Curvas isocinticas: x = [k1(T)-v/CoA]/[k1(T)+k2(T)]

T (C)
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0
55.0
60.0
65.0
70.0
75.0
80.0
85.0
90.0
95.0
100.0

k1 (1/min)
0.01531
0.02251
0.03265
0.04675
0.06611
0.09242
0.12778
0.17482
0.23679
0.31767
0.42233
0.55662
0.72755
0.94347
1.21422
1.55139
1.96848
2.48113
3.10743
3.86808
4.78675

Velocidad =

1.000

k2 (1/min)
0.00000
0.00001
0.00002
0.00006
0.00014
0.00033
0.00075
0.00166
0.00360
0.00761
0.01572
0.03176
0.06281
0.12176
0.23152
0.43217
0.79257
1.42910
2.53534
4.42836
7.62002

v (mol/lmin)
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000

x
-64.2912
-43.4017
-29.6059
-20.3665
-14.0956
-9.7851
-6.7861
-4.6758
-3.1749
-2.0976
-1.3187
-0.7536
-0.3447
-0.0531
0.1482
0.2780
0.3508
0.3788
0.3735
0.3457
0.3052

v (mol/l.
1.0
0.9
0.8
0.7

Conversin, x

CoA = 1 mol/l

k1 = 3,11e7 exp( - 5850

k2 = 1,71e18exp(-14900

0.6
0.5
0.4
0.3
0.2
0.1
0.0
0

10

20

30

40

Temper

k1 = 3,11e7 exp( - 5850/T)

k2 = 1,71e18exp(-14900/T)

v (mol/l.min).

10

20

30

40

50

60

Temperatura (C)

70

80

90

100

velocidad
(mol/lmin)
0.9998
0.9996
0.9993
0.9988
0.9979
0.9965
0.9942
0.9906
0.9850
0.9766
0.9641
0.9460
0.9205
0.8857
0.8399
0.7821
0.7129
0.6345
0.5507
0.4662
0.3858

v=0,0021.0 v=0,005
v=0,01
v=0,02
v=0,05
0.8692
0.6733
0.3469
-0.3060
-2.2648
0.9108
0.7776
0.5556
0.1116
-1.2205
0.9
0.9381
0.8463
0.6932
0.3872
-0.5310
0.9560
0.8919
0.7851
0.5715
-0.0695
0.8
0.9677
0.9224
0.8470
0.6960
0.2432
0.9749
0.9426
0.8886
0.7808
0.4574
0.7
0.9786
0.9553
0.9164
0.8386
0.6052
0.9792
0.9622
0.9339
0.8773
0.7073
0.6
0.9767
0.9642
0.9434
0.9018
0.7770
0.9705
0.9612
0.9459
0.9151
0.8229
0.5
v=0
v=0,002
v=0,005
v=0,01
0.9596
0.9527
0.9413
0.9185
0.8500
0.9426
0.9375
0.9290
0.9120
0.8610
0.4
0.9180
0.9142
0.9079
0.8952
0.8573
0.8838
0.8810
0.8763
0.8669
0.8388
0.3
0.8385
0.8364
0.8329
0.8260
0.8053
0.7811
0.7796
0.7771
0.7720
0.7569
0.2
0.7122
0.7111
0.7093
0.7057
0.6948
0.6340
0.6332
0.6320
0.6294
0.6217
0.1
0.5503
0.5498
0.5489
0.5471
0.5418
0.4660
0.4656
0.4650
0.4638
0.4602
0.0
0.385710 30 500.3854
0.3850
0.3842
0.3818
70 90
Conversin, x

T (C) v=0
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0
55.0
60.0
65.0
70.0
75.0
80.0
85.0
90.0
95.0
100.0

0 20 40 60 80 100

Temperatura, C

v=0,02

v=0,05

,005

velocidad
(mol/lmin)
v=0,1
v=0,2
v=0,5
v=1
v=2
-5.5293
-12.0584
-31.6457
-64.2912
-129.5822
-3.4405
-7.8807
-21.2010
-43.4017
-87.8030
-2.0612
-5.1218
-14.3033
-29.6059
-60.2112
-1.1378
-3.2743
-9.6839
-20.3665
-41.7318
-0.5115
-2.0208
-6.5488
-14.0956
-29.1890
-0.0817
-1.1598
-4.3943
-9.7851
-20.5666
0.2161
-0.5619
-2.8960
-6.7861
-14.5664
0.4239
-0.1427
-1.8426
-4.6758
-10.3421
0.5690
0.1530
-1.0950
-3.1749
-7.3349
0.6692
0.3618
-0.5605
-2.0976
-5.1718
v=0,01
v=0,02
v=0,05
v=0,1
v=0,2
v=0,5
v=1
v=2
0.7358
0.5076
-0.1773
-1.3187
-3.6015
0.7761
0.6061
0.0962
-0.7536
-2.4531
0.7940
0.6675
0.2879
-0.3447
-1.6099
0.7918
0.6979
0.4163
-0.0531
-0.9918
0.7707
0.7015
0.4940
0.1482
-0.5435
0.7317
0.6813
0.5301
0.2780
-0.2262
0.6767
0.6405
0.5319
0.3508
-0.0114
0.6089
0.5834
0.5067
0.3788
0.1230
0.5330
0.5152
0.4621
0.3735
0.1963
0.4542
0.4421
0.4060
0.3457
0.2252
0.3778
0.3697
0.3455
0.3052
0.2246

0.00
0.05
0.10
0.15
0.20
0.25
0.30
0.35
0.40
0.45
0.50
0.55
0.60
0.65
0.70
0.75
0.80
0.85
0.90
0.95
1.00

T (C)
k1
54.0
0.5271
55.0
0.5566
56.0
0.5876
57.0
0.6202
58.0
0.6543
59.0
0.6901
60.0
0.7276
61.0
0.7668
62.0
0.8080
63.0
0.8511
64.0
0.8962
65.0
0.9435
66.0
0.9929
67.0
1.0446
68.0
1.0986
69.0
1.1552
70.0
1.2142
71.0 Rgimen
1.2759
isotrmico
72.0
1.3404
73.0
1.4077
74.0
1.4780

isotrmico (T = 62C)
v
CoA/v
0.8080
1.2376
0.7635
1.3098
0.7190
1.3908
0.6745
1.4826
0.6300
1.5873
0.5855
1.7079
0.5410
1.8484
0.4965
2.0141
0.4520
2.2124
0.4075
2.4540
0.3630
2.7548
0.3185
3.1397
0.2740
3.6496
0.2295
4.3573
0.1850
5.4054
0.1405
7.1174
0.0960
10.4167
0.0515
19.4175
0.0070
142.8571
10
-0.0375
-26.6667
-0.0820
-12.1951

k2
0.0276
0.0318
0.0365
0.0418
0.0479
0.0549
0.0628
0.0718
0.0820
0.0937
0.1068
0.1218
0.1387
0.1578
0.1795
0.2039
0.2315
0.2627
(T = 62C).
0.2978
0.3374
0.3820

Rgimen ad

6
CoA/v

0
0.00

0.10

0.20

0.30

0.40
Conversin, x

0.50

0.60

0.70

0.80

0
0.00

0.10

0.20

0.30

adiabtico (To = 54C)

v
CoA/v
0.5271
1.8973
0.5272
1.8968
0.5252
1.9040
0.5209
1.9199
0.5138
1.9461
0.5038
1.9848
0.4904
2.0390
0.4733
2.1128
0.4520
2.2125
0.4260
2.3476
0.3947
2.5336
0.3576
2.7965
0.3140
3.1852
0.2630
3.8019
0.2040
4.9025
0.1359
7.3606
0.0576
17.3534
-0.0319
-31.3553
Rgimen adiabtico (To = 54C).
-0.1340
-7.4626
-0.2502
-3.9974
-0.3820
-2.6178

(min)
0.064
0.068
0.072
0.077
0.082
0.089
0.097
0.106
0.117 R = 1
0.130
0.147
0.170
0.200
0.244
0.313 =
0.438
3.519
2.413
10

0
0.00

(min)
0.095
0.095
0.096
0.097
0.098
0.101
0.104
0.108
0.114
0.122
0.133
0.150
0.175
0.218
0.307
0.618
2.628

CoA/v

0.10

0.20

0.30

0.40
Con versin, x

0.50

0.60

0.70

0.80

Anlisis de estabilidad: reactor de mezcla completa ( = 8,3 min)

Conversin, x =
q (kcal/molA) =

k1
0.0028143
0.0044054
0.0067795
0.0102666
0.0153127
0.0225129
0.0326510
0.0467471
0.0661141
0.0924234
0.1277816
0.1748182
0.2367861
0.3176743
0.4223346
0.5566225
0.7275520
0.9434664
1.2142228
1.5513925
1.9684763
2.4811338
3.1074277
3.8680814
4.7867498

k2
0.00000005
0.00000014
0.00000042
0.00000122
0.00000337
0.00000898
0.00002316
0.00005778
0.00013969
0.00032789
0.00074826
0.00166245
0.00360053
0.00761081
0.01571922
0.03175614
0.06281353
0.12176281
0.23152364
0.43217182
0.79257210
1.42910474
2.53534055
4.42836079
7.62002178

x (1)
0.0228
0.0353
0.0533
0.0785
0.1128
0.1574
0.2132
0.2794
0.3541
0.4334
0.5132
0.5887
0.6562
0.7126
0.7561
0.7852
0.7988
0.7957
0.7753
0.7373
0.6831
0.6156
0.5392
0.4596
0.3821

x (2)
Balance de materia:
Balance de energa:

Balances de materi
1.0

0
0.0952
0.1905
0.2857
0.3810
0.4762
0.5714
0.6667
0.7619
0.8571
0.9524

0.9
x (1)
x (2)

0.8
0.7

Conversin, x

T(C)
-20.0
-15.0
-10.0
-5.0
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0
55.0
60.0
65.0
70.0
75.0
80.0
85.0
90.0
95.0
100.0

0.6
0.5
0.4
0.3
0.2
0.1
0.0
-20

20

Tempera

0.80
26.0

ance de materia: v(x,T) = Cox(1)/t

ance de energa: x(2) = Cp(T-To)/(q/x-Hr)

Balances de materia (1) y energa (2)

x (1)
x (2)

20

40
Temperatura, T(C)

60

80

100