Professional Documents
Culture Documents
Jadval Tanavobi
Jadval Tanavobi
آﻟﻮﺗﺮوپﻫﺎ:
اﺷﻜﺎل ﮔﻮﻧﺎﮔﻮن)ﭼﻴﻨﺶﻫﺎي ﻣﺨﺘﻠﻒ اﺗﻤﻲ( ﻳﻚ ﻧﻮع ﻋﻨﺼﺮ ﺳﺎده.
ﻣﺜﺎل :آﻟﻮﺗﺮوپﻫﺎي ﻛﺮﺑﻦ؛ اﻟﻤﺎس ،ﮔﺮاﻓﻴﺖbuckeyball ،
آﻟﻮﺗﺮوپﻫﺎي اﻛﺴﻴﮋن؛ )O3 ،O2اوزون(
ﺳﺎﺧﺘﺎر اﺗﻢ:
اﺗﻢ :واﺣﺪ ﺳﺎزﻧﺪهي ﻋﻨﺼﺮ ،ﻛﻮﭼﻜﺘﺮﻳﻦ واﺣﺪ ﻳﻚ ﻋﻨﺼﺮ ﻛﻪ ﻫﻤﭽﻨﺎن ﺧﺼﻮﺻﻴﺎت آﻧﺮا ﺣﻔﻆ
ﻛﺮدهاﺳﺖ.
ﻫﺴﺘﻪ:
(١ﻣﺮﻛﺰ اﺗﻢ
(٢ﺷﺎﻣﻞ ﭘﺮوﺗﻮن)ذرهي ﻣﺜﺒﺖ ﺑﺎ ﻧﻤﺎد (p+و ﻧﻮﺗﺮون)ذرهي ﺧﻨﺜﻲ ﺑﺎ ﻧﻤﺎد(n
(٣ﺷﺎﻣﻞ ﺑﻴﺸﺘﺮ ﺟﺮم اﺗﻢ
اﻟﻜﺘﺮون:
(١ذراﺗﻲ ﻣﻨﻔﻲ)ﺑﺎ ﻧﻤﺎد (e-ﻛﻪ ﻫﺴﺘﻪ را اﺣﺎﻃﻪ ﻛﺮده اﻧﺪ.
(٢اﺷﻐﺎلﻛﻨﻨﺪهي ﺑﻴﺸﺘﺮ ﻓﻀﺎي اﺗﻢ اﺳﺖ اﻣﺎ ﺟﺮﻣﻲ ﺗﻘﺮﻳﺒﹰﺎ ٢٠٠٠ﺑﺎر ﺳﺒﻜﺘﺮ از ﭘﺮوﺗﻮن ﻳﺎ ﻧﻮﺗﺮون دارد.
ﻋﺪد اﺗﻤﻲ):(Z
(١ﺗﻌﺪاد ﭘﺮوﺗﻮنﻫﺎي ﻣﻮﺟﻮد در ﻫﺴﺘﻪ
(٢ﻋﺪد ﺗﻀﻤﻴﻦﻛﻨﻨﺪهي ﻋﻨﺼﺮ ﻛﻪ ﻫﺮ ﻋﻨﺼﺮ را ﺑﻪﻃﻮر ﻳﻜﺘﺎﻳﻲ در ﻣﻴﺎن ﻋﻨﺎﺻﺮ ﻣﻲﺷﻨﺎﺳﺎﻧﺪ.
ﻋﺪد ﺟﺮﻣﻲ) :(Aﻣﺠﻤﻮع ﺗﻌﺪاد ﻧﻮﺗﺮونﻫﺎ و ﭘﺮوﺗﻮنﻫﺎي ﻣﻮﺟﻮد در ﻫﺴﺘﻪ.
اﻳﺰوﺗﻮپﻫﺎ:
ﺑﺮ ﻋﻜﺲ ﻋﺪد اﺗﻤﻲ و ﺗﻌﺪاد اﻟﻜﺘﺮونﻫﺎ ،ﻳﻚ ﻋﻨﺼﺮ ﺧﺎﻟﺺ ﻣﻨﺤﺼﺮًا ﺑﺎ ﺗﻌﺪاد ﻧﻮﺗﺮونﻫﺎﻳﺶ ﻣﺸﺨﺺ
ﻧﻤﻲ ﺷﻮد.
اﻳﺰوﺗﻮپﻫﺎ :اﺗﻢﻫﺎﻳﻲ ﺑﺎ ﻋﺪد اﺗﻤﻲ ﻣﺸﺎﺑﻪ وﻟﻲ اﻋﺪاد ﺟﺮﻣﻲ ﻣﺘﻔﺎوت).ﻛﻪ ﻧﺎﺷﻲ از ﺗﻔﺎوت در ﺗﻌﺪاد
ﻧﻮﺗﺮونﻫﺎﺳﺖ(.
ﻧﻤﺎد اﻳﺰوﺗﻮپ :ﻧﻤﺎد اﻳﺰوﺗﻮپ ﻋﻨﺼﺮ Xﺑﺎ ﻋﺪد ﺟﺮﻣﻲ Aو ﻋﺪد اﺗﻤﻲ zX ، Zاﺳﺖ.
ﻣﺜﺎل :ﺑﻮر 5B ، ١٠اﺳﺖ ،اﻳﻦ اﻳﺰوﺗﻮپ ﺑﻮر A - Z = ١٠-٥=٥ﻧﻮﺗﺮون دارد.
ﺑﻪ ﻋﻨﻮان ﻣﺜﺎل ﻣﺲ) (Cuدو اﻳﺰوﺗﻮپ ﭘﺎﻳﺪار دارد؛ ﻣﺲ ٦٣-ﺑﺎ ﺟﺮم amu ٦٢/٩٣٢٦و ﻓﺮاواﻧﻲ ﻃﺒﻴﻌﻲ
%٦٩/١٧و ﻣﺲ ٦٥-ﺑﺎ ﺟﺮم amu ٦٤/٩٢٧٨و ﻓﺮاواﻧﻲ ﻃﺒﻴﻌﻲ . %٣٠/٨٣ﺟﺮم اﺗﻤﻲ ﻣﻴﺎﻧﮕﻴﻦ از ﻃﺮﻳﻖ
زﻳﺮ ﻣﺤﺎﺳﺒﻪ ﻣﻲ ﺷﻮد؛
٠/٦٩١٧×٦٢/٩٣٢٦+٠/٣٠٨٣×٦٤/٩٢٧٨=٦٣/٥٥
ﺗﻮﺟﻪ ﻛﻨﻴﺪ ﻛﻪ ﺟﻮاب ﻫﻤﺎن ﻋﺪد اﺗﻤﻲاي اﺳﺖ ﻛﻪ روي ﺟﺪول ﺗﻨﺎوﺑﻲ ﻧﻤﺎﻳﺶ داده ﺷﺪه اﺳﺖ.
ﺗﺮﻛﻴﺐﻫﺎ:
ﺗﺮﻛﻴﺐ آﻣﻴﺰهاي ﺷﻴﻤﻴﺎﻳﻲ ﭘﺎﻳﺪاري از ٢ﻳﺎ ﺗﻌﺪاد ﺑﻴﺸﺘﺮي ﻋﻨﺼﺮ اﺳﺖ.
واﺣﺪ ﻓﺮﻣﻮﻟﻲ :ﻧﺎم ﻋﻤﻮﻣﻲ ﻛﻮﭼﻜﺘﺮﻳﻦ واﺣﺪ ﻣﻤﻜﻦ ﻳﻚ ﺗﺮﻛﻴﺐ اﺳﺖ.
ﻳﻚ ﺗﻌﻤﻴﻢ ﺳﺎده:
(١اﮔﺮ ﻳﻜﻲ از اﺗﻤﻬﺎ در واﺣﺪ ﻓﺮﻣﻮﻟﻲ ﺗﺮﻛﻴﺒﻲ ﻳﻮن ﺑﺎﺷﺪ ،در آﻧﺼﻮرت ﺗﺮﻛﻴﺐ ،ﺑﻚ ﺗﺮﻛﻴﺐ ﻳﻮﻧﻲ
اﺳﺖ .در ﺑﺴﻴﺎري ﻣﻮارد اﮔﺮ واﺣﺪ ﻓﺮﻣﻮﻟﻲ ﺷﺎﻣﻞ ﻳﻚ ﻓﻠﺰ ﺑﺎﺷﺪ ﺗﺮﻛﻴﺐ ،ﻳﻮﻧﻲ ﺧﻮاﻫﺪ ﺑﻮد).ﻣﺎﻧﻨﺪ:
Ca(NO3) ,Fe2O3 , NaClو…(
(٢واﺣﺪ ﻓﺮﻣﻮﻟﻲاي ﻛﻪ در آن ﻫﻴﭽﻴﻚ از اﺗﻤﻬﺎ ﻳﻮﻧﻴﺰه ﻧﺸﺪهاﻧﺪ ،ﻣﻮﻟﻜﻮل ﻧﺎﻣﻴﺪه ﻣﻲﺷﻮد وﺗﺮﻛﻴﺐ
ﺑﺪﺳﺖ آﻣﺪه ﺗﺮﻛﻴﺐ ﻣﻮﻟﻜﻮﻟﻲ اﺳﺖ .اﮔﺮ واﺣﺪ ﻓﺮﻣﻮﻟﻲ ﺷﺎﻣﻞ ﻓﻠﺰ ﻧﺒﺎﺷﺪ در آﻧﺼﻮرت ﺗﺮﻛﻴﺐ ،اﻏﻠﺐ
ﻣﻮﻟﻜﻮﻟﻲ اﺳﺖ).ﻣﺎﻧﻨﺪ HCl , N2O , SiF4 ,H2O:و…(
ﻓﺮﻣﻮل ﺷﻴﻤﻴﺎﻳﻲ :ﺗﻌﺪاد ﻫﺮﻧﻮع از اﺗﻤﻬﺎي ﺑﻪﻛﺎر رﻓﺘﻪ در واﺣﺪ ﻓﺮﻣﻮﻟﻲ را ﻣﻲدﻫﺪ.
ﺑﻪ ﻋﻨﻮان ﻣﺜﺎل ،ﻓﺮﻣﻮل ﺷﻴﻤﻴﺎﻳﻲ آب H2Oاﺳﺖ .در آب ﻳﻚ اﺗﻢ اﻛﺴﻴﮋن ﺑﻪ ﻃﻮر ﺷﻴﻤﻴﺎﻳﻲ ﺑﺎ ٢اﺗﻢ
ﻫﻴﺪروژن ﺗﺮﻛﻴﺐ ﺷﺪه اﺳﺖ.
ﻗﺎﻧﻮن ﻧﺴﺒﺖﻫﺎي ﻣﻌﻴﻦ :ﻧﺴﺒﺖ ﺟﺮم ﻫﻤﻪي ﻋﻨﺎﺻﺮ ﻣﻮﺟﻮد در ﻳﻚ ﺗﺮﻛﻴﺐ ﺧﺎص ﻫﻤﻮاره ﺛﺎﺑﺖ اﺳﺖ.
ﻣﺜﺎل :ﺗﺮﻛﻴﺒﻲ ﺷﺎﻣﻞ ١٥/٠ﮔﺮم Brو ١٠/٧ﮔﺮم Fﺷﻨﺎﺳﺎﻳﻲ ﺷﺪه اﺳﺖ.ﭼﻨﺪ ﮔﺮم در ﻣﻘﺪاري از اﻳﻦ
ﺗﺮﻛﻴﺐ ﻛﻪ ﺷﺎﻣﻞ ٣٠/٠ﮔﺮم Brاﺳﺖ ،وﺟﻮد دارد؟
ﭘﺎﺳﺦ:
ﮔﺮم (١٠/٧ / ١٥/٠) = ٣٠/٠ (١٠/٧ / ١٥/٠) = ٢١/٤ﺟﺮم = Brﺟﺮم = ١٠/٧ / ١٥/٠ Fﺟﺮم / Brﺟﺮم) Fاز ﻗﺎﻧﻮن ﻧﺴﺒﺖﻫﺎي ﻣﻌﻴﻦ(
Lanthanides
} Rare Earths
Actinides
2) The vertical columns are called groups (or families). Some groups, as shown above, have special names.
3) The great majority of elements are classified as metals (defining properties: lustrous, malleable, ductile, good
conductor of electricity and thermal energy). The metallic elements lie on the left side of the periodic table.
4) The nonmetal elements lie on the right side of the periodic table. Nonmetal properties are opposite those of metals.
5) The metalloids (or semi-metals) are a thin band of elements that separates the metals and the non-metals on the
periodic table. The properties of metalloids are in-between metals and nonmetals: metalloids often behave
chemically like non-metals, but are lustrous like metals.
6) The group A elements (IA, IIA, IIIA, etc.) are sometimes called collectively the representative or main-group
elements.
Allotropes
Different forms (atom arrangements) of the same pure element
Examples: carbon allotropes – diamond, graphite, buckeyballs; oxygen allotropes – O2 and O3 (ozone)
Composition of the Atom
Atom – building blocks of the elements; the smallest unit of an element that still retains the properties of the element.
Nucleus – 1) the center of the atom 2) contains protons (positive charge, symbol p+) and neutrons (neutral charge,
symbol n) 3) contains most of the atom’s mass
Electrons – 1) negatively-charged particles (symbol e-) that surround the nucleus 2) account for most of the atom’s
size, but are about 2000 times less massive than protons or neutrons
Atomic Number (Z) – 1) the number of protons in the nucleus 2) The element “Social Security number”: uniquely
identifies each element
Mass Number (A) – the sum of neutrons and protons in the nucleus
Ions
cation – 1) a positive ion (formed by losing electrons) 2) the charge of the cation equals the number of electrons lost, e.g.
the Ca2+ ion has 20 protons and 20 – 2 = 18 electrons
anion – 1) a negative ion (formed by gaining electrons) 2) the charge of the anion equals the number of electrons
gained, e.g. the N-3 ion has 7 protons and 7 + 3 = 10 electrons
Isotopes
In contrast to the atomic number and the number of electrons, the number of neutrons in a neutral atom is not uniquely
determined by a particular element, but instead may vary
Isotopes – atoms with the same atomic number but different mass numbers (that is, different numbers of neutrons)
A
Isotope Symbols – For element X with mass number A and atomic number Z, isotope symbol is Z X,
10
Example: boron-10 is 5 B ; this isotope of boron has A – Z = 10 – 5 = 5 neutrons.
By international agreement, an atom of carbon-12 has a mass of exactly 12 atomic mass units (amu).
The atomic masses of the other atoms on the periodic table are tabulated by their time of flight, relative to carbon-12, in a
device called a mass spectrometer. For most all atoms, even carbon, the atomic mass given on the periodic table is not a
whole number. This is because many elements have more than one stable isotope, each with a different mass. The mass
which appears on the table is an average of the masses of the isotopes, weighted by the natural abundance of each isotope.
As an example, consider copper (Cu) which has 2 stable isotopes: copper-63, with mass 62.9326 amu and natural
abundance 69.17% and copper-65, with mass 64.9278 amu and natural abundance 30.83%. The average atomic mass is
then the weighted average, calculated by
(0.6917)(62.9326 amu) + (0.3083)(64.9278 amu) = 63.55 amu
Note that the result is the atomic mass that appears on the periodic table. ☺
Compounds
A compound is a chemical combination of 2 or more elements in fixed proportion
Formula Unit – general term for the smallest possible unit of a compound
A simple generalization: 1) If any of the atoms in the formula unit is an ion, then the compound is an ionic compound.
In many cases, if the formula unit contains a metal, the compound will be ionic
(e.g. NaCl, Fe2O3, Ca(NO3)2, etc.)
2) A formula unit in which none of the atoms is ionized is called a molecule; the
resulting compound is molecular . If the formula unit does not contain a metal, then the
compound is most likely molecular (e.g. H2O, SiF4, N2O, HCl, etc.)
Chemical Formula – gives the number of each kind of atom in the formula unit
For example, the chemical formula for water is H2O – in water, 2 atoms of hydrogen are
chemically combined with 1 atom of oxygen
Law of Definite Proportions – the ratio of masses of each element contained in a pure compound is fixed
Example – A compound is found to contain 15.0 g of Br and 10.7 g of F. What mass of F would be contained in a
sample containing 30.0 g of Br?