 1 1 2 1 X 1 X 2 1 1 1 1 Use Chemical 1 Hoses
2 1 1 X 1 X 2
Use Chemical H05en 1
Synthetic
Resins and Polymers
275
TABLE 1.70:
VARIOUS
THERMOPLASTIC
POLYMERS

HOSE POLYMER TYPES
RUBBER (continued)
CHEMICAL
L -
c2
3
I
C-Continued
Caseln ........................................
1
CastorCM.....................................
Caustic Potash (30%) .......................... Caustic Soda (20%) ............................ ............................. Cellosolve Ace!are Cellosolve. Union Carbode ..................... Cellugard. Cellugard 200 ....................... Cellulube, 80. 150. 220. 300 .................... 550. 1000 22OA. ST220 A60 ................. Chlorine Water (25%) .......................... Chlorme Gas .................................. Chlorine Trrtluorlde ............................ Chlorobenzene ................................ ChlorobrOmO Methane ......................... Chlorodane ................................... Chloroform .................................... Chlorosulfonic Acfd ............................
ChlOrO!Ol~ne .................................
1 1 I Usd Chemical Ho;es Use Chemical Hoses
>
X X X 2
X
2 1
No Hose Available
Chlorox..
ChOcOlale
..................................... Syrup ...............................
1 1 1
Hose Available I FJO UI ;e IZhernlcal l-lost 2 1
Chrome Alum ................................. Chromic Acid ................................. Chromium Salts ............................... Cider ......................................... Citpo A.T.F. Type F. Dexron .................... Crroo Citgo Citgo Citgo Cttgo FR Fluids. . . _.. . . . . . . . . . . ._. . . . . . Glycol FFMOXD ......................... Pacemaker .............................. Sentry ................................... Tractor Hyd Fluids ......................
UI 1 1 1 1 1 1 1 2 X 1 1 2 X US 2 2 2 -
Zhemxal 1 1 1 1 1 1 1 1 1 1 1 2 1 2 2 1 1
-c HlOs(
: 2 2 2 2 2 2 1 1 X -
Citric Acid .................................... CoalGas ...................................... CoalTar ...................................... CokeOven Gas ................................ Condor Oils. 1WO. 1002. 1004 ................. 1006.1008. 1010, 1012, 1014. 1016 Copper Chloride ............................... Copper Cyanide ............................... Copper Nitrate ................................. Copper Sulfate ................................. CornOils ......................................
.,
I
I
~tlonaead Oils ................................ Creosote ....................................... Creoaol (Cresylic Acid) ......................... Crude Petroleum Oil ............................ Cyclohexane . . . . . . . . . . . . . . . . . . . _. . . . . . Cyclohexanol
X 1 X
--
1 X :hemicel l-l 1 1
X X
!s -
.................................. Cycloheunone................................. Cymene ........................................
: -
X X -
Daaco. FR160: FR200. FRZOOB. FR310 ........................................ Daaco IFR ...................................... DC 200. 510. 550. 560.. ......................... DDT Weed Killer (DIL.) ......................... Docalm . . . . . . . . . . . . . . . .._.................._... Deionized Water ................................ Decrol R 6 0 Oils .............................. Denatured Alcohol .............................. Datergant Solutions ............................. Developing Solutions ........................... Dexron ......................................... Dextrin ......................................... Dtacetone Alcohol .............................. Diammonium Phosphate ........................
2 2 2 2 2
t
2 1 1 1 2 1
2 ltact Gate:
2 2
1 2 1 1
1 1 2 2
:ontlnued)
276
Corrosion
Resistant
Materials
Handbook
TABLE
1.70:
VARIOUS
THERMOPLASTIC
POLYMERS

HOSE POLYMER TYPES
RUBBER (continued)
CHEMICAL
D-Continued
Drazmon. Drlute ................................ Dlbutyl Phrhalate ............................... ............................... Dtchlorobenzene Drchloroethylene ............................... ..................................... DreselOrl D@thanolamlne (20%) ....................... Dlelhylamtne ................................... Drethyl Ether.. ................................. Drelhyl Glycol .................................. Droctyl Phosphate .............................. Dtoxane ........................................ Dow General Weed Killer (~~0) Dowtherm A ................................... Duro FR-HD., ................................. Duro OrIs ..................................... DP 47. 200 FluId (Dow) 2 X X 2 1 2 1 X 2 2 2 1 2 1 2 1 2 1 X 2 1 2 2 2 1 2 2 1 X 1 1 2 X X X 2 X 1 2 2 1 2
1 X X -
.................
;
X X 2
.........................
E
Enamels.......................................
Energol HL66 .................................. Energol HLPC66 ................................ EP Hydraulrc Orb.. Chevron ...................... Essential Oils ................................... Ethanolamrne .................................. Ethers ......................................... ....................... Ethyl Acetate ........... Ethyl Alcohol (Ethanol) ......................... ithyl Chlorrde.. ................................ EthylEther ....................................
................................ Ilhyl MerCaptan .............. Ethylene Chlorrde ............... Ethylene Chlorohydrin .......................... ilhylene Glycol ................................
1 1
2 2 2 2 X 2 X X X X X
1 1 X 1 1 1 1
1
1 1 1 2 2 1 X 2 X X 1
1 1 -
1 2 2 2 X X X 1
I I )
F
:actovis 52 :atty Acids
.................................... .................................... arrrc Chlorrde ................................. _.............. erric Sultate .................... errous Chloride ............................... errous Nitrate .................................
errous Sulfate .................................
1 1
1 1 1 1 -
1 ) > i 2 2 2
1 1
1 2 1
1
1 1 2 1 1 Use Chemical Hoses No HoseAvailable UseChemical tioaes
............... we Resistant ktyd Fluid (TeXaco) king Solutron (Photo) ......................... ................................. luorborickid luorine Liquid ................................. ._. ......... tuoailicic Acid ....................
ormaldehydc (37%). ........................... ormic Acid .................................... R Fluid D ..................................... R Hydraulic Fluid .............................. FtM ........................................... won (all tym) ................................ _. . _. ............... wit Juices ............... nloil........................................ . ............................ rmaric Acid ...... rran (Furturan). .............................. rrtural (Ant Oil) ............................... ....... ._. rrguard 150, 200. 226 ................. nquel go. 16Q22Q 300. sx). tooo. ............... 16RA0.22oA40.55oR&0.. _
1 -
3 2 2 2
X X X
2 I lha Chemical Hoses 1 1 1 Special Hose Raqurrad 1 1 I I Use Chemical Hosas 2 1 1
1 1
(continued)
Synthetic
Resins and Polymers
277
TABLE 1.70:
VARIOUS
THERMOPLASTIC
POLYMERS

HOSE POLYMER TYPES
RUBBER (continued) II
CHEMICAL
I
I
Use
Contacl
Galllc Ac8d .................................. .......... Gas, Natural .................. Gasoline. Regular Unlealed............... Gasolme, Regular. Leadec ..................... Gasoline. Premium .......................... Gasohol ....................................... Gelatin. ......................................
Chemical Hoses
Gates 1 1 X X
X X
X X X X
Glucose ......................................
Glue .........................................
1 1 1 1 1 1 -
1 1
2
1 1 1 1 1 1 1 1
1 1 1 1 X X
1 1 1 1 1 X X
Glycerine (Glycerol) ........................ Glycol FR Flulds ...............................

Grease....................... Gulf ..................
1 1 1 1 1
FR FluId G-ZOO .......................... t Gult FR Flutd P37. P40. P43. P45. P47 ..........
H
Petroleum) ...................... Heptane ....................................... Hexane .................................... Houghto-Safe 271.416 ......................... 520 526. 616. 620 625 640 Houghto-Safe 5046. 5046W ................... Hy-Chock 011 ................................ Hydra Fluld. AZR (L 0. A. 0. AA. C ............. Hydra FluId 760 ............................... HydraSol A .................................... Hydraultc Hydraulic Hydraulic Hydraulic Hydraulic Flwd FluId Flwd FluId Flutd HF-31 ......................... HF-16. HF-20 ................... (Std Petroleum). ............... (Phosphate Ester) .............. (Waler Glycol) .................
Heptachlor
(m
2 2 2 -
1 1 2 K
1 1
2
X -
2 1 1 1
2 2 2 2 2 1 : 1 2 2 -
1 1 1 1 1 1 1 1 1 1 -
2 2 -
2 2 2 1
Hydra&c FluId (Texaco Safely 200. 300). Hydraulic 011s (Shell) .......................... Hydrazme ..................................... Hydrobromlc Acid ............................. Hydrochloric Acld .............................
.......
: --
Use Chemical Hoses Use Chermcal Hoses Use Chemical Hoses 2 2
Hydrocyamc Acld ............................. Hydro-drme 011.. ............................. ................... Hydrofluoric Acid ........ __. Hydrofluosllicx Acld ........................... Hydrogen .................................... Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Chloride ............................ Fluoride ............................. Peroxide (lo). ...................... Peroxide (Over 10%). ............ Sulhde ..............................
Use Chemical Hoses Use Chemical Hoses Contact Gates
1 _. ..
Use Chemical Hoses
Use Chemical Hoses Contact Gates 2 2 1 1 -
Hydrolubric 011(Houghton) ............ Hydrolube (Water Glycol) ....................... Hypochlorous Acid ..... _. _. .................... I
._... _..
Imd. Imd 5150. 5220.5300. 5500 ................ lnduatron ..................................... .._ ................... Ink. Printers.. ............ lnrulating Oil, Transformer ......................
x 1 1 1 1
1 1 1 1 1 Use LPG Hoaea Only
IklIne ..........................................
Iodine. in Alcohol ............................... lrut Fluid 902 .................................. , .. ., ........ lrusFluid BOS ...................... lrobutane.. ................................... aobutyl Alcohol ................................ ..__....._ ................... soOctane.. ...... __. .................. a0 Ropyl Acetate ......... so Ropyl Alcohol (Iroproprnol) ................ 2
1
2 2
mo PropylEthw ............
., ..................
(continued)
278
Corrosion
Resistant
Materials
Handbook
TABLE 1.70:
VARIOUS
THERMOPLASTIC
POLYMERS
0

HOSE POLYMER TYPES
RUBBER (continued)
CMEYICAL
E -
I-Continued I.50Cyanate
_. _. _. J
_.
(Toluene Of-lsocyanate)
,e,FuelJP-3................................... let Fuel JP-4 _. _. let Fuel JP-5................................... let Fuel let Fuel JP-6 JP-X _. . _.. _. _. .__ .._. ._. _, . . . _. . _. ._._. ( 1
X X X X X
2 2 2
I
I I 1
2 1 1 1 2 1 2 1 2 1 : :
X X X X X
--
ttar0 Syrup ..................................... t(erosene ....................................... t(etones ........................................ L

Solvents ............................... _,.............. L actrc Acld ................... L asso (Ag Spray) ...............................
L ead L ead L ead L ead. L ead. L me L rme L.acquers L acquer .......................................
2 2 -
1 -
X X
X X Use Chemical Hoses 1 2 1 -
1 1 2
1 1 X -
Acetate ................................... Arsenate .................................. Sullate .................................... Telraethyl ................................ Tetramethyl ..............................
...........................................
1 1 1 1 1 1 2 X 2 2 2 -
Bleach .................................... L rme Sulfur ..................................... L mdane (Ag Spray). ........................... L tnseed Cake
L maeed
1 2 2 -
011 (Bolled)
............................
L iqutd Soap .................................... 011s ................................ Llubrlcatmg Llubrtcattng 011s
:
2 X
(Orester)
.......................
M
achrne 011 .................................... M agnestum Carbonate .......................... Chlorrde ............................ U agnesturn U agnesrum Hydroxide ..........................
M
1
: 2 2 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1
2 1 1
1 1 1 Use Chemical Hoses 1 1 1 1 2 1 Use Chemical Hoaea 1 1 1 1
X 1 1 1
1 1
2 1 2 2 2 2 2 -
agneswm NItrate . . . . . . . . . . . . . . .._._. a&3eswm Sulfate ............................. U agnus-Light ................................. ............................... U agnus-Medw'n hl alarhron (Ag. Spray C on C) ...................
U M
1 -
:
2
1 1 : 2 2 1 1 1 X
MImlathion (Ag Spray Dilute). .................... Ml8licAcid ..................................... Ul sngancae Satts ............................... Mlsnganeae Sulfnte ............................. sximut (Hyd. Fluid) ........................... Mc ,yonn.rsc .................................... *Iamine Varnish .............................. Mcwuric Chloride .............................. Mcwcuric Cyanide ............................... wcurous Nitrate .............................. MC Mercury ........................................ Marcury Slttr .................................. Metallic Soaps .................................. Meaityt Oxide .................................. Mathcne ....................................... Methoxychlor
Why1
(Inaectici6a)
. .. . . .. . . . . . . . . . . . . . . . 1
&elate UethylAcrylrt.
WhyI
................................. .................................
Alcohol (h40thW~M) ...................... .............
X
1 -
_I
2
X
2
(continued)
Synthetic
Resins and Polymers
279
TABLE 1.70:
VARIOUS
THERMOPLASTIC
POLYMERS

HOSE POLYMER TYPES
RUBBER (continued)
CHEMICAL
M-Continued
Me!hyl
Methyl Melhyl Methyl Methyl Methyl Methyl Methyl Methyl Methyl
AmIne (60%) ........................... ........................... Amlne (9%) Amy1 Carbmol.. ........................ Bromide ............................... Butyl Ketone (MBK) .................... Cellosolve .............................. Chlonde ............................... Ethyl Ketone (MEK) ..................... Formate ................................ lsobutyl Ketone (MIBK).................
X
X -
2 2 X 2 1 X X X 1 X X 1 1 1 1 1 X 1 Chemical Hoses 1
X X
X X X X -
X X X
X -
X X X X -
I
I I
I
Methyl isopropyl Ketone ....................... Methyl Methacrylate ........................... Methyl Salrcylate .............................. Methyl Sulfate. ................................ Methvlene Chlonde............................
2 1 X
X
1 1 1 2 2 1 X 2 -
X X 1 1 2
X X 1 1 2 2 2 X 2
Methylene Dlchlonde . . Milk ........................................... MIneral 011 .................................... MIneral Spirits ................................. Mobile Hydrauhc Oils .......................... Mobilmet S 122.. . .. .. . . .. . . . Molasses ...................................... Monochlorobenzene ........................... Motor 011s .................................... ................... Munatx Acid (Hydrochlonc)
1 1 1 1 1 X 1 U!
1 2 -
2 2 X 2 -
1 X
(Mustard.......................................
N
Naphtha (Low Aromatic Content)
. .. ........ .
2 / Contact Gates
Naphthalene ................................... Natural Gas ................................... Nickel Acetate ................................. Nickel Chloride ................................ Nickel Nitrate ................................. Nickel Salts ................................... Nickel Platmg Solution ......................... ..:. .................... Nxkel Sulfate ......... Nwzotine ....................................... Niter Cake (Sodium Bisulfatel ................... Nitric Acid . . . . . . .
1 1
: 2 1 1 1 X 1 1 2 2 1 Use Chemical 1 I 1 1
ies 1 1 1 X 1 -
. . . . . . . . . . . . . . . . . . . . . . . .._.
Nitrogen Oxide up to 50% . . . . .._. _.._..
__.
......
~~
2 2
-4
x 1 1 1 1 1 1 1 U 2
Use Chemical t X I 1 1
ms
X
1 -
2 2 Use Chemical F
X X
les
Nyvac20 (WG) 30 (WG) ........................ n-Octane .......................................
Ctctyl Alcohol .................................. Oil (SAE) ...................................... Oil of TurPwttine ............................... Oila. Animal.. .......... ... .... ....... .......
2 1 2 x 2 2 1 1 1 Chemiul 2
1 1 1
_I
X
(continued)
f 1
2 2 X :~ 2 2 2 2 2
280
TABLE
1.70:
VARIOUS
THERMOPLASTIC
POLYMERS

HOSE POLYMER TYPES
RUBBER (contimed)
CHEMICAL
2 1
O-Continued
Hydrauhc Flu&d ......................... (Sd0cate Ester Base) Oxakc Acid .................................... Oxygen ....................................... Ozone ........................................ P Pacemaker Types 15OT. 300T SC0T (Citgo) ................................ Pamt .......................................... Pam1 Solvents (Oil Base). ...................... Pamts (011 Base) .............................. Palm 011 ...................................... Palmmc Acid .................................. Paraffm (Petroleum) ........................... Paralormaldehyde ............................. Peanut 011 ....................................
OS 45
Use ChemcalI
-
2 es
1 -
X -
1 -
Pennant Motor OfIS ............................ Pentachlorophenol m 011. ...................... Pentane ....................................... Perchlortc Acid ................................ Perchloroethylene _. .
.
Use 20BHB C Use Chemrcal t es -
2 -
Pentasol ...................................... Petroleum 011s ................................. Petroleum 011s (Sour). ................. ._. ...... Pelroleum 011s (Refmed) ........................ Phenol (Carbohc Acid). ......................... Phenolates ..................................... Phorone ....................................... Phosphate Esters (to 150F) ..................... Phosphate Esters (above 15oF). ................ Phosphorrc Acid. ............................... Photographrc. Developers ....................... Photographrc. Emulsions ....................... Photographic. Fuung Solutrons .................. Phthahc Acrd ................................... PICNICAcid (Water Solution). .................... RneOil........................................ Pmene ......................................... Prperarme Hydrochlonde Solution
2 2 Use Chemical t 2 Use Chemmal Hoses
Use Chemical Hoses

1
...............
X
0-w
Prtch ........................................... Platmg Solution (Chrome) ...................... Polyester Resin ................................. Polyurethane (to 125F) ......................... Potassium Acetate .............................. Potassium Bromrde ............................. Potassium Bmarbonate . . . . . . . . . . . . . . . . . Use Chemical Hoses 2 2 1 1 1 1 1 1 2 1 1 1 1 1 2 -
.... ...
1 1 1 1 1
Potassium Potassium Potassium Potassium Potassium
Brsulphrte ........................... &ornate ............................. Carbonate ........................... Chlorate ............................ Chromate.. ......................... Chloride ............................. Cuprocyantde ........................
1 1 2 2
.I
Potassium Potasrium Potassium Potarsium Potassium
Ferrocyanlde ......................... Fluoride ............................. (low) ..................... @Mb) ..................... (50%) .....................
.......................... Dichromate
1
1 Uae Chamial Hoses Use Chamical Hoses 1 1 X X 1 1 -
Potarrium Hydroxide Potassium Hydroxide Potassium Hydroxide
Potasswm Iodide Potassium Nttrate Potassium Potassium Potassium Potassium Potassium
.............................. ...............................
Permanganate ....................... Permanganate (5%) ................. Panuttate. .......................... Phosphate ........................... Sulfate ..............................
(continued)
Synthetic
Resins and Polymers
281
TABLE 1.70:
VARIOUS
THERMOPLASTIC
POLYMERS

HOSE POLYMER TYPES t
RUBBER (continued)
u 0 , , , , I
CHEMICAL
p-continued
potassium Sulhde .............................. p0ta~sw-n Sulfite ...............................
potassr~rh Throsullate .......................... ....... Powerlube (Carter) ..................... :Prrmatol A. S. P (Agrrc Spray). ..................
: : -
1; / z
Use 2OBHB Only u! se Chemical Hoses 1 2 2 : 1 2 X 2 1 X 2 X 2 X X 2 1 2 1 1 1 1 2 1 1 X X 1 1 -
2 -
propane Gas
................................... P,op,onrc Acrd ................................. Propyl Acetate ................................. Propyl Alcohol (PrOpanOl) ...................... Propylene Glycol ...............................
2 -
1 2 2 1 2 1 2 X 2 1 X 2 2 1 1 1 2 1 1 1 1 1 1 1
2 2 2 2 2 X 2 2 ;
Purrna Insectrcrcte .................... Puropale RX 011s ............................... Pydraul F-9 ..................................... Pydraul SCIE .................................... Pydraul150 .................................... Pvdraul Pydraul Pydraul Pydraul Pydraul A-200 _. 260 _, _. _. 312 _.. 540 __. _. 625 _. _. _.
.........
2 X X
,
( ( ( ( ( ( ( ( ( > (
_._.
_.
_.
_. _.
_._. _.
_. _.
. _, _. _._. _._. ._. _.

.._.
X X X X X X X 1 X 2 2 2 2 2 1 2 2 2 2 2 1 2 X 1 1 1 1 1 1 1 1 1 1 1 1 1
Pydraul 10E 23E LT. 30E. 65E ll-SE.. Pydraul. 135.. ._. __. ..__.___. Pyrene (Carbon Telrachlorrde) Pyrethrum...................................... Pyrrdrne (50%). _. _. _. _._. _.
_._._. _. _. _. _.
1 1 2 2 -
Pvrooard 51. 53 55.. .._.___. _. F+ogard 160 230 630 .......................... PyrogardC.0 .................................. Pyronal (Transtormer 011) ....................... Ramrod (Ag Spray) ............................ RandoOrls .................................... Rape Seed 011. ................................. Red 011 (Comm Olerc Acrd). .................... Retrned Wax (Petroleum). ...................... Regal 011s (R 6 0). ............................. Rrtchlreld A Weed Keller ....................... Rosm (Lrghl) ................................... Rubrlene 011s.. .................................
1 1 1 -
2 2 2 1 2 2 2 2 1 1 1 2 X 1 1 1 2 1 1 1
jafetytex 215
...........
........................
jalrcylrc Acrd ................................... jail Water (Sea Water). ......................... jantosafe W-Gl5. W-G20. W-G30 ............... jauerkraut ..................................... ;CC 7204 (Strutter) ............................ ievin .......................................... *wage.. ...................................... ;FR Flurd B (Shell) ............................. ;FR Fluid C (Shell) ............................ ihellac ......................................... iiticone Grease ................................. iilicone OrIs ................................... iilw! Cyanide .................................. iilwr Nitrate ................................... ikydrol 500 A.1 7OW.. ......................... hap Solutrons ................................. ada Ash (Sodium Carbonate) ................. 0da Water ..................................... odrum Acetate
: 1 1 1 1 1 1 1 1 1 1 1 1 1 1
: 2 2 1 1 1
: 1 1 1 1 1 1 1 1 1 1 1 1
................................ odwm Benzoate. ..............................
1 1 1 1
2 1 1 1 1 1 1 1 1
odrum Btcarbonate ............................ odrum Brsultate (Nrter Cdke) ................... odwmBrsulfrte ................................
_A
: 1 1
,
continued)
282
Corrosion Resistant Materials Handbook 1.70: VARIOUS THERMOPLASTIC POLYMERS FOR HOSE STOCKS-GATES
HOSE POLYMER TYPES CHEMICAL G I z ! Y I t I U I a
TABLE
RUBBER (continued)
S-Continued
Sodmum
Sodrum Sodium Sodrum Sodjum

Sod!um
............................ D,ch,o;ate Ferr8cyanrde ......................... Ferrocyanide .......................... Fluorrde (70%). ......................... Hydrosulfrde ........................... ............................ HydroSUlflle Hydroxrde Hydroxide Hydroxrde Hydroxrde (10%). ...................... (40%). ...................... (50% 115F). ................ (50% 160F). ................
Use Use Use Use
2 2 2 -
CheTrcal Chemical Chemrcal Chemrcal 1 + + k

ES ES es
Sodrum Sodiwn Sodrum Sodrum
es
ES
Sodun Hydrorrde (60%) ....................... Sodtun Hypochlonte (5%) .....................

jodjum HypochlOrlte (20%) ..................... Sodwm HypoSuffate ............................
..... Sodlurn Metaphosphate ._.................. ................................. Sodaurn Ndrate

jodrum jodrum Sodrum jodrum
So&urn
Use Chemrcaf 1 2 1
1 -
1 -
X X -
Perborate .............................. Peroxrde ............................... Phosphates. ........................... .jrlrcate .................................

!julfde
1 1 1 1 1 1 1 -
1 1 1 1 1 1 1 1 1 1 1 2 1 1 1 1 1 1
1 1 1
................................ ................................ Sod#m !&lflle ................................. Sochum Throsulfate (HPO) ..................... jodrum Trrpolyphosphate (STPP) ............... Solns011s ..................................... Solvac 1535 G ..................................
jodrum Sulfate
.............................. Slannous Chlorrde

jtanorl Starch jtaysol jtearrc jtearin No 15. 16. 25, 31. 35. 51 ................ ......................................... FR ..................................... Acrd ............................ ........................................
joybean DIG.................................... jtannrc Chlorrde. ..............................
....... 2 1
jtoddard Solvent ............................... jtrarght Synlheuc OrIs ....................... (phosphate ester. phosphate ester base ) jtyrene (Monomer) ............................ ................. julfamrc Acrd ............... julfate Liquors ................................. jurfur (2OO%F) ................................. julfur Chlorrde ................................. julfur Droxrde (Dry) ............................
__
X 1 Use Chemrcaf k Use Chemrcal HOSeS
1 2 1 X X 2 1 Use Chemical Hoses 2 2 2 2 2 x 2 2 1 Chemtcal 1 1 1 I 1 1 1 1
julfur Droxrde (Lrqurd). ......................... jullur Dfoxrde (Moist) .......................... _. ., julfur Hexaflounde (Gas) ................ julfur Trroxfde (Dry). .............................. julfurlc Acid ...................................
sses
untac WR Oils
.................................
..................... unvisOils (700.6@3.900) uper Hydraulic Oils ........................... 33 Fluid (ConooO) ............................. ynthetic oil (Citgo). ........................... T allOil ......................................... IIIOW ......................................... uvrrc Acid (10%) .............................. u (Bituminous) ............................... vOrl......................................... rrlaric Acid.. ................................. dlus Oils ..................................... rnol Oil8 ...................................... *pinwl ......................................
2 1 2 2
Synthetic
Resins and Polymers
283
TABLE 1.70:
VARIOUS
THERMOPLASTIC
POLYMERS
0

HOSE POLYMER TYPES 2 1 2 : 1 1 2 2 I Use Chemical Hoses Use Chemical 2 v E
RUBBER (continued)
U c
Terresstlc .............................. Telraethyllead (TEL). ................... TefrahydrOfurNl (THF). ................. Tetralm ................................ Th,open ................................ Toluene (Toluol).. Toluene Dllsocyanate.. Transformer 011 (Petroleum Type) Transformer 011 (Askarel Types). Transmission FluId (Type A) Trlbutoxyethyl Phosphate.. Trlbutyl Phosphate Trtchloroethylene.. _. . Trlcresyl Phosphate (Skydrol) Tne:banolamine ITEA)
T-Continued
2 2 -
X
X X
I
i
. . _.. _. _. . _, _, . . . _. _._. . . . . . . ._ _. _._. ._.
. .
._ .
1 I
-i-
2 -
Hoses
I i
2 -
I r
Use Chemical Hoses
Tnpolyphosphate (STPP) ....................... Tung 011 ....................................... Turpentme ..................................... Tycol Avalon 50. 51. 60 ......................... Tycol A Turblo 37. 50. 58. 60 ....................
t
: 2
Ucon MI ....................................... Ucon Hydrolube Types 15OCP. 2DOCP. 275CP. 3OOCP. 550CP. 900CP. 150DB. 275DB. 150LT. POOLT. 275LT. 300LT. 2OONM. 300NM Umon Union Unton Union Union C-2 Flwd ................................ C-P 011 .................................. ATF Dexron ............................. ATF Type F .............................. Hydraulic Oil AW .........................
...
2 2
2 2 2 2 2 2 2
Umon Hydrauhc Tractor Flwd ................... Urea Solubon .................................
2 2 1 Vmyl Acetate. .................................. Vmyl Chloride (Monomer). ...................... Vltrea Oils ...................................... X 2
2 2 1 -
A?(:hemlcal Hcse
Water .......................................... Water (Potable) ................................ Water(Brine) ................................... Water (Demineralized) ......................... (Distilled) ................................ Glycols ................................. in Oil Emulsions .......................... 6 Bagley No. 2190 Cutting Oil ............. Oil .......................................
1 1 1 ntact Gate 1 1 1 1 1 1 : 1
I
I I
Water Water Water White Wood
X
(XyW) .. .. .. .. . .. . ... ... . . . ... . ... ... . . X
xykme
z
2 : 1
zenc ........................................... ZmcAcetsle...................................

Zinc Chloride Solutions ........................ Zmc Hvdrate ...................................
Zmc Oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Zinc Sulfate Solutions . . . . . . . . . . . . . . . . . . . . . . . . .

FDA Hoses Rwuired
: 2
Rubbers and Elastomers
TABLE
2.1:
ACRYLIC
ELASTOMER-AMERICAN
CYANAMID
CYANACRYL is especially noted for its ability to withstand most lubricating oils at 350F (176C). including those sulfur modified lubricants, essential in the performance of hot running modern cars. Other petroleum based oils, such as high and low aniline point lubricating aliphatic hydrocarbons offer opportunities for outstanding performance by CYANACRYL. Resistance to chlorinated hydrocarbons, degreasers, LP gases, fuel oils, animal and vegetable oils and silicate esters is very good. Aromatic hydrocarbons, such as toluol, have some moderate to severe effects but ketones, some alcohols and oxgenated solvents can cause severe swelling. Nonpetroleum based brake fluid, phosphate ester, and diester synthetic lubricants can have a severe effect so CYANACRYL should be tested in these environments before using. CYANACRYL shows fair resistance to dilute and concentrated acids and bases. Therefore, caution or a test first method is suggested when considering it for this type of application. Fluid Fluid Ethyl Acetate Amyl Acetate MEK Varsol Toluene Kerosene Naphtha Acetone Trichlorethylene Perchlorethylene Reference Fuel A Reference Fuel B Reference Fuel C Leaded gasoline Lead free gasoline Water Freon # 12 # 2 Diesel Fuel Silicone Fluids Ethylene glycol Elco # 28 Oil (SAE 140) Texaco TL 3450 (ATF) Wheel Bearing Grease Regular SAE # 20 Oil Premium SAE # 20 Oil Premium 1OW - 30 Oil Premium Outboard Motor ATF - Type A ATF - Type C Hydraulic Fluid Mil O-6081 Hytran Tractor Fluid ATF Chrysler MS4228 Anti-Freeze Lubrizol G L-5 (SAE 140) Jet II Hydrocarbon Fluid NOTE: Resistance Data for CYANACRYL Acrylic 212F(1000C) 7 hrs I1 wk 2wks Elastomer (Volume Change, %)
Room Temo. 24 hrs 118
250F(1210C) 70
1wk
;
i
--
lwk
193
110 1.8 !12 0.85; 5.9
I I
I I I f I 1
I I 1 1 I I
I
Ii
167 3.3 45 80 28 332
I 1
f ;7 to 14 27
I I
I I
26 10 12 1 1.2 1.2 2.0 2.3 0.5
I 8.0 21.9
)o to -5.1
I I 1 I I
Oi
I I I
I I I I
1.5 1.7
1 2:; ; 1 3.0 I I ! I 1
3.0 2.0
-1.5 I I 13.0 8.6 6.7 28 75
All values in this tab le i Ire (+) unless ot
Rubbers
and Elastomers
285
TABLE
2.2:
FLUOROELASTOMER-ELKHART
RUBBER
In many applications, AFLAS outperforms other elastomers because of the following characteristics: (1) High temperature resistance (400F long term; 55O+F shorter term); (2) Resistance to a wide range of chemicals (including acids, bases, steam, sour (H2S) oil and gas with amine corrosion inhibitors, oils and lubricants, hydraulic fluids of all types, brake fluids, bleaches, oxidizing agents, alcohol, etc.); (3) Durable physical properties; (4) Excellent electrical resistance-Dielectric constant at 60 Hz of 2.5. There are three grades of AFLAS. All provide essentially the same heat and chemical resistance but they differ in molecular weight (which can affect processing and physical properties). AFLAS 150E is the lowest molecularweight, AFLAS 150P is intermediate weight, and AFLAS IOOH is the highest molecular weight. AFLAS 100H is generally recommended for optimal extrusion, gas blistering, and compression set resistance. The following chart provides an indication of the chemical resistance of AFLAS. Since temperature, concentrations, mixtures, and elastomer compound selection can affect performance, this chart provides guidelines only. Unless otherwise noted, the tests were run on a 75 Shore A carbon black filled AFLAS 150P formulation with the following properties:
Orlglnal Pro~wtl*r of le.1 Formulation Shon A Hardness 75 Tensile Strength (pal) 2500 Elongation @ Break 120%
Where available, the chart shows the change in hardness (in Shore A points) and volume as well as the percentage of original tensile strength and elongation retained after immersion in the test fluid under the time and temperature conditions denoted. In other instances, volume change only is shown.
MEDIA
Adds .............................................................
RESISTANCE
OUIDELINES Amlnes ................................................. G to E 011s and Lubricants (Incl. synthetics. SF CD, etc.) .................................. G to E OXidlZlnQAQenlS ................................. G to E Sour (H2S) 011 and Gas with Conoslon lnhlbltors .................... G to E Benzene, Xylene, etc. .......................... F to G Fuels ..................................................... F to G Ketones ........................................................ F Chloroform ................................................... P F - Falr P - Poor
E Animal and VeQetable Oils ......................... E Bases ............................................................ E Brake Fluids ................................................. E Hydraulic Flulds (lncl. phosphate esters, Mil-H-5806, water/Qlycol, etc.) ........ E BteamrWaterlBrine ...................................... E Radiation ...................................................... E WeatherlnQ/Ozone ....................................... E Alcohol ................................................. G to E E. Excellent
G. Good
CHEMICAL
Test Condition
Property Retention After Test
CHEMICAL
Test Condition
rime lays
Property Retention After Test
AcetIc Acid Acetrc acrd/lO% Sodium chlonte Acetone Acetyl acetone Aeroshell Grease 67 Amrne Corroston lnhrbrtors (see Oilfield Media) Ammonia (28%) Ammonium (28%) hydroxide
73 212 73 73 176
7
1
1.0
!4.0 io.0 i4.0
ASTM Oil 13 Benzene Benzene/Methanol Bl~;;~nq, Bromine
212 350 73 3: 212 73
3 3 7 3 7 7 89 36
7.9 i3.0
Il.0 12.0 !l.O 0.0 6.2
7 3 2
8.0
30/X 501% powder 10%
158 73 7 180 3 7 Z
3.2 1 .o 1.0 2.5 3.2 .7 1.8 4.1
Aniline ASTM Oil I1
;: 158 73 212 350
Bromine 32%/ Hydrochlonc acid 1B%/Sulfunc acrd 25 % Calcium hypochlorite 10 % Caproic acid Carbon tetrachloride Castro1 325
212 212 73 73 176
1 7 7 7 2
6.0 0 6.8 16.0 6.0
(continued)
286
Corrosion
Resistant
Materials
Handbook
TABLE 2.2:
FLUOROELASTOMER-ELKHART
RUBBER (continued)
Test Condition Property Retention After Test
-CHEMICAL
Test Condition
Property Retentron After Test
CHEMICAL
Chlorine solution (saturated) Chlorine solution (Sat.), 35% Sodium chlonde 10% Sodium hypochlonte Chloroform Chromrc acid (62%) Chromic acid (46%)/ Sulfurtc acid (25%) Cyclohexane Cyclohexanone Diesel Fuel #2 95 Shore A Compcurw Diethyl ether D~octyl Cebacate Dloxane Dowtherm 209 Ethyl acetate Ethyl benzene Ethyl benzoate Ethylene Chlorohydrrn Ethylene glycolMlater/ Nalcool 2000 50/5C 4 oz. per gallon Exxon Caloria HT43 Freon TF Fuel B Gasoline Hydrochloric acid (37%
Nitric acid (20%) Nitrobenzene OILFIELD MEDIA Amine corrosion inhibitors (mtnerallblack filled compound) 1 % KW44 in water 10% KW44 in water 1% NACE A In water Sour gas, wet (35% H2S. 50% CH,, 15% COz. 10 ml Hd)) Sour oil. wet with 5% NICE B corrosion Inhibitor (47.5% ASTM %l oil. 47.5% HzQ, 5% NACE 6: Mixed gas 35% HzS 15% COz. 50% CHI under pressure) Skydrol 500 Skydrol 5008 Skydrol 500 84 Sodium chloride (35%)/ Sodium hypochlorite (10%) Saturated chlonne solution Sodium chlorite (10%) Sodium hydroxrde 50% Sodium hydroxide 20% 2:: Sodium hypochlorite (10 % ) Sour (HzS) gas and oil (See Oilfield Media) Stauffer 7700 Steam (93 Shore A cmpd) 212 7
212 73 73 73 73 73 212 302 73 212 350 73 212 73 73 73 73
2.5 7 7 7 7 7 ; 1 3 3 3 3 7 7 7 7
69 90
15
78 98 117
-9 -2 -1
5.9 12.0 1.7 2.6 13.0 22.0 9.0 29.2 42.0 8.8 20.0 57 0 6.3 88.0 22.0 26.7 0.0
NOTE Afhs rerrared
73 7 I I I 5fi I I
etastcmenc and dzl not
212 212 324 400
9c
i
14 4
2
66 40
150 144 194 86
-1
-4 -4
;.i
77 3.0
-3
75 70
103 121
-18 -5
350
111
-15
8.6
176 212 176
2 3 2
14.6 14.0 17.2
100 HI 15OP blend comoound
324 500 73 73 73 73 158 158 3: 212 73 73 73 185 73 73 320 392 73 73 73 73 212 212 400 400 73 73 73 73 73 5: 158
14 4
106 50
SOIVC
I 7 7 7
180 3 3 7 180 7 7 7 7 3 7 7 11 11 7 7 7 7 3 3 3 3 7 7 7 I80 30 7 I80 3
106 +; 164 -E \flas 15OP
1.1 11.0 58.0 25.0 .2 4.5 7.0 7.4 1.5 4.1 -1.1 0.0 19.0 2.0 .4 53.3 5.0 -0.3 -0.3 0.2 1.4 25.0 58.0 12.0 6.0 8.4 10.1 24.0 4.0 19.0 15.0 21.0 0.0 5.1 IO.0
212 212 2:;
100 57 58 63 105
107 112 85 117 99
-1 -2 -6 +1 c
Hydrochloric Hydrofluoric
acid (20% acid (50%
69 80 108 101 85 95 too
78 93 116 116 104 117 95
-9 -12 +2 -1 1; -1
5.9 22.0 1.2 1.1 -0.3 2.0 1.0
Hydrogen peroxide (30% lsoamyl alcohol Iso-Octane Kerosene KFlHF (111.8) Lacquer thinner Light oil Lithium Bromrde (58%) Lithium chromate Methyl alcohol Methyl cellosolve Methyl chloroform Methyl ether ketone Mil-H-5606 Mil-L-7808 Mobil 1 5W-30 Mobil Super lOW-40 n .hexane Naphtha Nitiic acid fuming Nitric acrd (98%) Nitric acid (60%)
94
111
03
106 99
106 1lC
+1 +1
Sulfur dioxide (5%) Sulfuric acid fuming Sulfunc acrd (96%)
350 320 392 392 550 104 73 73 73 2:;
3 7 ;:
4
80 91 ;z 65 69 76 98 99 :; 02 99
2 7 180 7 I80 3 : ; 7 7 7 3 3 7
obtained
120 84 97 100 145 84 98 99 101 98 104 105 98
-10 -3 :: -1 .4 -2 -3 -3 -1 fl 1;
Sulfunc Sulfunc
acid (60%) 2:; acrd (20%) 2:: 73 73 73 300 212 73
82 84
111 107
-6 -6
42
126
Toluene Tnchloroethylene Tnchlorotrlfluoroethane Wagner 218 brake fluid Water Xylene

l
87 89
from
120 117
-8 0
18.0 4.6 16 1.3 1.6 78 4.2 7.4 0.4 2.3 4.4 0.1 0.4 0.5 04 41.0 95.0 49.0 9.0 1 1 30 0
rho
above
94 44
95 107
publlshbd
/nfot?muo/l was technical literature.
TABLE 2.3:
FL,D RESISTANCE
FLUOROSILICONE
OF SILASTIC
RUBBERS-DOW
RUBBER
CORNING
FLUID RESISTANCE OF SILASTIC LS-70 FLUOROSILICONE RUBBER
LS-S3U FLUOROSILICONE
Nu,ds ASTM Reference Fuel B 1 1 4 1 1 4 1 1 1 1 1
lmmersron Condrtrons day/23 C (73 F) we&f23 C (73 F, weeks/23 C (73 F, day123 C (73 F, week/23 C (73 F) weeks123 C (73 F, day/&flux day123 C (73 F, week/23 C (73 F, day123 C (73 F, week/23 C (73 F,
Durometer. Pants Change -9 -9 -6

-10
TenSlIe srrengm Percent Change 42 -37 -39 -43 -36 36 -42 57 -57 -IQ 46 0 -30 -35 -9 -7 -13 -33 -70 -90
Elongation, PWCet Change -36 -36 -36 -36 36 -36 -44 -49 -36 -31 -33 -3 -5 -
tWlJIe s we//, PerCef Change +22 l22 +22 +25 +25 l25 +29 +26 +25 +23 +22 0 +4 +12 +6 +7 +tO +13 +6 +2a
TeSh?
Volume
Flwds ASTM Reference Fuel B 1 1 4 1 1 4 1 1 1 1 1 1 1
ImmerS!on Cond!trons day1123 C 173 F, week/23 C (73 F) weeks/23 C (73 F) day/23 C (73 F, week123 C 173 F) weeks123 C(73 i) day/Reflux day/23 C (73 F, week/23 C (73 FJ day123 C (73 F, week/23 C (73 F, day123 C (73 F, week123 C (73 F,
Duromefer. POllS Change -12 -12 -10 -10 -13 -15 -10 -19 -17 -16 -15 -5 -4
Strength. Percent Change -12 -13 -16 -16 -16 -20 -29 -42 -41 -37 -35 -4 -2
Elongarion. PerCent Change -10 -10 -14 -14 -14 -19 -33 -33 -19 -19 -14 -0 110
SbVe11. Parren,
_ __
+17 +17 lla 117 -30
I=
Change
ASTM
Reference
Fuel C
_.
ASTM Reference
Fuel C
10% Methanol/SO% 10% Ethanol,90% ASTM NO 1 Oil ASTM No 3 Oil Jet Fuel. JP-l Jet Fuel, JP-6 _.
No-Lead No-Lead
Gas Gas..
_. ._.... .................... ......................

_. _.
MIL-H-5606 (PO4226). MIL-L-7806F (Brayco 660 G, DI-P-ethylhexyl sebacate with 0.5% phenothwlne Skydrolt 5OOA.. _, _. _.
70 hrdl50 C (302 F) 70 hrs/lSO C (302 F) 70 hrs123 C (73 FI 1 day123 C (;3 F; 1 week123 C (73 F, 70 hrs1135 C (275 F, 70 hrs/150 C (302 F) 46 hrs/l50 C (302 F) 70 hrs1121 C (250 F)
-11 -6 -11 -12 -13 -11 -11 4 -6 -5 -7 -7 -7 -14 -7 -26
10% Methanol/SO% 1wb Ethanol/SO% Jet Fuel. JP-6
No-Lead No-Lead _.
Gas Gas.. _.
+20 +27 +22 +21 +16 +17 +3 +5 C
Obtained by add,9 1 0 phr arox to SILASTIC LS-70 l~~r~~~l~c~ne rubber Slabs 0 075 mch truck were press cured 10 m,~?,, (340 F, and post cured 4 hrsQc0 C ,392 F) prmr to testmg
*Obtam& by addIn phr Varox to SfLASTlC LS-53 fluorosillcone rubber Slabs 0 075 inch tluck were press cured 10 mm,,71 C (340 F) and post cured 4 hrs/2@3 C (392 FJ war to testw +Skydro, IS B rqstered trademark 01 Monsanto lndustrlal Chemu.1 Company FLUlD FLUID RESISTANCE OF SILASTIC LS-SSU FLUORDSILICONE RUBBER TenslIe Sfrengfh. PerCef Change -17 -21 -17 -23 -27 -20 -23 -47 49 -37 -37 -3 -27 -25 -6 -13 +5 -25 -22 VOlUl.9 SW/l, Percent Change +16 +20 +20 +22 +22 +22 +27 +2.3 +26 +22 +21 l1 +4 +10 +4 +5 +7 +10 +16 10 ml/171 C Duromefer. POllS Change -17 -15 -16 -16 -16 -15 -16 -23 -20 -16 -17 -1 -62 -10 -6 -9 -6 -19 -12 TenSlIe Strength. Percent Change -29 -29 -29 -33 -40 -37 -53 -63 -54 -54 -45 -0 -26 -9 -6 -6 -11 -60 -14 Elongarron. Percent Change -19 -19 -19 -20 -20 -20 -41 -37 -24 -30 -20 -2 -22 -0 -0 -7 -11 -22 -16 Volume SbWll. Percent Change 4-Z .e +t4 +15 +17 +16 +15 20 +26 20 +19 +14 +0 +3 +6 +3 +4 9 +12 6 RESISTANCE OF SILASTIC LS-2249U FLUOROSILICONE RUBBER
1 .O
Fluids ASTM Reference Fuel B _. 1 1 4 1 1 4 1 1 1
lmmersron Conddrons day/23 C (73 F, week123 C (73 F, weeks123 C (73 F, day/23 C (73 F, week/23 C (73 F, weeks123 C (73 F, day/Reflux day/23 C (73 F) week/23 C 173 F,
Duromefer, PO!tS Change -14 -13 -14 -16 -16 -13 -14 -19 -19 -16 -16 +1 -4 -6 -9 -9 -7 -10 -15
Elogeflon, PWCL?f Change -10 -13 -13 -16 -19 -16 -33 -35 -26 -19 -16 -10 -13 -20 a d -10 -25 -7
Flurds ASTM Reference Fuel B
,lmerS,O Condrfrons 1 day123 C (73 F1 1 v&k/23 d (73 k) 4 weeks123 C (73 F, 1 day/23 C (73 F) 1 week/23 C (73 F, 4 weeks123 C (73 F, 1 day/Reflux 1 day/23 C (73 F, 1 week/23 C (73 F, 1 day123 C (73 F) 1 week123 C (73 F, 70 h&l50 C (302 F) 70 hrs/lbO C (302 F, 70 hrs/23 C (73 F, 1 day123 C (73 F, 1 week/23 C (73 F, 70 ha1135 C (275 F) 70 hrz.1177 C (350 F) 46 hrs/l50 C (302 F)
ASTM
Reference
Fuel C
ASTM
Reference
Fuel C
10% Methanol/W% 10% Ethanol/SO% ASTM NO 1 Oil ASTM No 3 011 Jet Fuel, JP-4 Jet Fuel. JP-6
No-Lead No-Lead
Gas Gas..
b w a m $ h s 8 3 3
10% Methanol/90% 10% Ethanol/90%
No-Lead ND-Lead
Gas Gas..
ASTM NO. 1 Oil ASTM NO 3 Oil .,_., Jet Fuel, JP4 Jet Fuel. JP-6 _.
,_. _. _, _. _. _. _. _.
Jet 1,.
_._.
MIL-H-5606 (PO4226). MIL-L-7606G (Stauffer Skydrolt 500A..
_. _. _.
1 day/23 C (73 F) 1 week/23 C (73 F) 70 hrs/150 C (302 F) 70 hrs/l50 C (302 F) 70 h&23 C (73 F, 1 day123 C (73 F) 1 week/23 C (73 F, 70 h&135 C (275 F, 70 hrsIl50 C (302 F, 70 hrs/70 C (1% F,
_.
_.
_.
MIL-H-5= (Unwist J-43) MIL-L-7606 (Turbo 011 NO 15) DI-?-ethylhexyl sebacate wth 0.5% phenoth,az,e
*Dbta,ned by .,,.,in~ , 0 p,,, ,,ror (0 SILASTIC LS-SW ,,orosll,coe rubber Slabs 0 075 I& (340 F) ,nd port cured 4 hn/2OO C (392 F) prior to test!9 +Skydrol II a rq,s,ered trademark 01 Monsanto ldstrlal Chem,cals Compr~
thick IOre press curti
Ob,a,ned by add,9 1 0 phr arox to SILASTIC LS-2249 luoros~lwzonerubber Slabs0075 &ch thuck were presscured 10 ma/171 C (340 F, and post cured 4 hrsQc0 c (392 F) pnor to test!9 +Unws IS B reg,stered trademark of Humble 011and R&m9 Company
h>
(continued)
TABLE 2.3:
FLUID RESISTANCE
FLUOROSILICONE
OF SILASTIC LS-2311U
RUBBERS-DOW
FLUOROSILICONE RUBBER
CORNING
(continued)
FLUID RESISTANCE OF SILASTIC LS-2332U FLUOROSILICONE RUBBER
Duromerer,
FluIds ASTM Reference Fuel B Immersmn Codr,roS 1 day123 C (73 Fl 1 we&23 d (73 F) 4 weeku23 C (73 F) 1 day123 C (73 F) 1 week/23 C (73 F) 4 weekJ/23 C (73 F) 1 day/Reflux 1 d&23 C (73 F) 1 weeW23 C (73 F) 1 day123 C (73 F) 1 we&V23 C (73 F) 70 h&l50 C (302 F) 70 hrdl50 C (302 F) 70 h&23 C (73 F) 1 dav123 C 173 F) 1 we&/23 d (73 F) 70 hn/l37 C (275 F) 70 hrs/l77 C (350 F) 46 hrsl50 70 hrsIl21 C (302 F) C (250 F) POllS Change -12 -11 -9 -12 -13 -10 -15 -15 -17 -12 -13 -2 -2 -10 -4 -7 -5 -6 -5 -39
TenslIe svengm Percent Change -14 -14 -16 -15 -17 -15 -15 -40 -45 -31 -29 +2 +5 -10 -10 -13 +10 -9 +4 -74
Elongation. PBICBf Change -7 -14 -21 -7 -0 -14 -7 -29 -29 -0 -0 -6 -17 -17 +7 +7 -17 -17 -6 -17
Volume SWII, Percent Change +14 l14 114 +17 +17 +17 +20 20 +20 +16 +17 +1 +3 +7 +2 +3 +7 +7 +6 17
Fluds ASTM Reference Fuel B
lmmersmn Cod,hos 1 day23 C (73 F) 1 week123 C (73 F) 4 weeks/23 C (73 F) 1 day123 C (73 F) 1 week23 C (73 F) 4 weeks/23 C (73 F) 1 day:Reflux 1 day/23 C (73 F) 1 weeW23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70hrs/l50C(302F) 70 h&l50 C 1302 F1 70 h&23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 h&57 C (135 F) 70 hrsI150 C (302 F) 46 h&150 C (302 F)
Duromerer. Pomts Change -19 -19 -16 -21 -20 -20 -22 -23 -26 -21 -21 -0 a -6 -6 -11 4 -12 -1
TeS,le Svenglh PerCef Change -3 -2 -1 -3 4 -4 -33 -27 -29 -10 -10 _ -0 -2 -
Elongarro. percent Change -2 -2 -6 -2 d -2 -22 -11 -3 -2 -5 _ l5 +3 _ -
Volume SbVe,, P.YCet Change +17 +17 +17 +19 +16 16 +25 +21 +20 +17 +16 +0 +4 110 3 l4 +a +6 +Q
3 a 3
ASTM Reference Fuel C
_.
ASTM Reletence
Fuel C
2 _. x s
10% Methanol/W%
No-Lead Gas
10% Methanol/QO% No-Lead Gas 10% Ethanol/W% ASTMNo 1011 ASTM No 3 011 Jet Fuel. JP-t Jet Fuel. JP-6 No-Lead Gas
10% Ethanol/SO% No-Lead Gas.. ASTM NO. 1 011 ASTM NO 3 011 Jet Fuel. JP4 Jet Fuel. JP-6 ......................
5 s G > x 3 g 8 h
_. _._. ...................... _. _.
._ _._. _.
_. _. _.
MIL-H-5606 (Un,v,s+ J43) MIL-H-7606 (Turbo Oil No. 15) DI-P-ethylhexyl SebaCBte wth 0.5% phenothoazlne Skydrol SOOA
MIL-H-5606 (Unwist J-43) MIL-L-7606 (Turbo 011 NO 15) CV-2-ethylhexyl sebacate wth 0.5% phenothiazme
Obtmmd by add,9 1 0 ph, arox 10 SILASTIC LS-2311 ,,~r~s~l~c~e rubber Slabs 0 075 mch thick were press cured 10 rnIl171 C (340 F) and post CURCI4 hW?w c (392 F) pnclr to teStIn +Unw~r I) a repwwd trademark ot Humble 011and Refmmg Company Skydrol 1sa rsp~rteredtrademark 01 Monsanto lndusinal Chemicals Company FLUID RESISTANCE OF SILASTIC LS-2323 FLUOROSILICONE BASE
Obtafned by addq t 0 phr a,.. to SILASTIC LS-2332 l~r~~~i~c~nerubber Slabs 0 075 mch thxk were press cured IO mm/l71 C ,340 F) and post cured 4 hrsr200 C (392 F) prior to tesl,nQ +nws IS a regfrtered traclemark01 Humble 011and R&lQ Company
FLUID RESISTANCE
OF SILASTIC
LS-23SOU FLUOROSILICONE
RUBBER
Fluids ASTM Reference Fuel B
lmmersron Cond!tions
Duromeler. Points Chanoe
TeSlle Strength. Percenl Chanoe -14 -14 -16 -15 -17 -15 -15 -40 -45 -31 -29 +2 +5 -10 -10 -13 +10 -9
ElOWfl0. percent Chanoe -7 -14 -21 -7
Volume Swell. Percent Change +14 +14 +14 117 +17 +17 +20 +20 20 +I6 +17 +I +3 +7 +2 +3 +7 +7 +6 +7
Flurds ASTM Reference Fuel B
,mrerSiO Condlbons 1 day123 C (73 F) 1 week123 C (73 F) 4 weeks123 C (73 F) 1 day123 C (73 F) 1 week/23 C (73 F) 4 weeks/23 C (73 F) 1 day/Reflux 1 day/23 C (73 F) 1 week123 C (73 F) 1 day123 C (73 F) 1 week/23 C (73 F) 70 hrs/l50 C (302 F) 70 hrs/l50 C (302 F) 70 hrs/23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 h&150 C (302 F) 70 hrs/l50 C (302 F) 70 hrs/150 C (302 F) 70 h&150 C (302 F) 70 hrsi135 C (275 F)
Duometer. POifS Chanoe -11 -10 -9 -11 -11 -10 -12 -14 -15 -11 -10 +1 -1 -7 -6 -6 -7 -6 -9 +1 4
TeS!le SWenglh. percent Chanoe -16 -16 -14 -23 -22 -16 -26 46 -59 -37 -37 -1 -16 -14 +2 +1 -16 -29 -39 4 -26
Elongation, percent Chanoe -16 -16 -24 -24 -16 -24 -29 -41 41 -16 -16 +I6 -13 -9 -6 -0 -17 -25 -29 -21 -29
Volume .%e/i. Percent C.k3noe +15 +15 +14 +17 rlR +17 +21 +21 +19 +12 +15 +I +4 l7 +3 I? +I3 +a 9 +I +6
_.
10% Methanol/SO% No-Lead Gas 10% Ethanol/QO% No-Lead Gas.. ASTM NO 1 011 ASTM NO 3 011 Jet Fuel, JP-4 _........_...._.._.... Jet Fuel. JP-6 _.
_. _,_.
_. _. _.
MIL-H-5606 (Univist J-43) _MIL-H-7606 (Turbo 011 No. 15) Dt-P-ethylhexyl sebacate wth 0.5% phenothlazme Skydrol 5WA.. ._
C (73 F) 1 week123 C (73 F) 4 weeks123 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 4 weeks/23 C (73 F) 1 daylReflux 1 day/23 C (73 F) 1 week/23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 h&l50 C (302 F) 70 hrsllS0 C (302 F) 70 hrs123 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 hrs/135 C (275 F) 70 hrs1177 C (350 F) 46 hrsfl50 70 h&l21 C (302 F) C (250 F)
1day123
10% Melhaol/QO% 10% Ethanol/O% ASTM NO 1 011 ASTM NO 3 011 Jet Fuel, JP4 Jet Fuel, JP-9 _.
No-Lead Gas No-Lead Gas..
_. _.
_.
_.
_.
..
_.
MIL--5606 (P04226) MIL-L-7606G (Stauffer Jet 1). MIL-L-23699 (Mobil Jet II) ATF-Dextron (AMOCO). Crude Oil API 315
_.
10 m,nilllC(2~0
* Otame*
by a&j,np F) and post cured 4 hrs 200 C (392 F) prior to test,9
_. 10phr toSlLASTlC flOrO*lllCOeSlabs aror LS-2380 rubber 0075-4ch-thlck Cured wsre press
(continued)
TABLE 2.3: FL,D RESISTANCE
FLUOROSlLiCONE
OF SILASTIC
RUBBERS-DOW
RUBBER
CORNING
(continued)
RESISTANCE OF SILASTIC *125lJ SILICONE RUBBER TO IMMERSION IN SOLVENTS AND LIQUID FOODS
Ls-2640 FLUOROSILICONE
Tensde
Prop&lest Ekmgabon, P6XY?nf Change -27 -23 -26 -27 -39 -29 -27 -21 -17 - 13 -22 -6 -11 -62 -23 SWdl,
PWX?lll
Durometer,
POlfll
Floids ASTM Reference Fuel B ASTM Relerence Fuel C 1 day23 C 173 F) , weeW23 C (73 FI 1 day/23 C (73 F) 1 weeW23 C (73 F) 1 day:Reflux 1 day/23 C (73 F) 1 week/23 C (73 F) 1 day/23 C (73 F) 1 week/23 C (73 F) 70 hrs/l50 C (302 F) 70 hrsl50 C (302 F) 70 hrsi23 C (73 F) 70 hrsil50 C (302 F) 70 hrsIl5C C (302 F) 70 h&i70 C (156 F)
Change -13 -13 -13 -13 -19 -14 -14 -13 -12 +1 0 -6 -5 -13 -19
Strength, Percent Change -40 -40 -43 -42 -57 -53 -50 -42 -36 -7 -27 -20 -16 -64 -55
m
+16 + 16 +20 +21 +26 +19 +22 +16 +17 +1 +3 +11 +9 +6 +23
Immersmn Llqwd Water Detergent. 3% m water.
Test Condrtions 14 days/l00 C (212 F) 14 days/62 C (160 F) 3 days/20psi 7 dew/62 C il60 FI 7 da&l50 7 days/150 14 days/23 14 days/23 7 days123 C(302 ;) C (302 F) C (73 F) C (73 F) C (73 F)
Durorneter Hardness, Shore A-2, pornts change +3 t2 +5 +3 +2 +2 -2 -1 -1
TBnSlle Strength. percent change +a +2 -4 I-III -24 -29 +6 -10 -3
Elongation, percent change +7 -9 -9 -2 -35 -41 +10 -6 -2
Volume. percent change l1 -1 nil +2 +1 +1 +1 nil nil
Steari ___....._....,..__.,_....
coffee Vegetable 011.. Lard. Whiskey Cola Syrup Vinegar ........................
10% MethanolM% 10% E!hanol90%
No-Lead Gas No-Lead Gas
ASTM No. 1 oil ASTM NO. 3 011 Fuel. JP-4 MIL-H-5606 (PO-4226). ML-L-76M)G (Slaulfer Jet 1). Skydrol* 500A.
Jet
.................... .................. ................... ............. ...... ....................
................. ......................... ....................... .....................
~cm-rens lcanued wth molded onto0.075-m-,h,ck ASTM slabs (1 Slmm) tar 5 mmuter/llS C (240 F), and oven cured for 4 houroi200 k (392 F) torlgmal !&WI duromster hardness - 54 pomts. twslle rtrsngti- - 1200 p.c, slongatlo - 580 percant
10w.Rs TSSO 1W rubber wm,h,. Cadox per harts b wess
290
TABLE
2.4:
POLYSULFIDE
RUBBER-MORTON
THIOKOL
ST polysulfide rubber is a millable gum elastomer prepared from bis (2chloroethyl) formal and sodium polysulfide. Vulcanizates exhibit outstanding resistance to a broac spectrum of oils and solvents, to gas permeability, low temperature, ozone and weathering. Typical uses include gas meter diaphragms, rollers, printing blankets, o-rings, and many specialty molded items.
All of the solvent Immersion
tests were run with the following Parts by weight rubber 100 1 60 5 1 167
recipe:
Ingredients ST polysulfide Stearic acid
Sterling S Zinc peroxide Calcium hydroxide
Cure 30 minutes at 310F
SOLVENT
RESISTANCE
AT ELEVATED
TEMPERATURE, Swell, % 1 month 58 6 46 67 41
140F
Solvent Xylene Iso-octane Butyl acetate Methyl isobutyl ketone Water
Volume 1 week 45 6 46 37 21
RESISTANCE
TO WATER
(DISTILLED
AND
SALT)
Original Properties Tensile, psi Elongation, 96 Hardness, Shore A Volume Swell, % 1090 215 73
Immersed 14 days at 80F Distilled Water 1065 215 71 2 4% NaCl Water 1100 215 72 1
Immersed 14 days at 158F Distilled Water 665 150 67 12 4% NaCl Water 1050 215 70 2
(continued)
Rubbers
and Elastomers
291
TABLE 2.4:
POLYSULFIDE
RUBBER-MORTON
THIOKOL
(continued)
SOLVENT RESISTANCE (30-Day Immersion at 80F - ASTM-D471-66, Method B)

SOLVENT VOLUME INCREASE, CONDITION % Esters Ethyl.acetate Butyl acetate Tributoxy ethyl phosphate Dibutyl phthalate Plasticizer SC TP-SOB Plasticizer TP-95@ Plasticizer Dibutyl sebacate Dioctyl phthalate Flexol 3 G 0 Tricresyl phosphate Adipol BCA Ethers Cellosolve Solvent Bun/l Cellosolve Dibenzyl ether Butyl Carbitol Vegetable and Wood Oils Linseed oil Cottonseed oil Castor oil Corn oil White pine oil Crude soya bean oil Hydroxy Compounds Ethyl alcohol (denatured) Butyl alcohol Isopropyl alcohol Diacetone alcohol Prestone Methyl alcohol Ethylene glycol Gasohol Glycerine P-ethyl hexanol Inorganic Compounds 10% Sulfuric acid 20% Sulfuric acid 50% Sulfuric acid 100% Sulfuric acid 10% Nitric acid 50% Nitric acid 10% Hydrochloric acid 50% Hydrochloric acid 100% Hydrochloric acid 10% Sodium hydroxide 20% Sodium hydroxide 3% Sodium chluide sdution 10% Sodium chloride 10% Copper sulfate 10% Zinc chloride Water SOLVENT VOLUME INCREASE, CONDITION %
Aliphatic and Aromatic Hydrocarbons Mineral oil Benzene Toluene Xylene Halogenated Hydrocarbons Carbon tetrachloride Ethylene dichloride Trichloroethylene Perchlorethylene Dowtherm A Monochlorobenzene
-2 110 70 41
OK Tender Swollen but OK OK
46 230 159 28 127 161
OK Very tender Tender OK Tender Tender
35 30 4 10 6 12 28 2 -2 1 7 20
OK OK OK OK OK OK OK OK OK OK OK OK
Aliphatic and Aromatic Fuels, Oils and Solvents SR-6 (60% diisobutylene, 40% aromatics) SR-10 (diisobutylene) ASTM Reference Fuel Afa) ASTM Reference Fuel Bfb 73 octane gasoline 100 octane gasoline ASTM oil No. 1 ASTM oil No. 3 Turpentine Motor oil (Esso) Circa light process oil Diesel oil Circosol 2XH Paint thinner (Duco) Drip oil Gulf motor oil Pydraul F-9 Skydrol Sovaloid C Sovaloid N Sundex 53 Tetrahydrofuran JP-3 JP-4 Houghto-Safe No. 271 Organic Acids 10% acetic acid 50% acetic acid Glacial acetic acid Cresylic acid
14 11 30 13
OK OK Very tender OK
14 1 2 10 3 2 -4 -2 4 0 -2 3 -2 23 62 -3 37 24 30 2 -1 175 -2 1 2
OK OK OK OK OK OK OK OK OK OK OK OK OK OK Slightly tender OK OK OK OK OK OK Very tender OK OK OK
-2 -2 -3 -4 14 4
OK OK OK OK OK OK
2 2 0 18 3 6 0 5 1 1 2 -2 3 3 _ 2 2 3 3 5 2 5
OK OK OK OK OK OK OK OK OK OK
9 26 18 123
OK OK OK Tender
Ketones Acetone Methyl ethyl ketone Methyl isobutyl ketone la7 Reference Fuel A has the same composition
fbl Reference Fuel 8 has the same composibon
37 35 24
OK OK OK
OK Slightly soft Deteriorated 2 wks Deteriorated 1 day Deteriorated 2 wks Deteriorated 1 day OK Tender Deteriorated 1 day OK OK OK OK OK OK OK -
as Type I te?sffluid in Mil-H-3136 119501, i.e., fuel is 100% iso-octane. as Type III msf fluid in MY-H-3136 11950). i.e.. fuel is 70% iso-octane, 30% toluene (by volume/.
(continued)
292
TABLE 2.4:
POLYSULFIDE
RUBBER-MORTON
THIOKOL
(continued)
EFFECTOFHALOGENATEDHYDROCARBONS VS Original Physical

Dichloromethane 1 week 1 month Dibromomethane 1 week 1 month Diiodomethane 1 week 1 month Trichloromethane 1 week 1 month Tetrachloromethane 1 week 1 month 1.2.Dichloroethane 1 week 1 month 1,1,2-Trichloroethane 1 week 1 month 1.1.2.2.Tetrachloroethane 1 week 1 month Pentachloroethane 1 week 1 month 285 295 410 730 120 200 67 69 235 240 1100 1140 800 810 250 260 67 65 54 54 1020 1000 950 740 220 250 64 64 328 307 1110 1100 820 620 270 320 84 63 Properties -
T
1100
M
950
E
240
H
70
VS Original Physical
Trichloroethylene Proparties -
T
1100
M
950
E
240
H
70
285 260
1180 1200
930 910
240 290
72 71
1 week 1 month Tetrachloroethylene 1 week 1 month 2-Chloropropane
153 156
1210 1290
920 960
270 290
69 70
34 32
1180 1085
920 850
250 250
68 68
Decomposed Decomposed
1 week 1 month 1.2.3.Trichloropropane
25 26
990 1040
820 1000
230 230
67 68
318 320
1160 1200
810 850
280 280
68 65
1 week 1 month Chlorobenzene 1 week 1 month 1.2.Dichlorobenzene 1 week 1 month 1.2.4.Trichlorobenzene 1 week 1 month 1-Chlorobutane
306 -
800 840
570 360
300 400
53 54
159 164
1200 1150
1000 950
250 280
70 67
159 166
1100 950
880 750
250 250
67 58
135 146
300 600
160 180
48 50
340 N.A.
1030 1010
800 750
260 280
64 61
1 week 1 month
32 32
1050 1110
900 1000
250 235
70 70
Decomposed Decomposed
VS-
volume swell
TH-
tensile strength, psi Hardness, Shore A
E- Elongation, %
M- 200% modulus, PSI N.A.- not available
RESISTANCE TO KEROSENE AND BUNKER C FUEL OIL

Original Properties 100% Modulus, psi 200% Modulus, psi Tensile, psi Elongation, % Hardness, Shore A Volume Swell, % 420 890 1200 280 72 Immersed 1 weak at 80F Kerosene Bunker C 420 860 1140 270 71 1.2 420 880 1180 270 69 4.0 Immersed 1 weak at 158F Kerosene Bunker C 260 590 790 260 67 4.0 410 870 1120 260 69 4.8
Rubbers
and Elastomers
293
TABLE
2.5:
POLYSULFIDE is a heavy-duty,
SYNTHETIC two-component to expand
RUBBER
SEALANT-STONHARD
STDNLAST flexibility
ing materials currently

allows the those properties
in use, and is unaffected

material
synthetic rubber sealant. It adheres tenaciously to just about all buildby exposure to water or most corrosive gases. STONLASTs great and contract to compensate for movement, vibration, etc., and it retains (-65O to +215F). value of Stonlast sealant when exposed
over a wide range of temperatures
The purpose of this guide is to aid in determining the potential to the damaging effects of erosive chemical spillages.
The test procedure used was to totally immerse cured samples of Stonlast in the chemrcals listed for a period of 30 days at normal room temperature per ASTM 0471.62T. Method B. (This is an exceptionally severe test, since n-lost areas subject to chemical spillages such as these are flushed down periodically with water as part of the normal maintenance operation ) The resultant resistance of Stonlast to the various chemicals (It is assumed that normal good housekeeping procedures with clean water.) RATING E G The (number) Excellent Good appears F NR CODE Fatr Not Recommended IS the percent volume swell. is related are used, using the symbols listed below. includtng a daily flushing down
which
next to each rattng
ACIDS Hydrochloric - 10%. Hydrochloric - 30%. Hydrochloric - 37%. Nitric - 10% Nitric - 50% Sulfuric - 10% Sulfuric - 20%. Sulfuric - 50%. Sulfuric - 100%. E (1 %) E (6%) NR NR NR E (1%) .E (1%) NR NR Copper Copper Sodium Sodium Sodium Sodium Sodium Sodrum
ALKALIES
AND
SALTS E (3%)
Sulfate - 10% Sulfate - 14% Chloride 3% Chloride - 10% Chloride - 36% Hydroxrde - 10% Hydroxtde - 20% Hydroxide - 50%
E (5%)
E E E E E (1%) (1%) (1%) (0%) (1%)
E (1%)
SOLVENTS (Aromatic Benzene. Toluene. Xylene. (Halogenated Hydrocarbons) NR (314%) NR (138%) G ( 61%) Hydrocarbons) F ( 78%) NR (605%) NR (474%) E ( 43%) NR (401%)
AND
OTHER
CHEMICALS (Esters and Plasticizers) G E G E E ( 48%) ( 36%) ( 55%) ( 8%)
(Aliphatic and Aromatic Oils and Solvent) ASTM Oil No. 1 ASTM Oil No. 2 ASTM Reference ASTM Reference JP-5.. Motor Oil. Skydroltv. SR-6. SR-10. Turpentine.
Fuels,
:
Fuel A Fuel B
E E E E
Carbon Tetrachloride. Ethylene Dichloride. Monochlorobenzene. Perchloroethylene. Trichloroethylene. (Hydroxy Compounds)
E
E : : : : : ::G E E E
( 1%) (12%) (-1%) (12%) ( 2%) (-1%)

(59%)
(21%) (11%) (11%)
Butyl Acetate Butyl Cellosolve Adipate Dibutyl Phthalate Dibutyl Sebacate Dioctyl Adipate Dioctyl Phthalate Ethyl Acetate Propylene Glycol Ricinoleate TP-SOB Plasticizer TP-95% Plasticizer Tributoxy Ethyl Phosphate (Vegetable and Wood Oils)
: :E
G
( 0%) ( 33%)
( 64%) ( 5%) ( 26%)
:E
E G E
( 51%) ( 17%)
Butyl Alcohol. Diacetone Alcohol Ethyl Alcohol (denatured). 2-Ethyl Hexanol Ethylene Glycol Glycerol Isopropyl Alcohol Methyl Alcohol.
E E E E E E E E
(-2%) (10%)
(Ketones
and Ethers) G .E ( 50%)
Castor
Oil
( -2%)
(4%)
( ( ( ( ( (
2%) 1%)
4%) 1%)
2%)
3%)
Acetone. Butyl CarbitolM. Butyl Cellosolve~. Dibutyl Ether Ethyl Cellosolve? Methyl Ethyl Ketone. Methyl lsobutyl Ketone
( 19%)
E ( 8%) NR (605%) E ( 28%) F ( 87%) E ( 36%)
Corn Oil. Cottonseed Gil: Linseed Oil Soya Bean Oil.. White Pine Oil.
: ::: :::::
E E E E E
( -3%)
( 0%)
( 0%) ( 17%)
294
Corrosion
Resistant
Materials
Handbook
TABLE 2.6: CORROSION
SILICONE
ELASTOMER
LININGS-HURON
CHEMICALS
LTD
RESISTANCE DATA FOR SlLlGL4S~
LININGS* Temperature Conditions [Cl Test Duration Corrosive Effect Noted
Concentration Acids Hydrochloric (HCl] Acid

1.2% 1.2%
Pwl
90-1000 200
200
68
30 %
28 40
.4 mils/yr loss .04% weight gain 24 mils/yr loss
Nitric Acid (HN031
7% 25% 50% Reagent Grade
200 200 200 28
68 40 40 40
.2 1.3 10 4.4
mils/yr mils/yr mils/yr mils/yr
loss loss loss loss
Sulphuric (H2504I
Acid
10% 50% 50% 50%
200 200 600 85O
68 30 45 24
1 mil/yr 2 mils/yr 18 mils/yr 15 mils/yr
loss loss loss loss
Phosphoric (H2PO3)
Acid
5%
85O
48
Smils/yr
loss
Bases Ammonium (NH4W Hydroxide 10% Reagent Grade 85O 60~ 48 45 4% weight gain 1.18% weight gain
Potassium (KOH]
Hydroxide
50%
85O
48
33 mils/yr
loss
Sodium Hydroxide
( NaOH)
10% 10% 20% 30% 50%
200 90-1000 6oQ RT RT
42 28 45 40 42
1.4 11.6 15 5
mils/yr mils/yr mils/yr mils/yr 17 mils/yr
loss loss loss loss loss
(continued)
295
TABLE 2.6: SILICONE ELASTOMER LININGS-HURON
CHEMICALS LTD (continued) Test Duration Corrosive Effect Noted
Concentration Salt Solutions Potassium Chloride (KC11 100 gpl
Temperature Conditions [Cl
[Days1
30
65O
10 mils/yr loss
Sodium Chloride ( NaCL)
30 gpl 30 gpl 300 gpl 300 gpl 9Czo 200 90-1000
68 z 40
1 mil/yr loss
.I% weight gain
.5 mil/yr loss
.I&% weight gain
Oxidizing Environments Electrolytic Sodium Chlorate Production Cell NaCI, 50-250 gpl NaC103, lOO-600 gpl NaOCI, 1.5-2.Ogpl pH=7 Hydrogen Peroxide (H202) Hypotower Simulation (No over-chlorination) pH- 14+ 10 5% 85O 48 .2% weight gain 900 700+ 4 mils/yr loss
20-500
147
2 mils/yr
Hypotower Simulation (50 over-chlorinations) pH- 14+ 5 Sodium Hypochlorite (NaOCI-6%) pH 13 NOTE: lmil= .OOl inches.
2@800
70
7 mi Is/yr
200 600
42 45
2 mi Is/yr 7 mi Is/yr
* SiIigIas lining material is a silicone elastomer on a glass fiber backing.
296
Corrosion
Resistant Materials Handbook
TABLE
2.7:
URETHANE-AMERICAN
CYANAMID
CYANAPRENE A-8 CYANASET M 90% Shore A % V.C. . . . . . Acids . . . . . . . Acetic acid 5% Hydrochloric 10% Nitric acid 10% Sulfuric acid 3% Sulfuric acid 30% -3 0 -1 0 6.25 4.9 6.9 0.3
CYANAPRENE D-5 CYANASET M 90% Shore A % v.c.* . . . . . . . . . . . . . . . . . . . . . . . . -5 -3 -2 -2 3.7 3.3 5.7 0.8
. . . . . Alkalies
Ammonium hydroxide 10% Detergent heavy duty Sodium carbonate 2% Sodium carbonate 20% Sodium hydroxide 1% Sodium hydroxide 10% Soap solution 1% . . . . . . . . . . . . . . . . . . . Acetone Benzene Carbon tetrachloride Dimethyl formamide Ethyl acetate Ethyl alcohol Methyl alcohol Toluene Turpentine Water . . . . . . . . . . . . . . . . . . . ASTM #I ASTM #3 Heptane lsooctane Kerosine Mineral oil Toluene Transformer -3 -1 +9 +7 -8 -4 -2
. . . .. .. . . . .. . . . . . . . . . . . . . . . . . .
0.75 0 4.2 3.6 0 -1.2 3.4
-4 0 -3 -5 -4 -2 -3
2.5 -0.25 A.: 0:3 -0.4 1.5
. . . . . . . . . . . Solvents
-29 -13 -7 -15 -3 0 -7 -2 0
. . . . . . . .. . . . . . . . . . . . . . . . . . . . . .
105.2 76.4 27.5 40.4 17.8 11.4 37.8 3.2 1.4
-20 -11 0 -9 -5 0 -5 -2 -1 -2 -3 -1 0 -5 0
67.4 45.25 -0.25 31.4 13.9 14.6 21.3 0.3 1.3 0.3 1.3 1.0 0.5 21.3 -1.0
. . . . . . . . . . Oils, Fuels. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
0
0 +3 0 -7 +2
1.7 1.7 0.9 0.5 37.8 -0.3
oil
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Other Media . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Aniline Ethylene dichloride Hydrogen peroxide 28% Sodium chloride 10% *% volume change. ASTM Test Method: -38 -30 0 -3 ASTM D-543-60T 367.9 109 5.9 -0.04
-35 -14 -3 0
239.5 53.9 3.8 1.3
297
TABLE 2.8:
URETHANE-DEVCON
Devcon FLEXANE is a two-component room-temperature curing urethane for forming abrasion resistant linings, repairing rubber parts or equipment, and forming flexible molds and parts. FLEXANE is available in putty and liquid form in two durometers. A FLEXANE flexibilizer can be used to produce urethane of any desired durometer.
Chemical Resistance of Aexane-ImllWSiOn
SampleSize:Yz~x% xl Cure:7 Days@ Roomlemperoture Immersion:30 m
$g
Product Nome
Flexone 80 (Llquld &Puny) Rezone 94 (Llquld & RQ) Aerone High Petiormonce Pully Flexone Brushable Urelhone 1Rexone BIW I
,Ps
VG VG U VG
-D
_a?2
l3Y
VG VG U VG VG VG VG VG VG , VG ,
VG
VG VG VG VG ,
VG VG
U VG U
U U
VG U 1 VG
F F
U u F U 1 F 1
U u U U U 1
U u U u U 1
U u U u U 1
U u U u U 1
U u U u U 1
1
/ /
VG VG VG VG
V: U 1 VG 1
F F F
TABLE 2.9:
URETHANE
MEMBRANE-STERNSON
LIMITED
LIQUATHANE is a high performance elastomeric urethane rubber membrane. Applied as a liquid, LIQUATHANE is designed to protect concrete and steel from corrosive attack as well as exhibiting excellent resistance when used as a waterproofing/liquidproofing or between slab membrane.
CHEMICAL Exposure Acids
RESISTANCE
GUIDELINES
Resistance Good resistance to common industrial strength acids phosstrength
(0% to 15%), such as sulphuric. hydrochloric, phoric, lactic, dilute oxidizing agents. Alkalis Good resistance to common industrial
caustics (0% to 15%), such as sodium hydroxide, many chloride, sulfate and nitrate salts, saturated salt solutions. Fresh Water/ Sea Water Excellent resistance
298
TABLE 2.10:
VARIOUS
ELASTOMERS-AMERICAN
CYANAMID
Test Formulas CYANACRYLO J-c 100

100
-R CYANACRYL R Polyacrylate CYANACRYL L Polyacrylate c Polyacrylate cuwRn Chgn&um HR 665 vamac B-124 General Elecnic SE-3724 N-550 (FEF) Carbon Black N-990 (MT) Carbon Black Hi-Sil 215 Precipitated Silica Maglite D Hercoflex 600 Dioctyl Sebacate ~araplex G-25 silane A-189 zinc Oxide stearic Acid TE-80 Petrolatrrm Armeen 18-D NPS Red Oil Soap curative c-50 Spider Sulfur CYUFAM@DS Horfax Disk No. 1 DPG Total Parts 100
NBR -
124 100 55 60 60 15 40 10 5 10 5 0.4 3 1 2 40
2 0.5
3.5 0.3
3.5 0.3 8 0.3 0.3 2 1.2 165.8 170.3 179.7 186.7 100.0
-160.8
Imersion
in Synthetic Fluids for 168 Hours at 3OO'F CYANACRYL@ -!L L -2 -36 -47 +7
-R Valvoline ESP (Blend) Hardness Change. points Tensile Change, X Elongation Change. X Volme Change. x Mobil 1 (LAOO) Hardness Channe. points Tensile Chang;,~%Elongation Change, % Volume Change. X Polar Start DN-600 (LAB) Hardness Change, points Tensile Change. X ElongationChange, X Volume Change, X Chenlube (DAE) Eardness Change, points Tensile Chang;. X Elongation Change. X
Volume Change. X
NBR -
EA8 -2 -21 -33 +12
SI -16 -20 -12 +28
+1 -28 -45 +5
0
-5 -8 +7
+10 -67 -49 +1
-3 -31 40 +9
0
-6 -35 -41 +11
-2 -12 -11 +10
+16 -78 -86 +1
-5 -27 -36 +18
-13 -15 -4 +25
-14 -52 +7
-4 -21 -52 +10
-3 -12 -12 +10
+12 -71 -53 +2
-7 -14 -20 +15
-15 -24 -12 +28
-7 -6 -25 +13
-13 -30 -35 +20
-12 -22 -2 +19
+8 -77 -62 +6
-20 -39 -41 +42
-16 -25 -18 +28
Ultra E-11 (DAE) Hardness Change, points Tensile Change. X Elongation Change. X Volume Change. x
CYANACRY NBR EAE SI L acrylic elastomer nitrile polymer ethylene acrylic silicone
-9 -8 -12 +18
-17 -24 -15 +28

LAO0 LAB DAE
-16 -34 -3 f26
+13 -80 -100 +8
-19 -50 -49 +69
-16 -29 -13 +24
I inear alpha olefin oligomer linear alkylated benzene dibasic acid ester
Rubbers
and Elastomers
299
TABLE 2.11:
VARIOUS
ELASTOMERS
AND RUBBERS-DU
PONT
Chemical
GATlNG KEY A-Flurd B-Flurd C-Flurd has kttle or no effect has mmor to moderate effect has severe effect
Resistance *
T-No X-No data-kkely to be compatible data-not likely to be compahble VlTW@ ;:
chemical Acetaldehyde Acetic acid. 20% Acetic acid. 30% Acetic acrd. glacial Acebc acid. glacial Acetic anhydride Acetone Acetylene Alummum chloride solubons Alummum sulfate solutions Ammoma. anhydrous Ammonium chlonde soluhons Ammomum hydroxrde solutrons Ammonium sulfate solubons Amy1 acetate Amyl alcohol AmIme Anrlme Annme ASTM 011 xl ASTM 011x3 ASTM reference fuel A ASTM reference fuel B ASTM reference fuel C ASTM reference fuel C Asphalt Banum hydroxide solutrons Beer Benzaldehyde Benzene Benzoyl chlonde Borax solutions Borrc acrd solutions Bromme, anhydrous lrqurd Butane Butyl acetate Butyraldehyde Butync acrd Calcium brsulfite solubons Calcium chlonde solutions Calcrum hydroxide solubons Calcium hypochlonte, 5% Calcrum hypochlonte. 20% Carbon btsulfrde Carbon dioxrde Carbon monoxrde Carbon tetrachlonde Castor 011 Chlorme gas, dry Chlonne gas, wet Chloroacehc acid Chlorobenzene Chloroform Chlorosulfonrc acrd Chromtc acrd, lo-50% Citrrc acrd solutrons Copper chloride soluhons Copper sulfate soluhons Cottonseed 011 Creosote 011 Cyclohexane Drbutyl phthalate &ethyl sebacate Droctyl phthalate DOWTHERM A DOWTHERM A Eprchlorohydnn Ethyl acetate Ethyl acetate Ethyl alcohol Ethyl chlonde Ethyl ether
i t
C C
A
B 0 A
t B (100F) 1 : 1 1 A :: B A C
E
r A A A A L A A A AAB -
;; i
A&F)
: A (15BF) A (1WF) A(t$F) -
c
A
A
c
C A A A C A A A
(2:UF) 5t A
(ZO(PF) A (200F) A (2;VF) c,toBw, A B (:PF Ii
B-C X
:I:% A (15bF) A (15BF) B (l&F,
1;:; A 8-C C x A A : C ; C r : B X : A A A : T C 6 X : X C ; A A A A-B X C X T r T A (4&V, x x C ; f :: : (2t;F)
A (2!2F) A-B B(lWF) C (300F) A (300F) A (350F) A A A A (4pF) A * ,1LF, B A A B (2l;PF) A C C T A A A B (t:bF) : A (t:BF) A (2:TF) : A A C A A A A (3:1pF) A (212F) A B B
8 A (200F) A : A (ZL, A (200F) : C ;:; A (2OODF) A (Z&F, A (2:BF) A (2:EPF) A (200F) A(& B A X C A (&F, A A A A : : C B r C A (25F) ! r
T A B A A : B
;; T A -
7 A A A x B 7 C
: A 8 : B c A (l&F) C C B (&F) A B C c X (15kF) : B -
A (2:,F) B (4OBF) C (12PF) C
A C
(continued)
300
Corrosion
Resistant
Materials
Handbook
TABLE 2.11:
Chemical
VARIOUS
ELASTOMERS
AND RUBBERS-DU
PONT
Neoprene C(lZoT, A (1rFt 7 A(lyFI
(continued)
VAMAC
Ethylene dichlonde Ethylene glycol Ethylene oxide Exxon 2380 turbo oil (lubncant) Ferw chloride solutions Fluos~lw acid formaldehyde, 40% Formaldehyde. 40% Formic acrd FREON*-11 FREON-l 1 FREON-12 FREON-12 FREON-22 FREON-22 FREON-l 13 FREON-113 FREON-1 14 FREON-l 14 Furfural Fyrquel.220 (hydraulic fluld) Gasoline Glue Glycertn n-Hexane Hydrazme Hydrochlow acid, 20% Hydrochloric acid, 20% Hydrochlonc acid, 37% Hydrochloric acid. 37% Hydrochloric acid. 37% Hydrocyanic acid Hydrofluoric acid. 46% Hydrofluonc acid. 75% Hydrofluonc acid. anhydrous Hydrogen Hydrogen peroxtde. 90% Hydrogen peroxrde. 90% Hydrogen sulfide lsooctane Isopropyl alcohol Isopropyl ether JP-4 JP-5 JP-6 JP-6 Kerosene Kerosene Lacquer solvents Lactic acid Lmseed oil Lubrlcabng oils Magnesium chloride solutions Magnesium hydroxide solubons Mercunc chlonde solubons Mercury Methyl alcohol Methyl ethyl ketone Methylene chlonde Mineral oil Mobrl XRM 206A (aircraft lube) eng. Naphtha Naphthalene NWc acid. - 10% Nitnc actd. 30% Nitric acid. 30% Ndnc acid. 60% Ndnc acid. 70% NW acid. 70% NW acid. red fummg Nitric acid. red fummg Nitrobenzene Olelc acid Oleum. 20-25% PalnWc actd Perchloroethylene Phenol Phenol Phosphonc acid. 20% Phosphoric acid. 60%
A(2:IF) X
i 1 r 0 ks c a c E-c
i 7 -
VITOY' A-B(lZU'F) A(25O'F) C(l5c'F) A(39FF) A T
i
C,l;F) A-B T(lJ(PF) A.8 B(l3U'F) C X(lWF) T&F, B C&F) A(2lPF) A A A(2WF) z A A(23fTF) A(l5PF) B(2jg"F) A k&F, A A A C(27U'F) B(27BF) A A
c Y A-0 I (13U'F) A&F, A A(l3VF) A(&F) r&q B B A(lWF) AWW A A
a ;;
A&F) A(4OU'F) A(lOVF) C(S5U'F) :::z; C A A,lAF) A A ;1 B S&F, A(3k-l A(158T) A(l76F) A A
x x x x x X r B
,lAF,
A
C(&F, B
A(2:Z'F) A(2lPF) B(3WF) A(2:FF) (continuec

TABLE
301
2.11:
VARIOUS
ELASTOMERS
AND RUBBERS-DU
PONT
Wcoprcnc :: C C ;; A
(continued)
NOADEV A A C C 7 A A 8 F ;: A (2:lPF) A (21zF) ; ; A A : A C B A (350F) B : A A B A A t C : c z A s z C A (2;F) A A C A (&F, A(2:pF c T T A A A-0 X X ; ;; i T : : : A(15CF) c : i rT A(21tF) A (250F) A VAMAC'
Chemical Phosphonc actd. 70% Phosphoric acid. 65% Ptckkng solubon (20% nttnc actd. 4% HF) Pickling solution (17% nitric acid, 4% HF) Pickling solution (17% nitric acid, 4% HF) Picric acid Potassium dichromate solutions Potassium hydroxide. dilute solutions Pydraul312C Pyridine OFl-2023 (silicone brake fluid) SAE#lOoil Sea water Shell turbine oil 307 Silicone grease SKYDROL 500 SKYLUBE 450 Soap solubons Sodium chloride solutions Sodium dichromate. 20% Sodium hydroxide, 20% Sodium hydroxide, 46th% Sodium hydroxide, 46h% Sodium hydroxide, 50% Sodium hydroxide, 73% Sodium hypochlorde. 5% Sodium hypochlorite. 20% Sodium peroxide solutions Soybean oil Stannic chlonde Stannous chloride. 15% Steam (see water) Steam Steanc acid Styrene Sulfur, molten Sulfur dioxide, gas Sulfur dioxide, liquid Sulfur tnoxtde Sulfuric acid, up to 5% Sulfuric actd. 5-10% Sulfuric actd. 1 O-50% Sulfuric acid, 50-60% Sulfurtc acid, 60% Sulfuric actd. 90% Sulfuric acid, 95% Sulfuric acid. 95% Sulfuric acid, fuming (20% oleum) Sulfurous acid Sunoco XS-620 (EP lubricant) Tanntc actd. 10% Tartaric acid Tetrahydrofuran Toluene Tributyl phosphate Trichloroethylene Trichloroethylene Tricresyl phosphate Triethanolamine Tnsodium phosphate solutions Tung oil Turpentine Water Water Xylene Xylene Zinc chloride solutions
HYPALOW@ A (269v A (200F) A A(150F) _; A (26@v A (2rF) c c A : C A (20aF) A (2& A (2OpF) A :I:% A(& A (2WF) A A (2$F) A I) (1GFj E : C A A (2& A (1FF) A B (:;BpF) A ,& A A (2mF) C : C c A(l52F) :: A&F) A (2;rTF) A (2;F)
X
X
i
A (2&) T T ;7 A A (2:QF) A (1yF-f
BWV AW=-l
A
T
C
::
A ,& c r
A (lSi?Ff A (2:PF a (15IpFf A
A(IWF)
Doless
otherwise
noted,
concentration
of aqueous
solutions
ore saturated.
All
ratings
are at room
temperature
unless
speciflod
HYPALON HYTREL NEOPRENE
chlorosulfinated polyethylene polychloroprene
polyethylene
NORDEL VAMAC VITON
synthetic rubber ethylene acrylic fluoroelastomer
302
TABLE
2.12:
VARIOUS
ELASTOMERS
AND
RUBBERS-EXXON
CHEMICALS
Exxon butyl rubber and its chlorinated analog, chlorobutyl rubber are isobutylene-isoprene basically inert, nonpolar, stable elastomers which exhibit outstanding resistance to attack ent chemicals.
copolymers. They are by a great many differ-
VISTALON elastomers are classified generically as either ethylene-propylene copolymers (EPM) or ethylene-propylene terpolymers (EPDM). All grades of VISTALON EPM have a completely saturated hydrocarbon chain which makes them highly resistant to attack by chemical agents such as oxygen, ozone, acids, and the like that seek to react at the site of a double bond. Exxon elastomers offer good resistance to water, inorganic glycol base antifreeze formulations, and to most inorganic elastomers show good resistance to attack by acids, amines, ethers, and ketones. Resistance to detergents and soaps is or in 1% solutions which approximate the concentrations cations. salt solutions, bases, synthetic hydraulic fluids, ethylene acids. When immersed in organic compounds, Exxon and oxygenated compounds-alcohols, aldehydes, esters, excellent whether in concentrated form (as purchased) of these materials commonly used in household appli-
Exxon elastomers display good resistance to attack by animal or vegetable oils. However, they are like other petroleum derived synthetic polymers in that their resistance to the attack of hydrocarbons, oils, and other petroleum based chemicals is low. Only VISTALON 6505 blends with nitrile and polychloroprene rubbers maintain good physical properties after prolonged exposure to these materials.
CHEMICAL
RESISTANCE
OF COMPOUND
BASED ON INTERMEDIATE
UNSATURATION
BUl-YL RUBBER
72 Hours Immersion at 212OF VOlUnW change n WATER Distilled Water Sea Water--Atlantic Sea Water-Pacifu INORGANIC ACIDS Boric Acid (10%) Chlorosulfanic Acid (10%) Chromic Acid (10%) Chromic Acid (Cont.) Hydrochloric Acid (10%) Hydrochloric Acid (Cone.) Hydrofluoric Acid (Cont.) Nitric Acid (10%) Nitric Acid (Cow.) Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acid (Cont.) INORGANIC BASES Ammonium Hydroxide (10%) Ammonium Hydroxide (Gnu.) Barium Hydroxide (Cont.) Calcium Hvdmxide (10%) Potassium Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cont.) INDRGANIC SALTS (25% Sofutiona) Aluminum Chloride Aluminum Sulfate Ammonium Chloride Ammonium Nitrate Ammonium Phosphate +0.78 +0.56 +1.04 +0.93 Disintegrated +6.60 +19.6 +3.70 +15.9 -1.94 +9.09 Disintegrated -0.46 +0.24 Disintegrated +1.89 +1.88 -0.45 +1.16 +2.85 +1.92 102.4 94.0 93.5 82.4 +1 +2 Unchanged Unchanged Tensik stmngth Retained % 95.8 98.8 95.8 103.0 83.1 63.9 96.4 81.9 89.0 -
fl0llgdfOll
Retained % 81.8 90.2 88.8
Hardness Change Pts. +1 +2 +2
surface
Condition Unchanged Unchanged Unchanged Unchanged Unchanged V. Brittle Sl. Tacky Unchanged Unchanged -
94.1
75.1 68.6 78.4 109.8 58.2
+1
-2 -3 -2 -8 -3 -
958 105.4 98.8 97.0 98.2 101.8
86.3 96.1 86.9 82.4 88.2 91.2
-1 -3 +2 0 -2 -2
Unchanged SI. Tacky Unchanged Unchanned Unchanged St. Tacky Unchanged
+0.11
+0.50 +0.51 +0.13 +0.21 +0.57
99.4
89.2 97.0 94.0 95.2 96.4
88.2
78.4 83.7 83.7 85.0 82.4
0
-2 +1 +1 0 f2
(continued)
303
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
72 Hours Immersion at 212F VdumC Change K Banum Chloride Barium Sulfide Calcium Chloride Calcium Hypochlorite Cupric Chloride Cupric Sulfate Ferric Chloride Ferric Nitrate Ferrous Sulfate Magnesium Chloride Magnesium Sulfate Nickel Sulfate Potassium Chloride Potassium Permanganate Potassium Bisulfite Potassium Dichromate Sodium Borate (Borax) Sodium Bicarbonate Sodium Chloride Zinc Chloride Zinc Nitrate ORGANfC ACIDS Acetic Acid (10%) Acetic Acid (Glacial) Chloracetic Acid (10%) Citric Acid (10%) Formic Acid (10%) tactic Acid (10%) Oleic Acid (100%) Oxalic Acid (10%) Phenol (10%) Phenol (100%) Picric Acid (10%) Stearic Acid (100%) Tannic Acid (10%) Tartaric Acid (10%) ALcoHoLs Benzyl Alcohol Ethyl Alcohol Isopropyl Alcohol Methyl Alcohol Ethylene Glycol Gfycerol 1 Hexand Resorcind ALDEHYDES Benuldehyde Butyraldehyde Furfural AYINES Aniline Triethanolamine UDMH +0.17 +0.39 -0.46 +0.69 +0.48 +0.94 +1.50 +3.65 +0.48 +0.31 +0.82 +0.79 -0.07 +0.58 +1.41 +0.61 +0.34 +0.52 0.00 io.73 +0.24 Tensik Strengtfr Retained SC 95.8 94.0 89.8 98.8 98.2 91.6 95.2 97.6 92.8 94.6 94.0 94.0 90.4 93.4 92.8 91.6 94.6 94.6 100.0 94.0 94.6 Efongatifm Retained % 82.4 82.9 77.1 80.4 84.9 80.4 76.5 93.0 81.8 84.3 81.0 84.3 82.4 84.3 83.3 77.1 84.9 84.3 82.4 80.4 80.9 Hardness Change Pts. +1 0 0 -2 +1 +1 0 -4 +1 +2 +1 +1 +1 -6 0 0 -1 +1 -1 0 +2 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged V. Tacky SI. Tacky SI. Tacky SI. Tacky SI. Tacky Unchanged SI. Brittle Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged
+10.9 + 14.7 +9.w +0.69 +12.3 +6.12 +B22 +2.36 +2.82 -7.54 + 14.6 +92.8 -0.76 +1.u +3.19 +2.04 +2.44 +0.63 +0.36 -0.52 +17.B +0.50 +12.3 +24.9 +4.37 +7.97 -11.1 +13.7 +67.2 +43.7 +22.5 +14.7 +1.80
88.0 79.5 86.7 97.0 86.0 90.4 28.3 97.6 103.6 116.3 78.3 111.5 96.4 97.0 106.6 91.0 89.8 98.2 loo.0 98.8 95.8 103.6 94.6 69.9 108.4 98.2 100.6 54.2 31.3 51.2 88.0 60.2 112.1
73.9 67.2 72.0 85.7 68.6 74.5 50.4 81.8 94.1 110.4 61.4 105.3 86.3 88.2 98.0 82.9 91.6 91.6 84.9 86.3 104.6 91.6 102.0 90.2 101.4 109.2 88.8 79.8 46.5 78.4 83.7 67.3 103.3
-6 -3 -3 +2 -4 0 -38 +1 -4 -7 -5 -4 0 +2 -9 -3 -3 +2 +2 +2 -23 +3 -19 -25 -8 -15 +2 -18 -35 -33 -22 -17 -6
Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Unchanged Sf. Tacky Unchanged Unchanged Sf. Tacky SI. Tacky Unchanged Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged (continued)
ESTERS
Amy1 Acetate Dibutyl Sebacate Dioctyi Phthalate Ethyl Acetate Tricresyl Phosphate
304
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
72 Hours Im-ion TdkStNn#l

RJtJinedw RJunedY
at 212*F
HarlhleJJ ChJnrPts. suhce con&ion
Ehngation
ETHERS Dibenryl Ether Diethylene Glycd Monobutyl Ether Ethyl Ether Ethylene Glycol Monoethyl Ether HYDRDCARBONS
BelueM
+20.6 +4.89 +54.8 +5.01 +125.6 +243.5 +190.2 +144.1 +94.4 +108.8 +198.0 +206.8
99.4 110.8 28.9 W.0 19.9 18.1 15.7 15.7 22.3 83.1 10.2 16.3
111.8 104.9 30.0 89.6 24.1 17.7 26.1 22.2 22.2 75.9 26.1 25.5
-25 -12 -34 -12 -37 -37 -43 -35 -32 +12 -51 -45
Unchanged Sl. Tacky SI. Tacky Unchanged SI. Tacky Sf. Tacky Unchanged Unchanged Sl. Tacky Sl. Tacky Unchanged Unchanged
Cyclohexane Ethylbenzene Heptane

HexJnJ
Naphthalane Toluene Xylem HALDGENATED HYDROCARBONS 8enzyl Chloride Bromobenzene Carbon Tetrachloride Chloroform Ethylene Dichloride Perchlorathvlene OTHER SUBSTITUTED HYDROCARBONS Carbon Disulfide Nitrobanzene KETONES Acetone Methyl Ethyl Ketone Methyl lsobutyl Ketone DETERGENTS&OTHER CLEANING PRODUCTS Calgonite (1%) Clorox (1%) Clorox (Cont.) Joy (1%) Joy (Cont.) Lestoil (1%) Lux Flakes (1%) Rinse Dry (1%) Rinse Dry (Cow) Tide (1%) NATURAL FATS 6 OILS Butter Castor Oil Cottonseed Oil Lard Oleomargarine Olive Oil White Mineral Oil OILS 6 FUELS A.S.T.M. No. 1 Oil A.S.T.M. No. 2 Oil A.S.T.M. No. 3 Oil A.S.T.M. Fuel A A.S.T.M. Fuel B A.S.T.M. Fuel C Heating Fuel Oil Jet Aircraft Engine Oil Kerosine
+225.8 +85.2 -I-37.9 +194.3
Disintegrated Disintegrated 18.1 21.1 39.8 12.7
20.2 21.6 45.7 17.1
-38 -32 -24 -46
Unchanged St. Tacky SI. Tacky Tacky
+ 144.9
+11.9 +7.92 +15.7 +61.4
21.7 101.2 85.5 48.8 35.5
21.0 106.9 88.8 53.5 49.0
-30 -20 -11 -18 -32
SI. Tacky Unchanged SI. Tacky Unchanged SI. Tacky
+1.76 +1.13 +1.20 +2.08 -0.13 +2.94 +1.78 +1.18 +1.34 +1.38 +23.1 -1.25 +19.2 t28.9 + 15.3 +24.8 t 100.6 +64.3 +88.2 + 173.4 + 159.0 +199.5 +232.7 +224.1 +92.3 t262.0
102.4 103.0 103.0 102.4 100.0 100.6 105.4 101.8 95.2 100.0 66.9 89.8 71.1 75.9 81.9 71.1 28.9 38.0 33.1 16.3 18.1 13.3 13.3 13.3 13.3
92.2 88.8 88.2 91.6 90.2 96.1 96.7 88.8 86.3 93.1 97.7 86.9 94.1 104.5 102.6 99.4 31.4 56.3 59.4 40.6 25.5 22.9 21.0 22.9 22.2
+1 +1 Cl1 +1 +1 -1 0 +2 +2 -1 -21 0 -18 -22 -17 -21 -33 -34 -36 -46 -40 -45 -47 -45 -47
Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Unchanged
(continued)
Rubbers
and Elastomers
305
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
72 Hours Immersion at 212OF Volume Changa K AUTOMOTIVE PRODUCTS Chassis Grease Motor Oil (lOW.30) Gasohnc (RON 94) Gasohne (RON 99) Gasohne (RON 102) Gasolme: unleaded HYDRAULK FLUlDS Dronite Pydraul Pydraul Skydrol Skydrol 8200 F-9 60 500 +13.4 +27.7 +9.79 +14.1 +12.3 +2.39 +0.12 +1.11 -0.23 -0.12 69.9 74.7 98.2 92.2 88.6 100.6 101.9 101.2 97.0 93.4 79.9 102.0 103.9 107.3 103.3 85.7 86.9 88.8 88.2 82.4 -15 -26 -18 -24 -22 +2 +2 +2 -1 +3 Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Tacky Unchanged Unchanged Unchanged +44.8 +157.6 +200.8 +181.9 +202.5 + 162.0 40.0 17.5 15.7 15.7 14.5 12.7 45.7 30.8 21.6 20.2 20.2 18.2 -35 -56 -43 -39 -43 -43 SI. Tacky Unchanged Unchanged Unchanged Unchanged Tensik Strength Retained K Elongation Retained K Hardness Change Pts. Sur(acC Condition
MfSCELLANEDUS Gelatin (sat. soln.) Glucose (sat. soln.) Tincture of Iodine Prestonc antifreeze Dowgard antifreeze
One Month Immersion at 7S 2 5OF VOIU~ Chmge % WATER Distilled Water Sea Water-Atlantic Sea Water-Pacific lNORGANlC AClDS Boric Acid (10%) Chlorosulfonic Acid (10%) Chromic Acid (10%) Chromic Acid (Cont.) Hydrochloric Acid (10%) Hydrochloric Acid (Cont.) Hydrofluoric &id (Cont.) Nitric Acid (10%) Nitric Acid (Cont.) Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acid (Cont.) INORGANICBASES Ammonium Hydroxide (10%) Ammonium Hydroxide (Cont.) 8arium Hydroxide (Cow) Calcium hydroxide (10%) Potassium Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cont.) INDRGANIC SALTS (25% Sotutions) Aluminum Chloride Aluminum Sulfate Ammonium Chloride Ammonium Nitrate Ammonium Phosphate Ranum Chloride Barium Sulfide Calcium Chloride Cakium Hypochlorite -0.11 +0.32 +0.25 -0.11 Disintegrated +0.93 +43.7 -0.65 +2.67 +0.62 +0.63 +14.8 -0.33 -1.22 Disinteerated +0.69 -l-o.75 +0.13 +0.35 +0.11 +0.23 +0.11 TensUe Strength Retained % 100.0 102.4 97.6 103.0 99.4 10.2 98.8 98.2 98.8 103.0 28.9 98.8 98.2 Elongation Retained% 97.5 100.6 94.1 98.6 100.6 86.9 95.5 110.4 98.6 97.5 103.9 99.4 99.4 Hardness Change Pts. +3 +3 +3 -l-3 +3 -34 +4 0 +1 +1 -28 +3 +3 Surface Condition Unchanged SI. Tacky SI. Tackv 3. Tacky SI. Tacky Tacky SI. Tacky SI. Tacky Tacky SI. Tacky V. Tacky Sl. Tacky SI. Tacky
103.6 103.6 99.4 101.2 97.0 94.6 106.0 100.0 99.4 97.0 96.4 101.8 97.6 98.8 101.2 100.0
102.0 102.0 96.7 102.0 93.5 88.8 98.0
+2 -3 +3 +3 +3 +3 +2
Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged
+0.34 +o.SD -0.48 +0.42 +0.26 -0.83 -1.29 +1.43 +0.73
91.6 95.5 94.7 96.1 99.4 97.5 98.0 99.4 95.5
+3 +3 +4 +3 +3 +3 +3 +3 +2
Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
(continued)
306
Corrosion Resistant Materials Handbook VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued)
TABLE 2.12:
One Month Immersion at 75O 2 SF Volume Change X Cupric Chloride Cupric Sulfate Ferric Chloride Ferric Nitrate Ferrous Sulfate Magnesium Chloride Magnesium Sulfate Nickel Sulfate Potassium Chlorida Potassium Permanganate Potassium Bisulfite Potassium Dichromate Sodium Borate (8oru) Sodium Bicarbonate Sodium Chloride Zinc Chloride Zinc Nitrate ORGANIC ACIDS AcetIc Acid (10%) Acetic Acid (Glacial) Chloracetic Acid (10%) Citric Acid (10%) Fornw Acid (10%) Lactic Acid (10%) Oleic Acid (100%) Oxahc Acid (10%) Phenol (10%) Phenol (100%) Plcric Acid (10%) Steanc Acid (100%) Tanruc Acid (10%) Tartarlc Actd (10%) ALCOHOLS Benryl Alcohol Ethyl Alcohol Isopropyl Alcohol Methyl Alcohol Ethylane Glycol Glycerdl 1 .Hesarul ResorcinU ALMHYMS Renraldchyde Butyraldehyde Furfuraf AYINES Aniline Triethandamine UDMH ESTERS Amy1 Acetate Dlbutyl Sebacate Oioctyl Phthalate Ethyl Acetate Tr~~resyl Phosphate ETHERS O~benryl Ether Diethytene Glycd Monobutyt Ether Ethyl Ether Ethylene Glycol Monoethyl Ether +12.1 +1.32 -t-58.7 +1.29 loo.6 102.4 30.7 103.0 106.5 107.8 65.5 105.3 -16 -2 -24 -2 Unchanged Tacky Tacky Tacky +0.36 +0.39 G.00 +0.25 0.00 -1.04 +3.39 +0.32 +10.4 +21.6 +0.11 +5.07 +0.13 +10.5 +46.4 +22.8 +1.85 -l-24.2 -0.13 103.0 94.6 94.6 100.0 85.5 98.8 101.2 100.0 102.4 66.3 106.6 110.8 101.2 59.0 39.2 80.1 101.2 95.3 101.2 100.6 99.4 98.0 102.6 85.7 99.4 io3.3 98.0 106.9 81.4 106.5 108.4 100.0 82.4 45.1 96.1 103.9 86.9 103.9 -1 -8 fl -1 +3 +3 -3 +3 -15 -20 -5 -6 +4 -13 -23 -17 -1 -13 f2 Tacky SI. Tacky SI. Tacky SI. Tacky SI. Tacky Tacky SJ. Tacky SI. Tacky SI. Tacky SI. Tacky Tacky -1.00 +0.48 -0.11 +0.68 +0.70 +1.66 -0.12 0.00 -0.56 +4.09 +0.23 +0.63 +0.37 +0.25 -0.37 -0.12 0.00 Tensik strength Retained % 98.8 95.8 98.8 101.2 89.2 98.8 97.6 96.4 95.8 83.1 101.2 98.8 97.6 95.2 100.0 96.4 96.4 Elongation Retained K 93.5 96.1 97.5 101.4 93.5 97.5 93.5 97.5 94.7 78.4 loo.0 97.5 98.0 93.5 100.0 93.5 96.7 Hardness Change Pts. +3 +2 +3 +2 +2 +2 +2 +2 +3 +2 +2 +3 +3 i-3 +3 +3 f4 surface! Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Brittle Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
+1.88 +3.90 +1.24 -1.28 +0.38 0.00 +43.7 +0.23 +0.94 +0.59 +0.46 +6.14 -0.13 -0.36
105.4 97.6 105.4 97.0 96.4 98.2 69.3 98.8 109.7 105.4 105.4 106.6 96.4 98.8
105.3 102.5 105.9 97.5 94.7 95.5 81.0 98.0 108.4 108.4 102.6 109.8 92.8 96.1
+3 -2 +3 +4 f3 +4 -16 +3 fl -2 +2 -1 +3 f5
Tacky St. Tacky St. Tacky St. Tacky SI. Tacky SI. Tacky Unchanged
SI
SI. Tacky SI. Tacky Sl. Tacky St. Tacky Unchanged Unchanged St. Tacky
SI. Tacky SI. Tacky Unchanged Unchanged SI. Tacky St. Tacky Tacky Tacky
(continued)
Rubbers
and Elastomers
307
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
One Month Immersion at 75 * 5-F Vdwnt ww HYDROCARBONS Tensilt Strangth Rttaintd w 26.5 22.9 24.7 22.9 23.5 92.8 23.5 22.3 Elongation Retained% 27.5 18.2 23.5 21.0 21.0 82.9 22.9 20.2 Hardntss Change Pts. -27 -28 -31 -27 -27 -13 -29 -30 Surfact Condition
Btnztnt
Cyclohtxant Ethylbenzene Htptant Hcxane Naphthaltnt Tolutnt

Xyltnt
+71.4 +206.3 +167.4 +136.6 +160.8 +75.5 +123.6 +182.0
Unchanged Sl. Tacky SI. Tacky SI Tacky SI. Tacky Sl. Tacky Tacky SI. Tacky
HALOGENATEO HYDROCARBONS Btnryl Chloride Bromobenzene Carbon Tetrachloride Chloroform

Ethylene Oachlorlde
+12.8 +123.1 +192.0 +158.1

+25.6
57.2 24.9 22.9 21.7

50.0
77.5 26.1 18.2 19.7

62.8
-20 -31 -29 -30

-18
Per;hloroe!hyltt OTHER SUBSTITUTED HYDROCARBONS Carbon Dlsulflde Nltrobenzene KETONES Acetone

Mcthvl Methyl
+207.3
19.9
15.7
-32
Tacky SI. Tacky Unchanged SI. Tacky SI. Tacky SI. Tacky
+123.5 +7.64 +6.07 +10.2 +23.3
23.5 105.4 88.0 82.5 67.8
21.0 105.3 93.5 87.7 74.5
-28 -13 -10 -13 -18
SI. Tacky SI. Tacky SI. Tacky SI. Tacky SI. Tack;
Ketone lsobutyl Ketone

EIhvl
DETERGENTS &OTHER CLUNING PRODUCTS Calgon1te (1%) C1orox (1%) Clorox (Cont.) Joy (1%) JOY (Cone ) LestoIl (1 a) Lux Flakes (1%) Rlnst Dry (1%) Rinse Dry (Cont.) Tide (1%) NATURAL FATS L OILS Buntr Castor 011 Cononsetd 011 Lard Oltomargarint Olwt 011 Whltt Mmtral 011 OILS FUELS A.S.T.M. 1 011 No. 2 A.S.T.M. No. 011 A T.M. Fuel A.S.T.M Fuel A.S.T.M. Fuel Heating Fuel Jet Aircraft Oil Ktrosmt AUTOMOTIVE PRODUCTS Chassis Grease Motor 011 ( 1OW 30) Gasohne (RON 94) Gasoltnt (RON 99) Gasollnt (RON 102) Gasolvw. unleaded
-0.38 +0.64 +2.09 +0.13 -11.1 +1.55 +0.35 +0.36 0.00 +0.26 +2.12 -0.39 -I-2.49 +3.77 +2.51 +2.38 +13.1 +9.10 +9.88 +39.4 +84.2 + 143.8 +155.6 +59.6 + 17.2 +163.0
101.1 104.2 102.4 98.8 101.8 131.8 137.2 100.0 95.8 100.0 97.0 98.2 99.4 95.2 104.2 101.2 54.2 83.1 81.9 47.0 27.1 22.3 21.7 25.3 86.1 25.9
102.5 103.9 101.0 98.6 99.4 104.5 106.5 97.5 93.5 101.4 102.6 98.0 102.6 103.3 105.9 106.5 58.8 88.8 84.3 44.5 23.5 20.2 19.0 23.0 100.6 21.6
+3 +3 +2 +3 +4 +2 +3 +3 +3 +2 -3 -I-4 +1 -3 -3 -1 -13 -5 -6 -19 -27 -31 -31 -31 -13 -32
Unchanged Tacky Tacky Tacky Tacky St. Unchanged Tacky Tacky Unchanged Tacky SI. Tacky Unchanged Unchanged SI. Tacky Unchanged SI. Tacky SI. Tacky Unchanged Unchanged Unchangtd Unchanged Unchangtd SI. Tacky Unchanged
+13.3 +21.8 +137.9 +145.7 +15B.4 +181.6
75.9 50.6 23.5 21.1 22.3 23.5
77.8 51.0 19.6 19.6 21.0 20.2
-7 -18 -31 -31 -31 -31
Sl. Tacky Unchanged Unchanged Unchanged Unchangtd Unchanged
(continued)
308
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
One Month lmmcrsion at 75O -C 5OF volume Chanrm % HYDRAULIC FLUIDS
TensileStrength Elongation
Retained K Ratained K
Hardness Chanee Pts.
Surface Condition
Oron1tc 8200
Pydraul F.9 Pydraul 60
+2.81 +3.97 -3.04
101.8 103.0 105.4
loo.0 103.3 104.5
-1 -1 +2
Unchanged SI. Tacky SI. Tacky
Skydrol
Skydrol 500 MISCELLANEOUS Gelatin (sat. soln.) Glucose (sat. soln.) Tincture of Iodine Prestonc antifreeze Dowgard antifreeze
+1.01
+0.54 +1.24 +0.23 +6.44 +o.!X +0.73
112.1
107.2 99.4 96.4 93.4 98.8 98.2
111.2
108.4 96.7 96.1 85.7 100.0 97.5
-2
-2 +3 +2 +1 +3 +4
St. Tacky
Sf. Tacky SI. Tacky SI. Tacky SI. Tacky SI. Tacky Unchanged
Three Months lmmcrsion at 7S = 5OF volume Challm n WATER Distilled Water Saa Water--Atlantic Sea Water-Pacific INORGANIC ACIDS Boric Acid (10%) Chlorosulfonic Acid (10%) Chromic Acid (10%) Chromic Acid (Cow.) Hydrochloric Acid (10%) Hydrochloric Acid (Cont.) Hydrofluoric Acid (Cont.) Nitric Acid (10%) Nitric Acid (Cont.) Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acid (Cont.) INORGANIC BASES Ammonium Hydroxide (10%) Ammonium Hydroxide (Cow) Barium Hydroxide (Cont.) Calcium Hydroxide (10%) Potassium Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cow.) INORGANIC SALTS (25% Solutions) Aluminum Chloride Aluminum Sulfate Ammonium Chloride Ammonium Nitrate Ammonium Phosphate Barium Chloride Barium Sulfide Calcium Chloride Calcium Hypochlorite Cupric Chloride Cupric Sulfate Ferric Chloride Ferric Nitrate Ferrous Sulfate Magnesium Chloride Magnesium Sulfate Nickel Sulfate Potassium Chloride Potassium Permanganate -0.12 +0.13 -0.24 -0.13 -0.13 -1.30 -0.91 +0.36 +1.09 -1.13 +0.24 0.00 +0.68 +0.93 -0.26 +0.46 +0.33 -0.32 +2.90 99.4 102.4 98.2 98.8 96.4 97.0 99.4 98.8 98.8 104.8 loo.0 97.6 102.4 97.6 97.6 103.0 103.6 98.8 78.9 94.1 101.4 98.0 101.4 98.6 96.1 96.1 96.1 98.0 102.5 101.4 96.1 100.6 96.1 97.5 94.7 103.3 99.4 77.1 +3 +3 +4 +3 +5 +4 +3 +4 +3 +4 i-4 +6 +4 +3 i-4 +3 +4 +5 -3 Sf. Tacky Unchanged Unchanged Sf. Tacky St. Tacky Unchanged Unchanged Unchanged Unchanged Sf. Tacky Unchanged Sf. Tacky Sl. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Brittfe +0.11 .+0.32 i-o.37 -0.11 Disintegrated +6.52 i-47.4 -0.65 +11.8 +1.42 +0.88 Disintegrated Tensfle strength Retained % 103.0 102.4 98.8 94.0. 80.7 1.8 95.2 77.7 98.8 96.4 Elongatfm Retained % loo.0 101.4 96.1 93.5 88.8 13.5 97.5 115.7 98.6 95.5 Hardness Change Pts. +3 +3 +2 +2 -2 -33 +3 -3 -2 0 Surface Condition SI. Tacky Unchanged SI. Tacky SI. Tacky Unchanged V. Tacky SI. Tacky Sl. Tacky Unchanged Tacky
+0.11
+0.74 Disintegrated -l-2.42 i-2.88 +1.21 +0.93 0.00 +0.23 +0.55
100.0
98.2
99.4
96.1
+3
+4
SI. Tacky
SI. Tacky
108.4 109.0 98.8 101.2 102.4 98.8 104.2
102.0 102.6 93.5 101.4 99.4 95.5 98.6
+3 -2 f4 +3 +3 +2 -2
SI. Tacky SI. Tacky Unchanged Unchanned Unchanged Unchanged Unchanged
(continued)
Rubbers
and Elastomers
309
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Three Vdume Change Potassium Potassium Sodium Sodium Sodturn Elsulflte Dlchromate Borate Chlwde (Borax) Bicarbonate +2.29 0.00 0.00 -0.12 -0.49 -0.12 0.00 ACIDS +2.58 +8.20 +3.34 0.00 +I.76 +0.68 +90.3 +0.35 +2.97 +8.26 99.4 89.2 107.8 98.8 103.0 100.0 48.8 101.2 107.8 104.2 x Tensik Strength X
Months
immersion Elongation Retained 107.8 100.0 97.5 98.0 98.6 98.0 96.7 %
at 75O -
5F Surface Pts. Condition Unchanged Unchanged Unchanged Unchanged Unchanged St. Tacky St. Tacky
Hardness Change +1 +4 +4 +4 +5 +5 +5
Retained 106.6 101.2 96.4 loo.0 100.0 97.0 97.6
21nc ChlorvJe 210~ NItrate
ORGANIC AcetIc AcetIc
Acid (10%) Acld (Glacial) Acid (10%)
102.6 101.0 99.4 100.0 loo.0 98.0 59.4 98.0 111.2 119.0 -9 +2 +3 +3 +3 -26 +3 -3 -17
SI. Tacky SI. Tacky SI. Tacky SI. Tacky SI Tacky SI. Tacky Unchanged SI. Tacky SI Tacky
Chloracetlc Citric Formic Lactic
Acid (10%) Acid (10%) Acld (10%)
Ole~c Actid (100%) Oxalic Phenol Phenol PWXIC Steanc Tanmc Tartax Acid (10%) (10%) (100%)
SI. Tacky
Acid (10%)
Acid (100%) Acid (10%) Acld (10%)
+0.81
+13.9 0.00 -0.12
97.6
106.6 102.4 93.4
94.7
107.8 101.4 90.2
+1
-2 +2 +3
St. Tacky
Unchanged St. Tacky SI. Tacky
ALCOHOLS Benryl Ethyl Methyl Ethylene Glycerol 1 -Hexanol ReSoWlnOl ALDEHYDES Benzaldehyde Butyraldehyde Furfural AMINES Aniline Trlethanolamine UDMH ESTERS Amy1 Acetate Dlbutyl Dwtyl Ethyl Sebacate Phthalate Acetate Phosphate +11.8 +0.57 +7.90 95.2 101.2 57.2 +9.66 +21.7 -l-2.57 91.6 57.8 105.4 100.9 78.4 103.9 -17 -18 -7 SI. Tacky SI. Tacky SI. Tackv Alcohol Alcohol Alcohol Alcohol Glycol -0.96 0.00 +0.36 -0.36 -0.37 100.0 97.6 97.6 92.7 92.8 98.6 100.6 100.0 90.8 94.1 +3 -4 -1 -1 0 SI. Tacky SI. Tacky St. Tacky Sl. Tacky St. Tacky
Isopropyl
-0.25 +7.24 +0.76
100.0 86.8 loo.7
94.1 97.5 98.6
+5 -11 +3
Sl. Tacky
Tacky
Sl. Tacky
101.9
99.4 74.5
-13
+3 -12
Sl. Tacky
Unchanged UnChanRed
Tricresyl ETHERS Dibenzyl Ditthyltne Ethvl
-l-47.2 +23.5 +5.36 +10.9 +0.75 +11.6 +2.56 +57.4

+2.05
40.4 89.8 106.0 78.9 102.4
47.7 103.3 107.8 88.2 103.3
-22 -17 -3 -12 +3
Unchanged Unchanged SI. Tacky St. Tacky Sl. Tacky
Ether Glycd Monobutyl Ether
103.0 107.8 30.1 97.0
107.8 113.1 32.8 98.0
-13 -7 -25 -5
Unchanged St. Tacky Unchanged s1. Tacky
Ether Glycol Monoethyl Ether
Ethilent
HYDROCARBONS Benztne Cvclohtxant Ethylbenzene Heptone
+101.9 +230.2 +176.0 +178.0
25.9 21.7 19.3 23.5
25.5 17.7 20.2 20.9 22.6 00.4 22.9 21.0
-28 -28 -31 -28 -27 -7 -29 -30
Unchanged Unchanged g. Tacky
Sl. Trky Y. Tacky
Htxtnt
Naphthaltne Toluenc Xylenc
+169.0
+50.4 +114.8 +154.5
22.9
89.8 23.5 22.3
SI. Tacky SI. Tacky St. Tacky (continued)
310
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Three Montlta Immersion at 75O 2 5OF
1-w
R8tdlled%
HALDGENATED HYDROCARBONS Benzyl Chloride Bromobcnrtnt Carbon Tttrachloridt Chloroform Ethylene Dwzhloridt Ptrchlorotthyltnt OTHER SUBSTITUTED HYDROCARBONS Carbon Dmlfedt Nmobtnztnt KETONES Acetone Methyl Ethyl Ketone Methyl lsobutyl Ketone DETERGENTSaOTHER CLEANING PRODUCTS Calgonltt (1%) Clorox (1%) Cloror (COOC.) JOY (1%) Joy (Cone ) LestoIl (1%) Lux Flakes (1%) Ruvt Dry (1%) Rinse Dry (Cont.) Tide (1%) NATURAL FATS & OILS Butter Castor OrI +25.1 +114.4 +199.5 +137.7 +25.2 +212.4 57.8 24.7 20.5 la7 48.8 la7
-w~InedW 79.8 25.5 17.7 20.2 60.2 15.7
Hardness Chan8a Fts. -20 -32 -31 -30 -18 -30
surface
Condition SI. Tacky SI. Tacky Unchanged SI: Tacky SI. Tacky SI. Tacky
+183.4 -l-4.77 +6.14 +19.7 +22.2
19.3 86.1 89.2 86.8 56.0
20.2 98.6 97.5 94.1 70.0
-30 -12 -9 -12 -17
SI. Tacky SI. Tacky SI. Tacky Unchanged SI. Tacky
+0.50 +1.28 +1.48 +0.63 -11.32 +2.74 +0.71 +0.72 -0.36 +0.65 +8.92 -0.65 +5.18 +7.OO +6.52 +7.87 +53.6 +20.0 +lB.9 + 103.2 +162.9 +185.5 + 197.8 +190.0 +27.0 + 197.2 +19.8 +93.0 +189.0 + 182.4 +189.6 + 196.9 +4.56 +6.08 +1.39 +4.32 +1.67
98.8 101.2 106.0 96.7 98.8 102.4 98.8 95.2 93.4 101.2 101.2 95.2 95.8 97.0 106.6 94.8 41.0 74.1 74.1 34.9 25.9 22.3 22.3 22.9 66.9 22.3 54.4 37.8 21.7 21.1 19.9 20.5 97.0 107.8 106.0 1102 112.0
103.3 103.9 103.9 98.0 102.6 105.9 97.5 96.6 96.6 103.3 102.0 94.1 100.6 103.3 106.5 100.6 42.6 82.9 78.4 33.9 24.2 21.6 21.6 22.2 88.2 21.6 59.4 39.2 20.2 22.2 21.0 20.2 99.4 112.3 105.9 105.3 109.8
+3 +2 -1 +3 fl -1 +2 +2 +3 -2 -7 -4 -6 -4 -3 -7 -26 -8 -9 -27 -28 -29 -30 -32 -19 -31 -13 -37 -31 -31 -32 -32 -2 -4 -3 -3 -3
Unchanged SI. Tacky Tacky SI. Tacky Tacky SI. Tacky Unchanged SI. Tacky SI. Tacky SI. Tacky Unchanged SI. Tacky SI. Tacky Unchanged SI. Tacky SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Sl. Tacky Unchanged Unchanged Unchanged SI. Tacky Unchanged Sl. Tacky SI. Tacky SI. Tacky Sl. Tacks Unchanged SI. Tacky SI. Tacky SI. Tacky Si. Tackv
Cononsetd 011
Lard Oltomargarine
Olwt 011
White Mmtral Ott OILS & FUELS A.S.T.M. No. 1 Oil A.S.T.M. No. 2 011 A.S.T.M. No. 3 011 A.S.T.M. Fuel A A S.T M. Fuel B A.S.T M. Futl C Htatmg Fuel 011 Jet Awcraft Engine Oil Ktrosint AUTOMOTIVE PRODUCTS Chassis Grease Motor 011 (low 30) Gasohnt (RON 94) Gasoline (RON 99) Gasolmt (RON 102) Gasoline.* unltsdtd HYDRAULIC FLUIDS Oronttt 8200 Pydraul F-9 Pydraul 60 Skydrol Skvdrol 500
(continued)
311
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMlCALS
(continued)
Three Months Immersion Jt X0 2 5iF Vdwm CftJrrwx MISCELLANEOUS GJlJtln (SJt Soln.) Glucose (sat soln.) Tincture of Iodine Prestone antifreeze DOwgIrd JntifrJJZJ 0.00 +0.23 +12.5 +1.44 +1.33 TJmitJSbmngth R~bined K DJngJtknl Retained% 104.9 95.5 66.1 loo.0 95.5 fbrdncss ChJnp PLs. +3 +3 -2 -1 +3 SUrfJcJ bnditkm Si. TJCky Sf. TJCb Unchanged St. TJcky UnChJngJd
101.2 100.0 78.9 101.2 97.6
Six Months Immersion at 75O 2 IoF Vdume Charwe% WATER Distilled WJtJr !$ZJ Water-AttJntlC Sea Water-Pacific INORGANIC ACIDS Boric Acid (10%) Chlorosulfonic Acid (10%) Chromic Acid (10%) Chromic Acld (Cont.) Hydrochloric Acid (10%) Hydrochloric Acid (Cont.) Hydrofluoric Acld (Cont.) Nitric Acid (10%) Nitric Acid (Cont.) Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acld (Cont.) INORGANIC BASES Ammonium Hydroxide (10%) Ammomum Hydroxide (Cont.) Barium Hydroxide (Cont.) CJlcium Hydroxide (10%) Potrsswm Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cont.) INORGANIC SALTS (25% Solutions) Aluminum Chloride Aluminum SulfJte Ammonium Chloride Ammonium NitrJtJ Ammonium Phosphate SJrium Chloride Barium Sulfide CJlcium Chloride CJlcium Hypochlorite Cupric Chlortdr Cupric S,,ffJtJ FJrric Chloride Ferric NitrJtJ Ferrous SulfJtJ MJgnJsium Chloride MJgnesium Sulfite Nickel SulfJte PotJssium Chloride PotJssium PermangJnJte PotJsswm Bisulflte PotJsslum Dichromrte Sodium Borate (8orrx) SJdlUm 8iCJrbonJtJ Sodwm Chlonde Zmc Chlorde 2IK NltrJtJ -0.23 Disintegrated +12.4 +4a.3 -0.52 +8.52 +2.36 +1.13 Disintenrated +0.11 +0.61 DisintJgrJted +4.61 +5.14 +0.89 +0.82 +0.68 +0.35 +1.33 98.8 66.9 2.41 97.6 54.8 87.4 95.8 102.4 99.4 103.3 77.8 9.8 96.7 103.9 80.4 93.5 100.6 101.4 +2 -6 -27 +2 -8 -2 +1 +3 +4 SI. Tacky Tacky V. Tacky SI. Tacky SI. Tacky SI. Tacky V. Tacky TJcky Tacky +0.90 +0.32 +0.25
fJ"SilJ Stmgth
Retained K 101.2 105.4 105.4
ElcwlgJtion RJtainJd SC 102.6 104.5 100.6
HJrdness Change Pts. +4 +4 +3
SWfJcC Ccmdition Unchsnged UnchJnged Unchanged
111.5 108.4 101.2 101.2 101.2 109.6 106.6
103.9 96.7 97.5 95.5 96.7 97.5 100.6
+2 -3 +4 +4 +3 +3 -2
Unchanged St. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged
+0.81 +1.21 -0.61 0.00 0.00 +0.47 +0.26 +1.45 +1.58 -f-o.37 +0.84 +0.22 +1.23 +1.16 +0.26 +1.0) +0.66 +oz? +-a47 +5.51 +1.02 +0.85 i6.76 +D.25 +0.47 +0.36
96.4 95.8 94.0 96.4 98.2 88.6 97.6 95.8 110.8 96.4 94.6 100.6 100.0 98.8 96.4 101.8 100.0 94.6 85.5 111.5 96.4 94.0 96.4 94.6 94.6 101.8
90.2 83.7 92.8 95.5 98.0 86.9 95.5 96.7 103.9 96.1 92.8 101.4 99.4 96.1 96.1 94.7 101.4 94.7 88.2 108.4 95.5 96.1 93.5 95.5 92.2 103.3
+2 +2 +3 +2 +3 +3 +2 +2 -2 +2 +3 -l-3 +1 +2 +3 +2 +2 +1 -2 -3 +3 +2 +2 +2 +3 +4
Sl. TJcky UnchJngJd SI. Tacky St. TJcky St. TJC~~ Unchrnged UnChJngJd UnchJngJd St. TJC~~ St. Trky UnChJngJd UtWhJngJd T-=b UnchJnged UnchJnged UrKhJngcd UnchJngJd Sl. Tacky Brittle Unchrnged UnChJngJd UnchJngad UtKhJngJd St. Tacky Sf. Trky SI. Tuky
(continued)
312
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Six Months Immersion VdunW

ww
at 7S
2 VF
Hldll8SS surfra
TensileStrength
Robined%
Elongation
RetahdW
ChangePts. +1 -9 +2 +5 +3 +3 -26 +3 -7 -15 +2 -2 +3 +3 -6 -2 -6 -1 +4 +3 -10 +2 -13 -18 -8 -14 +3 -9 -23 -18 -7 -12 +2 -13 -9 -35 -7 -30 -31 -31 -28 -28 +2 -32 -31
Condition Sl. Tacky Sl. Tacky Sl. Tacky SI. Tacky SL Tacky Sl. Tacky Unchanged SI. Tacky SI. Tacky Sl. Tacky Sl. Tacky Unchanged Sl. Tacky Sl. Tacky SI. Tacky St. Tacky SI. Tacky SI. Tacky Sl. Tacky Unchanged Tacky St. Tacky SI. Tacky Unchanged TsClcy Sl. Tacky St. Tacky Sl. Tacky Unchanged Unchanged Si. Tacky Unchanged Tacky Unchanged Unchanged Unchanged 9. Tacky Unchanged St. Tacky Unchanged Sl. TIJly Tacky SI. Tacky Tacky Sl. Tacky
ORGANIC ACIDS Acetic Acid (10%) Acetic Acid (Glacial) Chloracetic Acid (10%) Citric Acid (10%) Formic Acid (10%) Lactic Acid (10%) Oleic Acid (100%) Oxalic Acid (10%) Phenol (10%) Phenol (100%) Picric Acid (10%) Stearic Acid (100%) Tannic Acid (10%) Tartaric Acid (10%) ALCOHOLS Bcnzyl Alcohol Ethyl Alcohol Isopropyl Alcohol Methyl Alcohol Ethylene Glycd Glycerol l-Hexand Rcsorcinol
ALOEHYDES
+4.58 +a.44 +4.00 +0.38 +3.14 +0.68 +93.9 +1.15 +5.69 +6.16 +3.34 +17.9 +0.65 +0.60 +3.70 +0.51 +1.23 +1.19 -0.24 0.00 +6.92 +2.46 +7.10 +21.6 +2.83 +10.6 +2.38 +4.89 +45.6 +21.6 +6.14 +11.8 +0.87 +9.92 +3.71 +52.6 -l-3.33 +112.2 +205.9 +140.0 +141.2 +129.3 +41.8 +139.5 +1642
104.2 07.4 114.5 98.2 103.0 101.8 43.4 101.2 108.4 105.4 106.0 101.8 100.6 98.8 104.8 89.8 89.2 97.0 92.8 95.8 91.6 97.0 86.1 99.4 108.4 98.8 97.0 51.2 42.2 93.4 109.6 81.3 105.4 108.4 102.4 29.5 101.2 27.1 22.3 20.4 25.3 21.7 81.3 21.7 21.7
101.4 96.1 103.9 92.2 101.4 99.4 57.5 102.6 109.8 113.7 104.5 101.4 97.5 98.0 103.9 96.7 90.8 loo.0 90.2 89.6 102.0 93.5 94.1 103.9 106.5 103.9 88.2 66.7 51.6 lD4.5 117.6 90.8 104.5 101.1 105.3 33.9 101.4 29.4 17.7 21.6 22.9 21.0 77.1 22.2 21.0
Bsnzaldehyde Butyraldehyde Fur(ural AMINES Aniline Triethanolamine UOMH ESTERS Amy1 Acetate Dibutyl Ssbacate Dioctyl Phthalate Ethyl Acetate Tricresyl Phosphatr EIHERS Olbenzyl Ether Diethylena Glycoi Monobutyl Ether Ethyl Ether Ethylene Glycol Monoethyl Ether HYDROCARBONS 8eruene Cyclohexane Ethylbenzene Heptane Hexarm Naphthalene Tduene XylWN HALOGENATEO WYOROCAR8ONS Eenzyl Chloride Bromobeozene Carbon Tetrachloride Chloroform Ethylene Dxhloride Perchloroethylene
+27.3 +115.6 +213.3 +170.1 +26.7 +220.0
57.3 24.7 21.7 19.9 56.0 19.9
78.4 26.1 19.0 21.0 70.6 18.2
-21 -32 -31 -32 -18 -33
Tacky SJ. Tacky Unchanged Sk Tacky SI. Tacky Unchanged
(continued)
313
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Six Months Immersion Jt 75 = 5F VOlUmC

ChJnmu OTHfR
lmsile Stnmgth RetJined SC
Elongation Retained K
HJblJJJ
SWfJCJ
Ch~nnJ Pts.
Condition
SU8STITUTEo +118.D +4.59 +5.29 +9.22 +22.4 21.7 103.0 84.3 82.5 59.6 20.2 104.5 89.6 86.9 74.5 -30 -9 -8 -11 -16 St. TJCky Tacky Unchanged St. Tacky SI. Tacky
HYORDCARBONS
Carbon Dlsulflde Nllrobenzcne KETONES Acctonc Methyl Ethyl Ketone Methit lsobutyl Ketone DETERGENTS&OTHER CLUNING PRODUCTS Calgonlte (1%) Cloror (1%) Cloror (Cow) JO 11%) Joy (Cone ) LestoIl (1X) Lux Flakes (1%) Rlnre Dry (1%) Rlnre Dry (Cow ) Tide (1%) NATURAL FATS L OILS Butter CJStOr 011 CoItonsud 011 Lard Oleomargarine OIIVC 011 White MlnerJl 011 OILS L FUELS A.S.T.M No. 1 Oil A S T.M No. 2 011 A S T.M No. 3 011 ASTM FuelA A.5 T.M. Fuel 8 A.S T.M Fuel C Heating Fuel 011 Jet Atfcr~fi Engcne 011 Kcros~ne AUTOMDTIVC PRODUCTS Chassrs Grease Motor 011 (lOW.30)
GJSOIWW GJSO~IIW GJSO~IW (RON (RON 94) 99)
i-O.88 +2.43 +1.85 +1.79 -11.3 +2.86 +1.30 +1.20 -0.50 +0.92 + 12.6 -D.92 +6.41 +11.8 +8.06 +12.0 +95.1
106.6 107.2 108.4 104.2 98.8 104.2 104.2 95.2 100.0 97.6 105.4 96.4 106.6 106.6 107.8 99.4 36.8 56.0 54.2 30.1 23.5 20.5 19.9 20.5 60.8 22.3 50.0 31.9 19.9 18.7 16.9 21.1
105.9 100.6 105.3 104.5 98.0 102.5 102.5 95.5 96.1 96.7 104.5 95.5 107.8 109.2 107.8 105.9 33.3 67.3 63.3 28.8 23.5 21.6 21.6 21.0 84.3 21.6 52.0 32.8 21.6 21.6 20.2 21.0
+5 +3 +2
t3
+3 +2 +3 +3 +3 +3 -12 +3 -4 -11 -7 -12 -26 -16 -17 -30 -28 -33 -32 -32 -21 -32 -21 -31 -32 -33 -33 -32
SI. SI. Sl. SI. Sl.
Tacky Tacky Tacky Tacky Tack;
SI. Tacky Unchanged SI. TJcky Si. Tacky SI. Tacky Unchanged Tacky SI. Tacky Unchanged Unchanged SI Tacky SI. Tacky Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Tacky
Unchanged
t30.8
+34.6 t 146.5 t-161.5 t189.7 t200.9 t 195.0 t41.7 t211.2
Unchanged Unchanged SI. Tacky Unchanged SI. Tacky SI. Tacky SI. Tacky SI. Tacky
t38.0
t118.4 +192.5 +1?6.9 +192.0 +201.9
(RON 102) GJsohne:* unleaded
HYDRAULIC FLUIDS Orontite 8200 edrJul F.9 Fydraul 60 Skydrol Skvdrol 500 MISCELIANEOUS Gelatin (sat. soln.) Glucose (sat. soln.) Tincture of Iodine Prestone Jntitreeze Dowgard Jntifreeze
+11.6 +7.89 t2.01 +4.98 +3.24
99.4 112.7 101.2 106.0 103.6 98.8 98.8 53.6 99.4 94.8
104.5 115.1 103.3 108.4 105.9 96.1 94.1 40.6 100.0 92.8
-7 -7 -3 -8 -6 +2 +3 -5 0
t3
Unchanged SI. Tacky SI. Tacky SI. Tacky SI. Tacky St. TJC@ Tacky Unchanged Unchanged Unchanged
+1.86 +0.23 +16.2 +I.67 to.39
(continued)
314
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
12 Months Immersion at 7S = 5F volume Chena K WATER Distilled Water Sea Wlter-Atlantic Sea Water-Pecifii INORGANIC ACIDS Boric Acid (10%) Chlorosulfonic Acid (10%) Chromic Acid (10%) Chromic Acid (Cont.) Hydrochloric Acid (10%) Hydrochloric Acid (Cont.) Hydrofluoric Acid (Cont.) Nitric Acld (10%) Nitric Acid (Co&) Phosphoric Acid (Cont.) Sulfuric Acid (10%) Sulfuric Acid (Cont.) INORGANIC BASES Ammomum Hydroxbdc (10%) Ammomum Hydroxide (Cope.) Barwm Hydroxide (Cont.) Calcium Hydroxide (10%) Potassium Hydroxide (10%) Sodium Hydroxide (10%) Sodium Hydroxide (Cont.) INDRCANIC SALTS (25% Solutions) Alummum Chloride Aluminum Sulfate Ammomum Chloride Ammonium N&rate Ammomum Phosphate Barwm Chloride Barium Sulfide Calcium Chloride Calcwm Hypochlorite Cupric Chloride Cupric Sulfate Ferric Chloride Ferric Nitrate Ferrous Sulfate Magnesium Chloride Magnesium Sulfate Nickel Sulfate Potassium Chloride Potassium Permanganate Potassium Bisulfite Potassium Dichromrte Sodium Borate (Borax) Sodium Bicarbonate Sodwm Chloride Zinc Chlor& Zinc Nitrate ORGANIC ACIDS Acetic Acid (10%) Acetlc Acid (Glacial) Chloracetlc Acid (10%) Citric Acid (10%) Fonmc Acid (10%) Lactic Acid (10%) Olelc Acid (100%) -l-O.78 +0.43 -0.25 -1.95 Disintegrated +20.2 f49.6 +0.37 +11.2 +2.18 +1.6f Disintegrated +0.11 -0.12 Disintegrated -l-5.88 +7.39 +1.02 +1.05 +0.23 +0.93 +1.77 Tensik sbmgth Retained w 95.2 100.6 98.8 98.8 56.6 5.42 104.8 56.0 90.4 101.2 98.8 95.2 Elongatii Retained% 96.1 102.5 96.1 106.5 77.8 12.3 102.0 88.8 67.2 101.4 101.4 95.5 Hardness ChannePts. +3 +4 +4 +3 -10 -21 +2 -11 0 0 +3 +4 Surface Condition Unchanged Unchanged Unchanged Tacky Tacky V. Tacky Tacky SI. Tacky SI. Tacky V. Tackv Tacky Tacky
106.0 101.2 100.6 96.4 100.0 104.8 104.8
96.1 89.6 99.4 98.6 96.1 99.4 101.4
-1 -3 i-3 f3 +3 +1 -4
Unchanged SI. Tacky Unchanged Unchanned Unchanged Unchanged Unchanged
+0.34 +1.34 +0.12 +0.13 +1.03 +0.47 +0.51 +1.55 +1.82 +0.13 +1.80 +0.44 +1.25 +0.81 +0.38 +0.69 +0.11 +0.56 +a.34 +7.80 +0.63 +0.73 +0.12 -0.99 +0.23 +0.24
98.2 103.6 95.2 98.2 101.8 104.8 98.2 95.8 107.8 94.0 96.4 98.8 93.4 97.0 94.0 94.6 94.6 98.8 80.7 113.3 98.8 100.6 98.8 93.4 98.2 93.4
97.5 105.3 99.4 99.4 103.9 105.9 91.6 94.1 107.8 96.1 99.4 98.0 98.0 95.5 96.7 96.7 99.4 100.0 87.7 102.0 99.4 103.9 100.0 96.7 100.0 94.7
+2 +3 +3 +3 +3 +4 +2 +1 -1 +4 +4 +3 +1 +3 +3 +4 +3 +1 -3 -4 +3 +3 +2 +3 +3 +4
St. Tacky Unchanged SI. Tacky SI. Tacky Sl. Tacky Unchanged Unchanged Unchanged Sl. Tacky St. Tacky Unchanged Unchanged Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Brittle Unchanged Unchanged Unchanged Unchanged Unchanged St. Tacky St. Tacky
+5.63 +10.7 +5.45 +0.38 +4.15 +0.45 +95.7
103.0 88.6 133.1 98.8 107.2 98.8 45.8
103.9 92.2 99.0 101.4 105.9 100.0 59.4
-1 -9 -1 +3 +2 +2 -27
SI. Tacky SI Tacky Sl. Tacky SI. Tacky Sf. Tacky Sl. Tacky Unchanged
(continued)
315
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
12 Months immersion at 75O 2 5F VolUmC charwe x Oxalc Acld (10%) Phenol (10%) Phenol (100%) PICNIC Acid (10%) Stcarx Acid (100%) Tannx Acid (10%) Tartarlc Actd (10%) ALCOHOLS &nzyl Alcohol Ethyl Alcohol lsoprowl Alcohol Methyl Alcohol Ethylene Glycol
Glyctrd
TenaifeSbangth Retained K 105.4 115.1 98.8 101.2 108.4 100.0 100.6 104.8 94.0 92.2 97.6 94.6 95.2 84.3 108.4 92.2 91.6 103.6 98.8 94.0 58.4 39.8 85.5 104.8 78.3 101.8 106.6 96.4 31.3 101.2 20.5 16.3 21.7 19.3 21.1 89.2 18.7 19.9
Elongation Retained% 104.9 112.4 109.8 99.4 108.4 96.1 103.9 103.9 96.1 96.1 96.1 92.2 89.6 96.7 99.4 98.6 102.6 103.3 103.9 90.2 77.8 48.4 103.3 109.2 88.2 102.6 103.9 106.5 35.3 103.9 26.9 17.1 24.9 21.0 23.5 79.0 26.1 21.6
Hardness ChanPcPts. +4 -11 -14 +2 +2 -1 +3 -8 -2 -2 -2 f4 +2 -11 +1 -13 -18 -9 -13 +3 -9 -24 -17 -12 -12 +2 -13 -10 -27 -7 -30 -32 -32 -30 -28 +2 -31 -31
surface Condition Sl Tacky SI. Tacky Sl. Tacky SI. Tacky Unchanged Sl Tacky Tacky SJ. Tacky Si. Tacky SI. Tacky SI. Tacky SI. Taccky Unchanged Sl. Tacky SI Tacky SI. Tacky Unchanged Tacky Unchanged SI. Tacky Unchanged Unchanged Unchanged SI. Tacky Unchanged Tacky Unchanged Unchanged Unchanged SI. Tacky Unchanged Sl Tacky Unchanced !X Sl. St. Sl. Sl. Tacky Tacky Tacky Tacky Tacky
+0.12 +7.35 +4.50 +2.07 +18.6 +1.05 +1.08 +2.79 +0.89 +1.53 +1.64 -0.36 +1.26 +6.60 +12.0 +7.28 +17.4 +5.34 -l-7.33 -l-o.77 +7.00 +45.7 +19.3 +9.13 +8.75 +0.49 +9.56 +3.85 +60.2 +4.35 +84.0 +218.5 -f-142.9 +142.0 +125.5 +41.9 +128.5 +142.5
1 -Htranol
Rtsorclool
ALDLHYDES Benzaldthyde Butyraldchydt Furfural AMINES Antlmt Trwthanolammt UDMH ESTERS Amy1 Acetate Dlbutyl Sabacate 01octyl Phthalatt Ethyl Acetate Tricrtsyl Phosphate nlims D~btnryl Ether D+tthyltnt Glycol Monobutyl Ether Ethyl Ether Ethylene Glycol Monoethyl Ether HYDRDCARBDNS 8tnzent Cyclohcxant Ethvlbtnztnt Htptant Htrant Naphthalane Tdutnt
Xyltnt
HALDGENATED HYDROCARBONS Btnryl Chlonde Bromobenrcne Carbon Tttrachloridt Chloroform Ethylene D&chloride Pcrchlorotthvltne OTHER SUBSTITUTED HYDRDCAR8ONS Carbon Disulfidt Nltrobtnrene KETONES Acetone Methyl Ethyl Ketone Methyl lsobutvl Ketone
+26.1 +118.0 +207.1 +169.5 +25.8 +200.5
56.0 22.9 19.9 19.3 52.4 16.3
79.8 26.1 19.6 22.2 62.7 18.2
-21 -32 -32 -33 -18 -33
T=ky St. Tacky Unchanged !X Tacky SI. Tacky Unchanged
+87.0 +3.36 +6.07 +8.60 +22.0
16.9 94.6 86.7 83.1 56.6
21.0 101.4 90.8 88.8 75.1
-31 -11 -8 -11 -17
Sl. Tacky TabV SI. Tacky Sl. Tacky SI. Tacky
(continued)
316
TABLE 2.12:
12 Months Immersion at 75 2 SF vohuna Tamlk sbwtgth
Elongation
Retained%
W%
DETERGENTSLDTHER CLEANING PRODUCTS Calgonltc (1%) Clorox (1%) Clorox (COrlC.) Joy (1%) Joy (Cone ) LestoIl (1%) Lur Flakes (1%) Rmre Dry (1%) Rmse Dry (Cont.) Tide (1%) NATURAL FATS 6 OILS Butter Castor 011
Ratainad n
liardness ChangaPts.
surfaa
ConditM
+0.63 +2.30 +1.85 +1.41 -10.6 +3.34 +1.53 +0.96 -0.74 +1.77 +28.4 -1.31 +11.1 +17.8 +27.9 +18.3 +108.5 +45.8 +5D.6 +151.8 +128.4 +156.1 + 140.0 +176.0 -l-44.7 +139.8 +53.6 + 149.8 +16D.9 +183.4 -l-203.7 +151.7
102.4 106.0 109.6 98.2 97.0 101.2 101.8 98.8 97.6 100.7 88.6 98.2 116.9 99.4 101.2 101.2 34.3 43.4 50.0 31.3 22.9 13.9 18.1 20.5 w.2 18.1 38.6 32.5 17.5 18.7 17.5 18.1
103.9 103.9 107.8 105.3 98.0 105.3 100.6 105.3 98.0 99.0 100.0 103.3 115.1 109.2 105.3 107.8 38.6 56.9 54.3 30.0 24.2 22.9 21.0 22.9 77.8 20.2 43.1 38.6 21.0 21.6 21.0 19.6
+3 +2 +1 +2 +3 -1 +3 +3 +4 +3 -16 +3 -13 -13 -16 -14 -33 -23 -22 -32 -29 -32 -33 -33 -23 -32 -26 -33 -34 -31 -36 -33
SI. Tacky Unchanged Unchanged Sl. Tacky SI. Tacky SI. Tacky Unchanged Unchanged St. Tack-y TaCkY SI. Tacky Tacky SI. Tacky Unchanged Unchanged Sl. Tacky Sl. Tacky Unchanged Si. Tacky Unchanged Unchanged St. Tacky SL Tacky Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky Sl. Tacky SI. Tacky Sl. Taskv
Cononsced011
Lard Oleomargarme Olwe 011 While Mineral 011 OILS 6 FUELS A.S.T.M. A S.T.M. A.S.T M. A S.T M. A.S.T.M. A.S T.M. No. 1 011 No. 2 011 No. 3 011 Fuel A Fuel 8 Fuel C
Heatmg Fuel Oil Jet Awcraft Engine Oil Kerosmc AUTOMOTIVE PRODUCTS Chassis Grease Motor 011 (lOW.30) Gasolmc (RON 94) Gasolmc (RON 99) Gasol~nc* (RON 102) Gasoline. unleaded HYDRAULIC FLUIDS Oronite 8200 Pydraul F.9 Pydraul 60 Skydrol Skydrol 500 MISCELLANEOUS Gelatin (sat. soln.) Glucose (sat. soln.) Tincture of Iodine Preston8 antifreeze Dowgard antifreeze
+13.7 +11.2 +6.70 +7.30 +3.37 0.00 +1.99 +19.4 +1.47 -0.79
101.8 103.0 104.8 106.6 110.2 95.8 98.8 53.0 96.4 94.0
104.5 110.4 106.5 110.4 110.4 96.1 94.7 41.2 99.4 97.5
-9 -10 -6 -7 -10 +2 0 -5 -1 +3
Unchanged Tacky Tacky SI. Tacky SI. Tackv Si. Tack-y T=ky Unchanged St. Tacky Unchanged
l Convcntmnel motor fuels contaming tetraethyl lead eddihve. Approximab **Motor fuel of premium grade containing no tatmethyl lead.
Research Octane Numbers Ind,ceted.
(continued)
317
TABLE 2.12:
VARIOUS
CHEMICAL
ELASTOMERS
RESISTANCE
AND RUBBERS-EXXON
CHEMICALS
(continued)
BU-I-YL RUBBER
OF COMPOUND
BASED ON LOW UNSATURATION

72 Hours Immersion at 212OF
vulume channc n Aniline Benraldchyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) Skydrol 500 Sudwm Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) +6.62 +11.0 +20.9 +1.20 +1.46 +56.7 +147.9 +4.57 +36.2 +134 +339.1 +1.47 +13.8 +0.12 +2.67 +3D9.3 +1.27
Tensite Strength Retained K 97.0 103.8 97.8 96.8 90.3 28.0 16.7 102.2 87.1 82.8 64.5 94.1 86.6 101.1 102.7 69.9 90.9
Elongation Retained K 99.4 94.6 98.6 88.1 88.7 46.3 24.1 80.6 100.0 87.3 17.7 79.9 96.2 87.0 94.1 26.9 87.3
Hardness Chanee Pts. -14 -21 -27 +2 -3 -28 -36 -4 -32 -20 -48 +2 -27 -1 -8 -53 0
Slll-faCe Condition Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Tacky Unchanged Unchanged Tacky Unchanged Unchanged Unchanged Tacky Unchanged SI. Tacky
One Month Immersion at 75O -C 5OF vuhmn Change K Anilme Benxaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassrum Permanganate (25%) Skydrol 500 Sodium Chlorrde (25%) Sodwm Hydroxrdc (10%) Tduenc Trde (1%) +10.0 +6.22 +3.09 -0.71 +0.36 +61.4 $166.9 -0.38 +4.02 +10.1 +251.5 +0.38 +1.89 -0.12 -0.12 +171.6 0.00 Tensile Strength Retained K 112.9 110.2 104.8 95.2 90.3 26.9 21.0 105.9 105.4 91.4 14.5 88.7 104.3 98.4 184.3 16.1 99.5 Elongation Retained K 103.3 110.8 103.7 94.3 96.2 51.9 27.9 99.4 105.7 93.8 18.4 84.9 99.4 95.2 96.6 25.5 99.0 Hardness Change PCs. -13 -17 -1 +4 +2 -29 -33 +3 -4 -16 -37 +5 -4 +2 +5 -36 +6 Surtace Cundiiiun Tacky Tacky Tacky Unchanged Tacky SI. SI. SI. Sl. SI. Tacky Tacky Tacky Tacky Tacky
Tacky Brittle SI. Tacky Unchanged Unchanged TKky T=ky
Three Months immersion at 75O f IoF VOtUme Ct=W% Aniline Benraldehyde Dioctyl Phthalatc Distilled Water Ethyl Alcohol Ethyl Ether Hexane Hydr&hloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potasswm Permanganate (25%) Skydrd 500 Sodium Chloride (25%) Sodium Hydroxrde (10%) Toluene Trde (1%) +9.00 +6.74 +5.06 -0.83 +0.11 +57.5 +X2.4 +0.38 +9.72 +7.55 +264.2 +4.30 +4.40 -0.97 +1.16 +187.4 0.00 Tensile Stmngttt Retainad % 98.4 103.8 100.0 109.7 90.3 31.2 18.3 98.4 111.3 93.6 14.0 95.7 lM.8 101.1 97.3 17.2 102.2 Elongation Retained% 101.4 97.2 99.0 99.0 97.2 50.5 25.9 97.6 103.3 94.3 19.4 89.1 101.4 94.8 96.6 27.3 98.6 Hardness ChangePts. -12 -17 -7 +5 -1 -27 -32 +2 -8 -14 -38 +5 -12 +6 +4 -37 +2 Swface Condition SI. Tacky Tacky Tacky Unchanged Unchanged Unchanged Sl. Tacky Unchanged Unchanged St. Tacky St. Tacky Unchanged Unchanged Unchanged Unchanged T=ky SI. Tacky
(continued)
318
TABLE 2.12:
Six Months Immersion at 75O _C5OF vokune Change K Aniline Benzaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) Skydrol 500 Sodium Chloride (25%) Sodwm Hydroxide (10%) Toluene Tide (1%) +4.15 +1.87 +8.42 -0.71 -0.24 +54.5 +162.5 +0.38 +12.0 +8.65 +256.5 +7.06 +5.73 -!-0.24 +0.58 +166.3 +0.37 Tensile Strength Retained K 103.8 97.9 102.2 101.1 89.3 33.3 18.8 100.0 116.1 91.9 14.5 96.2 101.1 97.3 103.2 18.3 103.8 Elongation Retainad % 100.0 99.4 99.4 96.2 97.6 48.5 26.9 88.7 101.8 91.5 20.2 88.7 99.0 96.6 95.8 28.7 104.2 Hardness Change PM. -12 -15 -9 +4 -2 -28 -36 +3 -16 -13 -39 -3 -13 +5 +4 -37 +3 Surface Condition SI. Tacky Tacky Tacky Unchanged SI. Tackv Unchanged Tacky Unchanged SI. Tacky SI. Tacky Tacky SI. Enttle Unchanged Unchanged Unchanged T=ky SI. Tacky
12 Months Immersion at 75 2 5OF votume Change W Andme Benraldehyde Omctyl Phthalate Olstllled Water Ethyl Alcohol Ethyl Ether Hexane Hydrochloric Acld (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potaswum Permanganate (25%) Skydrol 500 Sodwm Chloride (25%) Sodturn Hydroxide (10%) --__ Toluene Tide (1%) +6.00 +4.65 +11.6 +0.12 -I-o.97 +48.8 +123.2 -0.13 +21.8 +7.93 +262.1 +7.95 +4.81 -l-O.48 +0.81 i-131.9 +1.73 Tensile Strength Retained K 96.2 97.9 102.7 102.2 93.6 29.0 15.1 104.3 111.3 100.5 15.1 89.3 101.6 96.8 100.0 13.4 103.8 Elongation Retained % 100.4 98.6 112.7 99.7 100.0 46.3 28.7 97.6 103.3 92.9 18.8 87.7 99.4 97.2 94.8 28.7 98.6 Hardness Chanee Pts. -12 -15 -18 f3 -2 -31 -37 +1 -23 -12 -41 +4 -12 +2 +5 -38 +5 Surface Condition SI. Tacky SI. Tacky Tacky Unchanged St. Tacky Unchanged SI. Tacky Unchanged SI. Tacky SI. Tackv Tacky SI. Brittle Unchanged Unchanged Unchanged TafkV SI. Tacky
CHEMICAL
RESISTANCE
OF CHLOROBUTYL
1066 COMPOUND
72 Hours Immersion at 212F Vdume Change W Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 Oil Benzaldehyde Oioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Cesoline (RON 99) Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganatu (25%) -l-7.86 +78.8 +168.1 +50.8 +29.0 +6.96 +4.92 +62.6 +167.1 +129.0 +4.07 i-27.2 +19.9 +262.4 +2.59 Tensile Sbemzth Retained 4 95.0 47.0 28.3 67.2 75.3 98.0 92.4 38.9 21.7 29.8 102.0 78.3 61.6 18.7 97.0
qongation Ret&d K
93.4 62.8 51.1 57.2 68.9 74.6 72.9 40.7 28.9 28.9 84.0 67.5 61.2 21.9 72.9
Hardness Change Pts. -3 -27 -34 -14 -16 0 -1 -20 -34 -25 fl -16 -14 -33 +1
Surface Condition Unchanged SI. Tacky Sl. Tacky SI. Tacky Unchanged SI. Tacky Unchanged SI. Tacky Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged
(continued)
Rubbws
and Elastomers
319
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
72 Hours Immersion at 212OF VOlUtVW Tonsik sb-tngm Ret&W K 74.8 104.5 102.0 17.7 99.5 84.9
Elongation
Retained W 74.6 76.0 64.7 29.9 76.0 45.7
Qunp%
Hardness Change Fts. -15 +1 +1 -41 -2 -14
surface
Condiitm Unchanged Unchanged SI. Tacky Unchanged SI. Twkv Unchanged
Shydml 500
Sodium Chloride (25%) Sodium Hydroxide (10%) Tolutnc Tide (1%) UDMH
+19.4 +0.96 -Il.92 +238.2 +5.94 +18.6
One Month Immersion at 75O t IoF VdUmC Change K Tensile Strength Retained K 91.9 84.3 53.5 71.7 95.5 102.0 99.0 34.9 25.8 28.3 103.5 90.9 77.3 24.2 102.5 101.5 104.5 102.5 29.3 101.5 Elongation Retained% 87.1 75.3 49.4 62.8 85.4 91.8 91.1 35.3 23.5 25.2 93.4 64.7 66.6 21.2 84.7 91.1 91.8 92.5 28.2 92.5 77.6 Hardness Change-. +1 -4 -13 -9 +2 +2 +3 -20 -23 -21 +3 -4 -10 -23 i-4 +2 +2 +4 -22 d-4 -11 Surface Condii Tacky SI. Tacky Unchanged Tacky SI. Tacky Unchanged Tacky SI. Tacky Unchanged SI Tackv Unchanged 51. Tacky Sl. Tacky SI. Tackv Unchangid SI Tacky Unchanged Unchanged SI. Tacky Unchanned Unchanged
Andme
A.S.T.M. No 1 011 ASTM No. 3 Oil Benzaldehyde Dioctyl Phlhalatt Distilled Water Ethyl Alcohol Ethyl Ether Gasoltnt (RON 99) Hexane Hydrochloric Acld (10%) Lard Methyl Ethyl Ketone Perchlorotthyltnt Potasswm Pennanganatt (25%) Skydrol500 Sodium Chloride (25%) Sodwn Hydroxide (10%) Tolutnt Tide (1%)
+4.89 +11.1 +39.5 +21.9 +2.71 Lo.11 +1.78 +w.4 +158.2 + 138.4 +0.68 +3.75 +16.7 + 170.0 +0.69 +2.45 -0.12 0.00 +179.9 +1.01
Three Months Immersion at 75O * 5OF Vdume Chanm K Amline A.S T.M. No. 1 Oil A.S.T.M. No. 3 011 Btnzaldehydt Dioctyl Phthalatc Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Htxant Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Ptrchloroethyltnt Potassium Ptrmanganatt Skydrol500 Sodium Chloride (25%) Sodium Hydroxide (10%) Tolutnt Tide (1%) UDMH +6.64 +21.8 +114.s +31.7 +6.32 +0.58 +1.46 +62.8 +193.2 +156.3 +0.63 +8.20 +15.6 +220.0 (25%) +2.41 +2.80 0.00 -f-O.46 +182.5 +1.13 +17.0 TmsikStren#h Retained X 94.4 77.8 46.0 63.1 97.0 104.0 93.9 33.8 30.3 30.8 98.0 96.0 74.2 22.2 100.5 99.5 103.0 99.0 29.3 100.0 72.7 Ekmgation Retained% 90.1 65.9 37.5 54.1 65.4 91.8 m.0 36.9 27.5 25.9 87.8 87.1 64.2 19.5 86.4 65.4 88.7 64.0 27.5 87.8 68.9 Hardness Chanfp Pts. 0 -9 -21 -10 -1 +4 -3 -20 -22 -21 -l-3 -5 -9 -23 +4 +1 i-4 +2 -21 +1 -11 Surface Conditb SI. Tacky Unchanged Unchanged Tacky SI. Tackv Unchanged Sl. Tacky Unchanged Unchanged St. Tacky Unchanged Unchanged Unchanged SI. Tacky Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged
(continued)
320
Corrosion
Resistant
Materials
Handbook
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Six Months Immersion at 75O 2 5OF Vdurm W% Amline ASTM No. 1 oil A.S.T.M. No. 3 Dil Senraldehyde Dioctyl Phthalata Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Herant Hydrahloric Acid (10%) Lard Methyl Ethyl Ketona Perchlomethyltna Potassium Pcrmanganate (25%) Skydrd 500 Sodium Chlorida (25%) Sodium Hydroxida (10%) Toluene Tide (1%) UDMH +4.05 +43.7 +157.0 +36.5 +9.38 +1.97 +1.43 +59.8 +189.0 +131.6 +0.89 +14.7 +14.7 +213.4 +4.59 +4.79 +0.12 +0.23 +191.3 +2.27 +14.5 Tansik Strength Ret&ad % 96.5 66.2 43.4 54.0 93.4 loo.5 100.0 37.4 24.8 31.8 100.0 90.9 77.8 24.2 106.1 98.5 97.0 112.5 31.3 100.0 73.7 Elongation Hardness Retained SC ChangePts. 91.8 55.8 33.6 48.7 82.4 81.7 88.2 36.9 26.6 26.6 87.1 76.0 64.2 20.5 86.4 87.1 84.0 87.8 26.6 83.1 71.3 0 -15 -25 -11 -4 +2 +1 -21 -25 -21 +4 -9 -9 -23 +4 0 +4 +4 -23 fl -9 Surtaca Condition Tacky Sl. Tacky Unchanged T=ky Sl. Tacky Unchanged SI. Tacky Unchanged SI. Tacky Sl. Tacky Unchanged St. Tacky Unchanged Unchanged SI. Brittle Sl. Tacky Unchanged Unchanged SI. Tacky Unchanged Sl. Tacky
12 Months Immersion at 75O 2 5F VOlUnW Changa n Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 011 Btnzaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Htxant Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchlorotthyltnt Potassium Ptmanganatt (25%) Skydrol500 Sodium Chloride (25%) Sodium Hydroxide (10%) Tolutnt Tide (1%) UOMH +7.58 +52.8 + 135.0 +44.5 +12.8 f2.56 +2.82 +70.0 + 155.0 +110.4 +1.90 +19.9 +14.1 +220.0 +6.64 i-5.27 +0.25 +0.80 +127.5 f4.03 +13.5 Tensile Stigth Retaimd W 89.9 63.6 39.9 49.5 96.0 101.5 99.0 34.3 25.8 25.8 101.5 87.4 75.3 21.7 98.0 97.0 98.0 100.5 25.8 102.0 72.2 Elongation Retained% 92.5 54.1 33.7 46.4 82.4 88.7 82.4 37.6 25.2 29.9 80.7 81.2 66.6 22.3 77.6 88.7 86.4 84.0 27.5 87.4 72.2 Hardness ChangePtm -3 -20 -21 -13 -6 +4 +2 -22 -26 -28 +5 -11 -8 -25 +4 -1 +4 +2 -22 +4 -10 Surfaa Condition Tacky St. Tacky Unchanged Tacky Sl. Tackv Unchanged Sl. Tacky Unchanged Sl. Tacky Sl. Tacky Unchanged Sl. Tacky Sl. Tacky SL Brittle SI. Tack-y Unchanged Unchanged Sl. Tackv Sl. Ta& Unchanged
CHEMICAL
RESISTANCE
OF VISTALON
404 COMPOUND
72 Hours Immersion at 212OF Volume Changa K Anlllnt A S.T.M. No. 1011 A.S.T.M. No. 3 011 Benraldehyde Dtoctyl Phthalate f560 * 129.2 +216.4 126.4 139.6 Tensile Strangth Retained K 105.0 53 3 38.9 85.0 88.5 Elongation Retainad K 114 0 46 2 33.3 80.3 82.8 Hardness Change Pts. -3 -34 -35 -13 -18 Sutfaw Condition SI. Tacky Swollen Swollen SI. Tacky Unchanged
(continued)
Rubbers and Elastomers TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS (continued)
321
72 Hours
Immersion
at 212OF
Hardness Change Pts.
+2 -4 -28 -37 -30 +1 -10 -26 -12 -40 +5
volume Change W
DIstIlled Ethyl Ethyl Water +0.65 -1.31 +97.0 99) + 187.8 +177.6 Acid Aud (10%) (Cow.) +5.80 +37.7 +64.0 + 16.3 +207.1 (25%) +0.84 +9.54 +0.93 +0.40 +57.9 +0.91 +218.1 +16.5 Alcohol Ether (RON
Tensile Strength Retained w

106.1 107.7 41.5 38.4 36.9 100.0 80.5 69.2 83.0 23.6 103.7 99.8 111.5 107.0 Brittle 102.7 22.6 86.4
Elongation Retained W
102.2 105.0 36.5 35.2 30.2 88.0 72.6 66.7 78 3 40.4 94.3
Surface Condition
Unchanged Unchanged Unchanged Swollen SI. Brittle Unchanged Unchanged Swollen Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Cracked Swollen Unchanged Unchanged
Gasolme Hexane Hydrochloric Hydrochloric Lard
Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate Skydrol 500 Sodturn Sodium Sulfuric Chloride (25%) Hydroxide (10%) Acid (Cont.)
101.0
101.8 91.0 Brittle 100.0 30.2 97.5
-4
0 +3 136 +1 -35
ltde (1%) Toluene UDMH
-11
One
Month
Immersion
at 75O 2
YF
SUliWX
volume Chanp SC
Anlllne A ST A ST M No M. No 1 011 3 011 +2.14 +70.1 +214.4 +15.9 +9.08 -0.10 +0.12 +99.9 99) (10%) )
Tensile Strength Retained SC

103.8 57.2 46.8 79.8 103.6 109.3
Elongation Hardness Retained SC Change Pts.

109.5 47.2 34.0 76.8 94.0 105 1 -2 -23 -29 -8 -4 5
Condiiion
St lacky Swollen Swollen Unchanged Unchanged Unchanged Sl. Tacky Si. Tacky Swollen SI Brlttle
Benzaldehyde Dloctyl Phthalate Dtstllled Ethyl Ethyl Water
Alcohol Ether (RON
101.9
36.9
102.5
38.5
.h 1
-27
Gasoline Herane Hydrochloric Hydrochlow
+166.8
+ 190.9 +0.94 +7.53 +23.9 +8.59 +93.3 (25%)
40.8
36.4 114.4 101.6 93.2 92.7 45.8
33.3
28.9
-30
-32
Acid
110.1
116 83.6 83.6 44.3 7
15
-I 3 -13 -8 -29
SI. Tacky
SI Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Sl Tacky Unchanged Unchanged
Aced (Cone
Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate Skydrol 500 Sodturn Chloride f25%) Sodpum Sulfuric I de Toluene UDMH Hydroxide Aced (Cone (10%) )
+1.04
+1.08 +0.02 +0.14
94.5
104.3 107.8 103.6
83 8
103.8 103.8 99.5
-8
3 .: 6 +3
+10.1
+0.43 +182.9 +7.68
61.1
112.3 34.0 93.7
( I ?P, )
74.4 107.1
28.9 99.3
+4 .6
-31 -4
Three Months Immersion at 75O f 5*F VOlUllW Change K

Andme A S.T.M
Tensile Strength Retained W 103.8

51.7
Elongation Retained % 110.8

44.8
Hardness Change Pts. 2

-27
Surface Condition
Unchanged Swollen
+2.26
No. 1011 + 108.4
A S.T M. No. Benraldehyde Dloctyl Dlst!lled Ethyl Ethyl
3 Oil
+218.4
+27.3 +9.92 +0.44 +0.25 +94.4
39.4
77.8 103.7 106.9 97.2 40.8 43.4 32.5 105 85.2 98.5 41.8 0
32.7
74.4
-31
-8
Swollen
Unchanged Unchanged Unchanged Unchanged Unchanged Swollen Swollen SI Tacky
Phthalate Water Alcohol Ether LRON 99)
101.0
106.5 104.5 42.8 35.8 32.7 106 5
-3
- 5 -. 4 -28 -33 -30 6
Gasoline Hexane Hydrochloric Hydrochlonc Lard
+183.5 +175.8 t1.02 ) (Cow
Actid (10%) Acid
+11.0
+20.9 +8.54 188 1
95.5
1130
92.8 93.7 46 8
-2
-14 -5 -27
Unchanged Unchanged Sl. Tacky Swollen
Methyl Ethyl Ketone Perchioroethylene
(continued)
322
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Three Months Immersion at 75O f 5OF Volume Chane %

Skydrol Sodium Sodfum
Sulfurrc
Tensile Strength Retained %

a7 a
U0tlgG3tihl
Retained K
aa 5 105 1 106 101 48 100 5 a 2 0
Hardness Change Pk. 6 0

-3 ~ 7 -1 -7 -31 -3
surface Condition Unchanged Unchanged Unchanged l$hanged Unctiangod SWOlll?fl Unchanged
POtaSslUm Permanganate 500

Chiorlde Hydroxide Acid (Cow 125%) (10%) )
(25%)
2.67 11.15
104.3
;07 a 103.7 39 9 102 31.1 93.7 7
2 0.15 20 28 i 32.2 -0.56 +169.9 a.98
T!de UDMH
(I?,,)
Toluene
32 7 100 0
Six Months immersion

Vdumr Tensile Strength Elongation
at 75O t 5OF
Hardness Surface
Change %
Anlllne A S T M. No. A S T M. No. aewaldehyde Dmctyl Distilled Ethyl Ethyl Phthalate 1 011 3 011 -199 1130.0 1213.5 +3a J-10 -0 187 99) 1-181.6 2 1 28 5
Retained %
98.5 51 2 414 77 4 105 5
Retained %
103.2 44 a 37 6 74 4 107 104 2 4
Change ph.
-1 -25 -27 -10 -6 -6
Condition
Unchanged Swoller! Swollen Unchanged Unchanged Unchanged Unchanged Unchanged
Water
--0.66
103
Alcohol Ether (RON
99 a 39 4 42.8
101 a 410 37 a
-3
-25
Gasoline
Hexane
Hydrochlow Hydrochlorfic Lard Methyl Ethvl Perchloroeihylene Potassium Skydrol Sodaurn Sodturn Sulfurtc Tide Toluene UDMH Permannanate 500 Chloride Hydroxfde Acjd (Cow.) (25%) (10%) (25s6)
Acid (1046)
Acfd Ketone (Cont.)
1167 3 -1.63
+14 a +34 a +a.09 +a6 -2.65 -1.05 007 - 0 33 142 6 - 0 53 +I564 19 74 a
32 3 97 2
a6 a a3 0 94 0 40.3 93.7 106 5 99 a 103 103 30.4 91.7 7 7 23 4
32.5 108 2 98 2
a5 5 90 4 45 7 94 3 105 103 1018 28 3 103 a 32.5 96 a 2 2
-30 -27 -4 -3
-18 -6 -26 -3 -2 -4 -4 -2 -4 -27 -3
SWOilen Swollen SI Tacky

Unchanged Unchanged SI Tackv swoiler!: Unchanged Unchanged Unchanged Unchanged SI Tacky Swollen Unchanged
(1%)
12
Months Immersion at 75O 2 5OF Elongation Retained %

108.3 44.2 34.1 75 0 9 104 5 108 9 108 2 40.3 34 6 30 a 108 2 82 7 79 4 96.9 49 4 99 3 103 3 100 0 102 5 52 106 2
Volume Change %
Anllloe A S 1 M. No A ST Dloctyl M. No Benraldehyde Phthalate Olstllled Water Ethyl Alcohol Ethyl Ether Gasoline Hexane Hydrochloric Hydrochlorx Lard Acid (10%) Aced (Cow (RON 99) 1 011 3 011 1.90 f144 +211 +31.3 +10 5 10 55 -0.06 +107.5 f179.4 +193.5 2 8

105 42.8 81.3 108 107 9 107.4 38 5 42.8 32.5 110.2 75 a 83.8 98.6 424 98.8 1104 103.2 101 9 10.3 109.8 37 9 102 4 4 53.2

-1 -29 -29 -12 -6 -3 -2 -25 -30 -28 -2 -4 -16 -6 -30 0 -1 A3 -1 -3 -2 -30 -a
Surface Condition
Unchanged Swollen Swollen SI Tacky Unchanged Unchanged Unchanged Unchanged Swollen Swolfen SI. Tacky Unchanged Unchanged SI. Tacky SWOllell
fl54 123 3 132.1 +103 1038 (25%) +2.50 +1.01 +o 01 LO.19 767 1O +178.6 i12.4 69
Methyl Ethyl Ketone Perchloroethyiene Potassium Skydrol Sodium Sodturn Sulfuric Tide Permanganate 500 Chloride Hydroxide Acid (1%) (Cow (25%) (10%) )
Unchanged Unchanged Unchanged Unchanged SI Tacky Swollen Unchanged
Toluene UDMH
32 a 98 2
(continued)
323
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBE:RS-EXXON
OF COMPOUND
CHEMICALS
(continued)
CHEMICAL
RESISTANCE
BASED ON HIGH MOONEY EPDM
72 HOWS immersion
VdUlIla Anlllne
A.S.T.M No. 1011 3 Oil A.S.T.M. No Senzaldehyde Dloctyl Dlstllled Ethyl Ethyl
at 212OF Hardnasa Changa Pts. -1

-25 -28 -10
chnp% +1.72
t83.1 +119.9 +12.8 +24.7
Tamilc stnmgm Rabinad % 98.5

51.7 35.9 77.0 83.0
Elongation Ratainad W 87.6

49.5 37.2 72.4 73.0
Surface Condition SI. Tacky

SWOllen Swollen Unchanged Unchanged
Phthalate Water Alcohol Ether (RON 99)
-11 0
+1 -16 -25 -18 0 -8 -19 -7 -27 +1 -1 0 0 t29 t1 -25 -1
+1.10
-3.47 +62.6 +121.8 +93.4 Acid Acid (10%) (Cont.) +14.6 +32.3 +38.9 +5.15 +109.7 (25%) +1.65 +2.08 +2.69 +0.43 t66.9 t1.63 t150.2 +5.22
104.7
95.6 36.0 35.5 28.1 74.8 70.7 65.0 72.1 20.7 99.5 104.4 94.7 98.8 44.7 88.6 23.0 70.1
85 0
83.6 36.3 38.0 25.8 60.0 60.9 63.7 73.5 31.4 78.0 89.5 73.5 74.3 0
Unchanged Unchanged Unchanged Swollen Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Cracked Unchanged Unchanged Unchanged
Gasoline Hexane
Hydrochloric Hydrochloric Lard Methyl Ethyl
Ketone
Perchloroethylene Potasswm Permanganate Skydrol 500 Sodium Sodurn Chloride Hydroxide (25%) (10%)
Sulfuric (Acid Tide (1%) Toluene UDMH
(Cow.)
77.2
30.6 66.5
Ona Month Immersion at 75O -C SF VOIUIIN USC

AnNlIne A S T.M No 1 011 3 011 A S.1 M No Senraldehyde Dloclyl Dlstllled Ethyl Ethyl t 5.05 t53.1 t 128.6 +3.00 +3.35 to.37 -0.65 +61.6 99) t 106.9
Tans& Srw#h Ratained n

93.4 56.7 44.7 75.4 91.2 104.5 97.5 33.3 42.8
Elongation Ratainad%
90.7 48.5 35.9 71.4 87.7 94.4 89.5 36.3 363
Hardnass ChangaPls.
-1 -13 -16 -4 -2 i2 -~ 1 -12
sulfaca Condition
SI. Tacky Swollen Swollen SI. Tacky Unchanged Unchanged SI. Tacky SI. Tacky
Phthalate Water Alcohol Ether (RON
Gasoltne
Herane
Hydrochlonc Hydrochloric Lard Methyl Ethyl Acld Acid (10%) (Cont.)
+119.2
+1.22 t4.37 t20.8 +0.28 +73.5 (25%) +0.59 -5.99 +0.04 +0.45 t7.81 t 1.61 +121.1 t1.65
32.7
104.2 102.4 77.7 76.5 37.4 105.4 102.4 102.2 104.5 52.3 100.8 28.5 75.2
25.8
94.4 92.3 76.3 77.2 36.3 96.3
-17 -13
1 +2 -8 -1 -17 -t2 12 t2 *2 6 +3 -16 -c2
Swollen
Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged
Ketone
Perchloroethylene Potassium Permanganate Skydrol 500 Sodium Sodium Sulfuric Chloride (25%) tivdroxlde (10%) (Acid (Cont.)
97.2
93.5 95.2 37.8 94.4 26.6 60.8
Trde (1%) Tolue& UDMH
lhroa T_sbryth bt&md% t4.97 No. 90.8 51.7 36.5 83.8 99.5 106.0 95.8 39.6
Months
Immanion at 7b0 2 So*

w Retainad 89.5 46.7 30.6 80.8 97.2 % Hafdnesf Change -1 -17 -17 -4 -2 -2 1 -13 RI. Surfaa? --
Conditkw
Unchanged Swollen Swollen Unchanged Unchanged Unchangeg Unchanged Sl. Tacky Swollen Swollen
AnlIme
A.S T.M A S.T.M
1 011
+75.0 +128.4 t7.30 +3.52 +0.69 -0.67 t63.7
No. 3 011
Senzaldehyde Ouoctyl Phthalate Dbstllled Ethyl Ethyl Hexane Water Alcohol Ether (RON 99)
97.2
91.5 40.8
Gasolmc
+111.1
+111.4
43.8
30.4
400
31.5
-18
-15
(continued)
324
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Three Months Vdume

chanm K
Immersion Elongation Retained 83.6 91.5 62.0 85.7 41.4 89 5 96.3 97.8 93.5 22.8 97.2 29.4 58.7 %
at
75 + W
Hardness Change -1 -1 -9 -1 -17 -2 -1 i- 1 +3 -9 -2 -16 0 Unchanged Pts. Surface Condition SI Tacky Unchanged
Tensile Strength
Retained 90.8 97.5 61.7 85.7 37.8 91.7 101.8 103.8 99.5 35.5 102.2 26.1 71.8 n
Hydrochlonc
Hydrochloric Lard Methyl Ethvl
Acld (10%) Acid (Cont.) Ketone
+1.30 +9.43 +25.5 +0.62 -l-72.8 (25%) -0.91 -5.95 +0.23 +0.26 +32.1 +1.90 +117.3 +3.13
Unchanged
SI Tackv swon;n
Perchloroeihylene Potassium Skydrol Sodwm Sodlum Sulfuric 500 Permannanate -
Chloride (25%) Hydroxide (10%) (Acid (Cont.)
Unchanged
Unchanged Unchanged Unchanged Swollen Unchanged
Tide (1%) Toluene UDMH
Six Months
Immersion
at 75O t
5F
Vdume C)unm n
AntlIne A
TenslIe strsllgth Retained %

93.9 41.8 87.8 96.4 104 93.2 38.9 35.5 30.4 97.5 92.6 72.8 76.0 37.3 95.0 91.7 98.8 100.9 23.8 104.9 26.3 70.0 2
Elongation Retained W 48.5

37.8 80.0 94 4 100 0 87.7 40.0 37.8 31.5 89 808 74.3 77.2 39 2 89 5 91.5 95.2 93.5 11.4 98.0 28.6 56.3 5 95 3
Hardness Chance Pts. -15

-15 -3 -2 -1
Sur(aa Condition
Unchanaed SwolleG SWOlle Unchanged Unchanged Unchanged Unchanged Sl. Tacky Swollen Swollen SI Tacky Unchanged Unchanged SI. Tacky Swollen Unchanged Unchanged Unchanged Unchanged SI. Tacky
S T M. No. 1 011
3011
+85.0
+129.7 +9.90 i-3.72 +0.93 -0.51 +59.4 f110.5 + 103.0 +2.00 +12.5 -l-27.0 +0.36 f73.2 (25%) f1.88 -5.73 +0.20
+4.55
50.7
ASTM No Benzaldehyde Dloctyl Dlstllled Ethyl
Phthalate Water Alcohol 99)
.1
-1 -11 -17 -14 -2 -2 -10 0 -15 -3 -2 -2 -1 -8 1 -14 +2
Ethyl Ether Gasolme (RON Hexane Hydrochloric Hydrochlortc Lard Methyl Ethyl Potasswm Skydrol Sodwm Sodium Sulfuric Tide UDMH
Acid (10%) Acld (Cont.) Ketone
Perchloroethylene Permanganatc 500 Chloride (25%)
Hvdroxidc (10%) (Aced (Con; )
+0.26 +45.2 +1.82 +115.3 +4.30
(1%)
Toluene
Swollen
Unchanged
12 Months
Immersion
at 75O 2 5OF Hardness ChangePb.

-3 -18 -22 -4 -3 0 0 -10 -18 -13 fl 0 -9 -1 -14 +2 Al +2 0 +19 -1 -16 6 -3
Vdunw Change K
Aniline A S T M No. 1011 A S.T M No 3 011 Eenraldehyde Dloctyl Phthalate +6.53 +9D.9 +144.4 +7.63 +4.02 +1.92 +0.33 +69.4 +1104 + 128.3 Acid (10%) Acid (Cont.) +3.86 +18.3 +27.2 +2.04 +75.9 (25%) +2.46 -5.47 -0.14 +0.29 +55.8 +2.83 +114.6 +21.9
Tan80 Strom@ Retained %

95.0 47.8 42.8 87.9 110.3 103.6 100.3 35.3 38.7 30.4 88.0 79.7 69 2 74.6 32.7 101.8 100.8 96.7 100.8 Broken 105.0 39.9 61.3
Elongation Retained%
95.2 43.7 36.3 80.0 964 94.3 93.5 23.6 36.3 29.5 80.0 66.5 69.5 73.5 31 5 93.4 92.3 87.7 90.6 Broken 93.5 30.5 43
Surtaw Cat&ion
Unchanged Swollen Swollen Unchanged Unchanged Unchanged Unchanged SI. Tacky Swollen Swollen SI. Tacky Unchangid Unchanged Sl. Tacky Swollen Unchanged Unchanged Unchanged Si. EMtIe SI. Tacky Swollen Unchanged
Dlstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON Hexane Hydrochloric Hydrochloric Lard
99)
Methyl Ethyl Ketone Perchloroethylenc Potasswm Permanganatc Skydrol 500 Sodium Sodwm Sulfuric Chloride (25%) Hydroxldc (10%) (Acid (Cont.)
(continued)
Rubbers
and Elastomers
325
TABLE 2.12:
VARIOUS
CHEMICAL
ELASTOMERS
RESISTANCE
AND RUBBERS-EXXON
CHEMICALS
(continued)
EPDM
OF HIGHLY LOADED COMPOUND
BASED ON HIGH MOONEY
72 Hours
Immersion at 212-F Elongation Retained K 81.9 89.3 68 0

68 0 84.0 87.1 85.6 68.0 68.0 48.2 87.1 90.9 85.6 64.1 60.5 92.5 69.5 89.3 89.3 ,+12 -20 -35 -28 -4 -13 -15 -348
Vdume Change SC
Anlllne A.S T.M A S T.M Dloctyl Distilled Ethyl Ethyl No No 1011
Tensile Strength Retained SC 116.0 108.0 65.2

102.3 112.3 117.3 110.2 83.8 69.5 58.7 121.0 109.5 116.0 76.5 60.8 134.0 114.5 123.0 126.0 65.0
Hardness Change Pts. +10 -31 -39

+4 -2 0
Sur(ace Condition Unchanged

Swollen
3 011
-10.7 f57.1 +103.3

-5.26 +3.11 +0.66 -16.4 +21.9
Swollen
Unchanged Unchanged Unchanged Unchanged Unchanged Swollen Unchanged Unchanged Unchanged Unchanged Unchanged Brittle Unchanged Unchanged Unchanged Unchanged Broken Unchanged SI. Brittle Unchanged
Benzaldchyde Phthalate Water Alcohol Ether (RON 99)
Gasoline Hexane
+85.6 +59.8
Hydrochlow Hydrochloric
Acid (10%) Acid (Cont.)
+9.35 +25.2 +19.4 -8.71 +68.5 (25%) +3.13 -9.89 -0.18 +0.76 +74.2 +1.55 +96.9 -10.6
Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate Skydrol 500 Sodwm Chloride (25%) Sodium Hydroxide (10%) Sulfuric Acid (Cont.) Ttde (1%) Toluene UDMH
+2 +9 -3 +2 +I6
119.5
42.2 99.5
85.6
48.2 69.5
+1
-38 +7
One
Month Immersion at 75 5 5OF Elongation Retained K

94.7 90.8
* Surface Condition
Unchanged Swollen Swollen Unchanged Unchanged Unchanged Unchanged Unchanged Swollen Unchanged
votume Cm%
Anilme A S T.M No. 1011 AS T.M No 3 Oil Benraldehydc Dloctyl Dlstllled Ethyl Ethyl Phthalatc Water Alcohol Ether (RON 99) -5.40 +29.3
Tensite Strength Retained K

105.7 116.2 ::t 97.7 115.8 102.8 86.4 77.8 61.4 121.4 126.3 104.2 95.8 100.0 117.2 94.3 117.8 119.8 64.4 117.2 60.7 110.7

+5 -19
+a1.1
-5.76 -5.18 +0.16 -6.77 +27.5 +69.8 +70.8 +0.49 ) +4.31 +7.99 -7.73 +39.3 (25%) +0.64 -11.8 +0.05 +0.08 +15.5 +0.21 i72.9 -8.76
642
85.5 89.5 94.4 92.6 73.2 64.2 44.3 97.8 94.7 92.6 85.5 85.5 97.8 87.2 97.8 100.0 26.7 97.8 54.5 58.5
-26
14 -42 t2 16 -16 -28 -25
Gasolme Hexane
Hydrochloric Hydrochlow Lard Methyl Ethyl
Acid (10%) Acid (Cow Ketone
t2
+2 -8 +6 -24 +2 +8 0 t2 -3 +1 -25 +7
SI. Tacky
Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Brittle Unchanged
Perchhxoethylene Polasswm Permanganate Skydrol 500 Sodwm Chloride (25%) Sodwm Sulfuric Hydrorlde (10%) Actid (Cone )
Tide (1%) Tolene UDMh
Three Months Immersion at 75* 2 5F Vdw
c-w%
Anlllne A.S T.M. No. 1011 A.S.T.M. No. 3 Oil Benzaldehvde Dw~~tyl Phihalate Dlstllled -5.43 +48.7 +85.1 -6.19 -5.21
Tanslle~
Retained K
103.5 97.7 72.8 103.5 100.0
105.3 83.9 60.5 89.5 97.8

16 -24 -29 +4 -i4
Surface Condition
Unchanged Swollen Swollen Unchaneed Unchanged
Water
+0.35
-6.98 +28.1 99) -+71.6 +62.i
123.0
110.7 86.4 80.0 63.5
105.3
101.5 81.9 69.5 53 8
-+2
13 -18 -28 -23
Unchanaed
Unchanged Unchanged Swollen Swollen
Ethyl Alcohol Ethyl Ether Gasolme Hcxane (RON
(continued)
326
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
VOlUlllO Change K
Hydrochlorx Hydrbchlorlc Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate Skydrol 500 Sodwm Sobum Sulrur~c Chlonde (25%) Hydroxide A&d (Co&) (25%) Actd (10%) Acid (Cow) -I 0.39 +6.24 +10.0 -7.55 +34.5 +1.08 -11.5 +0.10 +1.12 +33.9 +0.31 +64.6 -7.84
Tensile strength Retained K

117.2 122.2 87.2 97.2 97.7 84.5 92.2 122.2 121.4 42.2 117.2 62.2 113.5
Elongation Retained ?4
100 0 96 3 85.5 89.5 81.9 81.9 85.5 105.3 105 3 9.4 100.0 55 0 62.6

-1 -1 -11 -6 -24 0 -4 -2 i2 0 t2 -26 f7
SUrfaCt Condition
SI. Tacky Unchanged Unchanged Unchanged Swollen Unchanged Unchanged Unchanged Unchanged Unchanged Swollen Unchanged
(10%)
ride (1%) Toluent UDMH
Six
Months Immersion at 79 Elongation Retained W

96.3 89.5 65 8 85.6 5 92 96 3 94.7 74 8 74.8 57.3 101.5 100.0 97.8 83.9 80.2 87.1 90 9 92.3 97.3 Broken 97.8 55.0 65.8
k SF Hardness Change pt*

-4 -24 -28 -5 12 -2 -4 -13 -29 -28 -2 -3 -13 5 -21 0 f8 -2 0 -3 -1 -27 +6
VOIUIIW Change W
Anlllne A S T M A S T.M. No No 1 011 3 011 -5.43 f55.6 +85.9 -7.03 -5.15 +0.32 -6.56 99) +44.1 +73.0 A-61 Acfd (1046) Acid (Cone +0.26 ) +8.58 +12.0 -7.77 +32.1 (250,) +2.79 -11.5 -0 01 -0.08 f410 +0.90 +68.1 -7.22 6

101.3 93.7 74.4 103.7 102.3 108.0 103 5 81.5 75.0 63.5 1185 124 2 108.5 96.5 91 8 102.8 99.4 106.3 113.5 Broken 111.5 58.5 119.2
Surface Condition
Unchanged Swollen Swollen Unchanged Unchanged Unchanged Unchanged Unchanged Swollen Swollen Sl. Tacky Unchanged Unchanged Unchanged Swollen Unchanged Unchanged Unchanged Unchanged SI.Tacky Swollen Unchanged
Benzaldehyde Dfoctyl Phthalate Dlsttlled Ethyl Water
Alcohol
Ethyl Ether Gasoline (RON Hexane Hydrochloric Hydrochlorx Lard
Methyl Ethyl Ketone Perchloroethylene Potassium Skydrol Sodturn Sodium Sulfurtc Permanganate 500 Chlortde (25%) Hydroxide (10%) Acid (Cone
12 Months Immersion at 79 Vdunw Change %

AnlIme A ST M. No A S.T M No Eenzaldehyde Dloctyl Phthalate Dtstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON Hexane Hydrochlor,c Hydrochlorx Lard Methvl Ethyl 99) Acid Acld (lo?&.) (Cone ) 1011 3 011 -4.31 +59.3 f88 0 -7.94 -5.18 +o 68 -5.64 +31.1 +75.2 +70.9 10.39 +12 2 +I0 6 -7.48 +36.8
2 SF Hardness ChangePts.
T3 -28 -29 15 -4 -1 5 -20 -29 -22 1 -4 -9 i3 -19
Tamik Strength RetBirmdn

109.2 91.5 77.9 106 108.5 107.0 116.3 82.2 75 7 64.3 1165 122.0 100.0 93.5 100 99.3 0 2
97 8 80.2 67.8 73.2 89 3 92.3 96.3 69 5 71.2 53.5 92.5 90 8 89 3 74 8 71 2
Surfaa Condii
Unchanged Swollen Swollen SI Tacky Unchanged Unchanged Unchanged Unchanged Swollen Swollen SI Tacky Unchanged Unchanged Unchanged Swollen Unchanged
Ketone
Perchloroethylene Potassium Permanganate Skydrol 500 Sodurn Sodturn Sulfuric Chloride (25%) Hydroxide ( IOn.) Acid (Cone )
(25%)
+4.56
-11.2 -0.34 +o.os +44.1 +0.51 -l-77.0 +9.78
104.5 1115
110.7 Broken 112.9 59.4 124.3
87.1
87.1
-2
+10
96 3
92 5 Broken loo.0 53.5 58.8
Al
0 18 -1 -28 -5
Unchanged Unchanged SI Brittle
SI. Tacky Swollen Unchanged
(continued)
327
TABLE 2.12:
VARIOUS
ELASTOMERS
CHEMICAL
AND RUBBERS-EXXON
OF NATURAL
CHEMICALS
(continued)
RESISTANCE
RUBBER COMPOUND
72 Hwrs Immersion at 212OF VobM

~w.W
Tensile Strength
RaMled K
Elongatii
Ret8hd SC
Hardness Change Pts. -19 -34 -35 -25 -30 -3 0 -15 -20 -4 -20 -21 -43 -1 -41 -3 -5 -3
SUlfXZ
Condiiion Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Si. Brittle Unchanged Unchanged SI. Tacky Unchanged
Aniline ASTM No. 1 Oil A.S.T.M. No. 3 Oil Benzsldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Heune Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) Skydrol500 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tida (1%)
+32.1 +77.6 +143.9 +244.8 +147.7 +6.14 +2.35 +84.6 +io8.a +11.2 +BO.9 +47.2 -l-465.4 +3.15 +48.6 -0.36 +2.96 Disinbgmted +5.89
30.2 38.7 11.2 4.3 10.2 89.2 78.4 34.a 26.2 61.0 36.7 44.6 3.6 54-4 22.6 89.5 94.8 86.9
45.5 70.0
50.8
16.2 27.7 78.5 58.4 34.6 28.4 49.2 42.3 51.5 17.8 49.2 65.4 83.1 83.1 75.5
One Month Immersion at 75O i BF Vuhnlle
-m%
Amline A.S T.M. No. 1 011 A.S 7.M No. 3 Oil Benzaldehyde Dtoctvl Phthalate Drstilled Water Ethyl Alcohol Ethyl Ether Heune Hydrochloric Acid (10%) Lsrd Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate(25%) Skvdrol 600 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) +a.90 +24.6 +107.3 +7a.3 +64.3 +1.32 +1.85 +95.5 +107.4 +2.17 +51.3 +46.a +219.7 +4.19 +25.8 -0.83 +0.72 +206.1 +1.92
Tmsile Sbwwth Reteined 2 94.4 88.2 42.0 34.4 54.4 102.6 88.9 28.2 31.5 96.1 63.6 53.4 23.0 84.3 89.2 105.3 102.3 20.7 97.1
Elonnation Hardness Retakd SC ChanpPts. 90.1 82.5 38.6 38. i 53.1 100.9 73.2 32.3 31.6 91.7 60.1 56.1 22.4 81.5 88.5 97.7 97.7 20.8 94.7 -5 -10
Surface condition SI Tacky Unchanged Unchanged Unchanged Unchanned Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Brittle Unchanged Unchanged Unchanged Unchanged Unchanged
-18
-20 -15 0 -4 -17 -16 -1 -15 -15 -20 -3 -11 -1 -1 -20 0
Three Months immersion at 75 2 5OF VOIUITIO Channn Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 Oil Benzaldehyde Droctyl Phthalate Drstilled Water Ethyl Alcohol Ethyl Ether Hexane Hydrochloric Acid (10%) +ii.a +41.8 +102.2 +87.0 +78.4 +2.98 +2.15 +119.3 +107.3 +3.61 Tmsile Stmngth Retained % 89.8 79.3 41.0 20.7 57.4 103.0 79.7 24.3 28.9 84.0 Elongation Retained% 88.5 74.6 38.6 30.7 55.4 98.6 78.5 31.6 30.7 79.2 Hardness ChanrgaPte. -7 -10 -15 -24 -19 0 -3 -21 -18 -2 Suliace Condiiion SI Tacky Unchanged Unchenged SI. Tacky Unchanged UnchanIyd Unchanged Unchanged Unchanged Unchanged
(continued)
328
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Thrn Vdume change K Lard Methyl Ethyl Ketone Perchloroethylcne Potassium Permanganate(25W) Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) +65.4 +4a.o +229.4 -1.29 +27.4 +0.71 +2.41 +2122 +3.28
Months Immersion at 75O t 5OF Etongatbl Retained% 53.1 44.6 21.5 68.6 77.8 91.7 77.2 23.1 91.7 Hardness Change ph -17 -20 -23 0 -10 +2 surface Condition Unchanged St. Tacky Unchanged Brittle Unchanged Unchanged Unchanged St. Tacky St. Tacky
Tensile Strength Retained K 56.4 31.8 22.6 71.2 76.4 98.0 84.3 21.0 97.1
0
-23 -1
Six Months Immersion at 75O I?I5OF Vdume chanee w

Anlllne
Tensile Strength Retained W 89.5 71.8 35.4 11.5 44.9 97.7 76.7 21.6 30.2 79.3 51.5 24.6 19.0 61.0 57.1 87.5 74.1 16.4 98.0
Ebngation Retained %
Hardness Chanae Fts.
Surface Condition SI. Tacky Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged Brittle Unchanged Unchanged Unchanged Tacky SI. Tacky
AST M. No. 1 Oil A.S.T.M. No. 3 011 Benzaldehyde Dmctyl Phthalate Distilled Water Ethyl Alcohd Ethyl Ether Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate(25K) Skvdrol5OD Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%)
+lO.B -I-47.9 +125.8 +91.6 +B2.9 +3.34 +1.81 +106.B +104.5 +4.22
+68.8 +50.8 +255.0 +0.65 +29.5 +1.31 +3.49 +246.8 +4.75
87.1 67.7 34.0 23.1 45.5 91.7 73.9 27.0 30.0 69.3
50.1 38.6 20.8 53.1 67.0 81.5 67.0 20.8 92.4
-8 -15 -20 -29 -20 0 -5 -23 -18 0

-16 -23 -25 -3 -18 0 -1 -26 0
12 Months Immersion at 75k 2 5OF

Vdume Change K Aniline A.S.T M. No. 1 Oil A.S.T.M. No. 3 011 Benzaldchyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Hcune Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloruethylene Potassium Pennanganate(25%) Slwdrol 500 Sodium Chloride (25%) Sodium Hydruxide (10%) Tduene Tide (1%) f14.1 +48.1 + 128.8 + 106.8 +90.0 +4.54 +3.59 +111.5 +81.7 +5.06 +74.8 +57.0 +211.4 +1.29 +32.4 -0.24 +7.34 + 187.6 +6.44 Tensile Strength Ratained % 83.6 68.9 33.4 4.3 32.8 92.1 74.8 16.7 25.3 67.2 40.0 13.4 13.1 71.2 37.4 84.3 57.1 12.5 90.2 Etongatien Retained W 84.8 67.7 34.6 19.2 39.9 84.8 68.6 27.7 30.0 60.1 44.6 32.3 19.2 67.0 53.8 76.2 50.8 20.8 76.2 Hardness Change Pts. -7 -20 -23 -36 -24 +4 -2 -29 -20 +2 -24 -3D -30 -3 -25 +3 0 -22 +2 surface Cendition SI. Tacky Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Unchanged SI. Tacky Unchanged Brittle Unchansed Unchanged Unchanged St. Tacky St. Tacky
(continued)
329
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
CHEMICAL
RESISTANCE
OF SBR COMPOUND
72 Hnurs Immersion at 212OF
VOlUn CRawa% Aniline A.S.T.M. No. 1 Oil ASTM No. 3 Oil 8enzaldchydc Dioctvl Phthalatc Distilled Water Ethyl Alcohol Ethyl Ether Huane HydrochloricAcid (10%) Lard Methyl Ethyl Ketone Perchloroethytene Potassium Permanganate (25%) Stwdrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) +71.1 +24.9 + 103.9 +150.6 +%.2 +5.17 -0.12 +68.7 +61.6 +12.5 +45.8 +52.4 +208.3 +3.74 +97.2 -0.11 +1.86 +255.7 +4.03
Tmiksbwhgul R&abed% 25.8 84.4 37.7 22.5 41.8 98.8 70.9 29.5 31.2 95.1 64.3 29.9 13.9 78.7 20.1 102.5 99.6 11.1 107.8
ElongM Retained% 34.0 66.0 55.8 25.5 40.5 62.3 47.3 28.3 32.0 59.5 51.8 33.1 16.2 51.0 38.8 65.2 70.8 18.4 70.0
Wardness change Pls. -26 -13 -26 -27 -22 +2 +3 -17 -17 -2 -17 -17 -28 0 -37 +3 0 -38 +2
Surface Condii Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged V. Brittle Unchanged Unchanged Unchanged Unchanged Unchanged
One Month Immersion at 75O * 5OF Volume CKawa% Aniline ASTM No. 1 oil ASTM No. 3 Dil Bcnzaldehyde Duxtyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Huane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylcne Potasswm Permanganate (25%) Skydrol 500 Sodwm Chloride (25%) wium Hydroxide (10%) Tduene Tide (1%) +x).3 +5.21 +58.0 +105.8 +53.3 +1.35 +0.79 +74.8 +92.5 +2.04 +16.2 +47.5 +190.5 +7.42 +46.6 +0.21 +0.71 + 196.4 +2.16 TeMikSbulgth Retained% 67.2 lM.9 53.3 28.3 53.3 111.9 99.2 29.5 32.0 109.8 70.5 34.4 24.6 109.0 56.5 109.0 108.2 25.0 107.8 gKJr.rgattafr Retainad% 58.1 92.6 45.3 26.4 47.3 96.3 85.8 29.2 30.3 92.6 61.5 34.8 19.8 88.7 53.0 90.7 90.7 19.8 96.3 Hardness ChangaPts. -11 -3 -18 -19 -16 0 -1 -17 -16 +1 -14 -16 -20 -2 -17 +1 +3 -19 +1 Surface Condition SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Unchanged St. Tacky SI. Tacky V. Brittle Unchanged Unchanged Unchanged SI. Tacky Unchanged
mrs0 Months Im-ton
at 75 * SF Hardness ChanlQPk -9 +6 -17 -21 -16 +3 0 -17 -15 +3 SurtKc CondRhn St. Tacky Unchanged Unchanged St. Tacky Unchanged Unchanged Unchanged Unchanged St. Tacky Unchanned
f-8-m
Rat&led% Aniline A.S.T.M. No. 1 oil ASTM No. 3 Oil 8anzaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Huane Hvdrochlaric Acid llOX\ +22.1 +9.m +91.8 +104.8 +75.9 +2.93 +0.45 +110.0 +93.0 +3.95 a.8 98.4 56.2 21.7 50.4 117.6 94.3 29.9 31.9 109.4
-WI*
btaimd% 50.1 84.1 45.3 22.7 43.3 93.5 77.3 28.3 32.0 87.8
(continued)
330
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Three Months Immersion at 750 ? 5oF Vdume change Y Lard Methyl Ethyl Ketone Perchloroethylcne Potasswm Pwmanganate (25%) Skydrol SD0 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) +54.7 +53.1 +189.6 +9.10 +45.3 +0.52 +1.74 +189.1 +3.67 Tensile Strength Retained K 68.0 32.4 22.9 101.2 53.7 113.9 107.0 23.8 109.8 Elongation Retained % 60.3 31.1 17.9 79.3 50.1 94.3 85.0 17.1 89.8 Hardness Change Pts. -16 -15 -20 -1 -12 +3 +1 -19 +2 Surface Condition Unchanged Unchanged SI. Tacky Brittle Unchanged Unchanged Unchanged Sf. Tacky Unchanged
Six Months Immersion at 75* 2 SF Tansife sbength Retained% 57.4 101.6 52.5 24.6 54.9 109.4 89.8 28.7 32.8 107.8 75.5 37.3 21.7 91.4 54.5 108.6 92.6 18.4 107.8 Elongation Retained W 47.3 85.0 41.6 23.6 44.5 83.0 71.7 27.5 31.2 77.3 66.0 34.0 17.0 70.0 50.1 85.0 70.0 16.2 82.2 Hardness ChangePts. -5 -6 -19 -22 -17 +3 0 -18 -15 0 -16 -16 -17 -2 -18 +3 f3 -20 +3 Surface Conditii SI. Tacky Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged SI. Tacky Brittle Unchanged Unchanged Unchanged Sl. Tacky Sf. Tacky
c Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 011 Benzaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Huane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Pwmanganate Skydrol 500 Sodwm Chloride (25%) Sodwm Hydroxide (10%) Toluene lade (1%) +19.6 +13.5 +88.2 +100.8 +a3.4 +4.28 +1.26 +73.7 +58.4 +3.49 +46.3 +52.9 + 195.9 +9.31 +45.8 +1.25 +2.84 +201.8 +4.75
(25%)
12 Months Immersion at 75* 2 SF Vdume Change% Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 Oil Benraldehydc Dtoctyl Phthalate Distilled Water Ethyl Alcohd Ethyl Ether Hwane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potasswm Permanganate (25%) Skvdrol 500 Sodaurn Chloride (25%) Sodwm Hydroxide (10%) Toluene Tide (1%) +26.5 +14.9 +87.8 +110.0 +78.3 +6.08 -l-O.42 +82.8 +52.7 +6.09 +36.2 +57.3 +204.2 +11.2 +46.4 +0.11 +4.06 +166.6 +6.48 Tensile Sbength ReteimdK 57.4 96.7 53.3 16.0 49.2 111.9 94.7 26.2 29.5 106.6 62.7 25.4 21.7 77.9 47.5 109.0 85.7 13.9 110.7 Elongatien Ret&ted% 56.7 82.2 45.3 21.8 41.7 76.5 72.8 27.5 33.1 72.8 64.7 27.5 19.8 55.8 47.3 83.0 61.5 17.9 78.5 Hardness Change& -6 -7 -19 -21 -17 +4 +2 -17 -16 +3 -17 -16 -22 -4 -17 +4 +1 -21 +4 Surface CendRfen Y. Tacky Unchanged Unchanged Y. Tacky Unchanged Unchanged Unchanged Unchanged Si. Tacky Unchanged Unchanged Unchanged Unchanged Brittle Unchanacd Unchanged Unchanged Sl. Tacky St. Tacky
(continued)
331
TABLE 2.12:
VARIOUS
ELASTOMERS
CHEMICAL
AND RUBBERS-EXXON
CHEMICALS
(continued)
RESISTANCE
OF NITRILE RUBBER COMPOUND

72 Hours immersion at 212OF
Vdume Aniline A.S.T.M. No. 1 Oil A.S.T.M. No. 3 Oil Benzaldehyde Dioctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexane Hydrochloric Acid (10%) Lard Mathvl Ethvl Ketone Pe~rchloroe~hylenc Potassium Permanganate (25%) Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Tolwne Tide (1%) chrne% +250.9 -1.17 +11.3 +229.5 +54.1 +7.16 +22.3 -t-33.5 +29.1 +9.71 +11.8 +0.41 +108.8 +51.4 -5.87 +154.2 +1.09 +1.22 +124.8 $7.54
Tensite strength Retained K 17.8 118.6 104.4 20.6 60.1 117.4 52.6 53.0 62.9 66.4 92.1 108.3 25.7 43.5 83.0 24.5 109.9 101.2 10.7 106.3
Elongation Ratainad K 21.7 79.4 83.0 19.9 55.2 97.5 49.8 51.6 62.9 57.8 75.8 85.6 24.2 48.0 57.8 33.6 84.8 86.6 17.0 86.6
Hardness Change Pts. -34 -1 -7 -28 -19 -5 -10 -14 -16 -9 -4 -2 -24 -22 +1 -34 -3 -5 -31 -5
Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged V. Brittle Unchanged Unchanged Unchanged Unchanged Unchanged
One Month Immersion at 75 * SF Vduma Ckarw% Amllne A S.T.M No. 1 Oil A.S.T.M. No. 3 Oil Eenzaldehyde Dioctyl Phthalate Drstilled Water Ethyl Alcohol Ethyl Ether Gasoboe (RON 99) Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Tolwne Tide (1%) +204.2 +2.69 +4.30 +198.2 +15.7 +2.51 +11.0 +21.8 +35.9 +11.0 +1.44 +5.52 +128.2 +43.2 +1.68 +X34.2 +0.71 +1.11 +112.4 +2.54 Tarstic Sbwgth Ratainad % 24.5 104.0 105.1 26.1 79.8 109.5 86.2 53.8 80.2 85.4 102.8 105.5 26.1 60.5 110.3 37.9 111.5 111.1 29.3 101.2 mree Months TdkStmr@h WnadW 29.6 110.7 109.1 M.6 71.2 110.7 80.8 52.6 75.5 80.6 Elongation Retaii W 20.6 93.9 97.5 22.7 74.7 103.6 82.0 55.2 78.3 83.0 97.5 100.0 24.2 60.3 109.4 35.0 101.1 100.0 28.9 93.9 Hardness Change Fts. -23 -4 -7 -23 -10 -4 -11 -15 -13 -9 -3 -3 -23 -18 -7 -24 -2 -2 -23 -3 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged SI. Tacky Unchanged Unchanged Unchanged SI. Tacky V. Brittle Unchanged Unchanged Unchanged St. Tacky St. Tacky
lmmarskrn at 75O 2 5*F RoRgatim lkwnad% 21.7 97.5 97.5 19.1 63.9 101.1 78.3 54.2 75.8 78.3 Rardness Change Pts. -22 -3 -3 -23 -18 -3 -10 -16 -13 -8 Surface Condition Unchanged Unchanged Unchanged SI. Tacky St. Tacky Unchanged Unchanged Unchanged SI. Tacky Unchanged
G Anihne ASTM No. 1 Oil A.S.T.M. No. 3 Oil Benzaldehyde Dmctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane +211.8 -1.24 +4.54 +202.8 +37.4 +3.88 +10.6 +19.4 +18.6 +9.36
(continued)
332
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Three Months Immersion at 75O % 5OF Vdume -_-___~.-Hydrochloric Acld (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanaanate (25%) Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) Ch=w% +1.92 +1.02 + 126.0 +55.8 +1.56 +150.9 +0.48 +1.73 +119.5 +3.55 Tensile strength Retained w 99.6 111.1 24.9 53.8 98.8 36.4 114.2 96.8 28.9 1028 Elongation Hardness Retained SC ChangePts. 91.3 102.2 28.7 54.2 98.6 32.5 108.3 86.6 30.7 96.4 -4 +1 -22 -17 -4 -23 0 -4 A23 -4 SlllfaCe Condiion Unchanged Unchanged Unchanged Unchanged Brittle Unchanged Unchanged Unchanged Unchanged 5l. Tacky
Six Months immersion at 75* 2 5F volume change % An,t,fle A S 1 M No 1 011 A S T M No 3 011 Benzaldehyde Dmctyl Phthalate Dlstllled Water Ethyl Alcohol Ethyl Ether Casolbne (RON 99) Hexane Hydrochloric Actd (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) Skydrol 500 Sodium Chloride (25%) Sodwm Hydroxide (10%) Toluene Tide (1%) +220.0 -0.21 -f-6.87 +191.0 +56.3 +5.44 +10.0 +34.5 +22.3 +9.20 +2.88 -0.71 +154.6 +43.6 +2.63 +142.6 +1.90 +1.60 +127.4 +5.79 Tensile Strength Reteined W 21.0 111.9 116.6 19.8 64.0 105.9 84.2 49.8 77.1 79.1 104.0 115.9 24.9 46.3 98.0 35.6 107.9 94.9 27.7 104.7 Elongation Retained % 19.1 95.0 74.7 20.6 55.2 93.9 77.6 49.5 75.8 72.2 93.9 101.1 25.3 49.5 98.6 35.0 90.3 79.4 27.8 93.9 Hardness Change Pts. -25 -1 -4 -24 -18 -4 -10 -15 -Xi -6 -3 +1 -24 -18 -6 -24 -3 -4 -23 -4 Surface Condition Unchanged Unchanged Unchanged Sl. Tacky Unchanged Unchanged Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Brittle Unchanged Unchanged Unchanged Sl. Tacky Sl. Tacky
12 Months Immersion at 75O 2 5OF volume Change SC

Afl,ltIW
Tensile Strength Retained % 17.4 105.9 94.1 20.6 64.8 108.3 81.8 55.3 72.7 85.8 106.3 107.1 24.9 57.7 97.2 33.6 111.1 89.7 24.5 102.0
Elongation Retained K 22.7 87.7 79.4 24.2 57.8 92.8 75.8 55.2 72.2 76.9 86.6 92.8 25.3 55.2 89.2 35.0 97.5 73.3 28.9 89.2
Hardness Change Pts. -28 0 -5 -23 -18 -3 -9 -16 -14 -7 -3 -2 -24 -18 -6 -24 -1 -4 -24 -5
5urlace Condition Unchanged Unchanged Unchanged SJ. Tacky Unchanged Unchanged Unchanged Unchanged Y. Tacky Unchanned Unchanged Unchanged Unchanged Unchanged Brittle Unchanged Unchanged Unchanged Unchanged St. Tacky
ASTM No 1011 AS TM No 3011 Benraldehyde Dtoclyl Phthalate DMllled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) Skydrol SO0 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%)
+230.1 -0.70 +9.00 +216.3 +53.0 +6.92 +14.2 +38.0 +27.6 +26.9 +3.25 +12.3 +151.6 +59.6 + 1.92 + 147.7 +0.71 +7.04 +110.2 +8.02
(continued)
Rubbers
and Elastomers
333
TABLE 2.12:
VARIOUS
ELASTOMERS
CHEMICAL
AND RUBBERS-EXXON
OF POLYCHLOROPRENE
CHEMICALS
COMPOUND
(continued)
RESISTANCE
72 Hours Immersion at 212OF Vduma CharIRe K

Andme
Tensile Strength Retained SC 22.9 100.0 46.1 25.0 39.1 97.2 85.6 44.7 41.2 78.5 93.3 95.4 32.4 22.9 89.1 17.3 95.8 101.4 15.9 91.6
Elongation Retained X 58.3 88.3 67.3 40.4 61.4 85.2 79.4 53.8 58.3 80.7 76.2 89.7 52.5 42.6 71.8 57.0 76.2 89.7 37.2 74.9
Hardness Change PM. -45 -4 -24 -35 -34 -4 -4 -20 -28 -15 -8 -15 -28 -38 +2 -45 +5 +1 -44 -9
Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged V. Brittle Unchanged Unchanged Unchanged Unchanged Unchanged
A.S.T.M. No. I 011 AS T.M. No. 3 011 8enzaldehyde Diuctyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hcxane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanaanate (25%) Skydrol 500 Sodium Chloride (25%) Sodaurn Hydroxide (10%) Toluene Tide (1%)
+ 143.3 +5.74 +61.7 +61.3 +116.6 +9.34 +2.92 +49.5 +69.6 +24.5 +15.1 +20.0 +72.3 i242.9 +3.07 +151.0 +1.20 iO.24 +2D9.1 +11.6
One Month Immersion at 75O 2 5F Vduma challm K Amllne A.S.T M No. 1011 A S T M No. 3 011 Benzaldehyde Dmctyl Phthalate
Dlstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Herane Hydrochlonc Acld (10%)
Tensile Strength Retainad W 63.0 110.9 91.9 30.6 56.7 112.7 97.5 41.2 57.8 86.3 107.8 104.2 32.4 31.0 108.8 30.7 112.7 104.6 29.9 109.2
Elongation Retained % 76.2 100.0 85.2 40.4 58.3 106.3 91.0 52.5 62.8 80.7 95.5 98.7 52.5 37.2 97.3 53.8 97.3 94.2 35.9 100.0
Hardness Changa Pts. -28 0 -13 -25 -24 0 -4 -20 -17 -13 +1 -8 -30 -23 -1 -31 0 0 -24 $1
Surface Condition Unchanged Unchanged Unchanged SI. Tacky Unchanned Unchanged Unchanged Unchanged Unchanaed Unchanged Unchanged Unchanged Unchanged Unchanged V. Brittle Unchanged Unchanged Unchanged Sf. Tacky Unchanged
+67.3 +0.57 +19.5 +132.0 +77.1 +3.67 +3.26 +49.8 +45.8 +19.4 +2.65 +7.08 +70.6 +132.6 +4.16 +115.6 +2.3G +1.41 +141.5 +3.78
Lard Methyl Elhyl Ketone Perchloroethylene Potassium Permanaanate (25%) Shydrol 500 Sodium Chlonde (25%) Sodium Hydrorlde (10%) Toluene Tide (1%)
Three Months Immersion at 75O 2 5OF Vdume m% Aniline A.S.T.M. No. 1 Oil A.S TM. No. 3 Oil Benzaldehyde Dtoctvl Phthalate Dlstdled Water Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexane +67.8 +o.S4 +37.5 +146.2 +108.7 +6.35 +2.44 +54.8 +48.9 +21.1
Taleik stremglh
Rat&ad 50.0 108.1 87.0 24.7 46.1 114.4 94.0 46.8 60.9 70.1 %
Elmlgation
Retained% 70.4 98.7 80.7 35.9 49.3 94.2 86.6 60.5 68.6 77.6
Hardness Change PM. -27 +1 -15 -29 -25 0 -4 -23 -19 -12
Surface Condition Sf. Tacky Unchanged Unchanged Sf. Tacky Unchanned Unchanged Unchanged Unchanged Unchanaed ~ Unchanged
(continued)
334
TABLE 2.12:
Three Months Immersion at 75O 5 SF Volume Change K Hydrochlortc Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylcne Potasswm Permanaanate (25%) Skydrol 5DO Sodwm Chloride (25%) Sodium Hydroxtde (10%) Toluene Tide (1%) +4.09 +14.4 +85.5 +132.5 +7.22 +X30.6 +2.53 +3.17 +166.5 +5.99 Tensile strength Retained % 108.8 110.9 29.5 32.8 112.0 32.0 116.2 103.5 28.9 107.0 Elongation Retained W 95.5 103.1 51.6 37.2 95.5 53.8 97.3 92.8 35.9 94.2 Hardness Change Pts. +1 -10 -30 -24 0 -35 +1 -5 -25 0 Surface Condition Unchanged Unchanged Unchanged Unchanged SI. Brittle Unchanged Unchanged Unchanged Unchanged Unchanged
Six Months Immersion at 75* 2 5OF VdUtlW Change K AnlIme A S.T.M No. 1 011 A.S.T M No 3 011 Etenzaldehyde D~octyl Phthalate Dlstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane Hydrochlcr!c Actid(10%) Lard Methyl Ethyl Ketone Perchloroethylene Potasswm Permanganate (25%) Skydrol 500 Sodwm Chlorlde (25%) Sodwm Hydrorlde (10%) Toluene Tide (1%) +62.7 +1.20 +44.2 +156.4 +114.4 +10.5 +2.48 +51.9 +50.7 +20.3 +5.77 +15.5 +92.8 + 142.9 i9.72 +142.3 +3.02 +3.87 +204.2 +9.42 Tensile Sb-ength Retained W 51.4 112.3 91.9 20.1 48.6 94.7 90.1 38.4 50.7 75.7 102.1 107.4 23.2 26.8 106.7 25.0 112.3 95.8 23.2 91.2 Elongation Retained % 77.6 101.8 83.0 39.0 50.7 80.7 69.7 57.0 64.1 73.1 85.2 94.2 49.3 31.4 83.9 53.8 94.2 86.6 31.4 77.6 Hardness Change Pts. -29 +1 -20 -35 -26 -4 -5 -25 -20 -12 -1 -14 -34 -29 -2 -40 +2 0 -28 -3 Surface Condition SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Sl. Brittle Unchanged Unchanged Unchanged Unchanged Unchanged
12 Months Immersion at 75O 2 5OF Vduma Change K Aniline A.S.T ht. No. 1 011 A.S T M. No. 3 011 Benzaldehyde D~octvl Phthalate Dtstllled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potassium Permanganate (25%) Skydrol 500 Sodium Chlonde (25%) Sodaurn Hydrorlde (10%) Toluene T#de (1%) +65.9 +1.10 +43.8 +190.0 +125.5 +ia7 +6.05 +56.8 +54.6 +20.8 +9.13 +17.5 +94.4 +147.5 + 13.0 +156.7 +1.81 +3.99 +171.5 +12.3 Tensile strength Retained % 28.2 96.9 70.5 7.4 38.7 79.6 89.8 34.5 47.9 65.1 95.8 94.0 21.5 25.0 90.5 la7 104.6 816 20.4 84.2 Elongation Rabined% 67.3 94.2 79.4 35.9 49.3 70.4 86.6 59.6 67.3 70.4 73.1 95.5 55.2 37.2 70.4 57.0 83.9 73.1 35.9 64.1 HarW Chanp -38 0 -19 -51 -29 -8 -4 -29 -23 -13 0 -14 -38 -31 -4 -43 -7 +1 -34 0 sulfaa Condition SI Tacky Unchanged Unchanged SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Brittle Unchanged Unchanged Unchanged SI. Tacky Unchanged
Pts.
(continued)
335
TABLE 2.12:
VARIOUS
ELASTOMERS
RESISTANCE
AND RUBBERS-EXXON
OF CHLOROSULFONATED
CHEMICALS
POLYETHYLENE
(continued)
COMPOUND
CHEMICAL
72 Hours Immersion
VdUmC
at 212-F
Hardness Change Pts. -54 +4 -21 -30 -29 -4 -6 -17 -30 -14 -1 -11 -24 -30 -5 -32 -1 0 -37 -5 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged SI. Brittle Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Brittle Unchanged Unchanged Unchanged Unchanged Unchanged
change K Aniline A.S.T.M. No. 1 011 A.S.T.M. No. 3 011 Benraldehyde Duxtyl Phthalate Distilled Water Ethyl Alcohol Ethyl Ether Basoltne (RON 99) Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Penhloroethylene Potassium Pennanganate (25%) Skydrol5DO Sodium Chloride (25%) Sodium Hydroxide (10%) Toluene Tide (1%) + 147.4 +6.59 +66.9 +40.4 + 125.3 +9.43 +4.80 +44.9 +104.7 +24.7 +4.25 +20.3 +61.2 +150.2 +7.74 +108.7 +1.14 +1.07 +171.1 +8.65
Tensile Strength Retainad K 86.4 73.3 49.6 20.1 28.4 97.2 81.1 34.5 25.4 49.3 103.9 76.3 27.3 22.3 100.8 23.1 99.7 96.1 17.8 85.0
Elogatio Retained K 73.9 35.3 114.5 29.0 49.8 80.7 82.1 48.3 53.1 62.8 88.4 77.3 40.1 37.2 80.7 44.9 83.6 78.7 36.2 73.9
One kkmth Immersion at 75 5 5OF Vdume Ctwv% AmIme A S 1 M. No 1 011 A S T.M No 3 011 Benraldehyde D~octyl Phthalate DMllled Water Ethyl Alcohol Ethyl Ether GasdIne (RON 99) Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroethylene Potasswm Pennanganate (25%) Skydrol 500 Sodwm Chloride (25%) Sodium Hydroxide (10%) Tolucne Tide (1%) +63.1 +0.59 +B.O2 +117.4 +40.3 +1.17 +2.51 +43.0 +48.4 +22.1 +1.80 +5.04 +70.0 +112.7 +2.50 +88.0 -0.23 +0.58 +128.8 +1.98 Tensile strength Retained 54 47.6 104.7 82.5 28.4 56.6 104.5 97.5 28.7 37.8 57.7 109.8 81.9 32.3 27.6 109.8 40.4 109.2 109.5 25.6 108.1 Three Months Vdunm ChrnOls% AmIme A.S.T.M. No. 1011 A.ST.M No 3011 Benzaldehyde Dmctvl Phthalate Olstllled Water Ethyl Alcohol Ethyl Ether Gasoirne (RON 99)
Herane
Elongation Retained % 67.6 101.5 82.1 33.8 61.4 x30.0 98.1 46.9 51.7 67.6 102.9 85.5 43.5 37.2 101.5 44.9 98.1 114.5 33.8 100.0
knmerrion
Hardness Change Pk. -18 0 -3 -16 -21 +1 -4 -18 -20 -11 +3 -2 -16 -6 0 -19 +1 +2 -18 +2
Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged St. Tacky SI. Tacky Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
at 75
!TF Surface Condiin sl. T8cky Unchanged Unchanged Unchanged Unchanned Unchanged Unchanged V. Tacky Tackv Unchanged
T-=-m
RM8MW 38.7 108.6 74.9 25.4 43.7 109.6 94.4 35.1 37.9 47.6
&nation
Rabined% 61.4 96.7 75.7 33.8 42.0 88.4 90.3 51.7 53.1 59.4
Hardms Chanm Pk. -20 +2 -9 -19 -16 +2 -2 -16 -19 -11
+64.1 +0.34 +1a.2 +115.2 +115.5 +2.45 +5.50 +45.6 +51.7 +23.6
(continued)
336
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Three Months Immersion at 75 * 5OF volume Change W Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Parchloroathvtene Potassium Pennanganatc (25%) Skydrol 500 Sodium Chloride (25%) Sodium Hydroxide (10%) Toluenc Tide (1%) +2.36 +7.56 +68.4 +125.5 +4.17 +87.8 l Fo.23 l Fo.93 i-135.4 +3.95 Tenrite Strength Retained < 108.6 96.1 28.1 281 115.9 42.1 116.4 99.7 23.7 107.8 Elongation Retried % 98.1 90.3 40.1 33.8 98.1 44.9 99.0 90.3 32.4 96.7 Hardness Change Pts. +2 -4 -16 -18 +4 -17 +5 0 -18 +1
Surfs
Condiiien Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SJ. Tacky
Six Months Immersion at 75O 2 5OF volume Chenge W Anlllnt A ST M No. I 011 A S 1 M No 3 011 Benraldehyde D~octyl Phthalatc
Dtst~llcd Water
Tensik Strengtft Retained W 35.1 109.8 77.7 28.4 41.0 113.9 98.6 33.7 35.1 60.2 108.1 86.6 29.5 25.1 111.4 40.1 113.9 107.0 26.7 104.2
Elongation Retained K 62.8 93.2 82.1 37.2 42.0 91.8 91.8 51.7 58.0 62.8 95.2 84.5 42.0 30.4 90.3 48.3 95.2 90.3 33.8 88.4
Hardness Change Pts. -22 +2 -10 -20 -17 0 -3 -18 -20 -11 +2 -7 -17 -19 +1 -19 +3 +2 -18 +2
surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky Tacky Tacky Unchanged Unchanged Unchanged Unchanged Unchanged SI. Brittle Unchanged Unchanged Unchanged Unchanged SI. Tacky
+62.0 +0.44 +3G.3 +103.8 + 122.8 +5.13 +6.54 -t-46.0 +51.1 +23.6 +3.27 +16.4 +68.4 +1G9.0 +6.80 + 102.2 +0.46 +1.28 +143.6 +5.16
Ethyl Alcohol Ethyl Ether Gasoline (RON 99) Hexanc Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Perchloroathylene Potasswm Permanganate (25%) Skydrol 500 Sodium Chloride (25%) So&urn Hydroxide (1.0%) Toluana Tide (1%)
12 Months Immersion at 75O -C 5OF Volume Change K

AflhW
Tensite Strength Retained K 26.2 108.6 72.4 24.5 39.8 116.2 101.7 33.9 32.3 54.6 114.2 75.2 28.1 24.5 114.2 32.9 115.9 110.3 24.5 112.3
Elongation Rtiained K 64.3 95.2 75.9 37.2 43.5 87.0 91.8 58.0 51.7 66.2 90.3 78.7 42.0 37.2 87.0 48.3 93.2 90.3 35.3 82.1
Hardness Change Pts. -29 +2 -12 -21 -20 0 -11 -19 -19 -11 +4 -10 -20 -20 +1 -19 +4 -l-4 -2G 0
Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Si. Tacky Tacky Tacky Unchanged Unchanged Unchangad Unchanged Unchanged St. Brittle Unchanged Unchanged Unchanged St. Tacky Unchanged
A S 1 M No. 1 011 ASTM No 3011 Benraldehydc Dwtvl Phthalatc Dlstdled Water Ethyl Alcohol Ethyl Ether Gasolme (RON 99) Hexane Hydrochloric Acid (10%) Lard Methyl Ethyl Ketone Parchloroathylcne Potaswm Permanganata (25%) Skydrol 500 Sodwm Chloride (25%) Sodium Hydroxtde (10%) Tolucne Tide (1%)
+71.8 +0.59 +40.3 +119.8 +110.5 +6.86 +5.53 +47.8 +51.8 +25.0 +16.1 +24.9 +86.0 +105.7 +8.83 +88.6 +1.03 +X52 +188.0 +9.11
(continued)
Rubbers
and Elastomers
337
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
CHEMICAL
RESISTANCE
OF V&TALON
6505 COMPOUND
72 Hours Volume Change X A.S.T.t.4 A.S.T.M. A.S.T.M. No. 1011 No. 3 011 Fuel B + 129.3 + 222.4 + 171.9 +0.5 -4.6 Tensile Strength Retained % 30.8 20.9
Immersion
at 2 12F Hardness Change Pts. -37 -44 Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged
Elongation Retained % 45.9 29.5
14.1
93.2 87.5
21.3
77.0 82.0
-11
+l +3
Dtistllled Water Ethyl Alcohol
Hexane
Hydrochloric Acid (10%) Methyl Ethyl Ketone Olive Oil Skydrol 500
+69.0
+ 10.4 + 10.7 +41.6 +5.5
18.6
66.9 62.7 55.1 98.1
24.6
57.4 70.5 65.6 88.5
+2
-2 -9 -27 -9
Unchanged Unchanged Unchanged SI. Tacky SI. Tacky
Sodium Chloride (25%) Sodium Hydroxide (lD%) Trde (1%)
+2.8 -0.4 +0.6
88.6 93.9 89.7
75.4 75.7 75.4
+l 0 -1
One Month Volume Change % ASTM No Tensile Stmngth Retained % 40.3 25.5 19.0
immersion
at 79 2 5F Hardness Change Pts. -18 -29 -27 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
Elongation Retained % 49.2 24.6 23.0
1011
+42.8
A S 1 M No 3 Oti ASTM Fuel B
+ 162.3
+ 168.7 + 1.25 +1.9
Drstllled Water Ethyl Alcohol
111.0
98.9
96.7
95.1
-2
-5
Hexane Hydrochlonc Acid (10%) Methyl Ethyl Ketone Olive 011 Skydrol 5DO
+159.9
+1.2 +3.1 + 14.6 -1.8
20.2 107.2 82.9 81.0 103.0
23.0 101.6 90.2 85.3 101.6
-26 -2 -10 -9 -4
Unchanged Unchanged White Res. Unchanged V. Tacky
Sodrum Chlonde (25%)
+0.6
97.3
loo.0
-2
White Res.
Sodwm Hydroxtde (10%) Tide (1%)
+O.l +0.7
95.8 92.0
95.1 95.1
-3 0
Unchanged Unchanged
338
TABLE 2.12:
VARIOUS
ELASTOMERS
AND
RUBBERS-EXXON
CHEMICALS
(continued)
Three Months Immersion at 75 2 5F Volume Change K ASTM No 1011 t83.7 t 175.0 7183.3 -0.9 +i.2 Tensile Strength Retained % 36.1 24.3 17.9 98.1 88.9 Elosgation Retained % 42.6 26.2 16.4 96.7 93.4 Hardness Change Pts. -26 -27 -30 0 -4 Surface Condition Unchanged Unchanged Uuchange?d Unchanged Unchanged
A S T M. No. 3 011 A S T M. Fuel El Drstrlled Water Ethyl Alcohol
Hexane Hydrochlonc Actd (10%)
+ 152.6 t1.7 +2.7 +25.4 -2.2
20.5 108.4 77.6 76.8 104.2
22.9 95.1 83.6 85.2 96.8
-29 cl -16 -2 7
Methyl Ethyl Ketone Olrve 011 Skydrol 500
Sodwm Chlonde (25.) Sodrum Hydroxide (10~) Tide
0 -0.2 +0.2
91.2 98.5 85.2
88.5 96.7 90.2
-0 +l 0
( 1%)
Six Months Immersion at 75 + 5F Volume Change %

A
Tensile Strength Retained K 36.1 27.8 18.6 98.5 82.1
Elongation Retained % 42.0 27.9 18.0 98.4 88.5
Hardness Change Pts. -27 -31 -31 +I -2
Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
S TM
No
Oil
+115.3 t 198.9 +211.0 -0.5 +1.25
AS TM
No
3011
A S 1 M Fuel 8 Dlstrlled Water Ethyl Alcohol
Hexane Hydrochlonc Acrd (100.)
+192.1 +0.6 t2.8 +29.0 -2.6
19.4 98.9 82.5 73.8 100.0
23.0 95.1 86.9 83.6 95.1
-28 +l -5 -15 -2
Methyl Ethyl Ketone Olive Oil Skydrol 500
Sodium.Chlonde
(25%)
-0.2 0 +0.4
94.3 98.5 92.8
91.8 93.4 93.4
+2 +l 0
Sodrum Hydroxrde Trde (1%)
I ~WC.)
CHEMICAL
RESISTANCE
OF 30 VISTALON
6505170
BUTYL
RUBBER
BLEND
COMPOUND
72 Hours Immersion at 212f Volume Change X A.S.T.M. A.S.T.M. A.S.T.M. No. 1 Oil No. 3 011 Fuel 8 + 68.2 + 136.9 + 133.7 +2.2 -2.0 Tensile Strength Retained X 57.6 36.6 30.2 98.8 91.9 Elongation Retained % 57.1 35.7 35.7 92.9 78.6 Hardness Change Pts. -25 -28 -27 0 +l Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged (continued)
Dishtled Water Etnyl Akohol
Rubbers
and Elastomers
339
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
72 Hours Volume Change % Hexane Hydrochlonc Acid (10%) Methyl Ethyl Ketone Olwe 011 Skydrol 500 +51.9 +7.1 +12.8 +28.1 +a.5 Tensile Strength Retained % 35.5 88.4 68.0 71.5 84.3
Immersion 212F at
Elongation Retained % 35.7 75.0 71.4 78.6 85.7 Hardness Change Pts. -5 0 - 12 -20 -12 Surface Condition Unchanged Unchanged Unchanged SI. Tacky SI. Tacky
Sodium Chlonde (25%) Sodwm Hydroxide (10%) Tide (1%)
+0.8 -0.1
100.6 95.9
85.7 85.7 82.1
+l -1 -2
+0.9
92.4
One Month Immersion Volume Change % A S 1 h4 No AS TM 1 011 +15.1 +67.9 +117.2 +2.5 +2.5 Tensile Strength Retained % 73.8 49.4 34.9 98.3 94.2
at 75
z SF Hardness Change Pts. -8 -16 -19 -1 -2 Surface Condition Unchanged Unahanged Unchanged Unchanged Unchanged
No 3011
A.S 1 M Fuel 8 DIstilled Water Etnyl Alcohol
Herane Hydrochloric Aild (10%)
+ 104.6 +0.2 +5.7 +5.3 +0.4
33.1 101.7 74.4 93.6 94.8
32.1 96.4 78.6 92.9 ?07.1
-18 0 -8 -5 -2
Methyl Ethyl Ketone Olwe 011 Skydrol 500
Sodurn Chloride (25:0) Sodium Hydrorlde Tide (1OQ
+O.l +0.2 +0.2
95.3 102.3 100.5
96.4 100.0 100.0
-1 -2 0
White Res. Unchanged Unchanged
I looI
Three Months Immersion at 75 II sF Volume Change % A.S.7.M A.S.1.M

No.
Hardness Change Pts. -12 -17 -21 +l -2
1 011
+29.0
+ 108.6 + 132.3 -0.4 -1.8
66.9
45.4 34.3 100.0 91.9
No. 3 011
A S.T.M. fuel 8 DistIlled Water Ethyl Alcohol
Herane Hydrochlortc Acld (10%) Methyl Ethyl Ketone Olwe 011 Skydrol 5DO
+117.3 +0.5 +6.5 + 10.6 io.4
37.8 95.9 75.0 85.5 97.7
35.7 96.4 82.1 89.3 96.4
-18 +l -7 -8 -3
Sodwm Chloride (25%) Sodurn Hydroxide (10%) Tide (lo.1
-0.11
0 +0.3
97.1
92.4 94.8
78.6 89.3
85.7
0 +l
0
(continued)
340
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Sir Months Immersion Volume Change % A.S T.M. No. 1011 A S T.M. No. 3 011 A.S.1.M Dlstllled Fuel 8 Water +45.2 + 118.0 Tensile Strength Retained % 59.9 45.3
at 75
z SF Hardness Change Pts. -17 -20 Surface Condition Unchanged Unchanged Unchanged Whrte Res. Unchanged
+151.1
-0.1 +1.7
33.7
97.7 89.0
28.6
100.0 85.7
-19
+l 0
Etnyl Alcohol
Hexane Hydrochlonc Methyl Acid CIOO~l
+159.0 +0.5 +5.9 +15.8 +o. 1
37.8 98.9 79.7 87.2 94.2
32.1 92.9 82.1 92.9 92.9
-18 -8 -7 -9 -3
Elhyl Ketone
Olwe 011 Skydrol 500
Sodwm
Chlonde
(2!X.) (I@41
-0.3 0 +0.3
98.8 93.0 97.7
92.9 89.3 96.4
+3 +2 +l
Sodaurn Hydroxide Tide
(1%)
RESISTANCE
CHEMICAL
OF 30 VISTALON
6505170 VISTALON
2504 BLEND COMPOUND

at 2 12F HarrJness Change Pts. -27 -32 -12 -1 0 Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged
72 Hours Immersion Volume Change % A.S.T.M. No. 1011 c94.7 + 141.0 + 138.0 -13.0 -2.7 Tensile Strength Retained % 59.6 37.3 32.4 105.9 94.5
A.S.T M. No. 3 011 A.S.T M Fuel 8 bstllled Water
Ethyl Alcohol
Hexane Hydrochloric Methyl Acid (10%)
+49.8 +12.2
40.5
89.3
37.0
74.1
-2
-4
Ethyl Ketone
+11.9
+34.9 +8.4
73.0
68.6 91.9
77.8
74.1 96.3
-10
-22 -10
Okve 011 Skydrol 500
Sodium Chlonde Sodium Hydroxide Tide (1%)
(25%) (10%)
+1.7 +0.3 co.2
106.5 105.4 98.8 One Month
88.9 107.4 88.9
0 +l -2
immersion
at 75 2 5F Hardness Change Pts. Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
Volume Change % A S 1 M No AS TM No I 011 3011
Elongation Retained %
+42.3 +114.0
+126.5
68.1 47.0
30.8
66.7 40.7
29.6
-15 -21
-21
A S T M Fuel I3 Dlstllled Water
+l.l
+1.9
105.9
101.6
107.4
96.3
-1
-4
Ethyl Alcohol
(continued)
Rubbers
and Elastomers
341
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
One Month Volume Change % Hexane Hydrochior,c Methyl Acjd (IO,) +115.7 +0.5 +5.6 + 14.9 +0.6 Tensile Strength Retained % 37.8 107.0 89.1 85.4 101.6
Immersion
at 75
2 5F Hardness Change pts. -18 Surface Condition Unchanged Unchanged White Res. Unchanged V. Tacky
Elongation Retained % 29.6
111.1
100.0 96.3 103.7
-3
-8 -9 -4
Ethyl Ketone
Olive 011 Skydrol 500
Sodturn Chloride Sodaurn Hydroxtde Tide Cl,)
(250,)
+0.3 +0.2 +0.4
104.3 104.3
107.4 100.0
-2 -2
(10.)
101.1
Three Months
100.0
Immersion Elongation Retained % 62.9 40.7 25.9 103.7 92.6
-1
at 75 2 5F Hardness Channe Pts. -19 - 19 -22 0 -2
Volume Change %
A !, 1 M No I
Tensile Strength Retained % 64.2 47.0 33.5 106.5 97.3
Surface Condition Unchanged Unchanged White Res. Unchanged Unchanged
011
+69.5
+ 123.9 +135.6 +o. 1 +1.2
A S I M No 3 011 A S 1 M Fuel B Dlst!lled Waler
Ethyl Alcohol
Herane Hydrochloric Methyl Acid
t 121.9
42.2
102.7 88.7 82.7 101.6
33.3
96.3 85.2 92.6 100.0
-20
0 -7 -13 -3
White Res. Unchanged Unchanged Unchanged Unchanged
I lo.)
t23.9 -0.6
0
+7.0
Ethyl Ketone
Sodbum Chloride (25%) Sodium Hydroxide Tide (loo)
+O.l +O.? +0.08
98.4 98.9 103.8 Six Months immersion
81.5 92.6 100.0 at 75 + 5F
0 0 -1
(lO.l
Volume Change % A !z, T M No I 011 t 100.6 t 122.1 +156.8 +0.4 +2.4
Elongation Retained %
Surface Condition Unchanged Unchanged White Res.
58.9 46.5
34.6 103.8 101.6
55.6 37.0
29.6 103.7 100.0
-20 -23
-22 0 0
A S 1 M No 3 011 A S T M Fuel B Dwllled Waler
White Res. Unchanged
Ethyl Alcohol
Hexane Hydrochlonc Methyl Acid (lo,)
+157.3 +0.5 +5.6 t26.2 500 -0.2
42.2 99.5 88.1 86.5 102.2
37.0 85.2 85.2 81.5 100.0
-20 0 -8 -13 -3
White Res. Unchanged Unchanged Unchanged Unchanged
Ethyl Ketone
Olive DII Skydrol
Sodlum Chlonde (25% Sodwm Hydroxide
-0.3 +0.3
104.3 105.4 103.2
100.0 100.0 96.3
+l 0 0
White Res. Unchanged Unchanged (continued)
(:O%)
Tide (1%)
+0.9
342
Corrosion Resistant Materials Handbook VARIOUS ELASTOMERS

RESISTANCE
TABLE 2.12:
AND
RUBBERS-EXXON
CHEMICALS
(continued)
OF 30 VISTALON
6505170
NATURAL
RUBBER BLEND COMPOUND

at 212F Hardness Change Pts. -37 -45 -38 0 +l Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged
72 Hours lmmersron Volume Change % A.S.1 M No 1011 + 121.5 b232.4 + 155.9 +3.5 - 1.2 Tensile Strength Retained % 42.3 12.6 18.1 101.5 104.8
A.S T M. No. 3 011 A S.T.M. Fuel 8 D,stllled Water
Ethyl Alcohol
Hexane Hydrochlonc Methyl Acid (lo.)
+39.5 + 16.4 +37.8 + 76.6 +35.7
31.8 74.1 59.4 48.8 55.4
38.7 67.7 67.7 61.3 90.3
-4 -4 +3 -31 -28
Ethyl Ketone
Olrve 011 Skydrol 500
Sodium Chloride Sodwm Tide Hydroxide
(25%) (10%)
+0.2 co.9 +3.1
107.6 98.8 109.2
93.5 90.3 97.8
+l -1 -2
(1%)
One Month Immersion at 75 = 5F Volume Change % A.S T M No. 1011 A.S.T M No. 3 011 A S.T.M. Dlstrlled Fuel B Water +37.2 + 141.8 +178.9 +1.7 +3.1 Tensile Strength Retainrd % 61.5 41.2 18.1 111.4 105.9 Elongation Retained % 64.5 41.9 16.1 100.0 103.2 Hardness Change Rts. -7 -25 -2 -1 -6 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
Ethyl Alcohol
Hexane Hydrochlorrc Methyl Acid (10%)
+ 131.4 +l.l +34.0 +45.4 + 13.9
32.4 110.3 47.2 65.9 77.9
38.7 106.5 58.1 64.5 83.9
-24 -1 -17 -14 -4
Ethyl Ketone
Sodwm Sodlum
Chloride Hydroxide
(25%) (10%)
+O.l 0 +0.9
105.9 116.9 107.0
106.5 112.9 103.2
+2 -2 0
Trde (1%)
Three Months Volume Charwe % A.S.T.M. A.S.T.M. A.S.T.M. No. 1011 No. 3 Ori Fuel 6 +64.3 +157.1 + 193.5 +I.5 +2.4 Tensile Strength Retained % 60.4 39.0 23.1 114.7 84.5
Immersion at 75 z 5F Elongation Retained % 61.3 38.7 29.0 106.5 96.8 Hardness Change Pts. -20 -25 -32 0 -4 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
Drstrlled Water Ethyl Alcohol
(continued)
Rubbers
and Elastomers
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued
Three Months Immersion at 75 2 5F Volume Change % Tensile Strength Retained % 31.3 100.4 52.7 53.2 65.9 104.3 104.8 104.8 Elongation Retained % 35.5 96.8 74.2 54.8 77.4 80.7 93.6 100.0 Hardness Change Pts. --20 +l -21 -23 -13 +l 0 0 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
Hexane
Hydrochloric Acid (10%) Methyl Ethyl Ketone Olive 011 Shydrol 500 Sodwm Chlorrde (25~~~) Sodrum Hydroxide Tide
t141.3 +1.4 +35.1 +63.4 +16.5 -0.1 +0.5 +1.7
( 10o)
1loa)
Six Months Immersion at 75 + 5F Volume Change % ASTM AS TM AS TM No 1011 No 3011 Fuel 8 +79.0 + 161.8 -258.2 +1.9 +2.4 Tensile Strength Retained X 57.6 41.2 19.2 107.0 58.7 24.1 103.2 24.7 65.9 39.5 101.0 98.2 110.3 Elongation Retained % 58.1 41.9 29.0 100 0 74.2 29.0 96.8 54.8 61.3 64.5 90.3 87.1 100.0 Hardness Change Pk. -25 -29 -33 Al -3 -29 +l -25 -23 -17 +2 42 +l Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged
Dtstllled Water Ethyl Alcohol Hexane Hydrochlonc Acrd (10%)
+ 189.9 +1.8 +41.1 +72.7 +21.8 -0.3 +0.7 +2.2
Methyl Ethyl Ketone Ohve 011 Skydrol 500 Sodrum Chlonde (25%) Sodrum Hydroxrde (10%) Trde (1%)
CHEMICAL
RESISTANCE OF 30 VISTALON 6505170 SBR BLEND COMPOUND

72 Hours Immersion at 212F Volume Channe % Tensile Strength Retained % 74.9 50.7 16.8 97.7 87.5 Elongation Retained % 66.7 42.9 28.6 95.2 81.0 Hardness Change Pts. -17 -22 -23 -1 -1 Surface Condition SI. Tacky Sl. Tacky Unchanged Unchanged Unchanged
A.S.T.M. A.S.T.M. A.S.T.M.
No. 1 011 No. 3 011 Fuel B
+ 41.8 + 107.0 +115.1 +5.3 -2.1
Drstilled Water Ethyl Alcohol
Hexane Hydrochloric Acid (10%) Metnyl Ethyl Ketone Olrve 011 Skydrol 500
+ 28.8 + 12.8 +30.6 +39.4 +37.7
39.6 94.9 55.4 67.0 64.7
42.9 76.2 57.1 61.9 66.7
-2 -2 +4 -18 -19
Sodrum Chlonde (25%) Sodrum Hydroxtde (10%) Trde (1%)
+2.7 +0.6 +5.3
102.4 104.2 101.9
85.7 85.7 85.7
0 0 -1
Unchanged Unchanged Unchanged (continued)
344
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
One Month Vdume Change X AS 1 M No 1011 +13.1 +84.9 + 105.8 +2.86 +2.8 Tensile Strength Retained K 91.2 53.1 34.4 105.6 94.9
Immersion
at 75 z 5F Hardness Change Pts. -7 -17 -17 -2 -3 surtrcc Condition Unchanged Unchanged Unchkged Unchanged Unchanged
A S 1 M No 3 011 ASTM Dlstllled Ethyl Fuel 8 Water
Alcohol
Hexane Hydrochloric Methyl Acld (10%)
+75.7 +1.8 +31.9 +22.5 +21.9
40.9 106.6 53.5 81.9 77.7
33.3 109.5 57.1 76.2 76.2
-16 -2 -12 -8 -8
Ethyl Ketone
Sodun Sodium
Chloride Hydroxide
(25%)
+0.5 +1.2 +1.3
103.7 106.9 93.0
100.0 109.5 95.2
-2 -2 0
L10%)
Tide (1%)
ihrea Volume Change X AS 1 M No 1011 3 011 +23.4 +98.2 + 108.7 +2.6 +3.1
Month
Immersion Elongation Retained X 71.4 47.6 33.3 95.2 100.0
at 75 : SF Hardness Change Pts. -11 -16 -18 0 -3 Surface Condition Unchanged Unchanged Yellow Res. Unchanged Unchanged
Tensile Strength Retained K 77.7 54.9 36.8 100.1 94.5
A S 1 M No
A.S 1 M Fuel 8 Dlstllled Water
Ethyl Alcohol
Herane Hydrochloric Methyl Acld (10%)
+82.9 ~2.8 +32.7 i24.3 + 19.9
42.8 102.4 61.4 74.5 76.8
38.1 95.2 61.9 76.2 71.4
-16 +l -13 -13 -10
Ethyl Ketone
Olbve 011 Skydrol 500
Sodbum Chlonde Sodwm Hydroxtde
(25%) (10%)
+0.6 +2.0 +2.5
99.1 98.7 99.6
76.2 95.2 104.8
0 0 0
Tide (1%)
Six Months Volume Change X A S T M No A S 1 M AS No 1 011 3 011 +31.0 +99.0 +126.1 +3.7 +1.3 Tensile Strength Retainrd X 82.8 64.4 39.1 102.8 90.7
fmmersion
at 75 + 5F Hardness ChanRr Pts. -13 -18 - 16 +l -1 Surface Condition Unchanged Unchanged Yellow Res. Unchanged Restdue
Elongation Retained K 76.2 47.6 38.1 90.5 85.7
1 M Fuel B Water
Dlstllled
Ethyl Alcohol
(continued)
Rubbers
and Elastomers
345
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
Six Months Volume Change X Tensile Strength Retained X 44.7 85.6
CHEMICALS
Immersion at 75
(continued)
+ 5F
HIrdIleSS Sllr(NLe
Elongation Retained X 42.8 61.9 52.4 61.9 71.4
Change Pts. -16 +l -11 -12 - 10
Condition Yellow Res. Unchanged Yellow Res. Unchanged Unchanged
neaane
H,drochlor~c Methyl Ethyl Acid Ketone
+116.3 (lo,1 +3.7 +31.7 +39.3 + 19.6
57.7
72.1 79.1
Oilde 011 Skydrol 500
Sodium Chloride (250-i Sodium Hydroxide ;lO%) Tide (10.) CHEMICAL RESISTANCE
+0.5 +2.8 +3.3 OF 30 VISTALON
104.7 96.3 105.6 6505170 NITRILE
90.5 85.7 90.5
+l +l +l
RUBBER BLEND COMPOUND

at 212F Hardness Change Pts. -7 -22 -24 -1 -6 Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged
72 Hours Immersion Volume Change K A.S T M. No. 1011 A.S T.M No. 3 011 +19.4 +63.5 +84.4 +7.8 +9.3 Tensile Strength Retained X 77.5 62.0 37.1 106.6 83.6
A.S T.M. Fuel B Dlstllled Water Ethyl Alcohol
Hexane Hydrochloric Acid (10%) Methyl Ethyl Ketone Olwe Oil Skydrol 5OO
+27.8 + 10.7 +60.5 + 10.6 +73.5
53.5 98.6 31.9 80.3 23.9
50.0 65.6 37.5 65.6 34.4
-3 0 -29 -7 -37
Unchanged Unchanged Unchanged Sl. Tacky SI. Tacky
Sodium Chlonde (25%) Sodlum Hydroxtde (10%) Tide (1%)
+0.9 -0.5 +7.6
93.9 98.1 100.0
71.9 75.0 75.0
+l -1 -2
One Month Volume change x A S T M. No. 1 011 A S T.M. No. 3 011 A S.T.M. Fuel 8 Dlsttilled Water Ethyl Alcohol +6.0 +28.2 +79.9 +2.1 +6.9 Tonsila Strength Retainrd K 95.3 65.7 42.7 97.6 83.5
Immersion
at 75 d 5F Hardness Change Pts. -4 -17 -24 -4 -10 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
Hexane Hydrochlonc Acid (lo/,) Methyl Ethyl Ketone Olive 011 Skydrol 500
+45.4 +1.83 +99.9 +1.6 +96.9
49.3 98.6 40.9 103.3 46.9
46.9 87.5 37.5 93.8 43.8
-20 -2 -22 -1 -17
Sodium Chlonde (25O.I Sodium Hydrorlde Tide
+O.J
+0.8 +l.O
99.5
101.9 93.9
93.5
96.9 87.5
-3 -4 0
(lo.)
( 1%)
346
Corrosion Resistant Materials Handbook VARIOUS ELASTOMERS AND RUBBERS-EXXON CHEMICALS kontinued)
TABLE 2.12:
Three Months
Immersion Elongation Retained X 78.1 59.4 40.6 84.4 78.2
at 75 = 5F Hardness Change Pts. -4 - 18 -23 0 -8 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
volume
Channe A.S.T.M. A.S.T.M. A.S.T.M. DIstIlled No. 1011 No. 3 011 Fuel B Water +8.9 +50.2 +87.3 +3.2 i5.5 K
Tensile Strength
Retained 86.9 63.4 41.3 92.0 82.6 K
Ethyl Alcohol
Hexane Hydrochlonc Methyl Acid (10%)
+48.9 +2.3 + 110.8 +3.5 + 100.7
54.9 96.7 42.2 93.0 41.3
50.0 87.5 43.8 84.4 40.6
-18 +l -25 -2 -23
Ethyl Ketone
Ohve 011 Skydrol 500
Sodturn Chlonde Sodium Hydroxtde
(25%) (10%)
+0.5 +0.9 c2.2
95.8 94.4 98.6 Six Months
78.1 81.3 87.5 immersion
+l 0 0 at 75 + 5F Hardness. Change Fts. -5 - 19 -22 +2 -6
Tide (1%)
Volume Change % A S.T M. No. 1 011 + 16.6 +54.3 + 103.5 +4.2 +4.6
Tensile Strength Retained X 81.7 68.5 43.2 101.9 b9.7
Elongation Retained % 75.0 65.6 34 4 87.5 78.1
A S T M. No. 3 011 A.S.T M. Fuel B Distilled Water
Ethyl Alcohol
Hexane Hydrochlonc Acid (10%) Methyl Ethyl Ketone Olive Oil Skydrol 500
+90.4 c2.0 + 124.3 +5.1 + 103.5
53.1 99.1 35.2 100.0 36.6
46.9 84.4 34.4 84.4 37.5
- 18 +2 -23 -2 -24
Sodium
Chlonde
(25%) (10%)
+0.4 to.8 +3.1
96.2 91.6 96.2
84.4 75.0 81.3
73 +2 +l
Sodturn Hydroxide Ttde (1%)
CHEMICAL
RESISTANCE
OF
50 VISTALON
6505150
NITRILE
RUBBER
BLEND at 2 12F
COMPOUND
72 Hours Immersion Volume Change % A.S.T M. No. 1011 A.S.T.M. A.S.T.M. Dsttlled No. 3 011 Fuel El Water +43.9 + 100.3 +263.3 + 13.2 t5.0 Tensile Strength Retained K 64.0 45.7 34.9 100.5 96.8
Hardness Change Pts. -15 -29 -33 tl -4
Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged
Ethyl Alcohol
(continued)
Rubbers
and Elastomers
347
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued9
72 Hours lmmerston at 212F Volume Change % Hexane Hydrochlorrc Methyl Acrd (10%) +33.3 t11.1 +35.7 +18.7 +76.5 Tensile Strength Retained % 48.9 91.9 52.7 83.3 42.5 Elongation Retained % 42.9 60.7 50.0 64.3 50.0 Hardness Change Pts. -3 -3 -23 -12 -31 Surtace Condition Unchanged Unchanged Unchanged SI. Tacky SI. Tacky
Ethyl Ketone
Sodrum Chloride Sodrum Hydroxrde Tide (1%)
(25%) (1046)
+ 1.3 -0.3 +4.4
101.6 101.1 98.5
71.4 75.0 75.0
+2 -1 -3
One Month Immersion at 75 + 5F Volume Change % AS 1 M No 1011 +16.3 +69.8 +95.4 + 4.8 + 4.3 Tensile Strength Retained $6 87.6 58.1 42.5 103.2 96.2 Elongation Retained % 71.4 50.0 39.3 92.7 89.3 Hardness Change Pts. -10 -23 -26 -4 -10 Surface Condition Unchanged Unchanged, Unchanged Unchanged Unchanged
A 5 1 M No 3 011 A S 1 M Fuel B Drstrlled Water E!hyl Alcohol
Hexane Hydrochlonc Methyl Acrd (10,)
+64.9 +1.7 +61.7 +5.3 500 +37.9
47.9 104.8 53.7 98.4 65.6
46.4 100.0 50.0 89.3 60.7
-22 -2 -. 20 -5 -15
Ethyl Ketone
Olrve Oil Skydrol
Sodrum Chlonde
(25?0)
+0.2 +0.2 +1.2
104.8 106.5 101.1
92.6 92.6 89.3
-3 -4 -1 at 75 + 5F Hardness Change Pts. -15 -23 -27 -1 -8
Sodrum Hydroxrde(lO%) Trde
(loo)
Three Months Immersion Volume Change % ASTM AS TM ASTM No 1011 +29.0 +81.1 +99.7 +0.3 +3.3 Tensile Strength Retained % 79.0 61.3 42.5 104.8 82.3
No 3011 FuelB
Drstrlled Water E!hyl Alcohol
Hexane Hydrochlonc Methyl Acrd tlO.)
+74.5 +1.4 +62.9 +9.5 +54.6
48.4 101.1 61.8 94.6 61.8
42.9 82.1 53.6 78.6 53.6
-23 0 -21 -6 -20
Unchanged Unchanged Unchanged Unchanged rlnchanged
Ethyl Ketone
Sodrum Chlorrde Sodrum Hydroxrde Trde (lTO)
(25%) (lo.)
+0.3 +0.4 +4.3
96.8 99.5 102.2
75.0 89.3 89.3
-1 0 -1
(continued9
348
TABLE 2.12:
Six Months Immersion Volume Change ?4 A S T M No I 011 +41.2 +83.9 Tensile Strength Retained % 67.7 61.3
at 75 = 5F Hardness Change Pts. -15 -24 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
A S 1 M No 3 011 ASTM Dlstllled FuelB Water
+114.4
+O.9 +2.5
33.9
99.5 85.5
32.1
82.1 78.6
-24
+l -6
Ethyl Alcohol
Herane Hydrochlonc Methyl Aod (10%)
+ 104.6
50.0
42.9 85.7 46.4 71.4 53.6
-21 +2 -19 -6 -21
Unchanged Unchanged White Res. Unchanged Unchanged
+ 1.9
+63.0 +12.6 +56.6
98.4
53.8 89.8 56.5
Ethyl Ketone
Sodium Sodium Tide
Chlonde Hydroxide
(25%) (10%)
+0.4 0 +2.8
96.2 93.0 99.5
85.7 75.0 82.1
+2 +2 +l
(1%)
CHEMICAL RESISTANCE OF 70 VISTALON 6505130 NITRILE RUBBER BLEND COMPOUND

72 HoursImmersion at 212F
Volume Change K A.S.T.M. A.S.T.M. A.S.T.M. No. 1 011 No. 3 Oil Fuel 8 +70.0 + 130.9 +224.0 +2.2 - 12.7 Tensile Strength Retained K 53.9 43.9 33.9 100.6 97.8 Elongation Retained X 51.7 37.9 27.6 75.8 86.2 Hardness Change Pts. -25 -32 -34 +l -8 Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged
Distilled Water Ethyl Alcohol
Hexane Hydrochloric Methyl Acid (loo/.)
+27.4 + 12.6 +32.6 +26.3 500 +38.3
45.0 94.4 67.2 71.1 65.6
34.5 65.5 62.1 65.5 72.4
-2 -1 -1 -16 -25
Unchangqd Unchanged Unchanged SI. Tacky Sl. Tacky
Ethyl Ketone
Olive Oil Skydrol
Sodium Chlonde Sodwn Hydroxide
(25%) (10%)
+0.7 -0.3 +2.4
97.2 98.9 97.2
72.4 79.3 72.4
+2 -1 -1
Tide (1%)
One Month Immersion at 75 + 5F Volume Cheq. x A S 1 M No Tensile Strength Retained K 80.6 62.7 Elongation Retained K 68.9 44.8 Hardness Change Pb. -13 -23 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
011
+26.6 +98.1
A S T M No 3 011 AS TM Fuel 8
+114.9 +1.9
+3.1
42.8 98.9
95.0
34.5 93.1
93.1
-25
-3 -7
Destilled Water Ethyl Alcohol
(continued)
349
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
One Month Immersion Volume
at 75 r 5F Hardness Change Pts. -22 -2 -17 -7 -12 Surface Condition Unchanged Unchanged White Res. Unchanged V. Tacky
change
HeXan.? Hydtochlorlc
Methyl
Tensile Strength Retained c 45.0 104.4 73.3 93.3 71.1
+66.6 Acid
f IO,)
+1.2 +29.9 +7.6 +2l.l
Ethyl Ketone
Olive Ott Skydrol 500
Sodturn Chloride (2Ya) Sodium Hydroxide Ttde (IO.1
0 +0.3 +0.6
103.3 98.9 96.7
100.0 96.6 93.0
-3 -3 -1
(loo)
Three Months Immersion Voluma Tensile Strength
at 75 : 5F Hardness Change Pts.

18 -23 -26 -1 -6
Change K
AS 1 M No AS 1 M
No
Retained X
67.8 51.1 44.4 98.9 93.9
Elongation Uetained K
55.2 41.4 34.5 89.7 86.2
Surface Condition
1011 3011
+49.1 + 106.3 +115.6 +0.3 +1.8
AS 1 M Fuel B Dlstlllcd
Ethyl
Water
Alcohol
tiexatle Hydrochlorw Methyl Acid IlO.)
+98.6 io.73 +31.1 +16.1 +22.2
47.8 98.3 77.2 86.1 86.1
34.5 86.2 72.4 79.3 75.9
-23 +l -19 -10 -14
Unchanged Unchanged Gray Res. Unchanged Unchanged
Ethyl Ketone
Sodaurn
Chloride
(25O.1
+0.2 +0.3
105.0 94.4
86.2 82.8
+l 0
Sodium t-lydroxlde lldt
(lo,)
11-c)
+l.l
97.2
93.1
0
at 75 ? SF
Six Months Immersion
Volume Change K
A.S T.M. No A.S.T.M. 1011 + 61.8 + 109.8 +138.1 +0.8 + 1.6
Tensile Strength Retained X

65.6 51.7 35.4 98.9 93.3
Elongation Retained X
55.2 44.8 31.0 93.1 86.2
Hardness Channe Ptr.

-19 -25 -24 +1 -4
Surface Condition
No 3 Oil
A S T M. Fuel 8 Dlstdled Water Ethyl Alcohol
Hexane
Hydrochloric Methyl Acid (lo.)
+ 137.6 +l.l
+30.3 + 18.9 +23.2 (25J (1o0) Ethyl Ketone
52.2
44.8
-22
Unchanged Unchanged White Res. Unchanged Unchanged
100.0
71.7 88.9 77.2
86.2
69.0 79.3 75.9
+1
-16 -10 -14
Olwe 011 Skydrol SO0
Sodwm Chlonde Sodwm Hydroalde
+0.2 +0.2
100.0 96.1
93.1 82.8
+2 +1
Tide (1%)
+l.l
97.2
86.2
(continued)
350
Corrosion
Resistant
Materials
Handbook
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
CHEMICAL
RESISTANCE
OF
30 VISTALON
6505170
POLYCHLOROPRENE 72 Hours Immersion
BLEND at 212F
COMPOUND
Volume Change % A.S.T.M. A.S.T.M. A.S.T.M. Distilled No. 1 Oil No. 3 011 Fuel B Water +25.1 +99.8 +92.3 +10.9 -0.1
Tensile Strength Retained % 86.8 46.2 33.8 96.6 91.9
Hardness Change Pts. - 10 -27 -25 -1 +2
Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged
Etnyl Alcohol
Hexane Hydrochloric Methyl Acid (lD?/J
+27.9 +7.1 +28.5 +32.0 500 +73.3
53.8 88.4 50.9 71.4 40.6
60.9 75.0 65.2 73.9 65.2
+3 0 -18 -17 -33
Ethyl Ketone
Olive Oil Skydrol
Sodium Sodium
Chloride Hydroxide
(2596) (10%)
to.2 +2.0 -
100.4 89.3 96.6
73.9 78.3 82.6
+6 -3 -1
Tide (1%)
One Month Vdume Change % A S.T M No. 1011 AST.M AS TM Dlstllled No. 3011 Fuel 8 Water +7.6 ~55.8 +a4.4 +3.5 +8.1 Tensile Strength Retained % 95.7 59.0 38.9 103.0 88.5
Immersion
at 75 + 5F Hardness Change Pts. -4 -16 -19 -1 -6 Surtace Condition Unchanged Unchanged Unchanged Unchanged Unchanged
Ethyl Alcohol
Hexane Hydrochloric Methyl Actd (10%)
+51.9 72.3 t40.0 +9.4 +50.3
51.3 105.9 52.6 92.3 56.8
60.9 108.7 73.9 83.3 69.6
-15 -1 -16 -5 -14
Ethyl Ketone
Sodlum Chloride Sodium Tide Hydroxide
(25,)
+I.2 +3.1 +0.3
101.3 101.3 105.6
100.0 91.3 100.0
0 -2 0 at 75 z 5F Hardness Change fb. -6 -17 -22 -1 -6
I lo.1
1lo01
Three Months Immersion Volume Change % A S T M No. 1 011 + 13.8 +72.8 +89.4 +6.2 + 10.6 Tensile Stmngth Retained % 85.9 55.9 40.2 104.7 79.1 Elongation Retained % 78.3 56.5 43.5 95.7 82.6
A S.T M No. 3 011 A S.1.M Dlstllled Fuel 8 Water
Ethyl Alcohol
(continued)
351
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Three Months Immersion et 75 = 5OF Volume Change % Hexane Hydrochloric Acid (10%) Methyl Ethyl Ketone Olive Oil Skydrol 500 +54.8 +4.3 +41.0 +19.5 +53.9 Tensile Strength Retained % 49.6 100.4 57.7 84.6 49.2 Elongation Retained % 52.2 87.0 69.6 82.6 69.6 Hardness Chanp Pts. -15 +l -17 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
-11
-21
Sodturn Chloride (25%) Sodium Hydroxldc (lC?o) Tide
+1.5 +5.0 +5.8
100.0 95.7 97.9
75.9 87.0 87.0
+l 0 -1
1I,)
Six Months Immersion at 75 r 5F Volume Change % A S 1 M No 1 011 +20.7 +76.9 +87.4 +8.5 +11.2 Tensile Strength Retained % 80.3 57.7 39.3 99.6 79.9 Elongation Retained $6 78.3 56.5 47.8 87.0 87.0 Hardness Change Pts. -8 -21 -20 -1 -4 Surface Condition Unchanged Unchanged Unchanged Unchanged Residue
AS 1 M No 3011 A S 1 M Fuel B Dtstllled Water Ethyl Alcohol Heaane Hydrochloric Acid
+54.2
46.6 93.6 48.7 83.8 44.4
52.2 82.6 65.2 78.3 52.2
-15 +l -17 -12 -23
(lo.)
+5.7 +41.6 +23.3 +57.8
Methyl Ethyl Ketone Olive 011 Skydrol 500
Sodium Chlonde (25%) Sodwm Hydroxide (10%) Tide (l/.) CHEMICAL RESISTANCE
+1.9 +6.3 +8.4 OF 50 V&TALON 6505150
102.1 86.8 102.6
87.0 78.3 87.0
+2 +l +l BLEND at 2 12F Hardness Change Pts. -21 -30 -27 -1 +2 +2 -2 -16
Unchanged Unchanged Unchanged COMPOUND
POLYCHLOROPRENE 72 Hours Immersion
Volume Change % A.S.T.M. A.S.T.M. A.S.T.M. No. I Oil No. 3 011 Fuel B +46.4 +114.0 +118.4 +6.7 -2.3 +33.3 +15.0 +21.2
Tensile Strength Retained X 70.8 42.7 37.1 98.1 88.3 46.5 84.0 59.3
Elongation Retained % 68.0 48.0 48.0 80.0 80.0 48.0 64.0 72.0
Surface Condition SI. Tacky SI. Tacky Unchanged Unchanged Unchanged Unchanged Unchanged Unchanged SI. Tacky SI. Tacky Unchanged Unchanged Unchanged
Distilled Water Ethyl Alcohol Hexane Hydrochloric Acid (10%) Methyl Ethyl Ketone Olwe Oil Skydrol 500
+33.4
+43.4 +O.Ol + 14.6 +6.2
72.5
53.5 95.1 87.5 97.3
72.0
80.0 76.0 72.0 84.0
-22
-28 +3 0 -2
Sodturn Chloride (25%) Sodwm Hydroxide (10%) Tide (1%)
(continued)
352
TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON
CHEMICALS
(continued)
One Month Immersion at 75 + 5F Volume Change lb A.S 1 M. No. 1011 A.S.1 M. No. 3 011 A.S.T.M. Fuel I3 +17.5 +81.3 +99.0 +2.7 +5.2 Tensile Strength Retained X 82.3 47.4 39.7 104.5 88.7
Elongation
Retained X 76.0 48.0 44.0 96.0 84.0
Hardness
Change Pts. -9 -21 -23 -2 -7
Surfwe
Condition Unchanged Unchanged Unchanged Unchanged Unchanged
Dlstllled Water Ethyl Alcohol
Hexane Hydrochlonc Actd (10%) Methyl Ethyl Ketone Okve 011 Skydrol 500
+73.6 +2.5 +27.8 +ll.O +29.6
40.5 102.8 62.3 88.7 77.2
48.0 100.0 76.0 84.0 84.0
-18 -2 -16 -8 -13
Sodium Chloride (250,~) Sodium Hydrorlde (10%) lode
+2.0 +2.2 +2.1
98.1 101.1 98.1
96.0 96.0 .%.O
-3 -3 -1
(1%)
Three Months immersion at 75 : 5t Volume Change X A S T M No AS TM

1
Tensile Strength Retained X 72.5 50.3 38.4 101.5 86.2
Elongation Retained K 76.0 52.0 40.0 96.0 88.0
Hardness Change Fts. -14 -21 -25 -1 -6
Surfacr Condlion Unchanged Unchanged Unchanged Unchanged Unchanged
011
+32.1 93.3 +110.5 +4.0 +10.6
No 3011
A S 1 M Fuel 8 Dlstllled Water Etnyl Alcohol
Hexane Hydrochlonc Aild
+81.6
44.8 97.3 68.3 84.5 72.5
48.0 92.0 76.0 84.0 80.0
-21 0 -17 -14 -18
t 10-o)
+3.1 +28.8 +20.8 +30.2
Methyl Ethyl Ketone Olive 011 Shydrol 500
Sodwm Chloride (2fP01 Sod~urn Hydroxide

ltd.? II"ab
+0.6 +2.7 +3.8
97.7 97.7 98.1
72.0 92.0 92.0
0 -1 -1
(IO.)
Six Months Immersion at 75 = 5F VdlUllO Chrngo X A.S.T.M. A.S.T.M. A.S.T.M. No. 1011 No. 3 011 Fuel B +41.6 +95.8 + 130.3 ~6.3 +6.1 Tonsil0 Strength Retained X 67.8 46.9 36.7 101.5 85.8 Elongation Retainrd X 72.0 52.0 44.0 92.0 88.0
HlrdMSS Surface
Change Pts. -16 -25 -24 -1 -5
Condition Unchanged Unchanged Unchanged Unchanged Unchanged
Dtstllled Water Ethyl Alcohol
(continued)
353
TABLE 2.12:
VARIOUS
ELASTOMERS
AND RUBBERS-EXXON
CHEMICALS
(continued)
Six Months Immersion at 75 r 5F Volume Change K Hexane Hydrochlonc Acrd (10%) + 114.7 +4.6 +28.5 +23.6 +31.5 Tantile Strength Retainad K 42.7 90.0 60.6 80.2 68.3 Elongation Retained X 44.0 76.0 72.0 76.0 94.0 Hardnass Change Pts. -20 -1 -16 -14 -19 Surtrce Condition Residue Unchanged Unchanged Unchanged Unchanged
Methyl Ethyl Ketone Olbve 011 Skydrol 500
Sodrum Chlonde (25%) Sodium Hydroxrde (10%) Tide (1%) CHEMICAL RESISTANCE
+1.2 +4.3 +5.8 OF 70 VISTALON 6505130
99.8 93.0 99.8
88.0 84.0 88.0
+l 0 -1 BLEND
Unchanged Unchanged Unchanged COMPOUND
POLYCHLOROPRENE
72 Hours Immersion at 212F Volume Change X A.S.T.M. A.S.T.M A.S.T.M. No. 1 011 No. 3 Oil Fuel 8 +66.4 + 130.9 + 137.4 +4.0 -1.5 Tensile Strength Retained $6 61.0 39.5 29.5 101.5 91.5 Elongation Retained K 62.5 45.8 37.5 87.5 83.3 Hardness Change Pts. -24 -32 -27 0 +3 Surface Condition St. Tacky SI. Tacky Unchanged Unchanged Unchanged
Dlstrlled Water Ethyl Alcohol
Hexane Hydrochlonc Acrd (10%) Methyl Ethyl Ketone Olive 011 Skydrol 500
+47.4 + 12.3 + 15.5 + 37.0 +25.6
41.5 91.0 64.0 72.5 72.0
45.8 75.0 _ 79.2 75.0 87.5
-1 -1 -14 -21 -21
.
Sodium Chloride (25%) Sodium Hydroxide (10%) Tide (1%) +0.8 +0.6 +3.6 108.C 95.0 91.5 83.3 79.3 83.3 +2 -1 -1 Unchanged Unchanged Unchanged
One Month Immersion at 75 + 5F Volume Change K AS TM No 1011 + 27.0 + 102.2 +115.3 + 2.5 +*3.8 Tensile Strength Retained K 79.0 50.0 29.5 108.0 98.0 Elongation Retained % 75.0 45.8 33.3 100.0 95.8 Hardness Change Pts. -11 -21 -23 -2 5 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
A S 1 M No 3 011 A S T M Fuel B Drstrlled Water Ethyl Alcohol
Hexane
Hydrochlonc Actd (lo.1 Methyl Ethyl Ketone Olrve 011 Skydrol 500
+81.5 +2.3 +15.5 + 14.4 +15.3
35.5 109.5 61.5 90.5 89.5
37.5 108.3 75.0 91.7 91.8
-21 -2 -12 -9 -10
Sodrum Chlonde (.25.) Sodrum Hydroxide (lO.J Trde
+O.? + 1.2 +1.4
101.5 95.5 100.0
100.0 87.5 100.0
-2 -2 -1
(I,)
354
TABLE 2.12:
Three Months Immersion at 75 2 5F Volume Change X A.S 1 M No AS TM No 1011 3011 +47.6 +112.4 + 128.5 +3.1 +4.5 Tensile Strength Retained K 67.5 45.5 37.0 103.5 93.5 Elongation Retained % 70.8 45.8 37.5 100.0 91.7 Hardness Cnange pts. -15 -21 -23 0 -4 Surface Condition Unchanged Unchanged Unchanged Unchanged Unchanged
A S.1 M. Fuel 8 Dlstllled Water
Ethyl Alcohol
Hexane Hydrochlonc Methyl Acid (l(P,)
+ 105.4 +2.3 +17.1 +25.3 +14.3
43.0 100.0 79.0 80.5 83.5
41.7 91.7 87.5 79.2 95.8
-21 0 -13 -14 -12
Ethyl Ketone
Olwe 011 Skydrbl 500
Sodwm Sodium
Chlonde Hydroafde
(25.) (1P.l
+0.6 +1.8 ~2.4
104.0 100.0 107.5
83.3 95.8 95.8
-1 0 -2
Tide (1%)
Six Months Immersion at 75 2 5F Volume Channe K A.S.T.M. A.S.T.M. A.S.T.M. Dlsttlled No. 1011 No. 3 011 Fuel 8 Water +60.9 ~116.1 + 155.6 +4.5 +3.2 Tensile Strength Retained K 66.0 51.5 36.0 104.5 95.0 Elongation Retained K 70.8 50.0 37.5 95.8 87.5 Hardness Change Pts. -19 -23 -23 0 -2 Surface Condition Unchanged Unchanged Unchanged Unchanged Residue
Ethyl Alcohol
Hexane Hydrochlonc Methyl Acid (10%)
+ 147.3 c3.4 c17.7 ~28.0 + 14.9
39.5 102.0 67.5 86.0 85.0
41.7 95.8 75.0 83.3 95.8
-20 0 -12 -14 -13
Ethyl Ketone
Sodwm Sodturn
Chlonde Hydroxide
(25%) (lD%)
+0.7 +2.2 +4.0
104.0 99.0 102.5
95.8 87.5 91.7
+l cl 0
Tide (1%)
Rubbers
and Elastomers
355
TABLE 2.13:
VARIOUS
ELASTOMERS
AND RUBBERS-MINOR
RUBBER CO.
CHEMICAL
COMPATIBILITY
CHARTS
(continued)
356
TABLE 2.13:
VARIOUS
ELASTOMERS
AND RUBBERS-MINOR
RUBBER CO. kontinued)
glcium C.lClrn
Carbonat* ChlowJ.
AIAIAIAlAl
lAl*IClJI*I
~I~I~I~I~l~I~l~l~l~l~l
(continued)
357
TABLE 2.13:
VARIOUS
ELASTOMERS
AND RUBBERS-MINOR
RUBBER CO. (continued)
358
TABLE 2.13:
VARIOUS
LEGEND
ELASTOMERS
AND RUBBERS-MINOR
u
A A B B
a
A B B
u u
llllCl
u u
u u

u I u
u

c
u

u I
B B B B
B B B B
n u
lvlele
C
u
C B
u c
B it-. B A .
u u u u
c c
B
c
A B _
u n n
B A
AL c
B
c
R
u
B
B
B
n c
B A 4
u n
B B B
u
U U
IB
A B B B B
B B B
B C
u
u
u
B
u
B
B Ilclllsiclclcle
u
u
8 A
B B
U B B
u
A A A A
A
c
B B A
A A
B B U
u u
A B
u
_~
u
A 6 A
A A
u
8
u u
8 B A A A
u
B A A A
,
B ._A
!.-_ u
A A
u
A
8
A
C A
fi
u
_
u
B A A A
u
A A
c
c
A -.
A
d--4
(continued)
359
TABLE 2.13:
VARIOUS
ELASTOMERS
AND RUBBERS-MINOR
ICI
iI B
iI
6 I
6 I
a__
I-
ui~l~l~l
IAlA
IAl
Lg
g;
(continued)
360
Corrosion
Resistant
Materials
Handbook
TABLE 2.13:
VARIOUS
LEGEND
ELASTOMERS
/
AND RUBBERS-MINOR
/ / / / /

/ / / / / / / /
362
Corrosion
Resistant
Materials
Handbook
TABLE 2.13:
VARIOUS
ELASTOMERS
AND RUBBERS-MINOR
-+ -+
B --i-
-+
-5
A
A
-z--zA
c c
-+-
--&
+_
-&

_-!A
---Ti--E-
Rubbers
and Elastomers
363
TABLE 2.13:
VARIOUS
LEGEND
ELASTOMERS
AND RUBBERS-MINOR
(continued)
364
Corrosion
Resistant
Materials
Handbook
TABLE 2.13:
VARIOUS
LEGEND
ELASTOMERS
AND RUBBERS-MINOR
ikelly. solent ikdrol500
B. c. E
:Lydrol7000
km Vacuum AC781 AM ,Gmsw,

bconv Vacuum PD959B ia& Ash
hap Sofwm* $cow Mobtk
Type A
UI
U u A
ulul
u u A u u A _:
VI
u
Al
A A A A
181
B B A
U B A
UI
l
B A A U
u l
u U A _::
B B
A A A
tinued)
Rubbers
and Elastomers
365
TABLE 2.13:
VARIOUS
ELASTOMERS
AND RUBBERS-MINOR
_!I-_
I,
a
II
un
--tA
---_
-4
+ -+
-2
(continued)
366
Corrosion Resistant Materials Handbook VARIOUS ELASTOMERS AND RUBBERS-MINOR RUBBER CO. (continued)
TABLE 2.13:
Rubbers
and Elastomers
367
TABLE 2.14:
VARIOUS
RUBBER AND ELASTOMERIC
TANK
LININGS-ACME-FISHER
Linings Recommended to Resist Various Chemicals

LININGS. A - Abrasron Resistant B - Soft Natural C - Semi-Hard Natural Natural D - Hard Natural E - Neoprene F - Polyvinyl Chloride G - Chloro-Butyl H - Ethylene Propylene NR - Not Recommended
(Koroseal)
CHEMICALS INORGANIC ACIDS Arsenic Battery Acid (Sulphuric) Carbonic Chlorine Water Cupric Acid (Copper Sulrate) Fluoboric Fluosilicic Hydrobromic Hydrochloric Hydrofluoric Hydrofluoric Max. Cont. Hydrogen Sulfide Water Nitric Nitric Perchloric Phosphoric Sulfonic Acid Sulphuric Sulfurous
SALTS a ALKALIES Abrasive Solutions Aluminum Salts Alums Ammonium Hydroxide Ammonium Persulfate Other Ammonium Salts Barium Salts Barium Sulfide Calcium Bisulfite Bleach Lrquor Calcium Hydrochlorite Other Calcium Salts Copper Salts Iron Salts Lead Salts Mercuric Chloride Nickel Acetate Potassium Hydroxide Potassium Drchromate Other Potassium Salts Sodium Hydroxide Sodium Bisulfite Sodium Hydrochlorite Sodium Hypochlorite Other Sodium Salts Sulphur Chloride Silver Nitrate Tin Salts Zinc Salts
CONCENTRATION
TEMPERATURE
OF
LINING DB
DB D-H F DB DBE DB DB DB G DB DEF F DF EDB DB DB D
Any
To Saturation To Saturation Any Any Any Any To 50% To Saturation 10% 25% To Saturation To 85% To 50% To Saturation
175
High Bake Phenolic 175 125 140 175 175 175 186 175 225 160 90 70 120 180 180 160 160 OF 180 175 175 160 175 175 175 180 175 140 175 175 175 175 175 180 160 175 160 180 160 160 150 225 180 NR 175 175 175
To To To To To To To To To To To To To
Saturation Saturation Saturation Saturation Saturation Saturation Saturation Saturation Saturation Saturation Saturation Saturation Saturatron
A DB DB D DB DB DB DB DB D D DB DE DB DB D DE DB DF DBE DB DF D G-H DBE D-B DE DE
To Saturation To Saturation To Saturation To Saturation To Saturation To Saturation To Saturation 16% To Saturation To Saturation Any To Saturahon
(continued)
368
TABLE 2.14:
VARIOUS
RUBBER AND ELASTOMERIC CONCENTRATION
TANK
LININGS-ACME-FISHER TEMPERATURE OF 140
(continued) LINING F-B-D
CHEMICALS PLATING SOLUTIONS

Brass Cadmium Chromium Copper Gold Lead Nrckel Silver Tin Zinc ORGANIC MATERIALS Acetate Solvents Alrphatic Solvents Acetic Acid Acetic Anhydride Acetone Alcohols Castor Oil Citric Acrd Coconut Oil Cottonseed Oil Dye Stuffs Citric Acid Ethylene Glycol Formaldehyde Formic Acrd Fumaric Acid Furfural Gallic Acid Glucose Glue Glycerine Lactic Acid Malic Acid Minerals Oils Oxalic Acid Soaps Tannic Acid Triethanolmine Vinegar
Trace to Any Any To 25% Any Any
To Saturation Any 40% Any
To Saturation Any Any Any Any To Saturation
Any To Saturation Any
OF NR 160 160 150 150 175 150 160 150 150 150 160 160 100 100 180 100 160 175 175 175 160 150 160 160 175 175 175 150
E D D DB DB D DF D D D F DB D D BDF D DB DB DB DB D DB ED D DB DB DB DF
The temperatures given are somewhat conservative; however should be conducted to satisfy users particular problem.
If higher
operating
temperatures
are anticipated,
tests
Cements, Mortars, and Asphalt
TABLE 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD STONCLAD is a three-component, epoxy-base floor surfacing system. It was specifically designed for surfacing and patching industrial floors exposed t o corrosive spillages and abrasive, wheeled traffic. STONCLAD-HT i s a threecomponent, epoxy-base floor surfacing system. It was specifically designed for surfacing and Fatching industrial but floors exposed t o corrosive spillages and abrasives, wheeled traffic a t temperatures above 140 F (60C), less than 250F (122C). The test procedure used was to totally immerse cured samples of STONCLAD in the chemicals listed for a period o 90 days at normal room temperatures. (This is a n exceptionally severe test, since most f floors subject t o chemical spillages such as these are "flushed down" periodically with water as part of the normal floor maintenance operation.) The resultant resistance of STONCLAD t o the various chemicals is rated using the symbols listed below. (It is assumed that normal "good housekeeping procedures" are used, including a daily flushing down with clean water.) RATING CODE
E - Excellent G - Good F - Fair NR - Not Recommended
OS - Suitable for use

where "occasional spillages" occur, when followed by immediate water flushing.
Chemical Resistance Guide for STONCLAD ACIDS CHEMICAL Acetic - 5%. . . . . . . . Acetic - 10%. . . Acetic - 20%. . . Acetic - Glacial. . RATING CH EM1CAL RATING
. . . . . . . . os
Benzoic - Sat. 3%.. . . . . . . . . . . . . . E Boric - Sat. 30%. . . . . . . . . . . . . . . E Butyric - 10%. . . . . . . . . . . . . . . . . . F Chromic - 10%. . . . . . . . . . . . . . . . .G Chromic - 15%. .. Chromic - 20%. . . Citric - 50%. . . . . . . . . . . . . . . . . . .E Cresylic. . . . . . . . . . . . . . . . . . . . . . . OS
Heptanoic.. . . . . . . . . . . . . . . . . . . . . OS Hydrochloric 15%. . . . . . . . . . . . . E Hydrochloric - 37%. . . . . . . . . . . . . G Hydrofluoric - 5%. . . . . . . . . . . . . . G Hydrofluoric - 10%. . . . . . . . . . . . . F Hydrofluoric - 15%. . . . . . . . . . . . . OS Hypochlorous - 5%. . . . . . . . . . . . . E
Lactic Lactic
- up t o 20%. . . . - over 25%. . . .
. . . . . . . . . . . . . . . . . . .G
Fatty . . . . . . . . . . . . . . . . . . . . . . . . . . G Formic - up t o 10%. . . . . . . . . . . . .OS Formic - over 10%.. . . . . . . . . . . . . NR Fluoboric. ..................... G
Maleic - 30%. . . . . . . . . . . . . . . . . .G Maleic - 40%. . . . . . . . . . . . . . . . . .F Maleic - 60%. . . . . . . . . . . . . . . . . . OS Malic - 50%. . . . . . . . . . . . . . . . . . . E Monochloroacetic -5%. . . . . . . . . . . F Monochloroacetic 10%. . . . . . . . . OS
Nitric - 10%. . . . . . . . . . . . . . . . . . . E
................G . . . . . . . . . . . . . . . .F . . . . . . . . . . . .NR Nitric - over 40%

(continued)
369
370
Corrosion Resistant Materials Handbook (continued)
T A B L E 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD ACIDS (continued) CHEMICAL Oleic. . . . . . . . . . Oxalic - Sat.. . . RATING
CHEMICAL Phthalic..
RATING
.............E . . . . . . . . . . . . .E
......................
Pelargonic. . . . . . . . . . . . . . . . . . . . . OS Perchloric - 35%. . . . . . . . . . . . . . . F Phosphoric - u p t o 50%. . . . . . . . . i F Phosphoric - 70%. . . . . . . . . . . . . .os Phosphoric - Conc. 85%. . . . . . . . . NR Picric - Sat.. . . . . . . . . . . . . . . . . . . E ALKALIES AND SALTS CHEMICAL RATING
Succinic - Sat.. . . . . . . . . . . . . . . . .E Sulfuric - 20%. . . . . . . . . . . . . . . . . E Sulfuric - 50%. . . . . . . . . . . . . . . . . G Sulfuric - 70%. . . . . . . . . . . . . . . . . F Sulfuric - 98%. . . . . . . . . . . . . . . . . NR Tannic - Sat.. . . . . . . . . . . . . . . . . . . E Tartaric - Sat.. . . . . . . . . . ....E
CHEMICAL
RATING
Aluminum Chloride - 50%. . . . . . . . E Ammonium Chloride - 50%. . . . . . . E Ammonium Hydroxide - up t o 20%. E Ammonium Hydroxide - 409b.. . . . . G Ammonium Nitrate - Sat.. . . . . . . . . E Ammonium Persulfate . . . . . . . . . . . .E Ammonium Sulfate - Sat.. . . . . . . . . E Calcium Chloride - 50% Calcium Hydroxide - Sa Calcium Hypochlorite - up t o 15%. . G Copper Fluoroborate Ferric Chloride.. . . . . . . . . . . . . . . . . G Ferrous Sulfate.. . . . . . . . . . . . . . . . . G Potassium Hydroxide
Sodium Benzoate. . . . . . . . . . . . . . .. E Sodium Carbonate (Soda Ash)-Sat.. E Sodium Bicarbonate - Sat.. . . . . . . . E Sodium Bisulfate - Sat.. . . . . . . . . . E Sodium Bisulfite - Sat.. . . . . . . . . . . E Sodium Chloride (Salt) . . . . . . . . . . . .E Sodium Glutamate.. . . . . . . . . . . . . ..E Sodium Hydroxide - up t o 5 0 % . . . .E . Sodium Hypochlorite - up t o 10%. .G Sodium Propionate.. . . . . . . . . . . . . .E Sodium Sulfate - Sat.. . . . . . . . . . . . E Sodium Sulfide - Sat.. . . . . . . . . . . . E Trisodium Phosphate - Sat . . . . . . . E Zinc Nitrate..
- up to 40%. . E
. . . . . . . . . . . . . . . . . . .G
SOLVENTS AND OTHER CHEMICALS SU B STAN CE Acetone, . . . . . . . . . . . . . . . RATING SUBSTANCE RATING
Alcohol (Methyl). . . . . . . . . . . . . . . . . 0 s Alcohol (Ethyl, Propyl. Isopropyl, Butyl). . . . . . . . . . G Amyl Acetate.. . . . . . . . . . . . . . . . . . E Beer . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . os Aniline, . . . . . . . . . . . . . . . .
Diacetone Alcohol. . . . . . . . . . . . . . . E Diethyl Phthalate. . . . . . . . . Dimethyl Phthalate. . . . . . . . Ethyl Acetate. . . . . . . . . . . . . . . . . . . OS Ethylene Glycol. . . . . . . . . . . . . . . . . E Ether. . . . . . . . . . . . . . . . . . . . . . . . . OS Ethylene Dichloride. . . . . . . . . . . . . . .NR Formaldehyde.
. . . . . . . . . . . . . . . . . . . os Butyl Acetate. . . . . . . . ........G
. . . . . . . . . . . . . . . . .E
E E E
Butyl Lactate. . . . . . . . . . . . . . . . . . . G Bromine. . . . . . . . . . . . . . . . . . . . . . . NR Carbon Disulfide.. . . . . . . . . . . . . . . . Carbon Tetrachloride. . . . . . . . . . . . . Chlorobenzene. . . . . . . . Corn Oil. . . . . . . . . . . . . . . . . . . . . . . Cyclohexane. . . . . . . . . . . . . . . . . . . . Cyclohexanol. . . . . . . . . . . . . . . . . . . Cyclohexanone. . . . . . . . . . . . . . . . . . Chloroform. . . . . . . . . . . . . . . . . . . . .
NR E
Gasoline.. . . . . . . . . . . . . . . . . . . . . . Glycerine. . . . . . . . . . . . . . . . . . . . . . . Glyoxal ....................... Hydrogen Peroxide
- 10%.. . . . . . . E
E E E OS NR
JP5 Jet Fuel.. . . . . . . . . . . . . . . . . . . E Juices - Fruit. . . . . . . . . . . . . . . . . . E Juices - Vegetable. . . . . . . . . . . . . .E Kerosene
......................
OS (continued)
Cements, Mortars, and Asphalt TABLE 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD
(continued)
371
SOLVENTS AND OTHER CHEMICALS (Continued) SUBSTANCE Lanolin. . . . . . . . . . . Lard. . . . . . . . . . . . . . . . . . . . . Linseed Oil.. . . . . . . Mayonnaise. . . . . . . . . . . . . . . . . . . . G Methyl Ethyl Ke . . . . . . NR Methyl Isobutyl . . . . . . . . . . . . NR Methyl Salicylate - 50% in Toluene. . . . . . . . . . . . . . . Methylene Chloride. . . . . . . . . . . Muriatic Acid (See Hydrochloric Acid) Mustard. . . . . . . . . . . . . . . . . . . . . . . Naphtha. . . . . . . . . . . . . . . . . . . . . . . RATING SUB STANCE RATING
.............E . . . . . . . . . . . . .F Phenol - 5%. . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . NR
Skydrol ....................... Sucrose - Sat. (Sugar). . . . E
Trichloroethane. . . Trichloroethylene. . Triethanolamine. . . Triethylene Glyco I.
. . . . . . . . . . . . . . .E
E F Vinegar
. . . . . . . . . . . . . . . .E (Household). . . . . . . .
Water. . . . . . . . . . . . . . . . . . . Wine. . . . . . . . . . . . . . . . . . .E Oils - Mineral. . . . . Oils - Vegetable. . . Xylene. . . . . . . . . . . . . . . . . . . . . . . . Chemical Resistance Guide for STONCLAD HT ACIDS CHEMICAL Acetic - 5%. . . . . . Acetic - 10%.. . . . Acetic - 3 0 % . . , . , Acetic - Glacial.. . . . . Benzoic - Sat . . . . . . . . . Boric - Sat . . . . . . . . . . . . . . . Chromic - 10%.. . . Chromic - 150h.. . . . . . Chromic - 30%. . . . Citric - Sat . . . . . . . . . . . . . . . . . . .E Cresylic. . . . . . . . . . . . . . . . . . . . os Diglycolic. . . . . . . . . . . . . . . . . . . . . . G RATING CHEMICAL RATING
Lactic - u p to 20%. . . . . . . . . . . . . . F Lactic - over 25%. . . . . . . . . . . . . . OS Maleic Maleic Maleic Maleic - 10%.. . . . . . . . . . . . .E - 30%. . . . . . . . . . . . . . . . . .G - 40%.. . . . . . . . . . . . . . . . . F - Sat . . . . . . . .
Mr,nochloroacetic Mmochloroacetic
-1 - 20%. . . . . . . . . 0s
Nitric - 20%. . . . . . . . . . . . . . . . . . . E Nitric - 30% ......... G Nitric - over . . . . . . . . . . . . . . . NR
Fatty.. . . . . . . . . . . . . . . . . . . . . . . . . E .F Formic - u p to 10%.. . . . . . . . Formic - over 10% . . . . . . . . . . . NR Fluoboric. . . . . . . . . . . . . . . . . . . . . . G
Oleic.. . . . . . . . . . . . . . . . . . . . . . . E Oxalic - S a t . . . . . . . . . . ....E

Pelargonic. . . . . . . . . . Phosphoric - 70%. . . Picric - Sat.. . . Phthalic.. . . . . . . . . . . . . . . . . . . . . . . Succinic -Sat
. . . . . . . .os
Hydrofluoric - 5%. . . . . . . . . . Hydrofluoric - 10%.. . . . . . . . . . . . G Hydrofluoric - 15%. . . Hypochlorous - 5%. . . . . . . . . . . . . E
. . . . . . . . . . . . . os . . . . . . . . . . . . .E Hydrochloric - 37%. . . . . . . . . . . . . G
....
..E (continued)
372

(continued)
T A B L E 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD ACIDS (continued) CHEMICAL RATING
CHEMICAL
RATING
Sulfuric
. . . . . . . . . . . . . .E . . . . . . . . . . . . . .F - 98%. . . . . . . . . . . . . . . . .NR
..............
.E ALKALIES A N D SALTS
Tartaric - S a t . . . . . . . . . . . . . . . . . . E Trichloroacetic - 5?6 . . . . . . . . . . , G Trichloroacetic - 10% . . . . . . . . . . .F Trichloroacetic - 20% . . . . . . . . . .os
Tannic - Sat..
CHEMICAL
RATING
CHEMICAL Potassium Hydroxide
RATING
Aluminum Chloride - 50%. . . . . . . . E Ammonium Chloride - Sat . . . . . . . E Ammonium Hydroxide - u p t o 20%. E Ammonium Hydroxide - u p t o 40%.G Ammonium Nitrate . . . . . . . . . . . . . . . E Ammonium Sulfate - Sat.. . . . . . . . . E Calcium Chloride - Sat . . . . . . . . . . E Calcium Hypochlorite - up t o 15%. . G Copper Fluoroborate. . . . . . . . . . . . . E Ferric Chloride - Sat.. . . . . Ferrous Sulfate. . . . . . . . . . .
- up t o 40%. . E
Sodium Carbonate (Soda Ash)-Sat.. E Sodium Bicarbonate - Sat.. . . . . . . . E Sodium Bisulfate - Sat.. . . . . . . . . . E Sodium Bisulfite - Sat.. . . . . . . . . . . E Sodium Chloride (Salt). . . . . . . . . . . .E Sodium Hydroxide - u p t o 50%. . . . E Sodium Hypochlorite - u p t o 10%.. . G Sodium Sulfate - Sat. Sodium Sulfide - S a t . . . . . . . . . . . . E Trisodium Phosphate - Sat.. Zinc Nitrate..
......E
. . . . . . . . . . . . . . . . . . .G
SOLVENTS AND OTHER CHEMICALS SUBSTANCE RATING Acetone. . . . . . . . . . . . . . .OS Acrylonitrile. . . . . . . . . . . .OS Aniline. . . . . . . . Isopropyl. Butyl). . G Amyl Acetate. . . . . . . . . . . E Beer.. . . . . . . . . . . . . . . . . E Butyl Lactate. . . . . . . . . . . G Bromine. . . . . . . . . . . . . . . NR Carbon Disulfide. Carbon Tetrachlo Chlorobenzene. . . . . . . . . . E Corn Oil. . . . . . . . . . . . . . . E Cyclohexane. . . . . . . . . . . . E SUBSTANCE Formaldehyde.. RAT ING
. . . . . . . . . . . . . .E
Gasoline.. . . . . . . . . . . . . . . . . . . . E Glycerine. . . . . . . . . . . . . . . . . . . . E Glyoxal. . . . . . . . . . . . . . . . . . . . . .E Hydrogen Peroxide - 10%.. . . . . E
S U B STANC E RATING Naphtha.. . . . . . . . . . . . . . E Naphthalene . . . . . . . . . . . . G

oils - Cutting.. . . . . . . . . E Oils - Mineral. . . . . . . . . . E Oils - Vegetable. . . . . . . . G Peanut Butter.. . . . . . . . . . E Perchloroethylene. . . . . . . E Phenol - 5%. . . . . . . . . . . NR Pyridine.. . . . . . . . . . . . . . NR Sucrose
JP5 Jet Fuel.. . . . . . . . . . . . . . . . . E E Juices - Fruit. . . . . . Juices - Vegetable.. ...... E

Kerosene . . . . . . . . . . . . . . .G
- Sat. (Sugar). .. E
Lard.
. . . . . . . . . . . . . . . . .E .......... .........F ................ E
Chloroform.
. . . . . . . . . . . . NR
Diacetone Alcohol. . . . . . . E Diethyl Phthalate., . . . . . . E Dimethyl Phthalate. . . . . . . E Ethyl Acetate. . . . . . . . . . . 0 s Ethylene Glycol. . . . . . . . . E Ether. . . . . . . . . . . . . . . . . 0s Ethylene Dichloride. . . . . . . NR
Methanol . . . . . . . . . . . . . . . . . . .NR Mayonnaise. . . . . . . . . . . . . . . . . . G Methyl Ethyl Ketone.. . . . . . . . . . .OS Methyl Isobutyl Ketone.. . . . . . . . . OS Methyl Salicylate - 50% in Toluene. . . . . . . . . . . . . . . . NR Methylene Chloride. . . . . . . . . . . . NR Milk.. . . . . . . . . . . . . . . . . . . . . . .E Mineral Spirits. . . . . . . . . . . . . . . .E Muriatic Acid (See Hydrochloric Acid) . . . .E Mustard. . . . . . . . .
Toluene . . . . . . . . . . . . . . . . G Triacetin.. . . . . . . ....E Trichloroethane. . . . ..G Trichtoroethylene. . . . . . . . G Triethanolamine.. . . . . . E . Triethylene Glycol. . . . . . . E Urea
. . . . . . . . . . . . .E
Vinegar (Household). ... E
Cements, Mortars, and Asphalt TABLE 3.2: EPOXY FLOORING COMPOUNDS-ATLAS
373
REZKLAD C IS a monolithic overlay designed specifically for use in applications where hydrofluoric acid and high concentrations of sodium hydroxide are encountered. REZKLAD C has been formulated to incorporate toughness, ability t o tolerate temperature cycling and good physical strength.Thls material IS installed dlrectly on the concrete slab t o give a durable, corrosion-resistant topping.
CHEMICAL RESISTANCE OF REZKLAD C FLOORING COMPOUND
_____
Acetic A c i d b e l o w 5 %
-~
-~
RT
140'F ___
-_
_ _ _
~-_
-~1400F I? __ T - -.
R - Recommended
N - Not Recommended
Acetic Actd 5% to 10% - _______ Acetic A c~- 10% t o 50% id Acetone ~- _ ~ _
C
N
-__
N N _
Lactic A c i d above 10% Lard Lux L i q u i d
N N R _
N N C
.
R A l u m or A l u m i n_ _ _ Sulfate um _ A m r r ~- i u- i- C h l o r i d e Nitrate Sulfate_ R i n - . __._ _ 50%

~
R R
Magnesium C h l o r i d e Nitrate Sulfate Maleic A _ _ _ _c i d 25% Methyl A l c o h o l ~ _ Methylene C h l o r i d e -
R -~
N C N N
~ ~ C - Conditional May
A m m o n i u m H y d r o x i d e 10% R R ---__ ___________ Amrnonium H _ d r o x i d e 30% R C _ _ y_ _ Aniline -~ Aqua Regia N N N

~
Methyl Ethyl Ketone Milk

----
N_ R N N R
_-_~
be s e r v i c e a b l e i f t h e c o n t a m i n a n t is i m m e d i a t e l y removed
__
__
__.
or washed off the surface
- - --- -
_ _ ~N f l d r i u m Chloride_ Sulfate R _~____ ___ Beer ~ _ _ _ ~ ~R Benzene __ - - -_ _ _ _ - _ _ _N_

~
Mineral _ _Oil_ _ _ _ _ _ R_ R ~ ~ N i c k e l C h l o r i d e Nitrate Sulfate
Benzene S u l f o n i c Acid 10%

-
Benzoic Acid
~
- ~ _ _
___
Black Liquor - - - - _ _ _ _ Bicachinq Liquor below 2%

-
R R
C ~N Nitric A c i d b e l o w 5% _____ t o _. C- N N Nitric A c i d -5% _10% _- -- . ~ _ - - ~ R Oils Vegeldble c c - __ _____ ----- ~~-__ Oleic _ _ _ ~ _ _ _ Acid N ___ N R _____
_
~~
R R
_ ~ - _ __
_R_ _
Oxalic_ _ _ - _ Acid Perchloroethylene - _ _ ___ Petroleum --__ _ ~ - _ Phenol below 5% ~ ~

~~
R N ____ N
N ___________ N Boric Acid R __ _ _ _ ______ R Butyl Acetate N N ___ - _ t3ulyl AILotloI R ___ C - _ _ _____ Uutyric Acid N _____ N n C d I L i u i C h I o ri d e _ iI-~Iat e_ - ____ R R _ N rat e Su I Cnlci u ni~- r o x i d e Hyd R _ _ _ _ - _ ~- R CdlClUm H y p o- h l_ r i t _ c o e N _ _ _ _ _ C -___ Ctilorine Dry C N ______ Chlorine Wet - ~ c ~c Ctiloririe Wdlcr ___ - __- C - N ___ ClllOlOdLellC _~ _ _ _ _ _ _ _ Acid 10% ~ N~ N _ Chloroform _ _ R _ _C_ ~ C N C h r o m-~c i d 5% ic A _-____ C h r o i n i c A c i d 5% to 10% N N - -__ _ _ _ _ _ ___ R Citric Acid 10% - ~ _ _ _______ N __
~ ~ ~~ ~
_ _--
c _ _c _ _
c _ - - _ _ _
-
_N _ _
N R
Phosphoric_Acid _ 25% _-_ _ to ___ __Phosphoric Acid 25% Io 50% _~ -~ Phosphoric A c i d above 50% __________
_ - ~C~
R-~ C N N __R-~ C R ____ R R R R
Pycric Acid to 5% Potassium__- r i d e Nitrate Sulfate Chlo - -- __ -___ Potassium H y d r -____-_o x i d e below 25%
-
__
R R ____
Potassium H y d r o x i d_ . _ 50% e 25% to _ - ~Sodium Bicarbonate Carbondre ___ ______ _ _ Sodium Chloride Nitrate Phosphate _ _ ~ - Sodium _ -__Sulfate Sulfide _ Sodium H y d r o x i d e t o 25% ________Sodium -
____C
R
R
R R
R R
H y d r o x i d e 25% t o 50%
S o d i u m Hypochlorite below 6 % Stannic C h l o r i d e Stearic Acid Sugar Salt Solution Sulfuric A_ _ _ 40% _ _ _ c i d below Sulfuric Acid _ _ _ 50% -
R C -____ C N
N - -~ N __ R C --_R N ____
S o d i u m Hypochlorite 16% -______
Copper_ _ _ _ Chloride Nitrate Sulfate - -
~-
Ether
E t h y l_ Acetate - - -__ E t h y l Alcohol _ _

~
- -_____
R N N R
R ____
N N R
R C _____
E t h_ k n-e Dichloride y_ _-Ethylene - l y c o l G _____ F i~-~.___t t i Acids Ferric C h l o r i d__ e Nitrate Sulfate - _ _ _ Fluosilicic A c i d
- -.-
c
R
R
c
R
C
i _l l u r i_ ALid ~ ~ ~i _ c _ _ above 50%
____-
_R _ _ _ _ C
C N - - - -C N
_ _ _ _R_ ~ C
S u l f u r o u s Acid below - 10% Toluene Toluene Sulfonic A c i d Tpmato Juic ____e

-~
______
R R _ _ _ _ -_ _ _ ~ _
__
-___
___
c
R
N
c
N
Formaldehyde below 37% _____ Formic A c i d 90% _ _ ~ _ _ _ _

~
c
R
c
C
~~
R ___ R
N C
-
Trichloroethylene Trisodium _Phosphate
Grape Juice_ ~ _
~
___.
R
C R
_____ t l y d r i x h l o r- c ALid 20% to .36% - i ---__ - ~ C _ N_ _ _

- - - _ _ - _
H y d r o f l u o r i c A c i d t o 2Ooh
H y d r o b r o m i c A c i d 20% -. Hydrochli;ic A c i d t o 20% _
- ___
R - -C R C
__
~ _ _ Turpentine
Urine ~Vegetable O i l Vinegar -~ Water Fresh ~-
_
~~
Urea, t o 20% -____
R _____ R_ _
___
R
C ~
c
R R
c
C R
Hy id ~ d r o f l u o r i c A c_ Hy _ _ pochlorous&id
20% t o 70%
H y d r o g e n Peroxide
R
C R R C C
t o 5% Jet Fuel Kerosene Lactic A c i d b e l o w 5%
__
_
N N N N
Water _ _ _ _ Distilled Water a n d Sewage _______

~
~
.
R R
R R
N
~
Xylene
C ______ ~
Z i n c C h l o r i d e Nitrate Sulfate
Lactic A c i d 5% to 10%
(cont Inued )
374

(continued)
TABLE 3.2: EPOXY FLOORING COMPOUNDS-ATLAS
REZKLAD 250 i s the trowelable counterpart to sprayable REZKLAD 125s. REZKLAD 250 utilizes a room temperature curing, aromatic amine hardening system, thus the reason for i t s outstanding chemical resistance. In addition, this material has been formulated t o incorporate outstanding physical properties. REZKLAD 250 upgrades t h e surface of existing concrete floors and provides positive protection a t a reasonable cost. Rezklad 250 complies with ASTM C722, Specification for Chemical-Resistant Monolithic Surfacings.
CHEMICAL RESISTANCE OF REZKLAD 250
H e i k i a d 250 R l 15O'F
Rezklaa 250
Lactic Acid. 5% t 10% R R Acelic A c i d . below _ ~ ~ _ ~ ~ - ~ _ _ _ R~ _ - _ _ . _ _ _ _ o_ ~ 5% R_ ~ ~~-~ _ _ AceGc Acid. 5% t o 10% R -._ R Lactic Acid, R C - .-. . ... -~ . _-_. _______ above 10% __.._ Acetic A c i d , 10% t o 50h R C Lard R R .-.. ..___ ~~-~ - ___________ ._____ Ace - n e . ~.. _ _ . . . .___._to ~ . C NR Lux L i q u i d R R - .... .__._ ..__________
~
- .___ __. .-
. -
~-_ ~ _ _ ..- _ . _ ~
--.
- T~ ~ R ._.__ 150F
~
R - Recommended
__
NR - Not Recommended
_______
-
C-
Conditional
Alurn n_ ~ . R R - ... or A l u m i. u m Sullate _ _ ~_______ .A m m o n i u m C h l o r i d e , nitrate sulfate. 50% R R - _ _ - . _._ _ . . . __._._ - . .R R~ A m m o n i u m H y d r o x i d e , 10% _ . . .~ _ . _ _ __ ~ _ _ _ _ _ _ ~- .. _ - ~ A mon R ~C _ m- _ i u m H y d r o x i d e . _ . _ _ ~ 30% ~ . _ _ _ Aniline C ..--. NR _ ~ _..___._.._ _-. ______~A q u a Regia NR ~~~_~ __...._-._ ~ ~ _ ______ _ NR _
~~ ~~~~ ~ ~ ~ ~ ~~ ~ ~ ~
Magnesium Chloride. Nitrate. Sullate R R - ~ ___._ _ ________.___ Maleic Acid-__._.__ _ ~ _ ~ _____
R~ R _
May be s e r v i c e a b l e i t t h e c o i l l a m i n a n t is im-
mediately
removed
Methyl~A l c o h o l _
_ . ._.__._ ~.
_______
_~_______
_~_._~ .
c
NR
--
or washed of1 the A
Methylene C h l o r i d e
~
Methyl .~
Ethyl Ketone
_
-
~ Milk
~~~
-'---:- ~ Silica _
~ .
--
R. R.R
,e ;
~
B a r l u m Chloride. Sullate
~
~ ~ _ ~ ~ ~ _ - _ _
~
R R _ _ _
_ _ ~- _ - _ -_ _ _ . _ - ~ ~
. ..__
~ ~
____-___
~
R_ R ~
__ N i c k e l ~ h l o r _ e , Nitrate Sulfate C id _~~ ~~__--______ . ~

~
Mineral C i I
R ~
- ~
Benzene NR N't.'L%A2d~be!5"" ~ ~ _ . - .___.__ .__.__ ~- R Benzene S u _f o ~ i c~ A c i d~ 10% _ .- -_._____~ ~ l n ~ , - R R Nitric Acid, 5% t o 10% Benzoic A c i d R R Oils. Vegetable
~
5"/.___
_.-~ . _ ~ _ _
.~ __.___...
~ ~
__._
__._
__..____ _ ~ _ _ _ _ _ ~ _ .._ ..- . -..

~
black Liquor ~ ~ . ____..__~.____ i l e a c h i n g Liquor. below 2% . . _-._ - .~_____ ___-Bleaching L i q u o r . ~ _ n c _ _ _ _ _ _ _ _ co __ .. ._._._-___ Boric Acid
.. _ _ . . _ . . _ ~~~
R R
~
R R
NR NR
Oleic A c i d ~~~~~ ~ ~ _ Oxalic A c i d _ _ _ _- -~- .- - ~ - . _Perchloroethylene .___._._

_._.____-
. _ _ _ -.---..~__._
B - May c o n t a i n t r a c e s c c of hydrofluoric acid c or acid fluorides. - .- - c -. - . c c_. Silica filler may be __.___ _ R R attacked. See "A".
R C_
R R~ ~ R R
surface filler will be a t t a c k e d . Sealing t h e surface may prolong t h e life. -
B u t y l Acetate - __. .._ .. . . . Butyl Alcohol __ - ~_ Butyric Acid

~ ~ ~ ~~ ~~
c
c
-
R R -~
Petroleum
R
~
---
___
. . - - ~~_ .. . . .
NR
CalL I u n i C h l o r i d e . Nit r dte, Sullat e Cdlcium Hydroxide

~ ~ ~ ~~
_ _ . . . _ _ __._..___
~_~
R
R
Phenol, _ ~ _ _ 5% c -~_~~ ~ below_.__._. _ .__-_ _ _ _ _ _.___ _ ~ Phosphoric _ Acid, to 25% . R B RB _~_____ ~ _ _ _ Phosphoric A c i d , 25% to 50% CB N R ~~. _ _ _ _ _ . __._ ~ . . _ ~ . _ ~ ___._. -~ . - _ _ Phosphoric Acid. above 50% NR -. __ - - ~ - - - ~
~
R R c Calci u m H y p _ c h l~ i_ _ _ _ _ _ _ _ _ _ _ _ _ ~. -. ~.. _ o r t e o Chlorine. D r y c -~. ~________

__..__. --~__
~~~ ~~
__.__
Picric Acid. t o 5% _._.__ _ _ _ _ _ _ _ _ _ _ _ ~ Potassium Chloride, Nitrate. Sulfate _Potassium H y-.__._ _25% o - _ _ ~ . d r. x i d e , below ~ _ _____ Potassium H_ r o x i_e_ 25% to ~ _ _ _ _ _ _ _ ~ yd _ d , ~ _ --. 50%
NR
R _
C h l o r i n e , Wet .. . . -C h l o r i n e Water
. . . ._--_
-_
~ _ ~ _.____ _ _~
~ . ._._.
~~
_ _ _ _ c_
R
--
c
R R R R R
C
cR R R R R
NR
--
C t i Ior oac et i c - -........._._w 1 0% Ac i d , be l o _~

. .
S o d i u.___d e , t o 25% m Hydroxi ----_-___ ~ _ _R _ c _ _ _ .~~ ___..~ -.--. ~ . . Cllrornic Acid. 5% Io 10% c_ _ _ ~ S o d i u m Hydroxide. 25% t o 50% NR . -.- _ _ ~ _ __ ~ - ~ _ _ _ _ ~ Citric Acid, to 40% R R S o d i u m Hypochlorite. below 6% __._ ______ ~.. . - - . ~ ~ - ~ ~ . _ _ _ _ __ ___ C h r o m i c Acid. below 5%
.
~ ~ ~
C t i Iu f olor ni ~
~~
_ _
_.....__
_ _ _ _ R ~ -_
_ _ _R _R _ . ~
S o d i u m Bicarbona;e, Carbonate -~ s d _ Chloride. _ o _ i u m _ _ ~ - Nitrate. Phosphate S o d i u m Sulfate. Sulfide --__
_ _ _ _ _
c c
Cuppal Chloride, Nitrate, Sullate

.-. - ~ .
--_ ~ - _ _ ~ -Ethyl l ~ ~A l c o h o_ _ _~~ _ __-N R -Ethylene D i c h l o r i d e . __ _ _ _ _ _ ______

Ether . . _________ .
~__~__~ ____
_ -._-._.__
~___
S o d i u m Hypochlorite. 16%
~~
E t h_ l Acetate y _ ~
c c
R
R
Stannic C h l o r i d e __ Stearic A c i d ___ Sugar, Salt Solution Sulfuric Acid. t o 80% - Sulfuric Acid. above 80% Sullurous ___ . Toluene
~
Ethylene G l y_ o l c ~ ~ Fatty . Acids~ ~ .~
_ _ __
~
~ ~~_ _ - ~ . ~
R NR ___ R R -~ R R R R C NR
. ~
__ c c ._..__ ~
R
A C
Acid. b e l o w 10% ~
Ferric Chloride. _ ~ Sullate Nitrate. ~ ~ ___.._..___ . _
R R
R R
R NR
C R
Fluosilicic Acid. _30% . ~. __.. ~ _ ____-_______ A Forrndldehyde. b e~ w_37% lo . ~ -. ~ _ ~ _ ~

.. .
Formic_Acid. . . ~ _ _ _ 90%
R R ___
R
Toluene Sulfonic A c_ _ _ _ ~ _ _ _ _ ~~ id Tomato Juice__.._________.__ __-.-_

~~ ~
__---
. ..____
. -
__~
~~~
Grdpe~. . _ _ . _ _ ~ Juice .~ . H y d r o b r o m i c A c i d . 20%

~ ~~
R _ _ R
.
Trichloroethylene _ _ _ _ _ _ C NR _____-__ __ Trisodium Phosphate _ _______.-R R ~__~~_ __~

~~
-____
__.___
- -._~__~~ ~~
t i y d r o c h i o r i c Acid. t o 20%
R R
Turpentine ~-~ .__-.

~
-~~ ~
~~~
Urea, t o 20%
_ _ ~ ~ _ _ _ ~ _ _R _ _ _ _ -__________________ R R
~
~
~ y d- o c h l o r i_ Acid. 20% t o 36% H r _ c

H y d r o l l u~.Acid. t o 20% oric _ ~ ...___. . __.._ ~-~~
-~
C
~
H y d r o l l u o r i c Acid. 20% to7OUh
~___
A _ _ _ _ _ _A -
Urine Vegetable O i l
R -
C -
__~___
~ _ ~R _ R_ _
~ __
___._._
H y d r o g e n Peroxide ~ _ ____-~ H y p o c h l o r o u s Acid. t o 5% .__..___._.

~ ~~
A _ _ _ _~ NR _ ~ ____ R -_ _ _ _ _
Vinegar _ _ _ _ ~~ Water, Fresh

~~~ ~ ~
R R --~~ .___.__..._
_ _ _ _ _ _ _ _ ~ . ._____
Jet Fuel -.~ Kerosene
R _-~_________C R --____ .~
Water. Distilled -.____ __

.. ..
_ _ _ - ~ R R R_ R _ _.__ ~~-~
R R
~
Water and Sewage xylene
_____~.___ ._.___..._
--
- ~ - _ _ _ _._._. - __.
NR -R ~ - - . ~ _
._______~
Lactic Acid, below 5% _______
R __ R
Zinc -. C h l o r i d e , Nitrate. Sulfate .. -. ~
KEY:
Resistant to 160'F (71'C)
The highest temperature tested, may and/or could be revised basis of further test.
Resistant to 90F (32OC)
Carbon filled
Not Resistant
* * Resistant to 70'F (21'C)

1
376

(contlnuedl
TABLE 3.3: EPOXY MORTAR AND FLOOR TOPPINGS-PENNWALT

Calcium hypochlorite. . . Calcium nitrate, saturated Calcium sulfate. Carbon dioxide.
............ ............. ..................
Ferric chloride, below 50% Ferric chloride, anhydrous Ferric nitrate or sulfate. . .
..............
.................. Carbon disulfide . . . . . . . . . . . . . . . Carbon monoxide . . . . . . . . . . . Carbon tetrachloride . . . . . . . . . . . . .

Caustic (see Sodium hydroxide) . . . . Chlorinated lime. . . . . . . . . . . . . Chlorine (dry). .
. . .
...
............... ............... Fluorine up t o approx. 50%. . . . . . . . . . . . . . . Fluosilicic acid 30%. . . . . . . . . . . . . . . . . . . Formaldehyde, below 37% . . . . . . . . . . . . . . . Formic acid 90%. . . . . . . . . . . . . . . . . . . . . . Fumaric acid . . . . . . . . . . . . . . . . . . . . . . . .
Furfural. Furfuryl alcohol Gallic acid Gasoline
. . . . . . . . . . . . . .. ........ Chlorine water . . . . . . . . . . . . . . . . . Chloroacetic acid 100% . . . . . . . . Chloracetic acid 10% . . . . . . . . . . Chloronaphthalene . . . . . . . . . . . . . . Chloronitrobenzene . . . . . . . . . Chromic acid 5 % . . . . . . . . . . . . . .
Chlorine (wet) 500 ppm Chromicacid 5-10o. . . . . . Citric acid 406 . . . . . . . . . . . Coolant brines . . . . . . Copper acetate, saturated
........................... ......................
.......................... ........................
Glycerine. . . . . . . . . . . . . . . . . . . . . . . . . . Glycol. . . . . . . . . . . . . . . . . . . . . . . . . Glycol acetate. . . . . . . . . . . . . . . . . . . . . . . .
. . .
..
...................... Heptanoic acid, any. . . . . . . . . . . . . . . . . . . Hexachlorocyclopentadiene. . . . . . . . . . . . . . .

Glycolic acid Household ammonia (see ammonium hydroxide). Hydrochloric acid, any. . . . . Hydrochloric acid, below 10% Hydrochloric acid Hydrofluoboric acid
............
...........
. . . . . . . . . . Copper chloride, nitrate, sulfate . . . . . . Cottage cheese . . . . . . . . . . . . . . . . . Cottonseed oil . . . . . . . . . . . . . . . . . . . Cresols . . . . . . . . . . . . . . . . . . . . . .

................. .................. Cyclohexanone . . . . . . . . . . . . . . . . . . Dichloroethylene. . . . . . . . . . . . . . . Diesel fuel . . . . . . . . . . .
Diethylene glycol DiethylenetrLamine Crude oil . . . . Cyclohexane. .
........... 10-32%. . . . . . . . . . . . . . . .
................. ............... Hydrofluoric acid 20.70%. . . . . . . . . . . . . . Hydrogen peroxide 50% . . . . . . . . . . . . . . Hydrogen sulfide. . . . . . . . . . . . . . . . . . . Hydroquinone . . . . . . . . . . . . . . . . . . . . . . Hydrosilicofluoric acid. . . . . . . . . . . . . . . . . Hypochlorous acid. . . . . . . . . . . . . . . . . . . . .
Hydrofluoric acid 10.20% Iron sulfate, saturated . . . . . . . . . . . . . . . . Jetfuel . . . . . . . . . . . . . . . . . . . . . . . . . . . . Kerosene . . . . . . . . . . . . . . . . . . . . . . . . . . Lactic acid 85%.
. . . .
..
. . . . .
..
Dimethyla(1inoethanoI . Dimethyl formamide D in i tr o be n ze ne Diphenyl or diphenyl oxide Ether Ethyl acetate Ethyl alcohol
..................... Lard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Magnesium bisulfite. . . . . . . . . . . . . . . . . . .

Magnesium chloride, saturated Magnesium sulfate, saturated Maleic acid, below 40%. Maleic acid 40% Maleic anhydride Mercury Methacrylic acid
.................. . . . . . . . . . . . . . . . . . .
........... . . . . . . . . . .
............
. . . . . . . .
Ethylamine, 40% aq sol.. Ethyl chloride. Ethylene dichloride
.............
. . . . . . . . . . . . . . . . . .
..................
................. Ethylene glycol. . . . . . . . . . . . . . . . . . . . Fatty acids . . . . . . . . . . . . . . . . . . . . . .
Mercuric chloride, saturated
. . . . . . . .. . . . . . . . . . . . . . .
...
....
377

Methyl a c e t a t e . . . . . . . . . . . . . . . . . . . .
(continued)
.................... Methyl amine 40%. . . . . . . . . . . . . . . . . . Methyl "Cellosolve". . . . . . . . . . . . . . . . . Methyl chloride. . . . . . . . . . . . . . . . . . . . Methy cyclohexanol. . . . . . . . . . . . . . . . .
Methyl alcohol
Po:assium chloride, nitrate or sulfate. . . . . . . . . Potassium cyanide, saturated . . . . . . . . . . . . . . Potassium ferricyanide, saturated . . . . . . . . . . . Potassium hydroxide 50%. . . . . . . . . . . . . . . . Potassium nitrate, saturated. . . . . . . . . . . . . . . Potassium permanganate, below 5% . . . . . . . . . Potassium peroxide 5%. . . . . . . . . . . . . . . . . . Potassium persulfate, saturated . . . . . . . . . . . . Po?assiurnsulfate saruratsd . . . . . . . . . . . . . . . Potassium sulfide. Prussic acid
................ ................ Methylene chloride . . . . . . . . . . . . . . . . . Milk . . . . . . . . . . . . . . . . . . . . . . . . . . . Mineral o i l . . . . . . . . . . . . . . . . . . . . . . . Miscible oil. . . . . . . . . . . . . . . . . . . . . . . Monochlorobenzene. . . . . . . . . . . . . . . . . Motor oil (see Crude o i l ) . . . . . . . . . . . . . .
Methyl ethyl ketone Methyl naphthalene. Muriatic acid (see Hydrochloric acid) Naphthalene.
..................... .........................
Pyridine. . . . . . . . . . . . . . . . . . . . . . . . . . . .
.....
.....................
Nickel chlorate, nitrate or sulfate . . . . . . . .
.................... Nitric acid 70%. . . . . . . . . . . . . . . . . . . . Nitric oxide gases . . . . . . . . . . . . . . . . . . N it r o be nze ne . . . . . . . . . . . . . . . . . . . . . Nitrosylsulfuric acid. . . . . . . . . . . . . . . . . Nitropropane . . . . . . . . . . . . . . . . . . . . . Oils (saponifiable) . . . . . . . . . . . . . . . . . . Oleic acid. . . . . . . . . . . . . . . . . . . . . . . . Oleum . . . . . . . . . . . . . . . . . . . . . . . . . .
Nitric acid 5%. Oxalic acid. Oxygen
..................... .................... Salicylic acid . . . . . . . . . . . . . . . . . . . . . . . . Salt, saturated. . . . . . . . . . . . . . . . . . . . . . . . Sodium acetate, saturated. . . . . . . . . . . . . . . . Sodium bichromate . . . . . . . . . . . . . . . . . . . .
Quinoline sulfate. Saccharin solutions Sodium c h lor ide, carbonate, bicarbonate, phosphate, nitrate, sulfate or chlorate Sodium hydroxide 50% Sodium hypochlorite, below 6% C12.
....
.................
...................... .........................
....... ........................ Perchloric acid . . . . . . . . . . . . . . . . . . . . Perchloroethylene . . . . . . . . . . . . . . . . . . Petargonic acid . . . . . . . . . . . . . . . . . . . . Petroleum . . . . . . . . . . . . . . . . . . . . . . . Phenol, below 5% . . . . . . . . . . . . . . . . . .
Paradimethylaminobenzophenone
Paraffin.
........ ............... Sodium peroxide 5% . . . . . . . . . . . . . . . . . . . Stannic chloride . . . . . . . . . . . . . . . . . . . . . . Steam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Stearic acid, any . . . . . . . . . . . . . . . . . . . . . . Sugar, saturated . . . . . . . . . . . . . . . . . . . . . . Sulfur chloride . . . . . . . . . . . . . . . . . . . . . . . Sulfur dioxide. . . . . . . . . . . . . . . . . . . . . . . .
Sodium hypochlorite 2 7%. Sulfuric acid 80% . . . . . . . . . . . . . . . . . . . . . Sulfuric acid 98% Sulfurous acid, below 10% Sulfur monochloride Sulfuryl chloride. Tannin
..................... ...............
Phosgene . . . . . . . . . . . . . . . . . . . . . . . . Phosphoric acid 85% Phthalic anhydride.
................
................... ..................... ............................
Phosphorous chlorides
...............
Tar, tar oils . . . . . . . . . . . . . . . . . . . . . . . . . Tartaric acid, cold saturated . . . . . . . . . . . . . .
................. Picric acid 5%. . . . . . . . . . . . . . . . . . . . . Picric acid 50%. . . . . . . . . . . . . . . . . . . . Potassium bromide, saturated . . . . . . . . . . Potassium carbonate, saturated . . . . . . . . . Potassium chlorate, 50%. . . . . . . . . . . . . .
..................... Tetrachloromethane. . . . . . . . . . . . . . . . . . . . Tetrahydrofuran . . . . . . . . . . . . . . . . . . . . . . Toluene. . . . . . . . . . . . . . . . . . . . . . . . . . . . To Iuenesu If on ic acid . . . . . . . . . . . . . . . . . . .

Tetrachloroethane
378

(continued)
........................ Trichloroacetic acid . . . . . . . . . . . . . . . . . Trichloroethylene . . . . . . . . . . . . . . . . . . Triethanolamine . . . . . . . . . . . . . . . . . . .

Towngas Trisodium phosphate Turpentine.
Urine . . . . . . . . . . . . . . . . . . . . . . . . . . . . Vegetable oil . . . . . . . . . . . . . . . . . . . . . . . Vinegar . . . . . . . . . . . . . . . . . . . . . . . . . . . Water, fresh . . . . . . . . . . . . . . . . . . . . . . . . Water, dis;illed . . . . . . . . . . . . . . . . . . . . . Xylene . . . . . . . . . . . . . . . . . . . . . . . . . Zinc chlo: de 5096 . . . . . . . . . . . . . . . . . .
................ ......................
Urea 20%. . . . . . . . . . . . . . . . . . . . . . . .
Solutions Common to the Plating Industry Floor and Wall Service (Not for Immersion; Acidcopper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
AcidZinc . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum bright dip +? 41 Phosphoric acid heat
Bath alumabrite Concentrate # 41 Aluminum Pickle - Northwest AI, Alume
......................................... D.S.. . . . . . . . . . . . . . . . . . . . . . . . .
Aluminum Pickling, Enthone Nitric acid with Enthone actane i 70 i
............................ Alkaline t i n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Anodizing Electrolyte - 15 - 1806 sulfuric acid . . . . . . . . . . . . . . . . . . . . . . . . . Brass bright dip - 50% nitric, 50% sulfuric . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cadmium bright d i p . with nitric acid with Kenvert conversion additive. Cadmium plating bath Calolume L. Cadmium cyanide bath
........
......................................... ................................ Chrome plating bath - approx. 4502 CR t o gallon 4502 sulfuric . . . . . . . . . . . . . . Chromium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Copper F luoroborate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Copper Lume, Copper cyanide. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Copper plating bath - cyanide with #625 Allied Research additive . . . . . . . . . . . . Copper plating bath -straight cyanide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Enthone stripper. SI8 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Iron Chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Rochelle salt, Copper cyanide Watt's nickel.
....................................
Udylite bright nickel # 425. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
............................................... ....................................... Delchem946 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Enthone Stripper. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Zincalume, Cyanide zinc. Nuvite Take-off Stripper.
A-29-S Stripper.
....................................... .............................................
Note: Top service temperature for continuous service is 14OoF (6OOC). Exposures to 16OoF (71OC) acceptable for not more than 20 minutes.
R
C
recommended t o 71OC. Contact Sternson Limited f o r h i g h e r t e m p e r a t u r e recommendations. u s e Talychem C highest temperature t e s t e d . further tests. s p e c i f i c chemical t e s t e d . may d i s c o l o u r s u r f a c e , w i l l n o t l o s e p r o p e r t i e s . c o n t a c t S t e r n s o n Limited f o r recommendation. n o t recommended. May be r e v i s e d w i t h
32 30%
50%
* NR D
380
TAB LE 3.4: EPOXY SUR FACl NG CEMENTS-STE R NSON Iconttnued)
Calcium s u l p h a t e Carbon Dioxide Carbon d i s u l p h i d e Carbon monoxjde Carbon T e t r a c h l o r i d e C a u s t i c ( S e e Sodiun, Hydroxide) C h 1 r i n a t e d 1i m e o Chlorine (Dry) C h l o r i n e (Wet) 5000 ppm C h l o r i n e Water C h l o r o a c e t i c a c i d , 100% ('hloroacetic. 10% Chloroform Chloronaphthalin C h l o r o n i t r o b e n z ene Chronic a c i d , below 5% Chrorric a c i d , 5% Chromic a c i d , 5 t o 10% C i t r i c Acid, below 5% C i t r i c Acid, 5-402 Coolant b r i n e s Copper a c e t a t e , s a t u r a t e d Copper c h l o r i d e , n i t r a t e o r sulphate C o t t a g e Cheese Cottonseed O i l Cresols Crude O i l Cyclohexane Cyclohexanone D i c h l o r o e t hylene Diegel Fuel D i e t h y l e n e Glycol Diethylenetriamine Dimet hylaminoethanol Dimethyl Formamide Dinitro-benzene Diphenyl o r d i p h e n y l o x i d e Ether Ethyl Acetate E t h y l Alcohol Ethylamine, 40% aqueous s o l . Ethyl chloride Ethylene d i c h l o r i d e Ethylene g l y c o l Fatty acids F e r r i c c h l o r i d e , below 50% F e r r i c c h l o r i d e , anhydrous Ferric n i t r a t e o r sulphate F l u o r i n e up t o approx. 50%
RD R 32 R 32
R R R
R NR
32 R 32 32 R
R
32
R
R 32 R R
R R
NR
R
*
R
R R
R
R 32 R R R
R 32 NR NR RD 32 R R R
NR
F l u o s i l i c i c Acid, 30% Formaldehyde, below 37% Formic a c i d , 90% Fumaric a c i d , any Furfural Furfuryl alcohol Gallic acid Gasoline Glycerine Glycol Glycol a c e t a t e G l y c o l i c Acid Heptanoic Acid, any Hex ac h 1o r oc yc 1 opent a d i ene Household ammonia ( S e e Ammonium hydroxide) Hydrobromic a c i d , any Hydrochloric a c i d , below 10% Hydrochloric a c i d , 1 0 t o 32% Hydrofluoboric a c i d H y d r o f l u o r i c a c i d , below 10% H y d r o f l u o r i c a c i d , 10 t o 20% H y d r o f l u o r i c a c i d , 20 t o 70% Hydrogen p e r o x i d e , 50% Hydrogen sulphid'e Hydroquinone H y d r o s i l i co f l u o r i c a c i d Hypochlorous a c i d Iron sulphate, saturated J e t Fuel Kerosene L a c t i c Acid, below 20% L a c t i c Acid, 20 t o 85% Lard Lead A c e t a t e , 25% Lead C h l o r i d e , s a t u r a t e d Magnesium b i s u l p h i t e Magnesium c h l o r i d e , s a t u r a t e d Magnesium s u l p h a t e , s a t u r a t e d Maleic a c i d , below 40% Maleic a c i d , 40% Maleic a n h y d r i d e Mercuric c h l o r i d e , s a t u r a t e d Mercury Methanol Methyl a c e t a t e Methyl a l c o h o l Methyl amine, 40% Methyl "Cellosolve" Methyl c h l o r i d e
RC R NF 32 R 32 R
R 32 32 NR
NR
RD R RD RC RC RC 32C RD R R 32C
R R R RD RD R RD RD R RD RD RD 32D R
NR
R
4
32 R R R
NR
(continued)
381
TABLE 3.4: EPOXY SURFACING CEMENTS-STERNSON
(continued)
Methylcyclohexanol Methyl e t h y l k e t o n e Methyl n a p h t h a l e n e Methylene c h l o r i d e Milk Milk o f l i m e Mineral O i l Miscible O i l Molybdic Acid, s a t u r a t e d Monochlorobenzene Motor O i l (see Crude O i l ) M u r i a t i c a c i d (see Hydrochloric Acid) Naphthalin Nickel C h l o r i d e , n i t r a t e o r sulphate N i t r i c a c i d , below 2 1/2% N i t r i c a c i d , 2 1/2 t o 5% N i t r i c a c i d , 70% ( c o n e . ) N i t r i c oxide gases Nitrobenzene Nitrosylsulphuric, acid N i t r opropzne O i l s ( saponifiable ) O l e i c a c i d , any Oleum Oxalic a c i d , any Oxygen Paradimethyl-amino-benzophenone Paraffin P e r c h l o r i c a c i d , any Perchloroethylene P e l a r g o n i c a c i d , any Petroleum Phenol, below 5% Phosgene Phosphoric a c i d , below 2% Phosphoric a c i d , 2 t o 5% Phosphoric a c i d , 5 t o 50% Phosphoric a c i d , 50 t o 85% Phosphorus c h l o r i d e s P h t h a l i c anhydride P i c r i c a c i d , 50% P i c r i c a c i d , 5% Potassium bromide, s a t u r a t e d Potassium c a r b o n a t e , s a t u r a t e d Potassium c h l o r a t e , 50% Potassium c h l o r i d e , n i t r a t e o r sulphate Potassium cyanide , s a t u r a t e d Potassium f e r r i c y a n i d e , s a t u r a t e d
*
R
NR R R R
R
RD
32
R RD R R NR
m *
NR 32 R R NR R
K 32
R
*
R
R R
21* 32 RD
RC
RC RC
R
32 R R 32
R R R
Potassium hydroxide, below 25% R Potassium hydroxide, 25 t o 50% R Potassium n i t r a t e , s a t u r a t e d R Potassium permanganate, below 5% RD Potassium p e r o x i d e , 5% R Potassium p e r s u l p h a t e , s a t u r a t e d R Potassium s u l p h a t e , s a t u r a t e d R Pot as s i um s u l p h i de R R Prussic acid Pyridine 32 Quinoline s u l p h a t e R Red O i l * Rochelle S a l t , 25% R Saccharin s o l u t i o n s R Salicylic acid 32 Salt, saturated solution R Sodium a c e t a t e , s a t u r a t e d R Sodium bichromate *D Sodium c h l o r i d e , c a r b o n a t e , b i c a r b o n a t e , phosphate, n i t r a t e , s u l p h a t e , sulphide o r chlorate R Sodium hydroxide, below 25% R Sodium hydroxide, 25 t o 50%. R Sodium H y p o c h l o r i t e , 50 ppm C12 R Sodium H y p o c h l o r i t e , 5000 ppm C12 R Sodium H y p o c h l o r i t e , below 6% C12 R Sodium H y p o c h l o r i t e , 27% 32D Sodium H y p o c h l o r i t e , 16% 32D Sodium p e r o x i d e , 5% 32 Stannic chloride 32 Steam R S t e a r i c a c i d , any R Sugar, s a t u r a t e d s o l u t i o n R Sulphur c h l o r i d e NR Sulphur d i o x i d e R S u l p h u r i c a c i d , below 10% R S u l p h u r i c a c i d , 10 t o 20% R S u l p h u r i c a c i d , 20 t o 40% RD S u l p h u r i c a c i d , 40 t o 50% RD S u l p h u r i c a c i d , 50 t o 60% RD S u l p h u r i c a c i d , 60 t o 70% RD Sulphurous a c i d , below 1 0 % RD Sulphur monochloride 32 Sulfuryl chloride 32 Tannin R Tar, tar o i l s 32 Tartaric acid, cold saturated R Tetrachloroethane NR Tetrachloromethane NR Tet rahy d r o f u r an 32
(continued)
C H
nuosllicic acid Acetic acid glacial Alum Alurmnum Sulfate Ammomum Hydroxide - Ammal_olls _ _ _ ~ _ _ Bakely Roducls .- _ ~ _ Beer Benzoic acid _ Bonc acid _ _ ~ _ _ Butter Butync acid _______ Calcium Chlonde
~ p _ _ ~
C H
Formaldehyde Formc acid
c n
s o l u m Hypochlonte up to 3%
c n
S o l u m Nitrate
Horse R a b h
_ _
~~~
~~
._______-
Jams % Jellies
-~
Calcium Hydronde
______
p _
Cheese all chloGGWatZp ~ ~ _ Chloroacetic acid 10% . -~ __.____Cider .~ _ _ _ ____ Cilnc acid Maleic acid _ _ _____ ___ . Citrus Fmts Coffee _______~ _ _ _ _ _ Corn Syrup Methyl Alcohol .~ _ _ _ _ ~ _ ~ ~ _ _ _ - Egg Yolk _ _ _ _ _ - __ Ethyl Alcohol . .__.__ __ Ethylene Glycol Mmeral 011
_ _ p _ _ ~ ~
____-
Mmeral Spints id - Munatic a c ~ _ _ Molasses Mustard _ ~ _ _ _ _ Nitnc acid Oleic acid 1 1 Olive 0 TxzCacid Pectin P _h e_ o l _ _ _ _ _ _ _n_ -_ Phosphoric Acid ~ _ _ _ Plckels -~~ PIcnc acid _ _ _ _ _ _ _ ~ _ _ Potassium Bicarbonate _ _ ~ _ _ _ _ _ ~ Potassium Carbonate _ _ ~ _ -_ Potassium Hydronde up lo 30% ~ _ ___ _ ______ Potavlum Hydronde 33% and over _ Salad Oils ~ Sahcylic acid Shortemng _______ Silver Nitrate ~ ~ _ _ _ Smokehouse Resicues.-- _~ _____ _ _ Sodium Bicarbonate S o l u m Carbonate %&um Chlonde _ __ -__ ___ S o l u m Hydroxide up to 2% 0 ~ _ Sodlum Hydronde 30%and over
p~
_ ~
_S o_u m Sulfate _ l ____

S o l u m Sulfite
._________
__ ~ _ _ _ ~
~S o l u m mosulfate
Soft Dnnks _ _ _ _ __ Soft Dnnk Concentrates soups ~_Soya 011 _____ ~~_ Steanc acid - _ ~ _ _ ~ _ _ _ Sugar ~ _ _ - - Sulfunc acid up lo 50% ~ - _ sulfunc acid 80% __-___ _ _ _ Sulfunc acid 93%
. _ _ _
___
~~
_______
~
S~P----T a M i C acid ___ Tartanc acid
-~
___
~
Tea __
~
________
_____ Tnchloroethylene _____ -~~

~
Tnsolum Phosphate -~~_~~

~~
~ Tung Oil_ _
urea
_ _ p
_
-
UMe _______-Vinegar ~ _ _ Yeast
___-_
Solution Concentrated Ammonium Hydroxide 10% Ammonium Hydroxide 10% Sulphuric Acid Concentrated Nitric Acid 10% Nitric Acid Concentrated Hydrochloric Acid 10% Hydrochloric Acid 2 5 % Aqueous Calcium Chloride Distilled Water Brake Fluid Gasoline Toluene Methyl Alcohol Motor Oil
14 Days
None None None None None None None None None 0.1% None <0.1% 0.5% 0.4%
90 Days
3% None
355 Days
1.1% 0.5% 0.2% 1.8% 0.6% 0.7% 1.1% 0.4% 0.5% 0.6% 0.4% 1.1% 0.5% 0.7%
Appearance Change Very Slightly Darker Very Slightly Darker Very Slightly Darker Slightly Yellow None Slightly Darker None Very Slightly Darker None None None Slightly Darker None Very Slightly Darker
0.2% <0.1?6
0.4% 0.5%
0.5% <0.1% 0.396 0.2% 0.7%
2
0
Y t ; c c a 'G 2
w
0 0
R
c
x
x
x
X
v-l z > 0 *
P
C .w
3
1 "
v 5 0 v e oU )
0
x
x x
gcnv
o
2
E?i
m 3
n
8 -
285
o yc z
c
' :.
":
C H
2 "
-2'"
c ; Q.c
L-
m'"Q
% m g
:: " v
2 :
0
;
x
x
x x x
U P
(A
5
5 2 a
m a n c m
k t;
' u N
z
Co
z k5 L%I 2ab
m
u .
0
4
r( 0
'0 0
U
l.4
y
" d
-Qgc 2.z.g
4 .m -B
4
04, m
D d l n
I
Y *
0 0
m u
A
z "
0
I
u
osp
E E w o E S ' " .
E-'" 5
u a c
c =
.
G20
N'
N
U
12:
0
-. D h D 0 m
d r ( C-I
c m - 0 a u u
U
0 P
u .
4
3u
h
0 0
*
e
0
0,
D . P O x
Co o
uc 4 c V) Pv
m *a!
U
4 V 0 0
$4
uX.-30P. g
v m r ( u ~ o +u ) 0 0 0 u u w m m * u t
o
0
V
, "
10
C d 4 E 4
6," 2 .c_
w,
M U
,"r
3 0
'=I
.
n m
m o
.Q
l.8
0 0 P V
5 . + a
L L m Z .szgg
L
3 u K . -
'"oup o p
w
- 4 n w l . 4
x:4x:<s;;;:"
OUO-m.,mmmNwNNNN
w o c
0 3
yo2 m o
ya , ~
0 0
4 0
xz
* Nr;sZ-N<
uq..::..
mcu-I2Ez
c * O M
.
0 M P
m ~ m m u e e * c c
U
toO m O O x:oox$ N
N m m - m 3 ; $ a v e ~ v
-03
z g x L
=-=
cI mU
v4i.4
GY :;0 0c, c
4 0
N - 4 -
s .= :
m m 'ma_=a . $E-2
L
r nw z v c
0 ,
0
;E;:
sz;
. P . .
u'uu;1
o "m 52 *
4 - 4
- 4 4 -
EL;-::
2,u3
* a
L.
5 a
2
"g"c
z g
*
g a m m
K
E,.-? m o ' " s ,IIo%F
m,:s
z
u
(0
:
3
=
,CEO0 3E E 0.- 3 - r Gm
2 a 0 .
~
LEG.!? FEE+
r( m
8 u m a 2
2
Z$=,.C
2
w
4 m
..
5
'D
geon s gYY
3v-g 2
m o m n
: : : 4 : 2 : : 7 .:U : . I :I 0 . I u v - 9 . . u a . a u a.2m:m.~mu-~ I ; ~ m . c V . W 0 m r ( w B X v d & v '=ugv24d ' mD r:~(=E ( wm Yi du C O a d u zz r m o 4 4s 1 J D"
..... ............ ............ . . . . . . . .. .o . .o. ... . . . . .4v . .... .* . , . .. . . . Y.(....

.4..
. V d
.'D -J:::::
. v . . . v . . . a . .
. U . . .4.
.4 . . U V . . r ( O . O .*4.4 . y * .u
. m u . v m - m
.4
- 9 ) .
44
. . L I . . Y - I . - I
v . . w y . y . d . . , + w . ' u
. C o d . +
. r ( .
oI * m 4 4 O V d U I v v d a m m v v
" U Y m C o -
. ..... .... . . a ... .. . .. .. . . . :. 2 : : : ;. .:. . .:. . m - r l . . . ... .... ... .... ... . . . ..* ... E i z z g . :. :. : ... c v v . . . . . . :: ..
. . I
P 0 . . O . O . . .
. . U
' u
o m K W v-u cU a h
0 -
m.5 u c
6.1
0 P . .
c".? -2 . 22 C ~ m 7o m v O
%--
m'"
W
v v v
..c
a . 4
r ( .
o v
. O
e
.r(
.a
--a
- 4 V V
: 5 ::: . 0 0 n e 0 . d . 2 -:: . :CUL
w . I .
S O U
V
.
. d m
4 4 0 * - C I U * r l O V ' D
u * C o v v P u r ( d ~ c ~ f J c v 8 m e ao)o)or( ~ ~ w 4 m O ' D I ( L . V ~ m ~ a c r ~ v n . ~ m e* am * w p ~ ( d t ~
~ ( P M P U C P V C ~ U C J O ~ X + ~ O . A ~ U
o u . c - 1 4 ~ v c c r(4v.cvc m m v o v a
O X I~ ( O C O O
'D 4-2 2 - o :;1 e 7:2

4 4 *'or(
-Dba
0 . v I . m .
v .m
0 .
L I . V
4 . U P
-0 . + g 2 0 * - L 5 x g 0 ' ;o .2mmgg, "1. . p $ + 2- . L a 2 >

r(N
.c a,-' o
a
0 4
a v
q==
A v
o x u x u o d u o
~ V Z I Z N U Z > ~ D . X
UT(V
m a v v
-boo ~ u a u
v 0 w
* s o
zrlr
m9v)
u<v)
l r m r
~ o l x
rlc
E!
x u
!S$; x .. :-;? 0 a ?
O h
E2
w u
v
m'GK
zs%
W U F d V I > w . C W
B 3
C .-
o E
u a W
U
I "
x
w F
v 0 E
x
x
X
x
x x
x
x
8
C
4-
Y z w o X
U C
-u
F Y
E
U
x
x x x x x x x x
a W
%..,;I
$E!
z g ;
x x x x x x x x
x x
@;
3 - z
W J g w
I C
;
0
3 U
8 q
n
d 0
W r(
z Q
x-x
c t-x
x
4
01
v . 4
v w c
I "
w V v c
X
u > w
X
o E w u
a :
z
Y
u o
w x
V W
w x
E
U
x
x x
a W
v)
5 ;; p
2 :
E
I-:
Q
c (
Ez
X
'?
2 "
3
u x
44
n z a
rn
Z X X
0
W
(L
I -
387
TABLE 3.9: URETHANE ASPHALT MEMBRANE-PENNWALT PENNGUARD Adhesive/Membrane is a twocomponent urethane asphalt composition used in the installation of the PENNGUARD Block Lining System. As an adhesive, it serves t o bond the PENNGUARD Block to a prepared substrate, and as a membrane, it serves as a moisture and chemical-resistant barrier. TUFCHEM I 1 Membrane i s an improved, two component, urethane asphalt based membrane system, that can be used, within i t s limitations, to protect concrete and steel surfaces from chemical attack and abrasion.
CHFlUlTCAL RESISTAWE OF URFTHANE ASPYALT MEXBFA!!S
PENNCSWIB Adhesivefidrane TUFCE3B I1 Membrane
Xey:
NR
C
- Resistant N o t Resistant - Conditional

-
A c e t i c Acid 25%
chromic Acid 35% Citric Acid 35% Hydrochloric Acid 35% N i t r i c Acid 35% O l e i c Acid Phosphoric Acid 35% S u l f u r i c Acid 35%
Acetone Benzene Carbon Tetrachloride Ethyl A c e t a t e Ethylene Glycol bkthyl Chloride Methanol Prapanol Toluene Xylene Water
NR
R
NR NR NR
R
NR NR NR NR
Aluminum Hydroxide Calcium Hydroxide, sat. sodium Hydroxide 35% Aluminum Chloride 35% Calcium Chloride 35% Calcium Sulfate, sat. Magnesium Chloride 35% Potassium Chr-te 35% s du CarbOMtE 35% oim Sodium Chloride, sat. Sodium Phosphate, sat. Sodium Sulfate, sat. B r ~ ~ ~ n i Nitrate urn
m
R
R
C R R R R
R
R R R R
m
m
R R R
NR NR
R
Chemical r e s i s t a n c e was determined by imnersion in a solution of the listed chemicals for one year at 132% (55.5oC).
388
TABLE 3.10: POLYESTER AND EPOXY FLOORING COMPOUNDS-ATLAS

The REZKLAD epoxy-based system consists of a Concrete Primer and Flooring Compound, plus an Expansion Joint Compound and Surface Sealer available for use where necessary. The CLADKOTE Flooring Compound i s a modified polyester, resin-based monolithic overlay for concrete. The composite of resins and siliceous reinforcing material cures t o a tough, chemical resistant topping. CLADKOTE C utilizes a 100% carbon filler specifically designed for service in hydrofluoric acid and fluoride salts.
CHEMICAL RESISTANCE OF
Rezklad*" FLOORING MATERIALS
.Clrdkob C Rcomnnnded
KHV
C 80F.
0 RECOMMENDED
Up to the temperature limilation of the material. In cafes where chemical boils below this limitation. resistance is intended to be shown up to the boiling point.
CONDITIONAL. may b suitable but con. Sult A t l a s b e f o r e using.
I !&MMENDED
389
TABLE 3.11: VARIOUS CEMENTS-ATLAS
Corrosion Resistance of Various Cements
390

(continued)
TABLE 3.11: VARIOUS CEMENTS-ATLAS
H = Recommended.
fl= Conditional, may be suitable.

0= Not recommended.
3 = Carbon-filled variation must be used. = Possible failure through crystalline growth
Sodium Hypochlorite, up to
3%
Sodium Hypochlorite, 15% and over
H = Up to the temperature limitation of the cement. In cases where chemical boils below this limitation, resistance is intended t o be shown up to the boiling point.
391
TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING
CORROSION-PROOF MORTARS
PERMANITE" Resin Mortar:

An all-purpose furan resin mortar. Satisfactory for non-oxidizing acids, alkalies, and organic solvents. Available in quick setting or slow setting type to suit the installation.
RESIBOND HF Mortar:
A selected polyester resin mortar with excellent adhesion to ceramics and metals. Satisfactory for dilute acids including those that contain fluorides, mild alkalies and many organic solvents.
AClDSlL Mortar:
An improved sodium silicate type mortar with greater water resistance and higher physical strength. Resistant to crystallization cracking, and vitrification to 1900F.
CORESITE Mortar:
An especially compounded hydraulic type mortar. Resistant to chemical attack by acids, alkalies, salt solutions, and organic solvents. Not recommended for handling strong acids or concentrated alkalies.
AClDSll K Mortar:
An improved potassium silicate type mortar with greater water resistance and higher physical strength. Resistant to crystallization cracking and vitrification to 1900F.
EPllOC Mortar:
A selected epoxy mortar with excellent adhesion to metal surfaces. Resistant to many nonoxidizing acids, alkalies, salts, and organic solvents.
AClDSll HK Mortar:
An alumina calcine mortar with great water resistance a n d bearing strength. Resistant to crystallization cracking, and vitrification to 2700F.
KNIGHTBOND C e m e n t :
A plasticized sulfur cement. Satisfactory for all acids and many solvents. Set immediately upon cooling. Available with either silica or carbon filler.
RESIBOND Mortar:
A selected polyester resin mortar with excellent adhesion to ceramics and metals. Satisfactory for dilute acids, alkalies, and oxidizing agents. Recommended for chlorine, chrome chlorine, dioxide and peroxide.
KABO:
An improved phenolic resin mortar. Resistant to non-oxidizing acids, weak alkalies, and most organic solvents. Supplied with either silica or carbon filler.
CH EMlCA L RESISTANCE
ACID
PH
NEUTRAL
ALKALI
8
11 (
11
12
13
14
CCRMANITE RESIN MORTAR
ACIDSIL MORTAR
~ ~
KABO RESIN MORTAR
(continued)
393
TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (contlnud) Chemical Resistance of AClDSlL and AClDSlL HK Mortars
(Meets ASTM specification 267 f o r chemical-resistant mortar) Acetaldehyde . . . . . . . . . . . . R R Acetic Acid . . . . . . . . . . . . . . . Acetic Anhydride . . . . . . . . . R .............. R Acetone R Alcohol, Amyl . . . . . . . . . . . . . . . . . R Alcohol, Butyl . . . . . . . . . . . . . . . . R . . . . . . . . Alcohol, Ethyl Alcohol. Iso-Propyl . . . . . R Alcohol. Methyl . . . . . . . . . . . . . . . R R Allyl Chloride . . . . . . . . . . . . . . . . . Aluminum Bromide .............. R R Aluminum Chloride ............... Aluminum Fluoride ............... NR R Alulnlnum Sulfate .................. Amnionla . . . . . . . . . . . . . . . . . . . . . . . NR Ammonium Bicarbonate ....... R R Ammonium Bromide ............. R Ammonium Carbonate ......... Ammonium Chloride ............. R Ammonium Fluoride .............. N R Ammonium N i t r a t e ................ R Ammonium Phosphate .......... R Ammonium Sulphate .............. R Amy1 Acetate ...................... R Amyl Chloride ........................ R Aniline ............................... ** Antimony Oxychloride . . . . . . . . R Antimony Trichloride ........... R Aqua Regia ............................ R Arsenic Acid ............................ R Barium Carbonate .................. R Barium Chloride ...................... R Barium Hydroxide .................. ** Benzaldehyde ............................ R Benzene ..................................... R ........................... Benzoic Acid R Bismuth Carbonate ................ R Boric Acid ................................ R Bromine .................................... R Butyl Acetate ........................ R Butyric Acid ............................ R Calcium Chlorate .................... R Calcium Chloride .................... R Calcium Hydroxide ................ N R Calcium H)-pochlorite ............ N R Calcium N i t r a t e ...................... R Calcium Sulfate ...._............ R Carbon Bisulphide ............. R Carbon Tetrachloride ............ R Carbonic Acid .......................... R Chloracetic Acid ........... R Chloral ............................. R Chlorine ........................... R ............. R Chlorine Dioxide ._.... Chlorobenzene .......................... R Chloroform ................................ R Chlorosulfonic Acid ................ R Chromic Acid .......................... R Chromic Chloride . .............. R Citric Acid ..._........._ ..__.............. R Copper Acetate ........................ R Copper Chloride ........... ........... R Copper Cyanide ...................... R Copper N i t r a t e _...___ ... .............. R Copper Sulfate ..............: ...... _._ R Creosote _.....__._ ....__._...... ..... ..... R R Cresylic Acid ............................ Dibutyl P h t h a l a t e .................. R E t h e r .......................................... R Ethyl Acetate ........................ R
~ ~
__
Ethyl Bromide R Ethyl Chloride R Ethylene Chlorhgdrin . . . R Ethylene Dichloride . . . . . R Ethylene Glycol . . . . . . . . . R Ethylene Oxide . . . . . . . . . . . . . . . R F a t t y Acids . . . . . . . . . . . R Ferric Chloride . . . . . . . . . R Ferric Nitrate . . . . . . . . . . . . . . . R ......... R Ferric Sulfate Ferrous Chloride . . . . . . . . . . . R Ferrous Sulfate . . . . . . . . . . R Fluorine . . . . . . . . . . . . NR .* Fluosilicic Acid . . . . . . . . . . . . . . Formaldehyde . . . . . . . . . . . . . . . R Formic Acid . . . . . . . . . . . . . . . . . R Furfural . . . . . . . . . . . . . . . . . . . . . R Gasoline . . . . . . . . . . . . . . . . . . R Glycerine . . . . . . . . . . . . . . . . R Hydriodic Acid . . . . . . . . . . . . . R Hydrobromic . . . . . . . . . . . . . . . . . R Hydrochloric Acid . . . . . . . . . . . R Hydrocyanic Acid . . . . . . . . . R Hydrofluoric Acld . . . . . . . . . N R Hydrogen Peroxide . . . . . . . . R Hvdrogen Sulphide R . . . . Hypochlorous Acid . . . . . R Iodine .............................. R Lactic Acid ...................... R Lead Acetate . . . . . . . . . . . . . . . . . . R Lead Chloride .......................... R Lead Nitrate .......................... R Linseed 011 .............................. R Magnesium Carbonate ........... R Magnesium Chloride ............. R ........ Magnesium Hydroxide ** Magnesium Nitrate ................ R Magnesium Sulfate ............... R Maleic Acid ........................... R Manganese Chloride .............. R Manganese Sulfate ................ R Mercuric Chloride .................... R Mercuric Cyanide .................... R Mercurous Nitrate .................. R Mercury ................................... R Methyl Acetate ........................ R Methyl Chloride ...................... R Methyl Ethyl Ketone ............ R Methylene Chloride ................ R Mineral Oil .............................. R Mixed Acids ............................ R Naphtha ...................................... R Naphthalene ............................ R Naphthenic Acid .................... R Nickel Chloride ........................ R Nickel N i t r a t e ........................ R Nickel Sulfate ........................ R Nitric Acid ................................ R Nitrobenzene ...................... R Nitroglycerine .......................... R Nitrophenol .............................. R Nitrous Acid ............................ R Nitrosyl Chloride .......__........._. R Oleic Acid .................................. R Oxalic Acid ..............._..... ......... R P a r a m n ...................................... R Perchloric Acid ........................ R Phenol ............................... ............ R Phosgene .................................. ** Phosphoric Acid ( t o 70% ) .... R
Phosphoric Acid (above TO',: ) Phosphorous Bromide Phosphorous Chloride . . Phosphol,ous Oxlchloride Phthalic Anhydride .. Picric Acid Potassium Bicarbonate Potassium Bromide Potassium Carbonate Potassium Chloi.ate Potassium Chloride . . . . . potassium Cyanide poiassiuni Fei rocyanide Potassium Dichromate Potassium Fluoride Potassium Hydroxide . . . Potassium Nitrate . . . . potassiuni Oxalate ... Potassium Permanganate . . . . . . . Potassium Peroxide Potassiuni Sulfate . . . . . . . . Potassium Sulphide .. Propylene Dichloride Pyridine . . . . . . . Salicylic Acid . . . . . . . . . . Silver Nitrate . . . . . . . . . . Sodium Acetate . . . . . . . . . . Sodium Bicarbonate . . . . . . . Sodium Bisulfate . . . . . . . . . . Sodium Bisulphite . . . . . . . . . . . Sodium Bromide . . . . . . . . . . . Sodium Carbonate ............... Sodium Chlorate . . . . . . . . . . . . . . Sodium Chloride . . . . . . . . . . . . Sodium Chromate . . . . . . . . . . . . . . Sodium Cyanide . . . . . . . . . . . . . . Sodium Dichromate .............. Sodium Ferricyanide .............. Sodiuni Fluoride .................... Sodium Hydroxide ............... Sodium Hypochlorite ............ Sodium Nitrate ........................ Sodium Nitrite ...................... Sodium Oxalate ................... Sodium Peroxide .................. Sodium Sulfate ....................... Sodium Sulphide ................ Sodium Sulphite ................... Sodium Thiosulfate . . . . . . . . . . . Steam ................................... Sulphur .................................. Sulphur Chloride ................... Sulphur Dioxide .................... Sulphur Trioxide .................... Sulphuric Acid ...................... Oleum ........................................ Sulphurous Acid .................... Tannic Acid ............................ Tartaric Acid .......................... Tin Chloride ............................ Tin Sulfate ................................ Toluene ...................................... Trichloracetic Acid ................ Trichloroethylene .................... Trisodium Phosphate ............ Vegetable Oils ........................ W a t e r ........................................ Xylene ........................................ Zinc Chloride ............................ Zinc Sulfate .............................
** R R R R R R R NR R R
NR
R R NR NR R R R NR R NR R
**
R R R R R R R NR R R R NR R R NR NR NR R R R NR R NR R * R R R R R R R R R R
**
R R R
NR R R R R R
R - Resistant.
NR - Not Resistant
"Consult M.A. Knight for specific recommendation.
(continued )
394
TAB LE 3.12: V A R IO US MOR T A RS-KOCH ENGINEER I N G (continuedJ Chemical Resistance of RESIBOND Mortar
(Meets ASTM specification 267 for chemical-resistant mortar)
E - Excellenr resisrance, all concentrations and temperarures to 250F G - Good resisrance. most concentrations and remperatures to 165F F - Fdir resistance. ddute concentrations and temperatures to 9 0 F NR - Not recommended for this s e n ice under most conditions Aceric Acid ( t o 5 0 5 ) E Hydrofluoric Acid G Hydrogen Peroxide ( 3 0 5 ) Aceric Acid (Glacial) NR Magnesium Chloride Ace r on e E Magnesium Hydroxide Aluminum Chloride E Methyl Alcohol A 1um in u r n Su 1fare E Methyl Ethyl Ketone Ammon i um Car bonare E Naphtha ( V M 8( P ) Ammonium Chloride G Nickel Chloride Ammonium Hydroxide ( t o 755 ) r \ ; ~ Nickel Sulfate Ammonium Hydroxide (conc ) E Nitric Acid ( t o 2 7 ) 0: Ammonium Nitrate E Nitric Acid ( t o 40% ) Ammonium Sulfate Aniline Barium Hydroxide Bcnzene Benzoic Acid Boric Acid Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Carbon Disulfide Carbon Tetrachloride Chloroform Chlorine Dioxlde Bleach Chlorine Gas Chlorine Water Chrome Plating Solution Citric Acid Copper Sulfate Ethyl Acetate Erhyl Alcohol Erhyl Ether Ethylene Dichloride Ethylene Glycol Ferric Chloride Ferric Nitrate Ferric Sulfare Formaldehyde ( 37% ) Furfural Glycerine Hydrochloric Acid
*Consult M.A. K n i g h t for specific recommendation.
L L E L NR G E
I : E
G
NR E E NR E p. E
+
F G F
E E
Nitric Acid (conc ) Oxalic Acid Perchloric Acid ( 20% ) Phenol Phosphoric Acid Potassium Chloride Potassium Cyanide Potassium Hydroxide (dilute) Potassium Hydroxide (conc ) Pyridine Sodium Bicarbonate Sodium Carbonate Sodium Chloride Sodium Hydroxide (dilute) Sodium Hydroxide (conc ) Sodium Hypochlorite (under 12 p H ) Sodium Hypochlorite (over 12 p H ) Sulfur Dioxide Sulfuric Acid ( t o 70% ) Sulfuric Acid (conc ) Sulfurous Acid Toluene Trichlorethylene Triethanolamine Trisodium Phosphate Water Xylene Zinc Chloride Zinc Sulfate
E E E F G G E
G E G
NR F E
E
E
#
NR
G NR
E E F E
E NR E
E E E E
E
E NR E F NR E G E
NR E E
F E E (continued)
Cements, Mortars, and Asphalt TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued) Chemical Resistance of RESIBOND HF Mortar
(Meets ASTM specification 267 for chemical-resistant mortar)
395
E - Excellenr resistance, all concentrations and temperatures to 250F. G - Good resistance, most concentrations and temperatures to 165F F - Fair resistance, dilute concentrations and temperatures to 9 0 F N R - Nor recommended for this Service under most conditions E Hydrofluoric Acid Acetic Acid ( to 50% ) G Hydrogen Peroxide ( 30% ) Acetic Acid (Glacial) NR Magnesium Chloride Acetone E Magnesium Hydroxide Alum in um Chloride E Methyl Alcohol Aluminum Sulfare Ammonium Carbonate E Methyl Ethyl Ketone E Naphtha ( V M & P ) Ammonium Chloride G Nickel Chloride Ammonium Hydroxide ( t o 7 % ) NR Nickel Sulfate Ammonium Hydroxide (conc ) ) E Nitric Acid (to 205% Ammonium Nitrate E Nitric Acid (to 40% ) Ammonium Sulfate Aniline F Nitric Acid (conc ) G Oxalic Acid Barium Hydroxide F Perchloric Acid ( 20% ) Benzene E Phenol Benzoic Acid E Phosphoric Acid Boric Acid E Potassium Chloride Calcium Chloride E Potassium Cyanide Calcium Hydroxide E Potassium Hydroxide (dilute) Calcium Hypochlorite F Potassium Hydroxide (conc.) Carbon Disulfide G Pyridine Carbon Tetrachloride G Sodium Bicarbonate Chloroform E Sodium Carbonate Chlorine Dioxide Bleach G Sodium Chloride Chlorine Gas E Sodium Hydroxide (dilute) Chlorine Water G Sodium Hydroxide (conc.) Chrome Plating Solution E Sodium Hypochlorite (under 12 pH) Citric Acid E Sodium Hypochlorite (over 12 pH) Copper Sulfate F Sulfur Dioxide Ethyl Acetate E Sulfuric Acid (to 70% ) Ethyl Alcohol Ethyl Ether E Sulfuric Acid (conc.) NR Sulfurous Acid Ethylene Dichloride E Toluene Ethylene Glycol E Trichlorethylene Ferric Chloride E Triethanolamine Ferric Nitrate E Trisodium Phosphate Ferric Sulfate E Water Formaldehyde ( 37% ) NR Xylene Furfural E Zinc Chloride Glycerine E Zinc Sulfate Hydrochloric Acid
'Consult M.A. Knight for specific recommendation.
E E
E E E NR G E E E G NR E E NR E E E + NR F E E E
#
NR G NR E E NR E F NR E G E F E E (continued1
396
TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued) Chemical Resistance of CORESITE Mortar
Acids:
Acetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .* Arsenic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R ............................... R Boric Carbonic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R Chloride Dioxide Water . . . . . . . . . . . . . . . . . R Chromic (Dilute) . . . . . . . . . . . . . . . . . . . . . . . . R R Citric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R Formic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NR Hydrochloric.. . . . . . . . . . . . . . . . . . . . . . . . . Hydrofluoric . . . . . . . . . . . . . . . . . . . . . . . . . . NR ........... R Hydrogen Peroxide . . . . . . Hydrogen Sulfide Water. . Hypochlorous (C12 water). . . . . . . . . . . . . . . R R Lactic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NR Nitric. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oxalic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . * Phosphoric . . . . . . . . . . . . . . . . . . . . . . . . . . . NR NR Sulfuric.. ............................. Sulfurous (SO2 water) . . . . . . . . . . . . . . . . . . . * R Tannic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Tartaric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R Borax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R Calcium Bisulfite . . .................. R Calcium Chloride . . . . . . . . . . Calcium Hypochlorite.. . . . .
Potassium Nitrate . . . . . . . . . . . Sodium Bicarbonate Sodium Carbonate . . . . . . . . . . . . . . . . . . . . . . Sodium Chloride . . . . . . . . . . . . . . Sodium Sulfate . . . . . . . . . . . . . . . Sodium Sulfide ...................... Sodium Sulfite . . . . . . . . . . . . . . . . . . . . . . . . . . Trisodium Phosphate . . . . . . . . . . . . . . . . . . . ............. Zinc Sulfate . . . . . . R R R R R
Organic Materials:
Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .......................... m ........................ Ethylene Glycol. . . . . . . . . . . . . . . . . . . . . . Formaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . Gasoline . . . . . . . . . . . . . . . . . Glucose . . . . . . . . . . . . . . . . . . ......................... ................. Milk . . . . . . . . . . . . . . . . . . . . . Mineral Oils . . . . . . . . . . . . . . . . . . . . . . . . . . . . Molasses . . . . . . . . . . . . . . . . . . . . Phenol. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soaps . . . . . . . . . . .................... Starch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sugar Syrup . . . . . . . . . . . . . . . . . . . . . . . . . . . . Triethanolamine . . . . . . . . . . . . . . . . . . . . . . . . . Vegetable Oils . . . . . . . . . . . . . . . . . . . . . . . . . . R R R R R R R R R R
Alkalies:
Ammonium Hydroxide . . . . . . . . . . . . . . . . . . .* Calcium Hydroxide ..................... R Calcium Hypochlorite . . . . . . . . . . . . . . . . . . . R Magnesium Hydroxide . . . . . . . . . . . . . . . . . . R Potassium Hydroxide (15%). . . . . . . . . . . . . R Potassium Hydroxide (Conc.) . . . . . . . . . . . *R Sodium Hydroxide (15%) . . . . . . . . . . . . . . . . R Sodium Hydroxide (Conc.) . . . . . . . . . . . . . *R Sodium Hypochlorite. . . . . . . . . . . . . . . . . . . . R Sodium Peroxide ........................ R
Salts:
Aluminum Sulfate . . . . . . . . . . . . . . . . . . . . . . R Ammonium Chloride. . . . . . . . . . . . . . . . . . . . R R Ammonium Nitrate ..................... Ammonium Sulfate ..................... R
'Consult M.A. Knight for specific recommendation.
R - Resistant NR - Not Resistant
(continued)
Cements, Mortars, and Asphalt TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued)
397
Chemical Resistance of KNIGHTBOND No. 6 Mortar (Meets ASTM specification 267 for chemical-resistant mortar) CHEMICAL MAX. CONC. MAX.TEMP. CHEMICAL MAX. CONC. MAX.TEMP. Yc by w t . o F. 7 a by wt. O F . 50 Acetaldehyde . . . . . 70 Hydrocyanic Acid ............... 10 70 Acetic Acid . . . . . . 100 70 **Hydrofluoric Acid ............. Any 200 Acetic Anhydride NR Any Hydrogen Peroxide ............ 30 70 Acetone . . . . . . . . . . . . . . . . . 50 70 Hypochlorous Acid . . . . . . . . . . . NR 70 NR Any Alcohol, Amyl . . . . . . Lactic Acid ........................ 25 200 50 70 Alcohol, Ethyl Lead Acetate .................. Any 200 50 70 Alcohol. Isopropyl . . . . . . Magnesium Chloride ......... Any 200 75 70 Magnesium N i t r a t e . . . . . . . Any Alcohol. Methyl . . . . . 200 Any 200 **Aluminuni Fluoride . . . Magnesium Sulphate . . . . . . . Any 200 Any 200 Mercurir Chloride . . . . . . . . . . . Any 200 Aluminum Sulphate . . . . . . NR 70 Mercuric Cyanide . . . . Any 200 Ammonia . . . . . . . . . . . Any 70 Mercurous Nitrate ... Any 200 Ammonium Cai.bonate . . . . 25 200 MEK . . . . . . . . . . . . . . . . . . . . . . . . . 15 160 Ammonium Chloride . . . . . . . 25 200 Mixed Acids . . . . . ..... 55 70 Ammonium Nitrate . . . 25 200 Naphtha . . . . . . . . . . . . NR 70 Ammonium Sulphate . . . . . Nickel Chloride .... Any 200 Aniline . . . . . . . . . . NR 70 200 Nickel Nitrate Any 200 Arsenic Acid . . . . . . . . . Any ............. 200 Nickel Sulphate Any 200 Barium Chloride Any Nitric Acid . . . . . . 50 70 Barium Hydroxide ............ NR 70 Barium Sulphide ............... NR 70 Nitric Acid .. 25 160 Benzene ............................. 7o Nitrous Acid NR 70 NR . . . . ................. NR 7o Oxalic Acid Any 200 Bi.omine 7o Perchloric Acid . . . . 25 70 Butyl Acetate ................... NR 2oo Phenol . . . . . . . . . . . . . . . . . . . . . . . . 50 70 Calcium Chlorate _ ............ Any 85 200 200 Phosphoric Acid Calcium Chloride .............. Any Calcium Hydroxide ............. NR 7o Phthalic Anhydride Any 200 7o Potassium Bicarbonate . . . 10 70 Calcium Hypochlorite ....... NR 2oo Potassium Bromide . . . . . . Any 200 Any Calcium Sulphate .............. Potassium Chlorate . . . . . . . ~ n y 200 Carbonic Acid ...................... 5 Potassium Dichromate . . . . Any 200 Carbon Bisulfide . . . . . . . . . . NR 7o Potassium Ferrocyanlde .... 25 70 Carbon Tetrachloride .......... NR Potassium Permanganate Any 200 Chloracetic Acid .................. Any 70 Potassium Sulphate .......... Any 200 Chlorine ............................. NR 70 Silver N i t r a t e ............ 15 200 Chloroform ...................... NR 70 Sodium Acetate . . . . . . . . . . . . Any 200 Chromic Acid . . . . . . . . . . . . . . . . . 35 70 Sodium Bisulphate . . . . Any 200 Chromic Acid . . . . . . . . . . . . . . . . 10 160 Sodium Bisulphite . . . . . . . . . Any 200 Copper Chloride ............... Any ......... 2oo Sodium Carbonate 25 70 Copper Cyanide . . . . . . . . Any Zoo Sodium Chloride . . . . . . . . . Any 200 Copper N i t r a t e . . . . . . . . . . . . Any 2oo Sodium Cyanide . . . . . . . . . . . 25 70
i:2
Sodium Ferricyanlde . . . . . 25 70 **Sodium Fluoride .................. Any 200 Sodium Hydroxide . . . . . . . . . . . NR 70 Sodium Hypochlorite ........ NR 70 Sodium N i t r a t e . . . . . . . . . . . . . . . . Any 200 Sodium Nitrite .................. 25 70 F a t t y Acids ....................... NR 70 Sodium Sulphite ............... 10 70 Ferric Chloride ................... Any 200 Sodium Sulphide .............. NR 70 Ferric N i t r a t e ..................... Any 200 Stannic Chloride ................. Any 130 Ferric Sulphate ................ Any 200 Stannous Chloride . . . . . . . . . . Any 200 Ferrous Chloride ............... Any 200 Sulphur Dioxide ................. Any 200 Ferrous Sulphate .............. Any 200 Sulphur Trioxide .................. NR 70 70 NR Fluorine ................................ Sulphuric Acid .................... 85 100 40 200 **Fluosilicic Acid ................... Sulphuric Acid .................. 60 200 35 150 Sulphurous Acid ................. Formaldehyde ..................... 10 70 Formic Acid .......................... 70 100 Trichloroethylene .............. NR 70 F u r f u r a l ......................... 50 70 Trisodium Phosphate . . . . . 10 70 40 200 Zinc Chloride ..................... Any 200 Hydrobromic Acid . . . . . . . . . . Zinc Sulphate ..... ......~ ....... Any 200 Hydrochloric Acid . . . . . . . . . . 30 200 **Use KNIGHTBOND # 7 Sulphur-Carbon Cement because hydrofluoric acid and fluorides a t t a c k fillers containing silica. Not Recommended for this service under most conditions. NR (continued) NR NR NR NR 50
70 70 70 70 140
Copper Sulphate . . . . . . . . . . . . Cresylic Acid . . . . . . . . . . . Ether . . . . . . . . . . . . . . . . . Ethyl Acetate . . . . . . . . . . . . . . . . Ethylene Dichloride .......... Ethylene Glycol . . . . . . . . . . . . . . .
NR
398
TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued) Chemical Resistance of KABO Resin Mortar with Carbon Filler
CHEMICAL RESISTANCE E Acetaldehyde . . . . . . . . E Acetic Acid . . . . Acetic Anhydride C E Acetone c Alcohol. Amyl E Alcohol. Ethyl . . Alcohol, Is0 PropyJ E E Alcohol. Methyl . . . . . E Aluminum Chloride' ... E Aluminum Hydroxide A I uni i num SUI t e pha E Ammonia _ _ . . NR Ammonium Bicarbonate F Ammonium Carbonate .. F Ammonium Chloride . . . E Ammonium Fluoride E E Ammonium N i t r a t e . . . Ammonium Sulphate . . . . E Amyl Acetate . . . . . . . . . . F Aniline . . . . F Antimony TrichloriPe E Arsenic Acid . . . . . . . . . . . . . E B a n u m Chrhonate . . . . . . E E Barium Chloride . . . . . . F Barium Hydroxide E Barium Sulphide . . . . . E Benzaldehyde . . . . . . . E Benzene . . . . . . . . . . Benzenesulfonic Acid E Benzoic Acid . . . . . . . . . . . . . E Bismuth Carbonate .... E Boric Acid ................ E Bromine ..................... NR Butyl Acetate . . . . . . . . . F Butyric Acid . . . . . . . . . . . . . G Calcium Chlorate . . . . . E Calcium Chloride _ _ . E Calcium Hydroxide ... NR Calcium Hypochlorite ...... F Calcium Sulphate . . . . . . . . . . . E .................... Camphor E E Carbonic Acid . . . . . . . . . . . . . . Carbon Bisulphide ........... E Carbon Tetrachloride ...... E G Chioracetic chi id .............. Chlorine ............................ G E Chlorobenzene ................... ..................... Chloroform E Chromic Acid . . . . . . . . . . . . . F E Citric Acid . . . . . . . . . . . . . . . . . Copper Chloride . . . . . . . . . . . . E Copper Cyanide .............. E CHEMICAL RESISTANCE Copper N i t r a t e . . . . . . . . . E Copper Sulphate ..... E E Creosote ......................... E t h e r .............................. E Ethyl Acetate . . . . . . . . . . . E Ethyl Chloride ........... E Ethylene Chlorhydrin G Ethylene Glycol ......... E F a t t y Acids ................. E Ferric Chloride .......... E E Ferric N i t r a t e ............... E F e m c Sulphate ........... Ferrous Chloride ......... E Ferrous Sulphate ........ E Fluorine ......................... NR Fluosilicic Acid ............ E Formaldehyde ............... E Formic Acid ................. E Furfural ........................ F Hydrochloric Acid ....... E Hydrofluoric Acid ......... E Hydrogen Peroxide .... F Wydrogen Strlphide E Hypochlorous Acid . . . . G Iodine ............................. NR Lactic Acid ................ E Lead Acetate . . . . . E Linseed Oil . . E Magnesium Carbonate E Magnesium Chloride ... E Magnesium Hydroxide F Ma@esium Nitrate . . E Magnesium Sulphate . . E Maleic Acid G Mercuric Chloride E Mercuric Cyanide . . E Mercurous N i t r a t e E Methyl Chloride E MEK . . . . . . . . . . . . . . . . . . . . . E Mixed Acids . . . . . . . . . . NR Naphtha . . . . . . . . . . . . . Naphthalene E Nickel Chloride E Nickel N i t r a t e . . Nicke] Sulohate . . . E F Nitric Acid ( D i l u t e ) Nitric Acid (Conc.) . NR . . E Nitrobenzene NR Nitrous Acid NR Nitrosyl Chloride Oleic Acid . . . . . . . . E Oxalic Acid .. E CHEMICAL RESISTANCE Perchloric Acid . . . . . . . . F Phenol . . . . . . . . . . . . . G Phosphoric Acid E . . . . . . . . . . Phthalic Anhydride . . . E Picric Acid - Alcoholic . . . . . E Potassium Bromide . . . . . . . . . . E Potassium Carbonate (Dilute) . C Potassium Carbonate tconc.) . F Potassium Chlorate . . . . . . . . . . E Potassium Dichromate . . . E Potassium Ferrocyanide E Potassium Hydroxide .............. NR Potassium Permanganate .... c Silver N i t r a t e ............. E Sodium Acetate . . . . . . . . . E Sodium Bicarbonate . . . . . . . . . E Sodium Bisulphate . . . . . . . . . . . E Sodium Bisulphite . . . . . . . . . . . . . . . E Sodium Carbonate (Dilute) ...... G Sodium Carbonate (Conc.) . . . . . F Sodium Chloride . . . . . . . . . . . . . . . . E Sodium Cyanide . . . . . . . . . . . . E Sodium Ferricyanide . . . . . . . . E Sodium Fluoride . . . . . . . . . . . . . . . E Sodium Hydroxide . . . . . . . . . NR Sodium Hypochlorite . . . . . . . . . NR S o d i u m N i t r a t e ......................... E S o d i u m N i t r i t e ....................... E Sodium Sulphate .................. E Sodium Sulphite . . . . . . . . . . . . . . . . . . E Sodium Sulphide ....................... NR Sulphur .............................. F . Sulphur Chloride ....................... NR Sulphur Dioxide ........................... E Sulphur Trioxide ......................... NR Sulphuric Acid ( t o 6 0 % ) ........... E Sulphuric Acid ( 6 0 - 8 5 g ) ........_ G Sulphuric Acid (Conc.) ............... F Oleum ............................................ NR Sulphurous Acid ........................... E Tannic Acid ................................... E T a r t a r i c Acid .............................. E Tin Chloride .............................. E Toluene .......................................... E Trichloroethylene ......................... C Trisodium Phosphate (Dilute) C Trisodium Phosphate tConc.) ... F Zinc Chloride ............................. E Zinc Sulphate ..............................
E - h t c e l l e n t resistance; ~ u i t a b l efor general serviceall concentrations and temperatures.
F - Fair resistance; suitable for some senrIces-dilute concentrations and temperatures t o 90" F .
G - Good resistance; suitable for most s e r v i c e k m o s t concentrations and temperatures to 212' F.
NR-Not recommended conditions.
for this service under most
KEY
a 0 a a
0
Resistant Not Recommended Limited Resistance Conairional Test Required Not Testeo
TYPE MORTAR
RESIN" SILICA & SILICATE

FURAN
MODIFIED PHENOLlC PHENOLIC

P
-g
SULFUR
x
PENNWALT NAME
-0
o
0
I
m
~
" p
rn
e z ~ p n> z
?a:=
D
v)
v,
ncnno
m= m e
-0
v )
ID
r
T)
r
--1
6
n
5
m
ZD
(? ? ?
? !
-06
r a'
u30T,ul=1,
o <
o z
c_@ e3
e=
2
Cl
F =. c
o 2
g
3
a i 5
p 5
KEY
0 Ressiant
TYPE MORTAR
SILICA 8 SILICATE
I
m
v)
RESIN
FURAN PHENOLIC
MoDFED PHENOLIC
SULFUR
0
0 Not Recommended
Llmltea Reststance Test Requlred
NOI Tesieo
5
PENNWALT NAME
fl Conamonal
r O
1
0 0
I
m
(n-nc7T-n
6 ?
4 m
- $5 n 6
? 52
2
g z .2 >z ng a
%
0
r !
D D W D O p g gEg; = c =w 3 6 2 5 : %0
<
a s
2 s
a
E ;
C
40 1
TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued)
a Conaitional. Test Required
L!miled Reslsiance
Not Tested
(continued )
402

(contrnued)
TABLE 3.13: VARIOUS MORTARS- PENNWALT
a Not Recommended
Llfnited Resisrance
Conditional Test Required
403
0 Not Recornmended
a Conditional. Test Required
Limited Resistance
(continued)
404

KEY
RES'N"
SILICA 8 SILICATE
TYPE
Llmited Resistance Conditional Test Required
Zmc Chloride Nllrale Sulfate
(continued)
Cements, Mortars, and Asphalt TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued)
405
Same cheqical resigtance with reduced physical strength above 750 F. (399 C) SeeTable 3.3 for epoxy mortars * * * Pennwalt K 1 4 8 Mortar has similar chemical resistances to CORLOK@ B Mortar and HB@ Mortar with some exceptions. Check with your Pennwalt representative for specific chemical resistances. t PENCHLOR@andCORLOK 6 Mortars should be tested for resistance in 1% range. All Mortars resistant in 10% and 25% range. @ Resistant up to 40% at 16OoF (71OC). Test higher concentrations and temperatures. S Up to 2% concentration. Q Limited resistance a t 48% concentration. Resistant t o 100F (38OC). Test for higher temperatures. A Strong oxidizers must not be added because elemental bromine would be freed that would make the rating of all resin mortars Not Resistant. Polyester Mortar probably resistant to boiling point in all three concentrations. Epoxy toppings may be considered up t o 10% but verify by test. H.E.S.@and HB@ Mortars will resist some concentrations. See Addenda. # Attack is slow a t 1% or less. Resistant to 20% at 100cF. (38OC)
c
+
+
+ +
& Resistant intermittent t o 1OO:F. (38zC) 0 Resistant ittermitt,nt t o 160 F. (71 C) ; = Up t o 302 F. ( 1 50-C)
ADDENDA H.E.S. and HB Mortars differ from other siliceous, silicate, or silica mortars in resisting exposures between pH 0.0 and pH 8.0 with the exception of acid fluorides and HF acid. In addition, they can be used in glycol acetate, potassium sulfate or persulfate, sodium sulfide and trisodium phosphate, all of which will damage other siliceous mortars. "Use this reference information as a guide only. The information given in the resistance chart is believed t o be reliable, but no guarantee i s made nor can we assume liability in connection with their use. Please contact the Corrosion Engineering Department for specific recommendations."
406
TABLE 3.14: VARIOUS MORTARS-STERNSON IN 0 BOND C is a high-purity quartz colloidal silicate mortar for use with all sizes of acid brick and i s especially suited for stack or chimney linings as in sewage treatment operations and other, and as a mortar for process linings. IN 0 BOND P is a potassium silicate based inorganic brick mortar formulated for use with all sizes of acid brick and i s especially suited for chimney, stack or vessel linings where an easy t o use mortar will facilitate quick installation. IN 0 BOND S is a sodium silicate based mortar designed for use with all sizes of acid brick.
FURABOND and FURASET are furan based cements that resist a wide range of strong corrosive solutions and severe mechanical abuse. They are formulated t o be used with all sizes of acid brick for protection of concrete and steel surfaces such as trenches, floors, piers, pump bases, supporting foundations, sumps, batching and pickling tanks, process vessels. They are especially suited for alternating alkali/acid conditions. STERNCHEM Polyester Mortar is formulated t o provide superior service for acid brick constructions in the chemical process, pulp and paper, plating, textile, fertilizer, and metal refining industries. They are especially suited for chlorine dioxide towers, bleaching vats, trenches, sumps, pits, bleaching solutions of sodium hypochlorite, oxidizing solutions of nitric and chromic acids t o 20% concentrations, hydrobromic acid, potassium and sodium dichromates, bromine water, s a l t solutions t o pH 11. STERNCHEM Phenolic Mortar is formulated t o provide superior service for acid brick constructions requiring the chemical resistance of carbon/resinous phenolic systems.
STERNCHEM CHEMICAL RESISTANCE GUIDE
R - Resistant NR - Not Resistant U - Untestcd 2'7OC - Maximum Temperature Tested 30% - Resistant To All Concentrations Up To 30% - In 0 Bond Series Not Recommended For Frequent Or Continual Concentrations Below 10% - Talychem Epoxy Mortar - Refer To Talychem Chemical Resistance Guide (Table 3.4)
EXPOSURE
c-
IN 0 BOND SERIES llO0OC P - goooc S - 4OO0C
FURABOND FURASET 175OC R R R NR 3OoC R NR R R R NR R
STERNCHEM SERIES POLYESTER PHENOLIC

120%
175OC NR R R R NR NR NR NR NR R NR R
(continued)
Acetaldehyde Acetic Acid, under 10% Acetic Acid, Glacial Acetic Anhydride Acetone Acetone Oil Acetyl-Bromide Acetyl-Chloride Acetylene-Dichloride Acetyl Salicylic Acid Aluminum Bromide Aluminum Chloride, Sulphate & Alums
R
R R
NR
3OoC NR
R
R NR R R R R
R
NR NR U NR NR U U
R
R
407
TABLE 3.14: VARIOUS MORTARS-STERNSON
(continued)
EXPOSURE
I N 0 BOND SERIES llO0OC P goooc
cS
4OO0C
FURABOND FURASET 175OC
STERNCHEM SERIES POLYESTER PHENOLIC 12oOc

U
175OC
NR R NR R R R NR
R R U R U
NR NR R R R NR
Bromide Carbonate Chloride , Sulphate Fluoride Hydroxide Nitrate (Neutral S o l u t i o n s ) Ammonium P e r s u l p h a t e Ammonium Phosphates Ammonium Sulphide Ammonium Tungstate Amyl Acetate , Alcohol Aniline Aniline Hydrochloride Antimony Chloride Ant imo ny Oxych l o r i de Antimony Potassium T a r t r a t e Aqua Regia Arsenic Compounds, Neutral o r Acid B a r i u m Chloride B a r i u m Hydroxi de Barium N i t r a t e Barium Sulphide Benzaldehyde - Neutral o r Acid Benzene (Bensol ) Benzene Sulphonic A c i d , ( o r Chloride) Benzoic Acid Benzyl Acetate Benzyl Alcohol Benzyl Chloride Boric Acid Bromine Bromine Water, S a t u r a t e d Butanol Butyl Acetate Butyl C a r b i t o l Butyric Acid Cadmium Chloride Cadmium N i t r a t e Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Calcium N i t r a t e ( N e u t r a l S o l u t i o n s ) Calcium Sulphate Carbon Bisulphide
Aluminum Alum Rmmonium Ammonium Ammonium Ammonium Ammonium Ammonium
Fluoride
NR R R R R NR NR R R R R R R R R R R R R R R
R R NR R R R R R R R R R R
R U R R U 35OC R U U R U
NR
NR
R R R R NR R R R R R R R R R
NR
R U U
NR
U R R R 3OoC
NR
R
NR
NR NR
NR
R
R R R R NR NR NR
U R
NR NR
R R
U U
U NR
R R
NR
R R
NR NR
NR
3OoC
R
U NR U
NR NR NR
R R R R NR U R R R
(continued)
NR
R R R R
3OoC R 70C R 3OoC R R R R
408
TAB LE 3.14: VAR 1 US MORTAR S-STE R NSON (continued) 0
EXPOSURE
I N 0 BOND SERIES llO0OC P - 9oooc S - 400C
c -
FURABOND
FURASET 175OC
R
STERNCHEN SERIES POLYESTER PHENOLIC 120oc
175OC
U
Carbon Dioxide Carbon Oxychloride ( Phosgene ) Carbon T e t r a c h l o r i d e C a u s t i c Soda & P o t a s h C h l o r o a c e t i c Acid Chloral (Trichloroacetic aldehyde) Chlorbenzene C h l o r i n e D i o x i d e , Water Solution Chlorine, Liquid C h l o r i n e , Gas C h l o r i n e Water, S a t u r a t e d Chloroform Chloronaphthalene C h l o r o s u l p h o n i c Acid Chromic Acid 10% Chromic Acid Chromic C h l o r i d e Chromium Potassium S u l p h a t e C i t r i c Acid Copper A c e t a t e , Chlorides & Sulphate Copper Nitrate ( N e u t r a l Solutions) Cresol Ether Ethyl Acetate E t h y l Alcohol E t h y l a m i ne E t h y l Bromide Ethyl Chloride & Ethylene Dichloride E t h y l e n e D i s u l p h o n i c Acid E t h y l e n e Oxide Ethyl Ether Ethyl Sulphate E t h y l S u l p h u r i c Acid F a t t y Acids F e r r i c C h l o r i d e , Nitrate, Sulphate F e r r i - & Ferrocyanides F l u o b o r i c Acid F l u o r i n e Gas F l u o s i l i c i c Acid Fo rmal d e hyde Formic Acid & Compounds, n o t a l l Furfural
R R R
U U 30C U N
NR
R R R
R R R R
R R
NR
NR R
NR
NR N
3OoC
NR NR NR
NR
NR R R R
NR
NR NR R R R
R
8OoC 35oc 35OC 20% N U U
3OoC
3OoC NR NR U NR
6ooc
NR
U U R
U R R
R R NR R 3OoC 30oC NR NR
R
R R R R R R R R R R R R R R R R NR
R R U U N 8OoC U NR
R R R R R
NR NR
R R R R R R R R R R
NR
U U 25oc 3OoC
3OoC
U
R 3OoC
3OoC
R 3OoC R R
R
U U
NR
NR
NR
NR R R R NR
(continued)
NR NR
R R U
NR
R R R
25Oc
3OoC R
R
NR
Cements, Mortars, and Asphalt TABLE 3.14: VARIOUS MORTARS-STERNSON

(continued)
409
EXPOSURE
I N 0 BOND SERIES llO0OC P goooc S 400OC
c -
F'URABOND FURASET
STERNCHEM SERIES POLYESTER PHENOLlC 12oOc
175OC
R R R R R NR NR R R R R
175OC
R R R NR NR NR NR R R R R NR NR NR R NR R NR NR R R R U NR R R R R R R
G a l l i c Acid Gasoline Glycerine Glycol Monoacetate Hydrazine S u l p h a t e Hydriodic Acid Hydrobromic Acid Hexane Hydrochloric Acid Hydrocyanic Acid H y d r o f l u o r i c Acid Hydrogen P e r o x i d e 1% Hydrogen P e r o x i d e 10% Hydrogen P e r o x i d e 25% H y d r o f l u o s i l i c i c Acid Hydrogen P e r o x i d e 30% Hydrogen S u l p h i d e Hypochlorous Acid Iodine I r o n Chlorides I r o n Nitrates Iron Sulphates Isopropyl Ether Iodoform Kerosene L a c t i c Acid & Compounds Lead C h l o r i d e Lead Nitrate ( N e u t r a l Solufuions) Magnesium C h l o r i d e , N i t r a t e , Sulphate Maleic Acid & Compounds Manganese C h l o r i d e , Oxides & Sulphates Mercuric C h l o r i d e Methanol (Methyl A l c o h o l ) Methyl A c e t a t e M e t h y l b u t y l e n e g l y c o l Acetate Methyl Cyclohexanol ' Methylene C h l o r i d e Methyl S u l p h a t e Methyl Sulphonic Acid Mineral O i l ivlolybdenum Acids & Oxides Naphthalene ( S u l p h o n a t e d ) Naphthalenesulphonic Acid Naphtholsulphonic Acid Nickel C h l o r i d e & S u l p h a t e
R R R NR R R R R R R NR R R R
U 25OC 70C
U U
NR 3OoC 25OC R R NR
NR
NR
NR
R
3OoC 3OoC 3OoC

NR 25OC R
NR
NR R R R R R R R R R R R R R R
NR
R NR
U
NR R 7OoC R 25OC NR 25OC R R R R
NR
R NR R R R R R R R
U
R R 3OoC R
R R 3OoC R
U U U
N
NR U
R R U R U
U
R U
U
U
U
U
R
U
R
(continued)
4 10
TABLE 3.14: VARIOUS MORTARS-STERNSON (continued)
EXPOSURE
c P S
I N 0 BOND SERIES
llO0OC
goooc 40OoC
FURABOND FURASET
STERNCHEM SERIES POLYESTER PHENOLIC 120%
175OC
NR NR NR R NR NR NR NR R R R R R NR R R R NR R R NR R
175OC
U NR NR
N i t r i c Acid 5% N i t r i c Acid 20% N i t r i c Acid 40% Nitrobenzene Nitrogen Oxides Nitroglycerine Nitrophenol Nitrotoluene O i l s - V e g e t a b l e , M i n e r a l , Animal O l e i c Acids & Compounds ( E s t e r s ) Oxalic Acids & Compounds
Paradimethylaminobenzophenone
P a r a f f i n Wax P e r c h l o r i c Acid Phenol (2 0 % S o l u t i o n ) Phenol S u l f o a c i d s Phosphoric Acid Phosphorous Bromide Phosphorous C h l o r i d e & Oxychloride P h t h a l i c Acid P i c r i c Acid Potassium Bichromate Potassium Bromide Potassium Carbonate Potassium C h l o r a t e Potassium C h l o r i d e , Nitrate, Sulphate Potassium Cyanide Potassium F e r r i & F e r r o Cyanide Potassium Hydroxide Potassium Oxalate Potassium Permanganate Potassium P e r s u l p h a t e & S u l p h a t e Potassium Peroxide Pyridine S a l i c y l i c Acid Selenium Compounds Acid o r N e u t r a l Silicon Tetrachloride S i l v e r Nitrate Sodium A c e t a t e Sodium B i c a r b o n a t e Sodium Bichromate Sodium B i s u l p h a t e , B i s u l p h i t e Sodium Carbonate Sodium C h l o r i d e , Nitrate Sodium Chromate Sodium C h l o r o s u l p h o n a t e Sodium Cyanide
NR R R R R R R R R R R R R R R R R R
7OoC
25OC NR NR NR NR U
3OoC NR NR
NR NR R R R U R NR NR U R
u
R R R
U
R
NR
NR U
R NR
U R NR R U
NR
U R
R R R R R
NR
R NR 3OoC R
R
NR
R R R R R R R
NR
R R NR R
U
R R U
3OoC
30OC NR U R R NR NR R
3OoC
U U
NR
R R R
8OoC
R NR 80C R R R U R R
8ooc 6ooc
R NR R
U U
NR
R R
R R R R
7OoC
R R R R U R R U U
NR
R R
NR
R R R
NR
R R R R R R R
U U R R R R R
3OoC
R R U 25OC (continued)
41 1
TAB LE 3.14: VARIOUS MORTARS-STE R NSON (continued J
EXPOSURE
I N 0 BOND SERIES
c -llO0OC
P S Sodium Hydroxide Sodium H y p o c h l o r i t e Sodium O x a l a t e Sodium P e r o x i d e Sodium S u l p h a t e Sodium S u l p h i d e Sodium S u l p h i t e Sodium T a r t r a t e Sbdium T h i o s u l p h a t e , T h i o s u l p h i t e Soya O i l S t e a r i c Acid S u l p h u r i c Acid 5% S u l p h u r i c Acid 50% S u l p h u r i c Acid 80% S u l p h u r i c Acid 93% Sulphur C h l o r i d e Sulphur Molten Sulpnurous Acid Sulphur Oxides Sulphur Dioxide (Wet o r Dry) S u l p h u r i c Acid, Fuming Sulphur T r i o x i d e (Wet) S u l f u r y l Chloride (Sulphur Oxychloride ) Tannic Acid T a r t a r i c Acid & Compounds Tetrachloroethane Tin Chlorides Tin Sulphates Titanium C h l o r i d e s , S u l p h a t e Toluene ( T o l u o l ) Toluenesulphonic Acid T r i c h l o r o a c e t i c Acid Trichloroethylene Trisodium Phosphate Tung O i l Urea U r i c Acid Xylene ( XyIol) Zinc C h l o r i d e , Nitrate, S u l p h a t e Zinc Nitrate
- goooc
40OoC
F'URABOND FURASET
STERNCHEM SERIES POLYESTER PHENOLIC 120%

175OC NR NR
175OC
R NR R
NR NR
NR R
R NR
R
NR
R R R R R R R R R NR NR NR R R R R NR
U U
R
U
NR R NR R R R R R R R 25OC 25OC
NR
R R R R R
3OoC R R R
U
R R R NR NR
NR
R R R R R R R R R R R R R R R R R R R R R
U
R R R R
U
R E R R NR 25OC NR R R U R R R NR
NR NR
R R R R R R R R R R R R R R R R 125OC
NR NR NR
R R U R R
R
80oc
U
NR
U
3OoC R
U U U
NR R R
NR
R R R R R R
3OoC
U 30OC R R
U U
R R
Ferrous Alloys
TABLE 4.1:
AUSTENITIC
ALLOY-ALLEGHENY
LUDLUM
AL-6X is an austenitic chromium, nickel, molybdenum-containing alloy developed for service in chloride and other pitting or crevice corrosion environments such as sea water. The 20% chromium and 6% molybdenum contained in the alloy produces outstanding resistance to pitting and crevice attack in chloride-containing solutions. The high nickel (24%) and molybdenum provide good resistance to stress corrosion cracking. The alloy content of the material produces excellent general corrosion resistance in a number of media. The alloy is readily welded by the inert gas processes. AL-6X possesses good ductility and high impact strength. AL-6X is available as welded tubing, sheet and strip.
The following table illustrates the corrosion resistance of AL-6X in various solutions in comparison to AISI stainless steel grades. Tests were performed in boiling acid (concentrations in weight percent) for five 46-hour periods. The listed values are corrosion rates in IPM (inches per month):
Solution 45% Formic Acid 20% Acetic Acid 10% Oxalic Acid 10% Sodium Bisulfate 10% Sulfuric Acid 65% Nitric Acid (ASTM A-262 Practice C)
Type 446 .61 9000
We
304 .143 .025 947 .230 1.36
Type
316 943 9002 906 ,014 .07f
AL-6X 9005 .OOOl .0009 .OOll ,010
12.0
Typical Analysis
.0007
9507
.0009
JO26
L
Alloy 304 316 AL-6X Samples initially
Carbon Manganese Phosphorus Sulfur Silicon Chromium Nickel Molybdenum
.025 1.50 .025 .Ol 0 2d.E 24.50 6.25
Data, including the boiling acid tests above, show that AL-6X is generally more corrosion resistant than Type 316. In environments such as sulfuric acid, concentrations and temperatures have a marked influence on corrosion rate, and specific conditions should be carefully determined. The following data determined for 2-hour coupon tests are illustrative:
Temperatures
Corrosion Rate, IPM 15VF AL-6X 316 AL-6X 316 AL-6X 316 AL-6X 316 AL-6X 316 904 .003 .CQ6 907 .009 .016 907 536 .031 905 175F 904 .007 .004 .013 905 .070 .OlO 1.646 .043 907 2OfYF 905 .012 ,007 .016 .013 .146 .019 3.023 .056 .026
TyPical Weiaht Changes and Sample Conditions Resuking Fibm 10 Per&t Fe& Chloride tixposure Tests72 Hours 70 F (21 C)
Crevices On Samples 0.45 Gram Weight Loss Severe Crevice Attack 0.40 Gram Weight Loss Severe Crevice Attack No Weight change to 0.000 Grams No Attack weighed about 10 g, No Crevices On Samples 0.45 Gram Weight Loss Severe Pitting 0.03 Gram Weight Loss Some Pitting, especially on sample edges No Weight change to 0.000 Grams No Attack
Concentrations of H,SO, Weight % 5 10 20 40 95
Ferrous Alloys
413
TABLE 4.2:
AUSTENITIC
STAINLESS
STEELS-JESSOP
STEEL
are high-alloy, fully austenitic, super stainwhere corrosive conditions are too severe for the standard grades of stainless steel. They have also provided cost-effective alternatives to more expensive nickel-base and titanium-base alloys. JS700 and JS777 are much more highly alloyed than the standard stainless steels. These grades contain nominally 25% nickel, 20% chromium and 4.5% molybdenum. The combination of the three major alloying elements gives JS700 and JS777 a high degree of resistance to stress corrosion cracking. Neither alloy is completely immune to this type of corrosion failure, as can be shown by such severe tests as stressed exposure to boiling magnesium chloride solutions.
Jessop Steels corrosion resistant engineering alloys, JS700 and JS777, less steels. These alloys are proven problem-solvers in many applications
Corrosion
Data
(48 Hr. Laboratory
Tests-All
concentrations
are by weight
%I. Corrosion
Rate 317L Plus 317L co.002
Environment
Temperature Boiling 250 Boiling Boiling Boiling 167 Boiling Boiling 155 Boiling Boiling Point
OF JS700 J8777 co.002 0.012 0.067 0.080
IPY
20% Phosphoric Acid 54% Phosphoric Acid 60% Phosphoric Acid 85% Phosphoric Acid Sensitized Material 25% Phosphoric 2% HF 60% Acetic Acid 1.1 Acetic AcidIAnhydride 5% Nitric Acid + 3% HF 25% Nitric Acid 65% Nitric Acid (Huey) 5% Hydrochloric Acid 10% Hydrochloric Acid 10% Hydrochloric Acid 10% Hydrochloric Acid 10% HCI in EDA (1 I 30% Sulfuric Acid Sensitized Material 50% Sulfuric Acid 50% Sulfuric Acid + %% HCI 70% Sulfuric Acid
Point Pomt Point Point Point Point Point
co.002 0.0024 0.059 0.122 0.124 0.008 co.002 0.001 <0.002 co.002 co.020 1.491 0.018 0.150 4.51 <O.OOl 0.150 0.160 0.247 0.880 57.6 0.264 0.096
HPSO~.
0.294
0 196
co.002
co.002 0.962 1 454 1.691
Boiling Point Room Temp. 140 Boiling Point Boiling Point Boiling Boiling Boiling Boiling Boiling Point Point Point Point Point
2.37 0.036 0.031 0.102 0.298 27.6
(4)
(4)
0.962
0.540
Butyl Acetate Mixture (2) Boiling Point Boiling Point Stretcher Test (3) (I) 1 Volume cone I-ICI in 9 volumes Ethylene Diamine.
(2) 75% Ester-l 1% Butanol-10% Acetic Acid-4% Water-0.3%
(3) 50% Sulfuric Actd + 0.6% Fe+) as ferrtc sulfate InhIbItor. (4) Dissolved COmPletelY in 48 hours. an&SiS) JS777 24 O-26 0% 19 O-23.0 43- 50 8 x carbon mm-80 40 max 04 1 00 2 00 04 03 1.90-2.50
Chemical
Composition JS700
[IIOtninai
Nickel Chromium Molybdenum Columbium Carbon, max Slllcon. max Manganese, max Phosphorus, max Sulfur, max Copper
24.0-26.0% 190-230 43- 50 6 x carbon mm-O.40 max .04 1 .oo 2 00 .04 03 50 max
The copper added to JS777 markedly Improves resistance to general corrosion in strongly acid environments. As shown In the tabulated corrosion test results, copper improves performance not only in oxidtzmg acids (e.g. sulfuric) but in media generally considered reducing (hydrochlorIcI as well However, m more nearly neutral media, where failure is by
localized corrosion, copper seems to be actually detrimental to performance. Field exposure tests (e.g. the TAPPI program IIT pulp bleach washers) and electrochemical current decay tests show pits to propagate more rapldly in JS777. JS700 is therefore the recommended alloy where pitting or crevice corrosion IS the primary concern.
Ferrous
Alloys
415
TABLE
4.3:
FERRITIC
STAINLESS
STEELS-ALLEGHENY
LUDLUM
(continued)
AL 29-4-2 Critical Pitting Potentials in Saturated Sodium Chloride Brine at 38C (lOOF) MillivoltsVs. Saturated Calomel Electrode Alloy
AL 29-4-2 E-BRITE
Alloy (contd)
Data and from paper one mill year bleach field corrosion tests at nine pulp
pH 10
+990 + 400
PH6
+ 990 +420
pH2
+ 860 +430
below. In this program, nine different pulp mills exposed corrosion test spools for one year. The AL 29-4-2 alloy was among those demonstrating the highest degree of corrosion resistance.
plants
are shown
TAPPI (0 Stage),) Corrosion

Stress COrrOSiOn Cracking in Various NaCl Tests
I c
---__~_~~___.~~i
Results
Mill -~__
I t
_---..-..-
i I
/ T&304 ___
I ,
in paranlherer indicale
C (72h.)
described
L--C_(250h.)
A692).
1 C (4%72hd (1) One

Year Exposure Chlorides: Up lo 4100 ppm : As low as 1.2 PH Temperature: Up to74C (lS*F)
II ~ II 11 / Ill II Ill
I/
II III Ill Ill
II Ii Ill Ill II Ill Ill Ill
(1) 1500 ppm Cl as NaCl (Procedure (Z)NC No Cracks: C Cracks. Numbers
in ASTM
the test duration.
Crevice Corrosion Test) in Synthetic Brine __.__ Alloy

AL 29-4-2 Titanium Monel400 E-BRITE ~ 316L
.._ 22C (72F)

.00N3) .OON .OON JJON OON
Weight Loss, mg/cmz 1 sOC(14OF)

/ ; I .OON .OON .08c .12 c .Ol c
j 107C (224F)
I I .OON .OOC .29 c cl6C
(2) Corrosion Classdicabon: I O-9 mil pit depth and4 mpy general corrosion rate II S-20 mil pll depth o,>l lo IO mpy general corrosion rate 111 > 20 mil pit depth or>10 mpy general corrosion rate
Source: A. I, Tuthill, J. D. R6hlo.
.I. .I. Oeirler. R. H. Heahy and L. L Edwards. %onorion Resistance of Alloys 10 Bleach Plan, Enwonmene. TAPPI, Nov. 1979. Vol. 62. No. 11, pp. 4%5l.
.oic
/
Performance of AL 29-4-2 and Other Alloys in Boiling 65% Nitric Acid Alloy Corn&n Rate, mm/a (MPY)
I1 ) PH 7.0.72-ho, test. crevices with rubber band and teflon soacers (2; brine composition (wt. %): 25% NaCI; 38% Na,SO.; .lS% &Cl,; .03% MgCI, No Corrosion; C Crevice Corrosion. (3) Visual appearance rating: N
Crevice Corrosion Tests in Boiling Brine with Sodium Carbonate
Alloy Al 29-4-2 E-BRITE Titanium Monel400
Weight Loss, mg/cm2

0.00
Visual Appearance
No Corrosion NoCorrosion No Corrosion Crevice Corrosion
boiling at
/ / / :
0.00
0.00 1.05
AL 29-4-2 1 E-BRITE Type 304 Type 347 Type 316 -- Type 430 -._ -.......
(1) ASTM
I I I
.._.__
i -.._ _ . .._ periods. C. Five who,
.05-.08 (2-3) .lO-.13 (4-51 .20-.61 (8-24) .25-.41 (10-16) .28-.89 (1 l-35) .51-.9l _...(2036) .._._. --.__. -
_ ^._..
(1) S&waled
NaCl brine conlaining 10% N&CO,, pH 11. 72.hour test, abnospheric pressure. wewces wdh rubber bands and tellon spacers.
A 262. Practice
Corrosion of AL 29-4-2 and Other Alloys in Hot Geothermal Fluid) Corrosion of AL 29-4-2 and Other Alloys in 50% Nitric Acid Containing Chlorides and Fluorides at 79C (175F)
i_!?lp(i~~!~---. ~-..-; _-.. -~.-__-
Corrosion Rate(?),mm/a (MPY) F.RRIT E1TVIX 3W [ %nium I.211.Ol; (0.6) 091 (3.6)
AL 29-4-2 ,117 025 ,079 (l.O), 1 .305 (3.1) ,102 (4.0) i ,914 ,241 (9.5) i 1.115
(l,Chlo,ides (2) Corrosion addedasH,& fluoride as HF. rate is the average 01 two 48-ho, periods.
(4.6) (12.0) (36.0) (43.9) __I
(1) 133C (271F) cl-776 ppm pH 7.23 lice; S4 ppm Nonaerated so: SO ppm 109 Day Exporure H,S 0.1 ppm (2) Penetrabon rate calculated from maximm (3) P-Present but not measured N-Not observed SO,Ce:
pit o, crevice depth.
D. W.~DeSe,,,. P. F EM nd C. C. Thomas. Malenals Setec,ion Guidelines (0, Geothermal power Syrlemr~, FM Ed.. Rad,w Cotp., lo, U. S. Dept. of Energy. Contract NO. EC-77-C-M-3904. Septembe,. 1978.
(continued)
416
(contrnued)
AL 29-4-2 Alloy (contd)

Other Alloys in Boiling Organic Acids
AL 29-4-2 E-BRITE
<O.Ol
(0.1)
0.01(0.4)
(2) 0.5 (18) 0.01 (0.4)
j j
/m_Fm_._
Source:
-periods
~-
(1) Average 01 five 48.hour
A. I, Asphahani. P. E. Manning, W. L. Silence. F. G. Hedge. Highly Alloyed Stainless Materials lor Seawater Applicalions, Illinois. Presented at NACE. March 3-7. 1980. CORROSION/80. Chicago,
Corrosion of AL 29-4-2 and Other Alloys in Boiling Dilute Sulfuric Acid Solutions
-__-.. _I-Corresion
I
Intergranular Alloy
Corrosion Tests on AL 29-4-2
t
Alloy625
I% H2sOI .005(0.2)
em-mm/a (M ____~_ 5% Ihso, .03 .27 .32 .23 .36 77 2.49 2.71 (1.3) (10 7) (12.7) (8 9) (14) (3020)3 (98.2) (107) .02 .46 .52 (0.8) (18.2) (20.6)
[ Corrosion Rate, mm/a (MPY) I Samole I

Test
Ferric ASTM ) Bolting ~ ASTM Sulfate-50% HzSO~ A763. Practice X 65% HNOI A262. Practm C Practice Y
Plain Containing Grain Sample Weld Dropping

.14 (5.6) .13 (5.0) None
I I
/ NA
A NA A NA
IE-BRITE I
/Type 316
1 A
.07 (2.6) .07 (2.8) .06 i2.2j .02 (0.7) 13.7 (541) .55 (21 7) 66 (25.8)
I
8.73 (344) L- ASTM A763
Crevice Corrosion of AL 29-4-2 Alloy and Other Metals In Simulated Flue Gas
Desulfurization Environmentn) Weight Loss (mglcmr) -Test c
7 I
Corrosion of AL 29-4-2 Alloy in Laboratory Caustic Solutions
1
AL 29-4-2 Alloy 625 i Alloy 625 /Type316 ,Type316 !Allov G i~lio;C-276
(1)7VCl
/
1
72h 24h 72h 24h 72h 72h 72h

I Wt. % CuCI.. 1 WI. %
---I
rot (158F) 0.2 N 4.2 C 20.6 C -
F
I_._ I
Compesitior
=-----I
Other -t- 1 -
Temperature IIuration.
C (F) Boiling Boding Boiling
1
5 4 4 4 4
4 4 4 4
Corrosion
Rate
Days
1 WPv)
j o.m(o I)* j 0.02 (0 8)
0.10 (3.8)
mm/a
Na&O.,
149 (300) Bng 177 (350) Boilmg Boiling 177 (350)
I
I .L
i 0.00(0.0) I 0.04 (1 5) / 0.19 (7.4) j 0.00(0.0) 0.00(00)

0.14
(5.6)
.HSOJ: 3 OI o Cl.
F&t>
(2),sualexam,nat,an.N NoCorrosion C CrertceCorrosion
(continued)
Ferrous A llo ys TABLE 4.3: FERRITIC STAINLESS STEELS-ALLEGHENY LUDLUM (contmwd)
417
The E-BRITE alloy is a high-purity specialty ferritic stainless steel which combines excellent resistance to corrosion with good fabrication characteristics. It offers outstanding resistance to stress corrosion cracking along with superior Pitting and crevice corrosion resistance, compared to conventional ferritic and austenitic stainless steels. General corrosion resistance is usually better than that provided by these standard materials and in some cases is even better than that of some nickel-base alloys. The E-BRITE alloy also is designed to provide excellent resisiance to intergranular corrosion. Added to all this corrosion resistance are unique ductility characteristics, particularly when compared E-BRITE j,,,,
Chromrum Molybdenum Nrckel Copper Manganese Phosphorus
to other ferritic Alloy Analysis __-
stainless steels. Crevice Corrosion Tests 10% Ferric Chloride ~_..~..__ -.._- ___. -. ._ _.__~____.._ .._~___~_ ..
250 -27 5 0 75 - 1 50 50 max 20 max 40 max 02 max 02 max 40 max 010 max 015 max 005 -020
__-___-
~~~W%!!!!J!Jz!_!_;I.~~
26 0 10 15 02 05 01 01 20 002 ,010 10
/ 1
L----_A110y.
E-BRITE T37L T316 ~QX2QCt&_ __--.
ASTM G-48
._ _ ___#Weight Loss, mg/cm 1 -____ RT _ -. _ 38C.11 DOF)m

03 50 11 5 _.___.._21..~__ -. 76 27.0 32 2
, j 1
~_~._ _ _38.3-
Suf:1r
SIlIEOfl
(1)72
hour
exposure.
Procedures
Carbon Nrtrogen Columbrum
Crevice Corrosion Tests 5.25% Sodium Hypochlorite i_AtlOY__ _-Weight
at i1C (160F) --.-8ampleAppearance

No Corrosron Crevice Attack 05 95
Loss,mg/cm*_
Chloride Stress Corrosion Annealed Sheet /r-----i Boiling I Solution J2OuMgCI,

c300 LIC 26Oc NaCl (II
F NF -
Resistance
E-BRITE Type 316 lyp&?Q__

(1) 96.hour exposure
~~t21)Crevj~e&tack_.
j
T304
F (81 F (22,
Time to Failure (Hours) _._______-.. E-BRITE T316 : -~

F 1241 F 1221 F (221) NF (2001 NF (500, NF (loot
F (J-31
Falure
Crevice Sodium
Corrosion Carbonate
Tests in Boiling Brine with
Slress Corroston No Fatlure
I i_AhY.
E-BRITE Titanium
--.--0 00 0 00 105
_-__
-__-.-
..-.
--_!--WeightLoss.
mgkmf-VisualAppearanceNo Corroston No Corrosron -Crevice=

pH 11. 72.hour lest. boiling at
Critical Pitting Potentials at 38C (1OOF)
in Saturated
NaCl Brine
I) , Saturate N&l brine containmg
10% N&O,.
I
KMnOd-NaCI Pitting Tests
75
kt?NaOH-/--C-
Urrosion Rate /-Temperature_. Duration _#1B.-Days _-mm~.___UkWT)

102
(215)
0 000
(220)
(230) (240) 1290) 1315)
5
7 5 5 4
0 001
0 000 0 001 0 003 0 084 QZZ0 381
(0 01, to 04) to oi 1 10 05) (0 111 13 3) 16-151_
!ld!Lal~~,,3 1
(1) 2%
(2) F
Resistance Containing
of E-BRITE Alloy to Caustic NaCl and NaC103
Solutions
20 45 50
KMnO.-24
Failure pottmg by
N&I.
no crev,ces
(pH 7.5)
50
50 i.SL 50
_
10 5 -5 5 5___. 5
! ~
01 0; 02
143 143 152 152 152 ~~_
(290) (305) (290) 13051 13051 (305)
/ 0041 (1 6) 003 li 0 076 (3 01 to 0 069 (2 71 _OLd28__ ~il~li 11 0 028 11
~~~~
(continued)
418
TABLE
4.3:
FERRITIC
STAINLESS
STEELS-ALLEGHENY E-BRITE Alloy
LUDLUM (co&d)
(contmued)
Corrosion of E-BRITE In Pulp Liquors

ik---------
and Austenitic
Alloys
Performance of E-BRITE Alloy and Other Stainless Steels in Huey Test
Corrosion Rate, mm/y (MPY)
2 Parts White Liauor to 1 Part
I /
Alloy
Corrosion Rate, mm/y (MPY)
i FcBpXZ
i
Type347 Type316 Type430 (1) ASTMA262.
I / 1
I
010-013 0.20-O 61 0.25-041 028-O 89 0 51-o 91 _____
I / /
(A-51
(8-22:) (10-16) (11-Z) (20-261 ~____
periods
/ 1 I 1
Pracltce C. Bollmg 65O~ HNO,.
Fwe 4%hour
Influence Corrosion
Corrosion Solution .__. . c_______-_ _. ..__. E-BRITE PPM F -IHNO, _ _----- PPM Cl
I---
__-..--.
of Chloride And/Or Fluoride On In 50% Nitric Acid at 79C (175F)
~~_.
Rate, mm/y (MPY)

Type304 Titanium (3 6) (4 61 1120) (360) 14391 106) 0091 ('0)'0117 (31),0305 (40) 0914 (95) 1115
5000 5Ow
300
!-
50% ~ 50%
snD/o
(I, Corros,on
300
1000
rate
I ; 20 / 20
'100
IS average
0005 0010 0025 0041 0089

of two 48.hour
(02) 0015 (04) 0025 (1 0) 0079 (16) 0102 (35),0241

permds
(2, Chloride
added as HCI. lluorlde
as HF
Corrosion of E-BRITE In White Liquor Under
and Austenitic Alloys Conditions of Heat Flux
Corrosion
in Boiling.
Dilute Sulfuric
Acid Solutions
(MPY) 5% lizSO NonActivated Activated
Corrosion Rate, mm/y
______ _Alloy ,E-BRITE Type316Tt ,Type317L 005-005 (0 2) 35 1138) Alloy
1% H2S04
Non-
Activated
Activated
___~.j_
___I
(1) Sample kept al 160C (32OF) immersed in while liquor at BOC (176F). (2) Sample temperature 160C (32OF). whde liquor jet at 8OC (176F) projected against sample.
Corrosion
Boilin
Or
anic Acids
In-Plant Corrosion Tests of E-BRITE Other Alloys in White Liquor
and
~~ I 1
___
Corra Alloy E-BRITE NI-CrAlloy600 Type329StamlessSteel Type310StalnlessSteel NI-Fe-CrAlloy800 NI-'hAlloy400 NI-Fe-CrAlloy825 Type304StadessSteei NI-CrAlloy625 Type316StamlessSteel CarbonSteel mm/y 0 000 0 005 0 008 0010 0020 0023 0 041 0168 0173 0 516 0886
3n Rate __.___/
WY)
(0 0)
IO 21 10 31 (0 4)
(0 81 ro 91
Comparison of E-BRITE and Other Alloys Boiling 88% Formic and 99% Acetic Acids r
in
IMPY) 99% Acetic
I
1 E-BRITE NI-Cr-MoAlloy276 Nt-Fe-CrAlloyG Nl-Fe-Cr Alloy825
Corrosion 88% Formic
Rate. mm/v
<o 01
005 0 10
(-'O 1) (1 8)
(4 0)
0 01
001 004 005 001 010 020
(1) While Liquor: (NaOH+Na,S). 260 7.8% NaCI. 1 5% NarCO,. Temperature: 127C (261F) Duratlon~ 154 Days (2) SCC - Slress Corroston Cracking Observed
NJ-Cr Alloy 625 NI Alloy200

3OoNa.SO,
NdZrAlloy600
Type304 StaInless Type 3:6 Stainless
0 08 0 23 0 33 0 38 2 44
(3 (9 (13 (15
0) 0) 0) 0) (96 0)
(9oj
(0 5) (04) (1.6) (20) (04) (40) (80)
0.23
046 005
(180) (20)
Ferrous Alloys
419
TABLE
4.3:
FERRITIC
STAINLESS
STEELS-ALLEGHENY
LUDLIJM
(continued)
Allegheny Ludlum Stainless Steel Type 439, a titanium stabilized, 18% chromium alloy, also known as ASTM XM-8 and by the IJNS designation S43035, is a ferritic stainless steel designed to resist corrosion in a variety of oxidizing environments from fresh water to boiling acids. It may be used either annealed, cold formed or as welded in many applications where other stainless steel alloys such as Type 304, Type 410, Type 409 and Type 430 are used. Type 439 may also be used in many oxidizing environments where Type 304 is considered adequate in terms of general corrosion resistance but is considered subject to chloride stress corrosion cracking.
Tvpical General Corrosion Data _.
TYPICAL
ANALYSIS Standard Grade ,025 .40 .025 ,003 .50 16.00 .30 .60 ______ ,025
MSR Grade
Corrosion Rates in Inches Per Month and Millimeters Per Annum ( )
Medium
.018 .40 ,025 ,003 .50 18.00 .30 .50 ,014
10% Oxalic Acid Boiling ___-
Corrosion Resistance Type 439 is resistant to attack by potable water and many mildly or moderately corrosive chemical environments which are oxidizing in nature. In various chloride solutions, study has shown pitting resistance of Type 439 superior to that of Type 304. In addition, Type 439 is not subject to stress corrosion cracking which may cause premature failure of austenitic steels in chloride bearing environments such as hot waters used in heat exchangers.
Stress Corrosion Cracking One of the most important corrosion properties of Type 439 is resistance to chloride stress corrosion cracking beyond the capabilltles of ConventIonal austenitic grades. This resistance is provided by the ferritic structure and low nickel content of Type 439. Results are equivalent for annealed, U-bent and autogenously welded Type 439.
MF-1 is the designation for a corrosion resisting steel developed by Allegheny Ludlum originally for automotive exhaust system applications. An 11% chromium alloy, MF-1 is a functional corrosion resistant material that has served outstandingly in strong acid condensates that form in automobile mufflers ard tailpipes. The functional uses of MF-1 as a corrosion resistant material for many other special applications can be equally attractive; suetas replacement for carbon steels, to avoid painting or other maintenance, or for galvanized steels under severe corrosive conditions. Corrosion Resistance of MF-1 jRates in Inches Penetration/Month Medium
; Carbon
TYPICAL
C
ANALYSIS
Cr Ti Fe Bal.
r-
.--~__
_----
: Steel .__ ..____ _

50.0 30.0 20.0 .0050 ,221
I j j
1
MF-1
,045
11.0
.50
--.-_______
Welded
25% Boiling Nitric Acid 20% Boiling Phosphoric Acid 60% Boiling Acetic Acid 50% Potassium Hydroxide at 240F 75% Potassium Hydroxide at 410F
samples show
; .0150 I .048 I I .159 ; .00055* / I .085*

corrosion.
j Type 304 I -/ I 1 .0002 1 I 1 / .0002 ~ .00055 i / I i I
no preferential
420
Corrosion Resistant Materials Handbook FERRITIC-AUSTENITIC STAINLESS STEEL-CABOT WROUGHT PRODUCTS
TABLE 4.4:
FERRALIUM alloy 255 is a patented, ferritic-austenitic nickel, 2% copper and 3.3% molybdenum. It combines tance to corrosion and erosion.
stainless steel high mechanical
containing strength,
approximately ductility and
26%chromium,5% hardness with
resis-
Comparative Aqueous Corrosion Data

Concentration, percent by $yt$mp., 0 weioht 10 50 Glacial Citric Acid formic Acid 50 20 40 60 88 Hydrochloric Nitric Acid Acid
1
Media Acetic Acid
Average Corrosion Rate, mils (mm) per year FERRALIUM Type 317L allov 255 Stainless Steel 0.2 (<O.Ol) NII 0.7 f<O.Ol) NII 0.4 (0.01) 0.4 (0.01) 0.1 (<O.Ol) 18 (0.46) Nil Nil 1.9 (0.48) 8.0 (0.20) Ntl NII 0.1 (<O.Ol) 0.2 (<O.Ol) Nil 0.1 (<O.Ol) 0.1 (<O.Ol) 0.4 (0.01) 0.4 (0.01) 0.2 (<O.Ol) 1.2 (0.03) 0.5 (<0.02) Nil Nil 1 .o (CO.03)
1.8 (0.05)
Borhng Borlrnq Borlrna Borhng Bowling Bollinn Boihna Bowling Room Room Borhng Borhng 150 (66) Bollma 150 (66) Bowling 150 (66) Boihna 150 (66) Bothng Room Boding Boiling Boiling Boiling Boiling Boiling Borhng 150 (66) Boiling 150 (66) Boihnq 150 (66)
0.2 (10.01 0.2 (<O.Ol) 2.9 10.071 0.2 (<O.Ol) 8.5 (0.22) 17 (0.43) 22 10.56) 9.2 (0.23) NII 11 (0.28) Nil NII Nil 6.7 (0.17) 0.1 (<O.Ol) 1.2 (0.03) 0.2 (<O.Ol) 0.3 (<O.Ol) 31 (0.79) 22 (0.56) NII 0.1 (<O.Ol) 148 (3.8) 29 (0.74) NII 200 (5.1) 8.9 (0.23) 490 (12) 50 (1.3)
2.5 10 65 Phosphoric Acid 10 10 30 30 55 55 85 Sodium Chloride Sodium Chloride plus 200 ppm Cu Sodium Chloride plus 0.5% Acetic Acid Sodium Chloride plus 0.5% Citric Acid Sodium Chloride plus 0.5% Oxalic Acid Sodium Chloride plus 0.5 % Ammonium Chloride Sodium Chloride plus 0.5% Phosphoric Acid Sodium Chloride plus 0.1 N Sulfuric Acid Sodium Hydroxide Sulfuric Acid 3 3 0.8 0.8 0.8 0.8 0.8 5 50 5 5
10
NII 12 (0.30) Nil 4OLl.O) NII
10 20
(continued)
Ferrous
Alloys
421
TABLE
4.4:
FERRITIC-AUSTENITIC
STAINLESS Average Corrosion
STEEL-CABOT Data in Mixed
WROUGHT Acids and Salts
PRODUCTS
(continued)
Media
5%
Test Temp., F (C)

8%
Average Corrosion Rate, per year mils mm 0.1 8.4 0.3 0.2
0.3
Citric Acid plus

plus
NaCl
H2S04
286 (141) 212 (100) 212 (100)

3%
co.01 0.21 co.01 <O.Ol

-co.01
Patmitic Acid Palmitic Acid
1%
Palmitic Acid plus 3% NaCl

PIUS 1%
H2S04 and
NaCl
212 (100)
212 (100)
Stearic Acid DIUS 3% NaCl Stearic Acid plus 1% H2s0.1 Stearic Acid plus 1% H2S04 and 3% NaCl
44% Sulfuric Acid plus 6% HN03
212 (100)
212 (100)
8.3
0.4
0.21
0.01
86 Corrosion Test Temp. F C 68 95 122 149 176 194 20 35 50 65 80 90 20 35 65 66

+*lnltla1lon of ptts
(30)
0.2
co.01
Data in Seawater
Media ASTM Synthetic Seawater*
Average Corrosion Rate, mils (mm) per year Nil Nil 0.1 (<O.Ol) 0.1 (<O.Ol) Nil Nil 2 (0.05) 0.8 (0.02) 7 (0.18) Nil
ASTM Synthetic Seawater Saturated with Chlorine Gas*
68 95 149 150
96.hr. exposure.
ASTM Synthetic Seawater Saturated with SO2 Gas Average dupbcale, smooth specimens. of
Crevice-Corrosion
Data in Natural
Seawater Percent Crevices Initiated* 0 81 1.6 28 76 97 41 0.8 28 Maximum Depth of Attack, mm co.01 1.2 co.08 1.9 1.9 1.1 3.1 <O.Ol 0.10
Alloy FERRALIUM alloy 255 Type 316 Stainless Steel FERRALIUM alloy 255 Type 316 Stainless Steel Type 317 Stainless Steel Type 317LM Stainless Steel 20 Cb-3Alloy FERRALIUM alloy 255 Type 316 Stainless Steel
. Number of Crewas lmtmted Number of Crewces Powble (120)
Test Duration, Days 29 29 30 30 30 30 30 30 30
Y 57 57 86 86 86 86 86 126 126
Temp., C 14 14 30 30 30 30 30 52 52
Trademark
of Carpenter
Technology
Corporation
(continued)
422
TABLE 4.4:
FERRITIC-AUSTENITIC
Crevice-Corrosion
STAINLESS
STEEL-CABOT
WROUGHT
PRODUCTS
fcontmuedf
Data in 10% Ferric Chloride Number of Attacked Crevices* 0 20 23
at Room
Temperature
for 10 Days
Maximum Depth of Penetration,
Alloy FERRALIUM alloy 255
mils
0 12
mm
0
Type 317LM Stainless Steel Allov No. 904L Type 317L Stainless Steel 20 Cb-3 allov Tvpe 316 Stainless Steel
Maxamum poswble number 01 crewces was 24
0.30 0.48
19 77 76 76
16 24 24
2.0 1.9 1.9 (Perforated)
Crevice-Corrosion
Tests in Simulated
SO2 Scrubber
Environment*
Allov FERRALIUM alloy 255 Alloy No. 904L Tvpe 317LM Stainless Steel Allov No. 825
45.000 Maxnwm 0.003%
Corrosion Rate per year mm mils 0.4 57 179 216 0.01 1.4 4.5 5.5
Number of Attacked Crevices** 0 24 24 24
Maximum Depth of Crevice Attack, mils mm 0 6 10 10 0 0.15 0.25 0.25
ppm Cl-,
150F WCI. ptf 2. SOz/O, I1 11 bubbled through solutmn. possible number of cw~ces was 24. F&h, 0.11% KCI, 0.5% MgCIz. 1.1% Cat&, 5.6% N&I. 0.02% CaFz and 2OOg11CaSO1.2fi10.
Comparative
Localized
Corrosion
Temperature
Data in Oxidizing Crevice-Corrosion Temperature, C F 35 95
NaCI-HCI
Solution*
Allov FERRALIUM allov 255
Pitting Temperature, C F 50 122
Allov No. 904L Tvoe 317LM Stainless Steel Tvoe 317L Stainless Steel CABOT allov No. 825 20 Cb-3 alloy Type 316 Stainless Steel
4% NaCl + O.OlM HCI + 0.1% Fez ISO,) 3.
45 35 25 25 20 20
113 95 77 77 68 68
20 15 10 s-5 s-5 1-5
68 59 54 523 523 523
Comparative
Stress-Corrosion
Cracking
Data
Time to Failure, hrs. Media 50% NaOH with NaCl 70% NaOH with NaCl
NC-No
Test Temp., F C Saturated Saturated 290 350 143 177

specmxens.
FERRALIUM alloy 255 NC NC
Type 316L Stainless Steel NC 200,648
Type 317L Stainless Steel NC 1031.1031
fadure in 1000 hours. All tests were
run on dupbcate
(continued)
Ferrous Alloys
423
TABLE
4.4:
FERRITIC-AUSTENITIC
STAINLESS Comparative
STEEL-CABOT
WROUGHT
Cracking Data
PRODUCTS
(continued)
Stress-Corrosion
Media ASTM Synthetic Seawater 0.8% NaCl + 0.5% Oxalic Acid* 0.8% NaCl + 0.5% Acetic Acid* 0.8% NaCl + 0.5% Citric Acid* Modified Wick TestXb 25% NaCl*** 30% NaCI 0.8% NaCl + COz* 4% NaCl + 1% HIPO~* 0.8% NaCl + 0.2% HaPOa* 45% Magnesium Chloride
*U-bend specimen. 30.day exposure U-bend spewne, 100-day exposure U-bend specmxn, 5OGhr. exposure NC-No Cracks C-Cracked -Not tested Localued attack blOOO ppm Cl (as NaCll and 500 pp FeCh
Pt
Temp.,C
TYpe 316 Stainless Steel NC* NC C C C -
FERRALIUM alloy 255 NC NC NC NC NC NC NC NC NC C C
176 286 286 286 212 393 Boiling 286 Boiling 286 Boiling
80 141 141 141 100 200 141
141 C C
Average
Aqueous
Corrosion
Resistance
of Weldments*
Average Corrosion Rate Per Year, mils (mm) Media 75% Acetic Acid 2.5% Hydrochloric Acid 10% Ferric Chloride 6% Ferric Chloride (With Crevice) 65% Nitric Acid 10% Nitric Acid + 3% Hydrofluoric Acid 55% Phosphoric Acid 10% Sulfuric Acid 50% Sulfuric Acid + 42 g/l of Ferric Sulfate FERRALIUM 255lo ltsell allay
Comparative Test Temp., Stress-Corrosion Calcium Chloride** 250 300 350 400 250 Cracking Data* Sodium Chloride** 300 350 400
Test Temp., F (Cl Bolllng Room 86F (30C) Room Boiling Room Boihng Bolllng Boiling
Base Metal 0.1 (<O.Ol) 0.1 (<O.Ol) 0 2 (<O.Ol) NII 4.7 (0.12) 2.3 (0.06) 1.4 (0.04) 37 (0.94) 13 (0.33)
% in. (12.7mm) Plate, SMAW Ntl NII 0.6 (<0.02) NII 8.3 (0.21)
l/B in. (3.2mm) Plate, GTAW 0.2 (<O.Ol) 1.7 (<0.05) 0.7 (cO.02) Nil 7.6 (0.19) 6.8 (0.17)
% in. (12.7mm) Plate, GTAW 0.2 (<O.Ol) Nil Nil

11 (0.28)
1.3 (<0.04)
1.6 (0.04) 73 (I .9) 19 (0.48)
4.1 (0 IO) 49 (I .2) 18 (0.46)
66 (I .7) 23 (0.58)
Alloy FERRALIUM alloy 255 Alloy No. 904L

20Cb-3 illov
1;
121
149
177
204
121 NC NC
149 NC NC
177 NC
204 C C
NC NC
NC
content
NC NC
NC
NC C
NC
C C
C
C
C
NC
NC
*l-week exposure. C-shaped spewnens. like alloy holder. Compositions were selected to provide the same chloride NC-No cracks C-Cracked
as a 25% NaCl solutmn.
424
TABLE
4.5:
IRON
ALLOY-CABOT
WROUGHT
PRODUCTS up to 15OOF and is readily
MULTIMET alloy is an iron-base alloy for use in applications involving high stresses at temperatures (816 C), and moderate stresses at up to 2000F (1093C). It has good oxidation resistance, ductility fabricated. Its high-temperature properties are inherent and are not dependent upon age hardening.
CORROSION
RESISTANCE
OF
MULTIMET@
ALLOY
All results are expressed in mils (mm) penetration per year. Acid strengths are given in percent by weight. In some instances, no measurable penetration could be observed. These instances are noted by the word, Nil. All data are steady-state as calculated from a minimum of five 24-hr. test periods. All data were obtained using corrosion solution heat-treated sheet. specimens prepared from 12-gage,
TYPICAL
PENETRATION ACETIC 10% 50% Nil
RATES ACID 99% Nil
IN CORROSIVE
CHROMIC 2% Nil 10% Nil ACID
MEDIA,
Mils (mm) Per Year

FORMIC 10% ACID 60% 69% Nil
20% Nil
20%
I 30%
-
40% 0.1 (CO.01) Nil
Room 150 deg. F (66 deg. C) Boiling
Nil
Nif
(<oo:bl)
(<t-k!Ol)
Nil
Nil 1 0.1 (~0.01) 1
Nil 0.1 (cO.01)
Ni 1 6.0 (0.15)
(&S)
(2%)
Nif
(<%)
(<YOl)
Nil
0.1
1 356
(9.09)
1 >lOOO
(>25.4)
1 4.0
(0.10)
(<O.Ol)
6.0 (0.15)
1_
1 (;;oo,
1 (zf5,
) (X0,
*Rate is for the fifth (24-hour) test period, not steady state rate.
CUPRIC 2% + NaCl 160 (4.06) 919 (23.3)
CHLORIDE 10% + 10% NaCl Nil
FERRIC 2% + 5% NaCl 193 (4.90)

71000
CHLORIDE 5% + 10% NaCl 71000
2% Room 150 deg. F (66 deg. C) Boiling Nil -
5%
5% + 10% NaCl Nil

71000
10% Nil -
2% Nil -
10% Nil
(725.4)
(>25.4)
(725.4)
HYDROCHLORIC 1% Room 150 deg. F (66 deg. C) Boiling 0.1 (<O.Ol) Nil 370 (9.40) 2% 5% 10%
ACID 150/o 20% 25% 37%
WET CHLORINE
(co67.01) Nil 934 (22.7)
(E3, 343 (8.71) .>lOOO (725.4)
(fE3) 572 (14.5) >lOOO (725.4)
$8) 431 (10.9) 71000 (725.4)
(EO) 424 (10.8) 71000 (725.4)
(K5) 687 (17.4)
(A!28) >lOOO (B25.4)
180 (4.57)
(continued)
Ferrous Alloys TABLE 4.5: IRON ALLOY-CABOT WROUGHT PRODUCTS (continued)
425
NITRIC ACID 10%

Room 150 deg. F (66 deg. C) Boiling Nil Nil
20%
Nil Nil 0.8 (0.02)
30%
Nil Nil 2.0 (0.05)
40%
Nil 0.1 (<O.Ol) 4.0 (0.10)
50%
Nil 0.3 (CO.01) 6.0 (0.15)
60%
Nil 0.4 (0.01)
65%
-
70%
Nil 0.8 (0.02)
(<od%l)
(O!&
(01320)
$6)
PHOSPHORIC ACID 10%

Room 150 deg. F (66 deg. C) Boiling / Nil
HYDROFLUORIC ACID 65%

5%
SODIUM HYDROXIDE
30%
50%
25%
45%
Nil
Nil
Nil
1 &?3,
1(iii[z
Nil
(<KY)
I (CYOl, I I (<oo:bl,
(&Ol) 0.3 (CO.01) 3.0 (0.08) 303 (7.70)
TABLE 4.6:
IRON ALLOYS-CABOT
STELLITE
DIVISION
The TRISTELLE alloys were designed to resist corrosion and all forms of wear. In particular, they were developed to withstand galling, the gross damage commonly encountered in metal-to-metal sliding systems. By virtue of their excellent resistance to cavitation erosion, they are particularly recommended for valve service.
Compositions
Fe TRISTELLE TRISTELLE TRISTELLE alloy TS-1 alloy TS-2 alloy TS-3 Bal Bal Bal
Cr 30
Ni 10
co 12
Si 5
C 1 2
Resistance to Corrosion
The following immersion test results relate to multilayer undiluted gas tungsten arc deposits. N/L represents an initial corrosion rate of greater than 50 mpy (1.27 mm/year) and a steady state corrosion rate of less than 5 mpy (0.13 mm/year).
30%CH&OOH Boilina TRISTELLE TRISTELLE TRISTELLE STELLITE STELLITE alloy TS-1 alloy TS-2 alloy TS-3 alloy No. 1 alloy No. 6 E U U G E
50%H,POd 66C E E U E E
65%HNOs 66C E G S
5%H2SOd 66C E N/L U E E
E = < 5 mpy (-c 0.13 mm/year) G = 5-20 mpy (0.13 - 0.51 mm/year)
S = 20-50 mpy (0.51 - 1.27 mm/year) U = > 50 mpy (> 1.27 mm/year)
426
TABLE
4.7:
IRON-
AND
NICKEL-BASE
ALLOYS-STAINLESS
FOUNDRY
& ENGINEERING
Corrosion
in Pulp and Paper Industry
Specialty
Alloy Designation
Alloys
Description
Erosion-Corrosion
in
Causticized
Liquor Metal Lolr Due To
CFBM Modified
IlllUM
,...,.__.,..,___.._._ ..Cast CN-7M (Alloy 20)
316
Alloy
Alloy
Specimen Before
Weight
fgmsl After
Erosion-Corrosion IRok Factor1
CFEM (316) Alloy Alloy Alloy Modified ILLIUM CN-7M ILLIUM IltlUM P (S-20) PD 98 CN-7M
30.3667 32.1459 29.7435 31.4510 29.8805 32.5120
30.3646 32.1437 29.7420 31.4491 29.8793 32.5109
0.65 0.57 0.41 0.37 0.31 0.27
P ,_..______.________.Base Cr-Ni-Cu Fe PD _._._______,,..___ Base Cr-Ni-Co Fe 98 .._.....___.,,__. Ni Base Cr-Mo-Cu
ILLIUM ILLIUM
Hardwood
Spent
Sulfite
liquor
from
Digester
Typical Specific Gravity (25C)
Analysis ..... . ............ 1 .048 .2.3 - 3.0 4.52% 0.18%

5.95%
pH ................................................... Co0 MgO Total Acetic ................................................ ................................................

Sulfur
on Solids
Erosion-Corrosion
in
Hardwood
Weight
Spent
fgmsl After
Sulfite
Liquors
Specimen All0y Before
Metal Losr Due To

Erosion-Corrosion IRate Fadorl
( '/.
Sl
..........................
Acid
...................................... ......................................
6.37% 1.26%
ILLIUM ILLIUM Modified
98 PD CN-7M
32.2792 29.8990 32.1 B 17
32.2789 29.8944 32.1722
0.51 0.82 1.73
Formic Acid OCH
................................................. 8.74%
Sugars Sulfur ............................. .25.00% 4.60%
Reducing Sulfonic
1 % Sl ......................
(Alloy 20)
Corrosion Boiling A 65% Nitric Acid Tests:
Resistance of ILLIUM
PD
Food Acids:
solution of boiling nitric acid test revealed PD is up to 10 times more resistant 316 PD (316) stainless steel Test results than
Tests cellent
conducted resistance
in boiling to attack
vinegar
and
mayonex-
that ILLIUM to attack were: ILLIUM CF-8M
naise demonstrate
that ILLIUM
PD exhibits
from food products.
1 to 1.8 mills per year 11.7 mills per year

Fluosilicic Acid:
Food processcrs severe corrosive

Sea Water and Salt Spray:
are becoming Fluosilicic A 25% ILLIUM
more aware of the chemicals and of these
nature of cleaning solution PD
disinfectants. B117 salt spray for the corrosive mills tests conducted resulted
acid is typical CF-8M
ILLIUM test.
PD passes the ASTM
agents.
of fluosilicic
Sea water corrosion

attack
acid at 125 F corrodes per year. corrosion rate of 0.25
at a rate of 500 has a measured
U. S. Navy at Portsmouth of corrosive to 75,000 psi for a period
in no evidence
on specimens
stressed at 55,000
mills per year.
of six months.
(continued)
Ferrous
Alloys
427
TABLE
4.7:
IRON-
AND
NICKEL-BASE
ALLOYS-STAINLESS
FOUNDRY
81 ENGINEERING
(continued)
Corrosion
in Phosphoric
Acid
Industry
Analysis
of Discharge Acid
Product
from
Phosphoric
Reactor Amount Present (percent by weight) RANGE 47-49% 1-2 to to % 5% 40%
MATERIAL Phosphoric Fluorine Sulfuric Solids Acid
AVERAGE 48% 1% l-2%
Compounds Acid
Measured Reactor
Corrosion Product
Rate of Alloys F
in
at 180
MATERIAL ILLIUM lnconel ILLIUM ILLIUM 98 625 P W
CORROSION
RATE 0.5 1.2 1.9 2.9 9.1
MPY
lnconel825 Carpenter Durimet 20 20
10.1 53.7
Alloy
Performance
in Phosphoric
Acid
Evaporator
(71% Phosphoric
Acid at 44OF)
MATERIAL
MEASURED
CORROSION IPY
RATE
ILLIUM ILLIUM ILLIUM 316 317 316 316L
98 G P
.0066 .0109 .028 .067 ,079 ,131 ,160
(sensitized) (3.3 MO) (2.6 MO) (2.2 MO)
428
TABLE 4.8:
STAINLESS
STEEL-ARMCO
STAINLESS
STEEL PRODUCTS
Armco NITRONIC 50 Stainless Steel provides a combination of corrosion resistance and strength. This austenitic stainless steel has corrosion resistance greater than that provided by Types 316, 316L, 317 and even 317L. plus approximately twice the yield strength at room temperature. In addition, Armco NITRONIC 50 has very good mechanical properties at both elevated and sub-zero temperatures. This is the material for equipment requiring excellent corrosion resistance-including that in which Types 316 and 316L stainless steels are marginal. NITRONIC 50 is an effective material for the petroleum, petrochemical, chemical, pulp and paper, textile, food processing and marine industries. Components using the combination of excellent corrosion resistance and high strength currently include pumps, valves and fittings; fasteners, cables, chains, screens and wire cloth; marine hardware, boat shafting, heat exchanger parts, springs and photographic equipment. A wide range of additional applications is made possible by high strength and toughness at sub-zero temperatures, low magnetic permeability even after severe cold working or exposure to sub-zero temperatures, and excellent mechanical properties at temperatures up to 1200 F (649C).
%
Carbon Manganese Phosphorus Sulfur Silicon Chromium .06 max 4.00/6.00 0.040 max 0.030 max 1 .OOmax 20.50/23.50
Composition
Nickel Molybdenum Nitrogen Columbium Vanadium
%
11.50/13.50 1.50/3.00 .20/.40 .l o/.30 .l o/.30
CorrosionResistance
Corrosion Rates in Inches per Year (IPY) Unless Otherwise Indicatedu) NITRONIC 50 Bar
Test Medium Annealed 1950 F (1066 C) NITRONIC 50 Bar Annealed 2050 F (1121 C) NITRONIC 50 High-Strength (HS) Bar Types 316 & 316L Annealed Bar Types 317 & 317L Annealed Bar -
10% FeCls, 25 C-plain(*) 10% FeCls, 25 C-creviced(*) 1% 2% 5% 10% 20% 1% 2% 5% 10% 20% H2S04, H2S04, H2S04, H2S04, H2S04, HzS04, HaS04, HzS04, HzS04, HaS04, 80 80 80 80 80 C C C C C
<.OOl g/in* <.OOl g/in* <.OOl <.OOl <.OOl .194
<.OOl g/in* <.OOl g/in* <.OOl <.OOl <.OOl 0.028 0.133 0.027 0.064 0.131 0.356 1.64 <.OOl <.OOl <.OOl 0.439
<.OOl g/in* <.OOl g/in* <.OOl <.OOl <.OOl 0.296 <.OOl 0.027 0.239 0.452
.Oll g/in* .186 g/in* 0.002 0.011 0.060 0.10 0.48 0.12 0.26 0.73 2.20 0.012 0.021 0.012 0.202 <.OOl 0.027 0.034 0.064 0.442
<.OOl <.OOl 0.036 0.049 0.155 0.013 0.027 0.093 0.465 1.30 0.002 0.023 0.148 0.263 0.012 0.201 <.OOl -
Boiling Boiling Boiling Boiling Boiling
1% HCI,35C 2% HCI, 35 C 1% HCI,80C 2% HCI,80C 65% HNOs, Boiling 70% HsP04, Boiling 33% Acetic Acid, Boiling 20% Formic Acid, Boiling 40% Formic Acid, Boiling 10% HN03 + 1% HF, 35 C 10% HNOs + 1% HF,80C
<.OOl 0.024 0.010 0.203 <.OOl -
ft)lmmersion tests performed on W dia. x % (15.9 x 15.9 mm) long machined cylinders. Results are average of five 48-hour periods. Specimens tested at 35 C and 813 C were intentionally activated for third, fourth, and fifth periods. Where both active and passive conditions occurred, only active rates are shown. MExposure for 50 hours with rubber bands on some specimens to produce crevices.
Ferrous
Alloys
429
TABLE 4.9:
VARIOUS
DUPLEX
AND AUSTENITIC
STAINLESS
STEELS-CLIMAX
MOLYBDENUM
Chemlcsl Analyses of Stainless Steels Studied. wt X Stainless Steel Type SK?
C 0.004
N 0.018
Si 0.24
Mll 0.34
P 0.005
Cr
Ni 10.93
Ho 1.89
CU -
Others Ti-0.54
0.012 25.51
s13
0.004
0.011 0.12* 0.14
0.30 0.43 0.34 -
0.35 0.88 0.65
0.005 0.015
0.014 25.18 0.012 25.02
10.35 6.91
2.91 3.07
1.04 0.64 -
Ti-0.48 w-o.11 __
DP-3
0.018
SAF 2205 FBRRALIDI@ alloy 255 VEW A905 T304 T316
0.012
0.017 '-0.003 22.13
5.70
3.05
0.019* 0.20* 0.034* 0.36* 0.068 0.03 -
5.8 1.07 0.007 -
26.00* 26
5.52* 3.7 9.25
3.33* 2.3 0.24
1.73* <0.1* 0.16
-__ __
0.52
0.014 18.29 0.014 17.2 0.005 20.5
0.052
0.43
1.58
0.017
11.2 25.10
2.2 4.40
__
55700
0.036
0.032
0.32
1.77
0.020
0.28
Nb-0.32
* Analyzed at Climax Research Laboratory FERRALIDM is a rqistered trademark of Bonar Langley Alloys, Ltd. VBW A905 Is a trademark of Vereinlgte Edelstahlwerke SAF 2205 is a trademark of Sandvikens Jeroverks Aktiebolag DP-3 is s trademark of Sumitomo Metal Industries. Ltd. X700 is a trademark of Jessop Steel Company 512 and 513 ere trademarks of Nisshio Steel Co., Ltd.
Critical Crevice Corrosion Temperature for the Duplex and some Austenitlc Stainless Steels in 10% FeClj.6H20 (pH 1)" Stainless Steel TYPO Highest Temperature of No Crevice Corrosion 'C Lowest Temperature of crevice Corrosion QC
s12 s13 DP-3
2.5, 2.5 0, 0, 2.5
7.5, 7.5 2.5
10, 10 17.5, 17.5
12.5. 12.5 20, 20
SAF 2205
VEW A905
17.5, 17.5
20, 20
FEP..RALI& alloy 255 T304
22.5, 22.5 -_
25, 25 -2.5, -2.5
T316
__
-2.5, -2.5
JS700
*Based on oneday exposure tests.
10, 10
12.5, 12.5 (continued)
430
TABLE 4.9:
VARIOUS
DUPLEX
AND AUSTENITIC
STAINLESS
STEELS-CLIMAX
MOLYBDENUM
(contd)
Corrosion Rates and Deepest Penetration In the Creviced Area for Duplex and Austenitic T304, T316 end JS700 Stainless Steels in Dilute Chloride (600 pprcCl-, 5 ppm Cu++, 02) Solution at 90C (194'F), One Week Exposure Deepest Penetration in Creviced Area, microns NAB, 47
Stainless Steel TYPO s12
Corrosion Rate rngdm-=/day 0.0, 0.1
Remarks some etched E.pots pits, rust spots -
513
4.1, 1.9
49, NMPb
DP-3
0.0, 0.0
NA, NA
SAF 2205
0.2, 0.3
28. 39
etched spots, small pits
VEW A905
0.8,
0.9
39, 32
small pits, discoloration __
FERRALIti alloy 255 T304
0.1, 0.1 33, 28
NA, NA
206, 77
numerolls pits, etched spots
T316
7.7, 0.9
175, NMP
pits. etched spots, rust spots -
JS700
0.1, 0.1
NA, NA
NA
no attack
bNMP-
no measurable penetration
Pitting Potentials for the Duplex Stainless Steels and T316 and 55700 in M NaCl Stainless Steel Type s12 s13 pitting Potential Volts 50C 60C 0.100, 0.100 0.120, 0.120 __ __
EDX Analysis of Austenitic and Ferritic Phases of the Duplex Stainless Steels
SegregationRatio
Stainless Steel TYPO s12 % in Ferrite/% in Austenite CT Ni MO Other
1.41
0.56
1.03
--
DP-3
0.320, 0.280, 0.240 Average 0.280 0.360, 0.320 Average 0.340 0.400, 0.340 Average 0.370
-s13 1.42 0.50 2.34 __
SAF 2205
-_ DP-3 1.29 0.43 2.39 --
VEW A905
__ SAF 2205 1.22 0.52 1.86 --
FERRALIlJt@ alloy 255
No pitting
0.080, 0.140 Average 0.110 VEW A905 1.11 0.6 2.53 0.8 (Mn) __ FERRALIIJM@ alloy 255 1.17 0.65 2.61 0.54 (Cu)
T316
0.060, 0.060
55700
No pitting
0.420
Ferrous
Alloys
431
TABLE 4.10:
VARIOUS
STAINLESS
STEELS-AMERICAN
IRON AND STEEL INSTITUTE
Relative
Corrosion
Resistance
of AISI Stainless
Steels
Chemical Salt Water Mild Oxidizing Reducing
TYPE Number
UNS Number
Mild Atmospheric and Fresh Water
Atmospheric industrial Marine
201 202 205 301 302 3028 303 303 Se 304 304L 304N 305 306 309 309s 310 310s 314 316 316F 316L 316N 317 317L 321 329 330 347 346 364 403 405 409 410 414 416 416 Se 420 420F 422 429 430 430F 430F Se 431 434 436 440A 4408 44oc 442 446
(S20100) (S20200) (S20500) (S30100) (S30200) (S30215) (S30300) (S.30323) (S30400) (530403) (530430) (S30451) (S30500) (s30800) (530900) (S30908) (S31000) (S31006) (S31400) (S31600) (S31620) (531603) (S31651) (S31700) (531703) (S32100) (S32900) (N06330) (S34700) (S34800) (538400) (540300) (S40500) (S40900) (S41000) (541400) (541600) (S41623) (S42000) (542020) (S42200) (S42900) (S43000) (S43020) (S43023) (543100) (543400) (S43600) (544002) (S44003) (S44004) (S44200) (S44600) (S13800) (S15500) (S17400) (Sl7700) lndlcale that a speck Stainless
x
x
x x x
x x
x
x x x
x
x
x
x x
x x x
x x
x x
x
x
x x
x x
x
x x
x
x x
x
x x x x x x x x x x x
x
x x x x x x x
x
x x x x
x
x
x
x x x x x
x x
x x
x
x x
x x
x x
x x
x
x
x x x
x
x
x x
x x
x x
x x x
x x
x
x x
x
x
x x
x
x
x
x x x x
x x x x x
x
x
x x
x x
x
x x
x
x
x x
x
Y
x x x
x x x
x x
x
x
x
x
x
x
x
x
Y
x x
x
The X nolallons *Steel Products
statnless steel type may be considered as reslstant to the corroswe enwonment Steels, December 1974, American Iron and Steel Institute,
categories. Washington,D.C.
Manual
and Heat Resisting
(continued)
432
Corrosion Resistant Materials Handbook IRON AND STEEL INSTITUTE

Where Different Grades
TABLE 4.10: VARIOUS STAINLESS STEELS-AMERICAN

Relative
Envrronment Acids Hydrochloric acid
(continued)
Corrosion
Resistance
of AlSl Stainless
Steels
Are Used*
Grades Stainless generally is not recommended except when solutcons are very dilute and at room temperature. There is usually no appreciable attack on Type 304 or 316 as long as sufficient nitric acid is present. Type 304L or 430 is used. Type 304 is satisfactory for storing cold phosphoric acid up to 85% and for handling concentrations up to 5% in some unit processes of manufacture. Type 316 is more resistant and is generally used for storing and manufacture if the fluorine content is not too high. Type 317 is somewhat more resistant than Type 316. At concentrations up to 85%, the metal temperature should not exceed 212 F I100 Cl with Type 316 and slightly higher with Type 317. Oxidizing ions inhibit attack and other inlubitors such as arsenic may be added. Type 304 can be used at room temperature for concentrations over 80%. Type 316 can be used in contact with sulfuric acid up to 10% at temperatures up to 120 F (50 C) if the solutions are aerated: the attack is greater in airfree solutions. Type 317 may be used at temperatures as high as 150 F (65 Cl with up to 5% concentration. The presence of other materials may markedly change the corrosion rate. As lrttle as 500 to 2000 ppm of cupric ions make it possible to use Type 304 in hot solutions of moderate concentration. Other additives may have the op posite effect. Type 304 may be subject to pitting, particularly if some sulfuric acid is present. Type 316 is usable at moderate concentrations and temperatures. Steels in the 300 series generally have good corrosion resrstance at virtually all concentrations and temperatures in weak bases, such as ammonium hydroxide. In stronger bases, such as sodium hy droxide, there may be some attack, cracking or etching in more concentrated solutions and at high. er temperatures. Commercial purdy caustic solutions may contain chlorides, which will accentuate any attack and may cause pitting of Type 316 as well Type 304. Acetic acid is seldom pure in chemical plants but generally includes numerous and varied minor constituents. Type 304 is used for a wade variety of equipment including stills, base heaters, holding tanks, heat exchangers, pipelines, valves and pumps for concentrations up to 99% at temperatures up to about 120 F (50 0. Type 304 is also satisfactory for contact with 100% acetic acid vapors, and-if small amounts of turbidity or color prckup can be tolerated-for room temperature storage of glacial acetic acid. Types 316 and 317 have the broadest range of usefulness, especially if formic acid is also present or if solutions are unaerated. Type 316 is Steel and the Chemical Industry, Climax
Environment
Grades used for fractionating equipment, for 30 to 99% concentrations where Type 304 cannot be used, for storage vessels, pumps and process equipment handling glacial acetic acid, which would be drscolored by Type 304. Type 316 is likewise applicable for parts having temperatures above 120 F (50 Cl, for dilute vapors and high pressures. Type 317 has somewhat greater corrosion resrstance than Type 316 under severely corrosive conditions. None of the stainless steels has adequate corrosion resistante to glacial acetic act@ at the boding temperature or at superheated vapor temperatures.
Mixed acids Nitric acid Phosphoricacid
Aldehydes Amines Cellulose acetate
Type 304 is generally satisfactory. Type 316 is usually preferred to Type 304. Type 304 is satisfactory for low temperatures, but Type 316 or Type 317 is needed for high tempera. tures. Type 304 is generally acceptable at moderate temperatures, but Type 316 is resistant to all concen. trations at temperatures up to boding. From the corrosion standpoint, esters are cornpar. able with organic acids. Up to about 300 F (150 C), Type 304 is resistant to fats and fatty acids, but Type 316 is needed at 300 to 500 F (150 to 260 C) and Type 317 at higher temperatures. Type 316 may be needed if exact color and lack of contamination are important. Type 316 is usually used for reactors, fractionating columns, traps, baffles, caps and piping. Type 304 is used for parts such as spray towers, but Type 316 may be preferred for spray nozzles and flake-drying belts to minimize offcolor product. Type 316 is used for preheat, piping, pumps and reactors in catalytic hydrogenation of fatty acids to give salts of sulfonated high molecular alcohols. Type 304 has only limited usage in tall-oil distillation service. High.rosin-acid streams can be handled by Type 316L with a minimum molybdenum content of 2.75%. Type 316 can also be used in the more corrosive high-fattyacid streams at temperatures up to 475 (245 Cl, but Type 317 will probably be required at higher temperatures. Tar distillation equipment is almost all Type 316 because coal tar has a high chloride content; Type 304 does not have adequate resistance to pittmg. Type 316L is generally required. Type 316 is usually selected for all parts in contact with the product because of its inherent corrosion resistance and greater assurance of product purity. Company, 1966, Greenwich,
Sulfuric acid
Citric, formic and tartaric acids Esters Fatty acids
Paint vehicles Phthalic anhydride
Sulfurous acid
Bases Ammonium hydroxide, sodnrm hydroxide, caustic: solutions
Soaps
Synthetic detergents Tail oil ipulp and paper industry)
Organics Acetic acid
Tar
Urea
Pharma
ceuticals
*Stainless
Molybdenum
CT.
CORROSION
RATES OF STAINLESS
STEELS IN FLUE GASES
(EXPOSURE
3 MONTHS)**
~~~
*Pitted
specimens-average White, Materials
pit depth. Protection, 2 (1963).
t Specimens 47.
destroyed.
l *W.F.
Ferrous
Alto ys
433
TABLE 4.11:
VARIOUS
STAINLESS
STEELS-CARPENTER
TECHNOLOGY
CORROSION
RESISTANCE
TABLE
This table shows the resistance of a number of materials to the more common chemicals. Many factors influence the resistance of materials lo various solutions. Factors which must be given consideration for service in corrosive environments are: temperature, concentration, aeration, influence fluence quency of inhibiting or accelerating contaminants. of recirculation, solids in suspension, velocity, of use, and equipment design. The corrosion infredata 350 662
CODE
l
0
0 X
Corrosion Rote less than 0.002 Corrosion RON less than 0.020
per year per ycor per year
Corrosion Rote lrom 0.020 to 0.050
Corrosion RON greotcr than 0.050 par year

20 40 60 80 100
for all grades except Carpenter 20Cb3 are reprinted from Corrosion Data Survey, 1967 and 1974 Editions, published by the National Association of Corrosion Engineers. The corrosion rates for Carpenter 20Cb-3 stainless represent a composite of the NACE Corrosion Data Survey and more current data developed in Carpenters Corrosion Laboratory.
The influence of contaminants is probably the most important from a commercial standpoint. Corrosive solutions are
300--250 462
212---175 150--125 257 347
seldom found that will be free of all contaminants. However, the majority of these contaminants have no influence on corrosion, the conditions greatly. When reviewing these but the ones corrosion that do generally affect
tables,
it is good to keep
the following in mind
:
to mild atmospheres.
100 212 _-------_____.__._ _-_- ____. ______.___________ _.__ ____ _____ _ _____
75 167 430 is resistant to industrial at50--to food processing and 25 77
20
Stainless Type 410 is resistant

Stainless Type mospheres.
Stainless Type 304 is resistant mild corrodents.
40
I
in Water
1ou
Stainless Type 316 is resistant to chemicals. 20Cb-3 stainless is resistant to severe corrodents.
Percent Concentration
Footnotes
1 2 3 4 5 6 7 a 9 10 11 12 13 14 15 16 17 16 19 20 21 22 23 24
for Corrosives
Toxic
Explosrve Flammable lhgestlon p&on Inhalant poison Attacks skm lrntant Vaoor harmful lgmtes orgamcs Fummg liquid Hygroscoplc Ltberates I-ICI in water Narcotic Volatrle Hazardous under pressure lgmtes combustrbles Fire hazard Exolosrve over 70% lgnrtes m morst arr at 30C Exothermrc m water Dust explodes Explosve dust Exothermic with water
Footnotes for Data Squares

1 2 3 4 5 No water No arr. oxygen Low arr. oxygen Pits Stress cracks
6 7 6 9 10 11 12 13 14 15 16 17 16 19 20 21 22 23 24 25 26 27 26 29 30 31 32 33 34 35 36 37 36 39 40
Stress corrosion Drscolors Crevrce attack Intergranular attack No chlorides May discolor May catalyze May prl May stress crack Transgranular attack Vapor Aerated Catalyzes Static Agitated -7 pH <7 pH >7 pi-i No HCI. H&O+ NaCl No ferric chloride -0.1% acetic acid Also sludge No iron salts No sulfuric acid Explosive With HzSO4 With steam No sulfur No stress No ammonia 300 psi Stress relieved No HCI. Cu. Ni ions No Cu, Fe ions Over 70% air
41 42 43 44 46 46 47 46 49 50 51 52 53 54 65 56 67 56 59 60 61 62 63 64 65 66 67 66 69 70 71 72 73 74
20-70% air, 530 psi With sulfur, <340X=x <IO mgil No HzSOI ~60 psi No sulfides <20% zmc Trace HCI pH2t03.5 Annealed, immersed >2.25% MO Erratrc With NaCl With NaCI. HCI. Hz02 No Fe, Cl With +-0.051% HaPOd or HISOI +SOz or HCOOH <RC 22. 60.000 Annealed No cold work No HnS Permeable to HZ Unsulfaled With or without 240 psi Cold worked X30% copper >20% sulfuric, bat nitric acid No MO; low C Red fummg Pits in chlorides Over 400C Steam and air 75-100% concentration
76 76 77 76 79 60 61 62 63 84 65 66 67 66 69 99 91 92 93 94
Low NaCl Wrth HCI <17% zmc ~0.23%. 200 psi 300 psi No SO3 No NaCl High pressure 75-120 psi No sodium sulfite +ammonia Avoid hydroxides Saturated Not wood No free acid Passivated <0.03% water Attacks stress zones near weld pH>12 >15 psig
:: :.oS??d pH 97 >200 ppm water :g ;t3sp;hen wet
(continued)
434
Corrosion Resistant Materials Handbook VARIOUS STAINLESS STEELS-CARPENTER TECHNOLOGY
TABLE 4.11:
(continued)
Acetic Acld vapor
Acelic AnhydrIde In Acebc Acid 4.7 9
Aluminum Chloride
Ammonium Carbonate
I I
I ,
I I
(continued)
Ferrous
Alloys
TABLE 4.11:
VARIOUS
STAINLESS
STEELS-CARPENTER
TECHNOLOGY
(contmued)
Formic Acld
GCilllC Acid
(continued)
436
TABLE 4.11:
VARIOUS
STAINLESS
STEELS-CARPENTER
TECHNOLOGY
(continued)
iydrogen Peroxide
iydrogen Sulfide Dry 1.4 Lactic Acid
(continued)
Ferrous Alloys TABLE 4.11: VARIOUS STAINLESS STEELS-CARPENTER TECHNOLOGY
437
(continued
Phthalic inhydride
I I I Potassium Carbonate
! ! ! I
Nitrous Acids
Perchloric Acid
Perchloroethylene
Phenol
(continued)
438
Corrosion Resistant Materials Handbook VARIOUS STAINLESS STEELS-CARPENTER TECHNOLOGY (continued)
TABLE 4.11:
olassium kmanganate 4. 10
eroxide
Dtassium Sullate
Pyridme
#ichroma 5 Sodium Bisulfate
El3
71 -t-.
P-u
e _._ _L
0
-7
Ferrous
A llo ys
439
TABLE 4.11:
VARIOUS
STAINLESS
STEELS-CARPENTER
TECHNOLOGY
(contmucd)
1 c
T L
T ml
T I
T I
440
TABLE 4.12:
VARIOUS
STAINLESS
STEELS-CYCLOPS
UNILOY Type 410: hardenable martensitic stainless steel UN I LOY Type 430: nonhardenable ferritic stainless steel UN I LOY Type 304 and 316: austenitic stainless steel CORROSION
MEDIA CONCENTRATION
DATA
TYPE 410 TYPE 430 I TYPE 304 TYPE 316
OP.
70 70 Boiling 60 Boilmg 70 Boiling 70 Boiling 70
Acetic
Acid
5% Aerated 10% Aerated 10% 60% 60% 100% 100%
II IV IV IV IV IV IV III IV I II II II II IV IV IV III IV IV -I II II IV ~___ I II -___ II IV III IV IV -___ II III III II I II III I -.__ -__
I I I I II I II II ____ IV I II II I I I II II IV IV IV II II III III IV II II I I I
II II III Ill III III III IV
Acetic Anhydride
90% Anhydride 90%
Acetylene Alcohol Ethyl Methyl --~_~~__ Aluminum Acetate 20% 20% Aluminum Chloride 5% 25% Aluminum Aluminum Sulphate Aluminum Ammonia Ammonium Carbonate _ Ammonium Ammonium Ammonium Ammonium Chloride Hydroxide Nitrate Perchlorate All concentrations 10% 10% Ammonium Sulphate _ Ammonium Aniline Barium Beer Benzoic Blood Boric Acid 10% Saturated Acid 10% Chloride Sulphite Concentrated 10% 10% 10% 1% 5% 10% Fluoride Potassium (Alum) Sulphate 5% 10% 10% 10%
I
II II II II IV IV IV III IV IV I II II IV
70 70 70 Boiling -___ 70 70 70 70 Boiling 70 -___ 70 70 70 Boiling ___. 70 70 70 Boiling 70 Boiling 70 70 70 70 70 70 70 Boiling 70
IV
II _ I
I
I II IV III IV IV II II III II I II III I I ~II II II II III II II I
I II II II II II II II I
II I I
II I
Buttermilk I-Very Good II-Good Ill-Fair IV-Poor
(continued)
Ferrous
Alloys
441
TABLE 4.12:
VARIOUS
STAINLESS
STEELS-CYCLOPS
(continued)
MEDIA
C ONCENTRATION -10% 10%
OF.
TVPE 4to
TYPE 430 III III
TYPE 304 II
TYPE 3t6 II
Hutyric
Acid
70 Bolllng 70 70 70 70
III III II II II II
II
I
II
I
Calcium Calcium Cane
Carbonate Chloride
10% 10%
I
III II II
II I II
II I II
Juice
~~ ~~___~~~
Acid Dioxide Acid Acid Acid (Dry)
Sugar Cane C.P.
Carbolic Carbon Carbonic
_~_
All concentrations 10% C.P. 50% C.P.
70 70 70 70 70 70 II IV III IV II IV III IV IV II IV II IV II III II -T,- IV II IV II II II II II IV II IV II II II II II II --
Chlor:wetic Chromic
Citric
Acid
10% 10% 50% 50%
Boiling 70 Boiling 70
.__
Copper
Chloride Chloride)
10%
(Cupric Copper
IV I IV
II I I
I
I
IV
I
Nitrate Nitrate)
10%
70
II
(Cupric Copper
Sulphate Sulphate) Oil
10% 10%
70 Boiling 70
II III I IV I I I I I
(Cupric Cottonseed Epsom
Salt Sulphate)
10%
70
(Magnesium Ethylene Fatty Ferric Ferric Glycol
___
All concentrations 100% 10% 10% _ ._ 50% 10% 50% 70 70 70 70 70 70 70 ~. I II IV II II II II IV 70 70 70 HIS 70 .-__ II II IV Ill I I IV IV II --.--- III ---! -;I_ II +w IV II II II II
Acids Chloride Nitrate
II IV II II II
II
IV II II II II _
Ferric
Sulphate
Fluorine
(Gas)
.__
100% .__ 40% _ 10% 50% Containing Refined
~_
Formaldehyde Formic Acid
II
_._
70 70 70 70
Glue Hydrobromic Hydrochloric Acid Acid
Dry All concentrations All concentrations
I-Very
Good
II-Good
Ill-Fair
IV-Poor
(continued)
442
TABLE 4.12:
VARIOUS
STAINLESS
STEELS-CYCLOPS
(continued)
MEDIA
CONCENTRATION 10% 10%
OF. 70
TYPE 410
TYPE 430
TYPE 304
TVPE 316
Hydrogen Lactic Acid
Peroxide
II IV II Ill IV II IV II II I J II IV II IV IV IV IV IV II IV II II II II I IV I
II IV II II I II IV II II II II II II II II III IV II II IV II II II II II IV I II II
I II II III I I I I I
70 70 70 70 70 Boiling 70
.._ .__
II II II I
Magnesium Magnesium Magnesium
Carbonate Chloride Sulphate
10% 10% 10% 10% 10%
I
I I I
Molasses Nitric Acid
10% 10%
20%
70 Boiling 70 Boiling 70 Bohg 70 70 Boiling -____ Air Free 70 70 70 70 70 .___ 70 70 70 Boiling
I
II I II I I IV II II II II II II I
I
II I II I
20%
40% 40% 90% 100% 100% __~___ Oxalic Acid Acid 10% 10% Aerated 10% Picric Acid Bichromate Chloride Dichromate Permanganat
I
IV II I II II II I I II II
Phosphoric
All concentrations
Potassium Potassium Potassium Potassium
10% 10% 10% 10% 10%
Propane Silver Nitrate
iooyr
10% 10% 10% 10% 10% 10% 10% 10% 10%
70 Boihng 70 70 70 70 _~____ 70 70 70 70 70 Oils 70 -___
II II I I II II III II II I II --
Sodium _~. Sodium Sodium Sodium Sodium Tannic Tartaric
Bisulphate Hydroxide Nitrite Phosphate Sulphate Acid Acid
I II II II II II I II I ___ II II II II II I II I ~~ II
Turpentine Uric Acid Vegetable
I -Very
Good
II-Good
Ill-Fair
IV-Poor
Ferrous A llo ys
443
TABLE 4.12:
VARIOUS STAINLESS STEELS-CYCLOPS

UNILOY TYPE NO. c ;
P s
(continued)
430 c .12 max Cr 14.00/1i).00
Mn 1.00 Si 1.00 P .040 S *o3o max. max. max max
410 *I5 =& ;d;o;~x*so

*040m==* .030 mar.
304 c .QI mar. cr iS.m/zo.m c

cr
316 .I mar. Hi 11l.W~r4.m

2.m 1111,. 1.m mar. .M5 mu. .030 Ina. 2.m/3.m 16.w~w.m
COMPOSITION Wt. per cent
Si 1100 r&
Ni S.m/io.m t4n 2.m 111.1. Si 1.00 max. P .045 max. 5 .a30 111.
Mn Si P s mo
UNILOY 13-8 Martensitic Stainless Steel UNILOY 13-8, a precipitation hardening, martensitic stainless steel, has high strength, ductility and toughness in large cross sections in both longitudinal and transverse directions.
TYPICAL ANALYSIS
(in weight percent) Carbon . . . . . . . . . . . . . . . . . . . . . . 0.05 Max. Manganese.. . . . . . . . . . . . . . . 0.10 Max. Silicon.. . . . . . . . . . . . . . . . . . . . 0.10 Max. Max. Sulfur.. . . . . . . . . . . . . . . . . . . ...0.008 Phosphorus.. . . . . . . . . . . . . . . .O.OlO Max. Chromium . . . . . . . . . . . . . . . . . . . . 12.25-13.25 Nickel . . . . . . . . . . . . . . . . . . . / . . . . 7.50- 8.50 Molybdenum.. . . . . . . . . . . . . . 2.00- 2.50 1.35 Aluminum.. . . . . . . . . . . . . . . . . . 0.90-
The general corrosion resistance of Uniloy 13-8 is superior to the standard martensitic stainless grades. Much like Uniloy@ 17-4 and Uniloy@ 15-5, this alloys corrosion resistance approaches that of Type 304 stainless steel. The general corrosion resistance is greatest in the fully hardened condition (H 950) and decreases slightly as the aging temperature increases. Uniloy 13-8, the most resistant to stress corrosion cracking of any of the precipitation hardening stainless steels, attains highest resistance at the higher aging temperatures.
UNI LOY
15-5 Martensitic
Stainless Steel
UNILOY@ 15-5, a precipitation hardening stainless steel, offers a broad range of mechanical properties for a variety of applications, particularly those that require high transverse strength and toughness. TYPICAL ANALYSIS (inweight percent) Max. Carbon . . . . . . . . . . . . . . . . . . . . . . . 0.07 Manganese.. . . . . . . . . . . . . . . . . . 1 .OO Max.
Silicon . . . . . . . . . . . . . . . . . . . . . . . . 1.00 Max. Max. Sulfur.. . . . . . . . . . . . . . . . . . . . . . . . 0.03 Phosphorus.. . . . . . . . . . . . . . . . . . 0.04 Max. Chromium.. . . . . . . . . . . . . . . . . . . 14.00-15.50 Nickel . . . . . . . . . . . . . . . . . . . . . . . . 3.50-5.50 Copper.. . . . . . . . . . . . . . . . . . . . . . 2.50 - 4.50 Columbium plus Tantalum.. . . 0.15 - 0.45
Uniloy 15-5 exhibits lower corrosion resistance but higher stress-corrosion cracking resistance. When hardened at H 1025 condition and tested in boiling 65% nitric acid, the corrosion rate is 0.127 inches per year (3.2 mm/year); in 1% hydrochloric acid at 100F (38C) the rate is 0.083 inches per year (2.1 mm/year); exposure in 5% salt fog at 95F (35C) for 10 days results in 0 to 5% rust.
UNI LOY
17-4 Martensitic
Stainless Steel
UNILOY 17-4 is a unique stainless steel. It is martensitic and magnetic, capable of precipitation or age hardening to various levels of hardness and strength. It is normally purchased in the annealed condition and because of its great stability, it can be machined very near finished dimensions prior to heat treatment (900 to 1150).
Carbon ...............
Manganese. ........... Silicon ............... Sulphur. ..............
Uniloy 17-4 has a high resistance to corrosion. It stands up to corrosive attack better than any of the hardenable stainless steels ( martensitic) and is comparable to Type 304. It is used regularly in such industries as chemical processing, dairy, petroleum, food processing, paper and marine.
YYPE ANALYSIS 0.07 Msx. 1.00 Max. . . . . 1.00 Max. . . . . 0.03 Max. . . . . 0.04 Max. . . . . 15.00-17.50 . 3.00- 5.00 . . . 0.15. 0.45 . . 3.00- 5.00 ..
..
PhorphonJr. ...........
Chrome. .............. Nickel ................ Columbium Plus Tantalum. Capper ...............
444
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
Stress Corrosion
Cracking
of
Stainless Steels U Bends in Boiling 42% MgClz

Alloy Type 304 Type 316 Type 430 Type 434 18Cr-2Mo 260-l 260-1 MO Mo-Ti Time to Failure, 8 48 624 NF 1800 NF 1704 1200 2000 2400 NF NF NF NF() hrs Ref
Crevice Corrosion in Oxygen Saturated Chloride Solutions, 90 C

Weight Solution 434 41.0 304 15.0 Loss, (mg/dm2/dayl 316 2.6 18Cr-2Mo 0.2
2 2 2 3 4 5 6 7 8
200 ppm Cl-, 1 ppm Cu* 600 ppm Cl-,
241 .O
11.8
3.5
0.8
l Grwald,R.
F. TAPPI,
Vol. 56, p. 129 (1973).
516 NF()
ZlCr-3Mo-Tic) 28Cr-4Mo
Corrosion ()Specimen ()Nominal was a stressed bolt 45% MgCl2
Rates for Stainless Exposure)
Steels
(24-hour
NF = No Failure
No Activation Corrosion Rate (mpy) 18Cr-2Mo T316 T304 30 0.4 81 73 2.4 110 74 785 1.3 1 .l 2.2 3.0 0.3 0.5 29 0.1 2.2 57 47 7.5 0 1.9 1.6 2.7 0.2 0.2 0.3 34 212 0.2 2.3 20 57(l) 2340 4.4 400 7.6 20 24 personal
Corrosive Medium 20% Acetlc Acid 80% Acetic Acid 20% Citric Acid 30% Formic Acid 45% Formic Acid 20% Lactic Acid 40% Nitric Acid 1% Oxalic Acid 3% Oxalic Acid 10% Oxalic Acid 50% Phosphoric Acid 2% Sulfuric Acid 25% Sodium Hydroxide 35% Sodium Hydroxide 50% Sodium Hydroxide
l
TUlIp. Boiling Boiling Boiling Boiling Boiling Boiling Boiling Boiling Boiling 30 c 100 c 1ooc 100 c Molybdenum
Pitting of Stainless Steels in Oxygen-Saturated N&l Solutions-90 C During 30-Day Exposure

Weight Loss lmg/dm2/day) 434 304 316 18Cr.2Mo 0.4 0 0 ,o 0 0
Solution 3% N&l (18.200 ppm Cl-) 0.1% NaCl (609 ppm Cl-, partial immersionl 1200 ppm Cl-, 400 ppm Cu * 180 ppm Cl-, 60 ppm Cu * 6OOppmCI-. 1 ppm Cu*, 5ppmZn 600 ppm Cl-. 5 ppm Cu* 6OOppm Cl-. 20 ppm Cu * * Steigerwald,
430 46 48
SW 40 -
400 14 4.7
187 5 6.1
183 0.9 0.4
Lizlovs,
E. A. Climax (1973). behavior
Co. of Michigan,
communication (1) Activebssive
24.3 82.5
14 84.4
1.4 9.0
3.3 6.0
Pitting FeC13
Corrosion
in 10%
- 6H2 O at Room Temperature*

Weight-loss (mg/dm2/day) 1250 485 97 0 0 0 0 J. 0.. Dundas, Ii. J. STP No. 425 ASTM, (continued)
Alloy R. F. TAPPI, Vol. 56, p. 129 (1973). 18Cr-ZMo-Ti Type 304 Type 316 22Cr-2Mo 260-l M& 26Cr-1 Mo-Ti 28Cr4Mo Bond, A. P., Marshall,
Philadelphia,
p. 116 (1948).
Ferrous
Alloys
445
TABLE 4.13:
VARIOUS
STAINLESS
STEELS AND HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Crevice Corrosion in 10% FeC13 - 6H20 Result

Alloy Type 304 Type 316 Carpenter 20Cb3 Room Temp. 50 c
10% Acetoc Acid
Comparison of Corrosion Behavior of Ferralium Alloy and Type 316 Stainless Steel*
Corrosion Solution
Rate
(mpyl
Alloy 0.4 6.5
Temperature
Bollmg Bolhng Boilong Boiling Room Boilung
Type
316 0.1 3.1
Ferralium
C C C C R R
20% Formic
Acid Acid Acid
C
R
10% Oxalic 1N Sulfuric 10% FeCll 3% NaCl 3% N&l+
39 2600 640 0.2 1 .o
235 46 25 0.4 0.4
lnconel 600 lnconel 625 Hastelloy 260-l MO Alloy C
20 ppm Cu-
Room
*Ferralium
Alloy,
Preliminary Kokomo,
Data Indiana.
Sheet,
Stellite
Division,
Cabot Corporation,
R R
R Vol. 30, p. 77 (1974).
C
R
Service Performance of an Austenitic-Ferritic
Stainless Steel*
3RE60 P*rf0rlnalU*
28Cr4Mo 28Cr4Mo-2Ni Titanium * Streicher, M. A. Corrosion,
R
R
M~terlal
Application Desaltmg Crude 011 Conditions BOO-900 ppm CIc Type Failed 304
5 years, no attack
pH = 6.7, 75.195
Falled by RreSSCO~rOSlO
C = Crevice Corrosion
R = Resists Crevice Corrosion
Air Cooler Desulfurizauon 5 ppm Cl -, 1000 ppm HIS, 10 ppm NH3 60.140 C Type 316Ti stresscorroslon 6 mo. Type316 Falled by stress-corrosion. 6 mo. 4 years. no corrosion
Pitting Potentials 1M NaCI-25

Alloy Tvpe 304 Type 316 Type 216 Armco JS700 Alloy 6X * Lizlovs, E. A. Climax (1973). Molybdenum 22-13-5
C
V vs
wasteWater
Treatment
5OOOppmH~S.15ppm ClpH=8.30-80 C 90 ppm mercaptan
3.5 years no corrosion
Pitting Potential, -0.030 0.315 NP NP NP NP
SCE
Heat Exchanger, Town Gas
3BO-409 570 psi
Type 321 stres*cOrro*lO 6-12 mo.
18 mo., no attack
Heat Exchanger Chemical Industry
River water 3M)-500 ppm cl-
Type 6 mo.
321
1 year, no attack
str,arscorroslon
Co. of Michigan. _
personal
Coolina Coils River water 300-500 ppm Cl Type 316T1 stresscorrosKl 6.12
l
communication NP = No Pitting
1 war no attack
mo.
Carlen, J. C.,
13.
Helmer,
C. NACE
CORROSION173,
paper
No.
Crevice Corrosion in 10% FeCIa - 6H20 Solution (pH=l)

Corrosion Rate Material Alloy 6X JS-700 Armco 22-13-5 Type 216 Type 316 Type 304 mgldmiday 0 0 1.4 50.8 207 376 Some crevice corrosion Crevice corrosion Severe crevice corrosion, some pitting Severe crevice corrosion, some pitting * Lizlovs, E. A. Climax (1973). Molybdenum Co. of Michigan, personal
10% HzS04 5% HCI 1.08% HCI 10% Oxalic 10% FeC& + 0.1 N HCI
Comparative Corrosion Rates for High Alloys*

Corrosion Rate Impvl IWWn#l Alloy 23 20 625 C
at 25 C
Hast~loy
Remarks
Solution 65% HN03 50% H2S04 41.29/l + Fe2(S04)3HZ0
Tamperature Boiling Bolling
MP35N 37 14
Alloy 440 190
Boiling Soiling Boiling Acid 6H20 Boiling 90 c
38 610 185 9.9 0
21 120 22 8.5 0
7.9 790 140 8.8 -
* Bond,
A.
P. Climax (1970).
Molybdenum
Co. of
Michigan,
Private
communication
communication
[The tables above have been reprinted
from Materials
Performance,
Vol.
13, No. 9, pp. 9-16
(1974)
September.] (continued)
446
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
KEY to special
symbols used in the following table to denote type of test, aeration and agitation during test, specific details of material samples tested and modes of corrosion.
test
Type of lest
F L
field or pilot plant test
Corrosion
Rates
sensitized low carbon grade (0.03% cast welded a b

C
I laboratory
Temperature
R.T. B.P.
: room temperature I boiling

: none
Capital letters in front of corrosionrate figures refer to condrtion of the material tested
C max)
Aeration
x xx
slight pitting (maximum incipient to 0.005 in.)
depth
of pits from depth of pits
; slight to moderate : strong

none slight rapid 302 or Type 304 with the standard maximum material is Carpenter 20; correspond to ACI CN-7M carbon
Alloy 825 Lower-case Iv..ters after corros+onrate frgures refer to observed mode of corrosion where the attach was not uniform
moderate pitting (maximum from 0.005 to 0.010 in.) severe pitting 0.010 in.) crevice attack cell corrosion) stress corrosion
Division.The
Agitation
(maximum (tendency cracking
depth
of pits over
to moderate
d r
to concentration-
xx
Type 304
l
Type
Over
Huntington Company,
Alloy Inc.
Products
International
Nickel
20
Wrought castings
Note:
The compositions the cooperating
of corrosion media reported companies and do not always
are those given by total 100%.
Corrosion mediums
Test conditions
Average corrosion rates (spy)
lPE
7PE
TWE
304 --P-P
316
317
20
ALLOY 825
Rayon 98.97%. water remamder Rayon
F F
142 150
414 234
0001
0 0001 nil <o 0001
99%. water l%, phosphates trace, 99%, 99%. 99.01% 0.07%. 98%. ethylene ethylene
acldlty pH 2.3
as acetlc
acid
0.014%.
Chemical
150
609
rlll
nil
oxide 1% oxide 0.85% methyl formate carbon 0.15% dloxlde
Rayon Chemical Chemrcal
F F F
133 144 150
1645 a37 147
<0.0001
ml rut ml
ethylene oxrde 1.92% krotonaldehyde 0 0% low boilers 2% (secondary
oxrdatron)
Chemical (dlstlllatmni Chemical F F F F 135 140 170 142 623
<o
0001
<0.0001
<o
0001
98%. 95%. 85%.
methyl methyl
formate formate 12%.
2% 3%. methyl acetate 2%
<0.0001 fill 0.0001 <0.0001 <0.0001 <0.0001 ml
Chemical Chemical
805
75
low borlers
acetic
actd 3% ether 5%,
93%. carbon dwde 6%, dlmethyl methyl formate 4%. butane 2%
Rayon
1158
(continued)
Ferrous
Alto ys
447
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hmtd)
Average corrosion rates (ipy)
TPE
TWL
TIM
304 P-PAcefaldshyda mixtures
316
317
20
ALLOY a25
80%. acetic rematnder 75%. 75%, water wyl methyl 0.3%.
acid
8%.
lormlc
acid
0.3%.
water
Chemical
220
357
xx
<0.0001
<0.0001
acetate
20%.
acetlc
acid 5% acetate 10.5%.
Rayon Chemical
f F
239 158
664 805
-~ x
xx x
O 0006
0.0002 ml
0 0002 rlll
formate l4%, methyl acetlc acid 0.2%
70%, 0.5%
acetic
acid
14.5%,
water
15%,
formic
acid
Chemical
210. 215 245
84.5
xx
0.0001
701, acetx remamder 70X, acetlc mamder
acid
14.3%,
lormlc
acid
0.3%,
water
Chemical
169
xx
0.0046a
0.0007
acid
8%.
low
boilers
3%.
water
re-
Chemical
220
100
WI
0 0001
70%. acetone 10%. methyl formate acetate 7X, vmyl acetate 5% 70%. methyl formate 10%. methyl acetone 7%, wnyl acetate 5% 70%. oxldes. acetone. methanol, water 2% acid 12%. higher
8%,
methyl
Chemical
158
133
<o
0001
<0.0001
acetate
8%,
Chemical
190
610
nd
illI
alcohols
and
Chemical
160
349
xx
IllI
50%. acetic remamder 50%. acetlc remamder
low
boders
3%.
water
Chemical
198
246
ml
<0.0001
IllI
acid
10%.
low
bodets
3%,
water
Chemical
198
81
llll
SO%, combmed organxs 45% ketone. methanol, trlmethylene oxide. etcl, sodurn acetate 1000 ppm approximately. formaldehyde 500 ppm approximately. some resmous matter, water 5% 4.5%, 4.5% acetaldol 40%, water 10.15%. high boilers
Chemical
195. 200
265
xx
<0.0001
<0.0001
Chemical
80
1025
rlll
rlll
42%. water 30%. IndIrect acid 4%, acetic acid 0.5% 40%. acetone, together 60% 40%. 60,. methanol,
acidtty
23%.
formic
Chemical
216
510
<0.0001
<0.0001
water
and
ethyl
alcohol
Chemvzal
176
456
<o 0001
x nd a
IllI
acetone. methanol lormaldehyde 2000
and glycol ppm max
together
50.
Research
L
F
176
542
IllI
40%. combmed orgamcs 40% k~cetone, methanol. oxldes etch. lormaldehyde 2000 ppm approw nlately sodwm acetate 1000 ppm approximately. pii 5560 37%. acetone. together 600 water, methanol and ethyl alcohol
Chelnlcal
230
265
xx
._ 0 0001
<0.0001
Chemical
176
456
~-00001
\o
0001
36.92%. water 62%. lormlc ene oxtde 0.01% PH 2.3
acid
1.07%.
propyl.
Chemical
195
II6
--
xx
0 28
0011
35%. water 40%. acetic acid 6% low 5, (methyl formate 20.60%. methanol, acetate and acetone), formic acid 1%
boders methyl
Rayoll
II7
335
xx
0000l1
0 0001
(continued)
448
TABLE 4.13:
VARIOUS
STAINLESS
STEELS AND HIGH NICKEL ALLOYS-CLIMAX
MOLYBDENUM
hntd)
Corrosion mediums
Test conditions r p
TIPE
TPE
TPS
ALLOY
20 825
304 --P-P
35%. water 38%, crotonaldehyde and aldol 24%, phosphoric acid, sodium phosphate Chemlcat F 225 183 xx ml
316
317
nil
35%. water 38%. crotonaldehyde 24%. phos-Chemical phoric acid, sodium phosphate and unidentified 3% : 30% approximately. water 67%, formic acid I Chemical I ll%, methyl lormate and propylene oxide : 29.5%. water 45.4%, crotonaldehyde 21.9%. hexadlene aldehyde 1.3%, butyl butyrate <1.3%, butyric acid <0.6% 20%. acetone 22%. r.butanol 20%, ethanol 15%, isopropanol 10%. water 6%, acetals 3%. acidity 0.5%. n-proponal 0.3%, carbonyls 0.2% 20%. low boilers 3% (methyl lormate. etc), water remainder acetate, methyl F
410
147
nil
nil
210
11.6
0.13
0.003
i : :
Chemical
220
449
xx i
<0.0001
<0.0001
Chemical
jF
150. 230
508
xx
0.0013c
O.OOOla
Chemical
140. 142 126. 140
174
xx
0.0001
0.0001
5%. r-butanol 29%, ethanol 21.9%. isopropanol 17.1%. water 12.6%. carbonyls 4.1%. acetone 3 94%. methanol 3.7%, n.propanol 1.3%, acetals 1%. acidity 0.36%, formic and acetlc acids traces
Chemical
508
xx
xx
<O.OOOla
<0.0001
: i
100%
100.80%
Rayon
;F
F
245 B.P.
756 3.5
; I
0.012
0.00016d <0.0001
<0.0001
100.80% lhalf Immersed)
! Chemical j i lsolvenlsl :
Chemical (solvents)
:F
BP.
3.5
,_
0.0048
<0.0001
100.80% (vapors) 99.98%. water 0.017% 99.98%. water 0.017% 99.9%, C.P. glacial acetic acid 99.9%. water <I% glacial acetlc acid glacial acetlc acid (column) glacial acetic acid glacial acetlc acid glactal acetlc acid (vapors) 99.7% 99.7% 99.7%
Chemical kolventsl Chemical Chemical Research Chemical Research Chemical ~d~st~llat~onl Research Research Synthetic Rubber Research Chemical Chemical
:F
B.P. 224 224
3.5 71 71 5.6 40 7 11 4 6 1 261 xx xx _ _ xx x x:
0.0076
0.00015 0.0042 0.0024 0.0009 0.0004 0.0003 0.0003 c0.0001 0.00084 CO.00036 L IllI III 0.032 0.0002 0.00018 <0.0001
1 F L F L L L F L 1
BP. 222 BP. 8.P BP. B.P. 932 249 244 293
0.027 0.012 0.023 CO.0064 0.0027 0.002
L0.0009 LO.0556
10.00075 0.270 10.0142
(continued)
Ferrous
Alloys
449
TABLE 4.13:
VARIOUS
STAINLESS
STEELS AND HlGH NICKEL ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
11PE
TYPE
IYPE
304
*ca*,c
99.5%
*cd
316
317
20
ALLOY 825
approximately
Icolumn)
Chemical idlstdlation) Chemical
266
51
0 003
0 004
0 0005
99.43%,
water
0 2%
222
28
23
x
x
0.0009a
0 00046
99.43%,
water
0.03%
Chemical
222
0.0012
0.00021
99%.
water
1%
RayOIl
235
266
xx
0.066c
0.0004
0.0004
0.0004
99%
Ivaporsl
Chemical Isolvents)
212. 249
a2
0.0025
99.99%
Chemical
244
625
xx
x -
0 Ol8a
0.0003
0 0003
99%.
water
2%
Plastlc
73. 112
157
-;0.0001 .-!I 006
ml
0 0001
99%
Chemical
128
51
0 0074
0.002 so 004 /
00012
0 002
97%
approximately
(column)
Chemical (dlstdlatlon)
250
51
0 042 r
0.016
0001
0 008
95%
Chemical
240
216
LX
0.055
0012
93%
approximately
kolumnl
Chemical (dlstdlatlon) acetic acld (bottom of Chemical Isolvents) Research Research
240
51
0 066
0 009
0 004
0.005
90%. commercially storage tank) 75% 75% 75% 75% 75% 70% 67%, 50% 50% 50% 50% 35% 30% 30% water 33%
pure
R.T.
13.8
<0.0001 <0.0001 0.033 CO.006 co.001 CO.860 co.007
0.0001
B.P. 285 340 355 395 B.P. 212 223 B.P. B.P. BP. 190 330 230
c<0.0001
L 1
L L
Research Research Research Research Rayon Jewelry Research Research Research Chemrzal Chemical Research
1
F L
377 2 0.25 -
;xx
0.17 0.002 0.0011 x 0.210 0.20 0.0004 0.0001 0.0001 ml C<O.OOl co.001 CO 0018 ml co 0002 0.001 0.0015
1
L L L F L
36.5
(continued)
450
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
hntd)
Corrosion
mediums
Average corrosion
rates (ipy)
TYPE
TYPE
TYPE
ALLOY
-20 825
--Acetic acid
304
316
317
30% 30% 30%

20%
Research Research Research Chemical
L L L L
330 350 370 213
co.010
co.140 CO 160
co.003 co.020 co.210 LO.0035 s0.0002
LO.0018 s0.0001
7 15 7 2 2 51 --. x xx x
10% 10% 10% 10% 10% 10% fcolumnl
Chemical Research Research Research Research Chemical fdlstillatlon) Chemical
L L L L L F
B.P. B.P. B.P. B.P. B.P. 232
0.0699
nil
0.0002 0.049 LO.053 0.0002 SO.00036 LO.0016 LO.0009 0.0003
c0.0001
0.004
5%
213
ACET,C.AC,D MlXTURES ANHYDRIDE
MMTURES
see
.,..a
ACETIC-ACID
WITH FORMlC MIXTURES WI
ACID and ACETICACETIC ACID
99.98%, water 0.017%, sulfur trioxide

99.9X, dichromate water <O.l% 99.9%, dlchromate water <O.l% 99.9%. 99.9%. 99.8%, 99.9%. 99.7%. 99.7%. dichromate prop~oruc prop~oruc prop~on~c water water 2% 2%, added
trace permd,
Chemical Chemical
F F
224 222
25 18 -
xx x
0.0033 0.0039a
0.0013 0.0024a
over one 24.hour
added
over one 24.hour
period.
Chemical
222
13
xx
0.0013
0.001
and permanganate acid and water acid aMwater actd and water manganese manganese traces traces traces
added
Chemical Chem!cal Chemical Chemical
F F F F F
251 245 245 245 253 248 255
31 36 50 93 29 40 21 -
xx
0.5a 0.06r : 0.082
0.02 O.OOBr 0.03 0.03r 0.001 0 0008 0.0026 0.0002 0 0005 0.004 0 025
acetate acetate
0.1% 0.1% and n-butync
Chemical Chenwal Chemical
(x
0.0008
0.0007
F
F
xx
xx 0.0058
99.7%. prop+omc acid. acids traces (column) 99.6%. water some chromate 99.5%. vapors1 waler 03.0.4%. added 0 45%.
isobutyrk
0.0005
acetaldehyde
0.02%,
Chemical
216
106
xx
0.00032
0.0001
sallcylates
0 05%
(column,
Pharmaceu tlcal Chemical
234
42.5
xx
0 005*
0.0041
0 003
00022
99.49%. water sulfur trloxlde
0.04%.
mineral
acid
trace,
no
211
25
xx
0.0055b
0.001 la
99.49%. water 0.04%, sullur trloxkde. chromate
mineral added
acid
trace,
no
Chemical
215
71
0.0036b
0.0006a
(continued)
Ferrous A /loys
451
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion
mediums
Test conditions * E
Average corrosion
rates (ipy)
1VPE
,VPE
VVPE
.
Acetic-acid mixtures
.
-
. f
304
3f6
317
20
ALLOY 825
99.49%. water 0.04%. mineral acid trace, no sulfur trioxlde 99.43%. water 0.04%. mineral acid trace 99.43%. water 0.04%. mineral acid trace 99.43%. water 0.04%. mate added 99.43%. water 0.04%, mate 35 lb/day 99.43%. water 0.04%, trloxtde trace mineral acid trace, chro.
Chemical
: .
211
71
0.0043b
0.00052a
Chemical Chemical chemical
: : j f 1
215 215 220
25 71 71 -
xx .. .
0.0038 O.OW79a 0.0003
0.0023 0.00036 <0.0001
. .
xx
mineral acid trace, chro.
230
aa
..
0.00067
0.00043
mineral acid trace, sulfur
215
25
xx
0.0038a
0.0023
99%. high boilers 1.2%. water 0.05% 99%, high boilers. 0.5%, water 0.5%, carbon deposit on all specimens, pressure 40 psig 99%, acetic anhydride 1%. pressure 2 psig 99%. heavy ends remainder SS%, water I%, acetic anhydride trace 9499%, high boilers l-2%, water 0.017%
Chemical Chemical
:F !F iF ;F :F iF ;
F
228 311
28 171
xx x
0.0024a 0.0027d L0.00108d 0.00071 0.04c 0.016a 0.0016 0.00084 0.0019a
O.WO41a 0.00108d
Chemical Chemical Rayon Chemical Chemical
250 248 235 228 235
638 833 720 23 00
0.00062a
xx x x
0.0012 0.00053 0.00092
O.Wlla
9999%. high boilers 1.2%. water 0.017%. dichromate 35 lb/day 9C99%. high boilers 1-296. water <0.1X water <O.l%, di-
Chemical Chemical
:F :
F
228 229
40 75
xx x
0.0004 0.0007
0.0002 0.0006
o.OW2
0.0002
99.99%, high boilers l-2%, chromate 50 lb/day 9&99X. high boilers l-2%, chromate 100 lb/day 9S%, acetic anhydride 2% 99%, high boilers, water trace 99%. high boilers festers) 2%
water <O.l%,
di-
228
13
xx
0.0017
0.0026
Chemical Chemical Chemical Chemical
F F
250 253 250 240
638 473 72 72
x xx xx xx
0.0073b <0.0001 0.0048a 0.002a
0.0065b O.WOl O.W21a 0.002a
99%. esters, high and low boilers, propionic acid trace SE%, glycol diacetate 1.9%. water O.l%, dichromate trace 99%. sahcylates 1.5%. water 0.5% vapors) fevaporator
:F : :
F
Chemical
252
43
xx
0.0001
o.WO4
Pharmaceu tical (evaporation) Chemical Chemical
265
xx
0.017
O.OQl 1
0.0009
0.0024
99%. light ends, esters, etc together 2% ~9.4%~ propionic acid 3.1%, 0.5% acetic anhydride
F F
235 248
73 50
xx ;
u
0.002 0.008
0.0009 0.0006 o.w4
.. .
99%. propionic acid 3.1%, butyric acid 1%. nitric acid 1%
Chemical
170 284
54
o.ooo2
0.0004
0.0004
(continued)
452
Corrosion Resistant Materials Handbook MOLYBDENUM
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
bntd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
Acetic-acid mixtures
(PROCESS)
INDUSIRV
. .
TVPE
TYPE
TVPL
.
125 36 50 93 30
. xx i :
,. : ;
304 P-P-P
0.05 0.02r
316
0.004 0.002r 0.0025
317
0.001 0.0016 0.002 ...
20
ALLOY 625
95%, propionic acid 5% 95%. propionic acid 5% 95%, propionic acid 5% 95%, propionic acid 5% 95.95% Ibottom of column1
; : ; :
f f f f f
176. 284 252 252 252 250
0.033
0.01 0.006
.
0.002
: Chemical ; (distillation) i
Chemical Pharmaceutical Pharmaceutical
x..:
94%. acetic anhydride 6% 91.96%, water 6.69%, naphtha 0.5% (vapors) salicylic acid OS%,
f f
265 246
638 58
xx xx
[ i
0.021
0.0007 0.014
0.0005 0.005 0.005
j ;
91.60%, water 7.46%, salicylic acid (vapors) 9t%, Propionic acid 6.596, acetic anhydride 1.5%, water 1% 9C66%, salicylic acid 8.4% (nozzle between exit of calandria and base section of still column) 90%. propionic acid 10% (variable) 90%, manganese acetate lo%, water 0.5%. man. ganese dioxide 0.15%. permanganate added 90%. manganese acetate 1056, water 0.5X, ganese dioxide 0.15%, permanganate added man-
f f
250 248
37 36
xxx; ,.
0.009
0.0012 0.007r
0.0011 0.001
0.001
i Chemical
; i
i
O.O65r
f PharmaceuF i tical :
Chemical : f
260
37
xx
0.137
0.034
0.011
0.103
,,,
275 259 259
137 96 75 -
O.Ola 0.0004 0.0006 0.0003
0.006r 0.0002
C0.002a 0.0003
j Rayon I i i f
Rayon
xx ; xx
I F
j ; ; i :
90%. manganese acetate 10%. water 0.5%, man. ganese dioxide 0.15%, permanganate added 90%. manganese acetate 10%. water 0.5%, manganese dioxide 0.15%. permanganate added 90%, water remainder, high boilers trace
ftayon
;F
72
xx
0.0024
0.0016
0.0015
Rayon
; f
259
72
xx
o.OOO3 O.OOl 0.0047
0.0002 0.0007
0.0004
Chemical
; .
300. 310 270 240
23
xx
co.002
67%. acetic anhydride 1396, pressure 4 psig 65%. acetaldehyde 2%, diacetyl 1%. glycol diacetate, oxygen trace 65%. acetaldehyde 2%, diacetyl I%, acetate. oxygen trace glycol di.
i :f : Chemical : Chemical ; F i Chemical i i f i f i : i :

Chamrcal f
638 12
xxx;
0.00073a 0.0006
O.OOQ36 0.0002
240
12
xx
0.0002
0.0004
65%. acetaldehyde 2%. diacetyl 1%. glycol diacetate 1%. dichromate 0.1%. water remainder, pH 1.4-1.6 65%. acetaldehyde 2% diacetyl l%, glycol di. acetate 1%. dichromate 0.1%. water remainder, pH 1.4-1.6 65%. acetaldehyde 2%. glycol dlacetate I%, diacetyl l%, unknown reducmg agent trace (passlbly sulfur dioxide). waler remainder. pH 1.2 65%, acetic anhydride 10%. water 5%. acetone, acetonitrlle. ammes. etc (vapor line, column)
235
xx
0.0005
0.0011
Chemical
235
xx
0.0033
o.Om3
.. .
Chemical
240
35
xx
corr
0.312
0.117
Chemical
239
875
xx
0.0036
0.0008
0.0007
0.0004
0.0003
(continued)
Ferrous Alloys
TABLE 4.13: VARIOUS STAINLESS STEELS AND
453
HIGH NICKEL ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
-..
85%. water 5%. acetaldehyde 12% oxidizer) (bottom of
INDUSIRY (PROCESS)
F F 194
1VPE
TYPE
,PE
.
35
.
xx
.
x !
304 p-p-0.0013 0.0014 0.386
316
317
20
ALLOY 825
Chemical
0.0003 0.0018 0.0358
0.0003
o.OW2
0.0019
75%. glycol diacetate 16%, water 9%, acetatdehyde 1.6%, diacetyl 0.8%. sodium sulfate and acetate 0.6%. unknown reducing agent trace 75%. glycol diacetate 16%. water 9%. acatafdehyde 1.6%. diacetyl O.E%, sodium sulfate and acetate 0.6%, unknown reducing agent trace 74.68%. water 24.97%, naphtha l%, salicylic acid 0.27% (vapors) Pharmaceutical fdistillation) Pharmaceu tical Idistillation) Pharmaceutical fdistillationl Chemical
300
15
xxx:
..
...
300
12
xxx:
O.W35a
0.0001
226
57.5
x I
>0.105
0.032
0.01
0.01
74.66%. water 24.97%. naphtha 1%. salicylic acid 0.27% (vapors)
226
45
x :
corr
0.077
74.66%, water 24.97%, naphtha l%, salicylic acid 0.27% (vapors)
226
28
xx
0.0004
0.0004
0.0004
72%, glycol diacetate 16%, water 9%, diacetyl 0.8%, sodium acetate and sulfate 0.6%. unknown reducing agent trace 72%. glycol diacetate 16%. water 9%, acetaldehyde 1.6%. diacetyr I%, sodium acetate and sulfate 0.6% 67%, propionic acid 33% 66X, water 30%, light ends 5% 64.6%. nitric acid 33.2%, tetroxide 0.6% water 1.6%, nitrogen
300
35
xx :
corr
0.128a
0.0528a
! :
Chemicpl
.F
300
26
xx
0.0002d
<O.OWl
Chemical Chemical
! ;
.F
F F
273 225 179
93 32 32 x;
0.016a corr 0.0002 s0.0003 10.0003
0.W22a 0.007 0.0003 0.0025 0.0004 0.0005
Chemical
64%, nitric acid 25%. water 11% 60%. water 35%, acid 1% propionic acid 4%, butyric
Metal fcleaningl Rayon
110
61
<O.OOOl s0.0001
1<0.0001
<0.0001
217
381
xx j
0.0001
O.WOl
o.ow2
69%. acetic anhydride 40%
Chemical
i F
25F 275 356
718
xx
0.01
0.001
0.0009
60%. hydrocarbons 18%. monoxide 8%, water 5% Sg-tO%. 0.25.4%
esters
9%,
carbon
Chemical
: F
300
xx i
0.009
0.004
acetic anhydride l-40%,
sulfuric acid
Chemical ; F Plastic jF 12: 104
75
xx ;
<0.0001
<0.0001
...
nil
57.5%. sulfuric acid 30.3%. water 12.3% (liquid line1 55.5%. water 43.48%, naphtha 1%. salicylic acid 0.016% 55%. glycol diacetate 40%. sludge (manganese acetate and resin) 4.g%, steam injection, water 0.1.0.2% 51%. propionic acid 29.5%. acetic 11.5%, propiooic anhydride 7.5% anhydride
74
_:
<O.OOOl
<O.OWl
<0.0001
Pharmaceutical Chemical
219
57.5
X 1
0.025
0.0016
0.0013
0.0017
310
97
xx :
0.W5a
O.Wl7a
Chemical
275
97
0.032
0.014r
...
...
(continued)
454
TABLE

4.13: VARIOUS NICKEL ALLOYS-CLIMAX
STAINLESS
STEELS
AND
HIGH
MOLYBDENUM
hwd)
Corrosion mediums
Test conditions
INDUSlIV Acetic-acid 51%. mixtures (PROCESS)
lYPE
TIPS
TYPE
ALLOY 20
.
f
.
275
p-p--
304
316
317
825
propmnlc
acid
11.5%, proptomc anhydride

50%. lo%, 50%. lo%, 50%, 50%, water 20%, hydrocarbons water 20%, hydrocarbons vinyl acetate vmyl acetate esters 5% esters 8% 50% 50%
29.5%. acetic 7.5% 12%. carbon
anhydride
Chemical
0.01
0.007
co.007
monoxide
Chemrcal
:F F
F :F
356
258
xx
xx
0.002
0.001
12%,
carbon
monoxide
Chemical
356
300
xx
YX
0.0004
0.0003
Chemical Chemical
266 194
133 150
0.002 0.0003 0.0005 <0.0001
0.001 0.0002
x
x
water 25%, ethyl acetate 7%, various ketones and alcohols together?%, methyl acetate 5%. methylethyl ketone 4%, acetone 2% 50%. water 25%, carbonyls and esters 25% acid
50%. esters,
i : i i I : i /
Chemical
131
360
<0.0001
Chemical Chemical ffractionation)
125 228
108 140 -
xxx
nil
nil 0.0005
II
50%, acetic anhydride and ethyhdene acetate
50%. some peracetic (column, liquid header)
<0.0001
45%, vinyl acetate tic anhydrrde 2%, 45%. high boilers
40%, acetaldehyde 12%, aceChemical light ends I%, acetone trace : 55% ethyl acetate 8%, propionic 5%, methylethyl ketone 5%,
220
609
nil
nil
.
0.0057
: I j
Chemical Chemical
F F
310 356
300 220
0.0016 0.03 0.007
40%. butane 20%, acid 6%, pentane
xx
..
other esters and ketones 40%. butane 20%. ethyl acetate 8%, propmnic acid 6%, pentane 5%, methylethyl ketone 5%. other esters and ketones 40%. butane 20%. ethyl acetate 8%, propiomc aud 6%. pentane 5%. methylethyl ketone 5%, other esters and ketones together 16% 40%. vmyl acetate tic anhydride 40%, water days 40%, water ethyl 95% 40%, acetaldehyde 15%, ace. Chemrcal F 347 216 x xx 0.003
0 002
0.002
Chemrcal
347
216
xx
0014
0.0013
i : : : i
Chemical
.F
194
150
0.06
0.0015
propionate and mixed
60% during alcohols 5%
16 days, during 36
Chemical
212
52
xx
0.0004a
0.0002a
butane 5%
25%.
esters
15%.
carbonyls
15%,
Chenucal
: :
345
108
0.0624~
0.0071h so.oo92c 0.0207

0 0092
35%, r..-butyl acetate 40%, Serbutanol 7%, .-propanol uene sulfonic acid 0.25% 35%. r.c-butyl acetate 40%, r.c-butanol 7%. .-propanol uene sulfonic acid 0.25% 30%, 30X, 30%. acetaldehyde acetaldehyde 3%. 0.5%, water
n-propyl acetate 8%. Chemical 7%, water 3%. tol- :
235. 245
75
n-propyl acetate 7%, water 3%,
8%, tol-
Chemical
235. 245
92
0.0912c 0.0519c
0.0312~ 0.0083c
0.0152~ 0.0067a
remainder remainder
I Chemical : I
Chemical Chemical Chemrcal -F
110 100
129 129
321 52
x x
xx -
x x
x xx
<0.0001 <0.0001
0.051 0.1735c
<O.OOOl <0.0001 0.0009 0.0512~
<0.0001 <0.0001 0.0002
water
light ends 20%,
water
remainder
F F
185 230
30%. r.c-butyl n.propyl acetate toluene sulfonic
acetate 42%. .-propanol 18%, 9%, se<-butanol 7%. water 4%. and sulfuric acid traces
(continued)
Ferrous Alloys
455
TABLE
4.13:
VARIOUS
STAINLESS
STEELS Test
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion mediums
conditions
Average corrosion
rates (ipy)
,YPE tNoSra (PROCESS) Acetic-acid mixtures . .
WPE
TlPE
.
28
.
x
.
x
304 p--p-
316
317
20
ALLOY 625
27%. high boilers 70%. water 3%, sulfuric acid used in hydrolysis, &chromate 28 lb/&y and soda 12 lb/day added 27%. high boilers 70%, water 3%, phosphoric acid used in hydrolysis. no dichromate or soda added 25X, organic esters 75% 24% approrimatrly tcolumnl 24%. water 74%. lormaldehyde trace 23.44%. water 75.56%. naphtha 1%. salicylic acid 0.01 I % (column. vapors) 20%. glycol dracetate 78%. sodium sulfate and acetate 1.2%. sohds trace, drchromate trace 20%. water 78%. benzene 2% 20%. water 30%. acelaldehyde remainder 9.7%. high boilers 89.8%. water 0.5% 5%, sulfuric acid 1% 5X, butyric acid
Chemical
280
0.025
0.00043
Chemical
280
12
x:
0.0031a
0.00025
[ i
Chemical Chemical hi~stillationl
L f f f
68. la5 231 95 212
15 51 115 57.5 xx x x
<0.0001 corr
nil 0.0027 <0.0001 0 0007 0.0027 <0.0001 0.0012 0.0002 0.004
i Pastic j Pharmaceu: tIcal [ : :

Chernlcal Chemrcal Chenucal
<O.owI
: :
0.042
: f
320 171. 208 210 335
42 214 112 72 20 54 220
x x
xx x I xx
0.0477c 0.0008 0.0026
0.007a (0.0001 0.0007 0.016
0.006a
: : : :
: :
...
0.0002 0.0032 . 0.001 .. . 0.001
i Chemical
: Pulpand i Paper ;
Chemical
70. 250 239. 284 356
<O.OOOla <O.OOOla
<0.0001 0.0017
xx
x xx 0.001
4%. butane 56%. other organics 27%. nitrogen i Chemical lo%, water 2%, carbon dioxide 1% .( 4%, butane 56%. other organics 27%. nitrogen lo%, water 2%, carbon dioxide 1% ;e:S.j.75%, furfural 0.5-l% (vapors and conden-
: j F j
f
0.0006
I i
Chemical
347
220
xx
0.0007c
0.0004c
...
...
Chemical
208. 220 223
132
._
0.0001
O.OQOl
0.0001
0.0001
0.0001
2.2%. methyl acetate 60%. water 18%. acetaldehyde 5%. methyl acetate 4-5%, methanol 4%, acetone 2.5%, ethyl acetate 1.5% 2.1%, ethylrdene diacetate 25.50%, acetic acid 2.4%. vinyl acetate 1.2%. toluene sulfonic acid 0.2% 1%. water 98%, carbonyls 1% 1%. water 98.4%, sulfuric acid 0.8%
: secondary
oxidation) Chemical
Chemical (distillation,
45
xx
0.031
0.0077
0.01
f <300
14
0.0003
0.0003
j ! ;
Chemical Chemical (distillation1
f f
212 224
29 87
xx xx
0.0001
0.0002 0.0132
.. . 0.0032 0.0041
99.9%, water <O.l%, acetaldehyde 0.02%, for. mic acid <0.01X, dichromate added over one 24.hour period 99.9%. water <O.l%, acetaldehyde 0.02%, mic acid <O.Ol%, no dichromate added for-
_ Chenucal : !
Chermcal
216
18.3
xx
0.0033a L0.0027a
O.OOlla
0.0021b
216
40
xx
0.0005
0.0004
0.0003
0.0002
(continued)
456
Corrosion Resistant Materials Handbook VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX Test conditigns
TABLE 4.13:
MOLYBDENUM
bntd)
Corrosion mediums
304 p--p99.9%.
7PE
316
TPE
317
TYPE
20
ALLOY
625
lormrc acid <O.Ol%
Chemical
F : F
248 216 244
296 15 243 -
x x xx
0.0007 0.0035a 0.00023 0.00019 0.0018
0.0003 0.0021a 0.00017 0.00015 0.0027a o.OQO34 0.0017
99.9%. formic acid <O.Ol% S9.S7%, formic acid trace
: : i
Chemical Rayon
;F
99.9%, waler 1.6%, permanganate 0.3%, formic acid 0.3% 99.8X, formic acid 0.02%, no water
Chemical
248
40
xx
xx
0.0016
0.0019
permanganate trace. i Rayon
; F
255
75
0.0025
0.0028
0.0022
99.9-9096, formic and propionic acids in Water, areotropic solution 99.736, formic acid 0.02%, permanganate 0.03%
Chemical
266
56
xx
0.0355
0.0124
0.0044
Chemical tdistdlatron. secondary oxidation)
248
152
0.005
0.0004 10.0004
0.0005
99.7%. <O.Ol%
permanganate
<0.02%.
formic
acid
Chemical tfractionation. secondary oxidatron) Chemical (evaporatlonl Chemrcal Chemical
244
244
0.0011
0.001
99.6%, formic acid 0.3%. circulahon evaporator) 99.6X, formrc acid <O.Ol%
water 0.1%
(natural
i i :
272
20
0.0058
0.0001
0.0001
0.0046
0.0002
j F : F
216 216
23 29
x xx
0.0011 0.00076a
ml 0.00015a
99.6%, acetaldehyde 0.02%, formic acid <O.Ol%, dichromate added 40 lb/day 99.6%, glycol dracetate O.l%, water <O.l%. formic acid. high boders and aldehydes remainder 99%. lormic acid 0.5%. waler 0.5% 99%. water 0.6%, formic acid 0.2%, formaldehyde 0.1%. propionic acid 0.1% 99.7X, propiomc acid 04%, lormic acid 0.3%, high boders. manganese dioxide, butyric acid trace 91.5%. water O.l%, boders remainder formic acid 0.01%. high
Chemrcal
290
436
xx
0.0015
0.0015
Chemical Rayon
F F
255 250
116 253 -
x xx
0.03b 0.028
0.0023 0.013
0.0017
Rayon
243
243
xx
0.011 0.0046
0.00043 0.00031 0 0027 10.0022 0.0024 0.0021 0.002 0.0018
Chemical
275
75
xx
99.2%. propionic acid 0.6%, water 0.4%, high boilers 0.3%. lormic acld 0.2%. butvric acid 0.1 sb. some manganese droxide 98%. formic acid 0.2%, remainder unknown 99%, proplonic acid 1%. water 0.7%, acid 0.2%. formaldehyde 0.1% W-96.5%, formic acid 1.5%, waler l-1.5% 97%. water 1%. formic acrd 2% 97%. water 1%. formic acid 2% formic
Rayon
248
243
xx
Chemical Rayon
F F
212. 252 257
6 253 -
xx
xx 0.07
<0.0001 <0.0001 0.006
<0.0001 0.0002
0.0004 0.0001
Rayon Chemical Chemtcal F F
255 240. 284 226
262 291 54
x xx xx 0.0053c
0.015 0.0003 0.0023 0.0002
0.01
0.006
0.0028
0.0021
(continued)
Ferrous Alloys
457
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bontd)
Corrosion mediums
Test conditions
TYPE
TIPE
1IPE
304 --P-P
@,cet~c~~wJ mmture* wth formic aad
316
0.0021 0.0069 0.0035
317
"20"
ALLOY 825
97%. lormrc acid 1.5%. water 1.5% 97%. lormic acid 1.3%. propionic acid heavy esters 0.5%. water 0.2% I%,
Chemrcal Rayon Rayon
346 225 246
692 362 382
x xx xx
: i :
0.0026 0.0004 0.0006
me traces
97%. lormrc acid 1%. heavy esters 0.5%. water 0.2%. methylethyl ketone. elhyl acetate and henformic acrd 0.2%. lormalde.
0.0025
0.0015
97%. waler 0.7%. hyde 0. I Sh
Rayon Rayon
262 342 250 336 239
253 76 337 315 243
-.
xx xx
0.03 0 055 0.04
0.0001 0.005 0.009 0.016 0.003
9796%. water 3%. lormrc acid 0.5% 965X, formrc acid 1.5%. esters l%,carbonyls 1%
f j F
. 0.006 0.008 0.0029 0.013 0.0015
Chemical
x ;
xx : xx
96%, formic acid 1.5% 96%, water 4%, formic acid trace, propionic acid trace, permanganate injected at tray 95.4%. water acid 0.1%
I Rayon i f i j
Chemrcal Rayon
:F
j
0.0098
0.011
15%.
formic acid 0.69%, propionic
: F
235
266
xx i xx ;
0.0002
0.0001
0.0001
95%. formic acid 1.5.3%. remainder unknown 95%, water 4%, trace
permanganate 0.5%.
: ;f
230. 291 311 567 -
0.0027
0.0024
0.0015
formic acid 1%. high boilers
Rayon
xx
0.0025 0.0032 0.012 0.0001
O.OQ58
0.0019 0.0089
95%. water, lormrc acid trace, high boilers re. mainder 94%. water 3.4%, acrd trace formic acid 2.3%. propionic
j j :
Chemical
290
43
<O.OOOl
Rayon
226
243
xx
0.00049
<0.0001
94%. high boilers 5%. formic acid 1% 91.5%. water 6%, formic acid 2.5% 90.1%, water 6%, formic acid 1.75% SO%, acetaldehyde 7%. water 3%, formic acid 1% 90%. water 8%. ethyl acetate 0.5%. unsaturates 0.5%. methylethyl ketone 0.4%. propionic acid, formic acrd trace, biacetyl trace 69%. acetaldehyde 7%, water 3%. formic acid 1% 99%. lormrc acid 1%. propionic and butyric acids 66.1%. water 10%. ethyl acetate 0.5%. unsaturates 0.5%. methylethyl ketone 0.5%, biacetyls 0.196, formic acid trace, propionic acid trace 67%, acetaldehyde 7%, formic acid 1X, low and hrgh boders. water remainder 96.565%. butyric and propionic acids together 9%, formic acid 3%. water 15.3%. pressure 3
Rayon
257 230 235 211 225
465 54 266 511 243
xx
0.003 0.006 0.0028 0.0002 <O.OOOld 0.031 10.0026 0.0001 <O.OOOld
0.001 0.001 0.0005 <0.0001
0.0007 0.0015 0.0031
_Chemrcal i j I
Rayon Chemical Rayon
:
: F : ; f
xx xx ;
xx xx
i :
Chemrcal
250
511 382 243
xx xx
0.006cd
0.0001 0.0004 0.0009 0.00078
<O.OOOl .. . 0.00051 0.00031 . 0.00051
i I : i I ! :
Rayon Rayon
j
IF
248 221
: i
0.0025
Rayon
:F
252
756
xx
: i
0.0027d
<O.OOOld
<0.0001
Chemrcal
: F
244
166
0.0068~
0.00074
0.001
wig (continued)
458
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(mntdb
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
ACettC-aCId mlXfreS W,,h
(PROCESS)
.
F
INOUSlRV
E =p
.
260
,PE
1TPE
TYPE
ALLOY
20 625
----
304
316
317
formic acvd
85%, acetaldehyde acid 0.75%. high 85%. acetaldehyde acid 0 75%, high
8%, low boilers 2%. formic boilers O.l%, water remainder 8%. low boilers 2%. formic boilers 0.1%. water remamder 8%. low boders 2%, formic hollers 0.1%. water remainder 8%. low boders 2%. formic boilers O.l%, water remainder methyl acetate
i : i i :
Chemical
0.0004
Chemtcal
235
0.0003
0.0002
85%, acetaldehyde
acid 0.75%. high 85%. acetaldehyde acid 0.759b, high
Chemical
250
0.0011
0.0006
! Chemical 1
Rayon
545
300
ml
0 0001
85%, acetaldehyde 7% water 5%. and formate 2% formic acid 0.5% 71.28%, acetaldehyde water and low boilers
221
756
xx
0.00011 0 00013 >o 12 0.0268
<0.0001
7.37%, formic remamder formic
acid
1.96%.
Chemical
240
I35
xx
0 0009
65%. acetaldehyde 15% hollers 196, water remainder 65.60%. formic acid 2-2.5S;,
acid
3%.
low
Chemtcal
245
558
xx
0 0001
0 0001
0 0001
water
remamder
Chemical
230
113
0.0004a L0.0046a 0.0085
0 004a
62%. acetaldehyde bollers I%, water
18%. formic remamder
acid
3%
low
Chemrcal
235
179
xx
0 0001
0018 0.002
62%. acetaldehyde 18%, formic boilers and water remamder 60%. mate 60%. 60%.
acid
1.5%,
low
Chemical
235
300
xx
0.0018
o.opo3
acetaldehyde 20%. water 12%. methyl and acetate 6%. formic acid 2% water 38%, formic acid 2% formic
for-
i :
Rayon
221
756
xx
<O.OOl
<o
001
Chemical
iF F
221 226
315 536 -
x xx
0.008 0.0007
0.004 0.0005 0.0003
i%.
water 35%. propionic butyric acid 1% formic water acid
acid 4%,
acid
Rayon
_,
60.55%. 0.5%.
l-1.6%.
methyl
acetate
Chemrcal
remainder 25.30%. 3.4%, acetaldehyde acid 3% Rayon F 10.1596, inChemical F
220. 240 217
57
xx
0.085 LO.076 <0.0001
C0.05b
60-509/o, direct
water
511
x-
acidity
formic
55.50%, formic acid 0.5%, esters, ketones. altohols. aidehydes. butane, pentane. nitrogen, carbon monoxide and carbon dioxide remainder 55.50%. formic acid 0.5%. esters, ketones, alcw hols, aldehydes, butane, pentane. nitrogen, carbon monoxide and carbon dioxide remainder 50.9%. water 43.2%. propionic acid 1.7%, acid 1.7%, butyrlc acid 0.5%, high boilers 50%. water 28%. ethyl acetate ketone 4%. propiomc acid 3%, methyl ketone l%, acetaldehyde mate 1%. formic acid 0.5% formic
365. 383
359
0.006
0.0008
Rayon
356. 378
360
xx
O.Olc
0.0035
/ ! : f
Chemical
221
452
xx
xx <0.0001
0.009 LO.0108 <0.0001
4%. methylethyl alcohols 3%. di196, methyl for-
Rayon
208
525
50.30%. formic acid 2.10%. methyl acetaldehyde. methyl acetate, ethyl tone. methanol, water remainder
formate acetate,
5%, ace-
Chemical
223
99
0 0089
0.015
(continued)
Ferrous
A llo ys
459
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
Average corrosion rates (iPY)
-..
Acetcacld mlxtre* wttl
INDUSTRY (PROCESS)
TlPE . . .
TIPS
1lPE
304
316
317
20
ALLOY 825
formic acid water 24%.
45%, high and low boilers 29.5%. formic acid 1.5% 40%, water50%,
Chemical
200
380
xx
xx x
0.0003 10.0008 0.0009 <O.OOOl
0.0001
acetaldehyde 8%, formic acid 2% l%, low
: Chemical !
Chemical
230 110
511 81
<0.0001 0.0001
40%, formic acid 1.5.2%. acetaldehyde boilers trace, water remainder 40%, formic acid l-1.3%, water remainder
;f
; F : F : F
! Chemrcal
Chemical
242 256 338. 374
277 247 358 -
xx XX
0.023~
0.0088b nil
40X, formrc acid 0.9.1.2%, water remainder 40%. butane 20%. esters and ketones 16%, ethyl acetate 8%, pentane 5%, methylethyl ketone 5%, formic acid 0.5% 40%. butane 20%. esters and ketones 16%, ethyl acetate 8%. pentane 5%, methylethyl ketone 5%, formic acid 0.5% 40.35X, formic acid 5.2% 40.30%. formic acid 4.1096, methyl acetate 0.5. 196, water remainder 40.30%. formic acid 1.1.5%
:
0.031
<0.0001 0.011
1Rayon :
Rayon
xx
338. 374
359
xx
0.006
0.002
Chemical
F F
230 220
131 112
x x
0.018
0.0006 0.0046
0.0006 0.013
Chemrcal
: Chemrcal : fdrstrllation I secondary : oxidation) ; Chemical :

Chemical Chemical Chemical
: F
220
106
xx
0.019
0.0001
0.0002
35%. acetaldehyde 3%, formic acid 1% 35%. formic acid 0.9.1.2%, water remainder 35%. formic acrd 0.9.1.2%. water remamder 35%. formic acid 0.9.1.2%. water remainder 35.25%, formic acrd 0.&1.5%, water remainder
F F F F
100 256 256 256 262 255
81 300 150 81 433 511 246 246 112 -
xx xx xx xx x
<O.OLlol 0.0089
<0.0001 0.0023 0.0007 0.0038a 0 0058 0.002 0.0001 c0.0001 0.0018
0.0001 0.0079c 0.026 0.003d 0.0001 O.OOOld 0.0045
j I
Rayon Chemical
:F
33%. formic acid 66%, water 33%. formrc acid 1.5%. water 33%, formic acid 1.5%, water 30%, formic acid 8%, water remainder
_Chemical : f
Chemical Chemical Uractiona-
F F F
270 270 275
x x
xx xx x
30%. acetaldehyde remainder
5%, formrc acid 4%. water
I tron. 1 secondary : oxidation) j Chemical

Chemtcal
245
300
0.0001
0.0001
30%, formic acid 1.2.1.6%. water remainder 30%. formic acrd l%, remainder 28%. water acid 1% 70%. acetaldehyde l%, water
F F
265 72
172 511 -
xx -
0.0202c <O.oOOl
0.0065b <0.0001
Chemtcal
formic
acid
1%.
proptonic
Rayon
208
382
xx
0.003
<O.OOOl
(continued)
460
TABLE

4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX
MOLYBDENUM
(-ntd)
Corrosion mediums
Test conditions
TlPE -,. INDUSTRY ,PRUCESS, .
TIPE
304 P-P>0.059
316
0 0033
317
0.002
1VPE
20
ALLOY
825
2536,
formrc
acid
4%,
low
boilers
1%.
water
remainder
:
25%. formic acrd IS%, low boilers 1%. water remainder
Chemical (drstillation, secondary oxidation) Chemrcal tdrstrllatron. secondary oxidation) Chemical
220
117
220
129
xx
0093
0.001
0 0003
:
acid 1.5%. low boders 1%. water
25%. formic remamder 25%. 21%, 18%. II%, water water water water
220
129
xx
0 0093
0001
0 002
73 5%, 78%, 81%, 82%.
tormrc formrc
acrd acid acid acid
1.5% 1%
Chemrcal Chemical
212
315 229 167 436 -
x
xx
0 008c
0.002 0.026
0001 0.012 0.0076 0.0007 0.01
F
: f F
239
208 210
formrc formic
l%, 1%
pressure
1 psig
Chemical
x x
O.lc
0.0145 0.0018 10.0007 0.018
I
low boilers
Chenucal
18%, ethyl acetate 35%, 9.5%, formic acid 6.7%
benzene
32%,
Chemrcal
235
213
xx
18%, ethyl acetate 35%. benzene 32%, 9.5%. formic acid 0.39%. water 1.5% 1512%. <0.2%, 12%. 12X, 12%, 12X, formrc methyl formic formrc formic formrc acid acid acid 0.3.0.4%. formate <O 2%, E-4%, M-3%. water water water water
low borlers
: Chemrcal
Chemical
194
696
xx
0.0099
0.0024
methyl acetate water remainder remainder remainder
265
169
xx
0.0001
0.0001
0.0001
Chermcal Chewal Chemical Chemical Rayon
F F F F
250 246 280 280 217
355 355 169 169 382 x x xx xx
0.014 0.0006 0.014 0.0001 0.034 0.006 0.0001
0.0023 0.0001 0.0001 0.009 0.0001
acid 0.5%. acrd 0.4%.
remainder remamder
10%. ethyl acetate 36%, methylethyl ketone 27%. benzene 18%. water 6%. propionate esters 2%. lormrc acid 0.5%, propIonic aud 0 5% 8%. water 87%. methanol methyl acetate, acetone 4%, formic acrd I%,
xx
Chemical
240
227
xx
0.02c
0 006b
7.5%, water 65%. methanol 8%. esters acetaldehyde 2%. ethanol l%, formrc acrd propronrc acid 0.2% 7%. waler 65%. methanol 7%. acetone methyl acetate 3%. ethanol 2%. acelaldehyde tormrc aud 0.5% 7.5%. water 91%. Indirect 0.5% 2%, formic acid I%, acidrty 1596,
7.2%. 0.3X,
i Rayon
158
585
xx
0.0003
00001
7%. 2%.
Rayon
191
706
xx
0.005c
0 0007
formic
i i i i
Chemical
208
511
<o
0001
<0.0001
acid 1%. acetaldehyde 6%. low remamder boders
water
Rayon
257
756
xx
0.00029d
0.0002ld
6%, methyl formate water remamder 6%. water methyl formate remainder 1%. forChemical F 250 95
0.00014 0.00013 0.0021
8%. methyl acetate mic acid 0 5-O 75%, 8%. methyl acetate mic acid 0.5.0.75%,
xx
0.0061a
l%,
for-
Chemical
230. 240
95
xx
0.002a ~0 OOOla
0.0034a
(continued)
Ferrous Alloys
461
TABLE 4.13:
VARIOUS
STAINLESS
MOLYBDENUM
(amtd)
Corrosion mediums
TIPI
TWE
7PE
ALLOY
304 --P
Acetic.acsd 6%, mixtures wth formic acid
316 <o 0001

<o 0001
317
--
20
825
methyl acetate mlc aud 050.75%.
6%, methyl formate water remamder
1%.
for-
Chemical
175
179
xx
6.4%. methyl acetate 6% methyl formate mic acid 0.5-0.7596, water remamder 4%. formic 4%. formtc 4%, formic acid 0 25%. water remainder remamder vapor 3%.
l%,
for-
Chemical
150
81
<o 0001
0.0004 0.00012 0 0004 ml
Chemical Chemical Chemwl formic acid Chemical
F F f F
222 217 222 210. 215
63 417 63 63
xx x xx xx
0.0002 0.0013 0.0002 ml
acid 0 25%, water acid 0.25%, water
4%. methyl acetate 7% 0 25% water remamder 0.5%. 3.5% 0.4%. acetaldehyde 35%.
methanol
water
20%,
formic
acid
216
436
0.006 0.0015 0 0021d L0.0037d ml
0.003
formx
acid 1 6596, water
remamdel
Chemical
230
40
xx
0.0031d
0.0031d
0 3%. formic remamder acetlc and formic
acid
04%,
solvent
trace,
water
Chemical
230
1025
suds,
ethylene
dlchlorlde,
water
Pulp and Paper Petrochemical Chemical
161
31
0 0107
0.0057
0.0049
mostly suds orgamc formic. carbon acetlc formic acetlc acetlc
acetic
acid.
formic,
propionic
and
butyrlc
650
63
0.019
0.0009 0.02 <0.0001
acids effluent cor;!ammg butyrlc, propiomc suds. dmxlde and ash acid, ethanol, acid trace and formic acid, toluene acids, 2 g/l, ethyl
vapors steam,
of acetlc, hydrogen.
R.T. 212
75
xx
xx
<0.0001
acetate,
acetaldehyde,
Chemical
205
880
xx
xx
<0.0001
<0.0001
<o 0001
<0.0001
<0.0001
water formic acid
Textde Textde
F F
212 210
35 10
xx xx
<0.0001 <O.OOOl
<0.0001 <0.0001
ACETIC
ANHYDRlDE
100% 100% acetlc anyhdrlde
Chemical Rayon Chemical
F F 1
277 273 283
571 287
x xx
0.012
0.005 0 0001
0.003
0.0001
0.0001
LO.0003 LO.0002
10.0003 LO.0007
65%, ethybdene dkwetate 33%, acetlc durmg 186 days, washed with water mamder unknown, durmg 68 days 55%, 50%. 50%. sollds ethyhdene acetIc actd dmcetate 10%. 40%. acetlc
acid 98%.
2% re-
Chemical
244. 323
254
xx
0.0003
0.0001
0.0001
acid
5%
Chemical Chemical
F F F
302 237 302
150 369 150 -
xx x
0.0003
0.0002 0 0001
esters 40%. acetlc acid 5%,
ethyhdene 5%
dlacetate
Chemical
0.0003
0.0002
0.0001
(continued)
462

AND HIGH NICKEL ALLOYS-CLIMAX
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
MOLYBDENUM
bntd)
Corrosion mediums
TYPE
TYPE
TYPE
304 p-p-AcetK.ahydnde
316
317
20
ALLOY 825
mtxture*
30%. ethyhdene dlacetate 65%. acetlc acid 5% 15X, ethylldene dlacetate 65%. solids 20% acetic anhydrIde, acetlc acid, acetaldehyde, vmyl acetate
Chemical
F IF F
158 167 302
150 150 888 -
0 0001 0.0002 0 002c
<0.0001 <0.0001 0.0001
... ... ...
... ... ...
Chemical
xx ;
xx
: Won
ACETIC-ANHYDRIDE
*cE*Ic KID
MIXTURES
WITH
99%. acetlc acid 1% 99%. acetIc acid 1%
Chemical Chemical
f F
310 230. 248 280. 291 250. 270 300 295 268 273. 280 160 290 284 266. 277 262 ia4 280 280 284 262. 282 285
219
637 165
xx xx 0.009
<0.0001 0.001
nil
99X, acetIc aud 2%
Chemical
718
xx
0.002
0.0008
0.0004
99%. acetlc aud 2%. petmanganate lb/day 93%. acetic acid 1% 97%. acetlc acid 13% 90%. acetic acid 20% 70%, acetlc acid 30%
added 150
Chemical
718
xx
0.014
0.002
0.001
Chemical Chewcal
F F F F
637 637 571 718
x x x xx 0.009 0.004
0.00011 0.0005 0.0006 0.0008
<0.0001 0.0003 0.0004 0.0005
Chemical Chemical
6536, acetlc acid 35% 63%, acetic acid 37% 60%, acetlc acid 40% 60%. acetIc acid 407 0
: Rayon Chemical Chemical Chemical
F F F
207 637 1183 718
xx x
0.0001 0.00048 <o 0001 L ml 0.005b 0 0008
0.0001 0.00028 llll 0 0006
<0.0001
xx
xx
F
F F F F F F
60X, acetIc acid 40% 60%. acetic acid 40% 55%. acetlc acid 45% 55%. acetlc acid 45% 50%. acetIc acid 50% 50%. acetic aud 50%
Chemwal Chemical Chemical Chemical Chenwal Chewcal
571 375 104 104 150 718
x xx x x xx
0.02
0.001 <0.0001
0 0004 \0.0001
0 0002 0 0007 0.002 0 007
0.0001 0.0002 0.0009 0.001
... ... ...

0.0007
... ... ...
xx
44%. acetic acid 56% acetlc anhydrIde. acetIc acid acetlc anhydrlde. crude acetIc acid crude a&c anhydride. acetlc acid
Chemical
637 735 II4 114
x 0 004 00711 0 0485
0 0004 I 0 0024 0 0134 0.0174
0.00023
Research Research
L L
246 230
(continued)
Ferrous
Alloys
463
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions
Acetoc-anhydride
mxturer
acid 34%.
with acetic
water
acid
(PROCESS)
twos7*
7PE
TIPE
TWE
304 P-P--
316
0 0009a
317
20
ALLOY 825
40%. acetlc 15 psrg acetlc anhydrtde.
20%.
pressure
Chemrcal
1166. 1184 1250 58 xx
00042a
glacral
acetlc
acrd. catalyst
added
Chemrcal
0 0021 0 0006
0.0019 0 0004
c0.0001
ACETONE
MIXTURES
98%.
mesltyl
oxide, alcohol
dlbutyl
alcohol,
water
F RayOn F F
137 77 145
181
~~
xx
000011
onnol 0 0001
SO%, dlacetane SO% Istill,
0000l
approximately, half Immersed1
olerc
lmolelc
acid
remamder
Soap (solvent recovery) Soap (solvent
rlll. 0.0001
00001
,..
83%,
fatty
acrds
remainder
(separator
tank1
32. 72
131
<0.0001
<0.0001
60%. methyl 5.0-6.0
acetate
30%,
acetaldehyde
10%.
pH
176
210
0 0003
0.00038
45%. methanol 2%. acetrc sod
38%. 0.1%
methyl
acetate
15%,
water
Chemrcal
135
210
xx
rlll
nil
acetone vapors from drstilhng a 40% water hn vapor llne from top of column) 40%, water charge Imet 26%. 1% water 60% Icolumn, 10 bottom
solutmn
in
: : I
Plastic tdrstdlatmnr Plastrc ldistillatronl Chemrcal
133
59
<0.0001
<0.0001
<o 0001
<0.0001
pump
dis-
145
59
<0.0001
<o 0001
60%.
methanol
13%,
methyl
acetate
190
583
rlll
16%, methanol 16%. methyl acetate dehyde 3%, ethyl acetate 1%. ethanol ethyl ketone acetone, mixture ethanol, ethyl acetate wth BP. 60.100 C
12%, acetal1%. methyl-
Rayon
138
294
xx
<0.0001
<O.OOOl
and solvent
naphtha
Textile
70. 86 165. 225
940
xx
xx
<O.OOOlb <O.OOOlb 0.0026
<OOOOlb
.,.
20X, water 80% tone 2%. caustrc
durrng 480 days, water 1% during 100 days
97%,
ace-
Chemrcal
580
0.0016
ACETONlTRlLE
4%.
Isopropyl-chlorrde
solutmn
Petroleum
192
l--
0 595
0.765
ACETOPHENONE
66X,
phenol
33%
Phenol
302
276
xx
0.0003
<0.0001
<0.0001
<0.0001
ACETVLENE
TETRACHLORIDE
acetylene
tetrachlorlde
Chemrcal
60. 60 205
22
0.0446
0.0442
acetylene
tetrachloride
(liquid
and vapors)
Chemrcal
17.5
O.Olc
0.0085~
(continued)
464
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosionmediums
Average corrosion rates bpy)
YYPI
TYPE
TYPE
ALLOY
"20" 625
304 --P-P
crude acetylene telrachlorrde, chlorme excess IO-21 g/l, drssofved won 0.15-1.65 g/l, acrdity as hydrochlorrc acrd 0.7-6.6 gi Chemrcal F 108. 120 0.00083b
316
0.0049b
317
acetylene tetrachloride, aqueous hme acetylene tetrachloride, aqueous hme
trichloroethylene
vapors,
Chemrcal
185. 202 202. 220
30
0.0026~
0.0018~
..
... ...
... ...
trichloroethylene
vapors,
Chemrcal
30
0.0028~
0.0012b
15%. methylethyl ketone 77%. water 8%. hydrachloric acrd trace fresrdue in evaporator consists of aconltic acid 50% and water 50%) 15%. methylethyl ketone 77%, water 8%, hydrachloric acid trace (residue rn evaporator consists of aconitic acid 50% and water 50%) 15X, methylethyl ketone 77% water 8%. hydrachlorrc acrd trace (residue m evaporator consists of acomtic acid 50% and water 50%1 0.5X, calcrum chlorrde 12%, methylethyl 8%, hydrochloric acid l%, water remamder ketone
Sugar By. product IevaporatIon) Sugar 8yproduct (extractloo) Sugar
190
0.016
0.005
100
8.5
0.005c
0.004c
70. 100
82
(0.0001
<0.0001
Sugar Byproduct fexfractronl Sugar
80
0.0003d
00004d
mother lrquor obtained alter one crystallization of the organic acid followed by removal of the acid crystals by centrrlugation
80. 100
15.9 -
0.0002 0.0001
<O.ooOI
96%. 45%, 30%.
methyl
ether hydroqumone water
1000 ppm 10%
Rayon Rayon Rayon
:F
77 150 F 250
116 20 3
_ xx
<0.0001 0.002
<0.0001 0.0009 0.0026 LO.0021

0.002
acetrc acrd 452, acetlc actd 30%,
xx
xx
water remainder
acryhc acrd
Rayon
122
rlll
orI
AMYL
Al.DEYDE Research (vapors) Research L L 266 248 20 20 0.0142 0.0917
crude alkyl aldehyde crude alkyl aldehyde
0.0045 0.0043
*LKL
AMlNES Metal nitrrte, methaChemrcaf L F 212 70 31 27 nrl nil 0.0012 c0.0007 0.003
alkyl amines mtxed (hqurd and vapors) alkyl amlnes. nol, water caustfc soda, sodwm
xx
LO.0045
alkyl phenol
Metal Idrstdlat&on) Metal fdistillatron)
401
45
0.0008
alkyl phenol [vapors)
401
45
0.0002
orI
(continued)
Ferrous
A/lo ys
465
TABLE 4.13:
VARIOUS
STAINLESS
STEELS AND HIGH NICKEL Test
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
conditions
TVPl
TYPE
VVPF
304
316
317
20
ALLOY 825
alkyl phenol-boron-trifluorrde alkyl phenol-boron-trrfluoride Al.MrNM
complex (vapors) complex
Chemical Chemical
201 201
9 9
0.032 0.021
0.047 0.011
0.008 0.004
0.006 0.003
x..:
CHLORIDE
aluminum chloride, water, oil
Chemical
jF
F
113. 195
30
xx
0.011
0.004
0.005
5%. ammonium chloride 5%, pH 2 aluminum chloride, dust, solvent fumes (mainly benzene) aluminum-chloride dust, rulfurrc acid and bromine vapors, mixture of many fumes (fan scroll1 aluminum chloride, some hydrochloric acid, possibly some moisture, tar residue from isomerization unit with heavy hydrocarbons (immersed in tar at bottom of vessel) alummum chloride and hydrochlorrc acid, ethyl benzene. ethylene benzene (bottom of reactor)
*LMINM FLOROSLFATE
Chemical Chemical
78
R.T.
08 30
xx xx
xx xx
0.0023~
0.00015a 0.0004b
0.00024~
f
F
0.0067b 0.0006b 0.004c
Chemical lventrlatronl Petroleum
R.T.
30
xx
xx
0.02c
225 250
44
xx
0.0945a
0.111
Chemical
240
35
corr
corr
alummum-fluorosulfate concentrated water solu tron, solids 1535%, pH 1.52 15% approximately. water solution, pH 2.3
Chemical fevaporatron) Chemical
190
2.5
xx
xx
0.016
0.011
0.0017
75
49
0.0095
0.0016
0.0002
47.6%, water solution, free nitric acid 0.12M Energy 12.7%. water solution, free nitric acid 3.OM Atomic Energy free Chemical
90
15
0 168
176
7 *,
__I
0.0003
lO%, water solutron, ferric nitrate nitric acid 2-lo%, pressure 300 psi
IO%,
400
0.078
0.182
10X, water solution, ferrrc rutrate 10%. nitric acrd 2.10%. pressure 300 psi
SULFATE
free
Chemical
400
xx
0.36
0.545
ALUUlNUM
60.20%
Chemical Chemical pH 2.3 Chemical Research Research Research
F F F 1 L L
244 244 225 235 190 175 220
36 36
xx
xx xx x
0.03 0.005 0.634~ 0.058 0.023 nil
0.009 0.0004 0.196 0.09
60.20% 5550%, 50.40% 40.30% 30%
8
>6 >6
0.0003
0.0006
0.0002
xx
0.0001
(continued)
466
TABLE 4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(cmtd)
Corrosion mediums
Test
conditions Average corrosion rates (by)
TPE
lPE
WPE
Alrnlrn
ru,rats
Research L L L 220 160 B.P.
. -
304
0.0005
316
317
20
ALLOY 825
30% SO%,
30.20%
manganous acid
Research Research
>6
xx
<00001 0.0001 0 0005 IllI 0.0009 0.324 0 0015

0.110 0 0005
>6
>6 -
x
x
30.20%
Research
B.P.
28.2% Inltlally, 51.1% fInally. ferrous lo <o 2%, ferric bon <O.l%, chromrc oxide trace mrtially, alummum oxrde trace hnally
28.2% ferric mrtkslty. 57.7% finally, ferrous Ion <0.2%. 40 ~0.1%. chromic oxide trace initially, oxrde trace finally
Chemical
225
44
xx
0001
0 0008
Chemical
215
44
xx
0 0009
0 0007
aluminum 28% 21.8%
Research Petroleum
219 120. 150 218
.:
60 x xx <0.0001
0.0001 <0.0001 <0.0001
:F : 1
F
Research Pulp and Paper sulfuric sulfuric acid 25 g/l, acid 3%, iron 0.002% potassium chromium sulResearch Petroleum 1L
xx
0.0005 <o 0001

<o
00015 0001
15%
110
45
6.1%. 4%. late
160
129 60 x
x I x:
0.0031 0.007
0.0018 0.003
c ml
<0.0001
;F
: L
7590 212
<0.0001
aluminum-sulfate sulfur trioxide aluminum oxide,
saturated trace sulfuric
hquor.
some
crystals,
14
LO.006
0.005
0.002
acid,
water
Chemical
j F
220. 250 154 247 260
21
xx
0.014
aluminum
sulfate
(vapors)
\F
90
xx
xx :
0.022
0.008
aluminum-sulfate
slurry, sulfuric
acid 50%
Research
: 1
>6
x :
0.0002
nil
AMINES
amines in water, sodium chloride, sodium hydroxide 2%. organic chlorides and polymer, pressure 50 psig Ireboiler kettle)
i :
Petroleum Imethylamine manufacture) Chemrcal
iF
260. 268
41
-.-.I
0.0004
0.0003
0.0003
I
F 320
aryl amines, Iautoclave) 100% 100% 20% 20% 20% oxide
hydroqumone,
ferrous
chloride
0.37%.
98
I.
<0.0001
<0.0001
<0.0001
aminoethyl aminoethyl ammoethyl aminoethyl ammoethyl
ethanolamine, ethanolamine ethanolamme, ethanolamine, ethanolamme,
pressure
10 psig
Research Research
L L L L L
240 240 285 240 240
llll 0.0013 IllI 0.001 0.001
ml 0 0009 nrl 0 0068
pressure pressure water,
35 psig 10 psig carbon di-
Research Research Research
(continued)
Ferrous Alloys TABLE 4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM
467
kontd)
Corrosion mediums
Test conditions
0 .
*miner
h f
f
s
.
x
$ .
x
$ -
TWX
7PE
TIPL
ALLOY
20 825
304
0.0021
316
317
20% ammoethyl hydrogen sulfide 20% ammoethyl
ethanolamine,
carbon
dmxide.
Research
240
ethanolamine,
hydrogen
sulfide
Research Chemical
L F
240 250
1 14
ml 0.29
19% amme hydrochlorides, 12%. sodwm chloride 3%,
water 65%. ammoma ammonium chloride 1% water saturated
XX
10% ammoethyl ethanolamme, with carbon dloxlde 10% ammoethyl ethanolamme. with carbon dioxide 10% ammoethyl 10% ammoethyl ethanolamine. ethanolamine. and fatty
Research
240
nil
0.0002
water
saturated
Research
285
1 1
1 33
0001
0.0044
water water acids
(autoclave) (autoclave) tcaustlc for
Research Research Chemical
L L F
240 285 510. 555 510. 555
x
X
0.0002 IllI 0 0003
ml nil 0.0003
polyethylene ammes cleanmg kettles) polyethylene ammes cleanmg kettles)
xx
and
fatty
actds
tcaustlc
for
Chemtcal
39
xx
0 007
0 0004
oxlme IintermedIate in preparation of a monomer), hydroxylamine sulfate 10%. sulfuric acid 7%
Chemical (oxlmation)
105
XX
0.0007
0.0009
0.0035
AMYONIA
90% gaseous mixture bon dioxide and water 26% ammoma remamder lstill
wth
hydrogen
cyanide,
car-
Plastic
221
30
0.0001c
0.0001
0 0001
0.0001
vapor. carbon dioxide overhead line)
14%.
water
Metal tdlstdlationl Petrochemical tsynthettcurea manufacture) Chemical
180
65
xx
<0.0001
<0.0001
<0.0001
22%. water 71%, carbon dloxlde mtrate trace, pressure 29 pslg vessel, bottom)
7%, ammonium (ammonia surge
150
300
0.0003 SO.0076
<0.0001 s<0.0001
0.0004
<0.0001
20%, water solution of orgamc acids, methyl acrylates, ammonium carbonate. pressure 1000 PSI 20%. water, low carbon dioxide (ammonia vapors below liquid trapout tray) desorber,
302. 320 215
300
0.0001 0.0002 0.0033 so.0039
0.015a
Petrochemical (syntheticurea manufacture) Petrochemical kynthetlcurea manufacture) Petrochemical lsyntheticurea manufacture) Chemtcal
250
0.0006 SO.0006
0.0002
00002
20%. liqwd
water, low carbon dloxlde and vapors above trapout
(ammoma tray)
desorber,
150
250
0.011 so.019
0.0016 so.003
20%. trate,
carbon pressure
dloxlde 5%. water, ammomum 65 ps~g (absorber bottom)
ni-
270
300
<O.OOOl s<0.0001
<0.0001 s<0.0001
<0.0001
<0.0001
20% approximately, amme l-2%, ammoma
water vapor
solutlon,
monoethanol.
207
36
<0.0001
<0.0001
(continued)
468
TABLE

MOLYBDENUM
bmd)
Test
Corrosion mediums conditions
TPL
TWL
TWX
304 ----Ammonia
316
317
20
ALLOY 625
12%. carbon Immersed1
dmxide
7%.
water
remamder
(half
: lurea
manufacture) Mmmg
Chewcal
85
16
xx
0.078 LO.151
0.019
0.015
12-10x. oxygen 8%. merts. (second-stage leach autoclave.
pressure vapors1
100
pug
175
33
xx
xx
(0.0001 s<0.0001 0.001 so 001
<0.0001 s<0.0001 0.001 so.002
10-B%, first stage of ammoma leaching 01 nickel concentrates, nickel, cobalt, copper and ammomum sulfates; water solutmn. iron hydroxide and sulfide pulp. some sulfur sesquioxide and sulfur p-trloxlde, pressure 100 ps~g 10.8%. second stage of ammoma mckel concentrates, mckel, cobalt. ammomum sulfates. water solution. Pslg 9%. oxygen 14% mtrogen remamder 8% approximately, ammomum sulfates. clave) 8.4%. fates, mckel. cobalt, water solution. saturated wth (leach autoclave. water vapor. vapors) leaching copper pressure of and 100
: Mmng
170
30
xx
Mmmg
175
33
xx
0.0001 s<0.0001
<0.0001 s0.00015
Metal
170. 180 175. 180
III
xx
(0 0001 so 0001 <0.0001
<0.0001 s0.0001 <0.0001
mckel, cobalt, copper and water solution 150 g/l (auto-
Metal
107
xx
xx
copper and ammomum solids as copper sulfide copper and ammomum solids as copper sulfide
sol2% sol2%
Mlnmg
207
22
--
xx
0.0002 SO.OOSb 0.0001 so.005
0.0001 so.0002 0.0001

S0.007b
E-4%, mckel, cobalt. fates, water solutlon, (copper boil rebodet)
Mmmg
215.
34
xx
225
0.4%. mckel, cobalt, copper and ammomum sulfates, water soluhon, solids as copper sulhde 2%. vapors of ammoma 4.5% and water vapor (copper boll reboilerl
Metal
215
95
xx
_0.0001
<:0.0001
225
5%. oxygen 9%. saturated wth water vapor,

mtrogen remamdet (leach autoclave)
Metal
170. 180
200. 204 214
107
xx
xx
10 0001 s<o 0001
\o 0001 s<0.0001
<O.Lml s<o.O001 <O.OOOl so.003 <O.OOOl
3.5% approximately. ammonium sulfates, 2.1%. pmg water autoclave) vapor.
nickel, pH 10.2 pressure
cobalt, (stripping
copper and autoclave1 (strip-
Metal
100
xx
j : :
<O.OOOl s<0.0001 <0.0001 so.002 <O.OOOl
lo-15 psig
Mining
:F
F
23
xx
1%. ammoma liquor. coal gas (tar decanter) 1% approximately,
hydrogen
sulfide,
trace
of
Coal Byproduct
155. 175 75
63
ammonia
hquor
Coal By product Coal By product
318
xx :
x xx
nil
0.5% fixed ammonia, ammoma still liquor, steam, calcium chloride, calcium sulfide, calcium cyanide, no free ammonia ammoma. and cupric ammonium chloride chloride, cuprous chloride
230
144
0.0001c
<0.0001c
Chemlcaf (ammonolysis)
420
36
<0.0001
0.0002
ammoma stdl waste, calcium acid, manganese sulfate l-4 ammonium chloride traces, pfi
chloride. sulfuric g/t, organics and l-2.5
Coat By
product
.F
170
13.5
xx
(continued)
Ferrous Alloys
469
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
TPl
TIPE
TIPE
304
ammonia liquor. steam, ammonium chloride, cyanlde and thiocyanate, hydrogen sulfide, calcium chlorrde, phenol. complex iron cyanide compounds (bottom of free still) ammoma vapors. hydrogen sulfide. carbon droxrde, phenols, hydrogen cyanide and steam (ammonia stdl. vapor outlet1 Coal By product F 240
316
317 ---
"20"
ALLOY
a25
<O.OOOla
<O.OOOla
Coal Byproduct
220
144
xx
<o 0001
<0.0001
AMMONIA
ANHOROS
lrquld ammoma, PW liquid ammonia, ganic chlorides, 99.1X, saturated ammonia ammonia vapors1 inerts
ammonuon
acetate,
pressure
1200
Research
483
0.2
1.06 x
0.002c
0.014
amines. polymer, 0.9% (line)
ammonium chloride, pressure 850 psig
or-
Petroleum
190
90
0.0006~
iF solution in liquid
932 68. 80 95
64
2
xx i --
0.0995 nil
>0.52 nil nil
ammonium-bromide
:L
Chemical .F
anhydrous.
ethyl
amine
trace
(column.
102
xx :
0.0001
0.0001
AMYONWM
BICARBONATE
ammonium
bicarbonate
185
61
xx
0.0007b
0.022 O.OOOla
AMMONIUM
CARBONATE
ammonium
carbonate,
ammonia,
pH 9-10
.Chemical
85.
41
0.0001
0.0001
115
AMMONIUM CHLORlOE
75%. isoptopanol. 6.5.8 5 75%. 658.5
water,
sodrum
chloride,
ptf
Chemical
120
183
! I :
0.0006~ SO.OOOBb 0.0003 s0.0007 0.0003a S0.0009a
<O.OOOlb S0.0005a 0.0002 s0.0004 O.OOOla S0.0002a
<0.0001c
<O.OOOlbd
<O.OOOlbd
isopropanol. water, (transfer line)
sodium
chloride,
pH
Chemical
120
12
0.0003
0.0002
0.0001
75%. rsopropanol. water, saturated with sodium chloride. some hydrochlorrc acid. some free salt, pH 6.8 (top cover of filter tank.1 75%, rsopropanol, water, excess of sodium Ide crystals, pH 5.7.5 (transfer line1 33%. water 34%. zmc chloride 33% 3%. chlor.
Chemrcal tfiltratlonl
120
13.5
0.0002a
0.0001
0.0001
Chemical
140
41
xx
0.0005ad S0.0008ad 0.0013c
0.0003ad S0.0005ad 0.0001c <0.0001
0.0003d
0.0002d
<O.OOOl
1 Chemical F
140 86. 176 194
33 68
__I x
lS%, sodium ammoma 2%.
chloride 8%, water (tubular
carbon dioxide gas cooler)
<0.0001
14.11%. water, some hydrogen sulfide, mercap tans and a nonabrasive solid (Texas reactor) 0.25%. recirculated water free sulfurrc acid 0 2.0.43%. 0.25%. recuculated free sulfurrc acrd scrubber) for scrubbing gases, pH 1.6.10 (pipe line) scrubbing gases, pH 1.6.10 (gas
Rubber
11.5
xx
0.0005c 0.0076 0.0006
0.0002
Chemrcal
120
8.5
xx
xx
0.0004
0.0004
water for 0.2.0.43%.
120
11
xx
xx
0.0004 <O.OOOl
<0.0001
co.0015
(continued)
470
TABLE

MOLYBDENUM
bmd)
Corrosion mediums
Test conditions
2 G : g . .
ammonrum chlorrde, sodum sulhle Chemical F 140. 147 140. 147 150 30
304 -----
TYPL
316
,PE
317
TPl
20
ALLOY 825
<O OOOla
<O.OOOla
ammonium
chlorrde,
sodrum
sulirte
lvaparsl
Chemical
30
<OOOOlb
<0.0001
0.0025b 0
ammonrumxhlorrde tals, glutamcc acrd crystalluerl
slurry, sodrum-chlorrde and other ammoacids
crys. (vacuum
Chemrcal
96
0005c
0001
50% to anhydrous fled ore 45%, trated
ammonrum
brfluorrde.
unidenti-
Metal
80. 390 230. 260 60
IO
xx
CO 0096
00071
suspended ferrous (batch digester)
titanate,
bung
concen-
Mmmg
0 127
LO 101 30 0
0011
34.5%. glass-etchmg solutron, total hydrofluoric acrd 30%. free hydrofluorrc acid 24.8%. combmed ammoma 12 5%. sodrum fluorosdrcate 11 5%
Glass
165 0 177
0.04
20%. trtanwm
15%. basrc ammorwm
fluorrde
8% excess. pli moderately
Mmmg Chermcal
1 L
R T. 125 94 xx
0.018 <0.0001
0 0018 <0.0001
<O.OoOI
hydroxrde
10%. glass-fortrfyq solutron. hydrofluoric acrd total 8.75%. sodrum floorosdicate 8.55%.. free hydrofluorrc acid 4 9%, combined ammonia 4 6% 10%. water solubon solution solutron. traces, hydrofluorrc acid, pH from hrghly acid
Glass
45. 80
30
0 0108 0.0082
0.0067
F Research Chemrcal L
77 200
61 >6 28 -
-
x x
0011 0.150 0 077
0.0095 0 140 0.047
0.0013
0.0005
6%.water
ammonwm.brfluor~de sulfuric acid and to highly alkaline
iron
R.1: il P.
66%. 65%.
free ammonia free ammonra
17%. 21.7%.
water water
17% 13.3%
Petroleum Research
F 1
R.T. 128
715 14. 20 300
x x
<o 0001 0 0284 0.0127 <0.0001 s<0.0001
<0.0001
0.0286
(0.0001
ml
<0.0001 <O.OQol
20X, water and carbon dloxrde traces, pressure 30 psrg (bottom of ammonra desorber, vapors)
Petrochemical Isynthetrc. urea manufacture1 Petro. chenucal
290
<0.0001 s<0.0001
ammonun
nrtrate.
free
ammoma
89
IllI
nil
24% approximately. perchlorate 7 6%. Icrystalhzer)
sodrum chlorrde 23%, sodium chlorate 0.2%.
sodium pH 4.8
Chemrcal
175
138
xx
c-0 0001
<0.0001
<0.0001
(continued)
Ferrous Alloys
471
TABLE 4.13:
VARIOUS
STAINLESS
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
TWE
WPE
,.E
304
316
317
"20"
ALLOY 825
ammonium monophosphate, saturated water solu tion 40% rpproxbrtely. ammonium monophosphate
Chemtcal
82
150
<O.OOm
<0.0001
<OOOOl
.,.
Chemical Chemical Chemtcal
L F
140 122. 158 212. 250
22 30 12
xx xx
x x
<0.0001
<O.OoOl 0.006 0.03la 0.001
ammonium phosphate, water. sulfuric acid 3% ammonium phosphate traces in steam; ammonia, ammonium sulfate, fluorine compounds and silica traces present (agitator)
0.001
ammonium silicofluoride, monia
alkalme
solution, am.
Chemical
110. 130
28
<O.OOOl
<0.0001
ammonium sulfate, saturated water solution, sul(uric acid 5% ammomum sulfate, saturated water solutton. sulfuric acid 5%, some crystals tcrystallizer) 40% approximately, hydrogen sulfide, free ammonia trace tautoclave. vapors) 30% apprOXimately. sulfuric actd 0.75%. ammonia added with the acid, and 20% ammonium sulftde 2 gal/600 gal approximately of reacted solution 36%, sulfuric acid IO%, sulfur droxrde 0.3% 6% apprOXimately. ruconium-hydroxrde slurry 0 3 lb/gal, pH 8 (vacuum drum hlter) 6% approxheately. zirconium-hydroxide slurry 0.3 lb/gal, pH 8 (vacuum drum filter) 3.2%, pH 5 1.01 sb, pH 8 ammonium sulfate, sulfuric acid (vapors) ammonium sulfate, sulfuric acid (filter)
Coal By product Coal By product Muting
IOO116 IOO116 140. 160 150. 200
33
<O.wol
<o 0001
ml
33
0.0001
--
0.03b S0.24b xx 0.339.c 0.75c
S0.03b
Chemtcal
0.024
Chemrcal Chemrcal
180 135 150
25 50 50 -
x x x
0.0075c <o 0001 <0.0001
0.0014
i ; i
Chemical
xx
Research Research
;1
;L
105 105 >230 125. 145 145. 165 155. 175
128 101 9 77 -xx! -
xx
corr 0.027 O.oool
nil 0.0068 0.0001 0.00014 0.0001 0.0007
C nil 0.002 0.002 C<O.WOl 0.0016
: i Chemica i Chemical i : i Chemical : : i

Chemical
xx
0.0035a
ammonium sulfate, sulfuric acid tcrystallixer)
77
0.032
0.004
<0.0001
c<0.0001
ammonium sulfate, sulfuric acid (crystallizer)
77
0.002
0.001
0.001
C<O.OWl
:
Chemical
ammonium sulfate, sulfuric acid, ammonia
.>230
xx
0.0003
0.0005 0.042 wo.01 0.04
0.001
c0.0004
ammonium-sulfate ammonia
slurry, sulfuric acid 412%,
Coal By product
221
15
0.045
CO.008
ammomum-sulfate slurry, sulfuric acid 1.4%
Chemical
;F
212
36
xx
<0.0001
<O.OoOl
<0.0001
(continued)
472 TABLE
Corrosion Resistant Materials Handbook 4.13: VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bmd)
Corrosion mediums
Test conditions
r- # . Chemical
P
TIPE
TYPE
316
0.0005
,PL
304 ----x
317
20
ALLOY 625
mlxlures of dilute or saturated free sulfuric acid 1 5%
ammonium
sulfate,
:F
221
13
xx
0.0008
55% approximately.
tap water 0.5%. ammonium sulfide 0.1%
Agriculture Chemical
1
f
120 230
2-6 31
xx
x
xx
0.0022 0.0002
<0.0001 <0.0001
35%. lbotler)
ammoma
31%
approximately
Coal Byproduct sulhde 1% pli 5 7 apChemical Coal By. product Coal Byproduct tap water Agriculture Coal By product
RI
27
<0.0001
<o 0001
<o 0001 to
0001
30%.
ammoma
5%. ammomum
F F
70 154
31 17 x
<0.0001 00001
30%, ammonwm.thlocyanate proximately (outlet from 20% approximately. thiocyanate scrubber) 10.7% 6.2%. approximately. water solutlon
vapors. evaporator) gas
coke-oven
tammonlum-
118. 133 120 63. 90 212
61
0 0006
<0.0001
L F
2.6 14
xx --
0.004 <0.0001
<0.0001 <0.0001
ammomum toluene
thlocyanate,
hydrocarbons,
water
vapor.
Coal Byproduct
16
xx
xx
0 044c O.OOlc
0.0002a
17%
approximately,
up to
saturation
(evaporator)
Metal tevaporatlon)
220
30
xx
OOOlb
0 OOOlb
OOOOla
AYYL ALCOHOL
12X, sodrum oleate 58%. water 189,, amyl chlorides 10%. amylene 2% durmg 77 days, sodwm oleate 58%. sodwm chloride 25%. sodwm hydroxide 19, and water during 77 days fslde near bottom of dIgester)
Chemical
340
154
00001
00001
AMYL CLORlDE
amyl.chlorlde brme. iamylene column)
sodium
hydroxide
0 35,
Chemical
175
!20
00001
0 0001
amyl chlorides mrxed, sodrum hydrochloric actd. ferric chloride amyl chlorides ferric chloride
chloride. traces and water tplpel
of
Chemvzal
R.T.
50
xx
<00001
<0.0001
mlxed. traces of hydrochtorlc and water [pump discharge)
acid,
Chemical
R.T.
50
xx
0.0044
0 0032
AML
CINNAMK
ALOEHIOE
amyl
cmnamlc
aldehyde
Chemical
30
ml
Ferrous Alloys TABLE 4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX Test conditions MOLYBDENUM
473 (am4
Corrosion mediums
Average corrosron rates (ipy)
*WE
,PE
,PL
ALLOY
"20"
-----
304
316
317
825
amylene.
amyf chlorrde
trace
lvaporsl
Chemrcal
175
23
0.0001
amyl mercaptan. ethanol. water, amyl chlorrde. drogen sufhde trace (top of column. vapors)
hy-
Chemrcal ldrstrllationl Chemical
212
69
OOOla
0001
wo0009
0.105 WO 161
amyl mercaptan. sodrum hydrosulfrde, amyl chlorrde. ethanol, water, sodrum chlorrde. pressure 250.300 psrg amyl mercaptan. ethanol, brrne. amyl dramyl suffrde. hydrogen sulfide trace chloride.
285
40
0.061 wo 086
coo095
Chemrcal fdrstrllationl Chemrcal idrstrtlatron~ Chemrcal fdrstillatron) Chemrcal fdrstrllation~
230
69
0.0001c wo 0005 0 0005c wo 0023 0 OOISC wo 0018 0 0007a woo019
O.OOOlb W0.0005a 0 0004b wo 0013 0.0005a WO.0018 0.0003 WO.0016
amyl mercaptan, ethanol, brrne. amyl chloride, dramyl sulfide. hydrogen sulfide trace fvapors) amyl amyl amyl amyl mercaptan, dramyl sulfide. amyl chlorrde. alcohol, ethanol, water, hydrogen sulfide trace mercaptan, dramyl sulfide. amyl chlorrde, alcohol, ethanol, water, hydrogen sulfide trace
250
74
322
78 78
285
amyl phenol, acid (vapors) amyl phenol, sulfonrc acid, amyl trace,
sulfurrc
acrd,
phenol,
phenolsulfonrc
Chemrcal fdrstdlatronl Chemrcal fdistdlationl Chemrcal
390
50
<0.0001
<0.0001
phenol. sulfurrc
caustrc-neutralrzed acrd trace sulfuric bottom) acrd,
phenol.
390
50
0.0001
0.0001
...
phenol, phenolsulfonrc acid. lmely drvrded clay trace ttank phenolsullonrc
acid
195
106
co,,
CO,,
amyl phenol. phenol. acrd trace (vapors) amyl phenol (vapors)
sullurrc
Chemical
195
106
0.0011
0.0009
...
Chemrcal fdrstillation) acrd 0.14% Chemical
390
96
0.0001
0.0001
...
amyl
phenol,
phospharrc
390
37
o.ooOa*a
0.0008a 0.0031b 0.0027a 0.00016
0.0002a
. . .. . .. .
amyl phenol,
phosphorrc
acrd 0.14%
fvaporsl
390
37
0.0022a
dramyl phenol, still kettle)
potassium
hydroxrde
1.2%
(batch
Coal Byproduct
230
15
<0.0001
andine. carbon drsulhde, hydrogen drsullrde. captobenzene, thrazole etc lautoclave)
rner.
Chemrcal
390. 518
230
0.00015
0.00025
c0.0002
antibrotrc fermentation medra, neutral, sometimes hydrochloric acrd acrdrfred. once sulfurrc acrd acidified to pH 2 5, occasronally sodrum hydroxide alkalized to pH 10.5 (tank bottom head)
Pharmaceutrcal
.F
75
27
SO.OOOla LO OOOlcd
nd a L nd a
ml a
nil
nil
(continued)
474
TABLE

4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX (mntd)
MOLYBDENUM
Corrosion mediums
Test
conditions $ r t 2
x s s s $f . . .
r
r : S
TIPE
304 ----ml ad
316
TYPE
1PE
317
20
ALLOY
625
antlbmtrc
APf
(evaporator)
I
vapors)
Pharmaceutical Pharmaceutical
150. 180 125. 150
25
1 II
antlbrotlc
APF
(evaporator.
25
O.OOOld
L ml
antibloW spent-beer acetate or acetone, pH 7.5 average antibIotIc spent-beer acetate or acetone, pH 7.3 average organrc lvacwm penicdlm preppratlo evaporator) broth
solutlo, water 90%, Methahne chloride
amyl trace,
Pharma. 1 ceutical ! : :
Pharma. ceutical f 172
42
xx
<o
0001
<0.0001
<0.0001
<0.0001
solution. water 90%. Methaline chloride
amyl trace,
42
--
<0.0001
<0.0001
contammg
ferric
IO. pH
7.0
Pharma. ceutlcal Pharmaceutrcal (fermenta. tionl Pharma. ceutlcal Ifermentatlonl Pharma. ceutlcal (fermenta. tlonl
390
61
<O OOOla
<O.OOOl
... ... ...
... ...
75
60
II
II
penullm
R.T.
144
0.0001
<0.0001 10.0001
penwllin
75
42
xx
<0.0001
<0.0001
streptomyon
media,
pH 6.2.8
Pharma. ceutical (lermentabon) Pharma. ceutlcal
85
56
0.0001
0.0001
..
..
streptomycm
media.
pti 2.0
RT.
46
00001
0.0001
antimony chlorofluorides. orgamc chlorofluorides. anhydrous hydrofluorlc acid, hydrochloric acid and chlorme Ipressure vessel) antimony chlorofluorldes. orgamc chlorofluorldes. anhydrous hydrolluoric acid, hydrochloric acid and chlorme Ivaporsl antlrnony <05% trlchlorlde. some hydrochloric acid, water
Chemical
200
35
0.0003
0.0002
Chemical
200
35
0.0018
0.0012
Chemical
212
12
xx
0 036
0.0002
0 0016 0 0025 0.0027 0.0009
0.001
0.0083 0.0089 0.0067
antimony trlchlorlde. i 0 5% (vapors1
some hydrochloric
acid. water
Chemical
2i2
12
xx
0.081 0.0054 0.008
0.0003
0.009 0.0029
antimony trlchlorlde 93%. alummum chloride system blanketed wth hydrochloric acid
7%.
Petroleum
0.003
apple pomace mush, sodmm tetraphosphate O.l%, hydrochloric acid 0.05%, mahc acid 0.05%. pH 7017
food
18
xx
0.0001* 0.0001
O.OOOld
(continued)
Ferrous Alloys TABLE 4.13:

VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX
475 hontd)
MOLYBDENUM
Corrosion mediums
,wt
UPC
TIM
ALLOY
20 a25
304
316
317
37.5%. sulfuric acid corrosro machrne) 37.5%. sulfurrc Immersed1 acrd
6.24%.
waler
lcircular.path
Agrrculture
a5
xx
0 00018
0 00018
6.24%.
water
(beaker,
half
Agrrculture
85
xx
0 0036
II
ascorbrc
acrd itop 01 leed
hopper1
Chemrcal
65
0 0001
0 0001
ASPN.I
asphalt converter, overhead au blow, hydrocar. bans. other organrcs, salt water (enters top at 35 fl. oxygen, sulfur dmxrde, mercaptans (asphaltplant gas scrubber) acrd
Petroleum
IOO500
xx
xx
0.0245~
0.0109c
0059c
0.0196c
0.0105c
heavy asphalt, crude 011 contarnmg naphthenic (vacuum-drstrllatmn tower, flash section1
Petroleum
650. 750
xx
0.0016~ 0 0005c
0.0001
<0.0001
0.0001
0 0001
atmosphere
at Bayonne,
N 1. (sheltered)
RI.
4340
xx
I
I
<O.OOOlb
II
II
atmosphere
at Bayonne,
N. J (exposed)
R.T.
4340
xx -
II
IllI
<0.0001
II
exhaust humrdrty
mme air, 100%
sulfuric
acid
0.14%.
relative
Mrnrng
60. 65 R 7.
70
xx
xx i
O.OOOld 0 OOOld O.OOOlbd O.OOOlcd 0 0006 0.0024b b
damp sullur-laden tunnel at Tuelto, locomotrve
atmosphere, w Va.) and steam
(Kmgwood
radroad
Rarlroad
407
xx
<OOOOlb
flue gases
ttunneh
Radroad
RT.
1775
an. at Baton industrral
to
Rouge. La., chlorides pollutron (Braun-Esso Rouge, La., chlorrdes pollutron (Braun-Esso wrth water, small
and sulfates compressor) and sullates compressor) of dust
due
RT
30
xx
<o 0001
<0.0001
<.00001
arr, at Baton to industrral au saturated
due
RT
158
xx
xi
xx f <0.0001
<:0.0001
amounts
Mrnrng
61
31
atmosphere ocean
at
Kure
Beach,
N. C.,
800
ft
from
R T
5474
xx
~:ooool
atmosphere
at Shore
Rack
and Kure
Beach,
N. C.
I i I
Research
jF :F :F
R.T.
36C
xx
xx ;
nil
<O.OBOl
. .. . .. .. .
... .. . .
(continued)
atmosphere
at Shore
Rack
and
Kure
Beach,
N. C.
Research
R.T.
1700
xx
xx
<0.0001
<O.OWl
atmosphere
at Wdmrngton.
N. C.
Marine
R.T.
200
xx
xx :
<0.0001
<0.0001
476
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
conditions
5
r
x
TPE
.
atmosphere at Wdmington, N. C.
Marine F R.T.
. xx -
I u .
304
1
<0.0001
----
316
TIPL
317
E"PE
20
ALLOY
825
160
<0.0001
...
atmosphere at Passamaquoddy Dam. Maine
Marme
R.T.
270
xx
ml
<0.0001
...
atmosphere of coast just south of San Francisco, Calif.
Powel
R.I.
184
<0.0001
<0.0001
...
ATUOSPHLRE.
PLANT INTERIOR
air, occasionally solvents and water hot air saturated with water vapor. pH of condensate 1.2 (paper drler) ozonated air, oxygen 5 mgll, nitrogen pentoxide 0.1 mgil approximately (ozone generator) air saturated with chlorine, chlorine 0.013 vol % air saturated with water, some sulfur dtoxide (economizer) hot moist au (paper machines)
Rayon Pulp and Paper Samtary
F F
70. 125 120
105
xx <0.0001
0.0001 <0.0001 ..
0.0001
330
xx
R.T.
60
xx
x I
0.0001 0.0003 0.124~ <0.0001
0.0004
...
... ...
Pulp and Paper Pulp and Paper Pulp and Paper
F F
63 110
35
--
0.118~ nil
35
xx
120
189
xx
0.0001 0.0001 : <O.OoOl
0.0001
.. .
av. caustic fumes. ammoma fumes 0.005%. mldlty 100%
hw
Metal
40. 110 R.T.
t 2&l
xx
<0.0001
...
au. some vapors of hydrogen sulfide and carbon disulfide (rayon-spmnm&room roof) air. humldlty high, probably sulfur compounds as sulfur dloxlde atmosphere, humldtty high. fumes and vapors of vinyhdme chloride. methylethyl ketone air, humidity htgh durmg 34 days, and air, humldlty high. ddute acetIc_acid vapors durmg 20 days (tilt drier) atmosphere. humldlty 100%. in which salt dust and steam flow periodlcally air, humldlty high. lacquer residuals
Rayon
152
xx
0.0001
TextlIe (wool1 Celloohane
175
56
xx
xx :
0.0008 0 0007 0.0001
0.0004
225
95
xx
0.0001
Synthetic Rubber
240
54
xx
ml
ml
Salt
75. 140 MO200
365
xx
<O.OOOld
O.OOOld
...
Pulp and Paper
28
xx
xx
0.0001
0.0001
0.0001
batwm chlbrlde. saturated water solution 30%. solution repeatedly evaporated 25%. water solutton. free chlorine, pH
Chemical Chemtcal
1 1 F F
R.I. 212 95 176
2.4 2-4 11 28
<0.0001
:
.. . ...
0.0001
1 :
Chemical Coal Byproduct
xx
20%, hydrochloric acid excess. sulfide trace, pH 2-3
0.25~
.. .
0.042cd
(continued)
Ferrous
Alloys
477 kontd)
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
Corrosion
mediums
Test conditions
Average corrosion
rates (by)
VVPE
VW1
VVPE
ALLOY
20 825
304 P--P-
316
317
barwm ltrate
Chemical
85
xx
0 005c
spent beer. orgamc actids and their salts, lactic acid 0.5%. dtcarboxylic acids. olyacids. tnccs 01 lormlc. acetic, prop~omc and bulyric acids beer. water 5%. alcohol. orgamc acids. ptt 3.4-3.7 beer tlermenter, vapors. hqudi beer ifermenter) beer topen fermenter) ale beer l8eaudelot cooler1
Brewing ~d~stdlalionl
212
105
<0.0001
<O.oooI
Btewm9 idlstlllailonl Brewmg Brewmg Brewmg Brewing Brewmg
F F
212 45. 55 R.T.
87 8
<O.OOOld nil
<o.ooo1
F f f f
40 75
<O.oOOl nil
<o.oM1 . .
R.I. coot
70 32
II <O.O!MI
...
.. .
BENZENE
98.5%. methytaldehyde 0.5%. lornuc acid ~~0.5%. formaldehyde cO.5%. methyl tormate. ek 99.3%. water 1.5%. acetic acid 0.04%. posdlon gases 0.02% 95% approximately. sullur~c acld 45%. lies from crude benzene lwasherl decom.
Chemical
200. 220 170
13
xx
0.0012
o.Ocul7
275
xx
O.OOOI
0.0001
Impuri-
Coal By product Chemical
122. 140 80
44
xx
0.0668cd co,,
co,,
90%. hydrochloric acid 5%. water 5%. chlorinated benzene benzene, water
60
0.02lcd
0.014cd
Pharma-
70
42
<O.ODOla
0.0001
50%. chlormated benzene JO?.. hydrochloric acld 5%. water 5% benzene. oleum, probably some sullur dooxide and trloxide tvapori during first 12 hours) benzene. furnace vapors. water. acetic anhydride, decomposition gases benzene, toluene. xylene. thiophene, condensed vapors. hydrogen sulfide, sulfur dioxide, oxygen, water benzene. toluene. xylene, some ammonia and solfur dioxide Icondenser. condensate)
Chemtcal
80
60
x-
0.05 I
0.054
Chemical
365
1.5
1.
xx
0.47 0.43 0.0019 0.0021 0.0007bd 0.0005
0.77 0.73
220
275
xx
0.0011 0.001
Coal ByDroduct
113
27
Coal By product (tar distillation) Coal Byproduct tlractionationt
181 250
74
xx
0.0061~
0.0012a
.. .
.. .
benwe. totuene. xylene. hydrogen sulfide, thiophene, sulfur dioxide, sulfur, oxygen, steam (light. oil condenser, condensate)
53. 155
28
0.0002bd
0.0001
. .
(continued)
478
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Average corrosion
rates (iPY)
TIPE
TIPE
TIPS
304 ----benzene. toluene. xylene. crude steam tlrght-ml strrpper, vapors) light oil and Coal Byproduct Coal By product ffractronationl F 190. 210 <0.0001
316
317
20
ALLOY a25
<0.0001
benzene. toluene. xylene, thiophene, hydrogen sulfide. oxygen. water, sulfur flight-oil condenser, vapors1
115. 257
28
0.0034bd
0.0003b
. .
benzene, totuene, xylene. throphene. hydrogen sulfide. oxygen, water, sulfur llight-orl condenser, vapors) benzene, vmyt acttale. some water
: :
Coal Byproduct
95 220
27
--.
0.0013bd
0.0005b
...
Plastrc
85. 105
156
x--
<0.0001
<0.0001
<0.0001
BENZENE
HEXACHLOR,DE
90%. 45%. 25%. 25%.
methanol, methanol, methanol, methanol
sodrum nrtrate sodrum ndrale sodrum nrtrate
0.5% 0.5% 0.5%
Research Research Research Research
L L L L
230 155 150 150 6
0 93 0.083 0.022 1.6
0 005 0.0047 0.004 0.12
BLNZOYL
CHLORIDE
benzoyl chlorrde benzoyl chlorrde
fvaporsl
Chemrcal Chemrcal
L L
75
R.T.
30 14
0 0042 0 0033bd
0.003 0.0008d
q.ORlC AClD
10%
50% 30% 15.7% 2.5% approximately treboderf
Chemrcal
I
L
302
_-
0.35 0.245 0.045 0.025 <o 0001 0.0001
302 302 75
1 1
---
Chemrcal Research Chemrcal rdrstrllatronl sulfates. mrxed hquor Chemrcal tborrc-acrd manufacture) Chemrcal Chemrcal
70 45 xx
195
<0.0001 0.0002 0 004gcd O.OOlb
bow
acrd. borax, sulfdes,
130. 220
45
xx
0.0001
borrc acrd. solutron borrc acrd, sublrmed,
saturated impurrtres
with sulfur dioxide
F F
140 130. 220
31 45
xxxx xx
x.0 OOOld 0 0047cd 0 002cd
\O.OOOld 0.0002a
99%. chlorine trace, dry except whdn hydrochlorrc and boric formed by hydrolysis
durrng shutdowns, acid traces are
Chemrcal
55.4
67
xx :
0.0003
0.0007
(continued)
Ferrous Alloys
479
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
TPE
TIPZ
TIPS
ALLOY
"20"
304
316
317
825
0.0019
95%. chlorme 5%. dry except during shutdowns. Chemrcal when hydrochloric and boric acid traces are formed by hydrolysis; ferric chloride and alumi. i nom chloride traces fcondenserl boron trichloride, chlorme. ferrrc urn chlorrde, srhco tetrachlorrde chlorrde. alumi. (filter inlet1 Chemrcal (filtratro)
I :
j F
53.6
60
xx
0.0021d
:F
158
24
xx
0.0019
0.0008
14%.
hydrolluoric
acrd 0.2%.
low pressure (vapors)
Chemical (drstillatronJ Chemrcal Idrstrllation)
F F
F
212
2.8
0.29
0.32
0.068
0.046
14%.
hydrofluorrc
acid 0.2%.
low pressure
212
1.7
xj
0.73
0.22
0.13
0.075
<1.5%.
aromatrc
solvents.
cresols.
water
trace
Coal Byproduct
203
15
xxx;
00013
0.0011
0.0012
0.0011
0.155%. (Nevillac
polymerrzed reactor)
hydrocarbon
oils,
pH 3.4-6.7
Chemrcal
77. 257 105
19
xx
0.024
0.012
boron trifluortde. some hydrofluorrc denser)
polymerized hydrocarbon and lluoroborrc acids, water
oils, Icon-
Chemical (distillatron)
IF
I F
105 230 302
92
<0.0001
<0.0001
boron trrlluorrde trace, polymerized hydrocarbon 011s (vessel bottom) boron trlfluorrde ether1 boron trrfluorrde canter) anhydrous. anrsole
and neutralized
Chemrcal
:
(methylphenyl Research
17.5
xx
0.0029
0.0009
32
0.0003
anhydrous,
fluorides,
pH 4.7
(de-
Chemical idtstrllationl
77
154
xx
<0.0001
<0.0001
boron-trilluoride etherate I hydrocarbon srbly slight hydrolyses of boron trrfluorrde bororvtrrfluorrde etherate m hydrocarbon sibly shght hydrolysis of boron trifluoride 1.5 vol%. 150.5 waler varrous crude hydrocarbon various unsaturated
011. pos-
Chemrcal
70. 135 70. 135 178 165
42
xi
0.001 0.002 0.0007 0.0003
0.0005
011. pos(vapors)
Chemrcal
42
x--I
0.0005
mrxtures hydrocarbons,
Chemrcal
IhI
F F
15 12
-xxx; xxj
0:027*
0.023 0.009 0.005
~01%. O-O 08%
0.009
BUTANE
90%.
rsobutane
1%. acetic
sod
0.5%.
water
0.5%
Chemtcal
185
276
II 0.0003 <0.0001
II
0.00015 <0.0001
99%. acelrc acrd 1%.

bon droxrde 65%. acetrc acrd IO%, water 3%
ketones.
esters.
water.
car-
Rayon
66. 113 125
363
xx
carbonyls
and esters
22%.
Chemical
108
x-
II
II
LII
x ,OOOOl 0 0002 <0.0001
60%. waler, ethyl acetate, methylethyl methyl acetate, acetone, esters, ketones. 56%. varroos organrcs 27%. nrtrogen 10%. acrd 4%. water 2%. carbon droxrde 1%
ketone. alcohols acetic
Rayon
131. 156 347
360
0.0001
0.0003 0.0003 0.0002
Chemrcal
210
xx
xx
(continued)
480

bnt'd)
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
Corrosion
mediums
Average corrosion
rates (by)
TWE
TIPE
WPE
304 ----20%. mlrogen 65%. acids hnainly rcelwt. esters and water 20%. mtrogen 75%. oxygen OS%, light hydrocarbons. acads and esters remamder 20%, nrlrogen and carbon dioxrde. water. hetones. esters, aldehydes trace butane. butylene. dibulyl suthle. sutlur~c acrd. waler trace tDBS debutanwer bottom1 bulane. dry hydrochtorlc acrd. powbly some tar rerldue arid morsture, pressure 250 psi (vapors) butane. some sulfur &oxide and dibutyt sulfate llop of separator, gas stream) Petroleum Pelroleum Chemrcal f 340 0.003c
316
o.owBa SO.OO12b nit 1 ml 0.0001
311
..
"20"
ALLOY
625
Chermcal
125
lo8
nit
...
86. 113 250 225. 250 115. 120
363
xx
0.0001
F f
52 44
XI
0.006b O.OScd
0.002a 0.0487bd
Petro. chemical tfractionalion)
49
<0.00016
o.oow
RUYANOL
99%. carbonyts 0.3%. esters. heavy alcohols trace 97.96%. hydrochloric aud 3-496
Chemical Pharma. ceuhcal Chemical
265
277 18
XI
IX -
o.wO35 0.0257a 0.014sbd
R.T.
f 250
62%. waler 8.59%. l.l.S%
higher alcohols 8%. carbonyls
243
xx
<O.OoOl
9%. tugher alcohols B%, carbonyts 0.5% 5%. water 95% 5%. water SO%, melhyl and ethyl alcohol 5% butanol. propanol Itogether 42.3%). waler 30%, carbonyls 3.8%. acelals 0.9%. sodium formale and acetate bulanot. benzene. dlbulyl phthalate (vapor line1
Chemrcal Chewat Chemical F F f
265 195 IS5 230
243 39 39 371
xs x x
<0.0001 0.0018 000013 0.003 <O.oOoI nil 0.002 nil
xx
Chemical tdrstrttal~onl
I70 380
44
(0.0001
<O.OOOI
BYYERYILK
see LACTIC
ACID
BUYYL ACEYYL
RlClNOLEAYE
bulyt acelyt rrcmoteate. charcoal. acetu acrd trace I)TL

PHENOL
140
60
--
0.0002
0.0003
paratertiary butyl phenol. formaldehyde, turpentine, boron triflooride, oxahc acid

TIN CHLORIDE
Chemical
392
75
0.0098
0.0014
o.ow7
0.0004
(DI-) BUTYL
dibuiyl tin chloride, molten lhalf immersed)
Chemical
130. 140
28
0.0001
<O.oool
06%. water 1.3%, botyric acid 0.7%
67
136
I-
<O.OOOl
nil
<0.0001
(continued)
Ferrous Alloys
481
TABLE 4.13:
VARIOUS
STAINLESS
STEELS AND HlGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosionmediums
Test conditions
Average corrosion rates (by)
mr
1WE
ALLOY
3;; 20 825
.
NUTIRIC AClD
304 P-P--
316
60%. sulfuric acid lo%, remainder unknown 2520%. acetic acid 40.45%, propionic acid 510%, formic acid 0.02%, sodium chloride 0.01.0.05%, hydrochloric acid trace butyric acid, small amounts of manganese Sulfate, magnasmm sulfate and water (vapors) butyric acid, propionic and acetic acids together 97%, formic acid 2%, water 1% butyric acid, propionic and acetic acids together 20%. some sulfur dioxide, water remainder (vapors) 3%, heavy ends 95%, propionic acid 1.5%. acetic acid 0.05%
Chemical Chemical
F F
330 105
10 38
I xx
0.26C
0.024 0.003
0.012 0.002 0.002 0.004
0.003
Chemical (distillation) Chemical
212. 250 248
32
xi
<0.0001
<0.0001
<0.0001 O.OWl .
f
F
315
xx
0.015
0.003
0.0015
Chemical
105
33
0.094
0.051
0.029
0.024
0.012
Chemical
284. 320
54
xx
0.009
0.0025
.. .
CACODILIC
ACID
cacodyhc-acid solution, boiled once, pH 2 cacodylic-acid solution, boiled once, pH 10
Chemical Chemrcal
L L
R.T. R.T.
3 3
x I
<0.0001 0.0002
<0.0001 o.woz
30% Ialternately immersed)
212
l-4
O.WlX
CALCWU
NNclM1DE
37.97%. water 41.97%. lithium bromide 11.53%, calcrum chloride 8.5846, specific gravdy 1.56 (under spray nozzles)
Metal fair dehumidification)
120
38
XX
XX
09009bd
O.Wl4cd
58% approximately, sodium chloride 1.1.3%, calcium hydroxide 0.1% approximately favaporatorl 30% approximately, cooling brine calcium-chloride cooling brme 21.69%. calcmm-magnesiumxhloride bittern, mag nesium chloride 8.69%. sodium chloride 1.06%. specihc gravity 1.38 (alternately immersed) 21.5%. sodrum bichromate 0.0017% as inhibrtor, pH 7-8.5 hn brme-spray au stream, dehumidifier) 21.5%. sodnan brchromate 0.0017% as inhibitor, pli 7-8.5 (boding tank, under spray chamber) calcrum and magnesmm.chlorrde brme liquors, total chlorides 50% (evaporator1
Chemical
330
31
xx
O.W2a
O.Wl7a
1..
Dairy Davy Chemrcal
F F F
10 10 175
355 372 130
x x
<O.OWlbd O.OOOla
<O.OOOlbd 0.0001
<O.OOOlbd <O.WOlbd
. .
Food (air coohngl Food
3-4
338
XX
XX
<OOWl
<0.0001
... .. .
90. 225 8.P.
337
<O.OOOl
<0.0001
Chemrcal fair condrtioning and relrigerationl
26
xx
xx
o.ow2a
0.0001a
(continued)
482
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion mediums
Test conditions
TIPX
TWX
TWX
304 P---P
calcwm. magnesium 28% concentratmn and sodwm-chloride brme in Chenucal lair conditioning and refrlgeration) F 160 <O.OOOlbd
316
~0 OOOlad
317
20
ALLOY 825
calcium
chlotlde.
sodium
chloride.
pH 9.0 tweu
box)
Chemical Chemical
131 212.
107 39
KX
xx x.
0.0004.d
O.OOOld 0.021c 0 02c
fumes and condensate lrom boiling calwm-magnesium-chloride concentrated solution, free hydrochlorlc acid 0.63% in condensate
xx
220
CALC,M
CITRATE
calcium-citrate
solution,
sulfurrc
acid excess 3%
Sugar (citric-acld manufacture)
195 212
02
xx
0.062
0 035
calcrum-hydroxide slurry, hydroxide and silica calcium-hydroxide so&urn sulfide calcium droxlde. hme
some undissolved
calcium
Chemical
194
203
<.0.0001
,.. <:o0001
e.0 0001
liquors,
ammonia
fumes,
180
< 0.0001
hydroxide. calcium sodium sulhde
carbonate,
sodwm
hy-
Pulp and Paoer
120
204
,.0.0001
U-7.4%
(turbo gas absorber)
Chemical
139
46
LO 0001
10
0001
CALCIUM 15%
YPOCLtJRlTE
approximately,
bleach chlorme 70.100 g/l,
Chemical Chemical
F F
75 90. 100 97 140 212 97 140
65 31
x
x
x x
0.012cd 0 006cd OOlcd 0 0216 o.fMo2 o.OGO5 ml <0.0001 0.0002 0.0037cd
0 0033cd
0 023cd 0 029cd
C0.022cd
10%. bleach slurry, avadable hme excess 20.30 g/I 6%
Chemical Cherrucal
L 1 1 1 :t
0 0347
6% 6% 2% 2% 2% calcwm chlorine chlorate, hypochlorlte and hme sludge, 40 g/l, some calcium chloride, calcwm carbonate and free hme bleach hquor. avadable calcium
<O.oooI
0.0004 0.0006
Chemical Chemical Chemical Chemical Pulp and Paper
<o.ooo1
0.0001
1 F
212 60. 100 30 0017cd
calclum.hypochlorlte wne 2-3 gl I
avadable
chlo-
Textde
65 100
31
xx
<o
0001
<O.OOOld
<O.O001d
(continued)
Ferrous Alloys
483
TABLE 4.13:
VARIOUS
STAINLESS
STEELS AND HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
TWE
TWX
TIPE
304 P-P-P
ALLOY
20 825
316
317
CALClY
LACTATE
5%. actwe carbon 0.5%
Dairy
140. MO 125
2?
<o.lloo1
<o.w01
calcwm lactate, lactic acrd. organic acids, calcium carbonate. pH 4-5.5, initially 6.5-7.5
food Ilermenta.
IlOd
303
<O.oool W<O.OOOl
<O.OOOl W<O.OOOI LW<O.OoOI
<O.Owl
ClLElY
PHOSPHATE
12X, calcrum monophorphale. solids 7.5%. phosphorrc acid 3X, fluorides 0.02%, pit I.2 texlraclion tank bottom) calcium phosphale. ran exchanged inosrtol. converler liquor. some protein
Chemical
02
18
<O.OOOl
O.lWllI
Corn Products
75
36
ml
nil
CALCIUM
SULFATE
10%. roaster calcme. sodrum vanadate 5.8%. sodrum chlorrde 3.7%. silrcates. hydrochlorrc acid and chlorme gases Ibetween roaster discharge and baker cooler)-
Mming (ore processlog
1520
63
0.021
..
0.028
CALCIUM
SULFITE
19.3%. calcwm-sulhte hquor. milk-of-lime solution I lb/gal, sulfur droxlde 10% lgas.absorbmg chamber, top)
Pulp and Paper
200
68
<0.0001 <0.0001
<0.0001
CARSON
actwated carbon SXAC-1 adsorbing acetone, methylene chlorrde trace actwaled carbon bed Norit Sorbonorrt Ill adsorbmg acetone containmg methylene chlorrde trace aclrvated carbon bed Lactol. petroleum solvent.
steam, carbon some unknown froth, water chloride from source (half Immersed)
Chemical
57
<O.OOOld
<O.OOOld
<O.OOOld
<O.OOOla
<0.0001
Chemrcal
57
0.0002bdr
O.OOOlbdr
O.OOOla
O.OOOlb
0 OOOla
Prmtrng
R.1: 230
70
O.OOOlcr
0.000lcr
<0.0001c
coolers
Chemical
f F R.T.
28 257
<O.OOOld
<0.0001
coal (coal chutes)
Power
0.0047
0.0046
carbowblack sludge. carbonates. chlorides. sulfates. carbon dloxlde and sullur dloxlde (half Immersed in water seal at cooler end of furnace)
Carbon Black
160. 205
61
O.OQOEc
<O.OOOla
carbon-black slurry carbonates, chlorides. sulfates. carbon droxrde and sulfur droxlde from coolmg water at pli 7 (bottom of prrmary coolerl carbowblack slurry. carbonates. chlorides, sullates. carbon dioxide and sulfur dioxide from cooling water at pli 7 (riser of primary cooler)
Carbon
Black
400. 900
42
O.Oilll
0.001
0.0007
Carbon Black
:f
900. 1400
42
0.0005
O.KNE
0.0004
(continued)
484
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
hontd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipyl
1VPi
NM
ALLOY
;; -20 a25
.
carbon-black slurry and water intermittently, pH 7 approxrmately (water level 01 cooler seal, ret and dry, air and slurry1 carbon-black slurry (half immersed)
.
xx
.
XI
---
364
0.0003cd
316
<O.OOGl
I i j
Chemical
:f
160
240
<O.OOOl
<O.OOOl
Carbon : Black
If
170
21
<0.0001 0.001 Ic 0.0004
<0.0001
<0.0001
carbon-black slurry, sulluric acid pH 2 Ileaching j Carbon : Black tank) carbon black loose, entrained combustion gases, water vapor, product occasionally on tire carbon black loose, entrained combustion gases, water vapor, product occasionally on fire cartnm~black slurry, water, total solids 7.2%. con. centrated carbon black 6.94%. sulfates 6.63 g/gal. lerric oxide 4.24 g/gal, nitrogen as ammonia 0.64 g/gal. chlorides 0.45 g/gal. reduction factor cquivalent to potassium permanganate 0.647 g/gal (half immersed) carbon black. hard water (fresh water 52 salt grains/gal). steam talternately immersed) carbon black. hard water ilresh water 52 salt grains!gall. steam (half immersed) carbon black, sullur. salt and water vapor. oxygen laet scrubber unit) 20% carbon-black paste, water 80% (mixer) carbon black, hydrogen sulfide 46 grains I100 cu It, steam 45.50 vol %. carbon dioxide and monoxide. hydrogen, nitrogen and oxygen 0.2.0.3% carbon black, laden with fuel gases
if
110
xx
IX
o.Ow5
0.0013
Chemical
:F
120
240
ss
<0.0001
<0.0001
<0.0001d
<O.OOQl
<O.mOl
Chemical
120
324
XI
0.0011c
o.lKmc
<0.0001c
O.OOOlb
O.OlKt4a
Carbon Black
:F
170
30
xx
xx
0.03lc
0.0003
0.0004
Carbon Black Carbon Black Carbon Black Petroleum Carbon Black Uiltration) ;F -F
178
30
XI
0.0021c 0.02& O.OMC
o.lKm
O.oool
<0.0001
152
30
xx
xx
O.WO1
0.0001
<0.0001
420
I5
xx
0.0402
0.0002
0.0001
F F
7s 220. 230
28 251 xx -
O.ONlld
0.0001 0.0043r
: i
: Carbon ! Black
160.
180
52
.,
<0.0001
<0.0001
<0.0001
33.34%. water 66.66%. ethanolamine trace (vapor line of Girdler reactivator) 26X, oxygen 6%. carbon monoxide 2%, sulfur dioxide. nitrogen trace
: I i
Chemical
I :
235. 240 104. 113
62
IX
0.0001
0.002
0.0001
Water Purification
75
xx
XI <O.oool
0.0012c
0.002c
12%. nitrogen 88%, condensed water has iron ions j Petroleum 40 ppm. sulfuric and sulfurous acids 10 ppm, nitric : and nitrous acids 3 ppm (pipe. gas stream1 10%. gas stream, carbon monoxide 2%. sullur dioxide 0.25%. some oxygen carbon-dioxide and sodium-chloride brine mixture teas contains carbon dioxide 33.40%. sulfur dioxide ~050.1%. air; brine contains sodium chloride 45.2 g/l, sodium sulfate 12.5 g/l, sodium carbonate 4.7 g/l and borax) (gas scrubber, center) carbon dioxrde and nitrogen, chlorine trace (gaseous mixturel
110
36
<o.ocm
<0.0001
<0.0001
i :
Mming
150
73
xx
xx
<O.OOOla <O.OOOla <0.0001bd
<0.0001
Chemical
132
80
356
xx
II
<O.GGOld
Petroleum
302. 392
198
xx
0.0022cd
0.002cd
0.0013cd
(continued)
Ferrous Alloys
485
TABLE
4.13:
VARIOUS
STAINLESS
MOLYBDENUM
bntd)
Corrosion mediums
I
; r
8
,FE
. carbon dwde. ammonia 0.2%. water. urea trace. stripper bottom) Petro. chemical Isynthetic. urea manulacturel Food F 315 x
I u . . x
rwe
,FE
ALLOY
20
<0.0001
304 P-P-
316
(0.0001 s<~0.0001
317
625
<0.0001
<_ 0.0001
s0.0001
pressure
68 pug iammonla
carbonated
water.
pressure
5 pug
II
CARBON
DISULFIOE
carbon drsulhde, water (condensate hqurd hnel carbon drsulhde. water
trace,
absorbmg
or1 trace
Chemrcal
93
110
<00001 s<0.0001 <O.OOOl

<O.OOOlbd <O.DOOlbd 0.0006cd 0.0018cd 0.0008cd
<0.0001 s<0.0001 <0.0001

<O.OODl
<0.0001
<O.ODDI
Chemical c25%. some sulChemrcal
F F
R.T. 60
240 76
xx
x
x
x
carbon drsulhde, water. sultur tur~c acid and hydrogen sulfide carbon drsullide. sulfur 20%
Chemrcal Chemrcal Chemrcal
:f F .F
104 104 112
180 363 363
xx
0.0006cd 0.0017cd 0.0006cd
carbon d~sulhde. sulfur carbon dwlhde. sulfur Ivaporsl
xx xx
CARBON
MONOXIDE
carbon monoxkde. hrgh pressure
Chemical
392
OK
CARBON
TETRACHLORIOE
90%. 90%. StIllI
Kolene Kolene
solvent. solvent,
benzene benzene
IOYb 10% Ibottom 01
Dry Cleanmg Dry Cleanmg ld~strllatronl Chemical
f F
R 1. 287
40 38
< 0.0001
0.0014ad
0.0014ad
<;0.0001 00008ad
xx
87.5%. water 129.. sod 0.1% lvaporsr
chlorme
04%.
hydrochloric
140. 185 176
1.57cd
I .26cd
crude carbon tetrxhlorrde
~columnl
Chemtcat Irectlhca. t1ont Chemrcal ldtstdlatlonl
133
xx
. 0.0001
<O.OODlad
25.5%. sultur chlorides dlchlortde. thlocarbonyl
75.95% chloride
lsullur mono- and etch lhqwd Ime)
125. 130
35.5
xx
0.0001
0.0001
CIRROTING
SOLUTlON
cdrrotmg solotton. sullur~c 3%. hydrogen peroxide 3%.
acid 4%. chloric water remainder
acid
Textde
R.T.
47
<0.0001
<O.OOOl
<0.0001
carroting solution. sulfurrc acid 4%. chloric 3%. hydrogen peroxide 3%. water remainder
acid
Textile
R.T.
0.067~
.. .
CASEIN
case,, leather brushes. shellac, wax. various resrns. both synthetrc and natural. slightly alkaline water solution or line dispersron
Tanning
180
0.0001
0.0001
(continued)
486
TABLE 4.13:
VARIOUS
STAINLESS
STEELS AND HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
TIPS
TIPE
TWE
304 P-Pcase,. leather fmrshes. shellac. wax. varros both synthetrc and natural. slrghtly alkalme solution or fme drspersron resms. water
316
317
20
ALLOY 825
180
0.0001
0.0001
cellophane
sprnrR
bath
Rayon
104
37
xx
xx
0 0039c
cerrum-sulfate liquor. sulfurrc anhydrrde I I% sulfurrc acrd IO 66%. phosphorus pentoxrde 4 596. hydrochlorrc acid 0 25, approxrmately dung wash cycle cerum.sutfate liquor. sulfurrc anhydrrde 11% sulfurrc acrd 1066% phosphorus pentoxrde 4596. hydrochlorrc acid 0 25% approxrmately durrng wash cycle
Rare-Earths Separatron tflltratlon)
70
22
0.0015
0.0005
0.0004
Rare-Earths Separatron
70
63
0.015
0 005
0 004
cerowchlorrde
solutron,
pfi 5 lopen
evaporator1
Chemrcal levaporat~on)
212. 275
30
0 0075cd
0 0087c
0 0073cd
CO 005cd
CHERR
JlCL
maraschmoxherry benzoate 0 1%
syrup. maraschmo
sucrose flavor
50%.
sodwm
Food
66. 75 132. 160
86
? no prts
0.0001
! no pits
0.0001 00001
maraschmo cherrres. hot procersmg, 600-1000 ppm rnrtrally
sulfur
dioxrde
Food
193
CLOR,NE
chlorme. chlorme.
dry dry arr mixture Irubber hose hne
Research Research Food lflour bleachmgl Textrle kottonl Pulp and Paper Petroleum hydroxrde. morst arc Chemrcal
1 1 F
600 650 80 82
0.06 0.12
0.03
0.06 0.022
... ... ...
... ...
5.5 VIII % chlorme. above flour agitator)
xx
xx
0 044
0.114%
awlable
chlorme
m bleach
solutron
63
OOOld
0 0007d
0.013%
chlorme.
arr mrxture
(exhaust
srde of fan)
62
35
0 124~
O.ll&
chlorme
fumes
(atmosphere)
F F
RT. l?O135
184 90
xx xx
x xx
0 0005c 0 0002 0.0002 0.0005
chlorme. sodrum oxychlorrde, rodrum sodrum chlorrde, sodrum-oxrde smoke, latmospherrc fumes from sodrum cells) chlorine. hydrochlorrc lene chlorrde (vapors1 chlorme, natorl chlorme. chlorme. hydrochloric acrd. naphthalene.
naphtha.
Chemrcal
330
52
00013
0.0012a
0.0014
0.0016
acrd.
propronrc
acrd
ichlorr-
Chemrcal
68
0.16
0.18
0 28
hydrochlorrc saturated
acrd. propronrc water solutron
acrd
Chemrcal Chemrcal
L L
68 RI.
I 7
0.0075
0 0065 0 527 0.0154
0 0064 0 478 0ot5
(continued)
Ferrous
Alloys
487
TABLE
4.13:
VARIOUS
STAINLESS
STEELS AND
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hmd)
Corrosion mediums
Test conditions t
.
CHLORINE OlOXlDE
.
x
z .
x
WPE
TWE
*WE
304 p-p--
316
317
20
ALLOY
625
chlorme-dmxlde
gas
Pulp and Paper gas and condensed solution Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper 45%. Pulp and Paper .F
180
45
cou
0.056 0.12
10.8%
chlorme-dwde
150
14.5
xx
xx
0.33
0.29c
chforme chlorate 7.2%
dloxlde, sulfuric 32%. methanol
aud
6OW
sodium
per-
:F
135
14.5
xx
>0.55
0.15c
CO.027
approaboately.
saturated
water
solution
38
70
x ;
xx
0.0051c
10.0052c
o.ooo9
0.0026b
0.0032
5.4%
approximately.
saturated
water
solution
36
14.5
0.0001
co.0007
chlorme-dloxlde sodwm chlorate
spent hquor. 20 gil
sulfuric
acid
155
14.6
0.016~
0.0025
co.0011
CHLOROACETlC 100%
AClD aced Chemral 66. 70 3 x 0.013a 0.0002
monochloroacetlc
80% crude monochloroacetlc (half Immersed1 78% monochloroacetlc aud.
acid,
water
solution
Chemical
RT. :F :
jF 122. 140 50. 77 F 70
31
0.0014
water
22%
Chemical
17
o.w97
0.0025
0.002
0.0018
78%
monochtoroacetlc
acid. water
221
Chemical
17
OOWld
<0.0001
<O.OOOld
<0.0001
monochloroacetlc acid. dtchloroacetlc acid acetyl chloride 155. some acid crystals monochloroacetlc aud. dlchloroacetlc aud acetyl chloride 15%. some aud crystals 70% 25%. 48.5% water mooochloroacetlc acetic acid 5% grade monochloroacetic acid, carbon
15%.
Chemical
xx
0.018
0.013
15%.
Chemical
70
xx
0.01 I
0.009
tetrachloride
j !
Chemical
105. 125
14
0.0084
CO.0088
technical
acid,
Chemical
12
90
x :
<0.0001
<0.0001
<0.0001
<0.0001
CHlOROBENZENE
monochlorobenzene,
phenol, water
trace i chemicat
;F
140. 159 F 70. 105 265
57
0.0053c
0.0066c
...
CO.0132
chlorinated
benzene.
hydrochloric
acid
i Chemical :
Chemical
90
chlorinated
benzene
137
LO 0001
0 0001
C,,LORO-DIPHENYLAMINE 20%
approximately todme
3xhloro-diphenylamine. 0 r9%, monochlorobenzene
sulfur re-
Chemical
266
30
5 34%. mamder
0.04c 0 09
0 059c
0.12
0.044c 0.077
488
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
VVPE
TVPE
VV,E
--
304
316
317 P-P
"20"
ALLOY 825
1. 2.dlchloroethane
Chemical
j L
935.
1035
1-.
0.03
tnLONOEvnYLENE
perchloroethylene
ItolvenWecovery
still)
Dry Cleaning (distillation) still) Dry Cleaning fdlstillation) Corn Products Textile (distillation) vapors) Textile
305
64
xx
<O.OOOlad
<O.OOOla
<O.OOOla
f 260 64 -
perchloroethylene
Ivsporsl
Isolvent-recovery
<O.OOOla .cO.OOOla 0.0003ad
<-O.OOOla 0 0001
0.0003
perchforoethylene
vapor. water
fextractorl
<I90
12.5
trtchloroethylene
Isolvent
recovery)
<0.0001
<o 0001
<0.ooo1 0.0003 .
trichloroethylene.
air twoof-drier
system,
115
--
<0.0001 <0.0001 0.0004

0.lmo4 0.0006 xx <O.OOOl
Irlchloroethylene. duct of blowyrl trkchloroethylene
air
IwooLdrier
system,
exhaust
Tertile
185
--
0.0006
crude (vapors and entrained
liquidl
Chemical (distillation) Chemical Idistillation) Chemical fdistillationt Chemical fdistillationl
.F
163
228
<OOOOl
.. .
trlchloroethylene liquldl trlchloroethylene hquid)
crude. water (vapors and entrained
212
230
xx
0.0007b
0.0003b
..
. .
crude. water (vapors and entrained
169. 198 163. 198
228
xx
<O.OOOl
<0.0001
trlchloroethylene crude. inhibited by controlled adP,%IJ;, of gaseous ammonia (vapors and entramed
94
xx
<0.0001
<:0.0001
.. .
trichloroethylene.
wool grease
<2.5%
Textile
88
--
<O.oool <0.0001
<o.ooo1
CLONOHDNlN
epichlorohydrm. chloroethylene
caustic soda, Eis Phenol. and sodium-chloride brine
tri-
Chemical
176. 212
16.3
xx
~.O.ooOl
<O.oool
<O.OcOl
<o.o001
<o.o001
chloro./+methylquinone. chlortde. hydrochlonc
nttrobenzene 85%. copper acid 596 during stripping
Chemical
212
2.5
xx
0.0027
0.0032
0.0025
chlorophenol. phenol. chlorme. hydrochloric-acid gas, ferric chloride (vapors. liqwd)
Chemical
123. 140
19
xx
0.0031d
0.0051d 0.0031d 0.0005d

34
0.0024d 0.0035d
0 002!d 0.003d
0.003 0.0018
dlchlorophenol
(vapors)
Chemical tdistillation)
330. 350
xx
0.0006
O.oool
(continued)
Ferrous Alloys
489
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion mediums
Test conditions
Average corrosion rates (by)
5 I .
dhzhloraphenol pure (overhead still pot, vapors) 2.4.drchlorophenol kolumnl Chemical (distillation1 Chemical (distillation) F 250. 290 265. 302 34 21
$ g
2 . :: . xx
7PC
,PE
TPE
ALLOY 20
p-p--
304
316
0.0007 0.004
317
825
0.0029
:F
0.009
CHLOROPICRIN
chloropicrin. water. calcium hypochlorrte. Irme. calcium chloride 7.0%. calcium carbonate. pli IO.11 chloroprcrm. sodium hypochlorile. sodium hydroxide, chlorine, sodwm chlorate
Chemical
203
0.0013
0.001
0.0028
0.0032
Chemical
75
10
0.0009d
0.0006d
0.0007d
O.OOOld
CHLOROTRlFLUOROETHYLENE
chlorotr~fluoroelhylene. hydrofluorrc and hydrochloric acids <- 1.0%. pressure 150 prig iprtrally lwhedl
Chemical
70. 120
86
0.0017
0.0015
0.0012
CROWC
AClD
chromic aud (hguid Ime) 33.33%. Cromodme. sodmm chloride remamder 33.33%. Cromodme. sodwm chlorrde remainder 30%. chromic sulfate 0.45% levaporationl
Automotive Metal Metal Metal (plating) Research Research Research Research Research Research Research Research Research Research Research Research
F 1 1 1
120 170 170 B.P.
60
0.0052 SO.0058 xx xx xx
0.0128 SO.0190 0.0005
co.0071 CSO.0161
I
2 2
0.0011 o.LlOO2 0.555
0.68
0.418
25% 25% 15% 15% 15% 15% 15% 15% 10% 10% 5%
5%
1 L L L L L L L L L L L
75 180 75 150 150 180 212 212 75 180 75 180 R 1.
3 3 3 2.5 5 3 2.5 5 3 3 3 3 60
.,
nil 0.73 0.0003 0.0098 0.0134 0.056 0.0979 0.1869 0.0002 0.0059 nil 0.0007 0.0002d
0.004l7 1.08
c0.0002 0.19 ... .
o.ooo4
0.0142~ 0.0258 0.018 0.3916 0.4272
0.0001
0.012 ml 0.0029 0.0002d ...
0.0002 0.036
5% approximately. Cromodme. hydrochlorrc acid
Metal
(continued)
490
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(amd)
Corrosion mediums
TPl
*we
TIPS
ALLOY
"20" 825
.
3.4%. water chromic 2 gal oxnde 10 oz. sodium sulfate 5 oz, Printing
. :
304
<0.0001
316
<O.OOOla
317
:f
: f
R.T.
50
..
.. .
chromx acid, 3% (develooer
water box)
solutmn,
sulfuric
acid,
acidity
Textile
140. 160
6.5
xx
I:
0.0003d
0.0003d
ClTRlC
ACID
citric ac!d, pure. dry (drum drwl 56% approximately
Chemical Chemical food
f f f L
155 130 125 B.P. 213
52 5 37.5 45 0.2
x.x 1.
xx xx II xx
<0.0001 0.0086b <0.0001
<0.0001
0.00082b <0.0001 0.0002
51.6.42.6% 20% 10%
Chemical
x.x
0.00062 0 00103
0.00047
10%.
chlorides
Chemical
125
36
xx
0.0001
0.0015
0 0006
10%. acid 10%. acid 6%
fermentatmn
sucrose
solution.
hydrochloric
Chemical
90
60
IX
xx
~~0.0001
fermenlat!on
sucrose
solution.
hydrochloric
Chemical
90
50
x:
xx
r00001
0 003
Chemical wlh calcium hydroxide Sugar
L f
213 180. 213
01 0.3
II: x 0 006
0.003 0.008
cltrlc acid. pti 2 neutralwed to ptl 7-8
acldlhed clay, sulfwc acid eqwalent hydroxide 4 mg iOorr thickener) acldtfied lthlckenefl clay slurry. sulfuric acid
to polasswm
Chemical
160
106
x-
0 0001
00001
0 0001
0 18-O 5396
Chemical
140
40
1.
0 0003d
0 0001
acldllled clay lOlIver Idleri acldlfled IthwAenerl acidlbed IthIckener) acldlfled Ithlckenerl acldtfied (thickener) clay
slurry,
sulfuric
actd
0 18-O 53%
Chenwal
150
40
xx
00001
0.0001
slutry.
sulfwc
acid
0 26.0 97%
Chemical
140
40
I:
0 0008
0 0001
clay
slurry,
sulfuric
acid
0.53-1.3%
Chemical
140
40
0.0005
0.0001
clay
slurry,
sulfurit
acid
0.88.2.1%
Chemical
140
40
0.0004*
0.0001
clay
slurry.
sulfuric
acid
l&3.5%
Chemical
IF
140
40
0.0003
0.0001
acidified clay slurry, sulfuric acid equivalent potassium hydroxide 60 mg Klorr thickener) acidified Ith&.ener) acldlfied clay slurry. sullurlc acid 3.5-&O%
to
Chemical
125. 160 140
106
I:
0.0002
0.0001
0.0001
Chemical
40
I:
0.0001
clay suspension.
sulfuric
acid 15.20%
Glass and Ceramics
70. 205
4.5
0.00106d
0.00036d
.. .
(continued)
Ferrous Alloys
491
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bmtd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
TYPE
TYPE
TYPE
ALLOY
304 p--pacrdrfred bentonrtrc clay slurry. drlute solution of alummum and iron sulfates. free sulfuric acid 0 15% IOhver lilted Chemical F 126. 158 0.0003
316
0.001
317
20
825
COBALT
ACETATE solution, free acetrc acrd trace Chemrcal F 227 <O.OOOld
cobaltacetate fevaporatort
396
<0.0001
COBILTOUS 5.31X, sodmm mckel fluoride
SULFATE 22 g/l, copper trace, ptf 3 6 g/l as sulfates, Metal (nickel refining) pH 1.2 Metal fnickel refining) Metal fmckel reflningt 15 Metal (cobalt refmmgl F 95. 185 3 xx
xx
nil
nil
2.58%.
mckel
as sulfate
10 g/l.
185
23
xx
xx
0.003
o.OC3
2.37%.
ruckel as sulfate
LOO g/l,
ptf 2.0
ll185
25
xx
xx
IllI
IllI
0.31%, nickel g/l as sulfates,
04 g/l, copper sodium chloride
02 g/l. iron trace, pH 2.5
104. 149
60
00031c
<0.0001
<00001
<0.0001
<0.0001
COFFEE 18% tar) coffee soluble coffee, liquid coffee extract fevaporaFood L 120 38 ~.00001 <0.0001
c,.o 0001
extract
.food
40
30
WI
COLUMBIUM 26%. hydrofluoric acid solution ore, 3.2N acid 4.5N, Mining Muting F F 70 70 42 42 xx xx x 0.036 corr 0.002 0.033 00021 0.03
dissolved columbde sulfurrc acrd 3.5N
hydrofluorm
CONDIMENTS bean sauce, tomato alcoholrc menstrua products and vanilla beans Food Food L F I55 65. 70 70 5 162 1 --x 0.0005 ~:0.0001 c_0.0001' ml <0.0001
mustard,
ground
fgrmdert
food
< 00001
salad dressmg. tron fcooler)
vmegar
4%,
sodrum-chlorrde
solu-
Food
190
10
< OOOOld LS. 0 0001 -xx 0.0001.d O.OOOld
<0.0001
sauces used m cannmg various types of dry-bean packs. tomato puree, chdi pepper, vmegar, etc
Food
195. 212
173
00001
COPPER
CHCORIOE chloride Jewelry 1 215 2 2.1
10% cupric
(continued)
492
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
f $ . . :
X
TYPE
TYPE
,PL
---
304
0.174c
316
317
--
20
ALLOY 825
10% cupric chloride cupric chloride, cupric sulfate and sodium chloride 1.66% cupric chloride, sodium chloride 226.7 g/2345.9 ml, pressure 6 in. of mercury 7.66% cuprrc chloride, sodium chloride 226.7 g/2345.9 ml, pressure 6 in. of mercury cuprous chloride, ammonia, magnesium oxide fcarbowmonoxide absorption chamber)
Research felectrotysrs)
1
f 60. 60 78. 80 78. 80 L R.T. 233 7
<O.OOOlcd
<O.OOOlb ml 0.0017 nil 0.0002 0.0565~
Chemical
- xx -
Chemical
:L
..
Automotive
--
44.5%. boric acid 4.07% 44.5%
Chemical
F L
120 130
0.0006 0.001 0.003 0.001 0.002
39.9X, boric acid 4.07% 11.46%. boric acid 4.07% 5.73%. acrd
Chemical Chemical
L L L
75 120 120 4
_
-
XX
nil 0.0008
0.0005
copper nicotmate. water solution, sulfurrc acid, Pf-f 1
Chemrcal
75
19
xx
0.0666c
0.02oc
65% approximately cupric sulfate, saturated solw tion, sulfuric acid 0.4.0.8% (evaporator) 17.5.10% approximately cupric sulfate, neutral leach, srlver ion 3-6 g/l as sulfate 16.511% approximately cupric sulfate, concentration 34Bc. total acrd 16.8%. copper ion 4.6%. free acrd 3.6% before evaporation; and concentration 4866. total acrd 24 3%. coooer ion 6.6%. free acid 5.5% after evaporation 12.5% approximately cupric sulfate, nickel ion 5 g/I and cobalt ran 2 g/I as sulfate, pH 2
Metal
170. 220 160
30
xx
0.0002
0.0002
0.0001
Mining
32
xx
xx
<0.0001
<0.0001
Metal levaporatronl
215
675
xx
0.0002ad
<0.0001
Metal hnckel refining) Metal F
.<149
36
xx
xx
nil
nil
10.6% approximately cuprrc sulfate, copper-refmery electrolyte. sulfuric acid 200.235 g/l, nickel ion 20-22 gi I as sulfate, pressure 6-4X approximately cupric sulfate, sulfuric acid ~0.3%. mining low-acrd leach, zinc ion 4.7 g/l, silver ion 2.5 g/l and manganese ran 1-3 g/l as sulfates
150
32.9
.,
<0.0001
<O.OOOl
<0.0001
Mining
140. 170
32
xx xx
<O.OOOld
<O.O001d
(continued)
Ferrous
Alloys
493
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
hontd)
Corrosion mediums
Test conditions
TIPl
TPC
1VPE
304
316
317
20
ALLOY 825
6.4% approximately cupric sulfate. sulfuric acid 3.6%. high-acid leach. zinc ion 5-6 g/l. manganese loo 2.3 gi I and solver loo l-4 g/I as sulfates 5% approximately cupnc sulfate, manganese dmxlde 9-10 g/I 2.613% acid 2.54 mersed) cupric-sulfate approximately 5%. sodbum cupric sulfate sulfunc acid 10%.
Mining
140. 170
32
xx
xx
<O.OOOld
<O.OOOld
Metal (plating)
158
63
xx
xx
<o 0001
<O OOOld
<o 0001
<o 0001
<0.0001
<o 0001
sulfate, sulfuric ~2% (half Im-
Metal
68. 140
194
xx
<O.OOOld
solution
Oacolyte
Metal ~platmg) arMetal lelectrorefinmg) F
129
30
xx
nil
nil
cuprnc sulfate and hydroxide. nnc. cadmium, sew calcwm sulfates and hydroxides. pH 6
185
111
<o
0001
<0.0001
<o 0001
<O.OoOl
<0.0001
COSMETICS
cream hawdress
emulsion
Cosmetic
RI
30 30
<0.0001
0 0004
cold permanent-waving ammoma l%, mmeral machme-wavmg l%, pli 10 solution. oil sodium thioglycolate, free Cosmetic L Rl
<0.0001 <0.0001 (0.0001 <0.0001 <0.0001 <0.0001 0.0002
lotton.
sulbte.
ammonia
Cosmetic
R.T.
30
hair-waving liquid neutralizing solution, acid and hydrogen peroxide, pli 2 glycerme lotnon, alcohol, alkaline detergent
phosphoric
Cosmetic
R.T.
30
Cosmetic
R.T.
CREOSOTE
creosote
and steam
Lumber
190
41
<0.0001
<0.0001
(0.0001
CRESOL p and m-cresol mersedl
mw.ture,
techmcal
(alternately
,m-
Chemtcal
R.T.
11
<00001
..,
P- and mcresol mersed)
mixture.
techmcal
(alternately
Im-
Chemical
160
11
<00001
CRESYLfC
ACID
cresyllc 66%,
acid. water 0 5% Ireboiler) acid 2%
Chemtcal Rayon
: f
300 350
60 55 135
-
xx
O.OOOla 0.007a
0.02b
0.0001
0.005b 0 Ola
0.0001
sulfuric
xx
crude cresybc acid, orgamc compounds cresylic cresylic acid, water, acid, water,
water
and
hydrogen
sulbde.
Rayon
350
xx
0.0008 0.0001 0.009c 0.02b
sodmm hydroxide sodium hydroxide 2.4%, zinc
Rayon Rayon Rayon
F F F
100 100 350
220 105 94 xx
crude cresyhc acid, sulfur 4%. water powder, caustic, ethylene dichloride
0.0002r
O.OOOlr
(continued)
494
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hontd)
Corrosion mediums
TIP6
TIPS
TIPS
ALLOY
20 825
304
cresylic acid, sulfuric compounds. hydrogen acid 2%. organic dlsulflde. water sulfurous Chemical 350 60 xx
316
0.039cr 0 032cr
317
0.015a
90.89%. cresol chlorx acid
8.10%.
partial
esters
2-E%,
hydra-
Rayon
R.T.
360
0.013b
O.OOEb
90.89%, cresyhc acid 5%. thlophenols nmum chloride 1%. hydtochlorlc acid chlorides trace: residual tar. tricresvl and magnewm chloride 90.88%. cresyllc acid 5%, thiophenols neswm chloride 1%. hydrochloric acid chlorides trace; residual tar, tricresyl and magnewm chloride 90.88%, cresyllc acid 5%, thlophenols nes~um chloride I%, hydrochloric acid chlorides trace; residual tar, trlcresyl and magnewm chloride 90.88%, cresyhc acid 5%. thlophenols nesium chloride 1%. hydrochloric acid chlorides trace; residual tar, tricresyl and magnewm chlortde
5%. ma& and organic ohosohate
Rayon
B.P.
179
xx
0 004a
O.OOOla
5%, magand organic phosphate
Rayon
700
306
xx
O.OOiar 0.024
0 005a 0 008
5%. magand organic phosphate
Rayon
700
140
xx
0 0006a
0 0003a
5%. mag and organic phosphate
Rayon
700
74
xx
0.007
0.035
90.88%. cresyllc acid 5% thiophenols 5%. magnewm chloride l%, hydrochloric acid and orgamc chlorides trace; rwdual tar, tricresyl phosphate and magneswm chloride 90.88%. cresyllc acid 5%. thlophenols nesium chloride I% hydrochloric acid chlorides trace, residual tar, trlcresyl and magnewn chloride trlcresyl monoaryl crude phosphate, phosphate 5X, mag_ and organic phosphate
Rayon
700
36
--
0.006
0.001
Rayon
700
22
xx
0.01 0.0006
0.0055 0.0003
traces of dlaryl phosphate, and phosphoric acid cresyl~c acid trace
Rayon
212. 240 176 100
4.5
xx
0.025
trlcresyl
phosphate,
Rayon Rayon :F
544 135
0.0003a 0.0025a
00003a 0.002
trlcresyl-phosphate scum, orgamc sulfur compounds.
sulfuric acid 2 ~01%. water. hydrogen sulfide
83%. water 10%. cohols, phosphoric 83%, water 10%. cohols, phosphortic 75%, acettc water 15%. acid 0 33%
acetaldehyde acid acetaldehyde acid acetaldehyde phosphates
0 75%.
heavy
al-
Chemical
: :
F
275
147
xx
WI
IllI
0.75%.
heavy
al-
Chemical
275
43
xx
0.0001
0.0001
10% acldlty trace, pH 4 5
as
Cbemlcal
200
608
xx
IllI
nil
.. .
crotonaldehyde. acldlty as acetlc 21.9%. butyrate
water 15%. acetaldehyde 10% acid 0 33%. phosphates trace
Chemical
120
1094
n1l
rlll 00002
0 0002 o.uoo5
water 45 4,. acetaldehyde 29 5% butyl 36. hexadlenal 1.3.. butyrlc acid 06;
Chemical
250
462
CUMENE
75%.
cumene
hydroperoxlde
25,
Chernlcal ldlstdlatlon)
212
347
xx
xx
0 0001
0.0001
0.0001
(continued)
Ferrous
Alloys
495
TABLE
4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Average corrosion rates iipy)
TPL
TPI
TWE
-----
304
316
311
ALLOY
"20" 825
alkyl benzene alkyl benzene
sulfontc acid sulfomc acid aryl sulfonate. water ammonium sulfonate
S0ap Soap Soap
F F F
120 120 62. 105
55 56 43 <0.0001 s<0.0001
0.0063 0.0022 <o 0001 s<0.0001
0 0039
0 0006 -0 0001
41.39% ammonium alkyl 39.40%, ethanol 14 516%. 4.7%. pH 6.9.13 3028% ammomum 46.5.49.5%, ethanol fonate 2.4% 57.53% sulfate 41-4936 alkyl
aryl
sulfonate.
17.5.19.5%. ammonium
water sul-
Soap
65
90
<00001
sodium alkyl aryl sulfonate. <3%, water remamder sodrum alkyl aryl sulfonate
active,
sodium
Synthetic Detergent Soap
150
392
<o 0001
<O.OOOld S0.0002cd
<o 0001
<0.0001 S<O OOOld
<:o0001
.;o 0001
85
95
\o 0001
24% sodium alkyl aryl sulfonate, sodium phosphate 16%. sodium tripolyphosphate nonyl phenol trace, water remainder, pH 9 alkyl aryl sulfonate slurry, fate ~3%. pH S-8.5 60% actwe. sodium
pyre16%.
Synthetrc Detergent
175
311
<o 0001
<0.0001
sul.
Soap Soap
130. 180 140. 160
70
<O.OOOld
drshwashing compound, mainly sodmm polyphosphates. sodium srhcates. sodium carbonates, small amounts of aniomc surfactants SAAS type non-ionic detergent slurry, containing water, phosphates, soda ash and sodium siltcate cleanmg compound. soya fatty acid soaps 3%. ionm detergents 2%. sodrum tripolyphosphate water, pli 10-10.5 90% 10% 0.2% 0.2% 0.2% Tide Nytron synthetic (half immersed) Nytron Tab Or synthetrc detergent, sodium poly-
60
c,0.0001
Chemical
140
0.00012
nonin
Soap
72
<00001
silicate
Soap
AI.
rlll
detergent
(half Immersed)
Soap Soap
L L L L
140 140 R.T. 140
0.25 0.25 7 025
xx xx -xx
O.ODol 0.0001
nit
synthetic synthetic
detergent detergent (hall immersed)
Soap Soap
synthetic
detergent
0.0001
DDT. sodium sulfate, dratomaceous earth, traces of sodrum, monochlorobenzene and chloral. pH 6-7 lhlterl
Chemical
270
xx
0.00124
O.OOOSd
0.0005d
O.ODLt5d
acrd dye solutron. murm colors
straight
acid,
Neolan
acid,
chro-
Textile
BP.
1 nil
10% Calcosrd orange YtID in methyl Cellosolve solution, acidrfied with acetrc acid 99.5% to pH 5.2
Wood Staining
80
<:0.0001
<0.0001
...
(continued)
496 TABLE
Corrosion
Resistant
Materials
Handbook
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion mediums
YWE
TWL
304 ----chromrumxhlorrde dye, 27% hydrochlorrc acrd lb. water 1000 lb, corn syrup 200 lb, sodium chromate 725 lb added chromrum-chlorrde dye, 21% hydrochloric lb, water 1000 lb, corn syrup 200 lb, chromate 725 lb added cotton dyeing and bleachrng regular processrng cycles solutron. acid sodium
316
0.002c
rrrr 317
ALLOY
20
O.OOZcd
a25
1100
di-
T&de
150. 216
68
0.005cd
1100
di-
Textile
150. 216
68
0.02
no Textone.
Textrle
160. 170
194
xx
<O.OOOlcd
<O.OOOlcd
<O.OOOld
<O.OOOl
dyestuffs and developrng baths durrng 250 hours, sodrum hydrosulfrte and caustrc during 5 hours fur washmg. bleachrng. dyer@ solutions, alkalies, orgaruc and rnorganrc acrds, oxidation and reducbon agents, concentrations <1.5% dyemg solutrons. hydrochlorrc acid and acetrc acid during 2 5 days, acetrc acid and sodium dichromate durrng 1.7 days, sulfurrc acrd during 1.5 days, and sodrum perborate during 0.7 days dye solutron. water, sulfurrc acrd, drum drchromate. cuprrc sulfate, scouring sodrum hydroxrde 0.5.7% sulfurrc wool water varrous acrd dyemg dyemg soluble solutron dyes, tallow and wool grease solution, acetic acrd. socolors, caustic (9 P.) dyes
Textile
11
xx
xx
1<0.0001
<0.0001
Fur
70. 100
25
<0.0001
<0.0001
Textile
50. 130
6.4
<o 0001
<O.OOOla
Textrle
ff.1: O.P
180
O.OOOla
0.0001
.. .
Palatine
Textde Textde Tanning Textde F F F
B.P. 212 100 45. 202
400 21 100 30 -
x -xxx!
xx
0.0002
00001
; x:
0.0001 0.0001
dye hquors
<0.0001
<0.0001
.. .
ERlTnRrTclL commercral erythrdol Chemrcal F 150. 220
194
--.
0.0009b 10.0028b
0.0005
99% set-butyl acetate, propyl acetate 15%. acrd 15%. set-butyl alcohol 8%. water 2%, alcohol 0 5% toluene sulfonrc acid trace 55% set-butyl acetate, propyl acetate butyl alcohol 6% propyl alcohol 4%, acetrc acrd 001% 33%. water
acetrc propyl
Chemrcal
200
92
xx
<0.0001
<0.0001
nil
SC2%.
Chemrcal
190
52
xx
0.0001
0.0001
LOOOOla
ESTERS. 100%
ETHYL
ACETATE
ethyl acetate
Chemical
171
17
xx
0.0002 <0.0001
0.0003
nil
99.92% <I%
ethyl
acetate,
ethanol
O-7%,
high
boilers
Chemrcal
316
490
xx
85% ethyl
ethyl acetate, ethanol propronate 2%. water
9%, 1%
heavy esters
3%,
Chemal
226
17
xx
0.0024
0.001
90%
ethyl
acetate,
methylethyl
ketone
20%
Chemical
158
39
0.0002
0.0001
<0.0001
(continued)
Ferrous Alloys
497
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions
TPl
,PI
,PL
ALLOY
20 625
304 P-P76% ethyl acetale. ethyl propionate 14%. acetic aud 5%. heavy eslers 5% Chemical f 176 17 O.oool
316
317
o.ooo2
70% ethyl acetate. benzene 23%. water 7%. acetic ~ Rayon acld 0.04% 70% ethyl acetate. benzene 30%. prop~omc and acelrc acods0.02% 70% ethyl acelate. benzene 30%. propiomc and acelIe acids 0.02%. mangaoous acetate 10 lb/day 61% ethyl acelate. benzene 26%. proplonic acid 11%. acellc acid 196. waler 1%. manganous acetate IO lb/day 51% ethyl acelale. benzene 33%. acellc acid 10%. water 6% ethyl acelale. esler~hcal~on. aceltic acid glacial 9500 gal. ethyl alcohol 9000 gal, sullunc acid 66Be 25 gal elhyl acelate. loluene. various volalde resms. plasIwers. waxes and lacquers Chemical
:f
177
246
0.owlr
0.0001
c0.0001
177
50
0.0002r
ml r
nil r
... ... ...
... ... ...
Chemical
177
34
O.OOOlr
<O.OoOlr
Chemical
190
34
0.06r
0.006
Chemical
120
807
ml
oil
Chemical
158. 221
180
0.002 00013
0.0025 0.0018
0.0017 0.0014
0.001 0.0009
0.0015 0.0014
Solvent Recovery
170. 240
318
0.0002
<O.OOOl
<O.OOOl
<O.OoOl
20% ethyl acrylate. phosphoric acld 70%. ethanol, ethyl acetate and acetic acid together 10%
Rayon
284
63
0 04
LO.OO75c 0.0069
0 0055b 0 2c
OOlb
60% methvl acetate. acetaldehvde 10%. water 5%. acetic aclb2%, acetone and alcohols 20% methyl acetate, ethyl acetate 20%. methyl. ethyl ketone 18%.acetone 15%,low boilers 14 4%. water 6.5%. acetaldehyde 6%, acetic acid <1% 18% methyl acetate, water 60%, acetone 16%. acetaldehyde 4%. acetlc acid 05%. formic acid 0.1% 14% methyl acetate, water 60%. acetaldehyde 13%. acetone 12%. acetlc acid 0.1%. tormlc acid 0.1%
Chemical (fractiona. IlOlll Chemical
223
131
0.0001*
0 0001
0.0001
144
390
<0.0001 1<0.0001
<0.0001
Rayon
199
1125
0.0004
0.0001
0 0001
Rayon
172
1158
<O 0001
<0.0001
<0.0001
propyl acetate, butyl acetate and isobutyl acetate together 65%. water, propyl. butyl and tsobutyl alcohol together 10%. acetlc acid 0 003.2% propyl acetate, propyl alcohol, water, ethyl acetate, ethanol, methyl amyl acetate, methyl lsobutyl car. binol. isopropyl alcohol, isopropyl acetate, acetlc acid
Chemical
200
57
0 0002
<o 0001
Chemical
167. 248
650
to 0001
<0.0001
(continued)
498
Corrosion
Resistant
Materials
Handbook
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(cantd)
Corrosion
mediums
Average corrosion
rates (ipy)
s .
TYPE
TYPE
TPE
304
316
317
20
ALLOY 825
100% wnyl 99% wnyl
acetate
Chemical Plast,c Chemical
176 F I60 162
150 77 302
0 0001 <00001 0 00001
II
acetate
<o 0001
<0.0001
< 00001
80% vinyl acetate vinyl propmnate 20% durmg 184 days and ethyl acetate 60%. other organ~cs lO6. waler 30% during 118 days 10% vmyl acetate, acettc anhydrlde 50% ethylldene dlacelate 30%. acetlc acid 10% durmg 186 days. and ethyl acetate. methylethyl ketone and ethanol together 40%. water remamder during 68 days vmyl-acetate residues. sulfuw acid 1%
Chemical
212. 293
254
0015
0.0007
Plastic
220
0 OBC 0.m
0 042d
0.035d
56%. sollds butyraldehyde 56%. solids butyraldehyde 56%, water 1% sulfurtc
23%. 1% 23%. 1%
water 15%. ethyl acetate sulfuric acid 0 5% (vapors) water 15%. ethyl acetate sulfuric actd 0 5%
5%,
Plastic
I67
132
<0.0001
<:0.0001
<o 0001
<o 0001
so 0003
5%. Plastic I67 132
<o 0001 0 0002 0.0001
<0.0001
\:o 0001 s<0.0001
15%. ethyl acetate 5%. acetic acid 0.5%. butyrlc actd 0.1%
acid
Chemtcal
I67
0 0004
47.42%. acetate polymer sollds 36%. ethyl 5 290, water 10% sulfuric acid 13.2.5%. acid 0 2-2 3% (vapors1
acetate acetlc
Plastic
167
so 001 0 0003 <o 0001*

180
0 0006
<o 0001
<0.0001 s<o 0001
0.0002
41.42%. acetate polymer sohds 36% ethyl acetate 529,. water 10% sulfwc acid 1 3-2.5%. acetlc actd 0 2-2 3% (vapors) 42%. I 5,. water 53,. ethyl acetate suifurlc acid 13% sulfuric and 2 3% acetic aud
Plastic
167
SO009ld 0 003.d
0.0009
0.0011 so 0017
0.0006
0.0004
PMlC idlstltlatlon) Chemical fdtstdlatlon)
f
F
I85
0 0061
0 0072
0 0068
9%. water 919,, lcolumn vapors)
acettc
acids
trace
188
0 0018
0 0005
0 0005
monoethanolamme
pure
Chemical
212. 320 338
00001
95.90%
monoethanolamme.
water
(vapors)
Chemical (dlstdlation) Petroleum
0 0005 36 245 0016~ <o 0001 0.022. <0.0001 <IO 0001
0.0004 0.0004 O.Ol7c <o 0001
95.90%
monoethanolamme.
water
338. 374 230. 272
28.5% monoethanolamme. and hydrogen sutflde
water.
carbon
dmxide
Petroleum
11% monoethanotamme. water. ptt IO-IO 5 frebader head) 15% monoethanolamme. hydrogen sulfide (bottom
carbon
dloude
2%.
Petroleum
230. 240 230
<o 0001
x,0 0001
water. carbon dloxtde tray of absorber)
and
Petroleum
270
(continued)
Ferrous Alloys
499
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
Average
corrosion
rates (ipy)
TIPI
rwt
,PL
ALLOY
20 825
.
15% monoelhanolamme. Irlethylamme 6% d~ethanolamme, mately Ivaparsl dlethanolamlne. ethanol 34%. water 25%. Chemical F
.
325
.
102
.
xx
.
x
-----
304
316
317
00001
0.0001
monoethanolamme
5%
approw
Chemical (dlstdlation)
410
30
0 015
0 0032
hydrogen
sulllde
P&ochemical (heat-exchanger Petrochemical
212
110
<0.0001
<0.0001
<0 OOOld
<0.0001 0 0002 (0 0001
<o 0001
<o 0001
dlethanolamlne. bonnet1
hydrogen
sulfide
200
110
xx
i 0.0001
c.0 0001
30% dlethanalamme. voli vol water, pressure irebolter) 30% voiivol dlethanolamme, water. prewre slurry.
water, carbon dtoxide 14 10 ps~g durmg 450 hours
Petroleum
100. 150
83
c.0 0001
<00001
<o
0002
water, carbon dmxlde 30 285 pug durmg 500 hours hydrochlow acid
Petroleum
IOO230 90. 200 338
83
0 0001
0.0001
00001
0 0001
trlethanolamme
Chemical
153
0.0009b
0 0004a
0 0002
mono-
dl- and trlethanolamme,
water
<O
5%
Chemical Idistillation) Chemical tdlstlllatianl
35.5
0.0009
0.0005
dl- and trlethanolamine.
monoethanolamme
trace
410
30
0.0052 0 0016
0.0012
mono-. dl-. and trwthylamw nol, pressure 175 ps,g
ammoma,
water.
etha-
Chemical
123
102
xx
xx
0.017
0.0017 0.0002
91% 2.ethyl butanal, acetals from glycol and carbanyls 6%,
and ketals water 3%
lormed
Chemical
300
xx
0.005
0.0035
90% approrimat.?ly2-ethyl butanol, carbonyls butylene glycol 3%. toluene sulfonlc acid copper sulfate 0 09.0.6%
3.4%. 0 5%.
Chemical
300
24
xx
<0.0001
IllI
0.00066
90% approrimately2-ethyl butanol. carbonyls butylene glycol 3%. toluene sulfonlc acid copper sulfate 0 09-O 6%
3.4%, 0.5%.
Chemical
300
xx
0.0067
0 0028
0 0023
ETHlLENE
ethylene, cracked gases acid trace, hydrochloric traces, pH 5 approximately
m quench acid and
water, carbon
organic dwxlde
Petrochemical
160. 170
0 002a
0.0005b
ethylene. cracked gases acid trace. hydrochloric traces. pli 5 approximately
m quench acld and
water, carbon
organic dloxlde
Petrochemical
160 170
0 019bdl
0 007adr
0.002
ethylene
dlbromlde
(vapors)
Petroleum
R.T.
60
_.
0.0004
0.0003
(continued)
500
Corrosion Resistant Materials Handbook (contd)
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
Corrosion mediums
Test conditions
:
.
ethylene dlbromlde icolumnl Chemical id~sttllationl fumes Chemical Chemical F 200. 212 85 80 287 287
z
,wt
TIPE TIPE
2 .
-----
304
316
0.004c
317
20
ALLOY 825
0.021c
ethylene ethylene
dlbromide dlbromide
fmlshed crude
f
F
<O.OOOlbd 0 0005ad 0.0005cd
<:O.OOOld 0.0003ad 0.0003cd
ethylene dlchlorlde. Pella acid trace lo11 stripper) ethylene dlchlorlde. acid trace Ivapors) ethylene hquld) dlchlorlde. Pella
011, steam,
hydrochlonc
Petrochemical Petrochemical Chemical idlstdlation)
210. 240 100. 220 80
79
0017
0.006ad
0.0055ad
0.002ad
oil. steam,
hydrochlortc
79
0.0261
0.015
0.004ad
dilute
hydrochloric
acid (vapors,
108
<o
0 OOOlad 0001
0.0002ad <0.000l
<o
0 0002 0001
0 0002a <0.0001
ethylene
glycol
Pharmaceutical Pharmaceutical
-30
112
00001
0.0001
ethylene
glycol
115
112
0 0001
0 0001
0.108% Z-ethyl suberlc acid. sebacic acid 0.10246, diethyl adipic acid 0.024%. heavy organic acid 0 008%. ndecanolc acid trace, remainder water
Chemlcai
500
42
xx
0015
0 0086
0 0098
0 0073
stearic stearlc
acid and oleic acids
Research Chemical Ldistillalionr
F f
445 475
I 147 x
0.0262 0.0142cd
IIil <O.OOOlad
... ...
... ...
steartc
and palmitlc
acids vapors.
no air Ml
unit)
Pharma. ceutical Chemical (distillation) Research Research
221. 257 212
32
<0.0001
<0.0001
crude fatty
acids,
mixed
43
xx
0.0213d
0.0049d
soap tatty soap tatty vegetable
acids, acids. latty
mixed mlxed acids, mixed, live steam
1 1 f
230 250 365. 374 490
1.7 1.25
0.0305 0.0218 0.0021
nil 0.017 0.0007
... ... ... .. . ... ...
... ... ... .. ... ...

(continued)
Chemical
cottonseed crude vacuum still) cottonseed vapors from expeller) tatty
fatly
acids
(top
vapor
outlet
of
Chemical ldistdlation) Soap
42
xx
0.01
0.0001
actds expeller cake (Anderson oil
f F
530 170. 200
50.5 18
x xx
0.0383~ <0.0001
<O.OOOlad
hot linseed
Chemical
Ferrous
Alloys
501
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion mediums
Test conditions
,wt
,,,I
TWE
--fatty acid Seedme. acid number 170 Rubber f 150
304
316
<O.OOOlad
317
--
20
ALLOY 825
<O.OOOlad <O.OOOlad 163 xx 0.0005 0 00022
90% approximately from anlmal foot. vacuum column1
fatty-acids vapor and strlppmg steam 20%
hquld (high-
Soap tdlstdlatlon)
420
<o
0001
40% ammal fatty acids, vacuum column bottom1 castor-od fatty acids
free
pitch
60%
fhlgh-
Soap (dlstdlatlon) Pamt and Varnish ldlstdlatwnl
440
163
<o
0001
<0.0001
F r700
45
xx
xx
0 0015
<0.0001
castor-od ammal
fatty-acld
condensate fatty acids fatty acids, mamly stearlc and
Chemical Soap Soap
F F F
75 135 160. 200 450. 500
119 1218 553
<o
0001
<o 0001
<0.0001 0 0001
and coconut
<0.0001 0 0001
anlmal and coconut ole~c actds. ptl 3.6
fatty acids vapors from fish 011s
Chemical Mstdlatlon)
210
0 0016a
0 00013ad
90% fatty acids. sulfuric acid 5%. sebaclc acid 3%. sodium sulfate, potasswm sulfate. water remamder fatty acids K, acid 0 I-O 25% to C,.l, primary alcohols, sulfuric
Chemical
220. 240 212
1:
xx
xx
0 083c
0 256~
Chemical (dlstdlation. estetlflca tlon) Soap
33 3
0 02
0 02
0 0045
90% approximattly 5.15% stearlc acid. Icypress tub) ddute
stearlc
acod. ddute
sulfuric
acid
215
30
0017 0.0029 0001 0 023 O.OC& oooo4
0.0018
00016
0.0018
sutlurlc
acid
washed,
water
Soap
215
57
II
o.ooo2 ooao3
stearlc and OICIC acids. their methyl and esters. phosphoric acid, sodium methylate, alcohol and methyl alcohol traces stearlc and 0 5% lllquld palmltlc ImeJ acids. 6O*Be
lsobutyl isobutyl
Chermcal
250
21
xx
<O.oool
co.0002
sullur~c
acid
Soap
180
35
xx
<.OCKlOl
<0.0001
crude fatty acids and water alternately ptt 3 due to sulfuric acid lrom previous 60% fatty acids. water 40%. sulfwc
(water has process) acid
Soap
140
730
<0000I WOtMl2 0 0049ad 0057 0 0021
C.O.0001
I 17%
Soap
212
21
xx
0.0007d 0.003lad 0.0006 0 0005 0 0006
ammal. vegetal and fish 011s. sulfuric chloride and sodwm sulfate, pti l-10 fatty acids. nltrdes. 10 ps~g (vapors) 44.3% mately. fatty acids, naphthalene ammonia
actd. sodwm
Soap
I30
I38
xx
and water,
pressure
Chemical
590
51
0071
0.03
0 0083
0 0062
sullur~c 14.3%
acid 40 ~01%
approxi.
115. 123 250
30
xx
0.0006
0001
0 0007
20-0.02X mixture of sebaclc, adlplc, stearlc acids and phthallc anhydrlde, toluene sulfonic acid 0 5% flwd. vapors)
Chemical
77
xx
0 125 0.016 0.039 0012
0.015 0 005
0.004 0 004
(continued)
502
Corrosion

NICKEL ALLOYS--CLIMAX
TABLE
4.13:
VARIOUS
~TAIIVIISS
STEELS
AND
HIGH
MOLYBDENUM
(mtd)
Corrosion mediums
Test conditions
,wt
304
,wt
316
,PE
317 20
ALLOY 825
20.0.02% mWwz 01 sebaclc, adlplc. stear~c and phthalic anhydrlde, toluene sulfonlc acid (Ilqutd. vapors)
suds 0 5%
Chumcal
250
46
xx
0021 0 003 0 007 0 002
0 003 0001
0 0008
0 0007
F 10% Research L
77 AT.
61 l
x0 145
corr
corr
corr
lerr~c
chloride,
ammonia.
fatty
acid
Chemical
216
106
xx
,o
0001
<.0 0001
(0
0001
saturated acid 2%.
lernc.hydroxlde ptl 3.5
waler
solution,
sulfuric
Chemical
60
0 001
0 0005
10X,
cltrlc
acid 0 5%. copper
mns present
Metal iplckhng) Chemical
170. 210 65 150. 168
38
xx
0 0004d
(0
OOOld
c nrl
<0.0001
5%. 1.4%
lerrnoxlde approximately.
slurry,
water ac!d 43 g/l
F F
32 ?I
xx xx
<o
0001
<0.0001 <o 0001
c<0.0001 <o 0001 c<o 0001
sulfunc
Mlnmg
c.0 OQOI
saturated ferrous-chlarlde water chlorlc acid 0 09% (evaporator) 30%. chlwc (Iliter orgamc wasles 5%. acid 0 5%. abrawe pressl
solution,
hydro-
Chemical
275
xx
0 0046
0.0054
resorcmol 3%, won restdue.
hydropH 1
Chemtcal
175
IO
xx
0.0017cd SO 0029cd L0.0017bd 0.006 O.Oga
0 0014cd
0 0012cd
O.OOlcd
16 5% approximately. lead bon 0.07-2 mn 0 07 g/l as chlorides, pti 1 2
5 g/l,
tm (evaporatmn)
150
I 75 -
xx
co.004 co.039
62%.
water
solutmn of an allphatic
Chemical Chemical
F F
75 300. 570 300. 570 300. 570
275x 340 -
x xx
0 003b <O OOOla <O OOOla 0.00015ad 0 00015ad <o
0 003 OOOla
0 28%. catalysts m reactmn product ketone and a dlamylamme. pressure 0.28%. catalysts m reactton product ketone and a dlamylamme. pressure 0.28%. ketone catalysts m reactmn product and a dlamylamme. pressure
<O OOOla
01 an allphatlc
Chemical
84
xx
<O OOOla
0 0003a
of an ahphatlc
Chemical
55
xx
O.OOOla
24%. trace crystalluerl
of wettmg
agents.
pti 2 5 (evaporator.
Metal (pIcklingI
90. 130
I6
xx
0 OOOld
OOOld
0 0001
(continued)
Ferrous Alloys
503
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLtMAX
MOLYBDENUM
(contd)
Corrosion medrums
Test conditions
k

p 3 $
2
I
& .
<z
.
sg
P up
f
T
TPE TIPE TWL
4 .
304 -----
316
317
20
ALLOY 825
20% sulfuric acid 19 5%. lltanwm dloxlde 10% as sullale, sohds 2-396. l~tanwm (3) !on 1.7 g/I as sullale, hydrogen sulflde trace (Oorr settling tank)
Metal
122158
5 12
11.5ad
20%. lelnc sullate sodwm hypochlorlle lcypress tank)
16.18; sodurn chloride 10% 0 5-l 96. hydrochloric actd trace
Chemical
203
18
xx
xx
0.19c
0 07cd
CO 05cd
16%. some crystalllrer~
wetl~ng
agents.
pH
2.5
Ievaporator-
Metal tplckllng~
180. 210
I6
xx
0 0006cd
0.0003d
0 0002
10%.
sulfuric
actd 5%
hydrafluorlc
acid 5%
Metal
120
1.7
xx
xx
0 393
0.191
ferrous PH 1
sullale,
sultur~c
acid
waste
pickle
Ilquor,
Metal lpxklmg)
140
67
0 0002cd so 0007C 0.0002b S0.0004b LO 0008b x 0.0005cd s0.001*c 0.0005cd S0.0007cd LO.OOllbd 0.017 0.017
0 00018ad so 00021
0 000 I3ad SO 00015ad
0.0003
lerrous PH
sullale.
sullur~c
acid,
waste
pickle
hquor,
Metal iptcklmgt
100
67
0.0004cd 50.0004b
0 0002cd 0 00025cd
0.0006cd
4%.
ferric
sulfate
sulfuric
acid.
pH 2 5
Pamt
162
27
xx
xx
0 0006
weak ferrous sulfate solution ferric sulfate and dllule sullur~c sel. llqutd mterlacel
possible traces of aud (pressure yes-
Pamt and Varnish Icryslallua. IlOll
450
33
0.0107
00122
00111 0 0206
lme Iton
lerrous sullldes. INme. pH 9
rock
with
0 03
lb/ton
solu-
Mmlng
91
22
xx
xx
0 0003
0.0005
commercial damp
fertdlzer
Swifts
5-10-5.
sometimes
Agriculture
RT.
290
xx
<O.OOOld
<O.OOOld
lert~l~rer, waler 67 89%. 75% phosphoric II 16%. potasswm chloride 9 7%. anhydrous moma 2 45% lhall Immersed)
acid am-
Research
100
28
xx
0 0001
0.0001
hquld
lertdtzer
Nllrana
(half
immersed)
Agriculture
100
14
xx
0.0001
WI
fertduer. 16.74%. ammoma
waler 65 05%. 15% phasphow acid potassum chloride 14 54%. anhydrous 3 67%. pH 6 6 (half Immersed)
Agrulture
135
28
xx
0 0001
0 0001
fertduer. water 52 43%. 75% 18.6% ammomum mtrate 9.34%. Ide 8.08%. urea 1.47%. anhydrous DH 6 5 (half Immersed)
phosphonc acid ootassum chlor&non~a 4 08%.
Agrwlture
135
28
xx
<0.0001
<o
0001
mued fertduer. superphosphate,ammonum sulfate, potaswm chloride, sand, ammoma, ammonium mIrate and sulfuric aud
Chemical
F (250
56
0 0015cd
0 0002bd
(continued)
504
TABLE

4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM (amd)
Corrosion mediums
Test conditions
TIPI
TIE
TWE
.
lerf~hzers Uran 32, Feran 21. N~trana 4 Agrlcufture F 60. 80 a4 -
. x
304 ----LO 0001 <:o0001 LO
316
317
20
ALLOY
825
0001
condensed
fish solubles.
pfi 4 2
Chemical Agriculture
i F
90 185
105 30
xx x
<0.0001 <0 OOOld
<0.0001 <0.0001
<0.0001
<0.0001
menhaden fish sllckwater. peptones. ammoaclds. gelatme-hke materials, sodwm chloride, calwm and magneuum salts, audIbed with sullur~c acid to pH 5 lsmgle eftect evaporator1 menhaden fish stlckwater, sohds 4 9596 acldlfled to pH 4 5 wth sulfuric acid ItrIple etlect evaporator) rdpurs frow menhaden llsh 4 95., sollds and acldlfled pti 4 5 stlckwater contalnmg wth sullur~c acid to
Agriculture
212
28
x
XX
x
XX
~.00001
00001
Agrwlture
212
28
<o
0001
<o 0001
llntreated menhaden llsh stickwater. caustic bollout 15, washedwth hydrochloric acid S%tevaporatorl bsh stlckwater, fural: acid 2% fIsti furlc stackwater. colltammg sodwm Itubular evaporator) sollds 8 30%. eftect chloride 1%. sol-
Agriculture
200. 220 124. 200 200
51
xx
<o
0001
<0.0001
Agrulture
41
~<0.0001
0.0001
acIdtIled
wth
sol-
Agriculture
51
O.OOOlbd
<o 0001
aLld to pti 5 3 (double
evaporator1
64.2%.
bortc acid 7 099;
Chemical slurry. ptt I 9 2
RT
32
0 066
fluoborlc
acid.
alunwwm-hydrate
Metal
200
137
xx
xx
0 0016cd
CO.OOZcd
0.0023cd
32%.
boric acid
I 5%
Chemical
75
30
0.0044a
0.0037
co.0021
24 1% 24 7%
Research Hesearch
L L
175 175
IO 9
0 221
0 0472 wo 052 0 0309 wo 0475 0 0467 CO 0015d 0.0008 c0.0006 0.0003d
3 84%.
lree hydlsfluorlc /II organic
acid trdce medium
pti
I7I
Metal Chemical
f 1
95 220. 250 220 250 120
137 013-
xx
xx 0 0053c
0 0003d 00013
1%. dispersed
013xx
0.0013
0 99%.
pH 3 2-3 4
Metal
127
xx
0.0055c
0 0104cd
0.0009cd
fluosullomc waste acld contammg chlorme. chlorine oxldes and sulfuric acid IO-25 ~01% added lstdl ootl
some acid.
oxygen, sulfwc
Chemical ldlstdlatlon)
490
44
0 tic SO 027~
0.29c
0 92c
0 43c
0 49c
0.029c
(continued)
Ferrous
Alloys
505
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
e
Average corrosion ratesiipyi
9 .
FLUX
I f
f
2
:
f
5
TrT TIM TIPE
9 .
304
316
317
20
ALLOY 825
25%
zmc.chlorlde
llux.
PH 4
Metal
75. 80 60
56
0.018c
0 044c
0.003
soldermg-flux solutmn. zmc chloride. water [half ImmersedI
chloride.
ammonium
Chemical
60
_-
alummum brazmg ftuorlde or sodun
flux llthwm fluoride. sodturn chlonde ialternately immersed)
Metal
800. 1300
xx
>0
56
>0.56
FOOD
BRINE
Prague pickle solution. dun nltrlte 6%. sodurn and glycerme
sodurn mtrate
chlortde 889,, so4%. some dextrose
Food
212
xx
0.0005cr
0.0001
<0.0001
<00001
vapors arwng from Prague pickle solution. chloride 88%. sodwm mtrlte 6%, sodium 4%. some dextrose and glycerme
sodurn nitrate
Food
175
xx
0 0004
<<O 0001
,.o 0001
c0.0001
meat-curlog solution, salt 4 lb, sugar Prague curmg powder kontams sodurn trite and chtorldei 0 28 Ib,l gal water
0 24 lb and nitrate, I-
Food
45
<o OOOlr
<o OOOlr
.<o 0001,
<0.0001
brme solutmn, <020 pH557
sodwm
chloride
2.3%.
mallc
acid
Food
70
43
0 0001
0 0001
otwe
brme
contammg
lactic
acid.
salt and water
Food
66. 75
95
0 OOOld
0 OOOld
90.80%. 04%
vacuum
25.10
mercury
tParaform evaporator1
rebollerl
Chemical Chermcai
F F
180 190. 200 150 130. 140 80 170 75
115 35
xx xx
nil 0 0001
rlll 0.0001
lnorzle
on side of Paraform
73%
(Paralorm
flrst.rtage
evaporator)
Chemical Chemical
f F
64 99
xx
0 0001
<0.0001
0.0001 nil
70.30%
formaldehyde 65.45% 37%
solution evaporator) Chemical Synthetic ReWl Chemical
f
F F
30 9 41
x xx -
<0.0001 0.0003 <0.0001
<0.0001 0.0002 <0.0001
(Paraform
20% 15% 10% lfractlonatmg 5% 6.7.1% 3.5% 0.15% tower)
275 176
71 996
xx x <O.OOOl 0 0004 0001 0.0004 0.0002 <o 0001
0.0001 <0.0001 0.0006 0 0001 0.0004 0.0001 0 0001
00001
Chemical Rayon Chemical Chemical Chemical
220 210
a7 560 3
xx x
<o 0001 <o 0001

0.0005 nil
F F F
283 285 297
xx xx
58 xx xx 5.8
x xx
ml
(conbnued)
506
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hmtd)
Corrosion mediums
Test conditions
Average corrosion rates bpy)
TWL
nst
TtT
ALLOY
---
304
316
317
--
20
825
99.5% trace
trmxane.
lormlc
acid
0 01%
lormaldehyde
Chemical
245. 265 220. 225 220. 225 220. 225
125
xx
0 01
0 0023
65.50%. fornuc water remainder 65.50%. water W-SO%. water 60.40% sullur~c sullurlc
acid
to
1%.
sulfuric
acid
2.4%.
Chemical
10
xx
00313
0 03
00214
acid
2.4%.
formic
acid
l-3%,
Chemical
18
xx
0.0244~
00183
sullunc
acld
2.4%,
formz
acid
0.5-l%,
Chemical
15
xx
0 0982
0 0398
formaldehyde acid 1.3%
vapors,
formic
acid
t-4%.
Chemical
222
30
xx
0 024
0017
57.5% approrlmately tnoxane, water 40%. dehyde 2%. methyl lormate and methylal total acldlty as lor~mc acid 0 5%. mmeral sullur dloxlde 0 002% oxygen 6 50.40%. total acldlty as lormlc 4 8 ppm, mmeral aud as sullur water remamder. pH 1.9 48.37%. 47 5%. amount methanol 8% max. lormlc
I ppm. pH
lormal. 05%. acid as 2 8
Chemical
250
33
xx
0 0003
0 0007 0 0003
00001
aud 2 9%. oxygen trioxlde 00001%.
Chemical
250
33
xx
0 0423
0 0023 0 0029
0 0023
acid, pti 3-5 small
Chemtcal Rayon
F F
120 245
189 556 -
xx
\ 00001 0 0032d
<o 0001
0 0002d
acidity as unsaturates.
lormlc acid 0014%. water remainder 26%. lormlc gas stream)
46%. water 28% lscrubbmg column
methanol bottom.
acid trace
Chemical
437
859
xx
<o ooota L~.oooolc s- OOGOI
L 00001
~.00001
42%. water 38.. meLhanoI 20% pH 3-3 5 irectkatlon column)
form!c
acid trace,
Chemical
167
859
00001
L<- 0 0001 d So. 0 0001 xx
00001
L._0000l
I
40%. water 37% methanol pH 3-3 5 lscrubbmg column
23,, lormlc bottom)
acid trace
Chemical
158
859
c on001
L* 00001 s< 0 0001 00001
L. 00001 oooot co 0001
00001
25.20%. column1
011s and
water
remamder
tpurlbcatlon
RayoIl
285
b21
-~
xx
37 5. water 22 8% formaldehyde gas, nitrogen 194% methanol IO 1%. hydrogen 8 3%. carbon dloxlde carbon monoxide 0.1%. formic acid trace iplpel
Chemical
878
63
xx
;o
0001
I896.
22%. 20%. 20%.
lormx water water
acid C 076%. 80%. 80%. tormlc lormlc
water
remainder,
pH 3
Chemlcat Chemical Chemical
F F F
280 235 225
306 198 198
xx x x
0 0007d 0.00081r WI
<0 OOOld <O.OOOld <O.OOOld

nil <O.OOOld
acld 0 1% acid 0.1%
18%.
lormlc
aud
0 1%. glycols
remamder
Chemical Chemical Iconcentra. IlOll)
F F
245 275
179
27
xx
xx
0 0002d
15.12%.
lormlc
acid 2%
0.073
0 04
14%.
water
81%
methanol
3.4%.
pH 3 6 acid iprlmary con.
Chemical Chemical
F F
264 140
114 444
xx xx
0 0006
0001
formaldehyde. denser Inlet
methanol. tormlc of gas stream1
0001 L~:0.0001 s<:o 0001

c.0
<00001 L<00001
(continued)
Ferrous Alloys
507
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions S Ei
TYPE
TYPE
TlPE
304
Formaldehyde mt~tures
316
311
20
ALLOY 625
0.3%.
water
99%.
methanol
0 770
Rayon
266
00001
< 0000l
4.6% 2%. lormaldehyde water remamder 0 5-l 596. resins. (tower) higher glycols.
Chemical Chemical koncentratmn1
L
F
338 300
1 27
0 14c 0 0184 woo113
0 073c 0 004 woo113 L0.0007 wto 0004 , 00001 0 003c 0 0003d
0 063~ 0 0024
1%. formaldehyde formic larmlc acid acid
1%
water
remamder.
pH 3
Rayon Chenwal
f F F
298 220 160
296 60 4.6
00001
formaldehyde hydrogen peroxlde
0016C
0 OOlrd
0.0004d
0 0002d x.0 OOOld
0.2%.
water
99.696,
unknown
0 2%. pH 3 8 average
Chemical
90
43
0 0001
0.0001
lurlural-water VapOrsI
mixture,
some
naphthalene
(column,
Chem!cal Idlstdlatvxd Chemical (dlstdlationl F
226
40
\o 0001
00001
lurlural water mixture, carbazole and other vapors)
anthracene, phenanthrene creosote residuals (column,
244
40
<o 0001
00001
lurlural restdue. sullur~c acid, acid 33.. pressure 100 ps,g 453.5% Mural vapors, sollds 0 01-O 02% traces acid and acetaldehyde 4.5.3 5% furlural sollds 0 01.0.04%. and acetaldehyde 4.5-3 5% lurlural sohds 0 01-O 04%. and acetaldehyde vapors, traces
levul~n~c
acid.
lormlc
Chemical
338
I
70
40
0 96
0 63
acetlc aud 1.752.5%, of lormlc acid. sullur~c
Chemxal
330
0 002
00001
0 0001
0 000 1
0001
acetlc acid 1 75-2 5%. of sullur~c. formic acids
Chemical
330
82
0 0029 0 0002
0 0009 0 0001
0 0003 u 0001
0005 00001
0 0002 0 0001
vapors, traces
acetlc aced 1.75.2.5%. al sullur~c, larmlc acids
Chemical
330
71
0 0044
corr 0051
0 0009 00017 0012 0 OOIR 0 0001
00012 00313 0 0088 0 0004 0 0001
0 0002 0 0036 0 0024 0 0004 00001
0 0002 00011 0 0009 0 0001 0.000 1
4 5 3 5% lurfural vapors. acetlc sollds 0 02-O 08%. sullur~c acid, acid and acetaldehyde 4 5 3 5% Mural acid 75-2 5%. dehyde tstrlpplng
acid 1.752 5%. traces of lormlc
Chemical
298
108
0 0018 0.0001
vapors and condensate, traces 01 formic acid and column) acetlc acid 1 75-2 5%
acetic acetal-
Chemical
208. 220
132
0.0001
0.0001
0 0001
0.0001
0.0001
lurlural condensate. pmg column bottom)
ktrlp-
Chemical
208.
132
0 0001
0.0001
0 0001
0.0001
0.0001
(continued)
508
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Test
Corrosion mediums
conditions L
coke-oven gas, leavmg sulfate some sulfwc acid tar trace mixed sullur dlgester gases, dloride air 86 5% 2% water dlgestlon
saturator,
moisture,
Coal Byproduct Chemical
140. 158 150. 550 100. II0
I33
xx
0 0005cd 0.0008cd 0.092cd
0 0002
hydrochlonc lb. sulfuric of rnllk waste
acid acid
10%. 0 5%
F
F
42
xx
xx
0.03bd
gas lrom
oa1ry
79
O.OOOlcd
<0.0001
drier exhaust air. wdtef 0 06vz sodturn Iluosllxate acid a!r remamder
3 19%. hydrochloric acid with 0 369; hydrochloric
Chemlcdl
F 100
26
xx
xx
0.015 0 013.a
0014a
gases contatnlng caibon dloxlde, water, volatlles and spray rondensate contammg acid as fluorine compounds
fluorine 2%
Chemical
175
52
xx
xx
<0
16
0.057r
0.0037
GAS.
FLUE
tlue
gas, dry sullur 25 grams 1000 cu II of lOOO~BTlJ
Chemical Research
L 1
f
a50 ao400 335
30 250
xx
0.14 oooo2
0.054 0.ooo1
llue gas. luel gas
llue gas. nitrogen. oxygen. dloxlde. sullur lrmxlde lheat
carbon monorlde exchanger1
and
Chemical
60
0.0097
0.0009a
o.oao7
0.0022a
O.W21a
flue gas and condensate. sulfur dloxlde 0.1 ~1%. sullur~c acid 50-75 lb/ hour. sobd fme ash 20 lb/ hour Mler)
Power
340
240
xx
xx
<o.Giw
<O.oool
<0.0001
<0.ooo1
<0.ooo1
flue gas. carbon dmxlde 14%. acid trace. remamder nitrogen.
oxygen 2%, sulfuric some moisture. soot
Chemical
100
138
xx
xx
0.013c
0.01 Ic
0.004c
0.004c
flue gas. carbon dmnde actid trace. nttrlc acid some moisture. soot
14%. trace,
oxygen 2%. sullur~c remamder nitrogen.
Chemical
90. I30
140
xx
<oOOolc
<0.ooo1
<0.0001
<O.OOOl
Bunker C luel-011 combustmn condensate, sullur~c. sulfurous acads and anhydrldes, other combustion products, no adddIve used
Power
91
xx
xx
0 027cd 0.027cd
0.03lcd
0.006
0.015c
flue gases from kiln burnmg water, some vanadates lbollerl
Bunker
C ml.
water
Power
360
158
xx
0.043 0.051
0.0246 0.0333
0 0027 0.0029
flue gas lram boder bred gas contaming sulfur dloxlde and trwde. water and some vanadates
Power
330
158
xx
<00001
<0.0001
<C.oOOl
llue gases from kiln burnmg Bunker vapor lrom wet dlatomaceous earth wth lmpurltles lrom raw sugar Ilquor. chamber)
C 011, water Impregnated pH 5-6 (dust
Sugar
60. 130
31
xx
0.0002c
<0.0001
<00001
<0.0001
flue gas. nitrogen 78%. carbon dloxlde 18%. oxynen 2%. sulfur dloxlde 1%. sulfur trmxlde trace hydrogen sulbde trace, chlorides 0 05% some magneswm-oxide ash suspended. and solution con. tammg sullur trmxlde 1%. sullur dwde combmed wth magneswm oxide 0 5%. pH 5-5 5. but 3.3 5 durmg 60 days
Pulp and Paper
500
535
xx
0.0042cd 0.003acd 0.0027cd 0 0036cd CO 0012cd
0 0019cd 0 0024cd 0 0016cd 0 0049cd
0 0031bd
0 0026bd
(continued)
Ferrous
Alto ys
509
TABLE
4.13:
VARIOUS
STAINLESS
STEELS Test conditions
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
c g . combustmn gases from natural gas and sulfurbearing 011. water vapor 50% approximately karbonblack bag collector) rombustlon gases from natural gas and sulfurbearmg 011. water vapor 50% approximately karbonblack bag collector) combustion gases from natural gas and sulfurbearmg 011. water vapor 50% approximately tcarbonblack bag collector) tlue gases, products ot combustion of sultwc-aciddlgested corn cobs, sulfur trloxlde. sulfuric acid. carbon monoxtde, carbon dloxlde. ndrogen, oxygen, water (heat exchanger1 llue gases, products ot combustion of sulfwc-aciddlgested co, cobs. sultur trloxlde, sulturlc acid, carbon monoxide, carbon dloxlde. nitrogen. oxygen, water (heat exchanger1 flue gases, products of combustion of sulfurlc-aciddlgested corn cobs, sulfur trIoride, sullur~c acid, carbon monoxide, carbon dtoxlde, mttogen. oxygen, water iheat exchanger1 flue gases. products of combustion ot sulfuruaclddlgested corn cobs, sulfur trloxlde. sulfuric acid, carbon monoxide, carbon dloxlde, ndrogen. oxygen, water (heat exchanger1 llue gas from combustion ot Ohlo strip-mme coal. BTUfb 12800,ash 129b.sulfur 2 5-4 5% (au heater1 flue gas from combustion of Ohlo strip-mme coal, BfLl lb 12800, ash 12% sulfur 2 5.4.5%, sulfur dloxlde 0 18-O 25 voloO. flyash 1% m the gas IN heater1 flue gas contammg sulfur dloxlde. combustion products of destructwe dlstlllatlon of furlural restdue. llquld runnmg down the mst ellmmatur has ptt 2 torganlc waste mcmeratorl tuel-od combustion products, carbonate. calcmed alumina scrubber1 tlue gases (from mcmerator) sulfur dloxlde. sodturn m suspension tgas Chemical F 460 240
s
2 .
IL
2
; .
0
TIM TIPS TPl
ALLOY
20
~.0000la
304
,_,o 0002a
316
c OOOOla
317
625
<00001a
.
<o
OOOOla
Chemtcal
410
224
_-
<o
0001
<O.OOOld
0001
(0
0001
<0.0001
Chemical
340
271
<o
OOOla
<o.o001a
,O
0001
<0.0001
<0.0001
Chemical
400. 450
73
xx
0.007bd
0 0078cd
0 0068cd
0 009cd
0 0075cd
Chemical
250. 215
71
xx
0.0072a
0 0063cd
0 0054bd
0 0071cd
0 0051cd
Chemical
300
71
xx
0 0008
<0.0001
~0.0001
<0.0001
<0.0001
Chemical
300. 400
71
xx
0 0004
<o
0001
<o
0001
<o
0001
<o
0001
Power
240
197
xx
xx
0 0022
0 0021
0 0003
Power
195
270
xx
0.001
0 0014
0 0003
0.0005
Chemical
500
50
xx
xx
0.003 0 020
0 003 0 017
0 003 0 018bd
0 002 0013
Chemical
200. 425
20
xx
xx
0.0002bd
<O.OOOlad
Publtc Works Chemical water water vapor irotatmg disc Chemical Fertduer
21
xx
xx
0 006
0.005
0 005
0.007
tlue gas, water
sprayed scrubber wth
L L F
200 120 131
30 30 58 xx
xx xx xx
0 029 0 043 0 0001
0013 0011 0 0001 0.0001 c0.0001 0.0001
tlue gas, m spent kdn gas saturated
00001
0 0001
type scrubber1 hot gases 2.4% saturated wlh water vapor. sulfur dloxlde Mmmg F 170 180 x
0 0001
0 OWI
wet flue gases, carbon dloxlde 14%. oxygen 2%. sulturous acid trace, nltrlc acid trace, soot trace, nttrogen remamder alummum Soderberg-pot gases and water scrubbing sprays. some tfuorme and sulfur dloxlde. pH 3
Gas purlflca. t1on Chemical
90. 130
65
xx
0.022c
0.003c
0.0001c
0 OOlc
120
57
xx
0 003 0 0014a
0.001 0.0008
(continued)
510
Corrosion
Resistant
Materials
Handbook
TABLE
4.13:
VARIOUS
STAINLESS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Average corrosron rates (ipy)
TYPE
Twt
TIPE
ALLOY
20 825
304 -----
316
317
hydrocarbon
mixture.
hydrofluorlc reactor
acid 2.6% contammg traces
Petroleum Petroleum
f
F
100 100
487 400
0 0004cd I 0000l
0 0004bd s-0 0001
0 0003ad <co 0001
95 Iso feed lo alkylation of condensate 86% lsobutane r,-butane fluorlc acld 2.3% 011 contalmng solution 3% hydrofluorlc
9%.
propane
2%.
hydro
Petroleum
100
250
0 001
0001
0 0007
acid,
sodwm
hydroxide
Petroleum
270
28
0 085~
007lc
0 0023a
alkylate. butane and Ilghter. sulfur dmrlde and trioxode. water, pressure 200 PSI bpors, hquld)
Petroleum
128
384
L<O
0001
<O.OOOla to 0001
co0001
<o 0001
cracked reduced pawer
gasolme distdlate, from crude cracklog, pressure teboderl
both gas od and 100 PSI (depro-
Petroleum
300. 350
123
0 0005
c.0 0001
process stream through fluId catalytic umt. hydrogen sulfide 1 mol% m vapors
cracking
Petroleum llractmnat1on1 Petroleum
270
330
<0
OOOld
(0 0001
hydrocarbon. some organx Ilde. pressure (150 PSI pars. Ilquld) stabdlzed slralght-run (crude stabdlzer) gas condensate stabtllzerl hydrocarbon. lor
acid and hydrogen (evaporator tower.
sulva.
F ~720
53
0001
0 002
gasolme.
pressure
105
psi
Petroleum
325
318
0 OOlcd
0 0002cd
reflux.
pressure
100 PSI (crude
Petroleum
150
318
0 0002cd
<o
OOOlc
water.
hydrochloric
acid,
chlorides
Petroleum
105
441
WLO 0016c
0.0075c WO.0203~ <o 0001 <o 0001 co 0001
hydrocarbon gases C, to C.. catalytic cracked gasolme and water 50 gpm, carbon dloxlde ~01%. carban monoxlde hydrogen sulfide 0 2 vol% oxygen \ 0 05 vol%
Petroleum
I ~0196,
110
317
<0.0001
hydrocarbons. water. hydrogen <l 5%. hydrogen sulfide mtrogen, carbon monoxide and dnxlde. together <:I% Ivapors) 100% tray1 crackedod vapor, sulfur 05% (tower top
Petroleum ilractlonatlon) Petroleum (fractIonaIIon) Petroleum
270
640
<o
OOOlc
<0.0001c
760
252
0 0027
0 0006
decomposttmn products tor tower bottom) restdue grawty
01 cracked
gas od tevapora.
780. 785 780
58
0 001
0.0014
,.
from cracked gas 011 and 9 API. sullur 1% Ievaporator
vapor. tower
speclflc bottom1
Petroleum
74
0 001
0.0009
hot lopped crude lbottom of hot.od
011. sullur separator)
05%
approximately
Petroleum
725
100
0 0013
0 0008
gasolme. speck gravity hydrogen sulfide 00029 stbly some ammoma
82 API, sulfur 0.021%, Ibibbl. waler trace. pos-
Petroleum
225. 250
359
0.0012cd
0.0005cd
(continued)
Ferrous
Alloys
511
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
Icontd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
TVPE
TIPE
WPE
.
vapors from ge sulfide. chloride prunary drstrllalron of crude od. hydra hydrochlorrc acrd and amrnmonrm Petroleum F
.
300
304 ----0 0004cd
316
O.OOOZbd
317
20
ALLOY 825
mrd contment crude ammonrum compounds Hop of tower1
011, chlorrdes concentratron
and sulfides. 0 05N. pH 7-9
Petroleum
245
258
xx
0 0032bd
0 0016bd
gas 011. specrfrc gravrty 40.45 sulfide. carbon droxrde trace sour naphtha, water. hydrogen wtth
API,
some
hydrogen
Petroleum
60
305
0 0004cd
< 00001
<0.0001c 0 0056~
c.00001
sulftde
and chlorrdes 46 c
Petroleum Petroleum
f F
390 240 245
167 355
--
x xx
0 oolxc 0 0064~
gasohne vapors treated It/hour ltop of tower1
ammoma
hydrocarbon stream, chlorrdes 45 ppm. sulhdes trace lprrmary trrbutor above top tray1 high end pomt mow hydrogen 01 tower1
130 ppm. phenols column. reflux dts-
Petroleum
285
430
~ OOOOfd
-10 OOOld
<o 0001
strarght-run gasolme. water, sulhde and hydrochlorrc acrd
am ttop
Petroleum
334
411
x-
0.0002
tO.OOO1
hydrocarbon vapors, water, hydrogen sulfide pprn hydrochlorrc acrd <I 3 ppm (between stages rn overhead condenser from crude tlonatorl reduced redwater sulfur compounds, crude oil. superheated some naphthenic acrds
<20 two frac-
Petroleum
180
137
O.OOOSbd
0.0002ad
steam,
Petroleum
690
175
xx
<0.0001
<0.0001
<O.OOOl
hydrocarbon hqurd and vapors trllatron of crude od. chlorides sulfide 5-10 glbbl (top tray)
m atmospherrc drs10 gibbl, hydrogen
Petroleum fdistrllation)
300
329
0.004a
0.003a
strarght-run gasohne lrqurd reflux)
drstdlate
hop of tower,
vapors,
Petroleum
195. 219
156
xx
0 0056b 0 Ollc
0.005c 0.0093c 0.0009a 0.0006a 0.0007a 0.0004a
hydrocarbon, concentratron
short charn, hydrogen chloride (tower. condensate receiver)
rn low
Chemrcal lfractronatlonl Chemical lfractionabon) Chemrcal tfractronatlonf Petroleum
85
II3
O.OOla 0 OOla
hydrocarbon, concentration
short chant. hydrogen chlorrde (tower. reboder sectron)
rn low
355
113
xx
<o
0001
<0.0001
<0.0001
hydrocarbon, cancentratron
short charn. hydrogen chlorrde (lower, reborler sectronl
rn low
470
I13
xx
<o
0001
<0.0001
<0.0001
crude
or1
270
I68
0 0003a
0.0002a 0 OOOla 0.0002a
drstrllates. water, hydrogen acrd traces, pfi 6 5-7
sulfide
and hydrochlorrc
Petroleum
250
412
xx
0 0002a
drstrllates. water, hydrogen acid traces, pH 6 5-7
sulfide
and hydrochlorrc
Petroleum
175
412
0 OOOla
0 0001
0 OOOla
overhead from crude-on fade, hydrochlorrc acrd
fractronahon,
hydrogen
sul-
Petroleum
190
I28
xx
0.0004ad
00002ad
0 0003a
(continued)
512
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions
TYPE
1VPE
316
,PE
304 -P--P
strarghtrun gasohne liqurd and vapor, gravity 61 API. water, hydrogen sulfide. some ammonium chlorrde. pH of condensmg water 8 (heat exchanger1 Petroleum F 260 165 xx 0.0004b
317
20
ALLOY 825
0.0003
Stralght-run average
gasolme,
malsture,
gravdy
35.5
API
Petroleum
240. 375
76
xx
O.OlZcd
0.006gcd
strarght-run gasolme, hydrogen sulfide
some
hydrochlarrc
acrd and
Petroleum
250. 260
116
xx
0.0034a
0.0012a
crackmg of Wyommg sour crude hydrogen sulhde 0 106%. mercaptan total sulfur 0.27% (top of tower)
or1 containing sulfur 0 066%.
Petroleum
342. 352
132
-.
xx
0 007ad
O.OOOlad
condensmg vapors contarnmg waler, hydrogen fide. mercaptan sulfur and fixed gases mrd-contment (top of tower) crude, gravdy
sul.
Petroleum
268. 378
189
0.003lc
0.0022c
36 API average,. pH 7-9
Petroleum
245
315
xx
0.0009cd
0 0003cd
crude or1 from varrous sources, hydrogen sulfide and hydrochforrc acrd rn various concentratrons, not desalled:mhrbdors added flop tray of fractionator)
Petroleum
150. 270
330
0 002
0002
butane, propane, ethane, hydrogen sulkde. ammoma. cyanrde (overhead condenser)
water,
Petroleum
130
160
xx
<0.0001
<0.0001
hrgh-end-pomt
gasolrne,
hydrochlorcc
acrd
Petroleum
ZOO375 140.
116
xx
0.018r
0.009r
0.0008bd
low-end.pomt
gasoltne.
hydrochlorrc
acrd
Petroleum
116
216
xx
xx
0.0016cd
255
low-end-pomt gasolme. hydrochlorrc acrd Petroleum (vapors. Petroleum F F 130 <O.OOOlad
<0.0001
<O.OOOlad
gasohne. wdh normal top of tower)
hydrocarbon
fractmns
106
xx
xx
0.0002ad
hydrocarbons, water, hydrogen < 1.5%. hydrogen sulfide, nrtrogen. carbon monoxide and droxide together ~1% loutlet from main fractionator condensers)
Petroleum
115
640
xx
<0.0001c
<0.0001
lrght strarght-run tom)
gasohne.
mercaptans
(tower
bot-
Petroleum
370
165
0.0005cd
<0.0001c
C,-poly gasolme, C, 5%, water ~1%. pressure 225 psrg fdepropanrzer reboiled crude resrdue fvacuum tlonl lower bottom,
pH
55,
Petroleum
200
68
0.0028
co.0014
slrlpping
sec-
Petroleum
700
750
0.0003
0.0002
0.0061
hqurd hydrocarbons and hydrogen fur 1.2.1.7% m liqurd. hydrogen ammonia 1% in gas hqurd hydrocarbons and hydrogen fur 1.2.1.7% in Irqurd. hydrogen .^I ammorua 1% rn gas
recycle sulfide
gas, sul3% and
Petroleum
600. 650
221
xx
0.0004
0.0005
recycle sulfide
gas, sul3% and
Petroleum
730. 775
221
xx
0.002
0002
(continued)
Ferrous Alloys
513
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
IWDUS~RV (PROCESS)
TIPI
TIPE
TIPI
ALLOY
20 825
304
316
317
.
F
.
600
.
6 -
.
xx
vapors III crankcase
top of flash
oil. sulfuric
tank used III the re-rehning acid 1 5%. pressure
of
Petroleum
j :
0 275cd
0.0189cd
steam d~stdlat~on of petroleum treatment wth 66BC sulfuric cewer too) steam dlstlllatlon of petroleum treatment wdh 66ElO sulfwc cewer top1
lubrlcatmg 011 after acid ldlstlllation re-
Petroleum
600
10
xx
00011
00014
lubrlcatmg 011 after acid (dlstlllatlon re-
Petroleum
600
30
xx
0 0004
00005
hght flashed dlstdlates and sour water hydrochloric acid (vacuum flasher)
wth
some
Petroleum
170
98
0.0002bd
0 00015ad
West Texas crude. being desalted, sulfur prorlmately, pH l-8 (condenser, vapors) mmed Louwana crude. sulfur lb/ 1000 bbl (vacuum flasher) tar. grawty 13 API (bottom 0.26%.
0.1%
ap-
Petroleum
150. I60 750
158
<O.OOOl
<0.0001
salt
3-5
Petroleum
238
xx
0.0025cd 0.0048cd
<0.0001cd
of Vitbreaker
column1
Petroleum Petroleum
F F
750 90
357 93
x x
<O.OOOl 0.031c
<o.o001 O.Olc
<O.orml
co.0012
<O.OOOl
gasoline and salt water. total acid ~1% calculated as sulfuric acid, hydrochloric acid trace (bottom of Rock tower) salt water under sour 011. chlorides 5850 ppm. so. dlum 4225 ppm. sulfates 2500 ppm. bicarbonate 2072 ppm. hydrogen sulfide 1714 ppm. calcium 835 ppm. magnewm 310 ppm. pti 7.8 sour water contammg some hght flashed and hydrogen sullide (vacuum flasher) 10% phenohc water vapor contammg 1320 ppm (phenol recovery tower) distdlate
Petroleum
80
360
<O.OQOl
<0.0001
<O.cnMl
Petroleum
130
309
O.OOOlcd
0.0001c
chlorides
50.
Petroleum
220
71
XX
0.004r 0.03c 0 02c 0.0003cd
0.004r 0.007
0.004r 0.0009
24 API gas 011. hydrogen Msbreaker bubble tower)
sulhde.
naphthenm
acids
Petroleum
725
35
<0.0001
<O.OOOl
<OOOill
condensed reactor sure 460 pug
etfluent
01 hydrocarbons.
pres.
Petroleum
100
258
0001
0.0007
0.0011
relormet etfluent. hydrocarbons. 0.02.0 03%. hydrogen, pressure
hydrogen 500 psig
sulhde
Petroleum
875. 975 100
258
<o 0001
<0.0001
<o
0001
<o
0001
reactor eflluent flash gas, hydrocarbons. sulhde 0 02-O 03%. pressure 460 pstg naphtha leed, sulfur 0 01-O 02%. pressure
hydrogen
Petroleum
258
0.0009
0.0006
0.0012
0006
520 pslg
Petroleum
600. 750 770. 790 625 700
258
0.0002
0.0002
0.0006
0.0003
testdue from cracked 0 6-0.7% (evaporator hydrocarbon vapors.
gas oil and vapor. total sulfur tower bottom) hydrogen. sulfur 0 053% methane 38%. Petroleum Petroleum
112
xx
0.0006
0.0005
F F
102 9 -
xx
x
0.0004a
0 0003a 0.0016
gas atmosphere, hydrogen sulhde
hydrogen 60%. 2% (vapors1
(continued)
514
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
hntd)
Corrosion mediums
Test conditions
.
gas atmosphere. hydrogen drogen sulhde 2% k~ors) 60%. methane 38%. hyPetroleum f
.
900
9 .
9
3 f
TYPE
304
,PE
316
0 027
TPE
317 20
ALLOY
825
0.025
gas atmosphere. hydrogen 60%, drogen sulfide 2% (vapors) hydrogen hydrogen hydrogen hydrogen 65-55 mol%. sulfide 12.20
methane
38%.
hy-
Petroleum
II00
0 086
0.108
hydrocarbons 35.45 mol%. grams/ 100 SCF (vapors)
Petroleum
640
130
0 0008
0 0007
65-55 mol%, hydrocarbons 35-45 mol%, sulfide 12-20 grams/ 100 SCF ivapors) hydrogen 60-40 mol% (vapors) mol%,
Petroleum
800
130
0 0013
00012
hydrocarbons 70.60 mol%. hydrogen solfade 0 03-0.04
Petroleum
650
130
0 0003
0 0004
hydrocarbons 70-60 mot%, hydrogen 30-40 mol%, hydrogen sulfide 0 07-0.09 mol%. pressure 400 ps+g (vapors) hydrocarbons 70.60 mol%. hydrogen 30-40 mol%, hydrogen sulfide 0 07-O 09 mol%, pressure 400 ps~g ivaporsl regeneralmn gas and overflow waler. carbon dl oxide. oxygen. sulfur dloxlde tract?, chlorme trace ammoma trace, pressure 300 PSI
Petroleum
650
291
\o
0001
<0.0001
Petroleum
555
130
00001
00001
Petruleum
IOO500
57
0.0197c 00651
0012lr 0.0178r 0 028r 0 067r 0.0065~ WO 0067~ 0 0012a
regeneratwn gas and overflow water, carbon dioxide, oxygen, sulfur dioxide trace, chlorme trace, ammonia trace. pressure 300 psi
Petroleum
IOO900
47
100114c WLO Ol9c
wgm naphtha feed, hydrogen solflde 5 grams; co 11 average, recycle gas IS 35% of charge contams 79 mol% hydrogen, pressure 310 PSI
100 and
Petroleum
910
90
0 0024
0.0025
unleaded
gasolme
(vapors)
Petroleum
R.1
365
<o
0001
<0.0001
CLLATlNC
evaporated gelatme solutmn contammg 20.30% gelatme, salts 0 75%. actdlhed wth hydrochloric aud to pH 3
Food
II0
100
0 0004d
<0
OOOld
<0
OOOld
gelatme Ilquor. pH 3 8-4 8
acldlfled
wth
hydrochloric
aud
to
Food
130. 150
55
00001
00001
gelatme
solutmn.
sohds 4.20%.
pH 3.8-6.8
food
173
27
<0.0001
gelatme,
hydrochloric
actd (0
6%
food
55
0.0003 0.0003
0.0002
Chemical
IIOI50
.,o
0001
<0.0001
50%
approximately.
pH 2 (evaporator,
llqwd
level)
Chemical
140. 150
..o
0001
\0.0001
(continued)
Ferrous
Alloys
515
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmd)
Corrosion
mediums
Test
conditions Average corrosion rates (ipy)
IWE
ll?E
IVR
.
WUE gum.arabrc adheswe solution. lb/SO gal fhqurd levell sulfur droxide 1.5 Ink f R.T. 79
.
xx -
304 -----
316
317
20
ALLOY 825
ml c
nil
crude glutamrc Ilquorl
acrd.
ptf 5.6 Mash
chamber
above
Food Ievaporation)
158
36
xx
000013ad
<O.OOOl
0.00024ad
f 77 28
glulamrc acrd. saturated rde. ptl 3.2 lcrystallrzerl glutamrc acrd crude,
solution
of sodurm
chlor-
Food
xx
xx
0.0021c.d
O.OOlBcd
O.OOllcd
_.
hydrogen
peroxIde.
pff 3.2
Food
176
xx xx
0.0092cd
0.0012ad
glulamrc
acrd crude, hydrogen
peroxIde,
pH
I8
Food
176
0.0019cd
O.OOOB4ad
GLYCERlNE concenlrated glycerme Iall 1 suspe*lon saturaled wrlh salt. some soap Idrstdlat~onl F BP. 27 xx : 0 0027 0.0020
coocentraled glycerme crystals Ivapors)
saturated
wcth
salt.
salt
Soap fdrstrllationl
300
89
xx
0.00042ad
0.00029ad
concenlraled crystals
glycerme
saturaled
wrth
salt.
salt
Soap fdrstdlatron)
F <320
124
xx
0.0079ad
0.007Bbd
_.
._. <O.OOOld <O.OOOld
110.15% glycerme Sanger evaporator)
saturated
wrth
salt
Ilooster-
Soap
140. 220
91
--
0.0003cd
O.OOOlad
30% half-crude glycerme. sodrum chlnrrde 20%. lree bufyrrc acrd trace. water remarnder. pH 4
Soap levaporafront
210
I2
O.CfJl3cd
0.0036ad
0.003ad
IO%, purrhed acrd. pH 6
cellulose
sausage
casting strip. acehc
Food
I30
61
0.0004cd
<O.OOOld
GRAPEFRUIT
JUICE
85%
grapelrurt
turce. orange
furce 15%
Food
72
36
<0.0001
<0.0001
GREASE
wool grease bemg rehned. dtlute sulfurrc and hydrochlorrc acrds. alcoholrc caustic solution. hydrogenperoxide bleach, strong sodium-hypochlorite bleach, 2-6 batch cycle
Chemical
F <210
105
xx
09014 0.0001
0.0001
0.00013 CO.BQOl
wool grease being rehned. drlute sulfurrc and hydrochlortc acrds, alcoholic caustic solutron. hydrogen-peroxrde bleach, strong sodrum.hypochlorrte bleach, 2.6 batch cycle ltank bottom)
Chemical
F <210
123
0 0024 0.0014
0.0035
00006
c0.0007
76% anrmal mamder
grease,
sullurrc
acid 22.1%.
water
re-
Leather
100
3.3
xx
0.0004 0.0004
o.OOG9
halmum hydroxide suspensron m ammomum-sulfate and ammonurm.hydrorrde solution. pH 758.5 IftIter press, hall Immersed)
Metal
115
58
x-1
<o 0001
<O.OOOl
<0.0001
(continued)
516
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
hmtd)
Corrosion mediums
Test conditions
WPE
IWE
TWE
ALLOY
20 825
-HLXAYINE
304
316
---
317
90% horrmme slurry, ammonia 0.1%. lormaldehyde 0.01% 43% heramme mother hquor, lormaldehyde 0.2%. ammonia 0. I % 25%. lormaldehyde 40%. monia 0.3% methanot 17%. am.
Chemical
: F
I40
32
II
II
<o.ooo1
<0.0801
...
...
Chemical
!F
125
28
XI
<O.OOOl
<0.0001
...
...
Chemical
150
32
ss
<0.0001
<09001
hrrane vapor. lowboiliq vapor horn lall oil, sullur dioxide 0.3%. waler 5%
Chemical
257
250
<0.0001ad
<09001
<0.0001
NVWINE
hydrasine, various concentrations
Research
.L
OK
1)
I1
I)
(1
nvDnoBnoYIC
ACID Chemical idistillation) f 200. 212 168 37 I O.OlRcd 0.0035cd
hydrobromic acid. variws concentrations, decomposition products 01 ethylene dibromide hydrobromic acid, hydrochloric acid, crude ethylene dibromide
...... ......
Chemical tdistdlation)
55
0.0274bd
o.ctos8w
nYDRocHLoaIc
ACID CnLORloE
s**
28%
.I0
HYDROOEN
Metal lplatm~ Metat (pickling) Water Treatment Research Research Plastic
124
1.2
0.18
0.067
0.036
hydrochloric-acid lumes lrom tank contaming hydra. chloric acid 19% approximately 15% (hall immersed)
166 180 R.T.
41
xx
0.00&Z
o.C@71c
0.0966a
0.0059C
xx
0.153 0.179
0.049
10%
L L F IF
150 75 75 75
0.00388
10% 10% dilute
1
12 105
:.
xn x O.OOla O.OW2d 0.9017cd O.OOlad O.lOOld 0.00126 54.1 1.4 x x x 0.LlOO6ad
o.mi66
O.OLKI8a
: Rubber
5% 3.52% 1% 1% 0.5%
; i
Research Research
i
;L
95 77 95 140 95
6 70 6 6 6
xc xx II xs -
.. .
0.16 81.4 0.14 .
.. .
: Researdl :L
Research Research jL IL
(1 = Molybdenum content above 0.5% catalyses decomposition 01 hydrarme
Ferrous Alloys
517
hntd)
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
Corrosion mediums
Test conditions
TYPE
,PE
TIPE
ALLOY
20 825
304
Hydrochloric
316
317
ld Research Research small amounts or traces of hydroMetal (pickling) :L F
0.36% 0.036% water conlaming chloric acid
77 77 160.
1.4
70
41
2.0 0.0016
180 : R.T.
137
0.003cd
0.0007
0.0022
0.001
moist au containing
hydrogen
chloride
O.Ml4cd
DRocLclR,C-ACID YIXTURES-*.* aus0 NITRIC-ACID MlXTURES WITH HYDROCnLORlC

ACID
20%.
sulfuric
acid 5%.
nitric acid 5%
Chemical (pickling1 amine-type inSoap
F
F
120
12
L5.23
3.28
1X%,
hibitor
non-ronrc 0.125%.
detergent 0.188%. water remainder
72
90
--
0.003c
0.003c x x 0.437c 0.437.c
0.0033
0.003
0.0029
6% approximately. Polyrad I1 1Oa aminetype in. hrbitor 0.5%. some ferric chloride and cupric chloride 1%. bow acid 0 1%. chlorme 0.02 g/l <IO0 ppm. water
Petroleum
100
0.656
0.485~
0.414c
Chemrcal Pulp and Paper
f F
77
87 90
xx
xx <OOOOl <0.0001
O.OWd
nil
O.D003d
0.015X,
free chlorme
waler, mmeral acids approxlmateiy 70.80 ptf 2.8.3.5. pressure 5 psig (heat exchanger)
ppm.
Heatmg Water
140
68
xx
<O.wol
<O.OOOl
<0.0001
<O.ooOl
wash water. usually of hydrogen chloride berl
low but varying Ihydrogenxhloride
concentration fume scrub.
Rubber
45. 70
210
xx
xx
0.0001c
0.0001 b
hydrochlorrc
acrd. chlorme.
waler.
bow
acid
Chemical
77
88
xx
xx
>O.l
o.oa66c
0.02c <0.0001 0.0001 O.cKlOl 0.0001
hydrochlorrc
acrd. lactic acrd. pfi 4.5 mixture. pH 1.5 hydrochlortc acid,
Dairy food
F 1
170
60 84
xx x
<0.0001 0.0015cd O.OO~Scd 0.0001
prolem hydrolysate some sulfur dioxide,
110
HlDROClNlC hydrocyamc
ACID actd fhqwd) Chemical F
45
169
<O.oOOl
<O.OOOl
WIDROFLUORK 70% commercial
A,tlD grade 17 ~01%. sulfuric acid 10 and conMining Chemical ,F
70 350
42 14
x. xx
corr
0.49 0.24 >0.38
0.15 co.43
0.14
12 vol%, waler vapor ~019~. lluos~hc~c acid densate)
I ~01% (vapors
65-60X. nydrolluorthcrc acla 1.5.2.5%. acid. 1.2%. won 10 0.01~0.03T 0 50%. sullwc acld 50%
sulfuric
Chemical
30. 80
R.1:
28
corr
corr
Glass
0.99c
0.026
140
(continued)
518
TABLE

VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM bntd)
4.13:
Corrosion mediums
Test conditions
Average corrosion rates
(ipy)
TVPE
VVPE
TIPI
lNUUSVRV
,PROCESS,
.
F
.
350
304 ----0 133 0.139 0 0634~ corr
316
317
20
ALLOY 625
50%. au 30% on tetrafluorlde 46.5 approximately. top vapors) 38%
waler 12%. sullur~c 1% (vapors) lsobutane
acid
7%.
SI~I-
Chemical
0.163 0 113 0.001
co 081
tregeneratcorAower
Petroleum
210. 220 230 167
Petroleum Glass
F F
2.oc
COlr
37%. glass.etchmg solutlon. amm~nu~m blfluorlde 9%. water durmg 200 hours, and 49% hydrofluorlc acid. ammonium blfluorlde 1500 sulfuric acid. water durmg 24 hours 29%. glass-etchmg solution. ammonia 14% as ammon~um blfluorlde water durmg 72 hours, and 40% hydrofluorlc. ammonia 15% as ammonium blttuo. ride. ammonw~ fluosillcate 4% water durmg I76 hours
Glass
140
lO3-
0 140
0.1
12%.
hydrofluosllw
acid 0 2%
Chemical
I82
7.2
xx
0 160~
0 7Olc
10%
Metal lplcklmgl
50. 70
30
--;
0 00038
<o
0001
10.1%
Petroleum
250
49
--
0 0359 0 0446
0.0015
8%. some fluosdlclc
acid letchmg
of tubes)
Televwon Tube Manulacture
RT
120
xx
0017
0013
co 0066 0 0064
8%.
sorne fluosllwc
acid tetchmg
of tubes1
Televwon lube Manufacture
RT
120
xx
xx
0 008 0 025
0 0034 0.0086
co001
0001 co 002 0 002
6%. organic
fluorides
71%. IO%,
benzene sulfuric
19% acid 5% taller-
Petroleum Metal (pickling) Fertihrer 07%. above Petroleum
F L
215 120
226 I 8
xx
xx
0012c 0.393
0012b
00041
5%. lerrous sulfate nately Immersed1 3%. fluorme Ilquor,
0.191
sulfwc
acid 0 5%
L F
R.T. I28
I41 226 -
0.023
0.008C
0.003 O.CHlO6
1%. regenerated hydroftuow acid. lsobutane n-butane 9 6%. propane 2 4% tdepropanlzer. top tray beslde feed Inlet) regenerated hydrofluorlc ~zer accumulator bottom) acid. propane
00008
0.0004
ldepropan-
Petroleum
250
226
0.0013ad
0.0014
0.001
23.1.9.1x 22% 20% 20%. phosphoric acid l5%, sulfunc aci!I i%
f F F F
145 I45 I35 I75
90
x. xx
xx xx
0.03gc
0.005 0.002cd
94
38 I6
xx xx
_.
0 005 0.003 0.015 0.003a 0.0007 0.005 0.005 0.001 0.0025 0.013
: :
0.02c
LO.OQS LO.021
16%, 0 3%
water
83%.
s~hca
05%.
phosphoric
acid
Chemical
120
62
0.016~
(continued)
Ferrous Alloys
519
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
TIPS HydrOrlYoSdICIC aad INDUSTIIY ,PlOCESS~ . .
TYPE
,PE
ALLOY
20 825
304 -P-P19 163 xx xx X xx: 0.0017bd
316
317
10%. some hydrofluoric and phosphoric acids 96%, sodrum-Ruosilicate crystals with 1012% crystal water 8.5%, electrolytic-lead solution, lead ftuosilicate, msoluble anode slimes, lead 80 g/l, total acid 149 111 hydrofluosihcic acid, water, fluorine 0.2% approximately as hydrofluosilicic acid (gas scrubbing tower base) spray water and gas containmg low concentrations of hydrofluorrc acid, sulfur dioxide, and sillcon tetrafluorrde (gas scrubbing tower) moist gas having a low content of hydrofluoric acid, sullur dioxide and silicon tetrafluoride (gas scrubbing)
Chemical Chemical
: f ;F
140 100
0.24
0.13
0.025
0.116
Metal (lead refiningl Chemical
176
60
0.023
0.001
.. .
nil
:F
85
22
--:
0.003
0.0018
0.0014
Chemical
122
22
xx
0.085
0 052
00086
Chemical
122
22
xx
0 018 0.018
0.0012
0.0013
0 0008
60% approaimately. hydrocarbons 20% approximately, hydrogen sulfide 2.10 graMlOG cu ft during 1 week, then 2 grains/ 100 cu 11 average, hydrogen chlorrde trace
Petroleum
950
250
XI
<0.0001
OROGEN CHLORIDE see a110 DROCHLORIC
ACID
hydrogen chlorrde. dry, pressure hydrogen chlorrde. dry hydrogen chlorrde. dry hydrogen chlorrde. dry hydrogen chlorrde. dry
Petroleum Research Research Research Atomic Energy Research
F 1
180 4w
234 xx xx xx 21 <0.005 OK NC LOO11
0.0075 <0.005 OK NG
1 <900 1 >900 F 930
hydrogen chlorrde, dry
1OQO
0.17 0.14 14 26 xx I: 0.196 0.139 0.0012 0.042
95%. dry, acetyl chlorrde 3%. acetrc acrd 2% hydrogen chlorrde. dry dry chlorine, orgamc materral hydrogen chlorrde, dry caustrc soda (autoclave, vapors) hydrogen chlorrde, dry, caustrc soda lautoclave, vapors) hydrogen-chlorrde vapors from vent system and absorber hydrogen chlorrde, au hydrogen chloride, hydrogen, Zucex process, hot cycle only
Chemical Chemical
F F
52 302. 527 573
Rubber
60
L<O.OOOla <O OOOla LO.OOOla 0.0004a
O.OOOla
Rubber
573
60
0.0002a
Ravon
RT
3.3
0.015r
A 1. Atomrc Energy 1112
135
0 0032cd LO.025 LOO21
0 0044cd 0.0077
0.06*(continued)
520
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
kamtd)
Corrosion mediums
Test conditions
TYPE
,PS
,PE
---hydrogen chlorrde. dry, hrghboiling ether Research 1 R.1
304
316
0.0017
317
20
ALLOY 625
0.0064
... ... ...
... ... ...
hydrogen
chlorrde,
wet. high-borhng
ether
Research
R.T.
0 0068
0.0035
hydrogen
chlorrde.
purge. high.borlmg
ether hydrochloricto woolrag Textrle
212
0.005
0.0046
hydrogen chloride made by volatthzmg acrd solution 31.5% (shaft leadmg carbonize0
220
0 0065ad
0.0036ad
hydrogenchlorrde chlorrc acid 19%
fumes from tank contarnmg approxrmately
hydra-
Metal iplcklmg)
160. 180
41
xx
0.0086c
0.0071c
0.0086a
0.0059c
10%
au 90%.
some chlorme
and water
R1.
R.T.
92 92
118
xx
xx
O.Olc
0.0082~ 0.008 0.013c
hydrogen
chloride.
chlorme.
moist au
xx
0.01
hydrogen
chlorrde.
chlorme,
moist au
RT
0.007c
hydrogenchloride
fumes m atmosphere
Petroleum
R.T.
184
xx
0.0057b
HVORWEN
lLROIUOE Chemical f 212
IOX, acetrc acid, cationic resin, acetylrted castor oil during 8 hours; and athaline wash, water wash, sodium sulfate during 6 hours tepoxydation reactor)
XI
xx
0.027d
0.008d so.059d
86%.
stabdrzed
with sulfuric
acid
Chemical
85
6
30
xx
-
<o.Mut1
6.1%. acrd
stabilized
with
acetandrde
and
phosphoric
Cosmetic
R.T.
<0.0081
3%. stabdized
MWEN
with retanilide
: Cosmetic
R.T.
30
<0.0001
SULFIDE
hydrogen 86%.
sulfide (generator.
vapors)
Chemical Petroleum
F F F 90 176. 302 100. 170 260
56 188 166 xx -
._ x -
<0.6001
<o.Lm <O.OOOla
<O.OOOlad
air, nitrogen sulhde. water teatraction unitt
<O.OOCIld <O.@Mlad
. ..
<O.oOala 0.9002ad
hydrogen
Chemical
hydrogensulhde
gas saturated
with water
vapor
Chemical
64
OMtO1
<0.0001
8566 oaf%. ammonia 7.12%. small amounts hydrocarbons fvaporst
3-17 mall. carbon dioxide of chlorrdes. cyanides and
Petroleum
288
xx
<0.mo1 <0.ooo1
<09001
hydrogen sullide. traces of ammoma. carbon dioxide and hydrocarbon, diethanolamine. water tvaporsl hydrogen sulfide, mercaptans. acidrc moisture, pres sure 25 psr (Cotter bubble tower, bottom head) hydrogen ndrogen. ILyagfdter sulhde. carbon monoxrde and droxide. oxygen trace, some carbon-black dust plenum chamber floor)
Petroleum
215
396
x ;
<O.oOol <0.0001 10.0003
nit
00001
<o.ooo1
725
242
10.0003
Carbon Black
220. 230
93
xx
<o.O001c <0.0001c
<0.cQO1c
< O.owI
(continued)
Ferrous Alloys
521
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
hydrogen sulhde, hydrochloric acid from breakdown of chlorides and sulfur compounds in crude oil (top tray of fractronator) 1.5 vat% hydrogen, hydrogen partial pressure 485 psC
IKSUSTRV (NIOCESS) ,-
VWE
TWE
VWE
.
180 220
304 ----O.WO8cd
316
317
20
ALLOY 825
Petroleum tfractionatroll) Petroleum
0.0003cd
750
25
_.
0.0122 WO.0083 CO.0084 LO.0104 1w0.0078 LCO.0057 0.0239 wO.0171 co.0154 10.0250 LW.0212 LCO.0123
0.0112 co.01 13 10.0119 LCO.0052
1.5 valX hydrogen, hydrogen partial pressure 405 psig
Petroleum
975
41
0.0208 CO.0220 10.0240 LCO.0117
hydrogan sulfide, sour water, light hydrocarbons water contaminatad with hydrogen sulfide, mow ethanolamine trace (vertical condenser)
Petroleum PetrochemiCal Idrstillationl Petrdeum
F F
100 72
568 106
-xx
<0.0001 O.WOlad
<0.0001 0.0001ad
<0.0001 O.ooOlad <O.OOflId
32 ppm hydrogensulfide gas, orygen 1X, saturated with water vapor
85
nil
nil
NVDRDQUINDNE IX.
sodrum-sulfite Inhibitor 0.033%. pH 6 5
Synthetic Rubber Rubber Synlhetrc Rubber
90
0.00011 <0.0001 <O.MMl nil nil
<0.0001
2.5% pH 3.6.2.9 (circular-path currosion machme) 2.5%. ptf 3.5 hank bottom)
1 F
120 54
IO 25
xx x
xx xv
<0.9001 nil
NVDDXVACETIC
ACID
10%
Research
B.P.
--
0.38
nil
prinhng ink, blue (half immersed)
Ink
R.T.
79
a-
nil
nil
IODINE
iodme, pressure 400mm mercury 10%. non-romc datergent 90%. some hydrochloric acid 8.3%. isopropyl alcohol 11%. hydrochloric acid 2%, nonronrc detergent remainder
: ! :
Research Soap
1 F
842 72 80
---
0.12 0.002 0.002 xx 0.0071 0.0071
0.081 0.9003 0.0002 O.Ooal
Soap
72
0.0023
0.0073
0.0039
KLROSLNL as% :
Chemical
410
276
xx
ml
nil
(continued)
522
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
.
I(srorsne
.
x
g .
x
TIP6
304 -----
316
NPE
TIPS
317
20
ALLOY
825
94%. trace
butane
5%.
acetrc
acrd 0.7%.
organrc
acids
Chemrcal
122
276
roohng felt stock from rags, small sene, paper, sawdust. consrstency proximately lcylmder machine)
amount of kero0.5%. pH 7 ap-
Construction
60
100
xx
<o
0001
<O.OOOl
KETENES
25%. carbon droxrde II%, acetrc acrd ll%, butadwne lene 1%. acetrc anhydrrde
carbon monoxrde 12%. 10%. allene IO%, ethy1%
Rayon
68
200
xx
c ---. LC
0.0001
hrgh.borlmg
ketone
Research (distillation) Research Idistillation) ketone 0.1%. Chemical
264
0.0134
0.002
high-borlmg
ketone (vapors)
266
0.0026
0.0003
94% methyl-rsopropyl ketone, ethyl-wnyl 3%. methylethyl ketone 0.1%. alcohols hydroquinone 25 ppm. water remainder
175
<o
0001
<0.0001
<o 0001
60% methyl+sopropyl ketone, ethyl-vmyl ketone 15% VI~YI-ISOD~~~VI ketone 0.5%. dimer 4%. methylethyl ketone 0 1%. alcohols 0.1%. water remamder
Chemrcal
190
60
.,
x :
<o
0001
<0.0001
<0.0001
44% 3%. I%.
methyl-Isopropyl phosphorrc acrd alcohols 1%
ketone, water 50%, l%, vmyl-rsopropyl
drmer ketone
Chemrcal
230
60
0.0025a
0.0021
00013
0.0006
36% 4.hydroxy methyl-Isopropyl
3-methyl 2-butanone. water ketone 10%. formaldehyde
50%, 2%
Chemical
225
125
<0.0001
<0.0001
1% methyl.rsopropyl ketone, water 10%. formaldehyde 1%. vmyl-rsopropyl alcohols li 0
60%. drmer ketone 1%.
Chemrcal
225
60
0 00013
0.00016
<o 0001
2 8% methyl-Isopropyl ketone, 4.hydroxy 3-methyl 2-butanone 3% ethylwnyl ketone 0 6%, phosphortc acrd O-6%, formaldehyde 04%. water temamder
Chemrcal
220
17
0.0001
0.0001
0.0001
0.0002
LACTK
ACID
65% >BO%. reduced pressure tstlll pot, Irqurd) Chemrcal tdrstdlationl won Dairy F
BP 330. 355 110
6 6.5 -
xx
0.036 0.0005 0 0006
60%. sofutron 100 ppm
saturated
wrth calcium
sulfate.
15
0.0039cd 0.0027cd
0.0005cd
60.30% lactrc-acrd vapor. vacuum lcontmuous evaporator)
26 in. of mercury
Corn Products
115
42
xx
0.0026cd 0.003cd
<O.OOOlad 0.0003ad W0.002d
<O.OOOld
45%
taccelerated
corrosron
test)
Chemical
R.T.
14
xx
xx
<O.cHIOl
<0.0001
(continued)
Ferrous Alloys
TABLE 4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX
523
(contd)
MOLYBDENUM
Corrosion mediums
Test conditions
Average corrosion
rates (ipy)
I g
f
2
&
9 .
1%. methylene ftank bottom1 blue 0 01%. possibly cupric loos Pulp and Paper
P .
0 f
TPl
TPE
TPl
ALLOY
20 625
304 ----<o 0001

<0.0001
S<O.OOOlad
316
317
70
90
xx
<0.0001 s<0.0001 L<O.OOOla
<0.0001
<0.0001
<0.0001 s<0.0001
L<0.0001
polylactlc acid. mdetmtte Chemical F 180 38
xx
<0.0001
<0.0001
LACTOSE mdk-sugar solutlon, lvacuum evaporator) hydrochlortc acid 0.0150.03% Dairy F 132 15 xx
<0.0001
<0.0001
LEAD
FWOSlLlCATE Metal (lead refmmg) F 117 25 x
lead-fluosdlcate electrolyte, total hydrofluosdicic acld 13 32%. free hydrofluosllw acid 6 49%. lead 6 9% as lead lluosdlcate. pH <O (pump tank)
0.0072
0.0063
0.0062
0 0065
LEAD
OXlDE and chlorides of lead. tm and slurry tdlrect-ttred evaporation Chemical F BP I23 xx
oxldes. carbonates antImany. aqueous pan1
0 0007
0001
0 0001
LEAD-PLATING
SOLUTION platmg solution. mainly fluoMetal (plating) -F 70 59 --
lead, tm and antimony berates
0.0003
0.0003
0.0009
lemon lwe,
pH 2 5
Chemical
:L
70
71
xx
<0.0001 s<0.0001 <o.OOa*
<0.0001
pure levuhmc
acid (vapors)
corn Products tdlstillation) corn Products
F ! iF
260
38
xx ;
0.034cd
0.043bd
98%
100
57
0.0009d 0.0008d x 0.0133cd 0.0124cd
0.0003
crude
levulmtc
acid (vapor head of acid still)
corn Products (distillation1
I F 225 ; :
F 140
29
0.0038bd
levuluwacld vapors. hydrochloric acid rmc acid 2.5% (evaporator. vacuum)
3.5%.
for-
Corn Products
10
0.2cd 0.19cd con corr
0.061cd
ldhlum bromide (vapors durmg 600 hours above 600 hours below 212 f)
durmg 4M) 212 F. then
hours, llquld hquld during
Metal
205 217
67
0.0007cd
0.0006bd
0 003bd
(continued)
524
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
Average corrosion
rates (ipy)
EWE
TWE
EWE
ALLOY
20 625
304 ----Illhum bromide lhqud durmg 1000 212 F. then 600 hours below 212 Fl hours above Metal f 205 217
316
317
<O.OOOla
<O.OOOld
<O.OOOld
30%
levaporatorl
Al,
Conditioning
240
40
xx
<O.OOOlr
<0.OOOlr
30% during 26 days. calcium chloride 146 days, vacuum (bottom of columnt vapors from a bodmg (evaporator) lithium-chloride
25%
during
Chemical (dehydration) Al, Conditioning
20. 68 240
172
x.
<0.0001
<0.0001
30%
solution
40
car,.,
0.0069cr
48%
(boll-down
kettle)
Chemtcal (evaporation)
330
55
xx
0.0043
0.0032r
42%
(evaporator)
Chemical
312
35
xx
0.000lcr
x
36.353, sodium chloride 0.8%. calcwm chloride 0.4%. traces of won, copper, mckel. manganese and sulfates. pH 5-6 (heating cod)
Metal
160
31
0 0002ad
O.OOOZad
7%. magnewm chlorate nesum hydroxide 0.25-l%, sorption tower)
3%. chlorme pfi 6.2-6.4
3%. magitop of ab-
131
20
>0.28 corr
>0.29 corr
C0.445cd
magneswm oxide. carbon dloxlde, sulfur d!oxlde (type N Rota-Clone clpltatorl
motsture. hydrostatic
some pre-
Chemical
160
235
xx
xx
0.0001 OOOOlb 0 OOOlc 0.001 lc 0 0014c
0.0001 0.0001 O.OOOla

0.0002c 0.0001c
40% 20.18% l&IO%. phthallc 10% 5% small acid amounts of naphthoqumone and
Research Chemical Coal By products Research Research
L F F
125 95 36
4 253 27
XI xx xx
x x x
0.147 <0.0001 <0.0001
nil <0.0001 <0.0001
c<0.0001 c<0.0001
1 L
125 125
1 4
xx xx
i x
0.16 0.0005
nil nil
2.7.2.1%. concentrated apple julce. soluble sohds 72% (mostly sugars). pH 3.3-3.45 (Maloonier vacuum pan) 0X1-0.33%. apple sauce. soluble solids 21% (mostly sugars). rodwm chloride trace, pH 3.4-3.7, temperature 216 F initially 0.45.0.35%. 14% lmostly fresh apple puce. soluble solids 12. sugars). pli 3 55-3 65 (tank bottom)
Food
135
42
xx
<o.ow1
<O.OoOl
Food
RT.
57
<0.0001
<0.0001
Food
50. 05
42
xx
<o 0001
(continued)
Ferrous Alloys
525
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmtd)
Corrosion mediums
3 $
2
:
I u . .
TWX TWX TIE
ALLOY
20 825
.
O.lS-0.35%. acrd 0.264%. hard elder, alcohol pH 3 553.65 6.67.5%, acetic
304
316
317
Food
65
88
xx
<0.0001
<O.ooal
morslure and sullur lumes lrom kiln drying of green malt lexhausl venlrlator slacW
Srawing
65
223
xx
<o.Ooot
<o.o001
YANGANLSE
CHLORIDE
37% neutral Immersed1 9.3%
manganouschlorrde
solution
Shall
Chemical
220
19
:
solutron. pH 3
xx
xx
Ievaporation) Chemical 1 168 75 x -
0.033
0.026
manganese-chlorida
0.0002d
0.0001d
0.0001d
manganese-sullale solution, specrhc gravrty 1.25. 1.35. sulfur droxrde 0 5 g/l. mostly pH 4-5 ltrrpod leg 01 hrst effect evaporator body) manganese-sulfate solutron. suspended 15%, sullurrc and sulfurous acids, pH 1-2 manganese copper sullale, traces of calcrum. solids 5.
M1nrng kvaporatron)
235
II
xx
0 0005*bd
0.0003a
Mllg
140
rx
corr
0.0029
rron. srlrcon.
Chemrcal levaporatron) Mrning
212
24
0 008~
0.0009
manganese sulfate, sulfurrc varyrng concentrahons
acrd, sulfurous
acrd of
60. 145 80
23
0.0001
c<o
0.0002 0001
0% approximately. neutral leachmg solutron from leachmg 01 reduced manganese ore, ammonmm sullate 130 g/l, ferrous sulfate 20 g/l. ptl 6.5.7.5 manganese-sullate solutron oblamed wrth manganese droxrde and oxrde ore and sullurrc acrd 5% approxrmately
Mlnlng
91
xx
xx
0.0001
0.0001
Chemical
180
245
xx
xx
0.0006
0.0005
o.oOC5
0 0005
o.clwJ5
MERCIPSOL
25.5SC 19 3%. 25.581 19 3%.
mercapsol solution. naphthenrc acrd 15%. mercapsol solutron. naphlhemc acrd 15%.
sodrum hydroxide cresols 10%. water sodium hydroxide cresols 10%. water sodrum hydroxrde cresols 10%. water sodrum hydroxrde cresols 10%. water sodturn hydroxrde cresols 10%. water
zo230 220. 230 zzo230 220. 230 220. 230
3.1
xx
0.0033 LO.0045 x 0.0087 LO 0087 0.013 to 011
0 0022 LO.0018 0.0058 LO.0069 0.016 LOOII
ml
24
XI
00016
.,
25 5S& mercapsol soluhon. I9 3%. naphlhemc acrd 15%. 25.586 I9 3%. mercapsol solutron, naphlhenrc acrd 15%.
24
xx
xx
0.0051
12
xx
xx
0 0006
0.0002
25 5Se mercapsol solution, 19 3%. naphlhenrc acrd 15%.
165
xx
xx
0 0006
0.0002
MERCURIC
CHLORIDE
mercurrc-chlorrde
solution
Tanning
:F
180
0.0001
0.0001
(continued)
526
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtdl
Corrosion mediums
lest conditions
TIPE
TYPE
TWE
ALLOY
20 825
melhacryhc acid. methyl methacrylate during days, and au during 110 days lcrackmg unlt) 330 Chemrcal
.
F
.
77
304 p---p
316
317
<0.0001
<O.OOOl
<O.OOOl
95.15%. captans,
ammonra. hydrogen sulfide, l-10 water and au together
various
mer-
g/I (vapors)
water
Paper tdrstdlation) Chemical
180
762
xx
<O.OOOld
<O.OOOl
60%. acetone 23%. methyl acetate 15%. 2%. acetlc acid 0 03%. pressure 16 psig 50%. acetone 35%, methyl acetate 3%, tone I%, water 1% 36%. 33% methyl acetate water 3% 2. Pdlmethoxy ethanol 2%. propane methylethyl
165
355
<0.0001
nil
nil
8%. ke-
Rayon
158
473
xx
<0.0001
nil
<0.0001
38%.
methylethyl
ketone
Chenwal
149
150
xx
<o
0001
<0.0001
36%. 33%.
methyl acetate water 3%
38%.
methylethyl
ketone
Chemical
104
417
<0.0001
<0.0001
35%, acetone 25%. methyl hyde 12%. water 5Y 0
acetate
20%.
acetalde-
Rayon
144
707
1x
<0.0001
<0.0001
22%. water 55%. acetone 20%. methylethyl ketone 1%. ethanol 19.. traces of esters and ammo. Norm hydroxide
Rayon
180
435
xx
<0.0001
0.0001
19%. water 60%. acetone 16%. ethanol 1%. methylethyl ketone 0 5% ethyl acetate trace, sodun hydrorlde mjecled. pti 12 10.5% methanol and methylal. water traces of formic acid
Rayon
223
294
xx
(0
0001
<o 0001
Chemical
200
52
xx
0.0001
<O.OOOl
LO.0002
and carbon g%, caustic
droxrde,
remamder Chemrcal F
1.15%. amme salt 12%. sodrum chlor-
85
20
xx
0 0001
rde 1% 5.3% methanol and melhylal. water 95.98% Chemrcal F
210. 220 225
52
xx
<0.0001
<0.0001
0.5%. water 98.99%, xcbutanol ethyl ketone trace, formaldehyde
0.5%, trace
methyl-
Chemrcal
37.4
0.00027
0.00018
dlmethorybutane
crude
thqud)
Metal
266
48
0.0002
0.0002
YE,LAt.DEHDE
95.92%
0.02%
Chemical Chemical
F F
120 212
x. x x
0.00021a <0.0001
0.00038 <O.OOOl
390
dlmelhyl
chloracetyl
Chemrcal lchlorina110) Chemrcal ..,
32
25
xx
<0.0001
<0.0001
&methyl
chloracetyl
212
17
xx
0 0006
0.0005
(contikd)
Ferrous
Alloys
527
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion medrums
Test conditions
f
2
$
I u .
NPI TIM WPE
.
methyl-chloride atmosphere, latty amme 75% solutmn m ~sopropanol, amme hydrochloride, qualernary ammomum chlorides. some free hvdtochlorlc acid, pH 3-8
304 -----
316
317
20
ALLOY 625
Chemtcal
190
55
xx SO 0004ad
0.0002ad S0.0002ad
0.0002ad
0 0002
0.0001
99.3%. methanol 0 5%, acldlly as hydrochloric acid 0 000756, chlorme 5.4 ppm, copper ton 5 ppm, ran eon I ppm tactwated carbon solvent recovery) methylene and water ethylene and water methylene chloride, tormaldehyde, traces of 011s
Texlde
75. 100
56
--
ml a
nil
Rayon
140
628
<0.0001
<00001
.,
chlortde,
formaldehyde,
traces
of
011s
Rayon
185
628
<0.0001
<0.0001
chloride,
formic
acid, methylaldehyde traces of hydrochlonc
Rayon Plastlc (solvent recovery) .F
100 70
22 59
x --
x <o
0 00016 0001
0.00016 <0.0001
ethylene chloride wet, acid and other ~O~JSI~~S
<0.0001
ethylene chloride wet, bung dried in a calcwm chloride bed, calcwm chloride concentrated solutton m regeneratmg cycle idrler)
Plastic (solvent recovery)
70
57
<O.OOOl
<O.OOol
methylene-chloride vapors. water vapor, possibly traces of hydrochloric acid and other couos~ves (top of column)
Plastic kolvent recovery, dlstdlationl
:F
100
59
<0.0001
<0.0001
<o 0001
methylene chloride. pyrldme. chlorlc acid trace (vapors1
water. acetone, hydro

tdtstdlation)
: F
100. 248
56
<0.0001
<0.0001
<0.0001
<0.0001
90%.
methylaldehyde
10%
Rayon
IF
100
22
0.0001 I 0.00018
0.00011
90%.
methanol
10%.
acetone
0 3%. acldlty as hydrochlouc bon dloxlde removal
acid
0 5.1%. water 1 ppm after
0.2. car-
Chemical
jF
65. 85
400
<o
0001
<0.0001
nil
40%. acetone 50%. water 10%. traces chlorlc acid and phenollc-type products 22.5%. water from adsorber 75%. methanol condenser) 2.5%
of hydrafreboder) outlet
Plastlc tdtstdlatmn) Textile Mvent recovery) Textile (solvent recovery) Chemical
F
F
175
60
O.OOOlad
O.OOOlad
O.OOOld
O.OOOld
thquid
IOO140
53
xx
x.
xx
nil
nil
22.5%. water 75%. adsorber cook0
methanol
2 5%
(vapor
inlet
to
100. 250
51
0 0008r
0.000lr
2.5%. acldlty
water 95%. methanol 2.5%. acetone as hydrochloric acid O-IO ppm
0 2%.
75. 85 75. 85
396
0.0001
0.0001
0.5X, water 98.5%. methanol chlorlc acid 0.007%. copper IO 6 ppm. MO IO 2.5 ppm
I%, acldlty as hydromn 12 ppm, chlorme
TextlIe fsolvent recovery)
560
IllI
nil
(continued)
528
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
TPS
TIPS
316 ---
T"Pl
317 20
--
304
ALLOY 825
hexamethylene tettamme, an alkyl chloride durmg 90 days. and ammoma. aryl.alkyl chlonde during 10 days lautoclavel
Chemical
303
100
<O.OOOla
<O.OOOl
<o 0001
90%.
ethyl
acetate
5%. 10%.
water
5% acid trace
Chemical Sugar Etyproduct Chemical Chemical
I67 190
390 9 x
x
xx
0.0002 O.llOc
0.00017 0 007d
0.00012
90%. water vapor Ievaporator. VaporsI 82%, water
hydrochloric
14%. methanol
trace,
ret-butanol
trace acetate acetate
F f
180 167
384
x xx
0 00028 0 0002
0.00013 0 0002
80.1%. pentane 9 1% water 9% ethyl 0 6% tertiary butyl alcohol 0 3%. methyl 0 2% 73%. water formaldehyde 57%. 50%. 44%. 14%. ethyl ethyl 15%. Z-3%, acetate acetate methyl alcohols 47%. 40%. 37%, isopropyl 2% 6% 10% esters
ketone
4%.
Chemical
160
125
. 0 0001 nil <O.OOOl O.OOOla
<:o0001
nil WI
water water other
Chemical Chemical and ketones Chemical
162 176 162
42 25 29
x
xx
0.0002 0.0001
ethyl acetate water 7% 75%.
xx xx
xx
25%, water ketones
ethyl
acetate,
other
esters
and
Chemical
167
29
0.0001
0.0002
20%. methyl acetate 20%. ethyl acetate 15%, acetone 15%. acetaldehyde 10%. waler 7%, alcohols 5%. methyl formate 4% 18%. water 80%. alcohols 1%. formaldehyde trace 1%. trlethanolamine
Rayon
140
535
0.012a
0 0007
Chemical
200
3.8
0.00021
0.00019
15%.
water
70%,
ethyl
acetate
15%
Chemical
f F
176 181
39 29
x
XI
0.0003 0.0005
0.0002 O.O@M
<0.0001
13%, ethanol ketones 22%,
35%. water 18%. butanol 12%
other
esters
and
Chemical
5%.
water
95%
Chemical
f
f
190 210
39 39
x
x
0.0002 0.00015
0.00022 <O.OOOl
0.00015 <0.0001
1%.
water
99%
Chemical
50%.
high hollers
50%
Chemical
300
106 135
xx
0 0001 0.0001
IllI
8.7%. boders
ethyl acetate 2 45%. water
84%, light remamder
ends
and
htgh
Chemical
0.0001
turnethyl phosphate, hght aud 0.31 g/l, pti 4 8
ends,
audlty
as acetic
255
241
xx
llll
nil
MILK
mdk
Dairy
145
28
0.00017
(continued)
Ferrous
Alloys
529
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX Average corrosion rates (ipy)
MOLYBDENUM
bntd)
Corrosion mediums
TIPS
TlPE
TIPS
ALLOY
"20" 825
304 ----dealbumlmzed mdk whey the dIgestIon of milk ppm, pH 7 5 tclarlfler) Dairy Dairy F F 190 80
316
<OOOOl
317
OOOOlad
oxtdued sludge effluent lram waste, total sohds 1000-1500 oxldlzed of mdk taeratmn
c.0 0001
<:00001
sludge and mwed liquor trom the dIgestIon waste. total sohds 0 8.1.2%. oti 5-7 7 tank1 hqwds from dtgestlon 01 mdk waste,
D.alry
82
<00001
< 0 0001
sludge and total sollds
I 57,pH 7.2 0
Dairy
104
79
,00001
<o 0001
.,.
<D.OOOl
dlgester sludge lexcess oxldlzed total solads 1.7%. pH 4 5-7 5 dIgestIon supernalant liquor mdk waste, total soltds 3000 dlgester dIgester gas from gas lrom dlgestmn dIgestIon lram ppm.
sludge
and whey),
Dairy
105
79
--.
cOOOD1
the dlgestmn pti 7.5
of
Dairy
98
79
<:o 0001
<O.ODDl
of mdk waste of mdk waste
Dairy Davy steam
F F
95 105
79
<O.OOlcd
0 OOOlcd
<0 0001 <D.OOOl
79
79
dlgester gas from heater
from
dlgestmn
01 mdk
waste,
Dairy
110
<O.OOOlbd
~0
0001
60% Sulfuric lnltrocellulose
acid. mtrlc bodmg tub)
acid
20%,
water
20%
Explosives
212. 215 150
12.5
0.0006
0.0003
59%
Sulfuric
acod. nitric
acid 22%,
water
19%
Chemical
7.2
DO013
0 0005
59% 40%
sullur~c rullur~c
acid,
mtrlc
acid 22%.
water water nltrlc
19% remamder ac!d 26%
Chemul Research Metal (plcklmg)
L L F
181 150 150
2.4
0.0065
0.0043 0.0012 c0.00014
acid. ntitrlc acid 20%,
31
0.004 x D.ODO13
0.0046 0.00011
23% approximately sullwc acid. appronmately, water remainder
MOLASSES molasses acldllled wth sulfwc small amounts of phasphonc acid. fumes acetlc lrom acid. acid contammg pti 6.6 5 Icooker) sulfur dloxlde. Sugar F 195. 210 RT: 150
I
33
IX
00019
0.0015
molasses mwng tank. calcium chlortde lbluwerl
Food
;DDODlbd
<OOOOlad
NlPTl naphtha 400 API, some hydrogen sulhde and phatic acids alter vapor.phase clay treatment allPetroleum tdlstdlatwd Petroleum Idlstdlatton) F 100 400 -
<:o0001
x
<0.0001
<O.DOOl
<O.ODOl
naphtha. IBP 257 F. EP 400 F, speclflc grawty 47 3, sulfur 00089,. small amounts of dissolved am. monla. traces 01 water and hydrogen sulfide (sump of top tray 01 column1
320
538
<O.OOOlb
<o.Ocma
heavy naphtha lrom West Texas crude sulfur 04. 0 5% hydrogen sulhde. traces ol hydrochlarlc acid, carbon dloxlde and water
Petroleum Idlstdlatmn)
85
156
.,O
OOOld
<O.OOOld
<o 0001
(continued)
530
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(cmtd)
Corrosion mediums
TIPf
TlPE
TlPE
.
tqht petroleum tower1 naphtha. cracked llop tray al bubble Petroleum tfractlonaIIon) Petroleum 215
. -
304
0 0167cd 0 0133cd
--
316
0.0186cd
317
--
20
ALLOY 825
lqht
naphtha
(top ot tower.
vapors1
200. 300 100
750
., xx
O.OOOlbd
0.0004ad
<O.OOOla
tqht naphtha. ammoma. chlorides trace. pressure
hydrogen 45 pug
suthde.
water.
Petroleum
369
1 ml
L nil
96% solvent slbly evolved
naphtha, some mtrogen Ml column, vapors)
oxides
pos-
170
35 s<o
0 0003 0001 0.0014
<0.0001 so 0002
00001
<:o 0001
vlrgm naphtha stock, hydrogen 24 ~01%. hydrogen sulhde 0 21 ~01%. hydrocarbons remamder. small amounts of amrnonla and hydrochloric acid polymerlred naphtha, fluoride etherate 5% resin distillate. boron tri-
Petroleum
576
150
xx
Coal By product (tar distillation)
123. 195
66
xx
0.04
0.015
0012
0 0075
NAPHTAl_ENE
crude naphthalene, associated K.P. 200-300 C) Icolumn)
neutral
coal tar oils
Coal By product (tar fraclionalion) Chemical (distillation) Coal Byproduct Chemical
440
65
xx
<0.0001
nit
naphthalene
185
36
<0.0001
naphthalene, naphthalene sulfonic acid, sulfuric acid 66BC and 50& (conical washer bottom) naphthalene, sulfuric acid 6OB& caustic wash lo%, water wash, cychc operation (washer bottom1 washmg naphthalene. sulfuric acid 66BC 1.1-1.3 ~01%. water washmg and neutralizing wth 10% caustic soda 8.16 ~01% 65% naphthalene, tar acids 19%, ammonium ride 0.7 lb/ 1000 gal. pti 5 5 (column) chlo-
190
45
XI
xx
corr corr* corr
corr
199
12
xx
corr
0 56
0 34
Coal Byproduct
ZOO210
20
xx
xx
0.0672
0.141
Coal Byproduct (tar fractlonalion) Chemical
380
60
xx
<0
OOOlcd
Illl
<O.OOOld
naphthalene, chloronaphthalene, calcrum calcium owde, hydrochloric acid trace
chlortde.
300. 360
63
--
0 0005 0.0002
0 0004 WO 0006 0.0002
0 0003
0 0002
NAPHTHANATES
naphthanates ganese
and thallates
of lead. cobalt
and man-
Paint and Varnish
R T: 350
382
<o 0001
<o
OOO!
<0.0001
naphthenlc naphthenlc petroleum.
acid acid I dlstdlates sulfur 2.4% from South American
Chemical Petroleum
F F
450 500
15 174 -
xx
0.057 <0.0001
0.0003 <0.0001
0.0002
0.0003
naphthemc acid m heavy dlstlllate Amer~canpetroleum,sullurcontentolgasolme
from
South 1.7%
Petroleum
554
59
0.0236
0.0002
(continued)
Ferrous
Alloys
531
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
TIPI
TWE
TWE
304
heavy dIstIllate from Lagumllas naphthenlc acids, neutralization hydroxide 2 5 mgig thigh vacuum naphthenlc acid tllquld I~ne) luel value tower) contammg potassum Petroleum lgasollne condensing) Chemical F 107 0 0365 LO 0187
316
0.0011
317
"20"
ALLOY 825
450
15
0 057 0.057
0 0003
0 0002
00003
NICKEL
AMMONlUM
SULFATE tree ammoma <300 ps,g 30 g!l. oxyMming F 300 11 s0.0004
24.3% approximately. gen partGil pressure
so0009
s0.0002
24.3% approximately. nlckel.ammonlum-sulfate vapars.freeammO"la 30 g/l. oxygen partial pressure <300 pslg 21.7% approximately, free ammoma gen partial pressure 375.400 ps,g. 500 psrg Ivapors, Ilquld) 30 g/l, hydrototal pressure
Mwng
300
11
so 0001
Mining
300
so.02 so 007
so.003 so 004
nickel-chlonde
solution
bung
evaporated
Metal lplatmgl
200
26
to 0015a
0 0013ad
NICKEL.PLITING
SOLUTION Metal Iplating) F 116. 120 121 <O.OOOld
punbed nickel-plating electrolyte, mckel 42 8%. sodwm sulfate 31 6%. boric acid 21 5%. calcium sulfate 121%. chlorme lo 0053%. copper IO 0 001%. IlO lo 0001%. pH 5.2 mckel-platmg phosphate 3.3 5 bath, nlckef chloride 27 ozigal. nickel ozigal. borx acid 5.5 ozigal, pH
<0.0001
12
Metal iplatIng)
135
42
0.0007
0.0005
NICHEL 39 1.23%. 1 O-0.751.
.sLfITE copper 0.0015-0.02 acid, g/I (evaporator) Mining Metal IplatIng) f F 191 160 232 176 <0.0001 0005lcd <0.0001 0.0005cd <0
hydrachlonc
pti 3.3.5
OOOld
<O.OOOld
NlCOTlNE nlcotlne solution Agriculture flnsectludes) f high 31 0.0146
0.00233
NlCOTlNlC
A.cILl n~acene amme. dtammonlum phosChemical L 535 0.31
mcotmlc acid. phate, ammonta
0.45
NITRIC 99% 99% 99% 98.5%
AClD Chemical Chemical Chemical Explosive L L 90 90 90 90 30 WO.026 WO.048 wo.05 0.09
110 130
:L
F
86
0.074
0.203
0.042
(continued)
532
TABLE
4.13:
VARIOUS
STAINLESS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmtd)
Corrosion mediums
niT
1PE
,wt
ALLOY
20 825
.
Nafric acid
,
-
304 --p-p
316
317
98.5%
(vapors1
Explosive
86
30
0.058
0.059
0.064 0.017
0.02
97% 97% 97%
Chemical Chemical Chemical :1 :L
90 110 130
90 90 90
--: -.
-_:
WO.0125 WO 027 WO 025 WO.024 LO.15
... ...
... ... ...

0.043
white fuming
nitrfc acid
Aircraft Missile Aircraft Missile acid, water 3.5 Aircraft Missile Aircraft Missile Aircraft Missile Chemical : Chemical Chemical
and
;L
160
white
lunung nltrlc acid
and
: i
L
R.T.
A.T.
30
/
--:
LO.0045
O.OCQ5
95.&S4.5% white fuming nitric 3.9%. nitrogen dmxlde 0.94.1.67% 95.694.5X white fuming nitric 3.9%. nitrogen dioxide 0.94-1.6796 95.M4.5% white fuming nitric 3.9%, nitrogen dioxide 0.94.1.67% 95% 95% 95%
and
10
0.0008
0.0008
acid,
water
3.5.
and
!1
L
122
10
--:
0.045
0.05
acid,
water
3.5.
and
160
10
__1
0.16
0.2
co.05
L :L :1
90 110 130
90 90 90
--
-:
wo.0012 wo.OQO7 wo.0014 wo.001
white fuming
mtrlc acid, inhibited
Aircraft Missile
and
: : :
L
R.T.
160
30
LO.OQO2
o.OOil2
white turning nitric acid, inhibited
Aircraft Missile dmxlde
and
LO.001
0.0067
92.8.92.3% red fummg 4 9% water 2 3-2 9% 92.8-92.3X red fuming 4 9% water 2 3-2 9% 92.8.92.3% red fummg 4.9% water 2 3-2 9%
nitric
acid, mtrogen
Alrctaft and Mtsslle Arcraft and Mssile Alwalt and hksile Chemical
R.T.
10 __j
10 --I
0 0006
0.0008
nitric
acid. nitrogen
dmxide
122
0.065
0.075
nltrlc acid, nitrogen
dioxide
160
10
--:
0.17
0.26
co.05
red fummg mtrlc acid. speclflc gravity nitrogen dloxtde 13.18%, water 2.5% red lummg water 2-396 red tummg water 2.3% 69.5% 65% 65% 65% nltrlc acid. nitrogen
1551.59,
R.T.
-.
0.0004
dloxlde
6.5%.
Research
250. 300 50. 80 98
0.3
12
2.5
&tic
acid,
nitrogen
dloxlde
6.5%,
Research
--
0.0006 0 0004 -
0.0007
-L
xx
I
0.016 0.0051 co.0102
0004
... ...
... ...
L L L
E.P. 251 251 2 6
0.016 0.0045 CO.0148
(continued)
Ferrous Alloys
533
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hmtd)
Corrosion mediums
Average corrosiQn rates (iPY)
TWE
TWE
TYPE
ALLOY
.
Research Research 65% Research Research Research Research Research Research Research Research Research Research Research Research Chemtcal Research Research M1fWlg Research Research Research Metal L L L L L L L L L L L L L L L L L F L L L L 251 251 251 251 210 98 98 200 98 98 130 98 98 212 BP. 75 150 120 210 98 212 86 6 6 6 6 2 6 10 6 2 6 6 -
. XXI
xx xx
--
304
316
---
317
20
825
0.011
0.011 0.017 0.0193

0.0034
65% 60% 60% 509. 42% 40% 30% 25% 20%

10% 10% 10% 10% 10% 10%
--
xx xx
0 0033
0.0002 <0.0001 0.0042 <0.0001 <0.0001 0.0002 0.0001
xx xx
xx xx
: :
<o 0001
<0.0001
0.0002 0.0003
6
30
xx
1 1
70 2 6 6 14 xx xx xx xx xx -
<0.0001 <o 0001
<0.0001
<0.0001 IllI <0.0001 0 0002
6% 5% 5% 5%
<0.0001 L,0.0001 ,.0.0001 LL.0 0001 ,O 0001

L< 00001
5%
Metal
140
14
xx
xx
5%
Metal
195
14
xx
xx
NITRIC-ACID MlXTURES DROCHLORlC ACID
WITH
70%. hydrochloric
70%. 67%. hydrochloric hydrochloric
acid 2%. water acid 2%. waler acid 0.1%. water
Chemical Chemical
F F
70 200 2 0.0001
Chemical
L L
L
El.P
0.0094 0 0091
67%.
hydrochloric
acid 0.1%.
water
Chemical
B.P.
0.0088
65%.
hydrochlonc
acid 0 1%. water
Chemical
B.P.
0.0079 0.0083
(continued)
534
TABLE

MOLYBDENUM
bmd)
Corrosion
mediums
Test conditions
Average corrosion
rates (iPY)
TYPE
TIPE
TIPE
304
65%. hydrochloric acid 0 1%. water Chemical L BP. 6 0.0078 0 0077
316
317
20
ALLOY
825
65.46%,
z~rconyl
nltrate
11.13%. chloride
ion
ppm. water
60%. hydrochloric acid 40%, water Metal L
258
10
0 063~ LO.12
0.16
0 049
0 026
0.007
65.4
55%.
hydrochloric
aud
5%. water
Chemical
212
xx
0 0049 0.045 0.015 10.0063 0.0005 0.0007
X1-20%. raffmate solutlo. chlorides ppm. fluorides 50 ppm (vapors, Ilqud, tar column)
500-1000 concentra.
Mllg banurn reflnlng)
F <175
200
0 0004
0 0004a
0 0004
00005
30% approximately. 885 ppm average column)
rafhnate (vapors.
solution, chlorides hquld. concentrator
Mllg (uranwm teflnlng)
F 1175
320
0 OOlad 0 002d
0 0009 0.0003
0001 0 0004
1%.
hydrochloric
acld
10%
lplcklmg
tank)
Metal
R 1: 160
>2
74cd
1.64d
65%,
hydrofluorlc
acid
trace
Metal
251
xx
LO 006 LO.06 0 038 0.058 0.06 CO.172
50.25%. 36 75% 20%
plckllng solutton for alummum. hydrofluorlc acid 13 7% acid 3%
water
Metal
fplcklmg) Metal fplckhngf
75
--
hydrofluorlc
120
>2.7 >2.7 >5.9
0.95
0.151
0.185 0 203
0.0005
20.15%.
hydrofluorlc
aud
3%
Metal (pIcklingI acid 1.1. salt deter. Metal fplckfmg)
130
1.8
LO 193
0218
0.161
12-b%, sulfuw acid 5.8% hydrofluorlc 12% phosphoric aud <I%. Virgo gent ll.lO%, sulfuric 09-l 1% 10%. hydrofluorlc acid ll-15%.
100
101
xx
0.002
0.0001
0.0014
0.0004 s<0.0001
0.0001
hydrofluorlc
acid
Metal (pickling) Research
70
3.3
xx
1.29c
1.65
acid 3%
176
03
xx
3.78 L
aa
L62.2 W 5.12
65%. 65%,
potaswm potasswm
dlchromate dlchromate
1% 5% organic dlowe acids as glucomc, and oxide, water,
Research Research Chemical
ff P.
B P. 165
---
1.97 7.65
3.19
9.37
0.0023 OK 0 0033
concentrated nttrtc acid. saccharlc acids, mtrogen corn starch
0 002
(continued)
Ferrous
Alloys
535
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hontd)
Corrosion mediums
Test conditions 6 $
TIPS
TIPS
TIPE
304 -p--p
NltrlC 8Cld
316
317
"20"
ALLOY 825
rmxtures slag Mining F 235
60%.
smelter
70 11
xx
xx
0.0015
0.002
60%.
onreacted
slag
Mining
-x xx :
0.00296
0.00242
.
0.0116
59.5X,
water
39%,
chromic
acid
1%
Rubber
F
1
68.
62 112
42
0.0061 0.0061
0.0076
10.0113 0.013
56.5%, 1.5%
phosphonc
acid
44%.
nitrogen
dioxide
Research
15
0.012
56X, based
metal mtrates on nrcorwm
11.13%.
chloride
ion 5 ppm
Chemical
:F
F
258
10.3
xx
0.063~ LO.lZc
0.16~
0.049c
0.026
45.40%. zirconyl mtrate 0.8M, sulfate ion O.OV.4, van loo 0.003M (concentrator column. vapors above reboller pot)
Chemical Ifractionation)
190
44.7
xx
0.0016
0.0022
0.0008
45.35%.
saturated
with zirconyl
mtrate
245
34
,.
0.049
0.086 0.047 0.042 0.049 0.043c 0.029 0.017 0.026 0.021 0.0058 0.013
4135%, Mate
saturated solutmn crystals (evaporator.
of 10.35% nrconylvapors, hquid)
Chemical
245
29
xx
xx :
0.027 0.026
45.35%. chloride
metal mtrates ion 3-20 ppm
(mainly
zirconium)
lo-20%,
Chemical
250
21
--Ix;
0.016 0.01 10.033 LO.027~
40%. mtrogen sorption tower)
tetronde,
nitrous
acid,
water
tab-
Chemical
95
15
xx
xx :
0.0001 s0.0001 0.0004 SO.0025
nil 10.0001
Ilil
36%,
potassum
nitrate
30%
approximately,
some
Chemical
165
-xxi
sodium mtrate, won, calcium and magnewm nitrates and sulfates, imall amount of chlorides, water remainder (evaporator1 mtrlc acid. mtrogen oxldes ..36%, methyl pyrldme, macm. pressure (Ilqwd. vapors) ethyl Pharmaceutlcal F <415
0.0014
0.0015
0.0006 c0.0007
0.0005
79
xx
0.0044 S0.0069a 0.0088 LO 0052b 0 0091 s>o 073 L 0017 001 0.002 0 0 LO Ll 0062 39 39 4
0.021 0.017
35.25%, 30%, 30%.
mtrous
aud
traces slag methyl
(concentrator
column)
Chemical Mmmg
F F F
240 215 617
33 70 13
xx -
xx xx xx
largely mcotlmc
reacted acid,
0.002 0.43 12
ethyl
pyrldme
Chemical
29.26%. mtrates fluoride rator) 25%. 25%.
free acid 20% approximately, remamder of iron, magnewm, lead and alummum, ion 3%. sulfate ton 2% (rattmate evapo-
Atomic Energy
160. 190
52
xx
XI
00013 so.04c
00012 so 03c
0 0009
potaswm potaswm
dlchromate dlchromate
2.5% 5%
Research Research
L L
130 130
00018 0 0043
0.0026 0 0069
(continued)
536
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion
mediums
Average corrosion
rates (ipy)
1lPE
TYPE
TPE
ALLOY
20
0 0074
304 --p-p
21.2%. chloride 20%. metal nltrates 02.25%. sullate lo 3-13 ppm based on zirconium 2.5.dtalkyl pyrldlne. nlac, trace, Chemical F 222. 265 365. 315 365. 375 11 303 1
316
0.012
317
625
0 0046
0.0052
LO 0098 0031
Chemical
0 039
20%.
2.5.dlaikyl
pyrldme,
macm
tvaporsl
Chemical
0 063
0071
20% 18%.
approximately, terephthallc
reacted aud
slag acld 0 2%
Mmmg Chemical
F L
0 00014 0 025 0041 0 064
0.00016 0019
6%. former
18%.
lormlc
acid 0 296
Chemical
350
0.056
0 043
IS%.
terephthallc
acid 6%. lormlc
acid 0 2%
Chemtcal
390
05 0 0002
0 32
18% approximately untreated nltrlc acid. rallmate contammg lree nltrlc acld 3N. combmed rutrates of won. copper. calcwm, cobalt 2 7N. some phasphates and arsenates of these metals, calcwm sol. fate 20 g/l, chloride mn 50 ppm nltnc-acid Ilquor, high co,wentratmns other morgantcs Ievaporator. vapors) of lfon and
Mmmg
195
IO
0 0005
0.00015
0.0004
Mmmg
212
60
0.0045
0 004
14% apprwmately raffmate. lree nltnc acid 4N. sullates 01 van. copper, cobalt, caluum 16N. phasphates and arsenates 01 these metals, chloride ion 50 ppm approximately ralfmate treated wth sulfuric acid. lree nltrtc acid 4 6N. free sullur~c aud 0 4N. sulfates 01 capper, iron. cobalt and calctum, phosphates and arsenates of these metals, chlonde non 50 ppm 13.25%. chloride 13 25%. chloride 13.25%. chloride 13.25%. chloride Z~rcexsolut~ons, 0 4M ivapors) Z~rcex solutmns. 0 4M Ivapors) Zlrcex solutions. 0 4M Ivapors-hqud hydrogen (on 3M uranyl
Metal
210
57
001
0.003
Metal
250
84
0 0175ad
0 02
0013
0 026
Ato,,,,c Energy
BP
0 13
2.16
hydrogen
bon 3M. uranyl
Atomic Energy
BP
28
00012 SO 0006 29 2
hydrogen mn 3M. uranyl Interphase1
Atomic Energy Atomic Energy Atomic Energy Atomic Energy
BP
0 I3
Zrcex solutions, hydrogen aon 3M. uranyl 0 4M Ivapors llqud Interphase) solutions. hydrogen tan 3M, uranyl
BP
28
0.0042 so 0057 2 13
13 25%. Zlrcex chloride 0 4M 13.25%. chloride Zlrcex 0.4M
BP
0 13
sotutmns.
hydrogen
ion 3M, uranyt
BP
28
0.0045 so013
2.65%. (vapors)
Ztrcex
salutmns.
uranyl
chlonde
0.4M
Atomlc Energy
BP
00081 SO.0098
2.65%. Zlrcex solutmns. (vapors--llqwd Interphase1
uranyl
chloride
0 4M
, Atomic Energy
BP
0.543 so 333 0.17
2.65%.
Z~rcex
solutions.
uranyl
chloride
0.4M
Atomic Energy
BP.
7 28
(continued)
Ferrous
Alloys
537
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmd)
Corrosion mediums
Test conditions
NltrlL
Kid
m,r,res
2.65%. Zwcex solutions. uranyl chlonde 0 4U
Atomic Energy
B.P
068 so a45
90%. carbon dmxlde 6%. carbon monoxide 1%. traces of butanes, penlanes, water and atdehydes
Rayon
86. 131
ii78
x~
<.0000l
0 0001
OIL.
CRUDE
o&betd crude 011lvaporsl crude o11, sodwm chloride 67 lb/l000 bbl. sulfur 0.342% as sulfides (top of crude flash tower1 o+fwld crude 011.salt water
Petroleum Petroleum (dlstillatmnl Petroleum
60 230
399
<0.0001c
xx
<0.0001 0 005cd
43
0.01 I 'cd 0 008Cd <0.0001
60. 130 250. 350 R25
399
<O.Oool
lllmo~s crude ml, API gravity 37, salt 100 lb11000 bbl, sulfur 0 4% (vacuum pipe stdll sweet crude, small amount of hydrogen sulfide (flash towert OIL. FUEL light fuel 011, some water, ethylene dichloride and hydrochloric acid hghl fuel ml, some water, ethylene dlchlonde and hydrochlwc acid diesel ml. pentachlorphenol 5%
Petroleum
463
<0.0001
<O.ooOl
Petroleum
73
0 0006
0 0008
0 0006
00015
0008
Petroleum
225
45
xx
0 02cd
0045c
Petroleum
150
45
xx
0 004ad
000%
Chemul
225. 232 ao105
46
--
<o 0001
<00001
IueM washmg. aud wash wth 6686 sulfwc acid 4 lbibbl durmg 4 hriday. and caustic wash wth Ioak sodurn hydroxide 1~1% combuslmn products of gases horn 011burners, sullur dmxlde, sulfur trwxlde. selentum dioxide (uptake from shmes roastmgl
Petroleum
56
xx
xx
0 018b
ooiaa
0017.3
Chemical
1100
42
xx
0 007b
0.007a
0 008
0.006
lube OIIL, azeotraplc salutmn of water and phenol 10% Ialternately Immersed) sour lube 011. hydrocarbons 58%. water 40%. WI. lur~c acid 2% (heavy 011agitator bottom) lubrlcatlng 011s.sulfurvz acid. total acldlty 25% lube-ml frachan of heavy crude prmr to neutraluatlon. naphthenlc acads. orgamc sulltdes. some strippmg steam (vacuum tower, vapors)
Petroleum
210. 230 100
230
xx
0 0002
00002
Petroleum
IS
0 ooaad 0 019ad 0 566 0 0016cd

00016'cd
0006a
Petroleum Petroleum Mstdlahon)
F F
220 620
10 I83
056
xx
00001
co 0001
(continued)
538
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
kontd
Corrosion mediums
Test conditions
,wt
TIPE
7PE
304 -----
316
317
26
ALLOY 625
98% mmeral 200 lb/day
ml, water
2%,
caustic
added at reflux
Rayon
392. 401 131. 158 52. 140
1168
<0.0001
0.0002
80% absorptmn od. butane and pentane 18%. bon monorlde and dmwde 2%. water trace
car-
Rayon
1168
<OOoOl
<0.ooo1
O.OO3d O.Wl4 CO.OW6
hght 011 washmg wth sullur!c actd concentrated and sodlum hydroxide 20%. carbon disulhde. hydrogen sulhde. water 5% tliqwd level1
coat Byproduct
189
0.002d
light 011 Ibenzene. toluene. sulfuric acid 92.98% and VOI %
aylene) warhmg wth wth caustic soda 16
Coal Byproduct
115
30
0.02cd 0.051c 0 OOSa
0.017 0.048 0 005a
co.025 co.033 co.004
crude benzol washed wth sultur~c acid 93%. dduted to 50% actd m cycle, lotlowed by neutralizatmn wlh mdk 01 hme
Coal Byproduct
110
41
0 073c 0.02 0 077c

0.00067ad
0.09c
0.087 0.015
0017 0.012 0.002
non-conderwble ml. condensed
gases and condensate of hght gas steam Ivacuum-stdl condensate Imel
Petroleum
90. 120
50
<O.OOOl
hydrocarbon trahzed wth
011. small amount of sulfuric acid, new caustic solutmn 10% (vapotsl
Chemical
110
57
<0.0001
<OolNl
hydrocarbon od. small amount ot sutfwc tralwed wth caustic solution IO%
actd. new
Chemical
120
57
<O.OOOlb
<O.ooolc
hght 011. steam dlstdled Itop. bottom ol stdlt
wth
creosote
wash
011
Chemtcal Icoal)
284. 320
nil 0.0002
cracked petroleum gas od. < 27C.. mercaptans. orgaw stage tar separator)
combmed sulbdes
rullu~ (second
Petroleum
760
175
xx
0.0042
0.0037
gas 011 lram of tower)
crude charge.
sullur
0 5%
(bottom
tray
Petroleum Ifractmnatlon)
715
116
II
0 0005
0.0005
strlpper 011. Jlmonene 95%. lighter alcohol, esters and other components durmg 7 days. and alcohol 65.60%. water during 239 days (freezer)
Beverage
-30
246
xx
xx
<0.0001
<0.0001
vapors and droplets of peroxldes. aldehydes, lem. fatty acids. 011 traces. all suspended (fume box at base of venturi scrubber)
acrom air
Chemical
30. 200
253
xx
xx
<o
0001
<0.0001
50.20%. sollds
sulfuric
acid
1.5.3%,
suspended
crystals,
Chemical
F
L
125
25
xx
0.0003d
0 0004
c0.00044
oxaltc acid, Oakde solution, sodium known wettmg agent 2% approximately
bisullate,
un-
Metal (pIcklIngI
180
--
0.0002 0 068
<o
0001
(continued)
Ferrous
Alloys
539
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmtdl
Corrosion mediums
Test conditions
TPt
TPl
TYPE
ALLOY
-20 825
304
OZONE
--
316
317
0.23% ozone approximately
III air,
nitrogen
pentoxlde
0.1
mg/l
Chemlcat
R.T.
60
0 0004
ozonated
tap water
Water Treatment
35. 70
\o 0001
ester gum. drymg
011s fvapors,
hquid)
Pant and Varnrsh
550. 600
20
0 0001 0 0001
neutralized varmsh, acetlc acid 63 7%, water 16%. methyl acetate 2 5%. ammonium sulfate 2 2%. lormaldehyde 7%. ammonwn acetate 0.3%
Plastic
122
73
<o 0001
<o 0001
PALM
OIL Metal
palm 011
350. 450 300
30
<0.0001
c.0 0001
palm 011
Metal
sulfite-dlgester hquor, free sullur dloxfde 7.02%. combmed sullur dloxlde 1 21% ImU composltlon average). cookmg acid has sulfur dloxlde 7.42% total. pH 1.32, pressure 65.70 psig sulhte sullur Ilquor, droxade lree sulfur dloxlde 6 3%, combmed
Pulp and Paper
131
55
<0.0001
<0.0001
I 2%
Pulp and Paper Pulp and Paper
172
51
0 0005bd
0 0001
0 0001
sulllte cookmg acid, total sullur bmed sulfur dloxlde 1% tat start
dloxlde 6%. of cookmgl
com-
260
96
co 0002
0 0004 0 0025~ c0.0002 0 0001
0 0007 0 0005
calcium-blsulhte 4 4%. combmed sulbte dloxlde pulpmg
cookmg tlquor, sulfur dloxrde vapors. large
I 1%
free
sulfur
dloxlde
79
172
to 0001
0 0001
0 0001
amount
of wet
sulfur
180
17
0 0002b
00001
paper
stock,
weakly
acid to pH 5 (flow
box)
Pulp and Paper sulPulp and Paper Pulp and Paper
65
109
0.00014cd
<0
OOOlad
paper stock. corwstency lurrc acid 4 mgil
3%
approxamately,
84
76
<o
0001
10
0001
water suspension of sulhte fiber 0 4%. sulhte liquor trace. pH 6 Illat screen header)
waste
35
48
n1l
nil
n1l
PAPER.
.NI~OIWI
A,CID PULPING.
SPENT
wUOR Pulp and Paper F
3x,
sulllteblsulflte pti 6.2 (top at packmg
solutlon, sullur dioxide m absorption tower)
103
0 0002
0 Ml03
(continued)
540
Corrosion

STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM (contd)
TABLE
4.13:
VARIOUS
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
TYPE
*WE
316
TlPE
.
Pawr.
.
107
.
2.2
.
II:
.
xx
304 ----0 0003
317
20
ALLOY 825
ace* pulptng.
spent ,,quo, Pulp and Paper Pulp and Paper Pulp and Paper F 0 0004 0 0004 0.0004
ammonium sulf~le~btsulf~te solutlan. sulfur dioxide 3%. pti 6 2 (top of packmg I absorption tower) dlgester hquor, sulfite 3 4% sulfite solved box1 sulfur dloxlde 4 7.5%. calcium bl-
70
faa
0 0001
0 0001
0.0001
pulp suspension. sollds 1500-2000
consistency ppm IsulfIte
O.SZ%, dtis. screen head
45
97
(0.0001
<0.0001
sulfite pulp consistency so screen head box) wash Dll) water from sulfite
0 25-O 6%.
pH 4 5-6 (Johns.
Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper
51
106
xx
I):
0.0001
0.0001
stock.
pH 5 75 fsulflte
seal
60
140
..o
0001
<o
0001
c<o 0001
c~ooool
wash water seal box) sulfite waste
from
sulfite
stock.
pH 5 twhlte-water
a4
140
xx
I:
00001
x.0
0001
Ilquor.
pH 3 5
F
F
265
132
1:
0 OOOlad
0 OOOlad
sulfde
waste
liquor
190
180
II
IX
0 0001
0 0001
00001
00001
water vapor base sulfite VaporsJ
wth orgamc sulfide, remainder sodwmhquor recovery. pH 4 5 (evaporator,
228
64
0 0001
0 0001
0.0001
sodwm hydronde II 5% expressed as sodtium oxIde. sodwm carbonate and sulfide etc 5%. cookmg Western red cedar tblow end cone of rotatmg dlgesterl
Pulp and Paper
F <350
31
0 0002
0 0006
0001
sodium hydronde II 5% expressed as sodwm oxIde. sodwm carbonate and sulfide etc 1 5%. cookmg hemlocks 90% and spruce 10% (blow end cone of rotatmg dlgesterl
Pulp and Paper
F ~350
31
0 0002
0.0006
0 0006
ktaft pulp stock, chme, flow boxI
alum
wed,
pH 6 5-7 (paper
ma-
90
43
<0.0001
<0
OOOld
flue gas from kraft black.hquor recovery furnace. sodium sulfate, sodium carbonate. sulfur dioxide. sulfur trloxlde. hydrogen sulfide. methyl mercaptan, water, orgamc oxtdatlon products. sodium compounds as sodturn sulfate 1.7 lblmin (venturi scrubber1 flue gas from kraft black-hquor recovery furnace, sodwm sulfate, sodium carbonate, sulfur dioxide. sulfur trloxlde, hydrogen sutflde, methyl mercaptan. water. organic oxldatlon compounds, sodium compounds as sodium sulfate 10 Ib/min (venturi scrubber) sodlum bonate carbonate. sodwm (mud thlckenerf sulflde. calcium car-
160. 200
66
0 012cd
0.0002cd
O.OOOlbd
O.OOOlbd
Pulp and Paper
400. 435
66
0 OOOlad
<O.OOOlad
<O.OOOlad
<O.OOOlad
Pulp and Paper
iao
204
<OOOOl
<O.OOOl
47.43%
black
hquor
Pulp and Paper
450
25
0.021
0 047
(continued)
Ferrous
Alloys
541
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
s .
41.43%
black lrquar Pulp and Paper 450 60
2 c y Q
. -.
s
TYPE
,PE ,PL
304 -p--p
0 028
316
0 049
317
20
ALLOY 825
Caustic
IllIrate.
pH 9 5
Pulp and Paper after last washrng fwhrte-water flume Pulp and Paper
140
45
xx
L.
OOOOld
L<O
0001
0 OOOld
<00001
<o 0001
<0.0001
bleached sulhte whrte water stage of calcrum hypochlorrte from deck& zmc-hydrosulhte bleach,
70. 85
a7
<OOOOld
<o
0001
pH 4.2 (Oliver
washer
vat)
Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper
139
209
0 0001
0.0001
bleached sulfate pulp contammg rme ffuststage bleach washer) waste 0.0350 water from 07 gi I chlormatron
some resrdual
chlo-
68. 78 60. 90 160
31
xx
0 002cd
O.OOlcd
0 0007d
0 0004ad
0.0003ad
washer,
chlarrne
F
F
83
<O.OOOld
<0
OOCIld
chlorme-droxrde water, chtorme-droxrde gas, hydra. chlorrc acrd 0 2 gl I, pH 3.5 thltratron box) bleachrng solutron, sodrum hypochlorrte 40 gl
45
xx
LO 0008 0.0006 0 0003c 0 0003
0 0002b
0.0002
0.0003
95
17
0 0003
bleachmg
solutron.
sodrum hypochlorrte
150 g/l
85
17
--
0.0014
0.0003c
<o
0001
bleachrng
solutron.
calcrum
hypochlorrte
40 g/l
95
17
--
0 0062~
0.0428~
0.0003
hypochlorde solutron, calcrum chloride 1.5 g/l. crum hypochlorrte 0.1 g/l. pH 7.2 (washer) Pratt pulp stock wrth resrdual bleach, pH 6 5 (head box)
Cal-
120
68
xx
xx
L0.0004bd
10.0002a
0.0093a
0.0003a
O.tXKfla
chlorrne-droxide
155
14
xx
0.0003a
O.OOOla
co.0002
0.0001
paper-mrll head-box stock, groundwood and sulfite pulp 0 5-O 6%, chlorme ppm, pH 5 2-6
Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper
97
169
xx
xx
0 0001
0 0001
groundwood crdes, pH 5
pulp to deckers,
alum
300 ppm, shmr-
120. 127 130
161
< 0.0001
<o
0001
groundwood stock au dry alum 4 4-4 1 ientrdnce to bull screenL groundwood teed. alum 0 469,, slrmrcrdes. pH 5 300
6-8
lb/tan,
pH
152
xx
i 0 0001
<00001
ppm,
consfstency
125
161
xx
<0.0001
<00001
groundwood pulp stock. sulfurrc droxrde pH 4 2-4 4 Wourdrrnrer) groundwood bottom) pulp, consistency 3.4%
acid
and
sulfur
87
210
xx
00001
0 0001
0 0001
(washer
flume
140
163
<O OOOld
(0
0001
vapors from groundwood
pulp grmders
(exhaust
fan)
91. 130
189
<o
0001
<0.0001
sultur droxrde. being absorbed m sodrum-carbonate solutron. sulturrc and sulfurous acrd, carbon drox!de. tree sulfur I the gas Itan rnletl
Pulp and Paper
160
45
0001
0 0007
0.0007
(continued)
542
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions
.2 .
neutral sulhle serm chemrcal coohmg hquor. spew me I sulfur-dmrlde gas durmg 52 days, I hquor wlhout sulfur bm~~de durmg 81 days. sodwm sul. hte 14 Ibcu 11 and sodwm carbonate 3 5 Ib:cu 11 I hnrshed hquor (absorplmn towerl Pulp and Paper
TYPE
TYPE
TYPE
.
140
304 -----
316
0.0001
317
0 0001
20
c0.0001
ALLOY 825
neutral washer
sulhte. vat)
semr-chemrcal
pulp
lvacuum
stock
Pulp and Paper
176
125
xi
xx
0.0001
0.0001
spent ratorl
neutral
sulhle
semi-chemrcal
hquor
levapo.
Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper
131. 216
56 6 x
I x
0 0001 0
00001
0 0001 c0.0002
0 0001 0 0001
spent neutral rator. vapors) spent rator) neutral
sulhte
semrxhemrcal
lrquar
tevapo-
131. 216 131. 233 212
0002
0.0004
sulhle
semi-chemical
hquor
levapo-
0 0001
0 0006
co 0003
water, steam, carbon dmxrde. sadrum carbonate and sulfate, sulfur droxrde and trmxrde (exhaust gas from tower, bemg absorbed m soda-ash salutronl sodrum-sulfite Me, thtosulfate evaporator) sodwm-sulhte Me. thmsulfate Irquor. and sodrum sulhde, polysulhde. pH sadturn sul10 (vacuum
95
xx
0 038~
0 0089
0.0062
Pulp and Paper
212
6.4 -
0 0001
0 0001
0.0001
hquor, sodwm and polysulhde,
sulhde, fodwm sutpti 10 tevaporatorl
Pulp and Paper
212
--
0 0022
00001
0.0002
bller stock contammg waste paper 75%. top lmer stock 25% tmlxture of sulhte. soda and kraft pulps wth envelope cuttings). alum treated to ptt 4.3 waste paper pulp tcyhnder mold1 waste paper pulp tcylmder mold1 0.25%. sodium chlortde 1%
Pulp and Paper
75
140
xx
<o 0001
<0.0001
110
115
180
xx
xx
<0.0001
<0.0001
025%,
sodrum
chloride
1%
115
180
xx
xx
0.0012cd
<0.0001
parchmentlzmg nrtrrc acid parchmentlzmg cwm sultate parchmentwng
solution.
sulfuric
acrd
65 5-68 5%
Pulp and Paper Pulpand Paper Pulp and Paper Pulp and Paper Pulp and Paper Pulp and Paper
60
88
53 50 53 88 x xx x x xx x
<0.0001
<o 0001
0 0001 0.0001
:o 0001
0 0001 0.0001
<o 0001
solutmn,
sulfuric
acid
54%.
cal-
65 65 60 70
0 0001 0.0001 00001
0 0001 0.0001
sotutmn.
sullur~c
acrd 35.40%
parchmentwng
solutmn.
sulturrc
acrd 35.40%
00001
0.0001
O.COOl
parchmenlwng nrtrrc acid
solutmn,
sulfurrc
acrd
35.38%.
<o 0001
x x 0.0001
<o
0001
00001
<o
0001
parchmentwng
salutron,
sulfuric
acrd 5.8%
70
53
0.0001
0 0001
0 0001
(continued)
Ferrous A l/o ys
543
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmtd)
Corrosion mediums
Test conditions
TYPE
TYPE
TWE
.
glue alum paper starch alum we. mg 1 3 days we. ptt 5-6 durmg 7.7 days, and small amount of zmc sulfate durPulp and Paper F
.
140
.
9
.
x
.
x
----
304
316
317
20
ALLOY 825
0.0001a
0.0001a
white water from bleach pH 3 7-4 durmg 167 days,
sulhte drssalvmg pulp, and 55.5 during 83 days
60
250
xx
xx
0001
0.0001 <0.0001 <0.0001 <0.0001
whrte water. consrstency 0.25%. sulfites 38 ppm, thmsulhtes 22 ppm. ptt 3.8-5 (paper machme wire prtl paper-machme whrte water. hber 0.07%, alum. suihte waste hquor. phenyl rnercuw acetate trace, pti 4.3 (canal from suctron box) sulhte whtte waler, alum. some pulp lpump box) we. trtanrum droxlde.
118
100
<~0.0001
Pulp and Paper
83
35
xx
xx
<o OCOl
<0.0001
Pulp and Paper
70
79
xx
xx
<o 0001~
<o 0001
<o 0001
groundwood pond) groundwood lgroundwood
white
water
(groundwood
screen
shower
f
F
88. 118 108
231
xx
xx
0.0001
<0.0001
wtute screen
water. consistency shower pond)
0.06%
295
xx
xx
<o 0001
<o 0001
groundwood white water. total acrdrty as calcwm carbonate 534 ppm. pH 42 average (groundwood screen shower pond1 groundwood 5 3 average whrte water. consrstency 006%. pH
123. 136
134
xx
\0.0001
<0.0001
<0.0001a
Pulp and Paper
108
141
xx
<0.0001
<o 0001
senwchemrcal
neutral
sulhte
hquor,
pH 7.2
Pulp and Paper
110
82
to 0001
0001
0.0001
0 0001
papevmachme
whrte
water
krffler)
80. 106
231
xx
xx
<00001
<0.0001
paper-machme whrte water. sulhte 18.22%, consrstency pH 4.4 approximately
groundwood 78.82%. 0.3% approximately.
66
150
xx
<00001 <0.0001
<o 0001
newsprmt whrte water, groundwood and sulfite furrush. small amounts residual wood acrd. sulfurous acrd. calcium bwlhte. bleach hquor (paper machmel paper-machme white water, total acvAty as calcium carbonate 37.3 ppm average. pH 4.3 average paper-machme 0 01%, whrte water. consistency 0.002.
Pulp and Paper
95
186
xx
xx
< 0.0001
<o 0001
87. 107 32
140
xx
xx
. 00001
~.00001
00001
974
llll
WI
pH 5 trltfler) sulfate and
paper-machme white water, aluminum hydroxrde. pH 5.2 average Ifourdrinierl
60. 85
185
0.0001
0.0001
(continued)
544
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions E r t; P r i-5 3 8 oc UyI -9s f

et2 L s
INDUSlIV IPIIOCESSI -. PAPER. WASTE WnlTE WATER. PAPER BOARD.
s c
I
g
1VPE 1VPE TPE
t .
4 .
304 -----
316
317
20
ALLOY 625
rrch whrte water from hardboard manufacture, ptl 4.346
Pulp and Paper
110
275
<O.OOOl
<O.OOOl
PAPER.
WlTE
WATER.
SODA
soda-pulp whrte water
Pulp and Paper
60
32
<0.0001
<0.0001
PAPER.
WHITE WATER.
SVLFATE
kraft and semrxhemrcal whrte water, pH 6-g flog shucmg) kraft whrte water. sulfate 0.045 g/l. sulfide 0.025 g/l. chlorrde 102 ppm, pH 7.3-g 2 (fog sluicing)
45. a5 45. a5
222
<0.0001
<0.ooo1
98
0.0001
0.0001
PARKERIZING
SOLUTION
Parco compound solutron. phosphorrc-acrd base
Metal
30
0.0bo1 O.OM)l <0.0001 <0.0001 0.0006d
<O.oooI
Parco Lubrrte
Metal
200
30
0.0001
Bonderrte K solutron. sodmm 0.62%. chlorate 0.51%. phosphate 0.251%. ndrate 0.25-l%, chlorrde 0 l-l%, zmc 025-O 75%, phosphorrc acid 0 25.0 5%. copper 0 005~0.01%. pH 2-2.5 BondeWe 0 180 solutron Eonderrte 160 so1uI1on
Metal
150. 160
33
0.004
Metal Metal
F F
30 30
<O.OOOl <O.OOOl
<O.OOill <O.OOOl
PECTlll
thin pectm hquor. lactic acid 0.26%. 0 05%. carbon 0.03%. pH 3.8
malic acid
Food
F 1E
3.8
xx
XI
<0.0001 <0.0001 <O.OOOld
<0.0001
thin pectm liquor, malic acrd 0.2%. sulfur dioxide 0.065%. pH 2.7 2% pectin extract from apple pomace. saturated with sulfur dioxide 2% pectm extract from apple pomace. saturated wrth sulfur dioxide Ivapors)
Food
F F
120
30
xx
<o.ooo1
Food Food
70. 190 120
39
<O.OOOld
<O.OOOl
39
<O.OGOld
<O.OOol
PENTANE
pentane vapors (compressor drschargef
175
56
xx
0.026~
0.027~
0.02ac
PESTICIDES
pestrcide solulron for spraymg vegetable crops. Orthane emulsron New Green. Malathion. 20-20-20 soluble fertilizer, ziw, copper. Aldrin. sulfur fspray tank bottom)
Agriculture
40. 100
346
xx
<0.OGO1
<0.ooo1
(continued)
Ferrous Alloys
545
TABLE 4.13:
VARIOUS
STAINLESS
MOLYBDENUM
hmtd)
Corrosion
mediums
.
varrely of pestrcrdes. Ovatran, ON dry mix, sulfur, copper sulfate, zinc copper 011. zmc copper sulfur mrxture. or1 emulsron hydrated hme, copper sullate. lead arsenate, Para. thron. Mrcrohne, Raped Grow soluble fertitrrer DOT SIO powder, wettable sulfur, Malathion emut.
AgrlCultUre
f s f $.
TYPE
IYPf
1VPL
. .
x xx xx
304
nil
316
<O.OoOl
317
20
ALLOY 825
60. 120
230
Agrrculture
90
277
<O.OOOl
<0.0001
<0.0001
Agrrculture
90
277
xx
<0.0001
heptachlor emulsron. copper sulfate, magnesmm sulfate, Zrram wettable powder, Zrreb wettable powder. Parathron emulsron. Parathron wet. table powder, DOT emulsron. TOE emulsron, Toxaphen emulsron. 1020-10 lrqurd fertrlrzer Drathane 2 qt/lDO gal, New Green 1 ptl100 pal. Malathron lb1100 aal. water-soluble olant rood 20-20.20 5 lb/ 100 &.zinc 0.5 lb/ 106 gal, cobalt, water
Agrmulture
70. 85
258
xx
<o 0001 <0.0001'
<0.0001
Agrrculture
40. 100
151
xx
<O.OOol
<o.OOo1
pesticide solutfons for spraying late wettable powder, Panate trrbasrc copper sulfate, Zerlate 2.4.dichlorophenoxyacetrc hol (top of still, vapors) monochtorobenzene. chloral. hydrochlorrc
tomatoes, Marwettable powder, wettable powder of butyl alco-
Agriculture
60. 100
420
xx
0.0001
0.0001
acrd ester
Chemical
140. 203 65 70 60. 75
13
xx
0.197
0.138
0085
sulfur droxrde. water acrd
Chemical Chemical Agrfcutture
F F F
157 156 3.2
x xx
xx
O.OOlcd 0.0008a 0.0002
0.0006cd 0.00056 <O.ocGl
C0.0005r co.Ooo3
Bordeaux mrxture. wettable sulfur, copper salts, nicotine sulfate. summer.oil emulsions, separately and in combmations (spray tank bottom) Bordeaux mixture, wettable sulfur and Irmesulfur, separately and in combmations (spray tank bottom) pesticide solution for spraying crtrus fruit, sullur. time sulfur, zinc. copper, iron, manganese, borax, molybdate, 011, magnesmm. 0.N , Ovatron. Sistax, Parathion, Malathion, 2-4-D
Agrrculture
76
1.3
xx
xx
ODD06 0.0074 <0.0001
0.0003
Agrrculture
40. 100
266
xx
nil
mrxture of acetone, phenol, ptf 5.8.8Icondenser) alcohol
water,
lrver compounds.
Pharmaceutrcal Pharmaceutrcal
70. 150
42
(0
0001
<0.0001
<o.Ooo1
slop from lrver extractron
91
\o
0001
<o.oOo1
alcohol
slop horn pharmaceutrcal
extractron
Pharmaceutrcal Pharmaceutrcat mmeral and am Pharmaceutical ffractiona tront Pharmaceutical
91
<O.DOOl
<O.OOOl
alcohol
stop from msulm
extractron
91
<O.OOOld
<0.0001
alcohol recovered from msulm extractron, rcrds trace, orgamc acrds trace, sodium monium salts trace Icolumn)
91
O.OOlcd <00001
<O.OWcd <O.oOol
salrcylrc. anhydrrde
acetrc
and
acetylsaticylrc
acrds.
acetic
140
33
0.0008ad
0.0006
(continued)
546
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmtd)
Corrosion mediums
Test conditions
Average corrosion rate: (ipy)
TYPE
304
15% sulfuric acrd and sugar lrom the digestion of tuber Barbasco. neutrahzation wrth lime at end of run lautoclavel 10% Roccal germrcide. pH 10 3 inrtially Pharmaceut1cal F 249
TWE
316
TIPE
317 20
ALLOY
625
O.lcr
0.051 co 051
Pharmaceutical Pharmaceutrcal
L
f
RT.
20
<0.0001
<0.0001
intravenous solutmn. dextrose IO-50%. water, sodrum chlorrde 09%. calcwm chloride, potassum chlorrde. ddute crtric acid, sodrum crtrate, sodrum lactate, extremely drlute vrtamm solutions, pH 4-7
70
62
(0.0001
<o 0001
PHENOL
phenol, 95%.
pure acetophenone 5% (bottom of column)
Cbemrcal Chemrcal ldrstillationl Chemical llractmnaIron) Chemtcat Petrochemical tdistdlation)
L F
590 311
--
IllI x <0.0001
nil <O.OOOl
276
<o COOI
phenol (bottom
of wlumn.
vapors)
302
125
xx
00217
0.0034
used plant phenol,
some sulfur
compounds
L F
590 435
--
IllI 0.1
0001 0.002
80.70%. ,,-methyl styrene. acetophenone and mesttyl oxide 5%. water 1.3%. pH 4-5 (top of head of vertical reborler of cracking still)
3.5
phenol,
hydrochloric
acid 0.26%
Chemical
378
1 12
-x
0.037
0.023 0.0008 so.0015 0.0007 0.0009
phenol, hydrocarbon alkylation. phosphorus trrchloride 1%. boron trifluoride 0.796, hydrochloric acid, possibly hydrofluoric acid liberated
Chemical lalkylatronl
175
pure phenol,
sulfur 0.5%
as butyt disullide
Chemical
590
l-25 xx
0.002
0.001 0.0055 <0.0001

0.0124ar 0.0506
phenol, amyl phenol, (vapors, liquid)
some
sulfuric
acid,
amylene
Chemical
113
0.0288 0.0004a
phenol, amyl phenol, some sulfuric acid, sulfurous acid (digester, vapors. liqwdl
amylene.
Chemical
230
17
0.0191r 0.153 0.0029 0.0117 O.OQ184
10% phenolic vapors, liqurdl
water,
chlorides
1320
ppm
ltower,
Petroleum
220
43
0.0025 0.0168
10% phenolic vapors)
water,
chlorides
lo-1320
ppm ltower.
Petroleum
220
71
xx
0.004r 0.004r o.Om
0.004r
0.004r
phenol, acetone, cumene. ldecomposer drum bottom)
sulfur
dioxide
100
ppm
Chemical
150
217
xx
<0.0001
<o.OOm
<0.0001
phenol, acetone, curnene, (decomoorer drum1
sulfur
dioxide
100
ppm
Chemical
150
16
xx
0.0003
0.00015
0.00014
phenol. curnene, ,t.methyt styrene. water, very mildly acid (bottom of column) phenol, cumene. +melhyl very mildly acid (bottom styrene. water, of column1
neutral
or
Chemical (distillation) Chemical ldistillationl
304
109
<0.0001
<o.cQO1
<O.OOOI
neutral
or
304
52
<0.0001
<O.OOQl
0.00014
(continued)
Ferrous
Alto ys
547
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions E r
a 05
.
phenol, ,B-methyl rtyrene. trace, neutral or very mildly acetophenone. cumene acid lbottom of column1 Chemical ffractionationf Chemical ffractionationl F 304 54
0
TVCE
TV?E TIPE
304 --p-p
316
311
20
ALLOY 626
<o 0001
<0.0001
<OOoOl
phenol, ,,-methyl styrene. trace, neutral or very mildly
acetophenone. cumene acid (bottom of column)
304
40
<0.0001
0.0001
<O.OoOl
phthahc anhydride. phenol, amount sulfurrc acrd Ivapors.
zmc chloride, liquid1
small
Pharmaceutical
214
28
0.11 0.0047
0.027 0.0057
co.017
0.0048
PENl.ACETlC
ACID
phenylacetrc organrcs
acrd.
some
chlorrdes.
possrbly
other
Chemrcal
390
18
0.033
,Ol.,
PHEWL
AMINE
molten mixture of drphenylamme part, rodme 05% approxrmately. thiazme and hydrogen-sulhde gas
3 parts, sulfur 1 to form phena-
Coal Byproduct
212. 221
14
xx
0 064
0 0004
PHEWLARSINE
92% rpprorimatsly __. u%. some tar
dtphenylarsme,
trrphenylarsme
Chemrcal khstnfatronl Chemrcal ldn.tdlation) Chemrcal tdrstdlatronf Chemical tdrstdlation)
240. 260 180. 185 I95 202 195. 520
xx
0 0018
0 0009
81% approximately phenyldrchlorarsme. drphenyl. arsme 17 5%. trrphenylarsme 5%. some tar
I I
3.3
xx
0 0039
0.0067
55% phenyldrchlorarsme, prsenrc trrchlorrde 32%. drphenylarsme 12%, trrphenylarsme 1%. some tar mrxture of arsenrc trichlorrde, drphenylarsme. triphenylarsme, phenyldrchlorarsme. some tar
xx
0.0178
0.0018
XI
0.0012
0.0009
MM., PENl_
CAR.ONATE
SIX.
phenol
I I%,alummum
chlorrde
complex
1%
Chemical
380
0 182 0.196
0 087 0.089
trrphenyl
phosphate.
technrcal
Rubber
75. 85
IO
0.0001
0.0001
0.0001
Research
450. 485 2m 358 358 >6

XI II
0.98
0.18
lfJS.1~103.6% 92% 92%
superphosphorrc acrd acrd
acrd
t 1 1
0 13
corr
0.0005
corr corr
c00001
plant phosphorrc plant phorphorrc
--
xx
(continued)
548
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
Pliosphor,s 90% Dlanl
a.z,d
5 5 . .
xx
TYPE
TYPE
rwt
ALLOY
304 --p-p
0.015
316
317
0 01
20
625
phosphoric acld
Research Research
L L
260 210
>6
xx
90%
co.02 co.05
xx
90%
3142.2%.
Research tmpwtles. lower uwdes of phosphorus Chemical Research
L f F L
280 190. 215

I90215
0.015
xx
0 024 0.021 0.021 0 005
xx
0579 0 58 NG co.05 co2 co.05 co.2
81.02%
0.005
95%
Research
125
85%
Research
175
95% 85% 99% 99%
L 1208 L L
200
xx xx
0.0054
00012 0.002 0.28 0.005 o.Lxl3 0.05 0.023 0.013 0.01 0.018
0.11
208 235
xx
15%
Research Research
235
96%
255
xx
95%
Research
255
0 14 0093 290
II
95%
Research
0.012 0.025 0.1 0.3 0.4 0.24 0 12 0 27 0.3 0.29 0.5
95%
Research
1290
DSX
Research Research Research Research Research
1 1 1320 L
300 300
XI
95%
B5X 85% 95%
325 245.
.
c>o.2 c>o.2
1
L
410
B.P. -85.5 69.2 xx
85%
Research
1.17
33.6
95% plant phosphoric acid
Research
1208
0.001
0.002 0.004 0.005
Research
MB
(continued)
Ferrous
A l/o ys
549
TABLE
4.13: mediums
VARIOUS
STAINLESS
MOLYBDENUM
hcmtd)
Corrosion
Test conditions S r
8 z f
.
85% plant phosphonc acid Research 1 235
s :: .
xx
5 :: .
TYPE
Twf
rrrr.
ALLOY
---
304
316
0 004 0.008 0.018 0.015 0.03 0.051 0.11 0.07 0.12 0.24 0.47 0.063 0.12 0.3
317
--
20
825
85% plant phosphoric acid 85% plant phosphoric acid
Re:earch Research
1 L
235 255
xx
... ... ...
... ... ... ... ...
Research
255
85% plant phosphor&cacid 85% plant phosphoric acid
Research Research
280
xx
280
Research
300
xx
85% plant phosphoric acid 85%. chlorides. sullates. mtnter. lron and arsenu tracer of lead.
Research Petroleum
L F
300 430 167
0.0181
0.007
66%. chlor&s. sulfates. mtrates. traces of lead. iron and arsenic
Petroleum
430
121
0.0187 0.0007 0.0029d 0.0015 O.WO8 0.0065 0.0033b 0.0261a
0.0028d 0.0006 0.0014
85%. chlorides. sullates. ndnles. MO and arsemc
traces of lead,
Perdcum
430
117
0.0005 0.0034 0.0013a 0.0074a
85%. chlorldts. sulfates, Mates. iron and arsemc 85-78X 8578%
traces of lead,
Petroleum
430
46
Research Research
L L
R.T. 220. 240 320 235
0.0001 0.23
0.0001
0.005
0.0092
O.Olc
84% 82%. pressure
Research Research
L L
c>o.2 co.02 co.05 co.05 co.2

x
82%. pressute
Research
290
86% 10%
Chemical Research
L L
R.T. 75
C,O.O001 co.05 co 2
o.ow1
<-0ooOl
80% 80%
Chemical Research
L L
175 255
< 0.0001 CO.05 co.2
0 0006
80% plant phosphoric acld 80% plant phosphoric acid 80% plant phorphorlc acld
L 1 L
150 200 200
>6 >6 >6
xx
xx xx
0.0009 o.OOfJ2
<WWl
0.0004
II
0.0032
(continued)
550
Corrosion Resistant Materials Handbook MOLYBDENUM bntd)
TABLE 4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX Test Corrosion mediums Average corrosion rates (ipy)
PhDLPhcmC
.
acK!
.
200
. .
xx -
k s a
0
304 -P-P1VPE
316
0 0033 0 0004
WPE
317
TWE
20
ALLOY 625
80% 80% 80% 80% 80.75%
plant phosphoric plant phosphonc plant phospharlc plant phosphoric
acid acid acid acid
L L
L L L L
200
240 294 167 185 212 75 210 122 60 >6 >6 .,
xx xx
xx xx
<0.004 NC 0.0006 0.66 NG 0 0035 0.112
B&70%,
small amount
of floorme
compounds
Research
80.10%
Research
coJm5 co.02 xx 0.0005c so Oowa x xx O.OJJOla 0 0002a 00001 0.0003 0.0001
75%
Chemical
75% 75%
(top of absorber)
Chemical Chemical
F F
153 158
328 23
xx
00001
0 096
0.0001 0.0005 w0.0004 0 0004
c0.0001 0 0001
15%
Chemical Chemical
F L
158 158
39 45
xx xx corr
0.0002 0 0001 IllI
15%
0.0003 wo 0005 0.0016 wo 0023 LO 0024 WLO 0022 0.0032 10.0005 0.0088 wo.0033 10.0106 WLO 0079 0 0026 wo.0023 to 0003 WLO 0004 0.0006 LO.0021 WO.0083 WLO.0056 0.0031 LO.0301 c>o.2
75%
Chemical
159
13
15%
Chemical
171
12
xx
0.0034
c0.0002
15%
Chemical
175
13
75%
Chemical
175
21
xx
75%
Chemical
190
12
xx
00013
c0.0003
75%
Chemical
199
>6
xx
75%
Chemical
210
12
xx
00188
c0.0074
75%.
pressure
Research
310
75%,
pressure
Research
240. 435
c>o.2
75%
commercial
phosphoric
aud
Chemical
172
<O.ool w<o.o01
0015 wo.0015
<O.OOi
<OOOl
<OOOl
75%
commercial
phosphoric
acid
Chemical
194
0.001 WOOOl
<o
001
<O.OOl
(continued)
Ferrous Alloys
551
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
TWL
TWE
,PE
ALLOY
20 625
304
Pholphorl aLd
316
311
15%
commercial
phosphonc
acid
Chemwal
208
<O.OOl
w>o 001
75% 75% 70% commerclsl approximately phosphoric acid Chewcal Chemical Research F 1 L 221 250 255
< 0001
~0001
<o 001
wo001 I
0 0007 0 0009 <0.0001 0.0013 0.0039
30
xx
xx co.05
co.2
0.0074
0.0099
70%
Research
BP.
12
xx
0.022 0 42 SO.42 15 <4.45 <0.0001 <0.0001 co.005 co.02 0.003 co 05 co.2 co.005 co.02 0.78 <098 0.00013 0.00068
70% 70% 65% 65% 66% plant phosphoric acid
Research Research Chemical Chemical Research
L L L L L
BP. 260 R.T. 175 175
xx
>6
x x x
xx
<0.0401 <0.0001
60% 66%
Research Research
L L
200 245
60%
Research
245
60% 60% 60% 50% 50% 66% plant phosphoric plant phosphoric acid acid
Research Research Research Research Research Research
L L L L L L
BP. 200 200 AT 175 240
I xx
xx
0.012
0.022 0 003 0.001
x x
<0.0001 <O.OOOl co.02 co.05
<0.0001 0.00041
<O.OooI
0.00044
50%
66-10%
Research Research
L L
BP. 125. 210 75
xx
0.0071 co.005 co.02 co.005 co.02
0.0071
504%
Research
45%
Agrw_dture (fertilizer) Research Research Research plant phosphoric acid Research
170
46
xx
0.0027ad
O.OLW
o.ooo7
40% 40% 40% 40%
L L L L
200 200 B.P. 200 1
xx 0.0031
0.006 0.001 0.0051 0.0004
xx
(continued)
552
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
Phorphc.rlc
8Cld
(PROCESS1 *
.
1 1 1 L L
r*DUs7
.
200 R.T. 175 217 230. 390 235 280 300 B.P. 190
I .
& i
5
2
f
$ .
---
lWE
TWE
TWE
ALLOY
-20 825
40% plant phosphorrc acid 35% 35% 30% 30%. pressure 30%. pressure 30%. pressure w4. 30x, pressure pressure
Research Research Research Research Research Research Research
. x x
304
316
0.002
317
<O.OWl <0.0001 CSO.008 co.2 c>o.2
<o.W01 0.0008 cso.w3
<o.Wo1 o.W4l2
1 L 1 1 f
co.02 co.05 co.05 co.2 c >0.2 1 12 0.0019 0.0001 0.001 OS001 WOSMOl o.OW2 0.001 xx
xx I
Research Research Metal kleaning) Resaarch Research Research Research Research Chemical
22%. p~~khng solution
: :
o.Wa13
o.ow4
20% 20% 20% 20% plant phosphoric acid 20% plant phosphoric acid 10% 10% 10% 10% 3.3% 3.3% <1%
1 1 L 1 1 1
200 200 B.P. 200 200 R.T. 125. 210 175 B.P. 77 77 80. 100
xx -
... ... ... ... ...

nil
... ... ... ... ... ... ... ...
0.0004
0.0004 o.Wo2 0.002
<0.0001
<O.Wcll co.W5 co.02
... ...
Research
1
1 L 1 1 L
o.WO12 xx <o.W04 o.Wo2 <O.WOl O.Wl 0.0002
<o.WO1 <o.Wo4
o.OW12
I
1 70
... ... ...
... ... ... ...
nil
...
PWOSPHcJRICACrD
YlX1UlE.s
95.85%. small amounts of fluorine compounds 95.85%. small amounts of fluormc compounds
Research Research
L 1
212. 239 165. 185 190 89 x -
0.045
0.036
0.0028
0.0032
_.
O.W24 O.Wll 0.0032 90.027
81%. water 16%. nitrrc acid 3%
. Metal
0.0041 S>O.O63
0.003 s>o.o99 LO.W41 0.007
80.70%. small amounts 01 fluorine compounds
Research
203. 230
0.0096
(continued)
Ferrous
Alloys
553
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
kmtd)
Corrosion mediums
Test conditions
YWf
1YPE
TV,e
.
70%, electrwfurnace technical grade Chemical F 75 310
.
x
.
x
304
<O.OOOl so.015 1<0.0001 <0.0001
316
<0.0001
317
20
ALLOY 825
58.2%. nowomc detergent 10%. amine-type inhrbilor 230. water. pH 0 2 6045%. lluos~l~c~c acid 2.4%. gypsum holatmg lilter drum) 41%. Phoscalord. vegetable 8.10% some suspended
Soap
72
90
xx
<O.OOOl
0.0002
<O.OLKll
Chemical
176
xx
0.0001
0.0004
0.0002
protem material
Waler Treatment Waler Treatment Water Treatment Metal Icleanmg)
130
xx
0.837
0.0018
43X, Phoscalold. vegetable material 8.10%
130
xx
xx
0.00 I 7
0.0004
43%. Phoscalmd. vegetable material 8.lOb
130
2.8
xx
0.291
0.001
IO%, sulfuric aud 5%. Ac~trol mhlbltor 0 05%. Lntomerse wettmg agent 0.25% Mop 01 Permubl P regeneratmg column) 40%. sulfuric acid 5%. Acitrol inhibitor 0.05%. Lntomerse wetlmg agent 0 25% 33.5-33X. Ruosrltc~c acid 3-3 5% (thIckenerI
120
82
.,o 0001
<O.OOOl
<:o0001
<0.0001
Metal lcleanmgl Chemical Chemical
200
62
xx
00001
0.0001
0.0002
0.0004
F F
170 127
33 8.4
xx
0 006gcd <O.OoOl O.Mml SO.0388 <O.oOOl
0.0016 <O.Llool LO.mol 1X1.0325 <O.oiMl
0.0009
31.41%. calcium sollate hydrate and silica Jo%. sullurr acid 1.84%. fluosilicic acid 1.48%. hydrafluoric acrd 0.12% Ifilterl 30.75%. water 25%. iodine 3.85%, non-ionic detergent remainder 22%. and Luck wash and regeneration with sulfuric acid 30% (Permutit unit) 22%. pickling solution
SW : : :
Metal ~cleaningl
F
f
72
90
xx
<O.OtMl
<0.0001
190. 210 195
83
xx
._
<O.owl
<O.OOOl m).lnXll <O.OoOl
<O.oool
0.0001
.. .
lpickliogl
Mdal
:F
81
<0.0001
0.00013
0.0002
18%. Deoxidrin
No. 171
SOlutiOn
I Metal I (treatingI
F
f
73
80
--
<0.0001
<O.oaol
18%. waler 86.8%. mdine 1.75%
nowionic detergent 15.75%. i Soap
90
--
<O.wOl
<O.ooLIl
<o.wo1
<O.OcQl
18.10X, 4hydroxy 3.methyl 2Manone 15%. poly mer 5%. methyl.isopropyl ketone 3%. formaldehyde 1%. water remainder 15.2%. water 85%. organics remainder 14.5%. nrlrlc acid 0.381%. pH 0.62
i I
Chemical
230
81
O.OOLl4
0.0001
o.ooo12
0.0225
Chemrcal Agriculture Uertilizerl Rayon Rayon Rayon Rayon F
200 158 32
x xx 0.0001
0.001 0.0001
0.0005 0.0001
o.OOa9 o.olw c0.0001
0.0012 0.mO1
10%. waler. mesityl oxide 10%. water. mesltyl oxide, diacetone alcohol 10%. water, mesrtyl oxide, dracelone alcohol 10%. water. mes~lyl oxrde. dracetone alcohol
F F F F
218 221 218 216
149 149 181 149
xx -
0.0001
0.0001 0.012d
0.00022 0.003
o.lm43 o.ooo7
(continued)
554
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(cmtd)
Corrosion mediums
Test conditions
0 .
4.2%. sollds 15%. gypsum slurry, sulfuric acid 1%. soluble fluorme compounds 0 2%. pH 1.9 (pump box) 3.86%. fluosdw water, ptl acid 0 15%. fluorine 0.38%, Chemical
0 f
TVPE
TVPE
,VPE
304
316
317
20
ALLOY 825
90
90
65 0.003cd
<0.0001
c<0.0001
Chemical
I2
123. 168
0.002cd
2.9%.
water
contammg
a sludge
Chemical
133
13
0.0004
0.0002 w0.0001
1%.
sugar 5%.
pressure
160 PSI
Research
L F
363 165 60
0 0009 ,0.0001
0.0003 <0.0001
1% approximately. oxrdrzmg agent
Cranodme.
small
amount
of
Metal [treating)
~1%.
small amount
of phosphorous
acrd
Research
150
0.002 0 003
00031
<I%. mately
acrd from
weak
acrd
sump.
pH
1 approxr-
Research
80. 100
>6
14
0 00015
nil
II 5%.
phosphorlc.acrd.type
catalyst,
organics
Chemrcal
RT600
0017
0.02 0.018
0 032
0.046
vapors contammg phosphorus pentwde 0 07% approxrmatety. oxygen 7.15%. fluorine 264 ppm ap proxlmatety
Research
129. 237
0.19
0.0037
0.006
2.1%
approximately
Research
78
70
<0.0001
PHOSPHORUS
phosphorus
Research
149. 158 co
0.0001
0.0001
phosphorus phosphorus. water, hydrogen, phosphine. hydra carbon, traces of carbon dioxide and carbon mok oxtde. pH 3.6 (vapors. hquid)
Chemrcal Chemical fdistillationi
F F
140 176
185 112
0001
<0.0001 o.w29 0.0025 CO.cQ28
.
0.0024
0.0031
buffered phossy water or tap water, small partrcles of phosphorus. adjusted with soda ash to pH 9
Chemical
140
185
<O.ooal
<O.oool
gas stream of phosphorus condenser. carbon monoxide 90%, nitrogen 8%. carbon dioxide 2%. small amounts phosphoric acid. phasphine. hydrogen sulfide and fluosilicrc acid
Chemical
150. 175
56
0.021
0.0023
phosphorus oxychloride and triethyl form tetraethyl pyrophosphate and gas
phosphate to ethyl-chloride
Chemical
300
0.0085 0.0085
0.0081
PHOSPHOTUNCSTIC
ACID
phosphotungstrc
acrd and hydrochloric
acid, pH 1.5
Pharmb ceutical
54
4.6
O.OOOSad
0.0003d
(continued)
Ferrous
Alloys
555
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
TYPE
NPE
TIPS
ALLOY
20 825
-phosphotungstrc acrd and phosphomolybdic used rn precrprtatron of basic dyes acid Prgment F 55 205 60 x
304
316
---
317
0 OOOlad
<0.0001
phosphotungstrc acrd. slurrred wrth water, and adlusted wrth hot barrum hydroxrde to pH 8-12
Pharma. ceutrcal
77
0.0002
<o 0001
PHOTOGRAPHK photographrc fdm chlorrdes acetone, fdm sensrtwng acrds. solvents, 10%. pH I
sOLTtONS dope, alcohol ethylene and propylene Photographtc inorganic together Chemical f 85 16 0.162a 0.0021d 0.034cd F 37 0.0001 0
0001
solutron, organic and salts and dye components
7% phthahc-acrd
vapor,
water
vapor
Chemrcal
356
40
xx
xx
0.2843 SO.1523
nil s0.0004
0 0007 c0.0001
phthalrc acid. water 98%
xylene.
phthalrde.
tolurc
acid <O.Z%.
Rayon
200
44
0.0005
0.0009
99%,
benzorc
and malerc
acrds
impurities
Ivaporsl
Chemical
536
25
xx
0.0001
<o
0001
0.0001
0.0002
0.0001
0.0002
9695%.
benzorc
and malerc
acids
Impurities
Chemrcal
536
25
xx
0.0002
0.0002
0.0002
0 0002
crude phthalrc acrd and water
anhydrrde. small amounts ftop of column, vapors)
of malerc
Chemrcal tdrstillatronj
410
45
xx
0.0393
0.0007
0 0001
phthalrc
anyhdrrde
Ivapors)
Chemical
435. 555
85
0 0092a
0.0006
<o
0001
crude
phthalic
anhydrrde
(vapors)
Coal Byproduct
320 545
59
xx
0.0002
0.0002
0 0001
0 0001
phthalrc anhydrrde, ethyl phthalate
methyl
Cellosolve.
drmethoxy
Chemrcal
284
221
0.0085
0.0054
0.0032
0.0028
00014
lrqurd phthalrc anyhdrrde, amounts of materc acrd. acid. naphtha qumones
phthalrc acrd. water, small malerc anhydrrde, benroic
Chemrcal fdistrllationl
329 518
70
>0.25
0 25
0 002d
0.008a
75%. potassrum 1 5%. bromme,
bromate 25%. uon trace
potassrum
hydroxrde
Chemrcal
65
3.4
xx
0.0078b
0.0057a
saturated ammonra.
potassrum.bromrde pH 8-9 5 ffrlterl
solutron,
dissolved
Chemical
185
20
<0.0001
<O.OOOl
<0.0001
<0.0001
17%. potassium brcarbonate 13%. chromate ion 2000 ppm. pressure 270 psrg (top of carbon-dioxrde absorber)
Petroleum
240
74
xx
<O.OOol
<0.0001
(continued)
556
TABLE

MOLYBDENUM
km4
Corrosion mediums
Test conditions
IHDUSTRV (PROCESS) -
b .
-,.
s .
74
f
2
$
t
WPE TYPE WPE
z .
xx
----
304
316
311
20
ALLOY 825
Polasswm
carbonate Petroleum f 240
16%. potaswm blcarbanate 14%. chromate ion 2000 ppm, pressure 8 pug (bottom 01 carbon-dioxide strIpper)
<0.0001
<O.ODDl
ppm (storage
potassium bicarbonate vessel leedmg to absorber1
10%.
14%. chromate 10 potassum hydroxide
Chemical
230
120
xx
<O.OOOl
<o 0001
5%. potaswm bkwbonate 21%. stripped carbondloxlde gas. water remamder tventmg ott stripper)
Chemical
221
120
xx
<0.0001
<O.ODDl
4%. potasswm bicarbonate 28%. chromate ion 2000 ppm, pressure 6 ps!g (top of carbon-dioxide stripper)
Petroleum
240
74
xx
0.0001
0.0001
~30%. 400-600 chloride OH 5 3-8
potaswm-chlorate slurry. sodwm chlorate gl. potawum chlor@e 20.500 g/l. sodurn 30-250 g/l. sodwm bichromate Z-14 g/l. 7
Chemical
122
132
O.OOOla
0 0001
0.0001
POTASS,M
CHLORIDE
31.5%, sodwm sulfate 0.5%. sodum chloride 0 05%. lead, copper, starch trace, pH 9-10 IDorr clardlocculator. overllow weir)
Chemical
180
65
0.0002c
0.0002
20%. saturated solution, potassium hydroxide 2-l g/l. potassium sulfate 2-3 g/l. potassium carbonate 1 g/l. calcium 3 5 ppm, specific grawty 1.18, pti 135
Chemncal
150
215
<O.OOOlad
<O.OOOla
C<O.OOOl
25%.
copper
trace
Chemical
70
64
xx xx
0.0002b
<O.ODDI
25% approximately, potaswm ion 13.95%. chloride ion 13.49%, sodium ion 0.59X, sulfate ion 0.5%. ferric oxide 0.29%, calcwm ion 0.07%. copper powder trace, amine acetate 210 ppm
Chemical
122
29
xx
0.0003d
<O.OOOld
POTASSWY
CROYlC
SULFATE
45% potasuum-chrome-alum acid 5% approximately
solution.
free
sulfwc
Chemical
50. 122
46
--
0.057c
<O.ODOl
C<O.DOOl
9%. ptt
5 8.6
Metal
190. 212
<0
OOOld
<O.DOOl
<O.ODDl
c<o.Ow
POTASSWY
OROXIDE
92.90%
80% approximately
Chemical
716
xx
0.35
0.25
co.092
0.02
Chemical
B.P.
0.1
0.008
50%
approximately
Chemical
BP.
XX
0.13
0.12
015
(contikd)
Ferrous Alloys
557
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
g
g
2 .
po,ar,wm 50%. sodum
hydrorlde
B
.
s
TYPE
TlPE TWE
304
316 ---<0.0001
0.0295 0.0292
317
20
ALLOY 625
hydroxide
50%
Chemical
F < 200
F 248
30
-xx
<o 0001
0 0228 0.0222
32.4%, droxlde
sodwm hydroxide 3% approumately
21 6%. ammonwm levaporator)
hy
Chemical
60
25.2%. potassum Isobulyrate 37 8%. potassium sulbde 5 5%. potaswm carbonate Z.l%, potassun mercaptldes I 9% treboder)
Petroleum
282. 290
140
xx
COW COW*
20%. dww
Isopropanol
sotutlon
of hexachlorocyclopenta-
Chemical
176
146
xx
0.0002a
0002
20%. dlene
rsopropanol
solutlon
of hexachlorocyclopenta-
Chemical
176
90
0 0001
00001
20%. ~sopropanol fvaporsl 20%. ~sopropanol
solutmn
of hexachloropentadlene
Chemical
202
18
0 0004a
00003a
0 0007a 0.004lad
solutmn
of hexachloropentadlene lsobutyrate (bottom of
Chemwal
F F
202 360. 380
19 276
x x
xx
0 0009a 0 0023ad 0 0024ad
11.2%. alkyl phenolate 28X. potasswm 19%, sulfide 08%. mercaptans 04% solut~zer regenerator tower)
k troleum
xx
POTASSIUY
PERCHLORATE
<30%. potasstum-perchlorate slurry. sodium perchlorate 600-900 g/l. potasswm chloride O-500 g/t, sodum chtorlde O-250 g/l, sodurn chlorate 6-24 g!I. sodium dtchromate 2-8 g/l, pfi 8 7 5 3
Chemical
122
132
xx
xx
0.0001
0.0001
0 0001
POTASSWkl
PERSULFATE
8 7% illally, 5.1%.
approximately 2 l-2 3 fmally pH 3
saturated
salutlon,
ptl
I 9 I-
Rubber
100
1
5
~~
xx
00015
ml
Synthetic Rubber Rubber Synthetic Rubber Synthetic Rubber Synthetic Rubber Chemical
R.T.
0.00035
0.0001
5%
76 85. 100 90
25 2
xx -
<0.0001 nil nil* WI ml* <0.0001
<0.0001 <0.0001
5%
:L
.f
4.8%,
pH 3
13
--
4%
R.T.
42
<0.0001
4%
80
61
<0.0001
<o 0001
PROPANE
propane. propane.
fatty
acids dionde, sulfurous acid (vapors)
Soap Petroleum
f F
RT. 110
365 262
xx
0.0001 0.0001 0.0001
free sulfur
o.ooo1
(continued)
558
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion mediums
.
PROPlOLACTONE
f 2
z g?
8
TPL WPL TIPS
ALLOY
20 a25
P .
304
316 ----
317
100%
~propmlactone
176
200
xx
L0.0003
0.0001 L0.0001 0.0001 L0.0002
85% fl.propmlactone, acetic anhydrlde 13%, dloxymethylene dlacetate 2 3%. aluminum chloride and zmc chloride together 0 2%. formaldehyde trace
Rayon
95
200
L.0002
100% 99.5%, butyrlc acld 0.3%. mg 219 days; and proplow 99 5% durmg 31 days 99%. sullurlc acid actd 1% 1% acetlc acid 0.2% acid 0.5%. butyrtc duracid
Rayon Chemical -
F F
293 120
200 250
-
xx -
0.038 0.0005
0.012 <0.0001
<0.0001
F F
F
280 282 302
10 12 625
x x x
0.02 0.073a 0.0078c
0.0043 0.011 0.0013
0.005 0.014 0.0004
QQ%, sulfwc
QQ%, sulfuric acid 1%. butyric acid 0.5%, decomposdion products 0.5%. durmg 12 days; and diverstfled operation durmg 613 days 96.2%. acetlc acid 3.4%, water 2500 ppm. copper eon 5-30 ppm O.l%, iron ion 35.
Chemical
291
50
0.0034
0.0016
96.2%. water 0.1%. manganous acetate 10 lb124 hours, iron ton 35-2500 ppm. copper ion 5-30 ppm 95%. acetlc actd p~onnc acld durmg 95%. butyrlc acid 5% during 46 days 2%. 200 days; 100% pro-
Chemical
291
34
0.001 lar
O.OOiX
Rayon
292
246
xx
0.0014
00003
0.0012
co.003
remamder
unknown
Chemleal
284. 329 302
125
xx
0.047
0.0024
94%. sullurlc acid 5%. posItIon products 0.5% 93%, acetlc acid 5%. and acetlc acid 97%. durmg 38 days 89-86.5. acetlc and won loos acid
butyric
acid
0.5%.
decom-
Chemical
12
0.0007
0.00027
0.00019
esters water
2% during 2%. formic
155 days, acid 1%
Chemical
233. 284
193
xx
0.006
0.0007
<0.0001
11.14%, water, traces of copper
Chemlcat
288
47
xx
0.01 0.003 0 0086b
0.006 0.0001 0.0013
IllI O.OM)8
86%. domestlc water lo%, butyrvz acid 3%. higher esters 1% durmg 213 days; proplow acid 75%, butyrlc acid 15%. acetlc acid 5%. higher esters 5% durmg 127 days, and propnow aud 85%. acetlc actd 6%. hlgher esters 6% dung 85 days 63%. butyvc acid 12%, sulfwc acid 5% during 7.4 12%, sulacid BO%, 3.2 days
Chemlcat
212. 340
425
Chemical Chemical
280 252. 286
x
x
0.045 0.16
0.003 0.011
0.0035 0.0047
63%, butyrlc acid 12%. sulfuric acid 5% days, butyrlc acid 63%. proplonic acid furlc acid 5% durmg 7.4 days; proplonic acetlc acid 10%. nitric acid 10% during
60%. butyric acid 10%. sulfuric acid 10% during 7.4 davs. butwc aud 80%. oromomc acid 10%. sulluriE acid iO% durmg 7.4da;s; and proplonic actd 70%. acetlc acid lo%, nltnc acid 10%. onknown 10% dung 3.2 days
Chemical
: F
228. 275
0.16
0.021
0.0045
(continued)
Ferrous
Alloys
559
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Test Corrosion mediums
.?z. ;
TIPE TIP6 TYPE
.
80%. sulfurrc acrd 10%. decomposrtmn products 10% durmg 7 4 days; butyrrc acrd 80%, sulfurrc acrd 10%. decomposrtron products 10% durrng 7.4 days, and propronrc acrd 80%. sulfurrc acrd 10%. nitric acrd 5%, unknown 5% durmg 3 2 days 15%. proprow anhydrrde 13%. acetrc acrd 12%. and propronrc anhydrtde 98%. acetrc anhydrrde and rmpurrtres together 2% 70%. glycol acrd 1.5% esters 16 5%. butyrrc acid 12%. acetrc Chemrcal F 310. 320
304 ----0.12
316
317
20
ALLOY 625
ia
0.012
0.005
Chemrcal
275. 338
36
0.025r
0 005r
0.004
Chemical
314
566
0.017
0.0046a
0 003
66%. rsobutyrrc small amounts 400 mgi
acrd 17%. n.butyrrc acrd of acetrc acrd. norvvolatrle
17%, 300.
Chemical
300
21
xx
0.012
0007
0.005
0.0035
65.60%. unknown
butyrrc acrd remamder
10-1296,
acetrc
acrd
4.7%.
Chemrcal
311
466
xx
0 027~
0 0061b
0 0039
50%. acetrc acrd 50%. propronrc acrd 54%. acetrc acrd 2596, water 20%. unknown 1%. and proprow acrd 97% acetic acrd 3% 50%. butyrrc acrd 45%. heavy esters 5% 155 days, and acetrc acid 96%. non-volatrles proplonrc acrd I%, water 1% durmg 38 days 48%, butyrrc acrd l3%, 2%. other hrgher acrds 9%, ethyl acetate acetrc acrd ~1% 63%. acetrc acrd 8%. remainder benzene 21%, nitric dung 2%.
Chemrcal
212. 284
125
xx
0018a
0.0025
0 0009
Chemrcal
251
193
xx
0 002
0 0007
0 0004
acid
Chemrcal
176. 284 199
250
xx
0.006
0.001
water
6%.
Chemical
25
xx
0.15
0.01
0 003
PROPlONlC
lNYDR,DE
99.9%,
impurrtres
Chemical
324
167
0.0041 0.006r
0.002r
0.001
99.8%
Chemrcal
347
50
0.002
0.0003
0.0002
99.8%
Chemical
347
93
0.003
0.0007
0.006
25% rsopropanol. water 57%, sodrum chloride la%, rsopropyl chlorrde bubbled through solution, sodium hydroxrde adlurted pH 10
Research
140
42
nil
nil
spent rsopropanol. sugar solids of sulfur droxide. hydrochloric phosphate, pH 3.45
3%. small amounts acid, sodrum tetra-
Food
100
37
0.0001
0 0001
50%
rsopropyl
chlorrde.
water
50%
(vapors)
Research
97
4.2
nil
II
Chemical
260. 270
51
xx
0.0004
<0.0001
(continued)
560
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion mediums
TWE
*FL
7PL
.
SO%, drpropylene hydroxrde 0 04% 6560%, hydroxrde 66%. glycol 8%. water l%, sodwm Rayon F 385 461
.
-
.
xx
--
304
316
---
317
20
ALLOY
825
0 0001
0.0001
drpropylene and sodum 15%.
glycol 15%, salts lormate 0.1% orgamcs
as sodrum
Chemrcal
360
123
xx
<0.0001
<0.0001
water
unidentihed
remamder
Chemical
194. 196 300
48
xx
0 0002
<o 0001
0.0001 <0.0001
30.20%. water 60.70%. methanol and methyl hyde 3%. formrc acrd O-I%. pH 3-3 5 15%, mate. drpropylene resms 5% glycol 80%, sohds as sodium
aide-
Chemical
F
F
51
xx
for-
Chemrcal
360
51
xx
<o
0001
<0.0001
propylene glycol. formic acid, formrc esters pylene glycol, traces of acetals and water
of pro-
Chemical
275
3.5
xx
0.023
0.02
90.65%. sodrum methyl aldehyde 20-15%. water traces of lormrc 0.1%. water
hydroxide 3.6%. together 3.5%
methanol
and
Chemical
llc140 360
51
<0.0001
<0.0001
75.80%. propylene glycol acrd and carbon droxrde glycol added
O.lO%,
Chemrcal
51
xx
<0.0001
<0.0001
formtc acid 1%. propylene remamder. sodrum hydroxrde
0.2%.
Rayon
218
462
0.0001
<0.0001
prune
processmg
water,
pH 3.8
Food
210
60
0 0001
0.0001
PlRlDlNE 56%. Water 50%. traces of methylene chlorrde and acetone 6%. sodum water chlorrdc (top 4.5%. hydrochloric (vapors) chloride acid, Plastrc (distdlatmn) 2%, Plastlc ldrstillatron) Plastic (distillation) F 100 52 xx <0.0001 F 200 61 xx <o 0001
<o 0001
<0.0001
<0.0001
<0.0001 <0.0001
methyfene
remamder
of column) methylene chloride Lbot-
pyrrdme. water, tom of reboder)
acetone,
230
56
xx
0.0001
0.0001
<0.0001
<0.0001
pyrrdme liquid1
bases
from
tar
and
carbohc
011 (VaporS.
Coal By product tdistdlationl
176. 212
0.025 0 079 10.024 10.072
0.008
0.05
pyrrdme densate rectrfred fate unwashed acrd 15%
sullate. unrectified hquor. sulfuric acid, pyrrdme sulfate.
pyridine water
sulfate.
con-
Coal By product Coal By product Coal By product
123
197
II
0.037
unrectified
pyridine
sol-
215
197
xx
xx
0.017c
0.014cd
pyrrdme sulfate. Icondensate)
carbohc
oil and Sulfuric
123
197
xx
0.0007cd
0.0003
0.0003
(continued)
Ferrous
Alloys
561
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
TPE
TIPE
TWE
ALLOY
20 825
-PYROLlONEOS ACID
304
316
---
317
pyrollgneous
hquor
vapors.
pressure
125 PSI
Turpentine ldlstillatmnl Chemical fdlstillation) Chemical
53
xx
<O.OOOlad 0.00107
<O.OOOla 0.00029
wood-dMillatton products, acetic lormlc acid etc. pressure 100 psi 12% approximately acid 2%. pressure pyrol~gneous 30 psi acid
acid,
methanol,
27
Ilquor.
sulfuric
275
14
0.00071
0.00063
pyrohgneous hquor. sulfwc mately, pressure 100 PSI pyrohgneous hquor, sulfuric mately, pressure 100 psi
10%
approxi-
Chemical
<335
8
18
xx
0.0098
0 00558
acid
10%
approxi-
Chemical
F <335
xx
0.045
0.0304
orgamc vaternary ammomum nol solutlon. possibly product carboxyhc acid. pH 2.3
compound in methaof lsonicotmate and
Chemical
195
42
xx
0.012
0.005
0.0015
QUEBRACHO
EXTRICT
condensate formed when mwng or bisulflting quebracho extract wth so&urn blsulflte 3%; reaction frees sulfur dloxlde and forms sulfurous acid with water vapors
Tannmg
JO206
50
<0.0001
<0.0001
coal dme
tar base of qumolme

impurltles, pH 8-9
type,
carbon
and dmcra-
Chemxat
110
185
0.0001
0.0001
RARE-EARTH
CHLORIOE
rare-earth.chlorlde sand. tare earth 0.04-O 2N
solubon, and thorturn.
residue composed of free hydrochloric acid
Chemical
105. 122
15.6
xx
0.046cd 0.087cd
C0.03cd
rare-earth sulfate soluhon, sulfuric acid, phosphoric acid. acldlty 0 9-l 1N. speclflc grawty 1.14-1.15 rare-earth sulfate crystals, sulfwc acid 25%, phosphorlc acid 17%. conslderable copper m solution rare earths 0 8N. slurry CIIIC. cerlum, and sulfuric conlammg sand and barium acids sulfate 05
Chemical
A.T.
69
xx
<O.OOOld
<O.OOOld
c<0.0001
Chemlcat
50. 70 159
xx
0.0002 0.0004 0.29.d 0.19cd 0.012 0.008 <o 0001
0.0004
0.0004
Chemical
2.5
xx
0.31d
C0.2d
rare earths, cer~c, cewm and sulfuric 0 EN. slurry contammg sand and bawm
actds sulfate
0 5
Chenucal
159
65
xx
0012
CO.008
rare karth phosphoric
sulfate acid
slurry. 16-1796
sulfuric
acid
18.2096,
Chemical
55
23
xx
0.0001
coooo3
rare earth phosphoric
double.sulfate and sulfuric
salts, sodwm sulfate, acids, acldlty 1 4.2N
Chemical
113
75
xx
IllI* 0.0004
0 0002
co.0003
(continued)
562
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hntd)
Corrosion mediums
Test conditions
,PE
TIPE
TWE
304
316
317
20
ALLOY 825
sulfurs acld late 15 259,.
15 5% coagulatmg bath, sodwm other ,norgalc salts l-5%
sol-
RayOIl
112. 130
30
0 056~ 0 037c
0 016cd
sullut~c acid 13%. rayon nwed fate 249, zinc sulfate hydrogen sulfide, water remamder
1536, small
acid.
sodlum solamount of
112
149
0 0122c
0 0106
00111
sulfuric carbon
aud 0 001 IO,. dilute coagulating bath, dlsulflde and hydrogen sulfide O-500 porn
Rapll
30
0.027 0.004 0.041 0 02 0017 r00001
0.0001 0 009 <O.OOOld
sullur~ lwors
acid 0.002 0 005% staple hber sodium sullate 0 006-O 015%
dramage
Rayon
132. 138
60
xx
~0
OOOlad
<O
0001
<O.OOOl
sullunc-acid 5.. a#r 2%
vapors. water 93%. carbon hydrogen sulbde 0 2%
dwlbde
Rayon
200
39
xx
0 0012cd
0 00014
<0.0001
acid
vapors
lrom
hardemng
bath
evaporator
Rayon
120
425
0 0029c
0 0033c
0 004c
rayon swng penetrants,
bath, gelatme. glycerme
vegetable
oil, softeners,
Rayon
155. 160
68
<,0.0001*ad <O.OOOlcd
<O.OOOl
rayon swng penetrants.
bath, gelatme, glycerine
vegetable
011. softeners,
Rayon
160
208
<O.OOOld <O.OOOlad
<0.0001
wscose
rayon
spm bath
(evaporator)
RaytIll
170
78
xx
xx o.oOO2c 0.0001
0.084
0.027
0.03
sulfurs acid fate 10.12% sulfurs aud fate 20.22%.
IO-12%.
rayon
spin
bath,
sodwm
sul-
38
III
xx
xx
0.0011c
10.12%. rayon spin bath, sodium some zmc sulfate. *orne organics
soI.
Rayon
F <I20
30
0.0107cd 0 059cd
0.0061ad
0.0061ad
sulfuric acid 20 5% zinc sulfate approximately
I I%, rayon
0.8%.
spm bath, hydrogen
sodium sulfide
sulfate 20 ppm
Rapll
119
60
0 013lc 0.0001
0 0001 0.02
co 0002c c0.0002
sulfuric
ac!d 8 1%.
rayon
spm
bath
Rayon
78
26
0.00035a
<o
0001
sulfuric acid 8%. rayon spw bath, water 71%, sodwm sulfate 14%. glucose 6X, zmc sulfate l%, traces 01 hydrogen sulbde and carbon dwlflde
Rayon
105
35
xx
OOIlcd
0 009d
sulfuric acid 7-896. rayon spm bath, sodwm 13.15%. some zmc sullate and orgamcs
sulfate
Rayon
F <II2
30
0 0062cd 0 0062cd
0.0035ad
0.0035d
sullur~c acid 7 25%. backchannel sulfate 18.19%. nnc sulfate 0 75%, 1 22 at 30 C
hquor, spec~bc
sodwm gravity
Rayon
104. II3
60
0 0076cd
0.0005
sulfuric acid 1.3% apprwmately. from rayon spmnmg machine
stretch
water
Rayon
167. 194
20
0.05cd
<0.0001
(continued)
Ferrous
Alloys
563
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
TIPE
TWL
TWL
.
sullwc sulfate actd 0 25%, 0 25% spent rayon spin bath, sodium Rayon F
304 -----
316
317
20
ALLOY 625
180
102
xx
xx
. ..d
<O.OOOld
sullur~c sulfate
acld 0 25%.
spent
rayon
spin bath,
sodium
Rayon
200
111
xx
xx
0.0001 0.0001
0.0001
rayon
spin-bath
drlppings
Rayon
119
40
X -
0.0238cd 0 0320bd
0.0168 0.0025 0.0195 0 0026 0.0176 0.0023
0.0054 <0.0001
0.0028 0.0191
rayon
spmbath
drlppmgs
Rayon
105 117
78 40
xx
0.0201
0.00025a 0 0136a
spmbath atmosphere, bath dnppmgs
hydrogen
sulfide.
and
spm-
Rayon
xx
0.03636
lumes from rayon dlsulbde. hydrogen
spm bath, sulfide
sulfuric
acid,
carbon
Rayon
R.T.
30
O.OOla O.OOSc 0.005b
0.001 0 0014
co0001
c0.0003
acid bath fide
fumes.
carbon
dwlbde
and hydrogen
sol-
Rayon
R.T.
30
xx
0.005 0.005
0.0006
rayon
spm
bath
fumes
Rayon
160
111
xx. xx
0.0001c 0.0001 <0.0001
0.0001
aud
lumes
and water
vapor
from
rayon
spin bath
Raven
176. 195 a4
20
x.x xx
<0.0001
exhaust gases above spmnmg hquors, free and other gases from sodium-hypochlorde mg, sulfur, other vapors
chlorme bleach-
Rayon
60
I)
xx
0 035c 0 042~
O.Ollb
0.01
atmosphere, stack
on roof
m wc~n~ty
of rayon
bath
fume
Rayon
57
30
xx
<0.0001
<o 0001
RESIN
Dowex
50
resm
saturated
wth
mtrlc
acid
6M
Atomic Energy Atomic fnergy Atomic Energy free Plastic
85
130
<o
0001
<0.0001
Dowex
50
resw,
saturated
wth
oxalic
actd 5%
85
125
<o
0001
<o 0001
Oowex
50
resm
m dtstdled
water,
slurry
85
125
<o
0001
<o 0001
65% approximately urea formaldehyde formic acid, pti 4 5-5 2 (vapors) urea-lormaldehyde and product. sohds 62% urea-lormaldehyde 31% synthetic dehyde 7 5% 23 5% calcium sodurn resm resm sulfuric zinc-chloride
rests.
212
58
I: xx
-
<O.OOOld 0 OOOld <0.0001 w<0.0001 <0.0001
<0.0001
0 00012
condensation
Synthetic Resm Plastic
75
42
<o 0001
F F
77 158. 180 185
31 179
<0.0001
0 00016d wo 00011
acetlc aud 41 5%. formalacid 296, water remamder
Synthetic Resin Plastic
0.0001ld
wnyl-resin sollds suspended by agltatlon m chloride 0 33, sodum Ih~osullateO 052% hydroxide 0 026% solution
23
0 0003cd
<0
0001
<0.0001
(continued)
564
TABLE
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
TIPE
304
synthetlc.rerm varmsh base. phthahc anhydrldc and glycerme. vegetable 011s and sodium hydronde 10% cleanmg solutlon Palot and Varmsh
TIM
316
TIPE
317 20
ALLOY
825
loo. 500
40
0.0002
O.WOl
fumes from synthetwesm varntsh manufacture. phthahc anhydnde. glycerine. vegetable 011s and sodurn hydrorlde 10% cleanmg solutton
Pamt and Varntsh
1 oo500
40
<0.0001
<0.0001
formaldehyde
resm.
water
98%.
methyl
alcohol
2%
Chemical
220
130
0.0013
0.0005
0.0006
ohenola-resm 001%. nltrate ppm. no sulllte.
slurry, Mate 0 19%. chlottne and nltnte 12 5 ppm. mtrates 3 pH 3 5.7
Plastic
40. 160
45
<o
0001
<O.OoOl
c<0.0001
<o
0001
vapors from a phenol-formaldehyde resm reaction kettle. contammg phenol 6000 lb, formaldehyde 3000 lb, and sullur~c acid 95% 120 lb phenol-formaldehyde 6000 lb, formaldehyde acid 95% 120 lb phenol-formaldehyde 6000 lb, formaldehyde 95% 120 lb Ivapors) resm obtamed from phenol 37% 3000 lb, and sulfuric
Synthetic Resin
212
63
0.0006bd
<O.OOOl
Synthetic Resin
212
51
0.055lad 0.0845a
0.0535ad
renm obtained from phenol 37% 3000 lb, sulfwc acid
Synthetic Resin
212
51
0.0063a
0.0039ad
rosm. orgamc aclds. phenols. aldehydes, non.aqueous resm media (autoclave) 60% pdch row 20% acids. (bottom olewlmolelc of tower\ acids 20%.
various
Chemical
525
610
<o.c301
0.0003
1<0.0001 L 0.0002 O.OOOla
<0.0001 0002
c<0.0001 co.0002 c ml
tall-oil
Research ifractlonation)
509
54
0.185
ml
tall 011. prmclpally outlet)
tall-oil
rosm
labove
reboder (fractlonation)
527
69
0.0002
0.0001
0 0002
0.0002
robber reclalmmg. alkalme, neutral condltlons (digester, vapors. Ilqwdl
and slightly
acid
Rubber
387
IO
0.0003 0.0002 ml 0.0003 0 OOOld
0.0004 0.0002 rlll 0.0001 nil d
rubber rec!almmg. alkalme, neutral and slightly condltlons IdIgester, vapors, hquld) latex COagU~atlOn, calcium chloride 1%. days, and acetlc acid. pH 3 durmg
acid
Robber
387
13
I%?18
pH 9 dur. synthetic
89 days 34 days; Rubber Synthetic Rubber Synthetic Rubber .F
200
107
latex, calwm chloride 2%. pH 9 durmg and acetlc acid 1%. pH 3 durmg 19 days mother liquor from Oluer biters. sodwm 3% approximately, sullurlc acid 0.1% mately. small amounts of hydroquinom bonates
200
53
<O.OOOld
nil d
chloride approxiand car-
90
12
nd nit*
<0.0001
treated water used in Bona s synthetic-rubber production, small amounts of styrene, pH 7.10 treated water for making up synthetic-rubber emulwoo. hardness 0. turbidity 3, pti 6-8 (tank bottom)
Synthetic Robber Synthetic Rubber
75
35
<0.0001
<0.0001
135
26
<O.wol
<O.ooal
Ferrous
A l/o ys
565
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosron mediums
Test conditions
$
:: .
Rubber
g
TIPE TIPE TWE
t :: .
364 ----<0.0001
316
317
20
ALLOY 625
synthetrc-rubber crumb, water 30%, salt 0.5%, traces of coagulatron hquor chemrcals. combined sodrum sulhde. blended trrphenyl phosphite ldrrerf actrvator solutron used m cold rubber production, glucose 18.4%. sodwm pyrophosphate 4.4%, fer rous sulfate 0 7% synthetic rubber latex
Synthetic Rubber
180
15
xx
x*
<0.0001
<00001
Rubber
80. 212
xl
I:
<0.0001
<0.0001
nil
Synthetic Rubber
F <140
xx
<0.0001 <0.0001
<0.0001
mrxed acrd serum horn synthetic-rubber coagula Iron, sodrum chlorrde 20% average. sulfuric acid 0.08% average, acetlc acid 0.08% average. pH 3 concentrated coagulatmg serum, 10%. pH 4-6 (serum evaporator) sodrum chloride
Synthetic Rubber
90
42
xx
0 0002ad
<O.OOOlad
Synthetrc Rubber Synthetrc Rubber
185
13
xx
xx
0.0035cd
0.0017ad
coagulatmg serum, strong sodrumchlorrde concentratron. drlute sullur~c acrd. rubber lures and soao. traces 01 auxrlrary solutron; rubber contarns carbon black 30% some carbon black suspended in soluIron, pH 3 5 average ddute acid solutron lor coagulatmg serum make-up. sodwm chlorrde 4%. sulfuric acid 0.35%
115
34
xx
xx
0.0025cd
0.00064bd
Synthetic Rubber
100
41
II
xx
0.0168cd 0.01115cd
0.0004d
recycle coagulatmg serum, sodium lute sulfurrc acrd, water, pH 4
chloride
4%.
di-
Synthetrc Rubber
100
64
0.00012ad <O.OOOl <O.OOOlad nil a nil
drlute mother lrquor used to coagulate synthetrc rubber, sodium chloride 4% approxnnately, sodium sulfate 0.3% approxunately, pH 3.5 (tank bottom)
Synthetrc Rubber
120
21
I(
ddute creamrng and coagulating solution for GR S synthetrc rubber latex, sodmm chloride 3 9%. sodrum sulfate 0.27%. pH 3 55 Ialternately im. mersed)
Synthetic Rubber
120
nil
nil
sodium chlorrde iOorr dewatermg
3 3%. sulfuric skrmmer)
acid 0.01%
solution
Synthetic Rubber
90
30
0.0007d
<0.0001
sodmm chlorrde 3.06%. sodium sulfate bon. ddute sulfurtic acrd. pH 4 3
0.33%
solu
Rubber
86
12
0 0002c nil
<0.0001 nil <0.0001
sodwm chlorrde 3 06%. sodium sulfate bon. drlute sulfurrc acrd. pH 4.3
0.33%
solw
Rubber
120
0.0011c
sodwm chlorrde 3.06%. sodrum sulfate bon, ddute sulfuric acid, pH 4.3
0.33%
solw
Rubber
120
12
<0.0001
<0.0001
sodrum chlorrde 2.68%. sodium sulfate bon. dilute sulfuric acid, pH 1.5
03%
solu-
Rubber
86
0.0001
0.0072
sodrum chlurrde 2 68%. sodmm sulfate bon, drlute sulfuric acrd. pH 1.5
0 3%
solu,
Rubber
86
12
0.0324~
IllI
sodmm chlorrde 2.68%. sodtum sulfate bon. drlute suffurrc acid, pH 1.5
0 3%
sohr
Rubber
120
12
0.0427~ 0.096
0 008 0.0005
(contmued)
566
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions
TIM
TWE
TIPC
ALLOY
20 825
304
316
317
selentous scrubber) fumes
aud,
sulfwc
and
nltrlc
acids
(gas
Precious Metal Precious Metal Prectous Metal
200
0 28
0.135c
0.058c
0 083c
0.17c
of selemous
acid.
sulfuric
and nitric
acids
130
004llc
0.061 lc
0 0564~
0 12llc
0 0506~
0.1189c f 650 0.029c 0.027~ 0 022c 0 024~ 0 029c
fumes of selemous (box scrubber)
acid.
sulfurtc
and
rutnc
acids
selenwm charge, chlorides 0 166, per 0 094%
sulfates 0.78%. sulfur 0.34%. won 0.13%, telluwm 0 11% cop-
Metal
1280
48 8 48
7.02
3 19
moisture-laden sewage gas from anaerobIc dlgesbon of packlng house waste, carbon dioxide 63%. methane 36%. hydrogen sulfide l%, pH 7.4 ap proxtmately (Nash vacuum pump) settled sewage, hydrogen sulfide 14.20 ppm. pH 6-7
Food (meal1
90
90
<o 0001
0 0003
<o 0001
0.0002
<o 0001
00001
<0.0001 0 0001
sewage Itreatment) Sewage fdlsposal) Sewage fdlsposal)
75 80 70
34
xx
xx
<o 0001
CO OOOld
<0.0001
flftrate from dewatered contams ferric chloride. flltrate from dewatered contains lerr~c chloride,
elutrlated sewage sludge, pH 6 (vacuum flltratlon) elutrlated sewage sludge, pH 5 5 6 (vacuum fdtratlon)
110
xx
<0.0001
70
139
xx
xx
0 0002cd
<0
OOOld
s~I~ceous ore pulp. soltds ferric sulfate added, ferrtc
50%. sulfuric acid and loo 2 g/l, mltlal ptf 0 5
Chemical
RT.
xx
0 001 0001
0 0006
s~hcon
tetramdide,
free
lodme
2%
(hall
Immersed1
Research
293
0.0032
0.0031a
0.0035
0.0029
>40% potash soap, derived lrom edible 011. hand washmg soap, fatty acids ~0 9 59.8
coconut 5%. pH
Soap
:f
72
<O.OOOl
<0.0001
35% soap made up lrom coconut fatty acids 50% and soya fatty acids 50%. glycol 5%. hand-washing soap, fatty acids (0 4%, pH 9.2-9.5 15% soap, made up from soya fatty acids 50%. tall 011 50%. wth sodlum sullate 1% and pine oil 1 5%. floor cleaner, pH 10.6 12.5% soap made up from soya fatty and tall 011 50%. wth free trisodium 1%. floor cleaner. pH 11-11 5 soap solutmn, pH 10.3 acids 50% phosphate
Soap
72
<o 0001
<0.0001
Soap
72
<0.0001
<0.0001
Soap
72
<0.0001
<O.OOol
Synthetic Rubber
135
IllI
llll
(continued)
Ferrous Alloys
TABLE 4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM
567
(amtd)
Corrosion mediums
Test conditions
lPL
TPl
TWl
304 ----soap and wash-hquor 15%. sodturn chlonde soap 2% fats, lye. sodium mixture, 10% sodturn hydroxide Soap
316
317
20
ALLOY a25
200
<o 0001
102 x x
<0.0001
chloride
ll%,
sodlum
hydroxide
Soap
200
<o 0001
<0.0001
<o 0001
fatty
acids,
caustic
soda
(bottom
of kettle1
Soap
90
217
35
<0.0001
soap, salts of alummum. z,nc. pH 4-l
calcwm.
magnewm
and
Soap
100 190 100

125
35
<o 0001
co 0001
<0.0001
preclpltated
soap and salt
Soap
35
<o 0001
tallow, stocks
acldulated cottonseed (tank bottom) cottowseed oil 011 soap stock
and soybean
011 soap
Chemical
138
11
xx
<0.0001
<0.0001
<0.0001
<o 0001
0.0004
aclduiated vegetable
soap
stock
and
mlxed
Chemtcal
147
62
xx
<0.0001
ddute soap solutlon of sodwm salt of sulfonated 011 of mdefmlte composition, sodurn oleates. paraffm 011s
Rayon
86
56
<0.0001
<0.0001
lo%, hyde 5%,
organws. 1%. water waler
bulyl alcohols 5.10%. remamder, pH 4.5 pH 4-10
formalde-
Chemical
230
38
xx
<0.0001
<o
0001
remainder.
Chemical
80 130 300
157
xx
0.0001
0 0001
5.2%. 0.1%.
water 93%. pH85-95
sodwm
formate
0.5.1%,
butane
Chemical
61
xx
xx
<0.0001
96% crystallme sodurn bicarbonate and ammonun chloride, remainder sodwm chloride, ammomum bicarbonate, hydrogen sulfide. water fliqwd); and air, sodurn-carbonate dust, ammoma. hydrogen sulfide. water Ivapors)
82
36
xx
<0.0001
<0.0001 w0.0001
20%, soda-ash draw liquor. ammonwm chloride 15%. sodwm chlor,de 5%, dissolved carbon dloxlde 2%. free ammoma 1.2%. solld ammonwm blearbonate I%. sodum sulfide trace (carbonating tower1
Chemical
85
280
xx
xx
0.0001
0.0001
0 0001
condensate
from
sodlum-bicarbonate
mother
liquor
Chemical
135
14. 28 3102 xx
L nil
0.00037
sodium-bicarbonate chlortde. sodwm tder lcarbonatmg
slurry chloride, tower)
m solution of ammonium and free ammonia 35
Chemical
84
0 0001
0.0001
slurry saturated wth carbonate. ammonium bonate. free ammoma carbonatmg tower)
sodum chloride, sodium bichloride, ammonium bicarand free carbon dioxide fbi-
Chemical
81
90
xx
xx
0.0003ad
0.0004d
(continued)
568
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmd)
Corrosion mediums
Test conditions
wet gas containmg carbon dioxide and ammonia, water 0.32 g/I ammonia 0.23 g/l;carbon dioxide 0.135 g/l III vapors; ammonium carbonate IM, ammonwm hydrorlde 1.3M III condensate. some hydrogen sulhde III vapors (heat exchanger)
Chemical soda)
185
70
x.
O.OOOlb
0.0001
feeder Ilquor. sodwn chloride 230 g/l. flxed ammoma 65 g/l, free ammonia 15 g/l, sulfide 0.04 g/l. won 0 006 gi I (coke-packed section of strippar still)
Chemical
185
105
xx
0.0016~ 0.0003c s0.0014c LSO.OO28c sooolc O.OOZlad 0.0015ad
0.0001c so.ooo2c
0.0001c SO.OOOla
blcarbonale lower slurry saturated wdh sodwm brcarbonate. ammomum bicarbonate. sodium chloride, ammomum chloride, free ammoma, free carbon dloxlde, some crystals of sodium bicarbonate
Chemical
75. 160
77
xx
0.0015a
SOOIM
CNtBONATE
25.4%. sodwm
so&urn sulfate
chloride 2 5%
8%,
sodium
borate
8%,
Chemical
150
60
xx
xx
0.016~
SOOWM CHLORATE
55%. sodium chlorfde 7%. rohd 5%. pH 9-10 [vacuum evaporator) salt m suspension Chemical F 230
174 62
xx
00001
00001
O.OOOlbd
c0.0001
saturated solution of sodium chlorate and sodium chloride from which the chlorate is crystallized, no hypochlordes, pH 6-7 saturated solution of sodium chloride, sodrum hypochlorite porr. pH 6-7 sochum water chlorate, sulfuric chlorate 2-5 g/l. and sodium chlorine va-
Chemical
100
O.OOOlbd
Chemical tevaporatiord
165
13
xx
0.0005ad
acid,
chlorine
dioxide,
Research
127131
10.0045 10.009 10.0156
10.0063 LO.0086
0.002
sootu
CHLORlOE Chemical F 90. 100 90
purlhed sodwm-chloride slurry from vacuum pans, brine 75% approximately, salt crystals 25% approximately saturated sodrum-chloride brme
xx
<O.OOOlad
<0.0001
Chemical
160
204
<O.OOOld C<O.OOOld
0.0004cd 0.0007cd 0.0012cd 0.0022cd
<O.OOOld
saturated materials saturated fdter)
sodium-chloride brine, some oxidizing lrom products of combustion of gas flame sodlum.chlorlde solution (Ohver vacuum
Chemical
180
52
Chenwal
90
90
xx
O.OOOla
saturated to 15.3% nate Immerslonl vapors from bodmg t10n Ievaporator) 25%. water
sodium-chloride
solution
lalter-
Metal
60. 80 210
160
O.OOOld
<O.OOOl
saturated
sodlumxhlorlde
solu-
Chewal
210
xx
0 OOOlcd <O.OOOlbd
remamder
Research
140
ml a
IllI
(continued)
Ferrous Alloys
569
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
1YPE
TYPE
WPE
---SDdlrn Ehlorlde
304
316
317
20
ALLOY 825
25%. 20%. 10%
waler
remamder
Ivapors. spray
Ilqwd)
Chemical Research Textile
L L L F
140 95 150 17
45 a4 4 90
nil a 0 00036~ 0.0007 0.00015cd LO.OOOlcd 0.00013cd LO.OOOllcd 0.0146b
ml a <O.OOOla <0.0001 <O.OOOlcd
sodbum-chloride
sodwm-chloride
solutmn.
pH 8 5
AN Conditioning Refugeration
sodwm-chloride
spray,
pH 6 5
17
90
<O.OOOld
4%
Research
195
<0.0001
saturated
salt brme. hydrogen
sulLde0.15gll.
pH 6.7 8%. SD remainder
Chemical Chemical
F F
100 400
393 27 0.004
0.0001c 0.0023
50% sodwm chloride. sodium hydroxide dum chlorate I%, ammonia 1%. water lammanla still1
~50% sodium-chloride brme, oxldlzmg materials from combustion products of gas flame (open evaporator)
Chemical
200 L
0 009bd 0215bd
0.041gbd
45.6% sodurn-chtorlde slurry. calcium chloride 17.6%. magneswm chloride 3.2%. solid salt in suspension, pti 6 3 fIlmed); pH 5.3 hmllmed)
Chemlcat
129
0.001 led
26% saturated chloride 10 g/l.
sodurn-chloride calcwm sulfate
solution, calcium 2 g/l, pH 6.5
Cherwcal
50
ia0
lJ.oOfJ~
23.6% approximately sodwm-chloride brme. calcwm sulfate 3 g/l. sodum chlorate 0 5 g/l, traces of sodium hypochlorde and mercury
Chemtcal
149
0.002
0.0007
23.5% approximately sodurn-chloride sulfate 18 g/l. sodium carbonate hydroxide I g/I 22% approrlmately dlum sulfate 60 g/l. l1zer tank1 sodium-chloride sodium hydroxide
brme. 16 g/l.
sodum sodium
Brme Product,on
R.T160
225
ml
solutlon. so7 g/I (crystal.
Chemical
48
<0.0001
21.2% approximately sodwm-chloride solution. free ammonia 39 g/l, llxed ammonia as ammonwn chloride 15 g/l. carbon dloxlde 19 g/l, hydrogen sulfide 0 5 g/I tplpmg) 19% approximately sodumxhlorlde chlorate 30-50 g/l. iron 1-l 5 ppm, ppm. sodwm hypochlorde as chlorme 16%. restdual 0 25% (fdterl 18%. residual 0 25% soap, aluminum brine. sodurn mercury l-l 5 0.2% hydrate
Chemical
145
<0.0001c
0.0001
Chemical
0.003cd
0.0006cd
chloride
S0ap
160
65
soap,
alumwm
chloride
hydrate
soap
165
65
ICI%, restdual soap, total proximately, free sodurn mately
sodwm oxide 0.03% apoxide 00003% approxl.
SOi3P
165
65
0.0002d
(continued)
570
TABLE

MOLYBDENUM
bmd)
Corrosion mediums
Test conditions c jj e
I
$ .
18%. restdual soap. total pro:imately. lree sodium mately 10%. alummum mately. pressure 18%. mately aluminum chloride sodium oxide 0.03% apoxide 0.0003% approxiSoap 140
5
2 .
xx
c
c
s
TYPE TlPE TlPE
0 .
65
4 .
xx
304
0.0004d
316
0.0002
317
20
ALLOY
825
hydrate
0.25%
approxi-
Soap
165
65
XI
xx
<0.0001
<0.0001
110 psi
chloride hydrate 0.25% approxiSoap 160 65 xx xx 0.00064~ 0.00036cd
18%. total sodwm oxide 0 03% approximately. sodwm oxide 0 003% approximately. pressure PSI 18%. total sodium oxide 0 03% approximately. sodium oxide 0 003% approximately. pressure Psi
free
soap
160
46
xx
xx
0.0004ad
0.00014
110
free 110
Soap
140
46
xx
xx
0.00084d
0.00038
15.3% approximately, ammomum perchlorate 240 g/l, sodturn perchlorate 78 g/l. sodwm chlorate 2 g/l, ammonium chlonde trace, pH 4 8 14% approximately slum chloride 12% center well1 sodwm.chlorlde approximately slurry, potasIOorr thickener,
Chemical
155. 170
98
0.0002cd
0.0001a 0OOOla
Chemvzal
77
38
0.0003a
0.0003
14% approximately sodium-chloride bittern, chlOr&de 10 5N. sulfate ion 55 g/l. magnesium ion 41 g/l, sodlum and potaswm ions balance of catloos. pH 2-5 (heat exchanger) 12X, acldlfled with sulfwc acid, petroleum added, pH 2 5 kheepskm degreasmg drum1 12% approximately waste brine, calcmm g/l. hydrogen sulbde 250 ppm (line) solvent
Chemical
170
90
xx
0.0036r
0.006~
0 0038cd
Tannmg
180
0 0001
0.0001
chloride
Mmmg kulfur) Soap
112
17
xx
xx
0.156cd
0.047cd
sodwm chloride and sodwm sulfate 13.16%. glycenne 10.12%. spent soap lye treated wth ferric chloride and sulfuric acid to pH 4 5. mud and water sodwm chloride lye treated wth mud and water and sodturn sulfate 13.16%. acid alkali to pH 9. glycerine lo-12%,
a5
I05
xx
WO OOlcd
WO.OOlcd
Soap
a5
105
WO 006cd wo 004c WO.OOOlbd 0.018a
W0.003cd wo.003 W<O.OOOld 0.016cd 0 005lad 0 0074ad 0 006cd
10.5%. acldlc salt strlppmg solution. chloride 70 g/l, sulfate 50 g/l. nitrate 20-25 g/l, thorwm 4.5 g/l. ferric ton 1 g/l. sulfuric acid 0 IN; pH 0.5 ap_ proximately 7% approximately. 05% pickle hquor, sulfuric actd 0 25.
Mmmg
86
21
--
Tanning
60. 70 60. 70 67
180
0.0022
0 0012
1% approximately, pickle 0 5% (above hquor level1 5%, potasswm chloride
Ilquor,
sulfuric
acid
0 25.
Tanning
180
<0.0001
<o
0001
4 5.
Chemical
35
xx
xx
<o
0001
<o
0001
5-4%,
sodlum
hydroxide
1% (bottom
01 column1
Chemical
220
58
xx
<O.OOOld
<O.OOOld
<O.OOOld
<O.OOOld
4.7%.
hydrofluosdiclc
acid 3.5%
Agriculture (fertilizer) Chemical
a0
35
0.0026cd
0.0007ad
2%. plantwaste elfluent. sohds 4-5%, chlorides, carbonates, sullates. sulfides and organic salts, water remamder, pH 10
60
105
<0.0001
<0.0001
(continued)
Ferrous
Alloys
571
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(mntd)
Corrosion mediums
Test conditions
VIPE
TlPE
,PL
---1.6% approximately, spent brme mme water from Frasch process, calcwm carbonate 500-1000 ppm, hydrogen sulllde 150.200 ppm, polysulfldes 75.100 ppm. thlosulfates as hydrogen sulfide 4-10 ppm. ptl 6-6 8 0.15%. chlorides sodium purllled chlorlc sodium o+field lo%, chloride, brme, bromme potaswm calwm and 04%, pH 6 chloride acldlfled wth hydra. magnewm Mming F 120 67 xx x
304
316
0.0001c
317
20
ALLOY
825
0.0001c
Chemical
149
144
xx
xx
0.016~
0.012c
Chemical Salt
F F
130 228
45 ia
xx -
xx XX
0.0022d
0.0022d 0.263 0.189
sodium-chloride brme. acid to pH 3 54.5 chloride, water blttern sodwm 3%.
ferrous
chloride head)
0 7%
Chemtcal Chemtcal Tannmg F F F 140 150 Soap F 140 220 190 169
147 168 180 1235 x xx xx
0 0002ad 0 0006cr 0.0002 <O.OOOlcd
0 OOOlad 0 0006~ 0.0001 <O.OOOl <0.0001 0 0002c
sodwm-chloride sodium sodium (vertical chloride.
(heatexchanger sulfate sulfate, glycerme.
chloride. sodium tube evaporator1
pH 6-10
Soap
saturated salt erine 15.80% salt and crude pH 79 salt and crude pn 5.5-9 organic sodium
solution of glycerine and water. glyc(Wooster-Sanger evaporator. vaporsl glycerme. soltds 7.25%, water vapor.
91
0 0003cd
<O.OOOlad
<O.OOOld
<OOOOld
Soap
24
llll
nil
gtycerme,
solids
725%.
water
vapor,
Soap
190
26
0.00012
<0.0001
maternal contammg unstated chloride and hydrochlow acid wth sodhum chloride
amounts
of
Chemical
212
14
,.
XI
0.0047cd
0.0043cd
air. saturated
Mmmg
77
84
xx
xx
0.0003ad
<O 0001
<0.0001
<0.0001
SODWM
CHLORITE
5%.
pti 3 5 5
Chemical
68
158 95
0.004c 0.006cd 0.0002cd
0.0001
0.5%. during 34 hours, aeratmn durmg 138 hours, calcium hypochlorlte direct chlorination wth added sulfuric acid to pH 4.5 durmg 572 hours (honzantal Bellmer bleach beater) 0.2.0.1%. mg, oxahc Textone cotton acid l-2 g/l dyemg and bleach-
Pulp and Paper
31
.x
xx
0 OOOlad
Textile
160. 170 210
194
xx
0.0006~
0.0003c
0 OOOlc
O.OOOla
0.1%. CF rayon bleach, 53% acetic acid 0 18%. synthetic detergent 0.1%. 0.035% hydrogen peroxide 100 vol, sodium carbonate 0.03% 0 04%. CF textde bleach, synthetic detergent 0.2%, sodium bicarbonate 0.15%, free chlorine as sodium hypochlorlte 0.15%. soda ash 0.07% 0.02%. Textone, caustic soda 1% lbleachmg klerl
Chemical
05
xx
0 003
0.003
Chemical
130
0.5
xx
0.001
0 002
TextlIe
215
23
0 0001
<o
0001
sodwm
cyamde
solutlon
MIlllog
a0
60
<0.0001
<0.0001
<0.0001
(continued)
572
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
Average corrosion rateS (ipy)
TVPE
TlPE
WPE
ALLOY
20 625
A
SOdlrn cyanide
.
F
F F F F
.
a5
75 70 74 1292
304 ----111 98 111 98 10
316
317
sodium sodium sodurn sadlum sodwm
cyanide cyanide cyamde cyanide. cyanide
solution salut~on water water fused tvapors) fvaporsl
Mmg Mmmg
%00001
0 0001 00001 0 0001 0.0377d 0 0464d
Mmng
0 0001
0 0001 0 0279ad 0 043d
Mmg
Chemical
SDD,M
FLOR,DE
sodum lluorlde, alummum lluwde, sodium fate. sodturn carbonate, sodwm bicarbonate. water. alummum oxide. DH 9
sulaw.
Metal
a7
63
00001
<o 0001
0 00011 0 00017
SOOIlA
t*alw
FLUORlOE
6.1% approrlmately saturated ride solul~on. crystals 30 g/l. 30 gl 6% itop trough 01 crystalluer)
sodturn acid fluahydrogen lluorlde
Chemtcal
175
30
0 OSIC 0 Olc
0 043
CO 032
Chemical
140. 180 50
IO
0 135
0 0562a
3.7% approximately s0lut10n. solne lree
saturated Crvslals
sadwm
acid.fluoude
Chemical
30
0 0023
0.0013
SODlUU
FLOSIL1CATE
sodwm-fluosd~cate
slurry.
hydrochloric
acid
5%
Chemical
130
0.153ad 0 116ad
0 055d
SOOIVM
FORLlALOLHYDE
SULFOXILATE
60.25% lvacuum
sodlum.formaldehyde-sulfoxylale evaporator)
l!quor
Chcmtcal
167
310
. OOOOlad
<0.0001
monosodwn
glutamate,
saturated
sodurn chloride
Food
86
28
solutwn tcrystalluer)
0.00015ad <O.OOOla 0 0014bd
SODIUM
HYDROSULFlDE
46.36%. 12-5X. ties
sodwm sodwm
sulfide sulhde
1% and polysullldes as impuri-
Chemical Chemical
F F
176 230
a4 50
<0.0001 <0.0001 <O.OOOl L<0.0001
<0.0001 <O.OOOl <O.OOOl <o 0001
SOOIUU
HVDROSULFITE
40%.
some sullur
dmxlde,
zmc suspension
in water
Textile
85. 125 110 90
42
<o 0001
0.002a x x O.OOOlcd
<0.0001
17.75% approximately
12.65% approximately
F F
57 58
0.0001 0.0001
0.0001 0.0001
c0.0001 c0.0001
(continued)
Ferrous
Alloys
573
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions 2 r :: 2 a
TPE
TPE
TlPE
304 ----TextlIe L 150 nil
316
317
20
ALLOY 625
llll
SODlUH
HYDROXlDE
75%
Chemical
275
35
0.005a 0 007a
0.007a
74% ltank car) 73%
Chemical Chemical
F F
265 248. 320 230 230
88 34 -
xx
0.1 I3
0 0084 0 105
73%
Chemical Chemical
F F
88 52
--
x x
0 045 0 038 0.0093 0.0039 0.0037 0.0268 0.0031
73%
72% 70%
Chemical Chemical
F f
250 194. 239 150 136 68 131
119 90 -
x -
51.49% 50% 30% 22%
Chemical Chemical Petroleum Chemical
F F F F
30 167 30 133
0.0001 <0.0001 <0.0001
<O.OOOl <0.0001 <0.0001
14% huttpte-ettect
evaporat00
Chemical
190
90
Scm,M-HYDROXIDEYlXTURES 50%. sodium chloride 10.15% 40.35% approximately. (salt settler) salt 6.7% approximately Chemical Chembcal F F 200 240 119 24
x x
0.0002 0.001
0.0002 0.0015
35%. chloride IO 3 ppm lvaporsl
Atomic Energy Chemical Soap
500
21
23% approxlmatety, salt 7.8% 23% caustic soda lye, sodium chlonde IO-15%. tallow, coconut 011. glycerme removed wth sodwm chloride. sodium hydrosulllte 0.050.15% added m alkatme solution 22.18%. mercaptans. cresolates
F F
200 190
48 64
00004
<O.OOOlcd ;OOOOlcd O.OOOlb 00001*a 0.0001 0.0001 <O.OOOl
0.0023 <OOOOla 0 0003
xx
Petroleum
100. 220 305
30
xx
0.0004
20%, potasswm hydroxide 2.7%. (stilt pot in crackmg column) 20% approrimately. Ievaporator) suspended crystalline salt
Plastic tdistdlalion)
60
xx
<0.0001
140
196
xx
00014
0.0036
574
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hmd)
Corrosion mediums
Test conditions E $
NPE
TlPE
TWE
----
304
316
317
20
ALLOY 825
IS%, naphthenrc gravrty 22.28&), 18%. naphthenrc gravrty 22~28Bel,
acrd, cresols, phenols fresultrng mercaptan sulfur 0 04% (tower) acid, cresols. phenols Iresulting mercaptan sulfur 0 04% (tower)
Petroleum
225
660
0.0001
0.0002
Petroleum
225
564
0.0001
0 0001
17.2%, chlarrde
organrc salt 12%. 7% lliqurd Imet
methanol
8%.
sodrum
Chemical
85
37
xx
<o 0001 s0.0001
<0.0001 so 0001
<0.0001
<0.0001
17.2%, chlorrde
organrc 7%
salt
12%.
methanol
8%.
sodrum
Chemrcal
85
37
_ -
xx
<o 0001 so 0001
<0.0001 s0.0002
<0.0001
<0.0001
15%. monochlorotoluene saturated wrth 2% and hydrochlarrc acid 2% approxrmately strll)
chlorine [batch
Chemrcal fdrstrllation)
212
33
0.023cd
0 022cd
0 018cd
15.1.5%. chloride
amme 7%
salt
12%.
methanol
8%.
sodrum
Chemrcal
85
20
xx
0 0001
to 0002
10%
caustrc
cell
Imuor.
salt
12%
Chemrcal
190
279
0 0002
<0.0001
10.3%.
occasronalty
some
sulfurrc
scud
Research
190
300 _
xx
0.03a
0.0083
CO 0006
0.0001
6%,
sodrum
hypochlorrte
~1%
(gas scrubber)
Petrocherlncal
80. 90
138
0 024cd
0 022cd
2%.
sulfurrc
acrd 10%.
sulfur
droxrde
0 1%. pH 4 3 normally acid
Chemrcal Chemical
F F
125 130. 140
104 99 x
x xx
io <o
0001 0001
<o
0001
sodrum solutron
hydroxrde.
sulfur
dioxide,
<0.0001
sodrum solution
hydroxrde,
sulfur
droxide.
normally
alkaline
130. 140
99
xx
<0.0001
<0.0001
sodrum hydraxrde, sodrum fide. mtermrttent exposure gen sulfide (gas absorption
hydrosulfrde. sodium sulto air, steam and hydrocolumnt
167
15
xx
0.00015
0.0004
sodrum hydroxrde, organic and arsenious acid fin resm
material, sulfuric of ro exchanger)
acid
167
30
0.0001
0.0001
0.5%.
water
99 5%.
traces
of butane
and kerosene
Chemrcal
320
275
II
nil
dilute caustic soda, rtrogen compounds
sodrum
formate.
methanol,
Chemical
86. 248
75
xx
<0.0001 0.0003
<o
0001 0 0003
<o 0001
<0.0001
6.3%.
sulluric
acrd 45%,
sulfate
turpentrne
oil
Chemical
100
103
--
xx
x 0.029cd O.OOllcd 0.000la
0.0003d
0.0002d
0 0002d
0.0003d
5% (tank bottom)
Cellophane
65
39
O.OOOSbd
<O.OOOl
2.94%
Textile
70
25
0.0006d
0.52X-O%, free sodrum hydroxide chlorrde 2-25 g/l. sodium rrlicate O-2 ml/l
4-35 g/l. sodium g/l. acid oils
Petroleum
R.T.
37
(continued)
Ferrous Alloys
TABLE
575
(contd)
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
Corrosion mediums
Test conditions
,PP
VIPE
1VPE
304 ----0.11%. sodium alummate 1200 ppm approximately 0.1% 0.042%-O%. sodrum chloride 3.21 g/l, free sodium hydroxide 6-13 g/l. acid ads 02 ml/t during 13 days; and sodium chloride 7-15 g/t. free sodium hydroxide 5.8 g/l during 42 days sodrum hypochlorite traces, sodium chloride <l%. sulfur base dye Beverage Chemical Petroleum
316
317
20
ALLOY 825
f
F F
70 140 R.T.
94 1.3 55 -
x-
<O.OOOld 0.0009d O.OOl&
<O.OOOlcd 0.00015d nil
Cellophane
:F
212
69
xx
<0.OOOlad
<O.OOOlad
. ..
<O.ODOlad
6&12X approximately, crude sodium-nitrate sohrIron fevaporalor)
Chemical
232
30
xx
o.ooa7c
0.0006
o.ow6
0.4-0.3X.
s&urn chloride 0.9%. diazoting bath
Textile
180
0.2
xx
0.0056 10.0058
0.0044
SODIUY
PHENOLATE
sodium phenolate, tar acids 20 WI% approximately. total alkalinity 20% as sodium hydroxide (tower)
Coal Byproduct
248
329
<O.OOOlcd
<o.o001
SODIUM PHOSPHATE
50% sodium trrpolyphosphate and sodium tetrapolyphosphate solution (hydrator) so&urn phosphate, salts 54.55%. hydrochloric-acid trace. ptl 6 9-7 (gas scrubbing, vapors, liquid) 10% dlsodium phosphate and sodium carbonate, sodwm.phosphate solution. pH 9 (bottom of tower) rhsodurm pyrophosphate during 38.6 days, disodium phosphate durmg 7.3 days, monosodium phosphate durmg 5.7 days, potassium phosphate during 4.3 days, potassrum pyrophosphate during 1.8 days, monopotassium phosphate during 1 day (rotary drier) disodium pyrophosphate during 38.6 days, disodium phosphate during 7.3 days, monosodium phosphate durmg 5.7 days, potassium phosphate during 4.3 days, potassium pyrophosphate during 1.8 days, monopotasswm phosphate during 1 day (rotary drier1 sodwm phosphate, sodium chloride, pH 4
Chemical
165
2.5
xx
xx
0.0001
0.0004
Chemical
185
16.5
II
xx
nil
nil
nil
Chemical
150
123
xx
xx
0.0001 0.0001 0.0001
0.0001
Food
:F
60
59
xx
xx
0.0001
0.0001
Food
70
59
xx
O.OOOla
0.0001
0.0001
Research
230
55
0.0012cdr
0.0011c
0.0016cd
SODIUM
PROPIONATE
~0.2% sodium and calcium propronates and acetales, so&urn salts, pH8 approximately
Chemical
F <160
45
xx
xx
<0.0001
(continued)
576
Corrosion Resistant Materials Handbook VARIOUS STAINLESS STEELS Test conditions AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM
TABLE 4.13:
bmtdl
Corrosion mediums
,Pl
TWX
,PL
.
saturated sodrum-sulfate solution, crystals 20% l%, Chemical F F 170 230 48 193 -
.
x
.
xx xx
304
ALLOY
20 825
316 -P-P
317
0.0001 0.0001
0.0001 0.0001 w0.0001 0.0003d
0.0001 0.0001
sodrum.sulfrte saturated slurry. tmc sodrum hydroxrde. pti 8 5-9 fevaporator)
sulfate
25.20%. top waters from organrc yellow sodrum acetate 3%, sodrum chlorrde 16% 14.8%. chlorrde ran 456, ran 1%. pH l-2 5 ferrrc ran 4%.
prgment.
Paper
158. 176 125
7 5
xx
xx
0 0006ad
phosphate
Pharmaceutrcal
20
xx
0.0028cd
O.OOlcd
6.547% approximately, sodrum fluorrde 5.20 g/l, sodrum carbonate 2.10 g/l, traces of sulfur dioxide and hydrofluorrc acrd, water remarnder (Soderberg gas scrubber) 5-0.5X. washmg 1.5% sulfurrc acid of sdrca gel 053%. wash water from
Metal
68. 104
55
xx
xx
0.0004c . ..0.0001
<0.0001
Chemical
150
28
xx
<O.OOOld
<0.0001
sodrum sulfate
hydrate,
sulfuric
acid 0.5% sodrum sulfide.
Textile Pulp and Paper
1 F
150 190
4.1 179
x xx
flll <O.OOOl
nil <0.0001
sodium sulfate. sodrum water, solrds 55%
carbonate,
SOOIUY 11%
,81-) SULFATE Metal fprckling) F 160 71 x-
approximately
<O.OOOla s<0.0001
<0.0001 S nil
SODIUM 60% 60%
WLFlDE Chemrcal F F 340 212. 355 300 26 81 xx xx
0.036 >0.073
0.038 >0.072
CO.081 co.11
_,
Ifusron pot1
Chemical
60-30X
(tube evaporator
tray)
Chemical
30
xx
0 092 0.114 0.084 0.23 0.0026 0.0075 0.0118 0.0001 0.0001 0.0005 0.0001 0.0001 0.0001 0.0001 >0.3
0.207
60.25%
Chemrcal
300
19
xx
40% 30%
mrtrally.
sodrum hydrosulfrde vapors)
45%
finally
Chemrcal Chemrcal
F F
194 255
160 30
x xx
0.0039 0.019
0.0015
0.0005
fevaporator,
15%
(evaporator,
vapors)
Chemrcal
185
30
xx
0.0001
10%
Ievaporator)
Chemrcal
185
21
xx
10%
Chemical
R.T.
81
xx
CO.owI
0.4%
Rayon
108
43
0.0002 <0.0001 0.0001 <O.OOOl <O.OOOl <0.0001
<O.OOOl
sodium-sulhde
solution,
pH 6.5 (bottom
of tanti
Pulpand Paper
100
65.
163
<O.OOOl
(continued)
Ferrous A l/o ys
577
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
hntd)
Corrosion mediums
conditions
IPROCESS L i .
sodrum-sulfide solution. sodium sulfhydrate Tanning
,YOUSl
0 .
I80
s -f i p $ z
ll?E
1WE
316
1WE
ALLOY
20 525
. .
x xx
P--P-
304
317
F
f 140
0.0001 O.WOl
0.0001 0.0001
sodnrm sulfide, sulfonicacrd derivatrves. pH >8 11 any hqurd entrained in vapors and noncondensable gases Ievaporator. vapors)
Pulp and Paper
84
2% sodrum trwlfide. sodium chloride 2%. sodium hydroxrde 0.5%. traces of ethyl amine, thiosulfates andsodmmmercapto-benzothlarole. water remainder
Chemical
105
70
xx
0.0001
<0.0001
6.64%
approrimately.
sodwm
bicarbonate,
pH 7.5
Pulp and Paper
75
28
<0.0001
<O.OoOl
nil
3%. orgamc false bottom
actds, sulfurous acrd. tannins 01 quebracho bisulhting tank)
(under
Tanning
180
xx
0.0001
0.0901
sodrum 0 12%.
sulhte alkalme
calculated Antrchlor
as sodrum solution
hydroxrde
Rayon
108
56
<0.0001 <0.0001 0 2038
<o
0001
0.063%. sulfates as sulfur trroxide 232 ppm, chlorrdes as chlorme 210 ppm. rron 28 ppm, nitrates as mtrogen droxlde 15 ppm. free sulfur 2 ppm
150.
200
55
nil
c rlll
20%. yandlm. treated under vacuum with sulfuric acrd to drove off sulfur droxrde. solution decomposed to sodrum sullate
Pulp and Paper
180
116
0.0002
CO.0008
6%.
organcc acrds. sulfurous
acid, tannins
Tanning
180
xx
0.0001
0.0001
16.4% approximately. drum chlorrde 3%
hydrochloric
acid
5%.
so-
Metal
125
30
xx
corr
0.069cd
0.065cd
0.188cd
SOYBEAN au. steam, Iexpeller) vapors from hot, moist soybean meal Agriculture F 165 33 xx xx <O.OOOld
<O.OOOld
au steam, vapors soybean meal
horn
hot. morst,
raw extracted
Agriculture
156
28
xx
xx
<0.0091
<O.OoOl
au steam. vapors soybean meal
from
morst.
toasted
extracted
Agriculture
175
28
xx
xx
<O.OOOld
<O OOOlad
steam. n-hexane vapors, some orgamc distillates from soybean extracted meal, no chlorrdes (half embedded m carbon, vapors mlet of absorption tower)
Chemical
80. 250
55
0.0002
0.0004
vapors and condensate from soybean and flaxseed flmseed) cookmg (vapors mlet of condenser)
Food
100. 400
145
iO.OOOlcd <O.OOOl <0.0001
<0.0001
fumes from soybean Ipressure cooker)
and flaxseed
(Imseed)
cooking
Food
450. 500
145
<0.0001
(continued)
578
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
Average corrosion rates Lipy)
g
g =
.
fumes frotn the heatmg
llaxseed (expeller 01 crushed soybeans condltloner ventdator) and food F
.
230. 240
.
39
$ .
x
e -
oz
,PL
304
,WL
316
7PE
317 20
ALLOY
a25
,.o 0001
<0.0001
SiARCH
wheat starch, water, sulfur dioxide and Dowicide. pH 2 Z-3.8 (drum drier, vapors during 35 days)
Food
32@ 340
68
0.0002c 0.0002c
<0.0001
STEAM
steam heater)
wrtually
devold
of all
solutes
fdeaerating
Power
220
244
--
<o 0001
<0.0001 s<0.0001 w<o 0001

0.0006 0.0003
steam, occaswnal tracer of ammoma. sodium droxlde. sodium chlorate and sodium chloride
hy
430
129
92.2% approximately, hydrogen sulhde 7.63%, mercaptans 0.17% (overhead hne from sour-waler stripper) geothermal steam cnndensate, carbon drogen sulhde. iamonia. pH 5.25 dioxide, hy
Research
ZOO230
291
IllI
c IllI
IllI
Power
240
55
<0.0001
<0.0001
geothermal steam and water, carbon dioxide, hy drogen sulftde. ammoma, pH 6.5 (steam and water separator) steam from Dallas city water, after zeollte soltenmg. sodturn chloride 292 ppm average. hydroxides 0.42 ppm, carbonates 10-36 ppm, bicarbonates O-6 ppm steam, fumes cooler1 lrom feedstufts and
Power
180
60
<0.0001
<0.0001
Chemical
225
30
xx
xx
0.0004c
<0.0001
molasses (tap of
Agrkxlture
190
112
c.0 0001
<0.0001
steam and water and other reagents mg vat agmg of printed goods
plcked
up dur-
Textde tprmtingl
F <,212
268
xx
O.OOOllad <O.OOOl
33%. small amounts of sodium chromate. pH 3-6 during 44 hours. pH I1 approximately durmg 35 hours. pti l-2 durmg 9 hours
Chemical
160
3.7
0.219ad P.217bd
0.07bd
Steffen Mate, total dry substance 70%, tsucrose IO%, aminoacids IO%, potassium salts remainder), pH 6.5 (evaporator) Steffan Wale, total dry substance 40%, (sucrose lo%, aminoacids 10%. potassium salts remainder). pH 8.5 (evaporator) Steffen filtrate. total 10%. aminoacids 10%. pH 8.5 (evaporator) dry substance 4%. (sucrose potassium salts remainder),
Sugar
178
127
<O.OOOla <0.0001
<D.DDDl
Food
176
127
0.0001
o.lxM2
Sugar
214
111
xx
OOOOla
D.DDOl
carbonated Steffcn filtrate sludge. total solids 23%. (calcium carboMts 87%. sucrose 4%. aminoacids 4%. mostly potassium salts remainder). pH 8.5 (Dorr thickener)
Food
125
59
xx
O.OOOla
O.DDDl
(continued)
Ferrous
A llo ys
579
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Average corrosion rates (ipyl
TWE
TPL
TPE
ALLOY
20 825
304 p-p-carbonated Steffen filtrate, total solids 3%, fsuclose 10%. aminoacids 10%. calcmm carbonate 6%. mostly potasswm salts remainder). pH 8.5 tOorr thickener) Food F 125
316
317
0.0001
0.0001
SUOAR.
CANE
sugv. hydtochlorlc acid, momurn chloride. pH 0.5,
ammomum pressure and
sulfate.
am-
Chemical
260
xx
0.037c
0.0059
0.0015
00013
91.90%
solved 60% 3%
sucrose.
solids sugar 60X, syrup.
sugar
syrups pH 3.5-S
liquors,
dls-
Sugar
160
133
xx
xx
<0.0001c
<0.0001c
caustic
soda 3%,
muriatlc
acid
Sugar
180
XX
0014
0.006
0 0006
concentrated Steffen bltrate. 60%. solids lmostly potassium slon 5% fcalandrla evaporator)
sohds salts)
m solution in suspen-
SUgal
176
105
IllI
nil
Invert sucrose syrup. acidified wth hydrochloric acid to pH 2.5-3. and neutrahzed with lime to pH 5-6 cane-sugar hquors (bone char filtratlon) bone sugar
Sugar
140
116
0 OQo3
0.0001
Sugar Sogal
F F
170 160
56 61 -
x xx
<0.0001 <0.0001
<0.0001 <0.0001
<O.OOOl
<O.OOOl
14.0.5% sugar, sweetwater from washmg char after use as a blter ald for refmed hquor (evaporator charge tank) 11%. 5%. lowpurlty sulfuric (75%) sweet water, fmal
pH 7.6
Sugal Research Sugar
F L F
160 363 ZOO1100 185
228
<0.0001 0.018 0.001
<o
0001 0.0033 0.002
acid 0.5%.
pressure
160 psi pH 6 fgrav-
sugar fdter media, ity fdter vessel)
superheated
steam,
0.2
xx
0.003
Steffen fdtrate. solids in cium carbonate precipitated pewon (Kelly falter)
solution 2.5%, IX, sohds in
CalSW
Sugar
105
<0.0001
<0.0001
waste water from bonexhat biters. inorgamc lmpuritles, pH 6.7-7.3 steam, destructively pH 6-7 ILIter) dtstdled otganics
orgamc
and
Sugar
170
74
x-
<O.OfJOl
<0.0001
<o 0001
<O.OOOl
at
800
F,
Sugar Irefmingl Sugar
ZOO700 160
50
xx
<0.0001
<O.OOOl
<0.0001
vapors lrom lowgrade sugar 27 in. of mercury (condenser) vapors from hot sugar liquor
masseculte.
vacuum
59
xx
xx
<0.0001
<0.0001
lchar
filter
trough)
Sugar
145
56
<0.0001
<O.OOOl
c.0 0001
<0.0001
SUGAR.
CORN,
CONVERSION
dextrose solution formed by washing with recirculated water. pH initially each day (sugar scrubber) dextrose. dilute hydrochloric
dextrose dust 7. fmally 3.7
Food
78. 88
16
xx
xx
<0.0001
<0.0001
acid, pH 1.33 51% solids to
Food Corn Products :F
214 90.
8 108
xx xx
0.016d
0.0002
corn syrup being concentrated from 80% solids (vacuum evaporator)
190
<O.OOOld
<0.OOOld
<O.OOOl c<0.Oc41
(continued)
580
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
hontd)
Corrosion
mediums
lest conditions
Average corrosion
rates (ipy)
COUI
Products Irefining) 95.50% rpprortmately. second sugar liquor, sodium chlorrde 4.2%. pll 4.2 Miial evaporator) 66% appruimrtrly. second sugar char liquor, pH 4.5 hmder surlace of carbon in column) 50% approstmalely, second sugar liquor, sodium chiorrde 2.7%. hydrochlorrc acid to ptt 4.4.4.6 45% approximately. glucose liquor from corn, pH 4.45 tfilter~ 22% approximately. refined dextrose solution, activated carbon suspension. sulfuric acid, pH 4 99.9% starch. hydrochloric acid tO*Be remainder 93.9% starch, lO*Be hydrochloric acid 3.11%. glacnl acetic acid 3.05% aerated cornstarch lermentation liquor, pH >3.2. pressure IS-18 psi starch slurry, hydrochloric acid to 0.02N. specific gravity 1.075. pH 1.8 ldextrose converter, vapors. hqurdl starch slurry, sulfuric acid to O.O4N, chlorides 0.0022%. pH 1.62 starch wash filtrates, sullur dioxide. pH 3.5 Sugar
:f
200
xx
xx :
<0.OOOlad
<O.OOOlad
I35
33
-xxx:
O.OOW
0.0003
0.0005 .F 70 42 xx 0.0002bd <O.OOOl
Sugar
Sugar
135
30
x-
<0.0001
<0.0001
Food
170
100
xx
0.0003cd
<O.OOOl
Corn Products Chemical Chemical
145
52
<0.000I w<0.0001 0.0015a 0.0003a
<O.cml w<0.0001 0.0005a 0.0002
F F
425 140
15 15
I, X
Food
77. 96 275
xx
xx
<0.0001 <0.0001
<0.0001
Corn Products (relining) Corn Products Corn Preducts beliiing~ Food
134. 217
xx
0.0002 0.0004d
<O.MUtld 0.0006d
120
57
xx
xx
0.0001 w<0.0001 O.OOld
w<o.O001
11
125
44
xx
xx
<0.0001
<0.0001
i
ltashed steam, hydrochloric acid, sulfur dioxide, various volatile decomposilton products from acid hydrolysis of corn march, pH of liquor 1.5 (vapor line)
: :
jF
60. 212
79
xx :
<O.OOOlcd
<O.OOOl
<0.0001
<0.0001
SULFONATCO COYfOUNOS 81.3% benzene
sullonic acid, sulfurs acid 3.8%
: Chemical
:
jf
204 329
0 15
-x:
0.66
0.07 0.046
0.12 0.036
99% filly;
benzene sullonic acid, sulfuric acid 4% sulfuric acid 66*Bi. benzene initially
Chemical
0.095
86.1% benzene sulfonic acid. sulluric acid Xl%, some water

9949% benzene sullonic acid, sulluric acid JO50%. benzene m~disullonic acid 0.15%. sullur dioxide m vapors 50% od-soluble sulionic acid, solvent naphtha 45%. water 5%. sulluric acid lrace (bottom of still) 59% oilsoluble sullonic acid, solvent naphtha 45%. water 5%, sulfuric acid trace (vapors1
Chemical
:F
264
11
0.53
0.7
: :
Chemical
98. 275
31
xx
xx
0.0017d
0.0011
Chemical Idistillation) Chemical (distillation)
60. 250 60. 250
3.8
1.451
0.93
0.346
0.316
3.0
0.061
0.06
0.063
0.059
(continued)
Ferrous Alloys
581
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bmtd)
Corrosion mediums
Test conditions
:
. liquor saturated wth organic sutlonic acids, sodmm sullate and sulfur dmxide. hydrochloric acid 2%. some sulfuric acid. acetic acid trace, pH 1.5-2 (vacuum biter. alternately Immersed) Ilquor saturated with orgamc sullonic acids, sodturn sullate and sulfur dioxide, hydrochloric acid 2%. some sutlur~c acad. acetic acid trace, pH 15-2 (vacuum filter) 66% ap~rextmataly dodecylbenzen sulfonic acid, spent sulluric acid 33% approximately, sulfur dioxide and trioxide (bottom of sulfonator) 66% qprnxtwlety dodecylbenzene sullonic acid. spent sulfuric acid 33% approximately, sulfur dioxide and trioxide kullonator, vapors1 33% appuiaalely dodacylbenzene sulfonic acid, hexane 64%. spent sulfuric acid 2.3% tbottom of teotd 33% a##rox*ataly dodecylbenzene sullonic acid, hexane 64%, spent sulluric acid 2.3% (vapors) dodecylknzeoe sullonic acid, from reaction of 20% oleum I.32 parts and dodecylbenzene I part dodecylbenzene sulfonic acid, from reactiowol 20% oleum 1.32 parts and dodecylbenzene 1 part, water 0.139 parts dodecytbenzen sutfonate paste, neutralized with mixture of alkali and alkaline metal hydroxidas sullonated kerosene. settling out of sulfuric acid 05% sutionated kerosene. in Jullurii acid 85% which during aashmg ranges from 85% to neutral naphthatern sullonic acid, solids 50%. pH 1 naphthalene sullonic acid, phenol condensates, pH 1-7 ibottom of tank1 30% phenol sutldnic acid, from reaction of phenol and 98% sulfuric acid I248 F during 12 hours). formaldehyde and water added, borax and ammonia to pH 3 22% p-chlorobenzene sulfonic acid, sulluric acid 74%. DOT 4% chlorosullooic acid, alkyl aryl organic. hydrochloric acid. sullur dioxide 20X, pyriime sulfonic acid, sulfuric acid I-S%. calcium srllate, mercury sullate suspension trace talternataty immersed) 1510% calcium pyridine sutlonate. pyridine I% approximately, calcium hydroxide 0.1%. pH 8 approximately Ialternately immerse@ calcium pyridme sullonate slurry, sulfuric acid I?I%, small amount of mercury sullate probably in mercurnc form (vacuum lilterl Chemical Petroleum Chemical
s
x
$f
Y
.
x
lwE
1WE
7WE
304 p---p
corr
316
317
20
0.002
ALLOY 825
98
0.0002a
Chemccal
78. 98
80
corr
0.0001
0.0001
:F
155
22
xx
0.0714
D.055d
O&W
0.0102
0.M
-F
155
22
xx
0.0436
0.04d
0.03d
0.0036
0.007
IF
80
22
X x :
0.0003
0.0009
0.0011
O.OOOE
0.0018
80
22
x :
<O.OOOl
<0.0001
<O.OWl
<o.OOD1
<D.DDOl
Detergent
125
16 16
xx
D.Old D.WJd O.WlSd
D.DD23d
0.0009
Detergent
;1
125
xx j
O.OD21d
O.Wll
Detergent Detergent
:L
125
16 111
xx
nil O.OD5d
nil
135
xx
0.004
Detergent
60 150 122 104. 284 158
111
xx
xx
0.W2ad
O.WJad
Chemical
F F
3.3 100
xx x
xx
0.0395 >O.D56c
0.0107 >o.O61c 0.039c 0.073c 0.136 CD.0084 0.013
40
0.142
Chemical
65
11
--
0.0003
0.001
0.002
Chemical
140
4.2
XX
0.0087
O.DO8
0.0068
0.0068
Chemical
75
37
xx
<D.ODOl
<D.DODl
Chemical
R.T.
4.7
xx
0.0012
0.0014
Chemical
100. 150
16
xx
<O.OOOl
<0.0001
(continued)
582

4.13: VARIOUS
TABLE
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
TIPS
TIPS
TIPE
ALLOY
-20 1125
--aconrlrc acrd. sodrum hydroxrde. solforrc acid, sodium m-brsulfrte (half Immersed) sulfonated turpentme. from reactron of sulfurrc actd 60% and turpentine in molar ratro 211 sulfonated alkylaled aromatrcs. sulfuric acid 96% at 145.170 F, and 63% at 195.222 f sullonated alkylated aromatrcs. sulfurrc acrd 98% at 145-170 f, and 63% at 195.222 F (vapors) sullonated waxes. sodrum chloride, water solutton, pH 5-a unspecrfred green sulfan~ acrds. unspecrhed car. boxylrc acrds, medwm vrscosrty lube or1 stock, in sulfuric acrd 3% solutron, neutralrzed wrth sodium hydroxrde to sodum hydroxtde <6% concentratron lb&w steam cart, bottom of tank) Chemrcal F 188. 195 32. 42 145. 222 145. 222 132 1
304
316
317
0.113ad
0.121
Chemical
0.001
0.001
0.001
0005
Chemical
14
xx
xx
0.21
0.122
0.048
Chemrcal
14
0.0017
0.0013
0.0013
0.001
Rayon
162
xx
x x
O.OOOlcd O.OOOlad 0.045c
0.0001
.
0.0027
Petroleum
150.
iao
60
0.027~
lrqurd sulfur. selenium lrqurd sulfur. rron and alumrnrum chlorides 600 ppm approxrmately. hydrochforrc acrd trace possible lfrlterl ltqurd sulfur. small amounts of sulfurrc acrd and won sulfate fair-sulfur interface1 lrquid sulfur. traces of morsture and hydrochloric acid liqurd sulfur. arr. small amounts of water, pH 1.5-3.5 lrqurd sulfur. water saturated. pressure 25 psig lrqurd sulfur. morsture during 10 days, and water durmg 51 days lrqurd sulfur, nitrogen 55%. water vapor 27%, carbon droxide 9%, hydrogen sulfide 4%. sulfur di. oxide 2% of gas (bottom of tower packmg support. scrubbing of sulfur vapors) sulfur. sulfurrc acrd. hydrogen sulhde, sulfur droxrde, sutfurous acrd trace, water vapor sulfur (vapors) sulfur Ivapors) sulfur. stagnant (vapors) sulfur. stagnant (vapors) sulfur, stagnant (vapors)
Metal fdistrllation) Chemical
F F
a50
275
7.8 a3
XI
0015 0 0037cd 0.0035cd
0.008
0.0024 0.0033
0.028
co.004
Mlnlng
Chemical
280
13
xx
xx
0.015 0015 0.0048Cd
0.018
0.017
0.015
302
105
0.0033cd
Mrnrng
Isulfur) Chemical Mming fsulfur) Chemical
305
11
xx
xx
0.037 0.035 o.oaac 0.005cd
0.02la 0.019bd 0.05ac 0.0015bd
F F
248 330
a.5 61 xx
xx
290
135
xx
0.0003cd
0.0001
Chemrcal
73. 284
ai 7.8 54 27 36
XX
0.004acd
O.OOlgbd
Metal ldistillatmn) Chemical Research Research Research
F F F F F
a50
1060 1020
0.02
0.023 0.0311 0.0022 0.02
xx
-
0.027 0.03 0.032 0.031 0.051 0.047 0.014
1100 1250
28
0.084
(continued)
Ferrous A llo ys
583
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
kontd)
Corrosion
mediums
Test conditions
Average corrosion
rates (iPY)
lPI
T"PS
316
TIPS
ALLOY
20 825
---sulfur,
304
0.11 0.18 0.004cd
317
stagnant Ivapors)
Research
1400
28
0.12
sulfur, traces of moisture and hydrochloric acid Ivapors) 6% sulfur, m acrd gates. nitrogen 55%. water vapor 16%, carbon dioxide 15%, hydrogen sulfide 6%. sulfur dioxide 3% 3% sullur vapors, in acid gases, mtrogen 55%. water vapor 27%. carbon droxide 9%, hydrogen sulfide 4%. sulfur dioxide 2% [bottom of catalyst support grad in converter) 2.5% sulfur vapors. in acid gases, nitrogen 59%. water vapor 22%, carbon dioxide 15%. hydrogen
sulfide 1%. sulfur dioxide 0.5%
Chemical
305
105
0.0023cd
Chemical
500. 600
163
0.0002
0.0901
Chemical
a00
135
xx
0.002
0.002
Chemical
500
276
<0.0001
0.0001
sulfur vapors half Immersed
m steam in water)
fvulcanization
autoclave,
Rubber
290
4.5
<O.OOOl <O.OOOl
<0.0001
sulfur compounds leached and steam or steam alone
horn
rubber,
hot water
Rubber
212
69
-xx
1<0.0001
<0.0601
sulfur compounds in reduced crude vapors. pressure 75.mm mercury (tar pocket, vacuum tower)
Petroleum
750
369
0.0002
LO.0601
96.3%. carbon chlorrde 0 01%
tetrachlorrde 0.13%, iron as ferrrc lreboder for bubble cap column)
Chemical frecbficaIlOrd Chemical frr;;ifica.
280
133
xx
0.00078
0.0004
96% approrinately cap column, vapors)
(below
bottom
plate
of bubble
257
133
xx
0.00035
0.00035
SULFUR 60%.
DlOXlOL 20%. water vapor saturated
mtrogen
Chemical Chemical
60 SW 700 100
94
xx
xx
0.0001 0.00025
0.00025
16X, small amount of sulfur trioxide lsulfur burner, discharge linof 17.13%. bower) morsture. small amount
and moisture
90
xx
0.0002
0.0003
0.0002
0.9901
of sulfur
trioxide
Pulp and Paper Sulfuric Acid
37
<O.OOOla 0.0003a
xx xx
<0.0901
<O.OOOl
10% approrimrtaly, saturated hquor contains sulfurrc acid scrubber)
with water, recycle 0.3.0.75% (Peabody
85. 95
20
0.0001
0.0001
0.0001
0.0001
<o 0901
10% approxknately, saturated wth hquor contains sulfuric acid 0.725% 167X, water 3090%. sulfur trioxide
water,
recycle
Sulfuric Acid Chemical Metal
125. 135
20
xx
XI
0.002a 0.254a 0.02 0.037 0.0056ad O.OOO&
0.052
0.006
0.003
0.002
57%
180.
200 400 40. 130
4.5
xx
0.021 LO 041 0.0046a 0.0007 <0.0001
0.02 0.0041 0.000&d
5X,
ruckel-converter
ps
39
5%
saturated
fumes tram calcining
process,
oxy9en
11%. carbon droxida 8%. sulfur trioxide mist 1 cu 11
Metal
34
xx
xx
<o 0001
<0.0001 c0.0001
(continued)
584
TABLE 4.13:
VARIOUS
STAINLESS
STEELSAND Test
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(=ntdI
Corrosion mediums
conditions
11rE
ll?E
----
31s
0.002 0.002
317
20
ALLOY 825
5% rpproximatcl~. air,
oxide 1% <5%. 125f
moisture 6%. sulfur tri-
425
68
_.
oxygen 15%. nitrogen remamder. dew pomt
Mining
200. 500 170. 550 300 500 31 185
79
xx
xx
0.0042b 0.0015cd <O.OOOl <O.OOOla o.axl2r
0.0007
42%. water-vapor s&waled gases 2.1.5X. oxygen and nitrogen remJinder 0.2SX. moisturs sulfur.dioxi&-containin( #Jr fspny tower1
Mining Ymiq Food Miniw Wrl f .F
F F
160 103
x xx
x II
<0.0001
<O.OOOl
<0.0001
<O.OOUcd <O.oOOl 0.184 0.035cd <O.OOOl 0.161 0.032bd <0.0001
62 13 15
x xx
I
xx XI
<0.0001 0.2 o.OfJscd
sullur dioxide, sulfuric-Jcid mist. seknious acid, nitrgan oxides from decompositkm of sodium niwe, wetrr vepor. ~Jses of wryin composition fCottnll exit pxsl sulfur dioxide. sulfuric.rcid mist. selanious rid. nitrogen oxides from decomposition of sodium ni. We. water vepor, 2lras of verging composition (Coftnll exit gases.1 sulfur dffxide. moisture. urban diixide. lwtic acid. or#Jnic-acid vapors sulfur diosidr. sulfur mist smell mounts of orygen. ukr vepor Jnd sulfuric rid Kottrefl prrcipitalor) suffur dioside. sulfur flowers added to burnin coke, suffur trioside. urbo~ monoxide Jnd dioxide. uncerlrfn concentrations. possibly sulfuric and sulfurous ecids ~e,diixide. trioside. cJrbon dioxide (locomotive
100
90
Chemical
100
90
a.8
II
0.15bd
O.W?bd
0.009bd
O.Olbd
Corn
frefiningl Mining
Products
200 400 no450 M)140
271
0.02lc
0.0002c 10.0001c 0.051 0.047
xx
0.094 0.035 O.WMd 0.0003d
Brewing (beer1
277
xx
xx
0.0001
RJilroed
R.T.
365. 620
xx
xx
o.mlJ
O.ooolJ
Ol.mRlC
AClD
olcum (25%)
f 1 1 :L 1 1 .L F
so90 60 100 104 150 175 200 49 77 104 60
55 1 0.06 1
xx XI x xx
0.0007 0.013 0.0042 0.022 0.15 i 0.138 0.177 <O.aml nil nil nil 0.059 0.0625 0.336 nil 0.064 0.26 0.551 <O.oool II
0.0002
RISe*rCh
Research RosJarch Reserrch Research Reserrch Plastic
0.08 x 0.08 x 0.08 102

I
--;
(OK
bserrch Research
1 1
1 1
XI es--j
0.017 o.c#2
nil nil
wx
(continued)
Ferrous Alloys
585
TABLE 4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
hmtd)
Corrosion mediums
Test conditions
l,E
rm
SlrlF
Xld
Research Research Research Research Research Research Research Research Research Research Research Research
.
1 1 1 1 L L L 1 L L L
.
100
.
1
.
-
.
I
-
304
0.736 0.022
316
0.282 nil 0.572 1.2 4.0 0.0007 0.05 0.54 0.144 0.43 1.06 0.258 cm 6.5 0.18 0.825 6.5 6.4 0.072 0.065 0.665 <0.0003
3;;
0.579
20
ALLOY 125
00% 10%
IO% (0%
10%
0.08 x xx
104
150
0.08 x 0.08 x 0.08 x 1

1
i ! :
1.26 2.1 7.05 0.0001
1.12 3.35 6.05
175
200 90 60 104 90 60 104 60 90 104 60 100 104 150 R.T.
77.6% 70% 70% 96% 99% 90% 99% 90% 59% 40% 40% 49% 40% 39% 39% 39% 30%
--..: xx xx -
: :
0.039 0.0875 0.204 0.306 0.346
1 1 1 xx xx xx
..
-
L L L L L L L
0.15 0.217
Research
Research
,..
1 1 0.09 1 0.09 1 1 1 62
xx xx x xx x -
4.4 0.048 0.85 0.9 13.0 0.6
Research
0.22
2.64
Research Research Metal tcleaning) Research Research
L L F
60 104 130
xx xx xx
xx
0.035 0.474
O.wOl
O.LMO4
26% 25% 20% 20% 20% 20% 20% 20% 29%
L L
60 104 R.I.
1 1 1 1 0.06 1 1 0.09 0.09
xx xx
0053 0.41 0.13
nil 0.47 0.009 IllI 0.0745
Research Research Research """"
L L L
60 100 104
xx I xx
0.44 1.01 0.437 0.U
0.024
0.11 0.027 0.191 0.94 0.199 0.576
:
L
L
104 150
175
Research
Research
x I
5.75
10.1
(continued)
586
Corrosion Resistant Materials Handbook VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM
TABLE 4.13:
(contd)
lY?E
TWE
TPE
Slrrlc
acod
.
Research Chemical 1 200
.
-
304
21.0 0.0002 0.0238 LO.OOu 0.03 0.024~
ALLOY
20 825
316 -P-P
1.77 0.0001
311
1.06
20%
20% approximalaly
0.08 x 8.5 xx
F <IO4
15% 15%
Research Coal Byproduct Research Metal lplckling)
1 F
60 59. 86 104 185. 195 R.T.
1 212
xx x
xx
niL 0.0014 0.0012
15% 12% approximately
1 F
1 14
xx xx
xx
0.292 0.0126
nil 0.0027
10%
10% 10% 10% 10% 10% 10% Research Metal lpicklmg) Research Research L F Research Research Research 1 1 L
I
1 0.08 xx x -
0.065 0.0175 0.39 0.193 0.17
nil ml 0.0096 nit 0.0036 0.09 L nil
60 100 104 104 140 120. 160 150 175 176
illI
1
1 1 23
xx -
llll
0.078 0.197
ml
0013
10%
10% 10% 10% 10% 10% approsimataly
L L
0.08 0.08 1
x x
I83 4.5
0081 0.15 0.18
Research Research Sugar
L 1 F
200 8.P. 68. 152
0.08 I -97
7.0 16.5
0.207 0.86 0.0001
0.55
.,
<O.OLlOl' <0.ooo1 0.0007 0.460
<O.OOOl 0.025
Research
176
9. 10 47 -
0.0001
0.0252
8%
5% 5% 5% 5% 5% 5% 5x
Metal tpickling)
130
0.0108 0.0504 0.047
0.0014
co.0059
R.T. Textile Research Textile Research F L F L R.T. 60 80 loo 104 Research L 104
I
104 xx -
nil <0.0001 nil nil nil nil nil nil
<O.OOOl 0.013
I 106
0.08 1 1
II x
x -
nil 0.222 0.058
xx
0.0875
(continued)
Ferrous
Alloys
587
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Test conditions
TWE
TWE
1PE
su,,ur,c ace* 5% 5% 5% 3% 3% 3% 3% 2.5% 2.5% 2.5% 2.5% 2% apprnximataly Pulp and Paper F Research Research Research Research Research Research Research 1 L L L L 1 L 150 175 2w 100 150 175 200 R.T. 104 140 176
.
0.08 x
0.08 x
.
-
304
1.1 1.63 5.4 0.067 0.388 0.528 13 0.031 0.036 0.16
316
0.036 0.74 0 14 nil 0.0082 0.04 0 094 nil nil 0.0036 0.036
311
0.0038 0 09 0.23 nll nil 0 058 0.12
20
ALLOY 825
0.08 x
0.08 x
0.08 x
0.08 x
008
nil
nil
1% 1% 1% 1% 1% 1% 1% 1% 1% 1% 0.5% 0.5% 0.5% 0.5% 0.5% 0.5% 0.5% 0.5% 0.5% Research L Research Research 1 1 Synthetic Rubber Research Research L L ., F Research L Research Research 1 1 Research L
R.T. 100 104 140 150 175 176 200 8.P. B.P. 100 104 80 110 140 150 175 176 200 B.P. 1 0.08 0.08 1 0.08 1 x x x -
0.025 0.0575 0 028 0.074 0.22 0.38
nil nil nrl ntl nil nil nil
0.79
nil 0 14
nil
0.3161 0.037 0.025 0.021 0.0056 0.047 0.0225 0.445
0.0489 nil nil O.Wl1 nil nil nil nil nil nil nil
0.79
O.W38 0.054
nil
(continued)
588
TABLE

MOLWDENUM
bntd)
Corrosion mediums
---slnc acod
304
0.036
1lPE
WPE
TPE
316
nil nil 0.0927
317
20
ALLOY 825
0.25% 0.25% 0.25%
140 176 9.P
1 1 1 ,.
83.9% oleum 118%1. pyrrdrne 16 1%
Chemrcal Chemical
F F
125. 152 329. 347 110 125. 152 75. a2 2:; 160 II0
6 2
x x
0.0013
0.0016
0.0014
c<0.0001
66% ohm (65%l, pyrrdme 33% (bottom 01 sullonatron kettle) oleum 140%). nrtrrc acrd 4% vapors over oleum (20%) and pyridine 9999%. ferrrc sulfate, ferric chloride, hydrochloricacid saturated (pipe) 99%. rodrum naphthanate Z-3.86 99.90% sulfuric-acid sludge, pressure 15-18 psi Isettling drum) 930%. aluminium sulfate 3090%. hydrated aluminum oxide (underside 01 tank cover, vapors and splash) 99% acetic anhydride 9.1%. water remainder 99% acetic anhydride 9.1%. water remainder (vapars) 9920%. tallow fat
0.123 0.111 0.00018 0.0001
0.07
co.053
F F F
6 x x
x I xx
O.OOCl O.Owl 0.ooo15
0ooo12 0.wo1 C nil
167
O.ooO27
omJ15
Petre chemical Petroleum
F F
90 25
xx I
0.0185d 0.017cd corr*
0.0136 corr
0.9959d
O.WWd
Chemical
4 270
165
0.0909
0.0002
<0.9901
<0.0001
Petroleum Petroleum
F F
65 105 65. 105 150. 2M) 95 100. 130 100
42 42
x XI
<0.9001
<O.OWl
c0.09011 c<0.wo1
<0.0001
Soap and Fatty Acid Chemical 5oaP
110
_.
xx
corr nil
0.072
0.012
19%. nitrogen oxides 78% hydrogen peroxrde 3.5%, VariOUs iron, manganese, chromium and nickel salts 69%. reclaimed sulfuric acid, sodium sulfate 49 50 g/l, nickel 3-S (II. arsenic l-l.5 g/l. copper
trace
F F
73 8 xx xx
nil
C nil 0.014 0.0022 0.005
0.0947
0.0082
Metal
33
0.14
o.ooo5
O.WB
97X, propane, propylene partially combined with the acid 61%. mmor hydrocarbon contaminants 63.41%, propylene
Chemical
104 167 77. 122 2:
113
IX
xx
0.075c
0.08c
0.0121
0.0059
F F
113 63
II xx
xx xx
0.015
0.0015
O.Wlb
O.Wl4
0.01
0.099
0.099
0.033
99% sulfurrc-acrd emulsion, manganese dioxide precioitated 40% 6920%. copper 45 g/l. 11.7 111 nickel 20 g/l, arsenic
.Pharma. ceutrcal Metal lelectrorcliningt
145
12
xx
0.0094
0.0094
B.P.
101
xx
0.0002
0.0002
0.0002
O.oorll
(continued)
Ferrous Alloys TABLE 4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM
589
hxmtd)
Corrosion mediums
Test conditions
W?E
TWE
?WE
ALLOY
20 625
304 -P--P
56.5%. rated selenrous acid 80 g/l, sodwm sulfate satuChemical F
316
<0.0001
317
0.007a
56% sulfurrc~actd sludge from light-oil washing, coal tar, saturated and unsaturated hydrocarbons, sulfur trroxrde fumes. steam
Coal By product
285
07
0.005
0.002
0.0903
56% sulfuric-acid sludge from light-oil washrng. coal tar. saturated and unsaturated hydrocarbons, sulfur trroxrde fumes, steam
Coal By product
255
0.2
0.06
0.011
56% sulfurrcacrd sludge from light-or1 washrng, coal tar. saturated and unsaturated hydrocarbons, sulfur trroxide fumes, steam
Coal Byproduct
256. 285
77
0 006~
0.003c
0.0013c
56% sulfuric-acid sludge from Irght-oil washing, coal tar. saturated and unsaturated hydrocarbons, sulfur trroxide fumes, steam
Coal Byproduct
256. 285
0.15
0.08
0.033
50%.
caustic
soda 20S
fneutralizer)
Petroleum
200. 250 160. 200 105
48
0.065cd
0.02cd
505%.
fats and orIs flop of tank)
Soap and Fatty Acid sulfate g%,
40
0.0056
0.0047
0.0028
0.0027
45%, sodrum brchromate chromrc sulfate 3%
0%.
sodwn
0 05
0041
35.6%. phosphorrc acrd 13.3%. aluminum and ferrrc oxrdes 3.4%. hydrofluorrc acid 1.396, copper 0.3%. rare-earth oxide 0.02%. thorrum oxide 0 01% (transport truck) 35.15% sulfurrc-acid sludge, tar, oil
Chemical
RT
0.0012 0.0004
0.001
0.0034
Petroleum
120. 200 120. 200 40. 110 212
19
0.121
0.059c
0 045
co.017
35-15X and or1 35.10%.
sulfurrc.acrd
sludge,
large
volumes
of tar
Petroleum
29
0.482
co.157
,.
ammoma,
ndrous
oxrde
Chemical
53
<0.0001
<0.0001
30%, clay
30% approximately, fonatorl sodrum-sulfate solution fsul-
Research
1
F
>6 51
0.0001
0.0008
Chemrcal
175. 202
0 34
0.39
0.46
3920%. copper sulfate 0.5.3.5%. mud from electrolytic copper-refmmg
abrasrve anode process
Metal
170. 180
0.131
0.096
0.072
25%. phosphorrc acrd hydrofluorrc acrd 0.3%. 25.22%,
15%. sodium sulfate rare-earth fluorrdes 56%
3%,
Chemical
RT. 212 150. 160 66. 70
corr
corr
coo1 I
0.013 0.005 0.009
sodrum drchromate
Arrcraft
0 021cr
0.01
24%. tdanrum ferrous sulfate gravtty 1.485
droxrde as trtanrum sulfate 12%. 9.6%. ldanrum 13) 2 g/l, specific
Metal
0.03
0.0024
22.16%, copper sulfate 3545 g/l. nickel sulfate 20-30 g/l, chlorrdes as sodrum chloride 0.5 g/I F
130. 150
<0.0001
<0.0001 L<O.OCOl
<O.OOOl
<0.0001
20%.
sodnon drchromate
4%
(stripping
tank)
Metal
150.
0.014
0.023
0.011
0.0064
0.019
(continued)
590
Corrosion Resistant Materials Handbook VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM (amtd)
TABLE 4.13:
Corrosion mediums
Test conditions
TWE
TWE
TPl
Slf,lC aced
mlxturel
.
F
.
140
.
25
.
x
.
x
304
316 P--P
0.014 wo.013 <O.OOOl
317
"20"
ALLOY
825
20%. copper sullate <5%
lcontmuous plcklerl
plckler,
Metal (pickling) Metal Ipickling)
0.188
0.015
CO.0056
2O%.lerrous and ferric bottom of sump tank)
won 2% tcontmuous
170. 180
xx
<0.0001
18.5%.
chromic
acid 3%
(bottom
of tank1
Metal
180
86
0.0091 S0.03la 10.012 0.0051 SO.024 0.53
0.016 so.04 10.027a o.Oct7 so.014 0.21
0.02la
0.0081
0.0038 SO.072
18.5%.
chtomlc
acld 3%
(bottom
of tank)
Metal
180. 185 170. 190 190. 210
23
18%,
sodwm
chloride
3%
Metal (pickling) Rodme 67 mhlbltor Metal (pickling)
xx
0 17
0.0004
0.11 CO.096 0.0006 c0.0003
18%. tron 1% approximately, added lcontmuous picklerl
19
xx
0.0004
0.0003
17.5X,
chromic
acid 3.5%
Electrow
160. 200 70. 80
30
0.003a 0.002d 0 0324~
0.0015
0.0008
15.6.8.5X, selemous acid 40-100 g/l. some selemum suspens!on. small amounts of sulfurous actd
Research
0.0004d
C0.0003d
nil d
15%.
anneal
and spray pickle cycle (conveyor
racks)
Metal
R.1: 1300 B.P.
xx
xx
0.012 10.014 0.0001 S corr 1 NG 0.095 0 077
0.007
0 005
15.10%.
copper
sulfate
Metal tcleanmg)
720
xx
0.00014
0.0001
15.10% sulfuric-acid sludge 011
sludge.
large
amounts
of
Petroleum
150. 200
22
xx
0.072
0.077
CO.046
13%
manganese
sullate,
mangamc
oude.
water
Chemical
80. 210 131. 208
30
xx
0 034
0.031
0 03
10%. manganese ganic acid
dloxlde
9-10
g/l.
some
perman-
Metal (plating)
76
0.0045
0 0047
0.0053
0.005
0.004
10%.
manganous
actd 8%.
slurry
Chemical (filtration1 (electrolytic zinc Metal (plating)
65. 70 95. 122
3.8
<0.0001
<o
0001
lo%, cell)
manganese-dioxide
sludge
60
0.0078
0.0083
0.0087
0.0069
0.0051
10%.
copper sulfate
2%
(spray pickling
machmel
Metal (pIckhog) Metal
90
7.3
xx
xx
<0.0001 <O OOOla <0.0001 SNC 0 053cd
<0.0001
10.5%.
copper
sulfate
0.25%
IOO200 IOO140 100. 140
162
xx
<o
0001 SNG 0 025cd 0 004cd
0.0001 SNG
10.5%.
sodum
sulfate
25%,
hydrogen
sulbde
trace
Petroleum
42
10.5%.
sodwm
sullate
25%.
hydrogen
sulfide
trace
Petroleum
23
0.062cd
0.018cd
0.0033cd
9%. water 85 5%. sodium sulfate 3%. hydrofluonc acid 1%. orthosdwc acid 1%. sodwm fluosdicate 05%
Chemical
62
0.015
0 007
0.001
(continued)
Ferrous
Alloys
591
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Average corrosion
rates (ipy)
1wc
,lPE
TWL
ALLOY
20 825
.
Su,rlC
.
I -
304
316
317
ac,Ll mlXtre*
8%. oxrdrzmg solution
constituent.
ferroclean
prcklmg
Metal
0 0004 0 0005
rlll
8-7.5%. alummum sulfate small amounts ot calcrum
3%. few sulfate IX, and magnewm sulfates
Chemrcal
200 210
15
xx
xx
0 025
0 006a
8.7%.
sodrum nrlrate
0 8-O 3 oz.gal
Metal lplcklmgl Pulp and Paper
155. 165 78
13
xx
0.036d 0 053d
0 0001 00031 0 0007
111 0 0022
90
xx
< 00001
0 08cd
<o 0001
0 02cd 0 002cd
5.5%. roasterxrubber ous acrd 83.7 g/l. 0.8 g/l 5%. zcrconyt sulfate
solutron, tellurum
selenium as setew as telluroos acid
Chemrcat
150. 160
30
0 025cd
0.3-0.4
lb/gal
100
90
80.
15
xx
xx
0.001
o.C.31
nit
5%. 5%,
z~rconyl sulfate Acrtrol
3.4% Metal (cleaning)
f f
I5 57
xx xx
IllI 0 077
0.001
0.0048
0.001 0.0008
rlll
inhibrtor
5%.
rodrum drchromate
1.11 lb/gal
Metal
Ipickling)
70. 85 175. 185 180. 212
30
0.0003d
<O.OOOld
c<o
0001
5%.
copper 0.5-0.56
or/gal
Metal lpticklmg) Chemical
30
xx
xx -
0.0003d
O.OOOld
co 0005
5.4% sulfurrc-acrd solutron settled from the acid warhmg of oleic acid, during settling periods only (bottom of lank1 4%. large amounts ot sadwm chlotrde
0 00016a
<O.OOOl
70. 82 95. 104 150
30
xx
0.0318cd
0.0246ad
4.1%. 1015% 3%.
arnmonwrn
sulfate
20.25%.
sodium
sulfate
Chemical
970
0.0001
0.0001
0.0001 c0.0001
0.0001
Cuprodme
powder
5 ozlgal
Metal (pickling) Metal tprcklingl (tower) Chemrcal
2.7
0.0057c
0.0011
3%.
Cuprodme
powder
5 ozlgal
150
2.7
xx
xx
0.071c
0.0021c
2.5%.
copper
sulfate
O.l%,
alcohols
200. 250 120. 128 120. 180
11
0.0725.
0 02
00188
2%.
sodrum chloride
saturated
30
xx
0.0072ad
0.0059a
1.61.0.027%. chlorrdes 0.015%. pH 1.1-8.1 <I%, ipressure ferrous vessel, and hquid
as
chlorme
ion
0.001.
Chemrcal
259
xx
<o.o001
0.0001
<0.0001 0.0002
<0.0001 0.0001
<0.0001 0.0001
0.026
lerrrc
sulfates.
pH
1.8-4.5
interface)
Paint and Varnish tcrystalliza. tion) Synthetic Robber
430. 470
0.0163
0.0427
0.0301
0.36%, liquor tbottom
some chlorides from acid used to dilute concentrated of tank)
brine mother sulfuric acid
70.
II
110
0.0088d 0.0040d
<O.OOOld
(continued)
592
TABLE

4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLyBDENuM bntd)
Corrosion mediums
Test conditions
TYPE
SlWK
ac,cl
mlxturer
.
clay, amylene. phenol, traces chloride, ferrrc and ferrous Chemical F 125 305 52 -
.
xx
304
O.Olcdr
316
0.0055c
TWE
TWE
311
20
0.005c
ALLOY 825
0.20.02%. Retrol of diamylene. amyl chlorides (vapors1
0.1%. sulfur droxide 0.04X, varying amounts of carbon, pff 2 iPeabody scrubber, bottom tray strip per section)
Chemical
164. 177
58
xx
XX
0.0023~
<O.OOOld
<O.OOOl
<09001d
0.1% approximately, salts, pH 2-3 5
tungsten
and
molybdenum
Chemical
170. 185
14
XX
0.147c
0.0004
0.050.01%. glycol 15%. side of hydrator tankl
water
remainder
(bottom
Petrochemical
210
57
<O.OOOlad
<0.OOOlad
<0.0001
0.0001
<O.OOOl
0.050.03%. glycol 15%. dome of hydrator tank)
water
remainder
ftop
Petrochemical
130. 150
57
<O.O001d
<O.OOOld
<O.oool
0.0003
<O.oool
sulfurrc acrd concentrated to very drlute. hydrochlorrc acrd, caushc soda, morganic chlorides, miscellaneous anthraquinone derivatives, various sotvents, pH l-12
Sewage Itreatment)
60. 1OC
35
xx
<0.0001 0.0006
<O.OOOl 0.0003
O.CJxll
sulfurrc acrd, phosphorrc acrd. hydrofluorrc acrd and fluosrlrcrc acrd mrrbrre, concentration 20% in water (scrubber) sulfurrc acid, ammomum sulfate
Chemrcal
225
30
xx
XX
0.0016cd
O.OOlad O.OOlcd
0.0005d
<O.OOOl
0.0001
Chemrcal
125. 145 162. 178
77
<0.0001 0.093
X
0.0003 w<o.o061 <O.OQOld
<O.OQOl
c<0.0001
sulfurrc acrd. ferrous sulfate, 1.5 (alternately immersed)
some
sulfide
ion, pH
Metal IrefuungJ
<O.OOOld
0.0001 c<0.0001
O.OOZad
sulfuric and sulfurous lclay dust washer)
acids,
pH 2.5 approximately
660. 690
8.2
xx
xx
0.24 so 43
0.0012 SO.OO25a SO.001 la 0.0014 SO.0018
sulfuric and sulfurous (clay dust washer)
acids,
pH 2 5 approxrmately
660. 690
8.3
xx
xx
S0.29cd 058cd
sulfurrc acrd. sulfurous acrd. sulfur droxrde. carbon alkylate. pH of water 3 approxrmately overhead column)
hydro(rerun
Petroleum
230
281
<O.OOOlb
<0.0001
<O.OOOl
ddute sulfurrc acrd m plant process water, acrd. sodrum hydroxrde. pH 3-14 fcollector sump)
acetic sewer
Chemrcal
60. 150
80
<O.M)Ola
<O.OOOl
dilute sulfurrc acrd. neglrgrble amounts of sulfomc and orgamc acrds (top of clay contact flash tower, vapors) drlute sulfurrc and acetic acrds mixture wrth sodium hydroxide 50% (sump) neutralized
Petroleum
265
247
<0.0001
<0.0001
Plastrc
60. 160
216
<0.0001
<0.0001
dilute sulfuric prckling
acid,
waste
acid
sewer
from
steel
Metal fpicklmg)
60
164
<0.0001
<0.0001
<o 0001
0.0001
c<o drlute sulfurrc lsulfonatorl acid, sodium sulfate water solutron Chemrcal F SO105 6.8 -
<0.0001 0.0002 0001
0.0001 wo 002
0.0001 WO.0025
0 0001
drlute sulfurrc tmg tank1
acrd. pH 2.3 (vapors
from
fat split-
Soap
70. 220
60
xx
O.OOZad
O.OOla
O.OOla
(continued)
Ferrous
Alloys
593
TABLE
4.13:
VARIOUS
STAINLESS
STEELS Test
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(co&d)
Corrosion mediums
conditions
Average corrosion
rates (ipy)
SULFUROUS
ACID
90.3%
Isulfur-dmxrde
scrubber)
Synthetrc Resin pH 2.5 approximately
l&9
0.00022
<O.OOOl w<0.0001 0.0054 so.0059 0.012d
co.ooo1
sulfurous and sulfuric May dust washer) sulfurous and sullur~c
acrds.
F F
Synthetic Resin F
660. 690 660. 690 127
8.3
xx
>l.O S>l.O
acids,
ptl 2.5 approximately
8.1
xx
(clay dust washer) 2.6% tsullur-droxide scrubber)
0.27d S0.43d <O.OOOl
so.011
<O.OOOl w<0.0001 0.00013d <O.OOOld C<O.OOOl
41.5
2.05% 1.7% drlute 0.01%
approximately.
sea water,
sodium
chloride
Chemical
55
30
xx
xx
O.OOlSad
C<O.O001d
sulfurous
acrd.
I propylene-glycol
solution
Chemical Synthetic Resin Power
F F
80 219
30 41.5
<0.0001 <0.0001
<0.0001 <O.OOOl w<0.0001 <0.0001 0.0002 c<0.0001
apprasimately
sullurous tratrons. 1.1-12.6
acrd and caustrc soda rn varymg concenwater effluent 01 arc heater washmg, pH
150
2.4
xx
0.0001
<0.0001
tall 011
Chemical lfractionationl Chemical tlractionatlonl Chemtcal (tractrowtion) acrds lrom southern kralt-paper mdls lractronating still, bottMn of tower) acrds lrom southern kralt-paper mills lractronating still. top 01 tower, vapors1 acids from kralt-pulp manulacand abretrc acids fhigh.vacuum Soap
545
0.175
0.001 0.004
0.0005
tall 011
572
0.497
0.003 0.004
0.0008
tall 011
600
0.804
0 027 0.072
0021
tall-otl latty Ihigh-vacuum taILorI latty fhrgh-vacuum
500. 550 470. 510 560. 590
195
co,,
0.014
Soap
195
corr
<O.OOOl
crude tall-or1 fatty tore. olerc. lmolerc lractionatmg still) talLoil
Soap
xx
0.048~
0.001
fatty acrds Ireboiler)
Chemrcal lfractiona-. tion) WIChemrcal
455. 473
50
xx
0.0018
0.0001
0.0006
0 0007
tall 011 and Its glyceryl esters, tall-or1 amides, furrzed tall 011 lbottorn of tank) tall 011 and Its glyceryl esters, taILorI furred tall oil ltop of tank, vapors) successrve furuatrons tall-orl esterrfrcatrons. amrdes.
300. 550 300. 550 300. 550
17.5
xx
0.009
0.0014
CO.0006
sul-
Chemrcal
17.5
<O.OOOlad
<O 0001
C<O.OOOl
amrdrzations.
sol-
Research
18
_.
0.009
0.0014
CO.0006
successwe luruatrons
taILorI esterrhcatrons. [vapors)
amidizations.
sol-
Research
300. 550
18
0.0001
0.0001
c0.0001
(continued)
594
TABLE
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hmd)
Corrosion
mediums
Test conditions
Average corrosion
rates (ipy)
TIPE
TPl
TPl
.
tall-or1 oleate methyl esters, rosr acrds 46%. and lrnoleate 44%. sterols 10% methyl OrIs and Fats L 378 La -
.
-
304
----
316
317
20
ALLOY 825
<o 0001
0.008
<o 0001
0 0034 00038 CO 0025
fatty
acrd,
rodrne,
rosrn tvaporsf
Chemrcal
250. 450
11
xx
tanrung solutron. small amounts 01 lactrc. acetrc and organrc acrds. pH rnrtralfy 5.4, alter 8 days 4.2, at end of l-day cycle 3 1
Leather
80
II3
xx
00001
0 0001
chrome
tannrng
hquor
Leather
ao220 60. 90 200
123
xx
xx
0.000acd
0 OOOBcd
O.OOlcd
chrome
tannrng
lrquor
Leather
123
0 0001
0.0001
0.0001
CO.032
chrome-tannrng mrum sulfate 55% tank) 50% tank) basrc
sofutron,
concentrated
basrc
chro
Tanning
30
0.185
0.089
co,,
chrommum-sullate
solutron
(bottom
01
Chemrcal
200
20
COll
0.026
basrc
chromrnum-sullate
solutron
(bottom
01
Chemrcal
130
38
0.0001
0.0008
0 0009
chrome-tannrng 150F durmg at 212F 2 8. at 7OF 5%, at IOOF
18,
solutrons sulfurrc acrd 16% at 16 hours, sulfonated naphthalene, pH durrng 25 hours; chromic sulfate, pH during 50 hours. sodrum brcarbonate durrng 25 hours organrc acrds, tannrns
Leather
70. 212
48
<0.0001
<0.0001
<0.0001
<0.0001
vegetable
tan Irquor,
Tannrng
140. 160
180
xx
<0.0001
co
0001
run-off bonate
I 5%.sulfurrc
on leather wrmger, acrd 0.013%. traces and anrmal grease
lrquor
tannrng lrquor of sodrum car-
Tannrng
114. 126
21
xx
<0.0001
<o
0001
vegetable tan Irquor. chestnut extract 40%. quebracho extract 30%. brsulhted prevrously wdh sodrum brsulfrte 3% and hemlock-bark lrquor 30%
Leather
110
53
xx
<o
0001
<o
0001
coal tar
Coal Byproduct (tar drstillatronl Icolumnl Coal By product (distillation) Coal Eyproduct fdrstillationl Coal By product tdrstrllationl Coal Byproduct fdrstillation) F 350. 420
116
xx
<o
0001
<o
0001
coal tar, some chlorrdes
60
0.065
0.023 SO.025 LO.021 0.016 so.022 LO 0145 0.009 SO.008 LO.007 0.012 so.01 LO.01
0.012
oooa
Icolumnl
350. 420
60
0.056
0.0085
0.0063
coal tar. some chlorrdes
(column)
350. 420
60
0.025
0.0033
0.002
lcolumnl
350. 420
60
0.023
0.006
0.002
(continued)
Ferrous
Alloys
595
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
Icontd)
Corrosion mediums
Test conditions
1VPE
1VPE
,PE
A
Tar
.
F
.
450
.
306
.
-
.
x
304 -P-P0.013r
316
317
20
ALLOY 825
coal tar lreflux condenserl
Coal By product fdrstillatronJ la remove chlorrdes (top of Coal Byproduct Itar fractlonatlon) Coal Byproduct Oar fractlonatlon~ Coal Byproduct (tar fractlonatmn) Coal Byproduct (tar fractronatron) Coal Byproduct itar fractlonatlon~ Coal Byproduct (tar frac. tlonatlonl Coal By product (tar distdlation) Coal By product (tar drstdlatmn) Coal Byproduct (tar drsttllatiord (bottom of column) Coal Byproduct ttar drstillatmn) Coal By product (tar drstdlatron) wrth steam (column, Coal Byproduct (tar fractronation) Coal Byproduct (tar fractlonahon)
0.0035r
coal tar. waler column)
washed
390
66
xx
O.Olcd
0.0002bd
coal tar, water column1
washed
to remove
chlorrdes
(top of
390
59
xx
0.002bd 0.005cd
<OOOOtd
coal tar. water
washed
to remove
chlorrdes
kolumn)
515
66
xx
nrl
nil
coal tar, water
washed
to remove
chlorides
Icolumn)
515
59
0 013c
<0.0001
coal tar, water
washed
to remove
chforrdes
(column)
500. 600
59
<o
0001
<0.0001
coal tar. waler of column)
washed
to remove
chlorrdes
(bottom
640
59
<0.0001
<0.0001
coal level)
tar kontmuous
stdl,
flash
box, above
hqurd
F <650
360
xx
<O.OOOl w<0.0001
<0.0001
coal tar, chlorides
0 08%
(top of still)
390
81
xx
0.035
0.012 WO.008
coal tar. chlorides
0.08%
515
81
xx
0.0025
0.001 WO.00023
coal tar. chlorides
0 08%
640
81
xx
0 00016
<0.0001
w<0.0001
coke-oven
tar Ivapors.
lrqurdl
180. 700
305
xx
<o
0001 0.0003
<o
00003
0001 <o 0001 c<0.0001
0001
coal-tar hydrocarbon vapors. Irquid)
mrxture
IOO145
48
0.0001
<o
coal-tar 011. naphthalene chlorrdes as pfi of feed 6
Carbohc 40.50%. ammonwn (bottom of
orI. tar acrds, tar bases, water l-3%, neutral 011s. chlorrde 4.17 lb/ 1000 gal. columnl coal-tar 011 constrtupH 5 approxrmately
510
53
xx
0.0002c
0.0002
tar acids. tar bases, neutral ents, ammonwn chloride, (vapors)
Chemrcal Idrstilfatiord
430. 460
13.3
0.099c
0.052
0.02c 0.0095c
tar acrds. tar bases, neutral coal-tar orI constrtuents, ammonium chlorrde, pH 6 approxrmately (top of column, vapors) hrgh borlmg tar acid (top of heating bundle in still)
Coal Byproduct (distillation) Chemical (distillation)
430. 460
97
xx
0.0089c LO 007lc
0 0024
0 0015
0001
356
188
xx
COU
0.0066
0 0002
0.0001
(continued)
596
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(contd)
Corrosion mediums
Average corrosion rates
(ipyl
IVPE
IPE
TPE
ALLOY
-20 825
.
Tar
.
-
.
xx
---
304
316
0.0002
317
tar acrds,
phenols,
cresolr,
xylenol.
sullur
corn
Coal By-
pounds (vacuumstill. vapors outlet, liquid)
product (distillation)
Coal By product
175. 375
374
547
0.0002
tar acrdi.
phenol,
cresol,
xylenol
32
xx
<0.0001
<0.0001
(distillation1
tar acrds. sodium sulfate, tres. ptl 6.8 (column) sodium carbonate impuriChemical (drstillation) Chemical (distillation) Chemical tdistrllatronl (vapors, some Coal Byproduct tfractionatiord Coal By product tdistdlatron) column, Coal By product (tar fractionabon) Coal By. product (tar drstillationl tar bases, creCoal By product Coal By product bar distillatronl Coal By product found rn of sulfur Metal (aluminum1 F
212. 392
212. 392 212. 392
38
xx
<0.0001
<0.0001
<0.0001
tar acrds. benzorc sod. phosphoric sulfate. pli 4.5 (top of still pot) tar acrds. benzoic acid, phosphoric sullate impurities (bottom of still) tar acrds. phenols, cresols, spray of hquid possible) xylenols
acrd,
sodium
11.5
xx
<o 0001
<0.0001
acid,
sodium
11.5 -
xx
0.0002
<0.0001
0.0001
350. 380
140
xx
<0.0001
<0.0001
tar acrds. phenol,
cresol,
xytenol
(vapors1
320
21.4
xx
<o 0001
<o 0001
coal tar, vapors)
vacuum
(top
of
fractionating
175
25
xx
0.0001
0.0001
coal-tar
vapors (condenser)
400
306
0.018~
O.OlJcd
coal-tar vapors. phenol, naphlhalene, sylrc acrds. some chlorrdes
250. 650
190. 375
128
xx
<0.0001 <o 0001
10 0001 <OOOOl
coal-tar vapors, phenol, naphthalene. tar bases, cresylrc acrds. some chlorides ttop of column)
128
xx
coabtar vapors. light oil
vapors.
water
230
24
<0.0001 <0.0001
<o 0001
<0.0001
<0.0001 <0.0001 <0.0001
gases contarnrng constrtuents commonly coal-tar pitch, hydrofluorrc acrd, traces and carbon dioxide, air gases containmg constituents commonly coal-tar pitch, hydrofluorrc acid, traces and carbon droxide. air
100
196
xx xx
found in of sulfur
Metal (aluminum)
100
196
xx xx
O.OOOlcd
<0.0001
<0.0001
<0.0001
<0.0001
O.OOOJcd
commercrakgrade tartarrc acrd, decomposrtron ucts, formrc and acetic acrds, etc vapors over tartaric acid, decomposrtron acetrc and lormrc acrds. etc
prod-
Chemical
395
xx
0.002 0.003
0.0045
00063
products,
Chemrcal
395
xx
0.0006
0.001
TclRIM
thorrum traces, solvent extractron lrom ionexchange barren solutron: lerrous ion 2-20 g/l. sulfuric acrd 2-3 g/I, ferric ran 1 g/l. nitrate ion 0.5 g/I, chlorrde ion 0.2 g/l. ptl 1.7; solvent. amine 5% rn kerosene. chlorine 2 g/l (extractor)
Metal
68. 86
21
xx
<0.0001
<O.OOOl
<0.0001
<O.OOOl
<0.0001
(continued)
Ferrous
Alloys
597
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(-ntd)
Corrosion mediums
Test conditions S .$
TPE
,PI
TPE
304 p-p-TIN CHLORIDE
316
317
20
ALLOY
825
Im chlorrde. sodrum chlorrde. zmc chlorrde. so? pended sohds. petroleum solvent conlammg small amounts of water lautoclave)
Chemrcal
80. 370
16
0 067
0.013
18% approrimately stannous tluoborate. free fluobow acid 200 g/l, gelatme 3 g/l. catechol 0.5 g/l. a_naphtholO.5 g/l
Metal tplatmgl
125
365
0 0056
0.0009
0.0003d
0.0003
stannous-sulfate saturated solution. 4 or/gal. hydrofluorrc acid 1 ozlgal
sulfurs
acid
Metal
14
0.00135 LO.00133 0.00037 LO.00038 0.0149
0.00626 0.00143
11.7% stannous sulfate. sulfon~c acrd 3 9%
sulfuric
acrd 9.4%,
cresol
Metal
140
0.0002
TOLWC
ACID
72.5% mtolurc acrd, p-tolurc acrd 2.6%. benzorc acid 2.6% 55%. rylene
acrd 22.3%.
o-tolurc
Petrochemi. cal Rayon
RT250 330. 380 350. 370 290. 320 340. 350
77
<o
0001
<o 0001
0.0003
<o 0001
<o
0001
phthalrde 12%. esters 12%. water 5%. phthalrc acrd and anhydrrde 5% phthalrc
lo%,
22 5
0 0002
50%. phthalrde 15%. esters 15%. and anhydrrde 10%. xylene 10% 40%. xylene 20%. phthalrde 15%, phthahc acid 4%, water remamder 40%. xylene phthalrc acid mainder 20%. 4%.
acid
22 5
0 0003
0.0005
esters
10X,
22 5
0.0005
0.0006
phthalide 15%. esters lo%, cobalt acetate 1%. water re-
44
0.001
0.0006
30%. xylene 50%. phthahde 8%, water phthahc acrd 3%. phthalic anhydride 3%
5%.
220
44
0.0005
0.0007
tolurc acrd. benzarc acrd. acetaphenone, tolualdehyde. undetermmed orgamc materlals treborlq)
Petrochemrcal Idlstrilalmnl
350. 525
34
0 029 0 033
0 0002
0 0013
0001
TURPEIITIRE
turpentme from kraft pulpmg. small amounts of hydrogen sulhde. methyl mercaptan. dimethyl sulbde (decanter)
Pulp and Paper
150. 200
97
0.0001
0.0001
URANIUM
CHLORlOE
12% 12% 12%
approximately. water sotutmn

approximately, approximately, water water solution solution (half Immersed) (vapors)
8.P.
6.8 6.8 68
LO.92 10.58 LO.012
0.44 0.43 0.018
0.125 0.97 0.0048
BP. BP.
(continued)
598
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(=md)
Corrosion mediums
Test conditions
0 s f f 2
lPl
,Pl
TIPS
i!
.
ALLOY
20 625
304 P-P--
316
317
103. 106 113. 118
23
0.00015 <0.0001
<0.0001
<o 0001
0.0009d 0.0013d <0 OOOld
uranwm ore, sollds 70%. free g/l. iron ton 5-6 g/l. uranwm rate 0 3 g/I
sulfuric acid 50.60 oxide 1 g/l. chlo-
Mmng
60
xx
xx
0.0019cd
L0.002d
pulped ranwn ore. sollds 60%. sulfuric acid 28. 55 g/l, ferric ton 5-10 g/l, some lerrous MI. sodwm chlorate 0 I% approximately pulped ferrous uranwm ore kdlcatel. sulfuric acid 5%. bon 6 g/l. ferric ton 0 5 g/l IOorr agItatorI pulp, sulfuric acid 4%
Mmlg
118
41
0 0002d
0.0001
0.0002d
0002
0.0001
Mlnlng M1nmg
Mmng
104. II6 103. 106 103. 106 103 106 103. 106 75. 90
42
xx
xx
0.109c
0.066c
0 028
0.07
uranwm-ore
23
00001 <00001 0 0003 0001*
<o
0001
co 0001
uranum-ore
pulp, sulfwc
acid 2%
23
x <o
<o
0001
<:0.0001
uranium-ore
pulp. sullur~c acid 1% approximately
12
;0.0001 < 00001~ (0 0001 <0.0001
<o.ooot
c.0 0001
uranwm-ore
pulp, sulfuric
acid 0.5%
Mmg Mmlg
23
<oOLlOt
<o 0001
O.OOOld <0 OOOld
uranwmore leach pulp. sohds 68% approximately, sulfur as sullate 10 13.2 g/l. ferrous ion 6.6 g/l. ferric IO 2.7 g/l. fluoride ion 2.7 g/l. chloride ion 1.2 g/l, free sulfuric acid 0.1 g/I uramum ore tgranlte rock), sodurn-carbonate pulp, sohds 50%. sodwm sulfate 6%, sodium carbonate 5%, sodwm bicarbonate 1.596, pressure 85 psig (half Immersed) wanurn and other tlon. from leachmg metal salts III suIturic-actd of uramum ores. pH 0.4-I solu-
38
O.OOOld <0.0001
Mming
200. 215
44
xx
xx
0.002 O.OOlcd
<O.OLlOl
Mming
100. 160 R I: 100
100
xx
xx
0.037 0.067 <O.OOOl
co 0005
0 0002
uramum and other metal salts m sulluric-acid solutlon, from leaching of uranium ores, pH 0.9-1.4
Mmmg
100
c<0.0001
<O.OOOl
uranylmtrdte 100% uranyl 80%, water of tank)
water Mate solution.
solution. being concentrated hexahydrate (evaporator) free nitric sod trace
to
M1nmg
BP
120
LO F 160. 215 36
0.0004 0004 0.0004ad
0.0003
(bottom
Mming
o.wo5 o.cOo3
0.0009 0.0004
0.00095a
0.001 0.0002
0.001
uranylmtrate ratlmate solutlon, nitric acid 30.40%. variable chlorides ~2000 ppm (concentrator column. vapors. Ilqudl
Mining
175
92
0.0011 0 0016
0.0011 0.0007
0.0006
0 0007
UREA 44%. 8% ammoma 31%. water 17%. carbon dooxide Chemical F 90 42 x xx
0.0001 0.0002 <0.0001
0.0002 0 0001 <0.0001
<0.0001
0.0002
43%. ammoma 32%. carbon dloxtde remamder (heat-exchanger head)
7%.
water
Chemical
90. 250
100
(continued)
Ferrous
Alloys
599
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
bntd)
Corrosion mediums
Test conditions
3 f 2
Urea
.
2
; .
$
rIPI TPl TPI
ALLOY
20 825
304 ----<0.0001
316
317
28%. ammonia
oxide 19%. merts
32 2%. 0.3%
water
20.5%.
carbon
dl-
Petrochemc cal Chemlcal Chemical
355. 360 300 250. 310 365. 375
150
<0.0001
<0.0001
<o.o001
SC0 0001
300 56 _ xx xx 0.028
s<o 0001 CDll

0.027
CO,,
urea. ammonia urea. ammon,a. reboderl urea, llquld carbonate
carbamate. carbon
ammonia. dloxlde.
carbon
dwde stwper
F F
011 (urea
ammonia.
carbon
dloxlde.
ammon~m
Chemical
125
xx
0.0015
S>O.O68 LO0016
00011 0.0089 so.0041 LO.0013 to 003
0.0013
00011
0.001 I
WNYL
CHLORIDE
vmyl chloride, vmyt peroxIde. hydrochlortc
acetate, acetlc acid, hydrogen acid, pH 3 5.4 5 tpolymerizerl
Chemical
RI. 150
xx
0.0004
0.0004 0.0008 so 0007 <0.0001
0.0006
0.0002 0.0009
0.0001
vmyl chloride, methyl acetal, a!ternatelyl
vmyl acetate, methyl acetate, dlau and moisture (vapors and resm
Chemical
60. 110
226
<0.0001
<0.0001
wnyl chlortde. probably contammg unsettled droplets of a sodurn-metablsulhte solutlon c 15% and 4-85 average vmyl chloride, probably contammg unsettled drop. lets of a sod~um~metab~sull~te solutlon < 15% and 4.8, average vmy:.chloride vapors and polyvmyl tramed m water vapor, pawbly traces and phosphates, vacuum 20% polyvmylxhlorlde phates 0 05%. pH 4.6 solutlon, chloride en. of peroxIdes
Chemical
60. 80
135
O.OOllcd
<O.OOOld
<O.OOO!
<O.OOOl
<0.0001
Chemical
60. 80
135
<o 0001
<0.0001
<o 0001
co 0001
<O.OOOl
Resin
110. 150
67
<0.0001
<0.0001
peroxldes.
phos-
Resm
80. 150
117
xx
xx
<o 0001
ml
bodet-feed mlzerl
water,
oxygen
0.01
ml/l.
pH 8.1 lecono-
Pulp and Paper
188. 190
56
xx
<0.0001
<0.0001
boder.feed water, sprayed mto deaerating heater. carbon dloude 70 ppm, sulfuric acid 30 ppm. oxygen 10 ppm
Power
100.
220
244
xx
<0.0001 <0.0001 <0 OOOldr S<O.OOOl w<o 0001 <O.OOOld <o 0001 w<0.0001
vented gases from steam deaeratmg dloxlde ~400 ppm. oxygen (80 softened water vapor. pH 4
heater. ppm,
carbon zeolite-
Power
210. 220
244
xx
brackish sea water, total sohds 1.8%. sulfur dioude l-2 5% lspeclmen removed and allowed to dry in au durmg 10 seconds1
Chemical
60. 95
158
xx
xx
corr
0.0003cd
O.OOOlad
0 0002d
Galveston
Bay water
(condenser1
Chemical
112
130
xx
xx -
0.0002 <0.0001
<0.0001 <0.0001
brackish water, denser box)
salt
200-15000
ppm.
pH 6-8 Icon-
Petroleum ldistdlatlonl
90. 115
181
brackish water. chlorides icondenser water box1
O-5000
ppm.
sullur~c
acid
Power
32. 85
400
xx
<:o 0001
<0.0001
<0.0001
(continued)
600
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hmtd)
Corrosion mediums
Test conditions c;
Y
Average corrosion rates (ipy) I

5s
*I
r -
2 3
WPE TlPE
IWoUs~aI (PROCtSS,
waler, braclush Everett, Mass. fammonra. Coal Byproduct
L .
rwt
304 ----P
63
00006cd
316
317
20
ALLOY 625
carcadmg brackrsh water, liquor coolmg cods)
RT
<OOOOlbd
WATER.
CmiDENSA*E
water condensed trom gas stream inItrogen 88%, carbon dwde 12% approxrmately), rron 40 ppm, sulfuric and sulfurous actds IO ppm, nttrlc and mtrous acids 3 ppm, pfi 6 approxrmately [alternately Immersed1
Petroleum
70 90
36
0 0001
(0
0001
<,o 0001
<0.0001
coohng water
(tower
basin)
Pharmaceutical Soap
62
112
xx
xx
<0.0001
<0.0001
coolmg
water,
pH 4.5
70. 110 42
360
xx
<0.0001 w<0.0001 <0.0001
<O.oOol
tap water, brcarbonates as calwm carbonate 20 ppm. sulfates 21 ppm. chlorrdes 11 ppm. iron and alumma 6 ppm. calcrum oxrde 5 ppm. sdica 2 ppm. suspended matter, pH 5 6 New then every each York Crty water sprayed Into atmosphere and drawn through arr washer; wdter replaced 33 hours, pH inrtially 7. fmally 4.5-4.8 during replacement perrod frmmersed and in spray) tailprpe water, pH 7.14
food
30
xx
xx
<0.0001
Food
45 50
16
xx
xx
<O.OOOl
<o.Lloo1
evaporator
Rayon
120
29
xx
<0.0001 <0.0001 <O.OOOld <O.OOOld <0.0001
<0.0001
evaporator
tadprpe
water,
pH 7.28
Rayon
120
36
xx
<O.OOOld
fresh water,
pH 7.3
Pubhc Works
68. 72
71
42
xx
<0.0001
well water, chlorrdes 40 ppm. carbon droxrde 30 ppm. won 5 ppm. sulfur droxrde 2 ppm, total hardness 200 ppm, pH 7 48 (pump discharge) fresh+vater supply to pulp grmderr. pH 7.6
Petroleum
63
xx
<o
0001
<o.ooo1
Pulp and Paper
95. 99
140
<0.0001
<0.0001
c0.0001
well
water,
hydrogen
sulfide
58 ppm approximately
Synthetrc Resm Water Heatmg Chemrcal
126
61
xx
0 0003ad
<O.OOOlad
domestrc
hot-waler
sopply
160
1555 89 164
CO OOOla
hot water
F <212
xx
<o
0001
<0.0001 <00001
untreated
water,
salts as chlorides
300-4000
ppm.
Petroleum
212
xx
<0.0001
pH 6 5-7.5
degassed
drstrlted
water,
pH 6.5, presrure
1235 psi
Research
572
30
<O.OOOl
<0.0001
(continued)
Ferrous
Alloys
601
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions
,PE
TlPE
VIPS
ALLOY
20 825
.
water. hrgh-purrty water, oxygen 20 ml/l. pressure 720 pst Research L hrgh-purely
304 P-P-P
30 xx
316
317
500 78. a2 450
catron-free
water,
pH 3 2
Research
200
dewwed water water heater)
and steam,
pH 9 fdeaeratrng
teed.
Power
655
xx
LC.0
0001
L<O
0001
Frood rnme durmg test)
water,
pH 3 4, (water
changed
3 trmes
Mmmg
I lo120 86
14
xx
00001
nrl
mane water, total sohds solrds 26 6 g/l, chlorrdes gravity 017
27.3 g/I 14 8 g/l.
total drssolved pti 6.8, specrftc
Mmmg
xx
~OOOOl L. 0.0001
<0.0001
rnme water from sulfide ore, ferrous sulfate 2.567 g/l. total sulfate ran 1.621 g/l. sulfurrc acrd 0 265 g/l. free sulfate ran 0 259 g/I coal-mme water, 0 4 ppm, pH 7 85 sulfate Ion 513 ppm, ferric ran
Mmmg
47
56
< 00001
<_0.0001
61 47
87
00001 0 0001 00001 00001
00001
mme water from sulfide ore, magnesrum sulfate 5230 ppm, ferrous sulfate 2599 ppm. calcrum brsulfate 2285 ppm, acrdrty 200 pprn mme water from ppm, magnesrum 603 ppm, acrdrty sulfide ore, calcrum sulfate 1710 sulfate 663 ppm. ferrous sulfate 150 ppm Mmmg
61
--
00001
47
61
0.0171d 0 0108d
<0.0001
rnme water from sulfide ore, ferrous sulfate 2835 ppm. magnesrum sulfate 2410 ppm. calcium sulfate 1408 ppm. acidrty 82 ppm mine water from sulfide ore. ferrous sulfate 1060 ppm, rnagneswn sulfate 1000 ppm. calcium sulfate 923 ppm. acidrty 7: ppm mrne water from sulfide ore. calcium ferrous sulfate 1310 ppm. magnesium ppm. acrdrty 52 ppm sulfate 1361. sulfate 054
Mmmg
47
61
xx
0.0095bd 0.0014d
<O.OOOl
Mmmg
47
60
xx
<0.0001
<0.0001
Mming
47
60
xx
<O.OOOld 0 0006d
<O.OOOl
rmne water from sulfide ore, calcium sulfate 923 ppm. calcium chloride 638 ppm, magnesium chloride 239 ppm, ferrous sulfate 61 ppm. acrdtty 23.5 ppm mme water, copper as sulfate 0.102%. available sulfurrc acrd as won sulfate 0 67% (water flows from launder mto sump. spools exposed to air durmg 5.15 mmutes, m water dung 26.5 minutes1
Mining
47
60
xx
0 0003d 0 0002d
<0.0001
Mmmg fcopper)
6061
58
xx
xx
<o 0001
<0.0001
mmeral sprmg water, potassium chloride 2584 4 ppm. talcrum sulfide 2743 ppm. calctum brcarbonate 113 2 ppm. alumma carbon aSoxIde 41
sodrum chlorrde 11190 5 ppm, 2614.9 ppm sodwm sulfate sulfate 1263.8 ppm, hydrogen calcrum carbonate 273.2 ppm. 221 3 ppm, magneswm sulfate 101 pprn. ferrrc oxide 93 ppm, 8 ppm, acrd, speclfrc gravrty
Sanrtary
80. 212
47
<O.OOOla <O.OOOlb
<o 0001
10169
hot sulfur-spring water, total solrds 269 pprn. calcrum carbonate 124 ppm, sulfates 23 8 ppm. chlorrdes 14 ppm, sulfides 12 ppm, pH 9.4 (Olymprc Na. lional Park, Wash) Samtarv F
120
120
xx
<0.0001
<0.0001
nil
(continued)
602
Corrosion Resistant Materials Handbook VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM bntd)
TABLE 4.13:
Corrosion mediums
TIPS
TIPE
TIPS
304
316
317
20
ALLOY 825
Arbuckle water, N. A. Hoffman 8 No. 6. Trapp Freld Barton Countv. Kansas. total drssolved solids 33640 ppm. chlor& ion 20165 ppm, sodium ran 10930 ppm, talcrum ran 2091 ppm. bicarbonate ion 476 ppm. total alkalrnrty 390 ppm, sulfate ion 24.19 ppm. large amount of hydrogen sulfide, pH 695, specrfrc grawty 1 0267 salt water from crude 011. pti 7 5 approxrmately settler vessel1 orl-field 2 ppm brme. chloride ran 16950 ppm, (salt
Petroleum
50. 70
90
<o OOOlc
0.0042~
<0.0001
Petroleum
170. 200 95
216
<O OOOla
<o 0001
chlorine
Petroleum
83
0 OOOld
<o 0001
Ncches River water, chlorine 0.2%. chlorrdes 3030 ppm. hardness 340 ppm. methyl-orange alkalinity 312 ppm. srlrca 50 ppm. pH 8.1 lcoolrng tower) Neches River water, chlorme 0 2%. chlorides 3030 ppm. hardness 340 ppm. methyt.orange alkalinity 312 ppm. srtrca 50 ppm. pH 8.1 (cooling tower) cooling water from Passau Rrver, chloride ion 834 ppm, calcium carbonate 328 ppm. sulfate ion 160 ppm. brcarbonate ran 46 ppm. sulfate/chtorrde ratio 0.19, drssolved oxygen trace, pH 8.5 rover water, chtorrdcs 1300 ppm. sulfates as sulfur 75 ppm. sutfrdes as sulfur 20 ppm. pH 6.3 (travel. hng bark screen) rwer water from let condenser IPotomac
Power
8b 92
74
O.OC&d 0.0003d
O.@lO2d <O.OOOld
0.0002d <O.OOOld
O.LlOO2d
<O.WOld
Power
82. 97
74
OOOOld
<O.OOOld
<O.OOQl
<O.OOOld
Power
65. 71
30
<O.OOOla
<0.OaO1
Pulp and Paper
45. 85
148
0.0001
0.0001
Pulp and Paper Chemical
R.T.
224
~O.Oooi
<O.OOOl
Mrssrssrppr
Rover water chlarrdes. varrous organrcs. intermit. (barometric condenser tailpitl
R 1. 90
90 169
c.00001
nrl
<O.oOOl ml
(O.wOI
rover water, tent chlorme
Kelly Lake water
Mmmg with organic Gas Manulacture
72
35
<0.0001
nrl
nit
Hudson Rwer water contammated waste from Poughkeepsie Crty
100
60
<O.oOOl
<O.OOOl
WATER.
SEA
,IYYERSED,
sea water
70. 02
212
<0.0001
sea water at Kure Beach, N. C.
R.T.
160
sea water
at Kure Beach, N. C.
Research
60
sea water at Wore Beach, N. C
Research
sea water at Kure Beach, N C
Research
R.T.
1645 (continued)
Ferrous
Alloys
603
TABLE
4.13:
VARIOUS
STAINLESS
STEELS Test
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
conditions
TIPE
TIPE
TIPE
ALLOY
20 625
.
water
rea ,wnmersedl
304 --p-p
0 0002c
316
317
sea waler
at Kure Beach,
N C.
Research
R.T.
480
-xx xx
sea waler al Curacao, Netherlands chlortdes 20000 ppm, pH 6 6 tpressure casmgi
West Indies. end of pump
Petroleum
79. 88
122
00001
<o 0001
sea water al Curacao. Netherlands chlorides 20000 ppm ptf 6 6 lsuctlon casmgi sea water at Curacao. Netherlands chlorides 20000 ppm. ptf 6 6 ipressure CaslllgJ artlliclal sea water, pH 7.7-8
West IndIes, end of pump
Petroleum
79. 88
44
xx
xx
0 OOOlad
0 OOOlad
West IndIes. end of Pump
Petroleum
79. 88
I2
xx
xx
0 0005ad
0 0004ad
Research
86
84
xx
xx
<O.OOOla
<o
0001
WATER. ZONE,
SEA.
AERATED
,IN
SPRA
OR TIDAL
sea water
at Kure Beach,
N C [half-tide)
Research
RT.
359
xx
xx
<o
0001
<o 0001
IllI
sea water
at Kure
Beach,
N. C. (half-tide
in basin)
Research
RT.
193
xx
xx
<o
0001
WATER.
SE&
IN
HARBORS
OMMERSEO)
sea water
at Wllmmgton,
N. P,
Research
R.T.
360
0.0007cd
<O.OOOld <O.OOiIlad 0 0001 0.0001
sea water
at Duxbury,
Mass.
Research
R.T.
I60
0.0001 0.0001* x xx 0 003c
6.5 86 concentrated clflc gravity I 0469
seawater (evaporation
brme, pH 28. pond)
spe-
Food
68
I05
0 0009c
0 0004cd
0 0006cd
WATER,
SEA. HEATED
Los Angeles Harbor West Basm sea water, total sohds m suspension 2.5%. organic matter m solotmn 2 0%. chloride ton 18800 ppm. sodturn loo 10478 ppm. sulfbte loo 2724 ppm. magnewm 40 1245 ppm. calcwm aon 451 ppm, potassium non 374 ppm. bicarbonate ton 165 ppm. bromme loo 12 ppm, SIIICP 6 ppm, phosphate ton 5 ppm. borate loo 0 3 ppm. won loo 0 2 ppm, pH 7.5 (18 m. below water level1 heated heated heated sea water, sea water, sea water, salt oxygen oxygen pH 7 6.07%, pH 8.1 lflrst.stage evaporaI5 ppm. pH 6.2 trace, pH 6.7
Petroleum
120. 140
350
0 0005cr
OOOla
L L L L
290 180 320 187 6.2
XI
xx xx xx
00124 0.0091 0.0002 0.00013
00131 0.0007 0.0002 0.0001 I
x
x
sea water, tor) sea water, rator) sea water, rator)
0.0001
salt 6 07%,
pH 8.1 (second-stage
evapo-
174
6.2
0.00018 <0.0001 _. <o 0001
0.00031
<0.0001 0 0001 <0.0001
salt
6 07%.
pH 8.1
lthird.stage
evapo-
174
6.2
0.00021
(continued)
604
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
hontd)
Corrosion mediums
TPl
304
TYPE
316
UPL
317 20
ALLOY
825
sea water, salt 5 95.6 13%. pH 8 8 levaporator) sea water. salt 5 95.6 13%, pH 8 8 (evaporator, vapors1
magneswm
hydroxide,
250
66.5
<O.OOOla
<O.OOOlar
<o 0001
<o 0001
magnewm
hydroxide.
250
66.5
0.0005c
0.0003at
sea-water brme. salt 13.1 4%, carbon dmxide ppm. pti 8 (first effect, bottom of unit)
Marme Idlstdtatlon) Marme tdlstdlatlon) Chemical
267. 270 253. 256 127
42
xx
00003
0 0002
sea water brme, salt effect, bottom of unit)
1.8.2.0%, pH 8 2 (second
42
xx
0.0002
0 0001
sea-water bIttern. Pachuca slurry, sodwm chloride 100 g/l, magneswm chlonde 75 g/l. calcium sulfate 50 g/l, talcum chloride 25 g/l. pH 6.7.5 lspeclmens covered wth crystals) sea-water blttern, sodum chloride 100 g/I. magneswm chloride 73 g/l, talcum chloride 25 g/l. calcium sulfate 2 5 g/l lheatmg tank) hot sea water, mIxtureI hot sea water, (vapors mIxtureI carbon dloxlde I ppm. pH 6 2 lvapors
107
xx
xx
0.0001
0.0001
Chemical
95. I26
84
xx
0.0004bd
0.0003ad
Marme
267. 270 253. 256
42
xx
0.0004a
0.0002
carbon
dioxide
I ppm,
pH 6.3-6.7
Marme
4.2
xx
0 0004
<0.0001
decatmrwed water mmeral bedl demmeralued exchangers zeohte-softened water.
ltop of catlon
exchanger,
above
Water Treatment Water Treatment Synthetic Rubber
65
210
xx
<00001
<00001
effluent
from amon and catwn
65
210
xx
<0.0001
<0.0001
water
(screen.
treated
water
line1
70
17
xx
<O.OGJl oil*
<0.0001
zeollte-softened OH 7
water,
small
amount
of
styrene,
Synthetic Rubber
I50
--
<0.0001
zeohte softenmg of well water at SIOUX Falls, S. 0, total hardness 23 2 g/gal, calcium hardness 16 3 g/gal. methyl-orange alkalmlty II 6 g/gal. ma& newm hardness 6.9 einal. chlorides 1.6 n/eal. sulfates I.1 g/gal tall these expressed as calcwm carbonatel. sdIca 20 ppm. iron 0 4 ppm. pH 8.1
Water Treatment
50. 60
365
xx
<0.0001
<0.0001
I.
__.
zeollte softenmg of wer water at Casper. Wyo, sulfates 40 g/gal. compensated hardness 29.1 g/gal, total hardness 264 g/gal, calcwm hardness 21 E gigal, methyl.orange alkalmlty 96 g/gal, magnewm hardness 4 g g/gal, chlorides 2 8 g/gal lall these expressed as talcum carbonate), silica 15 ppm, won 0 I ppm, pH 7.6
Water Treatment
50. 60
365
xx
<0.0001
<0.0001
WATER.
STEEP
10-4 Be steep water,
pH 4 (evaporator)
Corn Products corn Products
150. 190 127
242
xx
0 0005 <. 0.0001 <O.GQOld wo.OQa3
<0.0001
. .O.OOOl
<0.0001
corn steep actid. acldlty at end of steeping cycle as hvdtochlow acid 0.56%. sulfur dioxide initiallv OTl4%. fmally 0.018%. pti 4 average fin liquor jui above corn level)
44
xx
xx
<o.ooLN
WO.0006
(continued)
Ferrous
Alloys
605
TABLE
4.13:
VARIOUS
STAINLESS
STEELS
AND
HIGH
NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions
TIPI
TPl
TWE
ALLOY
-20 625
--corn steep acid. acldlty at end of steepmg

cycle as hydrochlonc acid 0 56%, sulfur dioxide ntially 0 12%. imally 0 012%. pH 4 1 average (below corn level) corn steep acid, acldlty at end of steepmg cycle as hydrochtorlc actd 0 5296. sulfur dioxide mltially 0.1 I%, fmally 0.011%. pti 3 8 average (below corn level) steep water from corn starch (evaporator) Corn Products
304
316
311
130
31
<o 0001
wo 0013c
<0.0001
wo.0012
<o 0001
corn Products
130
39
<o 0001 wo.ooo7c wo 0022c
<0.0001 wo.001
w0.0014
<0.0001
Corn Products Food
126. 130 150
80
<O.OOOld 0011 <0.0001 <0.0001
<0.0001 0.0019 <0.0001 <0.0001
steep 0.05%.
water. lack acid 051%. sullur dloxlde PM 3.54 5 (alternately vapors. lIquidI lactic acid 0.5.1%. (evaporator1 sulfur
40
vapors above steep water, dlonde 0.05%. pH 3.5-4.5
food
130 190
24
WATER.
TAP
tap water saturated wth carbon dloxlde contammg sullur dloude 0 008% average and traces of dissolved a~. pressure water saturated wth synthesis gas. hydrogen 38%. carbon monoxide 32%. carbon dionde 8%. oxygen 0 2%. nitrogen remamder, sulfur as hydrogen sulhde and organic sulfurs 300-500 grains/w 11
Power
4w425
32
0 006 0.0055 0.0001
0.0016
0 0018
0 0042
Chemical
150
30
0 0002 0.0003
chlormated
water
Plastic
85 115 70. 90
57
<o 0001
<0.0001
<0.0001
chlorinated lresh water, ptl 1, raw water composltlon methyl orange alkalmlty as caluum carbonate 212 ppm, total hardness as calcium carbonate 200 ppm, sulfate IO 32 ppm. chloride loo 24 ppm chlorinated fresh droxlde to pH 8. orange alkahmty total hardness as fate bon 32 ppm. spray1 chlormated lresh acid to ptt 6 9, orange alkalmtty total hardness as late ton 32 ppm, spray) water buffered wth sodwm hy raw water cornposItIon, methylas talcum carbonate 212 ppm, calcium carbonate 200 ppm. sulchloride ion 24 ppm Iwasher. m
Food (fruItI
32
c.0 0001
<o 0001
<o 0001
<0.0001
food tfrult)
70. 90
31
<o 0001
<o 0001
<o 0001
<o
0001
water acldlbed wth hydrochloric raw water composltlon methylas calcwm carbonate 212 ppm, calcium carbonate 200 ppm. solchloride loo 24 ppm (washer, in
Food tfrult)
70. 90
32
<0.0001
<0.0001
<0.0001
<O.OOOl
water. small amounts of hydrochtorlc we, pH 2 lbottom 01 condenser)
acid and chlo-
Chemical
195
61
0.0005bd
O.OOOZbd
tower water from Syracuse water supply, treated wth alglclde. Oaklte Samtlzer No 1, pH 8-8 5 (tower slwe-way1
Pharmaceu tlcal
45.
88
227
<0.0001 <0.0001
<o
0001
quench water, total sohds 0 64%. msoluble sollds 0 25%. ammonium chloride 0.1%. volatdes 0 09e%. calck chloride 0 066%. calcwm sulfate 0.062%. pH 6 5 (coke quenchmg tower, below spray header)
Coal
11.2
0 002lc 0.004c 0.0005
0.0003 0.0002
0 0004 0.0003
0.0002
(continued)
606

VARIOUS STAINLESS STEELS AND
TABLE 4.13:
HIGH NICKEL
ALLOYS-CLIMAX
MOLYBDENUM
(mntd)
Co rosion mediums
Test conditions
304 ----quench waler. total solids 0 64%. msoluble sollds 0 25%. ammonium chloride 0.1%. volatdes 0.098%, calcwm chloride 0 066%. calcium sullate 0 062%, Nalco No 161 mhlbltor added to coke sump feedmg at rate 01 50 ppmlgal water returned to sump (coke quenchmg tower, below spray header1 Chemical Coal F 11.2
TIPE
316
TPE
317
,PE
20
ALLOY
825
0 0013c 0.0093c 0 02lc 0 0084~
0.0002 0.0003
0.0002 0 0004
0 0001 0.0003 0 0002
waste-water effluent. hydrochloric acid, sulfuric acid. soda ash, caustic soda, chlormated solvents, organics, zmc sulfate. pH 2.10, generally acid (sump pipe Imel
R.T.
68
<0.0001
c<0.0001
<o 0001
waste water from fme-chemicals manufacture, drochforlc aud. sulfuric acid, or~an~cs. pH 6 5
hy-
Chemical
80.
30
<0.0001
<o 0001
100
Chemical
waste water from fme.chemlcals manufacture. acetlc acid. halogen suds, sullur~c acid, salts of these acids, traces of organic solvents and greases, pH Z-7.5, 6 5 average
55. 70
42
<o
0001
<o 0001
waste-process water. sodium sulfate, sodium chloride, sodium phosphate, ammonium sulfate, calcium sulfate. magnesvxn sulfate, pH 3.5-5 (vacuum evaporator. vapors)
Chemical
90. 118
63
<0.0001
<o 0001
<o 0001
<o 0001
water. chlorlc
various orgamc esters acid trace, pH 2 Icooler)
and
aclds,
hydro-
Chemical
86. 99
147
0 0116
0.0111
ammonwstdl coke flower,
waste water, for spray just above spray pIpIngI
quenchmg
of
Coal
RT212
I80
0 003c
0 0004c
wash water. dissolved acid gases generatmn gas, carbon dloxlde, chlorides
and oxygen, resullur dioxide,
Petroleum
IOO500
278
LO 0003a WLO 0003a
LO.OOOZa WL0.0003a
0.0002a
wash water, dissolved acid gases and oxygen, carbon dwnde. sulfur dwxlde trace, chtorldes trace. pressure 300 psb (bottom of tower1
Petroleum
125
211
electroplatmg waste, nickel, salts, phosphates, pH 2
chromium,
sodwm
Metal (plating)
70
105
(0
0001
<0.0001
WAX
wax, sulfuric I8 psi castor wax,
acid 5%
approximately.
pressure
15.
Petroleum
160. 190 180. 212 180. 212
25
0.02
0.014
sodium
hydroxide
SO%,
sulfuric acid
Chemical
25% castor wax. sodwm

25% hydroxide 50%. sulfuric acid Chemical F
0.0008 <0.0001
<0.0001
o.ooo9
thm stillage. sohds 4.5%. succimc aud. pH 3 8 gram and water mixture.
acetic
acid,
lactic
acid,
Brewing fwhiskyl Brewing
140. 185 110. 240
<o.o001
<o.ooo1
pH 5.8 (cooker1
(continued)
Ferrous
Alloys
607
TABLE
4.13:
VARIOUS
STAINLESS
ALLOYS-CLIMAX
MOLYBDENUM
(amtd)
Corrosion mediums
Test conditions
Average corrosion rates lipy)
TWE
TIPE
TPl
P-P-_
lactic 14%. acid, water, gram. pti 3 1 average Impurltles. total sohds Brewing f 60. 160 175 212 208 146 xx <0.0001
304
316
317
20
ALLOY
825
<0.0001
mixture 01 dlstdlers drmd grams syrup, sohds 40% 130% I syrup) vapors ol alcohol, orgamc
and
evaporator
Brewing
146
<0.0001
<0.0001
acids. water,
pli 5
Brewmg td~stdlat~on) Brewmg
87
xx
--
<o
0001
<0.0001
vapors from drymg solld syrup 30%. moisture. a~. traces of lack acetic, formic, prop~omc acids Ide. hydrator) vapors from evaporators to condensers. moisture. traces of lactic, formtc. prop~orw acids (vapor Ime, evaporator]
140. 180
151
O.OOOkd
<O.OOOlcd <0.0001
BleWlog
120. 200
146
<o
0001
<0.0001
XILENE
lwd xylene. small ph 3 appraxlmately
amounts
of water,
acetlc
acid.
Lumber
loo212 350 350
150
xx
<o 0001
0.0006 0.001 0.0003 0.0008 0.0018d <O.OOOl 0.0007 0.001
91.8%
98%
0 xylene, aromatlcs
o-xylene, water
1%
Rayon fbpll
f f
44 34
xx xx
xx xx
mixed condensate of xylene and water, small amount of acetlc acid. pH of aqueous phase 3 approximately
Lumber
70. MO 60
150
IX
<0.0001
15%.
tolulc
acetlc acid 2%. acid remamder
formic
acid 2%,
water
and
RayOn
22.5
<0.0001
0.001
75%. acetlc acad, toluic dehyde together 25% 50%. water 22%. ester 5%. phthahc
acid,
formic
acad. formal-
Rayllll
350. 370 ZOO220
22.5
0.0016
0.0014
tolulc acid acid 4%
15%.
phthallde
5%.
Rayon
225.
0.0004
0 0002
xylene. malelc acid I% as matelc zene, water trace Icotumnl
anhydrtde,
ben-
Chemical tdistdlation)
194. 302
14
0 104c
00031
0.0008
0 0074
0.0043
azeotroplc
mlxture
of xylene
and water
Rayon
80
460
xx
xx
0.0006
0.00045
xylene toppmg of reactor ettluent (effluent IS row lure 01 wter. acetic acid. benzolc acid. tolulc acad. tolualdehyde. acetophenone. hydrocarbons). vacuum 25 m. (column, vapors)
Chemical td~stdlatmn)
325. 350
a.7
0.148
0.00024
0.00043
00003
19.3% zmc-carbonate slurry, sodlum 10%. sulbdes, sullur~c acid, ptt 3
carbonate
70. 180
46
0.0001 <0.0001
c.0 0001
Chemical 33%. 5% ammomum apprarimataly. chlorwk 33%. water remainder Chemical Lumber twwd preserving)
160 140 140
27 33 144
0 032cd 0.0013cd <O.O001ad
0 032d <O.OOOlcd <0.0001ad
i1
F
sodium chromate
(continued)
608 TABLE

VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX MOLYBDENUM (contdb
Corrosion mediums
Test conditions
TYPE
NPE
,,PE
.
zinc and leadchloride (dust collector1 fumes. oil combustion gases Pamt and Varnish F
.
210
--4.5
*I
304
316
317
--
20
ALLOY
625
0.027a 0.027.a
0.013a
7JNC
FLOSILICA,E
3&30X
rpprutmately.
free Ruosilicic
acid 1%
Chemical
60. 80 lW116 106
70
IX
x xx
0.0024'a
09007
zinc fluosrlrcate sdwc acrd l%, zinc fluosdicate, acrdO050.1%
concentrated hydrochloric varying
solution, acid 0.5-l%
free
Ruo-
22.4
0.009c
co.012c
0.01 lc
concentration,
hydrochloric
Chemrcal
33
xx
0.0011
0.001
0.0915
ZINC FORhsALDEHVOE zinc formaldehyde acid l-15%
SLFOXLATE
sulfoxylate,
zinc
dust,
sulfuric
Textrle
115
25
xx
0.002
0.0904
saturated 44%
zincsulfate
solutron (evaporator) zmc-sulfate solutron.
Chemrcal Chemrcal
F F
B.P. 212. 225 IOO180
34 35
xx xx
0.006 corr*
00011 0.026a 0.006
CryStalS.
approximately, saturated sulfurrc acrd trace
36.30% ZlnC-Sulfate sdutmn sodrum brchromate, hydrogen peraxrde (flash evaporator) 36.5%. sullurrc acrd 66
bemg concentrated, peroxrde and lead
Chemrcal
48
xx
<0.0001
(0
0001
Be Ievaporator) and copper impurrties.
Chemical Chemical
F F
220 0.0097c
0.01 <O.OOOl <0.@301
0 0045 C<O.OOCl
0.0046
36%. iron, sodrum. cadmium, pH 5.2 (flash evaporator)
25% acrd zinc-sulfate solution, sulfuric g/l. copper 2 g/l. ferrous ion 0.8 g/l 25% neutral zmcsullate solution. copper
acid
2-3
Mining
90. 102 90. 103 61: 232 219. 232 125 150 90102 R.T.230
85
<0.0001
<0.0001
<0.0601 c<0.0001 <O.OoOl c<0.0001
0.4
g/l
Mining
72
<06001d
<0.0001
20%.
zmc chlorrde
8.8%.
ferrous
sulfate
1%.
water
Chemical
8.3
0.008lcd 0.008lcd 0.0026cd 0.0026cd I <O.OOOl
0.0047cd
20% approsnnatcly. mately. water rmc~sullate electrolyte,
zmc
chtorrde
9%
approxi-
Chemical
7.5
*I
0.0015bd
pH 3
Metal Iplating) copper Metal
31
I:
<O.OOOl
slrghtly
acrd zuwsutfate
solutron,
317
<O.OOOl
<O.OOOl
rmc sulfate, zmc chlorrde. ferrous sulfate, ferric sulfate, ferrrc chlorrde. chtorrde. water, in varying concentratrons (chlorinator) zmc-sulfate solution, copper 10 mglt. iron hydroxrde. zmc ferrrte. lead sulfate, solids grab samples showed pti 4 8 (Kelly filter) ztnc-sullate Z,RCON,U drrer fumes TETRACHLORtDE tetrachlorrde. hy-
Chemical
83
xx
xx
0.014cd
0.0033cd
Mming
113
48
xx
O.ooOl
0.0001
Chemical
110
31
xl:
0.0076bd 0.0068cd
0.0023ad 0.0004ad
CO.OOScd C0.0082cd
atmospherrc fumes of ruconurm drogen chlorrde. and chlorme gas
Chemical
60. 110
60
xx
0.0011
O.OOla
0.002
Nonferrous Metals and Alloys
TABLE 5.1:
ALUMINUM
ALLOY-ALCOA
Hydrogen Sulfide, on Aluminum Carbon Dioxide Alloys and Mild and Sulfur Steel Dioxide
Effect of
I
ALLOY HYDROGEN 2SH14 Aluminum ................. 3SH14 Aluminum ................. Mild Steel ........................ CARBON 2SH14 Aluminum.. 3S-H14 Aluminum.. Mild Steel.. . . . . .
Calculated
Volume of Metal bee ln.~/in.~/yr.~
1 Aqueous SULFIDE-%
Solutions HOURS
1 Moist Vapors
:i%:
.0117 DIOXIDE-96 HOURS
:Ef
,.0204
.. . .. . .. .. . ... . . . . . . . ..; . . . . . . 1 ... .. . ... .. . . . . .

SULFUR DIOXIDE-32 HOURS .0337 .0511 .5080
2SH14 Aluminum ................. 3S-H14 Aluminum ................. Mild Steel ........................
:E
45.oooos
NOTES: * Specimens .064 x .36 r 1.2 exposed to distilled water saturated with gas and also the gas saturated with moisture at room temperature. Daily cycle involved bubbling gas into water at 3 liters per hour for 8 hours and sealing the system off for 16 hours: s Test terminated after one hour because of rapid attack of metal. Resistance of Alumtnum Alloy 35 to Solid Chemicals Under Conditions of Hlgh Humldlty Non-Comoeire Ammonium dichromate Ammonium molybdate Ammonium nitrate Ammonium sulfate Barium carbonate Barium chloride Barium nitrate Borax Boric acid Calcium oxide Chromium trioxide Aluminum with 1.2% Mn. Citric acid Potassium thiocyanate Sodium acetate Sodium aluminum fluoride Sodium bicarbonate Sodium chlorate Sodium chloride Sodium nitrate Sodium sulfate Triphenyl phosphate
Border Line Ammonium chloride Ammonium fluoride Copper sulfate Ma rgt12 chloride ox&
Gxroeive
Aluminum chloride Calcjum chlpride Fom&ichlhlrlde rmanganate Sodium car E nate Sodium fluoride
NOTES:
I Shallow 2 diameter impact extruded containers of aluminum alloy 3s. s Chemicals placed in containers as a thin (rf) layer and as scattered aomll mounds. s Containerr exposed to an atmosphere having a relative humidity of approximately 100% room temperature for one month.
et
609
610
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
CORROSION RATE UNITS: The most commonly

accepted unit for expressing
metal is mils per year, abbreviated
the rate of corrosion of a mpy. One mil is
equal to 0.001. Resistant = less than 1 mpy attack Mild action = l-5 mpy attack Moderate action = 5-20 mpy attack Corrosive or corroded by = greater than 20 mpy
AL
ABIETIC ACID. Cz0H,,,02. Abietic acid has been handled extensively in aluminum alloy equipment. See also Ref: (1) p. 124, (2) p. 274, (3) p. 132, (7) p. 3. ACETALDEHYDE. CH,.CHO. In laboratory tests, 1100 alloy was resistant to aqueous rolutions of 0.1% to 100% acetaidehyde. Acetaldehyde has been produced and handled in aluminum alloy tubing. heat exchangers, stills, tankage and shipping drums. See also Ref: (I) p. 124. (2) p. I. (3) p. 120, (4) p. 73. (7) p. 3. ACETANILIDE. CH,.CO.NH.C,H,. Acetanilide has been produced in aluminum alloy equipment including tanks. pipes, valves, pumps, refiux condensers, vapor lines, heating coils, evaporators and reaction vessels. See also Ref: (I) p. 124. (3) p. 147. (7) p. 3. ACETIC ACID. CHJ.COOH. The effect of acetic acid on aluminum changes markedly with acid concentration and temperature. The rate of corrosion is low when exposed to acetic acid at all concentrations up to anhydrous glacial acetic acid below 50C (IZZ?F); at the boiling temperature of the acetic acid, aluminum is corroded in solutions up to about 90% concentration of the acid. when the attack falls off rapidly to less than 5 mils per year and the rate remains at that level until the anhydrous condition approaches. The corrosion rate of aluminum in glacial acetlc acid. uhich normally contains 0. I to 0.2% water. does not increase with temperature. Boiling anhydrous acetic acid is very corrosive to aluminum. Removal of the last trace of water increases the corrosion rate one hundred fold, while conversely the addition of 0.05% water stops the action. Aluminum has been used extensively in the manufacture of acetic acid, in its storage and handling. and in process equipment where acetic acid is one of the raw materials. In the manufacture of acetic acid from wood. the following aluminum alloys have been used: for storage tanks. alloys 1100. 3003, 5083. SOSZ: for stills, alloys 3003. 5052, hU61: for condensers. alloys 3003. 5052. 6061; for piping, alloys 1100. 3003. 6061; for ulves and fittings. alloys 356.0. 514.0; and for manholes. etc.. alloy 356.0. Alloys 1100.3003,5154, and 5052 have been the most commonly used for tanks and tank cars for storage of pure glacial acetic acid solutions at normnl temperatures. Aluminum alloys have been bed extensively in the textile industry for itorape fxiltties for xstic acid solutions down to 80% ioncentrations. although they are not recommended to rtore acid of Ins than 90% concentratism. Some tank failures have been reported by the textile industry in the storage of 80-84% acetic acid rolutions. Susceptibility of aluminum alloys to corrosive attack in acetic acid solutions is increased greatly by inorganic halides or reducing acids and reducing or-
ganic acids, esters and aldehydes normally encountered in the production and use of acetic acid. The presence of formic acid should be avoided. Potassium sulfate and bromide have no influence at ormal temperatures. but accelerate attack at elevated temperatures. Aluminum acetylation equtpment has been used I the cellulose acetate iwintry. Many large crornge tanks. tank can and shipping drums have been tired for handling acetic acid. See ~1s Ref: (I) p. 124. 12) pp. 3, 4. (3) pp. 21. 121. 136. 127. (4) pp. 22. 23. 24. 25, 27. 28. 29, 30. 31. 34. 61. h2. 64. 92, 1I I. (01 p. 20. (7, p. 3. ACETIC ANHYDRIDE. (CH,,CO):O. In limited laboratory tests. acetic snhydride caused moderate (I3 mpy) attack of 3003 alloy at IOOC (212F). in other tests, acetic anhydride caused mild attack of II00 alloy at ambient temperature and at 50C (122F). Acetic anhydride had mild action (-5 mpy) at the boiling point. Aluminum and Its alloys have been used for heat exchangers, reaction vessels, piping, storagetanks, drums and tank cars for handling acetic anhydride. Alloy A356.0 valves have been used for handling acetic anhydride. See also Ref: (I) p. 124. (2) p. 13. (3) p. 128, (7) p. 5. ACETONE. CH.CO.CHJ. Aluminum and AI-.Mg alloys are resistant to acetone in laboratory tests at all temperatures. Aluminum has been used with acetone for piping, (tills. heat exchangers and storage. Mild corroGon has been reported in an aluminum rtorage tJ.nk for redistilled acetone. Alloy 356.0 va!~es have been used for handlmg acetone. See also Ref: (I) p. 124. (2) p. 17. (3) pp. 121, 242. (7) p. 5. ACETONITRILE. CH,.CN. Alloy 3003 was resistant to acetonitrile at 100C (212F) in laboratory beaker tests. See also Ref: (3) p. 142. (5) p. 9. ACETOPHENONE, ORTHOHYDROXY. CH,COC,H,OH. Limited laboratory tests indicated that acetophenone was mildly corrosive to 3003 alloy under refluxing or boiling and condensing conditions. See also Ref: (1) p. 124, (2) p. 20. (3) p. 121. (7) p. 7. p-ACETOTOLUIDIDE. CH,CONHC,H&H,. Acetotoluidide has been distilled and handled in aluminum alloy equipment. See also Ref: (3) p. 144. (7) p. 7. ACETYLSALICYLIC ACID. CH,.CO.OC,H,COOH. In the production of acetylsalicylic acid, the raw materials, acetic anhydride and salicylic acid, and the final product have been handled in aluminum alloy storage tanks. piping and reaction vessels. See also Ref: (2) p. 26, (3) p. 130. (5) p. 9. (7) p. 7. ACONITIC ACID. C,H,(COOH),. In limited laboratory tests, aqueous solutions of aconitic acid (0.25% to 50%) caused moderate attack (-6 mpy) of 3003 alloy at IOOC (212F). See also Ref: (10) p. 77.
alloy Aluminum ACROLEIN. CH?: CHCHO. equipment has been used in the manufacture and shipment of acrolein. See also Ref: (I) p. 124. (3) p. 120. ACRYLIC ACID. CH?:CHCOOH. Alloys 3003. SOSZ. and 5454 were resistant to glacial acrylic acld at ambient conditions. Glacial acrylic Acid has been shipped in aluminum alloy drums. See also Ref: (I) p. 124. (3) p. 128. (5) p. 9. (7) p. 7. ACRYLONITRILE. CH?:CHCN. In laboratory tests. alloy 3003 uu resistant to acrylonltrilr. acrylonitrile saturated uith water and water raturated with acrylonitrile at room temperature and u hen exposed to boiling acrylonitrile. Aluminum alloy industrial equipment has been used for the prodoction and shipment of acrylonitrile and ~15 in further transforming it into acr)lonitr!le fiber. See also Ref: (I, p. 124. (3) pp. 112. 233. (1 p. -. ADIPIC ACID. HO,C(CHz)KO!H. ln iclborntory tests, adiplc acid in 20% nod SOW,> concentrations caused mild attack of alloy 3003. The acid and its salts have been piped, rhipped and stored m Jlumiurn. See also Ref: (3) p. 130. () p. 7. AEROSOLS. A generic term applied to pxkc of various liquid products under pressure. .ilum~num alloy cans have been used to package aerosol formulations. See also Ref: (3) pp. I IO. 239. ALDOL. CH,.CH(OH).CH2.CH0. In laboratory rests. 3003 and 1100 alloys were resistanr to aldol at 100C (212F) but at the boiling point alloy 3003 was mildly attacked (4 mpy). Aldol has been handled and shipped in aluminum alloy containers. See also Ref: (3) p. 121. ALKALINE SOLUTIONS. Alkaline solutions generally have some action on aluminum alloys. The pH of these solutions alone is not a reliable indicator of the performance of aluminum alloys. Usually. weak bases such as ammonium hydroxide, hexamine, alkanolamines and their aqueous solutions can be handled in aluminum because a protective film forms on aluminum after an initial period of reaction. Solutions made alkaline by hydrolysis of basic salts such as sodium carbonate form protective films on AI-Mg alloys containing 3.5% or more magnesium. Strong bases such as sodium hydroxide and potassium hydroxide dissolved in water are very corrosive and should not be handled in aluminum. See also Ref: (4) pp. 35. 37. ALKYL SODIUM SULFATE. RSO,Na. Alkyl sodium sulfates have been stored in aluminum alloy containers. See also Ref: (3) p. 246. ALLYL ALCOHOL. CH>:CHCH?OH. In laboratory tests under refluxing conditions. 3003 alloy was resistant to ally1 alcohol. See also Ref: (3) pp. 22. 114. (5) p. 10. (7) p. 9.
(continued)
611
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
dicated that alloy 3003 was resistant to 1%. 5% and 50% aqueous solutions of ammonium carbonate. Aluminum alloy storage tanks and piping have been used for handling ammonium carbonate. See also Ref: (I) p. 125, (3) p. 67. (7) p. 15. AMMONIUM CHLORIDE. NH,CI. In laboratory tests at ambient temperature, aqueous solutions (up to 20%) of ammonium chloride caused mild attack ( - 3 mpy) on 1100 alloy with localized pitting occurring at all concentrations. Solid ammonium chloride resulted in moderate attack ( - 6 mpy) on alloy 3003 in other laboratory tests under conditions of 100% relative humidity at ambient temperature. Concentrated solutions of ammonium chloride at the boiling point are very corrosive. See also Ref: (I) p. 125. (2) p. 50. (3) p. 62. (7) p. 15. AMMONIUM DICHROMATE. (NH,)&r?O-. Alloy 3003 was resistanr to solid ammonium dichromate in laboratory tests under conditions of 100% relative humidity at ambient temperature. Similar results were obtained in other laboratory tests involving aqueous solutions (up to IO%) of ammonium dichromate at ambient :empcrature. See alto Ref: (I) p. 125. (3) p. 0. (71 p. 17. AMMONIUM FLUORIDE. NH,F. In laboratory tests, solid ammonium fluoride caused mild attack (-3 mpg) of alloy 3003 under conditions of 100% relative humidity at ambient temperature. In other laboratory tests. 505 solutions of ammonium fluoride uere very corrwi\e co alloy 3003 dt 93C (ZOOF), but at ambient temperature. II00 alloy was resistant to solutions of 10% to 25%. See also Ref: (I) p. 125. (3) p. 63. (7) p. 17. AMMONIUM HYDROXIDE. NH,OH. In laboratory tests, ammonium hydroxide solutions have a rapid initial reaction on aluminum alloys which decreased dramatically as concentration and pH increase. The rate of attack of dilute ammonium hy droxide solutions was moderate ( - 6 mpy) for 1100 alloy but decreased to less than 1 mpy when the concentration reached 10 N. Similarly, the rate was mild (- 2 mpy) as the pH of the solutions reached 13. These decreases have been attributed to film formation on aluminum alloys which has been promoted by pre-saturation of the solution with aluminum. It has also been retarded or prevented by the presence of precipitation resulting from over saturation. Alumin~lm alloys have been used in processing equipment. including pressure vessels, piping. storage tanks and tank cars. See also Ref: (I) p. 125. (3) pp. 43, 58. 61. (4) pp. 34. 35. 36, 37. 69 (7) p. 17. AMMONIUM IODIDE. NHJ. Solid ammonium iodide caused mild attack (- 2 mpy) of 3003 alloy and mild attack (-4 mpy) with blistering of alloy 5154 in laboratory tests conducted under conditions of 100% relative hun idity at ambient temperature. See also. Ref: (3) p. 63. AMMONIUM LACTATE. NH,C,HjO,. In laboratory tests at amb;ent temperature. 30% and 30% aqueous solutiors of ammonium lactate caused mild attack ( - 5 mpy) on alloy 3003. while at boiling temperature. 30% solutions were very corrosive. See also Ref: (3) p. 71. AMMONIUM MOLYBDATE. (NHJzMoO,. Alloy 3003 was resistant to solid ammonium molybdate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (7) pp. 16, 17. AMMONIUM NITRATE. NH,NO,. See also AMMONIUM NITRATE (AMMONIATED). In laboratory tests. alloy 3003 was found to be resistant to
ALLYL ISOTHIOCYANATE. CH,:CHCH,NCS. Aluminum alloy columns and condensers have been used lo the production of all)1 isothiocyanate. See also Ref: (3) p. 138. ALUMINA. AI?O,. Alumina has been stored in aluminum alloy containers and shipped in aluminum alloy railroad cars. See also Ref: (3) p, 77. (4) p. 5. ALUMINUM ACETATE. AI,C~H,OzlI. In limited laboratory tests. aqueous solutions of aluminum acetate (0.2Svn to 25%) cauwd mild attack ( - 3 mpy) of alloy 3003 at ambient temperature. ,Aluminum alloy equipment has been used in the manufacture of aluminum acetate. See also Ref: (I) p, 124, (3) p. 78. 15) p. IO. () p. 9. ALUMINUM AMMONIUM SULFATE. AINH,,SO,):. I2 H!O. Laboratory tests \howed that dlloys 3003 md 5154 were re*i(tdnt to solId aluminum an?nwnlum \ulfare under conditions of 100% relat~w humidity at amtvent temperature. ALUMINUM BORATE. 2 AI>O,.B,OJ.~ Laboratory tests showed that alloys 3003 and were resistant to solid aluminum borate under ditions of 100% relative humidity at ambient perature. HKJ. 5154 contem-
per industry. Alloy 356.0 valves have been used for handling aluminum sulfate solutions. See also Ref: (1) p. 125, (2) p. 42. (3) p. 77, (7) p. Il. ALUMINUM TABTRATE. AIJ(CIHIO,),. Laboratory tests indicated that alloys 3003 and 5154 were resistant to solid aluminum tartrate under conditions of 100% relative humidity at ambient temperature. 2-AMINOETHANOL. NHzCHICHzOH. See monoethanolamine. See also Ref: (3) p. 145. AMINOETIIYLETHANOLAMINE. NH,CH,CH~NHCH,CH,OH. In laboratory tests, 3003 alloy was resistant to aminoethylethanolamine at temperatures from ambient to 204OC (40f~F). In other laboratory tests under refluxing conditions, aminoethylethanolamine was very corrosive to alloy 3003. Aluminum alloy tanks have been used to store aminoethylethanolamine. See also Ref: (7) pp. 12, 13. AMMONIA. NH,. (See also ammonium hydroxide) In laboratory tests. 1100, 3003 and other copper free aluminum alloys have been found to be resistant to dry, gaseous ammonia even at elevated temperatures. Alloys 1100 and 3003 were also resistant to pure anhydrous liquid ammonia but contaminants can result in pitting of the metal. In dilute ammonia solutions (up to - 10%) the initial rate of attack is controlled by diffusion of OH- ions to the aluminum surface and is a function of pH. Passivation of the aluminum surface occurs when a critical amount of corrosion product builds up at the aluminum surface forming a protective film. If solution saturation of soluble corrosion product is relieved before passivation. film formation may not occur. A careful analysis of exposure conditions is required in using aluminum alloys in dilute ammonia. Aluminum alloys have been used in refrigeration systems handling liquid ammonia containing up to 5% water and in producing synthetic ammonia. Aluminum alloy compressors. heat exchangers. evaporators. condensers. and piping have been used in producing ammonia. Aluminum alloy pressure vessels have been used for storing and tranrponing ammonia. Carbon dioxide and hydrogen sulfide have been used to inhibit corrosion under condensing conditions. See Ref: (1) p. 125. (2) p. 46, (3) pp. 43, S8. 61. 223, (7) p. 14. AMMONIUM ACETATE. CH,COONH,. Solid ammonium acetate caused mild attack ( - 3 mpy) of alloys 3003 and 5154 in laboratory tests conducted under conditions of 100% relative hunvdiry at ambient temperature. In other laboratory tests. I, 5 and 10% solutions of ammonium acetate at ambient temperature caused mild attack of 3003 alloy while the alloy was resistant to concentrated solutions. Dry ammonium acetate has been stored and transported in aluminum alloy containers. See also Ref: (1) p. 125, (3) p. 71. (5) p. 11. (7) p. 1.5. AMMONIUM BICARBONATE. NH,HCO,. Aluminum alloy equipment has been used in the production of ammonium bicarbonate. See also Ref: (1) p. 125. (3) p. 67. (5) p. 11. (7) p. 15. AMMONIUM CARBAMATE. NHzCOO.NH,. Ammonium carbamate has been produced and handled in aluminum alloy equipment, including tanks, piping and subliming equipment. See also Ref: (1) p. 125, (3) p. 68. AMMONIUM CARBONATE. (NH,)&O,. Solid ammonium carbonate caused mild attack (-2 mpy) on 5154 alloy Hhile 3003 alloy was resistant to solid ammonium carbonate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Other laboratory tests in-
ALUMINUM CHLORIDE. AICI,. Anhydrous aluminum chloride has been stored and transported in aluminum alloy containers. Moist aluminum chloride and aluminum chloride solutions are vety COP rosive to aluminum alloys. The severity of attack depends upon the quantity of free hydrochloric acid produced by hydrolysis and on the temperature. See also Ref: (I) p. 125. (2) p. 37. (3) p. 77. (7) p. 11. ALUMINUM FLUORIDE. AIF,. Laboratory tests showed that alloys 3003 and 5154 were reSiStant to solid aluminum fluoride under conditions of 100% relative humidity at ambient temperature. Aluminum fluoride solutions are corrosive to aluminum. See also~Ref: (3) p. 77, (7) p. 1 I. ALUMINUM FORMATE. AI(HC02),. Laboratory tests indicated that 1% and IO% solutions of aluminum formate caused highly localized attack of alloy 1100 at ambient temperature. However, aluminum equipment has been used successfully in the production of aluminum formate. See also Ref: (I) p. 125, (3) p. 78. ALUMINUM NITRATE. AI(N0,),.9 H*O. Solid aluminum nitrate was corrosive (50 mpy) to 3003 and 5154 alloys in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Aluminum nitrate has been stored and shipped in aluminum alloy containers. See also Ref: (I) p. 125, (3) p. 78. (7) p. 11. ALUMINUM OXALATE. AIJ(C?OJ),.H~O. Laboratory tests indicated that alloys 3003 and 5154 were resistant to solid aluminum oxalate under conditions of 100% relative humidity at ambient temperature. ALUMINUM STEARATE. AI(C,,HJ5.02),. Laboratory tests indicated that alloys 3003 and 5154 wre resistant to solid aluminum rtearate under conditions of 100% relative humidity at ambient temperature. ALUMINUM SULFATE. Al?(SO,),. 18 H>O. Laboratory tests showed that alloys 3003 and 5154 were rewtant to solid aluminum sulfate under conditions of 100% te!ative humidity at ambient temperature. Laboratory tests made in aqueous solutions indi. cated mild action on alloy 1100 by solutions of .Ol% to 25% aluminum sulfate. Aluminum piping has been used fur aluminum sulfate solutions in the pa-
(continued)
612
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
Aluminum
ASSOCIATION
(continued)
sol. (chlorophenoxy) acetic acid, copper oxychloride (0.5% Max.) and calcium polysulfides. In laboratory tests most insecticides were corrosive to aluminum alloys. See also Ref: (IO) p. 101. APPLE BRINE. Limited laboratory tests indicated that 5052 alloy was resistant to apple brine at 100C (212F). AQUA REGlA. A mixture of nitric and hydrochloric acid. In laboratory tests, aqua regia was very corrosive to all aluminum alloys. See aiso Ref: (2) p. 80, (3) p. 38. ARGON. A. Aluminum alloys have been used For pressure vessels and containers handling argon. See also Ref: (3) p. 35. ARSENIC ACID. H,AsO,. In limited laboratory tests, concentrated arsenic acid *as very corrosive to 6061 alloy at ambient temperature. See also Ref: (3) p. 49, (7) p. 25. ARSENIC TRIOXIDE. As,O,. Alloys 3003 and 5154 were resistant to solid arsenic trioxide in laboratorv tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (3) p. 49. (7) p. 25. ASBESTOS. Laboratory tests have shown that wet asbestos will cause corrosion when in intimate contact with all aluminum alloys. This has been confirmed by service experience. Dry asbestos does not cause corrosion of aluminum alloys. See also Ref: (I) p. 126. (5) p. 12. ASPARTIC ACID. HOOC.CH2CH(NHI).CDDH. In limited laboratory tests, alloy 3003 was resistant to aspanic acid at 204C (4M)F). See also Ref: (I) p. 126. (3) p. 146, (7) p. 25. ASPHALT. Bituminous substances From petroleum or purified tar. Aluminum alloy piping and tankers have been used For handling asphalt. See also Ref: (1) p. 126. (3) p. 221. ASPIRIN. CH,COOC,H,COOH. Aluminum alloys have been used in reaction and crystallization equipment for the preparation of aspirin. See also Ref: (2) p. 26. (3) pp. 130. 239. ATMOSPHERES. Most aluminum alloys have resisted atmospheric weathering in laboratory controlled tests and have been widely used For architectural and structural purposes. The earliest known example of aluminum exposed to the weather is the cap piece on the well-known Washington Monument erected in 1884. That 100 ounce casting was examined in 1934 and again in 1964. Both examinations confirmed the resistance to weathering of the cap, as evidenced by the legibility of the original engraved inscriptions. The earliest known use of aluminum sheet For a roof is Found on the St. Cioacchino church in Rome. Italy. Installed in 1897. examination after 70 years disclosed a measured corrosion depth of 0.06 mm (2.5 mils) average. A number of applications of aluminum For electrical power cables began early in the present century and continue in use today. An early stranded aluminum power cable in service near Hartford, CT, For 51 years. exhibited an average measured corrosion depth of 0.109 mm (4.3 mils). Aluminum castings have been used For thousands of spandrel panels on many buildings such as those in the Radio City complex completed during 1432 in New York and the Koppers Building completed during 1929 m Pittsburgh. pleted PA. The Empire State Building during 1929 in New York City applied also comhad about
dry ammonium nitrate at ambient temperature and to aqueous solutions of ammonium nitrate at ambiznt and elevated temperatures (up to 18OF). Ammonium nitrate solutions used mainly for fertilizers, have been produced. piped and stored in aluminum alloy tank cars in concentrations up to 83% by weight and at rempcratures up to 12 I C (250F). In the hot 83% solution. corrosion can be stimulated particularly at welds by the presence of Free nitric acid. To avoid this, the pH of the hot solution should be maintained above 6 and rhe solutigln agitated to maintain d uniform pH. Welded 3003 alloy is more tolerant of these acidic conditions and has been used For tank bottoms and piping. Mercury contamination can also be a serious problem in ammonium nitrate service and must be avoided. Roofing, siding, and prilling towers have been used in ammonium nitrate plants. See also Ref: (1) p. 125. (2) p. 55. (3) p. 66. (7) p. 17. AMMONIUM NITRATE (AMMONIATED). Ammoniated solutions of ammonium nitrate have been shipped, stored, and handled in aluminum alloyequipment. See also Ref: (1) p. 125. (2) p. 55. (3) p. 66.
alloys have been used For piping, coolers and tanks with ammonium sulfide. See also Ref: (I) p. 125. (3) p. 63. (7) p. 19.
AMMONIUM TH~OCYANATE. NH,SCN. AIIO~S 3003 and 5154 were resistant to solid ammonium
thiocyanate conditions temperature. of in laboratory 100% In other relative tests conducted under humidity at ambient
laboratory
tests, alloys 3003,
5052 and 6061 were resistant to 1. 25 and 50% solutions of ammonium thiocyanate at ambient temperature. Ref: (I) Aluminum alloy tanks and piping thiocyanate. have been See also used to handle ammonium
p. 126, (2) p. 66. (3) p. 69, (7) p. 19.
THIOGLYCOLATE. HSCH&OONHI. Ammonium thioglycolate has been handled and shipped in aluminum alloy containers. See also Ref: (3) p. 71.
AMMONIUM
AMMONIUM OXALATE. (NH&C20,.Hz0. Solid ammonium oxalate caused mild attack ( - 2 mpy) of 3003 alloy in laboratory tests conducted un- AMYL ACETATE. CHJ(CH1)lOOCCH,. In laboder conditions of 100% relative humidity at ambient ratory tests, alloys 3003 and 5052 were resistant to temperature. In other laboratory tests, 1% solution amyl acetate at temperatures up to 204C (4OOOF). of ammonium oxalate at ambient temperature In other laboratory tests, condensing amyl acetate caused mild attack ( -3 mpy) and 4% solution was caused mild attack ( - 3 mpy) of alloy 3003. Pure corrosive to alloy 3003; while at the boiling temperaamyl acetate has been stored in aluminum alloy ture. 1% solution was very corrosive. See also Ref: tanks. See also Ref: (1) p. 126, (2) p. 68. (3) p. 136. (I) p. 125. (3) p. 71. (7) p. 17. (7) p. 19. AMMONIUM PERCHLORATE. NH,CIO,. Aluminum alloy equipment has been used For producing and handling ammonium perchlorate. See also Ref: (3) p. 63, (7) p. 17. A,MMONlUM PERSULFATE. (NH,),StOn. Alloys 3003 and 5154 were resistant to solid ammonium persulfate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (I) p. 125. (2) p. 58, (3) p. b5. (7) p. 17. AMMONlUM PHOSPHATE. Monobasic NH,H,PO,. Dibasic (NH&HPO+ The action of ammonium phosphates on aluminum is a Function of both the concentration and the temperature. Solutions of the monobasic salt are less corrosive than are solutions of the dibasic salt and the rate of attack decreases with time. Laboratory tests showed that solutions of the monobasic salt up to 28% caused moderate attack (- 10 mpy) on alloy 3003. Solutions of the diammonium talt are corrosive to aluminum alloys and should not be used with aluminum equipment unless inhibitors are employed. See also Ref: (I) p. 125. (2) p. 60. AMMONIUM SULFAMATE. NH,SO,NHz. Laboratory tests indicated that II00 alloy was resistant to aqueous solutions of ammonium sulfamate at ambient temperature. See also Ref: (7) pp. 17. 18. AM,MONlUM SGLFATE. (NH&SO,. In laboratory tests, alloy 3003 was resistant to solid ammonium sulfate under conditions of 100% relative humidity at ambient temperature. Other laboratory
tests showed
45%
AMMONIUM THIOSULFATE. (NH,),S,O,. Laboratory tests showed that alloy 3003 was resistant to aqueous solutions of ammonium thiosulfate at ambient temperature. Aqueous ammonium thiosulfate solutions have been shipped in aluminum drums. See also Ref: (3) p. 65. (7) p. 19.
AJMYL ALCOHOL. CH,(CH,),OH. Limited laboratory tests indicated that alloy 3003 war resistant to amyl alcohol at 100C (212F). Amyl alcohol war very corrosive to 204C (JO03F) and at the boiling point. Aluminum alloys have been used to handle amyl alcohol. See also Ref: (2) p. 71, (3) p. 113, (7) p. 21. AMYL .MERCAPTAN. CH,(CH2),SH. Amyl mercaptan has been stored in aluminum alloy tanks. See alu, Ref: (3) p. 133. (7) p. 21. AMYL
Laboratory
VALERATE.
tests indicated amyl
(CH,),CHCH2COOCsH,,.
that 1100 alloy was resistat ambient temin aluminum valerate
ant to concentrated
perature. Amy1 valerate is handled containers. See also Ref: (7) pp. 20.
21.
ANILINE. C,HsNH,. Laboratory tests indicated that 1 LOO alloy was resistant to aniline vapors at ambient and 75C (167F) temperatures. However, concentrated solutions of aniline were corrosive to 1100 alloy at the boiling Point 184C (364OF). Aluminum alloy equipment has been used in procesru involving aniline. See also Rcf: (1) p. 126. (2) p. 73, (3) p. 144, (7) p. 21. ANISE OIL. Aluminum alloy tanks have been used for storing anise oil. See also Ref: (8) p. 12.5. ANTIFREEZE SOLUTIONS. Water Solutions of Methyl Alcohol, Glycerin or Glycol. Laboratory tests have shown that alloys I100 and 3003 were resistant to many commercial antifreeze solutions. In automotive applications, the antifreeze solution must be maintained at the proper concentration in order that sufficient inhibitor is present to prevent deposition corrosion by heavy metal ions picked up From dissimilar metals in the system. Aluminum alloys have been used for automotive radiators and heat exchangers. See also Ref: (I) p. 126. (3) pp. 23. 114, 115. 136.240. ANTIPESTICIDES, INSECTICIDES. Dinitrocre-
that
1100 alloy
sulfate.
was resistant
to 1% to
solutions
of ammonium
Aluminum alloys
temperature. handling
sulfate at ambient have been used for See also Ref: FF) p.
ammonium
125. (2) p. 62, (3) p. 64, (7) p. 19.
AMMONIUM
tests. 1100 alloy
SULFIDE. (NH,)*S. In laboratory

was resistant sulfide to 15% to 40%
SOlU-
gZS.OW pounds of aluminum
to its exterior.
tions of ammonium
at ambient
temperature.
(continued)

ALUMINUM ALLOYS-ALUMINUM
during 1930 m
ExamiButld-
613
TABLE 5.2:
Milwulkee. niltmn
ASSOCIATION
hminued)
contamers have been used for storing and transponing beryllium chloride. See also Ref: (2) p. 102. (3) p. 73. (7) p. 35. BISMUTH NITRATE. Bi(NO,),S H,O. Alloys 3003 and 5154 were resistant to solid bismuth nitrate in laboratov tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (8) p. 106. BITUMINOUS PAINT. Laboratory tests have shown that bituminous paint is protective to aluminum alloys. See also Ref: (I) p. 127, (3) pp. 218.221. (4) p. 141. BLACKBERRY NICE. In laboratory tests. blackberry pomace and juice mixture was corrosive to 3003 alloy at 100C (212F). See also Ref: (4) pp. 88. 89. BORDEAUX MIXTURE. A mixture of cupric sulfate, calcium oxide. and water. Aluminum alloy equipment has been used to handle Bordeaux mixture. See also Ref: (1) p. 127. BORIC ACID. H.,BO,. Alloys 3003 and 5154 were resistant to solid boric acid in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, alloys 1100. 3003 and 6061 were resistant to aqueous solutions (I-IS%) of boric acid at ambient temperature and at 60C (14OF). Aluminum alloy drying kilns, trays, conveyors. hoods, tanks and valves have been used for handling boric acid. See also Ref: (1) p. 127, (2) p. 108, (3) p. 51, (4) pp. 123, 124, 125. (7) p. 35. BORON TIUFLUORIDE. BF1. Aluminum alloy reactors have been used in the manufacture of naphthalene in which boron trifluoride is used as a catalyst. See also Ref: (1) p. 127, (3) p. 51, (7) p. 37. BOROSILICATES. In laboratory tests. 3003 alloy was resistant to borosilicate glass wool under conditions of 100% relative humidity al 52C (125F). See also Ref: (10) pp. 29, 108. BROMOFORM. CHBr,. In limited laboratory tests, bromoform was corrosive to aluminum alloys with the attack being accelerated as the temperature increased. Inhibitors such as amines have promise of reducing the attack to some degree. CAUTION: See Halogenated Hydrocarbons. See also Ref: (1) p, 128. (3) pp. 23, 106. (7) p. 37. BROMOMETHANE. CH,Br. In limited laboratory tests, bromomethane was very corrosive to high purity aluminum at 50C (122F). See also Ref: (3) p. 105. BULK (DRY) MATERIALS. Aluminum alloys have been used to handle a wide variety of materials in bins. cars. drums and wrappings. Listed below are some examples of these materials. See also Ref: (6) pp. 10, 11. 12. Flour Sugar Synthetic detergents Soap flakes Cocoa Instant coffee Phosphorus Cement Whiting Ethycel Salt suspensions
The A. 0. Smith Bulldmg completed

Wisconsin. curtain ner of aluminum mg disclosed
may hdve been the forerunwall corwruction. the Smith
iu 1962 of a cast panel from average
measured depth of attack to be 0.053 mm (2.1 mils) in the 6.35 mm (250 mils) thick metal. Aluminum residential roof shingles were marketed beginning in 1928 and examination of such a roof after 30 years in an industrial atmosphere revealed an average depth of corrosion pmetration of 0.076 mm (3.0 mils) in the 0.508 mm (20 mils) thick 3003 alloy sheet. Since 1930. many applications of aluminum roofing and siding have been made throughout the world. Alclad aluminum industrial roofing and siding have been used for many years in a wide variety of highly industrial atmospheres. Corrosion depth is arrested at the claddingcore interface under the effect of cathodic protection by the 1% zinc-bearing aluminum alloy cladding. Port facilities throughout the nation have used large quantities of those alclad aluminum sheet products for transit sheds, storage buildings and the like. Literally hundreds of studies have been made on aluminum alloys after service for many years in industrial and seacoast localities.
num alloys have been used for fermenters, yeast tubs. culture tanks, carbonating tanks, coolers, storage tanks. beer kegs and other containers. Aluminum alloys have also been used for wart receiving and settling vessels and filtering apparatus. Aluminum alloy beer cans are coated internally. See also Ref: (I) p. 127. (3) p. 202. (4) pp. 94, 95, %. 97, 128, (6) p. 10. BEESWAX. Conrainr about 8@G myricin. Beesuax ha> been used as a prorecti\e coating for alummum allo! strw corrouon cracking test fixtures. See also Ref: (I) p. 127. (3) p. 225. BENZALDEHYDE. C,,H;CHO. In laborator) tests. alloys 3003. 5052 and 51.54 uere resistant to benzaldeh\de at 5OC (122F) and 2WC (400 F). Under boiling and condensing conditions, benzaldehyde caused moderate attack u-lth localized pnting (- 8 mpy). In other laboratory tests. the addition of water to brnzaldehyde caused moderate corrosion with the maximum attack (- I2 mpy) of 1100 allo! developing at about a IO?& mixture of benzaldehyde in water. Aluminum alloy drums and tanks, dinillation columns. condensers and dephlegmators have been used to handle pure henzaldehyde. See also Ref: (1) p. 127. (2) p. 87. (3) p. 120. (7) p. 27. BENZENE. C,&,. In laboratory tests. alloys 3003. 5052,5l.S4 and 6&l were resistant to benzene at ambient and SOY (122F) temperatures. The addition of moisture increases the corrosivity of benzene towards aluminum alloy\. Aluminum equipment has been used for stills, fractionators, dephlegmators. condensers. tanks and heat exchangers for benzene. See also Ref: (I) p. 127. (2) p. 90. (3) pp. 104. 223. 242, (7) p. 31. BENZENE HEXACHLORIDE. C,H,CI,. Aluminum allob equipment has been used in handling benzene hexachloride. CAUTION: see Halogenated Hydrocarbons. See also Ref: (3) p. 110, (7) p. 31. BENZ& C,HrCOCOC,Hs. In limited laboratory tests. alloy 3003 was resistant to benzil at 204C (400F). Localized pitting was evidenced on the 3003. See also Ref: (3) p. 121. (7) p. 31. BENZOIC ACID. C,H:,COOH. Alloys 3003 and 5154 were resistant to solid benzoic acid in laboratory tests under conditions of 100% relative humidity at ambient temperature. Aluminum alloy sublimating equipment. hoppers and piping have been used in the production of benzoic acid. See also Ref: (1) p. 127, (2) p. 96, (3) p. 132. (7) p. 29.
B
BARIUM CARBONATE. BaCO,. Allo) 3003 uas resistant to solid barium carbonate in laboratory tests conducted under conditions of IOOYGrelative humldity at amhient temperature. See also Ref: (3) p. 76, (7) p. 27. BARIUM CHLORIDE. B&I,.2 H20. Alloy 3003 was resistant to solid barium chloride in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests. 1100 alloy was resistant to 0.001 to 0.4 N solutions of barium chloride at ambient temperature. See also Rcf: (I) p. 127, (2) p. 84. (3) p. 73, (7) p. 27. BARIUM HYDROXIDE. Ba(OH),.B H,O. Laboratory tests have shown that aqueous solutions of barium hydroxide are very corrosive to aluminum alloys. Aluminum alloys are not ordinarily used with barium hydroxide solutions. See also Ref: (1) p. 127. (3) p. 72, (7) p. 27.
BARIUM NITRATE. Ba(N0J2. Alloy 3003 was resistant to solid barium nitrate in laboratory tests under conditions of 100% relative humidity at am- BENZOYI. CHLORIDE. C,HJOCI. Limited labbient temperature. In other laboratory tests. 1100 oratory tests indicate that benzoyl chloride is cormalloy was resistant to dilute aqueous solution of sive to high purity aluminum at boiling temperature barium nitrate at ambient temperature. See also Rel: 198C (388F). CAUTION: See Halogenated Hy(3) p. 75, (7) p. 27. drocarbons. See al5o Ref: (1) p. 127, (3) p. 133. BmM SULFIDE. BaS. In limited laboratory tests, a 10% aqueous solution of barium sulfide was corrosive to 3003 alloy at ambient temperature and at 50C (122F). See also Ref: (3) p. 74. (7) p. 27. BAUXITE. Ore of aluminum. containing a high content of hydrated aluminum oxide together with lesser amounts of oxides of iron. silicon and titanium and some minor impurities. Aluminum alloys have been used for transporting bauxite and as building components in bauxite plants. See also Ref: (8) pp. loo. 190. BEANS. Beans have been canned in coated aluminum alloy cans. See also Ref: (6) p. Il. BEER. Laboratory tests have shown that beer causes mild attack of most aluminum alloys and even less of high purity aluminum. In the brewing of beer, alumiBENZYL ACETATE. C,H,CH,OOCCH,. In laboratory tests, alloy 3003 was resistant to benzyl acetate at 1005C (212F) but was corroded under boiling and condensing conditions.
BENZYL ALCOHOL. C,H,CH,OH. In laboratory tests. alloy 3003 was resistant to benzyl alcohol at 2O4C (4OOF) and under refluxing conditions. Benzyl alcohol has heen handled in aluminum alloy tanks. See also Ref: (3) p. 113, (7) p. 33. BENZYL CHLORIDE. C,H:,CHICI. High purity aluminum was resistant to benzyl chloride in lahoratory tests at ambient temperature. Benzyl chloride caused corrosion of other alloys, increasing as temperature increased. CAUTION: See Halogenated Hydrocarbons. See also Ref: (2) p. 100. (3) p. I I I, (7) p. 33.
IJ-BUTADIENE. CHz:(CH)z:CH,.This product has been stored and transported in aluminum alloy equipment. See also Ref: (3) p. 103. BUTANE. CH,(CH,),CH,. Aluminum alloy pipe and tube have been used to handle butane. See also Ref: (I) p. 128. (3) p. 214. (7) p. 39. BUTTER. Aluminum alloy equipment has been
BERYLLIUM CHLORIDE.
BeCl,. Aluminum
aIloy
(continued)
614
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
CALCIUM NITRATE. CalNO,)?. In laboratory tests. alloy 3003 was resistant to aqueous solutions (l-50%) of calcium nitrate at ambient temperature. See also Ref: (1) p. 128, (3) p. 75. (7) p. 47. CALCIUM OXIDE. GO. Alloy 3003 was resistant to solid calcium oxide in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In the presence of liquid water. calcium hydroxide is formed. leading to the formation of protective films on the aluminum surface (see CALCIUM HYDROXIDE). See also Ref: (1) p. 128. (31 p. 72, (7) p. 49. CALCIUM PROPIONATE. Ca(CH,. CHz. COO)>. Calcium propionate has been stored in aluminum alloy tanks. See also Ref: (3) p, 77. CALCIUM SILICATE. Ca,SiO,(OR 3 CaO. SiO,). Aluminum alloy driers have been used with calcium silicate. See also Ref: (3) p. 76. (7) p. 49. CAMPHOR. C,,H,,O. Aluminum alloy equipment has been used to handle camphor. See also Ref: (1) p. 129. (3) pp. 104, 121. 226(7) p. 51. CANE SUGAR LIQUORS. Aluminum alloy equipment has been used in the processing and handling of cane sugar liquors. See also Ref: (4) pp. 74. 90. n-CAPROIC ACID. CH,.(CH!)q.COOH. In laboratory tests, alloys 3003. 5154. and 6061 were resistant to n-caproic acid at 50C (122F) and at the boiling point. Under refluxing conditions, n-caproic acid was corrosive to aluminum alloys. This acid has been stored in aluminum alloy containers. See also Ref: (2) p. 24. (3) p. 127. CAFROLACTAM. CHz(CH:),NHCO. Laboratory tests indicate that caprolactam is discolored by contact with nluminum alloys. n-CAPRYLJC ACID. CH,(CHJ), COOH. In limited laboratory tats. alloys 3003 and 5052 \\\ttre resistant to caprylic acid at ambient temperaure. This aad has been shipped in aluminum alloy containers. See also Ref: (2) p. 24. (3) p. l2i. CARBOLIC ACID. C,H,OH. See PHENOL. also Ref: (2) p. 537. (3) p. 116. See
used to handle butter. Aiuminum foil has been used for packaging butter. See also Ref: (1) p. 128. (3) p. 205. (4) pp. 84. 100. 102. 103. 114. (6) p. 11. BUTYL ACETATE CH,COO(CH,LCH,. In laborator! tesw allo! 3003 was resistant to hutyl acetate at ambwnt temperature and at the boiling pomr. Under refluxmg conditmns. butyl acetate caused mild attack ( - 3 mp!) of 3003 allo?. Aluminum allo? storage tanks have been used for butyl acetate. See also Ref: (1) p. 128. (2) p. 118. (3) p. 136. (7) p. 39. BUTYL ALCOHOLS. CH,.CH2.CH2.CH:.0H. CH,.CH(OH).CH,.CH,. (CH,),C.OH. In laboratar) tests. allo) 3003 water cooled tube was resistant to condensing vapors from n-butyl alcohol. In other laboratory tests at 204C (400F). n-but!1 alcohol containing as much as i 3% eater was corrosive very to 3003 alloy. but with 5% water. 3003 alloy was resistant. At the same temperature. alloy 3003 was resistant to secondaq and tertiary butyl alcohols with 0.3% water. Aluminum alloy decanters, heat exchangersand tanks have been used with pure butyl alcohol or butyl alcohol-water mixtures. See also Ref: (1) p. 128. (2) p. 120. (3) p. 113. (7) p. 39. BUI?LCELU)SOLVE.CH,OH .CH,.O .C,I&. In limited laborator) tests, commercial pure bury1 Cellosolve caused very severe corrosion of 3003 al101 under refluxing condltlons. This corrosion was eliminated in those tests by the addition of a small amount of nitrobenzene. BUTYL CELLOSOLVE ACETYL RECINO. LEATE. CI,H,O,. This product has been manufactured and handled in aluminum alloy equipment. BIJTYL LACTATE. CHJH(OH)COOC,H, I,, laboratory tests, alloys 3003. 5052 and 5154 were re. sistant to butyl lactate at temperatures from ambient to 188C (370F). As condensing vapors, butyl lat. tate caused mild attack ( - 2 mpy) of 3003 alloy. Bury1 lactaw has been handled in drums. tank trucks and tank can made from aluminum alloys. See also Ref: (1 pp. 40. 41. o-BUTYRALDEHYDE. C2H,.CH,.CH0. In labOratoIy tests, 1 IO0 alloy was resistant to solutions of butyraldehyde (l-100%) at ambient temperature. Corrosion increased at elevated temperatures, particularly at lower concentrations in the same tests. Aluminum allo) still and condenser tubes, shipping drums and tank cars have been used with n-butyraldehyde. See also Ref: (3) p. 120. (7) p. 41. BUTYRIC ACID. CHd(CHJ> COOH. The effect of butyric acid on aluminum is similar to that of acetic acid and propionic acid. The corrosion rates pass through a minimum at 5% acid and then increase again at approximately 70-80%. Above this concentration, the corrosion rates drop to low values for commercial strength butyric acid containing about 0.2% water. Dehydrated acid. containing about 0.05% water corrodes aluminum. Aluminum alloy storage tanks and shipping drums have been used. Heat exchangers made of aluminum-manganese alloys have proved to be satisfactov. Alloy 356.0 valves are used for handling buryric acid. See also Ref: (1) p. 128. (2)~. 123,(3)p. i27, (4)pp. 24,29,30,31,(7)p. 41. BUTYRIC ANHYDRIDE. [CH, (CH,),COlzO. In laboratov tests, but@ anhydride and mixtures of butyric anhydride and butyric acid at tempemtuEs from ambient to boiling caused moderate attack (- 7 mpy) of 1100 alloy. In the same tests. a mixture of dehydrated butyric acid and commercial strength anhydride was corrosive to 1100 alloy. Aluminum alloy storage tanks and shipping drums have been
used for butyric anhydride. p. 41.
See Ref: (3) p. 128, (7)
C
CADMIUM CHLORIDE. CdCI*.2 % HsO. Solid cadmium chloride was very corrosive to 3003 and 5154 alloys in laboratory tests conducted under con. ditions of 100% relative humidity at ambient temper. attire. See also Ref: (3) p. 80, (7) p. 45. CADMTUM SULFATE. CdSO,. Alloys 3GU3 and 5154 were resistant to solid cadmium sulfate in laborator tests conducted under conditions of 100% relatwe humidity at ambient temperature. In other labonto?_ tests, aqueous solution (l-IS%) caused mild attack of 3003 alloy at ambient temperature. Aluminum alloy piping. filter press plates, and tanks have been used to handle cadmium sulfate. See also Ref: (3) p. 80. (7) p. 45. CALCIUM CARBIDE. Cd,. Solid calcium carbide caused mild attack of alloy 5154. while alloy 3003 was resistant in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (I) p. 128, (3) p. 76. (7) p. 4s. CALCIUM CARBONATE. CaCO,. In laboratory tests, saturated solutions of calcium carbonate caused mild attack (-2 mpy) on alloy 1100 at ambient temperature. The rate decreared with time. Drv calcium carbonate had no effect. See also Ref: (1) p. 128, (3) p. 76, (7) p. 45. CALCIUM CHLORIDE. CaCl?.6H,O. In laboratory tests, solid calcium chloride caused moderate attack (- 6 mpy) of alloys 3003. 5154, and 6061 under conditions of 100% relative humidity at ambient temperature. Other laboratory tests show that aqueous solutions (up to 455%) caused mild attack at ambient temperature with pitting in evidence. The action of calcium chloride can be inhibited by the addition of sodium dichromate. Inhibited calcium chloride refrigeration brines have been commonly handled in aluminum alloy equipment. Alloy 356.0 valves have been used for handline calcium chloride solutions. See also Ref: (I) p. 128.72) p. 129. (3) pp. 23, 73, 240, (7) p. 47. CALCIUM CHROMATE. CaCrO,. Calcium chromate has been used as an inhibitive pigment in organic coatings on aluminum alloys. See also Ref: (7) p. 47. CALCIUM GLUCONATE. Ca(HO.CH, (CH.OH),COOlx~HIO. Aluminum alloy tanks have been used in the production of calcium gluconate. See also Ref: (3) p. 77. (7) p. 47 CALCIUM HYDROXIDE. Ca(OH),. In laboratory tests, calcium hydroxide solutions have rapid etching action on aluminum alloys Hhich quickly subsides as the result of the formation of protective films on the aluminum surface. See also Ref: (1)p. 128. (2) p. 133. (3) p. 72. (4) p. 47. CALCIUM HYPOCHLORITE. Ca(CIO),.Z H:O. Solid calcium hypochlorite was corrosive (- 27 mpy) to alloy 3003 and caused moderate attack H IO mpy) of alloy 5154 in laboratory tests under coryditions of 100% relative humidity at ambient temperature. !n other laboratory tests, aqueous solutions. except those at very low concentrations, wem corrosive to 3003 alloy at ambient temperature. Aluminum baskets and rotary driers have been used with calcium hypochlorite. See also Ref: (1) p. 128. (2) p. 104, (3) pp. 73. 247, (7) p. 47.
CARBON. C. In laboratory tests, various aluminum alloys were resistant to carbon when dry. When wet. carbon acts as a cathode tocontacting aluminum and causes corrosion as a result of galvanic action. Carbon black has been handled in aluminum alloy containers and hopper can. See also Ref: (1) p. 129, (2) p. 50. CARBON DIOXIDE. CO2 Carbon dioxide in liquid. solid orgaseous form has been handled in aluminum alloy equipment including pipe lines. See also Ref: (1) p. 129, (2) p. 141. (3) pp. SO, 214, (4) pp. 43, 47, 48. 93. CARBON DISULFlDE. CS,. Alloy 1100 was resistant to carbon disulfide in laboratory tests conducted at ambient temperature and at the boiling point. Aluminum absorbers, distillation columns, condensers, and piping have been used in carbon disulfide recovery systems. Alloy 356.0 valves have been used for handling carbon disulfide. See also Ref: (1) p. 129, (2) p. 146. (3) p. 51 (7) p. 51. CARBONIC ACID. HJO,. Carbonated beverages have been handled in aluminum alloy equipment. SeealsoRef:(l)p. 129. (2)~. 141,(3)p. 22, (7)~. 51.
(contmued)
615
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
CHROMIUM OXIDE. Cr,O,. Chromium oxide in the dry state has been handled in aluminum alloy equipment. See also Ref: (1) p. 130. (3) p. 82. CHROMlUM POTASSIUM SULFATE. CrK(S0,)~~12H10. Alloys 3003 and 5154 were resistant to solid chromium potassium sulfate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (7) pp. 62, 63. CHROMIUM SULFATE. Cr,(SO,), I5 H20. Solid chromium sulfate was corrosive to 3003 alloy in laboratory tests conducted under conditions of lOO% relative humidity at ambient temperature. See also Ref: (1) p. 130. (3) p. 82, (7) p. 63. CHROMIUM TRIOXIDE. CrO,. Solid chromium trioxide caused moderate attack ( - 17 mpy) of 3003 alloy in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Alloy 356.0 valves have been used for handling chromic acid solutions. See also Ref: (2) p. 194, (3) p. 82. (7) p. 63. CIDER. In laboratory tests, 5052 alloy was resistant to apple cider at 38C (IOOF). See also Rrf: (1) p. 130. (3) p. 202. (4) pp. 78. 97. (6) p. IO.
CARBON TETRACHLORCDE. CCIJ. In laboratory tests. alloys 3003. 5052 and 5154 were resistant to carbon tetrachloride at ambient temperature. whereas. boiling carbon tetrachloride was corrosive to these alloys as well as to many others. Two products of this reaction are aluminum chloride and hexachlomethane. The reaction apparently is electrochemical in nature and accelerated by anhydrous aluminum chloride. The reaction decreases rapidly as the temperature is dropped from boiling 177C (170F)I to 50C (122F). The rate increases markedly on superheating. The presence of water. carbon disulfide or oxygen increases the action at lower temperatures and decreases it at higher temperatures. The action can also be minimized by add~ng stabilizers. Aluminum powder in contact with carbon tetrachloride should not be used as a milling medium for comminuting aluminum. CAUTION: See Halogenated Hydrocarbons. See also Ref: (I) p. 129. (2) p 153. (3) pp. 23. 106. CELLULOSE. (ChH,,,Or),. Aluminum alloy equipment has been wed to handle cellulose. See also Ref: (I) p. 129. (31 pp. 124. 231. CELLULOSE ACETATE BUTYRATE. Aluminum alloy 5110s. piping. Jnd conveyors have been used for handling cellulose acetate butyrate. See also Ref: (3) p. 130. (7) p. 53.
ture. Similar results were obtained with 2% and 20% solutions of chlordane in kerosene. However. the addition of as little as 0.2% distilled water to these colutions increased their corrotivity greatly. Aluminum alloy containers have been used for the bulk rhipment of chlordane. CACiTl0.V. See Halogenated Hydrocarbons. See also Ref: (3) p. 110. (7) p. 55. CHLORINE. C12. In laboratory tests, aqueous soIu+ tions containing 25.50. and 100 ppm chlorine caused moderate attack of I IO0 and 6061 alloys at ambient temperature. Dry chlorine gas does not attack aluminum alloys. but in the presence of water is corrosive. Aluminum alloy bus bar has been used in causticchlorine plants. Hot chlorine gar has been cooled in aluminum alloy heat exchangen. See also Ref: (1) p. 129, (2) p. 167, (3) pp. 36, 247, (7) p. 57. CHMROACETIC ACID. CHICI COOH. Laboratory tests indicated that pure chloroacetic acid is very corrosive to 3003 alloy at 204C (400F). CAUTION: See Halogenated Hydrocarbons. See also Ref: (7) pp. 56, 57. CHLOROBENZENE. C,H&I. Laboratory tests indicated that alloy 3003 was resistant to chlorobenzene at 100C (212F) and refluxing temperatures. Chlorobenzene has been shipped in aluminum alloy tank trucks. CAUTION: See Halogenated Hydmcarbons. See also Ref: (2) p. 173. (3) p. 111. (7) p, 57.
(HOOC)CH,C.(OH)(COOH) CITRIC ACID. .CH:COOH. In laboratory tests. II00 alloy uas CELLULOSE ACETATES. Aluminum alloys have resistant to aqueous solutions of citric acid at ambeen used in the preparation and storage of cellulose l-CHLOROBUTANE. C,H,CI. Laboratory tests blent remperarure. While increased concentration acetates. See also Ref: (I) p. 129. (3) pp. 136.232. (7) showed that 3003 alloy was resistant to I-chlorohad little effect, increasing temperature cawed the p. 53. butane at ambient temperature and 50C (IZZF). corrosivity of the solutions to increase subsrantlally. At the reflux temperature I-chlorobutane was corroThe presence of chlorides or heavy metals mcreaws CEMENT, PORTLAND. While in the fluid state, sive to alloy 3003 and high purity aluminum. CAUthe corroshity of these solutions. Aluminum has no Ponland cement causes etching of aluminum alloys TION: See Halogenated Hydrocarbons. harmful action on the organisms used in rhe manuas indicated in laboratory tests and in service applicafacture of citric acid and is suitable for cc:uipment tions. After the cement has set, no further corrosion 2XHLOROBUTANE. CH,&HICHCICHJ. In laboruch as fermenting vats. crystallizers, solution occurs as a result of a protective film forming on the ratory tests. alloy 3003 was resistant to 2.chlorostorage \ats. and piping. Alloy 356.0 vahes have aluminum. Galvanic corrosion will develop if alumi- butane at ambient temperature. At higher temperanum is coupled todissimilar metals in cement or con- tures, 2.chlorobutane been used for handling citric acid solutions. See also was corrosive to 3003 alloy. crete to which chlorides have been added for high CAUTION: See Halogenated Hydrocarbons. Ref: (I) p. 130. (2) p. 199. (3) pp. 131, 209. (4) pp. early strength. Aluminum alloys have been used for 22, 25. 26, 27, 28, 29, 30. 31, 109. 110. 113. (7) p. 6.5. freight can. hopper can, and tote bins handling ce- 2XHLOROETHANOL. CHzCICHIOH. In laborament. Aluminum has also been used successfully for tory tests, 3003 alloy was resistant to 2.chloroethanol CITRUS FRUlT IUICES. Laboratory tests indiracks and pallets in the concrete block industry, at ambient temperature. Corrosion increased rignificated that alloys 3003. 5052. and 5086 were resistant molds and forms. and terrazzo divider strips. See also cantly as temperature increased with 2.chloroethanol to citrus fruit juices at ambient and refrigerated temRef: (I) p. 129. (2) p. 161. (3) p. 228. being very corrosive at the boiling point. C4UTION: peratures. See also Ref: (-I) p. 90. (6) p. IO. 13. See Halogenated Hydrocarbons. See also Ref: (3) CEREALS. Aluminum alloy equipment has been p. 133. (7) p. 87. CLAY. Variable substance with a base of hydrous used for handling and preparation of cereals. aluminum silicate. Dry clay and clay slurries have CHLOROFORM. CHCI,. In laboratory tests, Ill!0 alloy was resistant to chloroform with a trace of water been handled in aluminum alloy piping, fittings, and CHEESE. Cheeses vary in their action on aluminum valves. See also Ref: (I) p. 130. (3) p, 228. at temperatures up to the boiling point 6lC (142F). alloys. In laboratory tests, aluminum alloys were resistant to some cheeses, while other cheeses were In the same test. anbydrouc chloroform uas cop~oCOAL.. Mainly carbon. containing also many orcorrosive. When necessary. aluminum alloys can be sive. CAUTION: See Halogenated Hydrocarbons. game compounds. A controlled field test indicated protected readily. Aluminum vats and molds have See also Ref: (1) p. 130. (2) p. 179. (3) p. 106. t) p. that aluminum alloys performed uell when contactbeen used for processing cheese. Aluminum wrap- 59. ing various types of coal for 30 years. Aluminum pings and containers have been used for cheese. NO:C,H,CI. In limalloys have been used for trucks, hopper cars. chutes, Those have usually been protected. See also Ref: (I) CHLORONITROBENZE,NE. skips, cages, trolleys. pit props, and hand tools in the p. 129, (3) pp. 199. 205, (4) pp. 84, 102, 103. 114, ited laboratory tests, 3003 alloy was resistant to chloronitrobenzene at ambient temperature. CrlUhandling of coal. Aluminum liners have given satis115. (6) pp. 9. II, 14, 15. TIO,V: See Halogenated hydrocarbons. See also factory service in coal bunkers to assist in the flow of CHERRIES. In laboratory tests, cherries in brine Ref: (2) p. 185. the coal. See also Ref: (1) p. 130, (3) pp. SO, 221. caused moderate attack of 3003. %2. and Alclad Aluminum alloy equipment has COAL GAS. Containing hydrogen, methane, car3003 alloys at amblent temperature. Alclad 3003 CHOCOLATE. been used in the preparation and manufacture of bon monoxide, ethane, carbon dioxide, oxygen, niwhen exposed at ambient temperature was resistant foil has been used to trogen and volatile organic compounds. Limited labto Maraschino cherries in another laboratory test. chocolate candy. Aluminum Fresh chemies in water have been carried by alumi- package chocolate products. See also Ref: (3) pp. oratory tests showed that 443.0 casting alloy was 200.203. (4) p. 115, (6) p. 12. num alloy irrigation pipe to processing tanks. resistant to coal gas at ambient temperature. See also Ref: (3) p. 221, (7) p. 65. CHROMIC ACID. H2Cr004. In laboratory tests, CHERRY MCE. In laboratory tests, sweet red cherry juice caused mild attack ( - 4 mpy) of 3003 1100 alloy was resistant to aqueous chromic acid COAL TAR. Containing benzene, toluene. naphup to 0.1 N at ambient alloy at lOOC (212F) while black cherry juice caused solutions in concentrations thalene. anthracene. xylene. other aromatics; moderate attack ( - 8 mpy). See also Ref: (4) pp. 88, temperature. See also Ref: (1) p. 130, (2) p. 194. (3) phenol, cresol, other phenolics; ammonia. pyridene. pp. 82, 236, (4) pp. 21, 121, (7) p. 63. 89, (6) p. IO. other organic bases. thiophene. Aluminum alloy equipment including distillation columns, condenCr. Chromium plated aluminum al- sers and piping have been used in the production of CHLORDANE. C,,H,CI,. In laboratory tests. 3003 CHROMIUM. alloy was resistant to technical chlordane with ot loy products have been used. See also Ref: (3) p. 82, coal tar. See also Ref: (3) pp. 223, 224. without 0.2% water additions at ambient tempera- (4) pp. 83. 134.
(continued)
616
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
tar. In laboratory tests. 1100 alloy was resistant to l%, 3%. and 100% solutions of cresylic acid at ambient temperature. See also Ref: (2) p. 221, (7) p. 67. CBYOIJTE. (SODIUM ALUMINUM FLUORIDE). Alloy 3003 was resistant to solid cryolite in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (7) pp. 160. 161. CUMENE. C,Hs CH(CH,),. In limited laboratory tests. 3003 alloy was resistant to cumene under refluxing conditions. Cumene has been stored in aluminum alloy containers. See also Ref: (7) p. 69. CURRANTS(BLACK AND RED). in limited laboratory tests, red currants were corrosive to 3003 alloy at 100C (212F). Aluminum equipment has been used in processing and preparing currants. See also Ref: (6) p. IO. CYCLOHEXANE. CJ& In laboratory tests, 3003 alloy was resistant to cyclohexane under &axing conditions. Aluminum alloy tank trucks have been used to ship cyclohexane. See also Ref: (3) p. 104, (7) p. 71.
COBALT COMPOUNDS. Solid cobaltous chloride tive films. Calcium chloride is often added to morwas very corrosive to alloys 3003 and 5154 in lab- tar and concrete to accelerate curing and to develop oratory tests conducted under conditions of 100% high early strength. Sodium chloride may also be relative humidity at ambient temperature. Solid cw present. as a contaminant of the water and sand. In baltous nitrate caused mild attack ( - 3 mpy) of 3003 laboratory tests, the addition of appreciable amounts alloy in the same tests. See also Ref: (3) p. 84, (5) p. of either calcium chloride or sodium chloride to concrete had little effect on the corrosivity of the con13. crete to aluminum alloys. However. these rests and COCA COLA* SYRUP. In laboratory tests, Coca service experience show that small amounts of chlorides will aggravate corrosion of alloys and even Cola syrup is corrosive to aluminum alloys. Unpro cause deterioration of the concrete when the co_ tected aluminum is not ordinarily used with this pro sion is of a galvanic nature. especially when the conduct. crete is either intermittently or continuously wet l &mcml tndrm.rt after curing. While aluminum alloys perform well in many applications involving mortar and concrete. COCONUT OIL. Contains Irimyristin. trilaurin. tripalmitin. tristearin. other glycerides. Coconut oil definite benefits may be obtained by using protec. tive coatings to prevent staining, eliminate crevice has been stored in aluminum alloy tanks. See also corrosion, minimize galvanic corrosion, and imRef: (7) p. 93. prove adhesion by decreasing gas evolution at the metal interface. See also Ref: (IO) p. 29. COD LIVER OIL. A fixed oil containing vitamins A and D. glycerides of palmitic. stearic. etc., acids, COPAL. Contains trachylolic acid, isotrachylolic cholesterol, butyl alcohol esters. Cod liver oil has acid, resene and volatile oil or contains dammaric been processed and stored in aluminum alloy equipacid. dammaran and a resin. Aluminum alloy ment. See also Ref: (I) p. 130, (2) p. 294. (3) p. 239. equipment has been used for the production of var. nishes made from copal resins. See also Ref: (1) p. COFFEE. Coffee has been prepared in aluminum 131, (2) p. 210, (3) p. 226, (7) p. 65. alloy cooking equipment and utensils. See also Ref: (1) p. 130. (3) p. 211. (4) pp. 80. 84.97, (6) p. 12. COPPER COMPOUNDS. In laboratory tests, COKE. (From destructive distillation of coal and other carbonaceous materials.) The resistance of aluminum to coke has been reflected by its use for coke conveyor buckets and as sprayed coatings to protect steel can used for coke quenching. Aluminum alloy equipment has been used in many applications handling coke oven gas. Deacidifien. pipes. heat exchangers, heating coils, regenerators, and absorbers made of aluminum allovs have been in service om. cessingcoke oven gas. S& also Ref: (1) p. 130, ($&. 210, 221, 223. COKE OVEN GAS. Contains hydrogen, methane, carbon dioxide and volatile organic compounds. Aluminum alloy deacidifiers. heat exchangers, and heating coils have been used in the Collins process for the desulfurization of coke oven gas. Condensation of moisture on surfaces contacting coke oven gas CM accelerate cormsion on aluminum alloys as the result of the formation of sulfurous acid. See also Ref: (1)p. 130. (2) p. 859. COLLODION. Pymxylin dissolved in alcohol and ether. Laboratory tests showed that alloy 6053 was Rsistant to collodion at ambient temperature. Collodion has been stored in aluminum alloy containers. See also Ref: (3) p. 124. CONCRETE. Aluminum alloys embedded in fresh mortar or concrete have been used in many applications. As shown by laboratory tests, 5ome surface attack occurs during the first few hours while the concrete is still fluid. However, further attack is substantially retarded because of the formation of highly protective films on the aluminum. Measured depths of the attack that take place during the setting period of concrete are generally less than 1 mil while after 6 months or after 8 or 27 years in service measured depths of attack have been found no greater than S mils. Laboratory tests have demonstrated that the volume of concrete in contact with aluminum as well as availability of external moisture have no more than a minor effect on the performance of aluminum alloys embedded in concrete. In many applications, aluminum alloys embedded in concrete are coupled directly or indirectly to reinforcing or structural steel. Laboratory tests have shown that aluminum is anodic to steel in concrete. Nonetheless. when coupled electrically in the laboratory to steel in concrete, aluminum alloys have been found less affected than when not coupled as the result of more rapid formation of protec-
CYMENE. C&I,. In laboratory tests. 3003 alloy was resistant to cymene under boiling and condensaqueous solutions of copper compounds were cot- ing conditions and under refluxing conditions. See also Ref: (3) p. 104. rosive to aluminum alloys causing localized pitting. See also Ref: (1) p. 131. (3) p. 238.
CORK. The light, porous outer bark of the cork oak. In laboratory tests, cork was corrosive to contacting 3003 alloy under conditions of 100% relative humidity at 52C (125F) which caused wetting of the cork. See also Ref: (10) p. 29. CORN OIL. A refined oil expressed from grain of Zea mays L. Corn oil has been stored in aluminum alloy containers. See also Ref: (6) p. II. CORN PRODUCTS. In laboratory tests, alloys 1100 and 3003 were resistant to many corn products tested. Aluminum alloy equipment has been used in the production of corn products. Aluminum alloy hoods. ducts. piping, and conveyors have been used. CORN SYRUP. A mixture of dextrose and dextrins in water. Laboratory tests indicated that 6061 alloy was resistant to corn syrup at ambient temperature. Corn syrup has been stored in aluminum alloy containers. See also Ref: (2) p. 229. (6) p. IO. COSMETICS. In laboratory tests. many cosmetics have been tested with variable results. Aluminum alloy containers have been used for a variety of creams, powders. lotions, and soaps. See also Ref: (3) pp. 117. 239. COTTONSEED OIL. A refined oil expressed from the seeds of Gossypium herboceun and other species of Gossypium. In laboratory tests, 6061 alloy was resistant to cottonseed oil at ambient temperature. Aluminum alloy storage tanks have been used for cottonseed oil. See also Ref: (2) p. 872. CREAM. Aluminum allovs have been used for ream separators. See also kefz (3) p. 204. (4) pp. 26. ICn, (6) p. 11. XESOL C,H,(OH)(CH,). In laboratory tests, 1100 alloy was resistant to 1%. 3%. and 100% solutions of cresol at ambient temperature. In other aboratory tests. ctesol was very corrosive to I I00 alloy at the boiling point. See also Refz (1) p. 131. (2) ). 221. (3) p. 116, (7) p. 67. XESYLIC ACID. A mixture of phenols from coal
2, 4-D. Cl,. C,H, 0. CH2. COOH. Limited laboratory tests indicate that dilute aqueous solutions of 2. 4-D caused mild attack of 3003 alloy at ambient temperature. 2, 4-D has been handled in aluminum alloy sprayers and piping. CAUTION: See Halo. genated Hydrocarbons. See also Ref: (3) p. 127. DAJRY PRODUCTS. Aluminum alloys have been used for milk pails, milk cans, storage tanks, truck tankers. pasteurizers. coolers. butter chums and tubs. foil hoods, and powdered milk driers. See also Ref: (3) p. 204. (6) p. 11. DDT. (CIC,H&CHCCII. Laboratory tests showed that 3003 alloy was resistant to dry DDT and dilute aqueous solutions of DDT at ambient temperature. Aluminum alloy cans have been used for aerosol w lotions of DDT. CAUTION: See Halogenated Hy drocarbons. See also Ref: (2) p. 226. (3) pp. I Il. 241. (7) p. 75. DETERGENTS. Aluminum alloys perform in different ways in different detergents. When in solution. some detergents stain andFor corrode aluminum. Since general conclusions cannot be drawn, detergents rhould be tested individually before use with aluminum alloys. Aluminum bins, silos. piping, and packages have been used for detergents. See alu, Ref: (I) p. 131. (3) p. 243, (4) pp. 34, 72, 75. 76, 85, 86, 87, 96, 103. DMCETONE ALCOHOL. (CHJ,C(OH)CH,COCH,. In limited laboratory tests. 3003. 5052. and 5454 alloys were resistant to diacetone alcohol at ambient temperature and at 54C (13OF). See also Ref: (3) p. 121. DICHLOROACETIC ACID. CHC&COOH. In limited laboratory tests, dichloroacetic acid was corive to 3003 alloy at 2OVC (400F). CAUTION: Set Halogenated Hydrocarbons. See also Ret (3) p. 127. DICHMROBENZENE. C&Cl,. In laboratory tests, alloys 3003 and 5154 were resistant to dichlorobenzene at 50C (122F). Dichkxobenzene has been
(continued)
617
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
ETHYLENE DICHLORIDE. CH2CI CHICI. Limited laboratory tests indicate that 3003 alloy was resistant to dry ethylene dichloride vapor at the boiling point. The presence of water causes increased corrosion because of hydrochloric acid formed by hydrolysis. CAUTION: See Halogenated Hydrocarbons. See also Ref: (1) p. 132, (2) p. 268. ETHYLENE GLYCOL. HO.CH,.CH,.OH. Laboratory tests have indicated that 3003 alloy was resistant to ethylene glycol at ambient temperature and under refluxing and boiling and condensing conditions. Aluminum alloyequipment has been used in the processing of ethylene glycol and for storage tanks and pressure vessels. Inhibited ethylene glycolwater solutions have been used in automotive radiators and heat exchangers. Aluminum alloys should not be used in applications with stagnant ethylene glycol where very high temperatures are involved [2OPC (392F) and above]. Violent reactions are possible under these condirions. See also Ref: (1) p. 132. (3) pp. 25. 114. (7) p. 89. ETHYLENE OXIDE. (CH,j20. Aluminum alloys have beeh used to produce and handle ethylene oxide. Violent reactions are possible if aluminum chloride and aluminum oxide are present. See also Ref: (1) p. 132, (3) p. 135, (7) p. 89. ETHYL FORMATE. HCOO.C,H,. In laboratory tests, alloy 3003 was resistant to erhyl formate at ambient temperature and at the boiling temperature. In other laboratory tests. 3003 alloy was resistant to ethyl formate ascondensingvapors. See also, Ref: (1) p. 132. (2) p. 136, (7) p. 91. ETHYL LACTATE. CH,CH(OH)COOC,Hs. In laboratory tests at ambient temperature. alloy 6053 was resistant to ethyl lactate. See also Ref: (I) p. 132, (3) p. 137. ETHYL PROPIONATE. CH,CH, COOGH,. In limited laboratory tests, alloy 3003 was resistant to ethyl pmpionate under boiling and condensing conditions. Aluminum alloy stills and condenser tubes have been used in the production of ethyl propionate. See also Ref: (7) pp. 90, 91. EUCALYPTUS OIL. A volatile oil containing eucalyptol: vale& butyric. etc., aldehydcs: d-pinene. Aluminum alloys have been used for handling eucalyptus oil. See also Ref: (1) p. 132. Aluminum EUGENOL. C,,H,IOz. have been used to store and transport alloy drums eugend.
handled in aluminum alloy tanks, filters, and heat exchangers. CAUTION: See Halogenoted Hydracarbons. See also Ref: (2) p. 173, (3) p. Ill, (7) p. 75. DICYCLOPENTENYL ALCOHOL. In laboratory tests, 3003 alloy was resistant to dicyclopentenyl alcohol at boiling temperature. DIETHANOLAMINE. HN(CHz CH*OH)*. Laboratory tests showed that alloy 3003 was resistant to diethanolamine at ambient temperature. However, at the boiling temperaturn and under refluxing conditions diethanolamine caused moderare attack. While aluminum alloy heat exchangers have been used to handle diethanolamine solutions, tests under the anticipated conditions should be made prior to use in service. See also Ref: (3) p. 145. DIETHYL4MlNE. (CJH&NH. Alloy 3003 was resistant to diethylamine in laboratory tests conducted at elevated temperatures of ICPC (212F) and 204C (400F). Aluminum alloy stills and condenser tubes have been used in processing and handling diethylamine. See also Ref: (7) pp. 76. 77. DIETHYLENE GLYCOL. HO. CH>. CH, .O-CIiZ CH:OH. In laboratory tests. 3003 alloy was resistant to diethylene glycol under refluxing conditions. See also Ref: (3) pp. 25. 135. (7) pp. 76, 77. n-DIMETHYL FORMAMIDE. HCON(CH,)x. In laboratory tests, 3003 alloy was resistant to dimerhyl formamide at ambient temperature and at the boiling point. Dimethyl formamide has been handled in aluminum alloy tanks. piping, heat exchangers. and distillation towers. See also Ref: (3) p. 147, (7) p. 81. UNS-DIMETHYlBYDRAZlNE (CH,),NNHz. In laboratory tests, alloys I 100, 3003 and SO52 were resistant to uns-dimethylhydrazine when exposed at 30C (86F) and 63C (145F). Dimethylhydrazine has been stored in aluminum alby containers. See also Ref: (7) pp. 80. 81. DIMETHYL SULFATE. (CH,),SO,. Dimethyl sulfate has been stored in aluminum alloy containers. See also Ref: (2) p. 233. DIMETHYL TEREPHTHALATE. C,H,(COOCH,,)I. Aluminum alloy containen been used for handling dimethyl terephthalate.
ESSENTIAL OILS Volatile oils derived from plants and usually taming the esxnt~al odor or flavor of
the plant used. Aluminum used m the preparation. sential oils. See also Ref: (I) 239. alloy equipment storage. has been of er(3) p, ond trxtsport
p. 131. (2) p. 2%.
ESTER GUMS. The glyce~l. methyl and eth!I esten of resin acids. Alummum alk>ys have been used for piping ester gums. ETHANOLAMINE. H,N.CHlCH,.OH. Limited laboralor) tests under reflusing conditions indicate that ethanolamine caused mild attack (-4 mp!) of 3003 alloy. Aluminum alloy heat exchangers have
been used for handling a ethanolamine-dieth~lene
glycol mixture to remow CO:. H2S. and water from natural gas. Aluminum allo! tanks have been used to transport ethanolamine. See also Ref: (I) p, 131. ETHER. C?H,. 0 C:H,. Laboratory tests indicated that alloy 3003 uas resistant to ether at both ambient and elevated temperatures. Aluminum processing. handling and degreasing equipment have been in use. Allo! 356.0 valves have been used for handling ether. See also Ref: (2) p, 258, (3) p. 135, (7) p; 77. ETHYL ACETATE. CH, .COO.C,H,. In laboratot tests. alloy 3003 was resistant to ethyl acetate and its condensing vapors. Aluminum alloy heat exchangers. tank cars, etc.. have been used for handling ethyl acetate. See also Ref: (I) p. 132. (2) p. 2bO. (31 p. 136. (7) p. 85. ETHYL ALCOHOL. CIHIOH. In laboratop tests. alloy 3003 was resistant to commercial (95%) ethyl alcohol and its aqueous solutions. In other laboraton tests, anhydrous ethyl alcohol was corrosive to aluminum alloys. Aluminum alloys have been used commercially for stills, hear exchangers, drums. tanks, and piping in the processing of ethyl alcohol and products employing ethyl alcohol in their manufacture See also Ref: (1) p. 132. (2) p. 28, (3) pp. 23, 112. (4) pp. 93. 97, 142. (7) p. ES. a-ETHYL4NUINE C:H,NHC,H,. In laboratory tens. alloy 3003 was resistant to n-ethylaniline at the boiling temperature and under reflilsing conditions. Erhylaniline has been stored in aluminum alloy containers. ETHYLBENZENE. C,Hs. CIH,. In laboratory tests, alloy 3003 was resistant to ethylbenzene af the boiling temperature and at 204C (4CPF). Ethylbenzene has been handled in aluminum alloy heat exchangers. See also Ref: (2) p. 263, (3) p. 104, (7) p. 87. ETHYLBUTYL ACETYLBICMOLEATE. Aluminum alloy equipment has been used to produce and handle ethylbutyl acetyhicinoleate. ETHYL BUTYBATE. CH,.CHz.CH>.COOC,H,. In laboratory tests, ethyl butyrate caused mild attack (- 2 mpy) of 3003 alloy under boiling and condensing conditions and under refluxing conditions. Aluminum alloy equipment has been used in the production and handling of ethyl butyrate. See also Ref: (I) p. 132, (3) p. 137, (7) p. 87. ETHYLENE. CH,:CHI. Ethylene has been handled in aluminum alloy heat exchangers and tanks. See also Ref: (3) p. 103, (7) p. 87. ETHYLENEDIAMINE. NHz.CHI.CH,.NHz. In limited laboratory tests, 3003 alloy was resistant to ethylenediamine al 100C (212F) and 204C (400F). See also Ref: (1) p. 132. (3) p. 145, (5) p. 9. (7) p. 89.
have
DIOCTYL PHTHALATE. C&I,(COOCHzCH(C~Hs)C,H&. Aluminum alloy tanks have been used to store dioctyl phthalate. See also Ref: (7) p. 81. DIPHENn C,Hs.C,Hs. Aluminum alloy equip ment has been used to handle diphenyl. See also Rel: (2) p. 247. (3) p. 104. (7) p. 81. DYES. Aluminum alloy equipment has been used in some manufactuting processes for dyes in some dyeing processes for dye kettles. dye sticks and drying pans. See also Ref: (I) p. 131. (2) p. 212, (3) pp. 10% 119, 121. 132, 144. 145, 146. 23.5. (4)~. 73. DYNAMITE. An explosive mixture containing nitroglycerin with other substances both inert and active. Aluminum alloys have been used for parts in dynamite packing machines and for dynamite driers and mixers. See also Ref: (I) p. 131. (3) p. I IS.
F FATS. Aluminum alloy equipment has been used to handle fats. See also Ref: (1) p. 132. (2) p. 271. (3) p. 198, (4) pp. 72, 78, (u, 84, 99. 100, 109. (7) p. 93. FATTY ACIDS. RCOOH. Laboratory tests have shown that fatty acids cause mild attack of 1 IGil alloy at ambient temperature. Anhydrous fatty acids were found to be very corrosive to aluminum alloys at the boiling point in other laboratory tests. Aluminum alloy storage tanks. separators. settling and receiving tanks, condensers, vapor lines, and steam trace lines have been used to process and handle fatty acids and fatty acid derivatives. See also Ref: (1) p. 132, (2) p. 274, (3) pp. 125, 127, (4) pp. 25. 100, (7) p. 93. FERRIC CHLORIDE. FeCIJ.6HI0. Solid ferric chloride was very corrosive (244 mpy) to 3003 alloy in laboratory tests conducted under conditions of loO% relative humidity at ambient temperatom. Also in laboratory tests, aqueous solutions of ferric chloride
E EGGS. Aluminum alloy equipment has been tised for the preparation and dessicarion of egg powder. Aluminum alloy trays have been used for drying egg whites. Seealso Ref: (1)~. 131. (3, p. 198. (4)~. IIS. (6)pp. 8. II.
(continued)
618
Corrosion
Resistant
Materials
Handbook
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
FUDGE. In laboratory tests, alloy 3003 was resistant to fudge at ambient temperature and 62C (143OF). Milk chocolate fudge has been processed in aluminum alloy equipment. See also Ref: (6) p. 12. FUEL OIL. Fuel oil has been stored and transported in aluminum alloy equipment. See also Ref: (I) p. 133. (3) p. 220. FUELS, MISSILE. United States Defense Research reports that aluminum is resistant to many oxidizers and fuels used as missile propellants. Aluminum alloys are used with chlorine trifluoride. ethylene oxide, fluorine. hydrazine. unsymmetrical dimethyl hydrarine. hydrogen peroxide. liquid oxygen. nitrogen tetroxide tO.l% or IeCs moisture). fuming nitric acid, n-propyl nitrate, liquid nitrogen. alkyl boranes. perchloryl fluoride (anhydrous) and liquid hydrogen. Ref: Titan 11 Storable Propellant Handbook-Bell Aerospace Company. New York. Report No. 81 II-933003 FURFURAL.. C,H,O?. In laboratory tests. alloy 3003 was resistant to solutions of furfural at ambient temperature and 200C t392F). Aluminum storage tanks, evaporators. condensers. valves and pumps have been used to handle gasoline-furfural mixtures. Aluminum bubble caps. trays and heat exchangers have been used uhere furfural is used as the selective wlvent. Pure furfural for pharmaceuticals has been stored in aluminum. ,Alloy 3jb.O valves have been used for handling furfural. See also Ref: (I) p. 133. I?) p. 325. (3) p. 148. (-1 p. 95.
were very corrosive to aluminum alloys. See also Ref: (I) p. 132. (2) p. 288, (3) p. 84, (7) p. 93. FERRIC OXIDE. FQO,. were resistant to solid ferric conducted under conditions ity at ambient temperature. Alloys 3003 and 5154 oxide in laboratory tests of 100% relative humidSee also Ref: (1) p. 132.
FLY ASH. Laboratory tests have shown that alloy 3003 is resistant to dry fly ash at ambient temperature. The results of similar tests showed that wet fly ash caused variable results depending upon the composition of the fly ash. particularly the pH. chloride content and heavy metal content. Tests should be conducted prior to using aluminum alloys in applications involving contact with fly ash. FOOD. (SEE SPECIFIC FOODS). The use of aluminum alloy cooking utensils has been universal for the preparation and cooking of foods. See also Ref: (3) p. 197. FORMALDEHYDE GAS. HCHO. Aluminum alloy equipment has been used for distillation. storage, and shipment of formaldehyde. Alloy 356.0 valves have been used for handling formaldehyde. See also Ref: (1) p. 133. (2) p. 307. (3) p. 119. (4) pp. 73, 86, 97, (7) p. 95. FORhALIN. A solution of formaldehyde gas in water usually with methanol added. Laboratory tests at ambient temperature and at 38C (100F) indicated that 1100. 3003 and 5052 alloys were resistant to 19% solution of formalin. At boiling conditions. formalin (37% solution) caused substantial pitting corrosion. Chlorides and copper salts increase pitting in formalin solutions. Aluminum alloy piping. storage tanks, drums and tank trucks have been used for handling formalin solutions. See also Ref: (1)P. 133, (3) p. 119, (7) p. 95. MRMAMIDE. H. CO. NH,. Alloy 1100 was resistant to aqueous solutions of formamide (LO-100%) at ambient temperature and at 50C (122F) in laboratory tests. Similar solutions (greater than 10%) at the boiling temperatures were very corrosive. See also Ref: (3) pp. 143. 147. (7) p. 95. FORMIC ACID. HCOOH. Solutions of formic acid caused mild attack of 1100 alloy in laboratory tests at ambient temperature. In laboratory tests at 50C (122F). the formic acid was corrosive, and at the boiling tempertore. formic acid was very COROsive. Aluminum is not recommended for use with forSee mic acid except in special cases. also Ref: (1) p. 133. (2) p. 315. (3) pp. 22. 124, 125. 227. (7) p. 95. FREON*. Agroupof halogenated hydwarbons used as refrigerants, propellants. blowing agents, fire extinguishing agents, and solvents. Laboratory tests have shown that 1100 alloy is resistant to most dry Freons at elevated temperature 200C (392F). In similar laboratory tests, the presence of moisture permitted hydrolysis of the Freons and subsequent corrosion of the aluminum. Aluminum alloy refrigeration and air conditioning equipment has been used with Freons. See also Ref: (1) p. 133. (2) p. 239. (3) p. 107, (7) pp. 58, 60. 74. l R.sllleRd TradeMlrk. FRUIT. Some of the acids in fruits have been found to be corrosive to aluminum alloys in laboratop tests. Because of the presence of denrose. proteins and pectin in fruit. the corrosive action is inhibited in many cases. Protected aluminum alloys have been used for canning fruit and foil has been used for wrapping and containers. See also Ref: (1) p. 133, (3) p. 208, (4) pp. 72. 79. 80, 81. (6) p. 10. FRUIT JUICES. (See also Citrus Fruit Juices). Fruit juices are processed and handled in aluminum equipment. Orange squeezers have been made of aluminum alloys. Fmzen juice cans have aluminum alloy ends. Fruit juices are generally less corrosive to aluminum alloys than are the corresponding fruit acids. See also Ref: (1) p. 133, (2) p. 321. (3) pp. 131. 201. (4) pp. 88. 89. 90. (6) p. 10, (7) p. 95.
FERROUS SULFATE. FeS0,.7Hz0. Alloy 3003 was resistant to solid ferrous sulfate while 5154 alloy suffered mild attack ( - 4 mpy) in laboratory tests under conditions of 100% relative humidity at ambient temperature. In other laboratory tests at ambient temperature. aqueous solutions (O.COOl-10%) caused mild attack ( - 3 mpy) of 1100 alloy. Aluminum spray tanks and alloy A356.0 valves have been used with ferrous sulfate solutions. At elevated temperature. ferrous sulfate oxidizes to ferric sulfate which is aggressive to aluminum alloys. See also Ref: (I) p. 133, (2) p. 291, (3) p. 84. (7) p. 93. FERTILIZERS. In laboratory tests. the corrosive effects of fertilizers on aluminum alloys vary greatly with some being compatible and others very cormswe. Generally the solid and liquid nitrogen fertilizem have been the least corrosive while the complete mix neutral fertilizers have been the most corrosive. Aluminum alloy equipment has been used in the manufacture and handling of the nitrogen fertilizers. See also Ref: (3) p. 64. FLSB. Laboratory tests have shown that alloys 1100 and 3003 are resistant to most fish products at ambient temperature. Aluminum alloys have been widely used in the construction of fish holds and linings of fishing vessels, fish boxes, trays, smoke racks, and tables. Many fsh products can be preserved in either protected or unprotected aluminum alloy containers. See also Ref: (1) p. 133. (3) pp. 198, 207. 208, (4) pp. 72. 78. (6) p. 12. FLOUR. Aluminum milling and handling (6) p. IO. equipment has been used in flour. See also Ref: (3) p. 203,
G
GASOLINE. A minure of C, to C,! hydrocarbons: also paraffins, olefins. naphthenes. and aromatics: traces of tetraethyl lead. ethylene dibromide or dichlonde and proprietary additives. Laboratory tests have shown that aluminum alloys including 3003 were resistant to gasoline at room temperature. Thev tests also showed that the sump water in gam line tanks can be corrosive because of the accumulation of halogen and lead compounds. Gasoline has been handled in aluminum alloy drums and tanks. Aircraft fuel tanks have been fabricated from aluminum alloys. Alloys 3003, Alclad 3003, 5052, 6061, and A356.0 have been used with gasoline. See also Ref: (1) p. 133. GELATIN. Gelatins are handled extensively in aluminum alloy equipment. Aluminum vats are used to digest pork skins. calf skins, and animal bones at 66OC (150F) using dilute solutions of H&V,. HCI, HNO,, H,SO,. or SOS depending on the final pH requirementsof thegelatin (pH range 3-7). Aluminum alloys have also been used in evaporators, piping. tubing. tanks, pumps, drying tunnels. and convey ors. Aluminun is one of the few metals in which edible gelatin can be produced to meet requirements of the Pure Food and Drug Law. It is not recommended as containers for finished gelatin solutions unless protected because of the presence of salt. See also Ref: (1) p. 133. (2) p. 328. (3) p. 210. (4) pp. 48. 73. 84. 100. (6) pp. 10. (7) p. 97. GLASS WOOL. Fine filamentsof glass intermingled like wool. In laboratory tests, 3003 alloy was resistant to all dry glass wools, but when wet in 100% relative humidity environments. soft glass wools were cormsive whereas, 3003 alloy was resistant to hard glass (borosilicate type) wools. The binders used in glass wools may be corrosive to aluminum alloys in some cases. Glass wool has been used to insulate many aluminum alloy products. See also Ref: (10) pp. 29, 108. GLUCONIC ACID. CIIHIzO,. Laboratory tests indi-
FLUE GASES. The corrosivity of flue gases to aluminum alloys depends on the sulfur content of the fuel being burned and if condensation is present. The sulfur content of fuels increases in the following order: processed natural gas. fuel oil. hard coal. soft coal. Aluminum alloys have been widely used for flue linings and vent pipes serving domestic gas-fired appliances and has been specified by many gas companies and public utilities. Aluminum alloy flue liners have been widely used for house chimneys. Generally, aluminum alloys will suffer some corrosion if condensation is present in the flue. See also Ref: (1) p. 133. FLUOPHOSPHORK ACIDS. H,PO,F(or (HOhFOF); HPOlF, (or HOPOF>); HPF,. Aluminum alloy reactors and tanks have been used in the manufacture and handling of fluophosphoric acids. See alw, Ref: (3) p. 37. FLUORINATED HYDROCARBONS. Fluorinated hydrocarbons are the most stable halogenated hydrocarbons and the most compatible with aluminum alloys. They have been used as propellants and refrigerants in contact with aluminum alloys in many applications. See Freon and Ha&mated Hydracarbons. FLUORINE. F. In laboratory tests, II00 alloy was resistant to fluorine at temperatures up to 4SOC (842F). In the presence of moisture. hydmfluoric acid is formed which corrodes aluminum alloys. Dry fluorine gas has been handled in aluminum alloy equipment. A durable protective coating is formed on the aluminum surfaces contacting the gas. See also Ref: (I) p. 133. (2) p. 297, (3) p. 35, (7) p. 95.
(continued)
619
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
for covering on lighter than air ships. See also Ref: (1) p. 134. (3) p. 35. HEPTYL ALDEHYDE. CH,(CHI)SCHO. num alloy separators. rectifier tanks. and tanks have been used with both crude and heptyl aldehyde. See also Ref: (3) p. 120. (7) Alumistorage refined p. 99.
cated that 1100 alloy was resistant to 10% solutions of gluconic acid at ambient temperature. Increase in temperature resulted in substantially increased corAluminum alloy equipment has rosion been used to produce gluconic acid from sugars by the fermentation process. Neutralization of gluconic acid to produce calcium gluconate is carried out in aluminum alloy equipment. See also Ref: (1) p. 133. (2) p. 332. (3) p. 129. (7) p. 97. GLUCOSE. C,H,>Oe H20. Glucose solutions have been stored in alloy 6061 tanks. Alloy 356.0 valves habe been used for handling glucose solutions. See also Ref: (I) p. 133. (3) p. 12.3. GLUE. Originally an impure form of gelatin. In more modem times, glue is one of many types of adhesives uxd for bonding. In laboratory tests, most adhesives were found to be either innocuous or pmrectne to aluminum alloys. Houever. exceptions \rere found and included the alkaline water base latex adhesives, acetic anhydride adhesives, and adhesives that have been made electrically conductive by the addition of copper, silver. or carbon. Such adhesives ihould be used with caution and with the knowledge that corrosion could develop. Adhesives are used with aluminum alloys in many applications. See also Ref: (1) p. 133, (3) pp. 124. 199.231.2.33. (4) pp. 107. 11.5. R. L. Patrick, Editor. Treatise of Adhesion and Adhesives, Vol. 111. Marcel Dekker. New York, 1973.
H
HALOGENATED HYDROCARBONS. Aluminum alloys are usually resistant to pure halogenated hydrocarbons and other organic chemicals containing halogens under most conditions particularly at room temperature or lower. Under certain conditions some of these hydrocarbons may produce a rapid rate of corrosion of aluminum or a violent reaction. Hence, the service conditions to insure safety should be recognized or established before aluminum alloys are used with any halogenated hydrocarbon. Halogenated hydrocarbons may decompose by hy dmlysis if water is present or by other processes to yield mineral acids such as hydrochloric acid. These acids corrode aluminum alloys because they destroy the protective surface oxide fdm naturally present that provides inherent resistance to corrosion. Cormsion of aluminum alloys by these acids may also promote reactions of the hydrocarbons themselves hecause aluminum halides formed bv corrosion are catalysts for some of these reactions (e.g. AICI, for a Fried&Crafts reaction). In some instances. aluminum alkyls may be produced. Because of the rapid rate of evolution of heat, corrosion of aluminum and reaction of a halogenated hydrocarbon. once initiated, may tend to become autocatalytic. The reactivity of aluminum alloys with halogenated hydrocarbons decreases generally in the order of increasing chemical stability of these hydrocarbons, which may be established precisely by themwdy namic data whenever these data are available, or qualitatively by the structural formulas of the hydracarbons and by the halogens they contain. Thus. aluminum is most resistant to hydrocarbons halogenatsd with fluorine followed in order of decreasing resistance to those with chlorine. bromine and iodine. It is also resistant to highly polymerized halogenated hydrocarbons. reflecting the high degree of chemical stability of these materials. The behavior of aluminum alloys in a mixture of halogenated hydrocarbons. or mixtunzs of these hydrocarbons with other organic compounds cannot be predicted fmm its behavior with each of the compo. nents. Some mixtures (e.g. of methyl alcohol and carbon tetrachloride) produce rapid corrosion of some aluminum alloys at ambient temperature even though the components alone do not. The resistance of aluminum alloys to halogenated hydrocarbons tends to decrease as the temperature is raised and the rate of corrosion in many liquid halw genated hydrocarbons remains low until the boiling point is reached; in some, it is low or non-existent even at this temperature. Other factors that affect Rsistance include the presence of an inhibitor and the purity of a halogenated hydrocarbon; amines or various heterocyclic compounds have been effectively used as inhibitors in certain cases. Aluminum in a finely divided form, as in a powder, should not be exposed to a halogen&d hydrocarbon. The likelihood of creating a violent reaction that may lead to an explosion is increased when aluminum with a large surface area is exposed to a small volume of a halogenated hydrocarbon, and even more so when this operation is carried out under pressure. Specific entries in this book for fluorinated hydrocarbons such as Freons and inhibited halogenated hydrocarbons such as solvents for degreasing illustrate applications with halogenated hydrocarbons. In summary, the service conditions to insure safety should be recognized or established before aluminum alloys are used with any halogenated hydrocarbon. With respect to aluminum and a specific halogenated hydrocarbon under specific conditions. aluminum producers may be able to submit useful data. HELIUM. He. Aluminum alloys have been used for heat exchangers in the manufacture of helium and
n-HEX&NE. CH,.(CH2),CHI. Aluminum alloy heat exchangers have been used with n-hexane. See also Ref: (7) pp. 98, 99. HONEY. Contains mainly levulose and dextrose; some sucrose. wax. pollen. and other organic matter. Aluminum alloy equipment has been used for pasteurizing honey. Honey has been packed in aluminum containers. See also Ref: (I) p. 134, (3) p. 203, (6) p. 10. HYDRAZINE. H2NNHI. In laboratory tests, hydrazinc caused mild attack of 3oQ3 and 5154 alloys at ambient temperature. The action of hydrazine on aluminum alloys is increased by the presence of moisturn resulting in hydrolysis. See also Ref: (1) p. 134, (2) p. 353. (3) p. 44, (7) p. 101. HYDROARIETYL ALCOHOL. C,&CH,OH. Aluminum alloys have been used for piping, full flow filters, final condensers, and steam heated storage tanks in the production of hydmabietyl alcohol. See also Ref: (3) p. 115. (7) p. 101. HYDROCARBONS. Organic compounds containing hydrogen and carbon. In laboratory tests. alloy 1 I00 and 3003 were resistant to most hydrocarbons. Aluminum alloys have been used to piping, pumps, condensers, *eat exchangers, valves, impellers. ducts, fan and blowers. storage tanks, and shipping containers for handling hydrocarbons. See also Ref: (3) p. 101. HYDROCHLORIC ACID. HCI. Aluminum is carroded by hydrochloric acid. The rate of attack increases with acid concentration and temperature. Metal purity plays a significant role in the degree of Inattack by hydrochloric acid. creasing purity of the aluminum decreases the rate of attack by hydrochloric acid significantly. Inhibitors can be effective in reducing the corrosive effects of hydrochloric acid, particularly in dilute (< 10%) solutions. Such inhibited acid has been used to clean aluminum equipment and containers. See alw, Ref: (1) p. 134, (2) p. 359. (3) pp. 22.37. 244, (4) pp. 15, 16, 17. 27, 29. 30. 31. 34. 73. 74, 97, 127, (7) p. 101. HYDROCYANIC ACID. HCN. In laboratory tests, alloys 3003. 5052. and 6053 were resinant to a 77% solution of hydmcyanic acid at ambient temperature. Hydrocyanic acid has been processed in aluminum distillation towers. reflux condensers, final condensers. adsorption towen. heat exchangers. tankage, shipping drums, and piping. See also Ref: (1) p. 134. (2) p. 368, (3) p. 51. (7) p. 101. HYDROFLUORIC ACID. HF. Aluminum alloys are corroded by hydrofluoric acid. With most alloys, the action is uniform and imparts a bright silvery appearance. This acid has been used as an etchant on aluminum in preparing decorative patterns. See also Rrf: (I) p. 134. (2) p. 372. (3) p. 36, (4) p. 86. (7) pp. 101, 103. HYDROGEN. Hz. Aluminum alloy equipment has been used to produce and to store hydrogen. See also Ref: (2) p. 379. (3) p. 35. (7) p. 103. HYDROGEN CHLORJDE GAS. HCI (SEE HYDROCHLORIC ACID). Aluminum alloys are COT-
GLYCERIN. CH,OH.CHOH.CH,OH. Laboratory tests indicate that alloy 3003 is resistant to gly cerin solutions at ambient and boiling temperatures. Aluminum alloys have been used for still,. condensers. heat exchangers, storage tanks, and tank cars for handling glycerin. Alloy 356.0 valves have also been used. See also Ref: (1) p. 133. (2) p. 337. (3) pp. 115. 240. (7) p. 97. GLYCEROPHOSPHATE. H,O,IOCH~~CHOH~ CH@H. Glycerophosphate has been shipped in ahminum alloy containers. See also Ref: (3) p. 137. GLYCOLIC ACLD. HOCH&OOH (Hydmxyacetic Acid). In laboratoty tests, glycolic acid was corrosive to 3003 and SlS4 alloys at IO0C (212). Glycolic acid solutions have been stored and shipped in aluminum alloy containers. See also Ref: (1) p. 133. (3) p. 129, (7) p. 105. GRAPEFRUIT JUICE. Laboratory tests indicated that 1100 alloy was resistant to grapefruit juice at ambient and refrigerated temperatures (see Fruit and Fruit Juices). See also Ref: (4) p. 90, (6) p. 10. GRAPE JUICE. In laboratory tests. unfermented grape juice caused mild attack (2 mpy) of llC0,3003. and 3004 alloys at room temperature. Aluminum alloy equipment has been used for harvesting grapes and grape juice has been transported in aluminum alloy tank cars (see Fruit and Fruit Juices). See also Ref: (4) pp. 88, 91. (6) p. IO. GRAPHlTE. Alloys 3003. SIM and 6061 were resistant to solid graphite in laboratory tests under conditions of 100% relative humidity at ambient temperature and 54C (130F). Other laboratory tests have shown that graphite smears on aluminum are carmsive because of galvanic corrosion of the aluminum. See also Ref: (3) p. 50, (5) p. 13. GUM ARABIC. A dried gummy exudation from the stems and branches of Acacia. Aluminum alloy containers have been used for storing gum arabic solutions. See also Ref: (1) p. 134, (3) p. 226.
(continued)
620
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
80%) caused mild attack ( - 3 mpy) of 3003 alloy. At 100C (212F). aqueous solution of lactic acid was vety corrosive with the maximum attack occurring at about 5% concentration. See also Ref: (1) p. 135, (2) p. 417, (3) pp. 22, 129. (4) pp. 25. 26. 28. 29.30.31. 62. 92. 97. 102. (7) p. 111. LARD OIL. Lard oil has been handled in aluminum alloy equipment. See also Ref: (6) p. 12. LATEX. Principally isoprene polymers. In laboratory tests, latex with pH 10 caused mild attack of 3003 alloy at ambient temperature. Aluminum alloy tanks and steam-jacketed kettles have been used in storing and processing latex. Aluminum alloy cups have been used for collecting latex from rubber trees. See also Ref: (3) pp. 103. 125, 227. LEAD ACETATE. Pb(C2H,0&.3Hz0. Solid lead acetate caused mild attack ( -4 mpy) of alloys 3003.
5154 and 6061 at ambient temperature. but was carin laborarosive to the same alloys at WY (130F) tory tests conducted under conditions of
mded by hydrogen chloride gas. The reaction becomes more rapid as temperature is increased. Aluminum equipment has been used with dry hydrogen chloride gas at 288C (SWF). See also Ref: (2) p. 383. (3) p. 36, (7) p. 103. HYDROGEN CYANIDE GAS. HCN (SEE ALSO HYDROCYANIC ACID. In laboratory tests, alloy 3003 was resistant to hydrogen cyanide gas at ambient temperature. Aluminum alloy heat exchangers. reactor towers, tanks. and piping have been used in the manufacture of hydrogen cyanide gas. See also ReI: (2) p. 368, (3) p. 51. HYDROGEN PEROXIDE. H,Oz. In laboratory tests, alloys lC60. 5OS2 and 6063 were resistant to chloride free hydrogen peroxide at ambient temperature. Aluminum alloy distillation towers, heat exchangers, storage tanks. piping. tank cars and shipping drums have been used with hydrogen peroxide. Alloy 1060 has been preferred for long term storage, whereas, the SXXX series alloys often have been used for short term storage. Alloy 6063 has been used for piping. See also Ref: (I) p. 134. (2) p. 391. (3) pp. 39, 234. (4) p. 55. (7) p. 103. HYDROGEN SULFIDE. H,S. In laboratory tests, aqueous solutions of hydrogen sulfide and hydrogen sulfide gas caused mild attack ( - 2 mpy) of alloys II00 and 3003 at ambient temperature. Aluminum alloy storage tank roofs for sour crude oils, bubble caps. dnd heat exchangers have been used in refinery service handling hydrocarbon liquids and vapors containing hydrogen sulfide. See also Ref: (1) p. 134. (2) p. 3%. (3) pp. 40. 214. 223. 234, (7) p. 103.
[RON SULFIDE, FeS. Dly iron sulfide has been shipped in aluminum alloy containers. In laboratory tests, iron sulfide accelerated corrosion of contacting aluminum alloys as the result of galvanic action. See also Ref: (3) p. 84. ISOAMYL ACETATE. (CH,COO .CH,. CH*CH(CH,),. Laboratory tests showed that 3003 and 5052 alloys were resistant to isoamyl acetate at temperatures up to and including the boiling temperature. See also Ref: (3) p. 136. (7) p. 107. ISOAMYL ALCOHOL. (CH,)lCHCHICHzOH. Laboratory tests indicated that alloy 5154 was resistant to 85% isoamyl alcohol at 93C (2OOOF). See also Ref: (3) p. 113. ISOBUTYL ACETATE. CH, COO. CHz. CH(CH&. Aluminum alloy tank cars have been used to transport isobutyl acetate. See also Ref: (7) p. 107. ISOBUTYL ALCOHOL. (CH,)$H.CH,.OH. Limited laboratory tests indicated that 3003 alloy was resistant to isobutyl alcohol at ambient temperature, but is corrosive ( - 18 mpy) at elevated temperature 204C (4OOF). See also Ref: (3) p. 113. ISOBUTYRIC ACID. (CH,), CH.COOH. Isobutyric acid has been stored in aluminum alloy tanks and handled in aluminum alloy piping. See also Ref: The Corrosion of Light Metals (p. 14) Goddard, Jepson, Bothwell and Kane. ISOEUGENOL. C,,,H,,02. Isoeugenol has been stored and shipped in aluminum alloy containers. See also Ref: (3) p. 118. ISOOCTMOIC ACID. (CH,)zCH(CH1),COOH. Aluminum alloy containers have been used for storage and handling of isooctanoic acid. ISOPROPYL ALCOHOL. CH,CHOHCH,. Laboratory tests showed that alloy 3003 was resistant to isopropyl alcohol at IWC (212F) and 204C (4WF). See also Ref: (1) p. 135. (3) p. 113. (7) p. 109. ITACONIC ACID. CH,C(COOH)CH&OOH. Aluminum alloy pans have been used in the pmcessing of itaconic acid.
100% relative humidity. In other laboratory tests. alloy 3003 was resistant to 0.1% aqueous solution of lead acetate, while 1.0% and 10% solutions were corrosive at ambient temperature. See also Ref: (1) p. 135. (3) p. 81, (7) p. 111. LEAD AZIDE. Pb(N,)> Aluminum alloy trays have been used for drying lead azide at temperatures not exceeding WC (140F). See also Ref: (3) p. 81; H. Kast and H. Heid. Z. Angew. Chem. 38; pp. 43-52 (1925). LEAD MONOXIDE. PbO. Alloys 3003 and 5154 were resistant to solid lead monoxide in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (1) p. 135. LEAD NITRATE. Pb(NO,)z. Solid lead nitrate was very corrosive (more than 50 mpy) to 3003. 5lS4 and 6C61 alloys in laboratory tests under conditions of 100~0 relative humidity at ambient remperature. See also Rrf: (31 p. 81. (7) p. 113. LEAD OXIDE. Pb,O,. Alloys 3003.5154 and 6061 were resistant to solid lead oxide in laboratory tests under conditions of 100% relative humidity at ambient temperature and at 54C (13OOF). Priming paints containing lead should not be used on aluminum alloys because of the possibility of accelerated corrosion. See also Ref: (3) p. 238. LEAD TETRAJ?THYL. Pb(CzHs),. Laboratory tests showed that 3003 alloy was resistant to gasoline containing lead tetraethyl at ambient temperature. Aluminum alloy tank trucks and aircraft gasoline tanks have been used to handle leaded gasoline. In the presence of a separated water phase. some by products of the lead tetraethyl, such as lead bromide. accumulate in the water and cause corrosion. See also Ref: (1) p. 135. (3) p. 218. LEATHER. Aluminum alloy equipment has been used in handling leather. See also Ref: (9) pp. 42.43. LEMON JUICE. In laboratory tests, alloy 3003 was resistant to lemon juice at ambient and Rfrigerated temperatures. Domestic aluminum alloy juicers for lemons have been used (see Fruits and Fruit Juices). See also Ref: (1) p. 135, (4) pp. 88, 90. (6) p. 10. LIME. CaO. Solid lime caused mild attack (- 1 mpy) of alloy 3003 in laboratory tests conducted
under bient conditions temperature. of 100% relative humidity (I) p. at amSee also Ref: 128. (2) p.
I
ICE. Aluminum alloy equipment has been used in the manufacture of w and for refrigeration units. See also Ref: (3) p. 28. (4) p, 49. ICE CREAM. Aluminum alloy trays. molds, pans .md freezer components hake been used to handle ice cream. See also Ref: (4) pp. 102. I IS. (6) p, I I. INK. Laboratory tests have indicated that inks vary widely in their corrosivity to aluminum alloys. Generally. writing inks have been found to be corrosive, while marking inks are not. However, in view of the wide variability. it is desirable to conduct preliminary tests to establish the suitability of aluminum alloys Hith a particular ink. Aluminum alloy tanks have been used for transporting printing ink. See also Ref: (I) p. 134, (3) p. 199. 238. (NVERT SUGAR. A mixture of about 50% dextrose and 50% levulose obtained by hydrolysis of sucrose. Aluminum alloy piping and tanks have been used to handle invert sugar. IODINE. I> In laboratory tests, alcohol solutions of iodine were comxive to aluminum alloys. See also Ref: (1) p. 134, (2) p. 406. (3) p. 36. (7) p. 107. IODOFORM. CHI,. Solid iodoform caused moderate attack ( - 7 mpy) of alloy 3003 in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. CAUTION: See Halogenated Hydrocarbons. See also Ref: (I) p. 135. (3) p. 106. (7) p. 107. IRON OXIDES. FexO,,Fe,O,. Alloys 3003 and 5154 were resistant to solid ferric oxide in laboratory tests under conditions of 100% relative humidity at ambient temperature. See also Ref: (1) p. 135, (3) p. 83.
K
KEROSENE. Kerosene has been processed and handled in aluminum alloy equipment. Aluminum alloys have also been used for vapor degreasing equipment. See also Ref: (1) p. 135. (3) pp. 218, 219. KIPPERS. Kippers have been packed in aluminum alloy cans. See also Ref: (4) pp. 106, 108. (6) p. 12.
L
LACQUERS. May contain nitmcellulose or a viscous liquid obtained from plants plus diluents. plasticizers. resins and pigments. Lacquers have been used extensively for coating aluminum alloys. Aluminum alloys have been used for the production, handling, and storage of lacquers. See also Ref: (1) p. 135, (3) p. 225. (4) pp. 48, 79. 95. %, 97, 103, 105, 109, 110, 114, 115. 117, 119, 137, 140, 141. di-LACTIC ACID. CH,.CH(OH).COOH. In labxatory tests, aqueous solutions of lactic acid 10.0.5 to
133, (3) pp.
229, 242.
(continued)
Nonferrous Metals and Alloys TABLE 5.2: ALUMINUM ALLOYS-ALUMINUM ASSOCIATION (continued)
621
LIME JUICE. Laboratory tests showed that alloys 3003. 5052 and 5086 were resistant to lime juice at ambient and refrigerated temperatures. See also Ref: (6) p. IO. LIME MORTAR. Contains hydrated lime, sand. Portland cement. coloring. During the period when mortar is liquid. aluminum alloys show etching which ceases when the mortar dries because of the formation of a protective film. It is good engineering practice to protect aluminum alloys contacting mortar in a faying surface to minimize crevice corrosion. See also Ref: (1) p. 129. (2) p. 161. (3) p. 72. LIMESTONE. CaCO,. .Aluminum alloy equipment has been used in handling limestone. Aluminum alloy building products have been used in contact with limestone. See also Ref: (3) p. 76. LINSEED OIL.. Contains glycerides of linoleic, oleic. stearic. palmitlc and myrinic acids. In laboratory tests, alloy 3003 was resistant to linseed oil at 300. 350 and 380C (572, 662. and 716OF). In the same tests, linseed oil vapors at these temperatures were corrosive to 3003 alloy. Aluminum alloy vessels have been used to heat linseed oil to 25OC (482F). See also Ref: (1) p. 135. (2) p. 427, (3) p. 238, (7) p. 113. LITHIUM CHLORIDE. LiCI. Alloys 3003, 5154 and 6061 were resistant to solid lithium chloride in laboratory tests conducted under conditions of 100% relative humidity and at ambient temperature. In the same tests conducted at 41C (130F). solid lithium chloride caused mild attack of the same alloys. In I % to 40% aqueous solutions. lithtum chloride caused mild attack (- 3 mpy) of 3003, 252 and 6061 alloys at ambient temperature and at joC (122F). Local pitting was encountered in the solution tests. See also Ref: (I) p. 135, (2) p. 429, (7) p. 113. LITHOPONE. A mixture of zinc sulfide. barium sulfate and some zinc oxide. Solid lithopone caused mild attack ( - 1 mpy) of 3003 and 5154 alloys in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Aluminum alloys have been used for pipe lines and driers in the manufacture of lithopone. See alw, Ref: (1) p. 135. (2) p. 433. (3) p. 238. (7) p. 115. LUBRICATING OILS. Laboratoty tests indicate that alloy 3003 was resistant to most lubricating oils at ambient temperature and at 66C (150F). Aluminum alloys generally do not accelerate oxidation of lubricating oils. Aluminum alloy tank trucks and cans have been used for lubricating oils. Alloy 356.0 valves have been used for handling lubricating oils. See also Ref: (1) p. 135. (3) p. 220.
MAGNESIUM NITRATE. Mg(NO& .6 H>O. Alloys 3003. 515-I and 6061 were resistant to solid magnesium nitrate at ambient temperature but suf. fered mild attack ( - 2 mpy) at 54C (130F) in laboratory tests conducted under conditions of 100% relative humidity. In other laboratory tests, 3003 alloy was resistant to I%, 5% and 10% solutions at ambient temperature. See also Ref: (I) p. 136. (3) p. 75, (7) p. 117. MAGNESIUM OXIDE. MgO. Alloys 3003. 5154 and 6061 were resistant to solid magnesium oxide in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature and at 54C (130F). See also Ref: (3) pp. 72. 230. MAGNESIUM SILICATE. MgSiO,. Alloys 3003. 5154 and 6061 were resistant to solid magnesium silicate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature and at 54C (130F). See also Ref: (3) p. 76. MAGNESIUM SULFATE. MgSO,. 7H,O. In limired laboratory tests, 1100 alloy was resistant to aqueus solutions of magnesium sulfate (O.ooOl% to 10%) at ambient temperature. See also Rrf: (1) p. 136. (2) p. 440. (3) p. i5, (7) p. 117. MALEIC ACID. HOOCCH: CHCOOH. Alloys 3003 and 5154 were resistant to solid maleic acid in laboratory tests conducted under conditions of 100% relative humidity and ambient temperature. In other laboratory tests, 30% aqueous solutions of maleic acid caused mild attack ( -5 mpy) of I IO0 alloy It 52C (126F). Other laboratory tests conducted at IOOC (212F) showed that maleic acid uas crwsi\e to 1100 alloy See also Ref: C p. 136. I) (3) p. 131. (7) p. 117. MALEIC ANHYDRIDE. (CHCO)>O. Alloys JO03 and 5154 were resistant to solid m&ctc anhydride in laboratory tests conducted under conditions of 100% relative humidity at ambient tempemrure. .Mlren maleic anhydride has been stored in 3lumium alloy tanks. See also Ref: (I) p. 136. (3) p. 131. I-) p. I Ii). I-MALIC ACID. HOOCCH(OH) CH:COOH. In laboratory tests, aqueous solutions (up to 55%) of malic acid caused mild attack ( - 2 mpy) of 1100 3110~ at ambient temperature. In the same tests. these * lotions were corrosive to 1100 alloy at 100C (212F). See also Ref: (1) p. 136. (3) pp. 131. 209. (4) pp. 25, 26, 29, 30, (7) p. 119. MALONIC ACID. HOOC CH1. COOH. Limited laboratory tests indicated that 3003 alloy was resistant to malonic acid at ambient temperature. See also Ref: (1) p. 136, (3) p. 130. (7) p. 119. MAPLE SYRUP. In laboratory tests, alloy 1100 syrup at ambient was resistant to maple temperature. Aluminum alloys have been used for evaporators and other equipment in processing maple syrup. See also Ref: (I) p. 136, (6) p. 10. MARGARINE. A mixture of natural or hydrogenated animal or vegetable fats plus colonng and flavoring. In laboratory tests, alloy 3003 was resistant to margarine at ambient and refrigerated temperatures. Aluminum alloys have been used for storing and packaging margarine. See also Ref: (3) p. 206. (4) pp. loo. 103. MEAT. Aluminum alloy equipment has been used in the meat industry for steam jacketed pans. cookers. wagons. rods. racks, boilen and Taste barrels. Aluminum alloy foil has been used to wrap meat to be frozen. See also Ref: (1) p. 136. (J) pp. 198, 206. (4) pp. 72, 78. 80. 99. 106, 109. (6) p. 12.
MERCURY. Hg. The actwn of metallic mercury on aluminum is unique. It rends I amalgamate with aluminum to produce 3 surface that corrodes at an extraordinarv rate in the presence of moisture uith the production of voluminous columnar corrosion products. When that reaction is rtarted. the rxe of corrosion is dependent upon reletne humidity. When dry. metallic mercury reacts onl! nlth difficulty because of the oxide film on the aluminum surface. Traces of acidity or halides on the surfax dive rire 10 raped attack. Solutions containing mercu~ ions tend to cause rapid pitting of aluminum alloys because of plating out of mercury in localized areas. Mercury can be removed from aluminum wrf~es by treatment uith -0% nitric acid. Mercury can be distilled away from 3 aluminum curf~e by trentmenr uirh steam or hot a,r. See also Rrf: (I) p. 136. 12) p. 440. (3) p. 80. MERCURY SALTS. In laboratory tests. aqueous solurions of mercury salts uere \ery corrosive to aluminum alloys. See also Ref: (1) p. 136. (2) p. 444. (3) pp. <SO. 132. 238. METHANE. CH+ Aluminum alloys have been used for pressure vessels in the storage and transport of compressed methane gas. Aluminum alloy tanks and pipe lines have been used extensively for handling liquid methane at temperatures as low as -1bOC (-256F). See also Ref: (I) p. 136, (3) pp. 103, 214, (7) p. 121. METHYL ALCOHOL. CH,OH. Laboratory tests showed that 1100 alloy was resistant to commercial absolute methanol at ambient and boiling temperatures. In the same tests, aqueous solutions of methanol varied in their corrosivity with concentration. Anhydrous methanol at the boiling point was cormsix. Alummum alloys have been used for drums. tanks and piping for processing and handling methyl alcohol. See also Ref: (1) p. 137. (2) p. 449, (3) p. 112. (7) p. 121. METHYLAMINE. CHINHZ. Aluminum alloyequipment has been used in refrigeration systems perating uith methylamine. See also Ref: (1) p. 137. (2) p, 452. (3) p. 143. (7) p. 123. METHYL CHLORIDE. CH,CI. Methyl chloride. under certain conditions, reacts with aluminum alloys to form metallo-organic compounds which are spontaneously explosive up exposure to air. Aluminum is not recommended for use with methyl chloride. CAUTION: See Hnlogenated Hydrocarbons. See also Ref: (I) p. 137. (2) p. 454. (3) p. 105. (7) p. 123. METHYLENE CHLORIDE. CH#:. Limited laboratory tests indicated that alloy 3003 *as resistant to methylene chloride at ambient temperature and at the boiling point. Inhibited methylene chloride has been shipped in aluminum alloy containers. CA.!/TION: See Halogenated Hydrocarbons. See also Ref: (1) p. 137. (2) p. 437. (3) p. 106, (7) p. 12.5. METHYL ETHYL KETONE. CH,XO.CH>XH.,. In lnboratoly tests, alloy 3003 was resistant to condensing vapors of methyl ethyl ketone. Methyl ethyl ketone has been distilled and condensed in aluminum alloy equipment. See also Ref: (1) p. 137. (3) p. 121, (7) p. 125. METHYL laboratory formate at 137. (3) p. FORMATE. HCOOCH,. In limited tests, 3003 alloy was resistant to methyl ambient temperature. See also Ref: (I) p. 136. (5) p. IO. (7) p. 125.
M
MAGNESIUM CHLORIDE. MgCIz. Alloy 3003 was resistant to solid magnesium chloride in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests. alloy 1100 was resistant to aqueous solutions (up to 10%) of magnesium chloride at ambient temperature. Localized pitting was encountered in the aqueous solution tests. See also Ref: (1) p. 136. (2) p. 435. (3) pp. 73. 230. (7) p. 117. MAGNESIUM HYDROXIDE. Mg(OH)I. Limited laboratory tests showed that magnesium hydroxide is corrosive to 1100 alloy at ambient temperature and that the corrosion rate increases as the pH of the solution increases. See also Ref: (1) p. 136. (7) p. 117.
METHYL. GLYCEROL. CH,(OH)CH(OH)COOCH,. Aluminum alloy pipe and containers have been used for handling methyl glycerol.
(continued)
622
Corrosion
Resistant
Materials
Handbook
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(Continued)
METHYL ISOBUTYL KETONE. (CHJzCHCHICOCH,. In laboratory tests, alloy 3003 was resistant to methyl iwbutyl ketone under boiling and condensing conditions. Methyl isobutyl ketone has been handled in aluminum alloy tanks and piping. See also Ref: (7) pp. 124. 125. METHYL METHACRYLATE. CH2. C. CH, COO CH, Methyl methacrylate has been processed in aluminum alloy equipment and handled in aluminum alloy containers. See alw, Ref: (3) p. 137. METHYZ SALICYLATE. C,H,OHCOOCH,. Limited laboratory tests indicated that alloy 6061 was resistant to methyl salicylate at ambient temperature. Methyl salicylaw has been shipped in aluminum alloy containers. See also Ref: (3) p. 137. MILK. In laboratory tests. alloys 1100 and 3003 were resistant to sweet milk at ambient and boiling temperatures. Aluminum alloys have not affected the taste of milk. Aluminum alloy equipment has been used for handling whole milk and sweetened or unsueetcned condensed milk. Powdered milk has been dried in aluminum alloy towers. Foil hoods have been used to protect and seal bottles. Fresh milk has been transported in aluminum alloy equipment. See also Ref: (I) p. 137. (2) p. 463. (3) p. 204. (4) pp. 78. 84. 98. 100. 101. 102. 106. 109. (6) p. II. (7) p. 127. MLVERAL OILS. A mixture of liquid hydrocarbons from petroleum. Laboratory tests indicate that man? mineral oils are protective fo aluminum alloys. Mineral oils have been stored and transported in aluminum alloy equipment. Alloy A356.0 valves have been used for handbng mineral oils. See also Ref: (I) p. 137. (3) p. 102. MOLASSES. Alloys 3003, 5052, 5086 and 6061 were rerisfant to molasses in laboratory tens at ambient and 46C (I 14F) temperatures. Copper from earlier processing equipment can make molasses corrosive to aluminum alloys. It is dewable to resf a source of mulasses prior to handling in aluminum equipment. Aluminum alloys hale been used for fermenting vats. piping. containerc dnd tanks with molasses. See also Ref: (1) p. 137. (2) p. 474. (6) p. 10. (7) p. 127. MOLYBDENUM DISULFIDE. MO&. In laboratory tests. molybdenum diwlfide accelerated corxrlon of aluminum alloys in the presence of a conductive electrol~?e. See also Ref: (3) p. 82.
sion where contacting the mortar. See also Ref: 137. (2) p. 161, (3) p. 72.
(1)p.
temperature and was corrosive at 54C (13OF). See also Ref: (1) p. 137, (3) p. 84. NICOTINE SULFATE. (C,oH,,N?j2. HISO+ In laboratory tests. alloy 3003 was resistant to a 40% solution of nicotine sulfate at 204C (400F). See also Ref: (I) p. 137. (3) p. 149. NITRIC ACID. HNO,. In laboratory tests. the action of nitric acid on aluminum alloys varies with concentration and temperature and is increased by agitation or the presence of nitrogen oxide. At ambient temperature. the rate of attack of I100 alloy shows a maximum at 20% concentration. Above 82%. the attack is between 0 and 5 mpy. Aluminum alloys have been widely ued for storing and shipping fuming nitric acids. Red fuming nitric acid Inhibited with hydrofluoric acid is compatibile with all aluminum alloys to at least 71C (160F). Solutions of the lower oxldes of nitrogen and the gases themselves have mild corrosion effects on aluminum alloys. As a rerulf. aluminum alloys have been used for the catal}tlc oxidation of ammonia in the production of nitric acid. Aluminum alloy equipmrnt used in this prwe\s has included piping for wpplying ammonia dnd {oxygen to the oxidizing reactor. shwlumd yas mirrerc. refrigeration tanks for srorirq raw matuuls. principal parts of the autoCIZW. refining columns, intermediate reservoin, heat exchangers for cooling the nitric acid before storage, tanks and drums for storage and transportationof rheconcentrated acid. Seealso Ref: (1) p. 138. (2) p. 480, (3) pp. 22, 45. 244, (4) pp. 19, 20, 21. 29, 30. 31. 34. 74. %, (7) p. 130. NITRIC SULFURIC ACIDS. (MIXED ACID: NITRATING ACID). In laboratory tests. mixed acids had varying corrosive effects on aluminum alloys which were dependent upon the composition of the mired acids. Mixed acid containing 85% HNO,. 12% H2S0,. and 3% water caused mild attack ( - 2 mpy) of I IO0 alloy while an 80. IS. 5 mixture caused moderate attack (- 10 mpy) of alloy IloO. Mixtures containing 60% HNO,. 38% H+O,. and 2% H:O were corrosive while those containing 45% or less HNO, were very corrosive. Hydrofluoric acid has been used as an inhibitor for the less cormsive mixed acids. Aluminum alloy tanks have been used to handle mixed acids. See also Ref: (2) p. 466, (7) p. 127. NITROBENZENE. C,Hs NO>. In laboratory tests, alloys 3003, SO52 and 6061 were resistant to nitrobenzene at temperatures ranging from ambient to the boiling point. See also Ref: (I) p. 138, (2) p. 488, (3) p. 141, (7) p. 131. 2 NlTRO-I-BUTANOL. CH,CH2CHNOlCH,OH. Aluminum alloy equipment has been used to handle 2.nitro-I-butanol. NITROCELLULOSE. C,2H,eN,O,&EE ALSO CELLULOSE NITRATES). Nitrocellulose has been produced and washed in aluminum alloy equipment. Nitrocellulose lacquers and enamels have been used on aluminum alloys. See also Ref: (1) p. 138. (2) p. 490, (3) pp. 124. U2. (4) pp. 95. 140. 141. NITROETHANE. tests, alloy 3003 was (237F) and 204C stored in aluminum 141.
MUSTARD. Prepared mustard has been packaged in protected aluminum alloys. See also Ref: (1) p. 137. (3) p. 211. (6) p. 12. MUSTARD OIL. (Constituents: alkyl isothiocyanafe; carbon disulfide: alkyl cyanide). Mustard oil has been handled in aluminum alloy columns and condensers.
N
NAPHTHA. Limited laboratory tests indicated that alloys 1100, 3003, 5052 and 6061 were resistant to naphtha at ambient temperature. Naphtha has been handled in aluminum alloy stills, fractionators. dephlegmators, heat exchangers, condensers, and tanks. See also Ref: (7) pp. 128, 129. NAPHTHAIJZNE. C,,,&. Aluminum alloy stills, dephlegmators, fractionators, heat exchangers, and condenseen have been used at temperatures above 15oC (302F) in the production of naphthalene. Naphthalene has been stored in aluminum alloy tanks. See also Ref: (3) p. 105, (7) p. 129. NAPHTHEMC ACID. C;H,zOz. [n laboratory tests, alloy 3003 was resistant to commercial naphthenic acid at ambient temperature and 82C (18OF). Boiling naphthenic acid was very corrosive to 3003 alloy in the same test. Naphthenic acid has been transported in aluminum alloy tank cars. Aluminum alloy fractionating columns, condensers, receivers and piping have been used in the production and handling of naphthenic acid. See also Ref: (1) p. 137. (7) p. 129. NATURAL GAS. About 855 methane, 9% ethane. 3% propane, 2% nitrogen, 1% butane, occasionally helium or more nitrogen plus other contaminanfs. Natural gas has been handled in aluminum alloy equipment including processing equipment, disrillalion apparatus and pipe lines. Alloy .A3_%,.0valves have been used for handling natural gas. Large tanks on ships have also been used to transport liquid natural gas. See also Ref: (I) p. 137. (3) p. 214, NAVAL STORES. These include turpentine. rosin, copal. pentene. dipentene and pinene. In laboratory tests, alloy 3003 was resistant to products such as these. Naval stores have been processed and handled in aluminum alloy equipment including rosin kettles, evaporators, condensers. storage tanks, transfer lines, distillation equipment, piping and shipping containers. See also Ref: (3) p. 226. NEOPRENE. (CH,CCI:CHCH,).. In laboratory tests. various aluminum alloys were resistant to pure neoprene. However, the amount and type of filler materials were found to affect corrosion. See also Ref: (3) pp. 104. 110. 228. NICKEL COMPOUNDS. In laboratory tests, aqueous solutions of nickel salts at ambient temperature caused varying degrees (from less than I mpy to more than 60 mpy) of attack of 1100 alloy depending upon the concentration and the specific compound. Most solutions of nickel compounds are inherently corrosive to aluminum alloys. In laboratory tests conducted under conditions of 100% relative humidity at ambient and 54C (130F) temperatures, solid nickel chloride was very corrosive to alloys 3003, 5154 and 6061 at both temperatures, solid nickelous acetate caused mild attack of these alloys at ambient temperature and was corrosive (- 40 mpy) at 54C (130F). Solid nickelous nitrate caused mild attack at ambient
NH>CH>CH,OH (2 AMINOETHANOL). In labow rory tests. solutions of monoethanolamine have rc acted with aluminum alloys in much the same manner as ammonium hydroxide solutions. Solutions containing up to 50% monoethanolamine have an initial rapid reaction, but the aluminum develops a protective film that inhibits funher action. Medium strength solutions (- 15%) cause more corrosion while a film is forming than do either more dilute or more concentrated solutions. In greater than SO% solutions, initial cormsion is slight. The effects can be accelerated by elevated temperature. The presence of carbon dioxide or hydrogen sulfide in monoethanolamine solutions retards corrosion of aluminum alloys. Hence, aluminum alloy equipment has been used in natural gas processing plants employing monoethanolamine as an acid gas removal agent. See also Ref: (3) p. 145. (7) p. 127. MORTAR. In laboratory tests. conventional mortars react with aluminum alloys in the same manner as cement and concrete. While the mortar is liquid, etching of aluminum alloys occurs; but the reaction stops after the mortar sets. It is good engineering practice to protect the aluminum from crevice corro-
CH, CH]. NO*. In laboratory

resistant to nitmethane at 114C (400F). Nitmethane has been alloy tanks. See also Ref: (3) p.
2-NITRO-2 ETHYL-I, 3 PROPANEDIOL. CH,~OHC(C,H:,)NOJH,OH. Aluminum alloy equipment has been used to handle 2-nitro-2 ethyl-l. 3 propanediol. NITROGEN. N. Liquid nitrogen has been pro-
(Continued)
623
cessed and handled m aluminum alloy eqwpment. See also Ref: (II p. 138. (3) pp. 43. 214. NITROGEN TETROXLDE. YIO,. Nitrogen tetroride is handled in aluminum .~lluy missile fuel tanks under stringent moisture controlled conditions. See also Ref: (7) pp. 132. 133: Titan I1 Storable Propellant Handbook-Bell Aerospace Company. Buffalo, New York. Repon No. 811 l-933003. MTROGLYCERN. CIH;(ONOz),. Nitroglycerin hJs been handled ,n aluminum alloy containerr. pipe lines. Jnd tanks. See aiw Ref. (I 1 p. 138. (2) p. 497. (3) pp. 115. 112. (7) p. 133. NITRO~ETH.&~uYE. CH,NO!. Nitromethane has bwn stored in ,&mmum ~110) tanks. See r1l$o Ref: () pp. 132. 133. MTROPm&FFLYS. Organic compounds derived from paraffin h!drwarbons by replacement of one or more h!droyen atoms b) rl nitro (NO?) group. Controlled field renice reqts bhoued that nitroparsffins cduwd mdd atrack (If V03 a1lo.y. ,Nirroparalfins have been rtured I dlumlnum .dlo? tanks. MTROPHENOL. NO&H,OH. Alloy 3003 was r-esistant to solid p-nitmphenol in laboratory tests conducted under condirions of 100% relative humidity at ambient temperature. See also Ref: (1) p. 138. (2) p. 499, (3) p. 141. (7) p. 133. NITRO PROPANES (I- AND 2-j. CH,CHJHJN02. (CH3),CHNOl. In laboratory tests, alloy 3003 was resistant to nitm propanes under refluxing conditions and suffered mild attack under boiling and condensing conditions. Nitm pmpanes have been handled in aluminum alloy equip mew. See alw Ref: (7) pp. 132, 133. NITRO TOLUENES (0, m, p). NO&H,CH,. In laboratory tests, alloy 3003 was resistant to +nitm toluene at boiling and refluning conditions. Aluminum alloy equipment has been used to handle nitm toluenes. See also Ref: (2) p. 505, (3) p. 141. (7) p. 133. NITROUS OXIDE. NzO. Aluminum alloy retorts have been used in the manufacturing of nitrous oxide. See also Ref: (1) p. 138, (3) p. 47, (7) p. 135. NYLON. [CO(CH3,CONH(CHJ~NH].. Aluminum alloys have been used for tanks. piping, bins. railroad cam and tank cars for handling nylon. See also Ref: (3) p. 127.
was resistant to orange juice at ambient and refrigerated temperatures. Aluminum alloy equipment has been used for handling orange juice. Alummum alloy squeezers for oranges have been used a.s have foil closures for bottles of homogenized orange juice (see Fruit and Fruit Juices). See also Ref: (I) p. 138, (6) p. 10. ORES. Many ores have been handled in aluminum alloy equipment. e.g.. bauxite. Compocition and physical characteristics of the ore generally govern its suitability for use with aluminum alloys. ORLON. Acrylic fiber. a polymer containing at leti 85% acrylonitrile units (-CHzCH(CN)-). Aluminum alloys have been used in the manufacture, handling. storage. and shipment of orlon. .ReymrrrdTradeMlrr OxALlC ACID. HOOC.COOH.2 H>O. Solid oxa lit arId ~a3 cormwe t - 20 mpy) to 3003 allo! in lab oratoq tests conducted under conditions of 100% relative humidit) at ambient temperature. In other laborator? tests. aqueous solutions (0.1 to 12oi) were corrosive ( - 15 mpy) to 1100 alloy at ambient ten?perature. At 50cC (122F) and boiling temperatures. those solutions were corrowe IO 1100 allot. Oxalic acid has been handled in aluminum allot filter5 and cnstallizers. because aluminum salt) do not discolor the product. See also Ref: (1) p. 138. (2) p. 520. (3) p. 130. (4)pp. 22. 28, 29,30. 120. 121, 122. 123, 124. 12.5. 126. 127. 128. (7) p. 137. OXOGLUCOMC ACID. C,H,OO.. Aluminum alloys have been uwd in the fermentation process 01 oxoglucomc acid. OXYGEN. O*. Aluminum allo! equipment ha\ been used in the manufacture and transportation of liquid oxygen. Aluminum alloys are panicularly suitable for these apphcations since they retain mechanical properties at low temperatures. Alloy A356.0 valves have been used for handling liquid oxygen. See also Ref: (I) p. 138. (3) p. 38. (4) pp. 2. 117; Corrosion Effects of Liquid Fluorine and Liquid Oxygen on Materials of Construction, CORROSION, 17. No. 2. 80-82 (1961 February). OZONE. O1. Aluminum alloys have been used tn the construction of oronizers. See also Ref: (I) p. 139, (2) p. 524. (3) p. 38, (7) p. 137.
PARAFFIN. A wax consisting of a mixture of louer hydrocarbons with a softening point about SOC (122F) and having the general formula C.H,,,,. Paraffin has been processed and stored in aluminum alloy equipment. Block paraffin has been produced in aluminum alloy molds. See also Ref: (1) p. 139. (3) pp. 102.218,220. PARAFORMALDEHYDE. (CH,O),. Aluminum allo! equipment has hew uwd ro handle paraformaldehbde. Seealso Ref: (1)~. 139. (2)~. 52. 13Jp. 119. (71 p. 139. PARAL.DEHYDE. C&O,. Paraldehhde has been procersed in aluminum allo! equipment and handled in aluminum alloy drums. See also Ref: (1) p. 139. (3) p. 120. (7) p. 139. PEANUT OIL. Aluminum been used to handle peanut p. 872. alloy equipment has oil. See also Ref: (2)
PEMCtLLLI. CH(COOH).C(CH,),S.CH: N.CO.CH.NHCOR. Where R i, a side chain of varying identity. Penicillin has been produced in aluminum alloy equipment and packaged in vials with aluminum caps. See also Ref: (2) p. 529, (3) p. 146. PENTACHLOROETHANE. CCli.CHC12. Limited laboratory tests indtcated that alloys 3003. 5052 and 6061 were resistant to pentachlorwthane at ambient temperature and at 50C (122F). At the boiling temperature. pentachloroethane was vet corrosive to all alloys. CAUTION: See Halogenated Hydracarbons. See also Ref: (2) p. 530. (3) p. 109. (7) p. 139. PENTACHLOROPHENOL. Q&OH. Wood treated with pentachlorophenol or its sodium salt has been used in contact with aluminum alloy products. CAUTION: See Halogen&d Hydmcarbon See also Ref: (3) pp. 133, 242. (7) p. 139. PENTAERYTHRITOL. CrH,20+ Aluminum alloy filters have been used in the production of pentaerythritol. See also Ref: (3) p. 115. (7) p. 139. PENTAERYTHRITYL C5H eN40 1. Aluminum used forpentaery?hrityl pp. 115. 138. 142. TETRANITRATE. alloy containers have been tetranitrate. See also Ref: (3)
P
PAINTS. In laboratory tests, most paints were found to be protective to all aluminum alloys. Exceptions were those containing mercury, lead or copper compound pigments. These were corrosive. Aluminum alloy equipment has been used for process and storage tanks, pipe. heat exchanger tube. condensers. and reaction vessels in the paint industry. See also Ref: (1) p. 139, (3) p. 237, (4) pp. 95. 117, 119. 134. 137, 140. PALMlTIC ACID. CH,.(CH,),,.COOH. Palmitic acid has been shipped in aluminum alloy containers. See also Ref: (1) p. 139. (2) p. 274, (3) p. 127, (7) p. 139. PALM OIL. Containing palmitin, stearin. linolein. Palm oil has been handled in aluminum alloy equipment. See also Ref: (2) p. 872. PAPER. Mainly cellulose; clay, starch. fillers. Laboratory tests indicated that the corrosive effects of paper on aluminum alloys vary with composition of the papers. Paper when wet can cause corrosion of aluminum alloys by poultice action. Papers with controlled composition have been used to interleave aluminum alloy products. See also Ref: (10) p. 106.
0
OINTMENTS. Aluminum the packaging of ointments. alloys have been used for See also Ref: (10) p. 100. OLEIC ACID. CH,KH,)CH:CH(CH1)~.COOH. In laboratory tests, alloys 1100, 3003 and 6061 were resistant to oleic acid at ambient temperature. Oleic acid has been shipped in aluminum alloy tank cars. See also Ref: (1) p. 138. (2) p. 510. (3) p. 129, (4) p. 25. (7) p. 137. OLIVE OIL. Mixed glycerides of oleic. palmitic, linoleic. stearic and arachidic acids; squalene phytosteml. tocopherols. Olive oil has been processed and handled in aluminum alloy equipment. See also Ref: (I) p. 138. (2) p. 872. (3) pp. 129. 206. (6) p. Il. OMON JUICE. In limited laboratory tests. alloys 1100. 3003 and 5052 were resistant to onion juice at ambient temperature. See also Ref: (1) p. 138. ORANGE JUICE. In laboratory tests, alloy 3003
PENTANE. CH,.(CH&.CH,. In laboratory tests, 3003 alloy was resistant to pentane under reflurjng conditions. See also Ref: (3) pp. 103, 214, (7) p. 139. PEPPERMINT OIL. Aluminum alloy equipment has been used for stills. piping. drums, tanks. and condensers for handling peppermint oil. PERACETIC ACID. CHJO~O~OH. Peracetic acid has been shipped in aluminum alloy drums. See also Ref: (3) p. 126. PERCHLORK ACID. HCIO,. In laboratory tests. perchloric acid was very corrosive to aluminum alloys. See also Ref. (11 p. 139. (2) p. 533. (3) p. 37. (7) p. 139. PERCHLOROETHYLENE. See TETRACHLOROETHYLENE. See also Ref: (7) p. 139. PETROLEUM OR CRUDE OIL. A mixture of hydrocarbons obtained from an oil well. Usually an oil well also produces salt water brine. In general, these brines are corrosive to merals. Some brines are corrosive to aluminum alloys while others can be handled in aluminum alloy equipment. Tests are necessary
(continued)
624
Corrosion
Resistant
Materials
Handbook
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ture of phosphorus p. 48.
ASSOCIATION
sesquisulfide.
(continued)
POLYVIXYL ALCOHOL. (-CH,CHOH-).. A colorless plastic made bb the acidic or basic hydrolysis of a polyvinyl ester. usually the acetates. Polyvinyl alcohol ha2, been handled in aluminum alloy containers. POLYVIXYL BUTYRAL RESINS. Synthetic resins. Aluminum alloy containers have been used in handling polyvinyl butyral resins. See also Ref: (8) pp. 19. 199. POTASH ORE. Aluminum alloy equipment has been used in handling and transporting potash ore. It has also been used in many mine and mill building applications. See also Ref: (9) p. 34. POTASSIUM BITARTRATE. KHC,&Ob. In limited laboratory tests, dilute aqueous solutions of po. tassium bitartrate caused varied degrees of comxion of 3003 alloy at ambient temperature. 0.25% solutions caused moderate attack (- 7 mpy) while 1.8% solutions were corrosive. See also Ref: (3) p. 71. POTASSIUM BROMIDE. KBr. Limited laboratory tests indicated that potassium bromide solutions at ambient temperature have action on aluminum alloys similar to that of sodium chloride. See also Ref: (1) p. 140. (2) p. 585. (3) p. 63, (7) p. 147. POTASSIUM CHLORATE. KCIOj. Aluminum alloy dtying pans have been used in the commercial production of potassium chlorate. See also Ref: (1) p. 140, (2) p. 592. (7) p. 14i. POTASSIUM CHWRIDE. KCI. Alloys 3003 and 5154 were resistant to solid potassium chloride in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Granular potassium chloride has been handled in aluminum alloy hopper cars. See also Ref: (1) p. 140, (3) pp. 62, 63,214. (7) p. 147. POTASSIUM CHROMATE. K@3,. In laboratory tests, 3003 alloy was resistant to aqueous solutions (l-36%) of potassium chromate at ambient temperature. Potassium chromate has been used as an inhibitor in natural waters and chloride containing solutions carried in aluminum alloy piping and equipment. See also Ref: (1) p. 140, (3) p. 70, (7) p. 147. POTASSIUhI CYANATE. KCNO. Potassium cyanate has been prepared in aluminum alloy reactors. See also Ref: (3) p. 68, (7) p. 149. POTASSIUM DICHROMATE. K,Cr,O-. Potassium dichromate has been a u&accepted inhibitor for use with aluminum alloys in natural and salt waten. It has been used to inhibit the corrosion of aluminum alloy piping and equipment exposed to such waters. See also Ref: (1) p. 140. (2) p. 598, (3) p. 70. (7) p. 149. POTASSIUhI HYDROXIDE. KOH. In laboratory tests, potassium hydroxide was very corrosive to all aluminum alloys. See also Ref: (1) p. 140, (2) p. 606, (3) p. 61. (4) pp. 34, 35, 36, (7) p. 149. POTASSIUM IODIDE. KI. Limited laboratory tests indicated that potassium iodide solutions at ambient temperature have action on aluminum alloys similar to that of sodium chloride. See also Ref: (1) p. 140, (3) p. 63. (7) p. 149. POTASSIUM NITRATE. KNO,. AIloys 3003 and 5154 were resistant to solid potassium nitrate in Iaboratory tests conducted at 100% relative humidity at ambient temperature. In similar tests conducted at 54C (130F). solid potassium nitrate was very con sive to alloys 3003 and 5154. Aluminum alloy equip-
with the product of a specific oil field before using aluminum alloy equipment to handle oil field brines. The crude oil may also contain appreciable amounts of sulfur compounds in which case it is designated as sour. Sour crudes are more corrosive to metal than are sweet crudes. Aluminum alloys have found increased use in the petroleum industry as a result of their superior corrosion resistance compared to steel. They have been used for pipe lines, distillation columns, heat exchangers, storage tanks, piping and valves. A corrosion hazard to aluminum allovs is iron sulfide scale that may be deposited on ah&nun alloy equipment from sour products previously in contact with steel equipment. See also Ref: (I) p. 139, (3) pp. 102, 214. 216. PETROLEUM JELLY. Purified mixture of semisolid hydrocarbons. chiefly alkanes. Laboratory tests showed that many petroleum jellies are protective to aluminum alloys. PHENETHYL ALCOHOL. C,H&H,CH,OH. In limited laboratory tests, 1100 alloy was resistant to phenethyl alcohol at the boiling point - 204C (399F). See also Ref: (3) p. 114. PHENOL. C,H,.OH. In laboratory tests, alloy 3003 was resistant to anhydrous phenol at temperatures up to 50C (122F). Above that temperature, phenol was very corrosive to aluminum alloys. Aqueous solutions of phenol caused mild attack ( - 5 mpy) of 1100 alloy at temperatures from ambient to 50C (122F). Aluminum alloy tubes and A3.56.0 valves have been used to handle phenol. Solid phenol has been handled in aluminum alloy drums. See also Ref: (1) p. 139. (2) p. 537, (3) p. 116, (7) p. 141. PHENYL ETHER. CbHrOCIH%. In laboratory tests, alloy 3003 was resistant to phenyl ether at refluxing conditions and at 204C (400F). Phenyl ether has been handled in aluminum alloy heat exchangers and stored and shipped in aluminum alloy containers. See also Ref: (2) p. 263, (3) p. 135. PHOSPHATE ROCK. Aluminum allo! equipment and hopper cars have been used for handling phosphate rock. PHOSPHORIC ACID. H;PO+ In laborator?_ tests, aqueous solutions of phosphoric acid (S-85%) were corrosive to 1100 allo! and the corrosion increased with concentration at ambient temperature. The rate of attack was - 100 mpy at 570 and - 1200 mpy at 85% concentration. The action of phosphoric acid can be reduced by the addition of inhibitors. Aqueous solutions containing phosphoric acid and chromium trioxide have been used as cleaning solutions and as surface preparation for painting of aluminum alloys. See also Ref: (1) p. 139, (2) p. 566, (3) p. 132. (4) pp. 21. 29, 30. 74. 86. 138, 139, (7) p. 143. PHOSPHOR SUSPENSIONS. Suspension of substances which will fluoresce under ultraviolet light. Phosphor suspensions used in manufacturing fluorescent lights are handled in aluminum alloy containers. PHOSPHORUS. P. In limited laboratory tests, alloy 1100 was resistant to solid and liquid white phosphorus at ambient temperature. Water cooled aluminum alloy pans have been used to handle molten phosphorus. See also Ref: (1) p. 139, (3) p. 48. PHOSPHORUS PENTASULFIDE. P+s. Dry phos-, phones pentasulfide has been handled in aluminim alloy tote bins. PHOSPHORUS SESQUISULFIDE. P,S,. Aluminum alloy equipment has been used in the manufac-
See also Ref: (3)
PHTHALIC ANHYDRIDE. C,HI(CO):O. Alumi. num alloy condensers have been used in the produc. tion of phthalic anhydride. Molten phthalic anhydride has been stored in the aluminum alloy tanks. See also Ref: (1) p. 139, (2) p. 573, (3) p. 132. (7) p. 143. PICKLES. In laboratory tests. pickles were COTrosive to aluminum alloys. Sodium chloride and vinegar contribute to this cunosion. See also Ref: (1) p. 139, (4) pp. 78.92, (6) p. 11. PICOLINES. CsHINCH,. In limited laboratory tests, mixed picolines (alpha, beta. gamma) were carrosive to 3003 alloy at 66C (150F). Picolines have been handled in aluminum alloy containers. See also Ref: (3) p. 149. PINEAPPLE NICE. In laboratory tests, 1100 allo) was resIstant to pineapple juice at ambient temperature. In another laboratory test. pineapple juice was corrosive to 3003 alloy at 1oOC (212F). See also Ref: (6) p. IO. PINENE. C,,,H,,. Aluminum alloy equipment including stills, condensers, filters and tanks has been used with pinene. See also Ref: (3) pp. 104. 226. PiperaPIPERAZINE. NHCH*CH>NHCH,CH,. zinc has been handled in aluminum alloy piping and stored in aluminum alloy tanks. PLASTER. (CaSO& H*O. In laboratov tests, plaster caused an initial reaction of contacting aluminum alloys while the plaster was liquid after which comosion did not continue. Aluminum alloys have been used for nails. corner strips. and expanded metal lath with plaster. See also Ref: (1) p. 139, (2) p. 161. (3) p. 228. PLASTICIZERS. (Non-volatile organic liquids or low melting solids, now especially phthalate, adipate, and sebacate esters and aryl phosphate esters). Plasticizers have been shipped in aluminum alloy containers. PLUMS. In limited laboratory tests, blue plum pomace was corrosive to alloy 3003 at 38C (lOOoF) while red plum pomace caused mild attack (- 5 mpy). Coated aluminum alloys have been used for canning plums. See also Ref: (6) p. 10. POLYETHYLENE. (CH,CH,).. Polyethylene has been handled in aluminum allo: equipment including weighing bins, blending bms. storage bins. and conveyor systems. Polyethylene has also been used as a covering on aluminum electrical conductor and in laminations with aluminum foil. See also Ref: (3) p. 237, (7) p. 145. POLYPROPYLENE. (C,H,).. Aluminum allo) silos. driers. and conveyor systems have been used to handle polypropylene. See also Ref: (3) p. 237. (7) p. 145. POLYSTYRENE. (C,H,CHCH,),. In limited laboratory tests, alloys 3003 and 5154 were resistant to solid polystryrene under conditions of 100% relative humidity at ambient temperature. Aluminum alloy bins, hopper trucks, tanks, pipe lines and conveyors have been used in handling polystyrene. See also Ref: (3) p. 104. (7) p. 147. POLYVINYL ACETATE. (CH+ZOCOCH,).. In limited laboratory tests, 3003 alloy was resistant to polyvinyl acetate emulsions. Pol.yvinyl acetate has been prepared in aluminum alloy equipment including condensers and piping.
(continued)
625
ment has been used for producing and handling potassium nitrate. See also Ref: (1) p. 140, (2) p. 613. (3) p. 66. (7) p. 151. POTASSIUM PERMANGANATR. KMnO,. Solid potassium permanganate was corrosive to 3003 alloy in laboratory tests under conditions of 100% relative humidity at ambient temperature. See also Ref: (I) p. 141, (2) p. 617. (3) p. 70, (4) pp. 74, 75,17) p. 151. POTASSIUM PERSULFATE. K2S106. Aluminum alloy equipment has been used for processing and shipping potassium persulfate. See also Ref: (2) p. 622, (3) p. 65, (7) p. 151. POTASSIUM PYROSULFATE. K1S201. Potassium pyrosulfate has been cast in aluminum alloy molds and shipped in aluminum alloy containers to avoid contamination. See also Ref: (3) p. 65. POTASSIUM SULFATE. KZS04. Alloys 3003 and 5154 were n&ant to solid potassium sulfate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In similar tests at 54OC (130F), potassium sulfate caused mild attack ( - 3 mpy) of these alloys. See also Ref: (1) p. 141, (2) p. 625, (3) p. 64, (7) p. 151. POTASSIUM TARTRATE. C,H,O,K, h H,O. Solid potassium tartrate caused moderate corrosion of 3003 alloy (14 mpy) and was corrosive to 5154 alloy in laboratory tests conducted under conditions of 100% relative humidity at,ambient temperature. See also. Ref: (1) p. 141. POTASSIUM THIOCYANATE. KSCN. Alloy 3003 was resistant to solid potassium thiocyanate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, 3003 alloy was resistant to aqueous solutions (including saturated solutions) of potassium thiocyanate at ambient temperature. See also Ref: (I) p. 141, (3) p. 69, (7) p. 153. PROPANE. CH,CH&H,. propane has been handled in aluminum alloy tube. See also Ref: (I) p. 111, (3) pp. 103. 214. (i) p. 153. PROPIONIC ACID. CH, CHI. COOH. In laboratory tests, alloy 1100 was resistant to aqueous solu(ions (0.5% to 100%) of propicnic acid at ambient temperature. As the temperature increases, solutions of propionic acid become aggressive. Completely anhydrous propionic acid was very corrosive, but the addition of a small amount of water reduced the attack significantly. Propionic acid has been handled. stored and shipped in aluminum alloy tanks, drums See also Ref: (1) and tank cars. p. 141, (2) p. 628, (3) p. 127. (4) p. 24. PROPIONIC ALDEHYDE. CH,CH,CHO. In lahoratory tests, 1100 alloy was resistant to aqueous solotions of propionic aldeh)de at ambient temperature. At SOC (122F) and ICOC (ZIZOF), these solutions caused moderate attack. Fropionic aldrhyde has been produced in aluminum alloy equipment and has been stored and shipped in aluminum alloy containers. See also Rel: (3) p. 120. (7) p. 153. PROPIONIC ANHYDRIDE. (CH,CHICO)zO. In laboratory tests, 1100 alloy was resistant to propionic anhydride at ambient temperature and at 50C (122F). At the boiling point, propionic anhydride was very corrosive. Propionic anhydride has been handled in aluminum alloy storage tanks, drums and See also Ref: (3) p. 128. tank cars. PROPYL ACETATE. CH3COOC,H7. In laboratory tests. 3003 alloy was resistant to propyl acetate at the boilinn temoerature. Condensing vapors of propyl
acetate caused mild attack of 3003 alloy in the same tests. See also Ref: (7) p. 153. n-PROPYL ALCOHOL. CH,. CH2. CH? OH. In laboratory tests, n-propyl alcohol caused mild attack ( - 3 mpy) of 3003 alloy under boiling and condensing conditions. See also Ref: (1) p. 141, (3) p. 113, (7) p. 153. PROPYLENE GLYCOL. CH,C HOH CH*OH. propylene glycol has been handled in aluminum alloy stills, evaporators, and heat exchangers. See also Ref: (31 p. 114. PYRIDINB. N: CHCH: CHCH: CH. In laboratory tests, 1100 and 3003 alloys were resistant to pyridine at ambient temperature. Aqueous solutions (1% and 5%) caused mild attack ( -5 mpy) of 3003 alloy at ambient temperature. Aluminum alloy condensers and dephlegmators have been used with pyridine. See also Ref: (1) p. 141, (2) p. 633, (3) p. 149, (4) p. 73, (7) p. 155.
num alloy pipe and $hipped in aluminum alloy tank cars. Aluminum allo! equipment has been used in the manufacture of paints and varnishes containing rosin. See also Ref: (1) p. 141, (2) p. 866, (7) p. 159. RUBBER. Mostly obtained from the coagulated milky juice of Hevea 6rusiIknsti. Aluminum alloys have been used on rubber plantations for cups, latex vats, pans, buckets. coagulating tanks, and drums. Aluminum alloy molds have been used for the production of rubber articles and for vulcanizing. See also Ref: (1) p. 141, (3) pp. 103, 227. RUM. In laboratory tests, rum was corrosive to aluminum alloys usually in the form of localized pitting. See also Ref: (1) p. 141.
S
SALICYLALDEHYDE. HOC&CHO. In laboratory tests, aluminum alloys caused discoloration of salicylaldehyde. Alloy 5052 caused less discoloration than other alloys. See also Ref: (3) p. 121. SALICYLIC ACID. HOC,H,COOH. Alloys 3003 and 5154 were resistant to solid salicylic acid in laboratoq tests conducted under conditions of 100% relative humidity at ambient temperature. Salicyclic acid has been handled in aluminum alloy distillation columns. condensen, pumps and piping. The sublimed acid has been condensed in aluminum-lined chambers. In the preparation of aspirin. salicylic acid has been reacted with acetic anhydride in aluminum alloy kettles. See also Ref: (1) p. 142, (2) p. 644, (3) p. 130. (7) p. 161. SARDINES. Coated aluminum alloy cans have been used to package sardines. See also Ref: (3) p. 208, (4) pp. 106, 108, 109, (6) p. 12. SAUERKRAUT. In limited laboratory tests, sauerkraut caused localized pitting of 3003 alloy. See also Ref: (1) p. 142. (3) p. 209, (4) pp. 78, 80, 92, (6) p. 11. SEAWATER. Many aluminum alloys have been shown to resist seawater in both laboratory controlled field tests and in service. These include aluminum-magnesium alloys 5052, 5154, 5083, 5086, and 5456 and aluminum-magnesium-silicon alloys 6061 and 6063. The high strength aluminum alloys 2219, 2024, and 7075 require protective measures when used in seawater. In Januac. 1936, an aluminum hull section of a high speed boat was placed in the James Ri\er Estuary of the Chesepeake Bay. The hull was fabricated of 5052.H32 plate. the framing of 6053 extrusions and the assembly rivets of 6053.T4l. The outside of the hull below the water line was painted except for a small area that was left bare to ohsewe the effect of the seawater on the hull plate. When inspected 42 years later, even the unpainted area had resisted corrosion. The Alcoa Seaprobe was 244 feet long with hull of 5456 aluminum painted with a coal tar epoxy. When the vessel was decommissioned after 10 years of service, examination disclosed the hull plates to have resisted the effects of seawater. Aluminum alloys have been used forrowboats, canoes, and other pleasure craft; outboard motors; as well as naval and commercial vessels. When immersed in seawater, aluminum alloys, as most other metals, are protected from marine fouling by organic coatings. These antifouling coatings should not contain mercury or cop per compounds. See also Ref: (3) pp. 32, 62, (4) pp. 42.55356, 57.50, 59. SEWAGE. Aluminum alloys have generally per-
Q
QUEBRACHO EXTRACT. Contains quebracho alkaloids and tannen. In limited laboratory tests, quebracho extract caused mild attack (- 4 mpy) of 3003 alloy at 204C (400F). QUINOLINE. C9H:N. Quinoline has been handled in aluminum alloy containers. See also Ref: (1) p. 141. (2) p. 640, (3) p. 149, (7) p. 157.
R
RASPBERRY JUICE. In laboratory tests, alloys 1100, 3003, and alclad 6053 were resistant to black raspberry juice at refrigerated temperatures. In other laboratory tests, black and red raspberry juices caused moderate attack of 3003 alloy at 100C (212F). See also Ref: (I) p. 141, (4) pp. 88, 89 (6) p. IO. RAYON INDUSTRY. Aluminum alloys have been used in the rayon industry for spinning buckets and bobbins, piping for viscose and wash water, filter presses and guide holders, desulfurization machines, ventilating and heater ducts, and blower equipment. See also Ref: (1) p. 141. (3) pp. 124, 232. RESORCNOL FORMALDEHYDE. C-H,O,. Resorcinol formaldehyde has been handled in aluminum alloy bulk containers. RHUBARB. In laboratory tests. rhubarb pomace and rhubarb juice were corrosive to alloy 3003 at 100C (212F). See also Ref: (4) p. 80, (6) p. 11. RICE. Aluminum alloy equipment has been used to ptocess various rice products. See also Ref: (I) p. 141. RICNOLEIC ACID. CH~.(CH>)s.CHOH.CHICH:CH.(CHz),.COOH. In limited laboratory tests, 3003 alloy was resistant to ricinoleic acid at ambient temperature. Ricinoleic acid has been processed in aluminum alloy distillation equipment, condensers and piping. It has been stored in aluminum alloy tanks. See also Ref: (2) p. 274, (3) p. 129. ROSIN. Molten rosin has been carried in alumi-
(continued)
626
Corrosion
Resistant
Materials
Handbook
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
in the SODIUM DICHROMATE. Na,Cr,O-.ZH,O. SC,dium dichromate has been wed as an mhibitur to retard corrosion of alummum alloys in chloride solutions and ethylene glycol. See also Rrf: (1) p. 143. (3, p. 70. SODIUM DISILICATE. Na.Sis05. Sodium disiilcate has been used as an inhibiror of corrosion of ahminum alloys in alkaline solutions. See aJso Ref. (7, p. 165. SODIUM FLUORXDE. NaF. Solid sodium fluoride was corrosive to alloy 3003 in laboratory tests conducted under conditions of 100% relative humidit! at ambient temperature. In other laboratory tests. aqueous solutions of sodium fluoride (0.1% to 4%) caused moderate attack ( - 10 mpy) of 1100 allo! which varied ulth concentration. See also Ref: (I) p 143. (3) p. 63, (7) p. 167. SODIUM FLUOSILICATE. Na,(SiF,). Alloys 3003 and 5154 were rwstant to solid sodium fluosilicate in laboratory tests conducted under conditions of 100% relative humidlry at ambient temperature. See also Ref: (2) p. 688. (3) p. 69. SODIUM HYDROGEN SULFATE. NaHSO,. Solid sodium hydrogen sulfate was very corrosiw fo alloys 3003 and 5154 in laborator? tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests. aqueous sobtions of sodium hydrogen sulfate (l-25%) caused attack of 3003 alloy at ambient temperature which increased with concentration. Alloy 3003 ~a5 reslstanr to a I% solution. while a 2S% solution caused mild attack (- 4 mpy). See also Ref: (1) p. 142. (2) p. 65.3. (3) p. 64. SODIUM HYDROXIDE. NaOH. In laboratop tests, aqueous solutions of sodium hydroxide were very corrosive to all aluminum alloys at all concentrations and temperatures. Dilute solutions of sodium hydroxide have been inhibited by the addition of inhibitors, including potassium dichromate. ammonium metavanadate. or ammonium persulfate. See also Ref: (1) p. 143, (2) p. 693, (3) pp. 25. 60. (4) pp. 34.35. 36, 37, 49, 103. (7) p. 169. SODIUM HYPOCHLORITE. N&IO. In laboratory tests. aqueous solutions of sodium hypochlorite cause corrosion which varies with concentration. Alloy 1100 was resistant to dilute solutions of sodium hypochlorite at ambient temper. atore. whereas. more concentrated solutions HYIY very corrosive. Silicates have been used as inhibitors for corrosion of aluminum alloys by sodium hypochlorite. See also Ref: (1) p. 143, (2) p. 703. (3) pp. 63. 247. (7) p. lb9.
formed well when used with domestic and industrial sewage and the decomposition products of the sludges. including hydrogen sulfide. methane, carbon dioxide, and nitrogen. Aluminum alloys have been used for filters. gratings. thickeners, valves. pipes, and sludge handling equipment in sewage disposal plants. See alw, Ref: (1) p. 142, (3) p. 243. SHAVING CREAM. Many shaving creams have been packaged in mllapsible aluminum alloy tubes. See also Ref: (I) p. 142. SHELLAC. A resinous excretion of the insect LncC+ &co. In laboratory tests. 3003 alloy was resistam to shellac at ambient temperature. Aluminum alloy storage tanks have been used for shellac. See also Ref: (3) p. 226. SHOE POLISH. Typically a mixture of hard waxes (camauba. etc.), paraffin, ceresin of ozokerite, solvents (naphtha and turpentine. etc.) and dye. Aluminum alloy containers have been used for shoe polish. See also Ref: (9) p. 62. SILVER COMPOUNDS. In laboratoq tests, solutions of silver compounds were corrosive to all aluminum alloys causing localized pitting atiack. See also Ref: (1) p. 142, (3) p. 73. SOAP. Salt of fatty acids. In laboratory tests, the action of soaps on aluminum alloys is variable. Many soaps cause less than 1 mpy attack while others, usually those more alkaline, are corrosive. Aluminum allo? screw conveyon. compactors. packaging equipment. and tote bins have been used in the production of soap. Bar soap has been wrapped in aluminum foil laminates. See also Ref: (1) p. 142. (2) p 647. (3) pp. 117. 2.39. 245 (71 p. 160. SODA ASH. See SODIUM CARBONATE. SODA WATER. In limited laboratory tests. 3003 alloy was resistant to soda water at ambient temperature. When tap u ater is used. the amount of carroslon is dependent upon the composition of the water used. See also Ref: (9) p. 65. (10) pp. 46, 93. SODIUM. Na. Sodium has been heated on aluminum allo) trays in the production of sodium p~ducts. See also Ref: (1) p. 142. (3) p. 58. SODIUM ACETATE. CH,COONa.3H,O. Alloy 3003 was resistant to solid sodium acetate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, 1100 alloy was resistant to aqueous solutions of sodium acetate (0.1% to 36%) at ambient temperature. See also Ref: (I) p. 142, (2) p. 650. (3) pp. 25, 71 (7) p. 161. SODIUM ALUMINATE. NaAIOI. Solid sodium aluminate was very corrosive to alloys 3003 and 5154 in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (3) p. 70. (7) p. 161. SODIUM ARSENATE. Na>HAsO,. Solid sodium arsenate caused moderate attack (- 10 mpy) of 3003 and 5154 alloys in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (1) p. 142, (7) p. 162. SODIUM ARSENITE. NaAsO,. Solid sodium arsenite caused mild attack ( - 5 mpy) of alloy 3003 while 5154 alloy was resistant to solid sodium arsenite in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Aluminum alloy tanks have been used to handle SDdium arsenite. See also Ref: (7) pp. 162, 163. SODIUM BENZENESULFONATE. C6H5S020Na. Aluminum alloy rotary driers, fume
hoods, and duct work have been used manufacture of sodium benzenesulfonate.
SODIUM BENZOATE. CJ+. COONa. Alloys 3003 and 5154 were resistant to solid sodium benzoate in laboratory tests conducted under conditions of 100% relativ: !tumidity at ambient temperature. See also Ref: (3) p. 71. (7) p. 163. SODIUM BISULFITE. NaHSO?. Solid sodium bisulfite was corrosive to alloys 3003 and 5153 with evidence of localized pitting in lahorato~ test, conducted under conditions of loOr relative humidit! at ambient temperature. In other laborator) tests. aqueous solutions of sodium hisulfite t lob to 25b 1 at ambient temperature caused attack of alloy 3003 which increased with concentration Solutions Of 10% or less caused mild attack ( - 2 mp) Hhile 25%~ solutions were slightly more corrosive t - 4 mpy). See also Ref: (2) p. 657. (3) p. 64, (7) p. 163. SODEM CARBONATE. Na:CO,. Solid sodwm carbonate was vety corrosive to alloy 3003 in laborator?, tests conducted under condllions of 100% relative humidity at ambient temperarure. In other laborarov tests, aqueous solutions of sodium carbonate (1% to 10%) were very corrosi\e to 1100 allo> at ambient temperature. In the same tests. the action of these aqueous solutions was eftectively inhibited by the addition of silicates. Aluminum alloy hopper cars have been used to transport sodium carbonate. See also Ref: (1) p. 142. (2) p. 660. (3) pp. 23. 67. (4) pp. 34.37.50, 76,86,%, 103. SODIUM CHMRATE. NaCIO,. Alloy 3003 was resistant to solid sodium chlorate in laboratory tests conducted under conditions of 100% relative humidityat ambient temperature. Sodiumchlorate has been dried in aluminum alloy equipment and shipped in aluminum alloy tanks cars. See also Ref: (7) pp. 164. 165. SODIUM CHLORIDE. N&I. Alioy 3003 was resistant to solid sodium chloride in laboratoq tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests. aqueous solutions of sodium chloride (0.1 [PO 25%) to caused mild attack (- 2 mpy) of llo(l alloy at ambient temperature with some localized pitting. The presence of heavy metals in these solutions accelerated attack. Sodium chloride has been the basic ingredient in many standard accelerated corrosion tests used in evaluating the resistance to corrosion and stress corrosion cracking of aluminum alloys. Aluminum alloy equipment has been used for hoppers. elevator buckets. drying towers and bins for handling sodium chloride. Solid sodium chloride has been shipped in aluminum alloy railnay cars. Sodium chloride brines have been carried in aluminum alloy refrigeration systems. See also Ref: (1) p. 143, (2) p. 665. (3) pp. 25261, 213, (7) p. 16.5.
LACTATE. CH, CHOHC. 00~~. in laboratov tests, 30% solution of sodium lactate was coormsive to 1100 alloy at ambient temperature and at 1OOC (212F). In the same tests. 1100 alloy was reSODIUM CHROMATE. Na,Cr0,.4 HIO. Alloys sistant to an 80% solution of sodium lactate at ambi3003 and Sl_S4 were resistant to solid sodium ent temperature. See also Ref: (3) p. 71. chromate in laboratory tests conducted under conditions of 100% relative humidity at ambient tem- SODIUM LAURYI. SULFATE. perature. In other laboratory tests, 1100 alloy was CH,(CH,),,COONa SOz. In controlled field tests. resistant to aqueous solutions of sodium chromate aqueous solutions of sodium lauryl sulfate were COT(up to SO%) at ambient temperature. Sodium chro- msive to alloy 3003. mate has been used extensively as an inhibitor to retard corrosion of aluminum alloys in many aqueous SODIUM MERCAPTOBENZQTHIAU)LE. environments. See also Ref: (1) p. 143, (2) p. 678, (3) C,H,N:C(S). SNa. Sodium mercaptobenzothiazole pp. 61, 62, 70, 73 (7) p. l&S. has been used as an inhibitor to retard corrosion of aluminum alloys in ethylene glycol sohnions. See also SODIUM CYANIDE. N&N. In laboratory tests, Ref: (10) p. 30. aqueous solutions of sodium cyanide at ambient temperature caused attack of 3003 alloy which in- SODIUM NITRATE. NaNO,. Alloy 3003 was resiscreased with concentration. At 0.1%. the sodium tant to solid sodium nitrate in laboratory tests concyanide solution caused mild attack (- 4 mpy) while ducted under conditions of 100% Hlative humidity at 20%. it wasve~ corrosive. See also Ref: (1) p, 143, (2) p. 682. (3) p. 68. (7) p. 165. (continued)
somm
perature. In other laboratory stannous chloride (O.ooOl% tack (-4 rnpy) of 1100 allo) See also Ref: (1) p. 144. (3)
627
at ambiel;t temperature. In orher laboratow tests, 1100 allO\ was resistant to aqueous solutions of sodium nitrate (0.1% to 43%) at ambienr temperature Sodium nitrate has been used in combination uith sodium nitrite as an inhibitor to retard the corrosion of aluminum alloys. See also Ref: (1) p. 143. (2) p. 712. (3) p. 66, (7) p. 169. SODIUM NITRITE. NaNO,. Alloys 3003 and 5154 uere resistant to solid sodium nitrite in laborator) tests under conditions of ICVb relative humidity at ambient temperarure. See also Ref: (1) p, 143. (3) p, 66. (7) p 169. SODIUM OXALATE. Na,CzO,. Alloys 3003 and 5154 UCK resistant to solid sodium onalate in lab. oratov tests conducted under conditions of 100% relative humidit! al ambient temperature. In other laborator) tests. 300.3 alloy was resistant to saturated solutions of sodium oxalate at ambient remperature. while dilute solurions of sodium oxalate (3.1%) caused moderate attack ( - 7 mp)-) of 3003 alloy at 100C (212F). See also Ref: (I) p. 143. SODIUM PERBORATE. NaBO,. 4H,O. Alloys 3003 and 5154 were resistant to solid sodium perborate in laboratory tests conducred under conditions of 100% relative humidity at ambient temperature. In other laboram? tests, 3003 alloy was resistant in moist sodium perborate at ambient temperature. See also Ref: (2) p, 718. (7) p. 169. SODlUM PERCARBONATE. 2 Na,CO,.3 H>O. Na:CO,.H?OI.l/> H?O or Na,C,O,. Sodium percarbonate has been prepared in aluminum allo! reactors. See also Ref: (2) p. 720. (3) p. 68. (7) p. 169. SODIUM PEROXIDE. NalOl. Solid sodium peroxide was very corrosive to alloys 3003 and 51-54 in laboratoq tests under conditions of 100% relative humidity at ambient temperature. See also Rcf: (1) p. 144. (2) p. 725. (3) p. 60. (7) p. 171. SODILJM PHOSPHATE, DIBASIC. Na,HPO+ Alloys 3003 and 5154 were resistant to solid sodium phosphate, dibasic. in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (1) p. 144. SODIUM PHOSPHATE, TIUBASIC. Na,PO,. In laboratory tests, aqueous solutions of sodium phosphate, tribasic, were very corrosive 10 1100 alloy at ambient temperature. Sodium silicate was found to be an effective inhibitor for this compound. Cleaning products containing this compound should be used only with great caution on aluminum alloy products. See also Ref: (1) p. 146, (2) p. 734, (3) p. 67. (4) pp. 34. 37, SO. 69, 75. 76. 86. 103. (7)~. 171. SODIUM PROPIONATE. CH,CH$OONa. Sodium propionate solutions have been handled in aluminum alloy tanks. See also Ref: (3) p. 71. SODlUM SILICATES. SiO,(Na,O). The resistance to corrosion of aluminum alloys by sodium silicates depends on the weight ratio of SiO,/Na,O. Commercial sodium silicates with a weight ratio of 2 have been used as inhibitors of corrosion of aluminum alloys in alkaline solutions. In laboratory tests. sodium metasilicate with a weight ratioof 1 was very corrosive to 1100 alloy at ambient temperature. See also Ref: (1) p. 144. (2) p. 740, (3) p. 69, (4) pp. 37, 47, 76, 86, %. 103. 119. 12.3, 138, (7)~. 171. SODIUM SULFATE. Na,SO,. 10 HIO. In laboratory tests, alloy 3003 was resistant to solid sodium sulfate under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, aqueous solutions of sodium sulfate (0.1 to 14%)
caused mild attack ( - 2 mpy) of 1100 alloy at am bient temperature. Aluminum alloy tote bins have been used for handling sodium sulfate. See also Ref: (l)p. 144,(2)p. 744(3)p.64,(7)p. 173. SODIUM SULFIDE. NalS.9 H20. Solid sodium sulfide was very corrosive to 3003 and 5154 alloys in laboratory tests conducted under conditions of 100% relatix humtdity at ambient temperature. See also Ref: (1) p. 144. (2) p. 748, (3) p. 63. (7) p. 173. SODIUM SULFITE. Na2S0,. 7 H>O. In laborato~ tests, 1100 alloy was resistant to aqueous solutions of sodium sulfite (0.1 to 15%) at ambient temperature. Alloys 3003 and 5154 were resistant to solid sodium sulfhe in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (I) p. 144. (2) p. 754, (3) p. 64, (7) p. 173. SODIUM THIOCYANATE. NaSCN. In laboratory tests, 1100 alloy was resistant to aqueous solutions (0.1 to 40%) of sodium thiocyanate at ambient temperarure. Aluminum alloy troughs. tanks. rolls, piping and towers have been used to handle sodium thiocyanate solutions. See also Ref: (1) p. 144, (2) p. 760. (3) p. 69, (7) p. 173. SODIUM THIOSULFATE. Na,S201.5 HzO. Alloys 3003 and 5154 were resistant to solid sodium thiosulfate in laboratory tests conducted under conditions of 100% relative humidity ar ambient temperature. In other laboratoty tests, 1100 alloy was resistant to aqueous solutions of sodium thiosulfate (0.5% to 40%) at ambient temperature. Sodium thiosulfate has been used as a deicing salt on aluminum alloy equipment. See also Ref: (1) p. 144. (2) p. 763, (3) p. 65, (7) p. 173. SOILS. Soils vary widely in their corrosivity towards aluminum alloys. Soil composition, the nature of chemicals in the ground water, and the degree of wetness and aeration are factors in the cormsivity of soil; but the corrosion of aluminum alloys in soil is so complex that even that information is not sufficient for accurate prediction of performance in a given soil. It is recommended that soil corneivity be evaluated for each application while still in the design stage. Aluminum alloys buried in soi. are usually protected by claddings, coatings, or wrappings. Cathodic protection is also used, sometimes in conjunction with other protective measures. Alloys containing copper, such as 2024, should not be used in soil. Aluminum alloys have been used for oil pipe lines and culvert pipe in soil. See also Ref: (1) p. 144. SOBBITOL. C6Hl,0a. Sorbitol has been filtered in aluminum alloy filter presses and transported in aluminum alloy tank cars and shipping drums. See also Ref: (2) p. 766, (3) p. 115, (7) p. 173. SORBOSE. C&i,*O,. Aluminum alloy equipment, including r&dry fermenters and sterilizers, has been used in the production of Sorbose. See also Ref: (2) p. 768. (3) p. 123, (7) p. 173. SOYA OIL. Consists of glycerides of oleic. linoleic, palmitic. stearic and linolenic acids. Aluminum alloy weight tanks and kettles have been used in the pro. duction of soya oil. STWC CHLORIDE. SKI, Solid stannic chloride was very corrosive to alloys 3003 and 5154 in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (1) p. 144, (2) p. 774, (3) p. 81. (7) p. 175. STANNOIJS CHLORIDE. SKI,.2 H,O. Solid stannous chloride was very corrosive to alloys 3003 and 5154 in laboratory tests conducted under conditions of lOLl% relative humidity at ambient tem-
tests. dilute solutions of to 10%) caused mild arat ambient temperature. p. 81. (7) p. 175.
STARCH. Solid starch caused mild attack (-2 mpy) of alloy 3003, while 5154 alloy was resistant to solid starch in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Aluminum alloy conveyors and piping have been used in starch plants. See also Ref: (1) p. 144. (2) pp. 123, 124, 231. (4) p. 73. STEAM. HZO. In laboratory tests under static conditions, alloy 3003 uas found to be resistant to pure steam wer distilled water at temperatures up to 268C (514F). In fact, aluminum alloys exposed to steam at these temperatures had improved resistance to corrosion by other environments because of the increased thickness of the oxide film on the surface. In the same tests, steam at 268C (514F) was cormwe. High prw.sure steam can erode aluminum alloys by impingement corrosion erosion, particularly when the jet of steam is perpendicular to the surface. Aluminum alloy equipment including heat exchangers, dryers. steam jacketed kettles, piping have been used to handle steam in the petroleum. chemical and food processing industries. See also Ref: (1) p. 144, (2) p. 778, (4) p. 49, (7) p. 175. STEABIC ACID. CH,.(CH,),,.COOH. Aluminum alloy equipment has been used for steam distillation, filtering and storing stearic acid. Alloys 3003 and 5154 were resistant to solid stearic acid under conditions of 100% relative humidity at ambient temperature. See also Ref: (1) p. 144, (2) p, 782, (3) p. 127, (4) p. 25. (7) p. 175. STRAWBERRIES. In limited laboratory tests, fresh strawberries caused localized pitting of 5052 alloy. See also Ref: (4) pp. 106. 109. STREPTOMYCIN. C:,H,cNQl. Aluminum allo) media tanks. pre-seed ranks. absorption tanks, slurry tanks, pipe and fittings have been used in the production of streptomycin. See also Ref. (3) pp. 146. 239. STROBANE*. (Consrituents: Terpene polkchlorinates such as camphene, pinene and r&red compounds). In controlled field tests, 3003, 5052, and 5154 alloys were resiaant to Strobane at ambient temperature. Indcmrrl; STYRENE. C,HsCH.CHz. Aluminum alloy heat exchangers. bubble caps, tank trucks, conveyors. piping, polymerization vessels and storage tanks have been used in the styrene industry. See also Ref: (3) pp. 104, 105. (7) p. 175. SUCCINKACID. HOOC.CH2.CH2 .COOH. Alloys 3003 and 5154 were resistant to solid succinic acid in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, aqueous solutions of succinic acid (0.25% to 50%) caused attack of 1100 alloy that increased with concentration and temperature. At O.ZS% the attack was moderate ( - 6 mpy) while at 50% it was corrosive at 100C (212F). See also Ref: (1) p. 145. (3) p. 130. (7) p. 175. SUCROSE. CIZHnO,,. Alloy 3003 was resistant to solid sucrose, while alloy 5154 showed mild attack (- 2 mpy) in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Aluminum alloy piping, crystallizers and storage tank heaters have been used with sucrose. Dry sucrose has been handled in aluminum alloy piping. See also Ref: (1) p. 145, (2) p. 790. (3) p. 124. (6) p. 10.
(continued)
628
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
See also containers have been used for handling porting pure. dry titanium sponge. and trans.
SUGAR. C,zH,,O,,. Aluminum alloy equipment for piping. tankage and transportation has been used in the sugar industry. See also Ref: (1) p. 145 (2) p, 790. (3) pp. 123. 198,203,209, (4) pp. 73, 74,88,90, 91, 93,98, (7) p. 175. SULXAMIC ACID. H,N .S02.0H. In laboratory tests, aqueous solutions of sulfamic acid (0.1% to 20%) caused attack of 1100 alloy which increased with temperature. At ambient temperature, the attack was moderate (- 10 mpy). while at 50C (122F) and IOOC (212F). sulfamic acid solutions were very corrosive. See also Ref: (I) p. 145. (3) pp. 42, 244, (4) p. 124. SULFITE WASTE LIQUOR. Aluminum alloy tank trucks have been used for handling dilute, unneutralized waste liquors. See also Ref: (2) p. 7%. SULFUR. S. In laboratory tests, 1100 and 3003 alloys were resistant to liquid sulfur al l35-154C (275-310F). Aluminum alloy equipment has been used for the recovers and ourification of sulfur. in sulfur mining equipment. buildings, freight cars, hoooer cars and convevors. See also Ref: f 1) o. 145. (2;;. 800. (3) pp. 40. i27; James R. West,.S\lphu; and Sulphides vs. Materials of Chemical Plant Con. struction. Chemical Engineering, 1946 October.
I .
alloy tanks, pipe lies, and heat exchangers. Ref: (7) pp. 180, 181.
TANNlC ACID. CT~H~~O~. Solid tannic acid caused mild attack (- 2 mpy) of alloys 3003 and 5154 in lab. oratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratnn tests, 0.01% to 20%~ aqueous solutions caused mild attack ( - 2 mpy) of 1100 alloy at ambient temperature and moderate attack (- 9 mpy) at 50C (12ZcF). These solunons were corrosive at IOOC (212F). Aluminum allo! processing equipment has been used in tanning plants. See also Ref: (1) p. 145. (4) pp. 29. 30. (7) p. 181. TAR. Aluminum coils and heat exchangers have been used in tar distillation plants to condense hot creosote vapors. Tar and tar products have been handled in aluminum allo! tanks. See also Ref: (1) p. 145. (3) p. 223. TARTARIC ACID. HOO.C(CHOH)>COOH. Alloys 3003 and 5154 were resistant to solid tartaric acid in laboratory tests conducted under conditions of 100% relative humidlty at ambient temperature. In other laboratory tests. 1100 alloy was resistant to aqueoussolutions(O.l% to55%) at ambient temperature, but these solutions were corrosive at SOC (122F) and very corrosive at 100C(2120F). Tartaric acid has been processed in aluminum alloy filters and crystallizers and has been stored in aluminum alloy See also Ref: (1) p. 145. (2) tanks. p. 848, (3) pp. I3 I, 209. (4) pp. 22, 25,26,27,28.29, 30. 88, (7) p. 181. TEA. Aluminum alloys have been used for packaging, storing, and brewing tea. See also Ref: (I) p. 145, (3) p. 211, (4) pp. 79,843 97.98. (6) p. 12. TERPENES. Cl&,. (Polymers of lsoprene CrH& Aluminum alloy tanks have been used for storing terpenes. See also Ref: (3) p. 104. (7) p. 181. TETRACHLOROETHANE. CI,HC.CHCl2. Limited laborat? tests indicated that 3003 alloy was resistant to tetrachloroethane at ambient temperature but at boiling temperature tetrachloroethane was corrosive. CAUTION: See Halogenated Hydrocarbons. See also Ref: (3) p. 109. TETRACHLOROETHYLENE. Cl&. Ccl,. In limited laboratory tests, high purity aluminum was resistant to tetrachloroethylene at SOC (122F) and under refluxing conditions. In other laboratory tests. tetrachloroethylene caused mild attack ( - 5 mpy) of 3003 alloy under refluxing conditions. Aluminum alloy degreasing installations including stills and storage tanks have been used with tetrachloroethylene. See also Ref: (1) p. 145. (3) p. 108. THIOCARBANILLDE. CS(NHC,H&. In laboratory tests, thiocarbanilide caused mild attack (-4 mpy) of alloy 3003 at 204C (400F). Aluminum alloy drying trays have been used for handling thiocarbanilide at temperatures up to 88C (190F). THIOGLYCOLIC ACID. HS CH1. COOH. In laboratory tests. alloys 1 IO@. 3003 and 5052 were resistant to 7.2% aqueous solutions of thioglvcolic acid at ambient temperature. Aqueous solutibns of 45% concenlr.xion were corrosive. Aluminum alloy tanks and recehers have been used for thioglycolic acid. See also Ref: (3) p. 133. THIOPHENE. SCH:CHCH:CH. Limited laboratory tests indicated that 3003 alloy was resistant to thiophene at 204C (400F). See also Ref: (3) p. 148. TITANIUM. Ti. In laboratory tests, titanium was found to cause corrosion of contacting aluminum alloys in high chloride-containing environments by galvamc action. Hermetically sealed aluminum alloy
TITANIUM DIOXIDE. Ti02. Titanium dioxide pigment has been dried in large aluminum-lined steam tube driers. Aluminum alloy heat exchangers have been used to condense titanium dioxide vapors. See also Ref: (3) p. 78. TITANIUM TETRACHLORJDE. TiCI,. In limited laboratory tests, titanium tetrachloride caused mild attack ( - 5 mpy) of alloys .X)52 and 6061 under refluxing conditions. See also Ref: (7) pp. 182. 183. TOBACCO. In limited laboratory tests. moist tobacco caused localized pittmg of 3003 and SOS2 alloys at ambient temperature. Aluminum alloys have been used for packaging tobacco products. See also Ref: (I) p. 146. TOLUENE. C,H,.CH.,. In laboratory tests, 3003 alloy was resistant to toluene at ambient temperature and the boiling temperature. Toluene has been handled in aluminum allo) equipment. See also Ref: (1) p. 146. (2) p. 855. (3) pp. 104. 223, (7) p. 183. TOLUIDINES(m-,o-.andp-_).CH,C,I&.NH,. Toluidines have been handled in aluminum alloy steam heated stills. See also Ref: (1) p. 146. (3) p. 144. TOMATOES AND TOMATO JUICE. In laboratory tests, 3003 and 5154 alloys were resistant to tomato paste at ambient temperature. In other laboratory tests. 3C03 alloy was resistant to tomato juice at 1OOC (212F). Cooking and storage of tomatoes in aluminum al(oT vessels has caused pitting on the metal. TomatoJuIce has been processed in aluminum alloy equipment. See also Ref: (I) p. 146. (3) p. 209. (4) pp. 88. 91. 92. (6) p. Il. TOOTHPASTE. In lahoratoy tests, the corrosion effects of toothpastes are variable. with most causing little corrosion. Those contaming fluorides are corrosive IO aluminum alloys. Toothpastes hate been packaged in collapsible aluminum tubes. See also Ref: (I) p. 146. (3) p. 239. TOXAPHENE. C,&,,Clh. In limired laborato? tests at ambient temperature and 52C (126F). toxaphenc solutions caused localized pitting of 3003 alloy. Aluminum allo! tanks have been used to store and transpon toxaphene. CAUTIOS: See Halogenated Hydrocarbons. See also Ref: () pp. 182, 183. TRLXETIN. (CHICOO)JCIHi. Limited laboratory tests indicated that 6053 alloy was resistant to triacetin at ambient temperature. Aluminum alloy kettles and stills have been used in the production of triacetin. See also Rrf: (IO) p. 81. TRICHLOROBENZENE. C,H,CI,. In laboratory tests, 3003 alloy was resistant to trichlorobenzene at ambient, SOC (122F). 100C (212F). and 204C (400F) temperatures and under refluxing conditions. Aluminum alloy tank cars have been used to ship trichlorobenzene. CAUTION: See Halogenated Hydrocarbons. See also Ref: (3) p. 111. (7) p. 185. I,I,I-TRICHLOROETHANE. CCI,CH,. In limited laborator? tests. 3003 alloy was resistant to trichloroethane at ambient temperature and under refluxing conditions. CAUTION: See Halogenated Hydrocarbons. See also Ref: (3) p. 109. (7) p. 18.5. TRJCHLOROETHYLENE. CICH:CCI,. In limited laboratory tests. 3003 alloy was resistant to trichloroethylene in the dry condition at ambient temperature, 50C (122F) and under refluxing conditions. The
SULFUR CHLORIDE. SCI or S&I,. Sulfur chloride ha\ been shou n to be very corrosive to aluminum alloys in laboratop tests. See also Ref: (7) pp. 176. 177. SULFUR DIOXIDE. SO2 In laboratory tests. sulfur dioxide sarurated with water was corrosive to all aluminum alloys at ambient temperature. Aluminum alloy equipment has been used for refrigeration systems containing sulfur dioxide, for vulcanizing chambers, and petroleum refiiing stills involving sulfur dioxide, for heat exchangers in cooling sulfur dioxide, and for reactors converting sulfur dioxide to sulfur trioxide. See also Ref: (1) p. 145, (2) p. 806, (4) p. 97 (7) p. 177. SULFURIC ACID. HISO,. In laboratory tests, the corrosion of aluminum alloys in sulfuric acid varies with concentration of sulfuric acid. The corrosion reaches a maximum at about 80% acid concentration. Above that concentration. attack decreases rapidly until at 98% it becomes mild, less than 5 mpy. In other laboratory tests, fuming acids containing 101. 103. 107 and 115% sulfuric acid caused moderate attack of 3003 alloy at ambient temperature. Aluminum alloy heat exchangers, piping and tanks have been used to handle sulfuric acid in 98% concentrations and at temperatures as high as 200C (392F). See also Ref: (1) p. 145, (2) p. 811, (3) pp. 22. 41. (4) pp. 18, 19, 29, 30, 31, 34, 74, %, 97, (7) p. 177. SULFUROUS -40. HzSO1. In laboratory tests, dilute aqueous solutions of sulfurous acid caused corrosion of 1100 alloy which increased with concentration. At 0.1% sulfurous acid, the attack was mild (-4 mpy). while at 8%. the attack was moderate (- 12 mpy). Sulfurous acid condensed from gases containing sulfur dioxide and moisture will cause corrosion of aluminum alloys. See also Ref: (1) p. 145. (2) p. 841, (3) p. 22, (4) pp. 19,29,30, (7) p. 179. SULFUR TRIOXIDE. SO,. Aluminum alloy reactors have been used for converting SO1 to SO, (sulfur trioxide). See also Ref: (3) p. 40.
TALL OIL. Tall oil has been handled
in aluminum
(continued)
629
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
Aluminum alloys are well suited for handling steam condensate. They are not adversely affected by carbon dioxide and oxygen or by chemical agents such as ammonia. hydrazine. morpholine. filming amines and sodium sulfite added to condensate in the relatively small concentrations needed to protect steel. Large aluminum tanks have been in use at power plants for storage of alkaline condensate (pH 9-9.5). Laboratory tests indicate that the cwrosivity of natural fresh waters is difficult to predict. When they do cause corrosion. the attack is generally of the pitting type. The tendency of fresh natural water to promote pitting of aluminum depends upon the nature and concentration of salts dissolved in them. Small quantities of soluble chloride and heavv metal salts in some natural water will promote pitting of aluminum. especially if the water pH is 6 or below, Alclad alloys such as alclad 3003 and alclad 6061 are highly resistant to the development of deep pits. Waters that are handled in recirculating systems are generally corrosive to aluminum unless a suitable water treatment is used. Even if a water that in its natural state has little action on aluminum is used. the concentration of dissolved solids builds up as evaporation losses are made up or as contaminants are picked up from the system or the air and the corrosivity of the water could increase. Expert advise on suitable water treatments is available from a number of water treating concerns. See also Ref: (7) pp. 251. 252.253. L54. WAX. In laborator! tests. man) waxes were protective to aluminum alloys. Steam traced aluminum alloy piping has been used to handle liquid and molten waxes. Molten waxes have been solidified in aluminum alloy pans. Aluminum allo! dip tanks have been used to treat crude robber with molten wax. See also Ref: (1) p. 147. (3) pp. 220, 225. WETTING AGENTS. (Alkyl and alkylaryl sulfonates in the form of their sodium salts). Aluminum alloy containers have been used to handle these cornpounds. See also Ref: (IO) p. 100. WHISKEY. In laboratory tests. alloys 1100 and 3003 were resistant to uhiske! at ambient temperature but pronounced localized pttting occurred. The color of the whiskey was also affected. See also Ref: (1) p. 147, (3) p. 203, (6) p. 10.
presence of water accelerates the corrosive effects of trichloroethylene. Aluminum alloy tank cars have been used for transporting dry trichlonethylene. Inhibited trichloroethylene has been used for degreasing of aluminum alloy products. CAUTION: See Halogenated Hydrocarbons. See also Ref: (1) p. 146, (3) pp. 25. 108. 244. (7) p. 185. TRIETHANOLAMlNE. N(CHI. CH*. OH),. In laboratory tests, alloy 2017 was resistant to triethanolamine at ambient temperature while triethanolamine was comosive to 3003 alloy at 204OC (400F) and under refluxing conditions. Aqueous solutions were vey corrosive to aluminum alloys at ambient temperature. Triethanolamine has been stored and tram ported in aluminum allo! tanks. See also Ref: (1) p. 146. (2) p. bb2.13) pp. 25. 145, (5) p. 14. TRIETHYLAMINE. (C?H,),N. Laboratory tests indicated that 3003 allo!_ war resistant to triethylamine at 1OOC (212F) and 204C (400F). TRIETHYLENEDIAMINE. NH>(C,H&C>H,NH:. Alummum allov steam tube has been used to handle triethylenediamine. I. 2,4 TR[METHYLBENZENE (PSEUDOCUMENEI. C,H,(CH,),. Aluminum allo} stills have been used for the distillation of trimethylbenzene. See also Ref: (7) p. 187. 2, 4, 6.TRINITROTOLUENE. (NO&. CoH>. CH,. Aluminum allo! kettles and heat exchangers have been used in the manufacture of trinitrotoluene. Aluminum alloy vessels have been used for melting trinitrotoluene. TRI-o-CRESYL PHOSPHATE. (CH,.C,H,),PO,. In laboratoq tests, 3003 alloy was resistant to tri-ocresjl phosphate at 204C (400F). Under refluxing conditions tri-o-cresyl phosphate was corrosive to 3003 alloy. Aluminum alloy tank trucks have been used to transport tri-o-cresyl phosphate. See also Ref: (1) p. 146. (3) p. 138. (7) p. 18.5. TUNA FISH. In laboratory tests, 3003 alloy was resistant to tuna fish at ambient temperature. See also Ref: (6) p. 12. TUNG OIL. In limited laboratory was resistant to tong oil at ambient tests, alloy 6061 temperature.
V
VALERIC ACID. CH,(CHJ3COOH. In laboratory tests, 3003 alloy was resistant to valeric acid at IOOC (212F). See also Ref: (1) p. 146 (3) p. 127. VANILLIN. CH,O(OH)C,H,CHO. Aluminum equipment has been used to handle synthetic vanillin. See also Ref: (8) p. 124. VARNISH. A resinous solution or drying oil. Aluminum alloys have been used for varnish kettles. Lead drying agents have caused pitting and failure in some aluminum alloy varnish kettles. See also Ref: (1) p. 146. (2) p. 770, (3) pp. 131, 237. VEGETABLES. Vegetables have been prepared in aluminum alloy kitchenware. The cooking periods are relatively short, and even acidic vegetables have negligible effect. Aluminum alloys have been used for certain canned vegetables. See also Ref: (1) p. 146, (3) pp. 198.208, (4) pp. 78, 79, .%I.88, 106. 109, 115. (6) p. 11. VINEGAR. In laboratory tests, 1100 alloy was resistant to various types of vinegar at ambient temperature. At SOC (122F), the corrosion was increased and the attack was moderate (- 7 mpy). Aluminum alloy distillation columns, tube, pipe and tanks have been used in producing vinegar. Vinegar contaminated with chloride or heavy metal ions promotes pitting of aluminum alloys. See also Ref: (1) p. 146, (3) pp. 126. 198, 210, (4) pp. 22, 24. 31, 84, 92. VINYL ACETATE. CHI. COO. CH CH?. Aluminum alloy equipment has been used for polymerization kettles, driers, containers and tank trucks in the production and handling of vinyl acetate. See also Ref: (3) p. 136. (7) p. 193. VINYL CHLORIDE MONOhER. CH,:CHCI. Aluminum alloy aerosol containers have been used to handle vinyl chloride. Vinyl chloride slurries have been handled in aluminum alloy pipe. CAUTION: See Halogenated Hydrocarbons. See also Ref: (2) p. 875, (3) p. 108. (7) p. lc13. VINYL CHLORIDE CHLORIDE. POLYMER. See POLYVINYL
TURPENTINE. (Usually contains mainly n and 4 pinene; also camphene, dipentene. other monocyclic terpenes. p-cymene). In laboratory tests, 3003 alloy was resistant to turpentine at ambient temperature and at the boiling temperature. Production of turpentine has been carried out with aluminum alloy distillation equipment, heat exchangers, and tanks. Alloy A356.0 valves have been used for handling turpentine. See also Ref: (2) p. 866, (3) pp. 104, 226, 238. (7) p. 189.
U
UNDECYLENlC ACID. CH,:CH .(CH&,.COOH. Aluminum allo) receivers and storage tanks have been used for handling undecylenic acid. UREA. H2N. CO. NH>. Alloy 3003 was resistant to solid urea while 5154 alloy suffered mild attack in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, 3003 alloy was resistant to solutions of urea at ambient temperature. Aluminum alloy equipment. including distillation columns, driers, heat exchangers, storage tanks. and piping, has been used for handling urea. See also Ref: (I) p. 146, (3) p. 147. (7) p. 191.
WHITING. CaCO,. (Naturally occurring calcium carbonate about 98% pure). Aluminum allo) bins VINYL RESINS. Vinyl resins have been shipped in and drums have been used for inter-plant and inaluminum alloy tanks and drums. Alumincnl alloy plant handling of whiting. See also Ref: (3) p. 76. tanks, comeyors. and bins hake been used for inplant storage and handling of vinyl resins. See also WINES. In laborator) tests, the corrosion eftects of Ref: (3) p. 233. wines on aluminum alloys vary widely. Discoloration of some wines contacting aluminum alloys wa$ also \lTAMINS. Aluminum alloy equipment has been encountered. Aluminum alloy equipment such as pipused to process and handle vitamins. See also Ref: (2) ing, fittings, containers for transferring grape juice, p. 82. (3) pp. 104. 115. 124. 138. 198. 205. unfermented wine. fermented wine. and fortified wine as well as grape pulp or must har been used in the wine industry. Coated pure aluminum tanks have been used for storage and shipment of u ines. Wine has been packaged in coated aluminum alloy cans. SeealsoRef:(l)p. 147, (3)~. 202.(4)pp. 93.94, 142.
WATER. HIO. Aluminum alloys have been used for handling a wide variety of waters. In high purity water, laboratory tests show that a slight reaction occurs originally between the aluminum alloys and distilled, deionized. and uncontaminated rain water, but after a few days it ceases and aluminum pick-up by the water becomes negligible. Aluminum alloy tanks and piping have been used for storage and distribution &fdistilled and deionized water. At elevated temperature, - 200C (392F) and above, both distilled and deionized water cause very severe corrosion Of most aluminum alloys. Special aluminum alloys containing iron and nickel as alloying elements have been developed for use in high purity water up to temperatures of 360C (680F).
WOOD. Wet wood has caused varying degrees of corrosion of contacting aluminum alloys in laboratov tests. The degree of corrosion varied uith the type of wood tested. It is good engineering practice to apply protection where aluminum alloys will contact wood which may become wet. Aluminum alloy nails, screws. and bolts have been used in wood. See also Ref: (1) p. 147. (3) p. 231. WOOD CREOSOTE. (A mixture of phenols, chiefly guaiacol and cresol.) In laboratory tests, wet wood treated with creosote did not accelerate corrosion of
(continued)
630
TABLE 5.2:
ALUMINUM
ALLOYS-ALUMINUM
ASSOCIATION
(continued)
ZLNC STEARATE. A mixture of the zinc salts of stearic and palmitic acids and usually uith some excess of zinc oxide. Allov 3003 and 5154 were resistant to solid zinc stearare in laboratory tests conducted under conditions of l&We relative humidity at ambient temperature
contacting 3003 alloy under conditions of 100% relative humidi at SZOC (125F). Aluminum alloy equip ment including coils, heat exchangers. and tanks has been used to handle creosote. SeealsoRef:(l) p.131, (3) pp. 117, 223. WOOD PRESERVATIVES. In laboratory tests, wood preservatives were found to vav greatly in their corrosivity to aluminum alloys. Some caused less than 1 mpy attack while others, particularly those containing copper or mercury salts or zinc chloride, were very corrosive. Creosote. zinc napthanate and pentachlorophenol were found to be most compatible with aluminum alloys. None of the wood presep vatives was inhibitive.
to 10%) solutions of zinc acetate at ambient temperature. See also Ref: (3) p. 80. ZINC BORATE. 3 ZnO 2 B*O,. Alloys 3003 and 5154 were resistant to solid zinc borate in laboratory tests under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, 1100 alloy was resistant to dilute (up to 10%) solutions of zinc borate at ambient temperature. See also Ref: (3) p. 80.
X
XYLENE. C,H4(CH,)]. In limited laboratory tests, 3003 alloy was resistant to xylene at the boiling temperature. Xylene has been handled in aluminum alloy piping. condensers. and pressure vessels. See also Ref: (1) p. 147, (3) pp. 104. 223, (7) p. 193.
ZINC CHLORIDE. ZnC12. Solid zinc chloride was corrosive to 3003 alloy in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laborator) tests. dilute (up to 10%) solutions of zinc chloride caused mild attack of 1100 alloy ( - 2 tnp! ) with evidence of localized pitting at ambient temperature. See also Ref: (1) p. 147. (2) p. 892. (3) p. 79, (7) p. 195.
ZINC SULFATE. ZnSO,. 7 H20. Alloys 3003 and 5154 were resistant to solid zinc sulfate in laboratory tests conducted under conditions of 1CWo relative humidity at ambient temperature. In other laboratoy tests. 1100 alloy was resistant to aqueous solutions (up to 10%) of zinc sulfate at ambient temperature. See also Ref: (1) p. 147, (2) p. 8%. (3) p. 79, (7) p. 195.
References Alloys-Struc1. Mondolfo. L. F.. Aluminum Boston: Butteworth & ture and Properties. Co., 1976 (reprinted in 1979). New York: 2. Rabald. E., Corrosion Guide. Else&r Publishing Co.. 1968. P. and M. Sigxalt. Aluminum-Its 3. Joni&, Applicatton in the Chemical and Food lodustties, New York: Chemical Pubhshing Co., 1964. 4. Br+n. 1. M.. Alummium and Aluminium Alloss in the Food Industn. (Fw/ :,Iws~~~,I. liorr. Spcid Repurr. No. So). London. His Majestys Stationery Office, 1948 5. Witt. C. A., A. Labenski and G. Gerken. Resistance of Aluminlum to Various Chemicals.Alumi~~r~n~, 1979. 55. (8). 526-532. 6. Kunz. E.. Corrosivity of Different Food Groups in Aluminum Packaging Materials. Edited version. Institute for Food Technoloa and Packaging, 1974. 7. Hamner. N. E.. Corrosion Data SuwevMetals Section. Houston: National Assoclaiion of Corrosion Engineers. 1974. 8. Das Chemische Verhalten van Aluminium. Dusseldorf. Aluminium-Verlag. 1955. 9. Bohner. H. and H. Buschlinger, Survey of the Behavior of Aluminium Toward Chemicals and Food Products. Housrrirschrifr (1931) 9 (II), 301. 10. Aluminium in the Chemical and Food Industries. London: British Aluminium Co.. 1959.
Y
YEAST. Limited laboratory tests indicated that 11OC alloy was resistant to yeast at ambient temperatuw and 32C (90F). Production of yeast has been carried out in aluminum alloy vessels. Aluminum alloy equipment for brewing and distillation of yeast has been used. Yeast has been packaged in aluminum foil. See also Ref. (I) p. 147. (2) p. 889, (3) p. 210, (7) p. 193.
ZINC CHROMATE. Zn,CrO&OH)2.H~0. Alloys 3003 and 5154 were resistant to solid zinc chromate in laborator) tests conducted under conditions of 100% relative humidity at ambient temperature. Zinc chromate has been used as an inhibitive pigment in organic coatings used on aluminum alloys. See also Ref: (3) p. 80, (4) pp. 95. 139, 141.
ZINC NAPHTHANATE. Zn(C-H,,O,JJ. In laboratory tests. zinc naphthanate preservative treatment did not accelerate attack of aluminum alloys by contacting wet wood.
Z
Alloys ZINC ACETATE. Zn(CHICOO):.2H20. 3003 and 5154 uere resistant to solid zinc acetate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laborator) tests, 1 IO0 alloy uas resistant to dilute (up
ZINC NITRATE. Zn(NO,),.6H,O. Alloys 3003 and 5154 were resistant to solid zinc nitrate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, 1100 alloy was resistant to dilute aqueous solutions of zinc nitrate at ambient temperature. See also Ref: (1) p. 147. (3) p. 80.
ZINC OXIDE. ZnO. Alloys 3003 and 5154 were resistant to solid zinc oxide in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. See also Ref: (3) p. 79.
Designations
for Wrought Alloy Groups
Designations
for Casting Alloy Groups
Alloy No. Aluminum-99.00% minimum and greater. . lxxx Aluminum-99.00%
Alloy No. minimum and greater . 1xx.x
Major Alloying Element Aluminum alloys grouped by major alloying elements Copper ..................... Manganese .................. Silicon. ..................... Magnesium ................. Magnesium and Silicon ....... Zinc ........................ Other Element. .............. Unused Series ............... 2xXx 3xXx 4xxx sxxx 6xxx 7xxx 8xXx 9xxx Aluminum alloys grouped by major alloying elements
Major Alloying Element -Copper . . . . . . . . . . . . . . . . . . . . Silicon, with added Copper and/or Magnesium . . . . . . . . Silicon . . . . .1. .............. Magnesium. . . .............. Zinc . . . . . . . . . .............. Tin . . . . . . . . . . .............. Other Element .............. -Unused Series .............. 2xx.x 3xx.x 4xx.x 5xx.x 7xx.x 8xx.x 6xx.x 9xx.x
(continued)

TABLE 5.2: ALUMINUM ALLOYS-ALUMINUM ASSOCIATION (continued)
631
INHIBITORS
An inhibitor is a substance which, when added (usually in a small amount) to a liquid or chemical. reduces or prevents the corrosion of a metal which would otherwise occur. Some of the common inhibitors for aluminum and the media in which they have been used are:
INHIBITORS ARRANGED ACCORDING
TO ENVIRONMENT
Environment
Acid, hydrochloric, 1N
Inhibitor ..........
0.003 M aphenylacridine. finaphthoquinone, thiourea. or 2-phenylquinoline Tannic Acid or rosin 0.5 g/l acridine, 1.0 g/l thiourea, or nicotinic acid 0.06% acridine 0.05% hexamethylene tetramine 0.1% hexamethylene tetramine 0.1% alkali chromate 0.5% hexamethylene tetramine 0.6% ammonium hexafluorophosphate 0.5% sodium chromate 1.0% sodium chromate 5.0% sodium chromate Sodium metasilicate Dibenzyl sulfonic acids; phenyl quinoline Trace of Hz0 Sodium nitrite and sodium molybdate Sodium disilicate Agar Sodium silicofluoride Sodium chromate Albumins H,S; CO, + H,S Sodium silicate Sodium chromate Amines. Butylamine Alkali silicates; sodium chromate 0.2-0.5% formamide O.l-0.2% nitrochlorobenzene Sodium silicate Silicates (1%)
Environment
Glycol-water, 30 : 70
Inhibitor . . .
2% sodium cinnamate + 0.1% sodium tetrasilicate + phosphoric acid to pH = 9.5 Alkali metal nitrates; Sodium metasilicate Sodium silicate
Acid, hydrochloric, Acid, hydrochloric Acid, hydrochloric, Acid, nitric, 2-S% Acid, nitric, Acid, nitric, Acid, nitric, 10% 10% 20%
1 N.. . . . . . . . 0.25, 1 N (32F) 2 N .......... ..............
Hydrogen Hydrogen
peroxide peroxide,
...............
alkaline
....... .
................ ................ ................ ..............
Latex coagulation ................ Lead paint pigments or lead soaps
Sodium fluosilicate Linoleates, laurates ricinoleates
or
Methanol
or ethylene
glycol
...... .
Acid, nitric fuming Acid, Acid, Acid, Acid Acids
phosphoric, 20% ........... phosphoric, 20-80% ........ sulfuric, cone .............. sulfurous ................... ..........................
Methyl alcohol Methyl chloride. Pineapple Potassium
O.Ol-2% benzotriazole + O.l-2% Na molybdate or umenate or arsinite + OS-2.5% buffer to pH 7.5-10s Sodium chlorate + sodium nitrate Water Sugar Sodium
............. Alcohol, anhydrous Alcohol, (antifreeze) (See also methyl and ethyl). .....
Alkaline solutions (mild) ........ Alkaline solutions, e.g. sodium carbonate ..................... ........ Alkaline. soda solutions Alkalies ...................... Ally1 alcohol .................. Ammonia, condensing steam .... Barium hydroxide ............... Brines ......................... Bromoform; Chloroform Iodoform Calcium chloride. sat.
juice chloride
chromate
Seawater. . Soap.............. Sodium acetate Sodium carbonate.
. . . . . . . _. . . ... . . .. . .
............ ........... ..........
Sodium Sodium Sodium Sodium Sodium Sodium Sodium
carbonate, dil carbonate, 1% carbonate, 10% chloride, 3.5% cyanide.. hydroxide, 1% hydroxide, 1%
Carbon tetrachloridc Chlorinated aromatics Chlorine Detergents Ethanol, water
...................
......................
commercial
............. .
glycol
Ethanol. hot . . Ethyl alcohol or ethylene
. .
Ethyl formate Ethylene glycol
................... ..................
0.03% alkali carbonates, lactates, acetates or borates Potassium dichromate 1% (NaNOz + Na molybdate), 1% (NaNO* + Na tungstate), or 1% (NaNo? + Na selemate) Aconitic, formic or malonic acids (0.5%) Sodium tungstate or sodium molybdate; Alkah borates or phosphates; O.Ol%-1.0% sodium nitrate Albumins, collagen
Sodium hydroxide, Sodium hydroxide, Sodium hydroxide, Sodium hypochlorite in bleaches. . Sodium phosphate, Sodium sulfide . Sodium sulfide . Synthetic detergents Trichloroethylene Water, natural
4% 0.3 N (3X). 0.5 N contained
. . . . . ..., ... . . .
0.75% sec. amyl stearate Sodium silicate Alkali silicates Bone glue; vegetable glue; chromate; gelatin; gum arabic Sodium fluosilicate 0.25% sodium silicate 0.05% sodium silicate 1% sodium chromate Sodium metasilicate Alkali silicates 3-4% potassium permanganate 18% glucose 0.4% tragacanth gum 0.2% agar-agar Sodium silicate .SStfirm silicate
dibasic,
tribasic
. . . .. .
. . . ...
I % sodium metasilicate Sodium silicate

0.02-0.05% formamide
surface
. ...
Potassium chromate, dichromate; sodium chromate, dichromate 0.1% Na+O,, pH = 7-9. or 0.1% Na me&silicate + 0.1% Na
Water recirculating air conditioning.
for
g<zyhphate.
pH =
Fruit and milk acids
....
.. . . .
632
Corrosion
Resistant
Materials
Handbook
TABLE
5.3:
ALUMINUM
BRONZES
AND
NICKEL-ALUMINUM
BRONZES-AMPCO aluminum and shell
METAL bronzes and nickel-aluminum mold castings; forgings; rolled
The AMPCO alloys recommended for process applications are essentially bronzes. They can be produced in a wide range of forms-sand, centrifugal sheat and plate; extruded and continuous cast rod, tube and shapes. Applicability of AMPCO Alloys to Various
Chemical
Agents
Acetate Solvents (Pure) Crude Acetic Acid Crude Vapors Acetic Anhydride Acetone Acetylene (Wet) Alcohols Aluminum Fluoride Aluminum Sulfate Aluminum Hydroxide Ammonia Gas Drv Ammonium Chloride Ammonium Hydroxide Ammonium Nitrate Ammonium Phosphate Ammonium Sulfate Amy1 Chloride Asphalt Barium Chloride Beer Beet Sugar Liquors Benzene or Benzol Borax Boric Acid Brine Butane, Butylene, Butadiene Butyric Acid Calcium Bisulfite Calcium Hydroxide Calcium Hvoochlorite Carbon Dioxide Dry Wet Carbon Disulfide These ratings may usually be interpreted as follows:
RX R NR
R RRX
Rx R R
wit
R RF :: R! RX
Carbon Tetrachloride Chlorinated Hydrocarbon Chlorine Dry Wet Chloroacetic Acid Chloroform Chromic Acid Citric Acid Copper Sulfate Corn Starch Slurry Diesel Oil, Light Esters Ethers Ethylene Glycol Ethyl Sulfate Fatty Acids Ferric Chloride Ferric Sulfate Formaldehyde Formic Acid Freon Furfural Gasoline Glucose Glycerine Hydrocarbon Gases Hydrochloric Acid to 15% over 15% Hydrocyanic Acid Hydrofluoric Acid Hydrogen Fluoride (Dry) Hydrogen Hydrogen Sulfide zt Hydrogen Peroxide
Ketones Lacquer and Lacquer Solvents La&c Acid Magnesium Chloride Magnesium Hydroxide Magnesium Sulfate Malt Beverages Mercuric Chloride Mine Water (Sulfate) Molasses Monochlorobenzene Naptha Natural Gas Nickel Chloride Nickel Sulfate Nitric Acid Nitrogen (Dry) Oleic Acid Oxygen Paint Vehicles (except Soya-Oil) Palmitic Acid Petroleum Oils Sour Refined Phenol Phosphoric Acid Pickling Acid (except Nitric Chromic) Potassium Chloride Potassium Cyanide Potassium Hydroxide Potassium Sulfate Propane Shellac Soaps Soda Ash (Sodium Carbonate)
RX R
NR RX R RX RX R RX
!i ;
N; R R RX
Sodium Bicarbonate Sodium Bisulfate Sodium Chloride Sodium Cyanide Sodium Hydroxide Sodium Nitrate Sodium Perborate Sodium Peroxide Sodium Phosphate Sodium Silicate Sodium Sulfate (Soda Cake) Sodium Sulfide Sulfur (Molten) Sulfur Chloride (Wet) Sulfur Dioxide Dry Sulfuric Acid (to 50%) Sulfurous Acid Tannic Acid Tartaric Acid Toluene or Toluol Tri-Chlorethylene Tri-Sodium Phosphate Turpentine Varnish Vegetable Oils Water Fresh Salt (includes Polluted Harbor) Xylene Zinc Chloride Zinc Sulfate
wet
RX R :;
RX
R - Generally suitable. Corrosion rates less than 2 mpy. RX-Generally suitable however conditions such as aeration or temperature could restrict their use. Corrosion rates IeSS than 20 mPy. NR - Generally not suitable. Corrosion rates over 20 mpy. In evaluatmg this data, it should be understood that these are results of specific tests and are indicative of those conditions under which the tests were run, thus are a basis for recommendation, but not for guarantee.
CORROSION No aeration
IN BOILING SULFURIC ACID no agitation except boiling

AVG.
SOLUTION
CORROSION RATE, INCHES PER YEAR
/ I I
___
! _-. / : 1
MATER
I AL
5% HSO, 102O c (216 F)
10% HSO, 105 c (221 F) 23 hr. tests
19% H,SO, 105C (221 F)
150% HISO.
1 123C
(253 F) 20 hr. tests
/ MONEL ! ALUMINUM 400 BRONZE ALLOY

NICKEL 200 ALLOY CHEMICAL LEAD
(10%
AL)
0.0019 0.0034 0.034 0.016
0.0002 0.0024 0.12 0.015
0.0012 0.0075
0.0079 0.65
0.11
0.042
3.4
1.2
Nonferrous Metals and Alloys TABLE 5.4: ALUMINUM COATING-ALCOA
633
12-YEAR INSPECTION TESTS ON METALLIZED

PANBLTYPB BASE METAL PREPARATION
RESULTS
OF ATMOSPH.ERK
EXPOSURE
ALUMINUM
1 1
COATED CARBON STEEL PANEIS

2 1 3 1 4 1
ALUMINUM COATING THICKNESS, in&s TYPE TEST OF SEAL COAT

l
0.003
* NOM
0.003
0.003
0.006
WP+Av-1
WP+AV-2
NOlK
SITB LOCATION
ENVIRONMENT Base metal no( atracked. Sprayed metal intact but show a very faint yellOr gray stain 00 front of panels, ,witb a VT Ii&t rryhmc sod whne rust Base men1 not attacked. Sprayed meal intact Vinyl seaI coat on from of panels shows dull gray blacba. Vinyl saI ;sxo;to of panels
SALT-AIR
SamensType2.
Same u Type 1.
coLuh4zBus.
OHIO
URBAN
Base metal not attacked. Sprayed metal on front of panels shows many pinpoint aodw and a general dark gray deposit stain. Back of show a ,enerr:: gny sum. Base metal not attacked. Sprayed metal on from of panels shows many pinpoint nodes and a general dark ay deposit rain. Back o Y paneb show a dark gtn, deposit win. Base meal not attacked. Sprayed metal on front of panels shows dull blotches. Back of panels are leu blotchy. Both sides show some low unbroken blisters. Base meal not attacked. s rayed metal on front o P panels intact. Sprayed metal on back shows small to medium red rust snias. Base mm1 not attacked. Sprayed metal on front of panels shows many pinpoior nodes and a general gray deposit stain. Sprayed mm1 on back intact.
Base metal not attacked. Sprayed metal intact. The vinyl seal coat show L chin dark gray deposit sain on both the front and back of pnel.s.
Bue metal not attacked. Sprayed metal and vinyl se-al coat unaffeaed on both front and back of pan&.
Base metal ax attacked. Sprayed mm1 on front and back of panels shows many piapoinc noder and L general dark gray deposit stain
Base meal nor~rmcked. %~%*$z%mt of pan& shows a general dark depceit stain. Back shows a thin deposit stain. Same a Type 2.
EAS~TC&~GO,
INDUSTRIAL
Base men1 not attacked. Sprayed metal on both from and back of panels shows many pinpoint nodes and a thick dark deposit stain.
KURE BEACH, NORTH CAROLINA ( ao-ft la)
SEVERE WE
Base men1 not arracked. Sprayed meal intact_ Vinyl seal coat shows &li,z:rs og ;a$~ !&a balalcJff~nels
Same as Type 2.
Same aa Type 1
KURE BEACH, NORTH CAROLINA (800~fc lot)
SALT-AIR
Base metal not attacked. Sprayed metal intact. Vinyl seal ccat shows dull grr, blotch- 0~1 front side. Seal ccat on back unaffected. Base metal not attacked. Sprayed metal inuct. Vinyl seal coat on front of panels is spotted with medium sized gray deposit stains. Seal cou on back unaffected.
Same Y Type 2.
Base metal not attacked. Sprayed metal on from and back of panels intact.
INDUSTRIAL
Base metal not attacked. Sprayed metal intact. wn~lsea~~coaf
Base metal not amcked Sprayed metal on fronr of panels shows many pinpoint nodes and general gray deposit stain. Sprayed meal on back of panels shows gray deposit stains.
POINT R?zYES. CALIPOR?JIA
SALT-AIR
Base metal nor attacked. s rayed metal 00 front o P panels shows P general very light stain over lo-25 ?z% the surface, mostly near the edges.
Base metal not xacked Sprayed metal infact. Vinyl seal coat 00 front of panels shows light gray blotches. Seal coat 00. back unaffected.
Base mm1 not amcked. Sprayed metal inact. Vinyl real ccut unaffected.
Same as Type 1.
Typa
of b.ue
mehal papaaior
* Types of II& WP AV - 1 -2 -
cod
1. Covse silica sand 2. Coarse silica and steel dash
Wuh primer Aluminum vinyl One cca of specified seaI ccat Two cop= of q&&d ral cat
(continued)
634
Corrosion
Resistant
Materials
Handbook
TABLE
5.4:
ALUMINUM
COATING-ALCOA
(continued)
12-YEAR
INSPECTION
RFiSULIIs
OF ATMOSPHERIC CARBON
6 1
EXPOSURE STEEL PANEIS

7 1
TESTS ON METALLIZED
PANEL lYPB
ALUMINUM
5 1
COATED
bntd)
8
1
BASE hfl?TAL PREPARATION NUMlMJM
THICIWESS.inches
l l
COATING
0.006
0.006
0.009
0.009
wp+.4v--I
IYPB OF SEALCOAT
TEST SITE LOCATION
wp+Av--I
WP+AV-2
ENVIRONMENT
sameOS
Type 1.
COLUMBUS.
OHIO
URBAN
%x
Same a, Type 4.
Same ar Type 2.
same *I
Type 2.
salnew Type 4.
Same u Type 2.
KURE BEACH. NORTH CAROLINA ( SO-fc la)
SEVERE MARLXE
Same u Type 2.
$x
KUKB BEACH, NORTH CAROLINA (800h II_?%)
SALT-AIR
Same as Type 2.
NEW
YORK AREA
CITY
INDUSTRLU Same 0s Typc4.
Sameu Type 5.
Types of bnrr m&l 1. 2.
fwe,%rhw
Trpm of md cod WP AV - 1 -2 -Wash primer - Aluminum vinyl -One coat of specified seal coat - Two coats of specified seal coat
Coarse silica sand Coarse silica and steel Bash
(continued)
Nonferrous
Metals and Alloys
635
TABLE
5.4:
ALUMINUM
COATING-ALCOA
kontinued)
12-YEAR
INSPECTION
RE%JL.I-S OF ATMOSPHERIC COATED

10 2 0.012
EXPOSURE STEEL PANELS

11 2 0.012
TESTS ON METALLIZED
PANELTYPE BASH METAL. PREPARATION
ALUMINUM
9 1
WON
kontd)
12 2 0.012
13 2 0.015
ALUMINUM COATING THICKNESS. inches TYPE OP SEAL COAT .* ENVIRONMENT
0.009
wP+Av-2
NOllC
WP+AV-1
WP+AV-2
NOtIe
TEST SITE LOCATION
COLUMBUS.
OHIO
UmAN
NIX Tatcd
Not Tested
NOt TCStCd
Tlpc 2.
sameu
zd
KURE BEACH. NORTH CAROLINA ( 80-h la)
SEVERE htNuNE
same u
Type 2.
KUlU BEACH. NORTH CAROLINA ( 800~fI lot)
SALT-AIR
sameu Type 4.
Same aa Type 2.
NEW YORK CITY AREA
INDUSTRIAL g?
SALT-AIR
* Trpa WP AV -1 -2
of 14
cod
- Wash primer - Aluminum vinyl -One cat of specified al cat -Two coat, of specified al am
(continued)
636
Corrosion
Resistant
Materials
Handbook
TABLE 5.4:
ALUMINUM
COATING-ALCOA
(continued)
12-YEAR
INSPECTION
RESULTS OF SEA WATER COATED

2 2
EXPOSURE STEEL PANELS

3 2 4 2
TESTS ON METALLIZED
PANEL TYPE
ALUMINUM
1 2
CARBON
BASH METAL PREPARATION
0.003
0.003
0.006
0.006
TYPE OF SEAL COAT
l l
WP+CV-1
wP+CV-2
NOOe
wP+CV--1
TEST SITE
DMRONMENT
Base cat.41 shows
rw PREEPORT. TEXAS TOTAL IMMERSION
red CID3-5 % of the md back of pm&. Sprayed meml and vinyl seal cca dissipaccd in rbere area% Edges
front
Panela missin&
Base metal mt atacked. Sp? cd mm1 00 f1ont & ck of panels shows P for Mall sawed blisters and red rust rmins. Edea have been damaged mechanically.
Base meal not amcked. Sprayed metal intact on both sides. Vinyl seal coat una5med 00 both rides. Edges have been damaged mcchMiolly.
WR.IGHTSVILLE BEACH. NORTH CAROLINA ( t&w-low-tide)
TOTAL IMMERSION
Base mad not amckd. Sprayed metal showa a few small. unbroken blistm on both sidn of panels. Vinyl vnln diuipDocd
SameasTypc
1.
Base meal not rmcked. Sprayed metal shows a few medium. unbroken blisters both sides oa of panels.
SamcaaTypcl.
PANEL
TYPE
5 2
l
6 2
7 2
8 2
BASE MrrAL PREPARATION
NlJhUNUM COATING THxCKNE.SS. incbcr TYPE OP SEAL COAT

l
0.006
0.009
0.009
0.009
wP+CV-2
wp+CV--I
WPs_CV-2
TJZST SlTB
ENVIRONMENT
PREEPORT.
TEXAS
TOTAL IMMERSION
SameuTypc4.
WlUGMSVfLLB BEACH. NGRTH CAROLINA ( below-lowide)
TOTN IbfMERSION
SrmcUTlpcl.
SameasType
3. e;:
SameuTypel
WIUGHTSVILLE BEACH, NORtTTf_f$lNA

m
^rn%@
Al-d&N?
SameuTypel.
Base meal no( wackcd. Sprayed metal shows P few unbroken blinns.
Fkasc meal not ncmcked. Sprayed metal shows P few. unbroken blisrcrr.
Vinyl ad Coal diuipated.
SEA WATER TY,W of bar mstd $wspar&m 2. Csilica sand and steel flub
l
Typa
of a.4
cod
WP CV - 1 - 2
- Wash prima -Clew vinyl -One ccac of specified seal coat -Two c-0 of specified seaI ccw
(contlnued)
Nonferrous
Metals and Alloys
637
TABLE
5.4:
ALUMINUM
COATING-ALCOA
(continued)
I2-YEAR
INSPECTION RE!XJLTS OF SEA WATER
EXPOSURE
TESTS ON METALLIZED ALUMINUM COATED CARBON STEEL PANELS kontd)

PANBL ZYPE BASB METAL PREPARATION 9 2
l
10 2
11 2
12 2
13 2
ALUMINUM COATING THICKNBSS. incha IYPB OF SW TESTSITE COAT

l l
0.012
0.012
0.012
0.015
0.018
NOflC
WP+CV-1
wp+CV-2
NofM
None
ENVlRONMBNT
WRIGHTSVILLE BEACH, NORTH CAROLJNA
( below-low-ride)
TOTAL IMMERSION
$x
Same u Type 1.
et:
SImc II TYPC 3.
Type3.
Same *I
sameu Type 1.
COMFOSITION AND
DESCRlPTION
OF SEAL COATS
Wash Primer
Rain component: Pigmmt: Insoluble type, inert, zinc chmmate Nawolatilc vehicle: Polyvinyl l=vl Volatile vehicle: Butyl md isopropyl alcohol Acid component: phosphoric acid Ethyl (or isopropyl) &Aol plus water
8.2% 9.576 02.376 16.0% BllUXC
An air drying, two-part, acid-zinc chromate wash cc& primer
Mi low puts ol the resin component rich oat put of she acid component to obmia 6ml prima campoaitioa. Aluminum Vinyl Pigment: Non-leafing aluminum flake Nonvolatile vehicle: Vinyl copolymer md plasticizer Volatile vcbicle: Tolume and ketone Pi-: None Nonvolatile vehicle: Vinyl dllori&-a Resin PlUti&Cl Volatile v&hick: Ketones Ammatic hydrocarbons (Tolumc. benxol. viol) (0 A vinyl copolymrf aluminum ah. air-drying trp of coating nut&l
10% 20% 70%
Oar
Vinyl
16% 1.4% 37.6%
A clear. vinyl copol~mcr. rirdrying coating IlUtcri~l
45.0%
American
Welding
Society,
Inc.)
638
Corrosion
Resistant
Materials
Handbook
TABLE 5.5: GALVALUME
ALUMINUM-ZINC
COATING-BETHLEHEM
STEEL
is the trade name for a patented sheet steel product having a coating of corrosion-resistant aluminumzinc alloy applied by a continuous hot dipping process. The alloy coating of aluminum and zinc combines the best properties of both metals. It has the corrosion resistance, high-temperature oxidation resistance, and heat reflectivity characteristic of aluminum coatings, with the formability and galvanic protection of cut edges characteristic of zinc coatings. GALVALUME sheet, both bare and painted, is intended for applications where superior corrosion resistance is required, as in roofing, siding, pre-engineered buildings, appliances, air conditioner housings, and other uses. GALVALUME sheet is also used for applications where resistance to oxidation at elevated temperatures is important, such as fireplaces, toasters and automotive exhaust systems. Atmospheric Corrosion Resistance: Based on 13-year atmospheric test results (see Figure I), it is estimated that GALVALUME sheet will outlast galvanized by two to four times in marine, industrial and rural atmospheres. When compared to aluminum coated sheet steel, GALVALUME sheet has superior corrosion resistance at sheared edges. Salt Spray Corrosion Resistance: With cut edges protected, the coating on GALVALUME sheet steel lasts five to ten times longer than the coating on galvanized (see Figure 2). In salt spray tests conducted with bare cut edges exposed, the corrosion resistance is typically three to four times that of galvanized (see Figure 2).
HOURS
OF EXPOSURE
TO
FIRST SIGNIFICANT RUST ASTM B117 Salt Fog Test
CORROSION AFTER
LOSSES
OF GALVALUME EXPOSURE
AND
GALVANIZED
SHEETS
13 YEARS (AVERAGE
IN THE ATMOSPHERE. SURFACES) 0.5_ 0.6 0.7 0.8 0.9
TOP & BOTTOM
CORROSION LOSS (Mils) KURE BEACH (Sev;F_eTMalaye)
0.1
0.2
0.3
0.4
P
!OOO
GALVANIZED GALVALUME
KURE BEACH (Marine) 800 FT LOT
BETHLEHEM (Industrial)
SAYLORSBURG (Rural) Figure

Firat
1
Rust, 4 Years
l*Flnrt Rust, 10 Years
GNPR~TECTED EDGES Figure
PROTECTEI
EDGES 2
TABLE
5.6:
BERYLLIUM
COPPER
ALLOY-BRUSH
WELLMAN
Corrosion Rorirtanco of Soryllium Copper in Soa Water
Beryllium copper is the material of choice in an array of designs demanding corrosion resistance. From instrument springs and bellows exposed to hostile atmospheres, to bushings and tubular products used in harsh oil field environments, beryllium copper alloys are selected to solve corrosion problems. In combination with corrosion resistance, beryllium copper alloys are considered nonmagnetic and offer high electrical and thermal conductivity with high strength. BRUSH ALLOY 25, a heat-treatable beryllium copper product contains 1.80 to 2.00% beryllium. BRUSH ALLOY 25 is resistant to hydrogen embrittlement, and not susceptible to either sulfide stress cracking or chloride stress cracking. Moreover, in marine and certain industrial environments this alloy outperforms stainless steel, titanium, and most copper based alloys. Beryllium copper is available in a wide range of forms, including strip, tube, rod, bar, extrusions, casting and master alloy, and forging billet.
GUIDE TO ROOM TEMPERATURE USE OF BERYLLIUM COPPER* Acceptable Atmosphere Industrial Marine Rural Fresh Brine Softened Sewage Soil Chlorine Oxygen/Ozone Carbon Dioxide Sulfur Dioxide Ammonia Fuel Gases Alcohols Chlorinated Solvents Fuels Lubricating/Hydraulic oils Non-Oxidizinq Acids acetic acid hydrochloric acid dilute sulfuric acid phosphoric acid Alkalies Acetylene Not Recommended
=
TEST MEDIA 32-70
zzz?
=
E
-_ ,
R -_
n -.
CORROFON Ccmdltlon and Heat Treatment Phosphorus deoxidized copper................ AT (quenched from 1470 and ased 3 hr at 570 F) HT (quenched from 1470 F. cold rolled and aged 2 hr. at 525 F) mdd
-I-
IPY 0.0009 OSXW O.WJ4
5.6 2.3 2.3
-.
Interrupted alternate immersior in sea water 140 96 hours
-_ -_
96 hours i.91 0 1.89 2.74 2.99 0 2.0 2.5 3.5
-IEE: 0.0037 0.0034 o.OOQ7 0.0014 irIG& O.CiUX 0.0034 O.WO4 O.OtW4
-_
-.
-3.9 7.8 2.3 4.3 3.4 2.0 2.2 2.2 2.3
59 Z*i%
S~,Fg.~ 2.36 in.
-_ -7 weeks
-_
113 S:;9,l.~39 2.36 in. 3 weeks 0 1.5 2.0 2.5 3.5 3% NaCl solution saturated with CuCl Room yyg.39 2.36 in. 3 weeks 0 1.5 2.0 2.5 3.5 --
-Annealed % hr. at 1020 F A (quenched from 1510 F) AT (quenched from 1510 F and ared 3 hr. at 660 F) A (quenched from 1510 F) AT (quenched from 1510 F and aged 3 hr. at 660 F) A (quenched from 1510 F) AT (quenched from 1510 F and aged 3 hr. at 660 F) AT (quenched from 1510 F and aged 3 hr. at 660 F) 3.3 ;:: ::: 2.6 2.8 2.8
-I- 0.0035
::EE% ::EZ o.ooo5 O.GlXX 0.0005
Water
Gas (dry)
_-
Organic Compounds
Pyridine
Inorganic Chemicals
Ammonium Hydroxide Oxidizino acids/salts chromic acid nitric acid ferric chloride Mercury
Artiticial sea water
68
-Y:% ::3 9.96 2.P,
--_ 112.1 Annealed H hr. at 1020 F A (quenched from 1510 F) ;;U& AT (quenched from 1510 F and awl 3 hr. at 660 F) 100.2 A (quenched from 1510 F) 78.4 AT (wenched from 1510 F and aged 3 hr. at 660 F) 150.7 A (quenched from 1510 F) 154.9 AT (quenched from 1510 F and aged 3 hr. at 660 F) 42.9 A (quenched from 1510 F) AT (quenched from 1510 51.5 F and aged 3 hr. at 660 F) cast _,__. cast.. cast.. cast.. __. _. ._.
-I-
0.0180 %E: I::;:: ::k% ::E%
c,;as3;3~4 0.394 in.
15 days
.- -Artificial sea water Strip I168 hours
--
,...........,.... _-Ascast .. .
As As As As
..
--
*Corrosion can be affected by temperature. concentration, velocity, and the presence of other chemicals.
= =
lmdd = mgldmlday;ipy
= in/yr
Electrolytic copper. H (cold rolled). A quenched from 1480 F) A 4 (quenched from 14UJ F and aged 3 hr. at 570 F)
_- -/ 0.0052 F / / K%! , 2 , X:EE 4 _t 16.9

15.7 fQ:Z
IE27 I3.0035
IKQ28
(continued)
TABLE 5.6:
BERYLLIUM
COPPER ALLOY-BRUSH
WELLMAN
(continued)
Effect of Immersion in Hydrochloric on 2% Beryllium Copper
Effect of Immorslon in Bulfurir Acid on 2%
Beryllium Copper
=TemTYPE OF TEST Alternatr immerr;ion in 10% solution. 1% min. in solution and 1% min.inair -Interrupted alternate immersion in IO% solution ____ CntinUUs immersion in 10% solution ~-Continuous immersion in 5% WI. iuric acid ---COntiiWUS immcrciun
=
coRp;l,,tN
__
YE: F. 146
Tempera-
_-
Spedmen -S:~ip&Ox~ R in.
1Durntlon
0
Condltlon and lieat Treatment Phosphorus deoxidized copper. (quenched from 14iO F and aged 3 hr. at 570 F) IIT (quenchrd from 14iO F. cold rolled and aged 2 hr. at 525 F) ~_~
__ mdd
1 -_
ture.
F
m Spedmen sp&o;u 8 in. Duratiot 0 2.0 Gmdltlon and Heat Treatment Phosphorus deoxidized copper AT (quenched from 1470 F and aged 3 hr. at 570 F) HT fquenched from 14iO F. cold rolled. and aged 2 hr. at 525 F) _______~ 0 1.89 Not aged..
COR&$l,ON -mdd 453 332 332 -. IPY 0.073 0.058 0.058
bY
T:::TF Alternate immersion 1% min. in solution and I% min. in air in 10% HCI Interrupted alternate immersion $O% Cntinus immersion i; F3l%
__
2.0
AT
mm .5 i 1 J
4840
0.609 0.X92 0.852
70.75
_.
140
_.
strip
____ 96 hours 0 1.89 hotaaed...............
1240 1148
0.199 0.19x
140
--__ 96 hours
_~ 147 182 0.024 0.03
_~
68
_~
C~;;~;43;4 3.94 in. 24 hours
--2.05 As
cast.. .
____ IO0 O.Oli4 Rwm yipi Ip;O3I 7 days ___ 2 days 9 2.0 2.0
2.36 in.
_.-.
Room
_.___-.
Strip 24 hours 0 2.12
_. _.
Room
_.--Strip 6 hours 24 hours
.2.1 2.1 -2.1 2.1
-5% sulfuric acid + 3% potassium dtchromatf c -
10% solution
in
Electrolytic copper.. H (cold rolled). A (quenched from 1480 F) AT (quenched from 1480F and aged 3 hr. at 570 F) ---~ Apparentiv rolled. annealed and nged Same..................
Same.. _. ._. . ..
ir:
24 27 negligiljie 31 192340 18.600
-_ 0.0952 o.wl4 0.0642 0.0047 -_-_ -____ Continuous immersion i; &% Room -_ Strip. 0.039 x 1.18 x 2.36 in.
2.5 ~7 days 2.0
0.0054 3.46 3.24
~-_______ Annealed.. 1079 588 Annealed.. ~-~~ -__ A fquenched from 1470 F) AT fwenched from 1470 z: F and aged at 660 F) ~______~_ A (quenched from 1470 F) AT (quenched from 1470 2 F and aged at 660 F) ~__ ____-A (quenched from 1476 F) 402 656 AT (wenched from 1470 F and aged at 660 F) A fquenched from 1470 F) AT (quenched from 1470 F and aged at 660 F) As cast. 36U 585 50
-___
0.174 0.099 0.110 0.123
0.070 0.115 -Z:Z 0.009
_.
Strip 6 hours 24 hours
2.5 __24 hours
Same.,
_.
= =
=
iPY = in/Vr
Continuous immersion ;;,I% Continuous immersion ;;&O%
6s
ht.
0.394
2.05
x 0.394 x
mdd = mg/dmz/day;
a.94 in.
.68
--~ 3art. 0.394 x 0.394 x 3.94 in.

____itnp
24 hours
2.05
As cnst..
_.
90
0.016
In~uonco of Bwyllium Contw~tin Varying Concantratlonsof Sodium Hydroxide (Loss mdd) in
.Continuous immersion
_24 hours 0 2.12
__~__~
Electrolytic copper. H (cold rolled). (quenched from 1480 F) AT (quenched from 1480 F and aged 3 hr. at 570 F)
Rnt
.M
:: 45
Zy.5%
0.010 0.007 kX
I
TEBT CONDITIONS Continuous immersion for 24 hours et 68 F on cast specimens (not age hardened)
Bervllium Percent 0.49 1.00 5.05 2.05 9.96
I content. --1% Fz +? g :; 118 2.5%
CONCEhTRATION
4% . :::
__ 5%__ --139 130 I21
z=zzz=z 16% R s Z :: 30
7.5%
lmdd = mg/dm?day;
ipy = infyr
Infiue~nce of Beryllium
Content In Varying Concentrations of Acetic Acid (Loss mdd) in
Continuous immersion for 24 hours at room temperature on strip specimens a, iollows: Electrolytictopper.. Beryllium copper: H (cold rolled). _. . A (quenched from 1480 F). AT fguenched from 1480 F) andaged3hr.at570F) ..,__.__.,
__
9.4 10.6 7.7 11.6
E __--
......
...... ...... ......
_.
. . .
. .
TEST CONDITIONS
I?zcY i
I
CONCEhTRATlON
Percent ~lz.s46I5.ow(~/~
(continued)
TABLE 5.6:
BERYLLIUM
COPPER ALLOY-BRUSH
WELLMAN
(continued) hfluenca
of Beryllium Content in Varying Concentrarionr of Nitric Acid
=
TEST InRuonca CONDITIONS
(Loss in mdd)
I
1%
of Bwylllum Content In VaryIns Concontrotlonr of Ammonium Hydroxide (Less in mdd)

( I+rylllum
_-
-. 2.5% I -_--
CONCENTRATION 3% 312 269 w5 2.53 Ii7 251 215 2.53 I89 lR4 226 .
.__5%
10%
Continuous
immersion for 18 days at ro0m temperature on strip specimens. 0.039 x 1.18 x 2.36 in.. in annealed condition
/
lI%l2.5%1
CONCENTRATION
-__
.
__7.5%
_I 10%
1070 S 12 Sn 14 0 n Sn
-~ . -~ -.
120 Jo 3 -. 170 . . ... __..
_. _-
TEST
CONDITIONS* immrrsion specimens for 24 hours at 68 F (not age hardened)
pzz::v
5.5% ._ --
5%
.. . .
Continuous on cast
.. -Continuous immersion for 24 hours at r~)m temperatwe n strip specimens as follows:J~ Electrolytic copper.. Beryllium copper: H (cold rolled). (Quenched from 1480 F). AT (quenched from 1480 F and aged 3 hr. at 570 F). 0
E ii
... ... ... ... ... ... ... ...
_. _.
_. . .
Continuous immersion for 24 hours at 68 F on cast specimens (not age hardened)
... ... ... ... ... ... ... ... ... ... ... ... . . .. -__ ... .., . .., . .. Ii0
. . .., 1.50 r 2&L 94:500 750 1210 11.580
..
i:t;
2.!2
..,
88 % ::: 62
_Continuous immersion for 24 hours at 68 F on drawn specimens, 0.32 in. diam. x 0.60 in. long (not age hardened) Continuous immersion for 24 hours at room temperature on strip specimens as follows: Electrolytic copper.. Beryllium copper: H (cold rolled). A (quenched from 1480 F) AT (quenched from 1480 F and aged 3 hr. at 570 F). 100% cu 2.3% Be 10% Al 3:g
4o:oca __270 370 8530
*E&l :::
__
1070 3%
210 110 120 31.5w 94x+ 1% 11.050 --
..
-.
____ ,.,
._ . . . . =
--.-_
1695 I681 li48 1928 . ..,
. . .
zz==z=crz
..,
Corrosion
Rates in Phosphoric Acid and Vapor

D-80
Itaining
Phc phoric Acld
=
uanmy R3PoIandof 88 P Mist
HsPO (DrqbpPW
5-95s HaPO (~PPka) ytt&y >uantlties of FlUOlill~ Corn unds in a c ist of HsPOd At 212-239F
5-95s HaPO 1 con~t&h;;g a1 Amount of FlUO~lll~ Compounds At 165-185F

_-
MATERIAL TESTED
Beryllium Copper.. (2.02 Be, 0.21 Phos hor Bronze-C. (88 Sn). .
Units
. . mdd iPY mdd ipY 12.6 0.0022 11.1 0.z8 0.0009 3368 0.5900 4950 $jt$? 0.65& 1451 0.2550 O.bzO 148 0.0240 32.1 0.0054 yg$ .-2 3.422
Phoephorue in Store&z At 149-158F

6.8 +z312 0.0011 7.5 0.0012
Elemental
Traces of Fluorine Compounds At 185-212F

263 0.0460 538 O.&z0 0.0640 1709 0.3000 318 0.0540 o.zo
Ni) .
.
O.b> 515 o.OBo

0.1120
36.5 0izz4 0.0084 136.8 0.0220
Aluminum Bronze (57 Al). High bass.. (35% Zn). Cupro-Nickel.. (20% Ni. 5% Zn). Silicon Bronze (3.19, Si. 1.1% Mn) Monel, .............. (2.9% Cu). ........ Mild Steel (0.24% C). ........
25.9 i? O.CQ28 mdd iPY mdd iPY mdd ipY 29.7 i?? .?O= 0.0310
+i O.b% 48.4 o.Oa!30 41.6 0.0070 369 0.0600 Excessive Excessive 0.980 4375 O.T100 416 O.OioO
O.gl O.&l40 o.?zo O.%O
118 0.0203 43.2 0.0070 32.7 0.0055 86.1 0.0140 45.500 8.3100
4.1 0.0007 5.6 O.ooo9 7.1 0.0012 4.9 i?? 0.0040 --
........
...........
...
O.K?!O 274 O&45 197 0.0360
(continued)
642
TABLE 5.6:
BERYLLIUM
COPPER ALLOY-BRUSH
WELLMAN
(continued) Summarized
Corrosion
Resistance of Beryllium
Copper
Approximate Service Ratings (see note) Good

Acetic acid, 0.1% (RT) Alcohols Alum Ammonia, dry Atmosphere, rural marine industrial Boric acid Brines Bromine, dry Calcium chloride Carbon dioxide, dry or moist Carbon tetrachloride Chloride, dry Citric acid Fluorine, dry Freon Fresh water Gasoline I Iydrocarbons II,,,,,,n sulfide, dry Mercury (RT-200 F) Oxalic acid Phosphorus (150 F) Potassium. molten (up to 1112 F) Sea water (RT) Sodium chloride Sodium, molten (up to 1112 F) Sodium-potassium alloys, molten (up to 1112 F) Steam Sulfur dioxide, dry Tannic acid Trichlorethylene -
Limited
Acetic acid, 2.5-10% (RT) Bromine, moist (RT) Chlorine, moist (RT) Fluorine, moist (RT) Hydrochloric acid, O-5$& (RT) Mercury (200-700 F) Mine water Phosphoric acid, 3-95% (RT-212 Sea water (140 F) Sodium chloride, 3y0 + copper chloride Sodium hydroxide, l-10% (RT) Sulfur dioxide, moist Sulfuric acid, O-10% (RT) Zinc, molten
Poor
Aluminum, molten Ammonia, m.oist Ammonium hydroxide Bismuth, molten Bismuth-lead eutectic, molten Bromine, moist (ET) Cadmium, molten Chlorine. m_o_ist(ET) Chromic acid Ferric chloride Fluorine, moist (ET) Gallium, molten Hydrochloric acid, 10% (140 F) Hydrochloric acid, over 5y0 (RT) Hydrogen sulfide, moist Indium, molten Lead, molten Lithium. molten Nitric acid Sulfuric acid, 10% (140 F) Sulfuric acid, 5% + potassium dichromate, 3% Thallium molten Tin, molten
F)
Note:
RT-room
temperature ET-elevated temperature These ratings, based upon laboratory and field tests. are offered only as a guide. since corrosion rates are affected by agitation, temperature, aeration, concentrations, etc. Ratings based upon laboratory tests have the following significance:
Rating G_ood
Rate of attack, ipy
zzed
less than 0.001 0.001 to 0.010 more than 0.010
CHEMICAL
COMPOSITION
Nonferrous
Metals and Alloys
643
TABLE
5.7:
COBALT-BASE
ALLOYS-CABOT
STELLITE Nominal Chemical W C Composition, Ni MO Weight Percent Fe Si B Others
Cobalt-Base Co-0-W-C STELLITE STELLITE STELLITE STELLITE STELLITE
Alloys Type allov No. 1 alloy No. 4 alloy No. 6 alloy No. 12 alloy No. 20 Type
Forms
Cr
A&F A All All AS
30 33 28 29 32
12 14 4 8 17
2.5 1.0 1.1 1.3 2.5
Co-Cr-WiMo-NilFe-C STELLITE STELLITE STELLITE STELLITE STELLITE STELLITE STELLITE Code: A-Bare Cast Rod alloy No. 21 allov No. 238 alloy No. 306 alloy No. 694
A,B,C,F,G B C G A,BS A,B,F AS
27 26 25 28 31 33 25 12 1.5 19
0.2 0.1 0.5 0.9 1.3 1.7 2.0
2.8
5 3 20 5 1 5Nb, 1Mn 1v 8 10 18 15 1
6 5 8 8 22
alloy No. 2006 alloy No. 2012 alloy F
1.5
C-Tube
Wire-(Sub-Arc)
B-Covered
Electrodes
D-Tube
Wire-(Open
Arc)
E-Tube Wire (Gas Metal Arc) F-Powder
G-Solid
Wire
Comparative
Corrosion
Data*
Gas Tungsten Arc Deposits

Media Concentration and Temperature Acetic Acid 30% Boiling G E E G G E E G E E E E
Code: E-Less G-5 than 5 mpy (~0.13 mm/y) S-Over U-More 20 mpy (>0.51 mm/y) to 50 mpy (1.27 mm/y) than 50 mpy (11.27 mm/y) mpy (0.13 mm/y) to 20 mpy (0.51 mm/y)
Formic Acid 80% Boiling E E E E E -
Nitric Acid 65%,15OF (66%) S E U E U E E E E G G U
Phosphoric Acid 50%,15OF (66%) E E E E E E E E E E E E
Sulfuric Acid 5%,15OF (66%) E E E E U E E S E E E s
Alloy STELLITE alloy No. 1 STELLITE alloy No. 4 STELLITE alloy No. 6 STELLITE alloy No. 12 STELLITE alloy No. 20 STELLITE alloy No. 21 STELLITE alloy No. 238 STELLITE alloy No. 306 STELLITE alloy No. 694 STELLITE alloy No. 2006 STELLITE alloy No. 2012 STELLITE alloy F
Five 24-hr. test periods. Determined in laboratory tests. It is recommended that samples be tested under actual plant conditions.
644
TABLE HAYNES excellent
5.8:
COBALT-BASE
ALLOY-CABOT
WROUGHT
PRODUCTS good formability,

ALLOY
alloy No. 25 is a cobalt-base alloy which combines high-temperature properties to 1900F (1038C).
CORROSION RESISTANCE
wear and corrosion
resistance with
OF HAYNES
NO. 25
All results are expressed in mils (mm) penetration per year. Acid strengths are given in percent by weight. In some instances, no measurable penetration could be observed. These instances are noted by the word. Nil. All data are steadv-state as calculated from a minimum of five 24 hr test oeriods. TYPICAL PENETRATION RATES IN CORROSIVE MEDIA, Mlla (mm) Per Year
I
I Room 15Odeg F (66 deg. Cl Bolllng 10% Nil NII
ACETIC ACID
I 50% NII NII I w% Nil NII Nil
CHROMIC ACID Ilo% Nil I 20% Nil
1
Iml N Ntl !a% ,<%I, (cool)
FORMIC ACID IwYaI 40% (<oobl, N,I I 0% ,<%I, NII I 80% &I, 0.1 (cool)
12% Nil
N8
,oP,,
(0%)
,<?&
(<%l,
(0% CUPRIC CHLORIDE
(059,
I
I lx&
FERRIC CHLORIDE 5c&I ZxCl 10%
I 2% I Se&I I Nil
150 dep. F
l - I Nil 0.1 ,<O.Ol)
lQr&I
I 2% I I I I,AodTo,I Nil - I - I N I - I I
10% I NII I I NII Nil ( NII 1 -
166decl Cl Boiling
I -
Nil 0.5 (COO2)
HVDRDCHLDRIC 1% Room 15Odeg F (65 aw C) 0.1 (CO.01) NII 2% 0.1 (<O.Ol) 0.1 (C 0.01) 6% (02461, 474 (12.0) 10% (02564,
ACID 2on 6.0 (0.15) 266 I6 61) 25% (4oS0, ,;z, 37% ,0.05, 66 (1731
CH:%.4E
15% ,&, 552 (14.0)
(<OOlOl ,
-
I ll.&HC;, 16Odeg F (71 deg Cl 19Odeg F Wdeg 3

l
HVDRDCHLDRIC
NITRIC ACID MIXTURES 15.2%_;2,+ 17.2% HNOI (b&w~ht)
13.3% MNO, (tyehl)
(0%)
NITRIC ACID 10% ROOfll 150 deg. F (66 deQ. C)

Soiling
30% Nil NII 2.0 w5)
1ow NII 0.3 ,<O.Ol) 4.0 (0.10)
lQlc Nil 0.5 (CO.02) 9.0 (0.23)
50% Nil 0.6 (0.02) $6,
5m Nil 2.0 (0.05)
56% -
7& NII
Nil Nil 0.5 (CO.02)
,:.:7,
PHOSPHORIC
HVDROFLUORIC
SULFURIC ACID
Nonferrous
Metals and Alloys
645
TABLE 5.9:
COBALT-BASE
ALLOYS-WALL
COLMONOY
The name Wallex designates a line of cobalt-base hard-surfacing alloys. All of them resist corrosion well, but they vary in their ability to resist abrasion and impact, and in the way they can be applied. Wallex alloys would seldom be recommended for protection against corrosion alone. In most cases, they are chosen for their ability to fight the twin hazards of corrosion and abrasion. The specific alloy choice depends on a careful analysis of the extent of the problem presented by each hazard.
CORROSION
Corrosive Media
Wallex No. 1 and Wallex No. 6, containing chromium and tungsten, are virtually unaffected by the most commonly used corrosive chemicals, and by atmospheric corrosion. Wallex Nos. 40 and 50, containing chromium and tungsten, but also nickel and boron, are slightly less corrosion-resistant, but have the advantage that they can be produced in powder form for ease and efficiency of application, using the Colmonoy Spraywelder gun (or Fusewelder torch).
RESISTANCE
Concentration 10% 10% 50% 50% 50% 10% 10% 10% Sat. 2% 10% 10% 2% 10% 10% 10% 10% 2% 2% 10% 10% 20% Cont. 10% 10% 40% Cont. Cont. 10% 10% 10% 40% 5% 10% 2% 2% Temp. RT Boil FIT 15OF Boil
OF WALLEX
ALLOYS
IN VARIOUS
RATE:
MEDIA
PENETRATION Wallex No. 1 Nil Nil 0.2 0.2 2.0 Nil 1.0 Hiqh Nil 2.0 0.5 High 3.0 1.0 Hiqh Nil Nil 9.0 169.0 10.0 High 26.0 High Nil 0.1 0.1 0.2 Hiqh Nil 0.2 0.6 High 0.5 Hiqh 0.1 23.0 Nil High 0.2 0.3
Mils per year Wallex 40 & 50 Nil Nil NR 1.0 NR Nil NR NR NR Nil NR NR Nil NR NR Nil NR 39.0 NR NR NR NR NR 3.0 NR NR NR NR Nil Nil 63.0 NR Nil NR 157.0 NR NR NR NR NR
Wallex No. 6 Nil Nil 0.2 0.2 0.4 Nit 28.0 Hiqh High 0.7 0.5. Hiqh 2.0 6.0 Hiqh 0.5 1.0 0.1 120.0 9.0 High 16.0 Hish Nil Nil Nil 0.1 High Nil Nil Nil 0.1 Nil 2.0 0.1 Nil Nil High 0.1 Nil
Acetic Acid
Chromic Acid Chlorinated Water Cupric Chloride Ferric Chloride Ferric Sulphate
RTo 150 F Boil RT RT RT Boil RT RT Boil RT Boil RTo 150 F RT Boil RT Boil RT Boil RT RT Boil RTo 150 F Boil Boil Boil Boil RT 150F RT Boil RT RT
Hydrochloric Acid
Nitric Acid
Phosphoric Acid Sodium Hvdroxide
Sulfuric Acid
10% 10% 5096 90%
NOTES:
NR means either Not Recommended or loot I?arsd (i.e. unknown). RT means Room Temperature. Generally, a corrosion rate greater than 3.0 mils per year should call for caution. Whenever possible, it is advisable to make individual tests on specific applications.
646
Corrosion
Resistant
Materials
Handbook
TABLE 5.10:
COLUMBIUM-CABOT
KBI Corrosion Resistance of Columbium

S = normally no attack on purity V = variable, depending X = not resistant
Columbium has good resistance to many corrosive media, such as sulfuric, nitric, and hydrochloric acids, within certain defined limits. The accompanying table summarizes corrosion resistance of the metal. The following tests have been conducted with reagent grade chemicals, actual field testing could differ because of impurities. Field testing is htghly recommended.
Chemical
Temperature 2OC 60C 100C 66F Acetic acid (10%) Acetic acid (Glac. and anh.) Acetone Acetylene Alcohols (most) Aliphatic esters Aliphatic halogen compoundschloroform Alum Aluminum chloride Ammonia anhydrous Ammonium chloride Amyl acetate and chloride Aniline and compounds Aqua regia Benzoic acid Boric acid Brines, saturated Bromine, moist Calcium chloride Carbon disulfide Carbonic acid Chlorine, dry Chlorine, wet Chlorides of Na, K. Mg Chromic acid (80%) Citric acid Copper salts (most) Cyclohexane Detergent, synthetic Emulsifiers Ether Fatty acids (C=C6) Ferric chloride Ferric sulfate Fluorine Formaldehyde Formic acid Glycerine Glycols Hexamine Hydrochloric acid (10%) Hydrochloric acid (cont.) Hydrofluoric acid Hydrogen peroxide Hydrogen sulfide Ketones S S S S S 140F 212F S S S S S S S S S S
Chemical Temperature 20C 60C 1OOC 66 F 140 F 212 F Lactic acid (100%) Maleic acid Mercuric chloride Naphthalene Nickel salts Nitric acid (25%) Nitric acid (50%) Nitric acid (95%) Oils, essential Oils, mineral Oils, vegetable and animal Oxalic acid Oxygen Perchloric acid Phenol Phosphoric acid (25%) Phosphoric acid (50%) Phosphoric acid (95%) Potassium hydroxide Pyridine and compounds Seawater Silicic acid Silver nitrate Sodium carbonate Sodium hydroxide Sodium hyprochlorite Sodium silicate Sodium sulfide Starch Sugar and syrups Sulfates of Na, K, Mg, Ca Sulfites of Na. K, Mg, Ca Sulfonic acids Sulfur Sulfur dioxide, dry Sulfur dioxide, wet Sulfur trioxide Sulfuric acid (20%) Sulfuric acid (50%) Sulfuric acid (70%) Sulfuric acid (95%) Tallow Tannic acid (10%) Tartaric acid Vinegar Yeast Zinc chloride S S S V S S S S V S S S X S S S V V V X S S S S S X X X S S S S S S S S S X S X X X S S S S S S S
S
S
S
V S S S V X S S S X V S S X X X X S S S S S X X X S S S S S S S S V X S X X X S S S S S S
S
S S S V S S S X S S S S S V X S S S S S X X X S S S S S S S S S X S V V X S S S S S S
Gases Air 230 C (446 F) Reaction begins 388C (730 F) Accelerated reaction begins Nitrogen 300C (572OF) Reaction Hydrogen 204 C (400 F) Reaction Fluorine Attacked Chlorine 200 C (392 F) Reaction begins Steam 399 C (750 F) Fair resistance Metals molten sodium begins begins
S S S S S S S V S S S S S S S S S S S S S S S X S S S S X S
S S S S S S S X
S S S S S S S X S S S V S S S S S S V S S S S X S S S S : S S S S X X X X S S
S
S S S S S S S S S i S S S X S
Lithium, magnesium, potassium, 982 C (1800 F) maximum Aluminum Attacked Lead 849C (156OF) maximum Mercury 599C (111OF) maximum Bismuth 538C (lOOO F) maximum
S
S S ii
S
S S S S V X V S S
S
S
S
S V X X X S S
Nonferrous
Metals and Alloys
647
TABLE 5.11:
COLUMBIUM-TELEDYNE Corrosion
Solutions Acid Solutions
Hydrochlonc Hydrochloric Hydrochlortc Hydrochlonc Hydrochlonc Hydrochlonc Hydrochlonc Hydrochlonc Hydrochlotlc Hydrochlonc Hydrochlonc Hydrochloric Acid Acld Acid Acid Acid Acid Acrd Acid Acid Acid Acid Acid (aerated) (aerated) (aerated) (aerated) (aerated)
WAH CHANG ALBANY Data for Columbium

Concentralion (Weight %)
in Aqueous
Media
Temperature (C) Corrosion Rate mm/y Ww) 4
fill nil 0.025 (1 0) 0 025 (1 .O) 0 05 (2 0) 0 125 (50) 0 025 (1 0) 0 25 (10) 0 5 (20) 0 025 (1 0) 0 125 (501 0 05 (2 0) nil 0 025 (1 0) 0 5 (20) 0.0025 (0 1) 0 05 (2 0) 0.125 (5 0) 3 75 (150) 0 025 (1 .O) 0.25 (10) nil Embrlltle 0.125 (5.0) 0.25 (10) 0 5 (20) 0 25 (10) 1.25 (50) 0.5 (20) 0 25 (10) nil 0 25 (10)
15 15 30 30 30 37 37 37% 10% 10% 10%
wth wth wtth with and
Cl, 0 1 % F&I, 0 6% F.&I, 35% FeCI, 2% FeCI,
bolltng RT-60 100 35 60 100 RT 60 60 bolllng bolllng bollmg RT 250 bollfng RT 66 100 bolllng 66 botlmg RT RT bowling bolllng boiling boilmg bolltng bolllng bollmg 50-60 boiling
Nltrlc Acid Nllric Acid Phosphow Acid Phosphoric Actd Phosphonc Acid Phosphoric Acid Phosohoric Actd Phosbhorlc Acid Phosphoric Acld Sultur~c Acld Sulfuric Acid Sullur~c Acld Sulfuric Acid Sultur~c Acid Sullur~c Acid Sulfuric Acid Sulfur!c Acid Sulfunc Acid Sultunc Acid Sullur~c Acid
65 70 60 65 65 65 65 t+/~ with 4% HNO, 40.50% wth 5 ppm F 5-40 96 10 25 40 40% with 2% FeCI, 60 60% wth 0 l-l% FeCI. 20% with 7% HCI and-100 50% with 20% HNO, 50% with 20% HNO,
ppm
F-
Organic Acid
Acetic Acid Cttric Acrd Formaldehyde Formic Actd Lactic Acid Oxalic Acid Tarlarlc Acid Tnchloroacetkc Tnchloroethylene 5-99 7 10 37 10 1 O-65 10 20 50 99 boiling boiling b&ng bolllng b&ng balling RT-bolllng bollfng bolll!lQ n1i 0 025 (1 0) 00025(01) nil 0 025 (1 0) 1.25 (50) nil I-III nil
Alkaline
NaOH NaOH KOH KOH NH.OH l-40 l-10 5-40 1-5 RT 96 RT kz 0 125 (5.0) Embrlttle Embrlttle Embrlttle nil
Salts
AICI, AMSO.), AIKW.), C&I, WNO,), F&I, HgCl, KG& K&O, K,PO. MQCI, N&l, Na,CO, Na,CO, Na,HSO, NaOCl Na,PO.
25 25 10 70 40 10
saturated l-10 1 O-20 10 47 saturated
and
pH = 1
10
10 40 6 5-10 2.5 10
Na,PO.
NH,SO,H Nti,
ZnCI, Mlscellanaous
30 40-70
boiling botlmg bolltng boiltng boiilng RT-boiling boiling RT 96 RT bolllIlQ boiling RT boiling boiltng 50 RT 96 boiling boiling bollrIg
0.005 (0.2) nil 011 IllI nil nil 0.0025 (0.1) 0.025 (1 .O) EmbrIttle 0.025 (1 .O) 0 025 (1 .O) 0.025 (1 .O) 0 025 (1 0) 0 5 (20) 0 125 (5 0) 1.25 (50) 0.025 (1 .O) Embmtle 0 025 (1 .O) nil nil
Bromme
Bromine Chrome Solution Chrome Solution H,O, Hz01 Plating Plating
liauid
vapor
25% 00,. H,O 17% 00,. Hz0 30

30
12% H,SO.
2%
20 20 92 92 RT bolllng
nil 0 025 (1 .O) 0.125 (5.0) 0 125 (5.0) 0.025 (1 .O) 0.5 (20)
Na,.QF.. trace H&O,
648
Corrosion Resistant Materials Handbook COPPER ALLOYS-REVERE
TABLE 5.12:
relative corrosion resistance of common copper alloys to various types of environments

COppW Aluminum
ALLOV
CORROOENT ;r: !%a
c:bxCl so00
Rod Brass &l&Yw
Adminlty $&
BNU alloy Cwfoo
Phosphor BtVllZ9 llloy CSlOao
Aluminum Bronze alley Caeseo
Bma
SIlkOn
Yuntr Metal t&80
cotqw Nickel llloye CZ
Nlckal SllvW C?&ZO
&l&Y,
B A-B B-C A-B ?lD D A.-B
B A-B B-C A-B cDD
6 A-B B-C A-B coD
: A-B B-C A-B C-D D
: A-B B-C A-B coD
A A A-B :I: cDD
A 6 A-B B-C A-B c;D
B-C C ;: C ::
2 A-B B-C CAD D
lrwrgMlc ultr NeutralBelts Acid Salts Abatine 6&s DxktiringSalts MercurySsns wide Mineral Drgenic
w&tynyd# carboik P stem
BAC CED
BFC
B:C
BDC
ADB
*CDD
A-DB
6-DC
lllfw
w Moist
compound* i? :: 2 c i?i ! : t I! t
lmmon* Moist Ammomum Salts
A=Albys givenan A rating hew a provenhrstory excellentperforma~ m these environments. of * 6=Albys whbh how a provenhistory goodconosbn resistance the specific of in snviroomant Tends to dezmnc~ty. other alloys. use
C=The alby hm fair resistanceto the specMcsnvkonmenl. D=Tho alby is not w~able for use in thisenvimnment.
approximate composihon. per cent
trade name
uns
alloy no. form copper cu 99.95 0 9995 0 99.900 zinc Zn lead Pb mckel NI hn Sn silicon SI
density lb. per cu in 0.323 0 322 0316 0306
Oxygen Free (OF) n

Srlver SearingA Red Brass. 85% Cartndge Brass. 70%
I Cl0200 I sheet 1tube I 1Cl1400 1sheet

fOd
lo-15 oz. srlver per ton 150 150 300 30.0
99~0
C23000 C26ooo
sheet tube sheet rod tube sheet tuba sheet rod rod IUtxs sheet
650
650 70.0 700 70.0 60.0 71.0 M).O 60.0 60.0 76.0
Muntz Metal.1 Admiralty Metal (Arsenical) Naval Brass Free Cutting Naval Brass Revalon (Aluminum Brass) Copper-Nickel, Copper-Nickel. Copper-Nrckel. 10% 10% 30%
C26000 c44309 C46-400 c46500 c66700 C70600
I 300 I 1 40.0 1
1 28.0
3925 3925 37.5 220 1.75 As005
I
As0.05 I
I I
1.0
0.75 0.75 0 75 Al 20
I I
I 033.2
0304 0305 0301
0303
1c70600 1tube 1C71WO 1 sheet
95.0 Aluminum Bronze. 5% 95.0
1
I
*Leaded
I
As0.035
5.0 Al50
I
Revere
I I
containing
0320 0.295
0 Minimum A Alloy numbersCllrX). C11500andC11600arealsoavailable. Properties are approximatdy the same as shown for Alloy Cl 1400.
Muntz
Metal,
Alloy CS500.
0.40-0.9096 lead for improved machinability, for plate applications. n Available as 99.99% copper-Oxygen-Free GradeAlloyClOlCG.
is supplied Electronic
Nonferrous
Metals and AIIOYS
649
TABLE 5.13:
COPPER AND COPPER ALLOYS-ARC0 typlcA1

INDUSTRlAl
METALS,
AMERICAN
BRASS
USIS 01 COPPER AND COPPER ALLOYS
This section is not intended to cover all uses of copper and its alloys but is limited to the listing of a few typical applications where corrosion res~~~~e is important. ROATS AND SHIFS
BREWERIES
FIpimR Brew Lettick At(caprktd? cdb Lmter t.ba &It .,d, tmkk bar. Fluhinp Gutters md dowmpodta Fiinr for r.ter. lor>
COPPER, COPPER, COPPER, COPPER, COPPER, :z;:: COPPER
RED BRASS EVERDUR 655 CUPRO NlCKEL. EVERDUR 655 EVERDUR 655
lo%
705
BUILDING
CONSTRUCTION
~OEPDP~~*SS EJ,,D,$ 655, COPPER, CUPRO NICKEL,
COPPER, COMMERCIAL BRONZE, RED BRASS, MUNTZ METAL, ARCHITECTURAL BRONZE, NICKEL SILVER BRASS, BRONZE, NICKEL SILVER COPPER, COMMERCIAL BRONZE DISlILlERIES COPPER, Es;::: COPPER, GAS 011 INDUSTRY REFINERIES Condcnwr and he., rhax,Rer take. uARSENICAL ADMIRALTY, CUPRO NICKEL. SO% 716; 20% 710 AMBRALOY 687. RED BRASS LEADED MUNTZ METAL 365, NAVAL BRASS 464. CUPRO NICKEL, 30% 715. AMBRALOY 530, AMBRALOY 514 EVERDUR 551 MUNTZ METAL, NAVAL BRASS d64 RED BRASS RED BRASS esCOPPER. RED BRASS COPPER ARSENICAL RED BRASS ADMIRALTY
ARSENICAL ADMIRALTY
OBGANIC
CHEMICALS
pip line.
Coadcmer and he.1 chuSe+r cdkk TmL. she&a Stills ud
rvkpomtora md hut inks a-
COPPER, ARSENICAL ADMIRALTY, CUPRO NICKEL, 30% 115; 30% 710 LEADED YUNTZ METAL 355. NAVAL BRASS 454. CUPRO NICKEL, 30% 715. AMBRALOY 614 COPPER, EVERDUR 655
POWER
PLANTS
Conden.cr rhmpr
Tuk.
eheecu
ARSENICAL COPPER, ARSENICAL ADMIRALTY, AMBRALOY 687, CUPRO NICKEL, 10% 706: 20% 710; 30% 715 LEADED HUNT2 METAL 365. NAVAL BRASS 164. ARSENICAL ADMIRALTY, CUPRO NICKEL, IO% 706: 30% 715 AMBRALOY 614 CUPRO NICKEL, IO% 705; 30% ,I5 COPPER, COPPER, RED BRASS EVERDUR 655
PULP AND
PAPER MILLS
Waler @pin* Stock Bnn Wire kr Fmrdrinitr
.scrnlu
Slotted ,c,ccn pl.trk Paper mvhinr roBa of rkrions kin& Cylinder rwb Winding SALINE WATER CONVERSION mire
BRASS, PHOSPHOR BRONZE PHOSPHOR BRONZE, AMBRALOY
612
RED BRASS PHOSPHOR BRONZE, EVERDUR 655 COMMERCIAL BRONZE EVERDUR 651, PHOSPHOR BRONZE
507
and Candrascn
ARSENICAL ADMIRALTY, 80% 716; 30% 710; 10% AYBRALOY 687
CUPRO 706,
NICKEL,
Tube .hwt.
LEADED MUNTi! METAL 365, NAVAL BRASS 154, ARSENICAL ADMIRALTY. CUPRO NICKEL, 10% 706; 30% 715. AMBRALOY 614 PHOSPHORIZED COPPER 133. EVERDUR 655, CUPRO NICKEL, IO% 706 MUNTZ METAL 330, NAVAL BRASS 4.54. ARSENICAL ADMIRALTY, CUPRO NICKEL, 10% 706
ShrlL
SALT MANUFACTURE
COPPER, ARSENICAL ADMIRALTY, CUPRO NICKEL, 30% 715; 20% no; 10% 706
(continued)
650 TABLE
Corrosion Resistant Materials Handbook 5.13: COPPER AND COPPER ALLOYS-ARC0

SEWAGE TREATMENT PLANTS Piping Slotted acreem Electrical conduit Anchor bolta ..,d manhok steps V&e md g.te stems
METALS,
AMERICAN
RED BRASS 655 651
BRASS (continued)
COPPER, EVERDUR EVERDUR
Gates and gate fr.mea Weirs SUGAR PROCESSING h~poraor tube8
EVERDUR 655, EVERDUR EVERDUR 655, AMBRALOY BRONZE 4641, LEADED BRASS 691 EVERDUR 665 EVERDUR 655 COPPER, RED ADMIRALTY, BRASS, CUPRO
651 630, TOBlN SILICON
Cklandriu. syrnp tanks, mire ClysMizing pana Melting t&a He.1 exchanger tmbw Heat uchauer tube mheeta TEXTILES piping Printing rolb Electrical conduit piping Screens md rken~ framea Anchor bolt. md m.nhole nteps Valve and g.tc stem.
ARSENlCAL NICKEL, 10%
706
EVERDUR 666 COPPER COPPER ARSENICAL ADMIRALTY NAVAL BRASS 664 COPPER, COPPER EVERDUR COPPER, EVERDUR RED 651 RED 555 BRASS BRASS
WATER
WORKS
EVERDUR 655. EVERDUR EVERDUR 655, AMBRALOY BRONZE 664,. LEADED BRASS 697
651 630, TOBlN SlLlCON
CORROSION
A--Th 6 -Qe e.metaI should
RATING
CHARTS
be considered some property
be suitable with
under most conditions of use. rating when
metal offers good corrosion resistance. It moy on A than corrosion offers fair resistance governs corrosion its use.
iii place of a metal other C-lh 0 metal e metal
D -1h
COWER
resistance.
is not suitable.
COPtEKLOW-ZINC
BRASS
CO*MIRCIAt IROll2f 220
HIGH-ZINC BRASS
CAPTPIOGf BRASS 160
SPECIAL BRASS
TOBIll wloll2t ,6,,
WOSPHOR BRONZE
ALUMINUM BRONZE
SILICON ALLOYS CVIRDUR

655
CUPRO NICKEL .tUPRO

ICIfL. 109, 706 cuno IIICKtt. 30% 716
NICKEL SILVER I
SItVtR II% 152
Acetic Acetic Acetone
Acid Anhydride
6BBBDDDDCC;e B A D A B A D A
B A D A
1
230 !
CRCnlTECTURAL / lRSENlCAL ADMIRALI (13 BRONZl 385

MUllI 1 1 .,i 266 1 !
l 1
RED lRASS
AIMBRALOi
I
B A D A B A B A B A D D D D C A A c A A A A A B A
;~wlo
AMBRALO
630 1
10) 624 1
ffROUR 651 I
B A A
D A D A
D AA A A D A D A
D A A D A D A D A D
D A A A D A D A D A D D D D D ll
C A D A B A C A B A D D D D D A A
C A D A B A C A B A D D D D D A A c A A A A : A A A A
B A D A B A B A
e B A D A B A 6 A
e B A D A B A B A B A D D D D c A A c c A A A A A B A A C A A
e B A D A B A B A B A D D D D c A A c c A A A A A
e B A D A B A B A B A D D D D c A A c c A A A A A
e 6 A D A A A B A A c C C C B A A c c A A A A A B A A 8 A A
e B A D A B A B A B A D D D D c A
Acetylene* Alcohols Alum Alumina Aluminum Aluminum Aluminum Ammonia, Ammonia, Ammonium Ammonium Ammonium Ammonium Amy1 Amy1 Aniline Aniline Asphalt Atmosphere. Atmosphere, Atmosphere, Barium Barium Barium Barium Barium Beer. Beet Supar Syrups Industrial Marine Rural Dyes Acetate Alcohol Chloride Hydroxide Sulfate absolutely moist Hydroxide Chloride Nitrate Sulfate dry
B
A B A B A D
B
A B A B A D
II
A B A B A D
B
A B A B A D
D
A D A
D
A D
D
A D
B
A D D D D e A A c A A A A A B A A c A A
B
A D D D D C A A C C A A A A A B A A C A A
D
D
D
D
D
D
D
D
D
C A A c c A A A A A B A A C A A
D
C A A c c A A A A A B A
D
C A A c c A A A A A B A A
D
C A A c c A A A A A B A A A A
D D D
D B A
D D D
D B c
D D D
D B A
c :ccccc A A B B A A DB A B B B B A A D B A B B
c A A A A A C A A A A
: A B B A A D 0 A B
c A B B A A D B A B B
: c A A A A A B A A B A A
Carbonate Chloride Hydroxide Sulfate Sulfide
B
A A C A A
B
A A C A A
:CCBBBBBI A A A A
c A A
(continued)
Nonferrous
Metals and Alloys
651
TABLE 5.13:
COPPER AND COPPER ALLOYS-ARC0
METALS, AMERICAN
BRASS
bntinued
COPPERSILICON ALLOYS
LOW-ZINC
BRASS
COMMEWlAl
HlClLZlNC
IRASS SPECIAL BRASS
TOIIN
PHOS?HOR IRONZE
ALUMINUM DRONZE
rzn I
Benrine A A A A AAAABBBBAAAA Benzoic Acid Ben1ol A A A A block Liquor. Sulfate ProcessC C C C Bleaching Powder. Wet B B B B
BCWtJX
CARTRIOOE
BRASS 260 AKtUTECTURAL BR0ll2E 3*5
I-
CUPRO NICKEL CUIRO

KICKEL. 10% 106
NICKEL SILVER
SILVER. 10% 752
NICKEL
ADIiRALTV
443
1 1 1
A A D 0 A 0 B D A D A A D D B D 8 A c C C A D A o* D A D 1 A D D D 0 B C A D A A D D A B B D A D A A D D B D B A c C C A D A A D D A D _ A D D D 8 A A D D A B B D A D A A A D D A B B C A D A A 0-B C B D B A c C C A D A A D D A D _ A D D D B B A B B A B B B A B A A A D 0 A A A B A C A A A C B A A A S A C A A A C B A A A B A B A A A C 0 A A A A A B A A A A C B A A A 0 A B A A A B B A B A B A B B B B A B A c B A 0 A A A A A c B A A A B A B A : B B A B A B A B B B B A B A A c B A 0 A A A C c B A A A B A A A B A D D B B A A 4 B A A A A A A c B A A A B A B A : B B A B A
B
cum0 KICK& 30% 115 I
A A A c B A A A A A B A r B A A B A B A B B B B A
B
A A A B B A A A A A B A A^ B A A B A B A 8 B a B A A A A B B A D A A : c B A A A A A A A B A D D B B A A A I> A A A AA A A
A A A c 8 A A A A A B A A B A A B A B A B B B 8 A B A A c B A D
Bordeaux Mixture Boric Acid Brines Bromine, Dry Bromine, Moist BlMolle Butyl Alcohol Butyric Acid Calcium Bisultite Calcium Chloride Calcium Hydroxide Calcium Hypochlorite Cone Sugar Syrups Carbolic Acid Carbon Dioxide, Dry Carbon Dioxide, Moist Carbonated Water Carbonated Beverages** carbon Dirulfide
A A A B A B A : B
A A A B A B A A B
A A A B A B A
A A A 8 A
B A A :ACCc*C:::: B I)
D D 8 D B A c C C A D A A D D
B B A B I) A B B B A B A
B B A B B A B B B A B A
6 A A B B A B B
B B B B A A A A B B B B AAAABBBBAAAA B B B B A A A B B B B 8 B B B B BBBBAAAAAAB: A B A A c B A D A A A B A : B A D L. A B B B A B A c B
A
A B B B B A B ._ A A t: II AA D A A
carbon Tetrachloride, Dry * Carbon Tetrochlorida, MoisttB Castor Oil A Chlorine, Dry Chlorine, Moist c _Chloracetic Acid B Chloroform, Dry A <hromic Acid D Cider** A Citric Acid** A
A B A
A * c B D A A
A
D _
D 1
A D 1
A D 1
A D 1 -
A0 A A
A c
c_off.o** coppe Chloride r

COPP er
Nitrate coppu Sulfot. Corn Oil**
C B A
C B A
C B A
:
C B A
A D D D 8 B c A B
A
: c
C B A A B A A A a 0 D B B
C 8 A A B A A A n D D Et B
C B A A B A A A B D D 6 6
C B A A B A A A B 0 D B 6
C B A A A B A A A B A D D 8 B A A A B A A A A A A
c 8 A A A B A A A B A D D B B A A A B A A A
c B A A A 8 A A A B A D D B B A A A B A A A A A
A c C B_ A A A B A A A B A D D B B A A _A. A A A A 4
Cottonseed Oil** Czr0tO Crude Oil E!hars Ethyl Acetate Ethyl Alcohol Ethyl Chloride Etitylone Glycol F&c Chloride _.. Ferric Sulfate -___ Ferrous Chloride F~rJOUI Sulfat. Formaldehyde Formic Acid Fre0fl Fruit Juicer** --7 F_u.l 011 hrf&Ol G~s_olin* G*lotin*** Glucor.* EIU.
AAAABBBBAAAA A A A A B B B B A A A A A A A A A A A a B B AAAABBBBAAAA D D D D D D D D B B A A A B A A A A A B B A A A a A A A A * A B B A A A a A A A A A B 6
: A B
: A B :
D D D D
D 0 D D
D D D D
D D D b
A B A
A D :
A D B c A A B
A D : A Pi B
: A A A
A C A A A :
A B A A A A A
A B A A A A A
~AAAAAAAA A A A A B A A B
A A A A A_A.L_A
(continued)
652
TABLE 5.13:

low-zIwc BRASS HICKZlWC BRASS
METALS,
AMERICAN
BRASS (continued)
cottfu-
COttfR
WECIAL BRASS
tHOStHOI ALUMlNUM SlLlCOW CUtRO NICKEL

NICREL SILVER
Hydrocarbons, Pure ___ Hydk&l?%;-&id Hyd!ocyanic A&- -___ Hydroftubfi<-A&d Hydroflu&ilici~-Acid Hydrogen -~ Hydropal PTroxide ___ ._ _Hydrpge~_S+l+,Dry Hydrop.nS*flde, ________~ MOWI .--; Kerosene Lacquers
--;: : B D _~___ c B
~c : B
2 : __ B
A.--~___ D o^ DD~ D_ DD D 2 C A
A D D __ D .-D
D D D_ D
c^ D D-B :
_-c^ D D__ B A B
A c^ c __ D D C __. C-------B BP ______ A B-~ A ______ B
A-__ c-_ : B-B-B A B ----A-A ._~__ _? A~ ;L..-.-__ ;----
A-_._ A__. c_c -_ c* --~ D D D c c __--- c _____.- B A A B____ 6 A--~ __--. D D D A A A ~-A_~ : c A B
t D 0 B A B-B A C A
c^
: B A :~ A
A-~__ A A B--iA_A_&A-AB B __-~ D_ D A A A
A.--_--_-_--_ A C D A C A
: ~~~__~ : A .~-~~~~-__~ A-__ A B B D A C D A D A
A~____A
Limp &ne_Sulfur
~__=_~~~~~-.~-~_1_~_.~~~~~-. ~-AAAACCCCAAAA __ ~. __ A_-.~~~_~+_B A c c B B A-__ 8 D
A B_
__~. __-_c s B B~. A A D--D-___ A B B ----zA A-.~
AA ~-AA A.A._A --A__ : A A___ c 6 B A A D B B5,. A B. A ___ 2
B~~~-____ B B %eed.pil __ _. Magnesium Ch!qrido B B B Magneiium HydrckidsA AA--A-A-A .____--__-~~~-Mog%&%~~Sulfate A A A M+ry DDDDDDDDDDDD _ -_ -Merwy Salts D D D Methyl _Alc_ohol Methyl Chloride, Dry Mi .----p_-_-~.-.Mint Nat; &Ii.-i. AAAAAAAAAAA A A A
B D_
B D
C C : _____~._____ D~~. D D -____.D A A__A D A-D-~
B-__ B C C A__-.__ A A A D A --~ D A
B B A A A A D_-.D_.D.__ -----o D D -_~
__ L
D-DO-
B D : A-~~ A A A _A A A A
c^:____ .-- : :
--.
:~ : A A *A A A A
-__- D
2 YYYY_ c^ C A A D :-:-:-A C C i A C : B LDDCBB A D D B A A D D C A A .D D C A C D B A -.-. C A C D 6 A A B c A A D D B A

A
A_-----ZA A
A
AAAA-A
A A A-A7 B __: A A D D B A B A B e
A -A+ B _____~_ : A A A D D B A
A A B A B ._____ A B A D D 0 A A
A A A 8 A B B A D A A
A A A A.-:-A B A B A A D D A A A A A ___-. D__~_ A
A. A
jy~~~hn~&C> Poralfin Phosphoric Acid %t&&~arbk.not~ %i&Chl&id~ P_o~&s~~m_~h_~~mote ~_____ PoJorrium Cyonid_e Potosrium Dichromate, Acid Potassium Hydroxide Potassium Sulfate Propane
0 _@.-B_.LB.C A AA-A A B B B> A A A B B B A D* 0 D D D D B B B AAAABBBBAAAA A A A
B A B B A DD D 6B A A
_B_-_I) A___A B B A A A D_.D D ..D A_-; A A__! A A D A _A
A__~ A d D D D C C A A
A D D B A
Ken ~~
Sea Water SeW3ge Silver Salts Soap Solutions Sodium Sodium Sodium Sodium fodwm __~ Bkarbonate ~__~____ Bisulfote Bisulftto --B-B-B Corbonote Chloride
B B B B A A A A _D D D D AAAABBBBAAAA B _ B A B A D D : B _B B A B A D D :, B B B A B A : : B B B B __ A B A :: : B
A-
A
D c D D__ B-D A : c D c
A
D c D D B D A : c D c D cD D B-__ D A D : D c D ___
A
D
AA
~--D D B 6 B_B A B A D D : B
A
D B 6 A.~ A A D D B c 0
A
A A D A B-_____ B B A B A D D B C B
4_..AA.A
B ~__ B A A D D A A B B B A B A D B D c B B B B A--B
A A A A A A D D A B A
; C :
B 6 B B B B A ___~__ A BB A D D a c a
A-A A A AA__A A ___ A A A A D D A B A
--iSodwm Di&omote, Acid --Sodium Hydroxade %&urn Hypochlorite SXiuGiNhate
SodiUmCyanibe
Sodium Chromate
A .-___ A D D -. D 9 D : c B
A_~_____ A D__p D D -B A c c S__A
(continued)
Nonferrous Metals and Alloys TABLE 5.13: COPPER AND COPPER ALLOYS-ARC0 METALS, AMERICAN BRASS (continued)
653
LOW-ZINC
COwfR -cLEcTnoLvlIc BRASS COYYLRClAl
HIGH-ZINC BRASS
corrfurHosrHOu SILCIALBRASS BROHZf ALUMINUM KRONZE
SIllCOn
ALLOYS
CUPRO NlCKfl
NlCKfl SllVfR
CARlIDlx
Sodium Sodium Sodium Sodium Sodium
Peroxide Phosphate Silicate -Sulfate _ SultIde
C C C C A A A A AAAABBBBAAAA AAAABBBBAA C C C C
D B
D B
D B
D B
C A
C A
C A
C A A c B A B B D A A B A f A A A B A B
C A A
C A A
C A A
I) A A A B c A
B
B A A A 8-B B_.B A_e

B
B A A A
B D C C A D A A D A D D B B A d A C
B D __~
B D
B it
B B
c^ B A B B D A A B A__ i A A A B A B
Sodium Sulfite Sodium Thiosulfote _.Steam %:&Acid Supor Solutions SGtfu;7bry +lfur, S&fur Sulfur Sulfvr Sulfur Moltfn Chlortde,__Dry Dioxide, Dry Dioxide, Moist Trioxide, Dry
B D ::BBBBBBCC 9 c A A A A C B B B B C AbiAABBBBAAAA B B 6 B A D A AA B A B 8 A
A
c i D A A D A D D B B A D A C A D A ~A D A D_ D B B A D A C
A __~ A B ____B A D A A B A t A A A C A B B D A A B A k A A A C A
B
B C A .~ B A B D A A B A El B A A A A B A B
6 c B B A B D A A B A II B A A A A B-7 A 4 A A-. E_ A c
B c B B A B D A A B A B _B A A A A
A B D A A C A B C A A A A
A A D A AA C A B C--C A A A A B
A kt D A C A B A _A _A A B -. A B A
D A B A B 0 A
A
D A A B A 8 0 A
A
D A A B A B B A
A
D A A D A D D 0 B A D A C
Sulfuric Acidft Sulfurous Acid ~annic Acid Tar lartoric Acid** r_o! ce2e ~i<hJoroca(icAcid lrichlorethylene. Dry lrichlorethylene. --- ..Turpentme Varnish OiGgkor** w2GG--FGw I Zinc Chloride Zinc Sulfate Moist
AAAACCCCAAAA A A A A B B B ____.B A A A A B B B B
A A-&~__~~ B A B-_-A A A
____-.
B fl-.-- B A~_.~______~~~~ A A C B -. C B
B D -A _~... C D B_____ D
D ~c~~~_.cD ~.. .__~ D D
D C B C..-A C ~-a--A-~.-A-~~ ~ C__ B (I_ B
A
c -_B___
A ._ P
c _~_C B___ B
A
B A c B
~~--I__ A ..c __ B ~~
a~__8 ___B A A A
C ___~ _ B
___D -___D C D B ._ D _____~_
C B
.__
_B
*Copper and copper alloys are not attacked by dry gases at room temperature or lower. Acetylene forms an explosive compound with copper when moist and alloys containing more than 65% copper should not be used with the wet gas under pressure. Moist carbon dioxide is corrosive to brasses high in zinc but may be handled by other copper alloys. Tin coatings are highly resistant to moist carbon dioxide. Moist chlorine gas is corrosive to all copper alloys. Sulfur dioxide and sulfur trioxide in the presence of moisture form sulfurous and sulfuric acid, respectively. Copper, Red Brass, Everdur, Phosphor Bronze and Cupro Nickel, 30% 715 should be considered for handling these gases when moist. **Copper and its alloys are resistant to corrosion by most foods and beverages. However, consideration must be given to the possibility that such products handled in equipment made of copper or its alloys may dissolve traces of copper in amounts sufficient to discolor the product or alter its taste. In such cases it is recommended that the metal be tin-coated. TCopper alloys are resistant to most organic solvents such as the acetates, alcohols, aldehydes, ketones, petroleum solvents and ether. Organic acids in aqueous solution may be handled by copper and most copper alloys but corrosion will be accelerated if air is present. Binary copper-zinc alloys containing more than 15% zinc may be attacked by dezincification corrosion. Copper alloys may be definitely corroded by chloride hydrocarbons, such as carbon tetrachloride and trichloroethylene, at the boiling point in the presence of moisture unless the hydrocarbons are stabilized by a neutralizer. Of the copper alloys, Cupro Nickel, 30% 715 and tin-coated metal offer the best resistance to moist chloride hydrocarbons. ttCopper and copper alloys are rapidly corroded by oxidizing acids such as nitric and chromic. Corrosion by other acids is generally dependent on the presence of oxygen or some other oxidizing agent in the solution. Brasses containing not more than 15% zinc, and special brasses, can be used with many acids, but, in general, high-zinc brasses should not be used with acids due to the danger of rapid corrosion by dezincification. Copper, Red Brass, Phosphor Bronze, Everdur, Aluminum Bronze and Cupro Nickel offer good resistance to corrosion by hot and cold dilute sulfuric acid and to corrosion by cold concentrated sulfuric acid. Intermediate concentrations of sulfuric acid sometimes are less corrosive to copper alloys than either concentrated acid or dilute acid. Concentrated sulfuric acid may be corrosive at elevated temperatures due to breakdown of the acid with the formation of metallic sulfides and sulfur dioxide gas causing localized pitting attack. Tests indicate that the copper alloys may be corroded by pitting attack by 90 to 95% sulfuric acid at about 122OF (5OC). by 80% acid at about 16OF (71C) and by 60% acid at about 212F (1OOC).
(continued)
654
Corrosion
Resistant
Materials
Handbook
TABLE 5.13:
METALS,
AMERICAN
BRASS (continued)
RATINGS OF ALLOYS LISTED IN BRACKETSARE IDENTKAL WITH RATINGS OF FOLLOWING LlSTlNGS IN CHART
Certified OFHC Copper 101 OFHC Copper 102 Boron Deoxidized Copper 109 Silver Bearing Copper 113 Silver Bearing Copper 114 Silver Bearing Copper 116 DLP Copper 120 Phosohorized Couoer 122 Phosphirized Arsenilal Copper 142 Tellurium Copper 1452 OFHC Sulfur Copper 147 Amzirc (Zirconium Copper) 150 Hitenso 162 Hitenso 1622 Hitenso 165 Chromium Copper 182 Leaded Copper 187 Deoxidized Leaded Copper 1870 Anaconda Coooer 189 Gil&g 210 Phosphor Bronze 505 Phosnhor Bronze 507 Silicon Tin Bronze 5072 Calaun Bronze 607 Leaded Nickel Copper 7021 Yellow Brass 274 High Leaded Brass 353 High Leaded Brass 3531 High Leaded Brass 3532 Extra High Leaded Brass 356 Free Cutting Brass 360 Leaded Muntz Metal 365 Free Cutting Muntz Metal 3711 Free Cutting Muntz Metal 3712 Free Cutting Muntz Metal 3713 Forging Brass 377 Naval Brass Naval Brass Leaded Naval Brass Leaded Naval Brass Manganese Brass Leaded Manganese Brass Anaconda (Low Fuming) Bronze 462 464 482 485 675 676 681
we MUNTZ METAL 280
ne
COPPER
we TOBIN BRONZE 4641
Commercial Leaded Commercial
Bronze 226 Bronze 314 see
High Strength Commercial Bronze 316 Ambronze 405 Ambronze 413
COMMERCIAL BRONZE 220
Cum
Nickel, 5% 709
>
see CUPRO NICKEL, 10% 7~6
Cupro Nickel, 20% 710**
see
CUPRO NICKEL, 30% 715
Hardware Bronze 320 Ambronze 422 Ambronze 425 Ambronze 430 Trumpet Brass 435 Silicon Bed Brass 6941 Leaded Silicon Brass 6942
Phosphor
Bronze (A)
5090
see
Free Cutting Phosphor see RED BRASS 230
Bronze 544
PHOSPHOR BRONZE, (A) 510 sea PHOSPHOR BRONZE, (D) 524
Phosphor Bronze (C) 521

Everdur 6421 Everdur 661
see EVERDUR 655
Low Brass 240 Yellow Brass 268 Leaded Tube Brass 330 Leaded Tube Brass 3301 Leaded Tube Brass 331 Free Cutting Tube Brass 332 LOW Leaded Brass 335 Medium Leaded Brass 340 High Leaded Brass 342 Manganese Brass 667 *Slightly **Slightly less corrosion less corrosion resistant resistant
see CARTRIDGE BRASS 260
Nickel Nickel Nickel Nickel Nickel Leaded Nickel
Silver, Silver, Silver, Silver, Silver, Silver,
10% 12% 18% 12% 13% 10%
745* 757* 7641 770* 776* 796*
see NICKEL SILVER 18% 752
than Nickel Silver, 18% 752. than Cupro Nickel, 30% 715.
655
TABLE 5.14:
LEAD AND LEAD ALLOYS-LEAD
INDUSTRIES
ASSOCIATION Corrosion of Lead in Hydrochloric Acid at 75F (24C)

Chmniul lead 6% antimonial mPY (8) 33 20 43 150 160 200 540 lead
Corrosion in Phosphoric
Solution
of Chemical
Lead
Acid at 70F (21C)
Corrosion of Lead in Nitric Acid
I
(corn I) tcomil (c,nlI; (COrnl) (coml) (pure)
Corrosion
rate-mpy
(a) Solution !T Solution
May (a) 24 16 22 31 74 190 350
20% H,PO, 30% H.PO. 40% &PO. 50?/. &PO, 65% H,PO, 6c?G H,PO.
3.4 4.9 5.7 64 16 12.6 x 0 127) (a) mils per year (= mdd x 0.127) 1% HCI 5% HCI 10% HCI 15%HCI 20% HCI 25% HCI
(a)
m,,s
per year (= mdd
36% HCI (b) L (a) milr per year ((b) concentrated
Corrosion of Lead in Hydrochloric Acid-Ferric Chloride Mixtures at 75F (24C)
mdd x 0.127) avsilabk
HCI commwcially
-r
Chemical w lead SOlUtiOll (a) 5% Ha + 5% Fe Cl, + 5% Fe Cl, 26 lO%HCJ 41 15% HCI + 5% Fe Cl, 20%
Effect of Sulfuric Acid on the Corrosion of Lead by Fluosilicic Acid at 113F (45C)
lead
-4
mpy (0 37 76 160 190
6% antimonial
Chemvxl Solution mPY 53 + 5% H,SO, 9 64 + 1% H.SO. + 10% H,SO, 66 4
lead
6% antimonial
lead
mPY 77 14 115 76 9 I
5% H,SiF. 5% H,SiF, 10% H,SIF, 10% H.SiF. 1% H,SiF,
+ 5%
tia
ea
Fe Cl,
150
Corrosion of Chemical Lead with Sulfuric-Nitric Mixed Acids

Gxr1son Solution 75F (24C) rate-mpy
Effect of Nitric Acid in Sulfuric Acid on the Corrosion of Lead at 245F (IISC)
122F (WC)
70% k&SO. + 0% HNO, 76% H,SO. 76% H.SO. 70% H.SO, + 1% HNO, + 3.5% HNOa + 7.5% HNO,
1 3 3.6 4
2 12 16 35
I
Acid-Sulfuric
Chsm#cal lead Solution mpy
G%anlimonal
lead
mPY
Corrosion
of Lead in Hydrochloric
Chemical lead 1 WF
Acid Mixtures
6% antimomal mPY (a) lead 15OF (66C)
mPY (a) Solution 75F (24C) (66C) 75F (24C)
1% HCI + 3% HCI + 5% HCI + 7% HCI + 9% HCI +
9% H,SO, 7% H,SO, 5% H.SO, 3% H.SO, 1% H.SO,
5 14 14 16 16 10 17 41 66 140 62 65 66 64 120
9 32 42 45 47 22 42 74 120 160 -
5 21 21 22 30 22 60 90 110 150 53 64 120 130 210
12 41 65 74 64 34 56 160 180 210 -
5% HCI + 25% H,SO, 10% HCI + 20% H.SO. 15% HCI + 15% H.SO, 20% HCI + 10% H.SO, 25% HCI + 5% H,SO,
5% HCI + 45% H&O. 10% HCI + 40% H,SO, 15% MCI + 35% l&SO. 20% HCI + 30% H,SO. 25% HCI + 25% H.SO,
(a) mile per year (= mdd x 0.127)
(continued)
656
TABLE
5.14:
LEAD AND LEAD ALLOYS-LEAD Corrosion
INDUSTRIES
ASSOCIATION Processes
(continued)
of Lead in Chemical
I
Temperature Sulfstfon castor Tallow Olive Cod liver Neatsfoot Fish 01 011, with 25% rulfurk acid (66 Ee)-14OF (6OC) F C Corrosion mpy (6) 3 12 3 6 11 11 23 16 with 93% sulfurk scld (66 6.0) rate
Vegetable peanut Sulfonatlon
I
I I
Naphthalene Phenol Washing Sulfated and Neutrsllzatlon of Sulfated and Sullonatod Compounds
246 330
166 120
45 3
vegetable oil + water wash-neutralized
with sodium 140 60 9
hydroxide Naphthalene soda pH3 Washing Storaae tallow wth 2% by WI w Be sulfuric acid sulfomc acid + water wash-neutralized with caustic
156 250
70 121
39 5 0.3 I
of llauid alkvl deteroent acid-50% sulfur trioxide ammonium sulfate-S% 116 47
I I I
Storage of 50% chlorosulfonic
0.6
Mixing
tank
and
crystalhrer-saturated
sulfuric acid soluhon Splmlng Olive oil and 0.5% sulfuric Storage Storage of split fatty acids of spht fatty acids 01 Atumlnlum Sulfate from AlumInn acid (66 Be)
1 to 5
190
66 Liquid
11 Liquid 0.6 level 12
Extractton
I
I
Bauxite Bauxite
+ sulfuric acod-boiling + sulfunc acid-boiling 240 alum paper mill 120 116 49
Liquid 16 vapor 5 3 16 0.6 I
Alum evaporator Tank for dluolvmg Storage of 24% alum solutlon Tank ZO%ferrousslfate. lC% titanwmoxidearTiS0,
Dorr Settling
19 5sulfuricacid. Evaporator
156
70
10
Nickel sulfate solution Zinc sulfate solution
212 225
1w 107
6 6
Ammonium
Sulfate
ProductIon smmomum ammonium sulfate + 5% sulfunc sultate + 5% sulfuric acid acid 116 116 47 47 Mixmg tank 1 Crvstalllrer 5
I
I
I
I
i
Solution-saturated Solutton-saturated Add Washha Lube oll-treatment
I
I
with 25% sulfuric acid acid-steam :reatment washed with water,
220
104
25 20 I
Sludge oil + 15% sulfuric
Benzol (crude)-treatment neutralized with lime wth
with3%slfricacid
140 25% sulfuric acid. wahed hydroxide of sulfuric acid with water. 170 250
60
Tar oil-treatment neutraltzed
with sodium
n 121
24 6
Wet acid gases from regeneration Polym~rlz~tlon Polymerization Polymerization of butener of butena
with 72% rulfuric with 72% sulfuric
acid acid
175 175
60 60
0.5 14 pita
(continued)
658
TABLE 5.14:
INDUSTRIES
ASSOCIATION
(continued)
ifz$?ff ~ I=
)
CO"CS"- Corrosion
% trstion
Rate of Lead in Chemical
Environments
(Continued)
CoosTemp T 65 75 75-212 Aniline sulfite 75-212 75-212 75-212 sulfonic acid 75-212 75 75-212 10-30 90-100 50-70 rsll0 %
ClssI D B
carroslor CISSS A D I3 B B El
10
Alkyl naphthalen
SlfOiC
Lltid
B D
Ally1 sulfide Alummum
Anthrscsne Anthrsqutnone Anthrsquinone Antimony
75
acetate
75-212 75-212 75
Aluminum Aluminum Aluminum Aluminum
chlorate chloride ethylsto fluoride
10-20 -
A B 0
O-10
e
C B C A B B eB e D B D B B D D Et cl 0 B
chloride
AJItimOnv Dentschloride
75-212 75
75-212
Alummum Aluminum Aluminum Alummum AIUWW~ Aluminum Aluminum Alummum
fluorosulfste fluosilicste format0 formste hydroxide nitrate potsssium potassium sulfate sulfstfi
10 -
75-212
10-20
Azobenrene
75-212
20 10
Ammoszobenzene Amuwbenrens Aminobenzoic Aminophenol Aminosslicylic Ammonia Ammonrum Ammonium Ammomum Ammonium Ammonium Ammonium Ammonium acetate szide bicarbonate blftuorlde blsulflte urbamate carbonate acid sulfonlc scid scld
75 75-212 75-200
IO-70 10 IO-30 10 -
77 75 75-212 75 75-125 75400
3.85 10 10 -
B B B B A
Bsrlum sulfide
10 IO-100 -
B cl E B 6 B B B D B B B B B B 0 A A A B B C B B B B El B B B B B 0
1
10 O-10 -
t 1
75-212
B
B D
1
I
Benzene Benzene Benzene
hexschloride sulfonic sulfonic scld acid
75 75 212 212
IO-100 -
I
Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonium Ammonlum Ammonium Ammonium Ammonium Ammonium Ammonium Amy1 scntste Amvl chloride Amyl lsurste Awl ohenol Ami1 bropionate 75-212 B formate hydroxide hydroxylsmine metaphosphste nitrate ~~stst~ persulfate phosphate picrste polysulfide sulfsmste sulfate sulfide sulfite thlocysnsts tungststs + NH,OH 65-212 34 B
Benzldine Benzidine Benridine Benzllic dlsulfonic 3 sulfonlc scid acid acid 2.2 acid
75-212 75-212 75-212 75-212
10-100 -
I
I
Ben~obenzolc Benzocathscol Banzolc BsZOl Benzonltrlle BeZOPheOS Benzotrtchloride Benzotrifluorlde Bsnzoyl Benroyl acid
I I
75-212 75 75 75-;12 75-212 75-212 75-212 212 75-212 75-212 75-212 75-212 75-212 75-212 75-212 75-212
loo -
I--+
150 75-212 10 75-212 75-212 75 10 10 75-212 75-212 75 75 75 75 C B A
75-212
10-30 -
I I
I
chloride peroxlde
Benzvt acetate Banzyl alcohol Etenzylbutyl phithslste EIezyl cetlulws Benzyl chlortde Benzyt ethyl anlllm) Benwtphenol Benzylphsol Bezyfslfolllc Beryllium
sslicylate
acid
75-212 75-212 212
chloride
(continued)
659
TABLE 5.14:
INDUSTRIES
ASSOCIATION
(continued)
Rate of Lead in Chemical
Environments
(Continued)
Carbon
fluorides
Carbonic
acid
Butyl
butyrate
Butyfic aldehydes
Calcium Calcium
benr blurbonate
Calcium
bromide
Calcium
chloride
(continued)
660
Corrosion
Resistant
Materials
Handbook
TABLE 5.14:
INDUSTRIES
ASSOCIATION
(continued)
Corrosion Rate of Lead in Chemical
Environments
(Continued)
Chloroxylols Cholesterol Chromic Chromic acid chloride Eplchlorohydrin Diphenylamine
Ethyl auttate
Chromyl
chlorides
Ethyl cellulose
Cobalt sulfate
Ethyl formate
0 - creBsoI + 1wowater
Crolonaldehyde
Ferric ferrocyamde
Dmthylsmme Dwthylanlline Dlethylene glycol Odluoroethane Daglycollc Dllsobutyl Dunethyl OloXalW Olphenyl ether acld
75 75-212 75-125 75-212 75 75-212 75-212 75-212 75-212 75-212
D e B 0 0 e B e e B
Olhydroxydiphenylsultone
I_
(continua
Nonferrous
Metals and Alloys
TABLE 5.14:
INDUSTRIES
ASSOCIATION
(continued)
Environments
(Continued)
Oxalic ecld
Perchloroethylene
Qumme Qulnlne
blsullate tarirate
75-212 75-212 75-212 75-212 75-212 -
10
B B B 0
OllllllZFl~l~ OUl!lOllW OWlOIl
10
(Continued)
662
TABLE 5.14:
INDUSTRIES
ASSOCIATION
(continued)
Environments
(Continued)
Chemlcel stannlc Stannous stannous tetrachl0rla.3 blsulfate chlorlae acla actid (dry)
I
I I
Temp F 75 75-212 75 75-212 72 75-400 75
Concen-
Corrosion class B B cl B I3 B B A B B D B D B B A B B A A
tratlon % 100 10 10-50 10-50 3-20 90 90
~UCCIIVC
Sulfamlc sulfur sulfur
atoxlae trlorlae ac8a chlorlae matures .3cla
Sulfurtic .3c+a (Sea figure) sulfurous SUlfUfyl Tannma Tsnrw
I I
140 75 70 75 75 75 75-Km
I I
zo-loo So-70 10-100 10-30 -
Tsrtar~c acla Tetraphosphorlc Thmnyl chlonae
scla
Thlophosphoryl Tetrachlorethene Teamum Tewwm Toluene sulfate
chlorlae
75 145 75-212 75 75-212 75
tetrachlonae
Toluene-sultochlorlae Thnchloroethylene Trlchloronltromethane Trlathanolamme Triphenyl S&urn sodium Soalum Soawm Soalum Scdwm Soawm Sodium Soalum stanmc percarbonate peroxIde persulfate phosphate phosphate whcate sulfate suff0ae sulfite chlorlae (tri bsslc) 75 75 75 75-212 75 75 75 75-212 75-212 7j 75 10 10 10-100 10-M Z-20 10-30 10-30 20 D D 0 B D B A A B D D Turpentme Vmyl chlonaa zmc carbonate zmc fluoslllcate Zmc hyarosulflte Zinc sulfate zmc chlonae phosphlte
140 80 75 75 75 70 75 95 175
0.4 10 SO-36 25 B D B B B
SoOlum tartrate
Corrosion
Rate of Lead in Sulfuric Acid
Nonferrous
Metals and Alloys
663
TABLE
5.15:
MAGNESIUM-DOW
CHEMICAL
In the table the concentration of the chemical is shown in percent. Values of 100% refer to the pure substance in dry or liquid form. Concentrations less than 100% refer to water solutions of the chemical. The other column in the table indicates whether or not a test under actual operating conditions is warranted. A Yes in this column means that magnesium is basically resistant to the chemical or that laboratory tests have shown enough promise to warrant testing under actual service conditions.
Suitability
Acelaldehyde Acel~c Acid
ACtlOllt ACttykllt
of Testing
Magnesium
in Various Substances
Any Any
Any
100 100 100 100 1W 100 100 Any Any 100 100 Any Any 100 Any l-5 100 Any 100 100 100 Any 100 Any 100 100 100 100 100 100 Any 100 too 100 Any 100 100 100 Any 100 Any Any 100 100 too 100 Any 100 100
NO NO ves ves ver Yes ves NO ves ves NO ves

VCS
Ethylene Glycol SOlUllonS
Any
may
Alcohol Butyl Alcohol. Ethyl Alcohol. lso~ro~yl Alcohc4. Methyl Alcohol, Propyl Ammomd IGas or L~ouvJl A~monnrm F;aRs (Most) Ammomum Hydrowle AnlIme Anthracene Arsenates (Most) Benlaldehyde Benzene Ebchramales Bow Actd Brake buds (Most) Bromides (Most) Bromobenzene Butter BuFIIphenols Calcrum Arsenate Calcium Carbonate C&rum ChlOrlde Calcwm ttydroxlde Camphor Carbon BlWlphlde Carbon Dloxlde (Dry) Carbon Monoxrde
Calben
Ferra Chlonde Fluorrdes (Most) Fluord~c~c Acrd Formaldehyde Fruit Juues and Acrds Fuel 011 Gasohol (l&b Gasohol (lC% GeSobne (Lead-tree) Gasobne (leaded) Gtkllllt Glyccrme C.P Grew (Acrd-tree) Heavy Metal Sdns (Most) Heumme liydrochlonc Acrd Hydrolluaru Acid Hydrogen Peroxrde Hydrogen Suiirde lodrdes lodute Cr~rtals (Dry) Isopropyl Acetate lSopropYl Benzene (sopropyl Bromrde Kerosene Lanolin Lard Lead Areeitale Lead Oxrde Lrnseed 011 Ma~newm Arsenate Mapnesrum CarDonate Mqnesrum Chlorrde Mercury Salts Methane (Gas) Methyl Bromrde Methfi Cellulose Methyl Chlorrde Methylene Chloride Methyl Sabcykle Mdk (Fresh and Sour) Muteral Acrds Monobromobenzene Monochbrobenzene Naphtha Naphthalenc N~colme Sulphale N~lrsles (All) Ndrous G&es Nrtrrc Acrd Nllro~~CGrln 011. Anrmal - (Aad. and Chloride-Iret) 011. Mmeral (Chloride-free) 011. Vegetable (Chlorrde-tree) Olerc Acrd Obve 011 Orgamc Acrds lMos.11 Ocihochioraphenol OrthodlChlorobenzene Onhophenylphenol oxygen Ethanol) MelhanoI)
Fatiy Acids
Fats, Lhkmp IAcId-tree)
100 Any Any Any Any Any Any 100 1W 100
VCS, need Inhlbdors Yes NO NO Yes No Yes NO Yes
Yes ves NO ves ves NO ves NO ves NO VCS ves ves NO Yes VW ver ves ver VBS NO ves ver ves NO NO ver ves NO ves ves VCS ves Yes ves VCS ves ver ver Yes
Yes. II mhlblled Yes. 11mhrbded Yes. II mhlbded Yes. II mhrbrted VSS Yes YeS No Yes No Yes NO Yes NO YCS Yes Yes NO Yes Yes Yes Yes NO Yes Yes Yes NO NO Yes No Yes YCS Ye5 VeS NO No Yes Ye5 Yes VSS Yes NO No No NO Yes Yes Yes YCS Yes NO NO Yes YCS Yes
Paraphenylphenol ParadrchlOrobenZene Pentachloropheml Perchloraelhylene Permanpanales (Most) Phenol Phenvl Elhvl A&ate Phenylphenols Phosphates (Marl) Phosphow Acrd Polypropylene Glvcols P&rum Ruorrde Potasswm Hvdroxule Folarsrum Nitrde Pooswm Permanpsnate
1w loo 1w Any 1w 100 loo Any Any loo Any Any Any
tw
YCS YCS YCS YCS Yes Y.?S VCS

YLS YCS
NO
YCS
Yes
YCS
NO YCS
1W 100 Any 100 100 Any 3 Any s-60 hY 100 Any 100 100 100 Any 1W 100 1M) Any Any 1W Any 1LlO Any Any 100 Any 100 100 100 100 100 Any 100 100 100 1W 40 Any 100 Any Any Any 100 100 100 loo Any 100 100 100 100
Propylene Glycol u S.P. Propylene Ox&de
1w 100
may
Pyrrdme (Acti Free)
1W AnY loo 100 Any Any Any Av AnY Any Any Any Any Any 3 3 loo 1pD loo Any Any 100 1w Any Any Any 3 Any 1w Any 1w 100 loo loo loo 1w 100 1w 1w Any Any AnY 1w 1w 1w 100 loo loo loo
YCS Yes. need rh,b,tors YCS NO YtS No NO No Yes No Yes YCS Yes Yes Yes Yes YCS VCS ND Yes Yes Yes NO Yes Yes NO NO No NO NO Yes No YCS YCS Yes Yes VCS Yes Yes YeS Yes Yes NO No Yes Yes NO VCS Yes Ye5 Yes
Py&bl
Rubber h Rubber Cements Sea Water Sodrum Bromale Sodrum Ltromrde Sodrum Carbonate S&urn Chtorroe Sodrum Cyamde Sodrum Orhromale Sodrum Fluonde Sodium Hydrorrde Sodrum Phosphale (Tnbasr) Sodrum Lluale Sodrum Sulhde Sodwm Telraborale Steam Slurrc Actd (Dry) Styrene Polymer sugar Solullons (Acrd-Free) Sulphates (Most) Sulphur Sulphur Oioxrde (Dry) Sulphur Chbrrde Sulphwc Acrd Sulphurous Acrd Ttnmc kd Tanrung Solutmns Tar. Crude h 11sFrxtlons Tarterr Acrd Telrahydrowhlhskne Triaruum Tslnchlornle Tolwne (Toluol) Tnchbrathykne Trrchbrophenol 1unp 011 TUrpsnhne urea urea m Aqueous Sotuhon (Cold) urea I Aqueous Sohdron (Warm) VUteQplr Vmyhdme Chlorrde VInyI 1oblenc water. Water. water. Waxes XYIOI BollnlQ Drslrlkd Raul (Acrd-free)
Tetrachbrlde Carbonaled Waler Castor 011 Cement Chlorides (Most) Chlorme Chlorobenzenes Chlorolorm Chlorophenols Chlarophenylphenol Chromates (Most) Chromrc Acld Citronella 011 Cod Lrver 011 (Crude) Copale Camarm CreeDI Cyamdes (Most) Orchlorohydrm Orchbrophenol Orchromates (See BlChromales) Orelhanolamme Orethyl Anlme Orethyl Benzene Olelhylene Glycol Solutions
1W 100 100 Any
ves ves YCS Yes.
mayneed
mhrbrlors Yes Yes Yes Yes Yes YIP Yes Yes Yes Yes Ye1 NO Yes Yes Yes Yes Yes
OlPhenyl O~phenykmme Orphenylmethane Olphenyl Oxrde Orpropylene Glycol Owylbenzene Or, Cleanmg Flurds Ethers Ethanolamme (Mono) Elhyl Acetate Eth;l Benzene Ethyl Bromrde Ethylcellulose Ethyl Chlorrde Ethyl Sabcylale Ethylene (Gas) Ethylene Orbromrde
100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100
664
TABLE

5.16: NICKEL AND HIGH-NICKEL
ALLOYS-HUNTINGTON
ALLOYS
Alloy type
Alloy
Description
Nominal chemical composition, % (Maior elements)
A=Acceptable C-E=Good to excellent gG=Not ffecommended X=Check for specific
data
Corrosion resistance
Nickct
pure
nickel
200 +
COmmerCially pure wrought nickel, good mechanical properties, excellent resrstance to many corrosives.
!PoljEL so0
Hugh strength, good weldability, excellent corrosron resistance over wide range of temperatures and
nickelcopper
!lf$EL R-405
Similar to MONEL allov 400. Controlled sulfur added for improved machining characteristics.
Age-hardened version of MONEL 400 for increased strength and hardness.
alloy
NCONEL llloy ioo
Hugh nickel, hrgh chromium content for resistance to oxidizing and reducing environments; for severely corrosive environments at elevated temperatures. Excellent high-temperature mooerties, resistance to oxidizing,. carburizing, and sulfur-containmg atmospheres.
NCONEL IllOY
io1
NCONEL ;y;y NCONEL IllOY

125 la 3.6
nickelchromiun
NCONEL IllDY 890
A hi h-chromium modification of INCbEL alloy 600. Good resistance oxidizing chemicals and sulfur-containing gases. High mechanical properties. Excellent strength from -423 F to 1300 F (-253 C to 705 C). Age hardenable and may be welded in fully aged condrtion. Excellent oxidation resistance UP to 1800 F. (980 C). Age-hardenable alloy with good corrosion and oxidation resistance. Excellent relaxation resistance.
to
52.5
18.5
19.0
MO 3.1 Cb& Ta 5.1
LI(INfNEL
f-750 UNTlNGTOh llloy G
73.0
7.0
15.5
Ti 2.5
Excellent corrosion resistance in many media. Resists pitting, crevice corrosion, and intergranular corrosion. Excellent orrdabon resrstance and elevated temperature strength.
MO 6.5 44.0 19.5 22.2 :u, to Ta 2.1
IUNTINGTOI If0y IX
48
18.5
21.8
MO 9.0
t Nickel 201. low caroon version recommended for temperatures above 600 F (315 C) *Age hardened
(continued)
665
TABLE 5.16:
NICKEL
AND HIGH-NICKEL
ALLOYS-HUNTINGTON
ALLOYS
(continued)
Alloy type
Alloy
Description
Nominal chemical composition. % (Major elements1
=Acceptable C-E=Cood I=Not Recommended
toexcellent
X=Check for specific
data
Corrosion resistance
$0"'
INCOLOY
Strong and resistant to oxidation and carburuation at elevated temperatures. Resists sulfur attack. internal oxidation,, scaling and corrosnon in wide varlety of atmospheres.
46.0
G-E
G-E
INCOLOY
alloy
eooH nickelironchromiu INCOLOl :?!?

HUNTINGTOI alloy 6041 Age hardenable alloy provides high strength u to IOOOF (54OC) comparable to alloy a2%0CO~~OS,O reststance.
12.5
46.0
G-E
G-E
G-E
21.5
G-E
G-E
G-E
G-E
G-E
G-E
G-E
G-E
G-E
42 25.5
32 45.0
G-E
G-E -
G-E
G-E
G-E
G-E
G-E
G-E
G-E
G-E
G-E
G-E
G-E
G-E
_ _ _
A mckel-won chromium alloy with good high-temperature strength and corrosion resistance. Provides good resistance to oxidation and carburization. G-E G-E G-E
TABLE 5.17: ALLCORR

ments. 0 0 0 It high high high characterized
NICKEL-BASE
single
ALLOY-TELEDYNE
non-age properties: corrosion and crevice corrosion corrosion cracking hardenable, containing nominally
ALLVAC
corrosion 31% resistant chromium, alloy for service in highly 10% molybdenum, and and ductility workability
is a
phase,
alloy
corrosive
environIt is
is a nickel-base by the resistance resistance resistance resistance
2%
tungsten.
following to general to pitting
l high strength l good l good l good weldability hot
to intergranular to stress corrosion
and cold
l high
machinability
Corrosion rates in mils per year (micrometers per year) S&lCtJ* AUCORR SY YY T: ZY CzEzNTER ,I6 STAINLESS
666
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
ALLOY CHARACTERISTICS
HASTELLOYe alloy B-2-An improved wrought ersro of HASTELLOY allov B Allov B-2 has the fame excellent corrosion resistance as alloy S. but with Improved resistance to kmfe-lme and heatatfected.zone attack This alloy resists the formation of grain-boundarv carbide preciprtates in the weld he&-affected zonk, thus making it suitable for most chemical process appl!cabons m the as-welded condrtion. Alloy B-2 also has excellent resistance to pntmg and stress-corrosion cracking It is particularly well suited for equipment handlmg hydrogen chlonde gas, and hydrochloric, sulfuric, acetic, and phosphoric acids. HASTELLOY alloy C-27B-An improved wrought version of HASTELLOY alloy C with vastly improved fabncabilrty. It has outstanding resistance to a wide variety of chemical process envtronments including strong oxidizers. i.e., ferric andcupricchlorides. hot contaminated mineral acids, solvents. chlorine and chloride-contammated media (organic and morganic). dry chlorine, formic and acetic acids, acetic anhydride. sea water and brine solutions. It isone cf the few matenals that resists the corrosive effects of wet chlorme gas, hypochlorite and chlorine dioxide solutrons Alloy C-276 resists the formation of grarnboundary precipitates in the weld heat-affected zone thus makina it applicable for most chemical process uses in tiie as-welded condition. It has excellent resistance to pittmg and stress-corrosion cracking HASTELLOY alloy C-4-A new nickel-chromlummolydenum alloy with improved high-temperature stability as evidenced by high ductility and corrosion resistance even after long-time aging in the 1200 to 1900 deg. F (649 to 1038 deg C) range. This alloy resists the formation of gram-boundary precipitates in the weld heat-affected zone. thus making It suitable for most chemical process applications in the as-welded condition. Alloy C-4also has excellent resistance to stress-corrosion cracking and to oxidizing atmospheres up to 1900 deg. F (1036 deg. C). HASTELLOY alloy G-A columbium-stabilrzed, mckel-base alloy with excellent resistance to hot SulfurlCandphosphoricacrds AlloyG will wlthstand the Corrosive affects of both oxldizrng and reducing agents and can handle both acid and alkaline solutions It resists pltttng and has exceptional resistance to stress-corrosron crackrng HASTELLOY alloy X-A heat-resistant, nickel-base alloy rdeally suited for chemical plant equipment It has good high-temperature strength and exceptional resistance to oxidrzing atmospheres. CABOT6 alloy No. 625 has hrgh strength and toughness from cryogenic temperatures to 2000 deg F (1093 deg C). Its fatigue strength is excepbona1 This alloy derives its strength from the stiffening effect of molybdenum and columbium on Its nickel-chromium matrix. In addnion to good oxidation resistance, the alloy also reststscorrosiveattack by many other media; it is virtually immune to chloride-ton, stress-corrosion cracking.
Aqueous Corrosion Data for CABOT Alloy No. 625
ed 1 hr 8, lKrOF1871Cl
-FnmllC Acid 40 88 25 25 25 10 65 PhOIPhWlC Acid

55
at 17oOF 19270 73 93 N,l 0.5 472 34 0.7 20 0 19 0 24 NII <o 02 12 0 86 coo2 0.61 Averagecl four 24hr perrods Avera9.z lour 24.hr pet~Js of tOcMr lest 1Whr test tW_hr.test Aer.?9e four 24-M tests Of 24hr te Avera9eof f+ve48-h,
Bolllng BOlllng
NnncAd
, _.
50 50
Bolbng
240!116, 300,,491 BWllQ 681201 95,351 122,501 1491651 176 1801 194 190,
63
70 70 85
12 11 67 NII Nd 01 0
.~
199 (93) Bo,,m0 Borlrng Bodmg Bodmg Room 122,501 15800) 0.4 24 37 231 960 01 a1 196 001 006 094 59 24 <o 003 21 47 96-h, test 96hr test Average cf lo, 24-h, per,& Averageof f01lr24-h, perrods Average of four 24.hr ~er,ods 4Bhr lest 48-h, ter,, 48-h, test
.~
10
sueunc Acid
30 50
NII Nd
l 50% HzSOa(weight l*7% HISO,, 3% HCI

Nil-No measurable
percentl (volume
and 42gil of ferric sulfate percentagesl, 1%
CUCII and 1% Fe Ch (weight percentages).
penetrabon
could be calculated.
COMPARATIVE
RESISTANCE
OF HASTELLOY
ALLOYS
TO VARIOUS
CORROSIVE
MEDIA
KEY E G
s EXCellent Good Satisfactory Lass than 2 mllr 2 to 10 mllr (0.05 (O.OSmm) penetratlon panetratlon per year per year
to 0.25mm)
Over 10 to 20 mlls (~0.25 per year Over 20 to 50 mlls (aO.51 per year More than 50 mllr (1.27mm)
to 0.5lmm)
penetration
BorderlIne
to 1.27mm)
penetration
Unsatisfactory No Data
penetration
per year
(continued)
Nonferrous
Metals and Alloys
667
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
Trpr 316 Shinless
(continued)
HASTELLOY~ Corrosive Acetaldehyde Acebc Acetlc Acetic Acebc Acid Acid Acid Acid 4.5 Medic 98 2.5M 135 57
alloy _
G/G-2
-
1 C/C-276
E
G
--
Stnl
plus 1 E E 2 percent low bml~ng
Conditions material. 129 day test in top of tower
212 385 40-72 347
1 1
100 196 4.22 175
1 1 E -
I 1
E ___ E
1 1
-E E
1 immersed:
aeratw
lab test 41 6 days lab test a 1 days. purlflcabon aeration
2.5M 1
3
/ rack wtmllymtmg bottom. on

plus HCI to pH of 2 0 in streptomycin plus 56 percent carbon dmxlde, plus HCI
--
butane, 2 percent water. 10 percent mtrogen, 1 percent 27 percent other organ~cs Alloy C ~0 I mpy pwflcabon
Acetlc Acetlc Acebc
Acid Acid Acid
10
75
24
___
to ptl of 2.0 I streptomycm I starch conve,s~pn
10 10
100-140 214
38.60 101
E G E E
1 - / E
/ also HCI
Immersed, comparison of heat transfer CoAdltlons with slmple test. Corrodent renewed every 48 hrs.. total time 95 hrs plus prop!o~ and higher acids. 2to acid
~mmetwn
Acetlc Acehc A&c Acetic Acetic Acetlc Acehc
Acid Acid Acid Acid Acid Acid Ac!d
10 12 17 /
300 250 210 210 210 aolllng 239 I
149 121 99 99 I
--1 I 1 -
3 percent hardwood
tar creosote
011s
plus / plus
1 5 to 4 percent 1 percent H,O. formic
formic acid
I
I
20
I
I
I - I
1 _ -
E l-/-i
E E G --
30 percent
balance acetaldehyde. sallcylates acid.
acetaldehyde
Allay
C = 0 7 mpy
20
20.8 21
99
B01lmg 115
I -
j -
/ PIUSpercent 50
plus 0
test at top of tower 192.hr 78 percent test under water reflux Alloy C = a mpy (wolent
02 percent
plus 1 percent formic agltatlon of solution)
Acebc Acetlc Acebc
Acid Acid Actd
234 24 25 25
I 1
I
212 230 220
I 1
I
100 110 104
I
I
I
I
E
E E
l I
/ I
/ plus
I
0 011 percent chlwde 1.5 percent 4 percent
sahcyhc
actd. Alloy
13aO.hr
test m vapors
I-1
I--
some plus
contammabon formic formic acid. acid
C = 0 6 mpy test
99.129.day
Acetic Actd Acettc Acid
I i
220 100 110 275 230 220
104
1 -
I - / -
plus
plus0 Spercent plus 3 percent 135 110 104 ---plus plus a percent 5 2 percent
acetaldehyde. acetaldehyde, formic formic aad. acid
129.day 129.day Alloy Alloy
test, topolfractlanatlngcolumn test at bottom of tower
Acebc Acebc Acebc
Aud Acid Aud
30 30-40 30-50
C = 12 mpy C = 0 5 mpy methyl methyl formate. alcohol
plus Z-10 percent Iormlc aud and total 5 percent acetaldehyde, methyl acetate. ethyl acetate. acetone. Allay C = 7 mpy E 15 percent formic acid, 5902 hrs.
Acebc Acetlc
Acid Acid
33 40
270 347
132 175
E E
--
plus 20 percent butane. 5 percent pentane. a percent ethyl acetate. 5 percent methyl ethyl ketone. 6 percent propu~mc acid. esters. and ketones Alloy C = 0 7 mpy plus 34 percent mPY amyl alcohol, trace 01 chlorides 792.hr test. Alloy C = 1 0
Acebc
Actd
44
212
100
--
E C S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy (0 25 mm/y) Over 10 mpy (0 25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0 51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (127 mm/y)
M -
Molar
(continued)
668
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Acebc Aad
51
275
135
E 1 E --
1 -
30 / plus percent
percent
propb~n~c acld.
proplow
anhydrlde.
I1 5 percent acebc anhydrlde. Alloy C = 0.2 mpv
7.5
Acetlc Aad Acehc Acld Acebc Ac!d Acebc Acid Acebc Acid I
55.5 57 60 60 60
219
104
plus
0.016 percent sal~cyl~c acad. 1380.hr test an vapors

H?SO,. 12.3 percent 1 percent H,O. naphtha. lhqud and vapor phase Allov C = 46 mpv
1
I
100
B.P. 221 356
38 B.P. 105 180
1 I -
1
1
E 1-1-I
G E E I --I -
plus 30.3 percent
I PIUS 10 percent stbcvlates.
plus 2 percent format acid. 38 percent plus 18 percent hydrocarbons. water Alloy C = 2 mpy Allov C = 0.7 mpv. 9504.hr
water. Alloy C = 1.2 mpy percent
9 percent esters, 8 percentC0.5
Acebc Acld Acetlc Actd Acetkc Acld
67
212
100
--
test.
67 72
273 267
134 131
E I G --
/ -
/ plus percent 33
prop~omc acid. Alloy C = 0.2 mpv for an acebc acid recovery column lor an
tests for selecbon of materul acetaldehyde wt. 91 hrs. DIM 20 oercent or~amcs
PIUS 2 3 percent
Acebc Acld Acehc Acid
75
258 /
126
--
and 5 oercent
water
Allov C = 0.3 mov
80
195
IgllGIGI--I--I~
75.125 E --
formic actd. 3-5 percent prop~on~c acld. ethvlacetate small amount water (ethylacetateacetlc acid azeotrope dlstlllabon process) Alloy C = 4 0 mpy. 1126.hr test. plus h percent acetaldehyde. Alloy C = 1.4 mpy 5 percent water Extenswe aerabon.
Acebc Acid
85
167-257
Acebc Acid
85
237.273
I
Acebc Aud I Acebc Ac!d I Acebc Aad Acebc Acld I I 90 90 I I 225 275 89 255 89 251
/
j
114-134
1 1
/
1
1 1 -
/ 1 -
/ macebc
anhydrlde pwbcabon. Plus 10 percent acetic anhydnde. 5 percent water. acetone. acetondnde. ammes. etc. Alloy C = 0 1 mpy
lz5
plus I1 percent man~anous acetate. 0 15 MnO,. 58 ppm Cl.. a trace 01 / formic ac,d manganese acetate = IO 73 percent. manganese dloxlde = 0 15 percent. / water = 006 oercent 50 ppm Clplus 10 percent manganese proo,onu acetate. Alloy C = 3 mpv aad. Allov C = 1 mov
124 107 135
I
I
) I
I 1
E i-1-1 E I - I -
I olus
10 percent
percent sa Icy
Acebc Acid 99.6 244 118 E --E
IC XI
Immersed. comparison 01 heat transfer condlbons wth slmple mm~err~on test. Carrodent renewed every 48 hrs. total time 96 hrs -0 7 mpv, plus 60 ppm sodaurn dlchromate
Acebc Acid
99 6.99 9 (anhydrous)
216
102
E G S 6 U
Less than 2 mpv (0 2 mpy (0.05 mm/v) Over 10 mpy (0.25 Over 20 mpv (0 51 More than 50 mpy
05 mm/y) to 10 mpv (0 25 mm/y) mm/y) to 20 mpy (0 51 mm/v) mm/y) to 50 mpy (1.27 mm/y) (127 mm/y)
BP
Bodmg Pomt
(continued)
Nonferrous
Metals and Alloys
669
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Acebc Acid. Glacml
675 1 357 675 1 E E 1 E E 1 -/ -
m vapors and catalyst during 1 pyrolysis Alloy C = 0 1 mpy
manufacture
of .%et~c anhydrbde
by
Acetlc Acid. Glacial
1247
vapor velocdy, 175 It/w, 1776.hr test Spool exposed m Inlet leg of reactor cml I acetic anhydrade (99 percent acebc acid plus catalyst), Alloy C = 0 1 mpy
Acetlc Acld Vapor Acebc AnhydrIde
100 50
125.B.P. 297 1
52.8.P
-plus 40 percent acetlc acld percent ethylene dlamme tetra-acetlc acid and 10 percent
lb7 140 122 130 154 134 to BP -
E E E E E E
A;eilc
Anhvdrlde
I I
60 95 95 99 1M) All
I I
284 252 266 310 273 to B.P -
I I
Acebc Anhydnde Acebc Anhydnde Acebc Anhydnde Acebc AnhydrIde Acebc AnhydrIde Acetone
/ I
1 I
1 j ------
40 I - / olus I j
acebc anhydrlde.
Alloy C = m SPY
PIUS 5 pecent acebc acid KMnO, added for quahty control plus 1 percent acetlc acid and violent agltabon
Alloy C = 0.04 mpy
E E
activated carbon used lor absorbmg Allov C = 0 1 mpy plus 30 percent methyl acetate,
plus traces 01 methylene
chloride
Acetone Acetone Acetomtrlte Acetophenone

I
60 All 4 67 -
176
80
G E G
---
10 percent
acetaldehyde
pH 5.6
1 toE.P
376
1 1
I
toE.P. I
191 150 42-49
1
1
I
E --E
I 1
I
/ - I
I isopropyl chloride rolubon. /
I
1
I
302 108.120
1
I
E -
--
1 plus 33 percent
I
phenol Dissolved Fe=0 15-l 65 grams/liter. HCI
Acetylene 1Crudel Acetylene
Tetrachkwde
excess Cl, = IO-21 grams/lder = 0.7-6.6 Rrams/bter at top and bottom 01 dlstlllabon
Tetrachlartde
Column. m vapor and llquld
4cld Pulpmg lAmmonla Base1 Acombc Aad -
165.175
74.80
185.194
85.90
--
plus NaOH, H&O,. sbghtly
and sodturn
metablsulllde
Alloy C gamed wetght
Acrybc Ac!d AI,, Exhaust
212 110
100 43
s G
B E
-G G
H,SO,. acrybc aad reactor condenser aerabon. saturated wth water and contammg other organu compounds Ca(OCI),, Cl, and Hz0 Durabon 01 test chlormated solvents and
A AI, and Steam Alcohol, Ally1 100 100 All l Alkylammer I
180 180 75 BP to B.P 200
82 82
E --E ; E S
204 days
fl2p4
1 I 1 E I 1
II --
Alcohol. Ethyl or Methyl
I
/
to BP 93
I 1-I
I G(
I
alkyl ammes pH 10.12 m aqueous solubon contammg small amounts of CO,. during petroleum Allov C = 0 24 hrs rellnmg m depropanlzer tower. vapor and lhquld
Alkylate, Butane and LlRhter Alkylbenzene Alkyl Benzene. Sulfomc Acid E G S E iJ Less than 2 mpy (0 2 mpy (0.05 mm/y) Over 10 mpy (0.25 Over 20 mpy IO 51 More than 50 mpy Sulfonate
128
53
--
I mm
71 -
140 100-130
60 38-54
G E
--u E --
lab test (wgorous stlrrmg) tank durmg detergent manulacture Alloy
m settlmg tank and sullonabon C=06mpy
05 mm/y) to 10 mpy (0 25 mm/y) mm/y) to 20 mpy (0 51 mm/y) mm/y) to 50 mpy (127 mm/y) (1.27 mm/y)
BP
Bodmg Pomt
(continued)
670
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
TYpr 316 Stain-
(continued)
stwl
I alkaylabon. mwng AllOV c = 0 4 mov
Conditions and dlsbllabon processes lhquld and vapor phase
plus phosphated alumma hydrate hydrate, 75 percent H,POa (60 Bk H,SOJ 65 percent alumna
_ _ _ _ -
LIF, N&I, NaF, specimens VW! alternately over lO.day pernod as m ethyl benzene productmn. plus HCI at 250 pr,
exposed to wand
molten flux
!somerlzatlon.
Fwdel
Crafts synthesis
AICI, 85%. NaCl 12%. Al20] 3%. Fe& 700 ppm lnlbally NaCl 8.9%. Al,01 30.55%. &Cl, 0.5.1 5% flnal no
AICI, 35.60%
aeratton
AI>FJOd to pH = 2.3 Alloy C = 0 4 SPY Alloy C = 24 mpy
_ _ _ -
*paper
makers alum
I cm descallng Plus 0.01 percent ferric and 0 03 percent lerrous 10s as Fe,O,. trace Cr,Oj. Occasional exposure to NaOH cleanmg solution E 30% Warn. 20% orgamc acld, pH 10.11, polymeruabon kettle. 62 days
hot wash bquld Reacbon product of dlphenylamme and acetone m HBR catalyst after addlbon to 50% NaOH to yield pH of 12 14 Moderate aeration dissolved m isopropyl alcohol 73% NaOH to keep neutral Agltabon vmlent, 251 days S ammama aeratmn ammoma ammOls smmoma ammonia Methyl chlonde added to MNTN pressand Manulacture 01 fabric softener Au free
E G U G U E
20%. water 50% Lwd
phase
252
days. no agdabon
or
20%. water 50% Lwd 20%. water 50%
phase
20%. water 40%. 4 days, agdatmn 20%. water 40% Laqud phase
J 4Wsec.
aerabon -
one
3 25% NaOCI. 2% NaOH. 10% NACL. 69% H,O, Balance inuts pH 14. producbon of 3.Ammopyridme. Agdaban - none. Air Iree. 74 days plus 7 percent carbon dkwde ll,Pl nlnnt and water m ammoma wx~ery strtpper m
6% CO,. 66% w&r vapor (all by WI I, 131 days. test m heat exchanger. vapor zone Aerabon - shght. Aga:atlon - shght carbon dwde 68. water vapor 66% air 0 5.l0. all by volume
E E G S B U Less than 2 mpy IO.05 mm/y) 2 mpy 10.05 mm/y) to 10 mpy (0 25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (127 mm/y) Mote than 50 mpy (127 mm/y) BP Bmlmg Pa~nl
(continued)
671
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Conotiw Ammoma
Media
6 -
316 Stain. Iem Stnl plus ammonium chloride. Alloy C = 2.21 mpy cuprous chloride. cupric chloride. Awfree
WP
Ammow
Ltquld
Ammonia,
Llquld
I
ti ;: :o 50 1;:
75 loo-BP lOO:;.P. 75 loo-BP to 8.P to E.P. to 600 90 G E
m outlet chlorides of methallymme reactor contammg plus polymer. Alloy C = 0 1 mpy ammes NH&I. orgamc
Ammomum Ammomum
Blfluorlde Blfluonde
25 25.200
E G
_-
Alloy C = 1.1 mpy Alloy C = 8.4 mpy
i
Ammomum Ammomum Ammonwm Ammonium Blfluorlde Blsulfde Bromide Carbonate
-I-. G U
10 10 20 :: 40 40 50
1
I
300 157-162 75 to B.P to e P to 175 to B P to 175 BP BP 266
149 69-72 24 to BP to BP to 80 to 8.P to 80 0.P BP 130 -
E E s
fused, 40 days pulping lkquor Alloy C = 0.3 mpy
S S E : : _
S S E S S s 8
Ammomum
Chloride
6 22
0.07% mckel chloride. 2 95% ammom. 5 55% ammonium carbonate. pH = 10 8. recove,y of ammonw 24 hrs. plus H,S, mercapans Ind non-abraswe solfds I agdator and aerabon skght 98 days.
Ammomum Ammomum Ammomum
Chloride Chloride Chloride
11-14
194 86.176 180
90
E c E G -
Ammomum Ammonium Ammomum
I26.31 28-40 35 35-50 to 40 All 147 g/l
14.1
+i-+l-+
75.102 105-110 to 107 E E E to BP to BP 75 S S s E _
8% N&I:. 4 2% CO,. 131 days, agdatlon
flwng stsmless steel strip pnor to salderlng. Ourabon of test aerabon - moderate. agdatmn - 2-3 ft Isec m evaporabng tank Alloy C = 0.02 mpy Alloy C = 0 014 mpy
77-216
221-230 to 225
plus less than 0 5 percent NH,
plus 35 percent ZnCI, for 2 percent of pernod, tank contamed bakng solubon of 50 percent NW 4 percent ZnCI,, 0 15 percent PbCI, Alloy C = 0 1 mpy I both lhquld and vapor phases.
Ammomum
Chlotlde
to BP to B.P 167
E sodaurn chloride 78 g/I, carbon dmxlde 42 g/l (combmed as NH,HCO,. (NH,), COI, NaHCO,), ammoma 22 g/l (combmed as NH,HCOI. (NH& CO, NH, OH Sulfide trace. organa posrlble trace sole leather dye vat NH&I and enzymes dlsperseo I water
Ammomum
Chloride
+
Ammomum Ammontum Ammomum Ammomum Chloride Chloride Chloride Chloride
f
79.103 E E _ -
sodium sulfde mother IIOUOIS. Allov C = 0.003 mov m 336.hr plus sodwm rulflte mother Iutuor. Alloy C = 0.02 mpy I refmery c&r
test
plus HCI and hydrocarbons
bubble tower Alloy C = 0.1
1
-
w
400 grams/bter NH,CI plus 3-5 grams/kter NH3
Ammomum Ammomum Ammomum Ammomum Phosphate Ammomum Ammomum Ammomum E G S B U -
Chloride Chloride
I I
Alloy C = 2 12 mpy 350 grams/Met NH& plus 1.2 grams/liter free NH, Alloy C = 0 06 mpy
Chloride &hydrogen Satr Soln 1 82
449
I
1
I
E E
28
Alloy C = 0 004 mpy
I
Fluoride Fluoride Fluande 05 mm/y) to 10 mpy (0 25 mm/y) mm/y) to 20 mpy (0.51 mm/y) mm/y) to 50 mpy (1.27 mm/y) (1 27 mm/y) BP Bolllng Pomt 16.93 S
I
E _ _ plus excess NH,OH plur8percentbtamum plus suspended fluwdem theseparatlonoftltanlumfromttrore
fetrous tdanate IIlmenW
Less than 2 mpy (0 2 mpy (0 05 mm/y) Over 10 mpy (0.25 Over 20 mpy (0 51 More than 50 mpy
(continued)
672
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Ammomum Ammomum Ammomum
Fluos~l~cate Hydroxade Hydroxide
I I
18.5
90-110
248 572
32.43 120
300
I I
I 1
E*
1 I - I - I pluspercent free H,SIFG I --
l Slqht
weight gam
Cone -
G
s
I -
I 210 hours, 8% NH]. 2% HrS, 2% CO, and 0 3% HCN

contamed 2 grams cupnc chlonde test. no agrtatmn *Cracked and sodbum sulfate/gal, 159 hrs.. lab
Ammomum
Hydrorlde
150 268.275
66 131.135
E E
contams aeration
(NH,),COI.
(NH&S.
NH&.
NaCl
Ammomum Hydroxide, Ammoma. Carbamate Ammomum Hydroxide Mrxtures. Ammoma Ammomum Ammonium Ndrate Nttrate
21
122.194
75 32-212
50.90
24 0.100
--
carbon dloxlde aerabon
6%. water vapor 66%. au 0.5-l%.
all by volume,
shght
10 12
E E
--plus ammomum hydroxylamme nitrates Alloy C = 0.3 mpy E dwlfonate SO?. ammomum sulfates and
Ammomum Ferbbzers Ammontum Ammomum Ammomum Ammomum Ammomum
Notrate
13.38
100
38
E.
potaswm chloride 11.6to 301, cslclum phosphates, mono- and dl.. 1% to 14%; water 20%. lnerts 12%. pH 4 5 to 7 0. moderate aerabon
Oxylate Perchlorate Persulfate Phosphate Sulfate
10 All 10 5 All 45
l5 to 160 75 75 to B.P 190 212.213
24 to71 24 24 to B.P 88 100
E s E E s S. E
-------
hquld
anhydrous
NH,. H,SO,, and (NH&S
added m process
Ammomum
Sulfate
m ddute and saturated NHSO, mpy
plus 1 5 percent free H,SO, Alloy C = 0 7
Ammomum Ammomum Ammomum Amyl Acetate
Sulfate Sulfde Sulfde
45.46
156 103 275
69 39 135
E E E s
---E
plus SO? and other sulfur compounds plus ammomum NH,HSO,.
Alloy C = 0 06 mpy
blsulflte, 3 percent total SO,, pH = 6 2 Alloy C = 0 1 mpy
pfi 5.0 to 6 0 ol amyl acetate from amyl alcohol. glacial acetlc acid.
durmg produchon HSO,
Amy1 Alcohol
104
40
--
plus 44 percent acebc acid, 34 percent amyl alcohol. 2 percent rulfunc acad. balance water plus traces 01 NaCI. NaOH, Fe& and water Alloy C less than 0 1 mpy
Amy1 Chlonde Amyl Chlonde Amy1 Chloride 84 100 100 -
75 86 86 BP 230
24 30 30 BP
E E ;
E E III
---
plus 16 percent dry HCI Alloy C less than 0 3 mpy plus trace of HCI and water
Amyl Mercaptan
110
to 160
E
E
-__
E --
plustracesof ethanol, brme. amyl chloride. dlamyl sulllde and H,S 1656.
hr test m lkqutd and vapors ol dlsbllabon column pounds, water and a trace 01 H,S E plus some other amyl com-
Amyl Mercaptan -
to 320
Amyl Phenol
176
80
varws orgamc syntheses. lerbary amyl phenol. amylene. ddertwy amyl phenol, trace BF3.ether: t.nonyl mercaptan. sulfur. hydrogen sulfide dlterhary nonyl.polysulflde. magnesm. dlphenylamme. monene. nonyldlphenylamme. styrene. trace 98% H,SO,. clay, vapor phase , various organic synthesis tertiary amyl phenol. amylene. dltertlary amyl phenol, trace BF,-ether. t.nonyl mercaptan. sulfur. hydrogen sulhde. dlterbary nonyl.polysulflde, magnesia. dlphenylamme. nonene. nonyld~phenylamme. styrene. trace 988 H,SOI
Amyl Phenol
392
200
/ -
AfUllW AlUklle Amkne Sulfite
100
75
24 200-270 16 24
E E*
S E 7
I-1
I-1 plus CS,, H,S. mercaptobenzol. z SO, blown mto 10 percent thwole and others Alloy C = I 0 mpy
392-518
1:: ;:
sn~lme 011 I water
~~~~~~ (Methyl Phenyl Amsole Ether), Boron irdluorlde Anodizmg Alummum E G S B U Soluhon.
302
150
1 U
j --
1anhydrous.
18 5 percent
32 days
180
82
HPO,
plus 3 percent
H,CrO,
m lead+ned
tank
Less than 2 mpy (0.05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy (0 25 mm/y) Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy 10 51 mm/y) to 50 mpy (121 mm/y) More than 50 mpy I1 27 mm/y)
6 P -
Bolllng Pmnt
(continued)
673
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Conosiv~ Anbbmbc Fermentation
Ydia
COMSW tntion. ptrcmlt
Temprntun dw.f d-C
HASTELLOV~ G/G-2 WC-276
lky G
TYpr 316 StainSW
Ins
Conditions
Media
habc halocarbons.
anhydrous
hydrogen
fluor,de and
Anhmqny
Salts
-58.212
.50-100
vapor over mlred anbmony fluorochlor,des [SbFxCl(S-xi]. refluxmg condensate of ahphstlc halocarbons. anhydrous hydrogen fluoride and hydrogen chlortde mixed anbmony fluorochlorldes [SbFxCI@x)] and [ SbFyCI(%y)]. to which IS alternately added anhydrous hydrogen fluoride and altphatlc organic chlorides 25 percent HNO,. 75 nercent HCI
Anhmony
Salts
212
100
Aaua iha Aromabc AromatIc Atwne Bawm Bawm Chlarlde Chlonde Tar Tar
B.P
B P.
--
20.25 All 20 25 Saturated All 100 -
1 482
482 140 140.212 to BP
250 250 60 60-100 to BP
1
-
I E E
E E ---
I -
I d,st,llabon
d,st,llaban moderate
process, 167 hrs, welded samples process. 264 hrs, welded samples aerabon
_ s -
Allay C = 0 1 mpy
I
Banurn Chlortde Barium Hydrwde Beeswax Bleach Soltlo Benzene Benzene I Benzene Benzene. Chlorinated Benzene. Monochlor Benzene Sulfonlc Ac,d I
I
70 EiP I500 220
21
E S E
1 E
s ___ E
1--
1-
1Alloy
C=Ol
mpy
104
--
160 lb H,PO,. 50 lb K,MnOa and 300 lb H,O per 1250 lb of crude beeswax Alloy C = 0 19 mpy I / plus 40 percent chlorinated benzene. 5 percent HCI. 5 percent benzene H!O
50 90
a0 a0
127iBIB 1 I I
1
27
vJ6.P 130 16-27 1::
1 I I
/
s
E S G S S
1 E I I
1
1l-l-l I
1 -_ -1 --
1I 1 -
plus 5 percent HCI. 5 percent H,O and chlormated /mpy,A11oyC=O2mpy I 1 Alloy C = 0 1 rnpy I DDT producho plus 3 percent plus SO,, Alloy C = 0 3 mpy
Alloy B = 44
All 100 86
1 I
toBP 266 60-80
s
E E s U B
140 284 329
H,SO,
Benzene Sulfonx
Acid
90
I65
process starts wdh 66 Bi H,SO, and benzene Ftnal product percent benzene suI1on1c ac,d and 4 percent H~SO,
PIUS 3 8 perCent
IS 90
Benzene Sullon~c Ac,d Benzene Sulfamc Benzene Tetrachlor Acld
913 92 -
284 392 269-554
140 200
S E
s E
---
HISol suIfur,c
Alloy C = la mpy acid and 3 percent water
plus 5 percent
1 32-2ag )
30-35 24 to 240 232 to 52 El P -
C S -
1 E
--E s B E
/ ---
I -
I Interface.
I still at three wlnts Alloy C = 0 2 ,py I lhquld 0 5 mpy I Ihquld-vapal 0 7 rnpy , vapor
Benzene. Wet Benzo~c Ac,d BlsmuthLead Black Liquor Bleach Liquor E G S B U Alloy
10 Eutechc 43.47 100
86-95 75 to 464 450 lo 125
both Alloys B and C considered _ _ m produchon contalnlng of d,methyl rulflde
good for long hme use from black lhquor
avadable chlanne
Less than 2 mpy (005 mm/y) 2 mpy IO 05 mm/y) to IO mpy (0 25 mm/y) Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy 10 51 mm/y) to 50 mpy I1 27 mm/y) More than 50 mpy (1.27 mm/y)
Bo1hng Point
(continued)
674
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
TYpr 316 Stainless Stnf
(continued)
HWTELLOV~ Conoriw Bleach Solubon Media B/B-Z IX-276 E
alloy 6 --
Conditions 0.044 percent tree Cl,. 0 07 percent available Cl,, 0.025 petcentClO> hr. test. Alloy C = 1 1 mpy 48.
Boric Acid
= 0 2 mpy (vapor), <o 1
Boron Trlfluorlde
Bracktsh
water
Brass Ptckllng Solubon BrarIng Brtflo Flux
100 2-9
140
60
--
contams 19 to 28 percent H,SO, and 4 percent CuSO&. Completely Immersed m solubon m rubber-lmed tanks alkali fluorides m commercial dip brazmg furnace Alloy C = 5 6 mpy
1to
1090-1140 115-125
588-615 46.52 -
G E
---
plus glue and carbon black, H,SO, added to release fatty acid from soap addlbon. ptl = 2.0-Z 9, Alloy C = 0 065 mpy
Brtlle Brme. Saturated Brme. Saturated Brme Solubon. Waste Stream Brme Slurry
j I
125.150 140 240-245 107
1 I
52.66 60 115-118 42
/ /
-/
G
/ /
E E E E
1 I
1I
1310
I
grams/liter
NaC brine plus trace Cl,, pH = 104
Alloy C = ml mpy
1-1-I -E E aerabon contammg 23 g/l total dlsolved sollds conststlng 4 4 g/l sulfate p&l. 90 days contammg MgSO4,. H,SO,, KCI, N&I. to extenwe aerabon also NaTSO,. KCI. N&I. aeration of 10 g/l chloride and
195
91
MgCI,, trace of S, pH 7 7. moderate
Brme Slurry contammg MgSO,
196
92
E
I
MgCI,, trace of S. pti 7 7. moderate to extenswe
8
100 28 5 _ _ 150.700 to 150 59 59 158 225-250 120.140 66.371 to 66 15 15 70 107.121 49-60 G G G S E 5 E G B G 11 -----
Bromme, Bromme Bromme Butane Butane
Dry Gas Gas
m eqwkbnum m equihbrwm
wth
10% Br water solubon
Awelded samples
samples
wth Br lhquld Awelded
also 50 2% H,SO,. 21 3% water. synthebc plus Isobutane. _ hydrogen chloride sulfur
butyl acetate lhquors
Alloy C = 10 mpy
Butanes (Catalyst Cracked)
plus 0.02 percent
mercaptan
Calcwm
Bromide 117 47 E E E calcium carbonate, 11% (by wt)
Calwm Carbonate
slurry. not pH
talcum
sulfate. calcium sulfde. all suspended spec!fled, aerabon
as 6.
C&urn
Carbonate
80
27
calcwm carbonate. calcium sulfate. calcium sulflte and Ily ash all suspended as about 20% (by ) slurry. pH not speclfled. aerabon
wt
Calcum E G S B U -
Chlorate
All
to B P
toBP BP -
Boakng Pomt
--
Less than 2 mpy (0.05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy (0 25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0 51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (127 mm/y)
(continued)
Nonferrous lwetals and Alloys
675
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
bntinued
I QPJ I
Conoriw Calcwm Chloride
I
Media
Concmtntion. wcrnt 12
dw 75.85
I
Tmwratun F d-C 24.29

I I
HA6lELLOV~ WC2 G
I
Jlloy G
316 *instwl
IUS
WC-276 --I
Conditions PIUS a percent methyl ethyl ketone. 1 percent HCI. 0.5 percent acombc acid 10% KCI; concentrated brme I potash ertracban pllot plant. hall lhquld phase,
I-
Calwm Calcium
Chlortde Chlwde
20 29
220
104
E E
E --
167.194
to B.P. 350 ia0
75-90
to E.P. 177 a2 -
plus 8 7 percent M&I,, 1 percent N.&l hall I vapor. Bdtern Process Alloy C = 0 08 mpy E *shght gam m weight. Specimens
Calcium Chloride
All 40-60 40
E E* E
-_ -
m pdot plant evaporator
Calcium Chloride
zmc sulfate 40%. pH 2.8. 35% of ttme. alummum sulfate 3.30%. pH 3. 15% of bme: magnewm sulfate 40%, PH 3. 10% of hme. zinc chlorkde 40%. pH 1.8. 5% 01 bme, moderate aerahon 5 solutions. each smgly calcium chloride. PH 2. 35% 01 time. zinc sulfate 40%. pH 1 8. 35% 01 bme, alummum sulfate. 3.30%. pH 3. 15% of bme. magnesm sulfate 40%. pH 3. 10% of time. zmc chloride 40%. pH of bme Moderate aerahon hydrogen chloride recovery. pH about 3 to 4 Durahon of test - 305 hrs = 12 71 days Aerabon - moderate Agdatlon - 2-3 ft /xc partially purlfled N&I, 0.10 percent CatOH),. Alloy C = 2 1 mpy
Calctum Chloride
40
70.200
21.93
i 8.5%
Calcium
Chloride
54
260
127
--
Calaum Calwm Calwm
55 58 62 73 Brme la.20
I I
220 329
104 165
I
G I
-__ G
I
-I I
plus 1.0-1.3 percent 1 1 partially purdled
310 350 175 248.266
154
177 79 120.138 80.90
G G E G -
G ___ ___ -__ E
Calcium Chloride Calcium Chloride Calcwm Calaum Chloride Chloride
140 g/l C&I,,
80 g/l NaCI. 2 g/l Ca(OH), sullur. m sulfur separator
plus Na,S. Na,CO,. elemental -I I I
176.194
plus t&Cl, S I I
brme. pH = 5 0
Calcium Hydroxide
21
I
E 1 I
durahon 01test - 204 days, *severe pdbng
24 to 6.P
Calcwm
Hydroxide
to 50
to B.P.
Calcwm Hypochlorde (Lime Sludge) Calcwm-Magnewm Chloride Solubons Calcium Pyrldme Sulfanate Calcium Sulk
60.100
I
Cone 212.220
16-3a 1 100-104 S
E
G
I --
I -
I amounts
free Cl = 40 gramslhter.
CaCI,. CaCIO,. CsCD, and lree lhme in small
plus free 0 63 percent
HCI m Londensate
Alloy C = 6 7 mpy
100.150
38.66
--
plus 1-5 percent H,SD, and a t:ace of HgSO,
Alloy C = D 1 mpy
115
46
Calcium sulfate. ctklum Carbonate, fly ash. all suspended as 30.50% wt 1 slurry. pH not spec~bed
(by
Calcwm
Wide
117
47
cakwm sulfate. ctlclum carbonate. fly ash. all suspended as 10.15% (by wt.) slurry, pH not speclfti. aerabon
E G S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy 10.25 mm/y) Over 10 mpy (0.25 mm/y] to 20 mpy (0 51 mm/y) Over 20 mpy (0 51 mm/y) to 50 mpy (127 mm/y) More than 50 mpy (1.2.7 mm/y]
B.P. -
Eolhng Pomt
(continued)
676
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHXPRODUCTS
(continued)
COOCSllComsiw Calcium Sulfate Ysdis trstion. pwcsnt 10 dw.F to BP 96.221
Tsmpwstws
dW.C to B.P. 36-105 -
HAsTELLOv~ Slloy B/6-2 SI C/C-276 SIE -G
Stsin6trl -
?I7
Irs
Conditions
Clurdeblla Wax
plus N&IO,. 100.hr. test G
H,SO, and HNO, laud content
about 25 percent of total).
Captolactone and Ammoma Carbon Olchlotlde 65 250
664 hn.. producbon
of caprolactum
I
Carbon Dmxtdc 10 150
12
&
I
1
I
1
E
E
I 1 -
I - I HCI
1 -
plus 25 percent CU. 10 percent heavy organu chlorides saturated wtth and CIT. about 20-30 ppm H,O. Alloy C = 0.05 mpy SO,, 2 percent CO and some
m humtdlflcabon process plus 0.2 percent 10, AlloyC=O.O2mpy
CarbonSlurry
75
24
1-
1 - 1plus
HCI to a pH of 1.5. Alloy C = 0.02 mpy
11-week test
Carbon Tetrachlorlde
100 85-87
75 to 300 85.167
24 to 149 30.75
i S B
--G -plus 13-15 percent chlormated high polymer. 0 08 percent chlorine. 0 1. 0.2 percent HCI Normally anhydrous Alloy C = 2.2 mpy plus 12 percent H,O. 0.4 percent Cl,, 0.1 percent HCI Alloy C = 2 3 mpy Ccl, carrwd an au stream
Carbon Tetrachlorlde
Carbon
Tetrachlorlde
a7 5 -
185 932-1112
85 500.600
u G
G G
---
Carbon Tetrachlorlde Carboac Acid

I
Causbc (mdd)
0.6
40.212
4.100
--
plus tetra sodmm phosphate, 11.5 oercent acldl
ddute NaOCI. some lree Cl,. dilute HIS04
Caushc
80.90
27-32
---
absnrpbon of Cl1 and acldlc matenat from reactor off.gases tams 1 percent NaOCl maximum -plus 7 percent NaCI, 8 percent water III neutrabratmn pvxess plus orgamc and sulfurous
Solubon con.
Causbc
2.17
60.110
16.43
CHICOOH. 12 percent orgamc salt and Alloy C = 0 1 mpy
Chestnut Wood Extract Chloracebc Chlotacebc Chloracebc Acld And Acid I
90 1
150.200 73 158 to B.P 75 to 356 68
66-93 I23iEIEI-j-1
--
acids and tannm
100
to 70 80 100 -
70
E 1
T* E* E -
E s E
1-1-I ----
toB.P
20
24 to 180
lmonochlotacebc _
acid
Chloracebc Mono Chloracehc Mono Chloracebc Mono
Acid.
plus 15 percent dlchloracetlc ~0 1 mpy Alloy C = 14 mpy
acid and 15 percent acetyl chloride
Alloy C
Acid.
160.180
71.82
--
bud.
ii
77 77 77 140
Ill (21 (31 111
25 25 25 60
(11 (2) (3) (1) 30
T s S ;
E s
--11
plus 30 percent acetu acid. 1 5 acetyl chloride. 0 5 percent H,S m mother lhquor (1) no agdabon (2) slow agdatlon (3) fast agltatmn
Chloracebc Ackd. Mono (Tech. Grade) Chloracebc Acid. Mono (Tech Grade) ChloralphenoryAcetlc Aad. 2-4 DI Chlorethylene. Chlorlc Acid Trl
86
--
process IS to dissolve 945 grams/liter agdated wdh ao Alloy C = 0 2 mpy Alloy C = ml mpy
sobd MCA m water
Solupon
100 -
60.70
16-21
--
250
121
E E u --_ E
--
producbon of this acld from monochlorobenrene. monochloracebc and. NaOH and H,SO, vapor and lbqud somebmes steam and ammoma
dlchlorophenol
100 3
to BP 75
to B.P 24
present
--
4 percent HISO,. 3 percent H,O, carotbng solution day test saturated
Alloy C = 0 1 mpy 47.
Chlormated
Water
1M) 100 97
75 190 50-180
.$ 10.82
1 -
:: E
51 --
Chlarme
plus 3 percent Inert gas (CO? H,. etc (50 deg F). 09 mpy (180 deg f)
Iwater
saturated
Alloy C = 0 07 mpy
E G S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0 25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0 51 mm/y] to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
BP
Bollmg Pomt
(continued)
Nonferrous
Metals and Alloys
677
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
COllCO~Corrosive Chlorme Chlorme Chlorme Chlorme Media tntion. prrcmt dw.F 0 Amblent
T9mpmtun dq.C .18 Amblent B/B-Z -
HASTfLLOV~ alloy C/C-276 E G 6 --
Stsin-
Ins SW
E durabon chlorme of test smff 139 days, scrubber. organic actd
Conditions dry chlorine gas
400 hrs
68
76.86
20 I
24.30
Lt*
E
s*
l-l-l
B*
plusand HCI
mpy
feed Cl, to dlchloropropene at 5 ps,g, 672 hrs vapor phase I Ihquld. Alloy B = 30 mpy. Alloy C.276 = 13 mpy, Type 316 Stamless Steel = 32
Chlorine Chlorine
77.90. 86
25.32 30
E G
--
dry chlorme
gas m alkylbenzene hrs. und samples m chloronator CII-
chlormabon system culabng loop, 3936 -
Chlorme
120.135
49.57
above sodum cell I fumes chlotlde. sodum oxide smoke max pdbng w/entramed89 1% sulfwc phase
contammg sodaurn and motst air Alloy
oxychlorlde. C = 0 1 mpy.
sodurn 0.001 I
Chlorme Chlorme -
140 302
60 150
E E
---
acad and durmg
orgamc dechlormabon
lmpurabes Alloy C = 0 3 mpy
1000 ppm Cl, I vapor 1776.hr test
Chlotme Chlorme Chlorme Chlorme Chlorme
(Wet) IWetl (Wet) (Wet) (Wet)
100 -
75 60.200
24 16.93 30 40 50
G G E G E
--[-I-~T --Alloy C = 1 1 mpy. sea-water 67 8 hr test spray acld. chlormabon of polyethylene.
86 I
104 122
I - I
-
ntth some
plus hydrochloric 72 hrs orgamc test I vapor chloride
and hydrochlorous
Chlorme
(Wet) -
170
77
--
sokds. condensed 67 days space 01 sulfur
water. shght
attack under
spacer.
Duratmn
of
Chlorme
(Wet)
185
85
--
separator
Plus
H,O.
S. and
oqamc
thlo and
Chlorme
(Wet1
190
88
--
condensed lorated durabon durabon durabon

1
water and orga!c
sokds.
durabon
of test -
203 days.
per-
Chlorme Chlorme Chlorme Chlorme Chlorme
(Wet) (Wet) (Wet)

I
190 190 -
88 88 88
I
1
I
u G 1
1
--1-1-I
I
01 test of test 01 test of test -
28 days, 74 days. 18 days, 202 days.
perforated. severe moderate perforated pdbng.
salt brme
spray spray spacer
salt brme under
I
I
190.1 190 I
G G
attack
IWetl (Wet)
88
I -
l -
I durabon
condensed moderate durabon durabon
Chlorme Chlorme
(Wet1 (Wet)
I
I
I -
I
I
I lgo I
20;
I - I I- I- I
96 I I u
water and orgamc sohds/spacer. attack under soacer 01 test 01 test 40 days. 203 days. moderate salt brme pdtmg.
durabon
of test -
18days
205 I
96 I
l-l-l l-l-l
salt brme
spray
spray
E G S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y] to 10 mpy (0 25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0 51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1 27 mm/y)
(continued)
678
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
kontinued)
Chlorme
Dioxide
SD
10
--
O-l 5 grams/W CID, plus trace SD?, O-9 grams/Mer percent H,SO, I spent bquor tank. Alloy C = 0.5 mpy 78 percent GO.. 32 percent flo. rate of 6b g.p.m :351-h,. sodwm chlorate test
N&ID,,
18-38
Chlorme Dmxlde
135
57
--
and methanol
aerabon.
Chtorme Dioxide
150-170
I
Chlorine Chlorme Dloxlde Dioxide
I
155 155
60-77 I
68 68
E I E s ---
I -
I O.lZmpy
Cl0 water and gas. plus 0.2 grams/lder
HCI m water
ptl=3 5
Alloy C =
spent gas m vent lhne of bleach tower. 338.hr plus 45 percent bleachmg. t&SO,, 0.020 grams/liter
test sodium chlorate m pulp
Chlorme
Dlornde
155
68
--
pH q 6.5 spool exposed I headbox I No. 6 pulp washer Kraft pulpstock plus residual CIO; at top of bleach retenbon cyanogen chloride. chloride chloride tower Alloy C = 0.7 mpy
Chlorme Chlorme Chlorme Chlorme
Dloxlde (Matures) (Mwtures) (Mixtures)
175-185 59.86 68-85 169.212 1 1
79-85 15.30 20.29 76-100 1
-I-llJl I I 6 E
1
1
E E E
chlorme.
water (all gas) water vapor (about 1000 ppm) carbon tetrachlorlde. water (trace)
I cyanogen 1 cyanogen
(CNCI). chlorme. (CNCI) chlorme.
1 -
Chlorobenzene
60
40.100
Chlorobentene
I 1 -
I 250 lzl I - I E I - I - I I
1
77.338 ,i 25.170 j S 1 E
I 4c48 I E I - I EI I 1 -
chloral 40% (tnchloro acetaldehyde). water not over 0 5% hydrogen chlortde trace. IpH of water extract 2 01 commerul aerabon trlchlorobenzene vapor. amrnon~a and chlortdes. ertensw
Chlorotenzene. Mono
/ G
11114.lb
3.chlorod~phenylamme, 311.lb monochlorobenzene Alloy C = 15 mpy
sulfur.
1 l-lb
lodme. 475gal
Chloro Ethyl Ether, Ethylene Chlorohydnn Chlorofluoromethanes
302
150
stdl system for crackmg DI (Zxhloroethyl) acetal to vmyl 2.chloroethyl ethers and ethylene chlorohydrm Samples m kettle bquld. 300 hrs. tnchloromonofluoromethane and d~chlorod~fluoromethane. hydrogen chloride 20%. hydrogen fluoride IO%, carbon tetrachlorlde 1%. anbmony pentachlorade. oxygen. mtrogen. total 5% (all approx water not over 200
64
100.180
38.82
ppm Chlorofluoromethanes 60 100.180 38-82 E E d!chloromonofluoromethane and monochlorodafluoromethane. hydrogen chloride 20%. hydrogen fluoride 10% chloroform 5%. anbmony pentachlorade. oxygen. mtrogen. total 5% (approx water not over 200 ppm
Chloroform Chlaromethylphenoxyacebc Acid Chloromethylphenoryacebc Acid Chloronaphthalenes
loo 99
to B.P. 300
toB.P.
149
I
-
s
E
I --
I -
I
4.chloromethyfphenoxyacebc sodurn chloride. water. acid. small ants. hydrogen chloride,
99
315
157
4.chforomethylphenoxyacettc sodum chloride. water
aad.
small
amts.
hydrogen
chloride.
100 1W
300.360 300 122-140
149.182 149 SO-60
I S
;*. E
I --
vapor and lhquad m neutrakzabon l *vaoar and bawd oh&es m lkqwd and vapor phase dung from HCI. H,S. F&I, hydrogen chloride
of free HCI wdh lame
Chlorophenol -
chlormabon
of phenol
Contammabon
Chlorophenol. Dlchlorophenol E G S B U -
250
121
--
trace. water vapor trace. moderate
aersbon
Less than 2 mpy (0.05 mm/yj 2 mpy 10.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy ID.51 mm/y) to 50 mpy I1 27 mm/y) More than 50 mpy (1.27 mm/y)
6 P -
Bollmg Pomt
(continued)
Nonferrous
Metals and Alloys
679
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Chlaro-Trlfluoro Ethylene Chromic Aod
70.120
21.49
--
parMy
lhquefled plus 1 percent or less HCI and water m trace amounts
2 10 to 30 50 50 55 10
Bodmg Balkng to BP 125 130 150.250 to BP
Bmbng Bolllng to BP 52 54 66-121 to E.P
s S G S
G u --E B ---
-u -
120 hr lab test 120 hr. lab test
Chromtc Acid Chromic Sulfate (Bane)
Chromwm Chromwm Chromium Sulfate Cltrlc Acid Cltnc Acid
Sulfate (Baste) Sulfate (Baw) Potaswm
---
Alloy C = 0.07 mpy, mdd agdabon 4BO.hr test
10 10
60.180 80-170
16-82 27.77
S B
E G
---
manufacture
by aerobic fetmentabon
-a
spargmg
Alloy C = 0
I mpy
manufacture by acid by fermentabon Allov C = 4 mov
with sucrse. made acld wth HCI
Cltrlc Acid Cltrlc Acid
10 to 58
Balling 130
Bodmg 54
E G
--concentrabon =45mpy by bodmg sob&on from 15 to 30 Bk. 120.hr test, Alloy C
Cltrlc
Acid
All -
to B.P 105
to BP 41
E _
E E
-E E mIxed fermentabon tank effluent, 0.08 to 1.2% chloride, pH 5 sme cltrlc acid salt. 5 to 65% sokds.
Cdr!c And
Clarlfw
Llquld
180
82
E ---
clarlfw llqwd m mumclpal refuse mcmerator Water treated wth calverts coagulant II and ammoma to nommtl pH of 6. moderate aeratmn plus 0 01 percent H,SO,. 3.3 percent NaCI. pH dewatermg sklmmer
q
Coagulation Soluban. Synthebc Rubber CookIng Liquor Cookmg Liquor Cookmg Liquor Cookmg Liquor Copper Chlorides
90
32
3 3. m discharge wetr of
13.2 132 13.2 13.2
115 115 300 300 455
46 46 149 149 234
Ll* B -
u u* E tJ* E
s G -
u c B G U
aerabon aerabon. specimen aeration aerabon, *specimen corroded away or was lost cyanide. p.chloro phenol N methyl corroded away 01 war lost
cuprous chlwde. cuprous pyrrahdone. p_cyanophenol copper copper caushc sodlum plabng cyamde soda = cyamde solubon = 10 z /gal 4 oz /gal = 2 oz./gal
Capper Cyamde
170
77
--
Copper Smelbng
Gas
105
41
coppet smelbng gas contammg 0 75-196 SOI and some sulfurlc acid mfst (25-100 ppm). eatenwe aeratmn copper smelter gas after cookngm a Hz0 spray tower Gas cntalns H20 at 2.5 pH plus sulfuric acld mist (25-100 ppm). extenwe aeratton
copper smelter
Copper Smetler
Gas
135
57
Copper Smelter
Gas
100
30
gas and recycled cookng spray water (pH as low as 7 avg. 2 51 1.1 5% SO, m gas plus parbculate and SO,. eatenwe aeration 12% Cu avg. 0.5% H,SO,. 90 days. copper refmmg. acad. 1 free copper refmmg. moderate aetabon
Copper Sulfate copper Sulfate E G S B U -
45 BB
190
00
160
71 BP -
1 -
I E 112% rulfurtc
113 days
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy 1025 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy 10 51 mm/y) to 50 mpy (1.27 mm/yj More than 50 mpy (1.27 mm/y)
Eolkng Pomt
(continued)
680
Corrosion
Resistant
Materials
Handbook
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Conoriva Copper Sulfate copper copper Sulfate Sulfate
Media
CWtCantntinn. percent All -
Temperature de8.f to BP 150 160 dq.C bJ8P 66 71 1 1 149 165 1 1
HAnELLOr~ B/B-2 S 1 1 WC-276 E E u E E
alloy C ---
- less
Steel
TYpr 316 Stnin-
Conditions
electrolyte.
194 g/l &SO,.
49 g/l cuso,.
1 g/l cao AgrSO, rmecbon at 150 osr acrd and higher acrds
40-70 grams/hter
CuSo,. 3-6 grams/hter
Corn Starch creosote or1 Cresvhc Acrd Cresvhc Acrd
1
1
15-1.7 All -
1 1
300 329
1 1 -
1
1 -
1cornstarch
acrdrfied wdh HCI tooffof
1.5.1.7.steam
1 plus 7 percent acebc acrd. 2-3 percent propronu
I toBP
86-356
I 1
toBP
30-180
I 1
s -
I s 1 s
E E
l-l-l 1 --
1 u 1 cresyhc
acrd, phosphorous oxychlorrde, trrcresyl phosphates. hydrogen chlorrde, alummum chlorrde 1%. pyrrdmes less than 0.1%. Anhydrous. Alloy C = 0.5 mpy
Crwyhc
Acrd
100 113-266
38 45-130
plus NaOH and water E
Cresyhc Acrd
cresyhc acrd. phenol. lormaldehyde. sulfurrc acrd. ethylenedramrne. phosphorrc acrd. sodrum hydroxrde. carbon droxrde. ammoma. barrum hydroxrde. Corrosrve medra varied from mtxed phenol and sulfurrc acrd at 266F to 20% sodrum hydroxrde at 212F (Batch-baas manufacture of phenohc resms and varnrshes). moderate aerstron cresyhc acrd. phenol, formaldehyde, sutfurrc acrd. ethylenedlamrne. phosphorrc acrd. sodrum hydroxrde, barrum hydroxide. carbon droxrde. ammama. aerabon phenol. phosphorus orychlorrde. trrcresyl phosphate. hydrogen chlorrde. alummum chlorrde 0.5-l%, pyrrdrnes (1% Anhydrous plus HrS. H,O and some organrcs I borlrng solubon Alloy C = 0 04 mpv. some H,S Alloy C ~0 1 mpv
Cresyhc Acrd
266
130
Cresyhc Acrd -
284
140
Cresyhc Acrd Cresybc Acrd (Crude) Crude 011 Crude Or1
350 350
177 177
E E
---
145 750.780
I
Crude Toluene Cumeme Cumeme 1
75 1 339 140.160 207.221
1 )
1
63 399.416
1 1 E 1 G
U E
1 E 1 1
E --_--
1 1 1 -
1 E 1wdh or1 field bnne contamrng 1 - 1Ib, Lowslana crude, sulfur mrxed
1 S 1 drmethylandme hydrochlorrde
15 ppm S = 0.26 percent. salt content = 3-5 lb./ 1000
171 60.71 97.106
refmmg
crude toluene; 235 hrs
plus phenol. acetone plus 25 percent cumene hydroperoxrde. ohenol from cumene In lhqurd phase Manufacture of
Cyanurrc Chlorrdc
60.160
16.71
m carbon tetrachlorrne or toluene. chlorrne 0 5%. cyanogen chlorrde (CNCI) 0 3%. hydrogen chlorrde and phosgene (carbonyl chlorrde. COCI.) traces. moderate aerabon toluene. dlchlorocyanurarropropamrde (C,N,CI,NHCH (CH,),). sodium hvdroxrde. sodrum chlorrde 10%. DH 1 l-13. moderate aeration
Cyanurrc Chlorrde
50 lo
I G I E I-lEl
E E E E E 6 E E
Cyanogen Chlorrde Cyanogen Chlorrde Cyanurrc Chiorrde -
77 176 221
25 80 105
chlorme chlorme. toluene. water chlorme,
water yaw
(about 1000 ppm) water (trace) traces of chlorme. cvanogen chlorrde.
carbon tetrachlorrde. carbon tetrachlorrde.
Cytnogan E G S 8 U -
Chlorrde (Gas)
59-86
15-30 8 P -
G Bo1hng Pomt
water
Less than 2 mpv 10.05 mm/y) 2 mpv (0 05 mm/y) to 10 mpv (0 25 mm/y) Over 10 mpv (0.25 mm/y) to 20 mpv (0.51 mm/y) Over 20 mpv (0 51 mm/y) to 50 mpv (127 mm/y) More than 50 mpv (1.27 mm/y)
(continued)
Nonferrous
Metals and Alloys
681
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Detrose (Greens) Liquor Dkbaslc Drgamc Acld and Thmurea DI-baac Orgamc Acld and Thloutea D~chlorethane -
315.325 156
158.163 70
G E
-E
0.04 N HCI.AlloyC 4.35 mpy

q
1
1
156 to 125 355
1 1
70 to52 160 74
1 I
1 I
1 l-l-l
_ -
H,S 1 aeratmn.In vapor phase
100
s
E G
s
E* E
_ E
4.5% hydrogen chloride. durabon of test - 53 days, l shght attack under spacer hydrogen chloride 20%: hydrogen fluoride 10%. chloroform 5%. anbmony pentachlorlde, oxygen. nttrogen. total 5% (all approx.): water not over 200 ppm trace 01 hydrogen chloride and water vapor Durabon 01 test - 36 daqs Aerabon - moderate Agdabon - none Process mvolved - dlchlorophenol 2 cycles. hqwd 72 hrs.. vapor 130 hfs, malonomtrde process (pllot plant test)
D~chloromonotluoromethane and monochlorodlfluoro-methane Dachlorophenol
60
165
100
250
121
Dlethyl Malonate Olethyl Sulfate D!methylamhne Hydrochloride Unsymmetrical Dlmethylhydrazme Unsymmetrtcal D~methylhydrazme D!phenylamme -
77.212 160.194 212 86 146 212
25.100 62.90
G G
E E
-U
Alloy 8 pdted m Iwd.
tt$O, (small amt. probably) 153 hts
26
m
30 63 100
I 1
E I E I
E E
G I-lI E 1 E E --
117 hrs. held test, aqueous DMA-HCI
E 1 tesbng rocket fuels, 26 days tesbng rocket fuels, 7 days E hot wash Ihqud. reacbon product of dlphenylamme and acetone m H8r catalyst atter adddlon of 50% NaOH to ywld pH 01 12.14. moderate aeration plus SOI SO, spent H SD, at bottom 01 sulfonator Alloy 8 = 27 mpy IlWdl. j2 mby (apot;
Dodecylbenzene Sulfon~c Acld Dukes Mixtures
I / 1
145.165 70
I 1
63-74 I 21 1
8 -
I 1 E
I 1 -
I - I
1
Electrolyte Eplchlorhydrm
I -
150. a I S*
I E I E I EI
S / mdustrlal waste. water. low but wdely varylog concentrations of hydrochlow hydrobromlc. sultur~c. sulturous acids. alcohols. chlormated orgamc solvents pH about 1. moderate aerabon 194 g/l H,SO,. 49 g/l CuSO,. 1 g/l CaD *specimen corroded away or was lost, llf free
EGS8U-
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y] to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (127 mm/y] More than 50 mpy (1.27 mm/y1
8.P - 8odlng Pomt
(continued)
682
Corrosion
Resistant
Materials
Handbook
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
TYP 316 Stain6 ----stool
(continued)
Corrosive Ethyl Chlorfde
Yedia
Conmltlatton. Vet 25 50 70 1Cil
Tompmtun deg. F :: 75 75 dq. 2: 24 24 C
HASTELLOV~ WE-2 s : s C/C-276 s s s s E
alloy
IUS
Conditions
Ethyl Cvanoacetate Ethylene.

G%?S
/ I
100
1 j
77.212 160.170
1
1
25.100
/
/
G 1
E 1
11 -
/ 1 -
/ lab
test. aaltatlon
Some W@SK
Cracked
contms 7177 E / 0127mov
acids. CO?, HCI. H,O ptl = 5 0 approx..
Alloy C =
Ethylene Olamme Hvdrochlorlde Ethylene Olamme Hydrochloride Ethylene Olamme Tetra-acebc Acld Ethylene Olchlonde
to B.P
toBP
1 S
B
G
1-1-I
-m 50 percent ammoma solubon Alloy C = 5 7 mpv
8-8.5
250.365
121-185
M-60
183
84
--
plus 30.40 percent 16.800.hr test
anhydrlde
O-20 perceot
wilds
Alloy C = ml mpy.
100.220
38-104
/ -
1 -
1plus
water, pella (111. and occasional
traces 01 WI
Allov C = 72 mpv
Ethylene Glvcols
sodium hydronde d!ethylene glycol 80% tormmg sodturn dlethylene glycolate Addlbon of dlmethylamme. orgamc chloride. tormmg amide -
Ethylene. Crude
Trlchlor
156
69
E _
-_
plus gaseous ammoma
m dlstlllabon
process
Alloy C = 0 03 mpy
Exhaust Air
170
77
saturated wdh water vapor contammg chlorme (low concentration suspended droplets). sodium hvdroxlde. chromate and chromic (low concentrat~onl and chloride. extenswe aerabon
and m wastes
entramed phosphortc acid. sulfuric acid vapor. sullur trtoxlde. mtrous acid. s~hcon tetrafluorlde. water vapor. sprayed wth water contalnmg phosphorlc acid 0 1%. sulfuric acid 0 06%. combined Huortde 0 1% ex-
Exhoxylates Fabrx sdteners 8 Manufacture Fabw Softener Rx Effluent
94
35
36 hrs, samples m c~rculttor i~ne Sulfonabon chlorosulfonlc acld. HCI evolved
of ethoxylates
wth
80.85
160
71
--
secondary ammes of tallow dissolved m tsopropyl alcohol. methyl chloride added to MNTN press and 73% NaOH to keep neutral E quaternary salt of tallow m isopropyl alcohol wth 1.2% HCI to make shghtly acld. 18 H,O and Cl Manufacture of fabric softener agltabon Ikhtenmg m!xet. total davs 235 0 plus 5 percent H&O,. K&O, and H,O *Itquld 3 percent sebaclc aad. small amounts of Na,SOa.
130
54
Fatty Acids / Fatty Aads
90
220.240
104.116
I-.
100 100 -
to 275 to 600 210 455.473
to135
to 316 99 235.245 -
E E
E E E E
_ _ ---
_ _
and vapor phases
Fatty Acads Fatty Aads
m d~sbllabon from tall 011 durw, lracbonatlon Allov C = 0 5 mov
Few
Nitrate
IO 2-4
75 160
24 71
E E _
-_ E ferrous sullate 0.2% sulluw aeration slurrv reacbon mature. acid 0 5&n, pH 1 2. hydrogen peroxide trace.
Ferric Sullate
Ferric Sullate E G S B U -
235
113 BP -
Bodmg Pomt
lab test 68 7 davs. aerabon
Less than 2 mpv (0.05 mm/y) 2 mpy (0.05 mm/y] to 10 mpy (0.25 mm/y) Over 10 mpv (0.25 mm/y) to 20 mpy (0.51 mm/y] Over 20 mpy 10.51 mm/y) to 50 mpy I1 27 mm/y) More than 50 mpy (1.27 mm/y)
(continued)
683
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Fert~hzer. Slurry mu
wdh 121 ppm LN 12Oand pttadtustment
wdh NaOH.
mcmerator scrubber. munulpal mcmerabon. 85 days
sobd raste.excessoxygen
added during
E G S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (127 mm/y) More than 50 mpy (1.27 mm/y)
BP
53hng
Pomt
(continued)
684
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Flue Gas Flue Gas
ZOO-250
93-121
E E
E E
aeration etlluent (ram quench chamber mcmerabon added durmg mcmeraban. 85 days mclnerator cmerabon, scrubber, 85 days mumclpal 01 garbage, excess m an
212
300
100
149
B
B
Flue Gas
sokd waste. excess (11 added durmg I-
flue Gas Flue Gas -
305 350
152 177
E -
E E
s E
water and water vapor. pH 2.0 to 4 0. aerabon contammg sulfur oxtdes. nitrogen oxldes. CO, CO?. HCI. 0,. N, and Hy ash. pti 4 5, e*cess au to support 750 ppm. CO> 0 7%. H,O 1.3%. bal au carbon dwde 15%. oxygen 4 7%. ndrogen 804%. (all dry basls) water vapor abaut 25%. suspended sohds plus 1-5 percent HCI by volume and CO, ex-
Flue Gas Flue Gas -
370 400
188 204
E G __E -
E S
Flue Gas Flue Gas
100.800
38.427
1100
-
593
-
hot exhaustgases and steam from water sprays oft refuSe Incinerator. tensw aeration stack gas from fwtube operation lrom munwal 1 from mumclpal wth entralned aeration with entrained scrubbmg Ihquor. serstlOn b&r burmng 114D ~(4%
Flue Gas
sulfur content) m cyclic
Flue Gas Flue Gas Flue Gas Fluegas. Power Plant Fluegas. Power Plant Fluobonc Fluoborlc Acld Acid ~~~
reluse. aerabon reluse mcmerator H,O and slurry (calcium sulfate. ctlcwm sulflte). aeratlan
32 -
130.135 140 149.176 90.100
54-57 60 65-80 32.38
E -
1 E 1 /
E E --E -E E G
E E E B
plus I 5 percent
bone acid traces of HF
40 grams/lder H,BF, at pti 1 7 to 1 9 m gas washer Powble Alloy C = 0 2 mpy 10 grams/hter plus alummum _
Fluobonc Fluabonc Fluorme
Acid Acid 100 100 100 -
lOQ.180
160-209
38.82
71-98
G E ;
E E
--_
H,BF, at pH 3 2.3 4 m spent hquor tank Alloy C ~0 1 mpy trthydrate slurry at pH 1.9 to 2 1 Alloy C = 0 4 mpy
950 1112
iz 510 600
E. ---
*furnace gas atter lhme water spray Penetrabon rate wed from 0 7 to 2 6 mpy at lower temperatures Alloy C galned wwght shghtly
Fluorides.. Fused
NaF-ZrF,. lluorme IO gal /hr E -B
purge 63 hrs hehum purge 153 hrs fluorine flow rate
Fluos~kc~c Acid Fluos~kc~c Acld
Il.13 16
140.165 80.140
60-74 27-60
B S
G G
wet process H,PD,.
lhquld phase, 49 days. extenswe
aerabon Alloy C = 2
plus 0 3 percent H,PO.. 0 5 percent SIO,. 83 percent water mpy m fume scrubber Alloy C = 5 mpy
Fluos~l~c~c Acid Fluos~kc~c Acid
20 25 50 70 1
130.140 75 75 75 245
54.60 24 24 74
S : s
G ; s s
-11 ---
Formaldehyde
119
--
plus 0 2 percent lormlc acid. methanol. ketones and other aldehydes

138.day test wth agltahon and no aerabon
E G S B U
Less than 2 mpy (0 2 mpy 10 05 mm/y) Over 10 mpy ID.25 Over 20 mpy (0 51 More than 50 mpy
05 mm/y) to 10 mpy (0 25 mm/y) mm/y) to 20 mpy (0 51 mm/y) mm/y) to 50 rnpy (127 mm/y) (1.27 mm/y)
(continued)
685
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Formaldehyde Formaldehyde Formaldehyde 12-15 20 50 70 100 20 40
220 243 275 to to to to B.P. BP BP B.P
104 117 135 to to to to BP B.P BP BP
S s : -
.E
E G s ; s E
---11 ---
plus traces of formic aud. calcwm formate. and glycols. 07.day test nn battom of fractmnatmg tower 87.day test at center of tower plus 2 percent lormlc acid, 2 percent ~arws alcohols, aldehydes and resms. Alloy C = 7 mpy
Formaldehyde Formaldehyde
275 122
135
plus lo-15 percent volatdes (ethanol. acrolem acetone) and 0 1 percent formic acid. 71.day test wdh agdatlon and no aeratmn plus 10 percent methanol and 0.01 percent formic acid. 2%day test wth moderate agitation and aeration Alloy C = 0 04 mpy plus 0 5-l 5 percent formaldehyde, resms. higher glycols Alloy C = 0 4
I
Formic Acid Formic Acid Formic Acid Farmlc Acid
2 l 300 14g - I E I - I - I mov l I

10 10 10 20 40 6o 85 150 150 150 150 214
101 G G
5o
E l-l-l
Immersed, 96 hrs
66 66
G G G E 1 G s 1
G E ; E E G --B 1
--11 --1 I Alloy C = 8.1 mpy Immersed. 96 hrs -Immersed. 96 hrs *plus one percent acetlc acid and one percent formic acid and I trace of acetaldehyde and CO,
FormvzAnd FormvzAcid Formic Acid Formic Acid Furfural Furfural &due
25 50 a4 88.90 25 100
1 I
BP. 217 230 217 BP 75
B.P 103
ii0 I
103 B.P 24
E S S
E --S ---
100
38
EI I
I -
I -
I plus 40 percent H,O. 3-4 percent H,SO,. traces acetic and formic actds
GaseousStream Gasolme
302
4 550% Oz. lo-12% P,OI, 3.15 0 H,O and (small
100
325
163 I
E 1 -
I -
I straight run. crude, etc
in lhquldand wpor phases. 630 A P I 105 pslg
EGSBU-
Less than 2 mpy (0 05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
e P - EtodmgPomt
(continued)
686
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
bntinued)
Cmmsin Mdia GlYCerhle

GlYOXd
Cmcmtntion. pmmt 100

30.35
rm acF 75 266 I 1301 60 G 1 w.C 24
HA6lEuOv. B/B-? E/ElI G E
alloy 6
316 6th ti Coeditioes
bP
C/C-276
I--Is1
-11 --1 1 -
1%formic acid: 2% glycohc acrd: 3% formaldehyde: 10% ethylene glycol. 505 hrs.. lab test, glyoxal strlppmg system plus 0.5 percent methanol, 0.5 to 2.0 percent formaldehyde. O-O.3 percent NH? ptl = 11. Alloy C = 0.02 mpy
Hexamme
25.30
140
Hexamme
:o 40 80
140 130 140
:: 54 60
; E E
Hexamme Hexane Vapor Hexone Herone Hydrobromrc Acrd Hydrocarbons. Short-cham Hydrochlorrc Acrd Hydrochlwrc Acrd Hydrochlorrc Acrd Hydrochlorrc Acrd Hydrochlorrc Acid Hydrochlorrc Acid Hydrochloru Acid Hydrochlortc Acrd Hydrochloric Acrd Hydrochloric Acid Hydrochloric Acid tfydrochlorrc Acrd
80
140
60
1 plus 0 1 percent formaldehyde, 0.1 percent NH? Alloy C = 0.3 mPy low bodmg vapor from tall 011 0.3 percent S02, 5 percent H,O. Alloy C plus CO.1mov HCNS of HF (Zr free), 2-5 days
I I 48 -
I 257I 125 - I E I - I - I I
I Room Room I Room Room
I I
E s
j I
E s
1 --
I 1-
12mofr/hter I
wdh 2 mols/hter HCNS. prod&on
B.P 90
8.P. 32
s
E
--E
I -
ethylene methane. acetylene. ethane. propylene. propane. some butane and hrgher h~~drocarbons: hydrogen. carbon monoxrde. carbon droxrde. hydrogen sulfide; oxygen. ndrogen, water, heabngod. moderate aerabon -plus ammonm
Ddute (1 <l 1
50.90
10.32
sulfate III enzyme bath Allov C (0 1 mov
1
I
O-150 320
21.66 160 27 aolllrll -
1 1 I
G
S
1 -1-I-i
E --
plus organrc acrd. phosphates. sulfur compounds in pepsm extraction

plus Fe& and other salts pH = 3.5-5. Alloy C = ml mpy
1 2M 2M 2 5 5 5
1 I Bolllnfl I
Room 140.176 150 150 200
a0
E E E G S B
(
1
8
G E E G S S u
1 ILI --U u --
1-I
Cl*. CO a CO?,22 days
1 U* 1 drssolved. Lab test contammg approximately 1 mol NH,CNS per hter production of Hf (2, free) U U* m ethanol. ethyl sdrcated reactor, 120 hrs. *drssolved. Lab test 120 hrs.. lab test aeratmn
Room 60.80 66 66 93
200
93
I -
1-
I ferric chlorrde. Iconc. not stated). consfderable wiltloo
Hydrochlorrc Acid
EGSBU-
Less than 2 mpy 10.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy ID.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
6.P - Bolllog Pomt M - Molar
(continued)
Nonferrous
Metals and Alloys
687
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued
ttydrochlonc
Acid
Hydrochloric Hydrochloric Hydrochloric Hydrochloric Hydrochloric Hydrochtorlc
Acld Acld Acld Ac!d Acid Acld -
35 36 40
160.170 Ambent 76 Room
71-77 Ambtent 25 Room
1 I
Amblent 60-212
Ambent 16.100
Hydrochloric
Aad 30%. sulfurx acid 10 to 40%. nltrtc acid 10 to 25%. sodturn hydroxide 1 to 40% sodwm carbonate. dlchlorobenrene 2 to 5%. pomalus acid and fumarlc acid less than 5% mono- and dlnltrobenzenes and arMme. trace.
I
Hydrochloric Acid
lo4
140
4o
60
Hydrochloric
Aud
140
60
Hydrochloric
Acid
226
108
Hydrochloric Hydrochloric
Acid Acid
662 800.1000
350 427.538
40 45 55 : All Hydroftuwc Hydrofluorlc Hydratluarlc Hydrofluonc Hydrafluonc Hydrofluarlc Hydrofluorlc Aud Acid Acid Acid Aud Ackd Acid 65 70 8 10 14
120 Room 75 110 90 to B P Room 140 115
49 Room 24 43 32 to BP Room 60 46
140 60.140
60 16.60
Hydrofluorlc E G S 8 U -
Acid
Room
Room BP Bolllng Point
Less than 2 mpy (0 05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy (0 25 mm/y) Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy (0 51 mm/y\ to 50 mpy I1 27 mm/y\ More than 50 mpy (127 mm/y)
(continued)
688
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
COilCMlCorrosive Hydrofluorlc Media Acid tntion. oerceot -
Temperature deg. F 140.165
HASTELLOP den. C 60.74 WE-2 _
alloy
1WC-276 1 G
G _
Stainless
Y*?
Conditions ~mpurmes aeration born wet process u
Steal
phosphow
Il.13% lluos~l~c~c plus undescrlbed sod

acad Llquld phase, extensive H,SO,, 100.0~
Hydrolluorlc (Anhydrous)
Acad
o-100 _ -
.I0 to 300
-23 to 149
Hydrolluorlc Acld Barnum Fluoride Hydrofluorlc Acad [Boron Trlfluonde Catalyst)
68 248 -6 68 176 248 .2l 20 1;: Bollmg 1 G B : s --_ _ --
HF (as BF, calalysl) hquld plus

plus bquld aromabc ethyl benzene) _ _
aromabc
hydrocarbons
hydrocarbons
(ortho-. para-. and melaxylene
plus
Hydrofluorlc Acid, Chemical oure
60
Boding
4 days, vapor phase purged wdh 1% oxygen.
rest nitrogen
Ambient Amblent Amblent 80
I---I I B
1-
1 - 130days
(except HNOI.HF) polymernbon of a proprietary orgamc man aromabc solvent wdh a BF, catalyst. HF & possibly fluoborales present Open to moisture and air. HF attacked glass m vapor area and glass has spalled from surface during 350 hrs. ol actual exposure. extenwe aerabon 40% H&O,, 209b H,O moderate aerabon
Hydrolluorlc MlXtUreS Hydrolluorlc Mixtures Hydrafluosdlclc Hydrolluosdw Hydrolfuosdxlc Hydrolluosdwx
Acid
40
I
Actd I Aad Acid Actd Acid I- mm-~Pim -
65 l8 .10 to 300
/(I I GI-IsI
I B I _
--E G
-23 14gI Ia
1 43 1
I G I concentration 1
B -
(except HNO,-HF) anhydrous 100 to 0% faded
hydrofluorlc
sod 0 to lOO$. suIfurIc
sod,
120
1 G 1 -
1spool
10-11
12-13 30
I60
160 100
71
71 38
_ S
lmpurdles lmpurltles
from wet process phosphaw from wet process phosphoric
acid acid
plus 22 percent hydrolluorlc acid producbon --
acld and 0.06 percent H,SO, in fhydrolluorlc
Hydrofluosdnc
Acid -
35
80
27
plus 4 7 percent NaCl solubon becomes saturated wdh Na,, SIF, Alloy C = 32 mpy
Hvdrolluosdw
Acld
I65 -
74 _
12.13%.
wdh
imounbes
lrom from
wet orocess wet process
ohosohorlc phosphoric
acid. acid.
some some
Hydrolluosdlclc
Aad
E _
10.11%. wth lmpurdtes suspended, aeratmn
Hydrofluoslllclc Fumes Hydrogen Hydrogen
Acld
55
I3
salt water (horn estuary), sdvxn tetrafluorlde. to 2
phosphow
acid, a~. pH I
100 Chloride
to 700
to 371 1
I
1
1
E 1
I
-1
I
1
I
95
1
I
200.800
93.426
1 I
1 HCI resulbng from the decomposdlon of all types 01 we cludmg polyvlnylchlorlde-cooling water spray
I
msulatmn.
in
Hydrogen
Chloride
0 to 50
-18 to IO
--
plus 3 percent acetyl chloride and 2 percent acebc acid vapors Alloy C = 76mpy
Hydrogen Hydrogen
Chloride Chlwde
P-r--~
100 -
800 I to I
289 572 75
to4271 143
s s*
l-l-l-l
E -plus anhydrous orgarwhlorosdanes lhquld and 15 mpy m vapor. plus causbc soda I plasbc synthesis. moisture m gases evolved, concentrabon atmosphere, considerable aerabon and am~nes. Alloy B = 1 6 mpy m E E --Alloy C = 0.01 mpy low but not speclfred lndustrlal
Hydrogen Hydrogen
Chloride, Chloride
Dry
300 24 -
Hydrcw
Chloride
110 43
E
_
I G
I--
IGl vapor
B
(almost all HCI) leed to fracbonator IS normally phosgene (COCI,) and 23.6% monochforobenzene
0 4% HCI 70%
Hydrogen Chlorade and other gases and vapors. umdenbfied Hydrogen Chloride and other gase, and vapors, umdenbfled E G S B U -
600
316
800
427
Less than 2 mpy (0 05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy 10.25 mm/y) Over 10 mpy (0 25 mm/y) to 20 mpy (0.51 mm/y] Over 20 mpy 10 51 mm/y) to 50 mpy (I 27 mm/y) More than 50 mpy (127 mm/y)
(continued)
Nonferrous
Metals and Alloys
689
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
,r-
h-rosin
Yadia
COnCOiltntion. pwnnt -
kmpntun dq. 800 F dw.C 427
HASlELLOr~ GIG-2 W-276 s
alloy G -
316 StainStnl u
loss
Conditions
Hydrogen Chloride and other gases and vapors. umdenbfled Hydrogen Chlonde and other gases and vapors, umdenbfled Hydrogen Cyanide, Hydrocyamc Acid Hydrogen Fluortde
1300
704
--
100
122 224 to 1000
50 107 to 537
s --
HCN strlppmg
still feed line and tads Ime. 372 days feed. 672 hrs tads
Hypochlorlte
Bleach
110-130
44.54
0.1 grams/ltter CaOCI. 1 5 grams/liter Alloy C = 0 1 mpy plus some Protem. fats, HCI. ammoma 0.04 mpy
C&I,.
pti = 7. extenwe
aeration
lnsul~n Extract
to 100
to 38
--
salts. H,SO, and NaCl Alloy C =
lodme Moe lodlne lodme YBPCM
All -
to B.P 572 a42 572 842 105-180
to B.P 300 450
E s /S E
s G --lJ E --_ E
--pressure of mdme 400 mm Hg pressure of lodIne 400 mm Hg -24 hrs 24 hrs E aeratmn
1 Iron Ore Slnter. Plant Flue Gas and Scrubbmg Llquorr Isopropyl Isopropyl Alcohol Chloride -
300 450 41.82
11 50
72 95
22 35
E _
plus 9 3 percent mdme. 2 percent non-~omc detergent 811 bubbled through solution lhquld PIUS 20 percent E isopropyl
Alloy C 0 I mpy
Alloy B = 9 0 mpy m vapor and 32 Ompy m
Isopropyl
Chloride -
80
95 83
35 28
G -
E E
alcohol
HCI bubbled
through
lbquld
Kraft Flbers. (Hardwood or Pme) at 1% Consistency La& Acid
pH 5-6. low concentration !de. moderate aeration
of chlorides
and sodium. trace chlorine dlox-
60.75
16.24
S _ G S Bolllng Pomt
--
plus 0 01 percent melhylene mpy
blue and possible Cu
+ tons Alloy C 0 1
Lactic Acid Lacbc Ac!d
10 17
Bolllng Bolhng
Ewmg Bolllng
G G 10% ammomum acid serwce chloride 0 4% N&I. 115 hrs. lab test. proposed lactic
Lacbc Acid E G S B U -
All 25.60
to BP 130
to B P 54 8 P -
--f
--
Less than 2 mpy (0 05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy IO 25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (127 mm/y) More than 50 mpy (127 mm/y)
(continued)
690
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
hpmtun Conorivr Lachc Acrd Lacbc Acrd Lactrc Acrd Lanol,n Bleach Yedia dw.F 1 Bohla I I B01hng Bolhng 210 dq. C W-2
HAsTELLOr~
llloy 1 G
50
85 90
BolllnaI
Bollmg Bolhng 99
G
G E
1 W-276 I c
E G E
I ---
Strl I G I orooosed
S
TYpr 316 StainIUS
Conditions lactrc acrd serwce. 115 hrs.. lab test
proposed lactic acrd serwce.
115 hrs, lab test H,O, and strong NaOCl
plus drlute H,SO&. HCI. alchollc caustic soIut,o.s. bleaches Alloy C = 0 141 mpy
Lead.B,smuth
Alloy
Eutecnc -
to 464 982.1000
240 526.537
S B :
-argon atmosphere Top-lead. chlorrde upper phase mrddle lead chlorrde. bottom lead
Lead. Lead Chlorrde
u -__
Levulm~c Acrd Lame Slurry and Caustrc Soda LImestone Slurry
95
80-110 184
d43
I I
I -
*5
I
1
I
1
E
E E
8 -
/
I
120 89 107
1 I
49 32 42
Lrmestone Slurry Lrmestone Slurry
/
I
/
j
I-Ii1 1 E / I E /
1 E j
added to argamc
polymer
contammg
excess sullur~c acrd
E E
/ C&O,
C&O,,
CaSO, and lly ash. pH 5 O-6 0. moderate I water. OH 63-79
aeration
/ 15% C&O,
15% solrds. CaCO plus CaSOl and a small amount of CaSOa pH 3 7-6 7 / avg 5.6, mode,a;e aerabon
irmestone
Slurry
Lrmestone Slurry
lZ7
254
53
123
/E
lE
/ scrubblne
flue gas contammg 2 Ibs /mm of SO, pH 3 5-6 3 avg 5 7 91 days hquor Ior SO, removal from oowe, slant lhquor for SO, removal aerahon lrqm power plant flue gas. 91 days
1 1 :
/ E / E 1moderate I--lEl
wually
scrubbmg
Lrqurd leavrng bottom ot Fractmnator Lrthlum Chloride
265
129
1 I--E
lree of HCI mostly phosgene
and monochlqrobenzene
30
260
127
I
Lrthrum Chlarlde Manganese Sulfate
bal H?O. 2000 hrs, L!Cl productron. shallow prnrng, 1 5 mds deep bal H,O. 2000 hrs. LrCl productron
one sample
out of lour showed
I 10 10 25 ::
90
300 60.145
149 16-63 -
/E
~
s E E :
! j/I _
1 _
I acrds
manganeseore leach,ng(anax,deandsull,de)
Alloy C = 0 1 mpy
plussullur~candsullurous
Magnewm Magnesrum
Carbonate Chlorrde
to B P 75 to B.P 175.BP to B P 273
to BP 24 to 8 P 79.B.P to B P 134
i ~
s
: E E
Magnesrum
Chlorrde
30-40
--E.-
wrth small amounts 01 MgSO,, NaCI. KCI. LICI. lraces of Br 3-48 salads 01 MgSO,. 1 25 H,O. extenwe aeration l? NaCl ll? KCI 2% tICI. vapor phase moderate 120 hrs aeratrqn and agltatron
Magnesrum
Chlorrde
51
330
166
GEE
--
Magnewm
Chlorrde c:i
330-335
166.168 E I-
Magnesrum Magnesrum
Chlorrde Chlorrde
53 55
345 345
174 174
E G
1 ~ 1
l hrs wrth MgCI: brine only 1% N&l I+ KCI. Zb* LrCl as cqncenlOO trated from natural Banrwlle brmes 01 33% solubles Llqurd phase exposure. moderate to considerable aeratran
vapor phase above wrth 8.000 10.000 ppm HCI tn condensate wdh 1% N&I. I% KCI. and 2% LrCl as concentrated Bonneville brmes of 33% solubles from natural
E E
I 1/_
_
_
Magnewm
Chloride
85 IOU
266 334 310
130 168 154 -
E E G /
_ -1 _
I open-pan evaporator Cancentrat,on expressed as MgCl> 6H.0 = 0 1 mpy 165 percent1 0 3 mpy (100 PercentI
Alloy C
Magnewm
Chlorrde
I
Magnewm Chloride 335.355 168.179 i E
j
_ _
in vapor phase - vapors over 508 MgCI, wth 500 to 4 000 ppm HCI ,n condensate and 1 000 ppm MgCI. In lhqurd phase - 50+ MgCl, saiubon plus IJn NaCl 1% KCI. 2% LICI Concentrat,on of natural Bonnev,lIe b,,ne lrom 33% solubles to 508 53,>magnewm chloride wrth I+ NaCl I, KCI and 2q LiCl as cqncen trated lrom natural Bonrwlle brmes of 33% solubles moderate to cansrderable aerahon absorptron seratlon lhqwd IO, SO. Generates brsulhte COOkl,,g ac,d w/pH of 5 4
Magnewm
Hydrqxrde
150
66
E G S E U
Less than 2 mpy (0.05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy 10 25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy (0 51 mm/y] to 50 mpy I1 27 mm/y) More than 50 moy (127 mm/y)
8 P -
Bolllng Pomt
(continued)
Nonferrous
Metals and Alloys
691
TABLE
5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
kontinued)
CDrrorive Magnewm Magnewm
Mwha
COWerItrrtion. percent 25 50 -
T*mpmtre dw. 120 to B.P 125.8 P 198 F dq. 49 to B.P. 52.B.P 92 C
HA.SYELLOY~ alloy 616-2 E E WC-276 E s s E G E --_
TYW 316 Stainless St.&l E
Conditions llue gas scrubbmg hquor lor SO? removal. 238 days, moderate aeratton
Oxide Slurry Sulfate
Magnesium Sulfate
E _ _
brme slurry contammg MgSO,, Na,SO,. 7.7. moderate to extenwe aerabon
KCI. N&I. MgCI,. trace of S-, pH
Malac Actd
10 10 100 lo-18
1 I
to 175 BP to B.P. 32.40

I
to 79 B.P. to B.P o-4

6
E : U
I
_ -
Male~c Ackd Liquor
E
I
-I I
plus small amounts of alpha naphtha 02mpy plus phthahc anhydrlde. 1090.hr trav of fracbanabn~ column
qwnone.
phthakc acid Alloy C =
Male~c AnhydrIde
400.545
204-285
--
test I vapor veloc#y of 7 ft /set
at top
Mercurtc Mercuric
Chloride Chloride Vawrs
10 _
I to175
620-750
to 80 326.398
s
E
l-l-l
-air-free mtrogen atmosphere. Mercuric chlortde IS present as 10 percent welghtpercentafvarylngamountsof acbvsted carbon Alloy C= 1 1 mpy -
Mercury
All 100 All -
to 800 to 700 to B.P Bodmg
to 426 to 371 to B.P Bodmg
T E
-1-j-1
Methanol Methanol
E _
N, atmosphere.
methanol
recovery column stock solutions sent to lab for
Methyl Acetate
/
Methyl Acetate
60
/ t0144 1
to B P
*
blBP
1
-
E / E --
1-
plus 20 percent ethyl acetate, 18 percent methyl ethyl ketone. 15 percent acetone. 6 percent acetaldehyde. 14 percent low boders trace acetic Iacid AlloyC=OOlmpy wth 10 percent acetaldehyde. traces of acetone and alcohols 5 percent H,O. 2 percent acetic acid,
Methyl Alcohol
60
165
74
plus 15 percent methyl acetate, 23 percent acetone. 0 03 percent acebc acld Sllaht [lltbn~ plus 4 Percent HCI, CH,CI bubbled through Vapor phase = 16mpy. lhqu!d =55 mpy
Methyl Alcohol
95
203 g5
Methyl Chlonde
100
95-113
35.45
1 1
G S E
1 )
1 E 1 E --E ---_
1 - j phase j E /
E
Methyl Chlortde Methyl Chlarlde Methyl Ethyl Ketone Methyl Ethyl Ketone Methyl lsopropanol Ketone Methylene Methylene Methylene Methylene Methylene Methylene Methylene Chloride Chloride Chloride Chlwde Chloride Chloride Chloride
95.113 100
35.45 38 99 32.38 110
contawng bubblmg
100 ppm hydrogen through
chlonde
and 30 ppm water
water, 2 0 mpy I vapor phase, 3 0 I lhquld phase
1
77 44
210 90.100 230
Alloy C ~0.1 mpy plus 15 percent acombc and 8 percent H,O. trace al TIC
plus percent phasphorlc acld. 3 percent dtamer. 1 percent vinyl ISOPrODl ketone. DerCent alcohols
22 5 40 50 70
100.250 to BP 140.200 120.140
38.121 toBP 60.93 49.60 -
--
plus 2.5 percent
methanol
Alloy C = 0 2 mpy
E E 1 G E E 1 E E E E
---
plus 50 percent plus 30 percent
methanol methanol. Alloy C = nil mpy aeration
I
-
75 90
275 100-212 180.250 195-225
135 38.100 82.121 91-107
1 G 1 B / HCI 20%.
E E E
H,O 5%. 27 days m vapor above solubon. moderate methanol Alloy C = ml mpy
plus 10 percent contammated
w/H,O.
aerabon phosphorus 76 days
Methyldlchlorophosphlne (Anhydrous)
CH,PCI, lower cancentrabons methorydlchlorophasphtne. trlchlonde. phosphorus orychlorlde. triethylphosphate. aeratmn - one. agltatlon - rapld aelatIOn
Methylenedlaxybenzene Reaction Mixture
221.248
105.120
E _
E _ -
_ _ 10 E G S B U Less than 2 mpy (0 2 mpy (0.05 mm/y) Over 10 mpy (025 Over 20 mpy (0 51 More than 50 mpy
Ambtent Ambtent 75
Amblent Amblent 24 BP -
_ Bo~lmg Pomt
E E S
contamng
Cl>, 166 days
trace Cl,. 195 days
05 mm/y) to 10 mpy (0 25 mm/y) mm/y) to 20 mpy (0 51 mm/y) mm/y) to 50 mpy (127 mm/y] (1.27 mm/y)
(continued)
692
Corrosion
Resistant
Materials
Handbook
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
TYP 316 Staintws SW S
(continued)
Corrosive Molybdlc Aad
Media
COnCOIltntion. QWCU,t -
T~mparatun dq. 300 F dq. 149 C B/B-Z S E
HASTELLOV C/C-276 B --E
alloy G s
Conditions formed by reaction of MC&. oxygen and 5% HNO, H,SOI ccmc goes to 20% Jacketed vessel allows heabwcaolml! Extenstve aeration sodium, potasswm, or ammonium
Mono Phosphates Monoethanalamlne Hydrochloride Monoethanalamlne Hydrochloride Monomer & Otmer fattyAcids from Tall 011 Purlflcatlon Morpholme Mlxture Morphollne Reaction Sulfate
10 30
to B P 150
to B P 65
--
m methanol, 1 -
72 hrs, lab test 72 hrs., lab test
I
_
204
95
1 N, atmosphere.
537.550
281.288
aelatIon
_ -
156 392 374 170
125 200 190 77
G B B -
6 u 6 E
--E E
88 hrs, lab test
141 hrs.. lab test. valves for morphohne
sulfate serwce
Mumc~pal Garbage lnclnerator flue Gas Mumc~pal Garbage lnclnerator Scrubbing t1quor Naphtha Naphtha. Solvent /
from secondary chamberafterpassmgthrough scrubber marble bed plus entraIned hquor at pH 3-4. extenwe aerabon
160
71
S E
/ E 1
j water drammg
from marble scrubbmg.bed plus direct spray of neutral H?O pH = 2 0.3.5 Municipal garbage lncmerator flue gas scrubbing, moderate agttatwn. extenwe aeration 51 days
100 96 /
75 160-180 180 110 392 180 j
24 71.02
--1 1 1 / in vapor space of still column product and HCI vapor I vapor phase Some mtrogen axldes powbly evolved
Naphthalene Naphthalent? Chloride
_ _ _
1 82 1
1 G / _ 1 s j organtc condensabon
productlon
43 200 82 C E
01 naphthalene
Naphthalene Acid
Sulfonlc
lormaldehyde. condensation product 01. Ca(OHl,. NaOH CaSO,. Na?SO, natural aeratwn through agltabon
650-750
343-m /
E I -
I -
from / indlstlllatetowerheavy IasphaltmpY vacuum Al,Oy ol contalmng c
crude 011 m flash sectlo ol
Nickel Chloride
80
25
200 554
93
l-l-1 nickel chloride leed tubes to converters unstressed spectmens nickel carbonyl. nickel hexammlne chlwde. in an Amlnco ammomum bomb, pH 3 4. carbonate. am
I 2go u I a I - I I /
Nickel Chloride
E G S B U
Less than 2 mpy (0 2 mpy 10 05 mm/y) Over 10 mpy 10 25 Over 20 mpy 10 51 More than 50 mpy
05 mm/y) lo IO mpy (0 25 mm/y) mm/y) to 20 mpy (0 51 mm/y) mm/y) to 50 mpy Ii 27 mm/y) (1 27 mm/y]
BP - Bolllng Pomt M - Molar
(continued)
693
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Nitric Acid Nttrx Ndc Ndc Nitw Acid Aud Acid Acid MM
63 65 65 72 25
120 150 Boding 177-163 177-183 365
49 66 Boding 81.84 81.84
E s U -
E B E E
G -
15% by wt. (20% by vol.) 40 Edor 120 hrs.. lab test 120 hrs.. lab test 6% H,SO, 25% phosphate rock, 24% H,W,.
2% sodum
dichromate
(dehydrate)
4% HISOl
Ndnc-Sultunc Acid Mixtures Nltc.Sulfuc Aud Mxtures I 1 /
I
365
la5 I la5
200 I
I
I
B I E I -
I B I
U I
20% by vol 01 50% HrSO, 50% HNO, added to H,O and heated to 200 deg. C lor 18 hrs the cooled and later dried at 170 deg. C I 10% C102
I
392 1
20% by vol of 50% H&O, HNO, added to Hz0 and heated to 200 I deg C for 18 hrs. the cooled and exposed I 16 5% NaOCl at 170 deg C by vol of 50% tf$O, 50% HNO, added to H,O and heated to 200 deg. C for-18 hrs then cooled and exposed I 20% by vol of 50% HNO,. 50% HCIO, added to H,O and heated to 200 deg. C for 12 hrs
.50%
El
B / Et--I--I
/ B / 20%
Nitrldmg
Gases
I
I
All 85 -
1000 212
1
I
538 1
lWI
Nltrobenzene
UIGI-l-l
plus chlora-beta methyl qunone. copper chloride, 5 percent HCI I stripp!g ltrobenzene from orgamc solubon Alloy C = 2 6 mpy
Ndrosyl Chloride I Natrous Oxide Nonylphenol
Room
RoomI
416 171
E G
E G
I E -
I - I alcohol,
E U
dung
productlo from reacbon Alloy C = 2.5 mpy
of HCI. ndrous
oalde, and tsopropyl
10 60.75
780 340
c~rro~~~ rack test (m plant). balance O,, H1O. N2 dlnonylphenol 0 6%, water 0.1% mu, nonyl and dmonylphenol rulflde 67.73% and process 01125%. hydrogen chloride a few percent (Corn. poslttons of hquld phases) contalnlngddutesulfurlc acid (pfi 1.8) and possibly somecarbon 90 days, moderate aerabon dfoxlde.
Od-Water Emulslo
75
24
S E
----1 1
Olelc Acid Oleum Oleum Oleum Oleum Oleum Oleum Orange Jwce Organic Chlorides Orthoformyl Benrenesulfontc Acid Oxakc Acid Oxakc Acid
100 20
to B.P. 125
to 6.P. 52
1.32 parts to one part dodecyl / 1 vaoors DIUS pwdlne pyrldlne
benzene and SO, of ovndme. of pyrldlne
I I
20 20 25 40 75.120
1 1 I
125.150 125.150 50.90
1 1
52.66 52.66 IO-32 to 60 30.120 38.52 to B.P. 29
1 1
-
vaoors m sulfonatlo
B 1 E E
I --
I - 1plus
and 2.5 percent water I sulfonabon manufacture. HNOl Alloy C = 0.1 mpy
I detergent
to140
86-248 100.125
1
-
El--I--I G E --
plus 4 percent
25 to 98% HNOI. trace HF wdh pecb lhquor
S E
All 6.75
to B.P. 85
--E E
10 20
BolkP 110
Bolllna
-to which II added 93% H,SO, (approx 10% when diluted). pH lesstha plus calcium oxalate and calwm sulfate, moderate aerabon 1.
I
Oxakc Acid I Oxahc Acid Oxakc Acid Oxahc Aud Sat,. Sol. All B.P. to B.P 140 45 140
43 6o B.P to B.P 60
-1-I
G S S
E I s s E --E
I E I modeiate
slurry
35% sulfuric aeration
acid.
calctum
oxalate.
calwm
sulfate.
pH 1.
slurry, 35% sulfwc moderate aeratlo
acid.
calcium
oxalate.
calcium
sulfate,
pfi
I,
Oxldlzlng
Gases
100 1.5M
to 1600 285 323
to 982 141 162
E G G
-E 6 cookmg Ihquors: acid sulfate. sodwm oxygenated sodwm hydroxide base; alkalme. Kraft aeraio
Paper, Acid Pulping Paper, Alkakne Pulpmg CookIng Liquor Paper MeachIng E G S B U Less than 2 mpy (0 2 mpy (0.05 mm/y) Over 10 mpy (025 Over 20 mpy (0.51 More than 50 mpy
pulp dlgester
liquor, esterwe
114
46
0 01% chlorme.
trace chlorme dloxlde
pH 5 5 to 6.0, moderate aeratlo
05 mm/y) to 10 mpy (0 25 mm/y) mm/y) to 20 mpy (0 51 mm/y) mm/y) to 50 mpy (127 mm/y) (1.27 mm/y]
6 P - Elolllng Pomt M - Molar
(continued)
694
Corrosion
Resistant
Materials
Handbook
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Paper Bleachmg Paper aleachmg Paper aleachmg Paper Pulp, Bleached Paper Pulp, Bleached Paper Pulp Slurry
I I
1 -
132 56 145 150 135.165
I - I E l-l EI
/ / E / / E I
atmosphere over a 1% slurry of paper pulp; 0 05 chlorme. trace chlorme dwde. pH 7 0. moderate aeration paper pulp 1% slurry, 0.01% chlorme. trace chlorme dloxlde. pH 5.2, moderate aerabon atmosphere over ( 1% slurry of paper pulp, 001% chlorme. trace chlorme dwde, pH 5.2 calcium chloride 0 3%. residual chlorme dmxlde 002%. pH 5 5 to 6 0, ex tenswe aerabon 5.5 to 6 0. 95 days. aerabon and @bon extenswe
1 1 1.5
63 66
I - I E I - I El I 57-74 I E l - / E l I 1
57.74 46 1 S 1 E E
/ I
135-165 114
1-
E E
1 1 5% CaCI. ptl
Chlorme - 01%. pH 5 5 to 6 0 Ourabon of test - 58 days Aerabon - moderate Agdabon - moderate Type of test - field Process mvolved - paper pulp bleachmg 0.15 g/l HCI. 0.02 g/l free chlorme Kraft pulp stock. pH 9 5.10. moderate aerabon. flow rate of 4500 g.p m 337.hr test sulfonatmn of peanut and corn 011
Paper Stock Pacer Stock Peanut 011 Pentane Pew Perchlone Acld Perchlaroethylene Carbon Tetrachlorlde Perchloryl Ffuorlde Phenol Phenol Phenol D&&mate Phenol Formaldehyde Phenol Formaldehyde -
75 155 to 125
24 68 to 52
E E ___ E -
---
I
I
72 -
1 70 I to150 I 75.212
I
1 I 1
I
21 to66 24.100 121 30 150.160 Z 193 100 129
1
1
I
G /
S /
1
j-j-1 j-1-1
I I
plus traces of HCI. moisture and air Alloy C = 0 8 mpy eXtraCtlooOf pepslo with one percent HCI and org.WWaCodS. 4 a-7 0 pH
G
E E ___
1--
I u I
HCI and Cl,, durabon of test - 47 days E 519 hrs.. lab test. tank placed m air cabmet plus 5 percent acetaphenone. mildly bolllog solution
250 86
95
302.320 125 125 380 212 265
i
E E G
E
_-_ E E
/ z / 1 I ewwd19 days mvapor

E E U E
chlorlnabon Process exposed 19 days I llquld phase phase
90
plus I1 percent phenol and 1 percent AICll sulfwc acid. phosphoric acid. Ikme. caustic. moderate aeration ~Durabon of test - 107 days Aerabon - present Agltatkm - present Type of test - held Process mvofved - phenokc resm Remarks - vapors present mtermdtently dung operabog cycle.
Phenol, Paraterbary Butyl Phenol Sulfomc Acid
500
260 /
I -
I -
plus formaldehyde turpenbne. boron trlfluorlde. and oxahc acid m kettle AlloyC=OZmpy
Phosgene Vapor Phosphow Acid Phosphoric Acid EGSBU-
0.5 3-14
122 60 150
50 16 66
E S -
E --E
984 hrs, lab test H,PO, catalyst plus orgamcs
--
small amounts of fluorme compounds
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y] to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
(continued)
Nonferrous
Metals and Alloys
695
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Phosphoruz Actd Phosphoru Phosphoric Phasphonc Acid Acid Acid
35 36 36 40
350 100.111 172 158
177 38.44 78 70
B G E E -
plus newsprmt 2 9 percent
m 3.4 hn. heatmg cycle some hydrofluosdwc aud
H2S0,. 350 ppm chloride.
2.9 percent H,SO,. 350 ppm chloride.
some HF, 30 percent gypsum
129% P,O,l. sulfuric acid 2.3%. slurrv contams 2.3% calcium sulfate blhydraie (gypsum). 0.5% fluorine &pounds as hydrofluosdlclc acid, metalhc compounds plus lo-20 percent HNO,, lo-20 percent ZnO, 10.20 percent Na,CIOI, 5 oercent NaSO.. Allov C = 0.4 mov
Phosphow
Acid
40.80
225
107
--
Phospharlc Phosphoric Phosphortc Phosphoric Phosphortc Phosphonc
Acid Acid Acid Acid Acid Acid
45 45
77.266
25.130
sulfuric
acid 45 percent.
water 10 percent Allov C = 7.9 mov
I 1 I
45 50.55 50 52.5
1 / 1 I
145.155 266 ZOO.300 230 113
/ I
1
63.68 130 93.149
1 I
1
U G
/ I 1
1
G 1 E
B -
1 -
1half
m vaoors. half Immersed. acid 45%. water 10%
IEi-1 / - 1 ] 1 G
sulfuric
vaoors contamma / I wet

/ 1mmened96~hrs.
Hf. Allov C = 24 mov
11101
45
-I
U U -
G lEIGl
G u G u --u E U u
H!PO, (P,O, eqwalent 35%). sulfunc aud 2.9%. chloride 400 ppm hvdrofluoslhclc sod trace. fernc phosphate trace, moderate aerabon plus 1.2 percent HISO,. 1.2 to 1.5 percent plus 1 percent Hf Alloy C = 5 mpy H2S0,.9F,. and HF
Phosphoric Phosphortc Phosphoric Phosphoric Phosphoric
Acid Acid Acid Aud Acid
53 54 54t 55 55
250 260 310.335 175.185 221.261
121 127 154-168 79.85 105.127
m fume hood of defluormator 14 percent. 4 3 percent calcwm
H,SO,. 48 hours exposure. sulfate. hvdrofluoslluc ackd
hot wall
sofne tluorldes.
(40% P,Or). sulfurtc acid 3 0% (2 5% SO,). talcum sulfate (hemlhydrate) slurry. fluorine compounds Llquld phase. gases contalnlng H,O and SF. are evolved Foam dlstrlbutlon process sulfurtc acid 3.0 percent (2.5 percent SOJ. calcium sulfate (hemihydrate slurry), fluorme compounds reaaent nrade DIUS 0.8% hvdrofluonc acid
Phosphoric
Acld
55
221.261
105.127
Phosphwc Phosphoric Phosphorx
Acld Acld Acid
55 55 55
228 228 237
109 109 114
B U
-G B U
0.8 percent
HF
(40% P,O,l. sulfuric acid 3.0% (2.5% SO,). calcwm sulfate (hemthydrate) slurry: fluorme compounds Llquld phase, gases contammg H,O and SIF, are evolved mdme. nowomc detergent (nonyl IIYCOI). and water Alloy C ~0.1 mpv
Phosphoric
Acid
562
72 22
I - I E l-l-l
G U E S B U
plus
phenyl
ether of polyethylene
Phosphoric
Ac!d
61
176
80
(44% P,OI). filtered. contammg hydrofluosdictc aud (50% P,O& hydrofluosdw
small concentrations
of sulfunc ac!d and
Phosphoric
Acid
69
81
27
sulfwc acid 3.4%. ctlwm sulfate 3.4%. acad. alummum compounds. pH about 18 small concentratmns
traces
Phosphoric
Acid
69
212
100
(50% P,OI). fdtered. contammg hvdrofluosdwc acld
of sulfuric acid and
E G S B IJ
Less than 2 mpy (0 2 mpy (0 05 mm/y) Over 10 mpy (0 25 Over 20 mpy (0 51 More than 50 mpy
05 mm/y) to 10 mpy (0 25 mm/y) mm/y) to 20 mpy 10 51 rm/y) mm/y) to 50 mpy (1 27 mm/y) (1 27 mm/y)
t -
percent
P,O5
(continued)
696
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
I
Corrosive Phosphortc Acid Media COOCmb tmtion. pwcmlt 70.100
I
lempwtun d*. F de6. C 93.100 HAslLLLw~ G/G-Z WC-276 E alloy G --
Tva ,r316 Stainstni
I
Conditlonr
191s
200-212
acid met (0 04. 35 grams 100% H,PO, per standard cubic footor 0 10 86 grams 100% HIPOl per cubic meter (STPII Chloride (20-30 ppm) in cdy water used I scrubber liquor. extensive aerlt~on G ptl below 1,140 ppm ASlO, IS lmpwty Furnace process to produce phosphoric acid Moderate aerabon. total days - 375 agdatlon - 590 fpm velocdy pH below 1.140 ppm As,Ol Impurdy. 30 days apptox.. _ _ 30 days 30 days 726.793 moderate aeration
Phosphanc
Acid
75
68.212
20-100
Phosphoric Phosphow Phosphoric Phosphoric Phosphoric Phosphoric Phosphoric Phosphoric
Acid Acid Acid Acbd Ac\d Acid And Acid
75 75 75 75
100 185 194 203
38 85 90 95
_ -
E E G
E -_ _
hrs, agltatlon hrs, @bon hrs hrs, agitabon
acid velocdy 895 ft/mln acid velocity acid velocity acid Yelow 895 ft /mln 895 ft /mm 895 ft /mm
appvx 726-793 approx 726-793

726-793
75 75 75
I j I
212 212 221 240.260
I I
I
100 I
100 105
I
1
G/--I--I
I 6 1 G -
130
days Apple,
aatatm -
164 hours 48 hours HF. 30 percent I immersed Ca (C&O, plus H,O plus S10,l. half I vapors. hall
75
16-lz7 88.102 74.05 100.115 98 80.110
E E G
Phosphoric Phosphoric Phosphortc Phosohorrc Phosphoric
Acid Acid Acid Actd Acid
82-87 85-95 85-95 86 87-90
190-215 165.185 212.239 208 176,230
lower oxides 01 phosphorous small amounts
present 1s mpr,bes
E B E
-_ s E
of lluor~ne compounds 01 fluorme compounds m mnt Alloy C = 21 mpy
small quanbbes immersed
96 hrs 102 days. trace NaCl and HCI erat~on moderate.
lurnace process agltatlon none
Phosphoric Phosphoric Phosporlc
Acid Acid Actd
87-90 93 93s
194 260 375.410
90 127 190.210
G u -
furnace process (63 to 65% P,O,). trace HCI and NaCl moderate swabon
vapor above phosphoric acid 93 58 167+ P,O,i. wet pwcess. contaNnIng about 4 3% sullur~c acid and 4 4% won and aluminum oxldes Fluoride IS oresent below 1 51. moderate aeratton / 171 percent P,OI) sulfurs acid 4-6 percent. iron and aluminum trioxides. lluorme compounds 0 5 1 0 percent 2 8-3 0 ss
Phosphoric
Acid
98
390.460
199.238
Phosphonc Phosphoric Phosphoric Phasphorlc Phosphorfc
Acid Acid Acid Acid Acid
I___
101 103 117 118 -
300 300 140
149 149 60
B E
1 G I _ _ ~ _
/ solids
1 17 percent.
0 4 percent lluor~ne reaction 1000 hl$ mol estewmol
H?PO, IS catalyst 10 polymenzabon acid = 0 1 85 percent 1 P,O,
I B E _ E E E G G I
_ _
485 60.650
251 16.343
S _
gases conta,mng HF SIF,. SO,. wth entrained HISO& 3 70 (3 0% SO,). ertenswe aelatIOn 75 105% bv wt Alloy Alloy Alloy Alloy C C C C = = = = 1 mpy 14 mpy 1 mpy 4 6 mpy aerabon. 126 davs
H,PO,
9gc- (7Z
P.0.)
Phosphoric
Acid 75
230 172 194 208 221 320
110 78 90 98 105 160
_ _ _ _ S
E _ -
Phosphoric Acid Commercial
Phosphoric Acid Dehydrated Phosphoric Acid Fumes 75
plus acrylic acid and betaproprlolactone ryiate umt some P.0, and HS
Alloy C = 5 mpy at top 01 dc
122
50
Phosphow
Acid Mtst
206
97
0 04. 35 grams lOOo H,PO, per standard cubic loot or 0 10 &grams 100* H,PO, per cubic meter (STPil Chlarlde 120 30 ppmi m city wster used I scrubber Ihquor. extensw aer&on (28. P&i. sullur~c acid 2, hydrottuoslllclc and hydrolluorlc trace amounts. total lluorlde eqwalent about 2 suspended 30 weight Llquld phase moderate aerdbon
Phosphorr
Acid M~rtures
39
170.183
77.84
01 suspensfon
dc,ds in gypsum
Phosphoric Acid Plcklmg Soiutlon E G S E U -
22
180-200
a2 93
lor remwng
scale lrom parts to be bondewed
Alloy C = 2 5 mpy
Less than 2 mpy 10 05 mm/y) 2 mpy (0 05 mm/y) to 10 mpy IO 25 mm/y) Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y) Over 20 mpy (0 51 mm/y) to 50 mpy I1 27 mm/y) More than 50 mpy (1 27 mm/y)
(continued)
697
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Corrosive
Media
COllCSlltrat1on. pment
hmpnturs dq. F de.C 54 m-2
HAslELLOr~ slloy
1X-276
G B
Conditions s~llcon tetralluorlde approx 0 31-O 44 lb /IO00 cu It carbon dmxtde approx 0 47-O 68 lb /IO00 cu ft P>Os equivalent 0 00033.0 00048 lb /IO0 cu ft Possibly very small amount H,PO, as spray. moderate aerat,on i dlgester dwng producbon 01 wet prpcess H,PO, Plus CaSO.. 40 percent H,O. 2 percent H,SO#. percent fluorme Alloy C = 7 9 mpy
Phospharlc Acid. Productton gases and vapors
130
Phosphor!c
Actd Slurry
20
170.200
77-93
--
Phpsphwc Acid and Sulfuw Acid IO 4%)
0.1
122.248
50-120
Ouratmn Aeratmn Agltatmn Type 01 Process Remarks Ourabon Aerabon Agltatlon Type of Process Remarks
al test - 64 days (56 m H,PO,. 8 m H,SOJ - 11, free - extenwe test - f,eld mvolved - syntheses 01 tertiary and secondary - unwashed 01 test - 43 days (25 I HIPO,. 18 I H,SOaI - a,, free - extenswe test - field mvolved - syntheses of tertiary and secondary - unwashed HNO, I acid Alloy C = 0 1 mpy
amylphenols
Phasphorlc Acid and Sulfuric Actd (0 3%)
01
122.347
50.175
amylphenols
/
Phosphcmc Ac,d. Wet Process Phosphoric Acid. wet Process Phosphoric Aod. wet Process 14 5 158 70 E _ 28 G
plus 0 381 percent
180.230
82.110
42 days. 20-22~ H&O*.
I I 5% fluoslllclc
acid. aera,,on
modrrate
28
180.230
82.110
/ 30t 185
/ lluos~l~r~c ac,d. moderate

2 percent f. 4 5 percent
P,OI 20+
rulfwc
acid 20.22% flurorlde aeration H,SOI ill0
about
1! 5~
probably
IS
WetProcess
Phosphoric
And.
a5
121
;G
hours exposure).
lhquld
Phosphoric Acid. wet Process Phosphoric Acid. Wet Process Phosphoric Acid. Wet Process Phosphartc Acid. wet Process
30t
250
2 percent F 4 5 percent
H:SOA 1110 hours exposurej
hot wall
30t
/ ~
185
85
2 4 percent F 3 percent HISO,. 1 2 percent ferrous oxldes sollds (96 hours exposure) lhquld 2 4 percent F. 3 percent H,SO*. 1 2 percent ferrous oxides solIds (96 hours exposure). hot wall
1 1 percent
30t
250
121
! 1 percent
350 ppm phosphate
36
104
40
I j
sulfuric acid 2 9% chlwde P,Oi eqwalent 260 hydrolluostluc and trace alummum phosphate trace few trace moderate aerabon
Phosphoric Ac,d. Wet Process
36
172
78
P>OI equwalent 26&o rulfurtc ac,d 2 9%. chloride 350 ppm hydrofluorlc acid. trace water Suspended matter calcium sullate dehydrate 30a. of SUSP~~S~O~ wght. calwm phosphate 0 lk moderate ae,at,on 2 percent HISO&. total fluorides 12 percent gypsum 30 percent
Phosphow Acid. wet Process Phasphow Acid. Wet Process Phosphortc Acid. wet Process Phosphoric Acid. Wet Process Phosphortc Acld. Wet Process Phosphoric Acid. Wet Process
I 3g I 170lE3
39 170.183 39 183 538 121.149
77-84
j E/
G
-I
U
77-84
a4
1 ! 1 ~
96 days. hquld phase. 2% H,SO,. Hf and H,S,F. trace aeratmn moderate agltatlon strong 28% P,O,. sulfurtc acid 2o. hydrofluosdw and hydrofluor,c Suspended gypsum 30h of suspenskw wetght. aeratmn evaporation of HPPO, plus 162-I 70 f. CaSO, m thickener Alloy C = 1 7 mpy H,POd (401 hydrofluoslluc P,OrJ. contalmng acid combined about
~
-
I Zc
49.65
-I
1 5-2 5 H,SO,.
2 percent
55
180
82
1
Go _ u U
fluanne.
talcum
sullate.
55
232
111
40% P,O, eqwlent. contammg 3b sulfuric acid and suspended calcwm sulfate. slurry Gases contammg water and fluonne compounds are evolved at the exoosure a,ea 2 percent H:SOd. 1 percent F 1 5 percent ferrous and a!ummum oercenl solids 148 hours exoosurel lhauld 2 percent HSO,. 1 percent F 5 percent ferrous and aluminum percent sohds (48 hours exposure). hot wall 2 percent H ,SO,. 1 percent F 1 5 percent ferrous and aluminum percent wilds 148 hours exposure). ho1 wall small amounts 01 Co. MgO Fe. AI.O>. SIO, Na 0 Cl No lluondesor present (4.3 how exposure). hot wall oxIdes. 4
Phosphoric Ac,d, wet Process Phosphoric And. wet Process Phosphoric Acid. wet Process Phasphorlc Ac!d. Wet Process
~ I
56t
190-230
I
56t 225.245
88-110 I
107-118
I _
I E
G
_
-I -
ondes. 4
56t
300
149
oxIdes. 4
56t 66t 66t 69
330 325 340 490 to 550
166 163 171
H.SO,
Phosphoric Acid. wet Process E G S B U Less than 2 mpy (0 2 mpy IO 05 mm/y) Over 10 mpv (0 25 Over 20 mpy 10 51 More than 50 mpy
hlghlv concentrated. t percent P,O\
aerated aud
69 P 0.. rtabc and agitated
05 mm/y) to 10 mpy (0 25 mm/y) mm/y) to 20 mpy 10 51 mm/y) mm/y) to 50 mpy (1 27 mm/y) (127 mm/y)
(continued)
698
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
30 40 E G S 8 U
to B P BP
to BP BP
- Lessthan2 "py 1005 mm/y, - 2 mpy IO05 mm/y) to IO rnr~y (025 mm/y) - Over IO mpy (025 mm/y) to20 mpy (051 mm/y) -Over 20 mpy (051 mm/y) to 50 mpy (127 mm/y1 - Mare than50 mpy (127 mm/y,
6 P - Bodmg POlfll
(continued)
Nonferrous
Metals and Alloys
699
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
durmg
manulature
of electrolytic
potarwm
hydroxide
Potaswm
Chloride
sodium chloride 1% a&c acid Ourat~on ot test - 93 days Aeratmn - extenswe Agatatlon - extensive
lmpwtles
M&O,.
CaSO,, MgCI,, 36 days
Potaswm
Ferrocyanlde
75
24
---
Potaswm Potasswm Potaswm Potaswm
Ferncyantde Hypochlwte Hypochlortte Hydroxide
30 IO 50 All 10 :: 40 50 60 90
75 200 to B P to BP IO il P to B P IO BP to El P BP to 125 203
24 93 to B.P to B P to 5.P to 8 P to B.P to E P BP to 52 95
s E _ S S : ; S _
I-_ E s s s S s 11 --E -I ~sopropanol and ~sopropanol solutmn of hexachlorpentadlene 0 09 mpy Alloy C = ----plus 50 percent NaOH. Alloy C = 0 03 mpy
Potassium
Hydroilde
20
E C S B U
Less than 2 mpy (0 2 mpy (0 05 mm/y) Over 10 mpy 10 25 Over 20 mpy 10 51 More than 50 mpy
8 P -
Bolllng Pomt
(continued)
700
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued
Potassium
Permanganate
25 50 75
75 75 75 15 to 125 140
24 24 24 24 to 52 60
_ -
E ; E s _ E
-II --catalyst for synthetic rubber productlo Alloy C = 0
Potasswm Potassium
Persulfate Sulfate
4 10 20 -
I mpy
s -
Potasswm
Sulfite
potasswm bsulftte. about 50% water. ptf 6 O-5 0. sulfur dlorlde gas, extensive aeratwl potassum potasswm potaswm blsulfk? blsulftte. bwlflte. about 50% water, ptf 5 9-l 2. moderate
I flue
Potassium Potassum Potaswm Potassium
Sulfite Sulfite Sulfite Sulfite
145 145 180 180
63 63 82 82
G u
E E E E
E E E G
aeration
about 50% water. ptf 6 0.7 2 about 50% water. pH 5 9.7 2 about 50% water. pH 6 O-7 0. sulfur dloxlde m flue
potassium b!sulflte, gas. aerabo potaswm potassium gas blsulflte,
Potaswm Potaswm
Sulfite Sulfde
180 230
82 110
S _
E E
E E
about 50% water. pH 6 0.7 2 m flue
b!sulfde. about 50% water. pH 6 5-5 0. sulfur dloxlde
Potaswm Potasstum
Sulfite Sulfite
270 280
132 138
G E
E E
potassum potaswm gas
bwlflte.
about 50% water, PH 6.8-5 5
blsulfde, about 50% water. pH 6 5 to 5 0. sulfur dmxlde m flue
Potaswm Propan Propanal
Sulfite
47 _
300 356 110
149 180 43 1 -
G E
-/ _ 1 -
E G
potaswm
blsulfite.
about 50% water. pH 6 8 to 5.5
3% formic acid. balance water. 24 hrs lab test plus free SO; and H,SOa. pH = 2 5-5 Alloy C = 0 1 mpy 1 plus 10.12percet butyrlcacld. 4.7 percent acebcacld Alloy C ~0 1 mpy
E E S
Prop~on~c Acid Proplonlc Acid
60-65 64
311 500
155 260
tl
if
35+ prop,on,c anhydrIde. feed 2000 cc per hour plus 2 5 percent butyrlc aud Alloy C = 0 7 mpy
1% mckel acetate, 7 hrs, lab test, conbnuous
Prop~onlc Acid
80
212.338
100.170
--
acid, 2 percent mtrlc acid. 0 1 percent acebc
Prop~on~c Acid
90
248.320
120-160
--
plus 4 percent butyrvz acid. mpy
I percent
nltrlc acid. scetlc ac!d Alloy C = 0 5
Prop~on~c Acid
94
85.356
30-180
1--
1 -
1plus 2 percent
dwng
butyrlc aud. 3 percent bollhng esters, 1 percent acebc acid mtrlc acid treatment Alloy C = 0 1 mpy acebc acid Alloy C = 0 07 mpy N.
Prop~on~c Aud Propuetary Compounds -
97
288 284
142 140
E E
plus 3 percent G
proprietary acid chlorides. toluol and VMP naphtha Also methanol 1.3% HCI durmg s cleanmg cycle, ~~~.ss~~nalf~ OMF also to clean proprietary ac!d chlorides. toluol and VMP naphtha Also methanol 1 3c0 HCI dwng a cleaning cycle, OCC~SIO~~~~ DtiF also to clean plus HCI to pH of 1 5 and some SD, mwng rn0 scetx anhydrlde aeratlo plus 5 percent N&I. 0 0 4%. acetlc dIgestIon
Proprietary
Compounds
329
165
G _
N.
Protel
Hydrolysate
100-115
38.46
tank Alloy C = D 6
2 Pthoxyethyl
Acetate
96
331
166
acid 0 2%, water unknown,
ertenswe
Pyrldlne
100.120
38.49
--
2 percent CH,CI,. 1 percent NaOH. and water Alloy C
Iw
from
Pyrldlne
50
80.100
27.38
--
plus traces of HCI CH,CI, and acetone I separatlon 01 pyrldlne water Alloy C 0 I mpy At 200 deg F. alloy C 0 I mpy plus IM ferric chloride. also il mixture 01 pyrldme. and lerrlc chloride. 6 to 48 hrs, lab test pyrldme
Pyndme
9M
572
300
--
hydrochloric
E G S tl U
Less than 2 mpy (0 2 mpy (0 05 mm/y) Over 10 mpy (0 25 Over 20 mpy 10 51 More than 50 mpy
I3 P - Elolllng Point M - Molar
(continued)
701
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Pyrogallic Acid Rayon
All
to B.P. 122.167
to B.P. 50.75 -
s E
-S rayon spin bath - 510% sulfuric acid: 1.6% zinc sulfate; 10.15% sodium sulfate. Free carbon birulfide present and saturated wlh hydrogen sulfide. Amines and ethylene oxide condensatmn produck present to 1%. rayon cascade bath - 1.15% sulfunc actd: 1.3%zincsulfate; 10.15% scdium Mate; free carbon blsulfide present and saturated wth hydrogen suifide. plus 0.1 percent sododlum chlorite, 0.03 percent sodwm carbonate, 0.1 percent synthetic detergent 0.035 percent lizOr. 0.07 percent acetic acid. Alloy C = 3 mpy 10 percent H,SO, phases. spinning bleach. hardening etc. Vapor and liqmd
Rayon
206
98
Rayon Bleach
210
99
--
Rayon Spin Bath
125
52
--
Rayon Spin Bath Rayon Spm Bath Rayon Spm Bath, Dilute Rayon Spm Bath. Spent Resm (Alkyd. Poly ester. Amine Types)
100.210 122 Room
36.99 50 Room -
G E G
----
extenrwe aeration.Alloy C = 4 mpy 11 percent HISO,. 24 percent SO,. saturated rtth H2S
in splash zone H,SO, 10 percent to less than 0.001 percent. From 0.500 ppm of CS, and H,S. Alloy C = 3 mpy H& = 0.25 percent Na,SG, = 0.25 percent m casbng machme. Alloy C = 0.1 mpy E sodwm hydrorlde cleanmg solubons (6% ba~lmg). Various raw materials mclude phthahc and malelc anhydrldes. tsopthabc acid. glycerol. pent. acrythntol; hnseed. soy, castor and tall 011s.vmyltoluene. propylene and ethylene and other glycols.
203
95
--
25
.4
Rosin and Rosin Oil Rubber
572 72
300 22
1 -
E E
1 --
I -
1in boiling
w&ion
at still bottom and m vapors. Alloy C = 0.1 mpy
elastomer dissolved in aliphabc solvent to rhlch bromine was added. pH 7.4, tested in absence of any light source, moderate aerahon. lab test, 500 hrs.. 14Wf.lG crackmg.
Rubodium
100
1400
15w 1600
Salicylic Acid Salt Water. Clean Scrubbed Botler Fluegas
ii: 671
; 9
XII ---
15OOTIGcrackmg. 1600f-no
crackmg
1 I I ~mduction of acid. pH varies from 12 to 2. Alloy c = 1.73 mpy
I
I
l
I
77.256
36
1 I
25.126
3
1
1
U G
1
I
E E
I--IEl E E 15% CO,. 3% O1. 400 ppm SOI. NOX and fly ash bemg scrubbed m slurry of 7% CaSOs. 2% CaSO,. ,596 MO. pH 5. Scrubbmg of SO2 and fly ash from power plant flue gas Aerabon - moderate Agltabon - 200.000 ACFM gas Total days - 158 limestone slurry. 1750 ppm SOI. 2.3% fly ash. 3% CaW,, 2.3% CaSG, plus CASO,. PH 6-6.4 2000.3000 ppm Cl. moderate aerabon 15% CO1. 3% 0,. less than 100 ppm S02. Llquld spray with some dissolved sohds present. pH 6-7 Scrubbmg of SO, and fly ash from power plant flue gas. Aerabon - moderate Ag!tabon - by gas flow Total days - 156 O-400 PPm S&. 10% water vapor, fly ash after limestone slurry scrub. bing, moderate aeration aeration for municipal refuse incinerator. Hot. acid chtorlde enwronment, range about l-6. extenwe aerabon pH
120
49
I
krubkd fluepar Boiler 120
I 49 E E E
Scrubbed Boiler Fluegas
Scrubbed Boiler Fluegas Scrubkr Scrubkr Effluent Gas Envuonment
T-r
190 -
a8
43.46
110.115
3w
I 14g - I E I EI EI I
I 204 I
49
Scrubber Environment Sfrubbmg Liquor Boikr Fluegas
4w
120
-I
-
EI-l
for mwwpal refuse incinerator. Hot acid chtorlde envwonment range about 1.6. extenswe aerabon
pH
4.4% CaSO,. 2.5% CaCO,. 0.5% fly ash. 0.1% CaSO,. pH 6-7. Scrubbmgof SO2 and fly ash from power plant flue gas Aeration - moderate Agitation - by gas flow Total days - 158 portable steam generator flue gases contammg SO?. NOX. N. CO, and 0,. Liquor alkatme ott field H,O wth 5000 ppm Cl, 21 days
Scrubbing Liquor E G S B U -
1%
66 B.P -
Boding Point
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy IO.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
(continued)
702
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Power Plant
Fluegas
E C S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mh/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 More than 50 mpy (1.27 mm/y]
mm/y) mm/y)
(continued)
703
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
NC
63
6 -iG G
colanon,
66177
aeratmn
HrS sparged Into crtrrc acrd N&O, plus absorbed SO, sotubo to put sullur. pH 4-5. Citrate process for sulfur dtoxrde removal (and sulfur
reCOVerYI
Scrubbrnp liquor, Power Plant fluegas
80
Aerabo - one Agitation - vrolent Total days - 91 Scrubbing Lrquor. Power Plant Fluegas 176 80
I
Scrubbing Lrquor. Power Plant fluegas
I
176 80
SO2 bemg absorbed m sofubon of crtrrc acrd. 80 g/l Na,COs; pH 4.0-5.0. Cltrated process for sulfur droxide removal (and sullur recovery) Aerabon - moderate Agdatro - by lrqurd flow Total davs - 91 recycled and makeup 190 g/l crtrrc acrd. 80 g/l Na,COI. pH 4-5. C&ate process for sulfur droxrde removal land sulfur recovery) Aeratro - none Agrtabon - agdated Total days - 91 SO2 1600-2000 ppm. 14% C02. 3% Or. exposed to lrquor spray at pH 10 contarnmg sohds. Scrubbmg SO? and fly ash from povrer plant flue gas. Aerabon - extensive Agdabo - 5.10 ft./see. Total days - 135.6 hydrochloric acrd. sulfuric acrd. sullurous acrd. hydrobromrc acid, orgamc solvents, some chlorinated, pH appmx. 1. moderate aerabon calcmm sulfite. &rum sulfate. calcium carbonate. fly ash. at1suspended as 10.15% fbv wt.1 slurrv. OH not specified flue gas containmg sulfur dioxrde. Entramed potassium rulfrte-beulfate solution, pH about 4.0. estenswe aeration
Swbbrng Lrquor. Power Plant Fluegas
240
116
IL
E E E E E E
E E
Scrubbmg Liquors Smoke and Fluegas Scrubbing Lrquors Smoke and Fluegas Scrubbmg Liquors Smoke and Fluegas Scrubbing Liquors Smoke and ftuegas -
70
21
117
47
130
54
135
57
flue gas scrubbmg liquor contaming ffy ash and drssolved chlorides. sulfur oxrdes. drogen oxtdes. carbon dioxide and carbon monoxrde. pH 4.5. extensrve aeration flue gas contarmng wetted fly ash. Scrubber liquor contammg rullurrc acrd 0.19%. hydrochlocu actd 0.057%. pH 2 to 5. extensrve aerabo
60
71
krubbrnn Liauors Smoke aid Fluegas Scrubbing Lrquors Smoke and Fluegas krubbmg Liquors Smoke and Fluegas Scrubbing Lrquors Smoke and Fluegas
I I 1 I
I I
164
73
170
77
175
79
I
175 79
=I=
-I
E
E c
ti
r
E E
water scrubber: pH 2.53: chloride 175 ppm. sulfate 75 ppm. moderate aerabon Hue gas from mcmerator. scrubbed
water from mcmerator scrubber. Chlorrdes 900-1000 pH 1.95.2.03. extensrve aerabon
ppm. rron 24 ppm.
-i
flue gas contamrng HrO. SO,. SOa. HCI. H2S and NaOH
flue gas conbmmg
H20, S02. SOs. HCI. HJ
and NaOH
I
93
93
-1
flue gas contarnmg H20. SO?. SO,. HCI. HP and NaOH
--IE
E
flue gas. water-scrubbed, from combusbo of munrcrpal reluse: nearly saturated wth water vapor. conrderable aeration S flue gas contaming sullur droxrde and sulfurtrroxrde. Canstderable liquid water and water vapor, DH 2.0 to 4.0. entramed. extenswe aerabon calcrum carbonate. calcium sulfate. calcrum sulfite. and fly ash alt suspended as about 20% (by wt.1 slurry. PH not specdied. moderate aerabon limestone slurry 15% CaCOa in water. pH 6.3-7.9
Scrubbrng Lrquors Smoke and Fluegas
280
138
I
27
32
34
38
4ILE E E
5% H2S0, scrobbmg sdotion for smatter gas containing 2.10% Or. less than 500 ppm sullur dioxide and 160 ppm chlorides. exhnsive aeratmn copper smelter gas and recycled cwbng spray water (pH as low as 1.7 average 2.5) 1.1.52 SOr I gas pius particulate and SO>. extenuve aeration
E G S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
(continued)
704
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
bntinued)
comom-
tntia.
prr#nt
TwDumn
&a F
105
tiA6lEUOV~ offoy
6/6-Z
-
StJo9%
Tt
caflditioml
copper smelting gas contmning .75-l% (25.100 ppml. extensive aerabo SO1 and some sulfuric acid mist
faloalvo Ydl
Scrubbing Liquors Sulfur Dioxtde Scrubbmg Liquors Sulfur Dioxide
dq. C
41
1 WC-276 1 6
E --
105
41
--
smefter gas in TCA scrubber and lhmestone slurry (15%. pfi 5.2.7) which is converted to CaSOl and some CaSO, by SO2 I the gas, extenwe aerabo lhmestone slurry 15% sohds. CaCO, plus CaSOl and a small amount of MO,. pfi 3.7-6.7. ave. 5.6, moderate aerabo calcium sulfite, calcmm sulfate, calcium carbonate. fly ash, all suspended as 30.50% (by wt.) slurry. pH not specified E calcium carbonate. calcium sulfate. calcwm sulLte. all suspended as 6. 11% (by wt.) slurry. ptl not speclfled. moderate aeratm flue gas contalnlng entraIned H1O and slurry (calcmm sulfate, calcwm sulfde. calcmm carbonate). moderate aetabo magnewm oxode slurry scrubbmg lkquor for SO, removal from power plant flue gas. moderate aerabo bader flue gas. 0.400 ppm SO,. 10% water vapor. fly ash after lkmestone slurry scrubbma. moderate aerabon E 6% limestone slurry. CaCOx. CaSO,. CaSO, and fly ash. pH 5.0-6.0. moderate aerabo boder flue gas and hmestone slurry. 1750 ppm SO,. 2.3% fly ash .3% CaCO,. 2.3% CaSOl plus CaSO,. pH 6~6.6.2000-3000 ppm CL moderate aeration sodtum sulfate scrubber hquor. Gas from 011 fued sodlum sulfate flash drymg system. Liquor contams dilute Na2S0,. H,SO,. pH 2.3. extenwe aerabo power plant flue gas scrubbmg lkquor 7% CaSO?. 2% CaSO,. 1% CaCOI. 1% chloride. pH 5.8-6.1 Gas I 2000.24W ppm SO, extenswe aerabo power plant flue gas scrubbmg kquor 7% CaSO,. 2% CaSO,. 1% CaCOI. 1% chloride. pH 5.8.6.1 Gas I 2000.2400 ppm SO2 extenwe aerahon scrubbed power plant flue gas conta~nmg 300.500 H20. extenwve aerabon ppm SO2 and 15%
Scrubbing Lwors Sulfur Dioxide Scrubbing bquors Sulfur Dioxide Scrubbing Liquors Sulfur Dioxide Scrubbmg Liquors Sulfur Dioxide Scrubbing Liquors Sulfur Dioxide Scrubbing Liquors Sulfur Dioxide Scrubbing Liquors Sulfur Dioxide Scrubbing Liquors Sulfur Dioxide
107
42
--
115
46
47
E
E
I-lEl
E
117
117
47
I - I I - I
-
120
120
I 4g - I E l-l-l I I 4g - I E I-lEl I
49 E 49 E E
120
120
Scrubbing Liquors Sulfur Dloxlde
120
49
Scrubbing Liquors Sulfur Dioxide Scrubbmg Lwors Sulfur Dloxlde krubbmg Llquots Sulfur Dloxlde Scrubbmg Ltquon Sulfur Dioxide Scrubbing Liquors
122
50
122
50
122
50
125
52
SO, gas scrubbing. 800 ppm SO?. 15% H,O. 12% CO?. 68% N,. 5% Oz. chlorides. 2000 porn fluotlde. some SO,. PH 3. moderate aerabon gas after lkmestone slurry scrubbmg contammg 0.1 of residual SO?. Effluent of absorber sechon of scrubber.
Sulfur lJoride
Scrubbmg Liquors Sulfur Dloxlde Scrubbmg Liquors Sulfur Dioxide Scrubbing Liquors Sulfur Dloxlde Scrubbang Llquots Sulfur Diomde 131 55 s B 135 57 E --
lb./ml.
SO2 scrubber gas. 5% SO,. 3% SOI. 7% 0,. balance N, saturated wdh H?O. Powble splashmg wdh wlubon contammg 1.3 g/l Cu. pH 6 copper smelbng gas after coohng m a H,O spray tower. Gascontalns H,O at 2.5 pH plus sulfurtc acid mist (25.100 ppml. extenwe aerahon scrubbed roaster gas; SO1 100-2000 ppm. H,SO, 100.1500 ppm. balance wet aw: heavy loadmg Hz0 droplets. contalmng Ca salts and ore dust
140
60
--
143
150
62
1 -
/ -
1 E / ae,at,on cobs. Gas 83%
wet venturi scrubbmg stream removmg fly ash horn holler burnmg corn N2, 360 ppm SO>. 80 ppm HISO,. Ash 6% Cl. extensw
Scrubbing Liquors Sulfur Dioxlde
I - I
I a I - I E l-l EI
66 B -71 --E E
scrubbng hquor for portable steam generator flue gases contamIng SO?. NOX. N. CO,. and 0,. Llauor alkahne 011 field H,O wth 5000 oom Cl. moderate a&abon wet flue gas after Hz0 spray. wubber slurry (CaSOI mamly. alsoCa(OH), or CaCOl plus CaSO,. pH 3.12) during upsets. scrubbmg hquor for portable steam generator flue gases contalnmg S02. NOX. N. CO,. and 0,. Liquor alkalme 011 held H,O wth 5000 ppm Cl, moderate aerabo dlmethylandlne contalnmg SO, steam and sulfur dloxlde
Scrubbing Lwors Sulfur Dioxide Scrubbing Lwors Sulfur Dloxlde
150
160
krubblng Liquors Sulfur DooxIde Scrubbing Liquors Sulfur Olorlde
167
75
--
176
80
SO7 scrubber gas. 5% SO?. 6.5% 0, and 88.5% N2 (dry basls) saturated wdh water vapor. eatenwe aeratton
E G S 6 U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/)] Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy Il.27 mm/y)
(continued)
705
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
concentnth. fhlldve rndl

Pm@nt
Trpnhn
acF
llA3nll6Y.
eoey
6
drcc
Vc2
C/C-276
Scrubbing Liquors Sulfur Dioxide Scrubbing Llquorr Sulfur Diorlde Scrubbed Power Plant Flueflas 370 108 E --
power plant flue ger xrubbmg. Cdrate roluhon phareof sulfur decanter. (Dilute and impure sodium cdrate) Hue get from e metallurgEel roaster. typlCal 02 grmr/cu. 1500 ppm. SD, 750 ppm. CD? .7% H,D l-3%, bal. a,r E conteinmg droplets of dbl. alkak scrubbmg kquor. aerabon
ft. dust, SD2
115.125
46-52
Aerabon Agdation -
moderate by gas flow
process black kquor Aeration - ertenwe Agdetion - 10.12 ft.&c. Scrubber Fluegas, lncmerabon of Sewage Sludge Scrubber Ltquor for Recovery bier Flueps
E C S 6 IJ -
Less then 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Dyer 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Dyer 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y] More then 50 mpy (1.27 mm/y)
i_LL
1 l&l
20.5g/l Na,CD,, 21.5 g/l NtHCD~. 3.1 g/l chlonde sokds. 15% traces Na2S~D3. Scrubbmg of recovery bode, flue gas ftrmg kraft process black
days -
67.0
(continued)
706
Corrosion Resistant Materials Handbook NICKEL-BASE ALLOYS-CABOT WROUGHT PRODUCTS (continued)
TABLE 5.18:
WM
WC-276 E
6 E
:z E
Conditions gas from or1 fired sodrum sulfate flash drymg steam ddule NarSO,, HrSO,. pH 2-3. extensrve aerabon Lrquor conlams
90% water saturated, downstream of scrubber and demrster pH 3-4. Mumcrpal garbage incmeratorflue gaascrubbmg: agdatron hrgh. aerahon extensrve; 51 days gas 10% CO>. 13% Or, Bal Nr IHI0 Satd). Fly ash carryover. pH below 0. Scrubbmg of SO, and fly ash from power plant flue gas. Aeration - extensive Agitabon - 5.10 IL/set. Total davr - 135.6
143
63
1plus fly
ash, aerahon
S -
defluormabon system. HF s&bon SO,. pH 3.0, 92 days
0.6% as F, 2000 ppm PIO,. 700 ppm
Scrubber Water Effluent
200
93
from prequench chamber of mumcrpal refuse rncrnerator scrubber about 1 hydrogen sulfide gas wdh mrst of de-aerated 5 months. flow rate 5 aom sea water
pH
Seawater Matures Sea Water Sea Water and Or& Fuel Exhaust Products Sebacrc Acrd
240 196 Ambrent
116 91 Ambrent
!-j-q-f
1 S 1 E
contammg chlorrdes. sodrum. sulfur, carbon
plus
small amounts of H,SO,. NarSO, and K,SO*
SeLwx
Acrd
10
90.220
32.104
plus 0.05-2 percent max. HrSO, balance. Alloy C = 0.4 may in sbll. Alloy C = 0.4 mpy
and traces of Na,SO,,
K,SO,.
H;O
Secondary Discharge Effluent Separate Water Solubons 55-104
I 3.40 I E I I3
29-35 E 116 E 38-71 E E
T
E E E E E E G E E E E E E E
municrpal garbage mcmerator flue gas from secondary chamber after passing through scrubber. marble bed plus entramed lkquor at pH 3-4. Agrtation moderate; aeration extenrrve. 51 days E mumcipal refusa incinerator flue gas effluent after HrO scrubbmg. Environment should be mainly steam wdh entramed rmpunbes. extensrve aeration municrpal refuse incmerator water quenched flue gas, acrd chlorrde en vironment. pH range about 1.6, extensrve aerahon 530% HCI. 10.40% HrSO,. 10.25% aeration and agdation moderate HNO,. 1.40% NaOH. 127 days,
Sewage
Gas
65.95
moisture laden gas from anaerobrc drgestron of packmg house waste. 63 percent COs. 36 percent CH, and 1 percent HrS. pH = 7 4 approx avg. comporrlion of brine: NH, 5 ppm. Cl 100 ppm. 8.0.0. moderate aerabon. pH 6.0 E aerabon 200 mg/l.
Sewage, Raw and Processed Sewage (Scrubbed) Sludge Incmerator Fluegas Sewage Sludge Incm erator fluegas Sewage Sludge Incinerator Fluegas Sewage Sludge Incrnerator Fluegas and Scrubburn Lrquor
240
100.160
66-72
19.22
sewage sludge mcrnerator flue gas berng scrubbed by once thru water plant effluent water, aeratron E E sewage sludge mcmerator flue gas bemg scrubbed by once thru water plant effluent water, aerahon
100-210
38.99
w,
Srhcon Tetrachloride Srkcon Tetrafluorrde E G S Et U -
150 & I - I E I
19W20
E E ---
I
7,,,.9,,0
6*-104 I :
371.46)
:
E E
E E
&
I I
G
sewage sludge incmerator flue gas bemg scrubbed by once thru water
in deacidification
of silica by rotary kdn. Alloy C = 0 04 mpy
100 -
140
60
I
113 45 Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) lo 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy Il.27 mm/y) More than 50 mpy (1.27 mm/y) B.P. Bodmg Pond
I
G
I
-
with dry HCI and Cl, bubbled through. In productron of hrgh punty srhca of pigment. Alloy C = 0.1 mpy acid spray of droplets containing phosphonc acrd. hydrolluosdw phosphate rock dust, water. acrd.
(continued)
707
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
cowoafva
Ye&
Coneenttetton. pwunt
Frnpntur c(yF 131 da9.G 55 VI-2 -
HAmlloY. c/c-m E
a9oy 6 -
316 St&az4 G CmMtiom acid spray containing hydrofluoricacid, acid phosphoric acid, hydroffuosdicic
Silicon Tetrafluoride
Silicon Tetrafluoride
1 I I I
10
10
1 I I I 1
167
1 I I I 1
75
1
I
1 s
I -
1 I -
1 B 1acid
I -
spray containing phosphoric sod 169% HsPO,. hydrofluosilicic acid, phmphate rock dust water
50%
Pro,).
Silicon Tetraiodide Silver Bromrde Silver Chforrde Silver Fines (wet, Grey)
285.300 75 75 212
140-149 24 24 100
I plus z percent free iodine under reflux half immersed
-1-I-I
I
1
I
1
s l-l-l
u 1 I I very dilute FeCI, bleaching powder and murabc acrd solubon. aerabon none, agdabon by boiling. Alloy C - 12 days
Silver Refnwrg
I - l 220 lo4 - l E I - I El I l
1 1 I 1 4s
acid leach slimes of silver refinery contammg Cu, Au. Ag. Se. le. Pt and Pd. moderate aeration
Sdver Refinmg
1 I I 1
220
1 I I 1
104
SW
1acid
Pd.
l sDeEimen
leach slimes of silver refinery contammg Cu. Au. Ag, Se. le. Pt and corroded WIW or was lost. aeration
Silver Salt Slurry $s;mCoagulatlng r
70
21 I 16 I
30-52 1
60
100.125
I I
/
E I - I E 1 E -I-I-1
1 E I possrbly mtrate. aqueous solubon: concentrabon unknown I E I 100 and hner. 2% HrSO,. saturated with SO,, pH 1.0-1.5 mesh 1 - 1strong NaCl solution plus dilute HrS.O,. rubber, soap and traces
steam, fatty acid, glycerol
of aux. diary solution. Rubber contains 30 percent carbon black pH = 3.5 avg. Alloy C = 0.17 mpy m cowersron tank
Soap Fat Sodium Acetate
465.480
240249
E 1
10
75
241
liter of sodrum hypochlorde.
il. No hypochlorites present. pH = 6.7.
E G S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy IO.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm&l Over 20 mpy (0.51 mm/y) to SO mpy (1.27 mm/y) More than 50 rnw (1.27 mm/y)
B.P. -
wing
Point
(continued)
708
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
gmll f&I,;
15-100 gm/l CaSO,; 0.2.
m chloride. sodium car.
E C S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) lo 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
(continued)
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Sodium Chloride me punficabon - salt productlon rabon - 1.5 ppm 0, dabon - 6 ft./set.
Sodium Chloride Sodium Chlonde
Sodium Chloride
Sodium Chloride Sodium Chlorde Sadlum Dialkyl Orthocarbonate Sodium hrncyamde Sodium flormaldehyde sulfolylate Liquor S&urn Fluonde preconcentrator. Alloy C = 0.006 mpy
Sodium fluo5dicate Dust godly Fluosdicate
Sodium Clutamata. Sodium Glutamate. Sodium Hydrosulfide
Mono Mono
Sodium Hydrorlde Pulp Dugester Liguor Sodium Hydromde Sodium Hydroxide
Mum
Hydroslde Durabon Aerabon Agdabon Type of test 150 days moderate normal flow - held
Sodium Hydroxide
Sodium Hydroxide
15
to230
to 110
--
Plus monochlortoluene saturated wdh approx. 2 percent each of HCI and Cl?. Alloy C = 23 mpy 10 to 15% NaOH. NaCl and NarCO1. HCI. COCI,. moderate aeratton plus cresylu aad. Alloy C = 0.5 mpy E dilute, chromate and chromu wastes. chlorides. all low concentrabons Dakms solubon. Alloy C = 0.1 mpy
Sodium Hydroxide Sodium Hydroxide Sodium Hydroxide Sodwm Hypochlorde 0.5 0.5 Sodium Hypwhlorde Sodium Hypochlorite Sodium HypochlOrite Sodmm Hypochlorite I Sodium Hypochlorite E G S B U 15 1 1.2 5
90 100 160 1:: 212 140 70 65 1:: 66
32 38 71 ;: 100 60 21 16 :: 30 M Molar
1 -
s E E : E G E E : E
--:I ---11 -E
Alloy C = 4.0 mpy plus umdenbfmd components. pH near 7 mpy
bottom of bleach makup
tank. Alloy C ,O.l
,,
plus 3 percent caustic soda. Alloy C 6amed iwght
shghtly
Less than 2 mpy (0.05 Imm /VI 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm, Y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm. /Y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.2 7n Im/y)
(continued)
710
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
ent sodurn
hydride.
and 0.1 percent
sodurn
oleate
Alloy C = 0.2
E G S B Ll
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy IO.51 mm/y) to 50 mpy (1.27 mm/y) Mare than 50 mpy (1.27 mm/y)
B.P. -
Bodmg POW
(continued)
711
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Sulfated Detergent E C S B U -
125
52 B.P. -
Less than 2 rnIpy ID.05 mm/y) 2 mpy ID.05 mm/y) to ID mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy 11.27 mm/y)
Boding Pomt
(continued)
712
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
bontinued
COllC0II-
ConosiwIMa
Sulfated 011s Of Fats
tntion. prrcrnt
Tampontun
HA3lELLOV~ alloy w-2 E G WC-276 --E 0
316 sttin3; 5 percent E Condiiionr H>SO,. NaCl and Na$O,
TYw
W.F
125
de8. C
52 21
Sulfonabon and 011s
70
sulfonatmns of castor, soya, sperm and red 011s. mmeral or1 and various other fatty acrds. fats and 011swdh 96 Baume H&O,. pH 1-4. Moderate aerabon, agdabon - 84 rpm turbme. sulfurrc acrd 98%. ammoma anhydrous. maldehyde, moderate aerabon sulfuric acrd 98%. ammoma anhydrous. maldehvde. moderate aershon or sodrum hydrorrde 33%. for-
Suffonatlon
98
248
120
Sulfonabon
Reacttons
176.320
80-160
--
or sodturn hydroxrde
33%. for-
Sulfonatlon Sulfonabon Sulfonabon Sulfonatlon
Acrd (Spent) Acrd (Spent) Aced (Spent) Acid (Spent)
272 341 392 392
133 172 200 200
G B G G
G G E G
U B E S
111 days
below lkawd level
8 days below hquld level 10 days below lkqurd level start - 25% pet. SO,. 6% HFSO3. 3% I?, 3% HI. 63% H,SO,. End HFSO,. 4% 12, 3% HIO, and 87% H$O,. 56.5 days 28 days below hqurd level plus 45 percent solvent naphtha, bonom of sbll 5 percent water and trace of H,SO, at 6%
Sulfonatlon Sulforuc
Acrd (Spent)
50 -
482 60.250
250 16.121
G -_-
Acrd
Sulfur
74.284
23.140
--
plus some HISO,. H2S. SO,. H2SOI and water vapor m melbngtank. ple half I vapor. half I kqwd. Alloy C = 0.52 mpy plus selenium. 11.7 day test, 7.8daysof 5.1 mpy (vapor) I
Sam-
Sulfur -
850
454
--
borlmg. Alloy C = 2.8 mpy (kqwd)
Sulfur.
Molten
775 300.315 284.302 265.295
412 149.157 140.150 129.146
:*
l aerated water at pH of 1.5 to 3.5.ll.day test permd m surface pope vlus hoe between well and gathermg stabon. Alloy C = 0 9 mpy. 6.day test perrod agrtated. plus au and unpurdresmcludmgsulfurlcac~d. and ferrrc sulfate. Tested up to 12 days
balance H,O. Alloy C = 0.19 mpy m sea water plus 1.7 percent N&I. Alloy C
q
Sulfur OroxIde Sulfur Ororrde Sulfur OroxIde
0.077
220
104
1 G 1
E E E
-1-1-I --
1.8 3.6
55 106.118
13 41.48
0.6 rnpy
about one.half saturated wth spray water I scrubber tower. Alloy C = 0.2 wy plus selemous acrd mrst and some sulfunc Alloy C = 0 9 mpy plus 3.4 percent calcium bwlfde oltw acrd m shmes bodmg kettle
Sulfur Droxrde
4-5
185.200
85-93
--
Sulfur Drorrde
4.7-5.0 (by volume) 5
70
21
--
m sulfde acrd senlmgtank
Alloy C = 0 1
Sulfur Droxrde
200-500
93.260
--
plus 15 percent O?. balance N, (dew pomt 125 percent) wet wmdboa. Allov C = 0.8 mov
In gas ofnake
Sulfur Drorrde Sulfur Droxrde
5 10
400 85-95 125-135
204 29.35 52.57
U U
G
;
I 11
I -
mckel I an
convertor.
Alloy C = 2.6 mpy
saturated wth water m bonom of scrubber Recycle lkquor contammg H,SO, m range of 0.30.0.75 percent. Alloy C = 0.1 mpy (90F). 3 mpy (130F) @US 3 percent 0,. trace SO, and mofisture. Allov C = 0.1 row for alkylabon untt Alloy C = 0 03
Sulfur Sulfur
OroxIde Dtorrde
18
500.700 60
260.371 16
E E
---
plus S,O, m compressor condensate mpy wth less than 1.0 mrl pdtmg. E E gas up to 1.5% SO? aerahon
Sullur
Dloarde
115.170 125
46.77 52
G -
E E
Sulfur Dlorlde
1000 ppm chlorrde. 2000 ppm fluorrde. some SO, and pH 3. 800 ppm SO,. 15ia H,O. 120 CO,. 68% N?. 5% O?. moderate aeration in gas stream wth spray from coolma tower contammn H,SO,. aeratron
Sulfur
Drorrde 1 1
130 131
54
Sulfur Ororrde
55
1 u*
U -
1 s
E G
/ E
/ 8
E E
specimen corroded away or was lost. aerabon. 5% SO,. 3% SO,, 7% 0,. balance N, saturated wdh water Possrble splashmg wdh solubon con. tammg 1.3 g/l Cu. pH 6 m flue gas from No 6 fuel 011. shale dust. water SO, lW-2000 H.0 droolets. ppm. HISO, 100-500 ppm. balance wet au. heavy loadmg contamma Ca salts and ore dust H,SO,. aerabon
Sulfur Otorrde Sulfur OroxIde
132 140
56 60
Sulfur E G S B U -
Dlorrde Less than 2 mpy (0 2 mpy 10.05 mm/y) Over 10 mpy (0.25 Over 20 mpy (0.51 More than 50 mpy
140
60
m gas stream wth spray from coolmg tower contammg
05 mm/y) to 10 mpy (0.25 mm/y) mm/y) to 20 mpy (0.51 mm/y) mm/y) to 50 mpy (1.27 mm/y) (I 27 mm/y)
713
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
bv@
(continued)
Cofrosiw redii
Sulfur Dioxide
ColKmtmtion. m
TIlaDmtum WF
145
HA6lEuOv~ all07 drcC

63
316 6th &

6
W-2
-
1 C/C-276 1 6
E G
conditions
burmng coal wth 3% S plus 940 ppm Cl, 19 days. fleld test, moderate aerabon. vmlent agdabon and MgD (scrubbmg produckofcombustionfrom aeration MgDrecoverysystem).
Sulfur Dloxlde
160
71
Sulfur Dloxldt
176
ED
tJ*
*specimen corroded away or was lost. extenwe aerabon. 5% SD?. 6.5% 0, and 88.5% N, Idw baslsl saturated wth water vaoor. swclmen corroded away or was lost extenwe aeratton. 5% SO?. 6.5% O2 and 88.5% N2 (dry baas) saturated wth water vapor. in hydrocarbon alkylate plus sulfut~c acid Alloy C = 0.01 mpy elemental sulfur mist Oz. H,O and traces of sulfuru acid. In preclpdator for recovery of sulfur from pyrde gas. Alloy C = 5.0 mpy
Sulfur DooxIde -
176
80
U*
Sulfur Dloxlde Sulfur Dtioxlde
230 300.350
110 148.177
G G
E G
---
Sulfur Dioxide. Moist Sulfur Oxldes (Oi 6 Tril Sulfur substltutad Amylphcnol Sulfur Trloxlde
1 1
1 1
180 350 257
1 1
82 177 125
1 1 G
1 1
I
E E G
I
I
I
I
I occasIonat SPfaShlngof Na,SO,

I
and H,SO+ Alloy C = 0.15 mpy
1 8
1 E
U
ISD,
16.2%. SD, 1.8%. Hz0 2.0%. 0, 1.4%. moderate aeratmn and
HCI (pfi-21. unreacted chlorme amyl-phenol. sulfur monochlorlde sulfur dioxide m trace quantities. extensive aeration
100
38
--
PIUS SOP. N,. CO, at top of Jennson towers m exhaust gas. Alloy C = 0.1 mpy PIUS O-5 percent Na,SO,. 0.0.5 percent ZnSD,. O-D.2 percent CSI. trace of H2S. Alloy C = 1.0 mpy hot sulfuric acld solubon (pH 3.0) contammg tungsten and molybdenum salts wth 2-3 g/l fluorides. moderate aeration plus 0.04 percent SD1 and varying amounts of carbon on bottom tray of SD? scrubber in tegenerabon of alkylabon acid. Alloy C = 0.8 mpy E hydrochloric acid 0.057%. pH 2 to 5.2360 waste hn.. mcmeratlon of muonpal
Sulfuric Acid
o-3
200
93
--
Sulfuric Acld
0.4
140
I w 1-l
73.81 U 60 Room -
E I-ICI
E -E E --
Sulfuric kid
0.1
164177
Sutfurlc
kid
0.19
140
Sulfuric k#d
0.26
Room
spent pukle s&tions. Cold wash water wth salts puked up m steel pck. ling (0.097 percent ferrous. 0.003 percent few) Alloy C = 0.05 mpy plus copper sulfate to saturation. Alloy C = 0.6 mpy plus vegetable, fats, greases. Alloy C = ml mpy 1
I
Sulfuric Acld Sullur~c kid Sulfunc Acld Sulfuric kid Sulfwc kid
0.4-8.0 l-5
170.220 220
77.104 104
1
I
E E 1
/
--1
I
1
I
lto23 2 2.5 2.8.9.3
1 1
302 118.126 200.250 83
1 1
I
150 48.52 93.121 28
E S
6 _ G E
) as scrubbmg liquid. moderate aerabon

t
1-1-1 -E
max. pdting = 14 mpy. Saturated wth NaCl plus 0.1 percent copper sulfate and some alcohols. Alloy C = 8.2 mpy alummum sulfate 0.8&3%. moderate aeration plus 20 oz. Na&rlO, potasswm chromium sulfate O-O 3%. water.
Sulfuric Acid
Sutfunc Acid Sulfuric kid Sulfunc kid Sulfunc Acid Sulfuru kid Sulfuric Acid Sulfuric Acld Sullur~c kid Sulfuric Acnd
5 5 5 5 5 5 5 5-15 5 to 150 g/1
70.85 90 90 122 137.153 175.185 180 113-131 160
21.29 32 32 50 58.67 80.85 82 45.55 71 -
E S
E --E E E E E E E
--
per 18 gal. Alloy C = 0.07 mpy
plus FeSD, and 0.05 percent li02 IO.008 percent vahds) -E ---E S E 3.4% zwconyl sulfate, 15 days plus sulfate 011s. traca of NaCl and Na,SO,. Alloy C = 0.3 mpy
G U S
aeration. lab test 29.5 days plus 0.50 to 0.56 oz./gal. of copper. Alloy C = 1.9 mpy plus ore contammg MnO and MnO, 1.5 percent orgamc salts. Alloy C = 0.16 mpy
plus 15.25 percent Na,SD,.
copparto 60 gilwe. 40. sdver 0 to 12 gILtye. 3.5. Sokds consfist of precious metals, sdlca. lead sulfate. and a few 0 or less of selemum. tellurium. anew antimony and bismuth plus 0.35 oz/gal. NaNO,. Alloy C = 34 mpy plus 0.8-0.9 oz./gal LND, m plckkng tank. Alloy C = 2.1 mpy
Sulfwc
kid
6-9 7.8 7.5-E
155.175 155.165 200.210
68-79 68.74 93.99
6 G E
---
Sulfuric Acid Sullwc kid
plus 3 percent alummum sulfate. 1 percent lerru sullate pfus traces of calcium and magnewm sulfates. Alloy C = 1.6 mpy steel ouklina tank. Allav C = 4.7 mov
Sulfuru Acld E G S B U -
120.140
49-60
--
less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
(continued)
714
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
TYpr
(continued)
concontrotion. Corrosive Sullurlc ACld Modio wow 9 dep. 80.120
Tompontoro F do6. 27.49 C B/B-Z U
HA6lELLOV~ alloy WC-276 E G --
316 Stoinloss Stool
Conditions plus I percent HF. 3 percent Na,SO,. 1 Na&Fi. balance water I separabon I percent of Na,W, $0,. ZH,OT. 0 5 percent Alloy C = 2 mpy
Sulfuric Sulfuric Sulfwc Sullwc
Acid Acid Acid Acid
10 10 10 10
175-180 200 Bodmg 225
80-82 93
U I I
s S
I
E -S
I
3% 672
chromic hrs. hrs.
acid
in dewwed
water
Bodmg 107
/ 120
I
lab test ,mpr,t,es. 240 hrs
nickel sulfide
Sullur~c Sultunc
Acid Acld
15 16
238.266 165
115.130 74
S U
B
s
I-I
-
1dlcyclopentadlend
hydrate
reactlon ferrous 3591
220
hrs,
pilot plant
0 09.ior~g~nal) to 0 54,:
to 5% (flnal before dlscardmgl. (fInall InhIbIted wdh Acbvol
sulfate
Sullur~c
Acid
18
170-180
77.82
--
I plckllng staInless fad wdh 3 Percent HCI added Flrsf pIckle,sfollowed by 15 ml I 10 percent cold HNO, Alloy C = I mpy -
Sullwc
And
I
19.28
I
140
/
60
I
E
I I
, Alloy
I
,
PIUS 1 6 10 4 8 Percent cOPPer sulfate C = I6 mpy separation sulfate. ferrous sulfate.
IOr flash
plckllng
of brass
PBnS
Sulfuric Sulfurtc
Acid Actid
20 20
Room
Temp.
Room
Temp
I
E B
1
I
E s
I I
1I
1Zr-HF
59.194
15-90
--
plus cobalt mpv
traces of copper
sulfate
Alloy
C = 12
7000 oz./ton AK. 200 oz /ton Au. 0 5. Sb. 0 5-. Co. Trace AK. Au. Sb. Co 90 days
10.12
brasw
anode
mud
lrom
electrolybc
plus 9 6 percent
ferrous
sulfate
12 percent
11 as sulfate
Wax
pitting
=3
E C S B U
Less than 2 mov IO.05 mm/v1 2 IIIPY IO.05 &I&) to 10 mf& (0.25 mm/y] Over 10 mpy IO 25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy IO 51 mm/y) to 50 mpy (I 27 mm/y) More than 50 mpy (I 27 mm/y]
(continued)
715
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Sulfuric krd Sulfuric Acrd Sulfurrc krd
25 25 2540
150 8oihng 158
66 Boiling 70
E 8 lJ
E G --
I -
I 120
hrs.. lab test
340 g/l sodium sulfate 10.15% phosphorrc acrd. 0.5% fluonda. agitation and aeration - hrgh phosphate ferbluer plant.
Sulfurrc Acrd Sulfurrc krd Sulfurrc Acrd
28
135.5
57.5
G 1 G 1
G G 1
G 1
hydrofluonc acrd 5.9% 1 tests for selection of material for an acetic acid recovery column for an acetatdehyde unit, 23 hrs. sulfur dioxrde purge
28
267
131
100 150 8oding 200
;rz i?o;;g 52.57 88.99
: G G 8
G u : E E
u ; ---
1 acrd regenerabon of resin. Alloy C = 0.8 mpy plus 22 percent HsPO, rn ran exchanger. Alby C
q
Sulfurrc Acrd Sulfurrc Acrd Sulfurrc Acrd
125.135 190.210
0.3 mpy
cetic acid, 12.3 percentHr0
at liquid-vapor utterface.
Sulfurrc krd Sulfunc Acrd Sulfuric krd Sulfurrc Acrd Sulfurrc Acid Sulfurrc Acrd Sulfurrc Acrd
4045 40 40 40 40 41.63 43 : 85
Room 176 176 176-194
Room 80 80 8090 125 20.95 Ambient Ambrent Ambient Ambient Ambient 1
S G U 1
E u U s U 8 ;
-G G -U
saturated wrth Clr. Alloy C = 1.6 mpy 28 day rmmersion test (plant) and various organrcs. acetate fiber productron. held test Zr-HF separabon 28 days
257 68.203 Ambrent Ambient Ambrent Ambrent Ambrent Boding
) -11
1-
120%
ethanol, 1% ethyl ether, balance watar. 432 hrs. lab test
plus propylene. Alloy C = 24 mpy saturated wrth Cl,. 8 day test
Sulfurrc Acrd Sulfurrc Acrd
45 45
Clr. 113 days
1 &ling 1 Sulfurrc Acrd Sulfurrc Acrd Sulfurrc kid Sulfurrc Acrd Sulfurrc Acrd 50 Ambient Ambient Ambient Ambrent -
1 E
G
1I-j-1 -
1U
plus 1% CP hydrofluorrc acrd: also 45% CP sulfunc acrd bath wrth ndrogen purge, 4 days
Clr. 3 days. lab test 40 days
I 1
50 50 50 50
I I
Ambiint Ambrent 70 70
1 I
E G E E* E**
saturated wdh Nr. 3 days, lab test
21
21
U* -
I -
1_
1109 days,
saturated **welded Ourabon Agdabon
saturated wrth CI,. welded
and annealed
wdh Clr. *as-welded and annealed of test - 132 days - 4.1 ft./see.
Sulfurrc Acrd Sulfurrc krd Sulfuru Acrd
50
77
25
--
saturated wdh chlorme. lab test
1 I I I
50
50
1 I I 1
80 122 158 Ambient
1 I I I
27 50 70 Ambrent
1 I -
1 I
1I-I-1
I-
1welded
sample m acrd saturated rith chbrine.
Alloy C = 0.6 mpy
E
E E
saturated wth chlorine, lab test
Sulfuric krd Sulfurrc Acrd E G S 8 U
50 ~4
I
I
I
I
I I -
I u I saturated
I -
wdh CI,. 66 days. 4.1
n/Kc. nor rate
I CI~. 36 days
- Less than 2 mpy (0.05 mm/y) - 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) - Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) -Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) - More than 50 mpy (1.27 mm/y)
(continued)
716
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
E G S B U
Less than 2 mpy (0.05 mm/y) 2 mpy IO.05 mm/y) to 10 mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy 10 51 mm/y) to 50 mpy (1 27 mm/y) More than 50 mpy (1.27 mm/y)
(continued)
717
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
deg. C for 18 hrs. then cooled and later dned at 170 deg. C I 10%
E G S B U
Less than 2 mpy IO.05 mm/y) 2 mpy 10.05 mm/y) to 10 mpy 10.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) Mare than 50 mpy (1.27 mm/y)
M t -
Molar percent P,O,
(continued)
718
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Corroriva
Ydia
COrKeotratioo. parcant IO.15 16-22 I 80.98 I
Tsmprntun da;. F dq. 66-93 82 I 08 93 I C w-2 G S s B
HASTELLOvo WC-276 ----I s E
alloy G
TYP 316 Sbinlass Stnl m large volume 01 011
Conditions
Sullur~c Acid Sludge Suliur~c Acid Sludge Sullur~c Acid Sludge Sullwc Acid Vapors
150-200 180 190 200
l-l-l
-plus 2 percent au. 5 percent CS,. percent H,S. 93 percent H,O. Alloy C 0.2 = 0.2 mpy plus H,S m two stage neutralwr vented m atmosphere
Sultunc Sullurous Sulluryl
Acid Vapors Acid Chforlde Oust
60.120
16-49
-,--
All 100 -
toB.P
70 to 325
I toB.P
21 to 163
s
G E
l-l-l
--plus trace water. Alloy C = 2 mpy Over exhaust stack contammg Alloy C = 0.3 mpy S HIPO,. H,SO,, H+F, 811 and moisture.
Superphosphate
Superphosphow
Acid
94.8
340
171
wet process (as ortho acldj. Total P,OI 68.54%. ortho P,OI 51.08%: Fe,O? = 2.30%: SO, q 2.19%; Al201 = 1.92% F = 0.33% Concentrabon gradually reduced to 80% H,PO, 154% PIOIl wet process. PlOs 70.5%. (HlPO, eqwalent 97.3%). SO, 4.70%. A1201 3.05%. Fe>03 1.67%. MgO 111%. SiO, 0.72%. CaO 0.44%. F 0.25% wet process and. concentrating to 705 P?O, 2-3 percent lhgnm m and discharge lhne
Superphosphonc
Acld -
155
68
Superphosphorx Tall 011
Acid
400
204 93
B E I-
--
1
(by volume) -
200
plus 0 5.1 0 percent Alloy C = 0.2 mpy
H,SO,.
Tall 011
300
149
--
durmg successive estenbcabons. amldlzabons and sulfurlzabans m hvghtemperature reactor. Alloy C = 0 1 mpy llquld and vapor phases
Tall 011
100
300.550
149.288
i I-
/ -
durmg successwe esterlllcabons. amldlzabons. (111.421 hours (hquld and vapor phase) *and Its glycerolesters. phases) amlds and sulfurlred
and sulfurlzabons
of tall
Tall 011
to 554 550.650 75
to 290 288.343 24
S -
,!-
products
lflquld and vapor
Tannlg
LlqUOr
40 percent chestnut extract. percent hemlock lhquor
30 percent
bwlfated
quebracho.
30
Tar Acid
1 / 1 j
212-392
100.200
/ / / -
1/ / -
1 plus
benzmc acid. H,SO,, Na,SO,. at PH =4 for 11 days then 76days wth tar acids contammg Na,SO,. Na,CO, at pH = 8. Alloy C ~0.1 mpy plus Na,SO,. N&O, as lmpurmes pH =
Tar Acid
212-3g2 1 1oo-200 1
356
1 E /
E
1,j* Alloy ..O mpy C 1 1I dlstlllabon
washed cresyl~c acid dlstlllabon
Tar Acid Tartarlc Acid Tetrachforoethane
1 /
All
/ 60-70 I - I 140-158l - j E 1- l - l
toB.P
j 180 / toB.P
/ I
Alloy C = 0 026 mpy
!-l-l
plus some d!chloroethane H 0. HCI. Cl,. acetylene and a~ I chlqrlnabon of acetylene Alloy C .O i ;py
Trlchloraacebc
Acid
All
to BP 302
to BP 150 -
s E
-E aeration
Trlchlorobenzene Vapor. (Commencal) Ammoma & Chlorides Trtchlaroethylene
to B P to B P 05 mm/y) to 10 mpy (0 25 mm/y) mm/y) to 20 mpy (0.51 mm/y) mm/y) to 50 mpy (127 mm/y) (1 27 mm/y)
to B P to B.P BP Balling Pmnt
vapor and lhquld
E G S B U
Less than 2 mpy (0 2 mpy IO.05 mm/y) Over 10 mpy (0.25 Over 20 mpy (0.51 More than 50 mpy
(continued)
Nonferrous
Metals and Alloys
719
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Twesyl
Phosphate
88.go I
88.90
580
700
304 I
371
E I E
I -
plus percent tnphenyl 5 IAlloC=O1m
phosphate,
traces of HCI and orgamc chlorides..
Tr~cresyl Phosphate
plus 5 percent cresyhc acld. 1 percent MgC12. 5 percent thlophenols Traces of HCI. organfc compounds. residue tar tank cleaned Inter. mdtently by sand blasttog. Alloy C = 0.1 mpy plus 5 percent cresyhc acid, 5 percent thlophenols. traces of HCI MgCI, and orwvc chlortdes. 43.day test exposure. Allov C = 0 2 mov 90 days m dlstlllation column
Trlcresyl
Phosphate
89.90
700
371
--
Twesyl Crude
Phosphate,
570
299
-_-
Trlcresyl Phosphoric Acid. Crude

! I
176
I
80
I
E
I
-I I
trace of cresyhc acld. Alloy C = 0 05 mpy. 13.8OiJ.hr
test
Trlethanolamme Hydrochloric Acld Slurry Trlfluoromethyl Oiphenylamme Thmcarbamlde, Hydrochloric Acld Uramum Ore -
90-220
32.104
--
30 percent
HCI IS added to trlethanolamme
I steel tank
1
-
3oo
139
1 14
59
1 s
1 G I U u
1-
m thlonabon ~AllovC=9mo
process plus some sulfur. todme and monochlor
benzene.
an aldehyde (unspecified). acebc actd (concentration neutrabzed wdh 23% sodium hydroxide.
unspwhed).
MIX
113
45
--
pulped uranwm ore contamng 60 percent sohds: 28-55 grams/lder HzSO,. 5.10 grams/liter fernc loos, some ferrous tons. about 0.1 percent NaCIO,. Alloy C = 1.3 mpy
Urea
28
355.360
179.182
--
0 plus 32 2 percent ammoma. 20.5 percent water. 19 percent CO?. 3

percent ~nerts. plus ar = 17 mpy In lhquld urea reactor 3 It below top head Alloy C
Urea
58.4
350
177
ammonia
16.8%. carbon dlorlde
14.8%. water 9.9%. aerabon
E G S B U
Less than 2 mpy (0.05 mm/y) 2 mpy (0.05 mm/y) to IO mpy (0.25 mm/y) Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) More than 50 mpy (1.27 mm/y)
(continued)
720
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Corrosive
Media
COnCmltration. percent -
Tompentun dq. 70 F dQ. 21 C
HASTELLOY 6/B-2 E C/C-276 E
alloy G --
. less
Steel lmpurlbes formaldehyde Conditions oxygen 05 -2.0%. N2 upto 10%. HCI 0-1Oppm. O-5 ppm. aeratmn H,OO-11%.
TYW 316 Stain-
Vmyl Chlonde Liquid and Vapor Vinyl Chlonde Vapor
above alumma bed m drier Alloy C = 0 1 mpy *Plus methvl methvl ethvl ketone Allov C = ml mov complex solubon, exact camp unknown. cept durmg 0.1 N HNOl wash ProductIon 1 moderate. idustabfe Cl,. 98 days, moisture Cl,, 167 days, moisture droplets droplets Na,SO, present. pH 12.86 ex. of N tube phosphors Aerabon
!i;i:?,lm Waste Gas
1 /
E B G E
200
200 _
93 1
93 -
_ -
I - j - / contalnlng
-_ contammg
wth wth
NaOH. NaCl NaOH. NaCl
Waste Gas Water, Brackish
m exhaust fumes aft 01 mulfler of 40-11 utlhty boat m New York harbor 20.day test Alloy C = 0 1 mpy E Newark Bay Contams 0 70% N&I. ppm HCI. moderate aerabon 100 ppm Ca ++ as CaCOj. pH 6 7.60
Water. Brackish
45
Water. Cold (Fresh)
54
12
at treatment plant Alummum sulfate 20 ppm. chlorine 2 0 ppm. potas. swm permanganate 0.3 ppm, clay 5 ppm. starch IO ppm Turbidity 5 0. 50 0 units pH 7 3 to 8.0 at treatment plant Chlorine 08-l 0 ppm. alummum suspended alum floe [alummum hydroxide) contalmng lde pH 7 3 to 7 6. saturated Alloy C ~0 1 mpy Only very slight dlscoloratlon sulfate 0.2 ppm. manganese d!ox-
Water. Cold (Potable)
54
12
Water, Dlstlfled and Degassed water Purlflcabon Solubon Water. Residues of lnsectudes and Breakdown Products Water. Rwer and Lake
600
315
--
68
20
water purlflcatlon (2 5? HCII
solotIon
1000 grams ground carbon.
2 5 gal water
85
29
mcludmg parathion. morganlc salts mcludlng amnon~um and sodium chlorides. argan,c reagents mcludlng urea. solvents. pH range 1 5 to 13 5. usually above 8. moderate aeration Lake Ontarlo pH 8 0 to 8 5 contains bldlty 5 0 to 50 0 umts algae. small fish. lake debris Tur-
52
11
E _
Water. Saturated wth Carbon Oloxlde Water. Inclnerator scrubber Water. Scrubbed Sewage Sludge lncmetator Gases Water. Scrubber Water. Scrubber Water. Scrubber Water. Sea
400.425
204.218
plus 0 008 percent SO, and traces ol dissolved afr Alloy C = 0 6 mpy (IIquid). 0 3 mpy vapor phase aeratvxl
170.190 -
77-88 -
_ -
140-165 160-180 300-400 60-95
60-74 7182 149.204 16-35
S G 6 G S E
E E E E --_ E
E E G -
aeration aeratmn
dUB110
plus 1 8 percent total solIds. l-2 5 percent SO: absorbed with water I absorption sump Alloy C 0 1 mpy scrubber strong Ihquor. I8 percent SO,. 1 7 percent NaCl
Water. Sea Water. Sea
_ -
75 82
24 28
-_ _
20 000 ppm. Cl eons at a pH of 6 6 Contans from 2 5 to 104 5 mg 0; per lhter Test at suction end 01 pump casing under high ag,tat,on I asphalt plant gas scrubber mpy Plus 0~. SO- hydrocarbon Alloy C = 0 8
Water. Sea
95.500
35-260
u _ _ G _
E G E E ___ E
Water. Sea
Water. Sea Water. steep Water. steep Wash Water from Rayon Staple Bleach Machme Wash Water from Rayon Staple Bleach MachIne E G S 6 U Less than 2 mpy (0 2 mpy (0 05 mm/y) Over 10 mpy (0.25 Over 20 mpy 10 51 Mote than 50 mpy
203 325 125.135 150 145.150
95 163 5257 66 63-66
_ ---
_.
saturated
with Cl, Alloy C = 3 mpy lhne of tubular heat exchanger Velocity = 5 11 per xc
I discharge
plus 0 10.0 14 percent SO, Alloy C 0 1 mpy (I,quld and vapor) plus 0 02 percent SO>. 0 5-l 0 percent IactIc acld pH 3 5-4 5
aer.aon
162 168
72-75
1 E 1 E 1 E / aerat,on
05 mm/y) to 10 mpy 10 25 mm/y) mm/y) to 20 mpy (0 51 mm/y) mm/y) to 50 mpy (127 mm/y) I1 27 mm/y)
(continued)
721
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
Conosiw Waste Effluent
Media
COlW4ltntion. pwxnt
TCmpm-aturo dy. 70 F dw.C 26 we-2 -
HAnELLOr~ C/C-276 -
dloy G E
TYW 316 StainIns Steel contammg sutlurx moderate aerstmn acid.
Conditions esters. lime. waxes. 011s. lormaldehvde.
Whey Salts
176.212
80-100
E ___
--
plus tacbc acld. NaCI. and lactose I 70 percent ethyl alcohol
Alloy C = nil
wv
Wood fracbons 70-100 21-38 alternately crude pine tar 011.pvrollgneous 1 percent methanol, phenols) -acld (2-5 percent acetIc acid
194.302
go-150
m malelc acid dehydrabon column Plus lmpurlbes such as benzene. 1 percent malelc acld as malelc anhydrIde and tracesol water Alloy C 0 1 mpv
Xylerle
325-350
163.177
--
effluent mixture contammg water. acetic acid. benzoac acad. tolulc aad. tolualdehvde. acetophenone and hvdrocarbons as pr!mary constituents under 25.111 vawum Alloy C = ml py plus 2 percent PCI, and HCI
XYlOl Solvent vapors Leot1te water Softener
77-293 -
25.145 -
E --
300 ppm chlorides. 10.38 ppm carbonates. 0 6 ppm bicarbonates I dome of deaerator m steam Extenwe aeratmn and high agabon Alloy C =Olmpv 2 lb per gallon Z&O> plus 10 percent Na,CO> sullldes and sullur~c acid as lmpuribes Process IS conversion of Na,CO, to Na SO, Alloy C = 0 03 mLw
Zmc Carbonate
Slurry
70-180
21.82
--
Zmc Chloride Zmc Chloride Zmc Chloride
71 80 All 100
225 Bolllng to 6.P to 700 to 260
107 fto1hng to 8 P to 371 to 127
1 S S E
E E ---
1-
1-
21nc Chlarlde.
Chromated
--
solubon made by mwng tm~m plnlng = 2 mpv
80 percent InCl
and 20 percent Na CrO
Max
211x Chlwde
flux
25 COllC
75.80 Room
24-27 Room
IJ
-
E
E
l-l-l
---_ _
Ireserwr
tank pr,or to welding ndrosvl chlonde
Alloy C = 0 007 mpy Alloy C = 0 16 mpy
Zinc Ckhvdrogen Phosphate Zmc Fluosdlcate
plus small amount
:: 36 50 21nc Fluoslllcate -
75 150 75 150 loo-116
;; :;t 38.47
7 _ U _ u _
E U E u E
plus I to IO percent
lree H:SIF,
above steam chest ol smgle stage evaporator percent free H.SIF, 40.day peraod m manulacture Alloy C = 0 1 mpy
Plus
to
1percent 1 HCI
Zmc Hydrosulbte 21nc Sullate
45lbs/gal 30.34
232 100-220
111
E E
38-104
Na:Cr 0 H,O and lead peronde Alloy C = I5 mpy
added to remove fron and manganese
21nc Sulfate
34
232
Ill
as ZnSO, 6H 0 plus 8 8 percent 2nCl water Alloy C galned wght shghtlv
1 percent
lerrous
sultate
and
21nc Sullate Zmc Sulfate. Acid Sotubon 21nc Suilate. Anhydrous 21nc Sudate Drw Fumes Zmc Sulfate Monohydrate 21nc Sullate Monahydrate 21nc Chlonde 21rcer Llquld Phase Hvdrochlorlnabon E C S 8 U Less than 2 mpv (0 2 mpv IO 05 mm/y1 Over IO mpv 1025 Over 20 mpy (0 51 More than 50 mpv
to 40 -
to BP 68.122
to BP 20-50
S _
s E
_ plus (at start) 252 gil H SO,. 56 6 g/l Zn. 0 04 gil Fe At llmsh H.SO,. 48 3 gil Zn. 0 41 g/l Fe and 046 g/l Cu 2 42 lb anhydrous IOO3mpv ZnSO, plus 213 g/l
219-232
103-111 I G I II-
I 04
lb ZnCl per Walton 01 water Allov C =
110
40 _
43 _
_
E
above rotary drum drwr
plus traces al Fe. Na. Cd. Cu. conslderabte 0 In flash evaporator concentrat,on ot load lhquor Alloy C = 0 5 mpv 93 percent H.SO, plus 34 percent InSO,
for
220
104
269-293 795
132.145 424
c U s
E _
u _
aelatIOn AICI,. NH,CI plus gaseous HCI. 7 day3 I hquad , soor
05 mm/v) to IO mpv IO 25 mm&l mmivj to 20 mpy 10 51 mm/v) mm/y) to 50 mpv I1 27 mm/v) [I 27 mm/y)
BP
9Oltlng POlnt
(continued)
Nonferrous
Metals
and Alloys
723
TABLE 5.18:
NICKEL-BASE
ALLOYS-CABOT
WROUGHT
PRODUCTS
(continued)
HASTELLOY alloy G-3 is an improved wrought version of HASTELLOY alloy G. Alloy G-3 has the same excellent general corrosion resistance as alloy G, along with greater resistance to heat affected zone attack and excellent weldability. HASTELLOY alloy G-3 has outstanding resistance to hot sulfuric and phosphoric acids. Alloy G-3 will withstand the corrosive effects of both oxidizing and reducing agents and can handle both acid and alkaline solutions. Alloy G-3 has excellent resistance to mixed acids, sulfate compounds, contaminated nitric acid and flue gases. Alloy G-3 is resistant to stress-corrosion cracking as measured by the boiling MgCls Test (ASTM G30 and G36). In oxidizing acid chloride pitting media, alloy G-3 has good resistance to localized attack.
Aqueous Corrosion Data for HASTELLOY

Concentration, percent by weisht Acid 99 10 10 Ferric Chloride + lO%NaCl Formic Acid 5 5 30 40 60 88 Hydrochloric Acid 1 20 Nitric Acid 10 65 Phosphoric Acid 30 50 55 70 a5 Seawater Saturated Gas with Chlorine Test Temp., F (C) Boiling Room 122 (50) Room 122 1501 Borlina Boding Borlino Boilina 150 (66) Room Boiling Boilrna Borlrng Boiling Boihna 300 (1491 Average
Alloy Penetration
G-3 Rate per year Alloy G mils mm
Media Acetic
Alloy G-3 mils mm 0.6 0.1 30 Nil Nil 4 4 5 6 0.3 5.7 <0.02 <O.Ol 0.76 NII Nil 0.10 0.10 0.13 0.15 <O.Ol 0.14 0.02 0.25 0.06 0.10 0.13 0.22 0.69 co.03 0.06 0.24 0.30 0.48 0.66 0.81
Ferric Chloride
14 a5 -
0.36 2.1
0.2 0.8 22 4 7 20 11 14 0.28 0.36 0.51 0.02 0.56 0.10 0.18 <O.Ol -
0.8
10 2.4 4 5 8.6 27 1.1 2.5 9.4 12 19 26
Boiling 68 (20) 95 (35) 150 (66)
Sulfuric Acid
5 10 15
Boihno Boding Boilina
Sulfuric Acid + 3% HCI + 1% FeCl3 + 1% CuCl2 Sulfuric Acid + 6% HN03 Sulfuric Acid + 42 g/l Fe2(SO.&
7 7 44 50 50
Room Rnnm 86 (30) Boiling Boiling
Nil 1 0.2 12 17
<0.03 co.01 0.30 0.43
*With cwwce bolt All weld metal IshIelded metal arc welded1 -Not tested
724
Corrosion
Resistant
Materials
Handbook
TABLE 5.18:
NICKEL-BASE
LOCALIZED
ALLOYS-CABOT
CORROSION
WROUGHT
PRODUCTS
kontinued)
ENVIRONMENTS
RESISTANCE
IN PULP AND PAPER INDUSTRY
AVERAGE
COMPARATIVE
FIELD CORROSION
DATA IN SO,
CONTAINING
CHLORIDES
Field tests of corrosion test spools in a variety of SO? pollutton control environments resulted ln noselective corrosion on any of the HASTELLOY@ alloy G or C-276 samples. All other alloys tested showed pitting and/or crevice corrosion to varying degrees A complete summary of the data IS shown in the table below
Chloride Average To11 TOmpW~tUrC. Avenge CO~lWlt, PPM deg. F (deg. C) pH Low pH Conditiona 165 550 1000 1500 105 120 120 127 Under 4.6 pH 2 5-7 45 4 3 5-5 7 4 6 23 7 (0 (0 (0 (0 10) 15) 58) 18)
(41) (49) (49) (53)
Low Chloride Condilionr 500 500 550 130 (54) 120 (49) 130 (54)
4.9 to 5.4 pH 5 54 49 5 (0 13) 17 (0 431 0

6 (015) 1 10031 0 3 (0081 lo 0 0
Low Chloride Conditionr 125 200 500 200 500 850 1000 120 (49) 120 (49) 120 120 120 115 (49) (49) (49) (46)
5.5 to 6.5 pH :: 55 59 6 6 62 : : (0 18) 0 03) 1 (0 03)
+
0 : 0 0 0
1(0
0 0
0
1 (003)
E i
:
0 0
E
:
0 0 0 0
High Chloride Conditiona 2250 2900 2900 120 (49) 110 (43) 110 (43) -
4.5 lo 5.5 pH 5 45 5.5 11 (0 28) 4 (0 10) 3 (0 06)
High Chloride Conditions 1500 2900 3000 10000 127 110 120 120 (53) (43) (49) (49)
pH above 5.7 57 85 7 6 0 0 1 (0 03) 2 (0 05)
High-Temper4lurc
2100 2100 2300
Condilionr 7 65 6 10 (0251 28 (071) 22 (0 561 1 (003) 0 (0 25) (0411 2 (005) 10 (025) 9 (0 23) 0 0 0 0 0 0
160 (71) 160 171) 150 1661
6 i1
: 0
Nonferrous
Metals and Alloys
725
TABLE
5.19:
NICKEL-BASE
ALLOYS-STAINLESS
FOUNDRY
& ENGINEERING
ILLIUM 98 and ILLIUM B perform very well in processes which involve the use of sulfuric, phosphoric, hydrofluoric, nitric, acetic and fluosilicic acids as well as sodium chloride brine. They resist erosion to abrasion in corroding environment. These alloys have high mechanical rigidity. The 98 alloy is nonhardenable while the B alloy is hardenable. Results of ILLIUM 98 and ILLIUM B in Tested Applications Corrosion Rate Inches Per Year ILLIUM 98 ILLIUM B
ENVIRONMENT Sulfuric Acid

98%
95% 90%
Temp. OF
Corrosion Rate Inches Per Year ILLIUM 98 ILLIUM B ENVIRONMENT Hydrofluoric Acid
Hydro100-O% Atid (in
Temp. OF
Sulfuric Acid
Sulfuric Sulfuric Acid Acid
2120 212 212
0.015
0.01
0.005
0 to
loo/_
0.0065
0.0095
fluorit, Sulfuric stripping 10%
0.0195
tolumn) Acids,
1 O-300
0.001
N.R.
Phosphoric
101%
98% (Super sulfuric fluorine 98% 55% voporr
Acid
Phosphoric) with and compounds otid 375-410 3% and compounds with hydro1000 0.0027 237O 300 0.0053
Hydrofluoric, Water Hydrofluoric, Sulfuric Water Acids,
Phosphoric, Phosphoric
8b0/e Sulfuric
4%
60'
0.0001
NJ.
7%
3%
90%
390-460'
0.0066 0.044
60'
None
Detected N.R.
Phosphoric Phosphoric,
Sodium Chloride Brine (Saturated)
sulfuric, fluorine 39% sulfuric, fluoric
0.024
Saturated
brine
in 1860 C 0.0001
< 0.0001
Phosphoric
evaporator Soturoted brine in evaporator hoot exchanger Saturated brine in evoporotor discharge
and fluorine compounds
233O
< 0.0001
< 0.000
Hydrofluosilicic
13% Acid 1
Acid
1 boo
Hydrofluorilitic
248
for this service,
0.0017
0.0021
N.P. NR Not recommended NJ.
0.0002
0.0001
Il /.
Acid
Hydroftuorilitic
1bO*
lLLlUM G is highly rated for its resistance to a wide variety of corrosive chemicals. It withstands the corrosion of both oxidizing and reducing agents, acid and alkaline, up to moderately high temperatures. It is especially resistant to most sulfur compounds. Generally it is not recommended for halogen; halogen acids or halogen salt solutions; it is, however, highly resistant to seawater and to fluorine compounds in an oxidizing environment. Results of I LLIUM Code: R = A = B= C= D = E= G in Tested Applications
Recommended for use-quantitative test results not furnished Not more than 0.004 penetration per annum - less than 0.004 to 0.015 penetration per annum 1 mg/cm*/day 0.015 to 0.050 penetration per annum-approx. 1 to 3 mg/cm2/day 0.050 to 0.125 penetration per annum Over 0.125 penetration per annum
Substance or Process
Conditions
Temp.
OF. RaIa
Subrtanco or Procorr
Conditions
lamp. lF.
Rok
Acetic Acid -Concentrated -50% 5% Concentrated -SO% Aluminum Sulfate Ammonio Plus 20% by Vol. 25% Formic Acid Plus approximately 2% KMnO. HISO boil of clay Effluent from clay boil
Boiling Boiling Boiling Boiling 230 300 210 70
A A A A A E A A
Ammonium Ammonium Ammonium
Bromide-30% Carbonate-25%
120 70 330 70 Still solution Agitated solution Agitated solution 70 70 70
A A A A A B A
Chloride-30% -25% Ammonium Hydroxide -Concentrated -Conce.nMed -28% Ammonium Sulfide Saturated
70 A (continued)
726
TABLE
5.19:
NICKEL-BASE
ALLOYS-STAINLESS
lamp. OF.
FOUNDRY
& ENGINEERING
(continued)
Tamp. OF.
Substance or Process
Conditions
Rate
Substance or
Process
Conditions
Rotm
Arsenic Acid-75% to 90% BoricAcid-liquor - 6% Butyric Add-60% Colcium Hypochlorihs Carbon Tetrathloride
Solution concentrated by boiling
Boiling 150 70 7o
2% available chlorine
7o Boiling Boiling Boiling 2oo 76O 76O Boiling Boiling 180 7o 7o 7o Boiling 167O 212O 7o 176O
Saturated with free sulfur Plus 3% by volume of Bromine Chlorine Moist Dry Chrome Tanning Solution Concentrated Chromic Acid-SO% -25% -25% -35% -Varying Citric Acid Copper Sulfate-25% -9% to 10% Ethyl Acetate-Crude Ethyl Acetate Ethyl Gasoline Fatty Acids Ferric Chloride-43% Ferrous Sulfate formoldehyde-lO% Formic Acid-80% -25% Fruit-Juices Gasoline (See also H,SO, mixtures) Distillotion 33%
A A A A C A A
E E R A A E E E A R R A A B B A R E R A A A R
Hydrofluoric Acid -Anhydrous -Anhydrous
Plus 77% by Vol. 98% H,SO. Plus 57% by Vol. 98% HSO. . _
70 70 70 &So 16D 700
A A A A R A A R R A R A R R A A B A B R A A A A B A A A A A A A 8 R A A A R A B A
HydrofluosilicicAcid - 0% Hydrogen Peroxide lactic Acid-10% -10% Lithopone Sludge Magnesium Citrate Malic Acid Mine Water (acid) Mercury Nickle plating solution Nitre Cake Solution Oleic Acid-Comm. Olive Oil Oxalic Acid-15%
5%
70 See Note 1 9 15% H,SO, 70 ? ? 70 70 Boiling 70 lSOO
Plus 5% by Vol. H,SO, Pump handling 1t/s% to 36% acid (See olso H,SO, mixtures) Solution concentrated by boiling
7o Boiling 7o With H,P04, SiO, ond steam in vopor phase of polymerization tower
- 8% Phosphate Rock Acidulation Hot gases (SD,, SD,, CD Pickling Solutions 10% to 12% H,SO, Spent solution Cold woter wash tank solution Hot water wash tank solution Picric Acid4onc. Potassium Aluminum Sulfate-30% -15% Potassium Dichromote--S% (See also H,SO, mixtures) Potassium Hydroxide -30% Potassium Permanganate - 2% Pyrogollic Acid-30% Pyroligneous Acid-pure Rayon-Viscose process Coagulating Bath (See OISOHxSO, mixtures)
70 250 70 70= Boiling 70 70 70
Hydrochloric Acid-Conr Concentrated -32% Hydrochloric Acid-22% -22% -16% Aerated solution -10% -10% - 7% - 7% - 5% Wosh liquor - 1% Concentrated fumes Hydrofluoric Acid -Anhydrous -Anhydrous Plus 5% by Vol. 98% HzSD.
5oo
loo0 7o 105O 1200 7o 120 loo0 70 120 7o 7o 113O 7o 7o
A E E E E D E C A E : R A A A
lor removed Various solutions generally containing 10% to 15% 70e H,SO, with sodium sulfate to and other salts 200
Sea Water-Gulf of Mexico Completely immersed Partially immersed Intermittent immersion (tides) Sewoge Silver Nitrate-SO% Sludge Acid Meter parts
Atmos. Atmos. Atmos. 120
Sodium Acid Fluoride
Refinery waste-37% HaSO. Refinery waste-25% HSO. Saturated soln containing HF
160 140
1200 c (continued)
Nonferrous Metals and Alloys TABLE 5.19: NICKEL-BASE ALLOYS-STAINLESS

Temp. Substorw or Process Conditions
727
FOUNDRY
Rate
& ENGINEERING
(continued)
Tamp. Rare
.F.
Substance or Procars
Conditions
OF.
Sodium Acid Sulfate -24% Sodium Aluminum Sulfote Sodium Chloride -Saturated -16% Concentrated -36% Sodium Hydroxide-70% 48% -36% -25% - 5% -Concentrated
(See also H,SO, mixtures) Pump in service Strong crude 104O 150 7o
A
R A
Sulfuric Acid-Mixtures Copper Sulfate-10% 5%
With Equal parts with 25% H,SO. Equal parts with 25% HSO. Mixed with H,S04 Equol parts with 25% HaSO. Equal ports with 10% HSO. Equol parts with 25% HaSO. Equal ports with 10% HSO. 5.8% of soln Cont. 1.8% H,SO. Equal parts with 25% H,SO. Equal parts with 25% 71/1$:f soln with 921/,% Cant H,SO, 23% of soln with 77% of 78% H& Equal parts with 25% H,SO, Equol parts with 25% HSO. Equol parts with 25% H& Equal ports with 25% H,SO. Boiling Boiling 138O Boiling Boiling Boiling Boiling 7o Boiling Boiling B B A B A
Salt spray test Kept olkoline with NaOH Plus traces of free Cl,
85O 140 122O 194O 80 7o loo0
-16% Ferrous Sulfote-Sot. -10% 5% 5%
A
A
Sodium Hypochlorite Sodium Metophorphate-1.3% Sodium Nitrate-IO% Sodium Sulfide- 8% Sodium Thiorulfate-Commertiol Stonnic Chloride-24% Sulfonotion Proczrs (Petroleum products) Sulfur (Molten) Sulfur Dioxide Sulfuric Acid -Fuming (109%) Sulfuric Acid-Mixtures with Acetic Anhydride Sulfuric Acid-Mixtures Chlorine Copper Sulfate--SO% With
Plus NoCl, Na,SO, NaClO, Effluent from cell, olro contoins NoCl, No,SO,, No,CO,, NoClO, 15% avoiloble Cl, Bleaching solution (?) Bleaching solution (?)
160
Hydrochloric Acid -Concentrated Nitric Acid -25% -10% -Concentrated Sodium Dichromote 45% Sodium Sulfate-10%
C 8
B
120 87O 77O 70 Boiling 7o 7o R 7o B R
54O 21 Boiling
A
E B B E B A A A A A A : A
25% HzS04, then 25% No,SO,, 25% NoOH See Note 2 Plus SO, ond CO, gores
1100 350 150 125O
A
B
Equal parts with 98% H,SO.
250
63% H,SO, saturated with 104O Cl, Equol parts with 25% Boiling f&SO.
Boiling Potossium Dichromote Boiling - 5% Potossium Permonganote Boiling - 5% Sulfurous M-0.75% 175O lortoric Acfd-25% 70 Tetraphosphoric AddConcentration not reported 140 Concentration not reported 24B Concentrationnot reported 356O Urea Under 1125 Ibs. pe.rsq. 3180 in. pressure Vegetoble Juices Yeast Wort 94O Zinc Chloride 70 From shorted dry cells
5%
Note
No.
l-MERCURY-In (I tendency This volumes to and tendency
common tokc up prohibits dimensions
with Mercury its
other use for be
complex
alloys,
llllurn bulbs,
G etc.,
exhibits wpillority. where Note cate gain periods
through kept. in in
some
intcrgranulor
thermometer
exact No.
must
2-MOLTEN lllium weight of time. G, or
SULFUR-Tests unlike many other from dimensions
conducted corrosion immersion
molten the tluid
sulfur does over
indi-
that in
resistant
alloys,
long
not
728
TABLE 5.20:
NICKEL-BASE
ALLOYS-WALL
COLMONOY nickel alloys are generally resistant
Corrosive media in which Colmonoy
Acetic Acid (cold) Alcohols Alum Aluminum Acetate Aluminum Chloride Ammonia (anhydrous) Ammonium Bicarbonate Ammonium Carbonate Ammonium Chloride* Ammonium Hydroxide Ammonium Nitrate* Ammonium Oxalate* Ammonium Persulfate* Ammonium Phosphate* Ammonium Sulfide Amy1 Acetate Arsenic Acid Azo Dyestuffs Barium Hydrate Barium Nitrate Benzoic Acid Benzyl Alcohol Black Liquor, Soda Black Liquor, Sulphate Boric Acid Butyric Acid Calcium Carbonate (cold) Calcium Chlorate (dilute) Calcium Chloride Calcium Hydroxide Cane Sugar Liquors Carbolic Acid (Phenol) Carbonic Acid 1 Carbon Dioxide Carbon Disulfide Carbon Tetrachloride Caustic Potash Caustic Soda Chlorine (anhydrous) Chromic Acid Citric Acid (to 15%) Copper Acetate Copper Carbonate Core Oils Cotton Seed Oil Developers, Photographic Di-Methyl Ethers Ethyl Chloride
Ethylene Glycol Fatty Acids Formaldehyde Formic Acid (5%) Ferrous Sulphate Ferrous Arnmonium Citrate Callic Acid Gasoline Gelatine Glutamic Acid Glycerine (Glycerol) Helium Hydrocarbons Hydrochloric Acid (dilute and cold) Hydrofluoric Acid (cold) Hydrogen Hydrogen Peroxide* Hydrogen Sulfide (anhydrous) Kerosene Lead (up to 900 F) Liquid Sodium, Potassium, or Nak (up to 900 Fj Linalyl Acetate Lye Lysol Malic Acid Manganese Carbonate Manganese Chloride Magnesium Chloride Magnesium Hydroxide Magnesium Nitrate Magnesium Sulfate* Mercury Molasses Molten Class Monoethanoiamine Naphtha Natural Gas Nitric Acid* Nickel Sulfate* Oleic Acid Palmitic Acid Peroxide Bleach Liquors
Petfoleum Oils Phosphoric Acid* Phosphorus Bromide Potassium Carbonate (cold) Potassium Chlorate Potassium Hydroxide Resins Rosin Shellac Silver Nitrate Silver Chloride Sodium Citrate Sodium Hydroxide Sodium Nitrate* Sodium Peroxide Sodium Silicate Stannous Chloride* Steam (up to 1000 F) Sulfur Dioxide* Sulfuric Acid* Tannic Acid Tar Tartaric Acid* Toluene or Toluol Trichloroethylene Turpentine Uric Acid Vanadium Oxide Varnish Vegetable Oils Vent Gas Vinegar (cold) Vinyl Chloride* Viscose Water (hot and cold) Whiskey Wines Xylene or Xylol Yeast Zinc Chloride Zinc Sulfate *Resistant under certain conditions.
TABLE 5.21:
NICKEL-BASE
AND OTHER
HIGH ALLOY
PIPE AND TUBING-COLT
INDUSTRIES
wnt, ch*moul shipping drums. mnt and piping. *lecbonic parts, zmponmt,. rocket mototqrcr. tit and Wcb-onic compownts, ! v.?meIs and I teat
A Q-E
NR G-E G-E G-E G-E
AG-EG
NR
GO-EG-EX
I Fu~ee mutfkn. &c.tmnic compbwnta. chemiut and xstrinp equipment, hoat Wlttng quipmom wgensnto, tubing. ALLOY
NR
Q-E G-E G-E
601
ALLOY
Q 23.00
UNS WMOl. ASME Co& clrr Ni 51.00 UNS NM525 ASTM 5704 Tube. ASTM 11-705 pip4 Cl 21.50Ma 9.w Ni 61.00
1500
E~cellcnt hiih-bmpntwe pmpefttie& resistance to Ra cxchmgcn, ha4t-tmating bqk@s and hrmmr. ordizinp, ulwizinp. and udtur-con(lining W1~sph4nr. ndiutt tube& thcmwwpk b~ubrr.combusbon qnr, Wcmti engine wnr. Hiih smnpm md toughnear (mm c*og+nic 1SWF (OWC) good oxidltton nittlncc, oxoptional btigue sbongth and #ood nsirllncc to m8ny conosivcs.
NR
A G-E G-E G-E A
625
ALLOY
trmprnbns to
Chcmic#l md pWtion co~tml quipmsnt, ducttng, bit bftw hmv3linpquipmcnl twl mxzk~. alter bumm.
G-E E G-E G-E G-E
G-E
G
ALLOY G-3
UNS ND5M7 ASTM S-625 T&m. ASTU Sdl9 pip CI 22.50Yo 5.50 Ni 44.00 Cu 2.W UNS No6985ASTM S-S28 Tub@, ASTM S-619 Pge b 21.00uo 1.00 )(i 724
E~cslknt nairbmc in many m&a. Resists pttttnp, cwicc conwion md mtwgnnulm eonotbn. Simlu to G. batter Ior welding, no anwll mquimd.
Y~nutxtw~ end USC ph osphxmc md ruttulic uidr, ot ftuc.ge, scwbbcn and 0th @Ipotlvbon control q*PmW cnponto,,, b.1 ..eh.m
Q-E Q-E G-E G-E G-E G-E Q-E G-E Q-E
20
ALLOY
ASlW&454F+p@ Cl 19.00Ma 2.00 11131.q w 3.q f&tt4 Cl 21.w Nt
600
ALLOY
3%
E-515 TW
oxid&m, ruling and conosion in I *wtpbww
dewted tempcntunr. rutt& Rwi4t1 W
Sbonp and nrisunt
to orid8tion and c.(lrbukHton It
I 1 crch~n~cn. Heat
pmctrr.pping,
ClfbUdzabOn ttxWNS Wd
I I I I I I I I I 1 1 1 1 1 1 1 1 1 I I I
A NR X A Q-E G-E
I
A A A
800H
ALLOY
URS Row10 ASTM B-515 Tub@. ASTM S.514 Pt@ Q 21.00Nt 32.50 WS -25 ASTM b7Y Tubr, ASTM b7S5 c12.5SyoS.% Nt42xQCuz20
Stmilr M 800 wtth brnrr high tempntun stmngth h,, drrign stmqth vaiwt IDI YH &we 115OF (5%C). Imprwd cmep aid ,tro,-to-rupem pmpetier in 1lWF to lMOwF(595C to 950%) ngc. Exd*m n,t,br_ ._ i._ .__i__. _. __-_:____ Rwista pttbng and oxtdirino
Chemical and po*ur plant rupcr helter and n-hwtcr tubby, hqtan and lumacc tubing, pmcesl piping. C___. _.__I___ _I____. - __..__. ^L__ i__l *-..L. .__I
826
I._____._ _..__._. .._.. zone.
_:_ .,__. _..__.__,__.._ mm-boundary urbda
. Q-E E Q-E G-E NR G-E Q-E G-E Q-E
I I
730
TABLE 5.22:
NICKEL-BASE
RODS, ELECTRODES
AND WIRES-CABOT
STELLITE
Nickel-Base
Nominal chemical composition, NrckeCBase Allow DELORO alloy No. 40 DELORO alloy No. 50 DELORO alloy No. 60 Form Cr C Si Mn
Alloys
percent Fe Ni Co B W Hardness, Rockwell MO
11
0.45
2.55
2.25 Bat
1.5
2.5
C-42
A A D,E B C A B A B A B D E
12 15 12 17
0.35 0.75 0.7 0.1
3.5 4 3.0 -
17 -
3 4
Bat Bal. Bat
2.5 3.5 2.3 -
c-51 C-57 C-46 B-96, C-37 B-96, C-35
HASTELLOY alloy C
Bal.
HAYNES alloy No. 711
27
2.7
23
Bat
12
c-40. C-43 C-42
26
1.1
1.5
29
23
11
0.5
3.5
C-30, C-32 C-24
17
0.4
17
5.5
Bat
6.5
4.5
C-27:
C-39
c-22. C-36 29 1.1 1.5 1 5.5 3 Bal. 3 0.6 2 c-37 C-26 Code: A-Bare Cast Rod B-Covered Electrodes C-Tube Wrre-Sub-Arc D-Tube Wire (Gas Tungsten Arc) E-Tube Wtre (Gas Metal Arc)
HAYNES alloy No. N-6
Maxrmum ** Work-hardened Gas-tungsten arc only
Comparativa
Corrosion
Data*
Gas Tunasten Arc Deoosits DELORO alloy No. 40 U U DELORO alloy No. 50 U U DELORO alloy No. 60 U U STELLITE alloy No. 6 E U HAYNES alloy No. 716 E U
Media Acetic Acid Nitric Acid
Concentration and Temperature 30%, Boiling 65%. 150 deg. F (66 deg. C) 60%. Boiling 5%. 150 deg. F (66 deg. C)
HASTELLOY alloy C E S
Formic Acid Sulfuric Acid
E E
S U
S U
G U
E E
E U
Five 24-hr. test periods. Determined in laboratory tests. It is recommended that samples be tested under actual plant conditions.
Code: E-Less G-5 than 5 mpy (~0.13 mm/y)
mpy (0.13 mm/y) to 20 mpy (0.51 mm/y) 20 mpy (>0.51 mm/y) to 50 mpy (1.27 mm/y) than 50 mov (~1.27 mm/v)
S-Over U-More
TABLE
5.23:
TANTALUM-NRC
Temperatures
at which various media attack Tantalum
Comparison of corrosion rates for Tantalum, 304 Stainless Steel and Platinum
Niobium, Titanium,
Air Alkaline solutions Ammonia Br0mine Chlorine, dry Chlorine, wet Fluorides, acid media Fluorine Hydrobromic acid, 2570 Hydrocarbons Hydrochloric acid, 25% Hydrotluoric acid Hydrogen Hydrogen bromide Hydrogen chloride Hydrogen fluoride Iodine Xtrogen Oxalic acid, sat. soIn. Oxygen Phosphoric acid, 85% Potassium carbonate Potassium hydroxide 10% Potassium hydroxide Potassium pyrcsulfate Sodium Sodium Sodium Sodium Sulfuric carbonate hydroxide 10% hydroxide pyrosulfate acid 98%
g*
aqueous gas gas gas gas aqueous gas aqueous gas aqueous aqueous gas gas gas gas gas gas aqueous gas aqueous aqueous aqueous molten molten aqueous aqueous molten UlOltell aqueous fuming gas aqueous
At temperatures over 300C At pH > 9, moderate temperatures some corrosion Pits at high temperatures and pressure At temperatures over 300C At temperatures over 250C At temperatures over 350C All temperatures and concentrations At all temperatukss Begins to corrode at temperatures over 190C React at temperatures around 1500C Begins to corrode at temperatures over 190C Corrodes at all temperatures and concentrations Causes embrittlement, especially at temperatures over 400C At temperatures over 400C At temperatures over 350C At all temperatures At temperatures over 300C At temperatures over 300C At temperatures of about 100C At temperatures over 350C Corrodes at temperatures over NW, at higher temperatures for lower concentrations Corrodes at moderate temperatures depending on concentration Corrodes at about 100C Dissolves metal rapidly (over 360C) Diisolves Corrodes cOrrodes Dissolves Dilves Begins to trations Corrodes metal rapidly (over 300C) at moderate temperatures depending on cow. at about 100C metal rapidly (over 320C) metal rapidly (over 400C) corrode at temperatures over 175C; lower concenbegin to corrode at higher temperatures at all temperatures
S.S.
Acetic Acid AICI, (lOye soln) SH,CI (10% win) HCI, 20%
100 100 100 21 109 21 100 100 loo 170 25 100 25 25 25 50
F 212 212 212 70 212 70 212 212 212 338 76 212 76 76 76 122 212 392 4S2 73 15s 78 167 76 76 70 205 70 212 212 176 76
Ta nil nil nil nil nil nil nil nil nil <l nil nil nil nil nil nil nil 3 rapid 0.5 rapid nil nil nil nil nil 0.1 nil 0.7 <l rapid rapid
Sb -(a) nil 0.04 0.1 4(b) nil nil <l 3(b) nil 0.1 0.2 O.S(b) 115(b) rapid -
Ti nil nil <0.5 175 rapid nil nil <5 8 40 7 60 high rapid -
304 20 20 > 20 high rapid 7 > 50 > 50 > 50 >>50 > 50 50 < < 1 1 5
, ronc.
HNOI, 20%
Pt nil nil nil nil 1 nil nil nil nil nil nil nil 8cQ 0.1 nil nil nil nil nil nil
, 70% , 65yc
HJO,, S-5% H,SO,, 10%
Sulfuric acid (&urn) (over 98% HSOJ Sulfuricttioxide Water
200 250 H,SO,. fuming (15% SOa) 23 70 Aqua regia 25 75 Chlorine, wet 25 H,O, Cl, sat 25 , sea 21 Oxalic acid 96 21 NaOH, 5% 100 100 910% SO 49% 25 HP, d%
, 40% 196% I w% ! 99% >98% 3WC
loo
(assume rapid)
nil nil nil nil 0.6(b) 1.1 rapid rapid
35 nil 5 nil 8 5 rapid
At all temperatures Corrodes at pH > 9; reacts at high temperatures
732
TABLE 5.24:
TANTALUM
AND
TANTALUM-COLUMBIUM
ALLOY-CABOT
KBI
The corrosion resistance of tantalum is generally compared with that of glass, although it withstands higher temperatures and offers the intrinsic advantages of a metal from a fabrication standpoint. Tantalum equipment is frequently used in conjunction with glass, glass-lined steel and other nonmetallic materials in chemical equipment. It is used extensively in repairing damage and flaws in glass-lined steel equipment. Heat transfer equipment constructed of tantalum includes straight-tube heat exchangers, condensers, bayonet heaters, spiral coils and U-tubes. Tantalum is also used in thermocouple wells, dig pipes, orifices, valves, diaphragms, and in other special areas. The leading anticorrosion applications are in the manufacture of hydrochloric acid and hydrogen peroxide, recovery of sulfuric acid, in bromine heaters and stills, in condensing ethyl bromide, and in the preparation of certain highpurity chemicals. Corrosion Resistance of Tantalum
(Reagent grade chemicals used when appropriate) S = no attack up to about 15OC (302F), or as specified V = variable depending on concentration and temperature X = not resistant Chemical Acefic acid AC+ anhydride Air, below 300 C (570 F) Air! above 300 C (570 F) Al6minum chloride Alhminum sulfate Amines Ammonia Ammonium chloride Ammonium hydroxide Ammonium nitrate Ammonium phosphate Ammonium sulfate Amy1 acetate or chloride Aqua regia Barium hydroxide Body fluids Bromine, dry, below 300 C (570 F) Bromine, wet Calcium bisulfite Calcium chloride Calcium hydroxide Calcium hypochlorite Chloric acid Chlorinated brine Chlorinated hydrocarbons Chlorine, dry, below 250 C (480 F) Chlorine, wet Chlorine oxides Chloroacetic acid Chromic acid Chrome plating solutions Citric acid Cleaning solution Copper salts Ethylene dibromide Ethyl sulfate Fatty acids Ferric chloride Ferrous sulfate Fluoride salts Formic acid Hydriodic acid Hydrobromic acid S S S X S S S V S V S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S V S S S Chemical Hydrochloric acid Hydrofluoric acid Hydrogen Hydrogen bromide Hydrogen chloride Hydrogen fluoride Hydrogen iodide Hydrogen peroxide Hydrogen sulfide Hypochlorous acid Iodine. below 300 C (570 F) Lactic acid Magnesium chloride Magnesium sulfate Mercury salts Methyl sulfuric acid Mixed acids (H2S04-HN03) Nickel salts Nitric acid Nitric acid, fuming Nitric oxides Nitrogen, below 300C (57OF) Nitrous acid Nitrosyl chloride Oleum (fuming sulfuric acid) Organic chlorides Oxalic acid Oxygen. below 3OOC (57OF) Perchloric acid Phenol Phosphoric acid, ~4 ppmF Phosphorous, below 7OOC (1290 F) Phosphorous chlorides Phosphorous oxychloride Pickling acids, except HNO,-HF Phthalic anhydride Potassium carbonate Potassium chloride Potassium dichromate Potassium hydroxide, dilute Potassium hydroxide, cont. Potassium iodide-iodine Potassium pyrosutfate, molten S X V S S X S S S S S z S S S S S S S S S S S X S S S S S S S S S S S V S S V X S X Chemical Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium bisulfate, molten bisulfate, solution bromide carbonate chlorate chloride hydroxide, dilute hydroxide, cont. hypochlorite nitrate pyrosulfate, molten sulfate sulfide sulfite X S S V S S V X S S X S V S S S S S X S V S S S S S S
Sulfamic acid Sulfur, below 500C (930 F) Sulfur chlorides Sulfur dioxide Sulfur trioxide Sulfuric acid, to 175C (350 F) Sulfuric acid, over 175C (350 F) Sulfurous acid Sulfuryl chloride Thionyl chloride Tin salts Zinc chloride Zinc sulfate
Liquid metals Bismuth to 900C (1650F) Gallium to 450 C (84OF) Lead to 1000 C (1830 F) Lithium to 1OOOC (1830F) Magnesium to 115OC (2100F) Mercury to 600C (1110F) Potassium to 9OOC (1650F) Sodium to 9OOC (165O*F) Sodium-potassium alloys to 900 C ( 1650 F) Zinc to 5OOC (930 F) Tin Uranium (continued) S S S S S S S S S X V V
733
TABLE
5.24:
TANTALUM
AND
TANTALUM-COLUMBIUM
ALLOY-CABOT
KBI
(continued)
KBI-40 Alloy is ties in common priced tantalum bayonet heaters,
a solid solution of 60% tantalum and 40% columbium. As such, it has many application possibiliwith both its elemental components, particularly tantalum. It is interchangeable with the higherin many applications, including: plate and shell-and-tube heat exchangers, reactors, condensers, thermowells, spiral coils, U-tubes, rupture discs, distillation columns, and piping. CORROSION RESISTANCE KBI 40 ALLOY OF V : : S S
Ammonium nitrate Bromine, dry, below 200 C Bromine, wet Chlorinated brine Chlorinated hydrocarbons Ferric chloride Ferrous sulfate Ferrous salts Hydrochloric acid
: ss S s
Hydrofluoric acid Nitric acid Nitric acid, fuming Organic chlorides Phosphoric acid, 4 ppm F Phosphorous chlorides Pickling acids, except HN03-HF Potassium dichromate Potassium hydroxide, dilute
z S z S V
Sodium hydroxide, dilute Sodium hydroxide, cont. Sodium nitrate Sodium sulfide Sulfuric acid, to 160 C Sulfurous acid Zinc sulfate
Key: S = Totally resistant to about 150 C (302 F) or as specified V = Varies depending on concentration and temperature X = Not resistant KBI-40 Corrosion Information actual field testing could differ because of
The following tests have been conducted with reagent grade chemicals; impurities. Field testing is highly recommended. (Rate is in mils/yr.)
Solution
5% HCI
Salt 10% NaCl 0.005% FeCI, 10% NaCl 10% NaCl 0.005-0.040% FeC13 0.005-0.040% FeCI, 0.005-0.040% FeC13 0.005% FeCI, 0.005% FeCI, 0.005% FeCI, 0.005% FeC13 0.1% FeC13 0.1% FeC13 0.01% FeC13 O.Oi-0.1% FeC13 5-15% AICI, O.Ol-0.1% FeCI,
TemDerature. C 101 boil 102 boil 190 190 102 boil 109 boil 109 boil 110 boil 110 boil 190 190 150 92 boil 92 boil 190 190 01 boil 81 boil 190 190 121 boil 101 boil 101 boil 102 boil 190 107 boil 107 boil 113 boil 190 113 boil
Pure Ta nil nil nil nil nil nil nil nil nil <l nil nil nil nil 1 1 nil nil 0 a nil nil nil nil nil nil nil nil nil nil
KBI-40 nil nil nil nil nil nil nil nil 2 <l nil nil nil 36 31 <l nil 141 259 nil nil nil nil nil nil nil 41 nil Cl
Pure Cb 1 <l 7 16 30 64 cl <l 2 5 7 -
10% 10% 10% 10%
HCI HCI HCI HCI
15% HCI 15% HCI 20% 20% 20% 20% 20% 30% 30% 30% 30% 36% 36% 36% 35% HCI HCI HCI t-ICI HCI HCI HCI HCI HCI HCI HCI HCI HCI
65% HNO, 10% H2S04 10% H2S04 20% H&O. 20% HISO., 30% H$Oa 30% H,SO, 40% HzS04 40% H$O., 40% H?SO,
(continued)
734
TABLE 5.24:
TANTALUM
AND TANTALUM-COLUMBIUM
ALLOY-CABOT
KBI
hminued)
Solution z&0 H,SO, 5OYo H2S04 5OYo HrS04 50% HIS04 50% HzS04 50% HPSOd 60% H*SO., 60% HPSOd 600/o H2SOd 60% H,SO, 60% HZS04 60% H,SO, 60% H;SO; 70% 70% 77% 77% 77% H2S04 HsSO., H2S0, HrSO4 H.SO. -
Salt
O.Ol-0.1% Fe&
Temperature, 123 boil 123 boil 110 120 120 123 boil 100 141 boil 190 90-100 120 120 141 boil 100 165 boil 100 175 189 boil 260 260 260 141 boil 165 boil 123 boil 101 boil *Highly oxidizing
oC
Pure Ta nil nil nil nil nil nil nil Cl <l nil nil nil Cl nil <l nil 2 2 5 15 21 nil <l nil nil
KBI-40 <l <l nil <l nil Cl nil <2 <2 nil cl nil 1 nil 6 nil 32 40 1 8 <l nil
Pure Cb 49 -
O.Ol-0.1% FeCI, O.Ol-0.10/o Fe& O.Ol-0.1% FeCI, 0.01% FeCI, 0.05-0.1% FeCI, O.Ol-0.10/o FeCI, 10Y0 NaCl 10% NaCl + 42gIliter Fe&SO,&*)
85% H-SO.
93% H-SO.
96% HSO. 80% H,SO. 70% H,SO, ASTM G-28 (50% HrSO,
Green Death (12Y0 H2S04 + 1.2% HCI + 1% FeCI, + 1% CuCI,) Soiling temperatures may vary with salt additions.
acid solutions.
735
TABLE 5.25:
TITANIUM-INDUSTRIAL
TITANIUM
FOLLOWING MEDIA.
COMMERCIALLY PURETITANIUM IS BEING USEDSUCCESSFULLY IN ALLOFTHE
SALTS
Aluminum Hydroxide Aluminum Potassium Sulphate Aluminum Sulphate Amonium Chloride Amonium Hydroxide Amonium Sulphate Aniline Hydrochloride Antimony Trichloride Barium Carbonite Barium Chloride Barium Nitrate Barium Sulphate Calcium Carbonate Calcium Chloride Calcium Hydroxide Calcium Hypcchlorite Carbon Tetrachloride Copper Carbonate Copper Chloride Copper Cyanide Copper Nitrate Copper Sulphate Cupric Chloride Ethylene Chloride Ferric Chloride Ferrous Chloride Hydrogen Peroxide Hydrogen Sulphide Lead Acetate Manganese Carbonate Manganese Chloride Magnesium Carbonate Magnesium Chloride Magnesium Hydroxide Magnesium Nitrate Magnesium Sulphate Mercuric Chloride Mercuric Cyanide Nickle Chloride Potassium Bichromate Potassium Bromide Potassium Carbonate Potassium Chloride Potassium Chlorate Potassium Ferricyanide Potassium Ferrocyanide Potassium Hydroxide Potassium Iodine Potassium Nitrate Potassium Oxalate Potassium Permanganate Potassium Sulphate Potassium Sulphide Silver Chloride Silver Cyanide Silver Nitrate Sodium Acetate Sodium Benzoate Sodium Bicarbonate Sodium Bichromate Sodium Bisulphate Sodium Borate Sodium Carbonate Sodium Chlorate Sodium Chbride Sodium Citrate Sodium Flouride Sodium Hydroxide Sodium Nitrate Sodium Phosphate Sodium Silicate Sodium Sulphate Sodium Sulphfte Stannic Chloride Stannous Chloride Sulphur Dioxide Titanium Tetrachloride Zinc Chloride Zinc Sulphate
ACIDS
Acetic Acid Acetic Anhydride Acetic Vapors Carbonic Acid Chloroacetic Acid Chromic Acid Chromic Acid CR Citric Acid Hydrocyanic Lactic Acid Malic Acid Nitric Acid Nitrous Acid Oleic Acid Oxalic Acid Phosphoric Acid Pyrogallic Acid Salicylic Acid Stearfc Acid Sulphurus Acid Sulphurous Spray Tannic Acid Tartaric Acid Uric Acid
MISCELLANEOUS
Alcohol- Methyl, Propyl Butyl Ethyl Aniline Beer Blood Chlorinated Water
Chlorine Gas-Moist Chloroform Flue Gases Fluorine Formaldehyde Fruit Juices
Only
Furfural Gasoline Hydrocarbons Meat Juices Mercury Petroleum Ether
Phenol Salt Salt Brine Water- Hot, Sea, Salt Brakish, Steam Whiskey
Nonferrous Metals and Alloys TABLE 5.26: TITANIUM

C
737
AND TITANIUM
T 207 (97) room 160 (62)
ALLOYS-TIMET
kontmued)
MEDIA Fluorine.commercial C gas-liquid aftematad *liquid lZgas liquid gas 10 37 10 25 50 90 10 25 50 90 9 loo 50 81,mixture 5 10 20 37.5 1 3 5 3 5 10 3 5 10 5 10 36 5 5 5 5 5 5 6.5 1 1 T gas-109 liquid(43) -320 (-196) -320 (-196) -320 (-196) -320 (-196) room ambient boilmg 572 (300) 212(1W) 212(1W) 212(1W) 212(1W) 212(1W) 212(100) boilmg 212(1W) 122 (50) room room room amblent 95 (35) 95 (35) 95 (35) 95 (35) boilmg boilmg boilmg 374(190) 374(190) 374(190) 374(190) 374(190) 374(190) 374(190) 374(190) room lW(36) 2w (93) lW(36) 200 (93) lW(36) 200 (93) 176 (60) boilmg boitlng R 16-34 (0.457xK664)
MEDIA Chlorineheadersludge and wet chlorine Chlonne gas. dry Chlonnadioxlde
R 0.03(0 001) may react <O.l (<OW3)
Chlorlnedloxlde I steam
~0.5 H,O 5 in steam gas + H,O and stir fS+some HOC1and wet Cl, 5 upto i some HOCI. Cl, 8 HZ0 100
Fluorine,HFhae Fluorine,HF free Fluorine.HF free Fluorosilicic acid Food products Formaldehyde Formamidevapor Formicacid.aerated Formicacid. aerated Formicacid, aerated Fomw acid, aerated Formtcactd. non-aerated Formicacod. non-aerated Formcc aad. non-aerated Formicacod. non-aerated Formicacid. -0 Furfural Glucomcactd Glycerin Hydrogenchloride.gas Hydrochloric acid aerated Hydrochloricaad. aerated Hydrochloncaad, aerated Hydrochloncacld. aerated Hydrochloncacld Hydrochloncacid Hydrochloric acid Hydrochloric acid. nitrogensaturated Hydrochloric aad. nitrogensaturated Hydrochloric aad. nitrogensaturated Hydrochloric acid, oxygen saturated chlorinesaturated
0.06(O.W2) co.43 (0.011) 0.42 (0.011) 1670 (47.5) no anack nil nil 0.16(O.W5)~~ 0.04(0 001) 0.04(0.001) 0.05(0.w1)~* nil 96 (2.44) 126 (3.20) 116 (3.00) <5(<0 127) nil ml nil nil 1.5 (0 036) 40 (1.02) 175 (4.45) 1990 (50.6) >lW(>2.54) 550(14 0) 400 (10.2) >1120(>26.5) >1120(>26.5) >1120(>26.5) >1120(>26.5) >1120(>26.5) >1120(>26.5) <l (~0.025) >1120(>26.5) 17.0 (0.432) nil 3.6 (0.091) 0.64 (0.025) 1.2 (0.030) nil 7.2 (0.163) 2.0 (0.051) 2.9(0.074) nil
llO(43)
ml
210(99) llO(43)
ml II
Chlorinetrliluorlde
~66 (30) 160 (62) bwng room bolllng 203 (95) bolllng 75 (24) 160(62) 75 (24) 160 (62) 171(77) 70(21) 212(100) 212(1W) 140 (60) 212(1W) boilmg 3W(149) room bolllng room ambtent boilmg bolllng 246(119) (boilmg) room 194 (90) room 302 (150) 212(100) bolllng 355 (179) mom bolllng room boiling rc0m room 212(100) boilmg 236(113) (bollmg) 302(150) room 175 (79)
Chloracetlcacid 30 Chloracetlcacid 100 Chlorosulfonlcacld 100 Chloroform vapor 8 llqutd Chloroplc 100 Chromlcacld 10 Chromicacid 15 Chromicacld 15 ChromicacId 50 Chromicacld 50 Chromiumplatmgbath 240 g.l contammgfluorlde platmgsalt 5 Chromicacld + 5% mtrlcacid Cttrlcacid 10 Cltrlcacid 25 Cltrlcacld 50 CitricacId 50 aerated Cttncactd 50 Cltrlcacld 62 Copper mtrate saturated 50 Copper sulfate Copper sulfate + saturated 2% H,SO, Cupriccarbonate + saturated cuprichydroxide Cupricchloride 20 Cupr~cchlorlde 40 Cupricchloride 55 Cupriccyanide Cuprouschloride Cyclohexylamine Cyclohexane(plus traces of formicacld) Dlchloroacebcacid Dkzhloroacetlcacid Dlchlorobcnzene + 4-5% HCI Dtethylenetrlamine Ethylalcohol Ethylalcohol Ethylenedichlonde Ethylenedlamme Femc chloride Ferric chloride Femcchlonde Fenicchlonde Femc chloride Ferricsulfate .9 Ii,0 Fenous chloride + 0.5% HCI + 3% resorcinalpH 1 Ferrous suffate Fluotmncacid saturated 50 100
wgorous reaclon C5.OfCO 127) 15 Of.cO 127) 7 5.12.3(0 191-0.31; 0 01 (0.000) 0 1 (0.003) 0.1 (0 003) 0.2 (0 006) 06(0015) 0.5 (0.013) 1.l (0 026) 56.3 (1 46) <o l(~O.003) 0.36 (0 009) 0.03 (0 001) 0 01(0.000) <5.0(<0 127) 5-50 (0 127-l -27) corroded nil nil 07(0016) nil nil 0.2(0.005) 0.1 (0.003) nil co.1 (<O.W3) nil 0.1 (0.003) <0.5(<0.013) 0.29(0 007) 4(0.102) nil 0.5 (0.013) nil 0.2-5.O(O.W5-0.127) nil nil <0.5(<0.127) nil nil 0.1 (O.W3) nil 0.2 (0.006)
100 100
1W 95 100 100 100 1O-20 1O-30 1O-40 50 50 10 30
saturated 5-20
room elevated
nil rapid
Hydrochloric acid, 200 ppm Cl, Hydrochloric acid, + 1%HN03 + l%HNO, + 5% HNO, + 5% HNO, + lO%HNO, + lO%HNO, + 3% HNO, + 5% HNO, + 5% HN03 + 1.7 g/l TiCI, Hydrochloricacid, + 2.5% N&IO, + 5.0% NaCIO, Hydrochloncacid. + 0.5% 003 + 0.5% 00, + l%CQ + l%ClQ, Hydrochloric acid, + 0.05% cuso, + 0.05% cuso. + 0.5% cuso.
10.2 10.2 5 5 5 5 5 5 5
176 (60) 175 (79) lW(36) 200 (93) lW(36) 200 (93) lW(36) 200 (93) lW(36)
0.37 (0.009) 0.25 (0.006) nil 1.2 (0.031) 0.72(0.016) 1.2 (0.031) 1.56 (0.040) 3.6(0.091) 3.6(0.091)
(continued)
738
TABLE 5.26:
MEDIA Hydrochlonc + 05%cus0. + 1%cuso, + 1% cuso. + 5% cuso, + 5% cuso, + o.o5%cuso, + 0.5% cuso. Hydrcchlonc
TITANIUM
C
acid. 5 5 5 5 5 5 5 10 10 10 10 10 10 10 1.48 100 l-HF -15HN0, 3 6 30 7.85
AND TITANIUM
T R
ALLOYS-TIMET
kontinuedJ
MEDIA Nrtncactd. aerated aerated aerated
C
20 30 40 50 60 70 40 70 20 35 70 17 35 70
T 104 (40) 122 (50) 122(50) 140 (60) 140 (60) 158(70) 392 (200) 518 (270) 554 (290) 176 (80) 176 (60) bolllng bolllng bo!l!ng room
R
0 21 (0 005) 0 61 (0 015) 064(0016) 1 46(0 1 56(0 037) 040) 610) 22) 102) 102)
200 (93) lOO(38) 200 (93) 1OOW) 200 (93) boiling boikng 150(66) 150 (66) 150 (66) 150 (66) boilrng boiling boikng room room room room room room 206-230 (93-l 10) 104 (40)
2.4 (0.061) 1.2 (0.031) 3.6 (0.091) 0.8 (0.020) 2.4 (0.061) 2.5 (0.064) 3.3 (0.094) 0.88-1.32(0.017-0.025) nil nil-O.68 (0.023) 0.88 (0.023) 11.6 (0.295) 11.4 (0.290) 9.0(0.229) rapid 5.0-50(0.127-l rapid <5(<0.127) <5(<0.127) <12(<0.305) nil 1.2 (0.031) 0.001 (0.000) <4(<0.102) nil pttted <5.0(<0.127) <5.0(<0 snacked good II nit nil It kmrted resrstance <0.4(<0.010) II II nil II .06 (0.002) 0.01 (0 000) 0 42(0.011) 0.04(0.001) <5(<0.127) II satisfactory II 119.4 (3.03) II 3.12 (0.079) 2.48 (0.063) 1 28(0.033) 3 26 (0.083) 0.17 (0.004) 0.11(0.003) II 0.19(0 005) 9.69 (0 246) 0.17 (0.004) 0.08 (0 002) 0.08 (0.002) 0.02 (0 091) 0.18 (0.005) 0.10 (0 003) 127) .27)
Nftricaad. Nrtrtcactd,
Nftnc ac!d. aerated Nrtnc acrd. aerated Nitnc actd. aerated Nttncacrd. Nrtrlcacrd. aerated aerated
156
24(0 48(1
(0 040)
acid,
Nrtric acid. aerated Nttric acrd. non-aerated Nrtncacid. non-aerated Nltnc actd Nltnc acrd Nrfnc acrd Nitrtcacid. whrte fumrng Nitric acid,
12 (0 305) 2-4 (0 051-O 3-4 (0 076-O 1.3 (0 025-O 076) 5-20 (0 127-O 506) 2 5-37 (0 364-O 940) 0.1 (0.003) nil 6.0(0.152) <5.0(<.127) <5.0(<.127) lgmtion sensitive not lgnltlo sensitive 0.12-0.99 4.8-7.4 (0.093-0.025)
+ o.o5%cuso. + o.2o%cuso. + 0.5% cuso, + l%CUSO, + o.o5%cuso, + 0.5%CUSO, + 02%cus0, + 0.2% organic amme Hydroftuoric acid Hydrofluoric Hydrofluoric-mtnc Hydrogen Hydrogen Hydrogen Hydrogen and 0.077% acid, actd anhydrous
!iqurd or vapor
room 180 (82) 252 (122) 320(160)
whtte fuming
Nitricacid, whrte fuming Nitrtc acrd, whitefuming Nttric actd. white fuming Nitricacid. red fumfng Nitric actd. red fummg Nitric acid + 0.1% CrOs Nttric acid + t 0% FeCI, + 0.1% Nitric acid
peroxtde peroxtde perxoide steam
<about 2% H,O >about 2% H,O 40 40 40 40
room room b&ng borkng bolllng
sulfide,
mercaptans acid dry + 17
Hydroxy-aceticacid Hypochlorous Cl,0 lodtne. potassium and Cl, gases
100 (38) 70 (21) room
(0.122-0.188)
gas
+ saturated 1 O-85 10
II-0.62(11-0.016)
lodtne in water
Iodide room 212(100) boiling 1500(816) 615-1100 (324-593) saturated room room 6OiXOO (316-482) 50 molten 5-20 S-40 saturated saturated 5-20 18-20 5 10 saturated saturated 100 106 91 300 (149) 1400(766) 8 1750 (954) 212(100) bolllng room room 212(100) 95 (35) 212(100) 212(100) 212(100) 212(100) room up to 100 (38) room 700(371) 95 (35) 700(371) 700 (371) 706 (371) 700(371) 5 20 50 10 20 30 40 50 60 70 10 212(100) 212(100) room room room room room room room room 104 (40)
Wr@s Nttncacid + 10% NaCIO, Nitnc acrd. saturated with ztrconyl Nrtncacid ziconyl Nitricacid NaNOs NaNO, and 329/l nttrate + 15% nitrate + 17991 NaCl
Iodine in alcohol Lacttc acid Lactic aced Lead Lead Lead acetate Lfnseedofl, Lrthium, botled molten
bolkng 33-45 65 20.8 27.4 245(118) 260 (127) bolllng bolting ambrent
0.12-1.40(.003-0.036) I! II S-11 6(0.127-0.295) 19-115(0.483-292) 0 26-23.2 (0.007-0.589)
Nitnc acrd + 170 g/l and 2.9 gl NaCl 011 well crudes. varytng amounts Oxalic of actd abraston
Lrthfumchlonde Magnestum Magnesiumchlonde Magnesium Magnestum Manganous Magnestum chlonde hydroxfde sulfate chlonde Maleic Mercuncchlonde Mercuncchlonde Mercuncchlonde Mercuncchlonde Mercunccyanrde Mercury Mercury Mercury Methyl Mercury Mercury Mercury Mercury Nickel alcohol + Fe + Cu + Zr + Mg chlonde 6H,O acid
1 1 25 saturated 106 99 saturated Solutlo 1 O-30 30-80 1 10 30 10 81
98.6 (37) borllng 140(60) room 86 (30) 86 (30) 70(21) room room borltng botkng bolllng 176 (80) 190 (88)
12 (0.025) 4247(1079) 470(11 9) 20 (0.508) 0.07 (0.002) kqurd 11 4 (0 290) vapor0 40(0.102) 0.8-2 (0,020-O lO(O254) 400(10 72(1 83) 2) 1030(26.2) 15(0.381) 051) 1 (0.063)
Oxaltc actd Oxaltc acrd Oxakc acrd Perchloryl Perchloryl fluonde fluonde + + liqutd CIO, 1% H,O Phenol Phosphonc Phosphonc Phosphonc Phosphonc Phosphonc Phosphonc Phosphonc acrd acrd actd actd acrd acrd
Z-30 (0.051-0.762)
acrd + 3% water
nttnc actd and 16% Phosphomsoxychlonde Phosphorus tnchlonde Pthaltc Potasstum Potasstum acrd Photographrcemulsrons saturated saturated saturated saturated 10 saturated room room room 140 (60) room room bromrde chloride 100 saturated room room 0 14(0 II <50(<0.127) II II II I II ethyl II II (continued) Ol(0 006) 004)
Nickel chlonde Ntckel nttrate Nttnc actd. aerated Nttnc actd. aerated Nltncactd. Nttncacid. Nttncacid. aerated aerated aerated
Potassiumchlonde Potasstumdtchromate Potassium Potassrumferncyanrde zanthate
Nttnc acrd. aerated Nttnc acrd. aerated Nltncacfd, aerated

AND TITANIUM
T 85 (29)
739
TABLE
5.26:
MEDIA
TITANIUM
C
13
ALLOYS-TIMET
R
II
(continued)
MEDIA Sodiumsulfate Sodium sulfide Scdlum sulfide Sodlum sulfite Sodium thiosulfate Sodium thiosulfate + 20% acetlc acld SolIs. corrosive Stannic chloride Stannic chlonde Stannicchloride, molten Stannicclonde Steam Steam 0.17% hydrogensulfIde mercaptans 100 100 saturated saturated 3.75 gl 7.591 7.591 100 major near 100 16 356(180) 365(165) room room bolllng boiling boiling 464 (240) 395 (202) room 600 (316) 0.1 (0 003) II II nil II lOS(274) 1.2 (0.030) II >43(>1.09) 0.1 (0.003) 0.2 (0 006) Sucww acid acid + air + 7.65% 5 24 100 saturated ambient 212(1Oq bolllng 150 (66) room 180 (82) 200.230 (93-l 10) II 0.12(0.003) 1.76 (0.045) nil II 0 01 (0.000) II
C
saturated 10 saturated saturated 25 20
T room boiling rwm bolllng boiling room
R
II 1.08 (0.027) nil II II nil
Potassium
hydroxide chlonde
+ 13% potassium Potaswm Polasslum

POtasslum
hydroxide hydroxide hydroxide hydrowde hydroxide lodlde
50 10 25 50
Sot0
80 (29) boiling bolllng bolllng 465-710 (241-377) room roi3m room 122 (50)
0.4 (0.010) cS.O(cO.127) 12 (0.305) lOa(2.74) 40-60(1.02-1.52) ml II o.t2(0003) 0.1 (0.003)
Potasswm Potaswm
anhydrous Potasstum Potass~m Potaswm saturated saturated 20 O-30 Potasslumpermanganate perchlorate perchlorate. KCL. O-5009 NaCI. O-25OgI N&IO,. Potasswm 6-24 g sulfate ~TI spec~mencafhodc) - NaCl0,.600-900gl
I I
10 1 vapor 35591 saturated 374 (190) room room 76 (24) 464 (240) room to 1100 (593) room boiling room room 150 (66) bolllng bolllng boiling room 104 (40) 100 saturated 25 saturated saturated 10 10 25 25 saturated O-721 g/t room II II rapld II II II II 0.3 (0.008) II good II 3.6(0.091) rapid II 72t1.83) II II nil II 0.1 (0.003)
Steanc actd, molten Succvw
Potass~umth~osulfate Prop~on~cacld Pyrogaltlc acid Sallcyllcacrd sodtumsalt Seanater Seawater, 4%~year test Sebaclc acld
Sulfamltc acid Sulfamlc acid Sulfamlc acld Sulfamlc acid + .3759/i FeCI, Sulfur. molten Sulfurmonochlorlde Sulfurdioxide, Sulfurdioxidegas water 4 saturated small amount SO3 and approx. 3% 0, Sulfuric acld. aerated wth air Sulfuric aad. aerated with a+r Suffuric acid, aerated with air Sulfuric aad, aerated with aar Sulfuric aad. aerated with air Sulfuric aad. aerated wth aw
Silver nttrate 50
Sodwm Sodlum acetate Sodlum aluminate Sodium blfiuorfde Sodwm Sodwm Sodwm blsulfate bisulfate btsulftte
1 3 5 10 40 75 75 75 1 3 5 80 80 concentrated concerttrated 1 3 5 1 5 5 30 30 30 30 30
140(W) 140 (60) 140(M)) 95 (35) 95 (35) 95 (35) roam bolllng 212(100) 212(1W) 212(1W) room boiling room boiling 212(1W! 212(100) 212(100) boiling boiling 200 (93) lW08) 200 (93) 100 (38) 200(93) 10008)
0.3 (O.W8) 0.5(0.013) 190 (4.83) 50(1.27) 340 (8.64) 42 (1.07) 427(10.8) 6082(1545) 0.2 (0.005) 920 (23.4) 810 (20.8) 316 (8.03) 7460 (189.5) 62 (1.57) 212 (5.38) 282(7.16) 830(21.1) loso(26.9) 700(17.8) lWO(25.4) nil 2.4 (0.061) 3.48 (0.088) 2.64 (0.067) 32.4 (0.823) 0.78(0.020)
Sod&urn blsulflte Sodiumcarbonate Sodwm Sodwm chlorate + + 14 g/l g/l chlorate
NaCl80-25091 Na,Cr,O, carbon 0.3-0.9 Scdwm
Sodium chloride chloride pHl.5 Sodium chloride pH 1.2 Sodwmchlonde. titanium in contact wthteflon Sodium chloride. pH 1.2 SOme dissolved chlorine Sodtum citrate Sodiumcyamde Sodiumdlchromate
saturated 23 23 23 23 saturated saturated saturated saturated 5-12
rmrn bolllng bolllng boiling boiling rwm room rwm room 230(110)
nil II 26(0.711) Corrosion In crevice nil II II nil 0.3(0.008) co.1 (<0.003)
Suffuric acid, aerated wth aw Sulfuric acid, aerated wtth av Suffuric aad. aerated with air Sulfuric acid, aerated with atr Suffunc acid. aerated with air Sulfuric acid, aerated with air Suffurfc acid, aerated with air Suffuric acid. aerated v&hair
Sodium fluonde
Sodturn hydrosulflde unknown A amounts of polysulfides Sodium hydroxide Sodwm hydroxide Sodium hydroxide Sodium hydroxide Sodium hydroxide Sodium hydroxide Sodium hydroxide Sodium hypochlorlte Sodium hypochlorite 12-15%NaCf NeOH + + 1% + l-2%
sodium sufflde and 5-10 10 20 40 50 73 50-73 6 1.5-4 70(21) boilmg room 176 (80) 135 (57) 265 (129) 370(188) mom 150-200 (66-93) 0.04 (O.Wl) 0.84 (0.021) 0.1 (0.003) 5.0(0.127) 0.5 (0.0127) 7.0(0.178) >43 nil 1.2 (0.030) (>1.09)
Suffuric acid. aerated withair Sulfuricacid. aerated with nitrogen
Sutfuricacid.aerated withnitrogen Sulfuricacid, aerated withnitrogen Sulfuricacid

Sulfuricacid Sulfuricaad, + 0.25% + 0.25% CuSO. cuso.
sodium catttonate Sodium nitrate Sodium nitrite Scd0pm perchlorate Sodium phosphate Sodium slkcate Sodium sulfate saturated saturated 900 g/f saturated 25 1 O-20 room room 122 (50) room boiling boiling nil nil 0.1 (0.003) nil nil nil
+ 0.25KCuSO. + 0.5%CuSO, + o.5%cuso. + 1 .O% cuso,
(continued)
740
TABLE 5.26:
MEDtA Sulfuric acid, aerated + 1.0% cuso, + 0 5% cro, + 0.5% CrCs + 1.O%cuso, Sulfuric acid vapors Sulturic acrd vapors Sulfuhc acrd vapors Sulfuric acid, + 10% HNO, + 30% HNO, + 50% HNOs + 70% HNO, + 90% HNO, + 90% HNO, + 50% HNO, + 20% HNOs Sulfuric acid saturated with chlorme Sulfuric acid saturated wrthchlortne Sulfunc acrd saturated withchlorme Sulfuric acid saturated wrth chlorine Sulfunc acrd + 4.79 glTi+ Sulfurousac~d Tannic acid Tartaric acid Tartarrc acid Tartaric acid Tartarrc acid Tartarrc acrd Tartarrc acid Tartaric acrd Terepthalic acid Tetrachloroethane. kqurd and vapor Tetrachloroethylene + H,O Tetrachloroethylene Tetrachloroethylene. kqurd and vapor stabrkzed wth ethyl alcohol Tin. molten Trtamum tetrachlonde Trtanrum tetrachlorrde
TITANIUM
C 30 5 30 30 96 96 96 90 70 50 30 10 10 50 80 45 62 5 02 40 6 25 10-M 10 25 50 10 25 50 77 100
AND TITANIUM
T 200 (93) 200 (93) 200 (93) boiling 100(36) 150(66) 200-300 (93-149) room room room room room 140 (60) 140(60) l40(60) 75 (24) 60(16) 374(190) 122 (50) 212(1W) room 212(1W) 212(100) 140(60) 140 (60) 140 (60) 212(1W) 212(1W) 212(100) 425(216) boollihg boiling
R
ALLOYS-TIMET
(contlnud)
MEDIA Urea + 32% ammoma, r 20.5% H,O. 19% CO Water. degasss Water, over. saturated wth Cl, Water, synlhetrc sea X-ray developer solution Zinc, subjected to zinc ammonium chloride oreflux C 26 T 360(162) 600(316) 2w (93) 95 (35) room molien
Fl
34.8 (0.884) nil nil 65 (1.65)

nil nil 0.4-0.5(0.010-0.013) 16(0.457) 25(0.635) 25(0.635) 4.0(0.102) I-VI 0.45(0.011) 15.7(0399) 62.5(1.59) 0.13(O.W3) 0.07(O.W2) <1(<0.025) >47(>119) passwe
3 l(O.079) IllI hll hll hll wthstood several thousand contact cycles l-M* nil 24(0.610) 6000 (203 2) nil
100
Zincchlonde Zinc chloride Zinc chlohde Zmc chloride Zinc sulfate
20 50 75 60 saturated
* May corrode
* TiCode-
in crevices
(Ti-Pd) immune
Corrosion Rate Data TiPd C = Concentration

T -= Temperature Oo F
(C)
mpy (mrny) 1 212(1W) 212(1W) 310(154) 350(177) room room boiling tkxkng bmkng room room room 156 (70) 158 (70) 158 (70) 158 (70) 158 (70) 156 (70) 374(190) 374(190) 3741190) 374(190) 158(70) 158(70) 158 (70) 158 (70) 158 (701 374(190) 374 (190) 374 ( 190) 374(190) 374(190) borkng bolllng borkng bolllng bolllng bolkng bollmg borkng bo,!lng 374(!90) 482 (250) borkng 374(190) 462 (250) R (1 (~0.025) 1 (0.025) MI ml skght gam <l (~0.025) skght gam skght gam 3 (0 076) < 1 (-0.025) 4(0 102) 11 (0.279) 3(0.076) 3 (0.076) 7 (0.176) 13 (0.330) 61 (1 55) 169(4 29) l(0 025) 4 (0.102) 350 (6 69) 1620(41 1) b: 1 (~. 0.025) 2 (0.050) 6(0 152) 26 (0.660) 78 (1 98) 5(0.127) 5 (0.127) 368 (9 34) - 1 (.O 025) 1140(29OJ 7(0 178) 32(0 613) 267 (6 78) 770 ( 19.6) 11 (0 279) 3 (0 076) 113(267) 5(0 127) 146(3 71) 9412 39) sl1ghtgarn 26(0 661 sltght garn slightgafn
R = Corrosion rate.
MEDIA Alummum Chlohde Calcium Chlorrde Chlorine, wet Chlorme, H,OSatd. Chromrc actd Ferric chloride Formrc actd Hydrochloncacrd. H,saturared c 10 25 62 73 10 30 50 l-15 20 25 1 5 10 15 20 25 3 5 10 15 land5 10 15 20 25 3 5 10 3and5 10 5 10 15 20 lo 10 20 10 20 30 30 65 65 65
nil ml <5(<0.127) 0.10 (0.003) 0.10(0.003) 0.02 (0.001) 0.13(0.003) nil 0 2.0.49(0.005-0.0121) ntt 0.02(0 001) 5 (0.127) orI 0.02(0001)
100 100
bolllng bolllog
100 99.6 trated 100 99
930 (499) 572 (300) room bowg bollng 70- 194 (21-90) 165
resistant 6211.57) hII 573 (14.6) 0.1~5(0003-0.127) hII ,.O.l (iO.003) Hydrochloncacrd. 0, saturated Hydrochloncacrd. Cl, saturafed Hydrochlorrc acrd Hydrochloricacrd. Air saturated
Tnchloroacetlc acrd Tnchloroethylene Uranium chlohde Uranyl ammomum phosphate filtrate + 25% chloride + 0.5% fluorrde. 1.4% ammoma + 2.4% uramum Uranyl nrtrate contamlng25.3g.l Fe..6.9g.l Cr..2 8gjl NI 1.5.9molar NOB 4.0 molar H _, 1.O molar Cl Uranyl sulfate + 3.1 molarL@O,, + too-200 ppm0, Uranyl sulfate * 3.6 molar LI,SO,. 50 psi O2 Urea-ammoma reactloo mass
20.9
120 g. I u
bolllng
012 (0.000)
3.1 molar
482(250)
O-0.76 (. 0 020)
3.8 molar
662 (3501 elevated temp. and pressure
0 22-17 (0.006-O 432) no attack
Hydrochloncacrd - 5g IFeCI, * 16glFeCI, + 169 IFeCI, A 16g.ICuCI, + 169 ICuCI, Nrtnc acrd
(continued)
Nonferrous
Metals and Alloys
741
TABLE
5.26:
MEDIA Nitricacid,
TITANIUM
C 60 10 10 5 IO 40 60 60 95
AND
T
boiling boiling 200 (93)
TITANIUM
R
ALLOYS-TIMET
(continued)
MEDIA Sulfunc acid + 0.0I?~CuSO~ + o.o5%cuso, + 0.50% cuso, C T Fl
Unbleached Phosphonc acid Sodium chlonde EInne Sodrumchlonde Sullurlc acid. N, saturated
15 5 (0.394) 5 6(0.147) 0 0005 (0 000) 1 (, 0 025) cl(.-0025) 1 (0 0251 9 (0 229) 34 (0 664) 645116 610 152) IO (0 254) 67(221) 164 (4 67) 226 (5 74) 62 (1 57) 5(0 5(0 59(1 5(0 127) 127) 50) 127) MEDIA Ammonium 4)
30 30 30 30
boiling boiling bolllng bolllng
1090 (27 7) I310(33 79 (2.01) 69 (1.75) 3j
I .O% cuso.
374 (190)
r0Cllll room rOOm room WXTl rOOm
Corrosion
Rate Data for TiCode% F (C)
66 (1 73)
Sulfuncacid. N, saturated
5 IO 40 60 80 96 I 5 10 20
156 (70) 156(7Oj 156 (70) 156(70) 156 (70) 156 (70) 374 (190) 374(190) 3741190) 374(190) 374(190) 374 (190) 374(190) 374(190) 374 (190) 374(190) 374((19Oj 374 (190) 374(190) 156(70) 156(70) I56 (70) 156 (70) 158 (70) 156 (70) boiling boiling boiling boiling boiling bolllng boiling bolllng
C = Concentratton T r Temperature
R = Corrosion rate, mpy (mm/y) C

30 10 (I pa HNO, - 3 parts HCI) Ammonium Chloride Chlonnecell off-gas Citric acid Formic acid Formic acid Fonicacid Hydrochloric Hydrochloric Hydrochloric Hydrochloric acid acid acid acid 50 45 06 90 5 5 5 2 3.32 4.15 0.54 1.06 1.62 190 (66) boiling bolllng boiling boiling 120 (49) 150 (66) 2OOwj 200 (93) 196(91) 196(91) boiling bolllng boilrng ,035 (0.001) 0.5 (0.013) nil nil 20.5(0.521) 0.1 (O.qo3j 0.2 (0.005) 1176 (29.9) 1.2(0.031) 1 .O (0.025) 2.3(0.056) 0.6 (0.015) 35.4 (0.699) 576 (14.7) 0.6 (0.020) saturated 10 bo1lrng boiling II nil 500 hours acrdifled lo PHI 5% NaOCl NaCl + + 2% bolllng saturated 600(316) 2.4 (0.061) II 500 hours 500 hours NaCl natural aeration natural aeration natural aeration 3700 hours 10 boiling nil T bolllng boiling boiling R nil nil 24 (0.610)
Remarks no hydrogenplck-up 500 hours
hydro-
oxide AlumlnumChlonde Aqua regla
355 (9 02) 3 (0 076) 5(0.127) 59 (I .50) 2440 (62.0) <l (~0.025) 2(0.051) 15(0.361) 3060 (77 7) 3 (0 076) 4 (0.102) 37 (0.940) 392 (9 96) 447(114) 63(2.11) 20 (0.0511 j 59 (1.50) 207 (5.26) 7 (0.176) ~1 (~0.025) 6(0.152) 67 (2.21) 25 (0.635)
Sullunc acid. 0, saturated
1 5 10 20 30
Sulfuncacid. CI,saturaled
1 and 5 10 20 30
Sulfuncacld. Air saturated
5 10 40 60 60 96
Sullunc acrd
5 10 20
HCI + 2g/l FeCI, HCI + 2g/l FeCI, Sulfuricacid Sulfunc acid Sulfunc acid Vapor above boiling HNO, MgClz Sodium Sulfate
Sulfunc acid + 0 591 Fel(SO,)s + 16gIFe,(SO,j, + 16g/lFe,(SO,j, + 4Og:I Fe&S0,j3 Sulfuric acid + 15%CUSO, Sulfunc sod t 10% FeSO, I70 g/l T102 23 to212(IOOj 64(2.13) 11% Solids. and 15 10 IO 20 40
4% NaOH
Titanium
Timet Designation ASTM Grade
Alloys Used in Industry

Yield Strength (min.) 0.2% Offset
Ultimate Tensile Strength (min.) 35,000
Nominal Composition
Ti-35A Ti-5OA Ti-75A Ti-6AI-4V Ti-Pd TiCode-
1 2 4 5 7 12
50,000 80,000 130,000 50,000 70,000
psi psi psi psi

PSI
psi
25.000 40,000 70,000 120,000 40.000 50,000
psi psi psi psi psi psi
C.P. Titanium C.P. Titanium* C.P. Titanium* 6% Al, 4% V 0.15% Pd 0.3% MO. .8% NI
Commercially
Pure (Unalloyed)
Titanium
742
TABLE 5.27:
ZINC ALLOY-NEW
JERSEY ZINC
The following are the ASTM Specification B 86 requirements for Zamak 3 die castings: Ingredient Alloy AG 40 A (Zamak 3)* % by Weight 3.5 - 4.3 .25 Max. .020 - .05 .005 Max. .004 Max. .003 Max. .lOO Max. Remainder
Aluminum Copper Magnesium+* Lead Cadmium Tin Iron Zinc
*Zinc alloy die castings may contain nickel, chromium, silicon, and manganese in amounts of .02, .02, .035, and .5% respectively. No harmful effects have ever been noted due to the presence of these elements in these concentrations and therefore, analyses are not required for these elements. **Magnesium may be as low as .015% provided that the lead, cadmium, and tin do not exceed 803, .003, and .OOl% respectively. THE CORROSION RESISTANCE OF ZINC ALLOY DIE CASTINGS
Zamak alloys have the strong resistance to atmospheric corrosion and weathering that has been associated for centuries with rolled zinc and zinc-coated iron. This corrosion resistance was confirmed by 10 years of test data compiled by NJZs research department and the appearance of die cast test bars after 20 years of exposure at the several ASTM exposure sites. Corrosion of Zinc, Galvanized Iron, and Zamak 3 (Penetration in Inches per Year) Palmerton, Pa. New York City .00028 .000064 Rolled Zinc .00027 .000052 Galvanized Iron 80022 .000078 Zamak 3 The above data establish that zinc weathers slowly and uniformly, with the corrosion rate influenced by the degree of industrial contamination and the frequency of fogs and mists. HYDROCARBON FUELS AND LUBRICANTS In the absence of moisture, zinc alloy die castings are strongly resistant to attack by acid-free hydrocarbons. In the presence of water some corrosion takes place which, while not seriously detrimental to the strength of the casting may, in the case of fuel handling devices, create some binding or clogging effect. It may be commented, in general, that no lubricants of animal fat origin should ever be used with zinc alloy die cast parts. This restriction applies also to those proprietary oils which contain varying quantities of animal oils in the formula. INK Printing inks appear to have little or no effect on zinc. The use of zinc engravings and lithographic plates in the printing industry gives ample evidence on this point.
(continued)
743
TABLE 5.27:
ZINC ALLOY-NEW
JERSEY ZINC
(continued)
ALCOHOL While pure ethyl and methyl alcohol are considerably less corrosive to zinc than water, mixtures of alcohol and water are more corrosive than water alone. This fact, combined with the probable presence of iron rust, makes undesirable the use of zinc alloy die castings in automobile cooling systems except in the presence of a suitable inhibitor. Alcohol-water mixtures represented by beverages are a special case, as the use of zinc alloy die castings in direct contact with potable alcoholic mixtures is not recommended. GLYCERINE Pure glycerine produces a smooth, light etch on the surface of the Zamak alloys. There is evidence, however, that glycerine-operated door checks and similar devices can be satisfactorily made of zinc alloy die castings. Glycerine-alcohol mixtures produce only a light surface etching on the Za, mak alloys when a pure grade of glycerine is used. The presence of water or the use of a low grade glycerine will result in pitting. INSECTICIDES In dry form insecticides have relatively little action on zinc. In water solution, those materials which contain copper, arsenic or lead tend to accelerate the corrosion of zinc by electro-chemical replacement. It is not recommended that zinc alloy die castings be used in insecticide spray devices. SOAPS AND CREAMS Ordinary good grade laundry soaps have a definite inhibiting effect on the corrosion of zinc in hot water. This is particularly well illustrated in the practically perfect surface found on washing machine drain cocks after years of service. In recent years soaps have largely been replaced by detergents, some of which are corrosive to zinc die castings. TRICHLORETHYLENE - CARBON TETRACHLORIDE In short periods of exposure necessary for degreasing prior to electroplating, neither trichlorethylene nor carbon tetrachloride will have any visible effect on zinc alloy die castings. Dry carbon tetrachloride has no visible effect on continued exposure of much longer duration. Dry trichlorethylene over a period of four months shows a very slight etching action. ILLUMINATING mak alloys. GAS Dry illuminating gas has no apparent effect on the Za-
FOODS AND BEVERAGES It is the considered opinion of medical authorities who have studied the subject that zinc salts in moderation are not toxic. Where moisture and acidity are encountered, zinc salts may accumulate. In sufficient quantity these salts are irritating and may cause nausea. Such applications of zinc alloys should be scrupulously avoided.
744
Corrosion Resistant Materials Handbook ZINC COATING-ALCOA
TABLE 5.28:
Corrosim
12-YEAR lNSPECTION PANEL TYPE ZINC OF PANEL COATING TYPE TESrSrrB RESULTS TYPB PREPARATION THICKNESS,
l l l
Tests
ON METALLIPD 2 I 0.003 wP+Av-1 ZINC COATED 3 1 0.003 CR-2 CARBON STEEL 4 1 0.006 N= PANELS
OF ATMOSPHERlC
EXPOSURE I 1 0.003 NO=
TESTS
inches
OF SEAL COAT
ENVIRONMENT
coLuMBus.
OHIO
URBAN
Base metal shows red Nsroa3%ofthe front of the DaneIs. Spnycd me& shows red tust stain on 60 % of the remainder of the front. Back of wnefs chin ahi~rusc .
Base metal shows red tusr staining. S rayed merrl shows I 5, staining OQ 60 % of the from nuface. CR seal coat dissipated on front. Sal coat 00 back lmaffccmd. Base meal ax attacked. Sprayed metal intact. CR seal coat on from of panel.9 completely dissipated, showing a gencrpl fight PY deposit stain. Seai car on back una&cred.
Ease meal nm atacked. Sprayedmeal in9a. bur shows very chin white nut OD front and back of paoelr
INDu.sTRuL
Basemetal 10% exposed on front of panels and 1% on back, showing red nut in these areas. Sprayed meal shows red nut stain on 25 % of the ygtz k_rq+a~d
Eksc meal ncx amcked. s rayed mad 00 froot o P panels shows a general Ii r dcpair ruin. Bat p d panel9 show a pnctal very thin whm run
on back.
Base meal LI(X nmckui. Spnyed metal showa many pinpoint nodea and some medium sized noda of white rust a0 front of panels. Vinyl seal car 75 % dissipated 011front. sprayed md pinpoint nodes of white nut. Viny1 ral coat SO% dissipated 00 back. Base mad shows red fust. Spayed metal 00 from of panels show redtusr0tl50% oft& sutface. CR seal copr is dissiparcd OD. nel fronts. Back or paneIs s$ygd. h Base metal *oc am&d. Spayed meal shows
KURB BEACH. NOR:% FRYLJNA
rusrova65% ofthe front of thepond. Back of panels shows red rust alon& buxom edge. Edges of jnnels show thick ahm tusr.
cm back shonrmall7
KURB BEACH, NORTH CAROLINA ( 800~ft la)
SALT-AIR
Base metal not atracked. S rayed meal w front d panels shows vev thin white tusr. ahach is ptcsem as horizontal scnpes. BDck of panela shows a ray rbm white Iuc Base metal shows red rust on front of pan& Sprayed metal on frost is complmly dissipated. 00 back of pan& spnyedmetalislS% dissipnr$ and the $$;e~ maaf Reminder me$olcka of sprayed rbor
Bw meal tmt am&d Sprayed meal intact. VinM&coar
Base mcpl nor amcked. S rayed me& on front o P panels show a very thin white nut. Spnycd metal intact 00 back. CR seal 0x1 is completely dissi r~o~~~ front and Izc . Base metal OII front of anelr shows ted nut. s prayed metal on from is rained with ted luff. CR seal coat is comlet& dissipated oa P rotIt. sprayed meal imacr on back. Seal coat oL1back ullaaacd.
Base meal not am&d. Spmyed metal shows traces of very thin white tusr on from and back of panels.
Base meal nor am&cd. Sprayed metal iprarr wn&lseal&c II
INDUSTRIAL NEw y= Cxn!
Base metal DO(am&cd. s tared metal on from o P pnnelr shows a thin deposit stain. Sprayed meal oa back shows a ety thin white Nx.
SALT&R
Base meai not amckcd. s rayed metal oil front d panels shows large light blue-green stams. S rayed metal on back o P paneIs shows general datk gray stains.
Base meal not amckcd. Base metal not affected. Spnyed metal show S rayed meal on front whim rust node and o P pen& shows general green stain o* 1520% thin white tust with of the from of panels. green stains Spnyed Vinyl seal coat diui ared metal on back shows blotchy white tust. CR 00 same 15-20% B seal coat completely panel fronls. s rayed meal shows wriate rust dissipated O(I both sides. Edges show thick white noda on 3,S% pf back zg$;F;a!a -
SaeuTypel.
(continued)
745
TABLE
5.28:
ZINC
COATING-ALCOA
(continued)
12-yEAR INSPECTION RESULTS OFATMOSPHEIUCEXFOSURITESTS

PANEL TYPE TYPE OF PANEL PREPARATION ZINC COATlNG THICKNESS.
l
ON METALUZEDZLNC
6 1 0.006
COATEDCARBON
7 1 0.009
STEEL P,QJEu
a 1 0.009
5 1 0.006
incha
EMCTC*GO.
INDUSTRIAL
.S~JIIC TIPC 2. 9)
SamcasType3.
SuneCrTmrl.
SameuTlpe2.
KURE BEACH, NORTH CAROLINA (80-h la)
ZZtZ5
Panela Missing,
KURE BEACH. NORTH CAllOWA ( 800-ft la)
SameuType3.
SameuTypel.
pdUCt.
(continued)
746
Corrosion
Resistant
Materials
Handbook (continued) EXPOSURE TESTS ON METALLIZED

9
l
TABLE 5.28:
ZINC COATING-ALCOA
I~.YEAR INSPECITON
RESULTS OF ATMOSPHERIC
ZINC COATED CARBON 12 2 0.012 CR-2
STEEL PANELS 13 2 0.015 NODC
PANEL TYPE TYPE OF PANEL PREPAB.ATION ZINC COATING THICKNESS,

l l
10 2 0.012 None
11 2 0.012 wP+Av--I
1 0.009 CR-2
incher
TYPE OF SEAL COAT TsT SITE
BNVLRoNhtBNT
coLuhtBus.
OHIO
URBAN
T%Z
?&
;:
Na Taad.
KURE BEACH, NORTH CAROLINA
(800.frla)
SALT-AIR
gz
SamcuTlpe2.
NEw CnY Z
LNDUSTFUAL
Et!
gg?
Na Taai.
tzed.
Y&d
(continued)
747
TABLE 5.28:
ZINC COATING-ALCOA
RESULTS
(continued)
EXPOSURE TESTS ON METALLIZED ZINC COATED CARBON STEEL PANELS
12.YEAR INSPECTION
PANEL
OF SEA WATER
lYPE
1 2
l
2 2
3 2
4 2
BASE hiETAL PREPARATION
ZINC COATlNG THICKNESS, incha TYPE TEST OF SW SITE COAT

l l
0.003
0.003
0.006
0.006
CR-1
CR-2
None
CR-1
ENVLRONMENT Base mernl shows deep corrosion pita over 20 % of the pa&l surfice. from and back Spnyed mm1 show generaI red aad white rust ovet the entire sutface. CR sal coat is completely dissipated. Barn mm1 shorn deep corrosion pits and Iti of steel at the edge& Spnyed meal shows ted nut. CR suI ccat complnely dissipated. Base meal shows deep corrosion pin and loss of steel at the edges. Sprayed mccaI show ted rust and rut stains. CR suI CODIcompletely dissipated. Base mcol shows dee corrosion pits ovct 4- 8 % of rhe p&l surface, from and back. Sprayed metal rhows general ted and white tust over the attire surface. CR sea1 copt is completely dissipated Base metal shows deep corrosion pi0 over 1% of the paiic1 sufnce. front and back. Sptayed metal show thin white rust and Iarge ted nut stains. front and back
FREXPORT. TEXAS
TOTAL IMhfERSION
Saw as Type 2.
WRIGHTSVILLE BEACH, NORTH CAROLINA ( b&w-low-tide)
TOTAL IhlhfERSION
btIXtUTlp1.
Base metal show cottosioo pits and lom of rtel at the edge. Sprayed metal sha scattered red rust.
SameuType
1.
WRIGHTSVILLE BEACH, NOR~~_~dO~A
Same as Type 1
Base metal sha deep corrosion pits and lar of steel at the edge& Sprayed metal sha ted tusandtwtstaitu.
Same u Type 1.
PANEL
-lYPE
5 2
l
6 2
7 2
6 2
BASE MFTAL PREPARUION
ZINC COATING THICKNESS. incho TYPE TEST OF SW SITE COAT

l l
0.006
0.009
0.009
0.009
CR-2
NOtK
CR-1
CR-2
ENVIRONMENT Base mcmI LIQ amckcd. Sprayed metal shows enI white nut ovct r 0% d&epMel uuface,frontMdbuk.
SameuTypc2.
Tot panels Lost-1965
FREEFQRT.
TEXAS
TOTAL IMMERSION
Same as Type 2.
Bucmrcllthorroolas of necl. Sprayed PI WRIGKTSVTLLE BEACH. NORTH CAROLLVA ( below-low-tide) TOTAL IMMERSION SameuTyp I. z!rzzf:
Bucmecnlsba~few corrosion pio and lorrofstcel~ithe cd&. spnSpn~et.& amI cat cotnplealy diuiaaed.
Basemenlnocmackcd Sprayed metal shows vhitc rust ovu eatire surface. CR seal cost complctcl9 dissipated
WRIGHTSVILLE BEACH. NORTH CAROLINA (man-tide)
?S%F
ATMC&ERE SEA+ZER SUUeuTgpC 1.
Buetnetdshowlrd amout of corrosion. SpnyedmcraIshoasred runandrusts&u.
SlmcuTlpcl.
Base men1 not rtackcd s rayed mcol compPetely corroded showmg white rust. CR ual colt CompI~Iy dissipated.
(continued)
748

(continued) EXPOSURE 9 2 0.012 None TESTS ON METX.LIZED ZINC COATED CARBON STEEL PANEI. 10 2 0.012 al-l I1 2 0.012 CR-2 12 2 0.01s NW 13 2 0.018 NW
TABLE 5.28:
ZINC COATING-ALCOA
12.YEAR INSPECTION
RESULTS OF SEA WATER
PANEL TYPE BASE METAL. PREPARATlON l ZINC COATING THICKNESS. in&n TYPE OF SW TEST SITB COAT
l l
ENVIRONMENT Tat paneIs La-1965
Tat pmelr La-1965 FREEPORT. TEXAS TOTAL IMMERSION
Tar pmelr Last-1965
~.!f&
ZkZi%
WRlGHTSVILLE BEACH, NORTH CAROLINA ( below-low-ride)
TOTAL IMMBRSION
smbeuTIpe8. tg? g? gz
WRIGI4TSVILL.E BEACH, NORTH CAROLINA

(
Ami%F
AT&&J? SEA WATER
Base mea1 Dot mskmi.
TFgL
T%Z
TEg
T%a
man-tide)
(0 American Welding Society, Inc.)
749
TABLE
5.29:
ZIRCONIUM
ALLOYS-TELEDYNE
WAH
CHANG
ALBANY
Zirconiym is used in a wide variety of industrial and chemical processing applications. This wide use is due to zirconium s excellent resistance to many chemical solutions, even at elevated temperatures and pressures. Zirconium is very resistant to corrosive attack in most organic and mineral acids, strong alkalis, and some molten salts. Because of zirconiums unique corrosion properties, it is an excellent material for use in chemical processes which require alternate contact with strong acids and alkalis. Zirconium alloys are not readily attacked by oxidizing media unless halides are present. It has excellent oxidation resistant properties to 400C in air, steam, carbon dioxide, nitrogen and oxygen. Zirconium alloys have little need for anodic protection systems. Zirconium alloys have high resistance to localized forms of corrosion, pitting, crevice corrosion, and stress corrosion cracking. The combination of these factors make zirconium alloys suitable for use in a wide variety of corrosive environments.
Chemical Compositions of Zircadyne Alloys

Grade (ASTM Designation)
Chemw.l Zr + Compositions. Percent 99.2 4.5 020 max. j 97.5 4.5 0.2-0.4 1 O-z.0 max. max. max. 0.005 0.025 0 05 0.16 0.16 0 005 0.025 0.05 95.5 4.5 0.2 0.005 0.025 0.05 2 O-3.0 0.16 max
Zircadyne 702 (R60702)
Hf. mm. max.
Hafnium. Fe Tin Hydrogen. Nl!rogen. Carbon, + Cr
Zirconium
CCJNCENTRATION CORROSIVE MEDIA 46
Corrosion
Data
, RATE. mpy Zr 705 REMARKS
CORROSION TEMPERATIJAE C Zr 702
Zr 704
Acelaldehyde Acetvz Acid AcetIc Acellc Ac:d (anhydrIde) Acid (glacjal) Chlorale Chloride
100 5-99 5
Bollmg 35-Boiling IRoom-Boiling Bolllng 100 35- 100 Bolllng 100 60
<2 <l
Cl
-Tgg
99 7 30 5. 10. 25 25 40
~1 <5 <2 Cl <; <2 <2 >50
1 _ _
~1 _ _ <l _
Aluminum Alummum
Alummum
Chloride
(aerated)
5, 10
Alummum Alummum Alumuum
Fluoride Potassum Sulfate Sulfate
I 20
10 25 60 + water -
Room Bolllng Boiling 100 36 193
1 -
1 -
1PH
= 3.2 = 32
I I
n,, 1 nil <2 <5 <, _ -
1 ml 1pH
ml -
Ammonla Ammonium
(wet) Carbamate
56.4% Urea. 16 0% Ammoma. 14 6o CO>. 9 9% Hz0 at 3.200-3.500 PSI
(continued)
750
Corrosion Resistant Materials Handbook ZIRCONIUM ALLOYS-TELEDYNE WAH CHANG ALBANY (continued)
TABLE 5.29:
CORROSION RATE, mpy

CONCENTRATION TEMPERATURE
CORROSIVE MEDIA
OC
Zr702
Zr 704
Zr705
REMARKS
Ammonium Chloride Ammonium Hydroxide
11.10. saturated
28
20
135-100 IRoom20 96 100 100 35- 100 100 Room 35 100 Boiling 20 20 100
1 4 1
<l x50 >50 <2 <5 41 c2 >50 Cl 5-10 Cl0 c2 < 2 <2 Cl Cl c5 Sl
1 / _ _ -
1 1 _ 20-50 250 -
1 1
pH = 6 pH = a
20 Ammonium Oxalale Ammonium Sulfate Aniline Hydrochloride 100 5. 10 5. 20 5.20 3:l 5. 20 25 loo-Liquid Vapor 100 100 100 5. 10. 25 70 75 Mrxture
Aqua Regia Banum Chloride
3 parts HCI/l part HNO,
Bromrne
Prtting Pitting
Bromochloromethane Cadmrum Chlonde Calcrum Bromide Calcium Chlonde
I
I
Room 100 35-l 00 Boiling Bowling 79
I -
I - I -I
I -I
Cl B.P. = 162OC 14% CaCI, 6% NaCl 0.2% Ca(OHb pH = 5 pti = 5
Calcium Fluonde
Saturated Saturated 2. 6, 20 Saturated
28 90 100
nil nil c5 -=5 1~ 2 >50 >50 250
Calcium Hypdchlorite Carbonic Acid Carbon Tetrachloride Chlorine (water saturated) Chlonne Gas (more than 0.13% H,O) Chlonne Gas (dry) Chlorinated Water Chloroacetic Acid Chromrc Acid Citric Acrd
I 1
100 Room-100 Room 75
I 1 -
I -I
I -
1 o-100
100
94
100 100 10-50 1O-50 10. 25, 50 50 -
Room 100 Boiling Bolting 35-100 100 Boiling
c 5 c2 c 1 c 1 < 1 Cl c 5 -
Chrome Plating Solution Cupnc Chloride
66 I
35-l 00 Boiltng Room Boiling Boiling Boiling
12-50
1 150 >50
1 s-50(;;:hemicals I
>50 >50 W.G. B.P. = 115C
I 5. 10, 20 20, 40. 50 Saturated 40 100 100
250 >50 =-50 W.G. 420 c5
Cupric Cyanide Cupric Nitrate Dichloroacetic Acid Ethylene Dichloride
(continued)
Nonferrous Metals and Alloys TABLE 5.29: ZIRCONIUM ALLOYS-TELEDYNE WAH CHANG ALBANY (continued)
751
CONCENTRATlON
TEMPERATURE
CORROSION Zr 702
RATE. mpy
CORROSIVE
MEDIA
Ferric Chloride
O-50 O-50 IO 6-37 O-70
Room- 100 Boiling O-100 Bolllng Room- 100 Elevated Room 35Boiling Room-l 00
>5( xi< <; ( C; >5( >5c <: <E < ml 1 1
Ferric Sulfa& Formaldehyde
Fluoborlc
Acid
5-20 10 1 O-90 1O-90
FIUOSIIIC~CAcid Formic Formic Acid Acid (aerated)
Hydrazlne
Hydrobromlc
Acid
40 Mixture
Bolllng Bolllng
<5 < 1
Hydrochloric
Acid
2 5 10 20 32 32
225 Room 35 35 30 62
1 c 1 c 1 < 1 <1
c < 5-10 <5 < 5c5 <5 Dlssolvec DlssClW ==50 1
20% HCI + Cl, gas 37% HCI - Cl, gas 10% HCI * 100 porn FeCI,
I-
58
I56 I30
II-
I I0
Hydrogen
PeroxIde Actd
50
100
c2 c5 Cl < <2 rlll
Hydroxyacetlc
I-
140
1 1
1 _
ml c 1
Manganese L4ercurlc
Chloude
1 5.20
1 -Saturated Saturated
Room35-100 Bollmg 35-100 100 Boiling
100
<
Chloride
<
<
Wkel
Chloride
5. 20 5-20 30
c 1 < I ml <
1 =z 1 c 1 -=z 1
< 1 < 1 -
rlll < 1
< 1 -
SCC
Observed
(continued)
752
Corrosion
Resistant
Materials
Handbook
TABLE 5.29:
ZIRCONIUM
ALLOYS-TELEDYNE
WAH CHANG ALBANY
(continued)
1
TEHPEPATURE
CORROSION zr 702 ( 1 1
RATE, ml i!r 7( _
CORROSIVE
MEDIA
"C
Zr 70 4 _ -
N~lrft Acid N,tr~c Acid Ntlrlc Acid
+ 1% Fe
l
65 65
204 _-
c ml
1 45% 304 S S
* 1% Cl-
fas NaCI) N~trlc And * 1% S&water
N!lr~c 4cfd * 3xaa Acla
1 FeCli o/o
100 100 Salurated Roar-
llll <
?erch?sr~c Acfd Phenol Dhosphorlc Acid
F
_-
c2 <5
5-30 5-35 5-50 35-50 45 50 65 70 05 65 65 MIXlUre MlXtUIe MIXlUre
Room 60 100 Room Eolllng Bolllng 100 Bolllng 38 60 Bolllng Room Room 69 60 Room 26 90 Bolllng 27 Bolllng Bolting Bollbng 241.377 29 Room- 100 Room- 100 ROOfT
<5 C5 <5 c5 c5 <5 5-10 >50 5-20 20-50 >50 nil WG >50 .=
_ _ 5-10 _ _ -
)
_ _ _ _ _ -
10-l! c20 a50 20.5( >50 _ >50 _ _ _ _ _ _ _ _
B.P = 106C BP = 123-126C
BP = 156C 36% t&PO4 + 0 5% HNO, 36% H,PO, + 5% HNO, 35% H,POa + 4% HNO,
otassium
ChIctIde
Saturated Saturated
<
nil
1
1
_ _ _ _ _ _ _ _ -
ofaswm
Fluoride
20 20 03
,H=09 ,H=69
a50 < 1 < 1
lolasstum
Hydroxfde
50 10 25 50 50.anhydrous Mixture
.z 1 < 1 <5 >50 < 1 <2 c2 <5 < .z 1
13% KOH.
13% KU
otasslum otassium
lodlde Nllrlte
iher NIlrate
10 ;odlum Chlortde 3-Saturated !9 3atutated ;aturated jaturated iodum iaturateo iodium iafurared iodtum iaturaled Chloride SO2 Chlorlae SO; Chloride SO,
l
-= 1
c _ < 1 _ idlusted rdlusled lo pH = 1 lo pH = 0 1 3P = 107oc
Bolllng 35.Bolltng 3ol!Ing =400m 301ilng 107 T30
<
< nil nil
1
1 1
< 1
35
!5
30
f-Ill
Saturated
30
nil
(continued)
753
TABLE 5.29:
ZIRCONIUM
ALLOYS-TELEDYNE
WAH CHANG ALBANY
(continued)
CORROSIVE
MEDIA
REMARKS
Sodium
Ffuorlde
Sodum
Hydroxide
9-11%
NaOH.
15% N&l 10% NaCl &
10% NaOH.
7% NaOH. 7% NaCIO,.
53% NaCI. 60-l 00 ppm
nded salt-violent
jodlum jlannlc
Sulfide Chloride
juccinlc
Acid
O-50 100
100 150 20 20 30 60 50 50 50 60 100 100 100 100 100 100 130 130 140
<2 <2 <l C5 20-50 10-20 <l 5-10 a50 <5 <2 <5 Cl0 <20 >50 Cl <5
Cl >50 >50 >50 >50 _ Cl _ >50 -
Cl >50 Cl0 _ =-50 <5 4 <5 <5 _ 250 <5 Cl0
;ulfurlc
Acid
o-75 60 60 77 5 75 77 60 75 65 70 75 76 77 775 60 65 70
(continued)
754
Corrosion
Resistant
Materials
Handbook
TABLE
5.29:
ZIRCONIUM
ALLOYS-TELEDYNE
WAH CHANG ALBANY

CORROSION RATE. mpy Zr 705 <5
(continued)
CONCENTRATION CORROSIVE 3~1lur1c Acid MEDIA ?/, 56 62 64 66 69 71 72-74 75 Sulfuric Acid Fe Fex* 60 60
m.wEwTURE C Bohng Boihng Boiling Bohng Bohng Bohng BOlllng Boiling Zr 702 es -=5 <5 <5 <5 5-10 1 O-20 Zr 704 <1 >50 so REMARKS
1 O-20
20-50 -
+ 1000 ppm + 10,000 ppm Sulfuric + 200-l + 10,000 Sulluric Acid
Boiling Boiling
<, <5
BP
= 152-t
55OC
Added
as Fe&SO&
000 ppm ppm Acid Fe
Fe3
65 65
Boiling Boiling
<5 5-10
B.P. = 152-155C Added as Fe?(SO&
+ 14 ppm
- 141 ppm
Fe,ppm Fe3
+ 200 ppm + 1410 ppm-10.000 Sulfurtc + 10,000 + 20,000 Sullurlc Acid FeCI, FeC13 Fe& ppm ppm Acid
70 70 70
Boiling Boihg Bohng
5-10 10-20 >50
B.P. = 167-l Added
71 C
as Fe,(SO&
+ 1000 ppm
60 60 60
Bolllng Bohng Bohng
<5 <5 20-50
<5 ~20 20-50
<20 20-50 >50
+ 200 ppm FeCI, + 1000 ppm FeCI, + 10.000 ppm FeCI, Sullurlc Acid + 10 ppm F&l, +
65 65 65
Bowling Bottling Boiling
c5 -=5 <5
c5 c5 -=5
<20 <20 <20
70 70 70 70 70
100 ppm
Bohng Boiling Boiling Boiling Boiling
<20 c20 <20 c20 20-50
<20 <20 c20 c20 >50
,50 a50 a50 >50 >50
FeCl,
+ 200 ppm FeCI, + 1000 ppm FeCI, + I 0.000 ppm Fe& Sulfuric Acid Cuz* ppm c1.12.
+ 200 ppm
+ 1000- 10.000 Sulfuric Acid
60 60
Boiling Boiling
<5 <l
Added
as CuSO,
+ 200- 10,000 Sulfuric + 3 ppm + 27-226 Sulfuric + 1000-l + 50,000 Sulfuric Acid CW ppm Acia
ppm
Cu2.
65
Boiling
<5
Added
as CuSO,
70 CW 70
Boiling Boiling
5-10 250
Added
as CuSO,
0.000 ppm ppm Acid NOa-
N03-
60 60
Bohng Bohng
<5 =-50
Added
as NaNO,
+ 200-1000
ppm NO,NO,-
65 65 65
Boiling Boiling Boiling
c5 10-20 >50
Added
as NaNOx
+ 10.000 ppm NO,+ 50.000 ppm Sullurrc Acid NO,NO,-
+ 200 ppm + 6000 ppm Sulfuric
70 70
Boiling Bohng
5-10 20-50
Added
as NaNO,
Acid N03NO3NO%60 60 60 Bohng Bohng Bohng c5 10-20 >50 Added as HNO,
+ 1000 ppm + 10,000 ppm + 50,000 Sulfuric ppm Acid
+ 1000 ppm
NOsppm N03-
65 65 Mwture Mlxlure Mixture MIxlure MIxlure MIxlure
+ 10.000-50.000 Sullurlc Acid
Bohg Bohg Room-100 Room- loo Bolllng 100 Room Bohng
<5 a50 Cl ml <l >50 Cl a50
a50 >50
Added
as HNO,
>50 >50
1% H,SO,. 14% H,SO,. 25% HsSO,, 50% HzSO,. 66% t-GO,,
99% HNOl 14% HNOl 75% HNO, 50% HNO, 5% HNOz
10% H&YiOa, 90% HNO,
(continued)
755
TABLE 5.29:
ZIRCONIUM
ALLOYS-TELEDYNE
WAH CHANG ALBANY

CORROSION RATE,
(continued)
mpy REMARKS
CONCENTRATION CORROSIVE MEDIA %
TEMPERATURE C Zr 702 Zr 704 Zr 705
Sulfuric
Acid (Cont.)
Mixture Mixture Mixture Mixture MIxlure Mixture Mixture MIxlure Mixture Mixture Mixture
Eoillng-135 Room Bolllng Eolllng Bollwig Boiling Boiling Bolllng Bolllng Bolllng Boiling
1 O-20 >50 <, <, <, 1-5 Cl <5 10-20 <20 >50
1 O-20 >50 _
>50 >50 >50
68% H,SO,. 75% &SO,.
1% HNOa 25% HNOa
7 5% H,SO,. 19% HCI 34% H>SOd. 17% HCI 40% H,SO,. 56% H>SO,, 60% H,SO,. 69% H,SO,. 69% H,SO,. 14% HCI 10% HCI 1 5% HCI 1.5% HCI 4% HCI
72% H$SOd, 1 5% HCI 20% H&O,. 7% HCI wtth 50 ppm F lmpuritles
Sulfurous
Acid
6 Saturated
Room 192
<5 5-50
756
TABLE 5.30:
TUNGSTEN
AND MOLYBDENUM-SCHWARZKOPF
DEVELOPMENT
Corrosion Behavior in Acids, Alkalis and Corrosive Solutions

Media Tungsten Molybdenum
. . . . . . . . . . . . . . . . . . . . . . . . At 2oc (68~). Hydrochloric acid, 10% Sulfuric acid, 10% Nitric acid, 10% Hydrofluoric acid, 3% Acetic acid, 10% Potassium hydroxide, 10% Sodium chloride solution, 3% resistant resistant resistant resistant resistant I.01 resistant
. . . . . . .. . . .. .. . . . . . . . . . .
resistant resistant resistant resistant resistant 1 .o* resistant
. . . . . . . . . . . . . . . . . . . . . . . At 100C (212F) Hydrochloric acid, 10% Sulfuric acid, 10% Nitric acid, 10% Hydrofluoric acid, 3% Acetic acid, 10% Potassium hydroxide, 10% Sodium chloride solution, 3% Corrosion resistant resistant approximately approximately resistant approximately resistant
. . .. .. . . .. .. . . . . . . . .. . . .
resistant resistant attacks approximately resistant resistant resistant
0.5+ 5 0.5*
5*
rate, grams per square meter per day.
TABLE
5.31:
COBALT,
Data
NICKEL
AND STAINLESS
STEEL ALLOYS-CABOT
STELLITE
Nominal Chemical Composition, Weight Percent
TRIBALOY T-400 CO Bal 30 28 5 8.5 26 .08 alloy T-700 30 El.91 _ 32 5 15.5 34 .OB T-800 B& _ 30 28.5 17 5 3.4 08
Comparative
Corrosion
concentration
Media and Temperature 50%. Baling lO%, Room Temp. 30%, 150deg.F (66 deg. 2) 45%. Boiling Hydrochloric Acid 5%. 150 deg. F (66 deg. C) 65%. 150 deg. F (66 deg. C) 65%. Bolllng Phosphoric Acid Sodium Chloride 65%. 150 deg. F (66 deg. C) 10% + 5% FeCl Room Temp. 5%. 150deg.F (66 deg. C) Sulfuric Acid 5%. Boilmg 10%. Ewmg Delermmed II laboratory tests. II IS recommended thal samples be lested de, actual plant codMms. T-400
TRIBALOY alloy T-700 T-600
STELLITE alloy No. 6
DELORO alloy No. 60 -
Stainless Steel Type 316
Acetic Ferric Chloride
Acid
Co+Fe Ni
Ni+Fe MCI
Cr Si
Formic
Acid
Maximum
U S E U U
Nitric
Acid
STELLITE Alloy No. 6: cobalt-base alloy DELORO Alloy No. 60: nickel-base alloy
Code: E-Less than 2 mpy (CO.05 mm/y) G-c20 mpy (co.51 mm/y) S-Dver 20 mpy (>0.51 mm/y) lo 50 mpy (1.2: mm/y) U-More than 50 mpy (~1.27 mm/y)
757
TABLE
5.32:
STAINLESS
STEEL, NICKEL
AND COPPER ALLOYS-CARPENTER
TECHNOLOGY
Corrosion Resistance Table This table shows the resistance of a number of materials to the more common chemicals. Many factors influence the resistance of materials to various solutions. Factors which must be given consideration for service in corrosive.environments are: temperature, concentration, aeration, influence of inhibiting or accelerating contaminants, influence of re-circulation, solids in suspension, velocity, frequency of use, and equipment design. The influence of contaminants is probably the most important from a commercial standpoint. Few corrosive solutions will be free of all contaminants. The majority of these contaminants have no influence on corrosion, but those that do generally affect the conditions greatly. The corrosion data for all grades except Carpenter 20Cb-3 stainless is reprinted from Corrosion Data Survey, 1974 Edition, published by the National Association of Corrosion Engineers. The corrosion ra!es for Carpenter 20Cb-3 stainless represent a composite of the NACE Corrosion Data Survey and more current data developed in Carpenters Corrosion Laboratory. Code: l Corrosion 0 Corrosion 0 Corrosion X Corrosion 360 6s2r
300-250 212-175 150-125 loo 75 257 212 167 --.__----.--___-I-_-_ 347 462
Rate less than 0.002 per year Rate less than 0.020 per year Rate from 0.020 to 0.050 per year Rate greater than 0.050 per year 20 4l 60 80 rml
60-25 777 *F e
20
4,;
60
80 in Water
too
Percent Concentration
(continued)
758
TABLE
5.32:
STAINLESS
STEEL, NICKEL
TECHNOLOGY
(continued)
(continued)
Nonferrous
Metals and Alloys
TABLE 5.32:
STAINLESS
STEEL, NICKEL
TECHNOLOGY
(continued)
/1
r 1
t a + ( 2 lY
(*
e
c c
tA _ t
F
1
3 ; .
Glutamc
ACld
(continued)
760
TABLE 5.32:
STAINLESS
STEEL, NICKEL
TECHNOLOGY
(continued)
(continued)
Nonferrous
Metals and Alloys
761
TABLE 5.32:
STAINLESS
STEEL, NICKEL
TECHNOLOGY
(continued)
(continued)
762
TABLE 5.32:
STAINLESS
STEEL, NICKEL
TECHNOLOGY
(continued)
Sodium Chloride
Sulfite
Liquor with 10% Sulfur Dioxide
Sulfur Chloride
(continued)
763
TABLE 5.32:
STAINLESS
STEEL, NICKEL
TECHNOLOGY
(continued)
Regtstered RegIstered
Trademark of Cabot Corporation Trademark of INCO
Footnotes for Corrosives:

1 2 3 4 5 6 7 6 9 10 11 12 13 14 15 16 17 16 19 26 21 22 23 24 m1son TOXIC Explosw Flammable Ingestlo poson Inhalant potso Attacks skin lrrttant Vapor harmlul lgnltes organics Fummg llqu!d Hygroscoplc Liberates HCI in water Narcotic Volatile Hazardous under pressure lgnttes combustibles FIR hazard Exptoswe war 70% lgnltes I moist arr at 30C Exothermtc in water Dust explodes Explosive dust Exothermlc wth water
Footnotes for Data Squares:

1 2 3 4 5 6 7 6 9 10 11 12 13 14 15 16 17 16 19 20 21 22 23 24 No water No aw, oxygen Low aw. oxygen Pits Stress cracks Sfress c~rros~~ Discolors Crewce attack Intergranular attack No chlorides May dwzolor May catalyze May pit May stress crack Transgranular attack Vapor Aerated Catalyzes Static Agttated -7 pH <7 pH >7 pH No HCI. HISOI. NaCl 25 26 27 26 29 36 31 32 33 34 35 36 37 36 39 46 41 42 43 U 45 46 47 46 No femc chloride -0.1% acetic actd Also sludge NO ro satts No sulfuric acid Explosive With HzSOI With steam No sutlur No stress No ammOma 300 psi Stress rekeved No HCI. Cu. Ni ions No Cu, Fe ums Over 70% aor ZO-70% air, 530 psi With sulfur, <34oC=x <10mg/1 No H&O. Go PSI No sulfides ~20% zinc Trace HCl 49 56 51 52 53 54 55 56 57 56 59 66 61 62 63 64 65 66 67 66 69 76 71 72 pti 2 to 3.5 Annealed, Immersed >2.25% MO Erratic With NaCl With NaCI. HCI. Hz02 No Fe. Cl Wtth +-0.05-l% HIPOI or HzSOI +SO, or HCOOH <RC 22,6O.CXXl Annealed No cold work No HIS Permeable to HP Unsullatad With or without steam 240 psi Cold worked >60% copper >20% sullur~c. bal. nitric acid No MO; low C Red turning Pits I chlorides over 4M)c 73 74 75 76 77 76 79 66 61 62 63 64 65 66 67 Steam and air 75-100% concentration Low NaCl With HCI <17% zinc ~0.23%. 2M) ps, 300 psi NO SOa No NaCl High pressure 75-120 ps, No sodturn sulhte + ammonia Avoid hydroxides Saturated
764
Corrosion
Resistant
Materials
Handbook
TABLE 5.33:
TITANIUM,
ZIRCONIUM
AND TANTALUM-ASTRO
METALLURGICAL
CORROSION RESISTANCE CHART FOR TITANIUM, ZIRCONIUM, TANTALUM

The reactive metals, titanium, zlrconlum and tantalum offer unusual resistance to most materials encountered In rhe Chemical Processing, Metal Finishing and Waste Treatment Industries. In many Instances they are the only metals that meet the service life requirements of the application.
THE IMPORTANCE
OF TEMPERATURE
IN MATERIALS
SELECTION
Corrosion data IS developed by exposing the material to environments at spectfic temperatures. However, when applied to process equipment. the fluid temperatures may not always represent the actual material exposure temperature. In evaluattng corrosion data, special attention should always be given to actual metal temperature in the particular environment. This IS especially important in selectIng material for heat exchanger services. Often solutions at higher temperatures than those recommended can be handled in a heat exchanger that is
designed as a cooler. This is due to the fact that the tube wall temperature will be below the temperature of the incoming solution. On the other hand. In heating applications. tube wall temperatures can exceed otherwise safe temperature limits even though the solution leaving the heater is within prescribed temperatures for the metal used. Consequently, in selecting material for heat transfer equipment, it is often important that theactual tube wall temperature should be computed before evaluating material selection for the planned process conditions.
MEDIA
CONCENTRATION %
TEMPERATURE TlTANlUM tlRCONlUM TI-PO F

150 Boiling Boiling Boiling Room 150 390 700 212 140 212 Room Room 212 Room Room Room Room 212 Room 104
TANTALUM
Acetaldehyde 100 Acetic Acid 5, 25, 50, 75, 99.5 Acetic Acid Vapor-33 Acetic-Glacial Acid 99.7 Acetic Anhydride 99 Acetone 100 Adipic Acid (plus 15/20% Glutaric Acid, 2% Acetic Acid ) 25 Adiponi trile Solution (NHJ) Vapor Alum 100 Aluminum Chloride (Aerated) 5, 10 Aluminum Chloride 25 Aluminum Chloride 25 Aluminum Fluoride Saturated Aluminum Hydroxide 100 Aluminum Nitrate Saturated Aluminum Sulfate Saturated Aluminum Sulfate (1% H&04) Saturated Aluminum Sulfate (1% Sodium Carbonate)Saturated Amidation Reaction Ammonium Acid Phosphate 10 Ammonia, Anhydrous (200 PSI) 100
A A A A A B A A C A A _ A A A A A A A
A A A A A A _ _ A A A A C A A -
_ _ A A _ _ -
A A A A
A A A C A A -
(continued)
Nonferrous
Metals and Alloys
765
TABLE 5.33: MEDIA

Ammonia
TITANIUM,
ZIRCONIUM
AND TANTALUM-ASTRO
METALLURGICAL IITANIUM
A A A A A A A A A _ A A A B A A B A A _ _ _ A _ A _ A A _ _ _ A _ C
(continued)
CONCENTRATION %
50 Plus Water 50 50 50 1, 10. Saturated 10 28 15-20 50 5. 10. Saturated 5. 10 10 98 5. 20 3HCL: 3:l
TEMPERATURE F
190 _ 212 212 Boiling 212 Room 80 80-190 212 Room 212 Boiling 316 99 Room 170
Ammonia Ammonium Bicarbonate 4mmonium Carbonate (Aqueous) Ammonium Carbonate Ammonium Chloride Ammonium Fluoride 4mmonium Hydroxrde Ammonium Perchlorate 4mmonium Sulfate 4mmonium Sulfate Ammonium Sulfate Ammonium Sulfate (Aqueous) Aniline, plus 2% AlCb Aniline Hydrochloride Aqua Aqua Regia Regra
_ _ _ _ _ _ _ _ _ _ _ _ _
_
A A A A C _ _ A A A A A A A
1 HN03
Banum Banum Bartum Banum Banum Banum Barium Banum Banum Banum
Carbonate Carbonate Chloride Chlortde Chlonde Chlonde Hydroxide Hydroxrde Hydroxrde Nrtrate
- 8H20
Benzaldehyde Benzene Benzene Benzene Benzorc Acid Benzorc Acrd Benzyl Sulfontc Acrd Bone Acid Bone Acrd Boric Acid Bromrne Bromine 3romine 3romrneMethyl Alcohol 3utync Acrd 3utync Acrd
15 Saturated 5. 20 20 25 Saturated Saturated 50 Saturated 10 100 100 Lrqurd Vapor & Lrqurd 75 Saturated 100 10 50 Saturated Liquid Vapor Water 1 Undiluted Undiluted
212 Room 212 212 Borlrng Room Room 212 Room Room 212 212 Room 176 212 Room 212 Borlmg 212 Room 86 86 Room Room Room 212
_ A A _ A A A
A A A
A A A A A A A A
4 A
A A A A A A A A C A A B A A _ C A A A A A A A
:alcrum :alcrum :alcrum Zalcrum Zalcrum :alcrum Ialcrum :alcrum
Brcarbonate Brsulfrte Carbonate Chlonde Chlonde Hydroxtde Hydroxide Hypochlorrte
100 _ Saturated 5. 10. 20 28 Saturated Saturated 2. 6 Saturated Saturated 99 Lrqurd Vapor
212 80 Boiling 212 Borlmg Room Boiling 212 Room Room Bowling Borlmg Boiling A A A A A A A A A A A A
A A A A A A A A A A A
A A
Calcium Hypochlorite Zarbolrc Acrd Carbon Tetrachloride Carbon Tetrachlonde Carbon Tetrachlonde
(continued)
766
Corrosion
Resistant
Materials
Handbook
TABLE HEOIA
Chlorine
5.33:
TITANIUM,
ZIRCONIUM
AND
TANTALUM-ASTRO
METALLURGlcAL TlTANlUM
A B A C A A A A A A B A A A B A A A A A A A _ 0 A A A A A B B A A B C B A A A A A A A A A
(continued) ZIRCONIUM
_
CONCENTRATION %
Dioxide _ _ _ 100 100 30 100 100 10 20 365 10. 25 50 50 50 Saturated 5 Saturated Saturated 20. 40. 50 Saturated 50 50 100 100 100 100 100 100 100 _ 2-100 95 Llquld Partial 100
TEMPERATURE F
180 Room 167 Room 200 180 Bowling Boiling Boiling Room 195 212 140 212 212 Room Room Room Boiling Room Boiling Room 212 195 212 302 100 212 212 Bollmg 212 212 250 212 Bolllng Room Room Bolllng
TI-PO
_ A A _ A
TANTALUM
A A A A A A A A A A A A A A A A A A A A A A
Chlorine (Water Saturated) Chlorine (Water Saturated) Chlorine Gas (Dry) Zhlonne Gas (more than 0.13% HzO) Zhloroacetic Acid zhloroacetlc Acid Chloroform Zhromlc Acid Chromic Acid Chromic Acid Citnc Acid Citnc Acid Citnc Acid (Aerated) Citrtc Acid (Non-Aerated) Copper Cyanide (Electroplating Solution) Copper Nitrate Copper Sulfate Copper Sulfate Cupnc Carbonate-Cupric Hydroxide Cupnc Chlonde Cupric Cyanide Cupric Sulfate Cuprous Chlonde Cyano Acetlc Acid Cyclohexane Cyclohexane Cyclohexane Dichloroacetic Acid Dlchloroacetlc Acid Dimethyl Ether Dloxane Esters Ethyl Acetate Ethyl Alcohol Ethyl Alcohol Ethyl Alcohol Ethylene Dvzhlonde
_ A _ _
_ I
_ _ C A _
1:
_ _
_ _ _ _ _ A A
A A _
A _ A A A A
A A A A
Im-erslon
Ferric Ferric Ferric Ferric Ferric erric
Chlonde Chloride Chloride Sulfate Sulfate Sulfate
5. 10 20, 30 5, 10. 20. 30 5. 10. 2L. 30. 40. 50 10 IO Saturated 49 5-20 Gas % liq.-% gas Llquld Gas (4 hr. exposure) (8 hr. exposure) (288 hrs. exposure) IO 37 50
Room 212 Boiling Room 212 Room 212 Elevated Room 310
A A A A A A _ C 0 A
C C C A _ A
A A A A A C
-errlc Sulfate luobonc Acid Fluorine Fluonne Eluorine rluorlne Fluorme. liquid Fluorme. gaseous Fluorme, gaseous Fluorosiliclc Acid Formaldehyde Formaldehyde, plus 2%% HzSO~
_ _
C A A (continue
Nonferrous
Metals and Alloys
767
TABLE
5.33:
TITANIUM,
ZIRCONIUM
AND
TANTALUM-ASTRO
METALLURGICAL
(continued)
MEDIA
Formamide Vapor Formrc Acrd Formrc Acid (Non-Aerated) Formrc Acid (Non-Aerated) Formic Acid (Non-Aerated) Formrc Acid (Non-Aerated) Formic Acid (Aerated) Formrc Acid (Hz0 Solutron) Furfural Alcohol _~ Glue Polyvrnyl Glycerrne Fiesrn
.-
______..-^._ --CONCENTRATION %
___^__.____
TEMPERATUREF
572 212 Borlrng Botltng 212 Botlrng 212 125 337 Room Room
--A A A C C C A B
~-TI-PO
--
TITANIUM llRCONlUM
TANTALUN
10. 25. 50. 90

10 25. 50 25 80 10-90 9
A A B A A B C C A B C A A A B A A A A A A A A A A A A B B B B B B B B B C B C A B _ A A A
Hydrrodrc Acrd Hydrobromrc Acrd Hydrochlorrc Acrd Hydrochlonc Acrd Hydrochlorrc Acrd Hydrochloric Acrd Hydrochlonc Acrd (Aerated) Hydrochlonc Actd (Aerated) Hydrochlonc Acrd (Aerated) Hydrochlorrc Acrd Plus 1% HNO, Hydrochlonc Acid Plus 5?0 HN03 Hydrochlorrc Actd Plus 10% HNO, Hydrochlonc Acrd Plus 10% HN03 Hydrochlonc Actd Plus 0.05% CuSO4 Hydrochlonc Acrd Plus 5% CUSOI Hydrochlonc Acid Plus 1% CuSO4 Hydrochlorrc Acrd Plus 5% CuSO4 Hydrochlonc Acrd Plus 50% Cr03 Hydrochlorrc Actd Plus 1% Cr03 Hydrochlorrc Actd Plus .50% CuSO4 Hydrochlorrc Acrd Plus .lO% CuSO4 Hydrochlorrc Acid Plus .20% CuSO4 Hydrochlorrc Acrd Plus .25% CuSO4 Hydrochlorrc Acrd Plus .50% CuSO4 Hydrochlorrc Acrd Plus 1% CuSO4 Hydrochlonc Acid (Non-Aerated) Hydrochlorrc Acrd (Non-Aerated) Hydrochloric Acrd (Non-Aerated) Hydrochlonc Actd (Non-Aerated) Hydrochlonc Actd (Non-Aerated) Hydrochlonc Acrd (Non-Aerated) Hydrochlorrc Acrd (Non-Aerated) Hydrochloric Acid (Non-Aerated) Hydrochlonc Actd (Non-Aerated) Hydrofluonc Acid Hydrofluonc Actd (Andydrous) Hydrofluonc - Nttric Acid Hydrogen Peroxide Hydrogen Peroxide Hydrogen Peroxide Hydrogen Sulftde Hydrogen Sulfide Hydioxyacetrc Actd Iodine m water Plus Potasstum lodtde Lactic Acrd
57 40 5 10 20 35 5 10 20 5 5 5 5 5 5 5 5 5 5 10 10 10 10 10 10 1 1 1 3-5 3-5 3-5 5 10 10 48 100 (lHF:l5HN03) 3. 6 30 50 Saturated Saturated _
Room Room Room 95 95 212 95 95 95 100. 200 100. 200 100 200 100. 200 100. 200 100, 200 100, 200 100. 200 100. 200 150 150 150 150 150 150 100 160 Boiling Room 160 Borltng 125 Room 160 Room Room Room Room Room 140 Room 70 104
C
A A A A A A _ _
A A _ A A _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
_ _ _ _ _ _ _ _ _ _ _ _ _ _ A _ _ _ A _ C _ _ A _ A _ _
HOH HOH
_ lo-85
Room 212
A A A [continue
768
Corrosion
Resistant
Materials
Handbook
TABLE
MEDIA
5.33:
TITANIUM,
ZIRCONIUM
AND
TANTALUM-ASTRO
METALLURGICAL TITANIUM
(continued) IRCONlUM TI-PD TANTALUM

A
CONCENTRATION % 10-100
Saturated
TEMPERATUREF
Room Room Room Room 212 212 Room Room 200 Room 212 212 Room 200 Room Room Borlmg 212 Room 180 80 95 212 347 392 518 554 Boll - 250 Room 95 212 Borlmg 180 252 320 Room 194-203 Room
Lactrc Acrd Lead Acetate Lmseed Oil, Boiled Magnesrum Chlonde Magnesrum Chlonde Magnesium Chlonde Magnesium Hydroxrde Magnesrum Sulfate Magnesium Sulfate Malerc Acrd Manganous Chlonde Mercurrc Chlonde Mercurrc Chlonde Mercurtc Chlorrde Mercurrc Cyanrde Mercury Methyl Ethyl Ketone Nrckel Chlonde Nickel Nrtrate Plus 61 HOH Nrckel Sulfate Nttnc Acrd (Aerated) Nrtrrc Nrtrtc Nttrrc Nrtrrc Nrtrrc Nrtrrc Nrtrrc Nrtnc Nrtnc Nrtrrc Nrtrtc Nrtrrc Nrtrrc Nrtrrc Nrtrrc Acid Acrd Acrd Acrd Acrd Actd Acrd Acrd Acid Acrd Acrd Acrd Acrd Acid Acrd (Aerated) (Aerated) (Aerated) (Aerated) (Aerated) (Aerated) (Non-Aerated) (Non-Ae:ated)
A A A A A _ A A _ A A A A A A A _ A A A A A A B B 0 A A A A A B B B A A C
5-40 5-40 40 Saturated Saturated 37 5-20 1. 5. 10. 55 Saturated Saturated Saturated All 5-20 50 40 98 5. 10. 20. 30 5-69.5 65 40 70 20 65 98 10. 20. 40. 69.5 10, 20, 40. 69.5 65 90
A A A A A A A
A A A
- Whrte - White White Whrte -
Fumrng Fumrng Fumrng Fumrng Acrd reactlc
A A A
Lrqurd 38
or Vapor
Nrtrrc Acrd
170 Adrprc
Nrtrrc Acrd Red Fuming ~ Less than 1% water = pyrophonc Oxalrc Oxalrc Oxalic Oxalrc Oxalrc Acrd Acrd Acid Acrd Acrd
1 0.5 5 10 0.5-25
98.6 95 95 95 140 Room Room
B B 0 A C A A B B B B B B
A A A A A
A A A A A
Perchloromethylmercaptan Plus 2 to 19/o Hz0 Perchloromethylmercaptan (Anhydrous) Phenol (Carbohc Acrd) Phosphonc Actd Phosphonc Acrd Phosphonc Acrd Phosphonc Acrd Phosphonc Acrd Phosphonc Acid Phosphorrc Acid Phosphonc-Sulfunc - CuSOa
Saturated 5-30 35-85 40 5-3 5 85 5 10 15H3POzvlOHzS04
Room Room Room 212 140 100 212 175 150
A A B A A B A A
A A A A A A A A
continue
Nonferrous
Metals and Alloys
769
TABLE 5.33:
TITANIUM,
ZIRCONIUM
AND TANTALUM-ASTRO
METALLURGICAL
(continued)
MEDIA
Phosphorus Photographic Potassium Potasswm Potassrum Potassium Potassium Potasstum Potaswm Potasstum Potassium Potassium Potasstum Potassium Potassium Potassrum Potassrum Propionic Sea Water Silver Silver Sodium Sodium Sodiun Sodrum Sodium Sodium Sodium Sodturn Sodrum Sodium Sodrum Sodium Sodium Sodrum Sodium Sodrum Sodium Sodium Sodium Sodrum Sodium Sodium Sodium Sodium Sodium Sodium Sodrum Sodium Sodium Sodrum Sodium Sodium Sodium Sodium Stannic Nitrate Nitrate Acetate Alumrnate Bisulfate Bwlfate Carbonate Chlorate Chlorate Chloride Chlonde Chloride Crtrate Cyanide Dlchromate Fluoride Fluonde Hydroxide Hydroxrde Hydroxrde Hydroxide Hypochlonte NItrIte Nitrite Phosphate Phosphate Silicate Sulfate Sulfate Sulfide Sulfide Sulfite Sulfite Sulfite Thtosulfate Thiosulfate Chlonde - Acetic Acid Trichloride Emulsions Bromide Chloride Chloride Dichromate Ferncyanrde Ferricyanide lodfde Iodide & 0.1% NazCO3 Permanganate Hydroxrde Hydroxrde Hydroxide Nitrate Sulfate Throsulfate Acrd & 5% NaCl
CONCENTRATION
Saturated _ Saturated 36 Saturated _ Saturated 0.5 Saturated Saturated Saturated 10 25 50 100 10 1 Vapor _ 50 15 Saturated 25 Saturated 10. 25 10. 25 Saturated lo-25 29 Saturated Saturated Saturated Saturated Saturated Saturated 20 10. 25 26 40 Saturated 6 Saturated 50 Saturated 20 25 10-20 Saturated 10 Saturated IO Saturated Saturated IO. 25 20-20 5
TEMPERATUF RE
Room _ Room Boiling Room _ Room Room Room Room Room Boiling Boiling Boiling 212 Room 374 Boiling Room 90 Room Boiling Boiling Boilrng Boiling Room Room Boiling Room Boiling Room Room Room Room 90 Borlmg Room 176 Room Room Room 200 Room 90 Boiling Boiling Room Boiling Room Boiling Room Boiling Boiling Room 212
TITANIUM
TI-PD
TANTALUM
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
A A A
_ _ _ _
(continue
770
Corrosion
Resistant
Materials
Handbook
TABLE 5.33: MEDIA
TITANIUM,
ZIRCONIUM
AND TANTALUM-ASTRO CONCENTRATION 0,

24 24 100 Saturated 68 100 _ _ 100 _ 1. 3 5 15 To 70% 5 30 30 5 30 30 5 30 5 30 96 90-10 70-30 50-50 30-70 1O-90 1O-90 50-50 50-50 6 Saturated Saturated Saturated
METALLURGICAL
(continued)
TEMPERATURE F
Boiling 140 Molten Room 212 360 365 Room 464 Room 275 140 140 Room 212 200 100 200 200 100 200 200 200 200 200 100-300 Room Room Room Room Room 140 95 140 Room 375 Room 100
rlTANlUM !ISCONIUM TI-PO - _

A A A A A A A A B B A B A A A A A A 0 A A A A A 0 0 B A A A A B A A A A A _
7-
TANTALUl
A A A A A
Stannic Chlonde Stanmc Chloride Stannic Chloride Stannous Chloride Stannous Chloride Steanc Acid Succinic Acid Sulfur Plus HO4 Sulfur (Molten) Sulfur Droxrde (Water saturated) Sulfur Dioxide (Dry) Sulfunc Acrd Sulfunc Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid Plus 0.25% CuSO4 Sulfurtc Acid Plus 0.25% CuSO4 Sulfuric Acid Plus 0.25% CuSO4 Sulfunc Acid Plus 0.5% CuSO4 Sulfuric Acid Plus 1.0% CUSOI Sulfunc Acid Plus 1.0% CuSO4 Sulfunc Acrd Plus 0 5% 003 Sulfunc Acrd Plus 0.5% CrO, Sulfuric Acid Plus 1 0% Cr03 Sulfurtc Acrd Plus 1 .O% Cr03 Sulfunc Acid Vapors Sulfunc Actd-Nitrtc Acid Sulfunc Acrd-Nrtnc Acrd Sulfuric Acrd-Nitnc Acid Sulfuric Acid-Nitric Acid Sulfunc Acrd-Nitric Acrd Sulfuric Acid-Nrtric Acrd Sulfuric Acid-Nitric Acrd Sulfunc Acid-Nrtnc Acid Sulfurous Acid Sulfurous Acrd Sulfurous Acid-Partial lmmersron Sulfurous Acrd-Partial lmmersron
A A A A A
Tannic Acrd Tartanc Acrd Tartanc Acrd Tetrachloroethane Toluene Sulphone Tnchloroacetic Tnchloroethylene Tnsodium Phosphate
(water mrxture) Chlortde
25 IO-50 10. 25, 50 100 _ 100 99 5. 20
212 212 140 Boiling Room 212 Boiling 212
A A A B A C B
A A A
Urea-Ammonra
Elevated Temp. 8 Pres
X-Ray
Developer
Solution 10 20 Saturated Saturated Molten
Room Borlmg 212 Room Room
A A A A A _
Zinc Chlonde Zinc Chlonde Zmc Chlonde Zinc Sulfate Zmc
Nonferrous
Metals and Alloys
771
TABLE 5.34:
TUNGSTEN,
TANTALUM
AND TITANIUM
CARBIDE
ALLOYS-KENNAMETAL
Kennametal hard carbide alloys

grade K602 is a carbide of tantalum and tungsten with a small amount of binder. It is used success. fully for applications in which both corrosion and wear are exceptionally severe. The corrosion resistance of K602 is almost equal to that of platinum, while its resistance to wear is better than most other tungsten carbides. Compressive yield strength at elevated temperatures is exceptionally high. K602 is used successfully in seal rings, including applications where the material runs against itself. Other applications include nozzles, orifice plates, bushings, valving parts, mortar and pestle sets. It has been found to be an ideal material where corrosion resistance and wear life are critical. It is sufficiently nonmagnetic for wear parts in magnetic tape recorders, particularly video tape applications. grade K701 is a tungsten carbide with chromium cobalt binder. It provides maximum wear resistance, good to very-good corrosion resistance, and is stronger than K602. K701 is recommended where the higher corrosion resistance of K602 may not be required, or where more strength is needed than that provided by K602. Used for homogenizing valve parts, K701 is withstanding solid-fluid dispersion materials at almost 1000 feet-per-se&ond in processing such products as food, paint, and tobacco. It is used in nozzle and valve parts for handling slurries in refining petrochemicals, clay, soap, detergents, and other bulk products. Other applications include catalyst compacting dies and wear parts for coal processing. grade K703 also conralns chromium and cobalt. It is not quite as resistant to corrosion and wear as is K701, but it is stronger and more easily fabricated. It has been used extensively for pulverizing coal, minerals and chemicals. grade K714 has an excellent combination of resistance to wear, corrosion and shock. It is easily fabricated and lower in cost than either K701 or K703. It has been applied with particular success in valving and nozzle applications where the components are used as sintered or with very little finishing because of cost considerations. grade K801 is the strongest of the Kennametal corrosion-wear grade series, but has less wear resistance than the other grades. It is a hard tungsten carbide made with a nickel binder instead of cobalt -the binder usually found in tungsten carbides. K801 was developed for use where other grades are not sufficiently corrosion resistant but where conditions may not require the higher corrosion resistance and correspondingly higher cost of K602 or K701. K801 has proved to be a better choice than other carbides for seal rings and other parts subjected to moderately corrosive conditions. It provides distinct advantages where electrolytic attack of the binder or etching may occur, such as when immersed in mineralized or boiler feed water. In sodium hydroxide and hot sulfuric acid tests, K801 has shown better corrosion resistance than K701. K801 can also be used to advantage in radioactive atmospheres because the nickel binder has a much shorter half.life than the cobalt used as a binding element in most other carbides. grades K3404, K3406, K3047, K3411 are used where highhardness and high resistance t0 imPaCt are primary requirements. Included in such applications are form crush rolls and hammermills; also inserts and tips for bits used to cut and drill Coal, rock and other minerals. grades K82, K84, K86 are a gall resisting series made under the most rigid quality control to accept the fine surface and polish required. They have fine grain size, cobalt binder and-due to the large WTiCZ content-a high resistance to pickup or galling. Compared to other Kennametal grades, they have slightly less abrasion resistance, but good strength, moderate rigidity and medium thermal expansion rates. The softer grades have higher cobalt content. These grades are applied most extensively to tube and bar drawing operations, sheet metal drawing, cupping, deep drawing applications and sizing mandrels. They are used where the slippery quality of the tungsten-titanium carbide, well known in the metal cutting field, provides properties that are not available in straight tungsten tarbide grades. grades K92, K94, K95, K96 are a wear resisting series, essentially tungsten carbide of fine grain size with a cobalt binder. The t,ardest grades have the highest wear resistance and rigidity. When compared with other Kennametal grades, thermal expansion rates are low to medium.
(continued)
772
Corrosion
Resistant
Materials
Handbook
TABLE
5.34:
TUNGSTEN,
TANTALUM
AND TITANIUM
CARBIDE
ALLOYS-KENNAMETAL
(continued)
Kentanium
grade K162B has a nickel-molybdenum binder and is the best general purpose Kentanium grade. It has the greatest resistance to oxidation at temperatures in the 1000 to 1400 F range. It is used in seal rings and bearings (can run against itself), also for valve parts, check valve balls and hot flash trimming tools. corrosion resistance of Kennametal and Kentanium is largely determined by the corrosion resistance of the binder metal since carbides themselves are nearly inert. At room temperature, cobalt has corrosion resistance about as good as other commonly used wear resistant materials. At elevated temperatures, however, it is attacked more rapidly. Therefore, Kennametal grades with the lowest cobalt content have the highest resistance in hot solutions. For more severe corrosive conditions the corrosion-wear series of Kennametal compositions has been developed. The corrosion resistance of grade K602, the carbide of tantalum and tungsten with a small amount of binder, is almost equal to that of the noble metals while possessing much greater resistance to wear than these more expensive metals. Use of carbides for their corrosion resistance alone is seldom justified since other materials having this property are more workable and less costly. However, when abrasion is involved, the combined corrosionwear resistance of Kennametal or Kentanium will give far better results.
corrosion-wear resistance of some carbides and metals

The weight loss in milligrams per square decimeter per day is shown in the table:
tyb?,yzr*
50% grade 22oc
NaOH 1oooc
5% 22%
HNO, 100%
5%
HrSOa
WC-TaC-Co K602 corrosionwear

series WC-Co-Cr
0.3 0.8 nil nil

ml
3.1 1.8 2.3 31.7

nil
9.5 390 928 364

534
35.1 125 920 498

2310 decom-
0.2 67 363
3.4 1713 3868
470 825 760 380 110
23,500 123 21 71 10
K701 K703 K714
_
,WC-Ni
53.3 1354 106 2126
K801
structuralwear. impact series

die and wear parts
WC-CO
K3047
WC-CO
K96
series
high temp. resistance series $t+entanium)
complex carbide-Co
-I-113
posed
706
/ d;;;e$- /
95
123 273
1661
2327
Tic-Ni-Mo
K1626
39
232
1231
/ d;;;,$- /
20
0.2 1
nickel
nil
39
poor
poor
3041
very
I poor I
16
0.05
metals
monel
1 65.4 1 ,$,
Co-Cr.Ni-W castalloy
*Corrosion resistance tests were performed with averages of duplicate runs. Solution strengths new solutions each day. **corrosion-wear factor has better = abrasion resistance resistance ground samples were calculated X 10 i 22-C binder in a Huey on a weight HCI loss. carbides in salt solutions. Corrosion Tester for basis and strengths seven days. The were mamtained above values by replacing are with
factor than the
l**Kentanium
corrosion
cobalt
tungsten
Nonferrous Metals and Alloys TAB1 .E 5.35: VARIOUS METALS AND ALLOYS-DURIRON
773
Nickel Chlorimet Chlorimet Duriron Durichlor Superchlor Durco Titanium Titanium-Pd 7ircnnium DC-5 51 2 3
195.0 I max
min Bal Bal
I
I
_ ._ _
_.
il.00
130.0-33.0 17.0-20.0
ll.OOmax 1 .OO max 14.20-14.15 14.20-14.75 14.20-14.75
l1.C 1.00 1.50 1.50 1.50 max max max max 0.07 max 13.0 max Bal Bal Bal 0.30 0.30 max max 0.70-1.10 0.75-1.15 0.75-1.15 0.10 max max
17.0-20.0 3.25-5.00 3.25-5.00
Proprietary N.0.05 N, 0.05 max; max;
Cobalt
Base Shaft max; max; 0,
Sleeve 0.35 0, 0.35
Alloy max. max; Pd. 0.12 min. 0.10
H,O.OlOO H, 0.0100
N. 0.03 max. H 0.004 mar. 0 0.20 max. Hf 4.5 max
0.10 mar
0.30 max
(continued)
774

(contmued)
TABLE 5.35:
VARIOUS
METALS AND ALLOYS-DURIRON
Brine, acid Brine, alkaline
PPPPPSPEEEEGEEE GGEEEEEIEEGGEEEE
Nonferrous
Metals and Alloys
775
TABLE 5.35:
VARIOUS
kontmutd
fhosphmc
acid+2
(continued)
776
Corrosion
Resistant
Materials
Handbook
TABLE
5.35:
VARIOUS
(continued)
Sea water Sodium bicarbonate
S S
S E
G E
G E
S E
S[S EIE
G E
E E
G E
G E
E E
E E
E E
E E
E = Excellent-Virtually unattacked under all conditions. G = Good-Generally acceptable with a few limitations. Suitable under many conditions; not recommended for remainder. P = Poor-Unsuitable under all conditions.
S = Satisfactory-
Nonferrous
Metals and Alloys
777
TABLE 5.36:
VARIOUS
METALS
AND ALLOYS-GENERAL
METALS TECHNOLOGIES
CORROSION
DATA-SALTS
MEDIA
I f
1 1 / I / I I I 1 I
1 / 1 1 1
1 I t
I 1
I I 1
1 I 1 1 1
1 1 I I 1
I I I
(continued)
778
Corrosion
Resistant
Materials
Handbook
TABLE 5.36:
VARIOUS
METALS
AND ALLOYS-GENERAL CORROSION
METALS
TECHNOLOGIES
(continued)
DATA-SALTS
. /
. .
/ , I I I I
. . . . .
I / /
e e /
I / I
A-Fully resatant B-Slightly attacked C-Unratisfactorv
&Sublect to pbttmg at air line or when allowed =--Keep solution alkalme t t -May attack when wlphurlc acid is present
to dry
t-May attack when hydrochloric acid 8s present o-Tlll.CO.3ted -Not recommended for use with beverages
(continued)
lLlWOW~ QQ****** 41
4.4~
4 Q*44*4*** Q
***<**u
rnDQ
*at
*a*
Q ****m**m* 4Q *ID I
zz
****.I
*QQQQQ
440
********* *
**m****
m u
*a**
*****
44
mmm
**
****v
WCC IWS
W,WS
4Q
4 *urn 4 4
**a
***
.*a~ :
Q 4
f*
z*.mm**
..<
*m*uv
9lC Idols na,uw,s

***m*m**0m
a**
4.4 4 * QQQQO
*~*.Q**. *~Q**.
f 0~

**a **o
**q
D
*au **v
****o
*o** *ma*
Q******
mm*o
a***
bOC I~W
******m %,l,WS llOlij O,l,lS
:**v
***g
I?******
rnrnDlDQ
**
vu
41D.I
*Q*~**.n.
**mm 44 4
**a -El4 4 QQQ
*ay
***~~~~o. 3
IDI
****y **$;1
001 IPlW
qa.~~~.**.
$~g. 9:
111 ml
mm**m Z **m : Z
mm -VU am
0
**
tjmtjm
zYj:z
0
oovPOW
*~~$~~~ra$ ~gqm
0
:9m :I:
~.~a*~~
l
:m
Qlll ID
::$rnz ~~
4
9:
z,$
*~~..~
:.:mm ugqmmv
009 lIO~~,
9LB *wo~ul
*******Q* *** 4
::9
-El- Q 4 ~~~~rn
.q.aq.n
a-*a* **v*~*~v***~
v.amrn~~v~*vv*
*m QQ
zm.. z ***
41
~~~~vvuuu
**m
*Q********
vuuvuu m***
44
zrn$m *****a* .~~~D4 ma*

**IDoLDLD*
**
41 I
****qq~qy*,**
****u
008 ~OIO~UI m
444
*****u**
Q***Q**** 4.4
,*v,*qgy
Q*QO*Q*Q
*(D*mu
7:: -0.
****
..3.. ~WlW
4 LDQ***mO
**a
4.4 Q**Q*
*a a*
4 *III***m*
a**
****
***
4.4
**QQ**
****
*QQ****
**~*o*m**o***
4Q.Q
..o..~Wlw4
*Q*******
*a*
4.4 *:g
**a a.2 y y
QQQO
**4****
*Qm***QQ*Q**
Q4.4
,wwN .o,.dn3
q**y*vqv,,
0.40.
44 44 4401D
Q Q
p~p~~pp
0
*m
:a*:
**!j
0
yg~#y*
***~~~~m.
***am
f addog
**~Q*mI.
****Q**** QQQ ****Q***
**a
.a#
a**fj
44 4 *Q
mmmLDIDu*
***~~~~m. **a
4 Q QQ ********** QQQQ **4**Q*
****y
,.
c 9302 on
mmdq
wn,un(~ Q.4 44
44
***ID*~*~*
4 44 ;
44
****
***m**m~(D
l ****
44
~~~~**,gg
9P
**,******
~**Q~ *a* *a<

l *******
*mm
**
*Q*~O***..
a:!$gu
7 14 ****
an,e,url
1 ; 1:
,*a
~********
***Q:
44
*****.*u***
****
>.>>>>>>.>>>>>>.>n>,>>>>D>*>***>>>DD>>D>D
Tll,llT
o**mnmo~~>>*n~cmD>o
~:>>~Dnff
~n>nnDnDn>~D.n
*>>>> ID D >>>>nn*
CVO
Nttkd
nutllloy HlldlO 7
>>>>
DD
>>>>>D>>.>
n>*>> DD
>>>*>*>.>>
**>>>>
>>>*>*>**>
C
>>>O>> D >>
n::
0
>>>:g:m :>g>n
*>>*n
on
>>>>>n
Incolo 000
**>>>>*>>>>
>~>n>>
gg* .>>> ng mo>>g >D D,
"D~brn,
n>nm
Incolo 025
Incontl Km
gig,
kg no,
gg>g;
* *,>>n
**;..>>
>~>>
>I0
Mod
4w
781
TABLE 5.37:
VARIOUS
METALS AND ALLOYS-WALWORTH
In an effort to be specific, first and alternate choices are designated in the following table for each solution listed. In making the first choice, consideration was given to such factors as corrosion resistance, material availability and economy. An alternate choice material is listed for most solutions. The alternate choice in most cases is equal in corrosion resistance to the first choice material, but is usually more costly.
Corrosive
First Medium
Temp F Choice
~
Alternate Corrosive Medium Temp F Alum (Potassium Aluminum Sulfate) 10% All Concentrations Digestion of Bauxite in H,SO, to make Alum Ammonium Bicarbonate In cont. to 90% Ammonium Carbonate All Concentrations Ammonium Chloride (Sal Ammoniac) In cont. to 50% In cont. to 50% In cont. to 100% Ammonium Chlorostannate (Saturated) Ammonium Hydroxide Amgm30/ni;m9~/trate_Neutral 00 00 Ammoniated Ammonium Nitrate Ammonium Oxalate In cont. to 30% Ammonium Perchlorate In cont. to 10% In cont. to 40% Ammonium Persulfate In cont. to 30% Ammonium Phosphate In cont. to 30% Ammonium Sulfate In cont. to 10% In cont. to 50% Saturated Plus free H,SO, Ammonium Sulfite In cont. to 50% Ammonium Bisulfite (Sulfite Cooking Liquor) Ammonium Thiocyanate In cont. to 50% Amyl Alcohol-SO% Amyl Mercaptan Aniline-Cone. Aniline & Ferric Chloride Arsenic Acid In cont. to 30% In cont. to 100%
First Choice
Alternate
Acetic Acid In cont. to 100% In cont. to 100% In cont. to 60% 60% to 100%
150 200 Boiling Boiling 175 244 Boiling Boiling 140 ;:oo 200 250 140 Boiling 140 230 200 :: Boiling Boiling Boiling Boiling 70 100 212 212 100 160 212
18-8s 18-8SMo 18-8SMo A-20 18-8SMo N-3 18-8s A-20 18-8s 18-8SMo A-20 18-8SMo A-20 18-8s A-20 18-8SMo A-20 18-8SMo A-20 18-8SMo ;;I;; 18-8SMo A-20 18-8SMo 18-8s 18-8SMo 18-8SMo A-20 18-8s 18-&MO A-20 A-20 N-2
18-8SMo A-20 A-20
18-8SMo A-20 A-20 18-8s 18-8s
A-20
100% Acetone Acetyl Chloride Acid Mixtures 50% HN03-50% H2S04 50% HNO,-50% H,SO, 50% HNO,-50% H,SO, 25% HNOJ-75% H,SO, 25% HNO,-75% H,SO, 10% HN03-70% H,SO, 10% HNO,-70% H SO, 5% HN03-30% H,$O, 5% HNO,-30% H,SO, 5% HNO-15% H,SO, 5% HNO,-15% H,SO, 90% Acetic-Z% H,SO, Acid & Salt Mixtures Fuming HNO,-10% KNO, Fuming HNO$-10% AI(NO& 10% H,SO,-10% CuSO, 10% H,SO,-2% Fe,(SO,), Acid Mine Water Aerorine-50 Alcohol Ethyl Methanol Alkylation-Sulfuric Acid Aluminum Acetate All Concentrations All Concentrations Aluminum Chloride All Concentrations 10% All Concentrations Aluminum Fluoride-20% Aluminum Hydroxide Saturated 10% Aluminum Sulfate In cont. to 50% Saturated Aluminum Chrome Sulfate-S%
Acitii /Anhydride 00
A-20 18-8SMo
18-8SMo 18-8SMo
18-8SMo A-20 A-20 18-8SMo A-20 A-20 A-20 $1;;;; A-20 A-20
1:: 212 70 212 212 160 200 200 200 200 200 212 160 212 150 212 280 175 350 300 200 650
18-8SMo A-20 Monel 18-8SMo 18-8s 18-8s 18-8SMo 18-8s 18-8s N-3 18-8SMo 18-8s
A-20 Monel Nickel A-20 18-8SMo 18-8SMo A-20 18-8SMo 18-8SMo
A-20 18-8SMo ;I;;
A-20 A-20
18-8SMo A-20
18-8SMo 18-8SMo 18-8s A-20 A-20 18-8SMo N-3
A-20 A-20 18-8SMo
1:: 300 160
Nickel A-20 A-20 18-8SMa A-20 A-20 18-8SMa A-20
2:: 212 212 70
A-20 N-2
(continued)
782
TABLE

5.37: VARIOUS METALS AND ALLOYS-WALWORTH (continued)
Corrosive Barium Carbonate All Concentrations 10% Barium Chloride $/Concentrations 00 Barium Nitrate-All Concentrations Ba$y Sulfate
Medium
emp
70 !12 70 !12 !12 !12 !12 !12 175 !12 100 340 !12 )OO L25 350 !12 125 150 too !65 212 300 212 212 212 212 125 180 212 70 125 200 200 150
First Choice
Lltemate
Corrosive
Medium
remp F
First Choice
Rlternate
18-8s 18-8s
18-8SMo 18-8SMo A-20
18-8s 18-8s A-20 18-8s A-20
18-8SMo 18-8SMo 18-8SMo
CoiEentrated Benzene (Benzol) Benzene Sulfonic Acid-go% Benzoic Acid In cont. to 100% 100% Black Liquor (Sulfate Pulping) In cont. to 75% Solids Borax-5% Boric Acid In cont. to 50% In cont. to 100% Boron Trifluoride-100% Bromine Wet Gas Dry (Gas or Liquid) Butyric Acid In cont. to 5% In cont. to 25% In cont. to 100% Carbonic Acid-In cont. to 100% Calcium Bisulfite (Sulfite Cooking Liquor) Cadmium Sulfate-30% Calcium Chlorate In cont. to 10% In cont. to 30% In cont. to 100% Calcium Chloride In cont. to 80% In cont. to 100% Calcium Hydroxide In cont. to 50% ca!lc~~. f!fy~~~if/~~fi~Chlorine In cont. to 40 g.p.1. available Chlorine Ca;b;n Tetrachloride Plus H,O Cellulose Acetate Chloroacetic AcidIn cont. to 100% Chlorobenzene-Concentrated Chloroform-Concentrated Chlorine Dioxide Solution from absorbers to bleach Solution from neutralizer Chlorine Trifluoride Chlorine Gas-moist, saturated Chlorosulfonic Acid-99.5%
;;I;;;; 18-8SMc 18-8s 18-8s 18-8s 18-8s N-3 Monel 18-8s A-20 N-3 18-8s 18-8SM( 18-8s 18-8SMr A-20 N-3 18-8SM( A-20 18-8SMI 18dSMI N-3 18-8SMI A-20 18-8SMI N-3 18-8SM1 18-8s A-20 A-20 A-20 18-8SMo 18-8SMo 18-8SMo 18-8SMo
Chromic Acid 5% In cont. to 50% Citric Acid In cont. to 50% All concentrations Coca Cola Syrup Coffee Copper ChlorideIn cont. to 100% Copper Cyanide-In cont. to Saturated Copper Nitrate-In cont. to Saturated Copper Sulfate In cont. to saturated Plus 10% H,SO, Creosote Cresylic Acid Cyanogen Gas Dichloroethane Diethanolamine Dinitrochlorobenzene Melted and Solidified Distilling Wort Dyewood Liquor Epsom Salt (MgSO,)-In to saturated Ether Ethylene Chloride, dry Ethyl Acetate, cont. Eth&Chloride 10% Fatty Acids (Tall Oil Distillation) High Rosin Acids--over 50% High Fatty Acids-over 60% Ferric Chloride18% (HCI-24.7%) Ferric Nitrate In cont. to 100% In cont. to 100% Ferric Sulfate 10% In cont. to 100% In cont. to 100% Fluorine-Dry Formaldehyde In cont. to 100% In cont. to 100% Formic Acid In cont. to 100% In cont. to 100% Fruit Juices Furfural-In cont. to 100% Gallic Acid-In cont. Glue (Acid Solutions) to 100% cont.
1::
18-8SMo
;;; 70 300 70 212 212 212 150 200 350 70 212 212 70 212
t8zMo L8-8s 18-8s Y-3 18-8s 18-8s
A-20 18-8SMo 18-8SMo
18-8SMo 18-8SMo A-20 18-8SMo 18-8SMo 18-8SMo 18-8s 18-8SMo 18-8SMo 18-8SMo
18z?Mo 18-8s 1-20 18-8s 18-8s 18-8SMo 18-8s 18-8s 18-8s
Nickel 18-8SMo
18-8SMo A-20 18-8SMo A-20
212 70 70 200 600 175
18-8s 18-8s 18-8s 18-8s 18-8s 4-20
18-8SMo 18-8SMo 18-8SMo 18-8SMo 18-8SMo
A-20
:!PMo 700 125 212 212 1;: 800 125 212 125 212 212 212 212 140 N-3 18-8s A-20 18-8SMa
A-20 N-3 N-2 18-8SMo
A-20 A-20
18-8SMa A-20 A-20

Nickel 18-8SMc A-20 18-8SMr A-20 18-8s 18-8s 18-8s 18-8SM( A-20 18-8SMo 18-8SMo 18-8SMo A-20 Monel
A-20
A-20 18-8SMo
317 A-20 Monel N-3 18-8s
A-20 Nickel 18-8SMo
(continued)
Nonferrous
Metals and Alloys
783
TABLE
5.37:
VARIOUS
METALS
AND First Choice 18-8s N-2
ALLOYS-WALWORTH
(continued)
Corrosive
Medium
Temp F 125 200 212 125 :;i 500 150 900 125 70
Alternate
Corrosive
Medium
Temp -F
First Choice
Alternate
Hydrazine Hydrobromic AcidIn cow. to 50% Hydrochloric AcidIn cont. to 37% Hydrocyanic Acid Hydrofluoric Acid In cont. to anhydrous (Air free) In cont. 90% to Anhydrous Hydrogen Fluoride-Gas Hydrogen Peroxide In cont. to 90% Hydrogen Sulfide OrY Wet lodoform Ink IsomerizationButane (HCI & AIC13) Kraft Mill Solutions Black Liquor In cont. to 75% solids White Liquor Green Liquor Lactic Acid In cont. to In cont. to Lard Lead Nitrate In cont. to In cont. to Linseed Oil Plus H2S04
N-2 18-8SMo Monel A-20 Monel 18-8s 18-8s 18.8SMo 18.8SMo 18-8SMo N-2
A-20
Nitric Acid In cont. to 80% In cont. to 65% 50 to 85% Fuming-86% and Higher Nltro Cellulose Nitrogen Tetroxide Nitrous Acid-All cont. Oleic Acid
125 212 150 110 70 100 70 70 400 600
18-8s 18-8s A-20 A-20 18-8s 18-8s 18-8s 18-8s 18-8SMo A-20 18-8s A-20 18-8s 18-8s 18-8s 18-8s A-20
18-8SMo 18-8SMo
18-8SMo 18-8SMo 18-8SMo 18-8SMo A-20
Nickel 18-8SMo 18.8SMo A-20 A-20 A-20
Oxalic Acid In cont. to 90% All Cont. Paraffin Pentaborane Petroleum Ether Phenol (Carbolic Acid) C.P. or crude Vapors Phosphoric Acid In cont. to 60% 60 to 85%-Aerated In cont. to 85%-Air Free 85% to 100% Air Free Photographic Developer Phthalic Acid Phthalic Anhydride Picric Acid-In cont. to 100% Propionic Acid-66% Propyl Acetate Polyvinyl Acetate, 2% H*SO Potassium Bicarbonate In cont. to 100% In cont. to 40% Potassium Carbonate In cont. to 100% In cont. to 60% Potassium Chlorate In cont. to 100% In cont. to 30% Potassium Chloride Quiescent-5% Aerated-20% Saturated Potassium Dichromate In cont. to 60% In cont. to 100% Potassium Ferricyanide In cow. to 100% In cont. to 60% Potassium Ferrocyanide In cont. to 30% In cont. to 90% Potassium Hydroxide
2:; Hot 70
18.8SMo
18-8SMo 18-8SMo
100
360 700 200 200 200 275 70 360 285 212 300 192 150
I iYMo
340 300 260
18-8SMo 18-8SMo 18-8SMo
A-20 A-20 A-20
100% 100%
160 212 Hot
18-8SMo A-20 18-8s 18-8s 18-8SMo 18-8s A-20
A-20 18-8SMo 18-8SMo A-20 18-8SMo
100% 60%
2;; 3;;
A-20 N-2 18-8SMo 18-8SMo 18-8SMo 18-8s A-20 18-8s 18-8SMo 18-8s 18-8SMo 18-8s 18-8s 18-8SMo 18-8SMo
;;:;g$~ A-20 A-20

N-2 A-20 A-20 A-20 18-8SMo N-3 18-8SMo A-20 18-8SMo A-20 18-8SMo 18-8SMo A-20 A-20 Monel Monel
Magnesium Chloride In cont. to 5% In cont. to 50% In cont. to 40% Magnesium Nitrate In cont. to 10% In cont. to 100% Magnesium Sulfate In cont. to 100% Maleic Acid Maleic Anhydride Methyl Chloride-Dry Mayonnaise Methylene Chloride-Dry Milk Mineral Oil Monochloroacetic Acid-70% Monoethanolamine In cont. to 100% Mustard
1:: 300 212 70 212 212 350 212 70 212 212 300 120 212 70
18-8SMo A-20 Nickel 18-8s 18-8s 18-8SMo 18-8SMo 18-8SMo 18-8s 18-8s 18-8s 18-8s 18-8s N-3 18-8s 18-8SMo
A-20 N-2 18-8SMo 18-8SMo A-20 A-20 A-20 18-8SMo 18-8SMo 18-8SMo 18-8SMo 18-8SMo A-20 18-8SMo A-20
160 150 212 212 70
A-20 A-20 Monel
18-8SMo 18-8SMo 18-8s 18-8SMo 18-8s A-20 18-8SMo A-20 18-8SMo
2;: 200 200
200 250 ::z Potassium NitrateIn cont. to 100% 212
Nickel Sulfate-In cont. to 100% Nicotine Sulfate-8% to 15%
212 200
18-8SMo 18-8SMo
A-20 A-20
18-8s A-20 Nickel Nickel 18-8s
18-8SMo Nickel lnconel 18-8SMo (continued)
784
TABLE 5.37:
VARIOUS
METALS
AND ALLOYS-WALWORTH
(continued)
Corrosive Medium Potassium Oxalate In cont. to 100% In cont. to 40% Potassium Sulfate In cont. to 100% In cont. to 20% Pyrogallic Acid In cont. to 100% In cont. to 60% Rayon Spin Bath i7to, lp;oH,SO, Ov 2 . Sea Water Selenious Acid-In cont. to 30% Silver Nitrate In cont. to 100% In cont. to 70% Sodium Bmarbonate In cont. to 100% In cont. to 40% Sodium Carbonate All concentrations In cont. to 50% All concentrations Sodium Chlorate In cont. to 100% In cont. to 70% Sodium Chloride Puiescent-5% Aerated-20% Saturated Sodmm Hydrosulfide-65 to 68% Sodium Hydroxide t2Cga;stic Soda) 50; 75% 100% Sodium Hypochlorite 3 g.p.1. Available Chlorine In cont. to 40 g.p.1. available Chlorine Soikiu; Nitrate iOO% Molten Sodium Sulfate In cont. to 30% Concentrated Sodium Sulfide In cont. to 100% In cont. to 50% So&+ Sulfite 300; Spirits of Wine Starch Solution
Temp F 18-8s 18-8s 18-8s 18-8SMo 18-8s A-20 150 190 160 212 ;I;0 A-20 18-8s 18-8s A-20 18-8s 18-8s 18-8s 18-8SMo A-20 2:: 160 175 212 176 18-8SMo 18-8SMo
Alternate 18-8SMo 18-8SMo IS-8SMo A-20 18-8SMo
Corrosive Medium Stearic Acid-Cone. Sugar & Sugar Solutions Sulfonic Acrd Sulfur Oioxide Gas, Moist Gas, Dry Sulfur, Molten Ory Plus Moisture Sulfur Monochloride (plus CCI,) Sulfuric Acid All Concentrations 5% iO%
Temp F 400 130 200 575 300 300 200 125 200 175 150 18-8s 18-8s 18-8SMo 18-8s 18-8SMo A-20 Nickel 18-8SMo
2:;
I 18-8SMo
A-20 18-8SMo A-20 Monel
;:;;
A-20 A-20 A-20 A-20 A-20 A-20 N-3 N-2 N-2 N-2 N-2 A-20 A-20 18-8SMo 18-8SMo 18-8SMo 18-8s 18-8s 18-8SMo 18-8s 18-8s 18-8s 18-8SMo 18-8SMo 18-8s 18-8s N-3 18-8SMo A-20 Monel N-2 18-8s 18-8s 18-8SMo 18-8SMo A-20 18-8SMo 18-8SMo A-20 A-20 N-2 18-8SMo 18-8SMo A-20 A-20 A-20 A-20 18-8SMo 18-8SMo A-20 18-8SMo 18-8SMo
18-8SMo 18-8SMo 18-8SMo A-20 A-20 A-20 !4o,nn:t 18-8SMo 18-8SMo Nickel lnconel A-20 KY? 90; Oleum Sulfurous Acid All Concentrations All Concentratfons Tall Oil Tannic Acid Tanning Liquor Ta;t,arJc Acid 50: Trisodium Phosphate-20% Turpentine Unsymmetrical Dimethyl Hydrazine Urea Vegetable Juices Vmegar Water, High Purity Zin;2Qnwrium Chloride-
300 150 525 150
;:;x
Monel 18-8s 18-8s A-20 Nickel Nickel 18-8SMo N-3 18-8s 18-8s 18-8SMo 18-8SMo
212 212 175
140 260 212 150 750 180 1:: :t; 70 175
18-8SMo 18-8SMo A-20 A-20
~ 70 1 200 175 200 100
18-8SMo A-20 18-8s A-20 18-8s 18-8s
~A-20
18-8SMo
Zmc Chloride In cont. to 70% In cone. to 90% In cont. to 50% All cont. to 100% Zinc Cyanide-Moist Zinc Nitrate, 10% Zinqo~lfate Satirated
I 18-8Shlo ~ 18-8SMo
Aloyco 18-8s Stainless Steel ASTM A351 Grade CF8

Chemlcrl Requlrementr Carbon . . . .._............. Manganese . . . Phosphorus
Sulfur bdicon
Chromum Nickel .._... . . . . .
Aloyco 18-8s ELC Stainless Steel ASTM A351 Grade CF3

.......... .......... .......... percent 0.08 Max. 1 SO Max.
0.04 0.04 2.00 18.00 8.00 Max. Max. Max.
..
.........
..........
..........
..........
to 21.00 to
Chemical Requlromento Carbon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .._..._.... Manganese . . . . . . . . . . . . . . . . . . . . . . . . . .._........._ Phosphorus . . . . . . . . . . . . . . . . . . . . . . . . . . . . .._..._.. Sulfur . . . . . . . . . . . . . . .._.........._............... Silicon . . . . . . . .._.................._.........._._ Chromium .. . . . . .._
Nickel . ............ . ........ .... ...
percent 0.03 Max. 1SO Max. 0.04 Max. 0.04 Max. 2.00 Max. 17.00 to 21.00
8.00
11 .oo
to 12.00
(continued)
785
TABLE 5.37:
VARIOUS
METALS
AND ALLOYS-WALWORTH
(continued)
Aloyco 18.8SMo Stainless Steel ASTM A351 Grade CFEM

Chemlcel Aequlrementr Carbon.. ........................................ Manganese ...................................... Phosphorus .................................... Sulfur ........................................... S&con .......................................... Chromrum ....................................... Nrckel .......................................... Molybdenum percent 0.06 Max. 1.50 Max. 0.040 Max. 0.040 Max. 1.50 Max. 16.00 lo 21.00 9.00 to 12.00 2.00 to 3.00
Cast Nickel-Molybdenum Aloyco N-2
Alloy
ASTM A744 Grade N-12M ASTM A494 Grade N-12M-1

Chemlcel Requlrementr Nrckel ...................................... Molybdenum Manganese percanl Remamder 26.0 lo 30.0 1.O Max. 1.O Max 4.0 to 6.0 0 12 Max. 0 20 IO 0.60 1.W Max.
....................................
Steel
................................ .................................
Aloyco 18-8SMo ELC Stainless ASTM A351 Grade CF3M

Chemlcel Requlfementa Carbon .......................................... Manganese ...................................... Phosphorus ..................................... Sullur ........................................... Srlicon ..........................................
Srhcon ..................................... Iron ........................................ Carbon.. ................................... Vanadium ................................ Chromium ..................................
percent 0.03 Max. 1 SO Max. 0.04 Max.
0.04Max.
1.50 Max.
..17.~lO 21.00
Cast Nickel-Molybdenum-Chromium Atoyco N-3 ASTM A944 Grade CW-12M ASTM A494 Grade CW-12M-1
Chemical Requlremenle Nickel ...................................... Chromium.. ................................ Molybdenum ................................ Tungsten ................................... Iron ........................................ Manganese Vanadrum Carbon
Alloy
Chromium ..................................... Nrckel ........................................... Molybdenum
9.Wlo13.W 2.00 IO 3.00
.....................................
percent Remainder 15 5 IO 17.5 16.0 to 16.0 3 75 IO 5.25 4.5 IO 7.5 1.O Max 1.O Max. 0.20 to 0 40 0.12 Max.
Aloyco 18-8 SCb Stainless Steel ASTM A351 Grade CFEC

Chemical Requlremenlr Carbon ......................................... Manganese ...................................... Phosphorus .................................... Sullur ........................................... Srhcon ....................................... Chromrum petcent 0.06 Max. 1SO Max. 0.04 Max. 0.04 Max. 2.00 Max 16.00 IO 21.0 .... .6 Carbon Mm 9010 12.0. 1.0 Max.
................................
Sihcon .....................................
.............................
................................. .....................................
Alloy
Nickel .................. Columbrum ........ AIC~CC Carbon 20
ASTM A351 Grade CN-7M
Chemlcel Requlrementr Manganese Phosphorus ................................ Sullur ....................................... S~lrcon .......................................... Chromium ....................................... NIckeI ........................................... Molybdenum .................................... Copper.. ........................................ AI~YCC
.......................... ...............................
pwcont 0.07 Max. 1.50 Max. 0.04 Man. 0.64 Max. 1.50 Max. 19.0 to 22.0 27.5 lo 30.5 2.0 IO 3.0 3.0 IO 4.0
Nickel-Chromium-Iron Aloyco lnconel
ASTM A744lA494 Grade CY-40

Chemlcel Requlramanlr Nickel ...................................... Chromium .................................. Carbon percent Remamcler 14.0 to 17.0 0.40 Max. 11 .O Max. 1.56 Max. 3.00 Max.
.....................................
Iron ........................................ Manganese ................................. Silicon ..................................... Tenelle Requlremantr
CD-~
ASTM A351 Grade CD4MCu

percent 0.04 Max. 1.00 Max. 1.OOMax. 0 04 Max 0 04 Max. 24.510 26.5 4 75 to 6.00 1.75 IO 2.25 2.75 to 3.25
Tensrle Slranglh. psi
........................
70000 Mm. 26000 Mm. 30 Mm.
Chemicel Requirements Carbon ......................................... Manganese ................................... Srhcon ......................................... Sulfur .......................................... ........................ Phosphorus ...... Chromwm Nickel Molybdenum Copper
Yreld Stranglh. psi .......................... Elongabon. percenl in z ....................
..................... ...
NIckelCopper Alloy Aloyco Monel ASTM A744lA494 Grade M-35

Chamlcel Roqulramenle Nrckel ...................................... copper ..................................... Srlicon ..................................... Iron ........................................ Manganese ................................. Carbon ..................................... Tenrlle Requlremente Tensile Slrength. psr ........................ Yreld SlrengIh. psi .......................... Elongabon. percenl in 2 .................... percant Remainder 26.0 lo 33.0 2.00 Max. 3.56 Max. .50 Max. 0.35 Max.
.......................... ............................
ASTM A744lA494 Grade C&l00
Nickel
Chemlcel Requlrementa Srlicon .......................................... Carbon.. ........................................ Manganese ...................................... Iron ............................................. Copper .......................................... Nrckel ...........................................
perconl 2.00 Max. 1.00 Max. 1.50 Max. 3.00 Max. 1.25 Max. 95.0 Min.
65000 Min. 3OooO Mm. 25 Mtn.
Glass, Ceramics, and Carbon-Graphite (contmuedJ
787
TABLE
6.1:
CARBON-GRAPHITE-U.S.
GRAPHITE
GRAPHITAR SEAL GRADES

GRADE TYPICAL APPLICATIONS
For low to medium pressure oil sealing applications. This grade has relatively high porosity, which aids seal face lubrication.
GRAPHITAR
Grade 30A Grade 38 Grade 39
For low to medium pressure applications. economical in many applications.
Grade 38 is relatively easy to mold and is most
A universal grade for use in high pressure applications. Can be used to seal almost any medium except very strong oxidizing or alkaline agents. Grade 39 is the hardest of all GRAPHITAR grades, with a scleroscope reading of 105. Similar to grade 30A in low to medium pressure applications.
Grade 67 Grade 70 Grade 86 Grade 114 Grade 2690 Grade 3048
Similar in many respects to grade 38, this grade will also perform well in non-lubricated service such as sealing air. A universal grade for lubricated or non-lubricated service. Grade 86 offers excellent compressive strength, an extremely low porosity and excellent wear resistance. A very strong, hard grade which is resistant to any chemical function at all. Frequently used in sealing gasses. in which GRAPHITAA Grade 2690 can is
A high temperature material for seal applications which exceed used almost exclusively for sealing high temperature gasses. Superior for aircraft engine main shaft seals. oxidation resistance for long service life. Combines excellent
700F.
lubricity with good
Graphitar
A 2 64 3 67 18 75 30A 80 34 84 48 110 2413
Grades
B 14 35 38 39 40 47 70 77 86 88 89 92 94 95 108
by Chemical
C
compatibility
D 2767 2840 2864 2865 E
2690
category.
F
101 102 103 105 107 109
2831 2832 2833 2835 2837 2859 2887 2957 3030
2866 2936 2980 3648
111 112 113 114
Resistance to chemical attack varies among the GRAPHITAR Grades because of formulation and processing differences. While each Grade was developed to meet specific physical requirements, the differences do produce chemical effects. The following chart provides a guide to the selection of the appropriate GRAPHITAR Grades. They can be grouped into six chemical compatibility categories-see chart at left.
GRAPHITAR COMPATIBILITY CHART

Chomiul Craphitar Cstr8ory Se~Slsd ABABAB-. D-f D-f -f
Galhc Glulamlc Hydrobromlc Hydrochloric Hydrocyamc Hydrolluorlc Hvdrotluos~hc~c Hidrogen PeroxIde Hywchlorous Isophlhal~ La& Lauw Malelc Mahc Muriahc
Crrphitrr C&gory Su~crtrd ABCDABCDABD. AB. D. A8. Df f f f f
ACIDS
Abrehc
Carbohc
Aceltc Acehc Anlrydrlde
Acel~lsal~cyl~c Adrplc
Aqua Reds3 AlWll~ Ascorbic Battery Ben~enrullomc 8or1c
ABCD-f ABDAB.D ABCD-f ABCDABCDABCD ABD. ABCDABCDABCD.F ABCD. ABCD-f
f F f
f
Benzorc Boder Actid Phosphates

EU~IIC
f f f f f
Carbomc Chloro?e Anhydrous Llquld Chlorlc Chloroos Chloroacehc Chlorosultorhc Chromic Cllrlc Cresyhc Cyanlc f ally Acids flooborlc FlUOSlllClC formIt
Ai:
AEkiib.
b: f
D-f
f f
;i::.F
AB: D. ABCD. ABCD. AB. DAB D A8.D (continued)
F
f f f f f f f
ABCD.f ABD-F ABCDf
ii::::
ABCD-f
788
TABLE 6.1:
Chrmical Nrlrahng To 7Sp;, Nrrrrc 0 to ZOZ; Nrtrrc 20 to 100% Nitrous Olerc Oleum Orlhophosphorrc Organrc Acrds Oxalrc Palmrhc Perchlorlc Phenolsulfonrc PhOsphorK Glrcral Phthahc Prcrrc Propronrc Pyrofialhc Sahcyhc Sorbrc Slearrc Succmrc Sulphurrc 0 15% Sulphurrc 15 96x, Sullurour lannrc Tarlarrc Terephlhahc Toluenesultomc TOIUIC Trrchloroacelrc urrc Valerrc Vrnyl Acetate
Crrphitrr Catqory Suggerled
GRAPHITE
Chemical
(continued) Craplitrr Category sugpslod

Chrmiul Sodwm Phosphates Sodrum Sdrcale Sodrum Sullale Sodrum Sullrde Sodurrn Sulhle Sodrum Throsullale Slannrc Chlorrde Slannous fluorrde Sulhle Lrquors Sultale Lrquors Trrsodrum Phosphale lrnc Acelale 2mc Ammonrum Chlorrde 2rnc Chlorrde 2rnc Hydrosullrle Zrnc Sullale Crrphitrr Catagory Suggested ABABAB. AB. ABAA;: ABAB. AB. AB. AB. AB. AB. AB. AB. D-f DD-f D-f D-f f
SALT SOLUTIONS
Alkylaryl Sullonales Ally1 Chlorrde Alum r Ammonra I Alum rChromer Alum t Polash I 4lumlnum Chloride 4lummum Sullale Ammoncurr Brcarbonate Ammonrum Carbonate Ammonrum Chlorrde Ammonwm Nrtrate Ammonrum Phosphate Ammonnrm Sullale Ammomum fhrocyanale Arsenrc frrchlorrde Bakmg Soda Barurm Carbonate Barnrm Chloride Barrum Suttate Barrum Sullrde Borax Boner Feed Waler Compou Calcwn Brsulhte Calcrum Chlorrde Calrrum Sullale Calgon Chromwm Potassrum Surlale Copper Chlorrde Copper Nrtrate Copper Sullale FemC Chlorrde Ferric Sullale ferrous Chloride ferrous Sulfate Clauber s Salt Ink Lead Acetate Lead Carbonate Lead Nrlrale Lrlhrum Carbonate Mapnesrum Chlorrde Magnesnrm Oxrde Magnesrum Sulrate Manganous Sullale Mercury Salts Nrchel Acetate krchel Chlorrde Nrckel Nrlrale Nrcher Sullale Nylon Salt Phosphorus Trrchlorrde Polassrum Brsullrde Polassrum Carbonale Polassrum Chlorrde Polassrum Chromale Polassrum Cyanrde Potasstum lodrde Polassrum Permanganale Polassrum Phosphates Polassrum Sultale Sal Ammonrac Sal Soda Sea Waler Sdver Nrtrale Soda Ash Sodurrn Alummale Sodrum Acrd Sullale Sodrum Brcarbonale Sodrum Brsullale Sodrum B6ulhle Sodrum Borate Sodnrm Carbonate Sodrum Chlorrde Sodrum Chromate Sodrurn Cyanrde Sodrum Drchromale Sodrum fluorrde Sodrum Ndrale Sodrum Nrlrrle ABCD AB AB-D AB AB AB. AB. ABAB. AB ABABAB. ABABAB. AB.D ABAB-D AB. AB.D ABCD-f AB.D AB. AB. ABCDABABAB. AB. AB. ABAB. AB AB. ;;: ABABAB.D ABAB. AB. ABABAB. AB AB.D AB. AB. A ABAB. AB.D AB. AB. ABA___.f AB. AB. AB. AB. AB. .D.__f AB. AB. ;;: AB. AB. ABAB. AB. AB. AB. ABABABAB. DD D D. D. 0. 0. D.f D. D-f D. D. D. D. DD-f F f f f f F f f f f f f f f f f f f 0. D. F f f f f f f f
ABD. AB. D. ABCDABCD-f ABAB. ABABAB. AD. ABD-f D. DDD-f D. D-f
F f f
F f F F
;:: D- F D- f D- f D- f D. f D. f D-f D. f D-f
;t;;:: AB. D-f ABD. f A. _. .f E&: ABCD AB AB AB AB AB AB AB f F f f f f f f
FOOD & FOOD PRODUCTS

Asprrm Alcohol Ale Beer Beet Sugar Lrquors Butter Bulterrnrlk Cane Sugar Lrquors Castor 011 Cheeses Chocolale Crder Crlrus Jurces Coconut 011 Cotlee Cola Drunks Corn 011 Cornstarch Slurry Collonseed 011 De&m Dextrose LUG f rsh 011 frurl Jurces Gelahn Hydrogenaled fats Ice Cream Jelly Kelchuo Lard Mall Monnrlol Mayonnarse Maple Syrup Mrlk Mrneral 011 Molasses Monosodrum Dlulamale Dleomargarrne Dhve 011 Palm Or1 Prchle Solubons Salad 011 Sorbrlol Saccharme Soybean 011 Sugar Solubons Soll Drrnhs Starches Vegetable 011 Vmegar Whrskey (L Wme Waler Yeast Yogurt ABCD.f B.B B. BB. B. -B BB. B. B. B. B. 8. D. D-f 0. D. D. D. D.f D. D. DD. D-C DD-f D. D. D-f D-f D. D. D-f D. D. D. D. DDDD-f D-f D. D-F D. f f F f f f f F f f f f f f f F f f f f F f f f f f
D D DD D D D
ALKALINE
CHEMICALS
AB AB AB-D A AB AB-D AB AB -D Aft ABAB AB. D D DD-f D D D. D-f D D D-f D D. f f f f f f f f F f f f f
Ammonrum Carbonale Ammomum Hydrorrde Amyl AmInesAnhydrous Ammonra Lrqurd Barrum Hydroxrde Bleachmg Powder Bulyl Ammes Calcrum Carbonate Calcwm Hydroxrde Calcrum Hypochlorrle Calcrum Oxrde Causbc Soda Cycloherylamme Delernenls Orethanol Amrne Drsodrum Phosphale Hydrazme Hydroxylamme Lame Slurrres Lrlhnrm Carbonate Ldhrum Hydroxrde Lye Magnesrurn Hydroxrde Monoelhanolamrne Morpholme Potassrum Brcarbonale Polassnrm Carbonate Polassrum Chlorate Polassrum Cvanrde Polassrum Hydroxrde Polassrum Phosphate Pyrrdme Soap 8 Soap Solubons Sodrum &carbonate Sodrum Carbonale Sodnrm Hydroarde Sodrum Hypochlorrle Sodrum Perorrde Sodrum Phosphate Sodnrm Telraborale Telramrne C Trrelhanotamrne Trrelhvlamme Trrsodrum Phosphale Urea Waler Glass
D. D D. D. D-f D-f D-F D f D-f ;:: DD-f f
E.
B-
6. 8.
BBB. 8.
ABAB AB-D AB ABAB--D-f AB.0 ADABABCDAB AB-.D.f AD: Aft. ABABAEABAB AB.
D. :
f : f f
D D-F D- f
f D- f D. f D-f D- f D- f D-f D.f f D- f 0. f .f D. f D- f F D-f D f D. f D. F D-F D-F D-f D. F D.f D. f
8. B.
BB. B-
E.
B8. 8. B. E-D-f
B:;:;:: BB. : 5: b: D:D:; BBB: ;: EB. 8. B. B. D. D;:: D.
b.
D. D-I DDD. D: D. D. D. D. D. D D-f
F f F f F
B.
D-f D.f D. D-
f f
t
f
f f f f f f f
;:: D. F D. f D. f D. f D- f D- f D-f D- f D- f 0. f 0. f
;:: 0. f D. f D. f 0. f D-f
GASES
Acetylene Au Ammonia IWeIr Ammonia (Anhydrousr Argon rlnerlr
x::
AB. D. A0. ABCDEF
f f
(continued)
Glass, Ceramics, and Carbon-Graphite
789
TABLE 6.1:
Chemical
Crrplitar
GRAPHITE
Chemical
(continued)
Craphitar Category suggested ABCD. ;t;;:: ABCDA6CD.f ABCDABCD-f ;;i;:: ABCD.f ABCD. z:.: ABCD ABCD.f ABC0.f ABCD.f ABCD ABCD.f ABCDABCD-f ABCD. ABCDABCD. ABCD. ABCDABC0.f ABCD. ABCD ABCD. ABCD-f A8CD.f ABCD.f ABCDf f f Chtmical Ketones Lubrrcalm Or1 Lacquers 1 Lacquer Solvents Lmseed 011 Lrgrorn t Petroleum Ether I Methyl Acetate Methyl Acrylale Methyl Alcohol Methyl Cellosolve Methyl Chloride Melbylelhyl Ether Methyl Ethyl Ketone Methyl formate Methyl Isobulyl Ketone Melhyl Sahcylale Mmeral 011 Mmeral Spurts Monochlorobenzene Naphtha Naphthalene Ntilrobenzene Oclyl Alcohol Oleyl Alcohol Orlho Drchlorobenzene PIml 6 Parnl Vehules Paraflm Paratlrn 011s Para Drchlorobenzene Paralormaldehyde Paraldehyde Perchloroethylene Phenol Pme Chl Polyethylene Polystyrene Polyurethane Preslone Propyl Alcohol Propylene Oxhlorlde Resorcmol Sloddard Solvent szrene Telrachloroethane Telrachloroethylene Toluene Tr%hlorobenzene Tr~chloroelhylene Trlcresyl Phosphate Turpenbne Varmsh Vmyl Acetate Vmyl Chloride Waler Wares Xylene Craphitar Category Suggested ABCD. ABCD. ABCD. ABCDABCD. ABC&f ABCDABCD ABCD. ABCDABCD ABC0 ABCDABCD ABC0 ABCDABCD. ABCD. ABCD-f ABCD.f ABCD. ABCD. ABCDABCDABCD. ABCD. ABCD. ABCD. ABCD. ABCOABCD. :;:;:: ;;:;:: AECD ABCD. AECDABCD. ABCD. ABCD ABCD AECD AECD ABCDABCDAECDABCD ABCD AECD ABCD AECDAECD-f AECD ABCD. AECD f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f f F f f f f f f f f f f f f f
Crtrpory suggested
ARA&;: ABCDEf ABCOEf x:: &ii! ABCDLf ox:: ABib;; ABCDEF ABCDEf AB: z;; ABCDEf ABCDCf ABCDff ABCDEf ABCDEf jk;;: ;;;:: :; 0. f
~;m;T~dluor~dc Butadrene BUlane Bulylenc Carbon Dlondc Carbon MonorIde Chlorme Cyanopen $c;ny ne Elher Ethylene fluorme freons Hydrogen Hydrogen Chloride Hydrogen fluorrde Hydrogen Sulhde lodme Melhrnc Natural Gas Neon klrlc Ollde NIlrogen Nrlrous Oarde Oxygen Phosgene Propane Propylene Sleam 110 5OOf.j Sullur Dlollde Sullur TrIorIde
Carbrlols t Dlethylene Glycol Ethers1 Carbon Lhsulhde WoZ; Telrachlorlde Chlorobenzene Chlorolhene ;;Egslrn Creosote Cresol ;;;e;Jdehyde Cycloherane Dlacelone Dlbulyl PhospWe Chbulyl Phlhalale Lhchloroelhane DrchlorOpenlane Chesel 011 Dlelhylbenzene D~elhyleneglycol Dlelhyl Sullale ;rxl$I Phlhalale D:penlene Dlphenyl Dowtherms Elher.Dlelhyl Ether. Petroleum Ethyl Acetate Ethyl Alcohol Ethyl Benzene Ethyl Chlorrde Ethyl Mercaplan flhyl Sullale Ethylene Ethylene Dlchlorrde Ethylene Glycol Ethylene Orlde formaldehyde :;yO;Lwehed I furlural furluryl Alcohol Gasohne Glycerme Glue Heplane Hydrazme Hydrate Isobulyl Acetate lsobulyl Alcohol Isopropyl Acelate Isopropyl Alcohol j;p;fcp;l Ether Kerosene
f f
f f f f f f f f f F
Ef
SOLVENTS
Acelaldehyde Acetone Acelophenone Acrolem Acetate Solvents Almond 011 Amy\ Acelale Amy1 Alcohol Amy1 Chloride Andme Anlhracene Asphalt fk&ehyde
& ORGANIC
MATERIALS
AtcCD-f ABCD-f ;;;;:: ;;;;:: ABCD. ABCD.f ;;;;:: ABCD-f ABCD-f ;;;;:: ABC0.f ABCDABC6.f ABCD.f
ABC0.f ABCD ABCDABCD ABCD-f ABCD AECD

ABCD-f AECO-
f f f f f f f f
Bulyl Acetate Bulyl Alcohol Bulyl Cellosolve Camphor
ABC0.f ABCDABCDABC&f AeC0.f ABCD.f ABCD.f ABCDA8CD.f ABC0.f
- Not ruommended lor IhIs enwronment Tins does not predU ladure lor a Owen Glade only that aMthe Grade would be prelerable. all other conslderabons bemg equal.
790
TABLE
6.2:
CERAMIC
FIBER
PRODUCTS-3M metal oxide fibers suitable for producing textiles tapes and sleevings are exceptional, high temperature performance requirements and to offer performance
NEXTEL 312 Ceramic Fibers are continuous polycrystalline without the aid of other fiber or metal inserts. Nextel fabrics, products designed to meet the toughest thermal and electrical far beyond the useful limits of other high temperature textiles. Individual fibers of NEXTEL metal oxides are (by weight) (SiOs).
312 are transparent, smooth and continuous. 62% aluminum oxide (AlsOs), 14% boron
NEXTEL 312 Fibers, in terms oxide (BsOs), and 24% silicon
of their dioxide
The effects of metals on NEXTEL 312 Fabric heated in air at 2000F are shown below. The metals which cause attack (molten copper and tin) are extremely reactive at test temperature. Most common metals, however, have no effect on NEXTEL 312 Fibers. The effects of chemicals on NEXTEL 312 Fibers after exposure to 10% chemical baths (room temperature) are also shown.
Effects
of Metals on NEXTEL
312
Fabric
Metal
Effect at 1100C (20 12F)
aluminum, platinum, chromium,
boron, cobalt, gold,
No attack No attack No attack No attack No attack Severe attack
iron, nickel, silicon, soft solder copper, tin (molten)
Effects
of Chemicals
on NEXTEL
312
Fibers
HCI (hydrochloric HA04
acid)
90 50
(sulfuric acid)
hydroxide) CaO (calcium oxide-lime)

After exposure to 10% chemcal
less than 1 40
baths and 10 ml at 815C (149YF)
Glass, Ceramics,
and Carbon-Graphite
797
TABLE 6.3:
CERAMIC
LININGS-ABRESIST
ABRESIST is a mineral material, a silicate with a high compressive strength and a high modulus of elasticity, with extreme resistance to abrasion, whereby a certain sensitivity to impact is also present. In addition to its abrasion resistance, fused cast basalt does not rust and thus always presents a smooth sliding surface. Even after an idle period in a wet transportation system, clogging and plug formation are largely eliminated.
Resistance of ABRESISP
Agent Potash lye (KOH 25 %) .353 K. hot, llowmg Potash lye (KOH 10 %). Sbll Soda lye (NaOH 25 %) 353 K, hot. flowmg Soda lye (NaOH 10 %) Soda solubon (Na,CO, 5 %) Calcium chloride (CaCI,). pasty, sbll and flowmg a1
agalnst Bases
Test * Plate test 100 % * 100 % * almost 100 % almost 100 % almost 100 %* 100 % OperatIonal 112davs test. no weight loss after
60C 2OC 6OC 20C 20C 20C
Materials Tesbng lnstltute Neuwled: no weight loss after 30 days OperatIonal test: weight toss of 0.6 % after 9 months Materials Tesbng lnsbtute Neuwled; 0.9 % weioht loss after 30 davs Materials Testmg tnstltute Neuwled. 0.2 % weight loss alter 30 days Operabonal lest; no weight toss after 25 days
The values cited are average values.
Resistance of ABRESISP
Agent
aaainst Acids
al 293
Test Plate to*1 ** Powder tss1

l
Hydrochloric acid (HCI 25 %). flowing rlydrochloric acid (WI 36 %). stilt Sulfuric acid (l-l&01 40 %). still Sulfuric acid (f-f&01 94 %). St111 Sulfuric acid (HzSO~), concentrated Nitric acid (HNO3 65 %). still Hydrofluorlc acid (HF 20 ?&) Hydrofluorlc acid (HF 40 %) Probintiure, still
almost 100 % Protective layer almost loo % almost

loo %'
operational lest up to 41 days; weight loss less than 0.2 % weak bleaching of surface Materials Testing Institute, Neuwied; 0.6 % weioht loss after 30 davs Operational test; no weght loss after 60 days
100%
Materials Testing Institute Neuwied; 0.4 % weight loss after 30 days 0.003 % weight loss after 7 days (19 Dec. 1966) Materials Testing Institute Neuwied; no weight loss after 30 days
almost 100 % loo %
LimIted resistance* Operational test; 0.5 mm w= etched away at surface after 20 days Limlted resistance* Materials Testing Institute Neuwied; 22.8 % weght loss after 30 days loo % loo % Materials testing lnstttute Neuwied; no weght loss after 30 days Attests by many dairies and the Kiet Testing Instihrte. No weight loss after 3 years
Lactic acid (6 %). flowmg and still
792
Corrosion
Resistant
Materials
Handbook
TABLE
6.4:
FOAMED
GLASS
BLOCK-PENNWALT
A totally inorganic borosilicate foamed glass block containing no binders, PENNGUARD Block offers excebtional resistance to most acids, solvents and weak bases, and over a temperature range up to 960F (516C). It is controlmanufactured as a 100% closed-celled, foamed glass block, impervious to acidic liquids and gases, is extremely lightweight, and possesses low thermal conductivity values even under completely acidic liquid operating exposures while its low coefficient of thermal expansion provides high resistance to thermal shock. PENNGUARD Block does not support combustion and can be used alone or in combination with refractory or chemically-resistant masonry/ monolithic linings at higher temperatures to provide a unique combination of acid corrosion protection and heat conservation. The block is installed in a manner similar to a chemically-resistant masonry lining, utilizing special mortar or an adhesive/membrane to fully bond the block to the substrate and to fully side joint between adjacent block.
Acid Condrnsste Solutlons end Gases Sulfuric Acid t-I&O, Nitric Acid. HNO, Hydrochloric Acid, HCI Phosphoric Acid, H3P04 Acetic Acid Hydrofluoric Acid, HF Steam Impingement Base and Salt Solutions Ammonrum Hydroxide, NH,OH Magnesium Hydroxide, Mg(OH)2 Calcium Hydroxide, Ca(OH)* Potassium Hydroxide, KOH . Sodium Carbonate. Na.CO, Sodium Chloride. NaCl . . . . . . . . .
Bese end Selt Solutions Sodium Sulfate. Na&O. Sodium Sulfite. Na2S03 Ammonium NItrate, NH,NO Oraanlcs Heptane Kerosene Benzene Toluene
5:_
1 I
l
Diethvl Ether Ethyl Acetate All concentrations including gaseous forms.
. .
I I
TABLE
6.5:
GLASS
PIPE-CORNING .8 .32
Acids Sulfuric, hydrochloric, nitric, and acetic are only a few of the most corrosive materials PYREX@ pipe can handle with ease. Halogenated Hydrocarbons Bromine, chlorine, brominations and chlorinations all are perfect for Cornings corrosion resistant systems. Pharmaceuticals Solutions are in contact only with PYREX@ Bra& Pipe and virgin TFE preventing possible contamination of product. Alkalies & Hydrofluorlc Acid. Low temperature can generally be handled. However, hot alkalies and hydrofluoric acid should be avoided. Addltlonal Applications Hydrogen peroxide Brines Hot. food grade phosphoric acid All chemicals in the neutral pH range
2 .28 ? E .24 0 2.20 6 Z.16
/ CORROSION OF CODE 7740 GLASS t BY NaOH SOLUTIONS
t i i i i i i i rii
20 Concentrated hydrofluorrc acid attacks Code 7740 glass at all temperatures. Mild solutions dumped mto drainlines can be tolerated at room temperatures.
60
100
140 OF.
180
220
TEMPERATURE,
Alkaline solutions attack g/ass very slow/y at room temperatures, but as temperature IS Increased over IOOF. the corrosion rate rises rap/d/y.
Glass, Ceramics,
and Carbon-Graphite
793
TABLE 6.6:
GLASSED
STEEL-PFAUDLER
corrode
The glass coating of the GLASTEEL composite is a non-conductive mixture of low energy oxides that can only by a self-limiting ion exchange reaction (acids) or by direct chemical solution (alkalis). Consequently, rosion rates of GLASTEEL can be accurately measured and valid predictions of service life can be made. Acid Resistance
the cor-
Outstanding acid resistance under extreme process conditions is a primary feature of Pfaudler GLASTEEL. The charts which follow can be regarded as reliable quantitative laboratory data on the corrosion resistanceof GLASTEEL 5000 in five common reagent-grade acid solutions (liquid phase). Chart data are presented in terms of glass loss expressed in millimeters per year. Average Pfaudler glass thickness is approximately 1 to 2.25 mm (40 to 90 mils) on reactors, high voltage tested. Therefore, approximate years of anticipated service life may be estimated from the charts.
Acid Corrosion Charts

GLASTEEL 5000-HYDROCHLORIC
Temp. F
ACID
Temp. C Temp. F
GLASTEEL 5000-SULFURIC
ACID
Temp. C !32
,
!04
177
I49
121
93
66 0 10 Cont. The graph shown and here 20 - wt. % IS also typlcal acids. for hydrobromic. The graph 30 37 0 10 20 30 40 50 60 70 80-100
Cont. _ WI.% shown acid. here IS also valid for sulphurous
hydrlodic
chloroacetlc
GLASTEEL
SOOO-PHOSPHORIC
ACID
Temp. . C Temp.
aF
GLASTEEL
5000-ACETIC
ACID
Temp..
(continued)
Glass, Ceramics,
and Carbon-Graphite
795
TABLE
6.6:
GLASSED
STEEL-PFAUDLER CARBONATE
Temp.
kontlnut?d)
GLASTEEL 5000-SODIUM
Temp. F
GLASTEEL 5000-AMMONIA
C 100 Temp. F Temp. C
356
320
284
204
t-
140
240
176
176
140 7 8 9 PH 10 11 12
60 7 8 9 10 PH 11 12 13
60
Corrosion Testing
Testing to the Boiling Point.
Testmg up to the boihng point is done usmg the equipment and procedures specified by the International Oragnrza. tion for Standardization (ISO).
Miscellaneous Media
Corrosion Rates (mm/yr.) liquid vapor phase phase
Acids
Sample Preparatron Test Unrt Procedure accordrng to IS0 2723 accordrng to IS0 2733 according to IS0 2743. (This procedure gwes quantttatwe hquid and condensmg vapor phase data for most acids.)
Agent
Temperature (C) (F)
Water
Sample Preparatron Test Unit Procedure according according accordmg procedure kqurd and data.) to IS0 2723 to IS0 2733 to IS0 2744. (Thrs grves quantdative condensrng vapor
Alkali
Sample Preparation Test Unit Procedure according to IS0 2723 accordrng to IS0 2734 accordrng to IS0 2745. (This procedure gives quantitative liqurd phase data for all alkaline solutrons up to 80C (176F). For temperature above 80C. consult Pfaudler.)
Aqua Regia Barium Hydroxide sat. sol. Bromine Chlorosulfonic Acid Ferric Chloride. 10% Hydriodic Acid, 20% Lithrum Chloride, 10% Lithium Chloride, 30% Monochloracetic Acid, 20% Oxalic Acid, 50% Phosphorous Acid, 70% Sodium Fluoride, sat. sol. Sodium Sulfide, 5% Succinic Acid, sat. sol. Tri-sodium Phosphate 5% Water Water
150 (302) B.f? 70 (158) 150 (302) B.P 160 (320) B.P B.f? B.P 150 (302) 110 (230) B.P B.P 200 (392) B.P B.P 200 (392)
CO.5 (0.1 to.1 (0.2 to.1 CO.5 (0.1 (0.1 (0.1 to.2 (0.1 <O.l CO.1 CO.5 CO.5 CO.1 CO.5
CO.2 CO.1 <O.l to.1 <O.l (0.1 CO.1 <O.l
Comparative Resistances of Materials of Construction
TABLE 7.1:
STEEL, ALUMINUM AND GLASS FIBER REINFORCED PLASTIC TANK CONSTRUCTION MATERIALS-AMERICAN IRON AND STEEL INSTITUTE RESISTANCE OF TANK-CONSTRUCTION MATERIALS
Material
CORROSION
TO AGRICULTURAL
and Rating
CHEMICALS
r
Chemical FERTILIZERS Nitrogen solutions (no free ammonia) Nitrogen solutions (free ammonia) Aqua ammonia Mixed liquid fertilizer (1-3-O) Mixed liquid fertilizer (X-X-X) Phosphoric acid (55% P2Os) (chloride free) Phosphoric acid (55% P2Oa) (300 ppm chloride) INSECTICIDES Aldrin (1 oz/gal) Aldrin (100%) BHC (1 or/gal) Calcium arsenate Chlordane (% lb/gal) DDT (5% in water) DDT (10% in water) DDT (paste) Dieldrin (1 oz/gal) Dieldrin (10%) Lead arsenate (100%) Parathion (0.5%) Parathion (10%) Toxaphene (10%) FUNGICIDES Copper sulfate (10%) Pentachlorophenol Carbamates (5%) Mercuric chloride (10%) Sulfur (100%) Zinc sulfate (10%) HERBICIDES 2.4-D (3 oz/gal) 2,4,5-T (3 or/gal) Sodium TCA (1 k lb/gal) Sodium chlorate (10%) Sodium arsenite (8 oz/gal) Arsenic acid (10%) DEFOLIANTS Magnesium chlorate (10%) A NO A C A A A ND A C A A :: A A A A B 2 A A A A B 2 A A A A B A :: A A A B Type 304 Stainless Type 316 Stainless
Carbon Steel
Glass-FiberReinforced Plastic
A C C ND ND A C A C A
: B A B : B : ND : C
A NO A ND A :: A A NO ND A ND ND
C
ND A C A B
A ND A NO ND ND
B r! ND A C
A ; ND ND ND
C
Solutions containing frw ammonia should not
Resina used to formulate glass-fiber-reinforced plastics vary in their resistance to alkaline solutionr. k caniad in a plastic tank unleu the tank is recommendelf swcifically for alkaline aolutionr.
Kay to Symbols: A. Resirtent to corrosion. Should pfwide low wvice life with little maintenance. (Ccaxion rates at wnbia-tt genwally IOU than 0.002 inch pet yew.) B. Mod~ratelv resistant. Will corrode to some extent. Maintenance and eventual replacement may ba necessary. (Corrosion ratea ambient twnfmrature are generally betwnn 0.002 and 0.020 inch per year.) C. Not resistant to conosion and not recommended for continuous UY. (Corrosion ratea at ambient tsmpwatun are gansnlly gnatat than 0.020 inch per you.) ND = No data. 796
tmpwrtunam
at
Comparative Resistances of Materials of Construction TABLE 7.2: METAL, CARBON, CERAMIC, RUBBER, PLASTIC AND WOOD CONSTRUCTION CORNING MATERIALS-
797
ACETIC ACID, 100%. CH. COOH ACETIC ACID, Dilute ACETIC ANHYDRIDE. (CH. CO),0 ACETONE. CH, COCH, ACETYL CHLORIDE. CH. CCC1 ALUhlINUM CHLORIDE. AICI. HYDROXIDE. Al (OH). SULFATE. Al, SO,, ALUM?,. CONC., AI&SO.), *K. SO., etc. ALUMS.DILUTE AMINES, various NH. AMMONIUM CARBONATE, (NH.), CO. 0 o --x o_ --x _ + xx x
xxx xxx xxx xxx x xxx x xxx xx xxx xx x xx xxxx x x x xx xxx xxx xxx xxx x xx x
x x
00x----*x xxxxx ++t+;
x
xx
t
-
NH,,PO. AMVL . SULFATE, (NH&SO. ACIiTATE. C.H,,COOCH.
x x x 0 0 x 0 x t
xy
ALCOHOL, C.H,.OH CHLORIDE. C&&J ANTIMONY TRICHLORIDE, StCI, ARSENIC ACID. HAsO, BARIUM CARBDNATE, EkCO, .. HYDROXIDE, Ba(OH). SULFIDE. BaS BENZALDEHYDE. C.H. CHO BENZENE, C. H. BENZOIC ACID, C. H. COOH BORAX, NaeB.Or BORIC ACID. H.BO, BROMINE, Wet. Br. BUTANOL. C.H.OH BUTYL ACETATE, C.H.COOCH. BUTYRIC ACID. C. H, COOH CALCIUM CALCIUM n
-+xX> xXxXx> xx __00 0 xxx x xx xx +xx
x . xx> X) XXI xx1 x x x 1 Y,
x +
x--xxxxx oo+tt--x~ 0 0 x 0 0 0 x: x: ox - xx. + --t 0 vx xx _ x _ x _ v I x (
BISULFATE. CARBONATE, CHLORATE. CHLORIDE. HYDROXIDE,
CaHSO, C&. C&IO. Cdl, Ca (OH).
000x0 ox 0 I I _vl x tt_ o _ ~^ x x xx -rn __
* ..
HYFOCHLORlT&Ca@CI). SULFATE. Ca SO. CARBON DIOXIDE &y). CO. . ti &,& cY).> CARBON DLSULFIDE. CS. CARBON TFlRACHLORlDE (Moist) CCI. CHLORACEIIC ACID. CICHd33.H
tt+x
; :, n ;
x x
x - _
x 0 x
CHLOW ACID. CHLORINE. (DRY).

n
HCIO.
Cl. H. Cl
(wa). Cl. CHLOROBENZENE. C CHLOROFORM. CHCL
xxxxx 0 0 00 x xxx
Cl 0
798
TABLE 7.2:
METAL,
CARBON,
CERAMIC,
RUBBER, PLASTIC AND WOOD CONSTRUCTION CORNING (continued)
MATERIALS-
MATERtAf.9 x -VUyGXdScn(&W + - Modmtc Scnka - LWtd or Vartablc Semkr 0 - uadaf8cly Bhmk - No Inform&tom CtiE.\IICALS SOLIDS ASSU~IED IN SOLN. HOO\I TEJIPEHATUttW ASSU>tED USLESS OTtlElWISE STATED
z <a* nlr-.
n ..-
&-, ,-,
CHROMIC ACID. CI 0. mln COPPER CHLORIDE. Cu Cl.

I
XXXX
x
x x x
I
CYANIDE, Cu(CNh
I.
**
xx t xxxxx x x x x x xxx xxx xxxxxxx
SULFATB CRESYLIC AClD DICHLORETHANE.
Cu SO. C. H. Cl.
x
x x x x x x x x xx xx
x
*
DICHLORIDE,
C.H.
Cl
, :
:
0
ox ox
tt-
0
0
x
x0
~""""""-
:-t-000+
-A
*-0
txx
XL xxx -xx xxx xxx xxx xxx
--t 0+x
x0
<Y
t xx
--xx xx FUEL OIL 0 : xx : : xxx GALUC ACID. (DHX C.H.CGOH -txmms, Remed GLYCEROL. CH. OH.CHOH CH. OH HYDROBROMIC ACID, HBr HYDROCHLORIC AClD. V2ac.l. HCl. * HYDROCYANIC ml 1 @Vd ACID, (Cat.), I
ix-o-x-x
xx x x x x xxx xx xxx xx x x ox
0 0
x
x x x
II
+r
0 0 0 0 0 0 x-x 0
0 0 0 3 0 0 0 oo--0 x
-ott-c xx XXfX -ttx c xx c xx t+tx (XX-fXXX --"""""x +# k 1 Ott o----t

L
x
x
-xx xxx
x-x--x
o----x
HCN fDil. & Gad
x ,.
xxxxx ,.
,000+--t ., -ot+t-t
30IXY ----
txx
+xx
-xx x*x. xxx x
-
xxrx xxxx xxxxx
xx xx x xc xxx xc x
t
x
<xx
1.
t IXtt+X x--x++0x--1.
-xx -xx
-x+
_
LEAD ACETATE, PMCH. Coo). 0 ___ x tot XX x x xt xx * MALEIC ACID. t-xxx xt xx t +XxX xx
SULFATE, Mg So. CO. H C. H. CO.
Ii
PtXttttX
x
Y
xxx x x
XXI )I
(continued)
799
TABLE 7.2:
METAL,
CARBON,
CERAMIC.
MATERIALS-
MATERLAIS X - very Good Sewh + - Modentr !kr*icc - Lhhrd or Vukbk Serrkt 0 - Umwiaf*ctmry Bkmk - No Inlormatka CHE>IICALS SOLIDS ASSU\IEU IN SOLN. HOO\I TE>IPEHATURES ASSU.\lED UULESS OTHERIIISE STATED MA&lMERCURIC MERCURY. METHANOL. 1 c -0. &&DE, ;iS. CL Hg Cont.. CH.OH H
(DdUre) METHYL CHLORLDE, CH. Cl NAPHTHA. Petrokum MCKEL CHLORIDE. Ni Cl. SULFm N. SO .I. NITRATING ACID @15% H.SO,) .. ,. (0% H. SO.1 3. (05% HNO.) NlTRlC .. ACID. *. tr 1% Aad) Gmc.. HNO. Dilute 6. N. NO.
NiTROBENZENE,
OLELC ACID. c. HI, CH:CH(CH.hCO.H OXALIC ACID. CO. H CO. H PHENOL (Co&.) C. H. OH (mute) PHOSPHORIC ACID I . PHOSPHORIC ACID WO%), 045% @45% tlP0. Hot) Cold) DN or Moist x * x ---
ACID (45%) ANHYDRIDE.
PHTHALlC ANHYDRIDE. C. H. (CO). 0 PICRIC ACID. Sch., H0.C. H. (NO,). POTASSIUM BROMIDE. KBr .. CARBONATE, K, CO, CHLORATE, KCIO, .. CHLORIDE. KC1 CYANIDE. KCN DICHROMATE, K. Cr. 0, FERROCYANIDE. K.FdCNI. HYDROXIDE. KOH .. NITRATE, KNO. PERMANGANATE, KMnO, * SULFATE. K. SO. SULFIDE. K. S PYROGALLOL. C. HI (OH). SILVER NITRATE. AS NO. SODIVM. SODWM .. *. * .
n
~Moires P,O.
+-l-Yx x x x x x x
Molten 210ACETATE;
400-F. COO
Na CH.
..
., *
BICARBONATE, NaHCO. BISVLFATE. Na HSO. BISVLFITE. NaHSO, BORATE Na BO. CARBONATE. Na. CO. CHLORATE. CIO. CHLORIDE. Na Cl CYANIDE, NaCN FLVORIDL NaF HYDROXIDE, (Gmc.), NaOH
Ns
I
-0
x x x x
-
x x
x x
xx x x
x
x x x
0
x xx xx
xxxx x x
xx x x
--ox
x x xx xxx
I,
(continue
A0 :
800
TABLE 7.2:
METAL,
CARBON,
CERAMIC,
RUBBER, CORNING
PLASTIC
AND WOOD CONSTRUCTION
MATERIALS-
(continued)
HATRRIAIS -verycod- Mdmtc ScrvtN - U&hd OI VUtSbkSWh 0 UMDMK1~ s*nk . No lnhrmwjom + CHEMICALS SOLIDS ASSULIED IN SOLN. ROO8I TEMPERATURES ASSUMED UNLESS OTIIERWISE STATED
SODIUM n
SWAT& N&SO. SULFIDE, N&3 SULFITE. Na. SO. STANNIC CHLORIDE. Sa CL STANNOUS CHLORIDE. So Cl.
* .I I .,
HYDROXIDE, (Dilu*) HYDRDSULFITE HYPOCHLORITE. N&Ct HYPOSULFATE NITRATE_ Na NO. PEROXIDE. Nan 0. PHOSPHATE, Crri) Na. PO.
.--I+
X+XxX
-0 O--x--xX 0 00 + 0
x--x
0
txotoxo t+txtxx
t
-00
xxxxx
.x+xXxXx
XXXXXXX
xx x --x
x x x x
-RIG SULFUR, SULFUR I
ACID, Motlen.
CH. S
(CH.),.
COOH
x x x
CHLORIDE. (WCC). S. Cl. DIOXIDE (Dry). SO. DIOXIDE (Wet) TltIOXIDE So. SULFURIC ACID (FuminS to 98%) . (Hot Ccc.) H. SO. I I (cold c-4 * (7SclL9Sk) *. n (IO%-7Sk) I * (do%) SULFUROUS ACID. H. SD. SULFURYL CHLORIDE so. Cl. TANNIC ACID TARTARIC ACID, (CHOH CODHh TOLUENE, CH. C. H. TR1cHL0RErHYL ENE. Dty.C3.. C CHU
-+txxxxx
+ xxxxxxx x
-
t tttxx -+t+ttxx
TF
xxxxx xx x x x x x
xxx xxx x
xx
xxx
x x
(continued)
Comparative
Resistances of Materials
of Construction
801
TABLE
7.2:
METAL,
CARBON,
CERAMIC,
MATERIALS-
MATERlAlS x -VcryGcmdSmica + _ Moderate Servicc - Lided 01 Variable Scrvkc 0 . unsal&fact.ry Ulank - No lnfommth CHEMICALS SOLIDS ASSUMED IN SOLN. ROOM TEMPERATURES ASSUMED UNLESS OTHERWISE STATED ACETIC ACID, 100%. CHI COOH ACETIC ACID. Dilute ACETIC ANHYDKIDE, (CH. CD),0 ACEl ONt, CH, COCH, ACETYL (HLOKIDE, CH, COCI
ALUMINUM CHLOKIDE. HYDKOXIDE, AICI.
Al (OH), SULFATE, Al, SO, 3 ALUMS. CONC.. AI&O.h *K. SO,, etc. ALUM& DILUTE AMINES. ar,ous ,. ._ NH. Am AMMONIUM CAKBONATE, (NH.), CO *. CHLORIDE, NH, Cl .. HYDROXIDE. NH. OH .. N-h. NH. NO, PERSULFATE. (NH.). Sz PHOSPHATE, (NH.k P( .. (NH.).H PO< NH. aPO. SULkATE. (NH.&O. AMYL ACBTATE, C.H,,COOCH, .. . ALCOHOL, C,H,,OH *I . HLORIDE. C.H,,CI ANTIMONY TRICHLORIDE. SbCI, AKSENIC ACID. HAS 0. BAKIUM CARBDNATE, BaCO, HYDROXIDE, Ba(OH), *. SULFIDE. BaS BENWLDEHYDE, C.H. CHO HENZENE. C. HI tJbNW1C ACID, C. H. COOH BORAX, Na.B.O1 BORIC ACID, H&O, BROMINE. Wet. Br, HUTANOL. C.H.OH BUTY 1. ACETATE, C,H.COOCH. BUTYRIC ACID, C> HI COOH
I,
x
-A
---_I
x x
-
BISULFATE. CaHSOa ft&,J FITF C&,.%0, CALCIUM CARBONATE, CaCOa .. CHLORATE, CaCIO. .I CHLORIDE. C&I, HYDROXIDE. Ca (OH), ,, HYPOCHLORITE, 01 @Cl) .. SULFATE, Ca SO. CARBON DIOXIDE (Dry), CO.
I.
CALClUM ..
(continued)
802
Corrosion
Resistant
Materials
Handbook
TABLE 7.2: METAL.
CARBON,
CERAMIC,
MATERIALS-
MATERIALS x-vuyGadsmkm + - Moderate Service

- Li&kdor Vu*bksaria 0 - Udactw Blank . No Infornutia CHElMlCALS SOLlDS ASSUMED IN SDLN. ROOM TEMPERATURES ASSUMED UNLESS OTHERWISE STATED CARBON DISULFIDE. CS, CARBON TETRACHLORIDE (Moist) CC% CHLORACETIC ACID. C1CH.CO.H CHLQKIC ACID. H&p CHLORINE (DRY). CL
CHLOROBENZENE, C. Ha Ci CHLOROFORM. CHCL CHROMIC ACID. CT Ch sob COPPER CHLORiD& Cu CL . CYANIDE, Ch(CNh n SULFATE Cu SO CRESYLIC ACJD DICHLORETHANE. Cs H. CL OIETHYLAIUINE !J&&), NH DIPHENYL. C2LC.H. ETHERS, Vlriour ETHYL ACETA~C. if,cmcb tITHYspN& I CHLOROHYDRlN. Cl (C. H&Xi DICHLORlD$ C.H. CL QLYCOL. CH. OHCH. OH
mw, CL
FATrY ACJDS, Vuiow FEKRlC CHLOKLDE. PeCL .* NITRATE. PdNOd. I Fe*(w) FERROUS CHLOKIDE, Fe ; a* SULFATE; Pas01 tLUOKIN&, P. C&O FOKMIC ACtD, HCOOH PUU OlL GALIJC ACID. (OHh C.H,CX)OH GLYCEKOL. CH. OH.CHOH CHI OH HYDKORROMIC ACID. HBr HYDROCHLORIC ACID. (Coot). HU. (huou) HYDROCYANIC ACID, (Cant..), HCN I (D&l. A Gu) (COllXHp * * ma& HYDROPLUOSLLJCIC ACID. HSiP. HYDKOCARBONS h4lwhutic~ *
--xx -x-x x *x x
h
x *
x *
*xx
-xx
x x x *
xxx xxx x *
x*- 0
0
n x
---x
--
(continued)
Comparative Resistances of Materials of Construction TABLE 7.2: METAL, CARBON, CERAMIC, RUBBER, PLASTIC AND WOOD CONSTRUCTION CORNING (continued)
803
MATERIALS-
CHEMICAL.5 SOLIDS ASSUMED IN SDLN. ROOM TEMPERATURES ASSUMED UNLESS OTHERWISE !XATED HYDROCARBONS -1 HYDNOGW GAS, Ii. HYDRDGEN PliuuuJx .. *. . 1
IODINE. I. WU IODOI-ORM. CHL
wA3Dc.h tb 0. t-j 1m 1 n. s Cd,
Kfil-ONESS. Vuiou LACIIC ACID, CHa CHOHCOOH LWD ACWATE. PMCHa COO). -.H8.I HYDKOXIDE. Ma (OH). ,. SULFATE Hy SO. MALUC ACID. CO. H C, H. CO. H
MERCURY. Hy METHANOL. tic.. CH.OH tDdUW METHYL CHLOKJDE, Ciia Cl NAPHTHA. Petdouat NICKEL CiiLOKIDE. NI Cl. !xJLFxrFR-soI * . Nl-IllATING ACID @I,% ti.%h) .. ,. (~15% HI So.) ** n (05% HNO.) ( IkAca NlTLUC ACID. Cum:, IWO. ,. .* Dilula
NI.1 ROtbENZENE, ,
6.
N.
l
NO.
OLEIC ACID. C, H,, CH:CHtCH.hCO.H OXALIC ACID. CO, H CO, H PHENOL 0mc.) C. H. OH w 1w PHOSPHOKl~AClD (100%). H.PO.
045 b HUI)
PHOSPHORIC ACID D45% Cdd) ,. ACID (45%) ANHYDRIDE. Drr or M&I Mollca, P.O. PHTHALIC ANHYDRIDE, C. H, (CQh 0 PICRIC ACID, Soln.. H0.C. H. @do.). POTASSIUM BROMIDE. KBr *. CARBONATE. K, CO.
.I . .
(continued)
804
TABLE 7.2: METAL,
CARBON,
CERAMIC,
MATERIALS-
*(ATERlAls
x - very Goad
+ - Modmt.
Scrvh
- LImIted ot vulmbk Srmim 0 - Um.utiaaM~~ Blwk . No Infonnatia
CHEMICALS !JDLlW ASSUMED IN SDLN. ROOM TEMPERATURES ASSUMED UNLESS OTHERWISE STATED
POTASWJMCHLORATE. CHLORIDE. * . .. KCIO, Kc1
.. ..
I.
CYANIDE. KCN DICHROMATE, K. Cr. 0. FERROCYANIDE. K.FdCN), HYDROXIDE. KOH NITRATE. IWO. PERMANGANi+E, KMnO,
SULFATE, K. So. SULFIDE. K, S PYROGALLOL. C. H. (OH). SILVER NITRATE. AS NO. SODIUM. SODIUM Molten 210ACETATE; 400-F. xxx I x x xxxxxx XXXYXX xxxx xxx xxx : : 1 ~ xx y x Y --xx x x x x x x x x x Ns CH. Coo
0
w .. .. *. 1. * .. I w I
BICARBONATE. NsHCO. BISULFATE. Na HSO. BISULFITE. NaHSO. BORATE NI 00. CARBONATE. Na. CO. CHLORATE. Ns CIO. CHLORIDE. Nn Cl CYANIDE. NaCN FLUORIDE. Nfi HYDROXIDE. 0mc.). NmOH HYDROXIDE, (MU@ HYDRGSULFlTE HYPOCHLORITE, N&cl HYPGSULFATE NITRATE. PEROXIDE. PHOSPHATE. Na NO. Na. 0.
x x
x x --x
xx
x x
x x x x x I x-0 x--xXxX ~ x _
oii) Na. PG. 0. I SULFATE, N&SO. * SULFIDE. NoS *. SULFITB. Na. So. ~ANNIC CHLORIDE. Sa CI. STANNOUS CHLORIDE. SD CI. STEARIC ACID. CH, (CH.),. COOK SULFUR, Molten. S SULFUR CHLORIDE. Wet). S, CI. . DIOXIDE (Dry). SO. DIOXIDE (Wet) * nuOXmE So. SULFURIC ACID ~Fiunin9 to 911%) *. L I
I
I x x x x -x *x0x xx-0
---0 0 xxotq 0 0 0 0 000 0 lxx-x/-x (XXXz4XX kx x I
x x 0 0 + 0
(Hot CODL) H, SO. (cola c-4 i73%-9JI1 (IO%-75%) (*IO%\ iD. s(x Cl.
*
I SULFUROUS
A&.-H.
SULFURYL CHLORIDE TANNIC ACID
-x
!
1 x
TARTARIC am. (CHOH 030~k TOLUENE, CH. C H. TRICHLORErHYL BNB. l7w.Q.. C. CHcl
LXXX
(continued)
Comparative
Resistances
of Materials
of Con.struction
805
TABLE
7.2:
METAL,
CARBON,
CERAMIC,
MATERIALS-
MATEUAIS
x - very
+
-
tioud
servtce
kvica
Modcnle Variabk
- Llmud
or Servke
CHEMICALS SDLlDS ASSUMED IN SDLN. ROOM TEMPERATURES ASSUMED UNLESS OTHERWISE STATED
y/c.CH.
COOH
AMY
L AChlATE. C.H,,COOCH. *. ALCOHOL, C,H,,OH

,. Hl.OKIDE. ACIO. Q&cl SbCL HAIO. TWICHLOIIIDE. CARBONATE. IhCO,
xxx-
-I
xx --
xx xx x x
x 0 x x
x x x x I
ANTIMONY ARSENIC t)AtLIlJM .,
.*
HYDROXIDli.
SULFIDE. C. H. BaS C.H.
lh(OH).
CHO 0 0 x xxxx xxx ox--00 0 ---ox x 0 x --I xx x xx IL x
x
x I x x x
x x
x x 0 x xxx I x .* +* x I x
OENZALDEHYDE. HliNLCNti:. HLNWIC BORAX. WWIC ACID. Ns,U&h ACID.
C. H. COOH
HdlOa tk.
OtlOMINti:.
IllJTANOl.. C.li.OH YUTYL. ACETATE, C.H.COOCH.

LiUTYKlC ACID. C. H. COOH
WCI.
00 x -
00X
x
x x
CALCIUM RISULFATE. CaHSO, *. CALCIUM CARBONATE. CuCOa *. CHLORATE. CaCIO. .. CHLORIDE. C&I, .. HY DWOXIIW CA KIHI. HYFOCHLOUTE. Ca @Cl). ** SULFATE, Ca SO, CARRON DIOXIDE (Dry). CO.
x xx xx x x xx xx x -xx-x0---00 x x xxx
x x x x x x x I x x
x I[
x x x
x x0x x x x 0 x x x 0 x
806
Corrosion
Resistant
Materials
Handbook
TABLE 7.2: METAL,
CARBON,
CERAMIC,
MATERIALS-
CHEMICALS SOLIDS ASSUMED M SOLN. RoWI TEMPERATURES ASSUMED UNLESS OTHERWISE STATED CAKBON DISULFIDE. CS. CARBON TETRACHLORIDE wlsc)ca6 CHLORACEX-IC ACiD. C1CH.CO.H CHLOYIC ACU). tiClo* CHLORINE (DRY). Cl.
3. wet). CL C. CHCL Cr 0. dn ox 0
x x x
XII
XI
xx xx
0 00
--.
--
--01 00
CHLOROBENZENE. CHLOROFORM. CHROMIC COPPER ACID, CHLORlDE
H. Cl
Cu CL
CYANIDE,
CXCNh
x x x x:
K
SULFATE Cu So* CKtSYLIC ACID OICHLORETHANE. C, H. cl* OIEYHYNH DIPHENYL. C.H.C.H.

ETHERS. ETHYL Vmau ACETAIlS C. H. COOCH.
I.
00
0 0 -
0 0 0
--0
--x x x x
--x
&ivr&f8Rt~ti3.H~na tiTtiYffne CHLORoHYDRlN. U (C. HJQn DICHLUWDti. c.u. CL I c~LYCOL. CH, OHCH. OH
. > x x
--xx
-x
CHLOKU&, Pact NWRAII!. PaNO.). SULVATE.PG-w~ CEYYOUS CHLoKIIXi. tw it .. SUL.pATl& Faso, tl UCMINE. t. --wxwirnE FOKMIC ACID. HCOOH IJuts. ml (IALLIC ACID. (OH). GH&OOH -txxmFlE # ucr~LYCulOL. CH. OtI.CnoH CM. on IIYDKULIYUHIC ACID. Hklr HYl)YO~tiLOKIC A(lD. t-k. HCI V(DilsJ I (DIY 0-J HYDYDCYANIC ACID, (Cm.), HCN . (Dk k ciu) CZD G30 1. HP .. khlulz, HY DYOPLUosIuClC ACID. HSIP. HY~MJCAK~WNS(A~I~~O~I~~
t+KKlc ..
x x x
x x
Y
x x
XX
x x x
x x x
x *
I
I I LXX
xx xx
xxxx \
A
x x x x
x x
I
x xxx
-_ x x
* x
x * x x
1 )I
x -
* _
I
--
x x _
_x_
__
I
--x1
(continued)
Comparative
Resistances
of Materials
of Construction
807
TABLE 7.2:
METAL,
CARBON,
CERAMIC,
MATERIALS-
CHEMICALS SOLIDS ASSUMED IN SDLN. RDD,M TEMPERATURES ASSUMED UNLESS OTHERWISE STATED
HYDWDCARIONS HYDYWW HYDYO(iW cijw. -1 H.
.*
Pwwxluli KiJcw. Hv 0. .I (DIIUKJ~ * (WeI)
IODlNE. L Wa
Mt.AlCUKlC Ml!I(CUYY. MKI tIANO1.
CHLOKJLW..
H&
CL
ng
Cuuc.. CH.OH
MEIHYL CHLORlDE, CH. Cl NAYHIHA, Pei~dorrm
tlSiLW)
I I
* *
NlrROUENLENE.
C.
N. NO.
_ _ II
lxx
I
x
0
1 *
,>
0 -
___-y
PHOSPHORIC ACID 945% Cold) ** ACID &4J%) w

.. PHTHALIC PICKIC POTASSIUM .. ACID. ANHYDKIDE. ANHYDIUDE. Dry C. H. H. Kbr K. CO. or MOIU P.O. 0 (CO). (NO.). Mullen.
Soln
BHOMIDE.
HOC.
CAKBONATE.
(continued)
808
Corrosion
Resistant
Materials
Handbook
TABLE 7.2:
METAL.
CARBON.
CERAMIC,
MATERIALS-
HATERLALS x - Vwy cod srwia + . hladmc~ *rvica . Lhllr( or Varisbk Senl~
0 . UualUu(*ry Blah . No Infarma(br CHEMICALE SOLIDS ROOM UNLESS ASSlJ,MED OTHERWISE IN SOLN. TEMPERATURES
ASSUMED
STATED
! ;fi
-m -
..
BlCARLiONATE.
NaHCO. x x
x,
+ t
x x x x
t1
x>
XI
-I
7 ._ _
---cl<
0,
RK
ACID.
CH.
(Cl&)..
COOli x 0
SULFUR. Mollco. S WUR CHLORIDE. (We). S, Cl. DIOXIDE (Dry). SO. - DIOXIDE (Wet) TRIOXlDE, SO* SULFURIC ACID (Fumes to 91%) I. L (Hoc Caac) H. SO. I I cAd Cm4 I f719b-9JZ)
x x
0 0 01
00
000
,<
j7 > I
_ -.
00
0 0 01
xxxxx--x
--
oxx-
--x
---
---x SULFUROUS ACLD. H. SO. SULFURYL CHLORIDE, SD, Cl.
c ---x x x x
l Durcon
5 would be the preferred
formula
Comparative Resistances of Materials of Construction TABLE 7.3: POLYMERIC HOSE AND STEEL, ALUMINUM AND BRASS COUPLERS-GATES RUBBER
809
LISTING Stock Twe

D D2 D3 H P M A AZ C CZ C3 K V W Z
OF GATES
HOSE
STOCK
TYPES
CornPosition
Natural Rubber and Styrene Butadlene. Slmllar to Type D stock except rt IS white and compounded Gum Rubber, tan color. lsobutylene and lsoprene (Butyl). to handle food products
Ethylene, Propylene and Dtene (EPDM). Chlorosulfonated Polychloroprene Polyethylene (Hypalon). (Neoprene). for edible products.
Similar to Type A stock except white color and is used principally Acrylonltnle and Butadiene (Buna-N).
A blend of Type C stock and plastic. Used pnmanly as hose cover matenal Modlflcatlon of Type C. Has some properties similar to Type A stock cross-linked polyethylene (Gatron)
Specially compounded Fluorocarbon Eplchlorohydrin. Polyamide (FPM)
Resins (Nylon type)
GATES Code:
CHEMICAL
RATING
SYSTEM
1 This fluid is expected to have minor or no effect on the polymer. 2 This polymer should give reasonably satisfactory service. Due to the nature of this chemical and under prolonged continuous exposure, the rubber may exhibit minor to moderate deterioration and/or solution discoloration. Environmental changes such as temperature, concentration, etc., may promote increased degradation. x The polymer is unsatisfactory for this chemical and should not be used. - Insufficient or no data available for this material. Testing is advised. Ratings shown in the table are based on a temperature solutions unless otherwise noted. of 70F and 100% concentrated or saturated
(continued)
Comparative
Resistances
of Materials
of Construction
877
TABLE 7.3: POLYMERIC
HOSE AND STEEL, ALUMINUM
AND BRASS COUPLERS-GATES

HOSE POLYMER Cz Cs TYPES It W Z
RUBBER
COUPLING
(contd)
MATERIAL
CHEMICAL
AZ
A -Continued
ASTM ASTM ASTM ASTM 011 No 1. ................ 011 No 2 ...................... ................... 011 No 3 .... Reference Fuel A
Bardol B ............. Barrum Carbonate ...... Barrum Chlorrde ...... Barrum Hydroxrde Eiirm Sulfate. .......... Barrum Sutlrde .......................
..... ... ..... ..... ...... ............. ......... ........ Beer .... ....... ........ ....
................... .... ... ................ .......................................
d) ................................................
......................................................... lol ................................................... ..............................
.........
.....
..................................................... C
1 ake Alum.. ......................................................... ; alcme Lrquor ..................................................... 2 alcrum Acetate ............................................... i 1 alcmm Brsuliate ............................................... 2 1 alctumBrsullrte.. 1 1 atcrumCarbonale ....................................................................................... 2 2 atcrumChlorate ............................................... 1 1 alcrumChlorrde. ................................................ 1 1 alcmm Hydroxrde.. ............................................ .............................. X 2 alctumHypochlorrte (5%). X 2 atcrumHypochlorrte (15%)......................
1 X
:
1
i 1
2 1
: .. : ....
1
: i
x
f x
1
: i
x x
1
1
1
1
i
1
i 1
1
I
1
1 x
2 x
X 2 x
1
1 1
..
2 2
:
2 X X 2
:
X
x
; x
x
x
Use FoodGrade Hose Onty
0 Cover
stock rating only; rating for tube stock X.
(continued)
Comparative
Resistances
of Materials
of Construction
813
TABLE 7.3:
POLYMERIC

HOSE POLYMERTYPES
RUBBER
(contd)
COUPLINGMATERIAL W 2 V Iron or 304 Carbor ss Steel 316 AUMBRA SS SS
CHMCAL
Da 02 D
/ AZ A
Cz
Cj
C -Continued
Cycloheranone Cymene
...
D
....... 1. ..
_
DR>co fR15~,fRZOO,fRZOO6. fR310 .......... Dasco IfR. DCZOC DC5101 DC550, DC560 .............
...
.:.
Decalm .......... Delonued Water .........
Dracetone Alcohol
3tbutyl Ether ............... 3rbutyt Phthalate. ........................ lrbutyl Sebacate
............ P@e_ntiE!her,,,_ .
Irchlorobenzene ..................................... .I......... llFselP~!.:~,.~,LL~_~.~ I~

Irethylamme.. .......................................... Irethylbenzene ....................................... lrethyl Ether.. ........ Irethyl Phthalate.. .........
yrpentene.. ...................................................... hrco 011s.......................................................... )owthermA.. ......................................................
)uroFR HD ......................................................
IuroOils.. ......................................................... tP47.200 Flurd. Dow.. .......................................
E
nergol HL 68 ...................................................... x nergol HLPC 68 ..................................................
I
1
:
1
:
1
:
1
thy1 Acetate.. .....................................................
thylMercaptan .................................................. thy1 Oxalate ....................................................... thylPentachlorobenzene.. ................................. thylSrlrcate .......................................................
X 2 X 2
X 2 X
X 2 X
X X
X X X
X X X
X X X
...
X X X 2
...
.........
2 2
2 2 1
...
1 1
... ....
0 Cover stock rating only; ratrng for tube stock X.
(continued)
814
Corrosion
Resistant
Materials
Handbook
TABLE 7.3:
POLYMERIC

HOSE POLYMERTYPES
RUBBER
(contd)
COWLING MATERIAL W
CHMlCAL
DJ D7 D
AZ A
Cz
Ca
I K /
I Z
Iron or 304 Carborx SS
316 ALUM. BRAS SS
Steel
E -Continued
Ethyl Bromrde (DI) Ethylene Chlortde (DI) Ethylene Chlorohydrm Ethylene Dramme Ethylene Glycol
i 2
1
x : 2
1
x :
2 1
x x
X 1
x x
;
x x
;
x
Y. X
1 2 ; 2 2 2 : 1
1 -
I 1
_
Factovrs 52 Fatty Actds ferrrc Chiorrde .: ,. ~e~~_Nrtrate,,~ .l~ Ferrrc Sulfate. ..... Ferrous Chlorrde Ferrous Nltrate Ferrous Sulfate ,. Fertrhzer (Lrquld. Manure! . : Fne ResIstant Hydra-Fturd~I[exaco) Fluoborrc Acrd (65%) : Fluorrne (Lrqurd) FIUOSIIICIC Acrd (50%) _........ Formaldehyde (37%) .., formtc Acrd .._.. ..._..L :j _: __L_ ?RTiztT~.r.~ FA tlydraukc flurd ._..... .._ FRM (Code 6SS22) _..... Freon 114 .._. Freon 12 ,, _._..~-_~_ll...
! : : 2
1 2 : 2
2 22
x
1
I
hc*cx x
SDEC a, b
)ec
rid asz:::::...:... .._. Fumarlc Acid ._..... ,...,..,..
X 2
zX 2
Furan (Furturan) .._......_....... ..__. Furfural (Ant 011) .._..... Fuse1011 ~1: 1 _~ ~_ Fvmuard 150. 200 .._ Fyrquel 90. 150. 220. 300. 550, 1000. 15R60, 220R&O, 550R&O .,...._.. .._... Frrtec 290, MF ,.,..__........ ..,.,. .,.
._
G
Galhc Acrd.. ....................................... ............. Gasokne (Standard) ........................................... Gasoline iPremIum j ........................................ dasolme (Unleaded Up To 50% Aromahcs) ........ Slat&rs Salt ..................................................... 3lucose .._...,_..,..__..._....,........,,.....,...................... 3lue ._,....,,_...__..._,_......,,.,............,,,.... .__,..,.......... 3lycerme (Glycerol) ._...._____..._..,...,.......... SOIS .. . . ;lycol FR Flurds .__...__.......__.._.............,................ irease ..__..._._._,._................................................ ireen Sulfate Ltquor ._.._____._.._._.___....................... ;ult FR flurd G-200 ._.._.._._._.._.............................. ,ulf fR FluidP.37. P.4.6, P-43.P.45T47
I:
-
H
talowax 011................................................. larness @I. .............. II ...................................... teptane.. ......................................................... IFiexaldehyde ................................................. lexane ................................................................ lexene ................................................. .......... L lexyl Alcohol (Hexanol) ................................... . loughto Safe 271, 416. 520. 525, 616, 620. 625, 640 ......................... _............................... loughto. Sale 1010, 1055, 1115. 1120. 1130.. bughto Safe 5046, 5046W ......................... 0 Cover stock rating only, rating for tube stock X.
(continued)
Comparative
Resistances
of Materials
of Construction
817
TABLE 7.3:
POLYMERIC

HOSE POLYMERTYPES
RUBBER
(contd)
CDUPLING MATERIAL
CtEutCAl
Ds Dt D M
AZ
Cz
Cs
kcm or 304 316 ALUM. BRAS CarborSS SS Steel
-Continued
2
X
Monoethanolamme Mould 011 Murlatlc (Hydrochlorrc) Actd Mustard N Naphlha (Low Aromatrc Content**)
Naphthallnet
2
X X
x x x I. 1
1 :
1
1 I x I i
: .I./
: x
., :... . ..
X X
Natural Gas Neutral 011
x x
2
2 x
2
x x I ii I 1
2
.._
x
2
x
1 : i
2 2
Contact De;vl er
., Nickel Chiorrde : Nrchel Nitrate .._. Nrckel Platmg Soluhon ,.. : Nrchel Sullate .,,. Nrcotme Salts .,. ,.. ; Ntler Cake (Sodrum Bwltate) Ndrrc Acrd (10%) ..,..... ! Nrtrrc Acrd (25%) Ndrrc Acrd (40%) .._._.......... i Ndrrc Acrd (60%) ..,... .._..... Nrtrrc Acrd (Red Fummg) ._.. x Ntlrobenzene ._.....__..._........... 2 Nitroethane ._._.....,.._........... .._. ........ Nitrogen ........... .......... ............................ 1 Yttrogen Tetroxrde .......................................... ............ 2 Rrtromethane .................................... x Vitropropane.. ..... .................... ............ ........... Ydrosyl Chlorrde. ......... .......... .............. Yvvac FR Flurd ............................................... Yyvac FRZOOflurd x bvac 20 (WG). 3D(WG) .._..... ,....... i-Mane .._._.....,.
i : :
2 x
:
: 1 x : ; ;
:
2 ; x ; : X x
:
2 ; x : ; x
f !
: ; x 2
:
i : : z
2 1 2 2
1
: X x x 2 1
x : x x
1 x x
i t No Hke AvaIlal ble
i
; ;
x x
x x
:
1
1
:
I : x
xI-I2l~IxI2
0
: Y (SAE) ........................................................... : i )lerc Acrd ........................................................... x Ileum (Fumtng Sullurtc Acrd) ............................ x 2 )Itve Oil.......... ................................................... 2 )xahc Acrd .......................................................... )a ygen ................................................................ x 2 Izone ..................................................................
ktyl Alcohol ....................................................
2 2 : 2 2 : : X2
2 ! 2 1
P
..... acemaker Types 1501.3001.5001 (Cdgo) amt ................................................................... aim Drl .............................................................. lalmitic Acrd ....................................................... araffm (Petroleum) .......................................... aralormaldehyde ....................... . ....................... eanut 011........................................................... ennant Motor Dds ............................................. erchlorrc Acid .................................................... erchlorocthvlene.. ...................... I....................... entatol .............................. etrokum 011s ..................................................... henol (Cartwhc Acrd) ........................................
- - 1
x
X
x
;
: c:
2 2
2 +
: t
F1x x x : : 2
:
f e : i2 2
L
: 2 x !
: : x ;
2
-5 +2 X
;?
x i
hosohorlc Acid (85%)
.._..._............................ cri; Acrd (Water Sol&n). .............................. me 011............................................................... inene ................................................................ prazme Hydrochlorrde S&Don (34%) ...........
horone ..____..................................................... hosohonc Acid(50%)_( .,,.,....
:
2
2 2 X X
x x i
x x
2 x
L (continued)
* ForSpecial Naphlhas Contact Gates

t
f(5*) 0
Soba At Room Temp
. Check
Solvents
Fluid dlscoloratfon may occur under cenam condmons Tesmg on lhe actual appkatlon for sultablllty IS recommended
818
Corrosion
Resistant
Materials
Handbook
TABLE 7.3:
POLYMERIC

HOSE POLYMER TYPES
RUBBER
(contd)
CCMFLING MATERIAL
1
AS
CHMICAL
P -Continued
Pla!mg Solution (Chrome) Polyester Resin Polyurethane (lo Iii f )foam Potaswm Acetate Potaswm Carbonate Potaswm Chlo:ate Potassium Chloride Potaswm Cyanide Potasstum Dlchromate Potasswm Hydroxide !3@?) (Caustic Potaswm NItrate. Potaswm Permanganalf 1 Potasswm Sulfate. Potasswm Sulfite Pakwll!tY IMe!) .1....1. ~. : Prlmatol A. S. P (Agrlc Sprayi Propane Gas Proplow Acid Propyi Acetate Propy Alcohol (Propanoli Propylene (Llquld or Gas)* Purma lnseckfde
DJ 02 D
AZ
A
Cz
C3
Iron u
Carbor
304
SS
316 ALUM
SS
Steel
Potash).
.._.. Pyronai (Transformer 011)
Q
Qumtolubrlc 822
1 I
R
I 1I l I
I l II
Ramrod(Ag Spray) Rando 011s Rape Seed 011 .,,, --~ Red &I (Comm. Olelc Acid)
.__ .._.....
Regal 011s R&O _.............................. Ruklene 011s .._.._............... .._............___............
S ____.__
iiltcone Grease
illlcone:.
.._...___..__..................... -__ .. ...
t 150.
*Only tf temperature
IS above -45F
(continued)
Comparative
Resistances
of Materials
of Construction
879
TABLE 7.3:
POLYMERIC

HOSE POLYMERTYPES
RUBBER
(contd)
COWLING MATERIAL W 2 V Iron or 304 Carbwl SS Ski 316 ALUM BAA SS
CHMlCAl
DJ 0
AZ A
Cz
Ca
It
S -Continued
Sodium Acetate Sodium Bicarbonate Sodium Blsulfate (NlterCakej....
Sodtum Blsulllte.
..I. ,. 1:
..
Sodturn Borate. Sodium Chlorfde Sodium Cyamde Sodium Fluorfde (70%) : :I.::. Sodium Hydroxide (40%) Sodium Hvdroxide (50%. 115 f ). Sodturn H;pochlorrk (5%) Sodlum Hypochlortte (20%) Sodium Metaphosphate. Sodium Nrtrate
__
5brnPiZate
Sodium Perorlde. Sodium Phosphates Sodturn Sulhte.
.._.... _ .._. ._.... .._...
S&p&oh_losulfate (HP01
Sodium Trqmlyphosphate (STPP)
Solnus 011s
Solvac 3535G...
Soybean ..,,.,.......,... 011 SpentAcid..
Stanmc Chloride... Stanorl No.15. 18, 25. 31. 35. 51 ._....... jtautler Jet 1 .,... jtautfer Jet 2... .._............. steam...._.........._...... jtearlc Acid jtoddard Solvent jtyrene (Monomer) .._......... iucrose Solutions ...... .............. ........ ;ulfamrc Acrd (10%) .................................... iultamtc Acid (10%. 170 f ) ............. ...... ........ iulfur (200 f.) ............................... Mur Chloride .................................................. iullur [horIde (Dry) ................. ...................... ....... ;ulfur Trroxrde (Dry) ........................... T iulfurrc Acrd (10%) .......................................... iultutlc Acid (30%) .......................................... iutiurrc Actd(50%) .......................................... iulfurlc (75%) ........................................ Acrd ............ ,ulfurrc Acrd (93%) ............................. ;uliurlc Acid (98%) ......................................... ;ulturw Acrd, fuming .......................................... ;ulfurous Acid (10%)......................................... ulfurous Acid (75%) ......................................... un R&O OllS...................................................... ,unsale F ............................................................ untac HP Oils .................................................... untac WR 011s .................................................... unvrs 011s700, 800, 900 ................................... uper Hydra& 011s (Conoco) ...........................
jtaysolFR
e On : 2 t X HOSI 2 3
se N
I-
--_
.................. ............................................... yrup T
03 flwd (Conoco) ............................................ ynthehcOS(Cltgo) ........................................
X X all01l (To 150 f.). ........................................ 2 allow ................................................................ 2 X anmc Acrd (10%) ............................................. X X ar(Brtummous). ........................................
X 2 X
X 2
2 2 2 2
1
; i ;I X
t (5%)
Consultlnausfrtal Calalog Hose 39993ForSelecfmg Correct The SteamHose

(continued)
820
Corrosion
Resistant
Materials
Handbook
TABLE 7.3:
POLYMERIC

HoSf POLYMERTYPES
RUBBER
(contd)
COUPLINGMATERIAL W Z V boil or 304 Carb SS Skel1 316 ALLM SS
CHLlCAL
01 02 0
ii
AZ A
Cz
T-Continued
Tartax Acrd Tellbs 011s Ten0 011s. Ter !o! Terpmeol Terresshc Tetraethyllead (TEL)
IetraTydrsfuran W)
: X 1 X
1 i
X
f
1
.. .. 1
Tdanrum Tetrachlorrde Toluene !Toluol) loluew Onsocyanate Transformer 011 (Petroleum lvpe) lrans!ormer 011 (Askarel Types) Transmrssron FlGrd r lvpe AI Trrbutoryethyl Phosphate lrrbutyl Phosphate Trrchloroeth lene Trrcresyl Phosphate Trrethanolamme (TEA). ..I. Trrpoyphosphate (STPP). lung 011. .._... Turpentme Tyco! Avaion 50. 51. 60 Tycol A Turblo 37. 50. 58. 60
X X X x x x X X
2 X
: 2 x x 2 x : : 2 x X X
X x x X x x x 2 2 x
! x x X 2 x x 1 :
x x 2
x x
:
2 x 2 X X x X
x
2 X X : 2 X
1 x
1 X k : : 1
: x x
x $X
U
UconMl
Ucon Hydrolube Tyksl~OCP: ZOkP. 275CP. 3OOCP. 55OCP.9OOCP. 150OB. 2750B. ISOtT. ZOOLT.275Ll. 30011. ZOONM. 300NM Urnon C-2 Flurd. ,., ,, ,, Urnor C P 011. Union ATT Oexron ., . Umon ATF Type F .._... Jnror ttydraultc 011AW Jnror Hvdrauhc Tractor Flurd Jrea Soluhon .., . .
V
larmsh _. legetable Ok** lerwlube F.50 , F.44 _.. lmegar ..,............._._..._........................ lmyl Acetate .._..._.. lmyl Chloride (Monomer) ................................ lmyl Fluorrde ................................ ............. Mrea 011s .._....._._._........ ..__...... x x :
I
1 X X i X X 2 x x 2 2 x x x 2
I
-
:-
; i
5
x x
1
1
-11
x x
2 x
x 2 x x
x 2 x x 1
x : x x
x 2 x x
x x
x x
1 2..
i x
2 1
w
Vater .................................................. ............. Vtnese ............................................................
m
2 1 1 x 2 1 1 1 2 1 1 1 1 1 2 1
I
I2 I2 2
i i
1 1
1 2
2 x
I ; I 1 I ! I ! I :
I ! I ! I ! 1 ! I ! I ! I ! II : 1:
1 ; 1 ! I :
X
.ylene ..,.......,...,............ ._
I x I x I x I x I x I x I x I x IO1
_._....... _...._.
I1
I2
II
I1
errc
..,..,....,,,..,.._ mc Mate ,,.,.,.. ,..._ ._.. mc Chlorrde Solubons

Chromate rnc Sulfate Solutions~
mc
2 2 X
l
: 2 2 2
1 1
2
1 2
.._
4;
1
0
1 2
1 l..
A (20%)
-011 Contamrnahon May Be A Pro&m
* Use Food Grade Hose Only.
Fluid discolorabon may ocwr under certain condttions. Testrng on the actual application for suilabiltty is recommended.
Comparative
Resistances
of Materials
of Construction
821
TABLE 7.4:
RUBBER,
RESIN, STEEL, ALUMINUM, LEAD, GLASS, CONCRETE MATERIALS-GATES RUBBER
AND WOOD LINING
Table A lists all those solvents denoted by a letter in Table B and should be referred to when indicated in the chemical listing. Always use the lowest temperature recommendation shown for either the chemical or the solvent. Table B shows lining materials, chemicals, solvents, concentration and temperature limits for use. The lining materials are described across the top as column headings. The various rubber groups are listed in their approximate order of relative cost, with natural rubber being the lowest. The chemicals are listed on the left hand side. These tables contain not only the common names of the chemicals, but also any names which may be synonymous. To the immediate right of the chemicals is a list of letters that denote the common solvents for the chemical. In some instances, a reference is given to See Solvents. This indicates that the chemical is solid, insoluble in water. The chemical will be dissolved in a solution of one of the indicated solvents or a solvent characteristic of the application. In the columns headed Concentration, either the word Any or a percent concentration will appear. Any concentration refers to a water solution of chemical from very weak to a saturation value. The percent concentration refers to a limiting ratio of chemical to water in weight percent. If the concentration is left blank, then generally that chemical will be used in its pure form and not in solution with any other compound. The temperatures shown in the tables are for pure chemicals. The rows of figures to the extreme right of the chemicals, each in a column for a given lining material, indicate the maximum recommended temperature which will give satisfactory service with the tank lining. In some instances, a lining material will be given a rating of 75F for a particular chemical. This indicates that the chemical was determined to be satisfactory at room temperature, has a possibility for use and could be tried at somewhat higher temperatures. A blank space in any material column indicates no available data. Code: Unmarked chemicals are liquids at room temperature. gas at room temperature. xLining material not recommended. Table A:
CHEMICAL RESISTANCE FOR LINING MATERIALS CoCetratl0 AY AY AY AY AY AY AY AY AY AY AY AY AY AY AY AV A; AY AY AY AY a 5 zi Sd a0 70 x 150 150 x x x x x x 150 x x x x 150 x 150 x 150 120 3 2 $3 rd I 110 I la5 150 x x x x x x la5 g, 62 la5 loo 150 150 185 x x x x x x 180 80
*Indicates a solid at room temperature. -No information available. Code

e ii 0 z 120 x x 200 2cxl x x x x x a0 180 x : P 110 x x 180 2oo x x x x x x 180 x x x 180 0 2 110 x x 150 150 x x x 150 150 x x x 150 I $2 2% lia loo 180 loo 1oiJ 150 x io io $ rii P ti 150 75 400 x x loo 70 75 x 75 70 130 loo 70 75 150 loo 75 x 170 110 x x x x x 75 75 170 150 150 70 110 70 100 100 110 100 125 150 x 70 170 70 150 P 0 lDo5 &?i 210 170 180 go 75 loo 70 70 130 70 70 170 loo 70 loo 150 70 loo 70 70 150 loo 130 x x 175 140 70 150 150 go 70 70 70 130 110 100 100 150 150 70 70 75 150 E 2 z < 150 170 180 75 75 loo 75 180 130 70 x loo 70 70 130 120 120 go x 170 200 loo loo x x x x 170 150 go 90 170 70 150 f5 110 loo loo 150 70 70 70 75 75 B s 210 x 210 75 70 70 70 180 130 100
**Indicates
Solvent
B b: d 210 400 210 lao 190 210 180 180 210 210 !z s 75 x 75 x x x x 75 75 75 x x 75 x x x x x x x x x x 75 70 75 3 z 75 75 75 75 75 75 75 75 75 75
Index a aa ac al am b ba cb Cl ct CY dg dt e
Solvenls Alcohol Acehc Acld Acetone Alummum Salt Solur~on Ammoma Salt Solur~on Benzene aulyl Acetate Carbon 51 (01) Sulhde Chlorolorm Carbontetrachlorlde Cyclohexanol lItethylene Glycol bxane Ether Elhyl Acetate Ethylene Dlchlorlde Elhvlene Glvcol Es& Ferc Salt Solul~ons Gasolme Glycerine Acid Solutions Except Organic Actds Hydrochloric (HCI) Sulfuric (H2S04)
x
x x 200 75 75 loo 75 140 110 150 170 120 loo 150 70 loo
ea
ed ea
110 x
loo x la5 la0 x 185
x x 150
70 75 70 180 70180 70 130 70 210 150
x 75 75 75 75 75 75 75 75 75 70 x 75 70 75
eS
g
18
a0
150 x 150 150 loo x 75 x 185 1I
x
150 x 150 150 70
x
200 100
x
150 loo
70 I 170 70 x x 2io x x 170 150 150 70 110 loil 75
210 210 140 210 170 210 250 230 210 4oo 4oo 75 x 170 180 210 110 170 75 170 130 140 130 210 150 175 210 170 75 75
g
h
la0
110
x
150 120
120
a0
150
a0
la.5
a0
x
38
50 25 AY AY AY AY AY AY A; AY AY AY A; AY AY AY AY A; AY AY AY
a0
150 115
a0
x x 150 x
134 100
10
x ao 200
a0
1; 150 150
hc ho k ke m me rno
NMc (HN03) Hydrocarbons Alkalme or Bass Solutions KerOSee Ketones

Methanol
x x 100
x x x x x x x x x 150 x x 150 x x x x x x x 185 x x 170 x
x loo
la5 a0
150
a0
I(
x
120 150
0
0s Pe ph PY I
hlonobutyl Ether MIneral Oil Naphlha MIneral 011s Organic Solvents Petroleum Elher (Llgrotn) Petroleum Hydrocarbons Pyrldme Toluene Tanax Ac!d Turpenf~ne Vegetable 011 Water xyksne
100 x
a0
x ao x a0
150 110 150
x x x x x loo x ia5 x loo la5 x
a0
130 x 130
x
130 I
70 75
x 75 75
a0
x x 100 x x 200 x
130
x x 150 150 150 150 x 70 150 I 150 70 70 150 75 75
100 150 x 70 170 75
75 75 x 75 I
75 75 75 75
ta
tu
0
w
XY
(continued)
822
Corrosion
Resistant
Materials
Handbook
TABLE 7.4:
RUBBER,
RESIN, STEEL, ALUMINUM, LEAD, GLASS, CONCRETE MATERIALS-GATES RUBBER (continued) Table B: Chemical Resistance for Lining Materials
The list of Chemical shows recommended concentration as water chemicals insoluble in reference to solvents is Resistance of Lining Materials maximum temperatures for solutions against the lining. For water, 100% liquid is listed or a given
AND WOOD LINING
CHEMICAL
RESISTANCE
FOR LINING
MATERIALS
z
is
a
eE
sz
LE
Acelaldehyde Acetamlde Acellc Acid 8. n. a. a. ac. b. e. g, I, I. xy, w e. w e. gl. VI Any Any 10 25 50 AY 1w 25 Any Any 25 Any 75 x 150 80 * x x x * x x x * x 80 80 120 x 210 75 600 x I
120
80
220 210 180
180 x
75 125 180 170 180 210 180 180 180 loo 100 180 180 160 170 350 350 180 180 180 210 x x 75 400 :o 70 130 130 70 70 160 75 150 150 75 70 70
400 4OG 400 600 x 210 210 210 210 ,210 210 210 75 175 175 75 75 210 210
x x x x 75 * x x x * x 75
75 75 75 x
icehc
Aldehvde
a. ac. b. e. o.
80 x
x 150 loo 100 150
x
x x x x x
x
200 x
x
75 80 80 75 75
n. 1. 1. xy. w
GlaClal
Acellc
AnhydrIde
a. e. w a. Cl. e. w a. Cl. e. w a. e. w a. Cl. 8. 0. w
50
80 x
x x x x
x x
* x 75 75 I x 75
Aceftc Ester Acehc Ether Acehc Oxide ACetOne Aceloacel~c Ester Acetophenone Acelylbenzene Aceryl Chloride Acetylene + Acetylene Telrabromtde Acetylene Telrachlorlde Acefyl Oxide Acrylamlde Acrylon~tr~le Adlplc Aad Agar-agar Agricultural Ax AIrshow Air-slaked Alcohol Aldehyde
50
120
80 I:
*
x
x x x
.
loo
75 75 170
150
400 75 200 200 400 75 170 170
210 150 150
OS. w
0% VI a. ac. e a. ac. w a. e a. e a. 8. w
a. w
AY
AY Any AY 100 100 25 50 150 AY AY AY AY AY AY AY AY AY see Solvent 100 AY 100 100 50 AY AY see Solvenls AY AY AY AY AY see Solvent See Solvent AY AY AV A; AY 100 100 AY 100 AY 36 AY 10 AY
Any
80 x 801
60x 80 i0 i&l
x x
x * 80
I :O
x x x. .
60
200 75
.
75
75 75 75
200 .
180 180
75 75
x
x x 80 80 150 150 150 150 80 x 120 120 80 60 185 165 185 185 x x x 185 185 185 li5 165 150
x
x
x
x
x
x
x
70 70
80x
x
x
x. x
x x
x x
OS. w w aa. gl. v gl. h. w
210
x 100 70 200 175 x x x 75 75
Lame
x x 180 180 200 200 200200150 200 120 70 200 110
150 150
2aO 100
Lame
gl. a. a. n.
h. w e. w ac. b. e. g, 1. tu. *y, w
80 x x x x x
x
x x x
150 110
lrw) 100
loo 150 125
200 210 210
x 150 210
x 210 75
x 210 600
75 75 x
75 75 x
Algaroth Powder Ally1 Chloride Allomaleac Aad Alpha Alpha Chloropropylene Chlorotoluene
HCI a. Cl. e. pe a. w a. Cl. e. pe a. e a. a. 91. w a. Cl. e. w h, ho w gl. a. a. w ____ h. h. a. w w w w a. a. a. a. w e. Cl. w 8. w ho ho ac. w
x 80 x x 120 II 1M 150 150 150 150 150
75 75 I 130
x 75 x x x 75 x x x
125 125 100 70 100 2w 150 180 75 70 75
x x x
x x 100 x 100
75 75 x x x
75 75 75 75
x 150 185 185 120 15c 120 150 185
x 80 2iO 120 120 180 200 200 150 150 150
210 200 210 170 210 180 180 x
Alpha Hydroxyproplonac Aad Alpha Hydroxytoluene Alum Alumma Trlhydrale Alummum Acetate Solution Alummum Alummum Aluminum Alumtnum Aluminum Alummum Alummum Alummum Alummum Alumtnum Ammomum Bromide Chloride Flourlde Gel Sulfale
185 165 185 185 165 185
80 * 200 120 120 180 200 200
loo 210 75
150
70 loo 110 75
75
75
I
220
75 Ii0 II 75 f5 x 75
x
x x x x 100 70 150
Hydroxtde Nwile Polawum Sulfate Sodwm Sulfate Sulfate
150
150 150 150
165 165 165 185 185 x
Amewa Ashes Ammobenzene Ammod!methylbenzene Amlnoelhanol Amlnoxylene Ammoma Alum Ammoma Water Ammorxated Cwc Ammomum Ammomum _
I 50
x ;o
b. e e Cl. ct. w e
x150 150 150 x 150 185 150 185 x 185
100 x
120 185 185 x 185
185 200 185 200 165 200 185 200 ___~~ 160 200 75 x 100 x 140 80 120 200 150 x 200
200 180 200 200 18C x x 80
150 150 150 150 150 150 I
75 200 200 200
75 150 200 180 180 70 150 180 200 x 70
100 70 x x x 100 75
100 75 100 x 75
100 200 75 200 160 210 100 210
x 180 x 75 75 200
75 75 75 75 75
150
x 210
x
1so150 150 100 150
100
gl. w Acid aw w
120 200 110 80 x
x
200 70 75 75 x 140
75
100
210
75 70 75
Bjtluotlde Carbonate
x
150
I
200 75 --
(continued)
Comparative
Resistances
of Materials
of Construction
823
TABLE 7.4:
RUBBER,
RESIN, STEEL, ALUMINUM, LEAD, GLASS, CONCRETE MATERIALS-GATES RUBBER (continued)
AND WOOD LINING
Ammanlum Chloride Ammonium Fluoride Ammonwm Hydrate Ammonium Hydroxide Ammonfum Metaphosphale Ammonium Ammomum Ammomum Ammontum Murate Nitrate Persulfate Phosphate
a. gi, iv
Anv AV 38 38 AV Any Any A; Any AV 100 AV A; I0 100
150 80
150
150 150 150 150 150
185 x 185 x 185 185 150 185 185 185 150
1.35 150 185 185 185 185 I85 185 185 185 x 180 x
200 100 200 200 200 200 200 200 200 200 x 180 100
200 too 200 100 200 200 200 100 200 200 x 180 100
150 80 150 150 150 150 150 150 150 150 * 150
200 180 200 200 200 200 180 200 75 200
x x 75 75 70 x 80 x
100 x 200 200 100 100 200 70 70 150 70 70
x x 75 75 75 x 140 x x x 70 75
210 :0 1w llxl x x 70 70 70 2:o 210 210 210 210 210 75 210 210
x I( 75 75 x x
75 75
a gl. w a. ho. rv w w
Ammomum Sulfate Amy1 Acetate Amyl Alcohol AmyI 8oraie Amvl Carbmol Am;1 Chloride Amy1 Chloronaphthalene Amyl Hydrate Amyl Naphlhalene Anderol L-774
Anhydr:re
w
a. e a e w a e a. e
150 150
x 150 x x x x 150
x
75 x
75 x75
x 75 70
140
a e.w
tgl. ho a. b e a. e. w
3
A?
100
AV
_x__x x 180
x
120 100 x -75

80 x 150
x
l&l x
70
-.
70_x_mm
70 75
210
140 -.
x 180
I
:a0
L See Solvents 100 AV x x 80 80 80 x 60 x x 100
Anhydrous Ammoma
e.
A!Ty
loo--
x x x x x I: x x 150
100 75
100 * 75
x 75 :5 185 150 x 100 x 160
09 r I I I ; x 150 x 160
x 150 * x x 150 x 150 x 100
1 75 75 x 85 I
170 70 x 75 * 70 x 100
200 70 x I 70 I 140 70
170 100 x x 100 x 100
75 I x 75 x 100 70
75 210 210 170 210 210 210 210 210
75 x x 75 I 75
7s * II 75 I
a,b AnMe Salts Anwnal Fats Ant 011 A,,chlor. Anl~mony Chloride Anl~mony Oxychlorlde Apple Aad Aqua Ammoma Aqua Foms Aqua Regla Arachtdontc Acad Aragonlle Arsenic Acid Arsemc Trlchlorlde Askew (Translomer 011) Asphalt ASTM Oil Il. 2 h 3 ATE Aad
a. e. w
a,b e
W
100 Any See Solvent See Solvenl AnV 30 See N~trtc Acld
HCI HCI a. e. w
80 150 x x
150 150
x 185
x 150 x x 150 150 :o 150
x 100
120 80
140 200
x 75
150 200
75 75
75 100
150 210 75 400 150 75 170 170
x 75
75
x
io 150 200 $0 180 150 200 75 75 1:o 150 x x 75 170 170 2cM 150 2LO I 75 70 170 x II
:o
120 150
x x
75 x
h a. gl. ho. w Cone HCI. ps
See Solvent Any 100
150 x x x .x x
.
hc w 100 See Nltrlc Acld Any
100
x
x.. 150 x x 150 150 150 150 150 150 150 150 80 80 150 x x x 150 x x 150 x x x x
x
185 x 185 185 185 185 185 185 185 1.35 80 80 185 x I
x
185
x x
Azo11c
-.
75 75 200 200
170 170
-.
170 170
-. -
Baking Soda Banana 011 Bardol B Barium Carbonate Barwm Chloride Barium Barurn Barwm Barwm Banurn Hydrate Hydroxide Monohydrale Monosulfrde Oclahydrate
a, e
h (except H2S04) w a. a. a. w a. e. w e. w e. w e. w H2S04 H2S04
200
200
1M x
x 185 185 185 185 185 185 185 185 80 150 185 75 x 75 70 x
x 200 200 200 200 200 200 200 2w 80 80 180 x x x 150 80 150 x x
x 200 200 200 200 200 200 200 200
1w 75 170 70 100 100
150 70 170 120 150 150

150
I 70 170 x x x
x
170 75 x x
x
150 210 170 1w 180 180 180 100 180 loo 210 x 75 75 75 75
75
See Solvents AV Any Av AY AV AV See Solvent Av See Solvent AV See Sulfunc Aad
150 150 150 150 150 150 150 150 80 150 150 x x 150 140 150 x 150 x
75 x x x x x
100
75
100 loo 100 x 70 170 x x loo x x x 110 x x loo x 110
150 150 150 70 170 170 70 150 loo 150 150 120 110 150 150 loo 150 200
x x x x 170 170 175 70 loo 70 150 x 110 150 70 loo 70 175
x x x 75 170 x 70 x x 70 x x 70 x 70
Bawm Sulfate Barium Sulhde Bar~te Basu IrOn Sulfate Battery Aad Beer Beer Sugar Liquor Bengal Gelatm Benzaldehyde Benzene Benzene Carbanol Benzene Carboxylc Acld Benzene Sulfomc Acid (Llgroln) Benzolc Acld
Cone :onc v
180 75 x 200 x x x 75 200 200 x 180 x x
x
-
aa.91. w
am, em, w a, aa, ac. cb. ct. e a. e. w a. w
4
Av AV Any AY 10 loo AY Any Any e Any AY
80 180 x x x
170 210 210 210 210 210 140 210 210 210 210 250 75 x 75 x x 75 x 75 I 75 75 75 75 -
. x 150 x -
BmZlne
1;o x x
75 75 75 75
Benrou Be201
Aldehyde
Benrol Hydride Benzophenol
91. w 0.
9. e. w P. aa. ac. cb, ct. e a.. aa. ac, cb. 0 a. ab, cl, e. ho.
75 x
x
loo
x
x
x
x
(continued)
824
Corrosion
Resistant
Materials
Handbook
TABLE 7.4:
RUBBER,

FOR LINING MATERIALS
AND WOOD LINING
CHEMICAL
RESISTANCE
Benryl Benmale
Banzyl Chlonde Betula 011 Btsmulh Carbonate. Bwnulh Oxvcarbonate Bwnulh Subcarbonate Black Sulfate Liquor Black Ash Blanc Flxe Blast Furnace Gas * Bleachmg Powder Blown Llnsaed 011 Blue Cc.ppwas* Copper Sullate Blue Salts Blue vllrloI Boiled Lmseed 011 Bolet~c Actid Borax* Borax Decahydrate Boracoc Acid Bordeaux MIXtUra Bone Aod Brake flwd. Vea Brimstone Bromma Bromtne Trifluwde Bromobenzene Bromochloro Methane Brown Acetate Bunker 011 Burnt Alum Butadlane Butane* Butanes Acld
Benryl Alcohol
a. Cl, a. w a. Cl. e a. e aa. a. v HCI. HN03

t-0. t-IN09 HCI, HNOj &K H2SO4 a. w cl. cb, a, 1 gt. w a. VI
AY
100
100 Any see Solvents See Solvenls see Solvents Any Any see Solvents 100 35 loo AY
x x x x
105
80
io
x x x
x x x
75 150 x 70 x 150 150 150 :0 150 150 150 150 150 I x x x ;o x 150 x x x 150 ,x
185 185 x 150 175 185 175
150 185 x 150 150 185 185 105 150
loo 200 x I( 80 200 200 200 60
200 200 x 1:o 200 290 200 180
150 150
200 75 -.
170 loo
150
x -
x -
1w . .
x
.
a.
150 130 150 150 150

130 150
75 75
1w 1w
I 75 x x x 75 75
x 70
100
70 180 70
1. 70 x x
200
x x x 180
210
75 75
130200 70 120
gt. w a. cb. cl. a. 1 a. w w. gt WY. gt w v w a. b. cb. cl. e a, cb. cl. a. w
AW
100
Any
AY AY AY AY
loo 75
150
185 185 185 185 185 150 x x x
200 200 200 200 200 loo x x x
180 180 200 200 200 150 x x x x 120 150 200 70 loo 150 x 150 150 150 150 x x x 150
.
-
.
-
x 130 70.200.
150 150 150 150
150 150 200

100
. .
. .
.
75 300 180 300
76
. .
I x x
. . .
75 75 75
AY
See Solvents Any loo loo loo AY Any Any loo Any Any Any loo Any Any Any Any Any 100 100 loo Any 1w loo loo see Solvenls see Solvenls Any Any An; loo Any Any see Solvenls Any Any see Solvents Any Any Any Any 15 Any 15 See Solvents Any Any
185 175 la5 . I: x x x
loo
2ou . x . . 130
150
x x . x . 150 70 170 x 75 75 x
200 . I
loo x loo
130 130 130
OS
OS a, w 91. w
x . x 150 150
x -
x .
75
. 150 130 170 200 75 75 200
. 210 150 170 170 75 75 210 210 180 210 210 180 .
Go
x 185 x x 180 x 150 75 150 185 x * * 150 f, 180 150 x x 75
x
80 200 :o x 150 x 1& x 150 x * x loo
x 70 170 110 75 75 70 70 150 loo . x :5 .
70 70 170
75 75
a. e. w a. e. w a. a, 0. w
x 185 x x 150 x
200 70
140 x
.
-
75 75 x 75 . 75 loo
75 x 150 150 . I: 75 70
x . 170
Butarol Butanone Butoxyethanol Butter Butter 01 Tm Butter Of ZlllC Butyl Acetate Bulyl Acetate Rtcmoleate Butyl Acrylate Bulyl Alcohol Butylamww Bu1yl Benzoate Butyl Carbltol Butyl Cellosolve Butyl Ether Bulyl Hydride Butyl 01eate Butyl Octadecanoate Butyl stearateBulyraldehyde
.
150 loo . x x 70 .
150 loo . x 1w 70 .
Ph. w ma
OS a. cb. I, w a. a. gt. w a. e. hc. w w a, a. w a. e. w a. e dg. me ph. mo. w OS a. a. a. a. e. e. 8. 8. mo, 0 r-no. 0 mo. 0 w
AW
x 150 150 x x x 150 x x x x x x x
. -
150 150
75 . ;5 . .
150 185 x x x 150
. x x . -
x
.
x x x
. . .
150
75
. x
x
x _ x m x x
*
x l5g 150 150 x x
. . .
loo
70
. -
. . . . .
. _
. . .
l4q 75
.
loo
.
loo
. .
180
. .
75
x x -
. _
. -
75 .
75 .
75 .
75 .
75 _
_ .
x x 150 x
.
X I: _
75 x 180 x
x x 150 x 200 80
.
75 75 . 1w 210
.
x . x 150
.
200
.
70 70 . x 75
_
I _ .
.
210 _ .
.
x . _. x 200
.
x . 75 75
Butyrlc AC&d
Euytric Alcohol Cajaputene Cake Alum Calamme Calclne CalcIte Caklum Calcium Calcium Liquor Acetate Bisulfite Carbonate
a. a. w a. 8. w a w a. Cl. ct. w h a. w a. w h a. w a. w gt. h. w gt. h. w w a, ac. w ;. ho h. w
.
150 x MO 80
_
140 x 150 -
. letI 150
150 185 185 80 140 __~_~.._._-..SO 120 150 150 150 150 80 150 150 150 80 150 180 120 185 185 185 185 150 It35 185 185
lW2w 210
x 120 200 200 200 200 I 200 x 150
120 200 200 MO 200 203 80 200 80 290
150 150 150 150 150 150 150 150 150
130 75 200 2w loo 200 200 loo 75 200 75
70 x 140 140 loo rw 70 loo 70 loo
130 180 150 130 200 200 70 130 70 loo
70 I 140 x x x 70 70 70 70
70 I I x I 1 x I
150 75 210 210 x 2:o 100 210 75
x x x 75 75 75 :5
75 75 75 75 75 75
Calcwm Chlorate C&urn Chloride Calcium Hydrate Calcwm Hydroxtde Calcium Hypochlonle Calctum Caktum Calcium Calcwm Calcwm Nrtrate Oxychlonde Sulfale Sulfide Slllco-alummate
.
la5 185 185 150 185 150 185
75
-_
75
Comparative
Resistances
of Materials
of Construction
825
TABLE 7.4:
RUBBER,

FOR LlhihG MATERIALS COCeSolvenrs trat,0n AY 100 100 100 loo loo AY Any AY AY AV z 2 ;g Lzz 9 2 E ; ;; 0% b B% 0 5 h : -N p: u 150 x x 25,
AND WOOD LINING
CHEMICAL
RESISTANCE
22 022 z i9 $
180 150 185 150 150 l x
52
150 200 x x
lia:s
loo
+ 1% (I) 4 130 170
a*
z +
E 2 E P 2 E
r;G, 5
170 170 75 200
0 _m
210 170
0 5
75
g
75
Callche Liquor Cane sugar Liquor Caprolc Caproxl Caproyl Aldehyde Alcoh& Alcohol
a. gl. w
150 150 x x x x x 150
185
8. a a. e a. Cl. e a. Cl. e
Capryl Alcohol Caprylic Alcohol Carbamlde Carbllol Carbazotlc Carbohc Carbon Carbon Carbon Actd Acid Blsulhde D!sulftde Dmxlde
a.b.
x x x
200 200 a0 x
ll0
70 150 x 110 75 75 170 700 75 70 x 110 100 100 x 100 100 loo
x x x
120 100. loo x 140 1M) x 140

150 150 150
180 150 70 200 70 70 170 700 70 150 150 150 170 150 200 150 200 loo 100
140 180 15o x 175 180 180 170 350 70 70 150 150 200 x x I x loo loo 200 180 210 250 180 180 170 700 210 210 210 75 170
140 150 x 70 180 180 170 75 lal x x 170 x x x l!O 150 150 1. x x 75 75 75 75 75 x x 75 75 75 75 loo 75
8. w
150 150 100
150 x
a. b. cl, e. w a. ct. e.
x x x x 150 x x 150 150 160 a0 150 150 150 150 x x x x x x 165 x x la5
x
x x x 150 x 150 150
loo 70 75 x a0 a0 200 200
x x x 200 x x 200
x x 1. MO x x 2uo
gl.ho.0.w
a. b., e. w a. b. e. w x x 185 a0 x 185
75 75 75 75 75 75 75 x 75 75 150 75 75
Carbon Monoxide Carbon Tetrachkmde Carbontc Acid Carboxybenzene CaseI Castor 011 CallstIc earyta* Causr~c Lime Caustic Potash Caustic Soda Cellosolve Cellosolve Acetate Cellosolve Butyl Celulose Acetate Cellulubes Cetyllc Acid Ceylon G&II Chalk Chile N~ter Ch,le Nitrate Chile Saltpeter Chmabean 011 Chlnawood 011 Chtnese Gelatm Chloe Aqueo Chloride Chlorine Wet Llauld Waler Dtoxlde Gas, Dry
a. b. cl. e. n. 0
100 AY AY 100
a0
75 75 75
150
150
a. b. cb. cl. e
a.8.w
AY
Any AY AY AY Any AY See Solvents see Solvents AY see Solvets AY AY AY loo loo AY AY AV
gl. h. w a. e. $. w a. gl. w JO. ph. w hc. w mo. ph. w ac, ea. ed. xy a. e aa. gl. w h a. gi. w a. gl, w a. gl. w a. cb. cl. e cb. cl. e. o aa. gl. w ho, w ho, w
185 la5 la5 la5
150 185 185 185 ra5 150 150 150 100
120 200 200 200 200 x x x x la0 200 200 200
150 200 2~) 150 150 x x 150 x 180 1% 15o 150
150 150 150 150
180
x x x la0 rao
100 140 200
75
75
150 150 150 150 x
la5 iao 160 la0
185 150 150 150
150 150 150 150
200 100 loo loo
x 180 iao la0 110 110
70 200 200 200 170 150 70
175 75 75 75 170 170 175 70 1 x x 210 210 210 75 75 75 75 75 75
x x
a0 120 12u 180
150 x
ia5
ia5
x
x x x 150 x70 70 x x x x x Regla x I x x x x Acid x x x I x x 185 x 150 150 150 x x x
x 1.
120 la0
150
200 200 200 200 100 la0 75 75
x x
x
x x x x
x
I( x x x I
x
150 150 x 150 150
x
70
75
3 a. w Q. e. es. 0. 0s b. ct. 0 a. e. w a. Cl. e. w pe 35
x x x x
70 x 75 x 75 150 x 75 I
70
75 75 210 75 210 180 x 75 75 ___ 75 I( x 75 75 75 70
Chlorine Tr,tluor,de Chiorlnaled L,me Chlorlnaled Salt Brine Chlorlnaled Solvenls Chlorlnaled Tar Camphor Chloroacetlc Acad Chloroacefone Chloroallylene Chloroazolfc Acid Chlorobenzene CCllorobromomelhane Cllorobuladlene Cloroelhae Chloroethyl Alcohol C%rolorm
x
150 x
x
x x
x
x 150 x
x
I x x
x
x I x
x
x x x 75 200 75 x x x x x x x x x a0
100 10 AY loo See Aqua loo loo AY 100 AY Any See Hydrochloric AY 100 AY AY 100 100 100 100 100 100 100 5
150 70 125 150 150 125 200 150 130 100 70 125 125 120 200 150 a0 100 70
15o
200
a.Cl. 8.
0s
I
I x x x x x x x
x
x 150 150 75 200 150 x x x 75
I(
x 150 x 70 150 150 130 x x 70
1%
x 1M 70 150 150 130
75
x x x x a0 x a0
x x x x x x x x
210 210 210 210 210 210
05 a. w 0s. w 05 w a b. e. o. n. w a. b. cl. ct. OS. w a. e aw a. a. a. 0s b Cl. e. w Cl. e. pe e. Cl. De ct.0
x 140 x 75 75
Cnlorohydnc Acid Cwxomethane ClOrOpetee Chloroprene CnlorDpropaoe Chloropropene ChloroProPvlene

Chloro~ro&4ene
210
x 150 x x 75 150 210 210 iao x x 75 75
x
x x x x x I x x )I. x x x x x x
x x
x x x x x x
x x
x x x x x x x
I
x x x x x
x x
75 75 75 75 x x 75
x.
x x 130 150 75 x x
x
x x 75 x 70 x x
Oxide
x
x x.. x
75 75 200
ChlCronaphthalene Chloro N~tro Elhane Chlorosulfonlc Acld Chlorololuene Chlorolr~~luoroethylene ChlCVOX
75 210 210 210 x i
a. e. ae. b. cl a. b. ke
x.
120 150
x
100
x
150
-.
100
-.
75
(continued)
826
Corrosion
Resistant
Materials
Handbook
TABLE 7.4:
RUBBER,

FOR LINING MATERIALS 5 3 ZB $2 150 150 x x x x x a. w w a a. e. w a ac.w a ac,w a. cb. cl. e a. cb. cl e. ea. AY a 2 $2 ?Z 185 185 $E ;a le.5 185 100 75 200 200 200 200 150 150 150 120 80 75 75 150 x x x
AND WOOD LINING
CHEMICAL
RESISTANCE
Solvents Chrome Alum Chrome Ammomum Chromic Aced w aw e. w
COCe,MY) AY Any 10 25 50 80 See Chromic Acld
Alum
x x x
x x x
x x x x 70 75
75 75 70 70 70 x 70. 75 75
x x 70 x x x
70 70 130 130 130 130
140 140 210 210 210 210 x
x x x x
x x x x x
Chromic Anhydrlde Chromvxat Chromium Ammomum Sulfate Chromium Potassium Sulfate Cnromum Trtoxlde Clee Ctrco Ltghl Process 011 CIVIC Acad Cleaners Naphtha Cobalt Chloride
x
185 185 --x x 185 x 185 185 150 150 185 185 185 150 185 175 185 185 185 185 185 100 185 150 100 x 150 150 200 200 200 200 x 120 x 150 120 185 185 200 200 x 150 150 x 2c3 200 80 200 200 x 180 80 200 200 120 120 150 150 200 200 200 200 x 120 150 150 200 150 150 150 150 150 150 150 150 140 170 75 200 200 120 200 150 150 x. 150 150 80 75 75
x
x x
150 150 x * x 150 150 x x 150 150 150 150 150 150 x 120 150 x x x x x x 150 x
x x -.
70 70
140 140
See Chromic Acld 100 AY 100 Any Any 100 100 100 AY AY See Solvents AY See Solvents AY Any 100 Any AY 100 100 Any AY AY See Solvenrs 01
200
180
100
210
185 185 x x
Gxoanut 011 codLwc!r 011
Cobaltons Chloride
cologne Spmts
Copper Acetate Ferrous Sulfate CoDper Arsenate
w
a. Cl. e a. e. w w h. ho w h. ho aw gl. w b cb, cl. e 180 x x x x 170 170 70 170 75 75 75 75 180 70 x 180 180 170 170 70 170 150 100 100 100 100 75 x x x 170 170 170 ,70 100 100 100 x 210 150 210 200 170 170 210 170 210 210 210 210 x x 75 75
Cqweras
Copper Chlortde Copper Cyanide Copper Nllrate Capper Sulfate Corn 011
cornSyrup
Corrosw
a. gl.w
a. a. a. a. a. b, e. e. 8. e.
Subltmate
a. e, 9. PY. w cb. cl. 0 gl. ho. gl. ho. gl. ho, e w w w
185 x
75 75 75
130 170 170. 170 x x x x
75
Cottonseed 011 Creosote CZSOl Cresyl Alcohol Cresyk Acfd Crude 011 Cryollle Cryscoat F H Rmse Cryscoat HC Cryscoat LT 8 SW 87, 89. 6 89M Crystal Ammoma Cumene Cupnc Chloride Cyanide
x x x
x x x
x x x
x x x
150 150
x x x x
75 75 75 75
al. fe
70 185
x 180
x x
150 180 x
180 1.90
185 185
x x
70
x x
70 70 70 70 70 x 180 180 70 70 150 x x x 70 70
70 x
Cryscoal 47.
x w a. b, ct. e w h. ho a. w gt, w 05 0. OS, w OS a. cl. e 0s. w a. e 8. e I a. 8 a. e Any 100 AY See Solvents Any AY 100 100 100 100 AY 100 100 100 100 100 100 a. w a. w Any AY AY Any Any AY Any 100 AY 100 100 AY 100 100 100 x. 150 150 150 x x x x. x x x. x. x x
x.
x 200
200 200 200 200
x..
70 150 150 150 150
70 75 100 120 100 75 75
70 140 x x x 70 x
x x
70 70
x x x
75 x 70 75 75
-.
x
70 200 150 210 200 75
Cuprc
150 185 150
185 185 185
200 200 200
Cupc Nitrate Cupric Sulfate Cvclohexane C&lohexaol Cyclohexenone Cylene DBP DDT 6 Kerosene Dscahydronaphlhalene DealI LIecane DeaOl Decyl Alcohol Deionized Waler Denatured Alcohol Developing Solubo Daacetfc Acid Dwebc Ester
x x 75
x x x x
150
x x
80 80 x x x x x
150 . . x
x
130 70
.
75 75 .
70
75
.
75 75 . -. . 140 140
.
150 x .
.
150 70
.
150 70 . -.
.
130 70
.
180 75
.
.
75
x
x
x 150 x x x x
x
x 150 x x 150 100

100
x x x
x
140 140 -
-.
150 150 150 80 80 x x . 80 x x x x x x x x
150 .
x
75 75
180
150 150 185 80 80 100 100 100 100 75
150 150 200 x x x x x 80 x :o
200 180 200 x x x x 80 x
150 150 150 x x -
70 170 170
70
Dlacetone
Damme
a.es.hc.
a.w a. e. w. as v OS P. 8. hc OS. w a. b. e OS. w
75 75
210 75 75
Dtacetone Alcohol kmmoelhane Dtbenzyl Ether Chbromoethane Wulyl Ether Dlbutylamlne Dlbul;l Phthalete Duhlorobenzine Dichloroditluoromethane Dichloroelhane
w a. es, hc. w
75 -
x 75 75 70 75 150 70 75 75 170 75 75 70 170 x x 170 70 . 75 210 170 75 . 75 180 75 210 :5 75
x
x
x
140
75
. -
x x x
75
x x x
x x
x x x
x x
x x
x
x
75
.
150 70 75 100 150 130 70150200 70 100 70 loo
.
x
.
75 75 75
75
180
loo
(continued)
Comparative
Resistances
of Materials
of Construction
827
TABLE 7.4:
RUBBER,
RESIN, STEEL, ALUMINUM, MATERIALS-GATES
LEAD, GLASS, CONCRETE RUBBER (continued)
AND WOOD LINING
CHEMICAL
RESISTANCE
FOR LINING
MATEAIALS COlICentratlon 100 loo loo * x x * x * lotl * x x 150

x
Solvents Oachlorolsopropyl Ether Olchloromethane Olchlorotetrafluoroethane Olcyclohexytamme Diesel 011 Olester Syn Lube 011 Olethylamme Orethylbenzene Olethylene Otoxlde Olethylene Ether Olethylene Glycol Olethylene Glycol Olethylene Glycol Orethylene Glycol Ether Acetate Olethylene Glycol Otethylene Owde Olethyl Ether Orethyl Oxalafe Olethyl Oxlde Oratky Ether Monoalkyl Ether Monoalkyf dg. me Monobutyl Ether dg. me 0% w a. b, cl. n. 0. w a. 8. ea. OS. w a. b. cl, n. 0. w a. ac. w a. 8. w a. ac. 8. eg. w b. ct. e 0. OS a. e
* * . 185 x x * x * 140 * x x 180

150
* x x * x * 120 * x x 180
x
* x x * 150 * x * x x 180 150 150 150
. x x . . * x . x x 150
. . . 75 . -
. loo x . . x . loo loo 130 x x
. 70 75 . . loo loo loo 170 70 70
. loo 70 . . 70 . 70 70 loo x x
. 70 loo . . . x 70180 70180
. 75 75 . . . 180 .,
05. w
0. OS a. w a. b. ct. e 0s. w 0s. w a. ac. 8. eg. w
W
1W 100 AY 100 Any AY Any
. . . 75 . x x x x I
. . 75 x x
x
loo loo Any Any Any Any AY AY Any 100 AY 1M) 100 100 x x x x x x * 100 150 150 x 80. x x x
x x
150 180 180 x
. x x x * 150 150 150
75 75
70180 x 210 x 210
.
. x x . 75 75 loo 70 70 . x x 130 loo 70 70 . 180 150 170 . 70 70 70 70 . x 70 loo .
. x 75 75 . x 75 x 70180 70 150 75 70 150 . .
x x x
* x 1w 180 x
150 x 120
x x x
*
x
*
x 75 75 70 70
120 x 150 180
Olethyl Sebacate Olgalltc Acod O~hydroxysucc~n~c Aad Olhydroxydrethyl Ether Owsopropylbenzene 01.tsopropyl Ether 01.tsopropyl Ketone Ormethyl AmIme Olmethyl Benzene Olmethyl Carblnot Olmethyl Ownethyl Olmeth$ Ormethvl
olnltro
a.ac.
0s. w
150 185 185
a.e a.e.w
OS. w 0s. w a. Cl. 8. 0, w a. e
x x loo
loo x 120
185 185 180
x x x
x 80. x x
-.
x x 70
-.
210 175 180
x 150 75 150 70 . . 75 70 . 180 75
75 . 210 75 210 75 75 70 . 70 -. 70 . 70 180 . 180 -. I . I x . x 75 75 1w 75 210 x
AY
Any AV A;
183
x * x x x x x * x x. Solvents Solvents Solvents Sulfuric Acrd x
. x
x x 120
x x 120 150 x x
x 150 120 x x
ioluene~
Elher Formamade Ketone Methane
x
x 1w 150
x x
x x x * x x x x
a. e
lo OS. w w OS. w a a. e a. e a. e OS, w a. e a. e mo
see Solvents
loo loo AY Any Any loo see See see See
x
x x x * x x
x
x x x . x x
x 1w
400 75 75 loo . loo
180 75 70 loo . loo -
01ocfyl Phthalate Ovxtyl Sebacate OlOXXle OlO*Olane Oloxethylene Ether 01pentene Olphenyt Olphenyl Ether Olphenyl OxideDlpprng Acid DMF ONT Dodecanolc Acid DOP Douglas Fir 011 Dowfume W40 Dow Purtfloc C-31 Oowtherm A Dowtherm E Oryad(1) Dry Cleanmg Flutds Dutch Llquld Dutch 011 Electrolyte Acld EMK Engravers Ac!d EP~ Eplchlorohydnn EFsom Salts Essence of Myrbane E!hane Elhanethlol Ethanolc Acrd Ethanal Ethanol Ethanolamme Ether Ethme Ethyl Acetate (1) Lrght.colored compounds
loo loo 80 * x x
140
120
AY see Solvents see Solvents 100 100 100
loo
II I x 1% x x 70 x. x x x x x 150 x x x I 150 80 3 x .
100
x x
150 a5
x 150
75
75
70 150
-.
170
75
x
150 75
a. ct. e
100 100
100
Any 100 100 See Sulfwc a. e. cl w 0s OS a. gl. w a. b. e. w a. 8. n. w a. a~. b. 8. 9. a, a. a. a. a. recommended. Cl, e Cl. ct. w b. cl. n. 0. w ac, w Cl, 8. II Acld Any See N~trrc Acld loo loo AY Any 100 Any See Acetic Aad Any IW Any AY AY AY
x x x
75 75 x
x x
-.
75 70 180 180 x 75 75 75 75 170 75 x 1w loo 150 130 130 100 170
x Lb x x
x x x
I
x x x
. 70
x
loo IW 150 75 75 140 70 75 70 70 x x 170 75 75
70
-.
100 loo 150 200 200 150 150
-.
70 70 150 75 75 loo 150 150 210 loo 75 70 75 130
-.
210 210 210 75 75 210 210 2w x
x x x
x x
185
x x
200
x x
200
x x
150
185
80 x x x I x
x x
150
x . x
70
. x x
170 210 2; x 125
.
150 210 180 1M 70 180 loo
.
x 75600x
150 80 80
80X
185 140 :0 loo 150 80 :o x
x
150 80 120 80 x
x
150 x 80 x
150 70 400 75
70 75 70
210 (50 75 210
200 75 75 x
75 75 75 75
but they may Cause some cloudiness
in the bleach.
(continued)
828
TABLE 7.4:
RUBBER,

FOR LINING MATERIALS Concentratnnl Any Any 100 loo Any AY 100 100 100 See Solvents 100 100 100 100 100 Any 7 5 zj %d a 2 ;j :a x cl0 x 150 x I loo I x I x x I x i
AND WOOD LINING
CHEMICAL
RESISTANCE
Solvents Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Acebc Acid Aceloacetale Acrylate Alcohol Aldehyde Benzene Benreroate Buranoare Bufyrafe CeiliJose a. 8. w a. *I a. Cl. e a. ac. b. e. g, n, I, tu. xy. w a. a. a. a. 9s b. ct. e. w e e e
I
x 1w
x x x
x 75 120 125
200 170 70 210 150 160 160 2oc
70 75
150
180 loo
210 150 tw 100 150 75 150 150 150 150
210 75 75 600 210 210 210 210
x 75
x 75 75 75
x *
I I I
x x
x x 123
x
I I *
140
140 140 I
75 160 160 2oc
E,, Chlor,de Ethy Chlorocar~orale E!hi Chlorolormc:e E!h,iene Ethi:ene Alcohol ElhVlene Ethv~ene Eth,Iene Emyiene E~hVIene BromNdt Chloride Chloroh,or,n Dlamme Dlbromldt
0s w a b cl e a b cl e a ~~ e Cl w 05 w cew w a e w mo ph w hc v
A I x I 100 x
165 ;5 150 x x
x x 180
160 II x
75
75
175
150 1 x
75 75
100 70 150 150 75 70 150 100 100
70 75 70 150 75 75 150 70 100
720 II 150 150 70 I 120 120 150 70 150 70 150 160
210 75 210 210 75 210 210 75 75 75
100
x
i0 x x 150 x * 165 150
Anv V Av_ 100 00 I Any
80 x 100 80 it6 x x x
x 165 x 150 x 150 150 x I 160 150
ko
75 2:o 100
I
x 150 75
210
75 L 75 75
ElhVlene D~chlorlJt Ethylene Glycol Ethylene Glycoi Mowbutyl Emflene Glycol Mowbutyl Ettw Acetate
E!er
II
Ferric Subsulfate Ferrx Sulfate Ferw Trtchlorlde Feruc Tr~sulfate Ferrous Chlortde Ferwus Nitrate Ferrous Sulfate Fenil~zer Solul~ons Aqua Ammonia 6 N~lroqen
Solution
w w a gt w w a u w
A; Any Any Av AV An; Any 25
150 150 150 150 150 150 150 150 150 150
165 165 165 165 165 165 165 150 150 150 loo 165
165 165 165 165 165 165 165 165 150 150 160 165
200 200 150 200 200 150 60200150200 200 200 150 60200150200 200200150200 200 200 150 200 160 160 120 200 200 60 100 120 200 150 160 150 150 150 150 150
75 200 75
x x x x x x 75
70 70 x 70 70 70 200
x x x x x 75 100
75 75 x 75 x
210 210 210 210 210 210
x x x x x x
75 x 75
200 200 200 200 200 100
(no-pm?ss,
100
Ammonum Phosphate (Neutral) Balanced MM (Complete Analysts) Nttrogen (Low Pressure) Falter Alum Frwood 011 Fish 011 Flaxseed 011 Flares Mart~s Flortnated Cyckc Ether Flowers 01 Sullur Fluoborlc Acid Fluorme* -Fluorobenzene Fluorochlroethylene Fluorolube Fluosttc~c Acad Formaldehyde Formtc Actd Formtc Aldehyde FWlTlOnltle Frauds Reagent 41 AV 100 100 Any 100 See Solvents 65 100 100 100 10 50 40 Any 40 Any 10
200
200 75 x 150 75 x 200 160 x 70 x 100 x x 70 x 100 100 )I 2:o x 210 I 75 200 x x 75 75
w a. b cb. cl. e a. cb cl. e. I. pe a g1.w a. b cb. cl e aw a. e a. b ke w
60 150 x x 150 x. 150 x x x. x 100 60 60 io 60 150
x
150 165 150
x
160
130
75
60200150200
x..
150
-.
150
165 165 x x x
x x x x
60
150
x x
150 60 60 150 60 x x
x x x x
x x.. x x
450
300
350
350
200
300
-. -.
75 75 100 100 100 120 200 x x x x x x x x x 100 150 100 150 x x x -150 70 150 70 x
-.
70 70 70 x 70 x x x 210 210 210 210 210 x x x x 75
165 165 150 150 150 150 150
150 60 60 60 x x
150 150 150 60 150 150 150
a.e.w
a,e w a. e. w a.e w w
75 75 x
(continued)
Comparative
Resistances
of Materials
of Construction
829
TABLE 7.4:
RUBBER, RESIN, STEEL, ALUMINUM, MATERIALS-GATES
AND WOOD LINING
CHEMICAL
RESISTANCE
FOR
LINING MATERIALS Concsrltrabel
SOlWlW
Freon' 116" Freon' 502" Freon' 503 Freon' MF Freon' TA Freon' TF Freon' TMC Freon' T-P 35
Fmnn
100 100
100
150 100 150

I
185 185 185

x
185 185
200 200
200 150.
. . 150 75 x x
100 140 100
100 100
185200200. ;5 x 150. 150100 x

x
x x
x
x
x
100
100
__
T-Wrl
_ krv _ __
aw ae abe
100
100 100
Fuel 011 (Acldlc) Fumartc Acid' Furan FUrfUr& FIJIWall Fusel 011 Gallic Acid' Galloramc Acid' Gasolme Gaultherla 011 Gelatm' Glauber'sSalt' Glucose Glue Glycerme Glycerol Glyceryl Tr~acetale Glyceryl Tnoleate GlvcervlTripalmMe
x x x I30 x x
x x
x 75 x
120 75 120 120 150
150 75. 150 150 150
150
170
Any 100 100
ae
sew a, e. 91.w a, ac. w
100
A~y_________~~ AW Any 100
x
150 100 x 150
185
x
x
x x
100
x
150 185 ;lo 185
x
x x x
x
180 __~ x x 100
-.
._~~ 150 150 150 100
-
210
75
150 ~~~~~_._.__.__._ 180 180
~~~~ 70 70
x 140
75 130 x 170 75 175 150 170 170 xx) 290 70
~
x 170
-. 140 ._
75 210 170 75 210 170 170 210 210
~~
x
aa.e.w
aa. 91.w gl.w a. 01.w 91,-h. w a. w a. w a. e. OS. w a, Cl.ct.e Cl.e 0s. w a. w w a. e. Cl a. e. w a. w
AV
Any Any AW A& AW Any Any Any see Solvents loo Any Any Any 100 Any Any 100 Any See Solvents Any See Solvents Any Any See Solvents Any 100 100
150 150 120 120 150 150 x x.-
180 200 120 150 150 150
180 200 120 150 180 180
150 150 150 150 x x
75 100 75 200 100
x 170 75 x 140 170 170 110 110
180 70 70 180 170 100 150 150
70 75
x x x
150 15U 150 x
150 185
150 150
75 75
140 170 170 70 70
75 75
808080x. loo 80120 150 120 8Oxxx 150 185 185 150 180 75 185 150 185 185 185 185 x x 150 200 150 100 x x 200 150 200 200 200 150 x x 150 180 200 150 150 120 100 200 150 200 160 200 200 100 x 80
.
150 x 150 150 150 150 150 150 150
.
200 140 75
.
75 150 110
.
70 150 150 70 180 70 130 70. 70
75 __ .
150 70 210 210 210 210 140 150 210 . 210 100 120 200 75
. x -
. . 75 -
GI&JIGlycolChlorohydrm GlycolAlcohol Graham's Salt' Grain Alcohol Grain 011 Gray Acetate' Grease 011 Green Copperas' Greenland Spar' Green SulfateLiquor Green Vitriol' Gypsum' Halite' Hartshorn' Heavy Spar' Hepar Calls' Heptyl Carbinol Hexachlorodlphenylmefhane Hexadecanolc Acod' Hexahydrobenrene Hexahydropyr!dme Hexamethylene Hexaldehyde Hexanaphlhene
nexane
120
x 150 150 150 x 80 x 150 120 150 150
75 150 200 x 100 75 70 75
.~
170 130 75 70 70 x 110. 75 75 75 75 170 75 75 x 75 140 100 75. 70
a, b. cb. cl,e w al.18 w ho, am. h a. 91.w ZO",. H2S04 h. w a, Cl,e
. .
70
75 x . x 75 75 75 75 75 75 75
150 150 185 185 185 x
. 70 70 70 100 75 x 150 70 75 70
150 x x x
150 x x 80
. .
70
a. 8. w
OS OS w
a. ac. e
OS
a.e
See Solvents
Any
100
70
170 75 75
x.
x x ;O x x ;o 150 x 80. 100 150 150
x x. 80 . x . 185 150 x x
x
x
80
fo
100 100 Any 100 100 Any 100 Any 100 Any Any 100 15
100
Hexanedtolc Acid Hexahol H.%erW Hl?XOfW Hexyl Alcohol Hydrated Lime Hydrauk 011 Hydrazme Hydrazmobenzene Hydrobromlc Acld Hydrochlortc Acvd
80 x 80 120 x 120 150. 1;O 200 150 x I 120 x
lo 80 120 loo
75 75
70 70 75
70 70
70 70 75
70 70
a. 8 OS. w ;i.eh, w a. w
x
x 75 80 185
120 x 100 200
.
70 loo 75 _ 150 200 200
. 150
. -
75 75 75 140
x x
. 150 200 150 x 75 . x x x 150 x x . x x x
l&l 150
1M)
210 140 x 75 . 210 210 210
75
75 x . 75 75
x
loo
x
x x x x
x
x
-
x . x x x
75 . x x x . x x x
38
185 185
150 x x
150 150 80
(continued)
830
Corrosion
Resistant
Materials
Handbook
TABLE 7.4:
RUBBER,

FOR LINING MATERIALS CoCentrsfK)n 20 98 10 20 48 75 10 50 Any AW Any See Hydrochlow AY 10 20 10 See Sulfuric Any AV A; Acid x ;o 80 150 150 80 75 x x x x 100 80 x 100 x Acid 80 80 x 80 150 150 180 180 150 75 x 185 185 x x x x x x I 150 80
AND WOOD LINING
CHEMICAL
RESISTANCE
SOlVentS Hydrocyanu Hydrofluorlc Acbd Acld a. e. w w
120 120 x x x 185 185
x x 150 80
I x 150 150
x 75 75 75 150 75 120 140 200 140 75 120 120
x x x 600 x 150 x 75 x x x 70 70 70
x x x 600 x
x x x 600 x
x 70 70 75 x x
x x x 75 210 21-x 210 210 x 210 75 125 125x
I 75
(Anhydrous) Hydrotluoroslllclc Acid (Hvdrofluosllxx AcIdI Hydrogen. Hvdrooen Bromide

I _
-.
75 x 75 75
a. e. w w Acid s. e. w w a. e. w a. w w a. w a. w a. e. w a. e. w h. ho a. e. w d. e. w a. Cl. e. gl. ho. 0. w. Cb a. Cf. ct w a. e. w 0s. w I. w al. 18 a. cb, cl. e. gl a. e. w a. gl. w a. w a. w a.
w
150 x 150 150 x
x 150 x x x x
x 150
150 80 150 100 100 100 140 120 120
Hydrogep Hydrogen Hydrogen Hydrogen Hydrogen Hydrogen Hvdroqe Hydrogen
Carboxyk Cyamde Dloxlde Fluorlde PeroxIde Sulfate Sulfide
Chloride'
.
x x
io 80 80 x
70 100 x 100 100 70 70
75 100 x 100 70 70 70
70 x 75 x 70 70 70
75
Hvdrooulnol. Hydroqumone Hydroskfluorlc Ac!d Hydrous Alummum Oxide Hyaroxyaceflc AcidHydroxlpropane Trlcarboxyk Hyaroxybenzene Hydroxyethylamme Hydroxysucctmc Acad. Hypnone Hype Hypochlorous Acid Iceslone* lod~ne Penfafluorlde lodoform IPA Iron Chlortde ~___ fro Olchlor,de
Iron Nitrate
x x
x 150 x 100 185 100 140 x 80 185 x x x 120 185 185 185 185 185 185 185 185 185 185 185 185 100 100 li5
x x
* 150 x 80 x x 200 I
x x
x 110 x 60 x 2iO x
75 x
75 75 75
Ac,d
See FIUOSIIICIC Acid see Solvents 10 x AY 150 AY x AY Any Any Any 5 See Solvents 100 AY AY AY AY An; AY AY AY AMY AY Any Any AY AY Any A;
100
x 150 x
120 x 210 140 150 150
x 110 150 x 200 x x
200 180 200 150 150 350 70 x
100 175 75 75 150 x
70 x 70
210 210 210 210 150 175 210 150
x x _ 200 I 75 75 75
80 80 x 150 320 x x 120 150 150 150 150 150 150
150 185 150 x x 185 185 185 185
120 ,:O 120
75 150 70 x
75
x x .x.. 120 120 120 80200150200 80 200 80 200 80 200 80 200 200 80 200 80 80 80 120 200 200 200 200 200 200 200 200 200 200 200 80 80 120 120 x 120 ;O 150 150 150 150 50 150 150 150 150 150 150 80 80 80 120 80
-.
75 x 75 100 200 75 75 75 200 75 75 200 75 x
x
x.
-. 70 x 70 70 x 70 70 70 x 70 70 x 70 70 x x x x * x x x x x x 75 75 x I x 75 I 75 210 210 210 210 210 210 210 210 210 210 210 x x x x x x x x x
x
75 *75 x
Iron Perchloride IrOn Persulfale iron ProtochlorIae ~____ IrOn Iron Iron iron Iron Sulfate Sesqulchlorlde Susqulsulfate Tersullate Trlchlorlde
gl.w
aw w
x I 1 x x * x x x
a. gi. w
w w
a.
w
gl.w
IrOn Vltrlol
lsobutanol lsobutyl Alcohol

ISo-OClSW
a. e. w a. e, w a. e. w OS, w a. e. w e. m. w a. e. w 0s. w P. e. w a. e. Cl as. gl. w
1% 185 50 185 150 185 185 150 185 150 --___ 150 Ez 80 io I.120 .io 80 i I. 150 x
I
75
XL10
75 75
x
x
75 75
210
lsopropaol Isopropyl Acetate Isopropyl Alcohol Isopropyl Chloride lsopropylcarbmol Isopropyl Ether fsopropyldleneacelone lsopropyltoluene Japanese Gelatm Jet Fuel Type A&Al Kerosene Type B Gasolme-Kerosene JP-1 Naphtha-Kerosene JP-3 Gasolme-Kerosine JP-4 Gasolme-Petroleum JP-566 Kerosene JPx Kerosene Ketohexamethylene Ketopropane Kurrols Salt Labarraques Solution
Any AY AY AY Any AY Any 100 Any
75 75. 75
70 70
70 70
75 75
210 210 210
BOX 120 120 1; -I 185 i0 I
x x
80
x
. -.
200 75 x 170 170 170 170 70 70 70 70 70 70
x
185
x
180 150
100
x
150 150
100
-.
175 170 170 170 170 170 170 170 170
75
-.
180
x
x
x
x
75 75 75
170 170 170 170
I x. x x I 0s Anv A; Any 20 I x L 150 I
x
x
x
x
120
100
150
loo
a.Cl, e.
x x x x
x 150 150 185
x 120 150 x 120 x 80 150 x x x

x 200
100
100
.
150 75 100 75 170 x 400 70 70 180 70 x 170 70 180 1: x 170 70 210 170 75 210 210 150 75 75 75
0, w
x 200
x 150 120
(continued)
Comparative
Resistances
of Materials
of Construction
831
TABLE 7.4:
RUBBER,
AND WOOD LINING
CHEMICAL
RESISTANCE
FOR LINING
MATERIALS Ctientratlon 50 1W Any 100 see Solvents 100 Any Any See Solvents Any Any Any AW A; Any 100 AY Any Al%, AlI; 100 Any see Solvents 100 100 100 120 I I x II 1% 80 1M 120 175 120 120 175 150 165 &l.._x__ I 150 80 120 150 I. 150 x x x 80 165 x x 165 150 x 150 x :5 x 165 x 165 120
180
SOlVentl Lactic Acld LXIOI Lacquer Solvents Lard Oil LaurtcAad Lavender 011 Layor caralga Lead Acelate Lead Arsenate Lead N~lrate' Lead Styphnale Lead Sulfate Lead Tr~n~troresorcmate'
LeUCoge
a. e, gi. w
80 x :o x 180 80 120 160 180 180 200 60 200 x 200
80 100 ,:o 100 160 80 120 120 120 120 160 130 200 120 2W
130
a, b. cb, cl, e a. e a, cb. cl. ct. pe aa. gl. w a. gl. h. w HNO, II a. w w h. w w w a. w ;th.w a. w a. w gl. h. w a a, ac, w h OS OS
150 120 120 120 120 120 150
200 200 75 75 75
x x x x
70 100 130 150 100
175 x x
x loo 150 70
200 210 180 x
75 75
185 165 165 185 x 165 180 150. 185
x x 75 x 75 75 :5.
Llchemc Acid' Llgroln Lime Lime Acetale Lime Bleach Lame Hydrate LlOnETne Lime Saltpeter LImestone LOll L~nole~c Acld Lfnolemc Acid Lmol~c Acid Lmseed 011 L!quld Oxyqen Llquld Petroleum Gas Llquld Rosm Lubrlcahng 011s Lube Oils Lye LYSOl Macassargum Maddrells Sal! Magnesia Alba Magnesium Magneswm Magneswm Magnesium Magneswm Magnesium Magnewm Bwlhte Carbonate Chloride Hydrate Hydroxide Nitrate Sulfate
150
100 130 loo 100
100 70 100 100
200 130 2W 130
x 70
x 70 x x
x 150 x 100
75
75 75 75 75
165
150
x 70
75 x
x
185 x
x
200
x
200
x..
150
x
150
x
x
x. x
80 60 130 x.. x 150 150 150 150 150 150
-.
200 200 200 200 x x 75 500 70 500 70 -. 400 170 170 150 . 70 70 loo 70 70 70 70 150 170 70 70 150 500 70 500 70 x 600 600 200 x x
75 75 600 170 170 x
OS
a, cb, cl. e. tu. pe
loo
100 100 100
x
I: x x x x x x x
x
150 x x
x
180 x x
x
180 x x 150 150 150 150 150 160 200 120
200 loo 200
-.
loo 170 170 75 x
x 170 170 x 175 x x x x x 70 110 170 70 70 75
-.
170 170 x 75 x x
-.
x x 185 185 150
x
120 120 200 150 180 200 120 200 200 200 200 200 x x x x 200
x
a. w aa. gl. w h w h a. w a. h, w a. h. w a. w w. a. gl Any Any Any see Solvents Any see Solvents Any AY Any Any Any loo 25 see SolvenIs 25 Any Any See Solvenls see Solvents Any A"Y A"Y Any A"Y loo A"Y Any 40
100
x
165 150 185 185 120
_
75
150 150 150 150 120 150 150 150 150 150
x
150
210 loo x x x 140 170 70 140 140 140 210 210 170 210 210 150 200
x 75 75 75 70
185 185 185 185 185
185 la5 185 185 165 loo
2W 2W 200 200 200 x 1: x 150 200
130 130 130 150 150 150 120 120 120 150
200 75 75 75 200 200 loo 140 75
70 70 70 70 110 170 x x x
x -I
MaIre 011 M&x Acld Malelc AnhydrIde Malemtc Aad Maltc Acld Manganese Marble Marl Sullate
a.b. w BC. e. cl.

a. b. w a. e. w w h h
b, cb. cl. e hc
x 80150x 80 150 150 150
75
80
150
x x 185
x x
75
MEA (monoethanolamme) MEK Mercwc Chlwde Mercunc Cyanide' Mercuroos Nltrale' MercwY Mercury Bachlonde' Mercury Vapor" Meaty1 Oxide Methanal Methane Methanol Melhanecarboxyhc Methyl Acetate Methyl Acrylale Methyl Alcohd Methylbenzene Methyl Bromide Methyl Butanol Methyl Butyl Ketone Methyl Chlortde Melhylene Chloride Actd
a. Cl. ct. w a. e. 0, w a. e. gl.PY. w a. w HN03.w a. 8. gl.PY, w a. e. w
80 x 150 150 150 150 150 x ia

x
60 x 185
140 IW 150 150 150 185 150
80 x x I: 80 200 I
80 x 150 150 60 200 150
x 150 150 150 150
210 x 200 75 70 75
150 150 x
150 150 x 70 140 x x
75 150 x x x x I(
150 I * x x
210 210 200 150 210 . 200
200 170 x x
75
, x -,
185 165
x 1.
_
x
x
a.e.w
a. e. w hc. I w a. e. w a. b. e a. e. w a. e. w a. b. cl. cl. OS. w a. e
x x
150
x
x
cl0 loo loo x
x
fo 150 150 x
.g .
150
.
loo loo -
.
75 x 150 75 75 150 170
.
70 rw
.
150
70 150 75 210 210 75 75 210 170
75
Any See Acetic Acad Any Any Any 100 loo Any Any Any 100
1w x x loo x x 150 x x x
. x x
185 75
120 -
150 150 170
90
75
x
x
.
75 90 170
150 170
.
75
_
. 75
la5 x 180 150
loo x x lea x x
150 x 75 180 x
12-J 150 150 I
loo 170
.
_ 115 x
.
70 _ x loo
.
70 _ loo 70
_
75 150 lf
.
-
. -
60x
x
x
x
x
x
.
70
. . 140 . 210 . 75 -
. . .
70
(continued)
832
TABLE 7.4:
RUBBER,

FOR LINING MATERIALS COnCell. tratlo
AND WOOD LINING
CHEMICAL
RESISTANCE
SOtVentS Merhylene Chlorobrom!de Methvlcvclo~ntane Meth;l tithe; Methylene Ovchlorlde Methyl Ethyl Ketone Methyl Methyl Methyl Methyl Methyl Formate Hexyl Carbmol lsobutenyl Ketone lsobutyl Ketone Isopropyl Ketone OS OS. w a. e
100
100 100
100
* x
x x x x x. x x x fo x. x 120 150 100 x x x x 150 150 150 x x x x x x 60 x x x x
x x .
. .
x x
x 100 x
* x
x x x x
x
150 x x 100
x . x x
.
. x
150
150
x .
70
210
.
. 170
75 .
.
.
100
_ 70 150
. 70 150 75 210 175 75 210 75 210
a.e.0.w
A?
100 100 Any Any Any Any 100 AllV 100 Any 100 AflV 50 Any 100
150
100 150
. .
-
a. e. w d. Cl. e a, 8. w a, e. w w. 05 w a. as
*o 120 * x
75
.
x x
.
150
.
75 150
.
70 150 70
.
150 70
.
150
x x I
x
x
;0
Methyl Merihacrylate Methyl Oleate Methvlohenol Methyl Polyslloxanes Methylpropanol
x x
x
x x x
60.
70
,_
a e.al. ho. w ~.~.=. ~.

8. e. w a. cl. e aa. e. w
x
x 100
x
f.
x
160 60
-.
-.
x -
75 -
x .
75
.
x
75
100 -
100
Methylpropytbenrene Methvl Sal&ate Milk i,c,d Mtlk 01 Magnesrd Milk. Whole
a.e.gl.w
am. h. w
165
x x 80
150 165 1M) 60 200 loo 120 60 x x
x x
60 200 100 150 150 x x
x.. x
130 130 loo 150 150 x x
75 loo 75 170
75 x 70 170
70 70 150 70 170 70 70 160
75 70 2& 170 70 75 75 150 x 70
I x 110 170
-.
75 200 140 170 170 170 75 75 210 x
.
x x x x
75 75 -
Mmeral Mmeral Mmeral Mmerat
011 Pttch Spmts Thinner d. b. e gt. I* w gl. w
x
x x x x x x 165 165 160 x
110
75 75 loo 170 75 75 140 x -
100
100 See Solvents Any Any Any Any 100 10 Anv 100 100 Any 100 100 25 100 Any 100 100 See Hydrochloric a. e a. e a. b. e hc. OS. w a. b. e lcil see Solvents 100 See Solvents Any 100
75 75
Mmerat Turpentme Mlrabllite Molasses Molyslte Monobromo Benzene Monobromotr~tluoromethane Monochloroacetlc Acid Monochloro Benzene
165 165
a.
200 200 150 200 200 150 602CO150200 * x x
140 x 100
x 75 70 70 75 75 150
210
200
100
75
s. e. w
150
x x x
x I x
60 *
x x x
60 x 100
Monoethanolamme Monomethylanlllne Monomethylether Monosodwm Acid Methanearsenate Monownyl Acetate Monsels Salt Marea Premhz Morrhua 011 Motor Spmts Murlatlc Ac!d Mustard Muthmans Llquld Myrtst~c Acid Naphtha Naphthatene Na;hthec Acld Naphthylbenzene Natural Gas Nave0 Neatstool 011 Nvzkel Acetate Nickel Nickel Nickel Nickel NuXine Chloride NItrate Salts Sulfate Bentonite
a. Cl. ct. w a. Cl, 8. w
60
140 75
x x x x
x -
x x
75
x
70 70 75 loo loo
210 -
150
210 75 75 210
200
75
80 x
165
w ae. a. cb. cl, e. pe
x 150 150 x x Acid x x. x x x x x 80 150 150 150 150 150 150 150 150 x x x I x I 150 60
200 165 150. 150 x
160.
x.
200 120 100 150 75
-.
x 70 x 75
-.
210 x
165 x
200
I 100 75 170 70
170
.
170 .
170 . -.
: . .
x x x x x x x x
x II
x 60 60
x.. x 100 150 x 170 75 130 170 170 70 200 170 170 75 130 170 170 170 170 170
75 210 170 170
x 100
a. cl. e. k a. w ho. w a. w a. w a. w a. e. I a. gl. w w
100 Any Any Any Any Any Any Any Any Any 10 25 40
80 I
,65 165 165 165 165 150 150 165 165 165 165 165 165 100 75 x 200 200 200 200 200 200 200 MO 60 x I
x 120 70 150 200 200 200 200 200 200 160 160 x x x
200 200 too 200
x 70 x x
70 70 70 70 70 70 130 150 200 175 140 70 70 :50 133 75 x x x I 70 160 x 70 x x 70 75 150 70 75 100 70 70 70 75 140 210 120 120 75 210 203 400 4cu 400 210 150 210 loo 75
x x .
150 150 150 150 150 150 150 150 150 115 100
iicotme Sulfate Nlter N~ter Cake N!tr!c Acid
150 100 125 125 60 130 x x I x
160 165
70 70 x x x I 70 x
75 x x 1. x x
x 75 x I x
Concentrated Fum.,rg Nmobenzene Nmocalclte N!tro Ethane Nltrogeo Nlrrogen Nitrogen Nitrogen Nltwgen Owxtae Fe~~luer Solution Petoxlae Tetraoxlde
x ii0
165 165
a. b. 8. w a. ac. 11 w ~IrN)~-w w
Any Any Any
I I I
200
x x x
200
x x x
150
x x
75 100
x x
170 100 75
80 I
II
80
I(
75
A? Any
150 185 1652fXI200 See N,trtc Acld 150 165 150 150 See Nwc Acfa See ww 4cla
150
150 _~.___~-.___-_ ~-~---
(continued)
833
TABLE 7.4:
RUBBER,

FOG Ll&iiNG MATERIALS COCenvatlo
AND WOOD LINING
CHEMICAL
RESISTANCE
SOlVetS NWohydrochlonc Actd Nltro Methane NrlromurMc Acid N~tropropane

Nltroxanthlc ACld
COflC
w w a b.cI a. ac. w a ho w a ac,w (I) AY AY AY A) AY Any 100 See Solvents AY
Lo x x 80 185 185 195 120 185 120 200 200 200 100 200 200 200 I( 150 150 150 120 150 70 70 75 100 loo 100
x 75
:5
x 75 f5 x 70 70 70
e w
50 :
150 150 150 195 150 185
75 x 100 100 loo
75 70 130 130 130
x x x x 210 1w 100 1w I x I I 75 75 75 -
Norge Nlter Norway Sattpetr~ Nonveglan Saltpeter NPN Oak&z Acid Mater&
Oaktte Alkahne Mater,als (1) Oaktle OC 31 Ill OC 32 (1) 33 (1)
oc
oc oc 34(1) oc 36 (I) oc 84H (1) OC 84M (1) cc 85 (1) oc 88(1)

131 (1)
150 70 70
I x
195 too 100
x x
200 85 85
150
100
x a5
85 a5
x I -
70 70 70 x
100 100 loo x
x x x I x x x x x
x
75
75 70
:o
70
70 x :o
:o 70 70 x 70 70 70 70 70 70 :o 70 70
I x
70
x x
70
x x x x x x
70 70 ;0
:o
85
70 70 70 70 70 70 70 70 70
70 70 70
70 x x x
100
0 Chromlcoat 47. 87. 69. 89M Cryscoat FH rmse
Cryscoals
Cryscoal HC
x
x 70 70 x x a. ac. e ph 0s a, e. 0s a. ac a cl. e 100 100 100 100 100 100 AY AY See Sutlur~c Acid 100 100 100 100 AY loo Any 10 100 40 loo loo see Solvents see Solvets see Solvents AY Ai Any A; AY 100 AY AY 1w 150 80 x x 150 x 150 150 x 185 185 x x x x x ?. x x x x x x x 150 :o 150 :o 185 : 150 x x x 100 100 x x
x x x x
:5 85
70 70
x
:0
x
70 70 x x
:o 70
Cryscoals LT 6 SW 0 Drycld (1) OFM 184 (I) 0 Stnpper SA Oaklte Solvent Matenals Ocladecane Octadecatrmolc Ac!d
x 120 80 150 x 90 150 x 200 x
x x
x x
$0 x x x x 70 x 70 x 70.
70 70 70 .
x f0 x
x ISO
x 120 x
70
70 70 loo 75
80
Ocladecenmc Acid Oclalluorocyclobulane N-Octane Oclyl Alcohol 011 01 Biller Almonds 011 of Mlrbane
x L x
x
x x
70
x -
x 100
210 75 140 210 210
75
120 x x
150 loo x 150 140 $5
011 Vltrlol 01
011. SAE Olelc Acid Olel Oleum Spmts Okve 011
a. a. w a. b. e. w
80x
x x loo
75
x
150 150
1:o
150 150 150 1w 70 200 loo 70
70 150 70
x 70
75
75
;olx,.
150 150 200
70 70 x 75 x x x
a, e. 0s a. cl. ct. e
x 75
210 400 300 75 210 210
x x x
75 70 75 75 75
a. cb. cl. e
w Acid a. ac. b. e. cu. w a. e. w
x
loo 185 k 185 loo 150 x
x
80 200 x x 200 100 80 x ,& 200 x x 150 loo 80 x
x
. 150 x x 130 loo 150
x
150 75 75 200 1w 75
Orthoborlc Actd Ortho-dlchlorobenzene Ortho.hydroxybenro1c Oxahc Acid Oxygen. Oxymethelene
loo ;o
130 loo
8.8.W
a. cb. cl. e a. e a. e Cl. e w a, 8. w ho. w ho, w w Cb. cl. e. pe w w a. e
70 x 150 75 70
x75 x x
loo 70
210 75
Ozone -*
PaInters Naphtha Palm 011 Palmax Actd Pahnm!c Ac!d Palmmn Paper Alum Paradihydroxybenzene Paraform Paraformaldehyde Patent Alum Peanut 011 Pear Alum Pearl Ash Pear 011 Penlachlorodlphenyl Pentachlorodlphenyt Ketone Pentachlorodfphenyl Oxvde Pentachloroethylbenzene Pentachlorophenylbenzoate Penramethylene Amme Pentasodwn Triphosphate Perchlorelhytene Perchlow Acid Perchloromethane a. e. w w a. e. 0. w w a. b. cl, e. n, o. w AY AY AY 10 Any
x
x x
80 80 x . x x
,@J
x
. .
75
,!=&.
x I x
200
x x x
2crJ
x x x
150 120
loo 120 75 75 100 . 100 150 75 75 75 75 75 75 . .
x 70 70 70 x x loo 75 75 75 75 75 75 . . 120 x 75
180 70 70 70 180 180 180 70
x 70 70 70 x x x 70 75 75 75 75 75 . . loo x 70
loo 70
. -
200 125 75 75 200 . 200 180 210 75 75 75 75 75 . . 75 210 210
x :5 75 x . x 75
75 75 75 75 75 . 75 75 75
185 x 185 185
185 x 185 180
200 x 200 200
200 150. 200 180
150 150 150
loo loo x
x
I
x
x
x x x x
x x x 150 x
x x x x
. . . x
x x x x
. . x 150 x
x x x x
x x x II x
x x I x
x x x I x
x x x x
. . I 150 150
. .
. . 120 5
. -
. .
. . . x 75
. . x 75
. .
. . 70
.
loo 200
loo
(1) Light-colored compounds recommended.
but they may cause some cloudiness in the bleach.
(continued)
834
Corrosion
Resistant
Materials
Handbook
TABLE
7.4:
RUBBER,

FOR LINING MATERIALS
AND WOOD LINING
CHEMICAL
RESISTANCE
Permanent Peroxvde
White
con I+$04 a. w gl. w gl. w
See Solvents 10
30
60x
x x
I
x
x
x
60
x
100
60
120
120
x
I
100
100
100
loo
x
x
Peroxydol Peroxyhydrate
Any Any
150 150
165 165
xx) 200
200 200
150 150
70 70
70 70
x x
x x
210 210 140 140
Phenol Phenol Polysdoxane Phenol Tr~n~lrale Phenvlamme Ph$enzent Phenylcarbmol Phenvl Chloride Phen;lethane Phenyl Ether Phenyl Ethyl Ether Phenylformlc Aad Phenyl Hy+z~ne Phenyllc Aftd Phenylmethane Phenyl Methyl Ketone Phenylsulfomc Aad Photone Phosphate Esters Phosphonc Aad
a. cl. gl. ho 0. w. Cb. e a. b. cl. e. w a. b. e
Anv 100 AV 100 Any
x x x x x x x x x 150 60. x x x x
loo
200 75 x
110 x 70
200 70 70
175 x 100
70 x 75
210 210 210
x x 75
x x 75
x
x
180
x
x
x
150
75
x
x 165 x
x x x
150 x x x x x
x x x.
x x x x x
x x
x 175 140 75 150 75
-.
100 150 150 100 150 150 100 150 150 210 210 210 x 75 75 75 75
a. Cl. 8. w 0s a. b. ct. e. w a. e
Any 100 Any see Solvents Any Any Any
x
x 100 x 70 x 120 165 165 120 120 165
-.
75 X.. x 150 lb -. 150 x 170 110 170 200 170 350 120 175 170 150 x -. x x 150 150
-.
x 70 170 150 70 210 210 170 175 210 x x
75 -
a. cb.. cl. 8. gl. ho. 0. w a. b. e OS. w a. w
Any 100 Any 10 100 Any 50
.
165
80 x
x x 160 150 x 200 120
x
x x 80 x
200
x -. x I x x x x x x
75 -
x x 150
2cxJ 130 200 70 70 70 loo x x 70 300 210 400 400 200 210 210 75 x x x x x x x 75 75 75 75 75 140200 200 200 150 100 75 75 75
Phospholeum Phosphoric Anydrlde Pickle Alum P~crtc Acid P~cron~tr~cAc,d P~melwz Ketone
w w a. b.. cl. 8. w ab. cl. e. w 0s
65 150 106 x 106 x See Phosphoric Aad Any 150 Any Any 100 60 x
x 165
x x x
160 70 70 70 x x x 70
200 100
80 x
x x
x x
x x
Potaswm Potaswm Potassum Potassium Potassium Potasswm Potassum Potasswm Potassium Potasswm Potasswm
Acetate Alum Carbonate Chloride Cupro Cyamde Cyanode 01 (61) Chromate Hydrate Hydroude Mur~ate N~trafe
a,w
Any Afly Any Any Any Any Any A? Any AY Any
120 150 150 150 150 150 x 150 150 150 150
175 165 165 165
150 165 160 165 150 150 150 165 165 165 165 200 200 150 150 120 200 200 150 200
120 160 160 150 150 150 150 150 150 160
150 150 150 150 150 150 150 150 150 150 150
75 200 150 200 120 200 100 100 75 200
75 1. loo 70 70 130 75 75 70 130
loo 150 160 150 70 100 150 130 130 150 130
x 70 x 70 x x 140 x x 70 160 100 x 70 x x 130 x :o 70
180
200 160 210 75 100 160 x 2:o 210
75 160 75 x 75 x 75 75 x 75
75 75 75 70 75 x 75 75 70 x
w w a. w w a. gl. w w a. e. gl. w a. e. gl. w a. w a. gl. w
loo
x 165 165 165 160
(continued)
Comparative
of Construction
835
TABLE 7.4:
RUBBER,
AND WOOD LINING
CHEMICAL
RESISTANCE
FOR LINING
MATERIALS
Propenenllrlle Propyl Acetate Propy~acetone PrOF/t Alcohol Propylene Propyllormlc Acid Propyl Nitrate PrOtochlOrldePruss c Ac,d Purple Salt Pyrldre Pyroacellc Ether Pyrol gneous Acid Pyronuc~c Aldehyde _ Pyrr01e
OS, w
AY
100
80
80
a.e.w a.e. -____w a.e.w a.w

a. e. w
a. hc. k. o
AY AY AV
too AW An; Any Any Any Any 100
80 x
150 120 x 120
x
x 120 x 120 75 120 x 150 x x 150 150 x x 120 130
150
75 150 70 75 x 75 200 75 70 75 x 75 75 210 x x
120
x x
150 80 x x x x *
x I(
120 150
x x
x I 1 x
185 80
185 x 130 100 150
120 x 100 75 x
75 75 125 dw x 00 70 75 70 130 75 75
70 too 100 180 70 140 70 70 100 150 70 170 70 150 150 too 70 loo 100 100 100 180 130 70 70 70 170 70 70
75 1w loo 180 70 100 70 70 76 140 70 200 50 70 x 75 70 x 150 100 x 180 x x x 170 110 _
70 x 100 210 100 70
210 130 210 210 140 210 125 200 210 180 200 170 120 150 150 210 210 210 140 210 130 180 210 130 x 130 170 75 75 75 75 x
75 x 75 75
a. a.e.I
w d. b. e. w a, Cl. e. 0. w a. w b. e
100 x
185 x
0Ul"Ol
Raoeseed 011 Raw C seed 31 Red ,,I Red Potasswm Chromate Relined Lmseed 011 R,onus 011
a. e. *I a. cb cl d cb. cl. e. me a. e. 35 w a Cb Cl. e tu. pe b cb. cl e
100 A"Y
100 100 100 AlV lci 100
x
30 x x * x io 150 120 120 150 150 80 150 150 150 150 150 150 80 150 x 150. x x 80 80 80 150 x 150 150 150 150 150 150 150 150 150 150 150 185 185 185 185 180 180 185 185 185 185 x
x
x 185 :50
x
x
I
I
x I50 130
150
-.
120 75 I 75 75 75 75
120 130
1
x 130 170 100 130 130 x 100 x 140 75 x 70 100 70 100 170
x x
75 x
Rock Salt
Saccharose Solutions Saccharum Solutfons Salammomac Sal Chalybls Salqhc Acud Sal Soda* Salt Cake Salt 01 Lemery Salt oI Tartar Salrpeler Salt water Sand Acid Salt Seed 011 Separan NP-10 sewage
a a,91w
4
Any Any Any Any Any Any AY Any AW An; 50 Any 100
185
150 150 150 185 120 120 185 185 185 185 185 180 185 185 x 185 too 150
x 180 120 200 120 120 200 200
150 180 150 160 120 120 200 2w 2io 209 180 180 180 180 80 180 150 180 180 80 180 180 180 x 200 180 200 200 2W 150 150 150 200 160 160
150 130 150
110
75 75 75 x x x 75 :5 75 75 75 75
75 75 75 75 75 75 75 75 75 75 x 75 75
a. w gi w a. ac b, e tu. w w gl. w w w a. gl w w a. gt. w a. b cb. cl.e a. ac. w
185
80 x
150 150
185
200 203 200 200 200 ZOO BO 200 150 180 x 80 120
lx)
200 75 75 70 100 75 150 150 75 75 75
x x x 120 140 70 100 130 75 x 75 170 x x
185 185 180 185 185 185 x
150 150 150 150 150 150 150 140 150 150
sea
200 75
Slllcale Esters S~t~cofluor~cAod SMzone Grease SIllcone 011s Salver Nttrate Skydrol Staked Lwne Soap Solullons Soda. Soda Alum Soda Ash Soda N~ter Soda Saltpeter Sodurn Aietate. Sodwm Aod Carbonate Sodwm Sodwm Sodwm So&urn Sodwm Aad Sullate Aod Sulllte Alummo S~hcate Alummum Fluoride Alummum Sullate
AV 50 100 100 A*Y 100 Any AW An; Any AV AW Ani Any AW A; See Solvenls See Solvents Any
185
-
150 x
100 100
_ 70 x
150 150
x 100 170 120 x 120 130 130 100 100 x
_ -
a. e. 91. w PI. h. w w w w a. gi. w a. at w a. e. w w w w al. fe w
150 130 185 150 185 185 185 185 185 185 185 185 185
200 x 200 180 200 200 200 200 200 120 200 200 200
200 100 70 100 70 100 100 75 75 75
130 200 70 100 200 100 170 170 150 150 100
210
x
70 x x x 75 75 x * x 70 170 x 75 x x x
x
170 140 75 140 210 210 150 150 x
75 75 75 75 75
75 75 : 75 75 75
150 150 150 150 150 150
75
150
185
200
200
150
100
200
75
75
(continued)
836
TABLE 7.4:
RUBBER, RESIN, STEEL, ALUMINUM, LEAD, GLASS, CONCRETE MATERIALS-GATES RUBBER (continued)
RESISTANCE FOR LINING MATERIALS CQncen,ratDn 2 Ei $2 150 150 150 150 150 150 150 150 100 150 150 150 x
I
AND WOOD LINING
CHEMICAL
= S Q PO 165 165 165 165 165 165 150 150 165 165 120(Z) 120 165 165 160 $E 52 165 165 165 165 165 165 150 165 150 165 165 165 120 60 165 165 165 165 165 165 165 165 185 165 150 150 165 165 165 165 165 165 165 165
t : I z 200 200 200 2W 200 200 150 200 1M) 150 2W 200 x x 200 200 200 200 200 200 200 200 xx) 200 x 200 200 200 200 200 2w 200 200 200 _9 s z 200 160 160 160 200 160 160 200 160 150 150 150 x x 200 200 200 150 200 2W 200 160 200 200 150 200 200 200 200 2w 180 200 200 200 ; 150 150 150 150 150 150 120 100 150 150 150 120 120 150 150 150 150 150 120 150 150
SOlVents Sodturn &carbonate Sodwm &sulfate Sodrum Bwlf~te Sodwm Borate Sodwm Carbonate Sodurn Sodwm Sodun Sodwm Sodturn Scdwm !%dwm Sodum Sodwm Sodum Sodurn Sodwm Sodwm Chloride Cyanide Dloxlde D~sulf~fe Fluoalummate Hydrate Hydroxide HypOChlonlefl) Iiyposulftle Melaborale Peroxy-hydrate Melaphosphate N~lrala Perborate
:: s De 2s u.IL 75 200 75 100 200 200 160
g : I 100 100 x 120 75 100 75
::f =% 61 150 150 loo 150 loo 70 100 loo 70 160 130 130 I x 70 loo 70 170 loo loo 150
150
f 5 < x x x x x x 100 -j J cl 150 150 x 75 140 130 210 140 210 s 0 H %
w
w w
AV AY 4
AV AV Any Any Any See Solvents Any AY Any 5 20 Any Any Any Any Any Any Any Any Any AY Any Any Any Any Any AY Any Any
AV
w
a. gl. *I a. VI w al. te w a. gl w a. gl. w w w I. w gl. w a, gl. w gl. w w
70 x loo x x 70
x 75 75 75
75 75 75 70 . -
Sodium Hexamelaphosphale
170 100 100 75 175
75 75 x x
100 x x x x
x x x x 70 x x x x 150 x x x 140 140 70 70 x 70

x
x x 150 150 210 140 210 210 140 MO-210 75 140 210 210 210 210 x 140 75 210 210 210
75 75 75 75
75 75
150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 150 x x
x
loo
.
x :5 x loo x
-
200
130 100 75 150 120 170 x 140 140 :o 75 -
75
: 75
Sodurn Peroxide Sodturn Phosphate Sodun Pyroborate Sodwm Sesqurcarbonate Sodium Sihcale Sulfate Sodwm Sodoum Sodwm Sodw-r~ Sodturn Sodwm Sodurn Sodum Sodium
Wwm
a.w
165
70 200 75 200 loo 100
91. I w a. cb. I. w gf. w gl, w I. w a. w w w. 91 I. w w w
165
150 150 150 150 150 120 150 150

-
100 170 x 160 180 70 150 loo 150 70

120
x x x 150 150
75 x x 75 -
75 75 75 75 .
Slannic Chlonde Sulfare Sulfate Decahydrale Subsulfrle Sulfite Suparoxode Telraborata Thiosulfate Triphosphale Tnpolyphosphale
. 165 165 185 165 165
70 100
A!
Any loo loo
x
IW
.
x
. , .
x -
75
l&l 150 150 150 150
.
-
loo 110
110
120 170 170 70 180 I( 150 170 150
x 170 170 70 loo I: I 170 150
soya 011 Soybean Oil

Spirrts of Turpentine Splrlls Of Wlne Slanmc Chlonde Slannous Chloride Starch Syrup Slearic Acid Sloddards Solvenl STPP Stripper SA styrene Sublimed While Lead Sucrose Solullon Sugar of Lead Sulfite L~auors Sulfamic ica Sulfur Sulfurated Llnw
a.cb. cl, e a.cb. cl, a a.aa.Cl. e

a, Cl. e
I
120 15 150 150 165 75
100
loo Any Any Any Any loo Any
x
150 150
150
x
.
a.cb. il.
I. w.
60120. 60120 150 1;o 150 I 150 I 120 60 150 120 200 _.
70
.
210
75 170 200 200 75
70 x I 170 120
I: 1:o x
210 210 170 450
a, ho. Ia. w a. gf. w cb. cl. cl. a. w w
120 x x x.. x x 120 120 60 IM 150 150 x I I
x . . 165
. -
. . x
75
x x
a. e
h. w a. gl. h. w Any An; AY ArlV An; a. b. cb. cl. e h. v a. b. cb. a a. 8. *I a. 1 Any Any see SolvenIs Any
x x x x
80 I x x x
. 75 75 . . 75 loo 75 75
. x -
. x
70 150 150 1w 100 . loo x 170 loo
. 75 x 70 x I . 70 I x 70
. x
150 130 x 100 .
.
70 75 160 150 200 170 . 75 150 75
165 lx) 120 120 150 165
160 120 80 120 150 1M
120 120 60 120 . 2-X
120 120 . 150
x . x I . 100 x I 70 75 x x I I: I 70 70 70 x x x x.
. 75 75 x x .
75 7; 75 x . 75
Sulfur Chloruh Sulfur Duwde SulfureIIad Hydrogen Sulfur Hexaffuorida Sulfur Monochbrida Sulfur Subchbrtda Sulfuric Acii
.
150 x
x
166 1M 60 x I 166 166 150 1w I x 150 loo x I
I
I x x x I 180 170 80 x I x I x x II
x
I x x x I 150 loo 80 I x 120 I x x x
. 140 -
.
70150. 150 70
I I 7s
a. 0. -
Any
10 30 50 75 95
x
x I 150 150 60 x x x x x x x.
75 75
cb. a a. b. cb. a
a.b.
16.5 166 150 x x X 150 150
.
150 150 150 60 x x 130 x
loo loo 170 170 170 I x I 75 75 75 _
I x 70 I lo M 70 70 70 170
x I I I: x I( x 70 70 70 x x
70150. 70150. 200~400 200 400 200400r 1704rxl 75 400 70 70 70 150 1M 150 210 210 150 210 x x x I 75 x x I: I
x
70 70 70 70 70 75 75
Sulfurr Ether Sulfurws Acid Sulfurous Acd Anhydride Sulfurous Oxychbrlde
a. b. cl. o. n. w
AnV IO 75 AV
a. a. Y
(1)Lrghl colored compounds recommended.
but they may causa sorna cloudiness in the bleach. processes of Sodium Hypochlorile.
(2)Use 26666 compound for storage and Hard Rubber for manufacturing
(continued)
Comparative
Resistances
of Materials
of Construction
837
TABLE 7.4:
RUBBER,

FOR LINING MATERIALS 0 5 e p z . . * i$ s I
AND WOOD LINING
CHEMICAL
RESISTANCE
SOlVetS Sultur Trtoxlde Superphosphonc Aad sweet 011 Sweet Birch 011 Table Salt Tallol Tall 011 Tanntc Acld T.dl Tanmng Solurtons Tar. Sltummous Tar Camphor Tartar~c Aad TCA TCP TEA Terra Alba Terra Ponderosa Terp~neol Tertwy Butyl Alcohol Tenlaw Bulvl Calechd Ten& Bl;l Mercaptan Telrabromoelhane Telrabromomethane Tetrabutyl Tltanate a. ac, w a. ac. w b. cb a, b. e a. e. w a. e. w OS a. Cl. w gl. ho
tratlon 100 106 100 AY
915 no3
1 <
I cl
E s
3
75
x x 150 x x 100 loo 100
.
-
160 .
loo 60,2fJ.
x x
150 150 150 150 150 IW 160 150 150 x x 160
200 75 75 200 200 75 75
x 75 75
. 70
. x
75 x x x x
70 400 75 130
x -
a. cb. cl. e aa. 8. w
a.w.gl
AY
AY AV see Solvets see Solvets AY AY 100 100 see Solvents see Solvents AY AY AY A; 100 Any loo loo loo loo 100 100 see Solvents
.
185
eo
150
100
75 75
165
150 150 150
x x
185 165 150
x x
100 x 160
loo 400 lW4WX x 180 x 160 70
600
-600. x 210 x 210 70 210 x x
70 70
150 go 80
185
165
100
150
150
75
I x15 75
150
x
*
70
x . .
185 150
x x
x 120
x 80
75
I50 75
175 210 75 210
75
70
.
75
70
a. e. w
:5 x
*
.. f5 x x * x *
. . -
;5 ,& &lmr x x
* f5 * x loo
$0 x
* x 120
75
a. e a. Cl. e. w OS
Telrachlorcethane Tetrachloroethylene Tetrachloromethane Tetradeconac Acld Terra Elhyl Lead Tetraethyl Orthoslkate Tetrafluoromethane Tetrahydrofura Tetrahydronaphthalene Tetralan Trlmethyl Pentane Tetrol Thenardtte Thtonyt Chloride Tmcal TI Chloride Tin Crystals Trn Olchlonde Tin Protochlonde Tm Salt Tin Telrachlorlde Titanium Tetrachlorlde TOlUee Transformer 011 Transmwo FluId TrZlVertle Trlacetm Trlbutoxy Elhyl Phosphate Trlbutyl Phosphale Tchloroacel~c Aad Tnchlorobenrene Trlchloroethane Tr~chloroethytene Trlchloromethane Trlchloromonoltuoromethane Trlchlorotrlttuoroethane Trlcresyt Phosphate Trlethanol AmIne Trlethyt Alumanum Triethyt Sorane Tr~lluorov~nyl Chloride Trlhydrorybenzolc Aad Trlhydroayethyt Am,e
a. e a. e. 0 a. b. cl. 8. n. a w a. e OS a OS. w OS OS a. 8 gt. w w a. cb. 1. w P. ho. ta. w a. ho. ta. v a. ho. ta. w a. ho. ta. w a. cb. 1. w HCI. w a. b, e
x x I *
x
x x x *
x
x x x
* x
x.. ......... * ........ ......... ......... x x x x x 75 75

. 150
@J
. .
75
75 75
70 70
1w loo 75 100
75 75 75 210 75
.
75
. 200 75 70 70
x
180 x
-120
180 x
100 loo 100 100 loo 100 loo AY AV A; AY Any AY AV A; IW loo loo loo see Solvers AY loo loo
x x
*
x x x x. 150 x. 150 150 150 150 150 150 150 x x x x
x x x
x x
180 x
* x *
150 x
75 x
75
70
. . loo . -.
140 IM . x x x x I * . 150
210 75
75 75
75 75
x
185 x 185 150 150 150 150 150 x I I x
iI3
120
x
200 x 200 I x I * I x x 120 loo
x
200 x 180 150 150 150 150 150 150 100 1. 150 loo 80 x x
-.
150 x 150 150 150 150 150 150 150 70 x I x x x loo 75 120 120 120 120 75 150 75
-.
140 x * x x I I * . 150 75 160 150 x 150 150 150 150 * 150 150 x I x x x I I 150 75
.
210 210 75 210 210 210 210 210 210 150 75 x I 75
x x x I
150 I
h a. e. OS. w Of a. e. w a. e. es. OS. 0 a. e. es, OS. 0
.& 75 x x x
80 80
120 75 x x
70 75
75
130
AY
x
I
x x x x
x
x I x x
x
x I x I
x
II
I
75 75 II
-
x
75 12-J 130 70 70 x 70
I
x 130 loo loo
a.e.es.OS, 0
a. b. e. n. 0. w AY loo
loo
x
I I
I
x
x I I
x
:5 75 I
loo 130 75 75 150 75
210 75 75 210 210 75 75 75 75 75
OS a. Cl. w hc OS a. b. Ire a. e. gl. w a. ct. w
1w AY 1w loo AY Av
&I 60 x x. II 150 80
185 150
x 1M
If
:o
75
75 75
210 -.
75
-. x
150
x x
x
x.. x. x
x 120
I
150 80
-. -.
75 75
-.
150 x
lea
75 70 :_ 210 75
(continued)
838
Corrosion
Resistant
Materials
Handbook
TABLE 7.4:
RUBBER,
AND WOOD LINING
Tnn,trophenoI Trtn~l~ololue~e Trtoctyl Phosphate TrlOleln Tnpalmrl!n Trfpolyphosphale Tnsodwm Phosphate Trltolylphosphale Tung 011 TlJrpenhne Turpenl~ne Subshlute 1lJrps urea. VarnlSh
eoetable
a b. cl e w a e a,ac e a Cl. e. CI Cl e w OS e cb cl. 0 a aa Cl. e a aa. Cl e a b. e, w
AV
loo loo See Solvents
x
I
x x x 150 80 x x x x 150 x
x
x x
x
100
100
Av Av
100 100 100 100 100 Anv 100 100
185
x x x 185 I x 150
185 185 x x x x 150 x 100
2k
x 120
)I
x
x
150 x
x
cm
FM 8 F50 a a. a. a. e gl w Cl e. w w e 8 AnV Any Any Any 100 100 Any Any 100 AnV Any An; Any See Solvenls 100 Any AnV 100 100 Any 100 100 AnV Any Any Any Any
150 150 x x 200 75 130
170 75 75 70
170 180 100 130
170 180 130 70
170 x 70 70
170 400 210 150 I x 75 75 75
Vers~lube
80 150 io x 80 x x 150 150 150 150 150 120 150 150 x 1Oa x I x B 150 150 150 150 185 185 185 . x
100
150 190 x x
120 150 I x x
wnegar Vinegar Niwhtha vmegar SalIs my, Chlor,de Vtnyl Cyanide ,nvl Trlchlonde VM~(L P Naqhlha water WalerproofIng !&all Whiskey Whtte Caustic White Coppea While Lead S~liate Wh,,e Vllnd Whltlng Wine WIntergreen 011 Wood Alcohol wood 011 Wood Tar wood vmegar xy1ene Xylldme Zeollte Zinc Zmc zmc Zmc Acetate Chloride Sulfate Vllrlol
100 x x x
I 80 x 185 185 185 195 185
120 x.. .#
OS w a. e. ke es
x
x 150 120 150 150 150 120 150 150
I
x 150 150 150 150 120 150 150 75 75 1w 100 75 100
w a. gl. w Ql. w i. w gl. w h e. aa. w a. e. w e. cb. cl. o a. a. a. a. w e. 0 w e e
x 185 120 150 185 150 185 150 150 185
x 200 120 150 200 150 180 150 150 100 120 x x x I 120 x 150 150 150
75 75 70 x 70 75 x x x
70 75 150 x 130 200 150 200 70
75 75 75 x x I )I x 75 90 170 70 70 75
75 75 x 170 150 170
75 75 75 210
x 75 x 75 I 75 x
75 75 75 75 75 75
2:o 180 210
80 x
150 120 x x x x 150 x 150 150 150
120
75 100
f5 150 110 75 x 150 -
150 150 150 70 150
150 x
75 210 210 140 75 100
75 x x
75 75
x 100 x 100 loo 150 185 150 150
70 x 150 150 150 150
75 x -
a. w a. e. pi. w gt. w gl. w
100 100 loo
x x I
100 200 200
x x x
75 170 170
210 210 210
x I x
x 75 75
Comparative
Resistances
of Materials
of Construction
839
TABLE
7.5:
IRON,
BRONZE, STEEL, SYNTHETIC

SHT rs, etC.
WES, IMPELLERS
RESIN AND RUBBER PUMP MATERIALS-ITT
JABSCO
IMPELLERS
KEY TO SYMBOLS: A Satisfactory. C May be suitable dependent on concentration and temperature. Contact factory for Engrneering Assistance. N Not recommended. 0 Blank: Information lacking at tome of printrng. Contact factory. Acetald* -_-- ___-. Acetamide _._ --._ Ace@ Solv.(Crude) AcelaJe Solv. (Pure) Acetic Acrd GlacraliY . . ._t. CH,CHg CHXONH,
Chemical Resistance Table*
SI -
DI ES, rbi. etc. - --r--.-
$u
-2
5: :C. ._A:
N N N N
A N N N A C C C
$0
B A _~.
A _A A .C A A C C C __ A N A N A A -~ A j9. A A A A A _~. .A. A Anlj_FEeze!by @lel~~el~~
z z !iI 2 m -. P C c x C A A -A A A -.
-CH,COOH
I* 10% --~ I825%
.-___._
(* 50% _lPy!e ~__1: Vapor Acetic Anhydjde ._~~c_H,co~~P ~_ Acetone .__ ~rX&O.CH> Acelylene HC*CH kcetylene Telrabromid; f$liBJ,), Acetylsaiicyhc Acid (Asp&l CH,CO*O*C..H,COOH ~~~__..___ Acrylomlrile CH,=CHCN Pdhesive (PVA) Bordon Chem. Co. -;, Fmdley__ . . ~~- _._ ____ :Pgcific Soap Alc_ohol.~Amyl C,H..CH,OH C,tl;CH;!IH
.N __c N C C_C CZ~_C A A A-. NN N
ma-Sta, Permaguard, Pyro Perm., Sears, Shellzone. Smith-Blue Cold, . Prestone Pyro Super ~--_.~. mm--3 .a..; -. varworene Aromatic Hydrocarbons .(+sjlt Factory) Arsenic Acid _. __._ H,ASO. . ..i A A _!-A A C A c P;A;Np C-A _A 9 N - A.----c A N :.A__ N A;..._ _ A-A __c N_: A c_ .._! A-t A ;!._A A!AI A Bay Oil__ Beef Extract N 1 C CC J-A _!_A A A A A A A AIA_N NT-A --N.A:.._J! C;A.A _tj N _A CJ N A__!! C jI_ -C__ L 1 N C i A A
: P 1.
A_ _CC N.-. N
._Y .BeW _Bulyl ------C,!@ilOH _/_D!acetone LCH,lXDHCH,COCH~ ~. ~--__ _ __ ._.~ __Jthyl ~_____~ CH&lltj Hexyl C,H,&tf,OH _~ _._ IsobuK ~*_I~~propy! Methyl -..-__. I Octyl _-I C,H$y_ C:H.CH:Ofi . CH,OH CH-H,XH,OH~. _ __ C:H.CH,OH I2 AICI, AIO, AIISOJ, R-NH,
A--A_ _A_-!. N A_
-4 _A
_A A i-A A-C A A A A A A A N N A A Nc --N N N N /i CA. _C_ _ AA A 1 A C..A N N -N -A IN -N .!!. C C N C N
A A A 4 A N A A A A
:-Prwl
Aluminum Etch Aluminum Chloride Oxide lSil!ate Amines
~~ 1. Wroxide:.~_ _ __ AI(
AmmonLa. &@~~:_Lii_qujd_ NtJ _A .mN _:>jquors -__. NH OH.H:O !!__N _. A N NH,NO, .~__ Nrtrate Am_Fonium Bicarbonate Bifluoride Carbonate ~___~ __~._._ _I(Ceenite6 LChloride _1_Hydroxide <itrate
44 II
NH,HCO, HH.F.HF fNHJ:CO, N&Cl
-4.
_N_ f! ! _ _.f!. _N_N
A ~mr! .P A A A A F; Ii A A A :i Ki A A A A A-N _A__.N .f!_ -A 4 A A
_N_H,o_H JLA NH,NO -- A N~tU,o (NI(&cJ
50% ___-__
~- Oxalate -_--~ Persulfate
A _!._._A -._ P N _!G A A _A_! ---~ h A -K _!! _&-A A JL!! _!L_! F. Titanium shaft 6. 8. 12.
KEY TO FOOTNOTES: 2. To 25% concentration-150 3. To 25% concentration 5. Use Hastelloy B shaft Data contained
Brinc.lfuL.l.dldik
Slow speed 10% at 85 F. Titanium shaft 15. To 10% concentration-100 F. temperatures unless otherwise noted. (continued)
Union Oil Brewery Slop
in the table is based on results of tests taken at ambient
840
Corrosion
Resistant
Materials
Handbook
TABLE 7.5:
IRON, BRONZE, STEEL, SYNTHETIC

BODIES, SHAFB.2 IMPELLERS
RESIN AND RUBBER PUMP MATERIALSBODIES, SHAFTS, etc. IMPELLERS
ITT JABSCO (continued)
Jigtane _Bu&not
.--_
(HACH:&t, tsee Butyl Atco&ol) NrA f A _ A. A A ~A A A ~A ._I. A A A _&-&A A A A A A
L. .L_
_A_ A A C A A 4-A A N X N_ N_c -..A A.. A A.-A._ CC

IC
Corn Oil
_I$&jiSG~i -. .------._-
CalrJ~Bisulfate__ _ Calcium Chloride
_Catt CaCI,I C 1 Al Al.-A
calcium Hypochlorde I0 Ia CafClO),
1~1 N
A A, A A A A
A A
Disulfide Tetrachloride
Chlorinated Lime Chlorinated Trisodium Phosphate
!!__A_ &-AA- _A_ A A A --A -A .-
c A N NA A N N A A N --.-!I.-!!__ C__A-.X N__k!__A .I NCA_ .._. _! -.-A -N N ._.__-N N -.-... .._._..... A 2 c -.._.-_-.
I
Cream h Creosote_Oil I A Cresols _CLesylic Acid .-. -______ Cutting Oh ((Water Soluble) (Sulfur Base) ______.. Cyanic Acid ~ cycle Hexane _Darex A.E.A. Oegerm, Deodorants (by trade name1 -.-_ Blue Chip ---_ Flushex H7BD tSO%l ~____ tloo%t Monogram OG19
+$
_kYEL-55_ __.
.I
L-55 #IO1
u
atlfl?
..---
Zhloro.Acetone
A --.-_-_- __ _, A A A N C--C_ .-A. U . .._..._..... .._ N N A_& c_______ __ N 4 tUA .-._-.-A t!. tU< .- ..-.. .- N A AU A N 1 N A_.._..._._ N:. A.. .!!!____ N
IY!!!__!?
__.
J~fia_s_j_Menascol
11._-.::At A
N1.A NIA NtA -...
y A
Dele!gen_t_t_. __... --_ Ofievloqrng SoJrtion Copy Mach
N N N
N
Dibromochloropropane
Chocolate Syrup Jhlo_c_AcM~Cotd I 50% Cider Cinnamon ._.~ Oil ..___ Citric Acid -__-_--Citric Oils ____
HXrO,
I!_ C.-C. IY.--_ IU-Y-A ._
teobjt-Special
*I
____ C,H,O-H,O L_.
I4.- ----.._ -! I ._!

I ._
IU..._!U. .._ .. A
Clove Oil
i _! ..! ! I
shaft
Shell-Premium --_ Standard~_ Oil Texaco 448 _ Fuel Chief BjesterSyn. Lub._O~ .---__. A Ehethytene Gtycol __! ](Cti&t@l), ,A Diethyl Sebacate [CCt M~coocJi,]l Di-Isopropyl Ketone fCXl,)IC_tCOCHfCH>L ------ i. Oinitro Toluene
A A A A
A.A !_.A
A A A
A
AAA A A .A
_..
A A A. A A A
_0:lyinfectantDeodorant
-i
KEY TO FOOTNOTES: 5. Use Hastelloy 3 IO. Chlorinated lime
11. Sodium He* _...___ r.._ sphate 12. Titanium shaft All impeller compounds i normally ok when concentration
is 1 part oil to 50 parts water.
(continued)
841
TABLE 7.5:
IRON, BRONZE, STEEL, SYNTHETIC RESIN AND RUBBER PUMP MATERIALSITT JABSCO (continued)
BODI S,
b!!
etc.
IMPELLERS
DIES, TS, etc.
P ii
Et&n+mine _,_~_H,N.~H_~CH;OH___. Ether Co?po_Fnds-_. .c EJlyyl Acetate CH,COO*C,H, - A ---_---_._---. - Axlate CHXHCOOCzH-. _--.-. ._ _..--.. _Chloride -- - ~-- CH,CH$I _-C _ ___:_ _.-_. -__ C,H,@+ _C Ether E!~~_nep~ide_~~~Cl~C~~~C~_ _. HOCtlz*CH,OH A Glycol ___.__.______._ __._ __.._ Ethylene Oxide (CH&O_J Fatty&ids C .___ Ferric Fe& y_ ----- Chloride Nitrate FeNO, --. ___-- Oxide K!?__ Sulfate FeSO, _y ferrous Chloride FeCI, .N _ .._-___. -.-___.. Sulfate _-. --- :.-_.. FeSO, N .-Fish Batter N __.._-.---_-. fluoboric Acid HBF, i; Fluosilicic Acid?PVC 25%) H$iF.. N_ Formaldehyde HCHO C @@c Acid HCOOH__v Freon CCl,F C_ .___-. II (MFP6 -~ --~-_ _
_k!2We!-. I_ 22. 113 ITi+
-_
.A
GoM.Monocyanide Grapefruit @I Grape Juice __
A A
A A
A A A
A A -A [A A N -_. A -..
Hair Solution (by trade name) Breck ._ Clairol _ _ __-.__ ._ __ _-. Ouart --___-_ - Mentos ----_-._
C A A :ti II? .-
--~--.Hydraulic _ .__..._. Fluid__ -. Skydrol 700_-._Petroleg_Base
W_!~ice___
Furan Resiq,
C IQ _. C N .N A N ._ .I! !J _G N A A A C C A 3 .-... _..____...__ _A 3 .N ..___.CCIF, ..C .A c __ __CJ&~,__ A .~ A .__i c _. A .A ,__ .A A A A -. -.A -A _h _A A _. A _. -A A 3 4 ..A A a -A -A 1 _ _-
Hydrazine (Water Base) _____ __ ~____._____-__ (Alcohol Base)
- _._~~_
,-..__ .._.. ~... ~._.

HY&l*ric Acid 6IFx,6-&INA.
HCN! N; N_A_N_A+A{A/Ai N., NL_._ C_ C
C AJ
.-- Arabol .____-Cohoes Emhar! Lavoris
_ _ _
__..-___ Kerosene
~--
Glycolic Acid (70%) -__._-._-----_ KEY 5. 6. !2. 14. 15.

TO FOOTNOTES:
HOCHICOOHL ._ -
-.
L._
Use Hastelloy 6 shaft Slow speed ~ita~n_ium shaft ._ To 40% concentration 150 To 10% concentration-100 Hype-See sodium thio sulfate
F.-Hastelloy F.
Bshaft
Impeller 16. Use Polyurethane 17. To 40% concentration To 20% concentration. Use Hastelloy Water soluble
B shaft
lmunallc acid t
(continued)
842
Corrosion
Resistant
Materials
Handbook
TABLE 7.5:
IDIES, TS, etc. IMPELLERS
-__--_
Lactic Acid Lard CHJHOHCOOH _____.~ Larvacide (Trichloro Nitro Methane) _!C_h!o~oP&i!~_ ____.. CCI.I.NO, Latex:_ _~ Lead Sulfamate Lemon Oil ~_______._ Lignin ~._ ~ Lirpror Lime _CaC Lindol Ljnseed Oil Lithium Bromide LiBr*H,O -__ __ _. Lubricants (by trade name1 _C!o!vn!~&avY.OutY .__~._.._Multi Puppse Lubrico-M6 Marfak--2H0 Multi-Circuit Etch N CHXOOtCHUH, A A A_ Mustard __-.__ N,Butyl_&etate N -Butyl Ether N_&Gritrile N-Heptane N-Hexane N-Pentane N+pyl Acetate N-Pro~~~Al~ohol. Naphtha Naphthalene.. Nickel Chloridell
CH,tCHJ,OtCHJ,CH, _ _C_ A_ _ _ ._~ -____. __. _ __ _ CHI(Ctl>XN CH.,(CHJ;CH, A A, _ __C_HACH,T,CH, CH.,tC.H,l,CH, A A_ A. _A
C_H,COOCHfCtt,~~ _A_ A CH,lCH.),OH __ A_ _A __ .~~ .tmjxturej A _A
.___
.__Ww
Magnesium Chloriderx MgCI$H,o_ Hydroxide _ __MgfCl$, I_ Nitrate MgfN_OJ<2H~O_ __ _MgO~ Sulfate -..-.---.___ ___ MgS_O?t7_ti,0 &aanese Nitrate_MnfNOJ1*6H,0 Mash Mayonnaise -.--~___.-..__. Melamine5 N.CfNH,)N.CtNH:)N*CfNH,! __--_ Mercury6 Hg Met~a~ol_fMethyl Alcohol) -___ flOO%l ..__ fSO%J Mercuric Chloridqf_ HgCI, __ Methyl Acrylate CH*CHOOCH, :: U!y!_Ke@e Cellosolve ___ Chloride ____ _L_!Wowk~e __IEthylKetone CH.8CO!CH&?ltl_ CHJ$tJXH,OH Oxide-
C,.,HI _A NiCt, N NiSO, HNO,_N .__~_F. N
C_ N C N
Nickel Sulfate Nrtric_Acjd fdilute)r2_ __60%. SC%_ ~_ _ _ ~_~_
_Z_-!?ude_.____ Red Fuming NitrobenzeneNitropropane ----.
Ir N N N __ N
i.. ..N
0:
C..H:.NOz C_ C_ CH,fCHJ,NO, __~ _._ _. . Ch!oro-Phenol_ CICH..!OH ___ _
0-Oichlorobenzene Oit .- --- Aniline Anise ___~_ -ASTM f 1 ASTM #3 :_Hay_-_.
._
C..H,CI, A A
___ _~_ A A A A
_-!%!I
C,,H, CH,CO4H,CH,
lsobutyl Ketone _____CH,COCHfCH,)CH:CH, Isopropyl Ketone _~__CH,C$tHCHfCHJz_ Methacrylate CH.CfCH XOCH .---___-<AL_._. Methylene
Milk
Bromide.
_____HrCti_ -CH,CI, _CH:CI,
Chloride
Dichloride -----________ Mineral Oil
-----~,Creosote Lub. ---- Diester Syn.--.
I Dromus A -__..___
12. 22. Titanium shaft Water soluble-slow
l
__--- * c--_
speed
._^ Hydrochloric Acid 20%.
KEY TO FOOTNOTES: 5. Use Hastelloy B shaft 6. Slow speed
Muriatrc Acrd-See
(continued)
Corwafative
Resistances
of Materials
of Construction
843
TABLE 7.5:
BODIES, IMPELLERS BODIES, SHAflS, etc -7-7 r- 7 IMPELLERS
Photographic Developer Crude
___ _________ ---- Palm __- Peanut
_ _
~~~
A A A A A A A A A A A c__ --C_ _ c_ -I?_ C -!-A A 1 -A 1 A A_ -AA _&A _A-_ _A__ A -z 2. 1 AA A-2 TA-__ _A__~! A__! &a _A__ AA _A._ A 1---fPotassium ____ ------- Bicarbonate Carbonate (Potash) __.__-_. -. -___ KHCO Klco
WBirchwood -__--
. Palm Oil ._-___ _Palplex 662 Peanut Oi! Peppermint Oil Perchloro E*lene -__
Cyanide Bath Fluoborate Bath Chromic-Sulfuric Bath Fluosilicate Bath\ Fluoride Bath -__-- Black Chrome Bath** Barrel Chrome Bath! Copper Sulfate Baths5 Copper Fluoborate Baths Copper Strike Bath Rochelle (1 Potassium Salt Bath? Rochelle & Sodium Salt Baths Barrel Copperjath Gold Plating (Teflon Face Seal) Indiueaanide PIat& Chloride Bath _____ .~_ Ferrous Sulfate Bath FerrousAmmonium SulfateBath --___ Sulfate-ChlorideBath Fluoborate Baths Lead Fluoborate Plating Nickel Fluoborate Bath All otkfirNkgL@ths*
Amber __~____.._ 16S2010) _~ Amber (6S2001) Lily White .___ _~_ Snow White ___~______ Phenol (Carbolic Acid)
phe?-!_C_qmgou_nds Phosphoric Acid, Crude I* O/45%_ __ ~_ -y7-_ 45:&W.sL_ KEY 5. 12. 15. TO FOOTNOTES: Use Hastelloy 8 shaft Titanium shaft To 10% concentration-100
tAll Impeller compounds are normally C+I when concentrabon IS 1 part 011to 50 parts water F. (continued)
844
Corrosion
Resistant
Materials
Handbook
TABLE 7.5:
IRON, BRONZE, STEEL, SYNTHETIC RESIN AND RUBBER PUMP MATERIALSITT JABSCO (continued) BOO BOD :s. IMPELLERS SHAFT etc.
IMPELLERS
-7 .--7- T-7
&
Sodium Hydroxide -. .-. Hydroxide -(Caustic Potash) --_______ __ ---- Permanganate ___ Phosphate Mono ___ ~_ Sulfate
g > -:
2
_!_!
$4 _.
1 -_
& A __. ._.-
-ResinSolvent 17073) Rose Oil Rum
-7
l---r;
-. -
!!_
Chlorinated Trisodium Phosphate Klenzade Sesame Seed Oil
Shellac-Orange Silica Gel Silicate Ester Silicone L45 _Silicone X527 Silver Nitrate ___-
Stannic Chloride j&k Stearic Acid Stoddard Solvent
c c
C .-
Soda Ash Eodmm Carbonate)
Bicarbonate -__ Carbonate
Sulfur Chloride ___. Dioxide* ._ _ ~Rvlolten)___ __ I. Trioxjde, Dry Sullurrc Acid 0% _.__ ~. 60% - __-_._.. . Over __.-__ 75% ___.fuming___ Sulfurous Acid:_ Tannic Acid _. Tanning Liwrls_ .._ _
--- Oil
i_ I\ .-
A
A .-
c
k
151
-.._-
-.-._
E -~
12. Titanium 26. To 20%
KEY TO FOOTNOTES: 5. Use Hastelloy B
shaft shaft concentration
27.
recommended.
Has effect
on binder for carbon seals and bearmgs: Model 3010-l
(continued)
Comparative
of Construction
845
TABLE 7.5:
IRON, BRONZE, STEEL, SYNTHETIC RESIN AND RUBBER PUMP MATERIALSITT JABSCO (continued) 6 DIES, S, IMPELLERS
SHI
el _-
TS, etc
IMPELLERS
~~~~~
Tetralin tletrahydronaphthalenel
ThioAlycolic Acid
N -~ _..
-. c
N
N -Y .-C 4 ._?!
Trichloroethane -__ Trichloroethane _____
Triethyl Gorane Triethytaluminum _~_~_ ..____.__ Triethanolamine ___.-_-Ift? Tungil Turco W.O. #I --_-_ ~.. Turpentine
Vanilla Extract -._._-___.__ Valclene 200 (DuPont) __~__ -.___ Varnish ______ -_-Vegetable Juice Vegetable Oil -Vinegar Water Acid Mine 2: Soiler-; --~--.~__.___-.. _. -.- Orstilled, Lab Grade fresh H:O Water, Salt~__~_ CoJd -___ Weed Killers (by trade name1 Amino-Triazole Atrazine-Divron ~____ ._~ _.._.. -_---.--.-.-_-.- Karmex-Diuron Ktoben 7-Prop@ne-50W _-__. Simazine-BOW :SplayJ*e --_- Vacate (Dactalt &I & Wines White Liquor (Pulp Mill) .~___ - White Water tPapar_MrIU -_.--.-_-.~ WRDA Xylene C&Ck, _~ _ ~--.-~ Zinc Chloride znct, Hydrosulfite ZnS:O, ---.--.__ Sulfate -@SO,
Undertakers Restorative Urea formaldehyrje Urine -.-_____ ;__--_KEY TO FOOTNOTES: 5. Use Hastelloy 8 12. Titanium shaft
shaft
846
Corrosion
Resistant
Materials
Handbook
TABLE
7.6:
IRON,
NICKEL AND COPPER ALLOYS
FOR CASTINGS AND FORGINGS-JANNEY
CYLINDER
CORROSION RESISTANCE CHART
Acid Mixtures Acid Mixtures
50%
HNO,
25% HN03
Chlorine Chlorine
(Moist) Dioxide
__ c
A A A B
._ c
A 0
c
A 0
-0 C
-c
C C
Ferric
Sulphate
1 O-30%
--
--
(continue id)
847
TABLE 7.6:
IRON, NICKEL AND COPPER ALLOYS FOR CASTINGS AND FORGINGSJANNEY CYLINDER (continued)
\
Fluorrne Formrc Acrd Hydrobromtc Acrd
. t ..
.. O-50% O-5% All All _. _-A 0 c -._.. c c
_.
I / ( -~ ( c E E r C
J--
..
A -__._ _. 8 c B c 0 c A A A A A A c __~_. A A A A __-A 7 c __ A A A C 0 -. -B A C C 0 C C 0 -_ c -A A A _-._ c -A A -A A A ._ A c c
..
A _ ._ c c c 0 A c
H~drochlorrc~Acrd Hydrochlorrc Hydrotluorrc HydrogenHydrogen Hydrogen Acrd Acrd Pe&rde Sulphrde Sulphrde (Dry) (Morst)
_.
A _. _. _. A 0 -~ _. A A --0 A -0 c
C A A A
_. __ __ --~--
Hypochlorrtes Lactic Acrd Chlorrde
c A C E c A C C A A B C B 0 c A A -z 0 c 0 0 0 c 0
A B .. -. c c A A B .~__ -A C __ A A A c C 0 0 0 C C 7
A B _. -. c c
C B c c B c B
C C --c c C C c -C c _. 0 ~_ 0 C 0 c c c c c c
Magnesrum Mercunc
_.
Chloride
I _____~___ __ ---__ __ O-7040 100% .___ __ All __-
8 _c A A B A ___0 A A c A
Nickel Sulphate .- - --~ Nitric Acrd -----.~_--______._ Nitrrc Acid Ol&c Acid ---Oxalic Acid Phosphoric Picric Acid Potasstum Potassium Silver Sodium Chloride ___Drchromate ____ Nitrate Chloride Acid --
A 0 _. A c __ A A A 0 c 0 0 0 c c
C c c C -__ C C 0 c c c c c c c
All __ O-30% All __
___
B 0 A A A B A A A 0 B 0
A _____ __. A A A 0 A 0 0 A __ B
_.
A
--___ O-10% __ All __ __ _~___ 2590% .-___-_ 9ti%
6 __-A A 0 -0 B
Sea Water Sodium Hydroxrde ._ __-. ____ Sodium Sulphide -_-._ ___ Sulphur Dioxide (Moist) .--__. ___ Sulphuric Acid ~_____ Sulphuric Acid
_
c
-A c c B
AA-Excellent resistance B-Good resistance C-Poor resistance -No information t t

l l l
Bpar Langley .4lloys Cabot lnco
TABLE 7.7:
VARIOUS
RESIN, ELASTOMER
AND STEEL TANK MATERIALS-NALGE
;Th,i,s chart will assist in the selection of NALGENE tanks for use with common chemicals. Under normal conditions, chemicals rated S may be safely handled in NALGENE tanks. Chemicals rated U are not recommended for storage in NALGENE tanks. This chart applies to unsupported tanks at operating temperatures from 70F/21C to 140F/600C.
s
s Acetic Anhydride Acetone+ Acrylic Emulsions Actylonitrile Adioic Acid
s
s
s : S s s
s s s I s
u
s s 5 s s
u
s u u u :
s u j
s u ; S-___
: u ii-j:
u
;
u
i?
: s
U G
50
! s _
& ; _
k! ; ; I
s s _
loo loo
849
s
8
I 13 Iv)
Ov)
, v)
I I
3
0
,*m
3cn
>mfn
,v)
3v:
3v: U-J= 3m
*=
3v:
3=
3=
ES
850
33u ov) I
nv,
I
n*
4
Comparative 851
Resistances
of Materials
of Construction
Iv,
Iv)
852
Corrosion
Resistant
Materials
Handbook
I I I I I
v) 3 v) > I 1 I I
WY I 1
,
I I
>
nou
Iv)
>
ov)v
Iv) -
,
Iv)
n
13m<
n
I ,
n
I ,
1 t
3v)
3v)w
854
Corrosion
Resistant
Materials
Handbook
TABLE
7.8:
METAL,
ELASTOMER
AND
PLASTIC
PUMP
MATERIALS-OBERDORFER
KEY SYMBOLS: This Chemical Resistance Guide was compiled from available charts and tables provided by material manufacturers Their nomenclature was condensed into key symbols. Their descriptive words shown below can aid in making judgements as to pump suitability for specific applications. (A) ACCEPTABLE: Excellent Resistance Fully Resistant Suitable Recommended Excellent Compatiblity Fully Compatible (0) QUESTIONABLE Good Resistance Minor Effect Moderate Effect Slight Effect Slight Attack Fair Resistance (N) NOT RECOMMENDED Severe Effect Unsatisfactory Not Acceptable Do Not Use ( ) DATA NOT AVAILABLE AT THIS TIME
CHEMICAL
CODE LETTERS Acceptable aA Questranable Not Recommended N BLANK-No Inlormatcon Sublect to pitting when allowed to dry. Sublect to attack when hydrochloric acid IS present.
RESISTANCE
GUIDE
EIASTOMERS NON-METALLIC
NAME OF LlQlJlO
Acetaldehyde Acelamrde AcetateSolvents Acetone Acetyl Chloride Acelomtrde Acetoohenone Acetylene Acetylene Tetrabromide Acetyl Chloride Acrd Mine Waler Acid, Acebc (50% Unaeraled) Acrd. Acebc (50% Unaerated) Acid. Acehc (100% Unaerated) Acid. Acehc (lC@io Unaeraled) Acid. Acehc AnhydrIde Acid. Acehc Anhydrrde Acid. Acehc. Vapor
Cold
1 ColdA Soilino
Cold8 Bodmg Cold Cold Cold Cold 6 Boding Cold Cold Boiling Cold Boiling Cold Boilmg I I I I I I I I
ZE
N A A
Acrds, Fatly Acid. Fluoroborlc Acrd. Fluorosduc Acid. Formic Cold lo Hot 0 0 N N N 0 ONOOOAA A A 0 N A/O A A A A
(continue1
Comparative
Resistances
of Materials
of Construction
855
TABLE 7.8:
METAL,
ELASTOMER
AND PLASTIC PUMP MATERIALS-OBERDORFER
(continued)
BLANK-No
lntormalmn
(continued)
856
TABLE 7.8:
METAL,
ELASTOMER
(continued)
BLANK-No
Inlormation
Subject to plthng when allowed to dry.
\lum Uummum Acetate (Saluraled) ,I.._.^.....
0 Cold 0
0 A A
A A I
A A
N A
1
I
(continued)
Comparative Resistances of Materials of Construction TABLE 7.8: METAL, ELASTOMER AND PLASTIC PUMP MATERIALS-OBERDORFER (continued)
857
Acceptable 0 Ouesbonable N Not Recommended BLANK-No Information

A
NAME LIIJUIO OF
Anhyotous Hydrogen Fluoride Anhyorous Hydrazme
I _ _ ^ _ .
I IAl IAl 1 IA]A~A]
I I
1 I
(continued
Comparative
Resistances
of Materials
of Construction
859
TABLE 7.8:
METAL,
ELASTOMER
(continued)
Acceptable A Puesbonable a Not Recommended N BLANK-No lnlormatlon Subtect to pltlmg when allowed to dry Subtecl to attack when hydrochlonc acid IS present
:alcum Acetate :alcwm Bisulphate .^I^:..- O.^..,_L.~^ 0 n ,u, N

I
A N n ,u, A A 111A A A
I I
Al AIA . . ,rr,n,n, A . N
1 1 I
I,,,,-,
(continued)
860
Corrosion
Resistant
Materials
Handbook
TABLE 7.8:
METAL,
ELASTOMER
(continued)
T
CODE LETTERS A Acceptable a Questionable N Not Recommended BLANK-No lnlormatron Sublect to prttmg when allowed to dry. Subtect to attack when hydrochlortc acrd rs present
ii
T
2 8 % *
I
ii
y? $
k2
2
El5
NAME LIQUIO OF
Calctum Carbonate Calcium Chlorate (Dilute) Calcium Chloride Calcrum Hydroxide (10%) Calcrum Hydroxtde (50%) Calctum Hypochlorite (2%) Calcrum Hvoochlorrte I%% on Ptashcst Calcrum Ndrate Calcrum Phosphate Calcrum Salts Calcium Sulphate Calgon Cahche Liouors Camphor Cane Sugar Liquors Caoella AA
Carhamate
Cold Hot or Cold Cold 8orlino Bodmg Cold Cold
B 2 a - a ii n - -ii A - a
a ii ii
-6 A ii T ii 5
T -i -
3 F E g Iii Li 25 m 5 f
w
2
is
E
I
Y k? 8 Y
s
I
9 -
Li ii-
-A- x-
n T-ii- si1 x
T
2 -
% * z 7
i?
cc
!z
a T
(1 a - 0 A A A A A A A
n a iz 4/1a - T T -
I-
n ii I IiiI
n iiij-
n -
Cold
Carbmol (Methanol) Carbon Otsulphtde Carbon Dioxtde Carbon Drsulphrde Carbon Monoxtde Carbon Telrachlorrde Carbonated Beverages Casem Castor 011 Catsup Caushc Soda (See Sodrum Hydroxide) Cetlosolve Cellulose Cellulube Cellutherm Cetane (Hexadechte) Chma Wood Oil (Tung) Chlormated Lime Chlormated Salt Bone Chlormated Solvents (Chl. Water on Plashcs) Chlormated Water (Saturated) Chlormated Brphenyl Chlorine (Anhyrous Liquid) Zhloroacetone grobenzene Zhloro Bromomethane Cold Cold Cold
n a a -i - - - - - n -7 T Yi - - - - - - - - - - - A ii T T n n 0 n -6 n T T
T
ii; iii ii
4
4
7 7
-
T T 0 - - -
a -ii a n T 7 -
n n 7 n 7
Yi
nn
a -iT - ii - - - - n
T A - - ii A T - - -
n n - - Ti0 -ii T - ii -
i-r
n
li-
A A
A 4 - +
A -
n -
4= a
T
0 -
a0 i T n -ii
ii
N
a a- i
A
n n -
A 0 T i-
nn - - - - - - - ii- -
n A 0 iiiT -
w
n
7 -
A -
n
n
;i A -
u
4 U
n -
T Ti -
n -
z ii (continued)
Comparative
Resistances
of Materials
of Construction
861
TABLE 7.8:
METAL,
ELASTOMER
(continued)
Not Recommended BLANK-No Information

N
Subject to prthng when allowed to dry. Subject to attack when hydrochlorrc acrd is present.
Copper Sulphale (5%) Copper Sulphate (Saturated) ^ ^ 1
Cold I
Borhng
iNIN
INI
lAi+lAlAlAl I, ,.I I
~o~N~Q~N~A~A[A~AIA~AI
1 I iAiNlAl I I IAINIAIoIA]A] I I I 1 ,.I
lAtA/ I I I
(continued)
862
Corrosion
Resistant
Materials
Handbook
TABLE
7.8:
METAL,
ELASTOMER

-I-
(continued)
CODE LETTERS A Acceptable 0 Ouestmnable N Not Recommended BLANK-No lnlormahon Sub]ect to plttmg when allowed to dry Subject to attack when hydrochlortc acid IS present
METALS -
ELASTOMERS 1 -
iii
iiEILI -
NAME Ll@JlO OF
:orn 011 Cotton Seed 011 :ream Zreosols :teosote 011(Coal Tar) :resvldmhenvl ,., Zrotonaldehyde :rude 011 :umene :upric Chloride :upr~c Nftrate Zuprous Ammoma Acetate :uttmg 011(Water Soluble) :uttmg Oil (Sulfur Base) :yamc Compounds Zyanogen Zyclehexamone Zycleweld LB08 Zvclohexane :vclohexanol Zyclohexanone :yclohexylamine )OT (Toluene Solvent) )OT (Kerosene Solvent) IaIry EE2 Iecalm Iecane Delco Shock Absorber FluId Ielvac 1100 Series Motor 011 Mvac 12tIl Series Motor 011 Mac 1300 Series Motor 011 )elvac Special Motor 011 lenatured Alcohol !eteraent Water Soluhons levelopmg Soluttons (Hypes) lkacetone lkacetone Alcohol llamvlamme ltbenzyl Ether Iibenzyl Sebacale llbromoethyl Benzene libutyl Cellosolve Adlpate Nlbromochlotopropane Hot Phosohale Hot
B
c
E 3
i4
v, _i
2
T 5 _ _ -
z z
2
3
2
&
e :
-I T 3
z
T
P % P
7 7 7 n n T -
a
Ti -
2 2 g ii? > K T
3 -
P B Y E
- T T T -ii - 7 _ A - n Yi n 0 n n n A n a Yi n -
a -ii
x
0 7i -
z n -
E t $ -
z < Y 2 H$ -ii- Ji Yi -
El z z G n n A n Ji n A K A _ -
z s 5 x
n n
E B 9
SJ
-x 7 t +
Tr - - -
J-
T -
n
n T -
T T - ii - a - _ _ - -
_ -
74 n
7 T - _ - T ._ - - - - ii -
77 ii- n - -
E
--
n ii T
n n
i7 -
T ii - 7 7
A n 7 -
n
A -ii -
-A: - n - - - - - - 0 - a - a - a
n -
7 -
Ti N -
n -
7 7 T ii
-ii- Yi Qi Ji - -_
3i-
A A -
n
n _ n n
n A A -
;; -
n
n -
n -
T A - - b
A
G A i-
- nn ii- 7
A 7 - - A ii-
A -
7 T
ii -
n -
n -
(continued)
Comparative Resistances of Materials of Construction TABLE 7.8: METAL, ELASTOMER AND PLASTIC P = PUMP MATERIALS-OBERDORFER METALS ELASTOMERS (continued) NON-METALLIC
863
-7
CODE LETTERS
A Acceptable Ouesbonable 0 Not Recommended N BLANK-No lniormatton

Sublecl lo plttmg when allowed to dry Sublecl to attack when hydrochloric acid IS present.
H 9
NAME OF LlljUlO
IIIbutyl
Ether
I I
I
I I
I
I
I
I I I I I I 1 [ I I [ I [ [ [ [ [ [ [ [ I C C C t C C C C C C C r IDlphenyl. Ether IDloctyl. Phthalate O~smleclant Deodorant I IAl
IAl IAlA I IAI I 1~1~1 I 1 I I I1 11 I I IAlA IQlAlAl
I I I I IAIAI 11 I I1 IAI 1 I I 11 1
I
I
IAI I I I I I
IAlA/
(continued)
URETHANE ZZ>P z ZD >POD?-P~x-I>~~P~P >x-PPP>Yax.IIZ * >?a zz x. D D P ETHYL BUTVL TEFLON NYLON NORVL POLYESTER 2-P >?a RVTON CHEMICALGRAOECARBON PROPVL.
3 %
BP
2-B
>
P ,k IT -5 F s
>
865
TABLE 7.8:
METAL,
ELASTOMER
(continued)
NAME LlfJJlO OF
I,,
,,,,,,,,
,,,,,
,n,
(continued)
866
TABLE 7.8: METAL,
ELASTOMER
(continued)
Acceptable a Ouesbonable N Not Recommended BLANK-No lnlormat1on

A
Sublecl to pitting when allowed to dry. Subject lo attack when hydrochloric acid IS present
f f f f f f f f f f f f f f f f f f f f f f f f F F F F F F F F F F F F F F F Fuel Oil Fwan. Furloran F.._.__..I A AAAAAPAA A A A A N A AAAAAA A ,+ 1 u 1 A 1 A d A A ~~LlllbULl3-l
(continued)
Comparative Resistances of Materials of Construction TABLE 7.8: METAL,

CODE LETTERS
867
ELASTOMER
AND
PLASTIC
PUMP
MATERIALS-OBERDORFER ELASTOMERS
(continued) NON-METALLIC
Acceptable a Ouestlonable N Not Recommended BLANK-No lnlormabon Subject to pittmg when allowed to dry. Subfect to attack when hydrochlortc acid is present.
x B z5
NAME OF LIQUIO
Alcohol f:urfuryl
( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( t t t t 1 t t t t t t t t t t t t t t H
H H
(continued)
868
TABLE
7.8:
METAL,
ELASTOMER
AN0
PLASTIC
PUMP
MATERIALS-OBERDORFER METALS
(continued)
CODE LETTERS Acceptable a Ouestronable N Not Recommended BLANK-No lnlormation Sublect lo prttmg when allowed to dry Subject to attack when hydrochlorrc acrd is present.
NON-METALLIC
x
B 5
&
NAME OF LIQUIO
Hvdrocarbons Liaht Hydro Drive MIH Lrght Hydro Drive (MlHlO and SO) Hydrogen Hydrogen Eromrde Hydrogen Chlonde tlvdroaen Peroxide Hvdroaen Peroxrde Hydrogen Peroxrde (10%) Hvdrogen Peroxrde (50%) Hvdroaen Sulohrde __ Hydrolube-Waler/Ethylene Glycol ifydroqumone lvdvne iyposulphrte Soda (Hype) ce Cream nk nsechctdes odme odme (In Alcohol for Plastics)
dnfnrm
El g % Li t s
z 3
a -
s
d
Y k+ bi b
L >
2 I3
E
9 -
ii -
Cold Hot
x T ii -iiii 7 - Ti 7 - - - -
z -
s n -
2 -
5 Li Y % I
2 -
zE
-
x r A T -
Ti T
ii-
A A - -
Cold
A Ii -ii I- ii Yi ii T ii -
iT 7 0 K
ron Sulohate sotane so-Butane so-Butvl Alcohol so-Butyl Methyl Ketone so-Butyl N-Butyrate so-Butvlene so-Butyraldehyde so-Octane so-Pentane soPropyl Alcohol so-Propyl Benzene soPropyl Ethers so-Butvl Alcohol sododecane sophorone (Ketone) sopropanol sopropyl Alcohol sopropyl Chlorrde sopropyl Ether cntnr Jet Fuel (JPI - JF6)
a ii ii -
ii .N -
n ii -
s i i i i ii i i r 4 1 4 1 u i
A ii iFi iT -
7 A A -
A 7i -
r r - - - - ii- A n- - - - -
i\- PI/( I A - I - A i/C A - ii iPi/C I
0 -
xn iia a
9
a- - ii z
j_ - - -
A - - - -
A 7 - - -
- - A A A A -
A - - 7 A - -
n -
A -
$
a
A i- A - a - Ti- ir
- A - -
- - - i- /
- - - - -
A ii -
r n i-
n -
s i-
Li
(continued)
Comparative
Resistances
of Materials
of Construction
869
TABLE
7.8:
METAL,
CODE LETTERS
ELASTOMER
AND
PLASTIC
PUMP
MATERIALS-OBERDORFER ELASTOMERS
l-
Acceptable a Oueshonable N Not Recommended BLANK-No lnformatron Subpxl Sublecl to prlhng when allowed to dry to attack when hydrochlorrc acrd IS present
- METALS
2
d
R E
H
NAME OF Ll@JlO
1 0 Auto Transmwon 1 0 T. 33 Oil 1. I. Case No. 144 011 cerosene kerosene 8 Naphlha {etones (eyslone No 87 HX Grease (eyslone Penelralmg 011 teyslone Vetostan .aquers .ard .arvacrde .alex .avender 011 .ead .ead Acetate .ead Nrtrate .ead Sullamale .emon 011 .rgnm Lrquor .rme .rme Bleach .rme Sulphur .rme Waler .mdol .mseed 011 .rquld Petroleum Gas (LPG) .rquor Lame .rquor Cold Flurd -
2 f
3 < -
9 2 n -
ii
P 8 ki -
z
I
El
5 -
2 A 7 -
* ?
0. -
n n
A Yi
T -
Hd ii Yi
Fs A - - - -
T -
T
-IiA
T A 7 A A T T Yi + - A - n A - - - - r - ii -
7 0
7-i T -
n A A -
n n
T
A -
ni - ii
-ii-
T 7-i - N -
7 A 7 A - A -
$
T
A A
0 T T Tii -
7 7 - - -
- Pulp Mdl
.rquor Sleep .rquor Sulphate .rthum Bromrde .rlhrum Chlorrde .rlhrum Hydroxrde .ube 011SAE 10,20.33 .ubncabng OrIs .ye. Caustic (34%) .y?.ol dagnesium Acetate lagnesrum Carbonate lagnesrum Chlorrde (5%) nagnesrum Chlorrde (5%) Cold Hot
A
HOI
an
n
TT 7 Yi
n ii A -
iiz r -
/ ,
Elc
Eorlmg
T n T A - - N
5; Li-
0 -
n - - a i- -
n T A -
ii i -
iL
I I
(continued)
870
Corrosion
Resistant
Materials
Handbook
TABLE 7.8:
METAL,
ELASTOMER
AND
PLASTIC
PUMP
MATERIALS-OBERDORFER LA
IS
(continued)
CODE LETTERS A Acceptable a Questronable N Not Recommended BLANK-No lntormation Sublect to prttmg when allowed to dry Sublect to attack when hydrochlorrc acid IS present
-n
iii ii
ii
T
G
25
NAME OF LIQIJIO
2 z i z f g
z
%
9
Wagnewm
Nrtrate Hot
Waonesrum Oxrde Wagnesrum Sulphate (5%) Wagnesrum Sulphite 8 Sulphate Walathon Sprav (50%) Waletc Anhvdrlde Waleic Hydroxrde Walt Beverages Wanoanese Carbonate Wanganese Chlorrde (5001.) Wanganese Nrtrate Warsh Gas Wash Wassey Ferguson Hyd 011 Wavonnarse Wedwm Synthehc 011A Walamme Resms Wercaptans Wercwc ftichlorrde Wercuric Chlonde tiercurrc Cyamde Uercurous Nrtrate Mercury tierwry Salts tiesrtvl Oxrde Metahcotl A165 Methanol Methyl Acetate dethvl Acrvlate dethyl Alcohol dethyl Bromrde dethvl Eutvl Ketone dethyl Cellosolve tiethyl Chloride vlethvl Chlorosllanes dethyl Cyclopentane dethyl Ether vlethvi Ethvl Ketone vllethyl Ethyl Ketone Peroxrde dethyl Formate dethyl lsobutyl Ketone vlethyl isopropyl Ketone dethyl Methacrylate dethyl Oleate A A A
N N A
7i -
2 ii -
s 8 s
T T
7
ii
1
L
2 8
E
9 L -
i? F
z
Li
-ii 5 - -
x T -
2 -
H2 E
T K i- 7 n - - A iT A A - - - _ - - - A - - - + - - + + A -
e e %
i?
n n _ -
--I-
n T _ -
Boiling
n T -
n - 5; -
N N
N
N _
n T 0 0 -
- - - - - nA h -
( 07%)
N N
-iT ?3 - T T ii -K ii A A
A a- 4 -
=F
0 Ti-
n s - -
T A - n -
T T iT
A A
+-
T T - - n 7 -ii i - - - A - T -
n n - -
nn
A -
- - ii- - n - - n - n - i- -
$
A 0 A A A
a -
Ti ii -
+ A A
+
A A
iii
n -
n na - i;
A 4 n i- - -
a - i - AL - - - - - - -
+ A 1 +
ir
0 -
nr n - - A u L nr - - A -
4 4 i-
5
A A
* 1
(continued)
Comparative
Resistances
of Materials
of Construction
871
TABLE 7.8: METAL,
ELASTOMER
(continued)
NAME LIIJIIO OF
Ickel Chloride lckel Ndrate tckel Plalmg (10%) Solution
Cold Cold
A A
A A
(1
A A A A
A A
A A
(continued)
872
Corrosion
Resistant
Materials
Handbook
TABLE 7.8:
METAL,
ELASTOMER
(continued)
Acceptable Questmnable 0 Not Recommended N BLANK-No lnformatlon

A
11,Peanut
I I
iAlA
II,Pella
/AiAlAl iNlAlAl 1 IAlA lNlAiAl I I . I . I1 . I I
I I I
I I I
IAl I I
I I
I I
(continued)
Comparative
Resistances
of Materials
of Construction
873
TABLE 7.8:
METAL,
ELASTOMER
(continued)
Acceptable 0 Ouestmnable N Not Recommended BLANK-No informalloo

A
NAME LIQUID OF
( ( ( ( ( ( ( ( ( ( ( ( ( ( (
( (
( ( ( (
(
( ( ( ( ( ( (
(
( ( f f f f f f f f f farker O-Lube feanuf 011 f I
I
IAlA
I I
I I
IAI
I
I
I I
I I
I
I I
_.
111111111*1111111111
[AlAi Ai
lNlA/Al
1 iAI 1
1 I
(continued)
874
Corrosion
Resistant
Materials
Handbook
TABLE
7.8:
METAL,
COOELETTEAS
ELASTOMER
AND
PLASTIC
PUMP
MATERIALS-OBERDORFER METALS -
(continued)
A Acceplable a Ouestmnabfe N Not Recommended BLANK-No lnlormatlon Sublecl to plltmg when allowed to dry. Subfect to attack when hydrochloric acid IS present.
NON-METALLIC
; ?
a:
NAME OF LlljUlO
enctllm. enolalube enola Llrws eppermmt 011
emI
Llquld
w E z -
Cola Phenol
entachforo entasol
sz - - - T - n- - - - n n
A
Hd 2 2 t 2 z a ::
T - T -i n- .7
z 2
w ti :
w
s z s 8 1 5
Y 2 ii -
z
I
B %
L -
;-i SJ
5 5
7 T ii A - - -
- - -
Whloroethvlene etrolatum etroleum Ether henol (Carbohc Actd) henol. Formafdehvde MIX henohc Resms henyl Benzene henyf Ethyl Ether henyf Hydrazme henyf Benzene henvl Cellosolve hasphate Esters hosphorlc AnhydrIde (Dry) hosohorous Trlchlorlde htographlc Developer hthahc AnhydrIde Icklma Sofubon lcofme Alpha llP I-Ill .__.. Ine Tar 011 Inene Ipefme Cleaner lashcizer olydetm Moisturizer Lohon ofyvmyl Acetate ofyvmyf Acetate Emulsion ostage Meter Ink olaswm otaswm otaswm Acetate Elchromale Bicarbonate Cold Cold Cold Cold Cold
_ -
n
7 -
n -
n n - A - _ -ir 0 n
7
n 0 -
Ji ii _ -
a -
n _ _ A _ -
2 _ _ 4 4 h T-
%
z _ -
ii-
x GE - - - - - _ - - T -
ZJ Y
a 7i - - - - _ - - - - 77 i7 - - - 77 0 - - -
(1 _ -
T -. i -
n n a ii
n -
A _ i1 i. 4 -
ii- -A - -
A
A K A 0 A n A n 0
n 4 ii- 4
A ii- i- - - ii-
a
A -
T7 A A
n 7 -
A -
ic A
A ii
-rA -
Yi -_ -
cr s n - ;; - n- A nn4 K ii- b - - A 7 -
i0 A A s - 4 i7 --
a -
r s
otasslum Ffromlde otasswm Carbonate olassium Chlorate otassium Chloride olassIum Chromate otassmm Cupro Cyamde
a
0
A ii
0 Yi Yi- - 0 7; - - n 7 -
n -
ii A A A ii
n -
r ii
A
4 i-
n n a n -
L -
_ 4
; + -
4 4 -
(continued)
Comparative Resistances of Materials of Construction TABLE 7.8: METAL,

CODELETTERS Acceptable a Oueshonable N Not Recommended BLANK-No lnformahon Subject lo pltlmg when allowed to dry. Subfecl lo attack when hydrochlorcc acid IS present A
875
ELASTOMER
AND
PLASTIC
PUMP
MATERIALS-OBERDORFER -I
(continued)
?I s 3
2
- NON-METALLIC - -
; y? 8
kd
NAME OF LIQUIO
otassium Cvamde otaswm Dlchromate Cold olasswm Ferrlcyamde otasswm Hvdrate otasswm Hydroxtde (5%) otaswm Wassum Hydroxide (50%) Hvoochlarlte Cold otassum Hvdroxlde 150%) otassium lodlde otasswm Ndrate otasswm Oxalate otasswm Perlluoroacetate otasswm Permanganate otasswm Phosohate otassium Sihcate otaswm Sulphate (5%) Cold Hot otassum Sulphate (5%) otasswm Sulphlte restone RL 3161 011 RL High Temp Hyd 011 toducer Gas topane rooone Proflomtrde ropanol roplon-Aldehvde roovl Acetate I-Propyl Acetone ropyl Alcohol ropyl Ndrate roovlene ropylene Chlorohydrm topylene Dxhloride ropylene Glycol vrldme ub Coloone ulp Stock urelube Motor 011s uritan Motor 011 ydravls yrolube umme Bwlphate (Dry)
c B
E
2
Ll
fl
32g z
F T ii n ii n Yi - z- - - 0 -
zi L F ii x
22 5 z
zz ; E
1
2
3
E
I
g >
G
-
z n n Ji ii A
1 / /
r
A iK A -
Hot
HOI
Boilmg
is 0 ij- T ii- a - - -
A ii- Ti
2 -
i=
E 2 Y % * B G z z
9 L
ir n A-
Yi Fi ii- n - - ii-
I , , ,
I i I I i
Yi
n n - - - - 0 7 - i- 7 0 i - - n - 0 7 ii n A
0 A - - _ _ A - - -
n -
-r
n n
K
A -
T A
A
iF A - - -
z n n T A A 7 A - n A n ii A z -
n n ic iin -N n - - -
, 1 ,
1 I
ii _
A -
A i_4 i-
n iizin ii0 ii -
nA - - - - - i - - - i- A
n ii 4 -
A A n c A -
I I I
ir - - - a - - - - - - - u
b _ _ 1
i r r j_ -
I I I /
ii ii4 iii i4
I I
h P h
umme Sulphate (Dry)
Ir K - - - i - 1 ii i - h -. - - -
P P P
1
v
-
4 1 K 4 K b 1 n 4 A 4 - - i - - - ii - 4 - - - - - - - - - - - - - i - - r ii u - i - - - r - - i- - - 4 1 i- i - - - i i- i - a - i - - - i - r 1 - - - \ - L
- 4 - h - s -
A i-
n -
A A - -
I I
ar a - - - - -
/ i / i
A A
cA
L , L
4 E
I
-I
LA \ A
I +
A
It
(continued)
876
Corrosion Resistant Materials Handbook AND PLASTIC PUMP MATERIALS-OBERDORFER METALS 1 ELASTOMERS (continued) NON-ME
l-
TABLE 7.8:
METAL,
ELASTOMER
COOE LETTERS A Acceptable 0 Oueshonable N Not Recommended BLANK-No lnformatlon Subject to plttmy when allowed to dry Subject to attack when hydrochloric acid IS present
il x
4
25
Y Y % %
El
5 ::
I I
NAME OF LIIJJIO
?apeseed Oil Red Gage 011 Resm Solvent Rose 011 Rosm Rum Rust lnhlbltors Salad Oressmg Sal Ammomac Salt Brme (Sat Salt Cake Salt Solutlon Salt Water jamhzers Sea Water Sesame Seed 011 Sewaoe Shave Cream Shell Alvama Grease No 2 Shell Tellus No 27 Sdica Gel 3hcate Esters 3lhcone X527 3hcone Tettachlorlde SIllcone 011s 3dver Bromide 3lver Chloride Sdver Cyamde Sdver Ndrale 3lver Salts Filrmg Starch Skellv Solvent 6. C. E
jkvdrol 500 41
4 iz E2
h -
z if B
s 5
2 E E
It
A
ii ii ii -
ix 0 T Al A
- - - - - - ii- a ii - i si-i; - - - a - - - - - 1
i n i
T _A
4 i i
i -
*A
A
8 7KYl Cold
soap Soluttions jocony ALHO No 1 joconv 60195 jocony Auto. Transmtssion Flwd jocony Delvac jocony M-4731-A jocony Mobil Type A jocony XRP 226A jocony XPP 227A jocony RL-362A Shock
I
A A A A A A A A A A N A N N N
T -ii T 0
A +
a
n
T T
i i i i -
ir -
n
n
n T T -
i A i-i i i 4 i s 4 i 4 4 -
n A -
i i i i 4 -
r i /
z n n
A
Ii-
0 ii 0 0 0 ii 0
0 ii
A -
n- h - - - - - - - -
K -
(continued)
877
TABLE 7.8:
METAL,
ELASTOMER
(continued)
NAME LIIJUIO OF
(continued)
878
Corrosion
Resistant
Materials
Handbook
TABLE 7.8:
METAL,
ELASTOMER
(continued)
Acceptable a Ouesbonable N Not Recommended BLANK-No informalloo

A
NAME LIIJUIO OF
Sulphur (Wet) Sulphur Oloxlde (Dry) Sulphonaled Fatty Alcohols A A A
A N A 0 A
A A A A
A A
II A
A A/O
(continued)
Comparative
of Construction
879
TABLE
7.8:
METAL,
ELASTOMER
AND
PLASTIC
PUMP
MATERIALS-OBERDORFER METALS ELASTOMERS -
CODE LETTERS A 0 N Acceptable Questranable
Not Recommended BLANK-No Informalron Subtect Subject to prttmg to attack when when allowed to dry hydrochlorrc acid
IS present
E NAME OF Ll(Wl
iulohonated iulohurrc iunoco ;unoco Veoetable Anhvdrrde SAE 10 No 3661 Grease 011s Cold
B
2
~unoco All Puroose #per Shell ,yrrthehc Gas
Detergent
t
ale Slurry all 011 allow annm annmg annmg ar ectyl eeool 502 Lrquors 011
$
A 0
s- 3
A
2 1 L -
n T
A A A
2 -
IA A
T T
A
n n n -
r-
eresso ertrary erharv ertrary
011 No 47 Butyl Butvl Eutyl Alcohol Catechol Mercaptan
etra Bromethane etra Rutvl Trtanate
T + + _ * / +
1 s
A A A A A
I /
I I i I i I /
5 z92 - - - - - - - - - - - - - - - - - - -
etrachloroethane etraethyl Lead
etrahvdroturan
(RO) Startak No 2
A A 0
exaco exaco exaco
Capella
6 8 0
Regal A&B
3450 Gear 011
$
/ , / , t
A A A I I h
E /! E P
h - -
n 1 -
b 7
_ -
z - * A
I
I
P P P P P
i- -
r *
1 1
i-
a
A
ntonyl
Chlorrde 011 Eteedol Mulh. Gear 140
ide Water in Salts rtamum oluene oluene
A -
t t
1
(continued)
Tetrachlorrde
Ortsocvamde
IF-
A -
c
(
(A
I I
I I
& I IA,
880
Corrosion
Resistant
Materials
Handbook
TABLE 7.8: METAL,
ELASTOMER
(continued)
NAME LIQIJIO OF
Vershbe F-50 Vfnegar
I
1
cold
~~~o~o~o[A[AIA~o~~INI
I I IllI III I
Ii
I
I
IAIAIAIAIAIAI III III
(continued)
Comparative
Resistances
of Materials
of Construction
881
TABLE
7.8:
METAL,
CODE LEllERS
ELASTOMER
AND
PLASTIC
PUMP
MATERIALS-OBERDORFER METALS ELASTOMERS -
(continued)
A Acceptable 0 Ouesbonable N Not Recommended BLANK-No lniormatlon Sublect to plttmg when allowed to dry Sublect to attack when hydrochlor!c acid IS present
NON-METALLIC
NAME OF UOUIO
t5 Y 5 k E 2i 1 z
z
Eh
5 3 I
2
0 %
2
I
53
z -
% i -
lmvlideoe Chloride lttrlol Oil Vater - Oelomred Vater lo 180F - lap Vater. Bodmg Vater Boder Cold N A A ?+ A A Cold Cold A 0 A 0 A A A A A N A A N A 0 A 0 A A A A A A A A A A A -_A A A/O A A A A A A A eohte mc Acetate mc Ammomum Chloride mc Chloride mc Chloride mc Cyamde mc Hydrosulflle mc Nltrate mc Phosphate Solubon mc Salts mc Sulphate (25%) mc Sulphale (Saturated) 0 N A A A N A A Cold Bollmg 0 0 0 N
ir 7 ii n - A _ -
T ii G 7 iT
vatnr lllsllllsd
Vater. Mme Vater, Salt Vater Sea Vater wth Soluable 011 Veed Killers Vemco C Vhlskey 8 Wmes Vhlte Gas Vhde Lmuor :ylene yhdenes - Mixed Aromahc Ammes .yl0l
T 7
n ij-
n ii-
a
a
4
c
h iii1 -
n -
n
A A
T - A - n G ;iA n is r A n -
n -
s i4 i-
$ sA A n
I
n n
i A -
t/I 1 A
-L9
_ A n -
/4
b 1 i\ _ _
z
4
i- N -
r 3 L -
A r- h/O- r- iiiii -
E
,4
A s -
(I
(I
a -
$
4 4 I 4
882
Corrosion
Resistant
Materials
Handbook
TABLE 7.9:
GLASS, METAL AND PLASTIC PIPING SYSTEMS-0-I,BCHOTT
PROCESS SYSTEMS
Chemical Resistance of Corrosion-Resistant Piping Systems

Ylaximum Opwatin~ Tampentura
MATERIALS A-Very Good Service 8-Moderale Service C-Limoted 0, Varlablc F-lJnsat,slaclo,y Blank-No lnlormal~on MATERIALS 4-Very Good Service B-Moderate Scrvlce Z-Limited o, Variable F-Unsatisfactory Blank-No Information To
2, P
Service
Service
cd 1 m ny ; = g- 22 d m:u ip $_ g
3 & s .u $
CHEMICALS Salads assumed an solu11on.
:HLMICALS hlids assumed in solution.
Zz=;% z-.,; z, mf 5 2 R B E r, #-
e
*Data represented IS to be used as a guide only. For speclhc ~nlormatlon. lest under actual operatang condltoonr.
z
9 ;
5
F C C A
4 A
Data represented IS to be used as a wade only. For spechc mtormat~cn. test rnde, actual operatang conddvans.
.;Lsg -I% D
ACETIC ACID. 100%. CHI COOH ACETIC ACID. Dilute 50% ACETIC ANHYDRIDE, (CHJ CO)?0 ACETONE, CHJ COCHI ACETYL CHLORIDE. CHJ COCI ALUMINUM CHLORIDE, AlCh ALUMINUM HYDROXIDE. Al (OH)3 ALUMINUM SULFATE. Al? (SO,), ALUMS, CONC., AI:(SO,)I - Kt SO,. etc. ALUMS. DILUTE AMINES. var,os AMMONIA (Gas), Moist. NH3 AMMONIUM AMMONIUM AMMONIUM AMMONIUM AMMONIUM AMMONIUM AMMONIUM AMMONIUM CARBONATE, (NH,)? CO1 CHLORIDE. NH, Cl HYDROXIDE. NH, OH NITRATE. NH, NO3 PERSULFATE, PHOSPHATE, PHOSPHATE, PHOSPHATE, (NH,)? S? 0, (NH&Hz PO< (NH&H PO4 (NH,)JPOI
AA A A
z: A A A A
A A A A
It t A
A
A A A
CHLORINE (Dry), Cl? CHLORINE (Wet). Cl? CHLOROBENZENE. Cs l-lb Cl CHLOROFORM, CHCIJ CHROMIC ACID, Cr 03 soln COPPER CHLORIDE, Cu Cl? COPPER CYANIDE, Cu(CN)z COPPER NITRATE Cu (NO& COPPER SULFATE Cu SO, CRESYLIC ACID DICHLORETHANE. Cq H, Clr DIETHYLAMINE, (&-ii,); NH DIPHENYL. CrH&Hh ETHERS, Various ETHYL ACETATE. C- HI_COOCHz _ ETHYL ALCOHOL, CvHbOH ETHYL CHLORIDE, CI Hj Cl ETHYLENE CHLOROHYDRIN, Cl (C? H,)OH ETHYLENE DICHLORIDE, C?H, Cl? ETHYLENE GLYCOL. CH, OHCH:! OH ETHYLENE OXIDE, CH$ OCH: FATTY ACIDS, Various FERRIC CHLORIDE, F&l:, FERRIC NITRATE, Fe(NO:JI FERRIC SULFATE, Fe: (SO,), FERROUS CHLORIDE, Fe Cl: FERROUS SULFATE, FeSO, FLUORINE, Fj FORMALDEHYDE. CH.>O 37% FORMIC ACID, HCOOti FUEL OIL GALLIC ACID, (OH)3 CsHjCOOH GASOLINE, Refmed GLYCEROL, CHr OH.CHOH CHi OH HYDROBROMIC ACID, HBr HYDROCHLORIC ACID, (Cont.). HCI HYDROCHLORIC ACID, (Dtilute) HYDROCHLORIC (Dry Gas) HYDROCYANIC ACID, (Cont.), HCN HYDROCYANIC ACID (011. and Gas) HYDROFLUORIC ACID, (Cow.). HF HYDROFLUORIC ACID, (Dilute) HYDROFLUOSILICIC ACID, H.ISIF~
ABBA A C f ABBA A B.F A B F A F F ABBA A A A
A A A A A
lAlA\AlA
A A A A
A A A A A A A A A I A IA
8 A A
A A A A B A A F
A A A P A A i P P :
I AABA I I I
IAIAIBIA
A z A A F
A A
AMMONIUM SULFATE. (NH&SO, AMYL ACETATE, CbH,,COOC& AMYL ALCOHOL. CSHIIOH AMYL CHLORIDE. CsHilCl ANTIMONY TRICHLORIDE, SbCh ARSENIC ACID, HAS 03 BARIUM CARBONATE, BaCOx BARIUM HYDROXIDE, Ba(OH)l BARIUM SULFIDE, BaS BENZALDEHYDE. CaHs CHO BENZENE, Cs Hs BENZOIC ACID, Cs Hs COOH BORAX, Na&l,Oi BORIC ACID, HJBOI BROMINE, Wet, Br? BUTANOL. C,HUOH BUTYL ACETATE. C.H&OOCHz BUTYRIC ACID, CJ H7 COOH CALCIUM BISULFATE. CaHSO, CALCIUM BISULFITE. Ca HSOs CALCIUM CALCIUM CALCIUM CALCIUM CARBONATE, CaCO.1 CHLORATE. CaClOr CHLORIDE, CaCI,! HYDROXIDE. Ca (OH):!
AAFA A A A A A B B A A I B I C IA
A A A A A
A A A A A
A A A A A L : P A A
A :
;: A A
CALCIUM HYPOCHLORITE, Ca (OCI)? CALCIUM SULFATE, Ca SO, CARBON DIOXIDE (Dry), CO?
CARBON DIOXIDE (Wet or H, COJ)
: A A
HYDROGEN PERbXlDE
(Cont.),
H, Oz
CARBON DISULFIOE. CS:! CARBON TETRACHLORIDE (hlolst) CHLORACETIC ACID, CICHzCOzH CHLORIC ACID, HCLOJ
KIMAXII the reglrtared
trade mark
Ccl.
: A A
Inc.
of
Owens-llllnolr,
(continued)
Comparative
Resistances
of Materials
of Construction
883
TABLE 7.9:
GLASS, METAL AND PLASTIC PIPING SYSTEMS-0-I/SCHOTT
PROCESS SYSTEMS (contd)
Maximum Operating Temperaturs

MATCRIALS A-Very Good Service B-Moderale Service C-Ltmlled or Varaable F--U~S~llSl~ClO~y Blank-No lnlormal~on
Servxe
B-Moderale C-L~mlted
Service or Variable
Service
F-Unsatislactory Blank-No lnlorn
tion
CHEMICALS Soltds assumed in solubon
CHEMICALS
Solids assumed in solution.
*Data represented 15 to be used as a gutide only. For specli~c Inlormabon. test under actual operatmg cod,t,ons.
*Data represented is to be used as a guide only. For SPSCI~IC mformabon. test under actual operating condibons.
zp 2 5 !z 2% =a 25: clo,%:E
A A A ABBAE A A 0 AAACf A A
L
IODOFORM. CHIJ KEROSENE KETONES, Various LACTIC ACID, CHJ CHOHCOOH LEAD ACETATE. Pb(CHa COO)2 MAGNESIUM CHLORIDE, Mg Cl;! MAGNESIUM HYDROXIDE, Mg (OH)? MAGNESIUM SULFATE, Mg SO, MALEIC ACID, CO! H C? Hz CO2 H MALIC ACID, CO? H CHr CHOH CO2 H MERCURIC CHLORIDE, Hg, Cl% MERCURY, Hg METHANOL, Cow., CHIOH METHANOL [Dilute\ METHYL CHLORIDE, CH3 Cl NAPHTHA, Petroleum NICKEL CHLORIDE. Ni Cln NICKEL SULFATE, Ni SOI NITRATING ACID (>15% HnSOd) NITRATING ACID (<15qr, Hz SO,) NITRATING ACID (<15% HN03) NITRATING ACID i<l% Acld1 NITRIC ACID, Conk. HriOa NITRIC ACID, Dilute NITROBENZENE. Ca N$ ~0~ NITROUS ACID, HNO! OLEIC ACID, CI Hi7 CH:CH(CH2),C02H OXALIC ACID, CO2 H CO2 H PERCHLORIC ACID PHENOL (Cont.) Cs PHOSPHORIC ACID PHOSPHORIC ACID 70% H5 OH (100%). HJPO, (>45% Hot) Cold) Cold)
POTASSIUM SULFIDE. Kz S PYROGALLOL. Cc Hs (OH)3 SILVER NITRATE. Ag NOa SODIUM. Molten 210-4OOF.
/ E
1 4 4 4 ; i
P :: P A
: A
I A
Ii : A : A
F A
A A A
i A A A A WDIUM SULFIDE. Na& SODIUM SULFITE: Na;SO, STANNIC CHLORIDE. Sn Cl, STANNOUS CHLORIDE. Sn Cl. STEARIC ACID. CH, (CHz),( COOH IFI F A A A A
: i \
A A A -
PHOSPHORIC ACID (>45% PHOSPHORIC ACID (<45% PHOSPHORIC ANHYDRIDE, Dry or Moist
zEE~~o:pI;2;~98%) SULFURIC ACID (Fuming to
liji
:: A A :: A :: 2
PHOSPHORIC ANHYDRIDE, Molten, PzOs PHTHALIC ANHYDRIDE. Cs H, (CO)2 0 PICRIC ACID, Soln.. HO.& Hf (NO& POTASSIUM BROMIDE, KBr POTASSIUM CARBONATE, K* CO3 POTASSIUM CHLORATE, KCIOJ POTASSIUM CHLORIDE. KCI POTASSIUM POTASSIUM POTASSIUM K,Fe(CN)s POTASSIUM POTASSIUM POTASSIUM POTASSIUM m KIMAXIs tha CYANIDE, KCN DICHROMATE. K2 Crt 0, FERROCYANIDE. HYDROXIDE, KOH NITRATE, KNOJ PERMANGANATE. KMnO, SULFATE, Kz SO,
registered trade mark 0, Owens-llllno~r, Inc.
~z&i,?L~Iji
TRICHLORETHYLENSE. Dry, Cl2. C. CHCI t A
A A
A A
884
Corrosion
Resistant
Materials
Handbook
TABLE
7.10:
NATURAL
AND
SYNTHETIC
FIBERS,
POROUS
STONE
OR POROUS
CARBON
FILTER
TUBE
MATERIALS-SETHCO Sethco filter tubes are fabricated of natural or synthetic fiber wound over a perforated plastic or metal core. The precision winding pattern covers the entire depth of the filter tube with hundreds of funnel shaped tunnels which become gradually finer from the outer surface to the center of the tube and trap progressively finer particles as the fluid travels to the center. This allows much greater solids retention capacity than is associated with surface filter media of the same dimensions. Types of Filter Tubes and Supporting Cores: Cotton, Dynel, polypropylene, acetate, porous stone or porous carbon filter tubes are available. Supporting perforated cores for cotton, Dyne1 or polypropylene are stainless steel, polypropylene or steel. Supporting cores for acetate tubes are tin plated copper with voile liner. Porous stone and porous carbon filter tubes do not require supporting cores. Stainless steel cores are recommended for mildly acid and all alkaline solutions, pH 4 to 14. Polypropylene cores are used where all metal contact must be eliminated or where stainless steel is attacked, such as high chloride and sulfuric acid solutions. It is recommended for all acid and alkaline solutions, pH 0 to 14. Two types of polypropylene cores are available: mesh polypropylene and rigid perforated polypropylene. The mesh type of polypropylene is satisfactory for temperatures below 140F. The more expensive rigid polypropylene cores are used for temperature applications over 140F, and for double and triple tiered filter chambers because their greater strength is needed here. Perforated steel cores are used for dilute alkaline solutions, solvents, lacquers, oils, emulsions, etc. Filter Tube Selection: Cotton filter tubes are recommended for moderately acid and alkaline solutions in the pH range of 3 to 11. Polypropylene, Dyne1 and porous carbon filter tubes are recommended for concentrated acid and alkaline solutions and for all fluoborate solutions over the entire pH range of 0 to 14. Polypropylene filter tubes are also recommended for electropolishing solutions, as well as certain other highly corrosive solutions. Porous stone filter tubes are recommended for concentrated acid solutions. Acetate filter tubes are recommended for water. Sethco filter tubes are available in densities to filter out particles from 150 down to 1 micron.
FILTER ACID TYPE ,ROBORITES, ACID TYPE ,NOT ~LUOBORATES,
TUBE
Yatrriaf/Cor*
CHEMICALS
FILTER
TUBE
M~teri~f/Cor~
Copper. Lead, Iron,
Tin
Polypropylene/PP or Dynel/PP Poilypropylene or Cotton/PP Polypropylene/PP or Oynel/PP Polyprapylene/PPor OynellPP Polypropylene/PP or Ovnel/PP Polypropyl&re/Rigid PP or Porous Stone PolypropylenejPP or Dynel/PP Polypropylene/PP or Cotton/PP Polypropylene/PP or Cotton/PP Polypropyfene/PP or Cotton/PP Polypropylene/PP or Cotton/PP Cotton/SS Cotton / SS. PolypropylenelPP or DyneljPP cotton/ss or Polypropylene/PP
ACIDS
Acetic-Dilute Acetic-Concentrated Boric Acid Chromic Acid, Hydrochloric, Nitrrc, Phosphoric, and Sulfuric Hydrofluoric. Fluoboric Acids
Copper, Tin and Zinc-Less than 6 m/gal sulfuric Copper, Tin and Zinc-Over 6 w/gal sulfuric acid Chromium Gold. Indium. Rhodum, Palladium Iron Chloride (190F) Nickel (Woods) Nickel (Wattts type & Bright) Nickel (Hi-chloride) Nrckel Sulfamate Electrotype Copper and Nickel
Cotton/SS or Polypropylene/PP PolypropylenelPP or Oynel/PP Cotton/SS or PolypropylenefPP PolypropylenelPP, DynelIPP or Porous Stonet PolypropylenelPP or OynellPP
ALKALIES
Sodium or Potassium Hydroxide Ammonium HydroxideDilute Ammonium HydroxideConcentrated
Polypropylene/PP CottanlSS or Palypropylene/PP Polypropylene/ PP or Oynel/PP
CHEMICALS. MISC
ALKALINE
TYPE
Tm (stannate) Brass*, Cadmum, Copper. Zmc Gold, Indium. Platinum.
ALKALINE CYANIDE TYPE
Pharmaceutical Photographic
solutions solutions
Silver
PYROPHOSPHATE ELECTROLESS
TYPE TYPE
Copper, Iron, Tin, etc.

t&eke1 Plating, Solutions Below 140F: Above 140F: Copper Below 140 F: Above 140F:
c0tt00fss or Cotton/PP
Polypropylene/PP Cotton/SS or Cotton/PP
Polypropylene/RPP cotton/ss Polypropylene/PP Polypropylene/ RPP or OR6ANlC LIQUIDS
Radioactive solutions Ultrasonic cleaning solutions Nickel Acetate Food Products 190F
c0n0n/ss, PolypropylenelPP or Porous Slonet Porous Stone or PolypropyleneiPP cottan/ss, Polypropylene/PP or Porous Stonet CottonlSS or Polypropylene/PP Cotton/SS or Porous Stonet Cotton Special B
Compound/SV Cotton/SS Cotton / SS or Polypropylene / PP Cotton/Steel or SS
CottonjSteel Cotton/Steel Cotton/Steel Cotton/Steel Cotton/Steel Cotton/ or or or or SS SS SS SS
Carbon Tetrachloride Oichlorethylene Hydraulic Fluids Lacquers Perchlorethylene or Trich!orethylene Solvents Fuel Oil, Diesel. Kerosene. Gasoline, Lube Oil
or SS
PETROLEUM
PRODUCTS
Steel or SS
*When ttorous
operated as hi-speed baths at high temperatures (above Stone is recommended for all acids except hydrofluoric
14OF) or with and fluoboric.
high
alkali
content,
use PolVProPVlene/PPor
DVnel/PP.
Comparative
Resistances
of Materials
of Construction
885
TABLE 7.11:
RESIN, STEEL, ALLOY, TITANIUM, PUMP AND FILTRATION
CERAMIC, RUBBER, NATURAL SYSTEM MATERIALS-SETHCO
AND SYNTHETIC
FIBER
Plating Solutions
PLATING SOLUTION
ANTIMONY ARSENIC BRASS
TEMP.
130F 1loF 1001 F 110F RT 160F 100F 90F 100F 130F 95F 130F 115F 95F AT 12oF 120F 150F 180F 140F 140F 150F 75F 75F RT 190F 150F 150F 160F 145F 140F
A A A A A A A A A A A A A A A A A A A A 4 4 4 4 4 4 4 A A 4 A E E A A E A A A E E E E E P P E E E P E /1 E 1 / A A A J E I I E E E B E E B E B B B I3 B B B B A A E A B f3 E E 6 f3 E E E 4 4 4 4 A A A A A A A A A D D D D 0 A A A A A A A A A A A D A A A A A A A A A A E A A A A A A A A 4 4 4 4 4 4 4 4 4 E E E E E A A A A A A A A A A P P P P P P P P P P P P E /1 I I / t / / I 4 \ 4 4 4 : 4 4 4 4 4 4 4 4 4 A A E E A A E A A A E E E E E A A r-E r-E r-E A E A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A 4 4 4 4 4 4 4 \ 1 4 4 4 4 3 3 E 3 E D D A A A A F A D D D E D D E E E D D D D D F E A D D E D D A A A A A A A A A A B B B B B B B A, P, PL PL F P, c) c) 8I E I I2 eI E EI EI EI 1 C t1 EI E3 f f I4 f3 f3 I f3 f3 ,4 A P P P P P P P P AA. AA. A. 1 I I I I i I 1 1 , , I / / I I I < 4 4 4 4 4 4 4 4 E 4 3 D P, -D A E A A A A F A A A A A A A A E A E A A E A F E A E E A A E A A 0-D B-D E B-D / E B-D I B-E , E A B 0 A A A E B-C) E E B A B A A A A A A A E A E A A E P A P/ B E E P, PL E E
I4 14
A A A A A A A A B E E E E E A B A A A A E A A A A B A A B B A B A A B A E A A B B A A B
A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A P P P E P P P P P P P P
L i
0 E A E B E B 6 E E E E E E D E B B E B A f3 B A A E E E E E E E PL ) C 1 C P, P, E P, E E E ) C E E
P E E E E E E E I4 I4 I4 I4 I4 I4 I4 I4 f f I Ii IE E E E A A A A A A A A P A A A P P A A PL A A P E
E A A A P
A, A, AL Pi P, P4 /4 4 c EI b i EI Ef /4 I1 /4 I4 I\ I4 1 4 ,& 9 4 A A A A A A A A A A A A A A A A A A A A A A
Reqular Brass Bath

Hrah Speed Brass Bath
4 4 A
BRONZE
Copper-Cad. Bronze Bath Copper-Tin Bronze Bath CopperZn. Bronze Bath CADMIUM CYamde Bath Fluobonte Bath CHROMIUM Chromic-Sulfuric Bath Fluosilicate Bath Fluonde Bath Black Chrome Bath Barrel Chrome Bath COPPER fACIO1 Copper Sulfate Bath Copper Fluoborate Bath COPPER ICYANIDE Copper Strike Bath Rochelle Salt Bath Hugh Speed Bath COPPER fMISC.1 Copper Pvrophosphate Copper fElectroless1 GOLD Cyanrde Neutral Acid INOIUMSULFAMATE IRON Ferrous Chloride Bath Ferrous Sulfate Bath Ferrous Am.Sulfate Bath Sulfate-Chloride Bath Fluoborate Bath Sulfamate LEA0 FLUOBORATE NICKEL Watts TYpe Hugh Chloride Fluoborate Sullamate Electroless RHOOIUM SILVER TIN-FLUOBORATE
4 4 4 PI 4 A A A A A A A A A A A A A A P P P A P P P P P E 1 1 L ! / / I I I / / I I 4 4 4 4 4 1 1 1 1 1 4 4 4 4 4 4 A A A A A A A A A A A A A A A A PL PL PL PL PL P/ A PL PL II3 A
AL PL P, E E E E E f E E I4 I4 I4 I4 4 9 4 A IE IE E E E E E E A E E A E E A E E E E E A
A 1 B -1 E E E E E A B -I3 A B B PL E P6 P, /1 4 P, E eI EI 1 C EI- D i4 EI- D /4 EI E3. D I\ f f3 I4 f3..D f3..D I4 f3 f3..D
115.16OF 130.160F 100.17BF 100.140F 200F 120F BO-120F
TIN-LEAD ZINC
Aod Chloride Acrd Sulfate Bath Acid Fluoborate Bath Alkaline Cyanide Bath
100F 1OoF
140F 150F RT RT
I4 I A
SYMBOL
A - Excellent f3 - Good C - Good to 80F
D E Moderate (use Not
IDENTIFICATION
effect limited conditions)
F - Autocatalytic
X Unknown
under
recommended
(continued)
886
Corrosion
Resistant
Materials
Handbook
TABLE 7.11:
RESIN, STEEL, ALLOY, TITANIUM, CERAMIC, RUBBER, NATURAL AND SYNTHETIC PUMP AND FILTRATION SYSTEM MATERIALS-SETHCO (continued) Industrial Chemicals
FIBER
CHEMICAL
ACETALDEHYDE ACETIC ACID, 20% ACETIC ACID. 80% ACETIC ACID; GLACIAL ACETIC ANHYDRIDE ACETONE ALUMINUM CHLORIDE ALUMINUM FLUORIDE ALUMINUM SULFATE AMMONIA, 10% AMMONIUM CHLOAIOE AMMONIUM NITRATE AMMONIUM PERSULFATE AMMONIUM PHOSPHATE AMMONIUM SULFATE AMYL ACETATE AMYL ALCOHOL AMYL CHLORIDE ANILINE AClUA REGIA ARSENIC ACID BARIUM CHLORIDE BARIUM SULFATE BEER BENZALDEHYOE BENZENE 03ENZOLl BENZOIC ACID BORAX (SODIUM BORATE) BORIC ACID BROMINE WATER BUTY L ACETATE EUTY RIC ACIO CALCIUM BISULFITE CALCIUM CHLORIDE CALCIUM HYPOCHLORITE CALCIUM SULFATE CARBON TETRACHLORIOE CARBONIC ACID CHLOROACETIC ACID CHLORINE WATER CHLOROBENZENE CHLOROFORM CHLOROSULFONIC AC10 CHROMIC ACID. 10% CHROMIC ACID. 30% CHROMIC ACID, 50% CITRIC ACID COPPER CHLORIDE COPPER CYANIDE COPPER NITRATE COPPER SULFATE CRESYLIC AC10 ETHYL ACETATE ETHYL CHLORIOE ETHYLENE GLYCOL FATTY ACIDS FERRIC CHLORIDE
E E3 D E E E A A A A A A A A A E B E E E A A A A E E A A A C E D
i
El D D E E A A A A A A A A A E B E E E A A A A E E A A A C E D A A A A C A A A E E C A A E A A A A A B E E A A A
u
3 3 3 U B A B A C A A X B A C x c c E X A A A x c A A A C C B A A X A c B c X x C X D E E A A D A A x B C A A A
c
A B C A B A A A A A A A A A E x x c X A A A A c c A A A E E A A A A A c A 0 E c E E A-l A-l A-l A A A A A x C E A A A
X A
E 4 D E E E A A A A A A A A A E E E E E A A A A E E C X A X x D X A A A X A E X E E E A A D A A A A A X E E A D A
x
A A A D D A A A A A A A A A A A A A C A A A A c C A A A A c A A A A A A A A A A A E A A A A A A A A A C A A A A
A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A
4 4 A A D A D C D A D A C A B A A C A E X c B A A A B A A E B B 8 C D B B B E E A A D B B c B B A A B A B A B A E
A A A A C A D D B A C A B A A A A A A E B B B A A A B A A E B A B A D B B A X B A A 0 A A a A B A A A A B A P P E
4 4 4 4 \ 4 4 3 1 4 4 3 3 4 1 4 4 4 4 .E I( 4 4 4 4 4 A 4 A A A A A A B A A A A B A A A A A A A A A A A A B B A A -t
4 , \ \ 4
A A A A A A A x A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A 4 4 A A E E E A A E X E A A E A E A E E E E E E E E A A A A P n E C1 P, B P, 4 I( 1 3 1 4 1 4 4 4 4 4 4 4 4 4
I E 1 C I C t /1 t I4 I\ I4 t I\ I\ I4 I4 t3 I t3 )< f I I( I3 4 I I IE IE IB B I E B X A A B A E B E E E E E E E E E B B B B X X E B A E
E A A E A D A A A A A A A A B E B E B B X B A A E E E B B E E E A A A A E B A B E E X A A A A B X B B X E D B X B
)I
A E E E E A E E D E D D D D D x B x x E E D D A A A X A A E A X B D E D A A X E A A E E E E A 0 A D D A A X A A E
( 4
>
E E E E I1 f E [1 I4 I I I I3 I III ,4 l3 I3 I I 4 4 I 4 4 D A B E A E X E E E A A E E A E E E E E D E A E D E A A X E E
L\ E L i E fi [1 4 4 4 4 4 4 4 4 3 3 4 4 4 A B A A E D A B B A E Cl A A 0 A A B A A A 0, E P P P P B B E B P E P e I3 B I4 I\ I4 I4 I1 I4 I4 I4 I4 I1 I4 I: I: I1 4 ,4 4 IE ID IE A A A A A A X A A A A A A A D A A A A D A A A A A D A A A A A
B
D E X A A A A A A A A A E D E E E A A A A E E A A A A E A A A A A E A X D E E X A E E A A A A A X E E A A A
4 4 < 4 i 4 4 I(
4
.D > 1 4 i 4 4 ( I\ 4 I\ 4 ( \ 4 < 4 4 4 4 4 : U A 4 K 2 c 4 A A A X A A X A A A A A A A A A A A X A X A A
4 4 4 4 4 4 E E 3 D 4 A E A A A A A D A A X P E A A A A A A A A A A\ A A P E Pi A P A P n El P,
A
A A A C A A A E E C A A E A A A A A B E E A A A
SYMBOL
A I3 C Excellent Good Good to 80F E D Moderate
IDENTIFICATION
effect limited conditions)
F X -
Autocatalytic Unknown (continued)
(use under Not
recommended
Comparative
Resistances
of Materials
of Construction
887
TABLE 7.11:
RESIN, STEEL, ALLOY,
TITANIUM,
CERAMIC,
RUBBER, NATURAL
AND SYNTHETIC
FIBER
PUMP AND FILTRATION
SYSTEM MATERIALS-SETHCO
(continued)
CHEMICAL
FERRIC NITRATE FERRIC SULFATE FERROUS CHLORIDE FERROUS SULFATE FLUOBORIC ACID FLUOSILICIC ACID FORMALOEHYOE.40% FORMIC ACID FREON 12 (WET) FUEL OILS FURFURAL GASOLINE GLYCERINE (GLYCEROL) HEPTANE HEXANE HYOROBROMIC ACID, 20% HYDROCHLORIC ACID, 0.25% HYOROCHLORIC ACID. 25.37% HYOROCYANIC ACIO HYOROFLUORIC ACIO. 10% HYOROFLUORIC ACID. 30% HYOROFLUORIC ACID. 60% HYOROFLUOSlLlClC ACID, 20% HYDROGEN PEROXIDE. 30% HYDROGEN PEROXIOE,50% HYDROGEN PEROXIOE.SO% HYDROGEN SULFIOE.AO.SOL. IODINE (IN ALCOHOL) KEROSENE KETONES LACOUER THINNERS LACTIC ACID LEADACETATE LUBRICATING OIL MAGNESIUM CHLORIOE MAGNESIUM NITRATE MAGNESIUM SULFATE MALEIC ACID METHYL ALCOHOL METHYL CHLORIDE METHYL ETHYL KETONE METHYL ISOBUTYL KETONE METHYLENE CHLORIDE NAPHTHA NAPHTHALENE NICKEL CHLORIOE NICKEL SULFATE NITRIC ACIO. 10% NITRIC ACIO. 20% NITRIC ACIO; 50% NITRIC ACIO. ANHYOROUS NITRO BENZENE OILS AND FATS OLEIC ACIO OLEUM, 25% OXALIC ACID PHENOL
A A A A A A B C C A A 4 4 A A B 4 4 4 4 K 3 4 3 3 K u 3 4 3 3 B I\ A K X X X D C X X A X A X X A A X A A A B X X C B X A B A A X X X X X X A E A D A A A A A A A A A C E E A C C A A A A A B B A A X X A C C E C A A C A A A A A E C C E C C A A A A C E C A C X A B A A A A B B A A A A E E X E X A A A A A D E q X X X A D X E E A A X A A A A A E E E E X X A A A 6 E E E X A E A E 4 4 4 A B B A A A A A A A A A X D A A A A A A A A A A A A A A A C A A A C X B A A A A A A A A E B D A A A A A A A D B X A E A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A B A E D B B A B E A B A A A A E E E A c c c 6 B B B B B A A A B A A B A A B A A A A A A A B I3 B B B B B A B x C B A A E B A B A A X A A A A A A E E E A c c c B A A A A B A A A A A A A A A A A A A A A A A B A A A A A A A B x B B B A B A A B A A X A A A A A A A 1-c :.c A B B B B A A A A A A A A B A A A A A A A A A A A A A A B A A A B B A B A B A A A A A E E A A X A X E A X X A D D X E E E E B X X A E A A A A A A A A A A A A A A A A A A A A A A A A A X X C A A A A A E E A A A A A A A A A C C C C E E E E X X X X A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A 4 > 4 3 4 4 u 4 4 E 4 D 3 E 4 E E E E A E E A A A X A E E E E E E A A E E E E E A Cl E X E 4 4 4 4 4 3 4 4 1 4 B B X X X A B E B 6 E B H A X E X X B X X X A E E E E E B E E X X A A A A X B E E E E D E B B E E E E E A A E X E B B B B B X B B E B X E B B B A A A X A A D X A A D B E E E X B E D A A A A 6 E E E E E E B B A A E E E X D E A E 4 3 3 3 4 B 4 4 4 4 A B A A A B A A E X B A A A A A A D A E E D A D B B A A A B E A D A A A 4 3 1 3 3 3 I( 3 4 4 4 4 4 4 4 4 4 < 4 > 4 c 4 4 4 4 I( 4 4 4 4 4 4 4 1. X X X X A A X A A A X A X E X A X X A A A A A A E X A X A E
c c
A E C 4 4
E
X X X E A X X X A A A A D D e A X X A X A E E D A A A A A X X E E E E E X A A D E E E E X X E D A
A
E C A A C A A A A C C D A A C E C E E E 0 El A C A A A A
c
A A A A
C C
D A A C E C E B E II B A C A A A A C E E E E B E A A A A A E E A A E A C
C
E E E E B E A A A A A E E A A E A C
SYMBOL
A B C Excellent Good Good to 8OF E D Moderate (use Not
IDENTIFICATION
effect limited conditions) F X Autocatalytic Unknown (continued) under
recommended
888
Corrosion
Resistant
Materials
Handbook
TABLE
7.11:
RESIN, STEEL, ALLOY, TITANIUM, CERAMIC, RUBBER, NATURAL AND SYNTHETIC PUMP AND FILTRATION SYSTEM MATERIALS-SETHCO (continued)
FIBER
CHEMICAL
PHOSPHORIC ACID. II?1096 PHOSPHORIC ACID, 50-100x POTASSIUM BICARBONATE POTASSIUM BROMIDE POTASSIUM CARBONATE POTASSIUM CHLORATE POTASSIUM CHLORIDE POTASSIUM CYANIDE POTASSIUM OICHROMATE POTASSIUM HYOROXIOE POTASSIUM NITRATE POTASSIUM PERMANGANATE POTASSIUM SULFATE PROPYL ALCOHOL SOAPS SOOIUM ACETATE SODIUM BICARBONATE SOOIUM BISULFATE SODIUM BISULFITE SODIUM CARBONATE SODIUM CHLORATE SODIUM CHLORIDE SODIUM CYANIDE SODIUM HYOROXIOE,ZO)( SODIUM HYDROXIDE. 9% SODIUM HYPOCHLORITE SODIUM NITRATE SODIUM SILICATE SODIUM SULFATE SODIUM SULFIOE STANNIC CHLORIDE STEARIC ACID STOOOAROS SOLVENT SULFURIC ACID, O-1024 SULFURIC ACID. 10.75% SULFURIC ACIO. 75.100% TANNIC ACID TANNING LIOUORS TARTARIC ACID TETRAHYOROFURANE TOLUENE (TOLUOL) TRICHLOROETHYLENE TRICRESYLPHOSPHATE TURPENTINE UREA VINEGAR WHITE LIGUOR (ACID) XYLENE (XYLOL) ZINC CHLORIDE ZINC SULFATE
A 0 A A A A A A A A A A A C A A A A A A A A A A A A A A A A A A E A A C A A A E E E E B A A A E A A 4 4 4 4 4 4 9 P, A A A A A A A A A A E A A C A A A E E E E B P P P E P P 4 I \ 4 4 i \ 4 4 4 4 4 4
,
1 4 4 4 ( \ I 4 4 4 I 5 ( 4 4 4 ( 4
A B A A A A A A A A A A A
\
4 4 4 4 4 4 4 4 4 4 4 4 I(. 4 4 D, A A A A A A A A A A A A A A X E A A P X X P E E E n n n P P E P P
,
4 4 4 4 4 \ 4 4 1 4 4 4 < 4 4 4 4 4 4 9 A A D D A A A A A A X X A D E X x X X E X x X X A X E A A
A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A x A D A A x A A A A A A A
4 4 4 4 4 4 4 4 4 4 4 4 4 4 L\ I\
e I
E I I I I 4 I 4 4 3 3 3 3 4 4 3 3 4 3 B B B A A A D A B A B E A A E E E B A B A A B A A R A A A B A
6 0 B B 0 A c B A B B B B A A B A A B A B B A A A X A B A B C A A P A P B P e J 1 E i i E / I / I I
4 .E I 4 1 ( .E 3 3 3 3 4 3 4 A
C C A A A A A A A t-C A A A A A A A A A A A A A A A A A X X A A A A C D E A A A X A A B X A A X X A A
A A A A A A A A A E A A A A A A A A A A A A A E E A A A A A A A X A A A A A A A A A A A A A A A A A
C ( I I 8 I 1 3 3 1 3 3 3 3 3 E 3 3
A A B B B B B B B B B B B 6 B A B B
I 1 I 1 3 3 3 3 3 3 3 3 3 3
E E A D A E D A E D E D D A A A A D D A E A A E E E 0 A C C 6 P A C E E P c .L L L J > L I / c I C C 1 < I( 4 4 1 3 A D 4 A A A E A A A A X X X E E E E X X A A E X A X A X A E D A 1
\ \ 4 4 4 1 4 4 \ 4 4 1 < I( 4 4 4 PI L\ A A A A A A A A A A x x X A A A A x x E E E x A x A x E A A
,
) \ 1 1 \
x
A A A A A A A A A A A A A A A A A C
a
B B B B B B A A A ,-I B B A B B A A B B B B A B A P P P P 8 E 1 E 8 E
a
A A A A A A A A A A A A A A A A A A P A P A A P P P P c P / P P !
a i a a
B B B B B E E 0 B A B B B A A A P A B A E x E P P P E E I L E i
a
B E B B B B E B A B E B E x D E E E A E E E E E E E E A E B A
f3
B B B B B 8 A B A B B D D x A A D B X B X E E E E A B X E B A
r\
K 4 P, A A X A
B
A X A B
x
A
x
A A C A A A c C C x c A A x E A A
E
A X A x B B x c B B x B A A
SYMBOL
A - Excellent B - Good C - Good to 80F
IDENTIFICATION
conditions) F - Autocatalytic X - Unknown
D - Moderate effect (use under limited E - Not recommended
Comparative
Resistances
of Materials
of Construction
889
TABLE
7.12:
PLASTIC
AND
STEEL
PUMP
MATERIALS-THOMPSON-CHEMTROL
Comparative
Resistance of Thompson
CF Pump Construction
Materials
to Various
Corrosive
Media
CODE A B c D E Excellent Good Good to 80 Fahrenheit Moderate effect: May Not recommended
be
used
under
certain
conditions
OPERATING Polyvinyl Polyvinyl Teflon Dichloride Dichloride
TEMPERATURE (CPVC) (CPVC)

(PVDC) (PVDCI
LIMITS 225O F (non-pressure) 180 F (oressure)
Type 316 Stainless steel Hastelloy C - 276 Type

PVDC Acetaldehyde Acetic Acrd, 20% Acetrc Acrd, 80% Acetrc Acrd. Glacial Acetrc Anhydrrde Acetone Aiumrnum Alummum Alummum Alummum Ammonra Ammonrum Ammonrum Ammonrum Ammonrum Ammonrum Ammonwm Ammonwm Chlorrde Fluorrde Hydroxrde Sulfate Lrqurd BrFluorrde Chloride Hydroxrde Nitrate Persulfate Phosphate Sulfate E C D D E E A A A A A A A A A A A A A E C E E D A A A A A A A E E A A A 316 SS A A A A A A D D A D A A A A A A A A B A A A A E A A A A A A A A A A A A Hastelloy C-276 A A A A A A C B A A A A A A A A A A A A A A A D. E A A A A A A A A A A A A Tef Ion A A A A A A A A A 0, A A A A A A A A A A A A A A A A A A A A A A A A A A
500 Very
Very
F . high
high
Type
PVDC Borrc Acrd Bromrne Water Butyl Acetate Butyrrc Acrd Calcwm Brsulfrde Calcrum Carbonate Calcwm Chlorrde Calcwm Hydroxrde Calcrum Hypochlorrte Calcrum Sulfate Carbon Brsulfrde Carbon Tetrachlorrde Carbonrc Acrd Chloracetrc Acrd Chlorine Water Chlorobenzene Chloroform Chlorosulfonrc Chromrc Acrd Crtrrc Acrd Copper Chlorrde Copper Cyanrde Copper Nrtrate Copper Sulfate Cresylrc Acrd Ethyl Acetate Ethyl Chlortde Ethyl Dichlorrde Ethylene Glycol Fatty Acrds Ferric Chloride Ferric Nitrate Ferric Sulfate Ferrous Chlorrde Ferrous Sulfate Acrd A D E D A A A A A A E C A C A E E D A A A A A A A B E 316 SS D D D A A A A A D A A B A D E A A B A B A E A A A A A A A A A E A D E A Hastelloy C-276 A A A A A A A A C. D B A A A A B A B A A. B A. B A _ A A A A A B B A A B. C A A B A .Teflon A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A
Ammoncum Carbonate
, 1OY 0
Amyl Acetate Amy1 Alcohol Amy1 Chlorrde Arlrlrlle Aqua Regra Arsentc Actd Barwm Carbonate Barrum Chlortde Barwm Hydroxrde Barrum Sulfate Barrum Sulfide Beer Benzaldehyde Benzene (Benzol) Bensocc Acid Benzorc Acrd Borax (Sodium Borate) ___~~~
Chromrc Acrd. 50%
E
E A A A A A A A
(continued)
890
Corrosion
Resistant
Materials
Handbook
TABLE 7.12:
PLASTIC AND STEEL PUMP MATERIALS-THOMPSON-CHEMTROL
(continued)
Type
PVDC Fluoboric Acid A A C C C A E C (Glycerol) A C C Acrd, 20% Acid, O-25% Acid, 25.40% Acid Acrd, 10% Actd, 30% Actd, 60% Acrd 30% 90% A B B A C C D D B C E C E B E D B A A B A A A A A A A A C E E E E C E A A B B B E E A A Ketone 316 SS D A A B E A A A A A A E E E A E E E E D D D D E A A A D B A A B A A B A E A A A A A A A A A D B A A B E A A A Hastelloy C-276 A A. B A A A A. B A. A A A B B. C B. C B B B B A A A A B A A A A A A A A A A B B B A A B A A A A A A B A B B C. D A A A Teflon A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A Oleum Oxalic Acid Phenol Phosphoric Acid, O-50% Phosphoric Acrd, 50-100% Potassrum Bicarbonate Potassium Bromide Potassium Carbonate Potassrum Chlorate Potassium Chloride Potassium Cyanide Potassrurr, bichromate Potassium-e Potassium Nitrate Potassium Permanganate Potassium Sulfate Propyl alcohol Soaps Sodium Acetate Sodium Bicarbonate Sodium Bisulfate Sodium BiSulfite Sodrum Carbonate Sodium Chlorate Sodium Chloride Sodrum Cyanide Sodium Hydroxrde, Sodium Hydroxrde, Sodium Nitrate Sodrum Srlrcate Sodium Sulfate Sodium Sulfide Stannrc Chlorrde Stearrc Acrd Stoddards Sulfuric Sulfuric Solvent Sulfurrc Actd, 0.10% Sulfurrc Acrd. 10.75% Sulfurrc Acid, 75.100% Tannic Acrd Tanning Liquors Tartarrc Acrd TetrahydroFurane Toluene (Toluol) Trichloroethylene Trrcresylphosphate Turoentine Urea Vinegar White Ltquor Xylene (Xylol) znc Chlorrde Zinc Sulfate 20% 50% PVDC E A C B B A A A A A A A A A A A C A A A A A A A A A A A A A A A A A E B B C A A A A E E E E C A A A E A A
Type
316 SS A A A A B A A A AA A A ----B A B B A A A A A A B A A A B E A A A A E A A D E E A D A B A A A A
A
Hastelloy C-276 A A. B A A. B A. B A A A A. B B B B B A. B B A A B B A A A A. B A. B A. B A, B B A B A A A. B B. C B.C B A A B A A A A

A
Teflon A A A A A A A A A A A A A A A A AA A A A A A A A A A A A A A A A A A A A A A A A A A A A A
A
Fluosilicic Acid Formaldehyde Formic Acid Freon 12 (wet) Fuel Oils Furfural Gasoline Glycerine Heptane Hexane Hydrobromrc Hydrochloric Hydrochlorrc Hydrocyanrc HydroFluorrc HydroFluorrc HydroFluorrc
HydroFloursrlrcrc
Hydrogen Peroxide, Hydrogen PeroxIde, Iodine (tin alcohol) Kerosene Ketones Lacquer Thrnners Latic Actd Cead Acetate Liquors Lubrrcants Magnesrum Chlorrde Magnestum Hydroxide Magnesrum Nitrate Magnesrum Sulfate Malerc Acrd Mercurrc Chloride Mercurrc Cyanrde Mercury Methyl Alcohol Methyl Chlorrde Methyl Ethyl Ketone Methyl lsobutyl Methylene Naphtha Naphthalene Nrckel Chlorrde Nrckel Sulfate Nitrrc Acrd, 10% Nrtrrc Acid Chloride
Hydrogen Peroxide, 50% Hydrogen Sulfide, Aq. Sol.
A A A A B B
A A A A B. C A
A A A A A A
, 2oY0
Nrtrrc Acrd. 50% Nrtrrc Acrd, anhydrous Nitro benzene Oils and Fats Oleic Acid
891
TABLE 7.13:
STEEL, TITANIUM,
ZIRCONIUM, COLUMBIUM AND TANTALUM COI LS-VULCANIUM Selection of the proper material for your heating or cooling coil requires that three factors be considered: 1) the solution; 2) the desired life of the coil; 3) the coils cost. To assist you in making the proper selection, we have developed the following table. To use this table, follow these steps: 1. From the column on the left, select the solution into which the coil will be placed. 2. Scan to the right and locate the column with a checkmark (ti) 3. Move up that column to find the material which Vulcanium recommends as being best suited for use.
HEATING
AND COOLING
*,ln msny appl~calions where
mald steel tolls gwe adequate serwce. a 304 stainless steel co11wll gwe better serwce at e modest increase I cost.
SPECIAL NOTE ON MATERIALS: than those l~sled above. includmg
Vulcanium can fabrncate coils from msler~als other Carpenter 20. Haslelloy and Inconel.
Company Name and Address Listing

The editor is indebted to the organizations listed below for supplying the data used in the preparation of this book.
Abresist Corp. P.O. Box 38 State Road 13 North Urbana, IN 46990 Acme-Fisher Division Broadway Rubber Corp. P.O. Box 1135 Louisville, KY 40201 Allegheny Ludlum Steel Corp. Division of Allegheny Ludlum Industries, 2000 Oliver Building Pittsburgh, PA 15222 Allied Engineered Plastics P.O. Box 2332Fi Morristown, NJ 07960 Aluminum Association, Inc. 818 Connecticut Ave., N.W. Washington, DC 20006 Aluminum Company of America 1501 Alcoa Building Pittsburgh, PA 15219 American Cyanamid Company Organic Chemical Division Wayne, NJ 07470 American Iron and Steel Institute 1000 16th Street NW Washington, DC 20036 Ameron Corrosion Resistant Piping Division 595 West Lambert Rd. Brea, CA 92621 Ametek, Haveg Division 900 Greenbank Rd. Wilmington, DE 19808
Amoco Chemicals Corp. 200 East Randolph Drive Chicago, IL 60601 Ampco Metal Division of Ampco-Pittsburgh P.O. Box 2004 Milwaukee, WI 53201 Arco Metals Co. American Brass Two Continental Towers 1701 Golf Rd. Rolling Meadows, IL 60008 Armco Stainless Steel Products P.O. Box 600 Middletown, OH 45043 Ashland Chemical Co. Division of Ashland Oil, Inc. P.O. Box 2219 Columbus, OH 43216 Astro Metallurgical Corporation Division of Harsco Corp. 3225 Lincoln Way West Wooster, OH 44691 Atlas Minerals & Chemicals, Inc. Farmington Road Mertztown, PA 19539 Barnant Co. 28 W 092 Commercial Barrington, IL 60010 Bethlehem Steel Corp. Bethlehem, PA 18016 Brush Wellman Inc. 17876 St. Clair Avenue Cleveland, OH 441 IO
Corp.
Inc.
Ave.
892
Company
Name and Address
Listing
893
Cabot KBI Division Cabot Corporation P.O. Box 1462 Reading, PA 19603 Division
Devcon Corp. Subsidiary 30 Endicott Danvers. of Illinois St. MA 01923 USA Tool Works, Inc.
Cabot Stellite
Dow Chemical Midland,
Cabot Corporation 1020 West Park Avenue Kokomo, IN 46901
The Dow Center Ml 48640 Corp.
Dow Corning Cabot Wrought Products Division Midland, Cabot Corporation 1020 West Park Avenue Kokomo, Carpenter Carpenter Reading, CEEL-CO 12990 West Cedar Drive CO 80228 Lakewood, IN 46901 Technology Corporation Duriron Dayton, Eastman Kingsport, Elkhart Randolph High Point, Everflex Artell Ludlow, Colt Trent 2188 Industries Tube Division Church St. WI 53120 Exxon
Ml 48640 & Co., Inc.
E.I. du Pont de Nemours 1007 Market St. DE 19898 Wilmington,
Steel Division PA 19603
P.O. Box 662
Co. Inc. OH 45401 Chemical Products, Inc.
Box 1145
P.O. Box 431 TN 37662 Inc. Park
Celanese Plastics Co. Division Chatham, Climax Division of Celanese Corp. NJ 07928 Co. Rubber 26 Main St. Lois Lane Industrial NC 27264 Inc. St. P.O. Box 7385
Molybdenum of Amax Inc. Plaza
One Greenwich Greenwich,
Products, MA 01056 Chemical
CT 06830
Road at Holyoke
Americas
P.O. Box 3272 Houston, Fabric0 4222 South Pulaski Rd. Chicago, IL 60632 Co. TX 77001
East Troy, Corning Corning, Cyclops
Glass Works NY 14831
Corporation Specialty Rd. Steel Division Gates Rubber 999 South Denver, P.O. Box 5887 CO 80217 Electric Co. Broadway
Universal-Cyclops 650 Washington Pittsburgh,
PA 15228 Inc. Division
Dart Industries Special Projects P.O. Box 37 Paramus,
General Noryl Selkirk, General 8800
Ave. NY 12158 Metals Technologies Court VA 23234 Corp.
NJ 07652
Dayco Corp. 333 W. First St. Dayton, OH 45401
Metro
Richmond,
894
B.F. Goodrich 6100 Cleveland, Haysite 5599
Chemical
Co.
Minor
Rubber
Company, Street
Inc.
Oak Tree Blvd. OH 44131 Plastics
49 Ackerman Bloomfield, Mobay
NJ 07003 Corp. Division
Reinforced
Chemical
New Perry Highway
Plastics and Coatings Pittsburgh, PA 15205 Polymer
Erie, PA 16509 Himont 1313 USA, Inc. St. DE 19894 Alloys, Inc. Nickel Co., Inc.
Monsanto 800
Products Blvd.
Co.
N. Market
N. Lindbergh
Wilmington, Huntington Division Huntington, Huntsman
St. Louis, MO 63166 Morrison Bristol, Morton Morton 930 Trenton, Nalge Co. Division of Sybron Corp. 75 Panorama Rochester, Creek Dr. Molded VA 24203 Thiokol, Chemical Ferry NJ 08650 Inc. Division Rd. Fiber Glass Co. Ave.
of the International WV 25720 Chemical St. Co. Center
400 Commonwealth
Business Technology 1445 Summit Columbus, Huron OH 43201 Ltd.
Lower
Chemicals
Casson Crane Division P.O. Box 308 Alexandria Industrial 3041 Northbrook, Interplastic 2015 N.E. Minneapolis, ITT Jabsco 1485 Dale Way Costa Mesa, CA 92626 Janney 7401 Cylinder Road PA 19136 Company Company Bay, NY 13607 Titanium Corp. Ave.
NY 14602 Inc.
New Jersey Zinc Company, Palmerton, Nibco Inc. Ave. IN 46515 PA 18071
Commercial
IL 60062
Corporation Broadway MN 55413 NRC Inc. Place MA 02164 Pump Division NY 13221 Corp. NY 14120 Inc. 500 Simpson Elkhart,
45 Industrial Newton, Oberdorfer Syracuse, Occidental Walck North Rd.
An Ampco-Pittsburgh State Philadelphia,
Chemical
Jessop Steel Co. Jessop Place Washington, Kennametal Latrobe, PA 15301 Inc.
Tonawanda,
0- I/Schott P.O. Box T Vineland, Peabody South
Process Systems,
1640 S.W. Boulevard NJ 08360 TecTank Inc. Park
PA 15650 Co. inc.
Koch Engineering M.A. Akron, Knight P.O. Box 109 OH 44309
Division
Industrial
P.O. Box 996 Parsons, KS 67357 Pennwalt Three Corporation PA 19102
Lead Industries 292 Madison New York,
Association,
Inc.
Ave.
Parkway
NY 10017
Philadelphia,
Company
Name and Address
Listing
895
Pfaudler Division
Co. of Sybron Corporation NY 14603 Co. Co.
Shell Chemical P.O. Box 1422 Houston, A.O. 2700 Little Inc. Sohio Chemical Midland Cleveland, Inc. Bldg.
Co.
Rochester,
TX 77001 Inc. St.
Phillips Chemical Subsidiary Bartlesville, Plastonics 951 Jaycox Avon, Quaker Chicago, Radiation Rockaway, Resistoflex Subsidiary Roseland, Resolite Division of H.H.
Smith-Inland West 65th
of Phillips Petroleum OK 74004 International Rd.
Reinforced
Plastics Division
Rock, AR 72209 Co.
OH 44011 Oats Chemicals, Mart Plaza
OH 44115 & Engineering, Street Inc.
Merchandize
Stainless Foundry 5 150 North Milwaukee, Inc. Sternson Brantford, Limited St. Ont., 22 Mohawk 35th
IL 60654
Technology, Rd. NJ 07866 Corporation of UMC NJ 07068 Industries, Inc.
WI 53209
108 Lake Denmark
Canada N3T 5NI
Ston hard, Inc. Park Avenue P.O. Box 308 Maple Shade, NJ 08052
Robertson
Co. Sulcon Systems P.O. Box 427 Champaign, IL 61820
P.O. Box 338 Zelienople, PA 16063 Products Inc. and Brass, Inc.
Revere Copper Subsidiary Rome, NY P.O. Box 300
of Revere Copper 13440
Teledyne Monroe, Teledyne
Allvac NC 28110 Wah Chang Albany OR 97321 Processes Inc. Road
P.O. Box 759
Rilsan Corp. Subsidiary Glen Rock, of ATOCHEM Rd. NJ 07452 139 Harristown
P.O. Box 460 Albany,
Thermoplastic Rohm and Haas Co. Independence Philadelphia, A. Schulman 3550 Akron, P.O. Box 1710 OH 44309 Mall West PA 19105 Thermoplastic Inc. St. Affiliate Warren, West Market 57 Stirling Rd. 1268 Valley Stirling,
NJ 07980 Scientifics, Inc. Processes, Inc.
of Thermoplastic NJ 07060
Thompson-Chemtrol Schwarzkopf 140 Lowland Holliston, Sethco Development St. Corp. Division of Finish Engineering Rd. Co. 921 Greengarden Erie, PA 16501 3M Ceramic Materials Department 3M Center St. Paul, MN 55144
MA 01746
Division Dr. NY 11788
Met Pro Corp. 70 Arkay Hauppauge,
896
Timet 400 Rouser Rd. P.O. Box 2824 Pittsburgh, PA 15230 Union Carbide Engineering P.O. Box 446 Marietta, OH 45750 U.S. Graphite, Inc. 1621 East Holland Saginaw, MI 48601 U.S. Industrial Chemicals Co. Division of National Distillers and Chemical Corp. 99 Park Ave. New York, NY 10016 Vulcanium Corporation 3045 Commercial Avenue Northbrook, IL 60062 Polymers
Wall Colmonoy Corporation 19345 John R Street Detroit, MI 48203 Walworth Co. P.O. Box 873 Valley Forge, PA 19482 Watersaver Company, P.O. Box 16465 Denver, CO 80216 Inc.
Westlake Plastics Co. Distributor for Mitsui Petrochemical Industries, Ltd. P.O. Box 127 Lenni, PA 19052
Trade Name Index

Trade name designations of the materials for which corrosion resistance data are given in the tables are listed in this index.
ABRESIST ACIDSIL
- 791
CHEMPRUF
- 242
- 391,393
AF LAS - 285 AL-6X - 412,445 AL 29-4-2 - 414 AL29-4C-414 ALFANE ALKOR - 389 - 389
CH LOR IMET - 773,797 CH LOROSOL - 355 CLADKOTE - 388 COLMONOY
- 728
CORESITE - 391,396 CO-REZYN - 159 CORLOK - 399 CYANACRY L - 284,298 CYANAPRENE - 296 CYANASET - 296 DELORO - 730,756 DELR IN - 220 DERAKANE - 108, 109,223 DEVCON - 32 DOW-251 DOWMETAL DP-3 - 429 - 797
ALLCORR - 665 ALLOY 825 - 446 ALOYCO - 785 AMBRALOY - 649 AMBRONZE
- 654
AMPCO - 632 AMTEX - 355 AMZIRC - 654 AROPOL - 179 ASPLIT - 399 ATLAC - 108, 109,223 ATLASTAFLEX - 242 ATLASTIC BAREX - 9 BEV-A-LINE
DURALON - 805 DURAN - 882 DURCO - 221,773 DURCOMET
- 242
- 773
- 172 BONDSTRAND - 33,170

BRUSH ALLOY 25 - 639 BUNA N - 355,809,854,885 BUTENE - 355 CABOT - 666 CALSUN BRONZE - 654 CARBO-KOREZ - 389 CARPENTER CARPENTER 433,445, CEEL-TITE CELANESE 20 - 446,797,885,891 20Cb-3 - 421,422,423,427, 665,757,777 - 1, 151
DURCON - 34,221,805 DURCOTHENE - 221 DUREZ - 95,805 DURICHLOR - 773,797,882 DURIMET - 427,773,797 DURI RON - 773,797,882 DURO - 355 DYNEL - 884,885 E-BR ITE - 417 EPILOC - 391 EPON - 35 ETHOCE L - 802 EVERDUR - 649,797 EXCELON - 154 EXTREN - 47 FERRALIUM FLEXANE
- 63
CELANEX - 52,239 CELCON - 3 CER-VIT CHEMIGUM
- 882 - 802
- 420,429,445,846
- 297
897
898
FLUOREL
- 355
FLUOROFLEX - 218 FLUOROSILICONE WK-8870 - 355 FN - 399 FORAFLON - 155
MERLON - 106 MF-1 - 419 MINCAR
- 355
MIRCO - 355 MIRPRENE - 355 MONEL - 632,641,664,757,777,781, 782,783,784,797,846 MULTIMET
FURABOND - 406 FURALAC - 399 FURASET FURNANE GALVALUME GATRON GLASTEEL - 809 - 793 - 406 - 382 - 638
- 424
NALGENE - 848 NEOPRENE - 242,299,355,367,802, 809,839,848,854,885 NEXTEL - 790 1900 (UHMW Polymer) N ITRON IC - 428 NORDEL - 299,355 NO RY L - 102,240,247,854,885 01 L ACE - 355 OR LON - 885 PEBAX - 110 PENCH LOR - 399 PENNGUARD - 387,792 PENNTROWEL - 375 PENTON - 247,802 PERMANITE - 60,391,392,805 PETROTHENE - 114 PLEXIGLAS - 6,802 PLIADUCT - 149 POLYCAST - 355 POLYMAN - 2 POLY THREAD - 37 PYREX - 792,797 PYROITE - 68 QO FA-RoK - 383 QUACOR R - 39 QUALATEX - 355 QU I K- LOCK - 33 RADGROUT-H - 383 RED THREAD II - 37 RESIBOND - 391,394,395 RESIST-O - 355 RESISTOFLEX - 218 RESOLITE - 53 - 648 - 373,388 REVALON REZKLAD
GRAPHITAR - 786 GREEN THREAD - 37 HALAR - 54,848 HASTE LLOY - 69,445,665,666,730, 757, 777,797,846,854,885,889, 891 HAVEG - 174,805 HAYNES - 644,666,730 - 648 - 805 HB - 399 HERCULOY HERESITE
- 112
H.E.S. - 399 HETRON - 108,179,223 HYPALON - 250,299,355,809,885 HYTREL ILLIUM
- 272,299 - 426,725 INCOLOY - 665,777 INCONEL - 427,445,664,665,777,

783,797,891
IN 0 BOND - 406 IRONSIDES - 355 JS 700 - 413,429,445 JS 777 - 413 K14 - 399 KABO - 391,398 KBI-40 - 733 KEL-F - 802 KENNAMETAL - 771 KENTAN IUM - 772 KIMAX - 882 KNIGHTBOND KODAR
- 391,397
- 116 KOROSEAL - 242,367 KYNAR - 69,247,251,848,885 LIQUATHAN E - 297 LUCITE - 802,885 LUSTRAN - 225 LUSTR EX - 225 MASTE RF LEX - 238 MATCH LESS - 355
RYN ITE - 220 RYTON - 120,247,854 S12 - 429 S13 - 429 SAF 2205 - 429 SARAN - 251,802 SDX - 399 SILASTIC - 287
Trade Name
index
899
SILIGLAS ST - 290 STELLITE STONCLAD
- 294 - 425,643,730,756,797 - 406 - 369
TR IBALOY TRISTELLE
- 756 - 425
STERNCHEM
TUFCHEM - 375,387,399 TUFFLEX - 272 TYGON - 238,802 UDEL - 147 UN I LOY - 440 USCOLITE - 802 VAMAC - 299 VEW A905 - 429 VI-CHEM - 355 VISTALON - 302 VITON - 238,263,299,355,802, 839,848,854,885 VITREX - 389 VITROBOND VITROPLAST - 389 - 389
STON LAST - 293 STY RON - 805 SUCOAT - 384 SULCON - 384 SUPERCHLOR - 773 TALYCHEM - 379,406 TECLINE - 155 TEFLON - 69,156,157,247,802,854, 882,885,889 TEMPALOY - 649 TENITE - 10,104,111,120 THERMOFLEX - 355 THIN SET - 375 THIOKOL - 355 TICODE- 741 TOBIN BRONZE 4641 - 649 TPX - 118,239 TRANSITE - 797 TRENT - 729
WALLEX - 645 WORTH ITE - 797 XYDAR ZAMAK - 107 - 742 - 749
ZIRCADYNE ZYTE L - 220
Corrosive Material Index
This index relates to the chemicals listed by manufacturers in the main portion of the book. Indexing in a book of this nature is complicated by the fact that different nomenclature is used by different firms for the same chemical. For example, most of the tin chemicals are listed under stannic or stannous; however, there are also headings for tin chemicals and tin salts. As another example, the reader will find information regarding HCI listed under Hydrochloric acid, Muriatic acid and Hydrogen chloride. The user of this Index should utilize as many synonyms and group designations as possible for the particular substance in which he is interested, in order to obtain as much pertinent information as possible. Some of the products listed are registered trademarks; however for purposes of this Index, trademarks have not been differentiated from generic names. Absence of trademark indication does not exclude the possibility that the name may be a proprietary name or the subject of proprietary rights. AN-O-3 - 355 AN-O-6 - 355 AN-O-366 - 355 AN-VV-O-366b - 355 ASTM G-28 Test - 666,734 ASTM oils - 110, 111, 148, 150, 154, 156,267, 274,285,287,288,291,293,296,297,299, 304,307,310,313,316, 318,319,320, 321, 322,323,324, 325,326, 327,328,329, 330,331,332, 333,334, 335, 336,337-354, 356,811,823,839,858,872 ASTM reference fuels - 284,287,288,289, 291,293,304,307,310,316,337-354, 356,811 ATE - 823 ATL-857 - 356 Abietic acid - 157, 610, 657, 787 Abrasive solutions - 367 Absorption oil - 810 Acetal - 156,810 Acetaldehyde - 27,47,60,63,65,69,106, 113, 1.14, 122, 149, 153, 154, 156, 159, 170, 174, 181,226,236.242,247,251,263,273,299, 355,375,379, 389,392, 393,397,398,399, 406,446, 610, 657, 663, 667, 736,749,764, 789,810,822,839,848,854,886,889 Acetaldehyde, fumes - 181 Acetaldehyde mixtures - 446,447 Acetamide - 63, 69,226,251,263,273, 355, 810,822,839,848,854 Acetanilide - 610,657 Acetate solvents - 27, 69, 122, 156,221, 368, 632,773,789,839,854 Acetic acid - 2,4, 6,9, 10, 17, 26, 27, 33, 34, 36, 37,39,41,43,44,45,46,47,52,53, 54,60,61,62, 63, 65, 67,69,95, 102, 104, r 106, 107,108, 109,111, 112,113,114,117, 118, 120, 122, 142, 147, 149, 151, 153, 154, 155, 156, 159, 169, 170, 174, 181,218,221, 225,236,239,240,242,247, 251, 263, 273, 285,291,296,299,303,306, 309,312,314, 355,359,368,369,371,373,374,375,379, 382, 383, 384, 387, 388,389, 392, 393,394, 395, 396, 397, 398, 399,406, 412, 413,416, 424,432,434,448,449,450,610,632,639, 640,642,644, 645,646, 650, 657, 663, 667, 668,669,725,728,731,732,735,736,756, 757,764,773,779,781,787,792,793,797, 801,805,810,822,839,846,848,854,882, 884,886,889,891 Acetic acid-acetic anhydride, boiling - 413 Acetic acid-anhydride - 434, 757 Acetic acid, boiling - 418, 419,420, 423, 424, 425,428,440,444,445,643, 645,647,666, 667,668,669,723,730,736,749,764,779, 78 1,854, Acetic acid mixtures - 181,450,451,452,453, 454.455,781 Acetic acid mixtures with formic acid - 455,456, 457,458,459,460,461 Acetic acid, vapor - 181,434, 448, 632, 669,735, 757,764,779,839,846,854 Acetic aldehyde (see Acetaldehyde) Acetic anhydride - 27,39,41, 43,44,45, 46, 47, 54, 60,65,69, 103, 109, 114, 147, 149, 153, 154, 156, 157, 159, 170, 174, 181,218,221, 232,240,247,251,263,299,355,368,375, 379,392,393,397,398,399,406,440,461, 610,632,650,657,669,732,735,749,764, 773,779.781,787,797,801,805,810,822, 839,846,848,854,882,886,889 Acetic anhydride, boiling - 440, 669, 736, 749, 779,854 Acetic anhydride mixtures - 461,462, 736
900
Corrosive
Material
Index
907
Acetic 463 Acetic Acetic
anhydride
mixtures
with acetic acid
- 462,
Acid cleaner-31% Acid crude tar Acidic Acidic
HCI - 109 environment base) - 669
- 156 - 384
ester (see Ethyl ether (see Ethyl acid
acetate) acetate) acetoacetate) 65, 69,95, 114, 117, 151, 153, 154,
and biochemical fumes
- 62, 181
(ammonia
Acetoacetic Acetoacetic Acetone 103, 37, 39,46, 104,
- 657
Acid pulping
ester (see Ethyl 52,53,54, 106, 109, 158, 159,
Acid rinse, photographic Acids - 116, 120, 297, 302, 303,
- 181
225, 240, 371, 372, 250, 285, 396, 432,
- 1, 2, 4, 6, 7, 9, 11, 18, 26, 27, 33, 34,

60,63, 111, 112, 113,
181, 220, 369, 370,
648,735,787,795,854
118, 120, 122, 156, 157,
142, 147, 149, 169, 170, 307, 394, 646,
174, 181, 218, 284,285,291, 355, 399,406, 669, 757,
230,239,247,251,263,273, 293, 296,299,304, 387, 434, 392, 393, 610, 632, 368,370,372,373,374,375,379,383,384, 395,397,398, 650,
310,313,315,
657, 663,
764, 781,
789, 792,
797,801,805,810,822,
839,848,854,882,886,889 Acetone cyanohydrin - 657 Acetone Acetone Acetone cyclohexane, mixtures oil - 399,406 hexane, water
- 726 - 303, 432, 648, 663, 664, 785 Acid soil slurry pH 4 - 61 Aconitic acid - 610, 669 Aconitic acid mixtures - 464 Acridine - 657 Acriflavine - 122 Acrolein - 610, 657, 789,810 Acrylamide - 181,822 Acrylic acid - 33, 37, 39, 43, 45, 109, 159, 170,
Acid sludge Acids, organic 174,181,375,379,383,464,610,669 Acrylic Acrylic Acrylic anhydride
- 181
- 181,463
- 157 - 181
chloride
dispersion:acrylonitrile dispersion:vinylidene emulsions
Acetonitrile 218, 232, 810,848,854
- 39, 53, 69, 147, 170, 174, 181,

241,247,251,273,463, 610, 669,
Acetophenetidin Acetophenone 157, 158, 273,355, Acetophenone p-Acetotoluidide Acetylacetone
- 230, 657
- 69, 103, 108, 122, 142, 156, 247,251,263,
- 181 - 62, 114, 122, 181, 210,848 Acrylic spray liner - 181 Acrylic wet ink varnish - 181 Acrylonitrile (vinyl cyanide) - 27, 39, 47, 54, 69,
Acrylic 105, 106, 251, Activated Adipic Adipic Adipol 263, 822,839,856 carbon beds 156, 355, 158, 370, 170, 174, 181, 214,218, 610, 657,810, 372, 383,
181,218,230,241, 657, 669,789,810,822 phenol with
- 463
- 610, 657 - 285, 355, 657 Acetyl dl alanine - 251

Acetylbenzene Acetyl Acetyl bromide chloride (see Acetophenone) - 399,406
- 181
263,
Adhesives - 839 acid
- 27, 53, 69, 149, 154, 181,251, - 736, 764
355,375,379,610,657,736,787,822,848 acid mixtures BCA - 291 chloride
- 34, 53, 69, 156, 174, 181,218,

263, 355, 384, 399,406, 657,
241, 247, Acetylene
251,
Adiponitrile Adipyl Adrenalin Adrenalin Adrogen Aero
777,781,797,801,805,822,846,854,882
- 54, 65, 69, 122, 149, 154, 156, 247,

299, 355, 375, 379, 440, 632, 646,
263, 273, Acetylene Acetylene
- 736, 764 - 181, 736 hydrochloride - 142, 230 in oil - 142, 230 - 355
items
650,657,663,788,810,822,839,854 dichloride tetrabromide (see Dichloroethene) (see Tetrabromo(see Tetrachloro-
- 181
and automotive
lubriplate 2300
Aeronautical Aero-safe Aeroshell 856 Aerosols
- 13
285, 355,810,
ethane) Acetylene Tetrachloride ethane) Acetyl Acetyl Acetyl Acetyl Acetyl Acetyl dl leucine nitrite oxide salicylic thiophene
- 273, 355, 810 oils and grease - 156,273,
- 251 - 251
anhydride)
- 610
wetting 50 agent
dl methionine
Aerosol Aerozene Agar-agar
- 181
components - 729
- 263
(see Acetic acid (see Aspirin)
Aerospace,
missile, rocket
- 355,781,856
chemicals lime
- 822 - 62 - 156 - 33, 37, 67, 156, 170, 251, - 822
- 657 Acetyl dl tryptophan - 251 Acetyl dl valine - 251

Acetylene ethane) tetrabromide tetrachloride (see Tetrabromo(see Tetrachloroethane)
Agricultural Agricultural Agricultural
spray oil
Air (see Atmosphere) chemical plant
273,355,646,691,731,732,747,748,788
Acetylene
- 183,431
902
Air (contd) chlorine coal dust heated humid, marine 746 methyl salt air sulfide, methanol - 181 - 633, 634, 635, 636, 637, 638, 744, containing - 691
Alkyl
benzene chloride
- 856
acid - 109, 182, 495, chloride 669
Alkylbenzenesulfonic Alkyl
- 183
- 42, 153 - 182

oxide surfactant sulfonic acid
exhaust - 669,682
Alkyldimethylbenzylammonium Alkyletheramine Alkylnaphthalene 746 Alkyl Alkyl phenol Alkylphenol-boron Allomaleic
- 810,822
trace sulfur
- 182
industrial
- 181, 196 - 633, 634, 635, 669, 744,745,
- 658 - 670
- 464,465
trifluoride
- 53, 431, 633, 634, 635, 744,745,
sodium sulfate
- 610
acid)
acid (see Fumaric
Ally1 acetate
745,746 steam - 669 urban Aircraft Aircraft Airshow
- 157 Ally1 alcohol - 27, 69, 114, 142, 149, 154, 156,
225,251,263,610,658,669,848
- 633,634,635,744,745,746
engine parts - 729 hyd. oil AA
Ally1 chloride 149, 263, 154, 375,
- 27, 39, 54, 63, 70, 109, 114, 122,

156, 379, 159, 170, 393, 399, 174, 658, 182,218, 251, 670, 788, 810,
- 273,810
- 822 - 822 - 14, 22

beer) (see Food 119, 124, 625,743, 114, 118,
822,856 Allyldiglycol carbonate Ally1 isothiocyanate Ally1 methacrylate Ally1 sulfide Almond Alpha Alum Alum, Alum, 285, 303, 646, 306, 648, 309, 312, 315, olefin
Air slaked lime Alcoholic
Air Wick odor neutralizer products) - 29, 56, 106,
- 856 - 611
beverages (excluding
- 157
- 658
sulfonate
154. 227,228,238,256,266,267, 788,844,850,876 Alcohols 226, 368, Alcohols, Alconox Aldehvdes Aldol
oil (see Essentials oils)
- 182
potassium sulfate) ammonium sulfate) sulfate)
- 36, 39, 53, 62, 67, 69, 120, 156, 225,

240, 273, 632, 639, 642, 650, 728, 822,
(see Aluminum ammonium chrome sodium 5
(see Aluminum
sulfate) (see Chromium (see Aluminum (see Aluminum potassium sodium Alum, Alum, Alum Alumina potassium potassium
839,846,848,856 aliphatic
- 63, 116
- 104, 117
- 116,226,241,303,306,309,312,
sulfate)
315,432,822
- 610
phenate powder based
- 273 - 156, 611, 650 Alumina hydrate - 670

Aluminum Aluminum, Aluminum - 790 molten acetate
Algaecide, Algaroth Alipal Aliphatic Aliphatic Alka form Alkalies Alkaline Alkaline
- 182
- 822 - 646
- 182
halogen compounds solvents
- 642, 646, 736 - 12, 18, 156, 355, 440, 611,

781,810,822,856 sulfate (Alum, ammonium) 788,810,
658,670,728,777, Aluminum 822,857 Aluminum Aluminum Aluminum Aluminum Aluminum 856 Aluminum chlorate chloride 118, 170, anodizing borate ammonium 54, 154, 218,252,263,
- 368
- 856
355,
611,777,
- 226, 250, 297, 639, 664, 665, 792, 795

cleaning - 891 film stripper
hot seal tank - 891
- 182 Alkaline soak cleaner - 182 Alkaline soil slurry pH 10 - 61 Alkaline solutions - 610, 731 Alkane sulfonic acid - 658 Alkanolamide, fatty acid - 182
Alkanolamide, Alkazene Alkyd Alkyl Alkyl nonionic surfactant
- 611 - 670
brazing flux bromide
bright dip - 891
- 355, 393, 399,406,810,822, - 658, 749

(sal ammoniac) 122, 142, 151,
- 182
Aluminum
- 12, 18, 27, 33,

108, 109, 154, 156, 302, 395, 646, 305, 152,
- 273, 355,810,856
34, 37, 47, 54, 60, 63, 66, 70, 106, 113, 114, 157, 159, 174, 182,218,
resin - 39 alcohol aldehyde
- 153 - 464 Alkyl amines - 464, 669 Alkyl aryl sulfonates - 658,669,
Alkylate, Alkylate, Alkylate Alkylation, butane, lighter (liquid, substituted sulfonates, aromatic
221,231,236,
240,242,247,252,263,273,299, 308,311,314,355,370,372,375,379,384, 788,810 vapor) - 669 387,388, 406, 757, 658,670,728, 764,773, 389, 392, 465, 393,394, 609, 611,
398, 399, 647, 650,
434, 440,
linear
- 182 - 182, 781 hydrocarbon - 182

benzene type
731,732,736, 777, 781,788,
740,741,749, 797,801,805,
810,822,839,846,857,876,882,886,889
Corrosive
Material
Index
903
Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum 122, 273,355,
chloride, chloride, chloride chloride
fluosilicic mixtures sludge
acid
- 182
solution
302,305,
308, 384, 398,
311,314, 388, 389, 399, 406, 650, 764, 773,
355,373, 392, 434, 777, 393, 440, 781,
374,375, 394, 395, 465, 466, 732, 735. 788, 797,
spent catalyst
- 182
379, 382, 396, 397, 736,
- 465 - 670
611, 632, 647, 749, 757,
658, 670, 725,
chlorohydrate chlorohydride chlorohydroxide chrome citrate etchant sulfate
- 182 - 70
- 109, 170, 182,247
801,805,810,822,839,857,882,886,889 Aluminum Aluminum Alums sulfate chlorohydride tartrate
- 857
- 781 - 182
- 611
- 170, 182
and deoxidizer
desmutter ethylate
- 182,839 - 658 fluoride - 27, 39, 54, 70, 108, 118,

156, 749, 159, 182,218,252,263, 399,407,440, 764, 611, 632, 777, 781,810,822, 393,397,
152, 154,
- 67, 114, 122,367,399,406,848,882 - 182 Amerex - 182 American ashes - 822 Amidation reaction - 764 Amides - 226
Amchem Amidosulfonic Amine Amine Amine Amines, 303, 882 Aminoazobenzene Aminobenzene Aminobenzoic Aminobutyric 2-Aminoethanol 822,856 corrosion acid (see Sulfamic inhibitors acid)
658, 670,736,
- 285, 286
857,886,889 Aluminum fluorosulfate Aluminum Aluminum Aluminum Aluminum Aluminum 156, 632, fluosilicate formate gel
hydrochlorides salt solution organic 306, 309, 736,
- 465, 658, 670
- 670 - 182
315, 355, 432, 810, 466, 467, 839,857,
- 658 - 611, 658

fixing bath - 182 - 27, 47, 54, 70, 113, 154, 398, 764, 777, 781, 797, 801,
- 42, 43, 70, 120, 226, 240, 285,

312, 797,801,805,
- 822
670, 732,
hardening hydroxide
- 658
(see Aniline) acid
159, 170,
182,218,252,263,273,
650, 658,735, nitrate
Aminobenzenesulfonic acid
- 658
805,810,822,839,846,848,857,882,889 Aluminum 384, 857 Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum 62,70,86, 165, 169, 242,251, 389,407, 670, 781, 857 Aluminum 182 Aluminum 182 Aluminum Aluminum 670,822 Aluminum Aluminum stearate salts - 149, 355, 367,810, sodium sulfate 848 potassium reduction sulfate, vapor and condensate and siding 726, 788, nitrate oxalate oxide solutions
- 27, 33, 47, 54, 70, 109, 159,

236, 242, 252, 263, 273, 355, 611, 658, 736,810,822,
- 658 acid - 252

(see Xylidine) 182, 240,247, 611, - 69, 108, - 182
170, 182, 218,
Aminodimethylbenzene
388, 389,465,
- 465, 764 - 611, 777,857
Aminoethoxyethanol Aminoethyl piperazine Aminophenol
- 182,839,857 oxychloride - 27, 54, 154, 252, 263 phosphate - 355 plating solution - 182 potassium sulfate (Alum) - 12, 19,
106, 170, 263, 434, 149, 355, 440, 150, 154, 373, 642, 156, 159, 384, 388, 650, 658, 773, 777, 856,
- 182 - 658 3-Aminopyridine - 670 Aminosalicylic acid - 658

Aminoxylene Ammonia 169, 375, 639, (see Xylidene) 53, 54, 63, 65, 67, 151, 154, 263, 658, 273, 663, 765, 156, 299, 159, 355, 142, 397, 736, 149, 252, - 1, 27, 33, 37,47, 182, 218, 247, 379,393, 642, 646, 732,
27, 33, 34, 36, 37, 39, 47, 50, 54, 57, 58, 61, 182, 205,218,221,232,236, 374, 382, 646, 647, 764,
70, 102, 122,
398, 440,469, 749, 764,
611, 632, 670, 725, 777, 788,
648, 650,
728, 731, 882 Ammonia,
728, 735, 797,801,
749, 757,
795,797,801,805,810,823,839,848,857, aqueous liquid (see Ammonium hydroxide)
805,810,822,846,
Ammonia Ammonia, 159,
gas mixtures
- 467, 468,469
355, 663, 671,788,
- 27, 65, 149, 154, 156, 157,
pot plant roofing
169, 182, 252,263, metal fumes
839,857,889 Ammonia-lithium Ammonia-nitric Ammonia-SOs Ammonia 33, 37,54, 118, 60, 122, 113, 114, 170, in solution
- 355
- 58, 154, 270, 658,
- 183 scrubber - 183

(household) - 13, 20
- 611
solution
- 130
sulFate - 1, 12, 18,27, 152, 154, 156,
Ammoniated Ammoniated Ammonium
mercury mercury acetate
63, 65, 66, 70, 106, 109, 142, 151, 231,236,240,242,247,
174, 182,221,
ointment - 231 - 40, 54, 122, 154, 159,
252,263,273,299,
183,252,263,273,611,658,736
904
Ammonium acid phosphate - 736, 764 Ammonium alum (see Aluminum ammonium sulfate) Ammonium aluminum chloride, molten - 736 Ammonium azide - 658 Ammonium benzoate - 183 Ammonium beryllium fluoride - 252 Ammonium bicarbonate - 47, 122, 156, 159, 170, 183, 273, 393, 398,469, 611, 658, 728, 736,765,777,781,788,839,857 Ammonium bifluoride - 12, 18, 27, 54, 70, 154, 218,231,252,263,470,658,671,822,839, 857,889 Ammonium bisulfate - 40, 156, 183, 777,810, 846,857 Ammonium bisulfide - 54, 263 Ammonium bisulfite - 34, 47, 159, 183, 658, 671,736,781 Ammonium bromide - 40, 60, 156, 252, 392, 393,399,407,671,725,777,857 Ammonium carbamate - 611, 658, 736, 749 Ammonium carbonate - 27, 47,54, 60, 63, 70, 113, 114, 118, 122, 152, 154, 156, 159, 169, 170, 183, 218, 232, 252, 263, 273, 355, 375, 379, 392, 393, 394, 395, 397, 398, 399,407, 434, 440, 469,611, 658, 671, 725, 728, 757, 765,777,781,788,797,801,805,810,822, 839,857,882,889 Ammonium caseinite .839 Ammonium chlorate - 736 Ammonium chloride - 12, 19,27, 33, 34,54, 60, 63.67.70, 106, 108, 109, 113, 114, 118, 123, 151, 152, 154, 156, 157, 159, 170, 183, 218, 221,236, 240,247, 252,263, 273,299,302, 305, 308, 311, 314, 355, 364,370,372,373, 374, 375,379,384,388, 389,392,393,394, 395, 396, 397,398, 399,407, 434, 440, 469, 470, 609,611, 632, 646, 650, 658,671, 725, 728, 731, 732, 735, 736, 741, 750, 757, 765, 773, 777,780,781, 788, 797,801,805,810, 823,839,846,857,882,886,889 Ammonium chlorostannate - 781 Ammonium citrate - 159, 183, 658 Ammonium dichromate - 54, 252, 263, 609, 611 Ammonium dihydrogen phosphate - 671 Ammonium diphosphate - 658 Ammonium fluoride - 27, 47,54, 60, 106, 108, 114, 118, 123, 149, 152, 154, 159, 183,218, 221,252,263,392, 393, 398, 399,407, 609, 611,658,671,736,750,765,773,823 Ammonium fluosilicate - 658, 672 Ammonium formate - 658 Ammonium hydrogen sulfate (see Ammonium bisulfate) Ammonium hydroxide - 1,2,4, 6, 9, 10, 17, 26, 27,32, 33,36,37,40,47,53,54, 60,61, 62,
63, 65,70,71,95,96,97,98, 102, 104, 108, 109, 111, 114, 117, 118,120, 122,142, 147, 149, 151, 152, 154, 155, 156, 159, 169, 170, 174, 182, 183,218, 221,226, 236, 239,240, 242, 247, 252, 263, 273, 285, 294, 296,297, 302, 305,308, 311, 314, 355, 367, 370, 372, 373, 374, 375, 379, 382, 383, 384, 388, 389, 392,394,395,396, 399,407,432,440,611 632, 639, 641, 642, 647, 650, 658, 663, 672, 725,728,732, 735, 736,741, 750, 765,773, 777,781, 788, 790, 792, 796,797,801,805, 810,822,823,839,846,848, 857,882,884, 886,889 Ammonium hydroxide mixtures - 467, 468, 469, 672 Ammonium hydroxylamine - 658 Ammonium iodide - 611 Ammonium lactate - 611 Ammonium lauryl sulfate - 183 Ammonium metaphosphate - 27, 54, 114, 123, 154, 156,252,263,273,658,810,823 Ammonium metatungstate - 183 Ammonium molybdate - 231, 609, 611 Ammonium muriate (see Ammonium chloride) Ammonium nitrate - 12, 19, 27, 33, 37, 47, 54, 60, 62, 65, 67, 71, 108, 113, 114, 118, 123, 152, 154, 156, 159, 170, 183,218,221,236, 240. 243, 247, 252, 263,273, 302, 305, 308, 311,314, 355, 370, 372, 373, 374, 375, 379, 384, 387, 388, 389, 392, 393, 394, 395, 396, 397, 398, 399,407, 434,440, 470, 609,611, 632, 650, 658, 672,728,732,733, 736, 757, 773, 781, 788,792, 797,801,805,810,823, 839,846,857,882,886,889 Ammonium nitrate (ammoniated) - 612, 781, 857 Ammonium nitrate fertilizers - 672,810 Ammonium nitrite - 273, 355, 810,857 Ammonium orthophosphate - 183 Ammonium oxalate - 156, 612, 658, 672, 728, 736,750,777,781,839,857 Ammonium perchlorate - 156, 440, 470, 612, 672,736,765,781 Ammonium persulfate - 27, 37, 47, 54, 71, 108, 113, 114, 123, 147, 154, 156, 159, 170, 183, 252, 263, 273, 355, 367, 370, 375, 379, 399, 407, 612, 658, 672, 728,777, 781,797,801, 805,810,823,839,857,882,886,889 Ammonium phosphate - 27,33,47, 54, 60, 62, 67, 71, 102, 108, 109, 123, 154, 155, 156, 159, 170, 183,218,221,252,263,273, 302. 305, 308, 311, 314, 355, 375, 379, 392, 393, 399, 407,471, 612, 632, 658, 672, 728,732,773, 777, 781,788, 797,801,805,810,823,839, 857,882,886,889 Ammonium picrate - 658 Ammonium polysulfide - 658
Corrosive Material
Index
905
Ammonium salts - 36, 149, 355, 367, 383, 648, 663,848 Ammonium salts, insecticide - 231 Ammonium salt of primary alcohol glycol ether sulfate - 108, 183 Ammonium silicofluoride mixture - 471 Ammonium sulfamate - 612, 658 Ammonium sulfate - 12, 19, 27, 33, 34, 47, 54, 60, 62, 65, 67,71, 106, 108, 109, 113, 114, 118, 123, 151, 154, 155, 156, 159, 170, 183, 218, 221, 236,240,243,247,252,263,273, 299, 355, 370, 372, 373, 374, 375, 379, 384, 388, 389, 392,393, 394, 395,396,397,398, 399,407,434,440,471, 472, 609, 612, 632, 650, 658, 672,732, 735, 736,750, 757, 765, 773, 777,781, 788, 797,801,805,810,823, 839,857,882,886,889 Ammonium sulfide - 27, 54, 106, 114, 118, 152, 154, 156, 183, 252, 263, 273, 355, 375, 379, 399,407, 612,658,725,728,857 Ammonium sulfite - 71, 183, 440, 658, 672, 781 Ammonium thiocyanate - 27, 108, 109, 113, 114, 118, 123, 154, 156, 170, 182, 183, 184, 231,252, 263,273,472, 612, 658, 781, 788, 810,857 Ammonium thiocyanide - 857 Ammonium thioglycolate - 231, 612 Ammonium thiosulfate - 109, 170, 184, 612, 839,857 Ammonium tungstate - 184, 400, 407, 658 Ammonium tungstate mixtures - 472 Amsco BKOH solvent - 184 Amseed oil - 142 Amy1 acetate - 27, 54, 60, 63, 65, 71, 108, 113, 114, 118, 123, 142, 149, 153, 154, 156, 159, 170, 184,218,227,236,241,243, 247, 252, 263,273, 284,299, 303, 306,309,312, 315, 355, 370, 372, 375, 379, 389,392, 393,398, 400,407,434, 612, 646, 650, 658, 672, 728, 732, 757, 777, 789, 797,801,805,810,823, 839,848,857,882,886,889 Amyl acetate, iso - 18, 156, 227, 620 Amy1 alcohol - 27,34,53,67, 69, 108, 109, 114, 118, 123, 142, 149, 153, 154, 156, 170, 184, 218,236,240,243,247, 252,263, 299, 355, 389, 393, 397,398,400,407,472, 612, 650, 672, 781, 789,797,801,805,810,823, 839, 848,856,857,882,886,889 Amylalcohol, iso- 10, 17, 60, 106, 156, 176, 286, 392,620 Amy1 alcohol, n - 10, 17, 174,225 Amy1 alcohol, tert - 10, 17, 823 Amylamine - 103,788 Amy1 borate - 273, 355,810,823, 857 Amy1 carbinol (see n-Hexanol) Amy1 chloride - 27, 34,54,71, 113, 114, 118, 123, 149, 151, 153, 154, 156, 170, 184,218,
252, 263, 273, 355, 393, 472, 632, 646, 658, 672,732,777, 789,797,801,805,810, 823, 848,882,886,889 Amyl chloronaphthalene - 273, 355, 810, 823, 857 Amylcinnamaldehyde - 226, 472 Amylene - 473 Amylene hydrate (see tert-Amy1 alcohol) Amy1 laurate - 658 Amylmercaptan - 232, 473, 612, 672, 781 Amy1 naphthalene - 273,355,810,823,857 Amy1 nitrate - 857 Amylphenol - 156,273,473,658,672,810 Amylphenol, sulfur substituted - 713 Amy1 phthalate - 142,227 Amy1 propionate - 658 Amy1 valerate - 612 Anderol esters - 355 Anethole - 65, 273 Anethym oil - 232 Ang-25 - 355 Anhydrite - 823 Aniline - 6, 7, 13, 20, 27, 33, 34, 40, 54, 60, 63, 65, 67, 71, 95, 108, 113, 114, 123, 149, 157, 753, 154, 157, 158, 159, 170, 174, 184, 218, 226, 236, 240, 243, 247, 252, 263, 273, 285, 296,299, 303, 306, 309, 312, 315, 317,318, 319, 320, 321, 322, 323,324, 325, 326, 327, 328, 329, 330, 331, 332, 333, 334, 335, 336, 355,370, 372, 373, 374, 375, 379,388, 389, 392, 393, 394, 395, 397, 398, 400, 407, 434, 440, 473, 612, 646, 650, 658, 663, 672, 735, 736,757,765, 780, 781,789,810,822,823, 839,846,848,857,886,889 Aniline chloride - 823 Aniline chlorohydrate - 27, 154, 263 Aniline compounds - 646 Aniline dyes - 756, 227, 355, 650, 773,870, 823, 839,858 Aniline, ferric chloride - 781 Aniline hydrochloride - 27, 60,71, 114, 149, 154, 159, 174, 184,221,252,263, 355, 392,400, 407, 658, 735, 736, 750, 765, 773, 777,810, 823,858 Aniline oil - 857,872 Aniline oils, fats - 273,355,823 Aniline paint oil - 156 Aniline salts - 823 Aniline sulfate - 159, 184, 658 Aniline sulfite - 434, 658, 672, 758 Aniline tint - 4 Animal fats and oils - 36, 67,84, 755, 756, 203, 279, 285, 355, 361, 382, 383,403,410, 646, 663,8 10,823 Anionic polyelectrolytes - 184 Anionic surfactants - 184 Anise oil (see Essential oils)
906
Corrosion
Resistant
Materials
Handbook
Anisole Anisole,
- 118, 123
boron trifluoride solutions
Aromatic
hydrocarbons
(see Hydrocarbons,
- 672
672,
aromatic) mercaptan - 200 - 184 Arsenates - 663 Arsenic - 367 Arsenic acid - 27, 54, 71, 106, 113, 114, 149, 154, Aromatic Arquad 156, 397, 170, 184, 218, 398,434, 787, 612, 796, 221,252, 797,801, 264, 805, 355, 758, 396, 773, 658, 726, 728,
Anodizing 773 Anolyte Ansul oil
- 34, 184, 212,221,
- 37
- 355,858 - 858 Anthium dioxide - 184 Anthracene - 663, 789 Anthracene oil - 53, 184, 658 Anthraquinone - 27, 54, 154, 263, 658 Anthraquinone disulfonic acid - 184 Anthraquinone sulfonic acid - 27, 54, 149, 154,
Ansul ether 264,658 Antibiotic Antifreeze 291, Antimony Antimony Antimony Antimony 673 Antimony 885,891 Antimony Antimony Antimony Antimony 108, 264, Antimony Antichlor Apache Apple Apple Apple Aqua tartrate - 400, 407 - 67, 273, 474, 673,858 sulfate - 658 trichloride - 27, 34, 54, 63, 71, 106, potassium salts 147, 149, 393, 398, 154, 170, 184,218,221,252, 735, 736,773,777,797,801, plating solution mixtures 305,308, chloride
779, 781, Arsenic 858 Arsenic
810, 823,
839,848,854,882,886,889 compounds, pentoxide salts neutral mixtures or acid
- 400, 407,
- 473, 474, 673

311, 313, 316, 358,364, 152, 375,
Arsenic Arsenic
plating solution
- 475 - 834,843,
885
- 5, 107, 123, 155, 156, 273, 284,
379,612,789,810,839,858 - 113, 123, 156, 273, 384,400,407,658,673,810,823,848 fluorochlorides oxychloride
- 673 - 393, 400, 407, 823 pentachloride - 108, 170, 184, 658, - 698,834,843,
- 67, 273 Arsenic trichloride - 355, 658, 788 Arsenic trioxide - 612, 658 Arsenous acid - 47, 159, 170, 184 Arsenous oxide - 736 Arylsulfonic acid - 27, 149, 154, 252, 264 Asbestos - 612 Ascorbic acid - 475, 658 Askarel (transformer oil) - 273, 355, 810, 823 Aspartic acid - 612 Asphalt - 27,71, 123, 156, 184, 274,299, 355,
475,612,632,650,789,810,823,839,858 Asphalt Aspirin Atabrine Atlantic emulsions, topping - 71, 247,839,858 - 63, 142, 230, 399, 406, 610, 612, 787,
788,839
- 22, 230
dominion F
- 356
(see also Air)
805,858,882 trifluoride (see Sodium
Atmosphere
- 612
industrial marine 648,650 mild rural
- 658
thiosulfate)
Atmosphere, Atmosphere, 639,642, Atmosphere, Atmosphere, Atrazine Atropine 60, 71, 114, 123, 375, 673, 184,218,236, 374, 612,646, Axle oil
- 94, 184,
431,433,475,476,638,639,642,648,650
Ant oil (see Furfural)
- 94, 431, 475, 476, 638,
- 184
acid (see Malic acid) brine
- 612
mush
- 433 - 94, 638, 639, 642, 648, 650
pomace regia
- 474
acid) 170, 174, 273, 407,
- 673
sulfate
Aqua fortis 149, 152, 239, 379, 731,
(see Nitric 154, 156, 264,
- 27, 40,53,54,
Avon cream cake Azelaic acid
- 142, 231 - 22
243, 252, 732, 736,
355, 373, 765, 787,
389, 392,393,400, 741,750,
795,810,
823,848,858,886,889
- 106 - 184 Azobenzene - 658 Azo dyestuffs - 728 Azotic acid - 823
BTX - 52
- 184 - 658 Arachidic acid - 658 Arachidonic acid - 823

Aqua regia, fumes Arabic acid Aragonite Argon (see Calcium carbonate)
Bacon, bacon fat Bactericide, Bakery products
- 14,227
based
phenate
- 184
300, 500
- 382
150, 200,
- 273 - 355,612.788,858 Armeen - 184 Aroclor - 71, 273, 355, 858 Aromatic fuel - 355
Arco C-2 100
Baltic types 100, Banana oil Barbeque Bardol B
- 274, 811
- 823
sauce
Banvel, concentrated
- 274,811 - 839,858
- 356,811,823,858
Corrosive Material
Index
907
Barite (see Barium sulfate) Barium acetate47,159, 170, 184 Barium bromide -231 Barium carbonate-27,47,54,71, 108, 113, 114, 118, 123, 142, 152,154, 156,159, 170, 184,218,231,252,264,274,393,397,434, 609,613,650,658,735,736,758,765.7777, 782,788,797,801,805,811,823,858,882, 889 Barium chlorate 658 Barium chloride 27,33,47, 54, 60, 63, 65,71, 108,113,114,118, 124,154,156,159,170, 184,218,221,231,236,240,243,247,252, 264,274,303,305,308,311,314,356,373, 374,375,379,384, 388,389,392,393,397, 398,400,407,434,440,476,609,613,632, 650,658, 673,735,736,750,758,765,773, 777,782,788,811,823,839,858,886,889 Barium cyanide- 72, 658 Barium fluoride 736 Barium hydroxide (hydrate)9,28,47,53,54, 60,72, 113, 114,118, 124, 151,154,156, 159, 170,184,218,236,243,247,252,264, 274,299,302,305,308,311,314,356,379, 384, 389, 392, 393, 394, 395, 397, 398,400, 407,434,613,650,658,673,728,732,736, 758,765,777,788,795,797,801,805,811, 823,839.858,882,889 Barium nitrate 54,72, 156,221, 236,243,264, 379,384,388,389,407,434,477,609,613, 658,728,735,736,758,765,773,777,782, 839,858 Barium peroxide- 658 Barium polysulfide658 Barium salts 67, 124, 149, 156, 356, 367,848 Barium sulfate 28, 47, 54, 72, 109, 113, 114, 118, 124, 151,152, 154, 156,159, 170, 184, 221,247,252,264,274,356,373,374,434, 650,658,735,758,773,777,782,788,811, 823,858,886,889 Barium sulfide 28, 47,54, 63, 72, 114, 118, 124, 151, 154, 156,159, 170, 184,218,236, 243,252,264,274,303,305,308,311,314, 356,367,388,389,397,398,400,407,613, 650,658,788,797,801,805,811,823,858, 882 Bases- 116, 120,220,240,285,302,432 Bath oil,bubble 22 Bath oil, pine - 14,23 Bath salts, Coty - 14 Batteryacid (see Sulfuric acid) Bauxite- 613 Baygon-273 Bay oil-839,872 BayolD- 356 Beans - 613 Beer - 1, 15,23,28,37,47,54, 60,62, 65, 67,
72,106,114, 118,124, 149,154,156,159, 170,184,227,238,252,264,274,299,356, 370,372, 373,374.375,379,382, 392,440, 613, 632, 650, 735, 788,811, 823,839,858, 886,889 Beer,brewing- 477 Beeswax- 613 Beeswax, bleachsolution 673 Beet juice - 124,227 Beltoil- 156 Bengalgelatin 823 Bentec- 184 Benzalchloride (benzyldichloride) - 174, 184 Benzaldehyde- 1,20.28, 34, 40, 53,54, 63, 65, 72, 109, 118, 124, 142,149,154,158, 170, 174, 184, 185,218,226,239,241, 247,252, 264,274,299, 303,306,309, 312,315,317, 318,319,320,321,322,323, 324,325,326, 327,328,329, 330,331,332, 333,334, 335, 336,356,375,379,393,398,400,407,613, 658,663,736, 765,789,797,801,805,811, 823,839,848,858,882,886,889 Benzaldehydeconcentrate 1 Benzaldehyde sulfonicacid 658 Benzalkonium chloride252,264 Benzamide-658 Benzanthrone- 658 Benzedrine-142,232 Benzene (benzol)1,2,4,6,7,9, 11, 18,28,33, 34,40,52, 53,54, 60, 61, 62, 63, 65, 67, 72, 95,104,106,108,109,111,112,113, 114, 117, 118, 124, 142, 147,149, 151, 153,154, 156, 158, 160, 169, 170,174, 184,218,223, 224,229.236,239.243,247,252,264,274, 285,291,293, 296,299, 304, 306, 309, 312, 315,356,370,372,373,374,375,379,383, 384, 387, 389, 392, 394, 395, 397, 398,400, 407.434.477.478, 613,632, 651, 658, 663, 673,736,758,765,782,789,792,797,801, 805,811,823,839,846,848,859,882,886, 889 Benzene in kerosene-47,160 Benzene in methanol-285 Benzene carbinol -823 Benzene carboxylic acid (see Benzoic acid) Benzenedisulfonicacid108,156,184 Benzene hexachloride (Lindane)-34,229, 478,613,658 Benzene monochloride (see Chlorobenzene) Benzenesulfonicacid -28,37,47,53,54, 63.72, 108,114, 124, 160, 170, 174, 184,218,236, 240,243,247, 252,264,356. 373,374, 375, 379,388, 389, 398, 400, 407, 434, 658, 673, 758,765,782,787,811,823,839,848,854 Benzenesulfonylchloride174,400,407 Benzidine-658 Benzidinedisulfonic - 658 acid
908
Corrosion
Resistant
Materials
Handbook
Benzidine-3-sulfonic Benzil Benzilic Benzine
acid
- 658
Beryllium Beryllium Beryllium
chloride fluoride
- 613, 658
- 659
- 613
acid
- 658
ether) acid
sulfate - 659
(see Petroleum
Betula oil Bichloride
Benzobenzoic Benzocatechol Benzoflex
- 658 - 658
- 824 Betz sulfite - 185

of mercury (see Mercuric chloride) (dichromates)
- 184 Benzoic acid - 28,47,
Bichromates Biocide Bismuth
- 663
53,54,63,67,72, 106, 108, 113, 114, 118, 124, 142, 149, 151, 153, 154, 156, 160, 170, 184, 218,221, 225,236, 243,252,264,274,356,369,371,373,374, 375,379,382,384,388,389,393,394,395, 398,400,407,434,440,613,646, 651,658, 673, 728, 736, 758, 765, 773, 779,782,787, 797,801,805,823,839,848,854,882, 886, 889
(see Benzaldehyde) acid ointment
- 185
solutions carbonate
Biological
- 884 - 28, 54, 114, 124, 149, 152,
154,156,253,264,393,398,811,824 Bismuth-lead Bismuth, Bismuth Bismuth Bismuth Bisulfite Bitter eutectic, molten nitrate molten - 642, 673, 736 - 642, 646, 732, 736
- 613 - 824 - 824

- 109
oxycarbonate subcarbonate in scrubber
Benzoic aldehyde Benzoic resin Benzol Benzole-alcohol
Benzoic and salicylic
- 230
almond,
oil (see Essential oils)
- 232
Bitumastic Bitumen
(see Benzene)
- 23,811 - 63
paint juice
mixture - 375, 379 - 823 Benzol still residue - 156 Benzonitrile - 72, 157,233,241,247,658,859 Benzol hydride - 823
Bituminous Blackberry
- 613
sulfide)
Black ash (see Barium
Benzophenol Benzophenone
- 613 Black chrome bath - 185 Black liquor - 28, 33, 34, 37, 40, 44, 54,90,
114, 147, 218, 221. 540, 541, 149, 651, 151, 154, 673,728,762, 156, 160, 373, 773, 253,264,274,356,
109,
- 356,658,811 Benzotrichloride - 175, 185, 356, 658 Benzotrifluoride - 658 o-Benzoyl benzoic acid - 47, 159, 185 Benzoyl chloride - 53,60, 124, 157, 175, 185,
252,299,375,379,392,478,613,658 Benzoyl Benzoyl Benzyl chloride peroxide acetate vapors
170, 185, 374,439, 782,783,
8 11,824,848,859 Black point 77 Blast furnace
- 356
sulfate)
Blanc fix (see Barium gas Bleach (see Sodium
- 478
375, 379, 400, 407, 118,
- 156,356,811,824
hypochlorite)
- 658,839
- 142, 227,
Bleached Bleaching
pulp
- 185
613,658 Benzyl alcohol 124,157, 379,
- 53,60,63,
309,
65, 67, 72, 106, 185,218,225,252, 312,315,356,375, 658,728,811,822,
158,160,175,
with KBr - 185 - 373,374,673,729,859 Bleaching powder - 285, 651, 780,788,824,825 Bleach, ferricyanide liquor 840,860 Bleach liquor Blood (pulp mill) - 109 Bleach lye - 114
263,274,303,306, 392,400,407,613, 824,839,848,856
- 253 - 185,233,356,811,824,859 Benzylbutyl phthalate - 658 Benzylcellulose - 658 Benzyl chloride (a-chlorotoluene) - 40,47,
Benzylamine Benzyl benzoate 160, 175, 307, 310, 185,218,229,241,247,253,304, 312, 315, 356, 375, 379,383,
- 15, 23, 72, 156, 375, 379, 396, 440, 735 - 185 Blue salts - 824
Blow gas absorber Blue vitriol 72, 384, Bluing (see Copper sulfate, basic)
- 124, 233 Body fluids - 732

Boiler acid phosphates Boiler feed water Boletic acid
- 787 - 788
400,407,658,811,822,824,839,859 o-Benzyl-p-chlorophenol Benzyl cyanide
compounds
- 40
chloride)
- 824
- 234
(benzal
Bonderite
- 185
Benzyl dichloride Benzylethylaniline Benzylphenol Benzylphenol Benzylsulfanilic Benzylsulfonic
- 174, 184
Bone oil - 839,872 Boracic acid (see Boric acid) Borax (see also Sodium tetraborate) 106, 113, 114,
Benzyl ether - 1, 230
- 658 - 658
- 22, 28, 40,
- 658 salicylate acid acid
- 658 - 765
124, 142, 149, 154, 156, 157, 170, 185,218, 231,247, 253,264, 274,299, 356, 392, 396, 609, 632, 651, 659, 782, 788, 797,801,805,811,824, 55, 60,67,72,88, 839,848,859,882,886,889
Corrosive
Material
Index
909
Bordeaux
mixture
- 67, 156, 185, 274, 356, 613,
Brine with sodium carbonate Broke chest fumes Brom Brom Bromic 113-356 114 acid
- 414, 415,417
651,811,824,859 Boric acid - 17, 28, 33, 37, 53, 55, 60, 63, 67, 72, 109, 113, 114, 155, 314, 156, 356, 236,243, 384, 388, 646, 253, 369, 124, 142, 175, 149, 302, 394, 609, 151, 152, 305, 375, 395, 613, 308, 396, 632, 154, 311, 398, 642, 157, 170, 371, 185,218,221,225, 379,382,
- 185
- 356 - 28, 55, 114, 149, 151, 152, 154,
264,274, 393, 478, 674,726,
155,218,264,659 Bromides Bromine 72,73, 157, 372, 642, 233,240, 646,
373,374,
389,392,
- 663 - 1, 28, 36, 40, 53, 55, 60, 63, 65, 67,
108, 158, 114, 124, 142, 149, 154, 299, 156, 370, 160, 169, 392, 651, 170, 393, 659, 175, 185, 218,221, 356,
400,407,434,440, 651, 663, 773,779,
728,736,758,765,
782, 787,797,801,805,811,824,
247, 253, 647,
264, 285,
839,848,854,882,884,886,889 Boric acid mixtures Boric copper sulfate Borneo1 in butanol Bornyl Bornyl Bornyl acetate chloride formate - 659 - 659 - 659
375, 379,
397, 398,400,407. 674, 732, 733, 736, 797, 792,795,
- 478 - 274
- 13
750.765,774, Bromine Bromine, Bromine, Bromine Bromine Bromine - 479 Bromine chloride methyl trifluoride vapor water
780,782,789,
801,805,811,824,839,846,848,859,882
- 253
acid, sulfuric solution alcohol acid - 285 - 736, 765
hydrochloric pentafluoride
Boron - 790 Boron fluids (HEF) Boron fuels - 839,859 Boron trichloride Boron trichloride Boron trifluoride 782,789 Boron trifluoride Borosilicates Bourbon etherate - 479, 674
- 356 - 478, 659, 674

mixtures
- 356 - 356,824
647,
- 55, 124, 149, 185,264,

765,848
674,731,736, 124, 149, 243, 264, 154, 356,
- 28, 33, 37,55,

156, 388, 160, 389, 392,
60, 63, 114, 118, 185, 218, 236, 400, 407, 736,
- 28, 63, 479, 613, 659, 674,
170,
780,849,886,889 Bromobenzene, mono 315,
- 613 - 185
- 55, 106, 253, 304,307,

bromide) 357,
Bottle washer solution Bowl cleanse 107, 356, Brandy
310,312, Bromobutane
356,363,663,824,859,871 - 11, 18, 156,275,
- 227 - 185 Brake fluid - 5, 20, 52, 96, 97, 98, 104, 106,
117, 118, 357, 359, 185, 233,274,285,286,301, 363, 366, 383, 663,8 11, 824,
(see Butyl
Bromochloromethane Bromo
659,750,812,824,825,840,860 chlorotrifluoroethane (see Ethyl
- 356
Bromodichlorophenol Bromoethane Bromoform
- 39, 41, 43, 44, 45, 46 bromide) 659 bromide) bromide) 613,
839,859
- 124,238
solution 160,
- 37,253,
Brass plating
- 30, 47, 58, 85, 115, 135,

185, 259,269, 368,834,
Bromohexane Bromomethane Bromotoluene Bromotrif 885,891 Brown acetate
(see Hexyl
150, 153, 154, 843,884,885,891 Brass pickling Brayco
(see Methyl
- 55,253,264
solution
solution
- 674
luoro methane
- 356 - 356 - 674 - 28, 149, 154
Bronze plating
- 832 - 160, 185,843,884,

acetate)
Bray GG-130 Brazing flux Breeder Bret 710 Brewery
(see Calcium
pellets, fish
Brown stock washer hoods Buffer pH 4.0
- 185
- 356
slop - 839,859 fumes
Brew kettle Brilliantine Brimstone Brine, acid
- 185 - 14, 22
pH 7.0
hair dressing (see Sulfur)
- 4, 52 -4 pH 10.0 - 4, 52
solution materials penetrox
Build detergent Bulk (dry) Bunker Burndys oil
- 221, 253, 774 Brine, alkaline - 221, 253, 774 Brine, chlorinated acid - 253
with chlorine - 156 - 674 Brine solution - 2, 28, 34, 55, 62,88, Brine saturated Brine slurry 156, 169, 185, 632, 190,218,264,274, 642, 646, 415,417, 839,859
- 186 - 613
- 274,292,356,811,824,859 A - 26
potassium 613, sulfate) 154, 156, 632,789, - 11, 20, 28, 55, 73, 149,
Burnt alum (see Aluminum 1,3-Butadiene 109, 124, 792, 356,414, 170,218,247,253,264,356, 8 11,824,849,859 Butadiene latex
651, 674,729,
- 186
910
Butane-
1,28, 55, 65, 67,73, 124, 149, 154, 156, 170, 229, 247, 253,264, 274, 299, 356, 479, 480, 613, 632, 651, 659, 674, 789,811, 824,840,849,859 Butanediol - 113, 114,253, 659,849
Butylated
hydroxytoluene
(BHT)
- 147
Butyl benzoate Butyl Butyl bromide carbitol
- 356,659,824,859
- 160
Butylbenzylphthalate
- 218, 253 Butyl butyrate - 227, 356, 659,859

(see Diethylene tert glycol monobutyl 879 glycol monobutyl ether)
Butanethiol Butanol Butanone
- 233
(see Methyl ethyl ketone)
(see Butyl alcohol) 186,225,824
Butylcatechol, Butyl Butyl Butyl Cellosolve Cellosolve Cellosolve chloride, ether)
- 365,837,
2-ButoxyethanolBis(2-Butoxy Butozyl Butter 274, - 379
(see Ethylene acetyl adipate
2,2-Butoxyethoxyethanol
- 186 ethyl)phthalate - 253
ricinoleate - 293, 356
- 614
- 14, 22, 67, 124, 142, 156, 227, 238,

304, 307,310, 313, 316, 356,382, 613,
663,788,824,840,859 Buttermilk Butter Butter Butter
- 73, 156, 440,788,840,859
of tin (see Tin chloride) of zinc (see Zinc chloride) oil
- 73, 218, 229, 253, 659 iso - 661 Butyl chloride, n - 175, 292, 615 Butyl chloride, set - 175, 615 Butylene - 28, 55, 73, 218, 247, 253, 264, 356,
Butyl chloride Butyl 632,789,849,859 Butylene glycol oxide
- 811
- 9, 10, 17,26,28, 111, 118, 157, 160, 37, 40,47,55, 142, 147, 149, 120, 124,
Butyl acetate 154, 156, 241. 299, 389, 356,
Butylene Butyl Butylethyl
- 47, 63, 160, 186 - 186

ether)
63, 73, 108,
ether (see Dibutyl alcohol
170, 186,218,227,236, 290,291,293, 374, 375, 379, 614, 384, 659, 373,
- 856
243,247,253,264,274, 370, 372, 777,789, 393, 397,398,400,407,434,
Butyl glycolate Butyl Butyl Butyl Butyl Butyl Butyl Butyl Butyl Butyl hydride lactate
- 659
- 824
674,758, Butyl acetate, Butyl acetate, Butyl acetate Butylacetyl Butyl alcohol 47,55, 110, 159, 273, 379, 114, Butyl acrylate
797,801,805,824,840,
842,849,859,882,886,889 iso - 11, 18, 142, 620, 789 set
- 17, 156
boiling
mixture, ricinoleate (butanol, 124, 142, 356,
- 413
- 356, 480, 674,824

methyl 147, 370, propanols) 106, 154, 374, 480,
- 218, 253, 356,824 - 28,40,

156, 375, 614, 108, 109, 253,264,
- 370,372, 614 - 218, 253, 659 mercaptan, tert - 365,811,837,879 methacrylate - 157 octadecanoate - 824 oleate - 356, 824,859 oxalate - 659 phenol - 28, 55, 149, 154, 218, 253, 264,
mercaptan phenol, phthalate stearate urethane p-tert - 694
480,659,663 Butyl Butyl Butyl 859 Butyl
60, 63, 65, 67, 69, 103, 170,215,236,240, 291, 293, 388,
149, 153, 243, 247, 372, 373,
- 28, 73, 108, 124, 142, 186, 227, - 55, 156,264, - 659
356, 659,811,824,
241,247,253,264,659,859
389,392,393,400,407, 735,789,
651,663, Butyl alcohol, 226, 277, 856,868 Butyl alcohol, Butyl alcohol, 159, Butyl alcohol, 837,879 Butyl alcohol, ketone Butylamine Butylamine, Butylamine, Butylamine, Butylated
797,801,805,811,824, 142, 156, 170, 198, 848, 154, 175, 154, 365,
832,839,848,849,856,859,882 iso - 10,81, 360, 620, 789,815,830,839, 149,
- 28 - 149, 154,264 Butyraldehyde - 40, 156, 170, 253,299,

Butynedial (erythrital) Butynediol 309, 312, 315, 356,480, 614, 840,859 Butyric
303,
306,
659,811,824, 108, 371, 674, 797,
n - 10, 17,28,54, set - 10, 17,28,
186,218,225,263 47, 54, 149, 186,218,225,226,263 tert - 10, 17, 186, 218,225, ethyl hexylacetate, diisobutyl 356,
acid - 1, 28, 34, 47, 53, 63, 73, 106, 149, 154, 379, 481, 156, 160, 382, 614, 389, 632, 779, 170, 356, 393, 651, 225,236, 374, 375, 441, 736, 243,253,264, 369, 659,
109, 114, 218, 373,
175, 186, 398,400,
407,434, 726,728, Butyric Butyryl C-56
758, 765,
782,787,
- 186 - 28, 73, 157, 158, 186,247, - 218,240 - 2 18 tert - 218

n set hydroxyanisole
801,805,811,824,840,849,882,886,889 anhydride chloride
- 233, 614
- 229
788,811,824,859
Butyrolactone
- 659
- 186
102 - 190
- 147
CWT
Corrosive
Material
index
911
Cacodylic acid - 481 Cadmium bromide - 231 Cadmium chloride - 47, 160, 236, 243, 388, 389, 407, 614,750 Cadmium cyanide - 28, 55, 154, 264, 659 Cadmium, molten - 642, 780 Cadmium nitrate - 236, 243, 388, 389, 407 Cadmium plating solution - 30, 47, 58,85, 115, 135, 150, 153, 154, 160, 186, 259,269, 368,834,885,891 Cadmium salts - 149, 156,849 Cadmium stearate - 231 Cadmium sulfate - 221, 236, 243, 388, 389, 434,481,614,659,758,774,782 Caffeine - 142, 230 Caffeine citrate - 264 Cajeputene (see Limonene) Cake alum (see Aluminum sulfate) Calamine - 824 Calcine liquors - 356, 811, 824, 859 Calcite (see Calcium carbonate) Calcium acetate - 356, 659,811,824, 859 Calcium acid phosphate - 659 Calcium arsenate - 65, 274, 663, 796 Calcium benzoate - 659 Calcium bicarbonate - 657, 659, 765 Calcium bisulfate - 152, 156, 218, 221, 274, 774, 797,801,805,811,840,859,882 Calcium bisulfide - 55, 67, 114, 154, 186, 218, 253,264,274,859,889 Calcium bisulfite - 47, 55, 60, 73, 125, 154, 160, 170, 186, 221, 236, 243, 253, 264, 274, 299, 356, 367, 375, 379, 384, 388,389,392, 396, 434, 632, 651,657, 659,732, 736, 758, 765, 774,782, 788, 797,801, 805, 811,824,860, 882,886 Calcium bisulfite, bleach liquor - 253 Calcium bromide - 231,481, 659, 674, 750 Calcium carbide - 614 Calcium carbonate - 28, 47, 55, 73, 113, 114, 118, 125, 151, 152, 154, 156, 160, 169, 170, 186, 218, 253,264, 274, 356, 385, 434, 441, 614, 629, 657, 659, 663, 674, 728, 735,736,758, 765, 777, 788, 797, 801, 805,811,824, 860, 882,889 Calcium chlorate - 28, 34, 47, 55, 108, 114, 118, 125, 156, 160, 170, 186, 218, 253,264, 274, 375, 379, 393, 398, 434, 659, 674, 728, 758, 777,782,797,801,805,811,824,860,882 Calcium chloride - 1, 12, 19, 26, 28, 33, 34, 36, 37, 47, 55, 60, 63, 65, 67, 73, 106, 108, 109, 111,113,114,118,120,125,147,151,152, 154, 155, 156, 157, 160, 170, 175, 186,218, 221, 231, 236, 240, 243, 247, 253,264, 274, 299, 303, 305, 308, 311, 314, 356, 370, 372, 373, 374, 375, 379,382, 383, 385, 387, 388, 389,392,393,394,395,396,397,398,400
407,423, 434, 441, 481, 482, 609, 614, 642, 646, 647, 651, 659, 663, 675, 728, 732, 735, 736, 740, 750, 758, 765, 774, 777, 782, 788, 791 t 797,801,805,811,824, 840, 860, 882, 886,889 Calcium chloride brine - 675 Calcium chloride in alcohol - 63 Calcium chlorohypochlorite - 156 Calcium chromate - 614, 659 Calcium citrate - 482 Calcium cyanide - 356 Calcium dihydrogen sulfite and SOs - 659 Calcium disulfide - 659 Calcium fluoride - 659, 750 Calcium gluconate - 614, 659 Calcium hydrosulfide - 482 Calcium hydroxide - 9, 17, 28, 36, 48, 53, 55, 60, 67,73, 113, 114, 118, 125, 151, 154, 155, 156, 160, 170, 186, 218,221, 226, 236, 243,253, 264,274, 299, 302, 305, 308, 311, 314, 356, 370, 373, 374, 375, 382, 385, 387, 388, 389, 392, 393, 394, 395, 396, 397, 398, 400, 407, 482, 614, 632, 651, 659, 663, 675, 728,732, 735, 736, 765, 774, 777, 782, 788, 792, 797, 801,805,811,824,840,860,882,889 Calcium hypochlorite - 12, 19, 33, 35, 37, 40, 48, 53, 55, 60, 63, 67, 73, 106, 113, 114, 118, 125, 142, 147, 152, 154, 156, 160, 170, 175, 186, 218,221,231,253,264,274,285,299, 303, 305, 308, 311, 314, 356, 367, 370, 372, 373, 374, 376, 379, 380, 392, 393, 394, 395, 396, 397,398,400,407,482, 614, 632, 651, 675, 689, 726, 732, 735, 736, 750, 765, 774, 777, 782, 788, 797, 801,805,811, 824,840,849, 860,882,886,889 Calcium lactate - 483, 659 Calcium, magnesium, sodium chloride solution - 186 Calcium nitrate - 28, 33, 48, 55, 65, 74, 106, 113, 114, 118, 152, 154, 160, 170, 186, 218,236, 240,243, 247, 253, 264, 274, 356, 373, 374, 376, 379, 385, 388, 389, 393, 400, 407, 614, 659,812,824,860 Calcium oxalate - 659 Calcium oxide (lime) - 55, 67, 82, 172, 186, 231, 253, 264, 278, 609, 614, 620, 652, 780, 788, 790,842,851,869 Calcium oxychloride (see Bleaching powder) Calcium oxysulfide - 29, 57,81, 132, 156, 253, 267,278,361,652,869 Calcium phosphate - 12, 19, 28, 118, 125, 221, 356,483,659,774,860 Calcium propionate - 147, 614 Calcium pyridinesulfonate and sulfuric acid 659,675 Calcium salts - 67, 125, 149, 156, 356, 367,849, 860 Calcium silicate - 274, 356, 614,812
912
Corrosion
Resistant
Materials
Handbook
Calcium Calcium Calcium Calcium 109, 169, 374, 407,
silicoaluminate stearate - 659 sulfaminate 113, 170, 435,
- 824
Carbon dioxide 118, 149, 253, 152, 154, 393, 397, 676, 758, 156, 264, 160, 373, 860 Carbon dioxide, 441, 632, 849,882 Carbon dioxide, Carbon disulfide 149, 151, 304, 380, 659, 299,
- 1, 28, 35, 48, 53, 74, 108, 156, 160, 380, 400, 408, 484, 485,
114, 609,
154, 376,
170, 186, 233,247,
- 659 125, 387,
sulfate - 1, 12, 19, 28, 33, 48, 55, 74, 114, 118, 385, 186,218,231,247,253, 483, 646, 659,
614,651,663,676,728,736,789,825,840, dry
- 55, 125, 218, 264, 274, 357,

651, 797,801,805,812,
376, 380,
398, 400, 777, 788,
639,
642,
797,801,805,812,824,840,860,878,882, 886,889 Calcium Calcium Calcium sulfide sulfite
wet
- 55, 125, 186, 218, 264, 274,
357,632,642,797,801,805,849,882
- 253, 274, 357, 659,812,824 - 48, 118, 125, 160, 357, 483, - 357 - 788,840,
- 2, 13, 20, 26, 28, 33, 37, 40, 48,

111, 156, 313, 389, 758, 112, 157, 315, 392, 774, 114, 160, 253, 357, 393, 614, 777, 121, 125, 154, 310, 385, 170, 175, 264, 274, 370, 372, 394, 395, 632, 646, 789, 797,
55, 60, 63, 65, 106, 153, 307, 383, 186,218, 299, 376, 397, 651, 221, 236,
659,675 thiosulfate Calgon (sodium 849,860 Caliche liquors - 659 chlorinated 68% hexametaphosphate)
243, 247,
- 156, 357, 812, 825,860,861 - 186
398, 400,
407,435,485,
Camphene Camphene, Camphor Camphor Canada
663, 728, vapor - 659
802,806,812,825,840,849,860,882,889 Carbon disulfide Carbon fluorides Carbonic acid 149, 151, 254,265,274, 435, 441, 614, 779, 758, 774, Carbon Carbon 152,
- 63, 142, 186,230,264,398,435,

oil - 114, 125,849 acid - 659 Balsam
- 186
614,659,663,758,780,789,860 Camphorsulfonic
- 28, 48, 55, 63, 74, 114, 118, 125,

154, 156, 357, 646, 367, 659, 160, 393, 170, 396, 186, 221, 397,398, 735, 750, 840,849,
- 15,23 Can cleaner, acidic - 186 Candelilla wax - 676 Canning plant waste - 186 Can treatment - 186 Capella AA - 860 Capric acid - 186, 659 Caproic acid - 285, 614 Caproic aldehyde - 357, 659,825 Caprolactam - 614
Caprolactone Capronitrile Caproxyl Caproyl Capryl Caprylic Caprylic Carbazotic Carbamate Carbamide Carbazole Carbitols Carbitol ethyl Carbolic Carbon - 659, 676
676, 728,
782, 787, 812,825,
854,882,886,889 methyl cellulose 154, 376, monoxide 151, 357,
- 48 - 28, 48, 53, 55, 67, 74, 114,

156, 160, 380, 435, 170, 186,253, 485, 663, 758,
125, 149, 264, 299, 789,8
12,825,840,849,860 - 659 (tetrachloromethane) - 1, 2, 106, 108, 142, 170, 175, 296, 299, 372,376, 392, 393, 485, 615, 33, 34, 37, 40, 48, 52, 117, 154, 118, 158, 121, 125, 160, 241,243,247, 370, 389, 435, 774, 825, 676, 765,
Carbon tetrabromide Carbon tetrachloride
- 842
alcohol
4, 7, 9, 11, 18, 26,28, 109, 111, 112, 151, 274, 310, 397, 651, 743, 114, 153,
alcohol alcohol acid
- 825 - 825
53, 55, 60, 63, 65, 67, 74, 95, 104, 147, 149, 186,218, 253, 264, 304, 307, 812, 860 394,395, 632, 735, 642, 736,
- 825 - 48, 53, 55, 108, 109, 160, 170, - 825
221,229,
236,239, 357,
186,218,253,264,614 alcohol acid (see Picric acid)
285, 291, 312, 315,
292, 293,
377,380,381,383,385,387, 398, 400,408, 659,663, 750, 758,
- 357,796,
(see Urea) (Diethylene
- 186,825
glycol ethers)
694,726,728, 777,782, 840,846,
- 226, 233, 659 - 253,789

solvent ether) acid (see Phenol) (see Diethylene glycol mono-
789, 792,
797, 802,806,812, vapor
849,860,882,884,886,889 Carbon tetrachloride Carboseal Carbowax gas antileak
- 186 - 15, 23
compounds
- 483,484,
water
614, 676 (see Water, carbonated)
Carbonated Carbonated Carbon Carbon Carbon
- 160,187 Carboxybenzene - 825 Carboxymethylcellulose Cardamon (spice) - 659 wax - 659 - 160, 187
beverages (see also Soft drinks)
156,651,860 beads, water treatment bisulfide dichloride
- 131
- 186
Carnalite Carnauba Carotene
(see Carbon disulfide)
- 233
- 676
Corrosive
Material
Index
973
Carpet
shampoo solution
Carroting Carrot, Carrot Carter Casein
- 187,207 - 485
Cetyl alcohol Cetylic Ceylon Chalk gelatin
- 126, 143, 225, 659

acid)
acid (see Palmitic
Carrot juice oil
- 227 - 238 - 274, 812
- 825
liquified
- 825 - 126
smoke) - 840 - 305, 307, 310, 313, 316 (liquid
- 125
oil
Char-co-sol Charsol Cheese
motor
- 28, 275, 382, 485,825, 860 Cassia oil - 142,233 Castor oil - 28,48, 55, 60, 67, 106, 113, 114,
125, 218, 126, 233, 142, 149, 254, 265, 154, 156, 160, 170, 187, 304, 663, 275, 291, 293,299,
Chassis grease Cheese spread Cheese water Chemical Chemical Chemical Chem- Rez Cherries, Cherry
- 62, 382, 615, 788 - 105

- 187 control equipment - 729 drums - 729 pollution processing - 729
307,310,313,316,357,368,393,651, 788,812,825,840,849,860,872 Castro1 325 Catalytic Cationic
- 285
feed
- 187
refining quaternary
- 187
382, 788,
- 187 - 14, 22, 38, 156,227, - 15,23

hydroxide)
Catsup (ketchup) 840,860 Caulking
compound
- 143, 227, 615 - 486, 615 Chestnut wood extract - 676 Chicken gravy - 227 Chicken soup (MBT) - 227
processed juice Chile niter, nitrate, oil saltpeter (see Sodium nitrate)
Caustic baryta
(see Barium - 729
Caustic etch tank vapor Caustic handling Causticized liquor
- 187
- 825 China clay slurry - 187

Chinabean China wood oil (see Tung oil) Chinese gelatin Chloracetic Chloral hydroxide)
- 426
oxide)
Caustic lime (see Calcium Caustic lime of soda - 891 Caustic mixtures
- 825
acid)
acid (see Chloroacetic
- 676
hydroxide)
Caustic potash (see Potassium Caustic soda (see Sodium Caustic, spent oil Cedarwood Celery salt Cellosolve Cellosolve Cellosolves ethers) Cell putty Cellugard Cellulose Cellulose 782,825 Cellulose Cellulose Cellulose Cellulube acetate nitrate butyrate
- 187 - 143,233
- 175, 254, 393, 400, 407, 659, 789 Chloral and MCB - 175 Chloral alcoholate - 40 Chloral hydrate - 28, 55, 63, 149, 154, 175, 254,
265 Chloramine Chloranil
- 227 Cellophane - 233,486

(see Ethylene acetate glycol monoethyl glycol ether) (see Ethylene glycol monoethyl
- 55,265,
- 659
659 - 659
Chloranthraquinone Chlordane 615,659 Chlordane, Chlorendic Chlorextrol
- 15, 24, 67, 175, 229, 275, 357,

5% in water anhydride
ether acetate) (see also Ethyl monoalkyl
- 74, 247, 254, 659 - 187 - 275,357,812 - 156, 615, 663,860 acetate - 221, 233, 432, 615, 659, 774, - 615, 659
- 156 - 187
Chlorethanesulfonic
acid - 659 659, 676,
- 357 Chloric acid - 28, 74, 149, 154,265,

732,779,797,802,806,854,882 Chloride Chloride Chloride cracking salts (water)
- 664, 665 - 383, 445, 663

- 154, 430, solvent 445
- 233, 659
- 659
tripropionate
Chlorinated Chlorinated Chlorinated Chlorinated 825,860 Chlorinated Chlorinated 733,840 Chlorinated bleaching Chlorinated Chlorinated Chlorinated
aromatic benzene
- 275, 357,812,825,840,860 Cellutherm - 357,860 Cement - 106,615,663 Cereal - 615

Cerium Cerium fluoride sulfate - 659
- 40 - 673 biphenyl - 860,863 brine - 33, 37, 160, 357, 732, 733, - 840 - 126, 632, 678, 732,
hypochlorite and
glue
- 486, 659 Cerous chloride - 486 Cerous nitrate - 187 Cesium bromide - 231
Cesium chloride Cesium hydroxide Cetane (hexadecane) - 659 - 659
hydrocarbons
lime (see Calcium powder) linseed oil organics
- 187
hypochlorite)
lye (see Sodium
- 157,357,860
- 187,241
914
CorrosionResistant Materials Handbook
Chlorinated Chlorinated Chlorinated Chlorinated Chlorinated Chlorinated Chlorinated Chlorinated 780 Chlorinated Chlorine
phenol
- 254 - 187 - 187
221,236, 312,314, 382, 487, 388,
243,254, 357, 389, 774, 369, 651, 779,
265,299,303, 371, 373, 398, 374, 400, 732,
306, 309, 376, 380, 408, 441, 735, 737, 797,
phenol disinfectant pulp stock rubber solvent TSP water polymer
393, 397,
- 187 - 32, 36, 46, 156, 297, 357,
615, 632,
659, 676, 782, 783, 840, 849,
750, 766, 889
787, 795, 854,882,886,
639,825,860
802,806,812,825,
- 840
hoods
washer
- 187
water)
Chloroacetone
- 156, 177, 357, 659, 825,840,

chloride acid
(see also Chlorine 645, 676,
- 33,
774,
860 Chloroacetyl Chloroacrylic Chloroallylene
34, 35, 37, 74,221, wax
677, 735,
- 254, 265, 659 - 678

acid - 659
- 48, 160, 187, 217

109, 114, 126, 169, 397, 676,
- 825
- 659 acid
- 13, 20, 28, 34, 35, 36, 37, 40, 48, 53, 149, 151, 154, 157, 158, 394, 659, 160, 395, 663,
Chloroaminobenzoic Chloroaniline Chloroazotic Chlorobenzene, 106, 114,
55, 60, 63, 65, 67, 74, 108, 143, 147, 187, 218, 398, Chlorine Chlorine 401, 254,265,275,393, 408, 435,
- 825
- 229
o-Chlorobenzaldehyde
615, 646,
mono - 1, 11, 18, 28, 33, 34, 37, 118, 161, 247, 363, 398, 126, 254, 370, 143, 144, 265, 275, 372,377, 487, 789, 782, 147, 291, 381, 615, 149, 151, 236,
677,728,758,789,792,840,849,860 absorption aqueon
38, 43, 48, 53, 55, 60, 63, 66, 74, 83, 103, 154, 156, 241,243, 171, 188,201, 218,229,
- 187
- 825 Chlorine cell off-gas - 741

Chlorine cell plant surfaces dioxide 389, 393, 677, 188,218, 394, 678,737,
292, 293, 385, 389, 632, 661,
- 187
243,254, 782,825,846 169, 171, 175, 374, 651, 797, 357, 642, 373, 646, 357, 487,
299, 392, 663, 889
357, 393, 673,
Chlorine 388, 659, Chlorine, 376, 726, Chlorine
- 34, 48, 53, 62, 109, 160, 169,

221,236, 395, 766,774, 154, 160, 299, 639, 396, 401,408,
401, 408,
171, 187,
678, 777,
797.802,806,
812,825,840, Chlorobenzene Chlorobenzol Chlorobenzoyl Chlorobenzyl
842,849,860,871,882,886, with sulfur dioxide - 659
dry - 149, 380, 731, 385, 732,
187, 236,
243, 254,265, 389, 737, 632,
- 156
- 659 - 659 chloride chloride
Chlorobenzotrifluoride
750,766,780,787,
802,806,812,825,882 Chlorine
- 55, 254, 265

(see Bromochloromethane) - 659
- 187 - 678 Chlorine monoxide - 737 Chlorine oxides - 678, 732

kill tanks mixtures NaCI, NaOCl - 286 - 187 Chlorine trifluoride - 275, 357, 737, 782, 812, Chlorine Chlorine 825 solution, stripping
Chlorobromomethane Chlorobromopropane Chlorobutadiene Chlorobutane
- 357,825,840,861
(see Butyl chloride)
Chlorodifluoromethane Chlorodiphenylamine Chlorododecane Chloroethane Chloroethanol Chloroethyl
- 681 - 487
chloride) chlorohvdrin) chlorohydrin)
- 357
(see Ethyl (see Ethylene
Chlorine 155, 380, 408, Chlorine, 374, 644, 736, Chlorites
water 156,
(see also Chlorinated 118, 171,175,
water)
- 53,
55, 60, 63, 67, 114, 161, 243,254,265,275,286,367, 382, 385,388, 731, 736, 740,
126, 149, 373,
151, 154, 374, 376, 401, 860, 175, 373, 642, 735,
o-Chloroethylbenzene alcohol Chlorofluocarbon Chloroform
- 363, 659, 873

(see Ethylene
187,218,233,236,
- 108, 188
(see also Freons)
389,392,394,395, 750,812,825,849, 160, 169, 171,
Chlorofluoromethanes
(trichloromethane)
- 678,832 - 2, 11, 18,26,28,
886,889 wet - 149, 376, 380, 646, 651, 740, 750, 154, 187, 221, 236,243, 385, 666, 766, 254, 389, 677, 774, 265, 299, 392,424, 726,731, 780, 782, 357, 632, 732,
797,802,
806,812,825,846,882,891
- 53
- 659 acid, mono 156, 161,
Chloroacetaldehyde Chloroacetic 153, 154,
- 28, 33, 34, 37, 40, 48,

114, 133, 149, 218, 171, 177, 188,201,
103, 106,111,114,118,121,126, 143,147,149, 153,154,156, 157, 161,171, 175, 188,215, 218,230,236,239,241,243,247,254,265, 275,285,286,292,299, 304, 307,310,312, 315,357,370,372,373,374,380,385,388, 389,392,393, 394,395,397,398,401,408, 435,615,632,646,651,659,663,678,735. 737,758,766,780,782,789,797,802,806, 812,825,840,849,861,882,886,889
33, 37,40,48,53,55,60,63,65,67,74, Chloroform Chlorohydric alkaloids acid
49, 53, 55, 63, 74, 83, 109,
- 188 - 825
Corrosive
Material
Index
975
Chlorohydrin Chloromethonic 4Chloromethyl Chloro-P-methyl
- 254, 659
ester - 659 phenoxyacetic quinone acid
156, 157, 221,
158, 302, 374, 396, 490, 766, 825,
161, 169, 240, 243, 305, 308, 376, 397, 615,
171, 247, 311,
175, 188, 218, 254, 314, 387, 408, 642, 732, 854, 265, 275, 357, 369, 388, 389, 424, 435, 644, 645, 735, 737, 882, 884,
225, 236, 299, 373, 393,
- 678
286, 371, 392, 646, 806, Chromic Chromic Chromic Chromic Chromic
Chloronaphthalene 678,825 a-Chloronaphthalene Chloronitrobenzene I-Chloro-I-nitroethane Chloropentane Chlorophenol
- 488 - 376, 380, 401, 408, 659, - 230, 357,812
380, 385, 398, 401, 632, 639, 728, 782, 849,
441,489, 750, 758, 812, 886,889,891
651, 660,
663, 726, 774, 779, 840, 846,
- 376, 380, 615, 659 - 357,825 I-Chloro-I-nitropropane - 254

(see Amy1 chloride) acetic acid - 659 678,842,861
787, 798, 802,
acid, boiling acid, sulfuric acid, with chloride fluoride
- 424, 645, 679, 737, 740,

acid - 114, 155, 175, 188,
Chlorophenohydroxy 383,488,659,663, 2-Chloro-4-phenylphenol Chloropicrin Chloroprene Chloropropane a-Chloropropylene Chloropropylene Chloroquinine Chlorosilanes Chlorosulfonic 112, 161, 275,
766,779,854 225,233,286,849 other acids
- 40, 74, 175, 241, 247, 357, - 254, 663 - 254, 265, 489, 679, 738, 842 - 825
- 1, 230, 292
- 188, 189, 726, 737

66C
- 393, 401,
408,
- 822, 825 oxide - 825
- 659 - 659 acid
- 28, 40, 48, 55, 63, 74,

153, 308, 156, 157, 311, 314, 825, 840, 158, 357, 846, 254,265, 737, 758,
- 660 Chromic hydroxide - 660 Chromicoat - 826 Chromic oxide - 188, 357 Chromic phosphate - 660 Chromic sulfate - 435, 660, 679, 758 Chromium - 615, 790
Chromium Chromium Chromium 153, 364, hardening oxide 188, fixing bath - 189
114, 126, 171, 175, 299, 302, 787,
149, 305, 435,
188, 218, 247, 659, 679,
- 615 - 30, 58, 85, 115, 135,

269, 280, 737, 357, 732, vapor 149, 750, 780, 195, 254, 259, 395, 647,
plating solution
393, 401, 408, 779, 782, Chlorosulfonic 659 Chlorothene Chlorotoluene a-Chlorotoluene o-Chlorotoluene Chlorotoluene Chlorotoluidine Chlorous acid 849,854,886,889
161,
795, 812,
368, 394,
818,834,861,884,885,891 Chromium Chromium plating solution, potassium 114, 275, sulfate 126, 355,
acid and 50% sulfur trioxide
- 188
alum) - 19, 154, 171, 189, 555, 408,
(chrome 152, 357, 401,
- 37, 40, 188, 789,812,840

- 659, 861 (see Benzyl sulfonic - 659 - 489, 659, 825 chloride)
28, 54, 106, 232, 615,660, Chromium Chromium
252, 263, 679, salts sulfate
788,826,849,861
- 188, 275, 357

acid - 659
Chlorotrifluoroethylene
- 787
- 659
Chloroxylenols Chloroxylols Chocolate Chocolate 860 Cholesterol Choline Chrome Chrome Chrome Chrome Chrome Chrome Chromates
- 67, 275 - 48, 161, 189, 615, 660 Chromium trioxide - 152, 254, 609, 615, 826 Chromous sulfate - 108, 189 Chromyl chloride - 218, 254, 660 Cider - 65, 114, 126, 156, 275, 382, 615, 651,
788,840,861 (see Limonene)
- 660 - 615, 788 syrup - 14, 22, 126, 238, 275, 840, - 660 - 188 - 188
potassium sulfate)
Cinene Cineol
- 233 - 226 - 106, 227

oil (see Essential oils) 357, 826 2XH - 291
Cinnamaldehyde Cinnamon Cinnamon Circosol chloride
- 663
Circa light process oil - 291, Citgo oils and fluids Citraconic Citrate anhydride
acid evaporator ammonium anodizing reduction tanning
alum (see Chromium solution process solution
alum (sulfate)
- 826
- 275, 280, 817 - 233

- 189
- 188 - 188
process for SO* removal
Citric acid - 1, 2, 4, 10, 17, 26, 28, 33, 34, 36, 37, 48, 53, 55, 69, 61, 63, 65, 67, 75, 95, 104, 106, 111, 151, 225, 303, 114, 117, 153, 154, 236, 238, 118, 121, 156, 161, 239, 243, 126, 171, 254, 143, 147, 149, 299, 189, 218, 221, 265, 275, 368,369,371,
- 726
Chromicacid 106,
- 1, 2, 6, 10, 17, 28, 33, 34, 35, 112, 113, 149, 114, 117, 154, 118, 155,
37, 48, 53, 55, 60, 63, 65, 67, 75, 95, 104, 108, 109, 147, 126, 143, 151, 152,
306,309,312,314,357,
916
Corrosion
Resistant
Materials
Handbook
Citric acid (contd) 384, 396, 609, 728, 782, 385, 615, 398, 401, 732, 735, 787, 812,
- 373, 374, 376, 380, 382,

389, 392, 393, 435, 660, 758, 766, 846,849, 394, 441, 774, 854, 395, 490, 779, 886, 408,421,432, 646, 651, 750, 840, 737, 826,
Cod liveroil 227, Coffee Coffee
- 1, 62, 106, 106, 616,
126, 126,
143,
156,
189,
387, 388, 632, 642,
357,616,663,812,826,840,861,872 - 104, 105, grounds liquid 143, 227, 782,788,861 238, 289, 651,
679, 726,
357,382,491, Coffee,
889,891 Citric acid, ammoniated Citric Citric, acid, boiling 779,854 lactic acids - 189 Citric oils Citroflex
- 822 - 420, 444, 647, 679, 741, 750,
- 14, 22 - 227 Coffee, powder - 227 Coffee roasting fumes - 189 - 616 - 227, 228, 788, 861, 874 - 616 - 864 - 826 - 14, 22
Cognac - 106 Coke Coke oven gas (see Gas, coke oven) Cola drinks Collodion Cologne Elba Lyn Pub Cologne Cologne
- 840, 861, 872 - 840 Citrondropar (lemon) - 126

(see Essential oils) juice
Citronella Citrus fruit, Clarifier Clay
- 382, 615, 788 Citrus pectin liquor - 840, 861

liquid - 679 615,861
- 875
spirits sticks
- 615
Columbium Combustion Compressor Concrete
- 491 gases - 189 oil
Clay slurry - 189, 490, Cleaner 508 - 189 Cleaning Cleaning Cleanser solution solution,
- 106, 156
- 732
food grade acid
- 616
- 491 1008
- 840
Condiments Condor Condor types
- 22 Lighthouse - 22 Old Dutch - 23 Sano-Genio - 23 Clorox ~2, 14, 102, 126, 155, 233, 275, 307,
Bon ami 310,313,316,357,812,825,840,860,861 Clove oil (see Essential oils) Coal
- 861 - 812 Conoco fluids - 282, 819 Convelex 10 - 357,861

Cooking Cooking Coolanol liquor - 679 oil
- 615 - 53
- 189 596, - 189 615,789,861
- 228 - 357,861 Coolant brines - 376, 380 Cooling tower inhibitor - 188, 189
towers, water - 189
Coal dust, moist
Cooling Copal
Coal dust scrubber Coal tar Coatings, Cobalt Cobalt Cobalt Cobalt butyl Cobalt, Cobalt
Coal gas (see Gas, coal)
- 616, 663 Copal varnish - 861

Copper Copper Copper - 790 acetate - 156, 171, 189, 357, 376, 380, 728,777,826,861
- 275, 594,595,
water reducible - 491
Coal water slurry - 189 - 790 acetate chloride
393,401,408, ammonium arsenate Copper
compounds
- 357, 826, 861 - 616

and tri-m- 189
acetate - 861 - 67, 156, 274, 826 Copper carbonate - 55, 154, 156, 254, 265, 728, 735,777,861 Copper 156, 275, 393, syrup) 679, Copper Copper Copper - 189 357, 368, 392, Copper 151, 782, chloride 161, 299, 397, (also see Cuprous, 106, 171, 357, 108, 373, 782, 113, 374, 408, 188, 218, 236, 376, cupric) 243, 254, 380,
Cobalt di(2-ethylhexyl)phosphate phosphate nitrate - 189 660 - 189 nickel plating solution sulfate - 491, betaine
- 28, 33,
154, 265,
48,55,67,
114, 118,
152,
- 812, 834
388, 389, 651, 660, 806, 826,
Cobaltous Coca-Cola
398, 401,
491, 492,
syrup (see Foods, soft drink dimethylamine - 106
735, 777, chloride, cleaner, cyanide 154,
788, 798, 802, - 189
Cocamidopropyl Cocamidopropyl Cocoa butter Coconut Coconut 161, Coconut fatty oil Cocoa, chocolate
840,861,882,886,889
- 189
silver nitrate Copper Brite
- 143,227,812,861
acid diethanolamide 227, 254, 265,
- 148
compounds 161, 393,
- 616 - 28, 48, 55, 60, 75, 114, 118,

171, 397, 806, 189, 218, 398, 826, 840, 254, 265, 861, 275, 679, 735, 766, 777, 882, 886,
- 28, 48, 55, 60, 62, 126, 143, 156,
189, 218,
357, 392, 889
616, 788,826,840,861,872 oil alcohols, derivatives
798, 802,
- 114, 849
Corrosive
Material
Index
977
Copper Copper Copper
electrolytic extractant fluoride
cells - 189, 766 - 189
Cosmetics Avon
- 493, cream
616 cake
- 28, 48, 55, 75, 114, 118, 154,
Bath oil, bubble Bath oil, pine Cologne Bath salts, Coty Elba Lyn
- 22 - 22
161, 189,218,254,265 Copper fluoroborate - 370, 372, 492, 840 Copper Copper Copper Copper 114, 236, 388, 735, Copper Copper Copper Copper Copper Copper Copper leach tanks matte nitrate 244, 737, oxide oxide, oxide, pellet nicotinate 118, 152, 245, 389, 393, - 189 bath dipping
- 14, 23 - 14
- 48, 109, 161, 189

55, 75, 108, 161, 171, 373, 374, 777, 782, 113, 380, 651, 798,
- 492 154, 397, 156, 189, 221, 376, 788,
- 28, 33,48,
265, 275, 774,
- 864 - 875 sticks - 14, 22

Pub Hair dressing
398, 401,
408, 435,
758, 766,
802,806,826,861,882,886,889
- 14, 22 - 15, 23 Wildroot - 15, 23 Hair solutions - 841, 867

Brilliantine Vitalis Hand cream, lotion
- 231
dust - 189 red - 1, 232 smelter
oxychloride
- 189 - 189 pickling bath - 48, 161, 189, 190 plating solution - 30, 48, 58, 85, 115,
153, 154, 161, 189, 190, 259, 269,
- 867 Hinds - 14, 22 Nivea - 872 Lipstick - 144 Coty - 14, 22

Grace Lady Perfume Esther - 14, 22
135, 150, Copper Copper
- 23
368,834,843,859,861,884,885,891 refining salts cells
- 190
- 127, 149, 357, 367, 646, 732, 861 Copper silver nitrate - 774 Copper slimes - 384
Copper Copper smelter sulfate fumes 106, 154, 236, 393. 492, 737, - 190, 679 113, 244, 394, 493, 758, 806, 114, 247, 373, 395, 609, 766, 826, 118, 171, 254, 374, 396, 632, 774, 840, 121, 175, 376, 397, 651, 777, 846, 127, 190, 380, 398, 679, 782, 861, - 19, 28, 33, 34, 36, 37, 48, 55, 156, 161,
- 226 - 874 Powder base cream, Max Factor - 14 Sachet powder - 26 Shampoo, baby - 232 Shampoo, liquid - 207, 235
Polyderm moisturizer lotion Shave cream Talcum Waving Cottage 113, 299, lotion - 14, 626, 876 Marie Earle powder,
Cadenza - 859 Perfume alcohol 5DA40
60,65,67,75, 143, 151, 152, 218, 291, 388, 401, 680, 788, Copper Copper 737, Cordage Core oils Cork 221, 231, 293, 299, 389, 392, 408, 435, 726, 735,
- 14, 22
265, 275,
- 493
357, 367,
Richard Cottonseed 190, 218, 304,
cheese
Toni - 15, 23 - 376, 380 oil - 6, 7, 28, 48, 55, 60, 67, 75, 104, Hudnut, 143, 247, 310, 616, 147, 254, 313, 149, 265, 316, 154, 156, 161, 293, 376, 826, 233, 307, 275, 291, 357, 368, 788,812,
114, 117,
796, 798, 802, sulfate, 774,782 oil basic
882,886,889
- 67, 824
acid - 190, 384, 416,
380, 392, 441, 840,849,862,872 Coumarin Cream 357, Creosote 143,
651, 728,
sulfate-sulfuric
- 812
- 663 - 227, 616,840,

393, 398, 493,
862 651, 660, 680, 782, 789,
- 28, 127, 156, 728

oil) - 1, 48, 60, 67, 118, 127, 227, 254, 275, 291, 616, 651,788,812,826,
- 15, 24, 63, 67, 75, 127, 156, 275, 299,
- 616
190, 218, 372,392, 293,
Corn oil (maize 156, 161, 357,370, 840,862,872 Corn oil, Mazola
812,826,840,872 Creosote, Creosote, Cresal Cresol coal tar - 156, 357, 862 wood
- 357 - 28, 37, 40, 55, 63, 65, 75,

127, 265, 660, 149, 275, 151, 357, 154, 190, 218, 376, 380, 401, 826, 840,
- 127
(methylphenol) 114, 254, 616,
- 102, 228, 238
- 48, 161, 190, 632, 680, 788 Cornstarch slurry - 861 Corn sugar - 161, 190 Corn syrup - 55, 61, 149, 154, 171, 190, 265, 382,
Cornstarch 616,812,826 Corn syrup, Corrosive
106, 113, 241, 247, 408, 493, 849,862 Cresol, fumes Cresol, Cresolic xylene
663, 789, 812,
- 190, 201 solution
- 131, 238, 278 sublimate - 826

Karo
compounds
- 156 - 233
918
Corrosion
Resistant
Materials
Handbook
Cresyl alcohol - 826 Cresyldiphenyl phosphate - 75, 241, 247, 862 Cresylic acid - 28, 55, 63, 67, 75, 114, 149, 154, 156, 161, 171, 190, 218,254, 265,291, 357, 369, 37 1, 392, 393, 397, 493, 616, 660, 680, 782, 787, 798, 802, 806, 826, 840, 849, 854, 882,886,889 Cresylic acid, fumes - 190 Crisco - 227 Crotonaldehyde - 28, 55, 149, 154, 218, 254, 265, 494, 660, 789,862 Crotonic acid - 660 Crude oil - 28, 33, 38, 55, 62, 66, 75, 84, 85, 147, 149, 154, 155, 156, 184, 190, 203, 218,247, 254, 265, 275, 288, 357, 364, 373, 374, 376, 377, 380, 381, 396, 537, 623, 651, 680, 728, 738,817,826,862,872 Crude oil, refined - 57, 66, 145, 156, 268, 632 Crude oil, sour - 13, 22, 38, 48, 50, 51, 57, 58, 62, 135, 150, 151, 154, 156, 161, 165, 166, 169, 171, 190, 203, 210, 219, 261, 268, 285, 286, 632, 762,852 Crude oil, sweet 48, 50, 135, 161, 165, 169, 171, 190,203, 214,537 Crude oil, tank bottoms - 190, 203 Crude oil with sulfur - 439 Crude oil, waste - 203 Cryolite - 156, 616, 812, 826 Cryscoat products - 826 Crystal ammonia - 826 Cumenaldehyde - 660 Cumene (isopropylbenzene) - 357, 494, 616, 660, 663, 680,789,812,826,862
Cumene Cupric Cupric Cupric hydroperoxide arsenate chloride
Currants Cutback Cutting Cyaf Cyanic Cyanides
(black diluent,
and red) refinery
- 616
- 190 357, 371, 372,
oil - 59, 262, - 190
271, 283,
812,840,843,844,862,873,878 5101 acid Cyanamide
- 660 - 75, 787,840
Cyanoacetic Cyanogen Cyanogen Cyanuric Cyanuric Cyanuric Cycleweld Cyclic ether)
- 663, 862 acid - 254, 660, 766

isobutylketone 782,789, 862 - 175, 680 - 190 - 156, 660, chloride acid
Cyanoacetic:methyl
- 175, 190 chloride - 680

chloride, L808 caustic scrubber - 190 cycle
- 862
ether (see Fluorinated
fluorinated
Cyclohexane ene) 127, 147, 226, 241, 307, 616, 646,
(hexahydrobenzene, 156, 247, 157, 315, 161, 169, 275, 370, 357,
hexamethyl171, 286, 372, 190,218, 299, 304, 376, 380, 826, 840, 113,
- 40, 48, 53, 55, 63, 65, 75, 106, 113,

254, 265,
309, 312,
660, 737,
766, 789, 812,
849,862 Cyclohexanol 114, 118, 171, 218, 370, Cyclohexanol Cyclohexanone 147, 149, 230, 241, 372, Cyclohexene Cyclohexylamine Cyclohexylamine Cycle-octadiene Cyclopentane Cygon 873 2,4-D Dairy Dairy (herbicide) EEZ - 190 - 1, 28, 33, 55, 63, 65, 75, 112, 127, 225, 143, 149, 240, 151, 153, 247, 254, 265, 275, 154, 156, 357,
372, 660,826,862 esters
- 660
ketone) 156, 265, 157, 275, - 1, 11, 18, 28, 114, 161, 286, 118, 127, 190, 218, 357, 370,
(pimelic 151, 247, 153, 254,
40, 55, 63, 65, 75, 103, 106,
- 660, 680
- 812
hydroxide - 737, 766 - 34, 60, 63, 75, 127, 147, 175, 303, 644, boiling 306, 308, 311, 735, 314, 737, 385, 750, 645, 680,
376,380,
660,813,826,849,862
carbonate-cupric 254, 441,
- 106, 660
- 40, 226, 660, 737, 788, 862

hydrochloride - 190
221, 231, 392, 424, Cupric Cupric Cupric Cupric Cupric Cupric Cupric
- 190 - 660
766,774,812,826,846,862 chloride, cyanide fluoride nitrate chloride-sodium
- 424, 645, 737 chloride - 644
p-Cymene
- 156,233,
275,
357,
616,813,826,830,
- 127, 435, 660, 737, 750, 759, - 55, 127, 154, 171, 265 _ 127, 441, 647, 680, 750, 777,
766,812,826
- 15, 24, 156, 161, 616, 796 - 616

seal
- 862 - 26
812,826,862 salts - 849 sulfate
products - 190,840
Dane Head radiator Darax 306, 308, 311, 314, 385, 441, Dasco products Dazad - 190 acid - 190 DBP DDTDDT
- 12, 55, 63, 67, 127, 154, 156,

303, 766,812,826 sulfate-sulfuric acetate
231, 265, 492,493, Cupric Cuprous Cuprous 127, Cuprous
- 275,813
sulfate-ferric ammonia chloride
- 826 - 813
275,495, 616, 15,53, 65, 127, 190,233,
- 862
774
DC 200,510,550,560 660,862 and kerosene
- 12, 19, 55, 106, 114, 118,
152, 154,221,265,680,737,766,
Cuprous
oxide - 231 salts - 849
- 156, 826, 862
Corrosive Material
Index
979
Decahydronaphthalene 127, 143, Decane Decanol
(Decalin)
- 28, 63, 106, 118,
Mr. Clean Nytron Oakite oz - 495
- 23, 234
156,233,275,357,813,826,862
- 495 - 153, 203, 872 - 190, 204 cleaner - 15, 23
- 357,826,862 - 190, 225, 826

brine - 190
Dechlorinated Decongestant
Pax Hyspeed Rad household Rinse Dry SkipStanley Temp Tide Wisk 110
- 15, 23, 26 Dectol R&O oils - 275, 813

Decyl alcohol Degreaser Dehydratine (see Decanol) 80
- 316-336
Servac - 15, 23 floor cleaner cleaner - 15, 23
- 840
- 840 Dehydroacetic acid - 225 Denatured alcohol - 275, 291, 293, 358, 813, 826,
862 Dental creams Dentrifice, Deodorants Deodorants, Desalination liquid
- 15, 23
337-354,
- 15, 23, 307, 310, 313, 316-336,

495
- 14, 131, 234 - 14, 23

- 15, 23
- 23 - 51, 167, 190, 211, 270, 711 - 48, 109, 161, 191, 211 solution (copy machine) - 840
sulfated sulfonated
Detergents, Detergents, Developing Dexoxyn Dexron
- 15, 23,840
powder sea water
- 207 - 254, 265
Descaling agent Desoxyephedrine Desulfurizer Desulfurizing Detergent Detergents, 95, 106, 157, 289, 296, 319, 320, 328, 329, 358, 432, 862,879 Detergents, Detergents,
- 16, 25
hydrochloride - 190
- 233 - 813 Dextrin - 28, 55, 113, 114, 127, 149, 153, 154,
2 18, 265, 275, 788,849
feed, refinery SOZ
- 190
alcohols - 190 general - 1, 5, 6, 7, 28, 33, 55, 63, 76, 107, 304, 114, 127, 190, 203, 307, 310, 323, 332, 130, 143, 233, 247, 313, 324, 149, 154, 265, 275, 318, 327, 336, 849,
- 275, 358 Dextrose - 28, 55, 113, 114, 127, 149, 154, 254,
Dextron 265, DFR-121 Diacetic Diacetone 826,862 Diacetone 254, Dialkyl 321, 322, 330, Diamine alcohol 681, 788,849
- 191
acid, ester
171, 185,
- 826
156, 230, 358, 789, 813,
316, 317, 325, 326, 335, 788, 840,
- 10, 17, 143,
321, 322, 330, 331, 495, 616,
333, 334,
- 54, 76, 127, 156, 218, 225,

291, 293, 370, 372, 616, 813,
646, 743, - 190
263, 275, sulfates
826,839,848,856,862 germicidal household 317, 325, 333,
- 52, 130, 304, 307, 310,

318, 326, 319, 320, 327, 328, 329, 336,495
Diallylphthalate
- 660 - 33, 161, 171, 191

(see Ethylene diamine)
313, 316, 323, 324, 331,332, Acclaim Axion
- 826
phosphate
Diaminoethane Diammonium Diamylamine Diamyl Diamyl Diamyl Diazinon
334,335,
- 48, 65, 161, 191,275
-5 - 232
- 862
- 156
Ajax with ammonia
naphthalene phenol
- 22 Calgonite - 5, 52, 102, 304, 307, 310, 313,

316 Cascade - 187 Cleaner, all purpose, liquid Dishwashing liquid - 192 Dreft
- 156
- 156
phthalate
- 276, 358 Diazo saits - 28, 114, 127, 149, 154, 255, 265, 849 - 185
Dibenzyl Dibenzyl Dibenzyl biodegradable - 190 - 660 ether
- 103, 291, 304, 306, 309, 312, 315, - 358,862 - 840, 862
dibromide) bromide)
- 14, 22
- 19
358,813,826,840,862 sebacate Dibromochloropropane Dibromoethane Dibromoethyl Dibrombmethane
Dicrobe
Dishwashing, Electrosol Fab - 495 Glim Handy lgepal Ivory Joy
- 5, 162, 192
(see Ethylene benzene
- 358, 862
- 14,22
Andy
(see Methylene
- 22
- 2, 5, 131, 198 - 105

307,310,313,316 316-336
- 14,22,233,304,
Lestoil - 102, 234, 304, Lux flakes
- 316-336 Lux liquid - 373, 374
- 48, 161, 191 1,2-Dibromopropane - 255 Dibutoxyethyl phthalate - 255, 265 Dibutylamine - 226, 358, 826, 863 Dibutyl Cellosolve adipate - 862 Dibutyl ether (butyl ether) - 48, 73, 156, 161, 175,
Dibromophenol 186, 191, 230, 241, 247, 293, 356, 358, 811, 813,824,826,840,842,859,863
920
Diethylene (Carbitol Dibutyl Dibutyl 127, 265, Dibutyl
glycol monoalkyl acetate)
ether acetate
Dichromate
seal - 891 ammonium
- 827
phosphite phthalate 153, 156, 276,
- 789
- 60, 63, 76, 108, 112, 114,

157, 171, 299, 175, 191,227,255, 393, 660, 358, 392,
291, 293,
chloride - 191 - 358,827 Dicyclopentadiene - 191 Dicyclopentenyl alcohol - 617 Diesel fuel - 28, 33, 41,48, 55, 63, 76, 106, 108, Dicocodimethyl Dicyclohexylamine 118,155,156, 161, 171, 172,191,218,241, 291, 358,376, 247,255,265,276, Diester synthetic 284,286, Lub. oil
789,813,826,863 sebacate 255,
- 7, 104, 117, 143, 156, 157,

265, 291, 293, 303, 306, 309,
197, 227, Dibutyl Dibutyl Dibutyltin Dicalcium
380,632,789,813,827,840,849,863,884
312,315,358,813,863 thioglycolate thiourea
- 840,863,872
128, 161, 660,663,782, 161, 175, 191,218,
- 660 - 175, 480 - 171, 191

- 171, 191
Diethanolamine 171,191, 788,863 Diethylamine 226, 255, 255,388, Diethylaniline Diethylbenzene 55, 76, 156, 265, 276, 388, Diethyl Diethyl 363, 392, 244, 233,863
- 1, 65, 76, 108, 109, 226, 255,276,617, 156,
- 660
dichloride phosphate acid 737,
- 41, 55,76,
265, 276, 358,
Dichloroactaldehyde Dichloroacetic 389,616,
617, 660,798,802,
- 191, 236,244,
- 191
806,813,827,849,863,882
750,766
- 660, 663,863
- 161, 191,358,663, -41, 128, 156, 157, 789,813, 161, 191, 827
2,6-DichloroGaniline Dichlorobenzene 161, 171, 389,616, 175,
- 41, 44, 45,48,

191,236, o
carbonate Cellosolve
660,681,737,813.826,863
Dichlorobenzene, 663,789,842,873 Dichlorobenzene, 363,663, Dichlorobutane Dichlorodiethyl
- 11, 18, 33, 37,41,42,43,

255, 292,
Diethyleneamine Diethyleneamine Diethylene Diethylene Diethylene
- 55, 218, 265 - 103

triamine - 193
45, 60, 143, 203,230, p
dichloride dioxide 128,
- 230
(see Dioxane)
- 11, 18, 143, 230,358,
789,873
glycol - I, 10, 17, 48, 63, 76, 108, 109, 143, 156, 162, 171, 175, 191, 380,617,660,663,789,813, ether
- 34, 358, 863 ether - 18

(see Freon) (DDD) 191, 292, 806, 380,
113, 114, 229,358,376,
Dichlorodifluoromethane 1,2-Dichloroethane 681, 882 Dichloroethene 884 Dichloroethylene 191,255,265,276 Dichlorohexylamine Dichlorohydrin Dichloroisopropyl Dichloromethane 156,681 Dichloropentane Dichlorophanol 663, 678, 681 2,4-Dichlorophenol Dichlorophenoxyacetic Dichlorophenoxybutyl Dichlorophthalic Dichloropropane Dichloropropene Dichloropropionic acid - 789,863 - 191, 376, 782, 789,
827,840,849,863
Dichlorodiphenyldichloroethane
- 660
383,488, 863, 660,
Diethylene Diethylene Diethylene 11, 108,
glycol dialkyl glycol 160,
- 827 - 827
ether (butyl 291,293, Carbitol) 304,
- 40,76,
798,802,
monoalkyl 186, 191,233,
ether (Carbitols)
826, 846, 399,406,
glycol monobutyl
306,309,312,315,356,400,407,811,824, 827,859 Diethylene Diethylene Diethylene glycol monoethyl ether (Carbitol) ether - 11
- 48, 55, 65, 76, 128, 156, 161, - 863

ether
- 11,
147,233,264,304,357,659,825,860 glycol monomethyl oxide - 191 oxide Diethyleneimide
- 663 - 358,827
chloride) (see also Freon) (see Methylene
(see Tetrahydrofuran)
Diethylenetriamine
- 33, 37, 171, 191, 218, 226,

ether) - 1, 7, 11, 18,28, 128, 129, 175, 33, 34,
Dichloromonofluoromethane
255,376,380,737,863 Diethyl ether (ethyl 37, 48, 52, 55, 60, 63,65, 67, 76, 77, 95, 104, 143, 147, 193, 176, 191,
- 39,41,43,46,
191,488,
489,
106, 112,113, 153, 154, 157, 218, 230, 236, 321, 322, 331, 372,
114,118, 162,171, 239, 323, 373,
- 41
acid acetate
244, 255,265,276,286, 324,325, 334, 374, 376, 397,398, 326, 327,328, 335,336, 401, 408, 358, 617, 380, 385,389,
- 191, 676 - 674
299,304,306,309,312,315,317,318,319, 320, 329, 330, 359,370, 332, 333,
- 175
- 161, 191 - 161, 191

- 191, 255
392,393,394,395, 646, 660,681, 850,863,865 (see also Freon)
782,789,792,813,827,841, - 191,863 - 17
Dichlorotetrafluoroethane Dichlorotetrafluoromethane 156 Dichromates
- 827 -
Diethyl Diethyl
formamide glycol
- 276
adipate
- 663
Di-2-ethylhexyl
921
Diethylhexylphosphoric Di-2-ethylhexyl Di-2-ethylhexyl Diethylhydrazine Diethyl 230 Diethyl Diethyl Diethyl Diethyl Diethyl Diethyl Diethyl maleate malonate oxalate oxide phthalate sebacate sulfate - 191,863 ketonephthalate sebacate
acid
- 162, 191
Dimethylaniline Dimethylbenzene Dimethylbenzyl Dimethylbutane
hydrochloride (see Xylene) N-alkyl
- 681
- 191 alcohol) - 192
- 104
- 287, 288
153, 156, 171, 175, 191,
detergents
- 863
1, 143,
- 356
(see Isopropyl
Dimethyl
carbinol
Dimethylchloroacetyl Dimethyldistearyl Dimethyl 660,728, ether) 104, 218, 106,
- 526
ammonium ether) chloride
- 255, 681 - 827
ether (methyl
- 128, 156, 157,
766,813,827,842,870
(see Diethyl
Dimethylformamide 117, 226, 239,
- 4, 7, 28, 37, 41, 63, 76, 95,

118, 128, 241, 248, 157, 162, 171, 192, 255, 265, 296, 358,
- 156, 370, 372, 813 - 156, 299, 358, 813, 827, 840,863
- 34, 108, 162, 191, 681, 789, 863 - 233 Difluorodibromomethane - 358 Difluoroethane - 660 Digallic acid - 827
N,N-Diethyl-m-toluidine Digester blow-down Digester Diglycolic room spills Diglycolamine vapors - 191
376,380, 265,617, Dimethyl Dimethyl Dimethyl Dimethyl 171,
617,813,827,863 (also see UDMH) 784
Dimethylhydrazine 681, ketone methane
- 55, 157,
2,6-Dimethyl-4-heptanone
- 230
(see Acetone) (see Propane)
- 191
morpholine phthalate 175,
- 191 acid - 28, 55, 114, 149, 154, 218, 255,

tallow ether
2,4-Dimethylpentane
- 162, 192 - 363 - 41, 48, 76, 143, 156, 162,

248, 255, 358, 370,
265,369,371,660 Dihydrogenated Dihydroxydiethyl
192, 218, 227,
- 191
(see Hydroquinone)
372,789,813,863 Dimethylpropanolamine Dimethyl Dimethyl sulfate
p-Dihydroxybenzene
Dihydroxydiphenylsulfone Di-P-(3,4-dihydroxyphenol Dihydroxysuccinic Diiodomethane Diisobutyl Diisobutyl
- 827 - 660
aniline)
- 41 - 233, 255, 617 sulfoxide - 76, 158, 192, 241, 248, 863
(DMT) - 617, 864
- 255
acid)
Dimethylterephthalate Dinitrobenzene Dinitrobutylphenol Dinitrochlorobenzene Dinitrotoluene Dioctyl Dioctyl 255, 248, adipate
acid (see Tartaric (see Methylene
- 376,380
in acid waste (DNCB)
iodide)
- 660
adipate
- 192 - 782,863,864
Diisobutylene Diisobutylene Diisobutyl 813,863 Diisobutyl
- 157 - 76, 156, 162, 191, 218, 248,

- 291
255,291,358,813,863 and aromatics ketone
- 358, 827, 840,863 - 156, 293 Dioctylphosphate - 65, 276

phthalate 128, 255, 266, 315, 317, 325, 334, 326, 335,
- 17, 28, 55, 63, 65, 76, 113,

147, 291, 318, 327, 336, 149, 293, 154, 156, 299, 303, 321, 330, 162, 322, 331, 827, 192, 323, 332, 849, 306, 309,
- 156, 175, 191,218,
114, 118, 312, 324, 333, 863 Dioctyl 863 1,4-Dioxane 156, 157, 276,286, Dioxolane Dipentene Diphenyl 364,
- 108, 109, 162, 191 - 863 Diisooctyl phthalate - 128, 358 Diisopropanolamine - 162, 191 Diisopropylbenzene - 358,827, 863
phthalate Diisobutyl sebacate Diisopropyl 56, 60,81, 277, 300, ether (isopropyl 131, 360, ketone 147, 385, 156, ether) - 11, 18, 42, 244,267, 409, 789, 176, 237,
319, 320, 328, 329,
358, 617, 813,
sebacate
- 156, 286, 358, 813, 827, 840,

128, 266,
- 11, 20, 37, 55, 63, 77, 106, 192, 218, 358, 233,241, 248,255, 660,766,789,813,827,863
388, 389, 402,
815,827,851,868 Diisopropyl 840,863 Dimethanolamine Dimethoxybutane Dimethylacetamide Dimethylamine 154, 410 Dimethylaminoethanol Dimethylaniline 255,358,8 p-Dimethylamino - 11, 18, 156, 358,813,827,
- 358,827,863 - 358,789,813,827,863
(biphenyl) (phenylbenzene) 617, 660, 663, 789,
- 255 - 526
- 191,255
- 76, 358,
798, 802,
376,
380,
806,827,863,874,882
- 28, 55, 114, 128, 149, 153,

benzophenone
171,218,255,265
- 377.381,403,
- 376,380 - 76, 156, 218, 233, 240, 248,
- 226,547, 660, 663, 681 - 547 Diphenylchloride - 660 Diphenylene oxide - 660 Diphenylenimine - 226 Diphenyl ether (oxide) - 76, 171, 177, 192, 231.
Diphenylamine Diphenylcarbonate 248, 255,358, 376, 380, 624, 663,827,840,863
13,827,863
922
Diphenylmethane Diphenylmethane Diphenyl Dipping 663 Dipropyleneglycol Dipropylene Dipropyl Dirco oils Disinfectant Breath 0 Pine chlorinated Lysol phthalate oxide acid Diphenylpropane
- 663
diisocyanate (see Diphenyl - 192 ether)
Dowtherm
- 28, 77, 156, 233, 241, 248, 276,
286,291,299,358,789,813,827,864 Drain cleaner - 192 Drain cleaner, Drain oil acidic, Clobber
- 660 - 33, 48, 76, 162, 171, 192,

dibenzoate - 698
- 148
- 827
glycol
- 156
- 192
Dipropylene
Drewsperse Drinox
glycol methyl
ether
- 192 - 255
- 841 Drip oil - 156, 291, 864 Dromus oil - 842

Dry cell solution, Drycid MnOz and NH4CI
- 233
- 813 - 22
- 827
fluids
phenol - 192
- 14, 22, 104, 105, 728, 780, 831,869 Showersan - 25 Zephiran - 148
Disinfectant Disinfectant Disodium Disodium 149, 849 Dispersants Distillery Distillery Distilling Di-syston Diversey - 192,203 stillage syrup wort - 192 - 192 and cleaner - 192
- 358, 663, 827,864 - 358 Duckseal sealant - 148 Dukes mixtures - 681 Duro oils - 276, 813 Dutch !i;uid, oil - 827
Drycleaning DTE light oil DW-875 DXE - 192 - 192
- 840, 863 methyl arsenate - 171 phosphate - 28, 50, 55, 113, 114, 128,
deodorant 154, 166, 209, 255, 266, 788, 844,
Dyanamite abrasive Rit
- 617 - 841, 864 - 841, 864

anodized treatment aluminum - 192 - 891
Dye - 495,496,617
152,
- 128
base
water
- 37 - 37
Dye for coloring Dye plant water Dye seal - 891 Dyestuffs Dyewood,
- 782, 841, 864
- 368
liquor
- 780,782,864
Divinylbenzene 663,864 DMA
- 37, 55, 156, 192, 255, 266,

EDTA - 192, 193, 682
6 weed-killer acid
- 161
peroxide - 192
EMK EVA
- 827 - 192 - 63, 238, 304, 307,

- 193 313, 316
DMP:MEK:MEK Dobanic Dodecane
EP 52-A65
- 128
- 103, 192 acid - 827 Dodecene - 108, 192 Dodecyl alcohol - 48, 161, 192
Dodecanoic - 156 sulfonic - 156 acid
Edible fats and oils, general 310, Eggs Egg yolk
- 617, 788 - 382

lubricant
Dodecylbenzene Dodecylbenzene Dodecyltoluene Dolmite Donax DOP 8
Elco 28-EP
- 358, 864
acid)
- 192, 681
Electrolyte Electrolyte Electrolytic Electronic, Electronics
- 681
acid (see also Sulfuric sodium electrical chlorate parts - 729
- 827
cell - 295
kiln gases, wet - 192
production
- 128 - 827
50-4
- 827
- 37,255,256,864
plant waste - 192 solutions
Douglas fir oil
Electropolishing Electrostatic Elixis
- 884
- 192
Dowanol
precipitator
Dow Chemical Dow Chemical Dow Chemical Dowclene Dowfax Dow Corning 9N9
- 358 - 358 ET 588 - 358

ET 378
- 841
fluid
Elvase - 192 Embalming Emulsifier Enamels Energol Energol
- 864
EC - 192 fluids surfactant
- 192, 646
- 233, 358, 359, 864 - 37 Dow fluid DP47, 200 - 276

Dowfume Dowgard W-40 - 156,827
- 276
HL68 H LPC68
- 276, 827 - 276,827

acid)
Engravers acid (see Nitric Ephedrine Ephedrine Epi hydrochloride sulfate
- 827
- 305, 308, 311, 313, 316, 358,858 Dow latex - 37 Dow Purifloc C-31 - 827
- 230
- 230
- 827
923
Epichlorohydrin - 77, 128, 156, 162, 175, 192, 218, 241, 248, 255, 299, 358,488, 660, 678, 681,813,827,841,865 Epoxy hardener - 24 Epoxy resin - 24, 358 Epoxy spray liner - 192 Epsom salt (see Magnesium sulfate) Eptam herbicide - 192 Erional NW - 192 Erythritol - 496 Esam-6 fluid - 358 Essence of myrbane (see Nitrobenzene) Essential oils - 13, 21, 67, 145, 234, 276, 617, 646,852 Almond oil - 122, 133, 182,227, 234,789 Anise seed oil - 232,234, 612, 839, 858,872 Bitter almonds - 13, 21 Borneol, 50% in butanol - 13 Cinnamon oil - 840,861,872 Citronella - 13, 21, 233, 663 Clove oil - 13, 126, 227, 234,840, 861,872 Eucalyptus - 13,21, 617 Ginger oil - 841, 867, 872 Lavender oil - 21, 361,831, 869 Lemon oil (flavor) - 13, 21 Lilac, artificial - 234 Menthol, 50% in butanol - 13 Nutmeg oil - 134, 228, 234 Palmarose - 13, 21 Pennyroyal - 13,21 Peppermint oil - 135,234, 623,843,872,874 Rose geranium - 234 Sandalwood - 234 Sassafras oil - 228, 234 Spearmint - 13, 21, 234, 235 Sweet orange oil - 21 Terpineol - 14, 21, 150, 178, 271, 282, 365 Thyme - 14,21 Turpentine (essential oil) - 14, 21 Vanilla - 21 Wintergreen oil - 14, 21, 234 Esso fuel - 358 Esso oils and fluids - 358, 865 Esstic 42, 43 - 358 Ester gums - 617 Esterification - 681 Esters - 36, 48, 116, 120, 149, 154, 218, 227, 241, 291, 293, 303, 306, 309, 312, 315, 432, 496,497,498,632,648,766,846 Esters, aliphatic - 646 Esters, fatty acid - 192 Etchant, fresh, spent - 193 Ethanal (see Acetaldehyde) Ethane - 77,358,660,789,827,865 Ethane tetrachloride (see Tetrachloroethane) Ethanethiol (see Ethyl mercapten) Ethanoic acid (see Acetic acid)
Ethanol (see Ethyl alcohol) Ethanolamine - 28, 43, 49, 77, 83, 128, 147, 156, 164, 177, 193, 201, 219, 248, 258, 268,276, 358, 363, 436, 498, 617, 622, 661, 663, 728, 760, 683,788,813,827,841,865, 871 Ethanolamine hydrochloride - 692 Ether petroleum - 789 Ethers - 28, 36, 53, 77, 149, 151, 154, 156, 241, 248, 276, 291, 293, 304, 306, 309, 312, 315, 358, 632, 651, 663, 798,802, 806, 841, 846, 865,882 Ethine (see Acetylene) Ethoxyethanol - 225 2-Ethoxyethyl acetate - 681 Ethoxylated alcohol, CIz-ls - 181, 193 Ethoxylated nonylphenol - 193 Ethoxylates - 682 Ethyl acetate - 1, 2,4,7, 9, 10, 17, 26, 28, 33, 37, 41, 48, 53, 55, 60, 63, 65, 77, 95, 103, 104, 107,111, 112, 113,114,117, 121, 128,143, 147, 149, 153, 154, 156, 157, 158, 162, 171, 175, 193,218, 227, 236, 239, 241, 244,248, 255, 266, 276, 284, 286, 291, 293, 296, 299, 303, 306, 309, 312, 315, 358, 370, 372, 373, 374, 376, 380, 383, 385, 387, 389, 392, 393, 394, 395, 397, 398, 401, 408, 435, 496, 497, 617, 651, 660, 663, 681, 726, 759, 766, 777, 782, 789, 792, 798, 802,806, 810, 813, 822, 827,841,850,865,882,886,889 Ethylacetic acid (see Butyric acid) Ethyl acetoacetate - 41, 108, 193, 218, 227, 255, 266,358,813,822,828,865 Ethyl acrylate - 28, 33, 37, 41, 56, 128, 149, 154, 162, 193, 218, 255, 263,266, 358, 497, 813, 828,841,865 Ethylacrylic acid - 358 Ethyl alcohol - 1, 2, 4, 7, 9, 10, 17, 26, 28, 33, 34, 37, 41, 47, 52, 54, 55, 60, 61, 63, 65, 67, 69,95, 103, 104, 106, 108, 109, 110, 111, 112, 113, 114, 117, 118, 121, 128, 129, 143, 147, 149, 151, 153, 154, 155, 156, 157, 158, 159, 169, 170, 175, 193,218,225, 226,236,239, 244, 255, 263, 273, 276, 291, 293, 296, 299, 303, 306, 309, 312, 315,317, 318, 319, 320, 321, 322, 323, 324, 325, 326, 327, 328, 329, 330,331, 332,333, 334,335, 336, 337-354, 358, 370, 372, 373, 374, 375, 376, 379, 380, 382, 383, 385, 388, 389, 392, 393, 394, 395, 396, 397, 398, 401, 408, 435, 440, 498, 617, 651, 657, 663, 669, 681, 735, 737, 743, 759, 766, 781, 789, 798, 802, 806, 813, 827,828, 839,848,850,856,865,882 Ethyl alcohol, vapor, condensate - 193 Ethyl alcohol, 50% in water - 96, 97, 98, 104, 111, 117, 121, 128, 129,743 Ethylaldehyde (see Acetaldehyde) Ethylamine - 103, 106, 156, 376, 380, 401,408, 499,813,865
924
Corrosion
Resistant
Materials
Handbook
N-Ethylaniline - 233, 617 Ethylbenzene - 33, 37,48, 77, 109, 143, 162, 176, 193, 229,255, 286, 304,307,309, 312, 315, 358, 617, 660, 663, 681, 789, 813,828, 865 Ethyl benzoate - 77, 143, 156, 227,286, 359, 828,865 Ethyl bromide - 1, 153, 156, 162, 193, 359, 393, 401,408,663,814,850,865 Ethyl butanoate (see Ethyl butyrate) 2-Ethyl butanol - 499 2-Ethylbutene-1 - 356 Ethylbutyl acetyl ricinoleate - 617 Ethyl butyrate - 63, 77, 113, 114, 617, 660, 813, 5827 2-kthylbutyric acid - 41, 147, 225 Ethyl Cellosolve - 171, 359, 865 Ethylcellulose - 156, 233, 359, 660, 663, 813, 827,865 Ethyl chloride - 28, 33, 56, 67, 77, 108, 114, 129, 143, 149, 153, 154, 156, 162, 171, 176, 193, 218, 230, 248, 255, 266, 276,299, 359, 376, 380, 393, 398,401, 408,435,651, 660, 663, 682, 728, 759, 777, 782, 789, 798, 802, 806, 813,828,841,846,850,865,882,886,889 Ethyl chloroacetate - 227, 255, 266 Ethyl chlorocarbonate - 359,828, 865 Ethyl chloroformate - 176, 193, 359, 828,865 Ethyl cyanoacetate - 255 Ethyl cyclopentane - 359 Ethyl dichloride (see also Ethylene dichloride) 156,865,889 Ethylene - 359,499, 617, 660,663,789,828,865 Ethylene, cracked gases - 682 Ethylene bromide (see Ethylene dibromide) Ethylene chloride (see Ethylene dichloride) Ethylene chlorohydrin (chloroethanol) - 28, 41, 42, 56, 63, 65, 74, 77, 106, 108, 109, 114, 149, 154, 162, 171, 193,218, 230, 247, 266, 276, 286, 359, 393, 398, 615, 660, 798, 802, 806, 814,828,860,865,882 Ethylene cyanohydrin - 660 Ethylenediamine - 41, 56, 63, 77, 103, 147, 171, 193, 218, 226, 240, 248, 266, 359, 617, 737, 814,828,865 Ethylenediamine, hydrochloride - 682 Ethylenediamine tetra acetic acid (see EDTA) 192, 193,682 Ethylene dibromide (ethylene bromide) - 28, 41, 56, 77, 149, 154, 156, 157, 193,218, 255, 266, 359, 435,499, 660, 663, 732, 759, 828, 865 Ethylene dichloride (ethylene chloride) - 5, 8, 11, 29, 33, 34, 41, 48, 53, 56, 60, 63, 72, 95, 104, 106, 111, 112, 114, 117, 121, 129, 143, 149, 154, 156, 171, 176, 193,218, 221,230, 236, 239, 241, 244, 248, 255, 266, 276, 291, 293,
296, 300, 304, 307, 310, 312, 315, 359, 370, 372, 373, 374, 376, 380, 385, 388, 389, 392, 393, 394, 395, 397, 401, 408, 435, 500, 617, 660, 682, 735, 737, 750, 759, 766, 774, 777, 782, 789, 798, 802, 806, 814, 828, 841, 846, 850,865,882,889 Ethylene disulfonic acid - 401, 408 Ethylene glycol - 1, 5, 10, 17, 26, 29, 33, 37, 41, 48, 49, 56, 63, 65, 67, 77, 102, 109, 111, 114, 118, 121, 129, 143, 147, 149, 151, 154, 155, 156, 157, 162, 169, 171, 176, 193, 218, 229, 236,239, 240, 244, 248, 255, 266, 276, 284, 291, 293, 300, 303, 306, 309, 312, 315, 359, 368, 370, 372, 373, 374, 376, 380, 382, 385, 387,388, 389, 393, 394, 395, 396, 397, 398, 441, 500, 617, 632, 651, 660, 663, 682, 728, 789, 798, 802, 806, 841, 850, 865, 882, 886, 889 Ethylene glycol monobutyl ether (butyl Cellosolve) 11, 37,55, 147, 160, 161, 170, 186, 193, 233, 264, 291, 293, 356, 614, 789, 812, 825,828, 859 Ethylene glycol monobutyl ether acetate - 828 Ethylene glycol monoethyl ether (Cellosolve) 11, 18, 26,28, 40, 55, 111, 121, 126, 143, 147, 149, 154, 156, 171, 218,227, 233,241, 265, 275, 291, 293, 306, 309, 312, 315, 357, 359, 825,860.865 Ethylene glycol monoethyl ether acetate (Cellosolve acetate) - 9, 11, 18, 40, 55, 143, 156, 275, 357, 812,825 Ethylene glycol monomethyl ether (methyl Cellosolve) 11, 18, 43, 57, 65, 83, 219, 234, 258, 268, 279, 286,361,377,380,789,816,842,851,870 Ethylene glycol monomethyl ether acetate - 11, 18, 26 Ethylene glycols - 682 Ethylene glycol/water - 52, 193, 216, 286 Ethylene oxide - 13, 20, 29, 56, 65, 77, 129, 143, 149, 154, 218, 231, 256, 266, 300, 359, 393, 401,408, 617, 660,789, 798, 802, 806,828, 841,850,865,882 Ethylene trichloride - 156, 256, 359, 865 Ethyl ether (see Diethyl ether) Ethyl formate - 359, 617, 660,865 2-Ethylhexanediol-I,3 - 17 Ethylhexanol - 865 Ethyl hexoate - 157 2-Ethylhexoic acid - 660 Ethyl hexylacetate - 193 2-Ethylhexyl alcohol - 10, 17, 103, 156, 291, 293, 359,660 Bis(2-ethylhexyl)phthalate - 117 2-Ethylhexyl sebacate - 8 Ethyl iodide - 156 Ethyl isobutyl ether - 156 Ethyl lactate - 10, 18, 143, 227, 617, 660
Corrosive
Material
Index
925
Ethyl
mercaptan
- 276, 359, 660, 789,813,

stannous octoate - 359
816,
Ferric 62, 129, 176, 266,
chloride 63,67, 151, 193, 276, 372, 398, 428, 639, 682, 756,
- 12, 78, 152, 198, 300, 373, 401, 429, 642, 722, 766, 828,
19, 29, 108, 156,
33, 113, 157, 308, 380, 414, 445, 646, 732, 782, 846,
34,
37, 158,
48, 118, 162, 248, 314, 394, 422, 609, 651, 735, 798, 882, 647, 256 723 502, 108, 171, 311, 395, 774, 866,
56, 121, 171, 256, 359, 395, 423, 617, 660, 737, 802, 886, 682,
828,865 Ethylmorpholene Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl Ethyl nitrate oleate oxalate parathion phenyl
106, 154, 218, 303, 374, 408, 441, 644, 723, 774, 830,
114, 240, 311, 393, 417, 502, 647, 733, 788, 866, 645, - 109,
- 34
- 118, - 359, - 193 - 359,813,828,865 ether (phenetole) 129 813, 828, 865
221,231, 306, 376, 412, 444, 645, 726, 777, 841,
370, 397, 424, 874 632, 663, 750, 889 Ferric Ferric
pentachlorobenzene
- 364,
834,
- 18, 617 propyl ether - 156 pyridine - 865 salicylate - 227, 663
silicate stearate suberic sulfate sulfhydrate - 193, 359,813,828,865
propionate
806,814, chloride,
boiling 750,
- 424,
445, acid
- 660
acid
737,740,
766,777,795,866 chloride
- 500
(see Ethyl 162, 632,732, mercaptan) 193, 789,865 408 oils) 236, 244, 388,
chloride-hydrochloric chloride-sodium ferrocyanide hydroxide nitrate 118, 221, 373, 798, oxide - 29, 129, 256, 374, 802, - 29, 33, 152, 266, 376, 806, 841,
Ferric Ferric Ferric 866 Ferric 114, 218, 359, 398, 782,
- 644,
774 266, 78, 162, 308, 394, 759, 841,
- 77, 109, - 660 acid - 401,

617 acid
- 221,
154, 34,
660, 156, 48,
389,401,408, Ethylsulfonic Ethylsulfuric Eucalyptus Eugenol Exalt Exhaust Exhaust Exsiccated Exxon Exxon Exxon Fabric Factovic Fat Fats Fats, Fatty lime latex turbo - 193
777, 113, 193, 314, 397, 777, 882,
56, 156, 306,
oil (see Essential
154, 303, 380,
- 13, 233,
air (see Air, gases caloria alum HT oil
393, 682,
exhaust) exhaust)
401,408,
435,441,
(see Gas,
814,828, 866
- 828
43
887,889
- 286
- 193
Ferric Ferric Ferric Ferric
- 618,
in water
perchloride phosphate salts sesquichloride subsulfate sulfate 118, 266, 395, 645, 766, sulfate, - 29, 154, 276, 397, 646, 774,
- 828
- 157 367, 392, 850
- 300
and manufacture
- 60, 149, - 828

33, 156, 359, 398, 651, 777,
softeners
- 682
Ferric Ferric Ferric 113, 256,
- 828
34, 162, 373, 401, 660, 782, 37, 48, 171, 374, 408, 682, 788, 682 56, 193, 376, 435, 683, 798, 67, 218, 380, 441, 737, 802, 78, 106,
52 - 276,814 - 828
- 617
cooking acid
221, 393, 502, 751, 806,
- 663
exhaust gas - 193 67,
Fat splitting Fatty acids 77, 129, 221, 376, 441, 726, 889 Fatty FC-43 FC 75 FC-77 FCU Feran FerriFerric Ferric Ferric nitrogen - 359 256, 380, 500, 728,
394, 632, 759, Ferric Ferric 682, 798, 692, 802, Ferrous Ferrous Ferrous 118, 193, 502,
esters - 29, 149, 266, 383, 501, 732,
- 65, 162
33, 34, 35, 36,48, 53, 56, 62, 151, 154, 162, 171, 193, 218, 276, 393, 617, 774, 359, 632, 779, 369, 646, 782, 371, 663, 787, 373, 374, 397,398,401,408,432,
814,828,841,846,866,882,887,889 boiling bleach
- 645,
acid
sulfate-sulfuric ammonium ammonium chloride 129, 218, 651, 143, 248, 660,
- 416,
423,
774 866 113, 171, 397, 788, 114, 176, 398, 798,
Ferricyanide
- 193
citrate sulfate
806,814,
828,841,850,854, compounds - 359 ether)
865,882,886,
- 728, 777, - 660, 683

56, 63, 156, 276, 737, 737 78, 162, 393, 777,
- 29, 152, 256,
48,
- 193
154, 266,
Fluorocarbon (cyclic feed - 193
683,735,
fluorinated
- 248
802,806,814,828,866,882,887,889 Ferrous Ferrous chloride-HCI hydroxide iodide nitrate salts sulfate
- 156
and ferrocyanides acetate acid ammonium ion - 171, 193, sulfate salts
- 256, - 266
- 401,
266 392
408
Ferrous Ferrous 660 Ferrous Ferrous
- 502 - 48, 56, 109, - 60, 149,

- 1, 29, 367, 36,
156, 392,
162, 733, 63,
171, 850 108,
193,
- 60, 149, - 384
218,256,266,276,814,828 48, 56, 114,
- 19, 231,
Ferric-chlorate
926
Ferrous sulfate (contd) - 118, 129, 147, 151, 152, 154, 162, 171, 193, 218, 221, 231,256, 266, 276, 303, 306, 308, 311, 314, 370,372, 393, 397, 398,435, 502,503, 618, 651,660, 683, 726, 728, 732, 733, 737, 759, 774, 777, 788, 798,802, 806,814; 826, 828,866,882,887, 889 Ferrous sulfide - 503 Ferrous sulfite - 231 Fertilizer - 24,48, 62, 162,503,504, 618,672, 683,796 Fertilizer fumes - 193 Fertilizer scrubbing - 194 Fertilizer solution - 153, 155, 194, 202, 215, 814,828 Fibers, wood - 683 Filter alum - 828 Fire resistant hydra-fluid - 814 Fire retardant liquid - 194 Firtec 290 - 814 Firwood oil - 828 Fish - 129, 238, 618, 620, 625, 629 Fish batter - 841 Fish oil - 106, 194, 359, 788, 828, 866 Fish oil meal, exhaust gas - 194 Fish solubles - 29, 114, 149, 154, 256, 266, 850 Fish stickwater - 504 Fish tanks - 194 Flavoring (see Foods and Essential oils) Flaxseed oil - 828 Flexol 3 GO - 291 Flo-Cool 180 (silicate ester) - 248, 866 Floor polish - 106 Floor wax polymers - 194 Flores martis (see Ferric chloride) Flour - 618 Flue gas (see Gas, five) Flue gas desulfurization - 416 Flue and stack gas scrubber - 729 Fluoboric acid (see Fluoroboric acid) Fluophosphoric acids - 618 Fluoride salts - 194, 663, 684, 731, 732 Fluorinated, chlorinated acid organics - 194 Fluorinated cyclic ethers - 359, 828, 866 Fluorinated hydrocarbons - 618 Fluorine - 29, 53,56, 63, 65, 78, 114, 149, 151, 154, 171, 194, 256,276, 359, 376, 380,393, 397, 398, 401,408,435,441, 618, 642, 646, 660, 684, 731, 735, 737, 759, 766, 780, 782, 789,798,802,806,814,828,847,850,882 Fluorine, wet - 154, 266 Fluorobenzene - 156, 359,828,866 Fluoroboric acid - 29, 41,48,56, 78, 114, 149, 154, 162, 171, 194, 256, 266, 276, 359, 367, 369, 371, 376, 380, 401,408, 504, 660, 684,
737,751, 766, 787,814,828,841,850, 854, 884,887,890 Fluorocarbon oils - 359 Fluorocarboxylic acid - 660 Fluorochloroethylene - 828 Fluorolubes - 194, 359, 828, 866 Fluoronaphthalene - 157 Fluoronitrobenzene - 157 Fluorosilicic acid (see Fluosilicic acid) Fluosilicic acid (hydrofluorosilicic acid) - 10, 17, 29, 33, 37, 41, 48, 49, 53, 56, 60, 63, 67, 78, 80, 109, 113, 114, 118, 129, 149, 151, 152, 154, 155, 156, 162, 169, 171, 194, 197,218, 221, 236, 244, 248, 256, 266, 276, 300, 359, 360, 367, 373, 374, 376, 380, 382, 388, 389, 392,393, 397, 398, 401,408, 426, 435, 518, 519, 652, 655, 660, 663, 684, 688, 725, 726, 737, 759, 766, 775, 779, 787, 798, 802, 806, 814, 815, 828, 830,841,850, 854, 855,882, 887,890 Fluosilicic acid fumes - 688, 779 Fluosulfonic acid - 194, 504 Fluothane - 63 Flux - 505 Fly ash - 618 Fly ash slurry - 194 Food brine - 505 Food processing - 433, 729 Foods and food products - 618, 737,743, 884 Accent - 848 Bacon - 14 Bacon fat - 227 Bakery products - 382 Barbeque sauce - 839,858 Beans - 613 Beef - 142, 228 Beef, extract - 839, 858 Beef, gravy - 227 Beer - 1, 15, 23, 28, 37, 47, 54, 60, 62, 65, 67, 72, 106, 114, 118, 124, 149, 154, 156, 159, 170, 184, 227, 238, 252, 264, 274, 299, 356, 370, 372, 373, 374, 375, 379, 382, 392, 440, 613, 632, 650, 735, 788, 811,823,839,858,886,889 Beet juice - 227 Blackberry juice - 613 Bourbon - 227 Brandy - 124, 238 Butter - 14, 22, 67, 124, 142, 156, 227, 238, 274, 304, 307, 310, 313, 316, 356, 382, 613,663,788,824,840,859 Buttermilk - 73, 156, 440, 788, 840, 859 Carbonated beverages - 156, 65 1,860 Cardamon - 131 Carrot juice - 227 Carrot, liquified - 238
927
Foods and food products
(contd)
Castor oil - 28,48, 55, 60, 67, 106, 113, 114, 125, 126, 142, 149, 154, 156, 160, 170, 187, 218, 233, 254, 265, 275, 291, 293, 299, 304, 307, 310, 313, 316, 357, 368, 393, 651, 663, 788, 812, 825, 840, 849, 860,872 Catsup (ketchup) - 14, 22, 38, 156, 227, 382, 788,840,860 Celery salt - 227 Cereal - 615 Cheese - 62, 382, 615, 788 Cheese spread - 105 Cherries, processed - 143, 227, 615 Cherry juice - 486, 615 Chicken gravy - 227 Chicken soup - 227 Chocolate - 615, 788 Chocolate syrup - 14, 22, 126, 238, 275, 840,860 Cider - 65, 114, 126, 156, 275, 382, 615, 651,788,840,861 Cinnamon - 106,227 Citric oils - 840, 861, 872 Citrus fruit, juices - 382, 615,788 Citrus pectin liquor - 840,861 Coca-Cola - 227, 861 Cocoa butter - 143,227,812,861 Cocoa, chocolate - 106 Coconut oil - 28, 48, 55, 60, 62, 126, 143, 156, 161, 189,218, 227, 254, 265, 357, 368,392,616,788,826,840,861,872 Cod liver oil - 1, 62, 106, 126, 143, 156, 189, 227, 357, 616, 663,812, 826, 840, 861, 872 Coffee - 104, 105, 106, 126, 143, 227, 238, 289, 357, 382, 491, 616, 651, 782, 788, 861 Coffee, cream - 227 Coffee, dry powder - 227 Coffee, grounds - 14, 22 Coffee, liquid - 227 Coffee, paste - 227 Coffee, sugar - 227 Cognac - 106 Cola, drinks - 227, 228, 788, 861, 874 Condiments - 491 Cooking oil - 228 Corn oil (maize oil) - 1, 48, 60, 67, 118, 127, 143, 156, 161, 190, 218, 227, 254,275, 291, 293, 357, 370, 372, 392, 616, 651, 788,812,826,840,862,872 Corn oil, Mazola - 102, 228, 238 Cornstarch - 48, 161, 190, 632, 680, 788 Cornstarch slurry - 861 Corn syrup - 55, 61, 149, 154, 171, 190, 265, 382,616,812,826
Corn syrup, Karo - 131, 238, 278 Cottage cheese - 376, 380 Cottonseed oil - 6, 7, 28, 48, 55, 60, 67, 75, 104, 113, 114, 117, 143, 147, 149, 154, 156, 161, 190, 218, 233, 247, 254, 265, 275,291, 293, 299, 304, 307, 310, 313, 316,357,368, 376, 380,392,441, 616, 651, 728, 788, 812, 826, 840, 849, 862, 872 Cream - 616,840,862 Currants (black and red) - 616 Dairy products - 616 Dextrin-28,55, 113, 114, 127, 149, 153, 154, 218,265,275, 788,849 Dextrose - 28, 55, 113, 114, 127, 149, 154, 254,265,681,788,849 Edible fats and oils, general - 63, 238, 304, 307,310, 313, 316 Eggs - 617, 788 Eggs yolk - 382 Fish batter - 841 Fish - 129, 238 Kippers - 620 Sardines - 625 Tuna - 629 Fish oil - 106, 194, 359, 788,828, 866 Flour - 618 Fruit - 618 Fruit extracts - 382 Fruit juice- 62, 63, 118, 129, 153, 156, 194, 238, 256, 276, 370, 372, 618, 651, 663, 726,735,782,788,841,850,866 Fruit juice Apple - 123 Grape - 15, 23, 105, 227, 373, 374, 619, 841,850,867 Grapefruit - 1, 106, 227, 515, 619 Lemon, lemonade - 14,22, 144,228,523, 620 Lime - 621 Orange - 15,23, 106, 145,228, 623, 693 Pineapple - 228, 624 Fruit juice concentrates, frozen Grape - 15, 23 Grapefruit - 14, 23 Lemonade - 14, 23 Orange - 14, 23, 145, 228 Pineapple - 14, 22 Tangerine - 14, 23 Fruit juices, pulp- 29, 56, 65, 114, 129, 149, 151,154,256,266,850 Fudge - 618 Garlic salt - 227 Gelatine - 29, 56, 67, 79, 130, 156, 195, 266, 277, 305, 308, 311, 313, 316, 359, 514, 618, 651, 663, 685, 728, 788,841,850, 867
928
Foods and food products Gin
(contd)
Mustard, Oliveoil
paste -2,6,
- 133
50,53,84, 104, 106, 111, 112, 134, 663, 165, 172,203,234, 726, 788, 817,833,
- 56, 114, 118,227,256,266,850 Grapefruit peel, oil - 106, 841, 867 Grapes - 62
Grape sugar - 114, 130, 850 Honey 867 fats - 788 - 382, 620, 788, 868 Iced coffee and tea - 14, 22 Jam, jelly - 382, 788 Jam, jelly, grape - 105 Hydrogenated Ice cream Ketchup Kool-Aid Lard 238,289, 318, 326, 319, 327, (see Catsup) soft drink 304,307, mix Horseradish 149, 153, 154,266,
117, 119, 363, Olives Onion Onion Onions Onion 382,
121, 623,
279,304,307,310,313,316,337-354, 843,872
- 144,228,619,841,850,867 - 14, 22, 144, 228, 382,841,
- 228
flakes juice salt
- 228 - 623
- 106 - 228 Orange drink - 104,105

Orange extract Orange peel, oil Oregano
- 115,852
- 14
144, 323, 156, 228, 316,317, 324, 325, 374, 310,313,
- 106, 228,238,843,873 - 228 Palm oil - 145, 156, 234, 280, 539, 623, 788,
817,833,843,873
- 14, 22, 67,81,
112,
Paprika Pasta
- 228 - 228
320, 321, 322, 328, 329, 330, 336, 361, 371,
Parsley flakes
331, 332,333, 372, 373, flavoring
- 62 - 14,23, 105,228, 371,372 - 62, 134, 135, 145, 153, 204,228,

623,694,817,833,843,873 382, 544, 873
334, 335, Lemon, Lemon Licorice Liquors, 870 Mannitol Margarine Mayonnaise Meat
Peanut butter Peanut oil 280,363, Pectin, Peel oil Pepper Pectin, Certo
376,380,663,783,788,816,842,869 lime, orange emulsion oil and peel powder liqueurs
- 228
- 228
145, 231,
- 228
- 29, 106, 154, 267,890
- 238
Malt, beverages, liquors
- 382,525,
632, 788,
- 204 - 106 - 227, 228 - 228,874

624
Pepper, black
- 788
621,788 105, 228, 788 132, 156, 228,238,278, 788,842,870 304, 307, 310,
Pepsi-Cola Pickles Plums
Maple syrup - 229,
- 62,382, - 624
- 14,23, - 14,22,
Pickle solution Rapeseed oil 844,873,876 Raspberry Rhubarb Rice juice
- 788
313,316,382,621, 371,372,426,783, Meat juices Milk
- 106, 281, 364, 818,835,843, - 625
- 62, 621 - 735
- 625
Meat sauce - 132, 133
- 625 - 228 - 106, 119,228,625,844,876

solution oil
- 14, 22, 29, 57, 62, 63, 66, 67, 83, 106,
119, 373, 622, 133, 144, 150, 381, 154, 156, 201, 1, 382,396, 528,
Root beer Rum Rye
115, 372, 529, Milk Milk, Milk,
219,228,238,258,268,279,363,37 374, 377, 652, 663, 788, 816,832,842,
- 228 - 377, 381, 662, 788
Saccharin, Safflower
851,871 paste sour
- 136 Salad dressing - 876

Salad oil - 106, 382,788 Saponified Sauerkraut Sausage fat Scotch oil
- 228 - 228
powdered
- 228
625
- 382 Mincemeat - 228

Mineral water - 106 104, 105, 115, 133, 156, 238, 258,268, 529, 622, 279,382, Molasses - 29, 57, 67,83, 150, 154, 396,442, Monosodium 709,788 Mustard
- 136, 238,281,
- 228
- 238 - 238 Sesame oil - 228,260,843,844,

Seafood Shortening Crisco Spry - 115,382,852 878
873,876
632, 728, 788,816, (MSG)
632,842,851,871 glutamate
- 370, 572,
- 227 - 238,365, Shrimp - 228

Soft drinks, Soft drink
- 14, 23, 66, 83, 104, 105, 106, 144,

228,279, 37 1, 372, 382,622,
beverages
153, 201,
Soft drinks concentrates
- 228,382, - 382
743, (fountain
788 syrups)
780,783,817,832,842,871
syrup concentrates
15, 24, 37, 114, 156, 227,
228,238,616,
782
929
Foods and food products(cont'd) Sorbitol-51,166,210,627,788 Soup solutions156,382 Soybean oil-139,156,228,282,301,365, 788,819,836,843,844,873,878 Soybean oil,epoxidized 162, 192,210 Soy sauce- 844,878 Spices-228, 229 Starches788 Strawberries627 Sugar,beet and cane liquor- 28,51,54,55, 62.72, 125,149,151, 154, 156, 160, 167, 184, 186,210,252,253,264,274,356, 357,441, 578,579, 614, 632,650,651, 728, 788,811,812,823,825,839,840, 858,860 Sugar juice- 90,878 Sugar,simple syrup- 1,229,238 Sugarsolution,syrup139, 153, 156, 173, 211,222,235,365,373, 374,377, 381, 382, 396, 646, 653,663, 711,776,784, 788,819,836,878,879 Sugar,sucrose51, 146,167,365, 371, 372, 382,627,711,878 Tea-140,146,382,628 Tea,powder-229 Tia Maria - 238 Tomato- 140,238,628 Tomato concentrate106 Tomato juice - 15,22,59,92, 104,106,229, 249,262,271,373,374,628,879 Tomato pulp,puree - 38,879 Vanilla extract 115,229,845,853,880 Vegetable juice - 370, 372, 727, 784,845,880 Vegetable oils36, 51, 57, 60, 63, 64,84, 121, 134,156,167,203,216,262,268,279, 283, 285, 289, 293, 366, 371,372, 373, 374, 378,382,383,385,392, 393, 396, 403,410, 442, 538, 632, 646, 663, 728, 788,820,838,843,845,852,873,880 Vegetables 625,629 Vinegar- 1,31, 34,38,51,59,60, 61,62,64, 66.67.93, 106, 115, 119, 140, 150, 151, 153, 154, 156, 167,173,216,229,238, 249,262,271,283,289,366,368,371, 372,373, 374,378, 382, 392,426, 629, 646, 653, 663,728, 784, 788,820,838, 845,853,880,888,890 Vodka-106,119 Wesson oil22,23, 111, 141,229,241 Wheat germ oil-141 Whey-62,217,721 Whiskey - 31,59,60,67,93, 115, 119, 141, 150, 151, 154, 156,217, 228,229,238, 262, 271, 289, 366, 392, 606, 607, 629, 728,735,788,838,845,853,881
Wine -25,31, 59,60, 62,64, 66,67,94, 106, 115, 141, 150, 153, 154, 156, 238.262.271, 366,371,372,393,629,728,788,820,838, 845,853,881 Worcestershire sause- 146, 229 Yeast - 115, 141, 153, 156, 382,646,778,788, 853,881 Yogurt- 788 Formaldehyde - 1,2, 13,20, 26, 29, 33, 34, 37, 41, 48, 53, 56, 60, 63, 65, 67, 78, 106, 108, 111, 113, 114, 118, 121, 129, 143, 147, 149, 151, 153,154, 156, 157, 162, 171, 176, 194,218, 221, 226, 236, 239, 241, 244, 248, 256,266, 276.300,359,368,370,372,373,374,376, 380, 382,385, 388, 389,392,393, 394,395, 396, 397, 398, 401, 408, 435,441,505, 526, 618,632, 646,647, 651, 660, 663,684,685, 726, 728, 735, 737, 751, 759, 766, 774,780, 782, 789, 798,802,806,814, 828,841,850, 866,882,887,890 Formaldehyde,gas- 618 Formaldehydemixtures-506, 507, 766 Formalin (seeFormaldehyde) Formamide- 176,194,618,660 Formamide,vapor- 737,767 Formic acid- 2, IO, 17, 29, 33, 34, 37, 41,48, 53, 56, 60, 63,65, 67,78, 106, 109, 114, 118,129, 143, 149, 151, 153, 154, 156, 157, 162, 171, 176, 194,218,221,225,236,239,240,244, 248,256, 266, 276, 300, 303, 306, 309, 312, 314,359,368,369,371,373,374,376.380, 382, 385, 388, 389, 392, 393, 396, 397, 398, 401, 408,412, 416, 418,424, 432, 435,441, 507, 618, 632, 644, 646, 651, 660, 685, 726, 728, 732, 737, 751, 756, 759, 767, 774, 779, 782,787, 798, 802,806, 814,828,841,847, 850,854,882,887,890 Formicacid-aceticacid mixtures-507 Formic acid, boiling 418, 420,424, 428,444, 445, 643, 647, 666, 685, 723, 726, 730, 740, 741,751,756,767 Formicacid,vapor- 194 Formonitrile (seeHydrogen cyanide) Fourdrinier dryingsection fumes- 194 Fourdrinier liquor-194 Fraud'sreagent828 Freon - 1, 16,25, 29,37,52, 56, 63, 65, 67,76,78, 83, 92, 106, Ill, 129, 147, 154, 156, 158, 162, 167, 194, 215, 233,239, 248, 256,266,276, 284, 286, 300, 359, 618, 632, 642, 651, 660, 678, 789,814, 826,829, 841,850,866,887, 890 FR FluidD - 276, 814 FRM-276,814 Fructose- 29, 113, 114, 129, 149, 154, 256, 266, 850
930
Fruit - 62, 143,227, 675, 618, 624 Fruit extracts - 382 Fruit juice - 7, 74, 75, 22, 23, 705, 706, 778, 123, 729, 144, 745, 753, 756, 194,227, 228,238, 256, 276, 370, 372, 373, 374, 515, 523, 678, 67 9, 620,627, 623, 624, 650, 652, 663, 693, 726,735,788,841,850,866,867 Fruit juice concentrates, frozen - 74, 15, 22, 23, 145, 228 Fruit juices, pulp - 29, 56, 65, 114, 729, 149, 757, 154,256,266,850 Fudge - 67 8 Fuel gases - 639 Fuel oil - 21, 29, 33, 41, 60, 62, 78, 95, 7 14, 737, 132, 756, 7 62, 177, 7 94, 27 8,223, 224, 248, 256,276,265,304,307, 370,373, 376, 359, 392, 537, 678, 651, 663, 789, 798, 802, 806, 814,850,866,882,884,887,890 Fuel oil, acidic - 359, 829 Fuel oil No. 6 - 359 Fuel oil with sulfuric acid - 29, 780 Fuels - 1 IO, 286,366, 639,841 Fuels, ASTM reference (see ASTM reference fuels) Fumaric acid (allomaleic acid) - 39, 41, 42, 43, 44, 45, 276, 359, 368,376,380, 874, 822,829, 855 Fumigants - 194 Fumigants, soil - 270 Fundal - 41,43 Fungicides, organic - 53, 194, 204, 796 Fungus - 7 94 Furan - 78, 757,218,248,276, 359,874,829, 866 Furan resin - 847, 850 Furfural - 20, 29, 36, 60, 78, 774, 729, 747, 149, 157, 753, 154, 156, 762, 777, 176, 194, 218, 247, 248, 256, 266, 276, 300, 303, 306, 309, 37 2,37 5,359,368,376, 380,392,393, 394, 395, 397, 398,407,408, 435,507, 678, 632, 657, 660, 685,735, 737, 759,780, 782, 789, 874,829,847,866,887,890 Furfuryl alcohol (fury1 carbinol) - 36, 60, 65, 174, 729, 743, 756, 776, 794, 226, 273, 359, 376, 380,392,767,789,867 Furfuryl alcohol resin - 47 Furnace mufflers - 729 Furnace oil - 7 94 Furniture polish Dart - 22 OCedar - 23 Pride - 23 Radiant - 23 Fuse1 oil - 156,874, 829 Fusion 72-62 - 195 Fyrguard - 276,814 Fyrquel- 276, 300, 359, 814
G-61 - 795 Gallic acid (trihydroxybenzoic acid) - 29, 56, 67, 78, 113, 774, 749, 153, 154, 156, 795, 275, 278, 225, 256, 266, 277, 359, 368, 376, 380, 407, 409, 435, 685, 728, 759, 779, 782, 787, 798,802,806,874,829,850,855,882 Gallium, molten - 642, 732 Gallotannic acid (see Tannic acid) Gallotannin - 7 95 Galvanizing line fumes - 795 Garbage incinerator, fumes and scrubber - 195 Garlic salt - 227 Gas - 685 Gas Coal - 65,278, 254,275, 675 Coke oven - 29, 55,126, 751, 156,265, 275, 357,432,508, 67 6,87 2,867 Exhaust - 508,682,685 Flue-48, 762, 794, 508, 509, 678, 683, 684, 692,735, 780 Illuminating - 743 , Manufactured - 29, 750, 754, 278,256 Natural - 78, 29, 33, 38, 49, 56, 67, 79, 733, 750, 754, 156, 162, 218, 256, 266, 276, 279, 287, 363, 432, 622, 632, 652, 728, 789,877,832,871 Sewerage - 706 Sour - 286 Town - 378, 382 Gaseous stream - 685 Gas odorizers - 24 Gasohol - 795, 277, 287, 288, 289, 297, 663 Gas oil - 41, 42, 43, 129, 795, 203 Gasoline1, 2, 5, 73, 20, 21, 26, 29, 32, 33, 37, 49, 53, 56, 60, 67, 62, 63, 65, 67, 79, 96, 97, 98, 704, 706, 707, 108, 709, 711, 772, 774, 777, 721, 730, 740, 743,147, 749,157,154, 155, 756, 757, 763, 769, 171, 176, 195, 200, 207, 278, 223, 224, 229, 236, 239,247, 244, 248, 256, 266, 277, 284, 286, 297, 297, 300, 305, 307, 310, 373, 376, 378, 319, 320, 327, 322, 323, 324, 325, 326, 331, 332, 333, 334, 335, 336, 358, 359, 363, 365, 370, 372, 376, 380, 383, 385, 388, 389, 392, 393, 396, 409, 447, 570, 618, 632, 642, 657, 663, 685, 726, 728, 735, 789, 798, 802, 806,814,829,847, 850, 858, 859, 867, 865,867,877,879,887, 882,884,887,890 Gasoline alkylation - 570, 57 1 Gasoline-benzene mixture - 63 Gasoline components - 7 95 Gasoline, cracking - 570 Gasoline distillation - 570 Gasoline fractionation - 512 Gasoline, miscellaneous processing - 57 2, 57 3 Gasoline reforming - 513, 574
Corrosive
Material
Index
931
Gasoline Gaultheria Gelatin 305,
storage
- 514
Glycolic
acid (hydroxyacetic 130, 149, 376, 266,
acid) - 29, 49, 56, 154, 163, 195, 218, 619, 660, 738,
oil - 829
79, 113, 114, 248,256, 195, 266, 277, 618,651, Glycol Glycols Glyoxal
Gear box oil
- 118, 130, 234

313, 316, 359,514,
380, 521,
- 29, 56, 67, 79, 130, 156, 308, 311,
751,767,841,850,855 monoether
663,685,728,788,841,850,867 Geothermal fluid - 415 Geothermal Geyser water Girling water
- 660 - 53, 56, 62, 229, 266, 360, 646, 814, - 37, 42, 163, 171, 195, 370, 372, 686 acid-formaldehyde - 384
acid - 195
850,867 Glyoxal-acetic Glyoxylic Gold - 790 Gold cyanide
- 195 - 195
condensate
Ginger oil (see Essential oils) brake fluid - 359 Glass cleaner - 195
- 233 Glass wool - 618

Glass wax Glaubers Glaziers Globrite Gluconic 737 Glucose 147, 233, salt (see Sodium putty - 195 acid - 49, 163, 171, 195, 514, 618, 660, sulfate decahydrate)
- 236, 244, 388, 389, 841, 850, 867 - 195 Gold plating solution - 30, 49, 58, 85, 115, 135,
Gold pickling 150, 153, 154, 163, furnace 195, 259, 269, gas, dust - 195 - 195 - 829 368, 834,
- 106
843,884,885 Gold smelting Golden-Glo Grahams Grain
- 195 salt (sodium polymetaphosphate) alcohol)
Golf ball scouring solution
- 1,29,
149,
49, 56, 65, 67, 79, 114, 154, 156, 277, 305, 619, 308, 311,
130, 144, 316,
153,
163, 171, 195,218, 313, 632, 651, 814,829,
- 62
(see Ethyl
256, 266,
Grain alcohol Grain mash Grain oil - 829
360, 368, 841,850,867 Glue
382, 396,
- 867
149, 153, 154,266, 850
- 67, 79, 130, 156, 277, 300, 360, 368, 396,

515, 619, 651, resin 780, 782,789,814,829,
Grape sugar - 114, 130, Graphite Grease 361, - 619 Gray acetate - 829
441,
841,850,855,867 Glue, polyvinyl Glue, sizing
- 767
- 5, 21, 65, 130, 156,277,

364, 365, 366, 515, 1,876,879 vitriol
284,
355, 360, 841, 850,
- 867 Glutamic acid - 435, 515, 660, 685, 728, 759, 787 Glutaric acid - 163, 685 Glutaraldehyde - 163
Glycerin 114, (glycerol) 121, 130, 163, 312, 435, - 1, 10, 17, 26, 29, 33, 37, 49, 109, 111, 113, 154, 144, 147, 149, 277, 389, 619, 291, 368, 151, 293, 153, 56, 60, 63, 65, 67, 79, 106, 108, 155, 156, 236,244, 306, 309, 380, 382, 396, 409, 663, 171, 176, 315, 360, 515,
663, 814,
859,867,869,87 Grease oil - 819 Green copperas, Green death Green
(see Ferrous sulfate) 156, 171,
- 734
liquor - 29, 33, 37, 42, 44, 90, 147,
195,360,439,681,762,783,814,829,867 Green soap solution Gulf oils, fluids, greases Gum, acacia
195,218,221,233, 300, 303, 376, 395, 660, 882, 394, 652, 867, 370,372,
256, 266, 385, 388,
- 16, 111, 121, 130 - 277, 360, 814
- 230 - 230
392, 393, 632, 646, 767,
Gum, arabic - 619 Gum, tragacanth Gypsum Gypsum, Hafnium
686, 728, 737,
743, 759,
774, 789,
- 106
slurry - 195,829 hydroxide
798, 802,806,814,829,841,850, 887,890 Glycerol Glycerol dibromhydrin triacetate - 195
- 515
(triacetin) acid
- 256, 366, 371, 372,
Hair dressing Brilliantine Vitalis
628,829,837 Glycerophosphonic Glycerophosphate Glyceryl Glyceryl Glycine Glycol 118, Glycol Glycol Glycol Glycol trioleate tripalmitate
- 660
- 14, 22 - 15, 23
- 15, 23
- 619
- 829 - 829 98, 106, 114,
Wildroot Halite
Hair solutions Halogenated Halothane Halowax chlorohydrin)
- 15, 23, 493,841,

chloride) hydrocarbons 304, 307,
867
(see Sodium
- 233, 256 - 2, 9, 29, 63, 65, 79, 96,97,

149, acetate alcohol 154,156,195,218,376,380,829
- 116, 120, 229, 230,

310, 312, 315, 619
291,292;293,
- 376, 380, 401, 409

- 829 (see Ethylene
- 360 oil - 360,814

lotion
Halso 99 - 195 Hand cream, Grace
chlorohydrin FR fluids
- 277, 814
- 867
932
Corrosion
Resistant
Materials
Handbook
Hand cream, lotion Hinds Nivea Hannifin Hartshorn
(contd)
Hexanedioic Hexanol Hexanol, Hexanol, carbonate) 360,823 - 729 Hexanol, Hexene Hexone Hexyl Hexylene 619, 728, 867 Hexylene Hexyl
acid (see Adipic
acid) 263, 360,814,816,
- 14, 22 - 872
Lube A
- 54, 156,226,234, iso n
829,839,848,856,867
Harness oil
- 360 - 156, 814

equipment, heat exchangers 45
- 103 - 144,226,303,306,309,312,315,
- 29, 80, 114, 149, 154
(see Ammonium
Heat treating
tertiary
- 41,42,44, Heavy metal salts - 663

Heavy alcohols Heavy spar (see Barium Heavy water Helium
- 814,829
(see Methylisobutylketone) bromide - 229 chloride - 196 glycol - 49, 163 glycol ammonium
sulfate)
- 360
sulfide)
- 79, 156, 195, 360,
Hepar calis (see Calcium Heptachlor Heptane
ether
- 230 - 360,867 - 360, 867
- 277 - 660
11, 18, 26, 29, 33, 39, 41,42, 114, 121, 266, 360,660, 371, 277, 130, 133, 147, 307,
High energy fuel
Heptachlorobutene
- 1, 5,8,
High viscosity lubricant Hog fuel flue gases - 196 Honey Horseradish Hough-O-Safe 814,867 Houghton products
44,45,49, 108, 109, 239,
52, 53, 56, 63, 65, 79, 95, 102, 111, 113, 163, 171, 176, 195,218,229, 296,304, 789,792,814,841, 376,380
- 144,228,619,841,850,867
- 14, 22, 144, 228, 382, 841, products - 102, 867 360,
149, 154, 156, 241,248,256, 309,312,315, Heptanoic Heptyl Heptyl Heptyl
Hot stack gases - 49, 163 156, 277, 291,
842,850.867,887,890 acid - 369, n - 619 (see Octyl alcohol) alcohol, aldehyde carbinol
- 867
Huey test Huff
- 418, 772
100%
- 144, 226
- 196
oil
Herbicides
- 15, 24, 25, 156, 161, 195, 217, 235,
- 256 - 867 Hexachlorobenzene - 230 Hexachlorobutadiene - 660 Hexachlorobutene - 660

Hexachloroacetone Hexachlorocyclopentadiene Hexachlorodiphenylmethane Hexachloroendomethylene anhydride - 195, 196, 376, 380 - 829 tetrahydrophthalic
276,281,616,796,845 Hercolyn plasticizer
- 53,201 - 277, 815 Hydra fluids - 277, 815 HydraSol - 277,815 Hydratite liquid - 841 Hydraulic fluid and oil - 1, 21, 33, 49, 52, 66, 67,
Humidity, Hy-Chock 79,87,88, 207, 282, 319, 328, 355, 274, 284, 320, 329, 360, 850, 107, 275, 305, 321, 330, 361, 815, 862, 110, 155, 156, 287, 288, 310, 323, 332, 364, 313, 324, 333, 163, 171, 196, 280, 281, 317, 318, 326, 327, 335, 336, 276, 277, 308, 322, 331, 363, 816, 278, 279, 316, 325, 334,
285,286,
289, 291,293,
300, 301,
- 196 - 157, 660 - 233
365, 366, 639, 811, 820,829,835, 872, 875,876, 870,
Hexachloroethane Hexachlorophene Hexadecanoic Hexahol - 829
813,814, 841, Hydraulic 878,884
818, 819,
864, 867,
acid - 829 (see Cyclohexane) (see Piperidine) (see Cyclohexane) tetramine) - 79, 196,
polyalkylene 355, 360,
Hexahydrobenzene Hexahydropyridine Hexaldehyde Hexamethylene Hexamine
Hydrazine 300,
glycol - 156 - 80, 157, 163, 171, 196, 267, 277, 516, 619, 660, 751, 783,788,
- 156,360,814,829,867
814,815,829,841,850,857,867 Hydrazine, Hydrazine Hydrazine Hydriodic dihydrochloride hydrate sulfate acid - 789
- 256
(hexamethylene
435,516,528,646,660,663,686,759,867 Hexanaphthene Hexane 147, 286, 319, 328, (see Cyclohexane) 104, 157, 244, 117, 118, 248, 130, 144, 196, 277, 318, 327, - 1, 2, 18, 29, 33, 37, 39, 41, 42, 44, 45, 49, 149, 154, 156, 307, 331, 163, 169, 171, 256, 266, 315, 334, 317, 325,326,
- 401, 409
(see Phenylhydrazine)
Hydrazinobenzene
- 176, 196, 218, 256, 385, 393,

- 619 113, 114, 130, 367, 373, 732, 147, 149, 236, 441, 374, 380,
53, 56, 63, 79, 103, 218, 229, 236, 239,
402,409,660,689,732,767,795 Hydroabietyl Hydrobromic 152, 385, 516, 154, alcohol acid - 29, 33, 34, 37, 42, 49, 53, 156, 266, 661, 163, 392, 171, 176, 393, 196, 218,
300, 304, 329, 330,
309, 312, 323, 324, 332, 333,
56, 60, 63, 79, 109, 244, 256, 652,
320, 321,322,
335, 336,
287, 360, 686, 731,
337-354,360,385,389,409,516,619,686, 814,829,841,842,867,887,890
388, 389,
397, 401, 409,
751, 767,779,
Corrosive
Material
Index
933
Hydrobromic acid (contd) 783, 787, 798, 802, 806, 814,829, 841, 847, 850,855,882,887,890 Hydrocarbon gases - 632 Hydrocarbon, light - 868 Hydrocarbons - 120, 196, 241, 304, 307,309, 312, 315, 360, 619, 642, 648, 686,728, 731, 735, 742 Hydrocarbons, aliphatic - 36, 116, 229, 291, 798,802,806,882 Hydrocarbons, aromatic - 36, 116, 123, 149, 154, 184, 229, 273, 291, 293, 798,803,807, 839, 858,882 Hydrocarbons, chlorinated - 126, 678, 732, 733, 840 Hydrocarbons, halogenated - 116, 120, 229, 230, 291,293,304,307,310,312,315,619 Hydrochloric acid - 1, 2, 4, 6, 9, 10, 17, 26, 29, 32, 33, 34, 35, 37, 39, 40, 41, 42, 44, 45, 46, 49, 52, 53, 56, 60, 61, 62, 63, 65, 67, 79, 95, 102, 104, 106, 107, 108, 109, 111, 112, 113, 114, 117, 118, 121, 130, 144, 147, 149, 151, 152, 154, 155, 156, 157, 158, 163, 169, 171, 176, 196, 197,218, 221, 223, 224,225, 236, 239, 240, 244, 248, 256, 266, 277, 286, 291. 293, 294, 296, 297, 300, 302, 305, 308, 311, 314, 317, 318, 319, 320, 321, 322, 323,324, 325, 326, 327, 328, 329, 330, 331, 332, 333, 334,335, 336,337-354, 360,367,369, 371, 373, 374, 376, 380, 382, 383, 384, 385, 387, 388, 389, 392, 393, 394, 395, 396, 397, 398, 402, 409, 413, 420, 423, 424, 428, 432, 441, 516, 517, 619, 632, 639, 640, 642, 644, 645, 646, 647, 652, 655, 661, 663, 664, 665, 666, 686, 687, 723, 726, 728, 731, 732, 733, 737, 740, 741, 751, 759, 767, 772, 774, 779, 783, 787, 790, 791,792, 793, 798,802,806, 814, 829,841, 847,850,855,882,884,887,890, 891 Hydrochloric acid, boiling - 413, 424, 445, 644, 645,647,666,686,733,740,756,767,855 Hydrochloric acid, chlorine - 647, 737, 740, 751 Hydrochloric acid-chromium trioxide - 737, 767 Hydrochloric acid-copper sulfate - 737, 738, 767 Hydrochloric acid-cupric chloride - 737, 740 Hydrochloric acid-ferric chloride - 655, 733, 740, 741,751 Hydrochloric acid, ferric chloride, ferrous chloride (boiling) - 647 Hydrochloric acid fumes - 726, 779 Hydrochloric acid-HCN - 436 Hydrochloric acid mixtures - 196, 197, 384, 647, 733,737, 751,767 Hydrochloric acid-nitric acid - 737, 767 Hydrochloric acid pickling (see Pickling, acid) 891 Hydrochloric acid saturated with chlorine - 163
Hydrochloric acid-sodium chlorate - 737 Hydrochloric acid-sodium chloride - 733 Hydrochloric acid-sulfuric acid - 655 Hydrochloric acid waste pickle liquor - 221, 774 Hydrocyanic acid - 29, 34, 49, 53, 56, 67, 80, 131, 149, 151, 154, 156, 163, 176, 197,218, 236, 244, 256, 267, 277, 300, 360, 377, 381, 385, 388, 389, 393, 397, 409, 517, 619, 632, 652, 735, 759, 779, 783, 787, 798, 802, 806, 815,830,841,850,882,887,890 Hydra-drive oil - 277, 360, 815, 868 Hydrofluoboric acid (see Fluoroboric acid) Hydrofluoric acid - 10, 17, 29, 33, 35, 37, 42, 49, 53, 56, 60, 63, 67, 80, 95, 102, 106, 114, 118, 131, 144, 147, 149, 151, 152, 154, 156, 157, 163, 169, 171, 176, 197, 218, 221, 225,236, 244, 248, 256, 257, 267, 277, 286, 300, 302, 305, 308, 311, 314, 360, 367, 369, 371, 373, 374, 376, 380, 382, 384, 385, 388, 389, 392, 393, 394, 395, 396, 397, 398, 402, 409, 425, 436, 517, 518, 619, 632, 644, 646, 652, 661, 664, 665, 687, 688, 725, 726, 728, 729, 731, 732, 733, 738, 751, 756, 759, 767, 775, 779, 783, 787, 791, 792, 798, 802, 806, 815, 830, 841,847,850,855,882,884,887,890 Hydrofluoric acid-boron trifluoride - 688 Hydrofluoric acid mixtures - 197, 517, 518, 688, 725,726,738, 767 Hydrofluoric acid vapors - 779 Hydrofluorosilicic acid (see Fluosilicic acid) Hydrogen - 29, 53, 56, 65, 67, 80, 114, 131, 149, 154, 156, 197, 218, 248, 257, 267, 277, 300, 360, 436,519, 619, 632, 646, 652, 688, 728, 731, 732, 759, 789, 798, 803, 807, 815,830. 851,868,882 Hydrogenated fats - 788 Hydrogen bromide - 49, 53, 114, 131, 163, 197, 661,731,732,830,868 Hydrogen carboxylic acid - 830 Hydrogen chloride (gas) - 33, 37, 49, 53, 80, 108, 114, 131, 163, 197, 218, 257, 277, 436, 519, 520, 619, 661, 688, 689, 731, 732, 737, 759. 789,798,802,806,830,851,868,882 Hydrogen cyanide - 29, 56,80, 218,257,267, 620,689,798,802,806,830 Hydrogen dioxide (see Hydrogen peroxide) Hydrogen fluoride - 29, 49, 53, 80, 131, 163, 197, 267, 277, 355, 436, 632, 689, 731, 732, 759,783,789,830,857 Hydrogen iodide - 197, 689, 732 Hydrogen peroxide (hydrogen dioxide) - 1,4, 6, 7, 14, 20, 26, 29, 33, 35, 37, 42, 49, 53, 56, 60, 63, 65, 67, 80, 95, 104, 106, 109, 111, 112, 113, 114, 117, 118, 121, 131, 144, 147, 149, 152, 154, 155, 156, 157, 163, 171, 176, 197, 198, 218, 221, 234, 236, 239, 244,248,257, 267, 277, 286, 295, 296, 300, 360, 370, 372,
934
Hydrogen 373, 393, 442,
peroxide
(contd) 380, 382, 396, 397, 732, 735, 385, 388, 389, 392, 398,402,409,436, 661, 807, 663, 767, 815, 738,751,759, 798, 803,
Hypotower Ice
simulation
- 295
374, 376, 394, 395, 520,
- 620
(see Cryolite) ore
620, 632,
646, 647, 652,
Ice cream (see Foods) lcestone llmenite lmollminoethyl Incinerator Chemical
689, 726,728, 775, 777, Hydrogen 267,851 Hydrogen
783, 787, 792,
- 198
- 198
830,841,847,851,868,882,887,890 phosphide - 29, 56, 114, 149, 218,
277,815 alcohol
sulfide - 13, 20, 29, 33, 35, 37, 49, 53, 131, 149, 151, 300, 396, 735, 156, 163, 169, 244,248, 171, 257, 176, 198,218, 267, 277, 392, 393,
- 198
56, 60, 62, 63, 67, 80, 114, 152, 154, 219, 360, 367, 231, 236,
Flue gas - 692 Garbage - 195 Scrubber Indium, lndium - 195, 198, 692 135, 150, 153, 154, 843, molten
376, 380, 652, 661, 767, 777,
385, 389, 663,
- 642
398,402,409,436,520,521,609,620,632, 642, 646, 738, 759, 689, 728, 732, 783, 789, 798, 803, 807,
plating - 115,
884,885 lndustron Inhibitors Ink oil Inks
815,830,841,847,851,868,882,887,890 Hydroiodic Hydrolube Hydrolubric Hydroquinine Hydroquinone, 114, 131, acid (see Hydriodic - 156, 277, oil 360, 868 acid)
- 277, 360, 815 - 631
- 156, 815 - 15, 24, 26, 106, 114, 131, 234, 277, 620, - 53, 612, 743, 796, 868
- 277, 815 - 661

hydroquinol
742,783,788,815,841,851,868,874 Insecticides
- 13, 20, 29, 56, 63,

153, 154,231, acid) 257,
Aldrin Calcium
- 796 arsenate - 796
144, 149,
151,
BHC - 796 Chlordane DDT
267,360,376,380,521,815,830,851,868 Hydrosilicofluoric Hydrosulfite Hydroxyacetic 841 o-Hydroxyacetophenone Hydroxybenzene o-Hydroxybenzoic Hydroxyethylamine Hydroxylamine Hydroxylamine 267 2-Hydroxy-1,2,3-propanetricarboxylic Citric acid) a-Hydroxypropionic Hydroxyquinoline Hydroxysuccinic a-Hydroxytoluene Hydyne Hyjet Hykil Hypo acid (see Lactic acid) acid (see acid (see Fluosilicic acid (see Glycolic acid) bleach (see Sodium hydrosulfite)
- 15, 24, 67, 175, 229, 275, 357,

127, 156, 190,233,275,
615,659,796
- 830,
- 15,53,65,
495,616,
660,796,862
- 610
acid)
Diazinon Dieldrin Ethyl Fundal 198,
- 276, 358
- 796 - 193
(see Phenol) acid (see Salicylic (see Ethanolamine)
parathion
- 41,43 - 67, 144, 156, 231, 278, 661,
- 788
sulfate - 29, 149, 154, 195,
Lead arsenate 663,796 Lindane
- 65
acid (see Malic acid) (see Benzyl alcohol)
- 360,868 - 156,815
- 278 - 25 Malathion - 26, 278, 361, 816, 870 Methoxychlor - 278 Methyl parathion - 41 Mortemoth - 24 Parathion - 204,796 Purina - 28
Malaphos Rotenone Sevin
- 360
No. 6 in water (see Sodium (see Acetophenone) thiosulfate) 154 or Sodium 80, 109, 380, 732, acid - 149,
- 156
Hypnone
- 281, 818 Sobicide - 235 Toxaphene - 16,25,

6-12
156,214,262,628,796
Hypochlorene Hypochloride hypochlorite) Hypochlorous 114, 267, 277, 385, 393,
Insect repellent
- 22
23, 25, 127, 129,
bleach (see also Calcium - 689, 775, 847 acid 360, 396,
Insect spray133,233,235 Insulating Insulating oil
14, 15, 16,22,
- 34,42,49,
154, 163, 397, 172, 369, 37S, 373,
53,56,
149, 151,
198,219,257, 374, 376,
tape
- 156, 815 - 106

- 689
Insulin extract Invert sugar lodides
398,402,409,661,
- 620
738,787,815,830,851,855 Hypophosphoric Hypophosphorous acid - 198 acid
- 663
149, 154, 156, 172, 176, 198, 219,221,
Iodine - 13, 29, 33, 36, 37, 53, 56, 60, 80, 104, 105,
- 176, 198
Corrosive Material
Index
935
Iodine 392,
(contd) 393,
- 230, 234, 257, 267, 277, 360,

409, 775, 521, 620, 661, 663, 798,803, 737, 780, 789,
lsooctanoic lsooctyl lsopentane
acid
- 620
398, 401,
689, 731, 732, Iodine, alcohol
807,815,841,851,868,882 solution
- 63, 112, 118, 131, 144,

305, 308, 311, 313, 316,
- 830 - 868 lsophorone - 42, 103, 360,868 lsophthalic acid - 787

thioglycolate lsoprep - 198 Isopropyl Isopropyl acetate - 11, 18, 81, 103, alcohol 144, 306, 156, 227, 277, 360,663,789,815,830
151, 230, Iodine,
234, 277,
738,868,887,890
- 63, 114, 732, 738, 767, 851 Iodine pentafluoride - 360,830

KI solution Iodine vapor - 198, 257, lodoform losan - 156,219, 689, 738 409, 620, 257, 360,402,
- 2, 8, 9, 10, 17, 29, 33, 37, 41,

103, 107, 293, 372, 689, 145, 148, 309, 312, 398, 559, 153, 315, 620, 155, 277, 360, 661, 156, 159, 291, 370, 663,
42, 43, 45, 47, 54, 60, 63, 65, 81, 102, 118, 131, 170, 300, 303, 176, 198, 226, 263, 273,
661.780,783,798,803,807,830,868,883
- 131
lrgasol DA - 198 Iron - 790 Iron and steel cleaning Iron chlorides bath - 49, 163, ferrous 198 chlorides) (see also Ferric,
392, 393, 397, Isopropylamine
789,815,830,839,841,848,851,856,868 - 49, 163, 198, 226, 257
Isopropylbenzene Isopropyl Isopropyl bromide carbinol chloride
(see also Cumene)
- 663
iso)
236,244,385,388,389,409,830 Iron iodide - 176 Iron nitrates 236,244, Iron oxides (see also Ferric, 385,389,409,830 ferrous nitrates)
- 663
(see Butyl alcohol, ether) oxide)
Isopropyl Isopropyl Isopropyl
- 360, 559, 689, 830, 868

(see Mesityl
ether (see Diisopropyl myristate palmitate
Iron ore sinter, fluegas, scrubber - 689
lsopropylideneacetone Isopropyl 843, lsotane lsotox ltaconic Jam, jelly
- 620
(see Ferric chloride)
- 42, 45, 109

- 49, 163, 198
Iron perchloride Iron persulfate 884,885 Iron protochloride
- 830
- 49, 163, (see Ferrous 198, 259, 834, chloride)
lsopropyltoluene
(see Cymene)
Iron plating solution
- 868 - 868
acid - 198, 620 (see Foods)
Iron salts (see Ferrous Iron sesquichloride Iron sesquisulfate Iron sulfate Iron sulfate, Iron sulfide
and Ferric salts) Japanese gelatin ferrous sulfate)
- 830 - 830 - 237,
- 830 - 304, 307, 310, 313, 316

154, 267, 380, 172, 198, 219, 291, 373, 257,
(see also Ferric, basic
Jet aircraft
engine oil 164,
244,376,380,385,389,409,830,868
Jet fuel - 29, 33, 37, 49, 56, 81, 109, 149, 155, 156, 278, 169, 289, fluid 287, 288, 374, 376,
- 823
- 620 Iron tersulfate - 830

Iron vitriol lrus fluid lsoamyl lsoamyl lsoamyl lsobutane lsobutyl lsobutyl lsobutyl (see Ferrous sulfate) acetate, iso) iso)
789,815,830.841,851,868 Jet II Hydrocarbon Jet propulsion JP fuel fuel JM adhesive - 198
- 284
- 277, 815
acetate alcohol aldehyde alcohol butyrate chloride (see Amyl (see amyl alcohol,
- 21
- 107, 198, 215, 219, 257, 267, 278, 287,

291, 293, 300, 360, 361, 370, 372,
- 156
(see Butyl alcohol, iso)
288, 289,
- 277,815,868 - 360,868
(see B%rtyl chloride, iso)
815,830,851,868 Kaolin slurry - 198
Kelex ligand (solvent extraction) Kel F liquids
- 42, 45
- 156, 868 lsobutyl phosphate - 661 lsobutyraldehyde - 868 Isobutyronitrile - 234

lsobutylene lsocure - 198 lsocyanates lsodecanol lsododecane I-lsoleucine lsooctane
- 361
110, 164, 300, 385, 663,
Kerosene - 1, 5, 6, 7, 21, 29, 32, 33, 37, 41, 42, 43, 45, 49, 53, 56, 60, 65, 67, 81, 104, 117, 144, 169, 172, 257, 267, 388, 728, 148, 149, 151, 154, 237, 292, 155, 239, 296, 620, 815, 156, 297, 382, 652, 198, 219,229, 278, 284, 286, 373, 374,
244,248,
- 65
- 198
361, 370, 372, 789, 792,
376, 380,
- 360,868
389, 392, 409,
521, 522,
lsoeugenol - 620
+ d-alloisoleucine - 257 - 8, 56, 63, 81, 95, 104, 1 IO, 117, 131, 158, 267, 277, 286, 290, 296, 300,
798, 803, 807,
830,841,
851,869,883,884,887,890 Kerosene and naphtha Kerosine Kester, No. 135 - 102
148, 156,
- 841,869 - 131, 296, 304, 307, 310, 313, 316
360,815,830,841,851,868
936
Corrosion
Resistant
Materials
Handbook
Kester No. 1544 - 102 Ketenes
Lauryl Lauryl Lauryl 154, 304, 789, 293,
mercaptan pyridinium oil
- 199
chloride - 199
- 522
(see Cyclohexanone) 149, 248, 278, 285, 291,
Ketohexamethylene 156, 219, 241, 307, 310, Ketopropane Keystone Kleenezy
sulfate - 29, 257
Ketones - 29, 36, 53, 81, 116, 120, 313,315, 522, 632,
Lavender Lead
- 21, 361, 831,869
Layor caranga (see Agar-agar)
642, 646,
- 157, 728
109, 118, 132, 221, 385, 153, 231, 388, 154, 389, 156, 392, 164, 172, 257, 267, 393, 397, 851,869,
798,803,807,841,851,869,883,887,890 (see Acetone) grease oil, fluid,
Lead acetate - 29, 49, 56, 60, 63, 81, 108, 113, 115, 176, 199, 219, 278, 361, 380, 237, 244,
- 361, 869
- 132 Kleenosan - 132

Kleer-View Knotter Kraft Kresol Kurrols windshield washer solvent
398,436,620,661,735,
738,759,768,775,
- 132
777,788, 883,887,890 Lead arsenate 796,816,831 Lead azide
798, 803,807,816,831,
fumes - 198
Kraft fibers, wood - 689 liquor - 29, 149, 154, 267
- 67, 144, 156, 231, 278, 661, 663,
- 132
salt
- 620, 661
alloy, eutectic - 690 - 690
- 830
- 198
Lead-bismuth Lead carbonate Lead chloride
Kymene LPC-
resin solution
- 788 - 56, 154, 199, 267, 380, 385, 393,
Lead, lead chloride 199 salt (see Sodium 620, 632, hypochlorite) Labarraques 278, 402,409,661 Lead chromate Lead dioxide
Lacquers and lacquer solvents 300, 361, 831,841,869,884 Lacquer thinner Lactams-amino Lactic acid 60.63,
- 81, 132, 156,
652, 789, 816, 890
- 661 - 661 - 523 - 81, 642, 646, 728, 732, 738, 780,
Lead dust, fumes - 199 Lead fluosilicate Lead, molten 869 Lead monoxide Lead nitrate 222, 115, 172, 248, 314, 382, 652, 132, 176, 257, 361, 383, 409, 661, 816,
- 6, 7, 29, 286,887, acids - 361

106, 109, 113,
- 2, 10, 17, 29, 33, 34, 37, 49, 53, 56,

65, 67,81, 149, 153, 300, 303, 154, 156, 164, 240, 244, 376, 380, 646, 759, 306, 309, 312, 374, 396,
144, 148, 267, 368, 278,
- 620 - 33, 49, 56, 81, 144, 164, 172, 199,

244, 267, 436, 361, 385, 388, 759, 389, 620, 661, 775, 783,
199, 219, 221,
225, 237,
231, 237,
393, 402, 409, 788,816,831,869 Lead peroxide 153, 154, Lead salts Lead oxide
369, 371, 373, 392, 393, 522, 523, 735, 787,
388, 389, 436, 442, 689, 775,
397, 398, 402,
620, 632, 738, 751,
726, 732, 779, 783,
767, 768,
- 523, 620,661, 663 - 661 Lead plating solution - 30, 58, 85, 115, 135, 150,
164, 199, 259, 269, 368, 523, 698, 834,843,884,885
791, 798, 803,807,
822,831,842,847,851,855,883,887,890 Lactic acid, boiling 779,855 Lactic acid salts Lactol
- 444, 647, 689, 690, 751,
- 777 - 156, 816,831 Lactose - 234, 523 Lanolin - 132, 144, 226, 371, 372, 663
Lanolin bleach - 690 257, 267, 355, 620, Lard (see Foods)
- 150, 367 - 63 Lead styphnate - 831 Lead sulfamate - 81, 361, 816, 842, 869 Lead sulfate - 56, 67, 154, 156, 267, 278, 661,
Lead stearate 816,831 Lead sulfide Lead, white, Lecithin Lehigh
- 222, 775
sublimed
Lead trinitroresorcinate Leather tanning
Lard oil - 29, 56, 149, 219, 816,831,851 Larvacide
- 831 - 836
- 199, 620
and finishing
- 842, 869
and solutions
- 816
Xl 169 Xl 170
Lasso - 164, 199, 278,816 Latex emulsions 113, 869 Laurie acid - 29, 49, 56, 148, 149, 154, 199,219,257,267,787,831 Lauryl alcohol Lauryl 219, chloride 257,267 164, 172, 115, 164,
- 15, 24, 33, 81,

851,
Lehigh 872
- 361 - 361
172, 199, 620,816,842,
Lemon oil
- 57, 118, 132, 219, 257, 267, 842,869,
dl-Leucine 164, 176, 199, Levulinic Lichenic
- 144, 199, 226

- 29, 49, 56, 149,
- 13, 21, 228 - 234, 257 Leucogen (I-Asparaginase) - 831

Lemon oil (flavor) acid - 49, 164, 172, acid 176, 199, 253, 690
- 831
Corrosive
Material
Index
937
Lighter fluid Lighter Lighter fluid, fluid,
- 15, 22, 234

butane - 669 naphtha
Liquid Liquid Lithium Lithium Lithium
rosin
wrench
- 831 - 1, 234
- 19,49,57, - 199, 788 150, 154, 164, 199,
- 234
Liquimoly
- 361
bromide carbonate chloride
Light gas cycle storage - 199 Light oil
- 286 - 156
257,267,286,523,524,842,869
Light oil residual Light water Lignin, Ligroin
Light process oil - 1, 234, 291 - 199, 216 - 869 Lignin - 199, 842 liquor Lignosulfonate Lilac, artificial Lime acetate Lime bleach Lime hydrate
- 33, 37,42,81,
172,
199,417,
436,524,621,661,690,738,759,795,869 Lithium chromate - 286 Lithium ether) Lithium Lithium, Lithium acetate) hydroxide) Lithium Lithopone hydroxide hypochlorite molten salts sulfate
- 33, 37,81,
156,
199, 436,
- 199 - 234
oxide) (see Calcium (see Calcium
661,759,788,869
(see Petroleum
- 661 - 642, 646, 732, 738
Lime (see Calcium
- 156
- 49, 164, 199
- 278, 361, 816, 831, 869 - 199
- 222,621, 661,775 Lithopone, sludge - 726

Livestock Lockheed spray base - 189, H 55 - 110 oil, grease (see also Greases) 115, 118, 364,365,366, 132, 150, 278,283, 199 Lix 64N - 199
Lime kiln stack gases Lime liquor - 869 Lime mortar Lime oil
- 621
effluent
Lime neutralization
- 199
nitrate)
Lubricating
- 13, 14, 21,

156, 172, 621,
- 831
(see Calcium
29, 52,57,82, 219,233,248,257, 301, 357, 361, 639, 742,789,813, 890 Lubrizol
Lime saltpeter
284,285,300, 367,537,
Lime slurry - 199, 788 Lime slurry and caustic soda - 690 Limestone Limestone Lime sulfur Lime water
816,820,827,831,838,
- 621,831
slurry - 690 (see Calcium - 199 oxysulfide)
842,851,852,869,871,872,875,884,887,
Lime, thiosorbic Limonene
2,4-Lutidine dl-Lysine MCS 312 MCS 352
- 284 - 234
hydroxide) hydrochloride
- 144, 156, 234, 869 - 824, 826, 831 Linalyl acetate - 728 Lindane - 278,816 Lindol - 156, 361, 842,869 Linear alkylate sulfonates - 199 Linoil - 831
(cinene) Linoleic Linoleic Linolenic Linolic acid - 29, 57, 81, 150, oil 154, 199, 219, 257,267,361,816,831 acid
Lye (see Sodium
- 257
- 361 - 361 MCS 463 - 361 MIL-A - 362

MIL-C362
- 57, 150 - 831

acid) 63, 67,81, 244, 102, 156, 257, 768, 869,
acid (see Linoleic
Linseed cake Linseed oil
- 65, 278
29, 33,57, 132, 148, 150,154, 237, 239, 361, 652, 371,
- 2,5,21,
106, 112, 115,118, 164, 172, 267,278, 291,
199, 219,234, 293, 300, 398,621,
372, 382,
385, 389,393,
663, 738,
783, 789, 816,824, 872 Linseed oil, blue Linseed oil, chlorinated Linseed oil, standard Lipstick
831,835,842,851,
- 132, 267 - 199

varnish
- 106
- 144
Coty - 14, 22 Lady Esther - 14,22 Liquefied Liquid petroleum
- 362 Ml L-F - 362 Ml L-G - 361,362 Ml L-H - 286,287,288,289,362,363 MIL-I - 362 Ml L-J - 362 MIL-L - 286,287,288,289,361,362,363 MIL-0 - 362 MIL-P - 362,363 MIL-S - 361,363 MIL-T - 362 Macassargum - 831 Machine oil - 21, 132, 150, 154, 267,278 Machine oil and S sumes - 199 Machine oil, light - 234 Maddrells salt - 831 Magenta dye, 2% solution - 132
Ml L-E Magnesia alba (see Magnesium Magnesite acid pulp mill liquor acetate - 869 carbonate)
- 156
- 248, 361, 831,869
- 42, 199
petroleum
gas (LW
Magnesium
938
Corrosion
Resistant
Materials
Handbook
Magnesium arsenate - 663 Magnesium bicarbonate - 199 Magnesium bisulfate - 82 Magnesium bisulfite - 49, 164, 199,376, 380,831 Magnesium bisulfite acid liquor - 199 Magnesium bromide - 231 Magnesium, calcium chloride - 436, 760 Magnesium carbonate - 19, 29, 33, 49, 57, 82, 108, 113, 115, 118, 132, 144, 152, 154, 156, 164, 172, 199, 219, 231, 257, 267, 278, 393, 398, 442,661,663,690,778,816,831,869 Magnesium chlorate - 796 Magnesium chloride - 12, 29, 33, 34, 37, 49, 57, 60, 63,65,67,82, 106, 113, 115, 119, 132, 151, 152, 154, 156, 157, 164, 172, 199, 200,219, 222, 237, 240,244, 248, 257,267,278, 300, 303, 306,308, 311,314,361,373,374,376, 380, 384, 385, 387, 388, 389, 392, 393, 394, 395, 397, 398,402,409,417,423,436, 442, 524, 609, 621, 632, 646, 647, 652, 661, 663, 690, 728, 732,735, 738, 751, 760,768, 775, 778, 783, 788, 798,803, 807. 816, 831,842, 847,869,882,887,890 Magnesium chloride, boiling - 444, 690, 722, 741, 751 Magnesium chloride hexahydrate; filter aid - 199 Magnesium chloride vapors - 741 Magnesium citrate - 267, 726 Magnesium hydrate (see Magnesium hydroxide) Magnesium hydroxide - 29, 33, 38, 49, 57, 63, 67, 82, 113, 115, 119, 154, 155, 156, 164, 172, 200, 219,237, 244, 248,257, 267, 278, 300, 361, 382, 385, 388, 389, 393, 394, 395, 396, 398,426, 621, 632, 652, 661, 690, 728, 735, 738, 760, 768,788, 792,798,803,807, 816,831,842,870,883,890 Magnesium, molten - 646, 732, 738 Magnesium nitrate - 29, 33, 57,82, 113, 115, 119, 152, 154, 156, 172, 200, 219,237,244, 257, 267, 278,373, 374,385, 388, 389,393, 397, 398,402,409, 621, 728, 735,778,783,816, 831,842,870,887,890 Magnesium oxide - 200, 524, 621, 691, 788,842, 870 Magnesium salts - 361, 851 Magnesium silicate - 621 Magnesium sulfate - 12,29,33, 34,49,55,57,60, 63,67,82, 106, 109, 113, 115, 119, 132, 152, 154, 156, 164, 172,200,219, 222,237, 244, 257,266, 267,278, 303, 306, 308,311, 314, 361, 376, 380, 382, 385, 388,389, 392, 393, 396,397, 398,402,409,436, 441,442, 621, 632, 646, 652,657, 661, 691,728, 732,735, 738, 760, 768, 775, 778, 782, 783, 788, 798, 803, 807,816,831,842, 849, 870, 883, 887, 890 Magnesium sulfide - 132
Magnesium sulfite - 119, 361, 870 Magnifloc - 200 Magnus Light - 278, 816 Medium - 278, 816 Maize oil (see Corn oil)
Malathion Maleic 49, 151, 244, 380, 436, 783, 887,890 Maleic Maleinic Malicacid 200,201, 369, 735, Malonic Malt Manganese, Manganese Manganese 525, 870 Manganese Manganese Manganese Manganese Manganese Manganese 267, 831 Manganese Mannitol sulfide 278, nitrate oxide 728, 371, 760, acid anhydride acid acid 53, 154, 257, 382, 524, 787, (see - 29, 57, 60, 164, 267, 388, 621, 798, tnsecticides) 33, 34, 38, 176, 369, 392, 691, 807, 39, 200, 371, 393, 738, 831, 41, 113, 373, 398, 760, 851, 257, 42, 115, 374, 402, 768, 855, 361, 43, 222, 44, 237, 376, 409, 775, 883, 376, 380, 45, 150, 67, 82, 172, 361, 389, 646, 803. 109, 144,
219,
- 33, 38, 200,

783,831,870
621,661,691,
- 831
34, 57, 225, 524, 779, 883 621 82, 525, 787, 132, 621, 799, 150, 278, 661, 153, 361, 726, 156, 368, 728, 816, 184, 222, 436, 775, 257,267,
- 29,
803,807,
823,831,855,
- 148,
ammonium
beverages,
liquors
- 382,
sulfates
525,
632,
788,
870
- 200
436, 778,
carbonate chloride 735,
- 728, 735, 778, 870 - 82, 222, 393, 402, 409,

738, 751, 760, 768, 775,
- 842, 870 - 402, 409

acid 156, 278 156, 200, 257,
oxide-sulfuric salts - 132, solution sulfate 392,
- 384
- 62 - 60, 63, 82, 106,

393, 402, 409, 525,
690,
788,
- 156
- 788 Maw gas - 816 Marble - 831

Margarine Marine Marl Marsh Mash (see Foods) fouling
- 2PO
- 831
gas (see Methane) 870
- 156,842, Matar - 200

Maximul - 278,816
Mayonnaise
(see Foods) Meat and beef - 62, 132, 133, 735,839,858 Melamine - 842 Melamine resin - 200,870 Melamine varnish - 278 Mentholatum - 230 Menthol crystals - 230
142, 227,
228,
621,
Corrosive Material
Index
939
Menthol Mercapsol
in butanol
- 13
2-Methoxyethanol ether) Methoxyethyl
(see Ethylene
glycol
monomethyl
- 525 Mercaptans - 870

Mercaptoethanol Mercaptopropionic Mercuric Mercuric acetate chloride
oleate
- 57, 258, 267

144, 156, 377, 380,393,
- 200
acid
Methyl
acetate - 11, 18, 63, 65, 82, 103, 245,278,361,
- 200
57, 152,
176, 227,237, Methyl Methyl Methyl 691, Methyl 870 Methyl 119, 154, 156, alcohol acetoacetate acetone
- 236, 245, 389 (bichloride) - 12, 29,34,49,

113, 115, 119, 367, 376, 775, 133, 144, 380,393,397,
402,409,497,691,789,816,831,851,870
- 156, 361 - 230 - 200
63, 67, 82, 106, 154, 156, 267, 398,402,409, 735, 738, Mercuric Mercuric 219, Mercuric Mercuric Mercurous Mercurous 154,
- 156
164, 172, 200, 219,222,231,257, 525, 751, 768, 632, 646, 647,661,
Methylacetophenone acrylamide acrylate
278, 300,361,
- 278, 361, 789, 816, 831, 842, - 8, IO, 17, 26, 29, 32, 33, 34, 38,
109, 111,115, 151, 278, 309, 377, 526, 738, 153, 286, 312, 380, 621, 743, 117,119,121, 154, 292, 315, 382, 652, 760, 839, 155, 156, 239, 293, 296, 361, 366, 383, 385, 397, 398, 657, 661, 781, 789, 842, 848,
778, 796, 799,803,
807,816,831,842,847,859,870,883,890 chloride cyanide 257, 267, nitrate sulfate vapors - 691 - 29, 57, 82, 115, 278, 393, - 219, 222, 397, 398, 738, 257, 436, 768,
39, 41, 43, 44, 45, 46, 47, 49, 54, 60, 63, 65, 82, 102,103,104, 133, 144, 157, 760, 775 148, 169, 170, 303, 389, 436, 150, 273, 306, 374, 440, 807,
778,816,831,870,890
176, 200,
219,226,237,
244, 258, 263, 297, 300, 387, 388, 402,409, 663, 669, 370, 372, 373,
Mercurochrome nitrate
- 57, 222, 267, 661, 775 - 14, 133,231

- 49, 164, 172, 200 - 29, 57, 82, 115, 119, 133, 152, 278, 393, 397, 398, 661, 778,
chloride
392, 393,
394, 395,
156, 267, sulfate
691, 735,
816,831,870 Mercurous Mercury 152,
792, 799, 803,
816, 831,
- 222, 775
108, 115, 119, 380,393,436, 726, 133, 621, 728, 732, 816, 157, 172, 200,219,234,258, 361, 376, 768, 661, 691,
851,856,860,870,883,887,890 Methyl 380, aldehyde (see Formaldehyde) Methylamine Methylamyl Methylamyl Methylaniline Methylated Methyl Methyl Methyl Methyl Methylbenzene benzoate bromide D-bromide butanol
- 29, 57, 63, 65,82, 154, 156, 300,
- 57, 82, 156, 268, 278, 279, 377,

acetate alcohol
267, 278, 639, 642,
621,816,851
646, 652,
735, 738, 760, Mercury Mercury Mercury Mercury alloys salts
780, 799, 803, 807,
- 156 - 156, 226, 279

(see also Hexanols) industrial
831,842,851,870,883,890
Methylamylcarbinol spirits,
- 816
- 738
ammoniated - 231 - 150, 156, 278, 621, 648, 652, 663,
- 363, 832 - 43
(see Toluene)
ointment,
732,788,851,870
- 361,816 Merthiolate, tincture - 231 Mesityl oxide - 144, 234, 278, 361, 876, 831, 870 Metalicoil Al85 - 870 Metallic soaps - 278 Metal phosphate salts - 200
vapors Metal plating solutions Metal sulfate salts Metaphosphoric Methacrylates Methacrylic Methallyl Methallyl Methanal Methane 436, acid (see Plating solutions)
- 227, 361 - 65, 83, 115, 133, 200, 219, 258, - 361
(see also Hexanols)
268,279,361,613,663,816,831,851,870 (see Amy1 alcohols)
Methylbutylcarbinol Methylbutylene Methyl Methyl Methyl butyl 842,851,870 carbonate Cellosolve ketone
- 234
816,831,
glycol acetate
- 402, 409
- 11, 18, 278,361,
- 200 acid - 176
- 361
(see Ethylene glycol monomethyl
- 39, 43, 45
- 157, 172, 200, 258, 376, 526 chloride - 43, 44, 46, 176, 200 ether of o-nitrophenol - 43, 44
(see Formaldehyde)
ether) Methylcellulose Methyl chloride
- 361, 663
- 29, 33, 57, 66, 67, 83, 115, 144, 156, 172, 361, 831, 377, 663, 691, 176, 200,219, 380, 760, 783, 789, 230, 799, 387, 398, 436, 870, 883, 887,
150, 151, 154, 258, 268, 279, 268, 278,361, acid) 527, 621, 803, 890 Methyl Methyl Methyl chloroform 652,
Methanamide
- 200
219, 258,
- 57, 65,82,
621,663,760,789,831,870 acid (see Acetic acid - 219, 258 alcohol)
807,816,
842,851,
Methanecarboxylic Methanesulfonic Methanol dl-Methionine Methoxychlor
(see Methyl
chloroformate chloromethyl
- 57, 200, 219, 258, 268, 286 - 361

ether - 176, 258
- 234 - 278
Methylchlorosilanes
- 870
940
- 258 - 226 Methylcyclohexanol - 377, 381,402, 409 Methyl cyclopentane - 361,832,842,870,871

Methyl cyanoacetate Methylcyclohexane Methyldichlorophosphine Methylene blend Methylene Methylene 113, 161, 381, bisthiocyanate, - 691 polychlorophenol
Methyl Methyl
laurate
- 227
(monomer) 361,
methacrylate
- 20, 57, 156, 157,

622, 816,832,
172, 201, 258, 842,851,870 Methylnaphthalene Methylol Methyl Methyl
268, 279, - 229,
377, 381
acrylamide oleate parathion
- 201
- 201
bromide chloride
- 57, 258, 268, 292, 842,871

(dichloromethane) 57, 63, 83, 103, 144, 371, 148, 150, 372, 373, 527, 621, - 9, 11, 18, 106, 154, 374, 661, 111, 156, 377, 663,
29, 33, 38, 43,49, 115, 164, 119, 133, 300, 361, 778, 783,
- 361, 832, 870 - 41, 43, 201 2-Methylpentane - 363 3-Methylpentane - 363
Methylphenol Methylphenyl Methylpropanol Methyl Methyl Methyl propyl n-propyl salicylate 371, (see Cresol) ketone (see Acetophenone)
172, 177,201,219,230,248,258,
279, 292, 691,760, Methylene Methylene Methylene Methylene Methyl Methyl Methyl 107, 153, 237, 286, 325, 374, 394, Methyl Methyl Methyl Methyl Methyl 870 Methyl Methyl Methyl Methyl
Methylpolysiloxanes
- 832
alcohols)
393, 402,409,436,
(see also Butyl benzene ketone 372,
- 832, 856
792,816,831,842,851,
- 832
- 11, 103, oil) 622, 663, 144, 230
87 1,887,890 chlorobromide dioxybenzene iodide succinic acid
- 268, 832
reaction mixture - 691
(wintergreen
- 144, 234, 258,

789, 816, 832,
279, 361, 870 Methyl Methyl
- 57, 258, 292 - 201 - 46

103, 150, 151, 230, 313, 324, 333, 393, 768,
styrene - 49, 164,201 sulfate - 29, 43, 57, 66, 150, acid 154, 237,245,
ether ethyl 111,
- 361
ketone - 1, 2, 9, 11, 18, 26, 29, 33, 115, 119,133, 157, 245, 297, 319, 164, 300, 320, 329, 385, 528, 144, 148,
ether of o-nitrophenol
268,279,385,388,390,402,409 Methylsulfonic Methyl Methyl Mickro Milk sulfuric
- 43, 172, 402, 409

154, 219,
34, 38, 43, 49, 53, 57, 60, 63, 66,83, 154, 156, 239, 241, 291, 293, 326, 377, 395, ethyl ethyl 172, 200,219, 304, 307, 321, 322, 330,331, 388, 389, 621, 661,
acid - 29, 57, 115, 150, - 258
258,268,732,851 trichlorosilane Klene
248, 258,268,
279,284, 310, 323, 332, 392, 691,
- 871
(see Foods)
315, 317, 318,
Milk acid
327, 328, 381, 383, 397, 398, ketone; ketone
Milk of lime Milk waste
- 832 - 381
334,335,336,337-354,361,371,372,373,
789,792,816,832,842,851,870,887,890 DMP; MEK peroxide peroxide
- 200
- 238, 832 - 201 Mineral acids - 663 Mineral heating oil - 106 Mineral oil - 2, 5, 6, 7, 12, 29, 33, 36, 38,49,
Milk of magnesia 60, 63, 67, 83, 84, 95, 102, 119, 133, 144, 300, 372, 150, 156, 104, 113, 115, 164, 172, 201,219, 313. 377, 381, 403, 316,363.
57, 117,
- 361, 870
ethyl silicone eugenol formate glycerol hydrazine isoamyl
- 234
361, 621, 789,816,832,
- 234
- 279,
234,237,239,241,245,248,258,268,279, 291, 296, 304,307,310, 373, 374, 788, 396, 402. 368, 371, 382, 383, 409, 410, 832,842,
- 621
(2-octanol)
385, 390,
392, 393, 663, 783,
Methylhexylcarbinol Methylimino
- 832
622, 646, Mineral Mineral pitch
789, 816,
- 363
ketone
851,852,871,872
ether - 195, 201
- 832
245, 279, 1 297, 371, 372, 382, 388, 390,
- 26 isobutyl alcohol - 47, 49, 133, 159, 164,

Carbitol ketone
spirits - 1, 15, 24, 32, 41, 42, 43, 155, 156,
234, 237,
172,268 Methylisobutyl Methyl 156, isobutyl 164,
- 172
(hexone) 177,200, 371, 372, - 9, 11, 18, 29, 133, 144, 201,219, 622, 661, 150, 154, 230, 686,
789,816.832,87 Mineral thinner Mineral Minesafe Mirabilite Miscible Miners oil
wool slurry Sunoco oil
- 832 - 201
3XF
38, 43, 49, 57, 66, 83, 103, 172, 176, 315,361,
- 156, 816 - 871

sulfate) (see Sodium
248,258,268,279,290,291,293,304,307, 3iO. 313, 890 Methyl isopropyl ketone 789,816,832,842,851,867,868,870,887,
- 377, 381 Missile fuels - 618 Mixed acid - 83, 150, 151, 222, 393, 397, 398,
421, 432, 775,781,846 436, 529, 622, 647, 655, 732,760,
- 156, 230, 279, 361, 691,
816,832,842,870
Corrosive Material
Index
947
Mobil
oils and fluids - 279, 286,
300,
355, 363,
Naphthalene 115, 133, 307,
- 11, 29, 49, 53, 57, 63, 66, 83, 209, 150, 153, 154, 230, 248, 315, 530, 832, - 692 acid 156, 363, 622, 842, 157, 164, 371, 646, 172, 258, 268, 279, 300, 372, 377, 661, 663, 887,
816,871 Molasses (see Foods) Molten glass
177, 201, 219, 304,
- 728
acids and oxides disulfide
309, 312, 398, 436, 789, 817, chloride
Molybdenum Molybdenum Molybdic Molysite acid
- 402, 409
779,855
381, 393, 692, 760, 890 Naphthalene Naphthalene,
- 49, 164, 622
851, 871,
- 381, 691,692,
(almond)
(see Ferric chloride)
- 133 Monel and Ni cleaning baths - 201

Mondludropar Monochloroacetic Monochloroacetone Monochlorobenzene Monoethanolamine Monomeric Monosodium glutamate) Monosodium methyl Mopar Monsels salt Morea premic Morpholine Morpholine Morpholine Morrhua Mortar Motor oil Mononitrotoluene acid (see Chloracetic (see Chloroacetone) (see Chlorobenzene) (see Ethanolamine) acid)
sulfonated
Naphthalenesulfonic Naphthalenesulfonic Naphthanates Naphthenic Naphthols acid
- 402,409 - 402, 409, 692

acid manganese
acid, with sulfuric
of lead, cobalt,
- 661 - 530
- 201, 363, 393, 436, 530, 531,
622,692,760,832,855
plasticizers glutamate methyl
- 62 - 363
(MSG) (see Sodium (see Sodium
- 157
acid
and dinitrotoluene
Naphtholsulfonic Naphthoquinone Naphthylamine Naphthylbenzene Natural Vegetable oils)
- 402, 409
acid
- 201
sulfonic
- 201
arsenate
- 832 - 304, 307, 310, 313, 316
arsenate)
fats and oils (see also Edible fats and oils; gas (see Gas, natural)
- 832 - 363
234,
brake fluid
Natural Navee Neodol Neon
- 832 - 43, 83, 109, 148, 201,219,

reaction mixture - 692
Naval stores
- 622 - 21, 133, 363, 832, 871
- 832
oil - 201
240,248,258,788,871 sulfate - 692
Neatsfoot
- 363,789
- 832 - 234
oils) - 1, 2, 5, 156, 164,201, 279, 280, 313, 316,
- 622
oil (see also Oils, lubricating 119, 121, 301, 133, 144, 305,
Moth flakes
glycol - 201 - 622 Neutral oil - 156, 817 Neville acid - 363, 855 Neopentyl Neoprene Nickel Nickel Nickel Nickel Nickel, Nickel 219, - 790 acetate - 29, 57, 268, 279, ammonium anolyte bright chloride sulfate 363, 367, 396,
13, 21, 22, 26, 29, 49, 52, 57, 83, 96, 97, 98, 107, 111, 233, 285, 234, 235, 291, 293, 241, 248, 268, 274, 307,310,
788,817,832,871,884
- 222, 531, 661, 775
358,383,812,817,862,871,875,879
liquor
- 201
- 156, 817 - 104 Mulsoline 6000 - 201 Multicircuit etch - 842, 871
Mould oil Mouthwash Muriatic 245, 855 Mustard Mustard Mustard Myristic NPN Nak (see Foods) gas oil acid ,(see also Hydrochloric 279, 377, 381, 388, 779, acid) - 150, 787, 817,832,
- 201
- 29, 33, 34, 38, 49, 57, 60, 67, 83, 151, 154, 156, 164, 172, 201, 363, 373, 393, 394, 632, 647, 788, 883,887, 245, 258, 385, 388, 751, 817, extraction 760. 268, 279, 390, 392, 531, 871, 768, 133, 381, 738,
113, 115, 374, 395, 377, 397,
222, 237,
398, 402,
409, 436, 832, 842,
691, 735, 799,803,807, 890 Nickel-cobalt (see s-Tetrabromoethane) Nickel Nickel Nickel
775, 778,
- 363 - 622
liquid
- 201
Muthmans
compounds electrolyte nitrate 268, 393,
- 622
acid - 49, 164, 201, 832
- 201 - 30, 33, 49, 57, 83, 113, 115, 119,

164, 373, 172,202, 374, 377, 219,237, 381, 385, 245, 388, 760,
- 833 - 728
- 1, 15, 24, 29, 33, 38, 43, 49, 53, 57, 109, 164, 113, 115, 133, 150, 154, 155, 393, 622, 632, 663, 826, 832, 169, 172, 201, 397,398, 529, 219, 230, 530, 248,258,
134, 154, 258, 390, Nickel Nickel 135, 279,
156, 279, 397,
Naphtha 66,83, 156, 268,
398, 437,
661, 691, 738,
768,778,788,817,832,871 plating, 150, electrorefining 153, 154, 156, plating solution 368, 531,
279,284,286,300,363,371,372, 789, 799, 803,807,817,
- 202 - 30, 38, 49, 58, 86, 115,

164, 202, 259, 269, 843, 859,
394, 395, 692, 728,
692, 726, 817, 834,
842,851,871,883,887,890
871,884,885,891
942
Nickel salts - 134, 150, 156, 279, 363, 646, 732, 817,832,851 Nickel soap catalyst - 202 Nickel sulfate - 30, 33, 34, 38, 50, 57, 60, 63, 84, 106, 113, 115, 119, 134, 151, 154, 156, 164, 172, 202, 219, 237, 245, 258, 268, 303, 306, 308, 311, 314, 363, 373, 374, 377, 381, 384, 385, 388, 390, 392, 393, 394, 395, 397, 398, 402, 409, 437, 531, 632, 661, 692, 728, 760, 768, 778, 783, 788, 799, 803, 807, 817, 832, 842,847,872,883,887,890 Nicotine - 30, 57, 67, 115, 150, 154, 219, 268, 279,531,851 Nicotine bentonite - 156,832 Nicotine salts - 156, 817 Nicotine sulfate - 156, 622, 663, 783, 832 Nicotinic acid - 30, 57, 113, 115, 150, 154, 258, 268,531,851 Niter cake (see Sodium bisulfate) Niter cake solution - 726 Nitrana - 156 Nitrates - 663 Nitrating acid (see also Mixed acid) - 788, 799, 803, 807,883 Nitrating acid, spent - 202 Nitration benzol (benzene) - 156 Nitric acid - 2, 4, 6, 9, 10, 17, 26, 30, 33, 34, 35, 38, 43, 50, 53, 57, 60, 61, 62, 63, 66, 67, 84, 95, 102, 104, 106, 107, 108, 109, 111, 112, 113, 115,117,119,121,134,144,147,150,151, 152, 154, 155, 156, 157, 165, 169, 172, 177, 202, 219, 222, 223, 224, 225, 237, 239, 240, 245, 248, 258,268, 279,286, 291, 293, 294, 296, 300, 302, 305, 308, 311, 314, 363, 367, 369, 371, 373,374, 377, 381, 382, 383, 384, 385, 387, 388, 390, 392, 393, 394, 395, 396, 397, 398, 402, 410,412, 413,414, 415, 416, 425, 428, 432, 437, 442, 531, 532, 533, 622, 632, 639, 641, 642, 643, 644, 645, 646, 647, 652, 655, 661, 663, 664, 692, 693, 728, 730, 731, 732, 733,735, 738, 740, 751,756,760, 772, 775, 779, 781, 783,788, 791, 792, 794, 799,803,807,8 17,832,842,847,851,855, 883,884,887,890,891 Nitric acid, boiling - 413, 419, 420, 423, 425, 426, 428, 442, 444,445, 644, 645, 647, 666, 692, 693, 723, 738, 740, 741, 751, 756, 779, 855 Nitric acid-chromium trioxide - 738 Nitric acid-ferric chloride - 733, 738, 752 Nitric acid fumes - 50, 165, 741 Nitric acid, fuming - 84, 119, 129, 134, 202, 219, 258,286, 300, 363,437, 532,732, 733, 738, 760,768,779,783,817,832,842,855 Nitric acid mixtures - 152, 202, 219, 222, 384, 415, 423, 428, 437, 533, 534,535, 536, 537, 693,733,738,752,760,768,775
Nitric acid mixtures with hydrochloric acid - 533, 534, 644,833 Nitric acid-potassium dichromate - 738 Nitric acid-sodium chlorate - 738 Nitric acid-sodium nitrate - 738 Nitric acid-sulfuric acid mixtures (see Mixed acid) 693,781 Nitric acid-zirconyl nitrate - 738 Nitric acid with chloride, fluoride - 418 Nitric oxide - 202, 377, 381, 732, 789 Nitriding gases - 437, 693, 760 Nitrilotriacetic acid - 177 Nitro alcohols - 63 Nitrobenzene - 13, 20, 30, 34, 43, 50, 57, 63, 84, 106, 115, 119, 134, 150, 153, 154, 156, 157, 158, 165, 172, 177, 202,219, 222, 229, 237, 241,245,248, 258,268,279,286, 300, 304, 307, 310, 313, 315, 363, 377, 381, 385, 390, 393, 398, 402, 410, 622, 661, 693, 760, 775, 789, 799, 803, 807, 817, 832, 842, 851, 872, 883,887,890 2-Nitrobutanol - 157, 622 Nitrocalcite (see Calcium nitrate) Nitrocellulose - 661, 783 Nitrocellulose lacquer - 106, 622 Nitrochlorobenzene (see Chloronitrobenzene) Nitro compounds - 42, 43 Nitroethane - 279, 363, 622, 817, 832,872 2-Nitro-2-ethyl-1,3-propanediol - 622 Nitrogen - 84, 156, 202, 248, 258, 279, 363, 537, 622, 632, 646, 652, 731, 732, 789, 817, 832, 872 Nitrogen dioxide - 258, 402, 410, 832 Nitrogen, liquid - 202 Nitrogen oxide - 67, 134, 154, 219, 279, 402, 410 Nitrogen peroxide - 832 Nitrogen solutions (fertilizer) - 172, 796, 832 Nitrogen tetroxide - 157, 363, 402, 410, 623, 783, 817,832 Nitroglycerine - 144, 234, 258, 268, 393, 402, 410, 437,623,661,663,760 Nitroglycol - 268 Nitromethane - 84, 157, 203, 219, 234, 241, 248, 258,279,363,623,817,833,872 2-Nitro-2-methylpropanol - 157 hlitrooctane - 156 Nitroparaffin - 623 Nitrophenol - 177, 203, 393, 402, 410, 623, 661 Nitropropane - 30, 156, 279, 363, 377, 381, 623, 817,833,842,872 Nitrosyl chloride - 156, 393, 398, 661, 693, 732, 817 Nitrosylsulfuric acid - 377, 381, 661 m-Nitrotoluene - 234, 403, 410 Nitrotoluenes - 623, 661 p-Nitrotoluenesulfonic acid - 203
Corrosive
Material
Index
943
Nitrous 268, 760, 883 Nitrous
acid 279,
- 57, 67, 84, 134, 156, 203, 219, 258,

393, 397, 788, 398, 437, 661, 732, 735, 855, 794, 799, 803, 807,
Octyl n-Octvl Octyl
aldehyde chloride
- 156
- 177
779, 783, gases
cresol - 115
- 663 Nitrous oxide - 30, 53, 57, 84, 150, 151, 234, 258,
268,402,410,437,623,693,760,778,789 Nitroxanthic Nonanedioic Nonautomotive Nonyl alcohol Nonylisophenyl Nonylphenol Nonylphenol, salt acid (see Picric acid) acid
- 235 - 843, 873 Oil of bitter almonds - 833

Oil, 3-in-One Oil of birchwood Oil of mirbane Oil of vitriol oils; Motor 276, 277, 301, 304, 364, 365, (see Nitrobenzene) acid) oils; Essential 261, 275, 284, 285, 361, 363, 815, 818, 864, 865, oils) - 13, 14, 21, 67, 283, 360, 862, (see Sulfuric
- 203 - 13, 14, 21
Oils (see also Crude oil; Lubricating oils; Synthetic 279, 307, 366, 827, 280, 102, 106, 112,
greases and oils
- 145, 226 sulfide - 256 - 203,693

ethoxylated
139, 156, 210, 235, 281, 282, 316, 843, 310, 313, 367, 537, 833, 842, oils) 284, 301, 361,817
- 203
sulfate, sodium
538, 813,
Nonylphenoxytriethoxyethanol
819, 820, Oils, ASTM
- 203
saltpeter) (see Calcium
867,868,872,873,875,876,878,879,880 (see ASTM Oils, SAE - 156, 279,
Norge niter (Norwegian nitrate) Northia Norway Novocain Nuclear Nuclear Nuclear No. 4
- 872
(see Ammonium nitrate)
Oils, saponifiable Oils and fats 154, 157, 258,
- 377, 381
304, 307, 310, 313, 316, 403,
dl-Norvaline
- 258
- 30, 32, 53, 57, 112, 115, 150, 151,
saltpeter
- 231
fuel recovery swimming and waste - 729 tubing - 729 liner steam generator
410,617,852,887,890 Oils of vegetables and spices Oil-water emulsion - 693
- 63
pool reactor
- 203
Ointments Oleates Olefin
- 203, 729 Nujol (see Mineral oil) - 234

Nuclear waste Nutmeg Nylon oil (see Essential oils) Nut oil, ground
- 623 - 403, 410 - 203 - 5, 6, 10, 17, 26, 30, 33, 34, 36, 50, 53,
106, 111, 117, 156, 245, 312, 410, 121, 165, 259, 134, 145, 268, 279, 370, 388, 387, 760, 818, 148, 150, 151, 219, 222, 300, 303, 393, 788, 852, 373, 374, 661, 663, 783, 281, 371, 652,
(Al) sulfonate
Oleic acid
- 203
57, 60, 63, 66, 67, 84, 95, 102, 104, 113, 115, 153, 154, 237, 239, 306, 309, 377, 381, 172, 177, 203,
- 623 Nylon salt - 788

Nyvac fluids - 279, 817 O-A-548A OPM Oakite Oakite Oakite Oakite Ocenol
314, 363, 437,
- 363 - 363 - 833 - 833
382, 383, 728, 735, 807, 817,
390, 392,
- 203
- 153, 203, 872 acid materials stripper solvent materials - 30, 150,789
398, 403, 693, 726, 799, 803,
623, 632, 833,
O-T-634b
775, 779,
843, 847,
855,883,887,890 Oleic compounds Olein Oleum acid) (see Glyceryl Oleoparathion
- 383
trioleate) acid, fuming) 151, 154, 300, 732, 279, 363, 775,
- 165, 203
- 203 - 30, 43, 50,

172,203, 377, 381, 784,788, 150, 165,
Octachlorotoluene Octadecane Octadecenoic n-Octadecyl n-Octane 833 Octanoic Octanol Octanoyl Octyl Octyl Octyl acid Octadecatrienoic
- 363, 872 - 363, 833, 872

acid (see Linolenic acid alcohol
(see also Sulfuric 259, 268,
57, 64, 119, 134, 219, 222, 393, Oleum Oleyl 398, 584,
- 833
- 157
693,731,
817,852,873,887,890 spirits - 156, 363,833 alcohol (see Ocenol)
Octafluorocyclobutane
(see also Freon) - 833 - 84, 103, 156, 219, 258, 279, 363, 817,
Olin 58981
- 203
5%
- 50, 165, 203, 225

alcohol)
Olive oil (see Foods) OMO Onion Ores solution, products
(see Octvl chloride
- 130 - 134
- 230
(see Foods) 21%
Octene - 219 acetate - 156 alcohol alcohol,
OPC 60 solution,
- 623 - 203
- 693, 732, 733 chlorides
- 103, 145, 279, 363, 789, 817, 833,

n
Ore smelting gas Organic Organic
839,848,856,872
- 177, 226
food acids
- 36
944
Corrosion
Organic Orlon Oronite
mercaptan
- 200
Organic waste
- 216
- 623 - 305, 308, 310, 313, 316, 363, 873

acid (see Boric acid)
151, 154, 156, 172,204, 280,300,363,421,623,632, 817,833,852,855

Palmitin Palm oil Paper
219, 225, 259,268, 652,728,788,
Orthoboric Orthocide Orthocryl Orthoformic
(glyceryl tripalmitate) - 833 - 145, 156, 234, 280, 539, 623, 788, 817,
- 873
yarn size acid
833,843,873
- 24, 873
acid - 693
- 623
liquor - 539, 693
- 737
fluid
Paper, acid pulping Cooking
Orthoformylbenzenesulfonic OS 45 Hydraulic OS 70
- 280, 363
Pulp stocks - 539 Spent liquor - 539,540 Paper, alkaline Cooking Pulp stocks pulping
- 363 - 203
Osmose Co. premix Oxalates
- 403,410 Oxalic acid - 2, 30, 34, 50, 53, 57, 60, 64, 66, 67,
84, 106, 109, 150, 151, 219, 222, 306, 309, 374,377, 394, 395, 437,442, 693, 726, 153, 312, 396, 538, 731, 113, 115, 154, 156, 315, 363, 119, 134, 145, 148, 177, 203, 303, 373, 393, 652, 661, 760, 807, 768, 817, 371, 165, 172, 368, 370, 388,390,392, 642, 646, 752,
- 540, 693 - 540 Spent liquor - 540, 541

liquor Paper alum (see Aluminum sulfate) - 189,206 Paper and pulp mill condensate Paper, bleach solutions Paper, groundwood Paper machine Paper, neutral Cooking Pulp stocks Paper mill liquor
225, 237, 381,382,385,
245, 259,
268, 280.
Paper and pulp mill gas, noncondensable
397, 398, 403,410,412,416, 609, 623, 788, 732, 735, 738,
- 203 - 541, 693, 694, 724 pulp stocks - 541
- 204 - 204, 206, 539, 724
775, 779, 783, Oxalic Oxalic acid, boiling
795, 799, 803,
sulfite
833,843,847,852,855,883,887,890
- 418, 419, 444,445,

acid
647, 693,
726,738,779,855 acid, with sulfuric gases
- 541 - 542 Spent liquor - 542

liquor Paper, paperboard waste Paper, parchmentizing Paper pulp, bleached Paper, sizing solution Paper stock - 694 Paper pulp slurry - 694
- 661
Oxidizing Oxidizing Oxidizing
agents - 116, 285 NaCI-HCI
- 542 - 542
Oxogluconic Oxymethylene Oxygen 381, Oxygen, Ozone 154,
- 53, 203, 693 solution - 422 acid - 623

(see Formaldehyde) 115, 268, 134, 147, 280, 663, 363, 150, 377, 219, 259, 639,
- 694
- 543
- 30, 57, 66, 67,84,

623, 632, liquid
Paper, white water Acid
154, 156, 203, 789,817,873 Oxygen-nitrogen
- 543
sulfite
646, 652,
731, 732,
Groundwood Neutral Newsprint Paperboard
- 543 - 543
- 361, 831, 873 mixtures - 203

30, 57,84, 115, 145, 234, 147, 150, 259, 268, 833, 204, 219, 623, 632,
- 543 - 544
- 20,26,
156, 157,203, 363, 539,
280, 285, 852,873
639, 817,
- 544 - 544 Paracetic acid - 30 Parachloride - 230

Soda Sulfate Paraffin1,57,60,64,84, 156, 177,234, 410, 623, 393, 403, oil 106, 652, 110, 119, 377, 134, 381, 141, 150, 392, 268, 280,
- 363 P-S-661 b - 363

P-D-680 Pacemaker 843,873 Paint and varnish remover Paint oil types (Citgo)
783, 789, 817,
- 280, 817
539, 623, 789, 817,
852,873 Paraffin Paraffin Paraffin
Paint - 15, 16, 24, 256, 280,
- 234, 789
410 (paraform)
ozone - 119 wax - 403,
- 16, 24, 25
- 156 - 280
naphtha - 291, 363,833,873
Paraformaldehyde 789,817,833,873 Paraldehyde Par-al-ketone Para oil - 119,
- 156, 280, 623,
Paint solvents Paint thinner, Paint vehicles Pale oil Palladium Palmarose
134, 623, 789
- 432, 632, 789 - 884

134, 145, 150,
- 363, 873 - 843, 873
- 843, 872
plating solution oil
- 234
G62
Paraplex Parathion
- 13, 21 Palmitic acid - 30, 53, 57, 67,84,
Para San - 156
- 204, 796
Corrosive
Material
Index
945
Parco
- 204
Perfume Perfume sulfate)
- 23
alcohol white 5DA40
- 156 Parkerizing solution - 344 Parker-O-Lube - 363,873

Paris green and lime Patent alum (see Aluminum Peanut butter Peanut oil Pear alum (see Foods)
Cadenza - 859
- 226
Permanent Peroxide Peroxide Peroxydol
- 834
peroxide) perborate)
Permanganates bleach
- 663 - 50, 165, 728 - 834
(see Hydrogen (see Sodium
- 62, 134, 135, 145, 153, 204, 228, - 833

carbonate) iso)
280,363,623,694,817,833,843,873 Pearl ash (see Potassium Pectin (see Foods) Pelargonic Pella oil acid - 370, 371, 377, 381 - 843, 872 Penetrox lubricant - 24 Penicillin - 23, 231, 623, 874 Pennyroyal oil - 13, 21 Penolalube - 874 Penola univis - 874 Pentaborane - 783 Pentachlorobenzamide - 157 Pentachlorodiphenyl - 833 Pentachlorodiphenyl ketone - 833 Pentachlorodiphenyl oxide - 833 Pentachloroethane - 177,292, 623, 661 Pentachloroethylbenzene - 833 Pentachlorophenol - 41, 42, 43, 156, 280, 623, 663,796,874 Pentachlorophenylbenzoate Pentaerythritol Pentaerythrityl Pentane
Peroxyhydrate Perphosphate Persulfate
Pear oil (see Amy1 acetate,
- 57 - 268 Persulfuric acid - 661 Pesticides - 544, 545, 612

Petrol (see also Gasoline) ether (ligroin) 115, 361, 392,
- 106, 110, 119, 834 - 53, 60, 64, 67, 85,

156, 172,204, 783, 259, 651, 735, 789, 816,
Petrolatum Petroleum 267, 106, 112, 356,
- 156, 259, 874 119, 132,
823,839,874 Petroleum Petroleum Petroleum Petroleum Petroleum Petroleum Petroleum jelly jelly,
- 145, 231, 624 carbolated - 231 liquefier - 150, 154

emulsion
oil and waxes, water oils (see Crude oil) products spirits
- 204
- 250, 843 - 834 Petroleum thinner - 834 Pharmaceuticals - 432, 545, 546, 792,884
Phenetole Phenethyl Phenol (see Ethylphenyl alcohol ether)
- 833 - 623
- 623
tetranitrate
- 624
acid) - 1, 5, 8, 13, 14, 20, 22, 26,
(carbolic
Pentamethyleneamine 363,544, Pentanedione Pentanol Pentasol Penthane
- 833
30, 33, 34, 36, 38, 43, 50, 53, 57, 60, 64, 66, 67, 73, 106, 156, 237, 280, 157, 239, 300, 109, 115, 119, 135, 150, 151, 268,274, 357, 364, 396, 397, 651, 153, 165, 241, 303, 390, 694, 787, 172, 306, 546, 177, 204, 253, 312, 394, 735, 309, 219, 222, 259, 315, 395, 761, 834, 225,
- 1, 67, 84, 103, 106, 156, 229, 280,

623,694,842,852
- 177, 285
triphosphate
245, 249, 392, 393, 728, 732,
- 103 - 833 - 234, 280, 817, 874
Pentasodium Pentene - 229
382, 388, 661, 663,
398, 437, 441, 779, 783, Phenolates
614, 624,
632, 646,
765, 775, 840, 843,
- 874 Pentylamine - 226

Peppermint Pep Set Peracetic Perchloric 109, 370, 397, Pepsin - 694 acid - 154,268, acid 115, 135, 371, 623 154, 156, 280, 393, 646, 389, 623, 165, 363, 172, 367, oil (see Essential oils)
789, 812,817,
852,854,874,887,890
- 67, 280
- 694 - 155,694,874
- 204
Phenoldicarbonate Phenol formaldehyde Phenolic resin
- 30, 33, 53, 57, 64, 67, 85, 108,

150, 151, 388, 437, 259, 268,
- 43, 204, 874 Phenolphthalein - 547, 694 Phenols - 67,204

Phenol solution 315, 364, 403, 410, 807852,883 Phenolsulfonic 403,410,661, Phenol trinitrate 2-Phenoxyethanol Phenylacetic acid acid -95, 104, 111, 117, 303, 374, 121, 135, 142, 145,204,219,234, 371, 546, 547, 259, 372, 373, 306, 377, 768, 309.312, 381, 385, 799, 803,
204, 219,
237,245, 377, 381,
394, 395, 694, 732,
398, 403, 410,
752,760,788,817,833,852,855,883 Perchloroethylene Perchloromethane Perchloryl Perchloryl fluoride fluoride (see Tetrachloroethylene) (see Carbon - 694 mixtures tetrachloride)
738, 752,
- 50, 85, 109, 165, 204, 259,
Perchloromethylmercaptan
- 768 - 738
694,788,834
- 834
(Phenyl Cellosolve)
- 226,874
Perfluoroxylene
- 157
- 547
946
Corrosion
Resistant
Materials
Handbook
Phenylacetonitrile Phenylamine Phenylarsine Phenylbenzene Phenylcarbinol Phenyl chloride
(see Benzyl
cyanide)
697, 698, 728, 752, 756, 792, 793, 760, 796, acid
729, 799,
731, 732, 779, 803, 807,
733,
735, 738, 790, 843,
(see Aniline)
768, 775,
783, 788, 817,834,
- 547
(see Diphenyl) (see Benzyl alcohol) (see 2-Phenoxyethanol) (see Chlorobenzene)
847,852,855,883,884,888,890,891 Phosphoric meta hypo - 198
Phenyl Cellosolve Phenyl compounds Phenylethane Phenylether Phenylethyl Phenylethyl Phenylethyl Phenylformic Phenylglycine, Phenylhydrazine 874 Phenylhydrazine 153, Phenylic
- 843
benzene)
(see Ethyl acetate alcohol ether
(see Diphenylether)
- 176 - 788 poly - 205, 834 super - 51, 167, 205, 213, 547, 718, 725, 837
ortho tetra - 439, Phosphoric 727, 644, 763 acid, boiling
- 663 - 63, 226

phenyl acid) 364,834, ether)
- 413, 419, 420, 421, 427,

738, 741,
(see Ethyl
428, 752
444,
645, 647, 666, 723,
acid (see Benzoic potassium - 219, 259,
salt - 259. 268,
Phosphoric Phosphoric Phosphoric 553,554, Phosphoric Phosphoric Phosphoric Phosphoric Phosphoric Phosphoric Phosphoric Phosphorous 554,661 Phosphorous Phosphor 761 Red Phosphorus,
acid fumes - 165, 696, 725 acid mist - 696 acid mixtures acid-nitric
- 204, 205, 222, 552, - 647, 738

- 696
hydrochloride
- 30, 57, 150,
647,696,725,752,768,775 acid acid pickling solution
154,259,268 acid (see Phenol)
Phenylisocyanate Phenylmethane Phenylphenol o
- 661
(see Toluene) 663
acid scrap liquor acid slurry - 697 acid-sulfuric anhydride acid I 795 acid-phosphoric
- 44, 45
acid - 697, 725 (see Phosphorus pentoxide)
- 204,259, p - 663
acid, wet process - 697, 698
sodium
salt - 259 - 694
- 42, 43, 237, 245, 386, 390,

acid - 698 642, 698, 732,
Phenylpiperazine Phenylpolysiloxane Phorone Phosgene
- 834
- 11, 18,280,364,817,834,874
suspensions
- 624
554,
- 30, 150, 151, 154, 177, 219, 259,

- 690
85, 219, 437,
268,377,381,393,400,408,661,694,789 Phosgene, chlorobenzene Phosphate Phosphate Phosphate Phosphate, Phosphate Phosphate Phosphate esters mix rock salts ester oils - 156, 280
White
- 834,874 - 204
acid waste
- 30,259,269 - 145, 234,624 Yellow - 30,57, 115, 152, 154,259

269 bromide chloride 732,
phosphoric
- 204
Phosphorus Phosphorus 661,698, Phosphorus 172, 732,738 Phosphorus
- 624
gases - 726 - 204, 383, 663, 692 acid, poly)
- 44, 393, 403, 410, 728 - 43, 377, 381, 393, 403, 410, - 34, 43, 53, 106, 135,
393, 403, 410, 554, 661,
rock acidulation - 891
733
oxychloride
Phosphatizing Phospholeum Phosphonitrilic Phosphor 720 Phosphoric 106, 109, 147, 150, 165, 237, 300, 370, 387, 442, 639, 169, 239, 301, 388,
177, 205, 259,
(see Phosphoric chloride vapors
- 204
was solution
pentachloride pentasulfide pentoxide
and yttrium
oxysulfide
Phosphorus Phosphorus
- 157, 259, 661 - 624 (anhydride) - 30, 50, 57,85,
acid - 1, 2, 9, 10, 17, 30, 33, 34, 35, 112, 151, 172, 113,115, 152, 154, 249, 308, 377, 393, 550, 644, 665, 119, 121, 135, 157, 145, 158, 225, 280,294, 364, 383, 396, 432, 647, 695, 367, 386, 397, 437, 632, 652, 696,
115, 150, 152, 154, 165, 205,219,259,698,

778,799,803,807,852,874,883 Phosphorus 883 Phosphorus Phosphorus Phosphorus 115, 150, 245, pentoxide, sesquisulfide tribromide trichloride 151, 269, acid molten - 799,803,807,
38, 43, 53, 57, 60, 61, 64, 66, 67, 85, 102, 155, 156, 259,269, 311, 381, 394, 551, 645, 666, 314, 382, 395,
177, 204,205,219,222,
240, 245, 302, 305, 374, 390, 392, 549, 643,
- 205, 624 - 661 - 30, 50, 53, 57,85,

177, 205, 390, 364, 386, 661,
106, 738,
371, 373,
154, 165,
219,237,
249, 259,
398, 403,410, 547, 548, 641, 642,
413,420,
425,427, 646, 694,
769,778,788,852,874 Phosphotungstic Photographic emulsions
552, 624,
- 554, 555 - 738, 769, 849
655, 661,
663, 664,
Corrosive
Material
Index
947
Photographic solutions, developers - 16, 24, 25, 30, 57, 85, 114, 115, 119, 127, 150, 153, 154, 191, 193, 194, 205, 210, 232, 233, 269, 275, 276, 280, 358, 555, 728, 780, 783, 813, 826, 840, 843,849,852,862,874,884 Phthalic acid - 34, 50, 64,85, 157, 165, 172, 205, 219, 222, 237, 245, 259, 280, 370, 371, 386, 388, 390, 393, 403, 410, 555, 738, 775, 783, 788 Phthalic anhydride, 85, 151, 205, 377, 381, 397, 398, 432, 437, 555, 624, 657, 661, 698, 732, 761, 783,799,803,806,874,883 Phthalic anhydride, vapors - 698 Phthalic, maleic anhydride - 437, 761 Phthaloyl chloride - 230 Pickle alum (see Aluminum sulfate) Pickles (see Foods) Pickling solution Acid - 38, 50, 53, 115, 165, 169, 301, 364, 632, 726, 729, 732, 733, 843, 852,874, 891 Alkaline - 53 Picolines - 624, 874 Picric acid - 30, 50, 58, 66, 67, 85, 113, 115, 135, 150, 154, 156, 172, 205, 219, 222, 237, 245, 259, 269, 301, 303, 306, 309, 312, 315, 364, 370, 371, 373, 374, 377, 381, 382,388, 390, 393, 410, 437, 442, 661, 726, 761, 775, 783, 788,834,843,847,852 Picric acid, alcohol solution - 165, 205, 398 Picric acid, water solution - 156, 205, 280, 303, 364,403,779,799,803,807,817,855,883 Picronitric acid (see Picric acid) Pigment slurry - 205 Pimelic ketone (see Cyclohexanone) Pine coating oil - 156 Pinene - 280, 364, 624,817,834,874 Pine needle oil - 235 Pine oil - 112, 156, 172, 235, 280, 364,789,817, 834,843,873,874 Pine tar, 156 Pine tar oil - 874 Pipe line cleaner - 843, 874 Piperazine - 624 Piperazine hydrochloride - 280, 817 Piperidine - 157, 235, 364, 834 Pipe Seal Compounds - 148 Pitch - 280 Plaster - 624 Plasticizers - 156, 256, 259, 291, 293, 624, 843, 874 Plastic01 - 843 Plating baths - 843, 884,885 Plating solutions - 30, 34, 38, 47, 48, 53, 58,85, 109, 115, 135, 150,151, 154,222,259, 269, 364, 368, 378, 382, 775,834, 843, 852,884,885
Aluminum - 182 Antimony - 698,834,843,885,891 Arsenic - 834, 843, 885 Brass - 30, 471 58, 85, 115, 135, 150, 153, 154, 160, 185, 259, 269, 368, 834, 843, 884, 885,891 Bronze - 160, 185,843,884,885,891 Cadmium - 30, 47, 58, 85, 115, 135, 150, 153, 154, 160, 186,259,269,368, 834,885,891 Chromium - 30, 58, 85, 115, 135, 153, 161, 188, 195, 254, 259, 269, 280, 357, 364, 368, 394, 395, 647, 732, 737, 750, 780, 818,834,861,884,885,891 Cobalt (nickel) - 812, 834 Copper - 30, 48, 58, 85, 115, 135, 150, 153, 154, 161, 189, 190, 259, 269, 368, 834, 843,861,884,885,891 Copper Brite - 161,859 Gold - 30,49, 58, 85, 115, 135, 150, 153, 154, 163, 195. 259, 269, 368, 834, 843, 884, 885 lndium115, 135, 150, 153, 154, 843, 884, 885 Iron - 49, 163, 198, 259, 834, 843, 884, 885 Lead - 30, 58, 85, 115, 135, 150, 153, 154, 164, 199, 259, 269, 368, 523, 698, 834, 843,884,885 Nickel - 30, 38, 49, 58, 86, 115, 135, 150, 153, 154,156, 164,202,259,269, 279, 368, 531,692,726,817,834,843,859,871, 884,885,891 Palladium - 884 Platinum - 109, 834, 884 Rhodium - 30, 58, 115, 135, 150, 153, 154, 207,259,269,884,885 Silver-30, 38, 50, 58.86, 115, 135, 150, 151, 153, 154, 166, 207, 259,269, 368,834, 843,884,885 Speculum - 259 Tin - 30, 51, 58, 86, 115, 135, 150, 153, 154, 167, 214, 259, 269, 368, 698, 834, 843, 884,885,891 Zinc - 30, 51, 58, 86, 115, 135, 150, 153, 154, 168,217,259,269,368,834,843,884, 885,891 Platinum - 790 Plus 5 - 205 Pneumatic service - 364 Polyacrylamide - 205 Polyacrylonitrile - 157 Polyamine - 698 Polycarbonate - 16, 23 Polychlorocyclohexane sulfide - 205 Polychlorophenates - 205 Polyco 2631 - 205 Polyderm moisturizer lotion - 874 Polyester resin - 280, 818
948
Corrosion
Resistant
Materials
Handbook
Polyester Polyethylene Polyethylene Polyethylene Polyethylene
white
enamel,
water - 259
reducible
- 205
Potassium 113, 172,
bromide 115, 205, 397, 735, 119, 219, 398, 738,
- 19, 30, 135, 232, 403, 761, 145, 260, 410, 769,
50, 150, 269, 437, 778,
58,
64,
86, 156, 377, 624, 803,
106, 165, 381, 661, 807,
- 624,
glycol glycol glycol
789 600E distearate monolaurate - 229 - 229
154, 280, 555, 799,
393, 699, Potassium
Polyformaldehyde Polyglycol Polymethylene Polyoxymethylene Polypropylene Polypropylene Polystyrene Polyurethane
(see Paraformaldehyde) emulsion polyphenyl in water isocyanate
874,883,888,890 carbonate 113, 205, 381, 410, 731, 803, 115, 206, 382, 437, 732, 807, 172, 377, 403, 728, 799,
- 38, 259 - 205

- 198, 205
- 30, 43, 50, 58, 60, 64, 66,

119, 219, 386, 555, 735, 818, 135, 237, 388, 556, 761, 834, 152, 245, 390, 647, 778, 843, 154, 260, 392, 652, 783, 874, 119, 377, 624, 804, 39, 106, 165, 260, 364, 393, 632, 761, 818, 156, 269, 393, 661, 788, 883, 135, 381, 661, 808, 41, 113, 172, 269, 373, 394, 646, 769, 834, 43, 115,
Polymer-toluene
86, 165, 280, 398, 699, 794,
109,
(see Paraformaldehyde)
- 624
glycols
- 663
- 624, 789 - 280, 789 Polyurethane, foam - 23, 818 Polyvinyl acetate - 153, 172, 205,
624, 783,874 acetate alcohol alcohol butyral chloride ND-2 latex - 165, emulsion resins
888,890 Potassium 219, 259, 364, 154, 393, 728, 259, 624 Potassium 44, 206 119, 206, 280, 374, 395, 652, 775, 45, chlorate 156, 397, 735, 205, 398, 761,
- 30, 58, 86, 115,

219, 403, 778, 260, 410, 783, 269, 437, 788, 19, 30, 64, 67, 155, 245, 311, 390, 556, 738, 804, 699 chloride 280, 387, 280, 556, 799, 33, 86, 156, 249, 314, 392, 624, 752, 808,
Polyvinyl Polyvinyl Polyvinyl Polyvinyl Polyvinyl Polywet Powderbase Potash Potash Potash Potash Potash Potassa Potassium 874 Potassium Potassium Potassium potassium Potassium Potassium Potassium Potassium 115, 205, 390, 888,890 Potassium Potassium Potassium Potassium Potassium Potassium Potassium Potassium 154,205,
- 50, 165, 874

170, 172, 205,
818,874,883,888,890 chloride 46, 50, 151, 222, 303, 381, 410, 699, 783, 135, 219, 295, 377, 403, 661, 778, - 1, 12, 58, 152, 232, 306, 386, 437, 732, 788, 60, 154, 237, 308, 388, 442, 735, 799,
- 33, 50 - 624 latex - 50, 165, 205,

Max Factor
- 205
cream,
- 14
(see Potassium brines mine ore
carbonate)
- 384
fumes
- 205
- 624 slurry - 205

(see Potassium acetate acid hydroxide) 280, 364, 818, 834,
843,847,874, Potassium Potassium Potassium 152, 652, Potassium Potassium - 269 Potassium 119, 237, 113, 172, 388, 874, 393, 661, Potassium 113, 172, 306, sulfate) 397, 661, 778, 303, 306, 309, 311, Potassium 154, 269, 783, 156, 788, 165, 843, chloride chloride, chromate 154, 156, 661,699, cyanate cyanide 135, 245, 394, 699, 151, 260, 395, 761,
883,888,890 brinesodium 260, 269, brine 119, 437, - 699 135, 624,
- 86, 157,
- 30, 58, 86, 115,

761,788,835,844,874
sulfate
(bisulfate) chloride sulfate
- 30 - 260
aluminum aluminum sulfate) amyl
- (see Aluminum
cuprocyanide
xanthate
- 30, 280, 364, 834, 874 - 624 - 12, 19, 30, 34, 38, 58, 86, 115,
156, 403, 788, 172, 410, 799, 177, 381, 437, 804, 206,219, 388, 632, 808, 390, 652, 818, 364,377,
antimonate 34Baume bicarbonate 119, 232, 393, 135, 237, 397, 150, 245, 661,
- 30
- 110
152, 269, 396, 778,
- 30, 50, 64, 86, 102,

152, 260, 698, 280,382,
834,844,875,883,888,890 dichromate 115, 177, 309, 398, 699, 783, 119, 206, 311, 403, 726, 799, 121, 219, 314, 410, 732,
- 30, 50, 58, 64, 86, 106,

150, 260, 364, 437, 733, 151, 269, 367, 442, 735, 154, 280, 386, 555, 738, 156, 301, 393, 624, 761. 165, 303, 396, 652, 769,
bichromate bifluoride bisulfate bisulfide bisulfite bitartrate borate bromate
(see Potassium
dichromate)
- 661
(acid
- 30, 58, 60, 177,
222,232,269,392,661,775
- 788 - 30, 280, - 624 - 30, 113, - 30, 106,
804,808,818,834, sulfuric - 269, 135, 237, 403, 136, 245, 410, acid 738 50, 145, 260, 437,
844,847,
874,875,883,888,890 dichromate, ethyl 115, 206, 390, xanthate 119, 232, 393, ferricyanide 172, 388,
314,661,699 115, 113, 135, 115, 150, 135, 154, 150,
- 135, 726
58, 269, 661, 64, 156, 377, 699,
Potassium Potassium 86, 165, 381, 735, 113,
- 19, 30,44,
156,260,269 232,260,269,280
154,
738,761,769,778,783,875
Corrosive
Material
Index
949
Potassium ferrocyanide - 50, 58, 64, 86, 115, 135, 136, 154, 165, 172, 206, 219, 237,245, 260, 269, 280, 388, 390, 397, 398, 403, 410, 437, 699, 735, 761,778, 783,799,804,808,883 Potassium fluoride - 30, 34, 38, 1 15, 119, 154, 206,260,269,280,393,661,663,756 Potassium fluoride, with HP - 286 Potassium hydrate (see Potassium hydroxide) Potassium hydroxide - 1, 2, 28, 30, 34, 38, 44, 50, 53, 55, 58, 60, 64, 66, 67, 74, 82, 86, 106, 109, 113, 115, 119, 136, 145, 147, 149, 150, 151, 154, 156, 157, 165, 169, 172, 206, 219, 222, 226, 237, 245, 249, 254, 260, 265, 269, 275, 280, 294, 301, 302, 305, 308, 311, 314, 364, 367, 370, 372, 373, 374, 377, 381, 382, 383, 386, 388, 390, 392, 393, 394, 395, 396, 398, 403, 410, 437, 555, 556, 624, 632, 646, 647, 652, 661, 663, 699, 700, 726, 728, 731, 732, 733, 735, 739, 752, 761, 769, 775, 778, 783, 788, 790, 791, 792, 794, 799, 804, 808, 812, 818,834,844,852,875,883,884,888,890 Potassium hydroxide, boiling - 419, 647, 699, 739,752,756,769, 778 Potassium hydroxide mixture - 752 Potassium hydroxide, molten - 731 Potassium hypochlorite - 30, 86, 156, 260, 269, 661, 699, 778,875 Potassium iodate - 661 Potassium iodide - 12, 58, 60, 136, 145, 222, 232, 269, 280, 392, 624, 661, 700, 735, 739, 752, 769,775,778,788,875 Potassium iodide-iodine (see Iodine, KI solution) Potassium metabisulfite - 661 Potassium, molten - 642, 646, 728, 732 Potassium muriate (chloride) - 834 Potassium nitrate - 30, 34, 50, 58, 64, 66, 86, 106, 113, 115, 119, 136, 147, 152, 154, 156, 165, 172, 206, 219, 222, 237, 245, 260, 269, 280, 364, 373, 374, 377, 381, 386, 388, 390, 393, 396, 403, 410, 437, 624, 657, 661, 700, 735, 761, 769, 775, 778, 783, 799, 804, 808, 818, 834,875,883,888,890 Potassium nitrite - 663, 752 Potassium oxalate - 87, 156, 206, 393, 403, 410, 437, 735, 761,778,784,875 Potassium oxide - 835 Potassium perborate - 30, 115, 119, 136, 154, 260,269 Potassium perchlorate - 58, 106, 113, 115, 119, 136, 152, 154,260,269,557, 700,739 Potassium perchlorite - 30 Potassium perfluoroacetate - 875 Potassium permanganate - 12, 38, 44, 50, 58, 64, 66, 87, 106, 113, 115, 119, 136, 145, 150, 151, 152, 154, 156, 157, 165, 172, 177, 206, 219, 232, 240, 249, 260, 269, 280, 303, 306, 308,
311, 314, 317, 318, 319, 320, 321, 322, 323, 324, 325, 326, 327, 328, 329, 330, 331, 332, 333, 334, 335, 336, 377, 381, 392, 397, 398, 403, 410, 438, 442, 609, 625, 661, 663, 700, 726, 735, 739, 761, 769, 778, 788, 799, 804, 808,818,835,844,875,883,888,890 Potassium permanganate-sodium chloride - 414, 417 Potassium peroxide - 44, 206, 377, 381, 393, 403, 410,438,661, 761 Potassium persulfate - 30, 50, 58, 106, 115, 136, 165, 172, 206, 260, 269, 280, 377, 381, 403, 410,557,625,661,700 Potassium phosphate - 172, 280, 647, 788, 844, 875 Potassium pyrophosphate - 44, 45, 108, 206, 214 Potassium pyrosulfate - 625 Potassium pyrosulfate, molten - 731, 732 Potassium ricinoleate - 206 Potassium salts - 150, 364, 367, 852 Potassium silicate - 875 Potassium silicide - 87 Potassium sulfate - 12, 19, 30, 34, 38, 50, 58, 60, 64,66,67,87, 106, 113, 115, 119, 136, 152, 154, 155, 156, 165, 206, 219, 222, 232, 237, 245, 260, 269, 280, 364, 373, 374, 377, 381, 388, 390, 392, 393, 397, 403, 410, 438, 625, 632, 646, 652, 661, 700, 735, 739, 761, 769, 775, 778, 784, 788, 799,804, 808, 818, 835, 844,875,883,888,890 Potassium sulfide - 30, 64, 87, 115, 119, 136, 219, 232, 260, 377, 381, 393, 735, 778, 799, 804, 808,875,883 Potassium sulfite - 87, 113, 115, 119, 136, 156, 281,364, 661,700,818,835,875 Potassium tartrate - 625 Potassium thiocyanate - 609, 625 Potassium thiosulfate - 281, 739, 769 Potato oil - 835 Powerlube - 281,818 Powerplant scrubber - 206 Prague pickling solution - 698 Premium oils - 284 Prestone - 156, 291, 305, 308, 311, 313, 316, 364,789,858,875 Primatol A,S,P - 281,818 PRL high temperature hydraulic oil - 364 Probinsaure - 791 Producer gas - 156, 364, 835,875 Propadrine - 235 Propane - 11, 18, 26, 30, 38, 58, 66, 67,81, 87, 136, 150, 154, 156, 172, 219, 229, 260,269, 281, 364, 442, 625, 632, 652, 789, 818,835, 852,875 Propane, liquid - 156, 229 Propanol (see Propyl alcohol)
950
Corrosion
Resistant
Materials
Handbook
Propanone Propargyl Propellor Propene Propenenitrile Propiolactone Propionic 206, 739, Propionic Propionic
(see Acetone) alcohol oil
Pyranal 115, 150, 154, 263 Pyranol Pyrene Pyrethrum Pyrethrum Pyridine 109, 136, 559, 156, 625, 165, 661, 177, 700, 148, 245, 377, 403, Pyridine Pyridine 625, Pyroacetic Pyrogallic
(transformer - 156, 364 (see Carbon
oil)
- 281,
364
- 30, 106,
- 156
(see Acrylonitrile)
tetrachloride) 281 119, 240, 372, 395, 700, 136,
(see Propylene)
- 67, 235, oil - 260

156, 249, 381, 410, bases sulfate ether acid 438, 661, 157, 260, 386, 438, 165, 269, 388, 560,
acid
- 558 - 50, 106,
- 44, 50, 58, 60, 64, 66, 87, 106,

177, 281, 390, 625, 206, 301, 392, 646, 219, 364, 393, 661, 237, 371, 394, 663,
225,281,438,558, 761,769,783,788,818,844,855 aldehyde anhydride
- 625, 875 - 103, 559, 625 Propionyl chloride - 206 Proprietary compounds - 700 Propyl acetate - 18, 87, 156, 281, 364,497,
736,783,818,835,842,875 n-Propylacetone Propyl 150, 364, 818, 890 Propylene Propylene Propylene Propylene Propylene 154, Propylene 113, 297, Propylene Propylene 560,663 Propylformic Propyl Protargol Protein Prune Prussic Pulp, Protochloride processing acid bleached nitrate acid (propene) chloride dibromide dichloride 156,230,260,269, glycol 115, 145, 559560,625, glycol oxide - 10, 163, 17, 32, 165, chlorohydrin alcohol 151, 370, 835, 154, 372, 839,
761,788,818,835,844,852,875
Pyridinesulfonic
- 560, 646 - 60, 222, 392, acid - 661

(see Acetone)
560,
661,
775
- 875
- 10, 17, 30, 219, 625, 848, 54, 226, 663, 852, 87, 106, 110, 263, 735, 875, 115, 281, 789, 888, 835, 875 150, 50, 151, 87, 281, 875 156, 387, 842, 260, 700, 856,
- 10, 17, 58, 87, 145,

701, 663, 364, 726, 735, 739,
156, 761, 883
225, 779,
269, Pyrogallol Pyrogard
784,788,852,856 - 219, 799,804,808, 818 vinegar)
- 281,
Pyroligneous
acid 726,
(wood
- 87, 156,
364,
- 87, 364,789,
- 11, 18
818, 260,
438,561, Pyrolube Pyromucic Pyronal Pyrrole Quaternary 844 Quaternary Quebracho
761,835,856 (see Furfural) oil)
- 364,875
aldehyde (transformer
- 87, 249, - 260 - 30, 115,

136, 34, 172, - 293 235,
- 281,
818
145, 49, 229,
- 364,
835 salts
393,789,875 38, 206, ammonium softener extract
- 44, 172,
206,
561,
663,844,875 ricinoleate
- 206 - 561, 625
- 58, 87, 219, - 835 - 364, 835, - 700

water
260,
269,
364,
Quinine 844, 875
- 235
hydrolysate
oil - 156 - 16, 23, 231, 661 Quinine bisulfate - 87, 661, 778, 875 Quinine sulfate - 87, 156, 778, 875 Quinine tartrate - 661 Quinizarin - 661 Quinol (see Hydroquinone)
Quenching
- 835 - 560
acid) (see Hydrocyanic 869
Quinoline Quinoline Quinone Quintolubric R-2 RJ-1 RJ-4 RP-1
- 561,
sulfate
625,
661 381
- 377, - 818
- 206 Pulp mill liquors - 383,

Pulp, Pulp, Pulp, Pulp, Pulp, Pulp Pulp Purina Purina Puropale Purple Pydraul 156, Pydroil paper paper paper paper paper stock stock, woody oils salt 281, mill mill bleach digester
- 661
822
- 206, 415 - 206 mill effluent - 50, 165 mill recovery boiler - 206 mill waste, acidic - 206 - 206,875
chlorinated
solutions
- 206
- 364
Fuel
- 207 - 285,
364
- 364
solutions hoods, (agricultural oils oil
Radiation
- 206
818 spray 818 permanganate) fluid 308, and oil) 310,
Radioactive Radiochemical Ramrod Rando Range
- 884
glove spray) boxes
insecticide plant
- 281,
- 207
818
- 156
- 281,
- 281,
(see Potassium Hydraulic 301, 305, 291,
(see also
- 66, 87,
316,
Rapeseed 873,876 Rare Rare earth earth
- 281,818 - 156 oil - 106, 281,

chloride sulfates
364,
818,
835,
843,
844,
313,
364,818,844,875
- 38
- 561 - 561
Corrosive
Material
Index
951
Raspberry Raylene Rayon Rayon 852 Rayon Rayon Rayon Rayon Rayon Recovery Red Red Red Red line
juice
- 625 - 701
bath bath
SCC SD-20 SFR
7204
- 281,818 - 281,818 - 210

- 293, 365 381, 662, 788 solution) sugar fuel solution solution solution 215 oil
- 207
bleach coagulating hardening industry
- 207
Fluid SR-10 oil treatment
- 30, 115, - 562
150,
154,
726,
SP-181 SR-6, Saccharin,
- 377, - 835
- 625, 701 sizing bath - 562 spin bath - 34, 165,

spin gage oil 100 liquor, bath, fumes gases
Saccharose Saccharum 178,207,562, 563, Sachet Safetytex Safflower Salad Salad oil
(see Sucrose,
powder
657,701,784 boiler oil pulp
- 26 - 28,818 - 136 - 876

382, 788 chloride) (see Ammonium
- 207 - 207
dressing
- 876 - 364
mill
- 106,
Sal ammoniac Sal chalybis 364, 381, Salicic Salicylic 225, 382, 662, chlorine 728
oil (see Oleic 818,835,843,844,873 gases
- 44, 207 acid) - 225, 281,
- 835 acid - 30
acid 237, 386, 701, acid,
Salicylaldehyde
Reducing Reformer Refrigerants Regal Resins Resin Resins, oils Rendering
- 53 charge - 207
- 219
- 58, 88, 219,226, 260, 269, - 50, 58, 64, 87, 145, 166, 207,
245, 388, 735, 260,269,281, 390, 739, 392, 761, 403, 779, 364, 410, 788, 377,381, 438, 818,
625 219, 625, 835,
- 281,
fumes, 564,
818 ozone, 701, 876 - 153 145, 177, 235, 303,
- 207
856 Salicylic Sal soda Salt Salt Salts 135, Salt Sand cake sodium salt - 739 carbonate) sulfate) nitrate) 303,421, carbonate) 648, 664, (see Sodium (see Sodium
- 563,
solvent wet
- 844,
strength
Resorcinol Resorcinol Rhodium 150, Rice Rice barn
- 64, 87, 119,

formaldehyde plating solution
of Lemery
- 835
302,
306,309,312,315,789
Saltpeter
(see Potassium
- 625 - 30, 58, 115,
- 53,231,232,
of tartar
665,735,788 (see Potassium
153,154,207,259,269,884,885 oil
- 625 - 136 - 207 1850 - 207 acid - 625

CDA oil) 237, 245, 381, 390 chloride)
Richamide R ichonate Ricinoleic Ricinus Rochelle Rock Rock salt wool
- 207 - 207 Sand acid - 835

Slurry Sandalwood Sani-Fresh Sanitizers Santosafe Saponified Sassafras Sauerkraut Scale 564, 625, 652, retarder Scrubbed Scrubber Coal - 156 Sludge oil soap
Dry
- 234
solution 818 oils)
oil (see Castor salts
- 207
- 150,
(see Sodium slurry
- 207 Roofing membrane - 250 Rose geranium oil - 234 Rose oil - 843,844, 873,876 Rosia oil - 156 Rosin - 87, 136, 156, 281,438,
701,728,761,876 Rosin oil
- 876 - 281,364, oil - 228

(see Foods) fluegases
oil (see Essential
- 16, 25 - 701,
705,
706
- 701
and water resinoid oil
Rotenone Rotenone Royal Rubber Rubber Rubber Rubidium
- 207 - 207 Synthetic - 666

effluent gas environment environment, for fly water liquors shrimp
- 235 - 843,
872 701 679 564,565,625,663,
Scrubber Scrubber Scrubber Scrubber Scrubber Scrubbing Seafood, Seasalt Seawater
Triton cement
- 701 - 701
sulfur dioxide
- 145,235,
coagulating
- 722
- 663
bath
ash - 719
- 565,
- 701 Rubilene oils - 281, 818 Rust inhibitors - 844, 876

Rykon 2EP - 102
- 706 - 701,
702,
703,
704,
705,
706
(see Foods) chloride) sea)
(see Sodium (see Water,
952
Corrosion
Resistant
Materials
Handbook
Sebacic acid Secondary Seed oil
discharge effluent
- 50, 166, 706, 739 - 706
367, 438,
382, 386, 442, 646, 769,
388, 390, 778, 784,
393, 788,
397, 398, 410, 728, 735, 739, 799, 804, 808, silver)
662, 707, 726,
- 835 Selenic acid - 30, 115, 260, 269, 852 Selenious acid - 50, 166, 207, 784
Selenious Selenium Selenium Selenium Separen acid with sulfuric, nitric acids
752, 761,
818,835,844,847,876,883 Silver plating solution (see Plating solutions,
- 662
Silver refining Silver refining
- 707
cells
- 566
chloride, NP-10 mono
- 207
707, 852, 876
- 232
Silver salts - 150, 156, 652, Silver sulfate
compounds
- 403, 410
Septic system Sequestering dl-Serine
- 835 - 207
agents - 207 - 260 Sesame oil - 228, 260, 843, 844, 873, 876 Sevin - 281,818 Sewerage, 384, 876 150, 154, 156, 183, 207, 281, 364, 835, 566, 625, 652, 706, 726, 780, 818,
- 58, 154, 269 Sinclair Opaline Lube - 364 Sizing starch - 876 Skelly solvent - 235, 364, 876
Skydrol 293, Skylube Slaked Slimetrol (see Hydraulic 301, 450 305, fluid and oil) 287, 288, 313, 316,
- 88, 107, 110,

289, 291, 317-336,
156, 196, 207, 337-354,364,
281, 286, 308, 310,
37 1,818,835,841,876 hydroxide)
- 301
lime (see Calcium
Sewerage gas Sewerage, Shampoo Shellac
- 706
fluegas
Sewerage sludge incinerator treatment
- 706
- 207
Shave cream Shellac,
- 207,232,235 - 14, 626,876
- 88, 136, 156, 281, 626, 632, 728, 876 orange - 844 Shell oil and fluids - 156, 364, 843, 873 Shoe polish - 15, 105, 137, 235, 626
Shortening Silica (see Foods)
- 44 Slimicide - 44, 207 Sludge acid - 726, 844 Slurry - 707 Clay - 207 Coal - 207 Rockwool - 207 Sand - 207
Smelting Smoke, furnace particulate gas and dust
- 207
Smokehouse Soap Ivory Lava
residues
- 382
. 566 - 706
- 208
Silica, acidified Silica gel Silicate 852 Silicofluoric Silicon Silicone Silicone - 790 esters
- 137, 156, 844, 876 - 364, 835, 844, 876 Silicicacid - 58, 113, 115, 150, 154, 269, 646,
acid (see Fluosilicic acid)
- 234 - 22 - 22 - 7, 26, 30, 50, 52, 58, 64,

115, 364, 117, 119, 239, 368, 780, 130, 137, 260, 270, 566, 166, 208, 104, 106, 157, 301,
Lighthouse 66,88,95, 150, 278,
Soap and soap solution 154, 156, 281, 296, 632,
- 301 - 64, 284 Silicone grease - 22, 281, 301, 364, 818, 835 Silicone L-45 - 844, 876 Silicone oil - 2, 21, 58, 88, 102, 106, 119, 137,
brake fluid fluids 156, 207, 876 Silicone X-527 269, 281, 364, 818, 835, 843, 873,
396, 432,
567, 626, Soap, boiling Soap curd Soap fat Soap oil
652, 743,
788, 816, 818,
835,844,852,876,888,890
- 101
serum
Soap coagulating
- 707
- 62
- 137
- 707 - 156,818 - 208 - 106 - 364, 876, 877

sulfate) nitrate) carbonate) sodium
- 844, 876 Silicon tetrachloride - 44, 403, 410, 706, 876 Silicon tetrafluoride - 706, 707 Silicon tetraiodide - 566, 707 Silver bromide - 88, 707, 778, 876 Silver chloride - 88, 707, 728, 735, 778, 876 Silver citrate - 728 Silver compounds - 626 Silver cyanide - 30, 58, 88, 151, 207, 219, 260,
269,281,735,778,876 Silver fines Silver nitrate 115, 207, 219,
Soapless detergent Soap plant fumes Soap, washing Socony
oils, fluids and grease
Soda ash (see Sodium Sodan - 156
Soda alum (see Aluminum Soda niter (soda saltpeter) Soda water Sodium Metal Molten (see Water,
(see Sodium
carbonated)
- 707 - 12, 19, 30, 50, 58, 64, 88, 106,

151, 152, 237, 245, 154, 156, 260, 269, 166, 281, 172, 364, 232,
137, 145,
- 234, 626, 728, 739 - 642, 646, 728, 732, 739, 799, 804,
808,883
Corrosive
Material
Index
953
Sodium acetate - 19, 30, 36, 50, 58, 64, 88, 115, 119, 137, 145, 150, 153, 154, 155, 156, 166, 172, 208, 219, 232, 237, 245, 260, 270, 281, 365, 377, 381, 388, 390, 393, 397. 398, 403, 410, 438, 567, 609, 626, 662, 707, 735, 739, 761, 769, 778, 799, 804, 808, 819, 835, 877, 883,888,890 Sodium acid fluoride (see Sodium bifluoride) Sodium acid methanearsenate - 832 Sodium acid phosphate - 31, 58, 138, 209, 270 Sodium acid sulfate (see Sodium bisulfate) Sodium alkylaryl sulfonates - 166, 208 Sodium alkyl xanthate - 208 Sodium aluminate - 88, 166, 208, 626, 662, 707, 739,769, 788,877 Sodium aluminosilicate - 835 Sodium aluminum fluoride - 609, 835 Sodium aluminum sulfate - 19, 58, 88, 154, 438, 727, 761,835 Sodium ammonium phosphate - 208 Sodium antimonate - 30 Sodium arsenate - 626 Sodium arsenite - 30, 626, 796, 844, 877 Sodium benzenesulfonate - 626 Sodium benzoate - 30, 50, 58, 64, 88, 115, 137, 145, 154, 166, 172, 208, 219, 232, 260, 270, 281, 370, 626,735,778,877 Sodium bicarbonate - 1, 12, 19, 30, 34, 50, 58, 60, 64, 67, 88, 106, 109, 113, 115, 119, 137, 145, 152, 154, 156, 166, 172, 208, 219, 222, 232, 237, 240, 245, 249, 260, 270, 281, 303, 306, 309, 311, 314, 365, 370, 372, 373, 374, 377, 381, 382, 388, 390, 392, 393, 394, 395, 396, 398, 403, 410, 438, 567, 568, 609, 632, 652, 662, 707, 735, 761, 776, 778, 784, 788, 799, 804, 808, 819, 823, 836, 844, 877, 883, 888, 890 Sodium bichromate (see Sodium dichromate) Sodium bifluoride - 50, 166, 572, 662, 707, 726, 739 Sodium bisulfate - 19, 30, 34, 50, 58, 60, 64, 88, 106, 115, 137, 154, 156, 166, 172, 177, 208, 219, 222, 260, 270, 279, 281, 363, 370, 372, 392, 393, 396, 397, 398, 403, 410, 412, 438, 442, 576, 626, 632, 647, 652, 662, 707, 727, 732, 735, 739, 752, 762, 769, 778, 788, 799, 804, 808, 819, 836, 844, 872, 877,883, 888, 890 Sodium bisulfate, boiling - 419, 769 Sodium bisulfate, molten - 732 Sodium bisulfide - 208 Sodium bisulfite - 12, 19, 30, 39, 41, 42, 44, 45, 50, 58, 64, 67, 88, 106, 115, 119, 137, 145, 152, 154, 155, 166, 173, 177, 208, 219, 222, 232, 260, 270, 281, 365, 367, 370, 372, 386, 393, 396, 397, 398, 403, 410, 438, 577, 626, 652, 662, 707, 739, 753, 762, 776, 788, 799, 804,808,819,836,844,877,883,888,890
Sodium borate - 12, 19, 67, 113, 115, 119, 137, 145, 152, 208, 232, 260, 270, 281, 303, 306, 309, 311, 314, 365, 735, 778, 788, 799, 804, 808,819,836,877,883 Sodium bromate - 50, 166, 173, 178, 663 Sodium bromide - 34, 38, 50, 58, 64, 89, 115, 137, 145, 154, 166, 173, 208, 219, 232, 260, 270,393,438, 663,707,732, 762, 778,877 Sodium bromide oil solution - 137 Sodium carbonate - 2, 4, 6, 12, 19, 26, 34, 36, 38, 43, 44, 45, 46, 50, 58, 60, 61, 64, 66, 67, 89, 95,104, 106,109,111,113,115, 117, 119, 121, 137, 145, 147, 152, 154, 155, 156, 166, 169, 173, 178, 208, 219, 232, 237, 239, 240, 246, 249, 260, 270, 281, 296, 364, 370, 372, 373, 374, 377, 381, 382, 387, 388, 390, 392, 393, 394, 395, 396, 397, 398, 403, 410, 438, 568, 609, 626, 632, 646, 647, 652, 657, 662, 663, 707, 731, 732, 735, 739, 762, 769, 778, 784, 788, 791, 792, 794, 795, 799, 804, 808,818, 836,844,877,883,888,890 Sodium carbonate, fumes, vapor, condensate - 208 Sodium chlorate - 30, 34, 38, 50, 58, 64, 89, 106, 115, 119, 137, 152, 154, 156, 166, 173, 208, 219, 222, 260, 270, 281, 377, 381, 393, 438, 568, 609, 626, 707, 732, 735, 739, 762, 769, 776, 778, 784, 796, 799, 804, 808, 877, 883, 888,890 Sodium chlorate-hypochlorite - 384 Sodium chloride - 1, 4, 6, 7, 12, 19, 26, 30, 34, 36, 38, 39, 43, 44, 45, 46, 50, 52, 58, 60, 61, 64, 66, 67, 89, 95, 96, 97, 98, 104, 106, 109, 111,113, 115, 117, 119, 121, 137,145,151, 152, 154, 156, 166, 173, 208, 219, 222, 232, 237, 239, 240, 246, 249, 260, 270, 281, 291, 293, 295, 296, 297, 301, 303, 306, 309, 311, 314, 317, 318, 319, 320, 321, 322, 323, 324, 325, 326, 327, 328, 329, 330, 331, 332, 333, 334, 335,336, 377-354, 365,370,372, 373, 374, 377, 381, 382, 386, 387, 388, 390, 392, 393, 394, 395, 396, 397, 398, 403, 410, 414, 415, 416, 417, 420, 423, 430, 438, 444, 445, 568, 569, 609, 626, 632, 642, 646, 647, 652, 657, 662, 663, 666, 707, 708, 703, 726, 732, 735, 739, 741, 752, 756, 762, 769, 776, 778, 780, 784, 788, 792, 799, 804, 808, 819, 836, 844,847,876, 877, 883,888, 590 Sodium chloride, acetic acid - 423 Sodium chloride, alkaline - 727 Sodium chloride, boiling - 416, 420, 445, 666, 752,769,778 Sodium chloride brine - 725, 735, 741, 780 Sodium chloride, carbonate (boiling) - 417 Sodium chloride, chlorine - 208, 286, 727, 739 Sodium chloride, citric acid - 423 Sodium chloride, copper chloride - 642 Sodium chloride-hydrochloric acid (oxidizing) 722
954
Corrosion
Resistant
Materials
Handbook
Sodium chloride mixtures - 569, 570, 571, 573, 756 Sodium chloride, molten - 201, 207 Sodium chloride, oxalic acid - 423 Sodium chloride, phosphoric acid - 423 Sodium chloride salt spray test - 727 Sodium chloride-sulfur dioxide - 752 Sodium chloride vapor, condensate - 208 Sodium chlorite - 30, 50, 119, 138, 166, 208, 209, 260,270,286, 392,571, 662,709 Sodium clorite, acid solution - 60 Sodium chlorosulfonate - 404, 410 Sodium chromate - 19, 44, 50, 89, 109, 138, 156, 166, 209, 249, 386, 393, 403, 410, 438, 626, 652, 662,762,788,844,877 Sodium citrate - 89, 438, 735, 739, 762, 769, 778, 877 Sodium cumene sulfonate - 209 Sodium cyanide - 12, 19, 30, 34, 38, 50, 64, 67, 89, 115, 119, 138, 151, 154, 156, 166, 173, 178, 209, 219, 237, 246, 260, 270, 281, 365, 388, 390, 393, 397, 398, 410, 438, 571, 572, 626, 632, 652, 662, 663, 739, 762, 769, 788, 799, 804, 808, 819, 836, 844, 877, 883, 888, 890 Sodium dialkylorthocarbonate - 709 Sodium dichromate - 30, 50, 58, 88, 89, 115, 119, 138, 145, 152, 154, 156, 166, 173, 208, 209, 222, 232, 240, 260, 261, 270, 282, 301, 377, 381, 386, 393,403, 410,438, 626, 652, 663, 735,739,761,769, 776,778,788,877 Sodium dioxide (see Sodium peroxide) Sodium disilicate - 626 Sodium disulfite - 836 Sodium dodecyl benzene - 261 Sodium dodecyl benzenesulfonate - 209 Sodium ethoxy sulfate - 209 Sodium ferricyanide - 30, 50, 89, 115, 119, 138, 154, 166, 173, 209, 222, 261, 270, 282, 393, 397,398,438,709, 762,776,778,877 Sodium ferrocyanide - 12, 19, 26, 30, 50, 115, 119, 138, 151, 154, 166, 173,209, 261, 270, 282, 778,877 Sodium fluoaluminate - 156, 836 Sodium fluoride - 12, 19, 31, 50, 58, 89, 115, 119, 145, 152, 154, 156, 166, 209, 219, 232, 261, 270, 282, 393. 397, 398, 572, 609,626, 663, 709, 735, 739, 753, 769, 778, 788, 795, 799, 804,808,819,877,883 Sodium fluorosilicate - 50, 166, 209, 572, 626, 709 Sodium formaldehyde sulfoxylate - 438, 572, 709 Sodium formate - 753 Sodium glutamate - 370, 572, 709, 788 Sodium hexametaphosphates - 50, 166, 209,836 Sodium hydrate (see Sodium hydroxide) Sodium hydrogen phosphate - 209 Sodium hydrogen sulfate (see Sodium bisulfate)
Sodium hydrogen sulfide (hydrosulfide) - 178 Sodium hydrosulfide - 44, 45, 51, 166, 173, 178, 209,282,438,572,709,739, 762,784,878 Sodium hydrosulfite - 49, 156, 572, 573, 662, 778, 800,804,808,877 Sodium hydroxide - 2. 4, 6, 10, 17, 26, 28, 31, 32, 34, 36, 38, 39, 41, 42, 43, 44, 45, 46, 50, 52, 53, 58, 60, 61, 62, 64, 66, 67, 74, 82, 89, 95, 96,97,98, 102, 104, 106, 107, 109, 110, 111, 112, 113, 115, 117, 119, 121, 126, 132, 138, 145, 147, 149, 150, 151, 152, 154, 155, 156, 157, 166, 169, 173, 178, 209, 219, 222, 226, 237, 239, 240, 246, 249, 254, 261, 270, 275, 282, 286, 291, 293, 294, 296, 297, 301, 302, 305, 308, 311, 314, 317, 318, 319, 320, 321, 322, 323, 324, 325, 326, 327, 328, 329, 330, 331, 332, 333,334, 335, 336, 337-354,361, 365, 367, 370, 372, 373, 374, 377, 381, 382, 383, 384, 386, 388, 390, 392, 393, 394, 395, 396,397, 398, 404, 411, 414, 416,425, 432, 438, 442, 573, 626, 632, 640, 642, 644, 646, 647, 652, 663, 666, 676, 709, 727, 728, 731, 732, 733, 735, 739, 753, 762, 772, 776, 778, 780, 784, 788, 790, 791, 792, 794, 799,800, 804, 808, 812, 819, 836, 844, 847, 852, 860, 869,877,883,884,888,890 Sodium hydroxide, boiling - 100, 414, 416, 417, 420,444,645, 666,739,753,769 Sodium hydroxide, chlorate, chloride - 417, 727 Sodium hydroxide, fused - 222, 776 Sodium hydroxide mixtures - 573, 574, 727, 753 Sodium hydroxide pulp digester liquor - 709 Sodium hydroxide scrubbing chlorine - 209 Sodium hydroxide vapor, condensate - 209 Sodium hydroxide, with sodium chloride - 422 Sodium hypochlorite reactor - 209 Sodium hypochlorite (bleach) - 2, 4, 6, 7, 12, 14, 19,22,31, 34, 35, 38,45, 51, 53, 54, 58, 60, 61, 62, 63, 64, 66, 67, 89, 95, 101, 104, 106, 107, 109, 111, 112, 115, 117, 119, 121, 126, 138, 145, 147, 149, 151, 152, 154, 155, 156, 157, 166, 169, 173, 178, 185, 209, 219, 221, 222, 232, 233, 237, 239, 240, 246, 249, 254,261, 264, 270, 275, 282, 286, 295, 301, 356, 357, 365, 367, 370, 372, 373, 374, 375, 377, 379, 381, 382, 386, 388, 390, 392, 393, 394, 395, 396, 397, 398, 404, 411, 417, 574, 575, 626, 646, 647, 652, 674, 709, 710, 727, 732, 739, 741, 753, 769, 776, 778, 784, 788, 800, 804, 808, 812, 819, 825, 836, 840,844,848,852, 860,877,883,888 Sodium hypochlorite vapors - 209 Sodium hyposulfate (see Sodium thiosulfate) Sodium hyposulfite (hypo) (see Sodium thiosulfate) Sodium iodide - 58, 60, 261, 270, 392, 753 Sodium lactate - 626, 778, 877 Sodium lauryl sulfate - 51, 109, 166, 209, 626
Corrosive
Material
Index
955
Sodium metaborate peroxyhydrate - 836 Sodium mercaptobenzothiazole - 626 Sodium metaarsenite - 209 Sodium metaphosphate - 58, 89, 138, 156, 170, 270,282, 365.727,819,836,844 Sodium metasilicates - 89, 438, 710, 762 Sodium methacrylate - 209 Sodium methyl arsenate - 177 Sodium nitrate - 12, 19,31, 34, 51, 58, 64, 67, 89, 115, 119, 138, 152, 154, 156, 166, 173, 209, 219, 222, 232, 237, 246, 261, 270, 282, 365, 373, 374, 377, 381, 382, 386, 388, 390, 393,397, 398,403,410, 438, 575, 609, 626, 632, 652, 662, 710, 727, 728, 732, 733, 735, 739, 762, 776, 778, 784, 788, 800,804, 808, 819,836,844,877,883,888,890 Sodium nitrite - 12, 31, 58, 89, 119, 156, 166, 173, 209, 219, 261, 270, 393, 397, 398, 442, 575,627, 662,739,769,778,788,877 Sodium oleate - 710 Sodium orthophenyl phenate - 844,877 Sodium oxalate - 393, 404, 411, 626 Sodium palmitate - 138, 270 Sodium perborate - 64, 89, 138, 156, 232, 270, 282, 365, 438, 627, 632, 662, 710, 762, 819, 836,844,877 Sodium percarbonate - 627, 662 Sodium perchlorate - 34, 58, 156, 222, 270, 438, 710,739,762,776 Sodium peroxide - 58,89, 156, 157, 219,261, 270, 282, 301, 365, 377, 381, 393, 396. 404, 411, 627, 632, 653, 662, 710, 728, 753, 778, 788,800,804,808,819,836,844,877,883 Sodium persulfate - 38, 166, 209, 662 Sodium phenolate - 575, 710 Sodium phosphate - 36, 43, 45, 51, 64, 67, 89, 138, 156, 166, 201, 209, 219, 222,261, 282, 365, 373, 374, 377, 381 I 387, 438, 442, 575, 632, 647, 653, 662, 710, 735, 739, 762, 769, 776,778,788,819,836,844,877 Sodium phosphate, acid (see Sodium acid phospha te) Sodium phosphate, alkaline - 58, 138, 270 Sodium phosphate, di - 28, 50, 55, 113, 114, 128, 149, 152, 154, 166, 209, 255, 266, 788, 844, 849,877 Sodium phosphate, dibasic - 627 Sodium phosphate, hexameta - 852 Sodium phosphate, meta - 58, 59, 138, 156, 170, 270,282,365,844,877 Sodium phosphate, mono - 51, 201, 209, 365 Sodium phosphate, neutral - 58, 138, 270 Sodium phosphate, poly - 844, 878 Sodium phosphate, polymeta - 829 Sodium phosphate, pyro - 214, 271, 731 Sodium phosphate, pyro, molten - 732 Sodium phosphate, tri (see Trisodium phosphate)
Sodium phosphate, tripoly - 51, 166, 210, 282, 366,819,820,836, 844,878,880 Sodium phosphate-phosphoric acid liquor - 209 Sodium phosphate vapors - 7 19 Sodium polyacrylate - 209 Sodium-potassium alloys, molten - 642, 710, 732 Sodium propionate - 370, 575, 627 Sodium pyroborate (see Sodium borate) Sodium resinate - 261 Sodium salts - 365, 367, 852 Sodium sesquicarbonate - 836 Sodium silicate - 12, 19, 20, 31, 51, 58, 64, 67, 90, 119, 138, 147, 156, 166, 173, 209, 219, 261, 270, 282, 365, 439, 627, 632, 646, 653, 662, 663, 710, 728, 735, 739, 753, 762, 769, 778, 788,800,804,808,844,878,883,888,890 Sodium silicate sulfate - 836 Sodium stannic chloride - 836 Sodium subsulfite - 836 Sodium sulfate - 31, 34, 36, 51, 58, 60, 64, 67, 90, 106, 113, 115, 119, 139, 151, 152, 154, 156, 166, 173, 178, 209, 210, 219, 222, 232,237, 240, 246, 249, 261, 270, 282, 365, 370, 372, 373, 374, 377, 381, 382, 386, 387, 388, 390, 392, 393, 396, 398, 404, 411, 439, 442, 576, 609, 627, 632, 646, 653, 657, 662, 710, 732, 735, 739, 741, 753, 762, 769, 776, 778, 784, 788, 792, 800, 804, 808, 836, 844, 876, 878, 883,888.890 Sodium sulfate decahydrate (Glaubers salt) - 360, 780,788,814,836, 867 Sodium sulfhydrate (see Sodium hydrosulfide) Sodium sulfide - 31, 34, 38, 51, 58, 60, 64, 66, 67, 90, 106, 115, 119, 139, 154, 156, 166, 173, 210, 219, 222, 232, 237, 240, 246, 249, 261, 270, 282, 365, 370, 372, 373, 374, 381, 386, 388, 390, 392, 393, 396, 397, 398, 404, 411, 439, 576, 577, 627, 632, 646, 653, 657, 662, 663, 710, 727, 732, 733, 739, 753, 762, 769, 776, 778, 784, 788, 795, 800, 804, 808, 844, 847, 878,883,888,890 Sodium sulfite - 20, 31, 51, 58, 60, 90, 115, 119, 139, 151, 152, 154, 156, 166, 173, 178, 210, 219, 222, 232, 237, 246, 270, 282, 365, 382, 386, 388, 390, 392, 393, 396, 397, 398, 411. 439, 577, 627, 653, 662, 710, 711, 732, 735, 739, 762, 769, 776, 778, 784, 788, 792, 800, 804,808,819,836,844,883 Sodium superoxide (see Sodium peroxide) Sodium tartrate - 404, 411, 662 Sodium TCA - 796 Sodium tetraborate (see Borax) - 51, 90, 145, 166, 2 10,232,663,788,836,878 Sodium tetrachlorophenate - 210 Sodium thiocyanate - 51, 166, 173, 210, 627
956
Corrosion
Resistant
Materials
Handbook
Sodium
thiosulfate
(hyposulfite) 90, 139, 151, 232, 237, 282, 411,
- 20, 34, 51, 58,

156, 163, 239,240, 386, 166, 173, 246, 388, E08,
Spirits of wine Stackfas mastic Stack gases
60, 64, 67,89, 178, 210, 249. 739, Sodium Sodium Sodium 282, Sodium Sodium 257, 769, 390, 392,
- 784, 836 - 210
219, 222, 261, 270, 393, 404, 776, 777,
- 711
365, 382, 627, 653,
710, 727,
778, 788, 800, 804,
819,823,836,844,862,868,877,878,883 thiosulfite triphosphate 366,819,836,844 vanadate xylene
- 411
(see Trisodium (STPP) phosphate)
- 210 - 210 Standard Oil Mobilube - 365 Stanisol - 235 Stannic chloride - 31, 34, 45, 51, 58, 60, 64, 90, 92,
Stack gas scrubbing Stainless steel pickle 108, 115, 373, 800, 890 Stannic chloride, fluoborate salts sulfate molten - 739 119, 139, 146, 154, 270, 627, 770, 156, 167, 173, 282, 301, 365, 662, 711, 7 18. 776, 778, 788, 878, 883, 888, 210, 219, 222, 374, 377, 739, 808, 804, 727, 735, 232, 261, 381, 397, 753, 819, 769,
tripolyphosphate
- 51, 166, 210,
- 577
- 210 Sodium xylene sulfonate - 51, 166, 210

sulfate concentrates (see Foods) Soft drinks, beverages (see also Cola drinks)
836, 844,
Soft drink
- 14,
Stannic Stannic Stannic Stannic Stannous
- 844, 878
382,743,788 Softener Soil Soil, clay Solder Soft - 790 Tin based Solnus oils oil Soluble B
- 210
- 150, 367, 852 - 64, 119

(see Stannic chloride)
- 62, 210, 627, 739 - 215
tetrachloride bisulfate 151,
- 662, 711 Stannous chloride - 31, 51, 58, 67, 90, 106, 115,
119, 139, 154, 156, 282, 157, 301, 762, 167, 173, 210, 365, 397, 439, 770, 776, 778, 219, 222, 627, Stannous Stannous 261, 270,
- 878
- 282, 819 - 878 Solvac 1535 G - 282, 819 Solvents - 220, 884
Solvents, aliphatic and aromatic
662, 711, fluoride salts
728, 735,
800,804,808.836,878,883
- 210, 788 - 150, 367, 852
- 157
Stanoil Starch 282,
Solvesso - 156
- 282, 819 - 58, 90, 115, 139, 150, 154, 156, 210, 270,
396, 578, 627, 646, 711, 784, 788, 844,
- 148, 788 - 51, 166, 210, 627, 788 Sorbose - 627 Sorghum - 844,878
Sorbic acid Sorbitol Soups (see Foods) Sour crude oil (see Crude oil, sour) Sour gas condensate Sovaloid Sovasol - 291
852,878 Starch, digested, Starch, sizing
hydrolyzer
- 210
- 876 Starch syrup - 836 Stauffer 7700 - 286, 365

Stauffer Staysol Steam Jet 1, 2 - 819
- 7 11
- 365, 878 Soya oil - 22, 51, 62, 90, 167, 210, 237, 246,
291,293, Soybean Soybean Soybean Soybean fatty 382, 388,390,411,627,836 acid
- 282, 819 - 53, 90, 156, 210, 249, 285, 286, 289, 301,
FR 381, 728, 393, 735, 578, 627, 642, 646, 653, II, 739,789,792,819,878 146, 150, 151, 153, 154, 225,237, 309, 312, 383, 653, 388, 663,
365, 377, 663,7
- 38
282, 301, 365,
Stearic acid - 10, 17, 31, 51, 53, 58, 60, 64, 66, 67, 90, 108, 156, 167, 246, 261, 315, 711, 890 dioxide generators 365, 735, 115, 139, 173, 270, 373, 762, 819, 178,210, 282, 374, 411, 770, 219,222, 306, 382, 627, 784,
oil - 139, 156, 228, oil, epoxidized processing
788,819,836,843,844,873,878
- 162, 192, 210
301, 303, 377, 381, 421, 439, 776, 779,
- 577, 578
Soy protein Spearmint Spent acid
- 711
oil (see Essential oils)
390, 392, 404, 804, 808,
Soy sauce (see Foods)
788, 800, 883, 888,
836, 844, - 739
852, 856,
- 210,819 - 38
liquor
Spent acid from chlorine Spent sulfite Spermaceti Sperm oil
Stearic acid, molten Stearin
- 426, 724, 736
- 66, 282
bath
- 235 _ 13, 22, 843, 844, 873, 878 Sperry oil - 261
Spices (see Foods)
Steel pickling Stoddards
- 25, 210 - 16, 25, 31, 58, 67, 90, 150,

241, 249, 261, 270, 282,
Steep liquor - 869 solvent 154, 156, 219, 235, Stove oil
- 106, 112, 139 Spirits of turpentine - 836

Spindle oil
365,789,819,836,844,852,878,888,890
- 210
Corrosive
Material
Index
957
Straight Streicher Stripper Stripping Strobane Strontium Strontium Strontium
synthetic test SA
Streptomycin
oils - 282 - 413 - 627, 711
- 836 - 53 - 232
- 173
solutions
- 712, 879 - 45, 156, 367, 646, 712, 784 Sulfonyl chloride - 211 4Sulfophthalic acid - 211 Sulfur - 20, 31, 42,45, 59, 64, 90, 106, 115, 139,
Sulfonation Sulfonic of fats and oils acid 145, 150, 261, 646, 653, Colloidal Molten 411, 53, 64, 66, 90, 261, 282, 301, 627, Molten, Sulfurated Sulfur Sulfur 151, 712, 154, 393, 156, 157, 211, 770, 776, 219,222, 780, 784, 270, 365, 398, 439, 582, 583, 628,
- 627
bromide carbonate chloride
732, 762, 233 712,
- 578, 711 Strontium hydroxide - 156 Strontium nitrate - 156 Strychnine - 231 Styrene acrylic emulsions - 210 Styrene monomer - 20, 34, 38,45,
106, Succinic 662, 109, 156, 167, 173, 210, 270, 365,627,663, 739, 753,
796,819,836,852,878 - 1, 225, 632, 653,
- 45, 90, 109, 211, 282, 301, 365, 404,

727, 739, 770, 784,800, 844,883
804,808,819, wettable
- 21 1
sulfide)
lime (see Calcium
789,819,836,844,852,878 370, 371, 770, 779, 788,795,855 (see Foods)
burner gas chloride 222, 393, 663,
- 211
261, 270, 282, 762, 365, 776, 367, 377, 583,628, 778, 784,
acid - 59, 139, 261,
- 34, 42, 45, 60, 91, 139, 156, 173,

398,404,411,439, 732, 739,
211, 219, 381,392, 632, 653,
Succinonitrile
- 167, 210
- 579, 580
Sugar, beet and cane liquor Sugar, corn, conversion Sugar, juice - 90, 878
800,804,808,819,836,844,852,878,883 Sulfur-containing 762 Sulfur Sulfur Sulfur 154, 365, compounds dichloride dioxide 156, 377, 642, 732, oils (see also Crude oil, sour)
Sugar of lead (see Lead acetate) Sugar, simple syrup - 1, 229, Sugar solution, Sulfadiazine Sulfamic 261, Sulfamic 270, Sugar, sucrose (see Foods) acid 238 syrup (see Foods)
- 648
- 139, 211, 219, 115, 270, 261 139, 282, 394, 609, 776, 844, 150, 151,
13, 20, 31, 34, 35, 38, 45, 51, 53, 67, 91, 109, 167, 246, 381, 411, 646, 735, 804, 169, 249, 386, 439, 653, 739, 173, 261, 178, 211, 219,222, 286, 301, 395, 397, 628, 632, 727, 778, 784, 847, 852,
- 231 - 34, 38, 51, 119, 139, 167, 211,

282, 375, 379, 628, 647,662, 739, 755 732,
59, 62,64, 235, 237, 398, 404, 639, 728,
819,836,844 acid, boiling - 419,
390, 393, 583, 584, 662, 663, 762, 770,
- 711 Sulfanilic acid - 51, 167, 211, 739 Sulfated detergents - 51, 167, 190, 211,270,
Sulfanilamide Sulfate Sulfate Sulfate Sulfate Sulfide Sulfide Sulfidic Sulfinol Sulfite 878 Liquors (see also Black, 762, Green liquors) 139, 156, 270,282, recovery salts anolyte, reduction - 90, 249, liquors 439, 788,844,869,878 sulfate)
712, 713,
711 - 59,
789,800, 878,883 Sulfur Sulfur Sulfur Sulfur
808,819,836,
dioxide-chlorides dioxide, dioxide fumes fumes
of lime (see Calcium boiler gases electrorefining process 878 628, 711.
- 724 - 211
- 211 - 21 1, 213
- 211, 383, 663 - 211
removal, scrubber - 211, 422 - 53, 211 Sulfur fungicide - 211 Sulfur hexafluoride - 282, 365, 836, 878 Sulfuric acid - 1, 2,4, 6,9, 10, 17, 26, 31, 32, 34, 104, 115, 151, 240, 106, 107, 35, 38, 39, 42, 43, 45, 51, 52, 53, 59, 60, 61, 62, 64, 67, 91, 95, 96, 97, 98, 102, 108, 109, 110, 140, 157, 224, 271, 302, 373, 388, 432, 632, 656, 725, 111, 146, 112, 147, 113, 150, 173, 239, 121, 139,
spent caustic
- 211
- 34, 59, 90, 173, 211, 222, 270,

724, 762, 776, 836,
365, 426, Sulfite
117, 119, 152, 154, 219, 296, 367, 396, 587, 714, 733, 246, 249, 365, 395, 586, 713, 732,
- 21 1 Sulfite liquors with sulfuric acid - 222 Sulfite pulping vapors - 711 Sulfoacetic acid - 711 5Sulfoisophthalic acid, sodium salt - 211
liquors, calcium base mill Sulfolane Sulfonated - 90, 241, aliphatics 249, 878
155, 156, 222, 223, 261, 270, 297, 301, 370, 372, 386, 387, 397, 425,428, 588, 628, 647, 753, 716, 717,
167, 169, 225, 237, 282, 305, 374, 390, 439, 639, 662, 728, 308, 377, 392, 444, 663,
178, 212, 293, 294, 382, 394, 585, 665, 731,
286, 291. 381, 393, 584, 664,
311, 314,
383,384,
- 211 Sulfonated compounds - 580,581, 582,712,878 Sulfonated detergents - 48, 109, 161, 191, 211 Sulfonation - 712, 727 Sulfonation acid (spent) - 712
398,404,
411,412,413,416,420,421, 640,642, 729, 730, 643, 644,646,
958
Corrosion
Resistant
Materials
Handbook
Sulfuric 739, 784, 808, Sulfuric Sulfuric Sulfuric 423, 715, 756, Sulfuric Sulfuric Sulfuric 770, Sulfuric Sulfuric Sulfuric Sulfuric 261, Sulfuric Sulfuric 591, Sulfuric 421, Sulfuric Sulfuric Sulfuric Sulfuric Sulfuric Sulfuric Sulfuric Sulfuric Sulfuric Sulfur Sulfur
acid (contd) 741, 753, 756, 790, 763, 770, 791, 792, 844, acid 772. 776, 855, 779, 804, 883, 787, 788, 819,823,836, acid-acetic 793, 800,
301,365, 628, 646, 789, 800, 883 Sulfuryl
386, 653, 804,
390, 662,
393, 713,
397, 731, 837,
398, 411, 439, 732, 844, 763, 779, 878, 879,
808,819,
847, 852,
884,888,890
chloride 411,
- 53, 106, 158, 178, 213, 377,

662, 718, 732, 800, 804, 808,
- 717 - 891
418, 420, 666, 714, 753, 754, 647, 739, 656, 741,
381,404, 883 Sulfuryl Summer Sundex Sunlight Sunoco
acid anodizing 428,445,
acid, boiling - 100, 413, 416, 632, 645, 734, 717, 723, 733, 776, 779,855 acid-chlorine acid-chromium acid-copper 781 acid, ferric 741, acid fumes acid, fuming 286, 301, acid mist 592, 647, acid-nitric 740, acid, oleum acid pickling acid saturated acid sludge acid-sodium acid-sodium acid vapors anhydride ions (boiling) 754,781
fluoride oil 53
- 262
- 156
- 291 - 94 - 301, 365, 879 - 282,819
- 740
trioxide
oils and grease F
- 770
Sun R&O oils Sunsafe Suntac oils
sulfate
- 739, 740, 741, 754, - 445, 647, 666,
733,734,
- 717 - 212 - 91, 112, 115, 237, 246,

439, 727, 763,
- 282, 365,819 - 282, 819 Sunvis oils - 282, 819 Super hydraulic oils - 282, 819 Superphosphate dust - 718
Super phosphoric Surfactants Swan Finch Sweet oil acid (see Phosphoric acid, super)
acid fume scrubber
- 213, 214
Lube, Hypoid
359, 390, 411,
- 365
779,800,804,808,819,844,852,856,883
Sweet birch oil
- 837
- 717 - 212, 213, 588, 589, 590,

723, 727, 734, 754, acid) 755, 717,
acid mixtures
770, 776 acid (see also Mixed (see Oleum)
- 214, 837 - 21 Sweetwater - 214 Synthetic oils - 282, 285, 298, 358, 819, 827, 840,
Sweet orange oil 863,870,872
770,781
- 891
with chlorine chloride
- 717, 727
- 796 - 837 TCP - 837

2,4,5-T TCA TEA (see Triethanol amine) TT-I-735b TT-N-95a TT-N-97B TT-S-735 TT-T-656b
- 718 - 657, 734 dichromate - 233, 727, 732 - 718, 740, 770
(see Sulfur trioxide) chloride) 51, 59, 60, 64, 67, 154, 246, 396, 632, 156, 167, 262, 381, 397, 653, 804, 271, 386, 398, 657, 755. 808, ether)
- 365 - 365 - 365

Type I-VI
- 365
chloride)
ether (see Diethyl monochloride ointment acid 140, 365, 392, 432, 718,
- 365
(see Sulfur
Table salt (see Sodium Talc slurry - 879 Talcum 214, powder
- 231 - 31, 38,44,45,

150, 367, 393, 439, 727, 779, 151, 152, 222, 237, 373, 394, 395, 593,628, 732, 784,
Sulfurous 173, 388, 404, 662, 763, Sulfurous Sulfurous Sulfurous Sulfur Sulfur Sulfur 173. Sulfurretted
(see Cosmetics)
91, 115, 282,301, 390, 411, 663.
Tall oil (Tallol) 594,628,682,
- 51, 59, 91, 150, 167, 173, 178,

271, 718, 282, 383, 432, 439, 593, 763,784,819,837,879
178, 213, 219,
219, 262,
374,377,
Tall oil purification Tallow 879 Tallow, Tanners Tannic 156, secondary oil - 156
vapors - 719 - 64, 91, 115, 140, 156, 282, 646, 819, 852, amines of
733. 735, 740. 788, 800,
770, 776,
- 670
819,836.844,847,852,856,883 acid anhydride oxychloride spray (see Sulfur dioxide) chloride) (see Thionyl
acid - 10, 17, 31, 34, 38, 51, 53, 59, 60, 67, 140, 146, 150, 303, 382, 728, 151, 153, 306, 388, 735. 309, 628, 740, 788, 800, 154, 312, 632, 755, 155, 167, 365, 173, 271, 368, 653, 776, 178,214,219,222,225,237, 282, 301, 370, 662, 779, 372, 663, 784, 390, 392,
91, 115, 119, 246, 261,
- 779
(see Hydrogen chloride) anhydride) 154, 246, sulfide)
oxides
- 411
hydrogen (sulfuric 150, (see Sulfur
315,
subchloride trioxide
393,396,398,404,411,439.442, 642, 646, 763, 770, 282, 169, 270,
- 31, 45, 51,

261,
53, 66, 91, 115,
156, 167,
804, 808,
178, 211,219,237,
819,837,844,852,856,883,888,890
Corrosive
Material
Index
959
Tannic Tannin Tanning
jelly
- 225 - 377,381,837,879
leather, drums
Tetrachlorodifluoromethane Tetrachloroethane 91, 106, 662, 669, 852,879 1,1,2,2-Tetrachloroethane 1 ,I ,2,2-Tetrachloroethylene 282, 377, 728, 381, 91, 111, 167, 172, 280, 319, 320, 113, 148, 177, 204, 292, 322, 331, 372, 628, 321, 330, 371, 623, 155, 214, 293, 323, 332, 372, 661, 740, (acetylene 755, 770, 156, 178, 377,
- 837
tetrachloride) 789, 822, 837, - 11, 18, 657, 845, 381,404,411,463,
- 214 Tanning liquors, extracts - 31, 59, 91, 115, 150,

154, 271, 594,662, 837,844,852,879,888,890 Tanning Tan oil 432, Tar acid Tar, Tar, Tar Tar, Tar oil 663, 718, 719, 726, 784,
- 38, 148, 230, 251, 628

(perchloroethylene) 156, 157, 219, 300, 324, 333, 374, 158, 165, 259, 318, 327, 336, -
- 843, 844, 873, 879
- 154
594, 595. 596, 628, 653, 663,
11, 18, 30, 33, 34, 38, 43, 52, 53, 64, 66, 67, 85, 230, 249, 304, 317, 325, 326, 334, 335,
Tar - 59, 64, 91, 140, 156, 271, 789,879
284, 291,
- 718
Tar, ammonia
- 222, 776 aromatic - 673 bituminous - 365, 819, 837 camphor - 214,837 chlorinated - 825 oil - 67, 91, 282, 377, 381
acid (dihydroxy 119, 140, 303, 150, 222, succinic acid) - 10, 31, 151, 225, 386, 432, 663, 779, 154, 312, 388, 442, 156, 315, 390, 167, 262, 365, 392, 728, 173, 271, 370, 393, 632, 735, 804,
328,329, 363,365, 437, 488,
377, 381,382, 718, 740,
663, 694,
760,789,817,833,837,843,852,874 Tetrachloromethane Tetrachlorophenol, Tetrachloropyridine Tetradeconic Tetraethyl 845,879 Tetraethyl orthosilicate acid lead Tetra(2-ethylbutyl) 173, 219, 262, (see Carbon Tetrachloride) 2,3,4,6-Tetrachlorophenol sodium
- 262
salt
Tartaric 115,
- 214
34, 38, 51, 53, 59, 60, 64, 66, 67, 91, 106, 178, 214, 219, 282, 301, 372, 377, 646, 237, 246,
- 214 - 837
silicate - 11, 20
306, 309,
- 31, 59, 66, 91, 115, 150, 154,

271, 278, 365, 620, 820, 837,
381, 382, 662, 776,
396, 398, 404,411, 647, 653, 770, 740, 755, Tartrates Tectyl Teepol Teller Telone Tenite Tenol
596, 628,
718, 727,
- 837
784, 788, 800,
Tetrafluoromethane Tetrahydrofuran 119, 249, 140, 262, 150, 271,
808,820,837,844,852,856,883,888,890
- 837 - 31, 45, 59, 64, 66, 91, 113, 115,

(see Freon) 153, 151, 283, 154, 219, 235,241, 365, 377, 381, 291, 301,
- 404, 411
Tea (see Foods) 502 - 879 solution scrubber fumigant oils
820,837,852,879,888,890 Tetrahydrofurfuryl 226 Tetrakis(hydroxymethyl)phosphonium 214 Tetralin (tetrahydronaphthalene) chloride hydroxide chloride alcohol - 10, 17, 45, 146, 178,
- 140, 845, 879 - 214
Tellus oils
- 282, 820, 876 - 214
- 235 - 282, 820 Terephthalic acid - 214, 740, 788 Tergitol - 214, 820
Terpenes
- 64, 91, 106, 140, - 219 - 262
146, 235,283.365,663,837,845,879 Tetramethylammonium Tetramethylammonium Tetramethyl lead
- 178, 628
(see also Essential oils) sulfate)
- 278
acid - 91, 662 (see Potassium - 167 (see Sodium phosphate, pyro-
Terpineol
- 14, 21, 150,
Tetraphosphoric Tetrapotassium phosphate) Tetrasodium Tetrasodium
178, 271,282,365,820,837,879 Terra alba (see Calcium Terra ponderosa Terresstic Tertiary Tertiary Tertiary tert) Tetramine C butyl
pyrophosphate ethylenediamine pyrophosphate (see Furan)
- 837 - 283, 820

alcohol (see Butyl alcohol, tert) tert) (see Butylcatechol, (see Butyl
butylcatechol butylmercaptan
pyre) Tetrol, tetrole Texaco Textile
mercaptan,
oil, fluids, grease bleach
- 365, 366, 879
Texas 1500 oil - 366
- 788
- 11, 18, 157, 251, 355, 822,
s-Tetrabromoethane 837,839,854,879 Tetrabromomethane Tetrabutyl titanate Tetrachlorobenzene
Textone Thallates Thallium, Thenardite Thermolin
- 718 - 167,214
of lead, cobalt, molten RF-230 manganese sulfate) acid
- 530
- 365, 837
- 642 - 214 - 719
- 365, 837, 879 - 673 Tetrachlorocyclopentane - 214 Tetrachlorodifluoroethane - 837
(see Sodium
Thiocarbamide-hydrochloric
960
Corrosion
Resistant
Materials
Handbook
Thiocarbanilde Thioglycol Thioglycolic Thiokol Thionyl 146, Thionyl TP
- 628
acid - 109, 167, 214, 628, 845
249, 319. 329,
262,
271, 304,
283, 307, 322, 374, 393, 653, 804,
284, 309, 333, 377, 394, 662, 808,
286, 312, 334, 382, 395, 663, 820,
291, 315, 335, 383, 728, 837,
293,
296, 328, 366, 387, 776,
- 214
297. 301, 330,
317, 318, 336, 386, 763,
320, 321, 373, 392, 632,
324, 325,
326, 327,
- 366,879 chloride - 31, 45, 51, 53, 59, 64, 92,

150, 154, chloride - 106, 165, vapor 173, 178, 214, 235, 262,
331, 332,
371, 372, 388, 390, 439, 789, Toluene 628,
398, 4104, 411, 845, 852,
271,366,662,732,837,845,852,879
- 214
792, 800,
Thiophene Thiophenol Thiosorbic Thiourea Thorium Thread Thyme Thymol Tidewater Tin fumes molten Tincal
140, 283,628 chloride
879,883,888,890 diisocyanate sulfochloride
- 34 - 662 - 681
271 lime
- 45, 214, 278, 283, 366, - 662 - 61 - 262

718,788
Thiophosphoryl
815,820,879 Toluene Toluene-isooctane Toluene-kerosene Toluenesulfonic Toluenesulfonyl mixture mixture acid
- 214
and organic acid - 596 cutting (oil)
oils - 59, 262,
- 38, 45, 51, 167, 178, 214, - 770
- 14, 21 - 366, 879
373,374,377,382,404,411, chloride Toluene Toluic Toiuic 732, 740, 780, 790 o-Tolyl vapor
- 231
oils and grease
- 214
788
acid - 597, acid, meta
- 214
- 92, 214, 642, (see Stannous 388, 390, 718,837 chloride)
- 718 - 214
(see Foods)
Toluidines
- 628
- 837
or Stannic 392, 393, chloride) 398, 404,
chloride products
Tin chloride 411,597, Tincture Tincture
Tomato
237, 246, 386,
Tin crystals (see Stannous of iodine
of green soap (see Green soap solution)
- 14, 23, 628, 845, 880 - 16, 25, 156,214,262, 628,796 Trancil 1 OC - 880 Transformer oil - 6, 7, 13, 22, 38, 51, 59, 64, 92,
Toothpaste, powder Toxaphene 95, 104, 106, 109, 173, 214, 818,820, fluid 278, 837, 283, 845, 112, 115, 271, 273, 117, 281, 119, 140, 156, 167, 283, 296,
- 106
chloride)
Tin dichloride Tin fluoborate Tinofix OF
(see Stannous - 597
364,366, Transmission (see Plating solution, tin) 273, 811, 275, 820,
837,845,852,867,880 356, 358, 865,867, 365, 366, 810, 876,
- 214
(see Stannous stannous salts) chloride)
- 5, 52, 96, 97, 98, 107, 214,

869, 871,
Tin plating solution Tin protochloride Tin salts (stannic, 879 Tin sulfate
- 367, 732, 837, - 237,
879,880 Travertine
- 837
(see Glycerol triacetate)
(see Stannic,
stannous sulfate) chloride)
Triacetin Triaryl
246,386,388,390,393,404,411,597 Tin tetrachloride Tirpineol Titanic Titanium Titanium Titanium Titanium Titanium Titanium 663, Tobacco Tobacco Toilet sulfate (see Stannic (see Terpineol)
- 366, 718, 880 Tribromoethylbenzene - 262 Tributoxyethyl phosphate - 283, 291, 293, 366,
phosphate 820,837,880 Tributyl citrate - 92, 262, 271
- 222
sulfate
- 628
chlorides, dioxide sulfate sulfate
- 404, 411
Tributyl Tributyl 154,
mercaptan phosphate 158, 214,
- 628 - 662, 718, 776

reduction 262, 271, process
- 366, 880 - 31, 59, 66, 92, 148, 150,

219, 262, 271, 283, 301,366,
- 214
628, 662,
820,837,845,880 Trichloroacetaldehyde Trichloroacetic 178, 214, 770,779, 59, 67, 92, 106, 219, 382, 393, 404, Trichloroacetonitrile Trichlorobenzene 178, 215, 880 Trichlorobenzene, Trichloroethane 845,880 vapor - 718 - 46, 167, 230, 366, 371, 372, 837, 230,
tetrachloride 735, tars 740,763,
- 13, 20, 31, 92, 115, 146,

366,439, 778,820,837,879
- 214
109, 119, 262, 647, 140, 156, 271, 653, 366, 718, 157, 740, 167, 755,
150, 154, 232,
acid - 10, 17, 34, 40, 45, 51, 53, 249, 411, 372, 378,
- 628 - 235 - 214
Tobias acid Toluene 111, 148,
788,837,845,856
tanks, aircraft
- 214 - 2, 5, 8, 9, 11, 18, 26, 31, 32, 34, 38, 45,

64, 66, 92, 95, 103, 104, 117, 119, 156, 158, 229, 237, 121, 167, 239, 140, 169, 241, 146, 173, 246, 106, 113, 219, 115, 222,
- 215
- 39, 41, 43, 44, 45, 46, 60, 156, 292, 392, 628, 663, 789, 837,
51, 52, 53, 59,60, 112, 150, 151, 154,
178, 214,
Corrosive
Material
index
961
l,l,l-Trichloroethane 103, 108, 1,1,2-Trichloroethane Trichloroethylene 115, 119, 140, 173, 262, 310,
- 9, 38, 40, 42, 46, 66, 92,
Trifluoromethyl Trifluorovinyl Trifluorovinyl
148, 215,628
- 103, 215, 262, 292

- 9, 11, 18, 31, 34, 38, 46, 51, 107, 111, 112, 154, 237, 372, 628, 718, 884, 156, 239, 293, 373, 394, 632, 719, 804, 888, 146, 271, 312, 148, 283, 150, 151, 219, 230, 371,
- 719 - 837, 880 chloride, oils, greases - 215

diphenylamine chloride acid (see Gallic acid)
Trihydroxybenzoic Trihydroxyethylamine Trim 5050/H,O
53, 59, 60, 64, 66, 67, 92, 103, 157, 167, 246, 249, 301, 307, 374, 642, 728, 890 Trichloroethylene Trichloromethane Trichlorofluoroethane Trichlorofluoromethane Trichloronitromethane Trichlorophenol Trichlorophenol, Trichloropropane 880 Trichloropropanolamine Trichloropropene fumes 395, 397, 647, 740, 178, 215.
- 837
- 102 acid - 178
Trimethylacetic Trimethylamine Trimethylamine Trimethylbenzene Trimethylbenzyl Trimethylbenzyl Trimethyl Trimethyl Trimethylene borate
286, 291, 292, 390, 676, 392, 393, 682, 883,
- 178, 262
hydrochloride - 629 ammonium ammonium chloride hydroxide alcohol) - 167
315, 366, 411, 763,
- 215 - 12, 20
- 10, 17
378, 382, 653, 743, 837,
383, 388, 662, 663, 755, 845,
398, 404,
439, 488,
770, 789, 800,
- 215
(see Butyl
808, 820,
852, 880,
carbinol
chlorobromide
- 215
763
3,5,5-Trimethylhexanol-3 Trimethylpentane Trimethyl phosphate
- 103
(see Chloroform) - 439, (see Freon)
(see Isooctane)
- 837
Trimethylpropane Trinitrophenol Trinitrotoluene Trioctyl 845, Triolein Triphenyl Triphenyl Tripalmitin
- 178, 528 - 31, 150, 154, 262, 271 - 20, 366, 629, 838, 880 - 366,838, 880
trioleate) tripalmitate) - 609
- 662, 842 - 51, 167, 215, 262, 663 sodium salt - 262
- 92, 156, 292, 439, 763,
(see Picric acid) (TNT)
phosphate
(see Glyceryl phosphate phosphite 547,662,
(see Glyceryl
- 226
- 439, 763, 837
- 230 - 286
phosphate) 291, 366, 494,
- 108, 173, 215, 241, 249,

(see Sodium phosphate,
Trichlorotrifluoroethane Trichlorotrifluoromethane Tricresyl 303, phosphate 306, 309,
439,
763,880 (STPP)
Tripolyphosphate
(tritolyl 312, 315,
- 31, 51,
301, 719, 629,
tripoly) Tripropylene Tripropylene glycol - 92 glycol methyl ether
66, 92, 157, 789,820,
167, 215,
262, 283,
- 262
phosphate) 215
837,845,880,888,890
Tritolylphosphate Trisodium 108,
(see Tricresyl
Tridecylbenzene Triethanolamine 108, 173, 306, 115, 140, 178, 215, 309, 312, 880
- 51, 167, 215 - 13, 31, 34, 38, 46, 59, 64, 92,
sulfonate 150, 235, 315, 153, 366, 629, 154, 156, 368, 371, 657, 662, 157, 372, 167, 303, 378, 262, 271, 283, 301,
Tris(hydroxymethyl)nitromethane phosphate 140, 219, 373, 395, 663, 232, 374, 396, 710, 115, 146, 150, 237, 378, 397, 755, 151, 246, 382, 762,
- 1, 31, 46, 51, 59, 60, 66, 93,

152, 249, 386, 770, 154, 262, 411, 156, 167, 271, 301, 392, 627, 795, 439,
173, 215, 370, 372, 393. 394, 632, 662,
388, 390, 784, 788, 877,880,883
382, 394, 837,845,
395,396,
788, 820,
398, 404,
Triethanolamine Triethanolamine Triethanol Triethyl aluminum
hydrochloride linear alkylate
- 719 sulfonate
800,804,808,836,838,844,852,
- 215
dl-Tryptophan Tuna oil 301, Tungstic Turbine Turbo Turco oil
- 262
246, 283, 812,
ammonium
lauryl sulfate
- 215
- 215
357, acid oil 366, 382, 388, 390, 411, 629,663, 880
Triethylamine 219, 262, Triethylamine Triethylamine Triethylborane Triethylene 371,372
- 366, 837, 845, 880 - 31, 43, 59, 92, 103, 173, 215,
788
Tung oil (China wood oil) - 93, 156, 237, 820,825,838,843,845,860,873,
271,629, salts
hydrochloride
- 215
- 44, 46
- 629 229,
- 178 - 156, 301, 366, 843, 873

- 845
- 366, 837, 845, 880

glycol - 10, 17, 92, 146, 215,
- 366, 865 - 235

115, 155, 279, 382, 784, 117, 156, 283, 119,121,140,146, 167, 291, 173, 215, 597, 629, 838, 845, 219, 632, 852, 293, 296, 301,
Triethylenediamine
W.O. #I red oil
Turkey
Turpentine
- 2, 6, 7, 26, 31, 51, 59, 60, 66, 67, 93,

106,111, 151, 262, 374, 663, 154, 271, 378, 728,
Triethylenetetramine Triethyl Triethyl phosphate phosphite
- 146, 226
- 92, 121, 249, 880 - 92 - 679
95, 104, 148, 235, 366, 653, 150, 249, 373, 662,
Tri Film 250 Trifluoroethane
- 880 - 366
392, 442, 789, 820,
Trifluorochloroethylene
880,888,890
962
Corrosion
Resistant
Materials
Handbook
Turpentine Tween Tycol Type Type
substitute
- 838
Vacuum
pump oil
- 106
- 719
- 167
products
Vagh resin solution
- 283, 820
Vagh varnish - 719 Valclene Valerie Valves, 200
I Fuel - 366 II Fuel - 366 Type III Fuel - 366 Typewriter oil - 235 dl-Tyrosine - 262
UDMH (Unsymmetrical - 102, dimethyl 156, 283, hydrazine) 366, 820 - 219,
- 845, 880
788
acid - 629,
pumps - 729 oxide - 728 sulfate-sulfuric - 215 - 21, 140 extract - 629 - 115, 229, 845, 853, 880 acid
Vanadium Vanadium Vanasol Vanilla Vanilla Vanillin Vapona
- 384
303,306,309,312,315,366 Ucon products Udylite #61 Ultraformer Ultrasonic Ultraviolet Ultrawet Undecyl
- 845
feed
Vanillindropar
- 140
- 215
- 215
solutions
- 880
K-300 222-90
cleaning detergent alcohol
- 884
Variquat Varisoft Varnish Varox
light - 94
- 215
156, 283, 366, 539, 629,
- 185, 215
- 93, 140,
- 93, 226
632,653,728,789,820,838,845,880 Varsol 185E - 215 - 16, 25, 148, 215, 219, 235, 284 - 59, 64, 102, 119, oil 140, 271
Undecylenic Undertakers Union Uran
acid - 629 restorative fluid
- 845
oils and fluids - 283, 820
Vaseline Vaseline Veedol Vegetable
Unvis hydraulic Uranium
- 366
_ 140
No. 60 - 880 - 36, 51, 57, 60, 62, 63, 64, 84, 167, 203, 293, 366, 385, 646, 663, 216, 371, 728, 262, 268, 279, 374, 410, 372, 373, 396, 403,
- 156, 215 - 732

chloride extraction fluoride ore - 598, SX units ammonium nitrate sulfate 151, 378, 598, - 598, - 597, 740
Aturbrio oils 134, 285,
Uranium Uranium Uranium Uranium Uranium Uranium Uranyl Uranyl Uranyl Urea 150, 374, 432,
121, 283, 378, 442,
156, 289,
- 215 - 215
719
382, 383, 538, 632,
392, 393,
788, 820,838,
- 215
acid - 384 phosphate 740
843,845,852,873,880 Vegetables, Veneer Vent gas vegetable fumes juices (see Foods)
sulfate-sulfuric
- 740
drying
- 215
880
- 740
153, 246, 382, 599, 154, 262, 383, 629, 155, 386, 663, 156, 167, 173, 215, 373, 788,
- 34, 51, 59, 61, 64, 66, 67, 93, 115, 140,
271,283, 719, 371,372, 727, 784, 770
- 728 - 283,366,820,838, Vicks VapoRub - 23

Versilube Vicks Vidden Vinegar Vinegar Vinegar Vinegar Vinyl 168, Va-Tro-Nol D fumigant (see Foods) naphtha and salt salts (see Ethyl - 23 - 216
219, 237,
388, 390,404,411,
acetate)
820,838,853,888,890 Urea-ammonia Urea-ammonium Urea-formaldehyde Urea resins reaction nitrate - 845, mass - 740, mixture 880 411, 439, 150, 382, 442, 755,
- 780
150, 154,
- 838
219, 262, 271, 283, 498,629,
- 215
acetate - 31, 38, 51, 59, 62,93, 173, 216,
- 215
719,788,789,820,832,871 Vinylacetylene Vinyl 59, 93, 115, 373, 374, 378, 154, 845, chloride 366,439, 820,838 Vinyl chloride chloride latex - 719 vapor Vinyl Vinyl
Uric acid - 1, 66, 67, 93, 225, 404, 728,735,763,779,788,856 Urine and Urea 156, 235, 853,880 Urotropine VV VV VV VV VV VV VV B-680 H-910 I-530a
- 363, 842 - 42, 46, 64, 93, 156, 262, 283,

599, 629, 662, 719, 728, 763, 789,
- 25,31,
271,
262,
- 108, 215
- 366
- 720
ether
2-chloroethyl
- 678 - 38
663, 881
Vinylcyanide
(see Acrylonitrile)
VV G-632,671~
- 366
Vinyl Vinyl
ester resin 45% styrene fluoride
- 366
- 366
- 156, 820
- 93, 262, - 157
Vinylidene
chloride
K-21 Id, 220a O-526 P-216a. - 366 236
- 366
825a
Vinylmethacrylate
L-751 b, 800,82Ob,
- 366
Vinyl
plastisol
Vinylpyridine
- 23 - 881
168, 216, 663
- 366
Vinyltoluene-
Corrosive
Material
index
963
Vinyl
trichloride - 629
Viscose Vitamins Vitrea
- 216, 838 - 728, 881
Geothermal Geyser Ground, Hot
- 216 - 216
784
- 216
organic contaminated - 196, 600, 601,
- 283, 820 Vitriol oil - 881 Vivo-Zyne - 216

oils VM&P naphtha (see also Naphtha)
High purity
- 34, 64, 96,97,

728,735,881
98, 99, 107, 110, 600,
- 148, 394
395,838 WRDA
- 845 - 366 - 216 - 720
Wagner brake fluid Wash solution Washwater Waste gas Waste oil Wastewater Wastewater, Wastewater Wastewater Water 67.93, 146,
Washer hoods, ducts, chlorination
- 216 - 222,601,632,642,652,775,871,881 Mineral - 106, 601 Oil well - 602 pH 3,7 or 10 - 216 Potable - 31, 51, 62, 141, 153, 216, 249, 250,
Irrigation Mine 27 1,283,358,653, Rain 720
- 216
rayon staple bleach machine
from
- 663 - 602,720
chlorine - 740 - 31, 32, 34, 38, 51, 59, 60, 62, 93, 137, 154, 632, 155, 639, 168, 701, 173,262,271,290, 735, 780, 818, 835, 392,
- 720 - 156, 216

- (see Water, treatment trickling 106, 147, waste) oils, chemicals
River and lake River, saturated Salt
- 217, 720, 721 - 216, 445 filters - 217

111, 119, 121, 141, 283, 629, 262,
141, 150, 364, Scrubber
845,853,876,881,891
- 16, 26, 31, 32, 34, 36, 38, 51, 52, 59, 66,
107, 110, 156, 157, 219, 286, 289, 372, 386, 290, 239, 240,271, 291,296, 394, 395,
- 720
153, 219, 305, 445, 647, 731, 154, 222, 308, 155, 311, 156, 314, 604, 664, 740, 168, 169, 271, 625, 665, 747, 386,421,423, 636, 666, 639, 706, 173,
Sea-31,34,36,51,53,59,62,66,88,112,115, 150, 151, 207, 216, 301, 642, 302, 646, 426,431, 249, 260, 281, 297,
284, 285, 366, 371,
297, 301,
387, 393,
728,731,788,789,795,820,838 Acid mine - 59,69, 271, Acid organic Boiling Brackish Brine 93, 150, 151, 154, 247, 726,780,781,845,853,854
602, 603, 652, 663, 735, 739,
720, 726, 881 735, 891 626,
748, 755,
- 216
769,776,780,784,788,818,847,876,881 Sea, desalination Sea, saturated 674, 720, Sewage Softened chlorine
Boiler feed - 93, 599, 845, 859,
- 663, 881
- 93, 599, 600, (soda)
- 207, 216 - 723
- 283,285,639 - 66, 146, 233, 281,382,
- 31, 59, 62, 88, 262, 271, 373, 374,639 - 604, 639 - 173, 216
720
Carbonated 651,663 City
Soil - 639 Steam condensate Steep Tap
- 216 Cold - 64, 845 Condensate - 216,600

Contaminated Cooling Degassed Deionized tower with solvents
- 604,605,
- 216
- 605 - 605 Waste - 605, 606

Treated With oxidizing With soluble oil 168, 173, Water glass salts - 156
- 53, 216
117, 150, 154,
- 740
- 93, 104,
190,216,249,262,275,813,826,881 Demineralized 150, Distilled 168, 314, 325, 154,
- 28, 31, 34, 38, 40, 46, 51, 93,

168,173, 62,93,95, 271, 283, 190,216,262,271,283 128, 149, 153, 154, 224,233, 311, 324, 333, 845, 853,
- 4, 6, 7, 25, 34, 36, 38, 41, 46, 51, 53,

169, 173, 317,318, 326,327, 663, 192, 216, 218, 223,
59,60,61, 255, 262,
290, 302,305,308, 330,331,332, 808,
319,320,321,322,323, 328,329,
- 881 - 235, 788 Water glycols - 283 Water-oil emulsions - 283 Water-oil separation - 216 Water paints, childrens - 235 Waterproofing salt - 838 Water purification solution - 720 Water softener - 52 Water soluble oil - 235 Water treatment chemicals - 62
Water treatment, Waterworks Waving lotions softening, solvent coagulating
334,335,336,337-354,373,374,378,382, 383, 392, 881,883 Fresh 720, 800, 804,
- 216
primer
- 156 - 15,23,493
(see also Cosmetics)
- 34, 36, 51, 52, 93, 141, 150, 154, 168,

271, 297, 648, 373, 374, 378, 382, 600, 639, 642, 720, 800, 804, 808, 845,
Wax - 93,606,629,663,789,812 Chlorinated Distillate
173, 262, 632, 853,883
- 217 - 156
964
Corrosion
Resistant
Materials
Handbook
Wax (contd) Molten Refined, Wax crayon, Wedac 276, Wemco
141, 173, petroleum pencil
146, 271, 307, 378,
148, 283, 309, 382, 404,
150, 219, 312, 386, 411,
151,
154, 290, 366,
156, 157, 241, 246, 291, 371,
168, 249,
- 64 - 281, 818 - 141, 235
178, 217,
229, 237, 315,
262, 304, 374,
285, 286,
293,301, 372, 373, 393, 721,
- 141 - 15, 24, 25, 156, 161, 195, 217, 235,

281,616,796,845,881 C
387, 388, 607,630,
390, 392, 632, 663,
Weed killers
394, 395, Xylene
728,789,820,838,845,853,881,888,890
- 366,881
- 62
Wesson oil (see Foods) Wet gases from copper smelting
- 217, 607, 721 - 64 Xylidenes - 366, 822, 838, 881

mixtures Xylenol Yeast (see Foods) Yeast wort Yogurt Zeolites Zeric
- 115, 629, 853 Wheat germ oil - 141 Whey - 62,217, 721
Wetting agents White White White acid - 219 caustic copperas
- 727
(see Foods)
- 838 - 838 White iodine - 235

White lead, sublimed lead sulfate
- 836 - 838 White liquor, pulp mill - 31, 44, 46, 51, 59, 94,
White 150, White White White White White White Whiting Wine Fermentation Storage Winery Wintergreen Wire pickling Witch Wolmar salt waste 151, 154, 168, 173, 217, 271,418, 783, 845,853,881,888,890 liquor with oil black liquor 293, 366
- 366, 721, 838, 881 - 283, 820 Zimmite, mud remover - 217 Zinc acetate - 173, 283, 366, 630, 788, 820, 838,
881 Zinc ammonium Zinc borate chloride
- 784, 788, 881
- 418
- 630 Zinc bromide - 232

Zinc carbonate 763 - 94, 146, 232, 439, 607, 662, 721,
- 156, 366 - 64, 94, 119, 141

(see Zinc sulfate)
pine oil - 291, spirit vitriol wax
White water
- 217, 845 - 235

838 (see Calcium carbonate)
- 217 - 51, 168 Zinc chloride - 12, 20, 31, 34, 38, 59, 60, 62, 64,
Zinc casting fumes Zinc chlorate 66,67,94, 146, 173, 262, 147, 271, 392, 607, 778, 106, 151, 283, 373, 393, 608, 728, 784, 108, 152, 219, 374, 394, 630, 732, 109, 154, 222, 378, 395, 632, 110, 115, 155, 232, 303, 382, 397, 646, 156, 237, 306, 383, 647, 755, 119, 141, 157, 158, 246, 249, 309, 386, 311, 388,
- 629,
Wick test, modified
- 423
178, 217,
291, 301,
- 217
314,366, 390, 439, salicylate and 776,
- 217 - 217
oil (see Methyl fumes
398,404,411, 653, 662, 763, 770, 820,838,
721, 727,
735, 740,
Essential oils) hazel distilled
788, 800,
804, 808,
- 217 - 146, 231
845,847,881,883,888,890 Zinc chloride, Zinc chloride Zinc chromate chromated flux
- 721
- 366
(see Methyl alcohol)
- 721
Wood - 629 Wood alcohol Wood fractions Wood oil Wood creosote - 629
Zinc cyanide Zinc Zinc
- 721
293,366,838
- 283,291,
Zinc Zinc Zinc Zinc acid) Zinc
Wood preservatives Wood pulp - 94 Wood tar
- 630
- 838 - 67, 156

sauce
Wood vinegar (see Pyroligneous Wool oil Worcestershire Xenon X-ray Xylene,
- 31, 630, 820 - 31, 94, 156, 784, 881 dihydrogen phosphate - 721 dimethyldithiocarbamate - 217 electrolytic cells - 217 fluoborate - 217 fluosilicate - 608, 662, 721 formaldehyde sulfoxylate - 608 hydrate - 67, 283
- 108, 217, 262, 662, 721, 788,
Zinc hydrosulfite
- 146, 229
845,881 Zinc, molten - 94, 642, 732, 740, 770, 780 Zinc naphthenate
- 366
developer xylol solution - 740, 770 - 2, 9, 11, 18, 26, 31, 34, 38, 39, 46, 51, 53, 59, 60, 64, 66, 94, 111, 112, 113, 115, 119, 121,
- 630
271, 374, 303, 306, 382, 386, 309, 311, 390,404,411, 314,
Zinc nitrate 237, 246, 370, 372,
- 31, 51, 59, 94, 154, 156, 168, 217,

262, 373,
41, 43, 44,45, 103, 106, 108,
630,784,881
Corrosive
Material
Index
965
Zinc oxide
- 20, 64, 119, 141, 232, 283, 630 - 231 Zinc phosphate - 173, 217, 881
Zinc oxide ointment Zinc plating solution Zinc salts (see Plating solutions, zinc)
728, 784,
732, 788,
733,
735,
740, 804,
763, 808,
770, 820,
776, 838,
778, 845,
796, 800,
881,883,888,890 Zinc sulfate fumes Zinc sulfate-sulfuric Zinc sulfite Zinc vitriol Zircex Zircex liquid
- 721
acid
- 150, 367, 853, 881 Zinc smelter fumes - 217

Zinc stearate - 94, 146, 232, 630 Zinc sulfacarbolate Zinc sulfate 108, 156, 388, 404, 109,
- 384, 721
- 217
(see Zinc sulfate)
- 232
119, 141, 219, 151, 152, 222, 232, 396, 397, 662, 154, 237, 398, 721,
solutions
- 722 - 721
- 31, 34, 51, 59, 60, 64, 67, 94, 106,

113, 115, 271 439, 178, 217, 393, 608,
phase hydrochlorination
Zirconium Zirconium Zirconium Zirconium
chloride
168, 173, 390, 392, 411,
- 722 raffinate - 46 - 608

fumes
246, 262,
I 283, 366, 373, 374, 382, 386,

394, 395, 630, 632, 653,
tetrachloride tetrachloride
_ 722

Corrosion Resistant Materials Handbook

Uploaded by

Copyright:

Available Formats

You might also like

Corrosion Resistant Materials Handbook

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Corrosion Resistant Materials Handbook

Uploaded by

Copyright:

Available Formats

CORROSION RESISTANT MATERIALS HANDBOOK

Library of Congress Cataloging Main entry under title: Corrosion

resistant materials handbook.

tained publisher for

the accuracy or completeness of the suitability for

Final determination or product user. any

the use contemplated that anyone of materials himself

publication and that standards. structions

as to such suitability, and health current inthat users seek and

he can meet all applicable safety We strongly recommend manufacturers or suppliers

for handling each material they use.

RESINS ABS Jackets ABS/PVC

............................................. ..................................................... Chemical ................................................

Fiberglass Fiberglass Fiberglass Fiberglass

.33 .34 .35 .37

113 114 116

116 118 120

.......................................... Chemical ........................................

. 152 . 154 . 155

Resins-Ashland. Resins-Du and Bisphenol

..................................... ............. Pont .................................... ........................... Resins-Duriron.

and Polyvinylidene and Polyester Halogenated SAN

and ABS Plastics-Monsanto. Polypropylene Tubing-Barnant

Glass-Reinforced Polymers-Westlake Resins-General

.............................. Resins-Celanese Plastics ................................ Plastics ..........................................

. 218 . 220 .221 . 223 . 225 . 236 . 238

Resins and Metals-Phillips Lined

...................... .................................... ................................ Linings-Watersaver.

and Elastomeric Polymers

. 251 . 263 . 272

........ Ltd ........

Urethane-American Urethane-Devcon. Urethane Various Various Various Various Various

Membrane-Sternson Elastomers-American Elastomers Elastomers Elastomers Rubber

and Rubbers-Du and Rubbers-Exxon and Rubbers-Minor Tank

............ ...... Co. ......

and Elastomeric AND ASPHALT Surfacing

.355 . 367 ..........

MORTARS, Epoxy-Base Epoxy Epoxy Epoxy Furan Furan Mortar Flooring

Compounds-Atlas. and Floor Cements-Sternson.

.......... .......... ..........

Surfacing Grout-Atlas Polymer

and Coating-Sulcon Membrane-Pennwalt. Flooring

Urethane Polyester Various Various Various Various

and Epoxy Cements-Atlas

..................... ............. Mortars-Koch Engineering Mortars-Pennwalt ................... Mortars-Sternson ...................

...... ...... ...... ...... ...... ...... ......

384 387 388 389 391 399 406

......................... Steel. ....................... Ludlum .....................

Ferritic-Austenitic Iron Alloy-Cabot Iron ironAlloys-Cabot

Steel-Cabot Products. Division

and Nickel-Base Steel-Armco Duplex Stainless Stainless Stainless Stainless METALS

Alloys-Stainless Stainless Stainless

Stainless Various Various Various Various Various

Steel Products. Iron and Steel Technology.

and Austenitic Steels-American Steels-Carpenter Steels-Cyclops

Steels and High AND ALLOYS.

433 440 444

Aluminum Aluminum Aluminum Aluminum

....................... ............................ ................ Alloys-Aluminum Association.