10.

5
960







(

(Volhards Method)

(SCN-)
(III)
(FeNH4 (SO4)2.12H2O)

Ag+(aq) +
SCN-(aq)

AgSCN(s)





(SCN-) Ag+
(SCN-) Fe3+
(end point)
37


SCN-(aq)
+ Fe3+(aq)

[FeSCN ]2+(aq)








Fe3+

(KBr)



+

Ag (aq)
+
Br-(aq)

AgBr(S)







(plot)
(KBr)

(AgSCN) (AgBr)

(AgBr) 7.2 (NH4OH) 62
(Na2S2O3.5H2O) 86.8 1


0.017
38



(AgS)

Ag+(aq)+2S2O32-(aq) [Ag(S2O3)2 ]3-(aq)

[Ag(S2O3)2]3-(aq) +e- Ag(s) + 2S2O32-(aq)

100%

(AgBr)
(Na2CO3)



1,200

(Anode)
316 ()
(Cathode)

(Anode) (Cathode)



Ag(a) Ag+(aq)+


Ag+(aq)+ Ag(s)

(cellulose acetate)


(sieve)
100%

Jeffery, G.H., et al. Vogels texboox of quantitive

chemical analysis. 5thed. New York :


Longman Scientific & Technical, 1989. p 353-


354.
. . :


(-), 2542, 137.
. . 8. :


, 2548,


311-313.
__________. .


6. :


, 2543, 99-101.
. . :


, 2547, 12-13.

39