1

(Final Examination of Spectroscopic Methods for Chemical Analysis)

Analysis

: 

8/10/2011

  1
(5 )

(hexanol) 1.0%(wt/vol) (percent transmittance, %T)

(infrared)  3360 cm-1 1 mm 50 % molar absorptivity
()    ( 0.81 gcm-3)

 Density



%wt/vol  %wt
%vol Density

  Molar absorptivity ()
  [Hexanol] = 1.0 %( wt/vol), %T = 50%, b = 1 mm = 0.1 cm d = 0.81
gcm-3
 1 M (molar)

10%
Mw

C=
=


.%(
 )





= 9.8 10-2 M
 9.8 10-2 M
 2 Molar absorptivity ()

A = bc = 2 log%T



M-1cm-1
b cm
c M
molL-1


%




%
.
 .

 

= 30.7 M-1cm-1
 Molar absorptivity () 30.7 M-1cm-1
Molar absorptivity () 30.7 M-1cm-1

 2
(5 )

(acetone) 2.5%(vol/vol) (absorbance, A)  1719 cm-1

0.5 1 mm molar absorptivity ()  (
0.79 gcm-3)


 
vol % 
Density

  Molar absorptivity ()
  [Acetone] = 2.5 vol %, A = 0.5, b = 1 mm = 0.1 cm d = 0.79 gcm-3
 1 M (molar)

C=
=

10%d
Mw

 . % .






= 0.34 M
 0.34 M

 2 Molar absorptivity ()

A = bc




.

=
.
 . 
= 14.7 M-1cm-1
 Molar absorptivity () 14.7 M-1cm-1

Molar absorptivity () 14.7 M-1cm-1

 3
( 10 )

(caffeine)   1656 cm-1

infrared  carbonyl 

(M)
0
0.2
0.4
0.6
0.8
1.0

Absorbance at 1656 cm-1

0
0.1
0.2
0.3
0.4
0.5

N
N

N
N
O

(
1.23 gcm-3)

 1 mL  10 mL 
 1656 cm-1 0.8  
A) Molarity (1 )
B) %vol/vol (3 )
C) %wt/vol (3 )
D) ppm (3 )

  Molarity, vol%, %wt/vol ppm

  A = 0.8, d = 1.23 gcm-3 dilution factor = 10
 1  (absorbance)



1 mL 
 10 mL
10

dilution factor

 2 Molarity (1 )

y = 0.5x

y  1656 cm-1
x

0.8 = 0.5 M-1 x

x = 1.6 M
dilution factor
1.6 M 10 = 16 M
 Molarity 16 M
Molarity 16 M

194 g mol-1

 3 vol% (3 )








g=

g=
= 2.624 g

vol% =



 







. 




. 



= 213 vol%
 vol% 16 M
Molarity 213 vol%
 4 %wt vol-1 (3 )
. 

 

%wt vol-1 =


= 262.4 %wt vol-1
 %wt vol-1 262.4 %wt vol-1
%wt vol-1 262.4 %wt vol-1
 5 ppm (3 )

ppm =

(
)
()
. 
 

ppm =



 
= 2.624 106 ppm
 ppm 2.624 106 ppm
ppm 2.624 106 ppm