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431 203 Physical metallurgy II

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(Case Hardening)
1.

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;/</'6=>//'()?@A6$BC6.D5E'()F "GA0HBC6F '()
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?@A6$."/(,#,M/;/6/ (Soft and Tough) '().(,< Core
0HBC6F '()/,'>M/#$A0?"(A,T< 5 U( $GA
 $7HTVW7W)6 (Carburizing)
 V/?,O7O6 (Nitriding)
 VW,V/O6 "GA $7 HV/?,O7O6 (Cyaniding or Carbonitriding)
 0HBC6F O,M@.8!V[ (Flam Hardening)
 0HBC6FO@,."/(),/>A6V[[] (Induction Hardening)
U(B'>M"@.O.8!(),/B8!6</F'6.$( $7HTVW7W)6 $GA '>M"@8N
$7HA/'()F.5)%;/ V/?,O7O6 $GA .5)V/ ?.=/'()F </VW,V/O6.5)'-;6$7HA/ B!E
V/ ?.=/'() F  W%) 6 ."E>  "- H ."!C '() ( 8   NU?0 $ 7 H A/?)>  /@ A ,<  "G A .'<  - H 0.2
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(Carburizing) (1)
.8_/U('().<B< B!E$cT'()0OM/U(0HBC6F .5)FBC6O@,U(/(;/,'>M/
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Case Hardening
5 6789::

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431 203 Physical metallurgy II


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Coefficient) B!E$B??<6A68N$7HA/E"<6'()F B!E#,M/;/6/ (CarbonConcentration Gradient) #,"!-6B5<A6$7HA/.@T< $6@6AA.?/V/'7'()E,E.!


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=T8 2 F#,/A (0O) ($7HA/< 0.8 .8A7.WC/?7 (Hyper-Eutectoid
Zone) O-6/-;/ $6@6'()VO@$GA .57!V'7 (Pearlite) '()!@AAHO@, $6<,W(./V??7 (Cementite
Network) H.Nc-OV8($7HA/8EN 0.8 .8A7.WC/?7 O-6/-;/ $6@6'()(.D5E.57!V'7
< /H . N0 O'@ , (W@ ,0 O) ( $7 H A//@ A,<  0.8 .8A7 . WC / ?7 (Hypo-Eutectoid Zone)
$6@68EAHO@,.[A7V'7 (Ferrite) B!E.57!V'7 (Pearlite) O,8NA6.[A7V'7.5)
%;/.G)A5=N $6@6=0!#$.@T<M=!6;/6/ 8N$7HA/=F.@T<#,M/
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Case Hardening
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431 203 Physical metallurgy II


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Case Hardening
5 6789::

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431 203 Physical metallurgy II


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6+ 1 & 03J 
,  I (1)
.  ! 
A0N"#T (F)
(-) 6) 1500
1550
1
0.012
0.015
2
0.017
0.021
3
0.021
0.025
4
0.024
0.029
5
0.027
0.033
6
0.030
0.036
7
0.032
0.039
8
0.034
0.041
9
0.036
0.044
10
0.038
0.046
11
0.040
0.048
12
0.042
0.051
13
0.043
0.053
14
0.045
0.055
15
0.047
0.057
16
0.048
0.059
17
0.050
0.060
18
0.051
0.062
19
0.053
0.064
20
0.054
0.066
21
0.055
0.067
22
0.056
0.069
23
0.058
0.070
24
0.059
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0.018
0.025
0.031
0.035
0.040
0.043
0.047
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0.056
0.059
0.061
0.064
0.066
0.068
0.071
0.073
0.075
0.077
0.079
0.081
0.083
0.085
0.086

1650
0.021
0.030
0.037
0.042
0.047
0.052
0.056
0.060
0.063
0.067
0.070
0.073
0.076
0.079
0.082
0.084
0.087
0.090
0.092
0.094
0.097
0.099
0.101
0.103

1700
0.025
0.035
0.043
0.050
0.056
0.061
0.066
0.071
0.075
0.079
0.083
0.087
0.090
0.094
0.097
0.100
0.103
0.106
0.109
0.112
0.114
0.117
0.120
0.122

1750
0.029
0.041
0.051
0.059
0.066
0.072
0.078
0.083
0.088
0.093
0.097
0.102
0.106
0.110
0.114
0.117
0.121
0.125
0.128
0.131
0.134
0.138
0.141
0.144

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Case Hardening
5 6789::

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431 203 Physical metallurgy II


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Na2CO3
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CaCO3
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Case Hardening
5 6789::

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431 203 Physical metallurgy II


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$7HTVW7'>8i,-HA#,M/.?C=EVO@xW$7HA/A//AW7VWO7 B!@B5<W%A6
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Case Hardening
5 6789::

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431 203 Physical metallurgy II


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2.2. 1M +0&'?5: 7U* (Gas Carburizing) (1)


("!-.5)$7HA/'()FA6;/6/.</.O(,-/-H.5)$7HA/'()FO@,A6BC6
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Case Hardening
5 6789::

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Austenite) '()FT6 '>M"@V<cVO@$BC6F ??@ A6 /A=/(;. 8_/'()'HO(<
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Case Hardening
5 6789::

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Case Hardening
5 6789::

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$.(, (Cr) ./.O(, (V) B!E !HO(/- (Mo) .8_/?@/
$!%FBC6=E'>VO@O('()0O.G)A(U?0AE!T./(,F8EN 1 .8A7.WC/?7 .G)A."!C
'() ( U ?0 A E!T  . /( , F8EN 1 .8A7 . WC / ?7 F<  /'>  V/?,O7 O 6 =E. O 8EAH
AE!T./(,V/?,O7 (AlN) B'A,T<#,M/ $6<,A6 $6@6.[A7V'7'>M"@."!C($
BC6B6
?-A,<6A6."!C'()c'>V/?,O7O6VO@
 ."!C!@'()(U?0F?)> B!E(AE!T./(,F (Aluminum-Containing Low
Alloy Steels)
 ."!C !@  $7 H A/8/!6'() ( U ?0 $.( , F (Medium CarbonChromium Containing Low Alloy Steels) ?-A,<6.</ ."!C!@M/!0< 4100, 4300,
5100, 6100, 8600, 8700 B!E 9800
 ."!C!@>"-H'>B<5576/(O@A/ (Hot-Work Die Steels Containing 5%
Chromium) ?-A,<6.</ HI1, HI2 B!E HI3
 ."!C !@  $7 H A/?)>  '() ( U ?0 $.( , F (Low Carbon-Chromium
Containing Low-Alloy Steels) ?-A,<6.</."!CM/!0< 3300, 8600 B!E 9300
 ."!C !@  V@  /  / O '() ( $6@  65G; / |/.8_ / .[A7 V '7 7 . '/VW?7 B!E
AA.?/V/'7
< )@75'5
(Nitriding Processes)
EH/'()M@'>V/?,O7O6(A,T< 3 /O $GA
 xWV/?,O7O6 (Gas Nitriding)
 A6."! (Salt Bath)
 5!V/?,O7O6 (Plasma or Ion Nitriding)

Case Hardening
5 6789::

10
6"$ 2551

431 203 Physical metallurgy II


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@AO( B!E@A.(,A6EH/'>V/?,O7O6'-;6/O $!@,$!%6-/-H'>$7


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'-;6/(;%;/A,T<-H$!%A6-;/FBC6'()?@A6 A,<6VC?$!%A6-;/FBC6'()VO@=
'>V/?,O7O6=EV<./ 0.5 !!.? 5!V/?,O7O6M@.!-;/'()0O B!E,-6c'>
$EAOF ; / 6/O@ ,50< 6 /F ; / 6/O@ ,A A A/V/?,O7 O6 O,( - 5 '7 '(). ( ,< 
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4.
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(Cyaniding or Carbonitriding) (1)
.5)$BC6FO@,U(/(;.8_/.5)'-;6$7HA/ B!EV/ ?.=/ O,c@?-!6'()M@
.8_ /.!G A"!A."!=E.( ,<  VW,V/O7 O 6 (Cyaniding) "G A?- !6'() . 8_ /x W .( ,< 
$7 HV/?,O7O6 (Carbonitriding) A0N"#T'()M@>"-HVW,V/O7O6 B!E$7 HV/?,O7O6=E
?)><A0N"#T'>$7HTVW7W)6 O,($<A,T<E"<6 760-875C E,E.!'()M@M/-F-
?-!6.5)$7HA/ B!EV/ ?.=/=E-;/ O-6/-;/$!%FBC6'()VO@=%6?G;/ O,A,T<E"<6 0.01
/; B!E 0.03 /; >"-HVW,V/O7O6 B!E$7 HV/?,O7O6?!>O-H
)*7)5'5

A-?</A6V/ ?.=/ B!E$7HA/M/-;/FBC6'().O==0<B<;/6/M/A<6.!GA


VW,V/O7"!A."! =EB8F-/?</FB!EA0N"#TA6A<6"!A."! O,8?8N
A6$7HA/M/-;/FBC6'()F!?O@,VW,V/O7O6=E?)><U($7HTVW7W)6 O,A,T<E"<6 0.5 B!E
0.8 .8A7.WC/?7 B!E8NV/ ?.=/A=.5)VO@=/c%6 0.5 .8A7.WC/?7 O@,."?0/(;=%6'>M"@-;/F=%6
0 HVO@ $BC 6 ??@ A 6c% 6 B@ <8  N$7 H A/=E?)> '-; 6 /(; . 8_ / F!=AE?AA6U?0
V/ ?.=//-)/.A6 c%6B@<!E!,.!GAVW,V/O7'()M@("!"!,</F B?< O,</M":<
B!@</F'()/,M@8EAHO@, 30 .8A7.WC/?7 W.O(,VW,V/O7 (NaCN) 40 .8A7.WC/?7
W.O( ,$7 HA./? (Na2CO3) B!E 30 .8A7 . WC /?7 W.O( ,$!AVO7 (NaCl) < /F/(;( =0 O
"!A."!'() 615C B!E( .c( ,#5O( A,< 6VC?$7HA/ B!EV/ ?.=/=EV< c
.O%;/VO@M/'-/'(=?-!6.!GAVW,V/O7 (NaCN) "!A."! B?<.!GA"!A."!.G)A-F-
-HA'() FH/A<6.!G A"!A."!B!@=EB??- M"@. !GAVW,./? (Sodium Cyanate,
NaNCO) O-6
2NaCN
+
O2
2NaNCO
(1)
4NaNCO
Na2CO3 +
2NaCN +
CO +
2N (2)
8N$7HA/A6-;/FBC6'().OM/A<6.!GAVW,V/O7.5)%;/?$.@@/A6
VW,V/O7M/A<6.!GA"!A."!

Case Hardening
5 6789::

11
6"$ 2551

431 203 Physical metallurgy II


#$%&'() 2/2551

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"',!-,.'$ / !,(0/(

?-A,<6.</ c@'>.5)8N$7HA/ B!EV/ ?.=/'()FM/A<6.!GA"!A."!'()


A0N"#T 845C O,(.!GAVW,V/O78EN 3 .8A7.WC/?7=Ec.5)$7HA/M"@-H."!C'()
T:.(,$7HA/'()F (Decarburized Steels) VO@ M/NE'()A0N"#T.O(,-/ B?<.8!(),/8N
VW,V/O7M/A<6.!GA"!A."!.8_/ 30 .8A7.WC/?7 O,M@.!=0<B<;/6/ 45 /'($7HA/=E
W%.@T<F!% 8EN 0.005 /; O,($.@@/A6$7HA/ 0.65 .8A7.WC/?7 =E."C/VO@<
EH/.5)$7HA/ B!EV/ ?.=/'()FO@,VW,V/O7(8E ,/7>"-H;/</'()M@6/
M/'6'()?@A6-;/FBC6H6l '()F .</ T .[A6.(,7/O.!C .8_/?@/ @A.(,A6
EH/VW,V/O7."GA/-H.5)$7HA/'()FO@,A6."! (Liquid Carburizing)
&'8)@75'5

$7 HV/?,O7 O6 $G A .5) $7 HA/ B!EV/ ?.=/'()F  O,M"@$@ A/- H
;/6/M/#5H,A6xW'()(</FA6$7HA/ B!EV/ ?.=/ O,'()$7HA/ B!E
V/ ?.=/cOTOW%.@T<F;/6/ A,<6VC?(.@M=FO< $7 HV/?,O7O6.8_/
8-H806EH/V/?,O7O6 B'@=6B!@$7 HV/?,O7O6.8_/8-H806EH/
$7HTVW7W)6 H6$-;6c.(,$7 HV/?,O7O6< VW,V/O7BHHB"@6 (Dry Cyaniding) "GA
VW,V/O7BHHM@xW (Gas Cyaniding)
</FA6xW'()/>5$7HA/ B!EV?.=/.@T<F (Carrier Gas) 8EAHO@,A6
FE"<6xW/>5 (Carrier Gas) xWA)?- (Enriching Gas) B!EBA ./(, O,8?xW
/>5=E.8_/xWFA6V/ ?.=/ V O.=/ B!ExW$7HA/A/AW7VWO7 (CO) </xW
A)?-=E.8_/xW 5.5/ "GAxWU?W%)6.8_/B"!<6>./O"!- (Primary Source) >"-H
.5)$7HA/'()F;/6/ </xWBA ./(,=E.8_/B"!<6>./O>"-HV/ ?.=/
8iA6V/ ?.=/M/ $6@6AA.?/V/'7.8_/?-H<6(;$B??<6E"<6$7
HV/?,O7O6 B!E$7HTVW7W)6 !<$GA $6@6AA.?/V/'7'()($7HA/-V/ ?.=/B'?-
A,T< (Carbon-Nitrogen Austenite) (.c(,#5'()A0N"#T?)>< $6@6AA.?/V/'7M/
."!C!@$7HA/UO (Plain Carbon Austenite) B!E=E.O.8!(),/B8!6 $6@6M/
A-?'()@< (Transforms more slowly on Cooling) O@,."?0/(;$7 HV/?,O7O6=%6c
E'>VO@'()A0N"#T?)>< B!Ec8!<A,M"@.,C/?-M/A-?'()@<M/E"<6EH/
0HBC6A6'>$7HTVW7W)6 (Hardening in Normal Carburizing) ./G)A6=EH/$7
HV/?,O7O6E'>'()A0N"#T?)> B!Ec0HBC6M//;>-/ ($7HTVW7W)6 ?@A60HM//;>) =%6
'>M"@;/6/.(),6?<AB?@ B!EHO.H(;,/@A,<$7HTVW7W)6 ./G)A6=V/ ?.=/<,.5)
$cM/0HBC6 (Hardenability) M"@-HU($7 HV/?,O7O6 O-6/-;/U(/(;=%6($cT
B!E."E>"-H."!C!@$7HA/'()?@A6.5)FBC6 M/NE'()U( Gas-Carburizing /,'>
Case Hardening
5 6789::

12
6"$ 2551

431 203 Physical metallurgy II


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."!C'()F</'>$7HTVW7W)6'()F
= U( .5)  $7 H A/ "G A V/ ?.=/'() F  O@  , U( @  6?@ / 3 BHH.8_ / 
.8!(),/B8!6</F'6.$('()F (Changing Surface Chemical Compositions of Steels) B?<
A6U(?<AV8/(;=EV<.8!(),/B8!6</F'6.$(B?<A,<6MO "!- $GA .HG;A6?@/."!C=E
cTM"@$@A/=/A,T<M/<6'() $6@6.8_/AA.?/V/'7 "!-6=/-;/8!<A,M"@.,C/?-A,<6O.C
.5G) A M"@ V O@ $6@  67 . '/VW?7 O- 6 /-; / ."!C '() = E/>   U( 0 H BC 6 F  O@  ,.8!V[ (Flame
Hardening) B!E0HBC6FO@,."/(),/>A6V[[] (Induction Hardening) M@VO@
=E?@A6.8_/."!C'()($cM/0HBC6 !<$GA$(8N$7HA/A,T<E"<6 0.3
c%6 0.6 .8A7.WC/?7
5.

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0HBC6FO@,.8!V[.)=M"@$@A/B<F."!CO@,xWAAWA.W?!(/O-6
BO6M/T8 6 "!-6=M"@$@A/=/;/6/(A0N"#Tc%6<6'().8_/ $6@6AA.?/V/'7B!@
?@A6'>M"@.,C/?-A,<6O.CW%)6A=M@5<//;>V8,-65G;/F;/."!C/-;/ $!%-;/FBC6'()VO@
=E!%<'>$7HTVW7W)6 O,A,T<E"<6 1/8 /; B!E /;

(. 6 
857;:1.3 )] (1)
@AO(A6U(.5)FBC6O@,.8!V[ $GA c@;/6/(/OM":< B!EV<c/>.@
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/;>?A,<6O.C.5G)AM"@VO@ $6@67.'/VW?7 A,<6VC?.5)$BC6'()FO@,U(/(;
=>.8_/A,<6,)6'()=E?@A6AH$!,.$(,O (Stress Relief) <A//>V8M@6/
Case Hardening
5 6789::

13
6"$ 2551

431 203 Physical metallurgy II


#$%&'() 2/2551

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6.


5: 7126+7 ?
)]]` (Induction Hardening) (1, 5)
.G)A.O.8!(),/B8!6A6EBV[[]'()V"!F</O!O."/(),/>C=E.O[!-W7A6
B<."!C (Magnetic Flux) c@/>."!CV8V@M!@l ANH.NA6[!-W7B<."!CC=E'>M"@.O
EBV[[]V"!#,M/."!C'().(,< Eddy Current "GAEBV[[]'()cT."/(),/>M"@.O/(;
.(,< Induction Heating A,<6VC?EBV[[]'()cT."/(),/>M"@.O/(;(B/ /@.O
.D5E'()FA6."!C.'</-;/ O@,."?0/(;=%6.(,8iN7/(;< Skin Effect O-6/-;/$!%-;/F
BC6'()VO@='>M"@;/6/.,C/?-A,<6O.C=EV<!% <6$c()'()M@M/."/(),/>M"@.O
EBV[[]V"!'()FA,T<E"<6 10,000 B!E 500,000 Hz
>!-6V[[] (Power) '()cT."/(),/>M/."!C=E.5)%;/?8N$"/B/</A6
[!-W7 B!E8E'U#5A6$@A/."/(),/> (Induction Heating) =EB8?$c()A6
EBV[[]'()V"!F</O!O A,<6VC?M/'68iH-?V<=>.8_/?@A6M@>!-6V[[] B!E$c()
T6 B?< ?@A65 = N!- &NE B!E/OA6;/6/.5G) A.!G AM@$<> !- 6 V[[]  B!E$c() M "@
."E
?-A,<6A6>!-6V[[] B!E$<$c()'()M@M/EH/?<6l (O-6/(; (5)
Application
Frequency
Power
Melting
50Hz-3 kHz
100 kW-100 MW
Forging and Forming
50Hz-10 kHz
10 kW-5MW
Case Hardening for depth 1-10 kHz
75-1000 kW
over 2.5 mm
Case Hardening for depth 10-100 kHz
10-100 kW
of 1.25-3.0 mm
Case Hardening for depth 100-1000 kHz
1-100 kW
less than 2.0 mm
Crystal
Growing/Zone 1-10 MhZ
2-10 kW
Refining
@AO(A60HBC6FO@,EBV[[]."/(),/> $GA
 ./G)A6=($"/B/</A6>!-6V[[]T6=%6'>M"@.!M/M"@$@A/-H
."!C-;/=%6V<'>M"@./A6."!C ? B!E0O'@,VO@H-?'()O(
 EAO V<(!#E.G)A.8(,H.'(,H-HU(AG)/l .</ $7HTVW7W)6 VW,V/O7O6
 $< M@ =< ,M/E"<  6EH/?)> .G) A .8( ,H.'( ,H=8E 'U # 5 B!E
$0N#56/'()VO@ c%6B@<?@/'0/T6
Case Hardening
5 6789::

14
6"$ 2551

431 203 Physical metallurgy II


#$%&'() 2/2551

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 '()$c()T6 (< 50 kHz) =EM@M/."!C "GA;/6/'()?@A6$!%-;/
FBC6?G;/l (Shallow Case)
 '()$c()?)> (E"<6 3 c%6 50 kHz) >"-H;/6/'()?@A6$!%-;/FBC6
 (Deeper Case)

Case Hardening
5 6789::

15
6"$ 2551

431 203 Physical metallurgy II


#$%&'() 2/2551

1.
2.
3.
4.
5.

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1?9?:
?

S. H. Avner: Introduction to Physical Metallurgy, 2nd Edition, McGraw-Hill Book


Company, ISBN 0-07-085018-6
Material Science and Metallurgy, 4th Edition, Pollack, Prentice-Hall, 1988
?=,7/- c=/O, AH0H."!C, ISBN 974-637-193-2
Knowledge Article from www.Key-to-Steel.com, Nitriding
Sanjay Premi, Induction Heating/Hardening Process, Private Paper, Induction
Services & Engineering Co., Ltd, 700/892 Phase 8, Amata Nakhon Industrial Estate,
Moo , nongkaha, Phanthong, Chonburi, 20160 Thailand

Case Hardening
5 6789::

16
6"$ 2551

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