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Chemistry Perfect Score Module Form 4 2011 No Logo
Chemistry Perfect Score Module Form 4 2011 No Logo
Chemistry Perfect Score Module Form 4 2011 No Logo
SET 1
Page 1 / 96
2.
3.
Type of particle
Example
4.
Property
Diagrammatic
representation of
the particles in
each of the
physical states
Arrangement of
particles.
Solid
Liquid
Gas
Forces of
attraction
between particles
Movement of
particles
Energy content
5.
6.
Symbol
Relative mass
Charge
but different
.
7.
8.
14
Page 2 / 96
9.
Isotope
Carbon-14
Uses
Cobalt-60
Sodium-24
PAPER 2 : STRUCTURE
1.
(a)
Diagram 1.1 shows the results of an experiment to investigate the movement of bromine particles in
air.
Air
Gar jar
Cover
Bromine
vapour
Diagram 1.1
Reddish brown
vapour spreads
throughout both
gas jars within 10
minutes
Cover
removed
(i)
(ii)
......
[1 mark]
State the type of particles present in bromine gas.
.....
[1 mark]
(iii)
Explain the observation in this experiment based on the kinetic theory of matter.
....
....
....
[3 marks]
Page 3 / 96
Temperature
83
Diagram 1.2
Time, s
(b)
Diagram 1.2 shows a graph of temperature against time when solid X is heated?
(i)
State the melting point of X.
...
[1 mark]
What happens to the temperature while the substance changes state? Explain.
(ii)
......
......
......
[2 marks]
(iii)
Diagram 2
2.
Diagram 2 shows the set-up of apparatus to investigate the reaction between concentrated hydrochloric acid
and concentrated ammonia solution to form substance X. Based on the information, answer the following
questions.
(a)
(i)
Page 4 / 96
(ii)
Name substance X
.....
[1 mark]
(iii)
(b)
(c)
3.
Table 3 shows proton number and nucleon number for atom W, X and Y.
Atom
Proton number
Nucleon number
11
23
17
35
17
37
Table 3
(a)
(b)
(i)
(ii)
....................................................................................................
[1 mark]
What is the number of neutron in atom W ?
......................................................................................
[1 mark]
Which atoms are isotopes? Explain why.
............................................................................................................................................................
(c)
...........................................................................................................................................................
[2 marks]
Write the electron arrangement of atom X .
.......................... ...................................................................................................................................
[1mark]
Page 5 / 96
(d)
(i)
Draw the electron arrangement of atom Y. In your diagram , show the number of
proton and the number of neutron in the nucleus.
[2 marks]
(ii)
.....................................................................................................................................................
[1 mark]
(iii) Write the formula of ion Y.
.....................................................................................................................................................
[1 mark]
(e)
A
Z
X.
..............................................................................................................................................................
[1 mark]
4.
(a)
Diagram 4.1 shows the set-up of an experiment to determine the melting point of
solid X.
Thermometer
Water
Diagram 4.1
The temperature of X is recorded at 30 seconds intervals as shown below.
Time/second
Temperature/oC
(i)
30
60
90
120
150
180
210
70
77
80
80
80
82
85
95
Plot the graph of temperature against time for the heating of X on the graph
paper.
[3 marks]
Page 6 / 96
Page 7 / 96
(ii)
On the graph that you have drawn in (a), label the melting point of substance X.
[1 mark]
(iii)
(iv)
..................................................................................................................................
[2 marks]
Draw the arrangement of particles in X at 85oC
[ 1 mark ]
(b)
(c)
Why has the solid X in the boiling tube be stirred constantly with the thermometer during the
experiment?
....................................................................................................................
[1 mark]
Why solid X is not directly heated without using water bath?
.......................................................................................................................
[1 mark]
5.
Chemical formula
I2
Cu
C2H5OH
KCl
Table 5
(a)
(b)
.....................................................................................................................
[2 marks]
Which of the following substances has a highest melting point?
(c)
...............................................................................................................................
[1 mark]
State the substance that can conduct electricity in the solid state.
(d)
...............................................................................................................................
[1 mark]
Name the particles present in potassium chloride.
...............................................................................................................................
[1 mark]
Page 8 / 96
PAPER 2 : ESSAY
6.
Diagram 6.1 shows an atom of an element based on the model by James Chadwick.
Electron
Proton
Neutron
Diagram 6.1
(a)
Compare the relative mass and the charge of two of the subatomic particles in diagram 6.1.
[4 marks]
7p
7n
Diagram 6.2
Diagram 6.2 shows an atom of element X.
(b)
(i)
Describe fully the atomic structure shown in diagram 7.2.
[4 marks]
(ii)
A
Z
X
[2 marks]
(c)
Temperature /o C
Melting point
Graph 6.3
to
t1
t2
t3
Time, minutes
Describe the graph in term of states of matter, particles arrangements and changes in energy.
[10 marks]
Page 9 / 96
(a)
(b)
Describe the change of the kinetic energy, arrangement and the forces of attraction between the
particles at the following states:
(i)
(ii)
(iii)
Before condensation
During condensation
After condensation
[10 marks]
(c)
14 n
3+
n neutron
e electron
e
e
e
ee
Diagram 7
[2 marks]
(ii) Y reacts with oxygen to form oxide Y, with the formula Y2O3.
The chemical equation for reaction Y with oxygen is show as:
4Y + 3O2 2Y2O3.
Given that the relative atomic mass of Y = 27 and O = 16.
Calculate the mass of oxide Y, Y2O3 formed when 10.8 g Y is completely burnt in
oxygen.
[4 marks]
PAPER 3 : STRUCTURE
Gas jar
cover
Jelly
Water
Gas jar
Potassium
manganate(VII)
Bromine
vapour
Diagram 8
Page 10 / 96
8.
A group of students set up the apparatus for an experiment as shown in diagram 8. The result is obtained by
the students are shown in table 8.
Experiment
A
B
C
(a)
Observation
After a few minutes the gar jar was filled with a reddish brown gas.
After a few hours, the water turns purple.
After a few days, the jelly turns purple.
(b)
(c)
State
(i)
The manipulated variable.
(ii)
.....................................................................................................................
The responding variable.
.....................................................................................................................
(iii)
(d)
(e)
Based on the observation, arrange the three states of mater in a sequence to show their speed in
increasing order.
..............................................................................................................................
Based on the rate of the movement of the particles, describe the arrangement of the particles in the
three states of matter.
..............................................................................................................................
..............................................................................................................................
..............................................................................................................................
(f)
Give the daily application of the process in one of the above experiment.
..............................................................................................................................
Page 11 / 96
Chloride
Nitrate
Hydroxide
Sulphate
Carbonate
oxide
Magnesium
Lead(II)
Copper (II)
Iron (II)
Iron (III)
Aluminium
2.
(b)
.
Nitric acid reacts with sodium hydroxide
(c)
.
Hydrochloric acid reacts with zinc metal
(d)
.
Copper(II)nitrate reacts with magnesium
(e)
.
Chlorine gas reacts with lithium hydroxide
(f)
.
Hydrogen gas reacts with lead(II) oxide
.
3.
(b)
(c)
(d)
(e)
Page 12 / 96
4.
5.
(b)
(c)
(d)
(e)
(b)
(c)
(d)
(e)
Page 13 / 96
7.
8.
Magnesium powder reacts with hydrochloric acid to produce salt and hydrogen gas.
(a)
Write the balance chemical equation for this reaction.
(b)
.
If 2.4 g of magnesium powder is added into excess hydrochloric acid, calculate,
(i) The mass of salt formed.
9.
PbO
CO2
Pb
(a)
(b)
Determine the number of moles of lead extracted from 0.5 mole of lead (II) oxide.
(c)
(d)
What is the mass of lead are produced if 44.6 g of lead (II) oxide is heated with
excess carbon.
[ RAM : Pb = 207, O = 16, C = 12 ]
Page 14 / 96
10.
Excess sodium carbonates is added into 50 cm3 of 0.5 mol dm-3 copper(II) chloride.
The chemical equation for the reaction is as follows:
CuCl2 +
11.
Na2CO3
NaCl
(a)
(b)
CuCO3
12.
When sodium bicarbonate is heated, it decomposed to sodium carbonate, carbon dioxide and
water.
(a) Write a balanced chemical equation for the decomposition of sodium bicarbonate on heating.
...
(b) If 8.4 g of sodium bicarbonate decomposes, calculate
(i) The volume of carbon dioxide gas evolved at room temperature.
Page 15 / 96
Mass of solute, g
Volume of solution , dm3
Number of mole of solute, mol
Volume of solution , dm3
Titration
Formula
Ma
Va
a
MaV2 = a
MbVb
b
Mb
Vb
b
Dilution
M1V1 = M2V2
13.
100cm3 of HCl 2.0 mol dm-3 reacts completely with excessive zinc powder. Calculate the
volume of gas released at room temperature? (Molar volume = 24 dm3 at room temperature).
14.
5 g of Calcium carbonates dissolves in 100 cm3 of nitric acid 0.5 mol dm-3 to produce salt,
carbon dioxide gas and water.
(i) Write out the equation.
..
(ii) Calculate the moles of calcium carbonates used. (RAM Ca =40, C = 12, O = 16).
Page 16 / 96
15.
16.
10 g of copper(II) oxide reacts completely with 100 cm3 hydrochloric acid to form
copper(II) chloride and water. Calculate the molarity of acid used.
(JAR Cu =64, O = 16 )
17.
(b) What is the molarity of the solution produced when 100 cm3 of distilled water is added to 50 cm3 of
this solution?
18.
In the titration experiment, 25.0 cm3 of 2.0 mol dm-3 sodium hydroxide solution is titrated with sulphuric
acid from a burette. 18.50 cm3 of sulphuric acid is needed for complete neutralization.
(a) Write a balanced chemical equation for the neutralization.
(b) Calculate the number of mole of sodium hydroxide used in this experiment.
(c) Calculate the number of moles of sulfphuric acid needed to exactly neutralize 25.0 cm3 of 2.0 mol dm3
sodium hydroxide.
19.
1.25 mol dm-3 hydrochloric acid reacts completely with 25.0 cm3 of 1.0 mol dm-3 sodium carbonate.
(a) Write a balanced chemical equation for this reaction.
(b) Calculate the number of mole of sodium carbonate used in this experiment.
(c) Calculate the volume of hydrochloric acid needed to exactly neutralize 25.0 cm3 of 1.0 mol dm-3
sodium carbonate.
Page 17 / 96
PAPER 2: STRUCTURE
1.
Diagram 1 shows the set-up of the apparatus for an experiment to determine the
empirical formula of an oxide of copper.
Oxide of copper
Dry hydrogen
gas
Heat
Diagram 1
Table 1 shows the results of an experiment after heating, cooling and weighing are
repeated until a constant weight is obtained.
Substance
Mass of combustion tube + porcelain dish
Mass of combustion tube + porcelain dish + oxide of copper
Mass of combustion tube + porcelain dish + copper
Mass(g)
18.75 g
20.75 g
20.35 g
Table 1
(a)
(b)
[2 marks]
(ii)
(iii)
[2 marks]
.
[1 mark]
(iv) Write the chemical equation for the reaction in this experiment.
...
[1 mark]
Page 18 / 96
(c)
Describe the steps that should be taken to ensure that all the air in the combustion
tube has been expelled , before any heating is carried out.
....
. .
...
[3 marks]
2.
(a)
[1 mark]
(ii) Zinc nitrate, Zn(NO3)2
Given that relative atomic mass of O = 16 , N = 14, Zn = 65 .
[1 mark]
(b)
(ii)
[1 mark]
[1 mark]
(c)
Find the number of moles of atoms in a sample containing 9.03 1020 atoms of
copper.
(d)
(e)
[1 mark]
[1 mark]
2Ag2CO3(s)
4Ag(s) + 2CO2(g) +
Page 19 / 96
O2(g)
A student heats 8.28 g silver carbonate. Calculate the volume of carbon dioxide gas, CO2 collected
at room temperature.
Given that relative atomic mass of C = 12, O =16, Ag = 108,
[3 marks]
3.
Diagram 3 shows 3.1 g of copper (II) carbonate being heated strongly in attest tube. The gas
given out is passed into limewater in a test tube through a delivery tube.
Copper(II)
carbonate
Heat
strongly
Lime water
Diagram 3
(a)
State the observation made when copper(II)carbonate powder is heated until the
reaction is complete.
(b)
[1 mark]
Write the chemical equation to represent the reaction that takes place.
(c)
.
[1 mark]
Calculate the number of moles of copper(II)oxide produced.
[2 marks]
(d)
[2 marks]
(e)
(i)
(ii)
..
[1 mark]
Calculate the mass of the substance produced.
[2 marks]
Page 20 / 96
PAPER 2 : ESSAY
4.
(a)
Carbon 85.70%
Hydrogen 14.30%
(i)
(ii)
(iii)
(b)
Page 21 / 96
PAPER 3 : STRUCTURE
5.
A student carried out an experiment to determine the empirical formula of magnesium oxide.
The steps and set-up of apparatus of the experiment are shown in Diagram 5.
1. The crucible and lid are weighed.
lid
crucible
123.3632g
digital balance
Magnesium
powder
128.1580g
white fumes
heat
4. The crucible, lid and magnesium oxide are weighed when cooled.
magnesium oxide
powder
131.3580g
Diagram 5
Page 22 / 96
(a)
Complete the following table by stating the observations and related inferences in
the experiment.
Observations
Inferences
(i) ................................................
(i) ................................................................
....................................................
....................................................................
(ii) ...............................................
(ii) ...............................................................
....................................................
.....................................................................
(iii) ) ....................................................
(iii)
.................... ...............................................
....................................................
....................................................................
[6 marks]
(b)
Round off the reading to two decimal places and record it in the table below.
Description
Mass / g
(c)
(d)
(i)
(ii)
(iii)
The student wants to determine the empirical formula of lead(II) oxide. He used the steps and set-up
of apparatus as the experiment before. Predict whether the empirical formula of lead(II) oxide can be
determined. Explain your answer.
...............................................................................................................................................................
Page 23 / 96
SET 2
Page 24 / 96
13 14 15 16 17 18
Transition elements
2. 1
2. 8. 1
2. 8. 18. 1
2. 8. 18. 18. 1
2. 8. 18. 32. 18. 1
5. Chemical properties :
Reaction
With water.
Product
Alkali and hydrogen gas
2Li + 2H2O
With oxygen.
4 Li
Alkali
Li2O +
Salt
2Li
Page 25 / 96
Chemical equation
2LiOH + H2
2 Li2O (white)
H2O
2LiOH
Cl2
2 LiCl (white)
O2
2
stable / duplet electron arrangement
2. 8
2. 8. 8
2. 8. 18. 8
octet electron arrangement
2. 8. 18. 18. 8
2. 8. 18. 32. 18. 8
ii)
When going down the group, the melting point and boiling point ...
This is because ..
Group 17 : HALOGEN
F
Cl
Br
I
As
2. 7
2. 8. 7
2. 8. 18. 7
2. 8. 18. 18. 7
2. 8. 18. 32. 18. 7
Page 26 / 96
5.
Chemical properties:
Reaction
With water.
With alkali.
With metal (iron).
Product
acid
salts
salt
Chemical equation
Cl2 + H2O
HCl + HOCl
Cl2 + 2KOH KCl + KOCl + H2O
2Fe + 3Cl2
2FeCl3 (brownish)
6. The Melting Point and Boiling Point increases down Group 17. Why?
Na2O
MgO
Base
Al
Al2O3
Si
Metalloid
SiO2
P2O5
S
Nonmetal
SO2
Cl
Cl2O7
Acidic
Amphoteric
Example
Cu
2+
Page 27 / 96
3+
Ar
PAPER 2 STRUCTURE
1.
Diagram 1 shows part of the Periodic Table of the Elements A, B, C, D, E and F do not represent the actual
symbol of the elements.
A
B
Diagram 1
Using the letters in the Periodic Table of the Elements in Diagram 1, answer the following questions.
(a)
(i)
(ii)
(b)
(ii)
(c)
(ii)
Page 28 / 96
(d)
(i)
(ii)
2.
Diagram 2 shows part of the Periodic Table of the Elements. P, Q, R, S and T do not represent the actual
symbol of the elements.
Group
P
R
Q
T
Period
Diagram 2
(a)
Using the Periodic Table of the Elements in Diagram 2, answer the following
questions.
(i)
(ii)
Page 29 / 96
(c)
(d)
Write the formula for the ion formed from an atom of element T.
....
[1 mark]
(e)
(f)
When a small piece of element R is put into water, ROH solution is formed
and hydrogen gas is released. State one observation when red litmus paper is
put into the water.
...
[1 mark]
(g)
State the common name of the elements between Group 2 and Group 13.
...
3.
A
D
C
E
F
G
Diagram 3
Using the letters in the Periodic Table of the Elements in Diagram 3, answer the following
questions
(a)
element D
...
[1 mark]
Page 30 / 96
(ii)
element B
..
[1 mark]
(b)
(ii)
(c)
(d)
(ii)
Draw the diagram of the electron arrangement for the compound formed
between D and E.
[2 marks]
(iii) State one condition by which the compound in (d) (ii) conducts electricity?
Explain your answer.
...
...
[2 marks]
Page 31 / 96
PAPER 2 ESSAY
4.
Diagram 4.1 and 4.2 show the diagrams of the electron arrangement for atoms of two
elements from Group 17 in the Periodic Table of the Elements.
Diagram 4.1
(a)
Diagram 4.2
Write the electron arrangement for the atom of the element and name the element.
[2 marks]
(ii)
Write a chemical equation for the reaction between this element and sodium hydroxide.
[3 marks]
(b)
Compare the attractive forces between the nuclei and the valence electrons in the atoms in Diagram 4.1
and Diagram 4.2 and relate this to their respectively reactivity.
[6 marks]
(c)
(d)
Diagram 4.3 shows the set up of the apparatus to investigate the reaction of an element from Group 17
with iron metal.
Iron wool
Chlorine
gas
Sodium
hydroxide
solution
Diagram 4.3
Part A
Page 32 / 96
Part B
(i)
State two precautions that must be taken while carrying out the experiment.
[2 marks]
(ii)
Describe and write the chemical equations for the reactions that occur in Part A
and Part B.
[6 marks]
PAPER 3 STRUCTURE
5.
Lithium
))
water
Potassium
))
)))) )
water
sodium
)) )
water
Table 5
(a)
[6 marks]
Page 33 / 96
(b)
(c)
(d) Based on the observations in the figure above, arrange lithium, potassium and sodium
in the descending order of reactivity of metals towards water.
Solution X was produced from the reaction of potassium with water. Classify the ions that exist in
solution X into positive ions and negative ions.
Positive Ions
Negative Ions
[ 3 marks]
PAPER 3 ESSAY
6.
The reactivity of the alkali metals increases as you go down the group
Refering to the statement above, plan an experiment to prove it true by using the reactions of lithium,
sodium and potassium with water.
Your planning must include the following items:
(a)
(b)
(c)
(d)
(e)
Problem statement
All variables involved
List of materials and apparatus
Experimental procedure
Tabulation of data
[17 marks]
Page 34 / 96
CHEMICAL BONDS
FORMATION OF IONS
Cations
Releases 1 electron
Half equation:
Li
Li+ + e
Lithium atom,
Li
Lithium ion,
Li+
2+
Releases 2 electrons
Half equation:
Mg
Mg2+ + 2e
Magnesium
atom, Mg
Magnesium ion,
Mg2+
Anions
Receives 1 electron
Half equation:
F+e
FFluorine atom, F
Oxygen atom, O
Half equation:
O + 2e
O2-
Page 35 / 96
+
+
Sodium atom
Chlorine atom
Sodium
ion
Chloride ion
Explanation:
The electron arrangement of sodium atom is 2.8.1 and chlorine atom is 2.8.7
Half equation: Na
Na+ + e
Chlorine atom receives one electron to form chloride ion, Cl-.
Half equation: Cl + e
ClSodium ion and chloride ion are attracted to one another by strong electrostatic force which called an ionic
bond
Example
X
X
+
Oxygen atom
XX
XX
X
XX
XX
Oxygen molecule, O2
Oxygen atom
Page 36 / 96
XX
Explanation
The electron arrangement of oxygen atom is 2.6
An oxygen atom contribute 2 electron and attain / achieve the octet electron arrangement.
Two oxygen atom share 2 pairs of electron to one another to form a double covalent bond
PAPER 2 : STRUCTURE
1.
Z
Z
Diagram 1
(a)
(b)
(i)
(ii)
.............
Write the electron arrangement of ion X.
(iii)
...
Draw the diagram to show the formation of ion X
(iv)
(v)
..
Explain the formation of ion X.
(i)
(ii)
Page 37 / 96
(iii)
(iv)
..
Draw the diagram to show the formation of ion Y.
(v)
(c)
(vi)
(i)
.
What is the proton number of element Z?
...............................................................................................................................................
(ii)
Atom of element Z has a nucleon number of 35. Calculate the number of neutrons in atom Z.
(iii)
(d)
(ii)
.
Draw the electron arrangement for the compound T.
(iii)
Page 38 / 96
(e)
(ii)
(iii)
Proton Number
11
8
1
Table 2
a) (i)
b)
(ii)
....
Write the electron arrangement for ion A
(iii)
............
Draw the diagram to show the formation of ion A
(iv)
(i)
.
Write the electron arrangement for atom B
.
(ii)
(iii)
.
Write half- equation to show the formation of ion B
Page 39 / 96
c)
d)
(ii)
............
Draw the electron arrangement of the compound formed in (c)(i)
(iii)
(ii)
(iii)
(iv)
.............................................................................................
Draw the electron arrangement of the compound formed in (d)(i)
Q
R
T
U
Diagram 3
Page 40 / 96
(b)
(i)
Atom R:..
(ii)
Ion P:.
(c)
....
(i) What is the formula for ion formed by Q
(ii)
(d)
..................
Write half- equation for (c) (i)
..............
Atoms of P and U can reacted to form a compound.
(i)
Name the type of bond in the compound formed between atom P and U
......
(ii) Draw the electron arrangement for the compound formed.
(e)
4.
Atom V and T can also react to form a compound. Draw the electron arrangement for the compound
formed.
Diagram 4 shows the chemical symbols of element sodium, oxygen, carbon and chlorine.
23
16
Na
11
12
O
8
19
C
6
Diagram 4
Page 41 / 96
F
9
(a)
(b)
(c)
Sodium atom:....
(ii)
Oxide ion: .
(iii)
Carbon atom:........................................................
(iv)
Flouride ion:..................................................
State the period and the Group for Flourine in Periodic Table of element
(i)
Period:.
(ii)
Group:.
Name the type of bond in the compound formed when sodium react with oxygen.
...
(ii)
(d)
Carbon atom and Flourine atom can also react to form a compound. Draw the electron arrangement
for the compound formed.
(e)
Compare one physical property of compound formed (b) and (c). Explain your answer.
..........
..........
..........
Page 42 / 96
PAPER 2 : ESSAY
5
Proton Number
6
11
17
Table 5
(a)
(b)
(i)
(ii)
[2 marks]
[2 marks]
[6 marks]
(c)
(i)
(ii)
[2 marks]
[4 marks]
(d)
The compound in (b) has higher melting point than in (c). Explain why.
[4 marks]
Page 43 / 96
SET 3
Electrochemistry
Page 44 / 96
Electrolysis
1.
Non-electrolyte
Meaning
Example
2.
Define electrolysis:
..
..
3.
Energy change :
Write the half equation to represent the discharge of anion and cation.
Anion
Hydroxide
ion, OH-
Half equation
Cation
Hydrogen ion,
H+
Chloride ion,
Cl-
Sodium ion,
Na+
Bromide ion,
Br-
Iodide ion,
I-
Lead (II)ion,
Pb2+
Copper(II) ion,
Cu2+
Half equation
Aluminium ion,
Al3+
6.
Page 45 / 96
7.
Cation
Anion
K+
F-
Ca2+
Cl-
Zn2+
Ease of discharge
increases
Page 46 / 96
Sodium nitrate
solution, 0.5 mol dm-3
Carbon electrodes
Page 47 / 96
Cathode
Potassium chloride
solution, 0.5 mol dm-3
Carbon electrodes
9.
Page 48 / 96
Cathode
Copper electrode
Iron electrode
Copper(II)nitrate
solution, 0.5 mol dm-3
Anode
Write the formula of all ions
present in the electrolyte.
Write the formula of ion/ions
which is/are attracted to anode
and cathode.
Which is selectively discharged?
Give a reason.
Page 49 / 96
Cathode
Zinc electrode
Copper
electrode
Copper(II)sulphate
solution, 0.5 mol dm-3
11.
Page 50 / 96
Positive terminal
Application of electrolysis
12.
13.
Silver electrode
Iron spoon
(a)
(b)
..
Write the half equation at iron spoon.
(c)
..
State the observation at silver electrode.
..
(d)
(e)
Page 51 / 96
15.
Purification of metal.
(a) Things to be purified must be at ...
(b) The other electrode ...
(c) The electrolyte ..
17.
..
The electrochemical series can be constructed based on;
(a) The potential difference between two metals, in voltaic cell. The higher the voltage value,
the
(b) The ability/ tendency of a metal to displace another metal from its salt solution. A metal
which able to displace metal below it in
the series from its salt solution.
PAPER 2: STRUCTURE
1. Diagram 1 show the apparatus set-up used to electrolyze 0.1 mol dm-3 of sodium chloride solution using
carbon electrodes.
Gas Q
Gas P
0.1 mol dm-3 of sodium
chloride solution
Electrode X
Electrode Y
_
Diagram 1
(a)
Page 52 / 96
(b)
(c)
...
[1 mark]
(i)
Name gas P collected in the test tube.
..
[1 mark]
(ii) State a chemical test to confirm your answer to (c)(i).
..
[1 mark]
(iii) Write a half equation for the reaction that takes place at electrode X.
(d)
(i)
...
[1 mark]
Name gas Q collected in the test tube.
...
[1 mark]
(ii) State a chemical test to confirm your answer to (d)(i).
..
[1 mark]
(iii) Write a half equation for the reaction that takes place at electrode Y.
(e)
..
[1 mark]
What difference will it make if the experiment is repeated by using 2 mol dm-3 of sodium
chloride solution? Explain your answer.
..
..
[2 marks]
2. Diagram 2 shows the apparatus set-up to carry out an electrolysis of aqueous copper(II) sulphate solution.
copper
elecrodes
carbon
electrdes
Experiment I
Experiment II
Diagram 2
(a)
Write the formula of all the ions present in the copper(II) sulphate solution.
..
[1 mark]
Page 53 / 96
(b)
(i)
..
[1 mark]
(ii) Write a half equation for the reaction that takes place at this electrode.
(c)
..
[1 mark]
(i) Name the product produced at the anode in Experiment II.
..
[1 mark]
(ii) Write a half equation for the reaction that takes place at this electrode.
..
[1 mark]
(d) (i)
What happen to the intensity of the blue copper(II) sulphate solution in Experiment
I?
..
[1 mark]
(ii)
(e)
..
[1 mark]
(i) What happen to the intensity of the blue copper(II) sulphate solution in Experiment
II?
..
[1 mark]
(ii) Explain your answer in (e) (i).
..
..
[1 mark]
3.
electrode Y
electrode X
electrolyte
Diagram 3
Page 54 / 96
Two different electrodes are immersed into an electrolyte. The voltage of the cell is recorded. The
experiment is repeated by using different pairs of electrode. Table 3 shows the results obtained. The
metals of which electrodes V, W, X, Y and Z are made of, for divalent ions.
Experiment
Pairs of electrodes
Positive terminal
Negative terminal
Voltage/V
X/Y
0.70
X/Z
1.05
X/W
1.55
Y/V
V
Table 3
0.50
(a)
(b)
...
[1 mark]
State the direction of the flow of electrons in Experiment 1 which used electrodes X and Y.
(c)
(d)
....
[1 mark]
Write half equation for the reaction that takes place at the negative terminal in Experiment 2 which
used electrodes X and Z.
....
[1 mark]
State a hypothesis for the above experiments.
..
[1 mark]
(e) Arrange the metals V, W, X, Y and Z in decreasing order in the Electrochemistry Series.
(f)
....
[1 mark]
A chemical cell is set-up using electrodes Z and V.
(i)
State the negative terminal of the cell.
...
[1 mark]
(ii) Calculate the voltage of the cell.
[1 mark]
(g)
(i)
State the pair of electrodes that will give the highest voltage reading.
..
[1 mark]
(ii) Calculate the voltage of the cell.
[1 mark]
Page 55 / 96
PAPER 2 : ESSAY
4.
(a)
(b)
[2 marks]
Zinc plate
Copper plate
copper electrode
copper(II)
nitrate
Cell X
Cell Y
Diagram 4
Cell X is a chemical cell while cell Y is an electrolytic cell. Compare cell X and cell Y.
[8 marks]
(c) A student wants to purify an impure copper plate by the process of electrolysis. Design an experiment in
the laboratory to purify the impure copper plate.
Your answer should include the following:
the procedure
observation
A student carries out an experiment to study the potential difference between two types of
different metals. The apparatus arrangement used is shown in Diagram 5.
After experiment
Before experiment
zinc plate
Zinc plate
iron plate
copper(II) nitrate
Diagram 5
Page 56 / 96
iron plate
(a)
State the observation and inference involved in the experiment in the table below.
Metal plate
Observation
Inference
Zinc
Iron
(b)
The student repeated the experiment by replacing the iron metal with copper metal,
aluminium metal and magnesium metal.
Table 5 shows the voltage reading obtained from the metal pairs.
Metal pairs
Negative terminal
Positive terminal
Voltage/V
Zinc iron
Zinc
Iron
0.4
Zinc copper
Zinc
Copper
1.1
Zinc almunium
Aluminium
Zinc
0.8
Zinc magnesium
Magnesium
Zinc
1.4
Table 5
Based on the information above, complete the table below.
Type of variables
Action to be taken
___________________________
_________________________________
___________________________
_________________________________
___________________________
_________________________________
[6 marks]
(c)
(d)
If the experiment is repeated by using lead metal to replace iron metal, predict the possible
reading recorded by the voltmeter.
..
Page 57 / 96
6. Diagram 6 shows two set-up apparatus used to electrolyzed 0.001 mol dm-3 hydrochloric acid and
1.0 mol dm-3 hydrochloric acid by using carbon electrodes.
Carbon
electrode
acid
acid
Diagram 6
(a)
(b)
(c) Write the observations at the anode and cathode for both sets of experiment.
Electrolyte
Terminal
Anode
Cathode
(d)
Write half-equation for the discharge of ions at anode for Set 1 and Set 2.
..
.....
Page 58 / 96
(e)
Predict the observation at the anode and cathode when 0.0001 mol dm-3 potassium
nitrate solution is electrolysed.
..
..
PAPER 3 : ESSAY
7.
Concentration of ions used during electrolysis affects the product of electrolysis at the anode.
Using sodium chloride solution, describe an experiment to prove the above statement.
Your answer should include:
(a)
(b)
(c)
(d)
(e)
(f)
Problem statement
Hypothesis
Variables
Materials and apparatus used
Procedure of the experiment
Tabulation of data
You are given the copper strip, lead strip, iron strip, zinc strip, aluminium strip, magnesium strip and
copper(II) sulphate solution.Referring to the statement above, plan a laboratory experiment to construct the
electrochemical series of the potential differences using different pair of metals.
Your explanation should include all the followings:
(a)
(b)
(c )
(d)
(e)
(f)
Page 59 / 96
SET 4
Acids and Base
Salts
Page 60 / 96
HCl
H+ + Cl-
2.
3.
A base is defines as a chemical substance that can neutralise an acid to produce a salt and water.
Example:
CuO + 2HCl CuCl2 + H2O
4.
An alkali is defined as a chemical compound that dissolves in water to produce hydroxide ions, OH-.
Example:
HO
2
KOH
5.
K+ + OH-
6.
7.
8.
9.
10.
Diprotic acid :
...............................
c)
Triprotic acid :
...............................
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11.
Ethanoic acid :
...............................
c)
Carbonic acid :
...............................
d)
Sulphuric acid :
...............................
e)
Product
Salt and hydrogen gas
Example and
Chemical equation
Zn + 2HCl ZnCl2 + H2
PAPER 2 : STRUCTURE
1.
An experiment is carried out in the laboratory to determine the end point of the reaction between 25.0
cm3 of potassium hydroxide solution and 1.0 moldm-3 of sulphuric acid. Phenolphthalein is used in the
titration to detect the end point of the reaction. diagram 1 shows the set-up of apparatus for the titration.
Sulphuric acid
1.0 moldm-3
Diagram 1
Potassium hydroxide +
phenolphthalein
Page 62 / 96
The volume of sulphuric acid added and the change of the colour of potassium hydroxide solution
shown in the Table 1 below.
Volume of sulphuric acid
(cm3)
Colour of potassium
hydroxide solution
4,5
4.6
4.7
4.8
Pink
4.9
5.0
5.1
5.2
5.3
Colourless
Table 1
(a)
Name the chemical reaction between potassium hydroxide solution and sulphuric acid.
..................
[1 mark]
(b)
(c)
[1 mark]
Write the formula of ions which are present in the conical flask when the volume of sulphuric
acid added is:
(i)
4.5 cm3
...................................................................................................................................
(ii)
5.0 cm3
...................................................................................................................................
[2 marks]
(d)
(e)
(f)
[2 marks]
If sulphuric acid is replaced with nitric acid with the same molarity, predict
the volume of nitric acid require to neutralise 25.0 cm3 of the potassium hydroxide solution.
Explain why.
....................................................................................................................................
....................................................................................................................................
[2 marks]
2.
Hydrogen chloride gas is dissolved in two different solvent, producing solutions X and Y.
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Solution Y
Gas bubbles
No changes
II
Electrical conductivity
Deflection of
ammeter reading
No deflection of
ammeter reading
Table 2
a)
(ii)
.....................................................................................................................................
Solution Y
.....................................................................................................................................
[2 marks]
b)
(i)
(ii)
.................................................................................................................................
What is the role of the solvent used to produce the acid in (b)(i)
.................................................................................................................................
.................................................................................................................................
[2 marks]
c)
(i)
(ii)
................................................................................................................................
Describe a chemical test to verify the gas in (c)(i).
.................................................................................................................................
................................................................................................................................
[3 marks]
d)
Solution X can conduct electricity but solution Y cannot. Explain this statement.
..........................................................................................................................................
..........................................................................................................................................
[2 marks]
Page 64 / 96
3.
Table 3, below shows the pH value of four solutions. The solutions are of the same
concentration
Solution
pH
14
Table 3
a)
(i)
.................................................................................................................................
(ii) Write a chemical equation for the reaction of Z in a(i) with sulphuric acid.
.................................................................................................................................
(iii)
b)
c)
(i)
(ii)
[3 marks]
d)
Explain why solution W and Solution and solution X have different pH values.
.....................................................................................................................................
.....................................................................................................................................
[2 marks]
Page 65 / 96
Filter funnel
Methyl benzene
`
Beaker A
Dry hydrogen chloride gas
Filter funnel
Water
Beaker B
4.
Figure above shows the arrangement of apparatus used to prepare hydrogen chloride in methyl
benzene and in water respectively.
a) What is the purpose of using filter funnels in this experiment ?
................................................................................................................................................
[1 mark]
b)
(i)
What is observed when a piece of magnesium ribbon is placed in Beaker A and Beaker B
respectively.
Beaker A : .................................................................................................................
(ii)
Beaker B :.................................................................................................................
State the reason for your answer in b(i)
...................................................................................................................................
.................................................................................................................................
[3 marks]
Page 66 / 96
d) Water is added to the solution in Beaker A and the mixture is then shaken. When sodium carbonate
solution is added, effervesence occurs.
(i)
Name the gas and suggest a suitable test to identify the gas evolved.
(ii)
................................................................................................................................
State the role of water that caused the liberation of the gas.
(iii)
.................................................................................................................................
Write the ionic equation for the reaction involving the liberation of the gas.
..................................................................................................................................
[3 marks]
5.
Diagram 5 shows four test tubes contain dry glacial ethanoic acid, aqueous solution of
dilute hydrochloric acid and aqueous solution of X.
Dry glacial
ethanoic
acid
Blue
litmus
paper
P
Aqueous
solution of
ethanoic acid
0.1 moldm-3
Dilute
hydrochloric
acid
Blue
litmus
paper
Blue
litmus
paper
Q
ethanoic acid,
Aqueous
solution
of X
Diagram 5
a)
(i)
State the colour change of the litmus paper in test tubes Q and R.
................................................................................................................................
(ii)
Write the formula of ion which caused the colour change of the litmus paper.
.....................................................................................................................................
[2 marks]
b)
Is there any changes of colour of the litmus paper in test tube P? Explain why.
..............................................................................................................................................
..............................................................................................................................................
[2 marks]
Page 67 / 96
c)
aqueous solution of
ethanoic acid
0.1 moldm-3
3.0
Table 5
Explain why the pH value of aqueous solution of ethanoic acid is higher than the pH value of
dilute hydrochloric acid.
..............................................................................................................................................
..............................................................................................................................................
..............................................................................................................................................
d)
[2 marks]
Calcium carbonate powder is added into test tube R. Write the chemical equation for the reaction
that takes place.
..................................................................................................................................................
[1 mark]
e)
..................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
...................................................................................................................................................
[3 marks]
Observation:
...................................................................................................................................................
..................................................................................................................................................
[1 mark]
Page 68 / 96
6.
(a)
A student carried out an experiment to study the pH of a few aqueous solutions using pH
The results were tabulated below.
Aqueous
solution
pH
13
20
paper.
Table 6
Which of the solution in the table above could be
(i)
Distilled water
(ii)
.
Vinegar
.
(iii)
Sodium hydroxide
.....
(iv)
Hydrochloric acid
.....
[4 marks]
b)
(i)
An apple contains maleic acid C4H8O5 which is a weak acid, What is meant by
weak acid ?
.
(ii) The pH of 1.0 mol dm-3 maleic acid solution is higher than hydrochloric acid with the same
concentration. Explain why.
.....
.
[2 marks]
c)
(ii)
Page 69 / 96
PAPER 2: ESSAY
7.
(a)
(i)
[1 mark]
Describe how 100cm3 of 2.0 moldm-3 sodium hydroxide solution can be prepared in the
school laboratory,
Your description should include the calculation
Use the information, Relative atomic mass of Na = 23, O =16 , H = 1
[7 marks]
-3
Using the 1.0 mol dm sodium hydroxide solution from (a) above.
Describe how you would determine the unknown concentration of a sample
of hydrochloric acid, HCl using the titration method.
(ii)
(b)
(a)
(b)
The label of a reagent bottle was dirty caused by a chemical substance. The reagent is suspected to
contain dilute hydrochloric acid.
Describe two chemical tests which can be used to identify the chemical
chemical solution is dilute hydrochloric acid.
solution if the
[8 marks]
(c)
Glacial ethanoic acid does not release any gas when it is poured into pieces of calcium carbonate.
However, effervescence occurs when several drops of water are added into the mixture of ethanoic
acid and pieces of calcium carbonate.
Explain the statement.
[ 6 marks]
Page 70 / 96
PAPER 3: STRUCTURE
9.
Diagram 9 shows the results of titration between sulphuric acid and sodium hydroxide solution.
Initial reading
Final reading
Based on the diagram 2, record the final and initial burette readings of the burette.
Final reading
. cm3
Initial reading
. cm3
cm3
[3 marks]
(b)
Construct a table that can be used to record the result of the experiment.
[3 marks]
Page 71 / 96
(c)
(d)
(i)
(ii)
[3 marks]
State the inference of the colour change.
.
[3 marks]
Write the operational definition for the neutralisation.
[3 marks]
(e)
You are given three examples of acids; sulphuric acid, ethanoic acid and hydrochloric acid.
Classify them into monoprotic and diprotic acids.
[3 marks]
(f)
Based on the titration results, calculate the molarity of sodium hydroxide solution used .
Given the chemical equation for the neutralisation is as follow:
2NaOH + H2SO4
Na2SO4 + 2H2O
[3 marks]
10.
A student carried out two experiments to determine the concentration of HX acid solution.
Experiment I
Titration of HX acid solution of unknown concentration with 20cm3 of sodium hydroxide
solution 1.0 mol dm-3 using phenolftalein as indicator.
Experiment II
Titration of similar HX acid solution of difference concentration with 20cm3 of sodium
hydroxide solution 1.0 mol dm-3 using phenolftalein as indicator.
Page 72 / 96
Diagram 10, shows the initial and final burette readings for both experiments.
Experiment 1
20
21
Experiment II
15
25
16
26
(a)
Construct a table to record the initial and final burette readings and the volumes of the acid used
for both experiments.
[ 3 marks]
(b)
Page 73 / 96
(c)
NaOH
NaX
+ H2O
Experiment I
(ii)
Experiment II
[ 3 marks]
(d)
(e)
If HX acid is replaced with sulphuric acid of the same concentration, it is found that
the volume of the sulphuric acid used in the titration is half of the volume of HX acid. Explain
why.
.......
.......
.......
[ 3 marks]
PAPER 3 : ESSAY
11.
Solid sodium hydroxide does not give any effect on dry red litmus paper. On the
other hand, sodium hydroxide solution changes dry red litmus paper to blue.
[17 marks]
Page 74 / 96
SALTS
1.
Solubility of salts.
Type of salt
Sodium, potassium and
ammonium salts
Nitrate salts
Solubility in water
All are soluble.
Sulphate salts
Chloride salts
Carbonate salts
3.
4.
Example / Reactants
Magnesium and hydrochloric
acid
Chemical equation
Mg + 2HCl MgCl2 + H2
Chemical equation:
AgNO3 +
Ionic equation :
Page 75 / 96
5.
Solid
Solution
Sodium,potassium,magnesium, ammonium,
Na+,K+,Mg2+,
Green
Blue
Brown
(b)
Colour of residue
Hot
White
Brown
Page 76 / 96
Cold
(c)
Test
Carbonate,
CO32-
Chloride,
ClSulphate,
SO4 2-
Nitrate,
NO3-
(d)
Cation
Reagent
Observation
Ammonium,
NH4+
Iron (II),
Fe2+
Iron (III),
Fe3+
Lead (II),
Pb2+
Page 77 / 96
PAPER 2: STRUCTURE
Oxide M
Compound J
White
precipitate Q
Reaction I
(Dissolved in
excess sodium
hydroxide
+ NaOH (aq)
solution)
(Brown when
hot, yellow
when cooled)
Heat
Gas L
(Colourless)
Reaction II
Colourless J
solution
White precipitate R
+ H2SO4 (aq)
Diagram 1
1.
b)
c)
d)
Name two cations which produce white precipitates with sodium hydroxide solution that do not
dissolve in excess sodium hydroxide solution.
....
[1 mark]
Page 78 / 96
(e)
Describe a confirmatory test which you can use to differentiate the cations you named
in (d).
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
[4 marks]
2.
An experiment to investigate the effect of heat on solid lead (II) carbonate is shown on diagram 2.
Boiling tube
Heat
Lime water
Diagram 2
(a)
(i)
[2 marks]
(ii)
(iii)
Name the residue formed inside the boiling tube at the end of the experiment
.....
[1 mark]
Page 79 / 96
(b)
Mass (g)
12.45
23.13
22.56
Table 2
(i)
(ii)
(iii)
Calculate the volume of carbon dioxide evolved at room temperature and pressure.
[2 marks]
[2 marks]
[2 marks]
(c)
All the residue is formed during the heating of lead (II) carbonate was dissolved in dilute
nitric acid to form a colourless solution. When excess of sulphuric acid is added to the
colourless solution, a white precipitate is formed.
(i)
Name the white precipitate formed.
(ii)
..
[1 mark]
Write an ionic equation for the reaction.
..
[1 mark]
Page 80 / 96
3.
Diagram 3 shows the formation of zinc nitrate and its conversion to other substances
+ dilute nitric acid
Zinc nitrate
W
nitrate
Nitrogen dioxide +
Gas X
Y + sodium nitrate
R + sodium nitrate
Z + potassium nitrate
Diagram 3
(a)
(b)
W is a white powder which reacts with dilute nitric acid. The powder is yellow in hot.
Give the name of W.
[1 mark]
A small amount of sodium hydroxide solution is added to zinc nitrate solution. Precipitate
Y is produced.
(i)
Write the chemical formula of Y.
(ii)
(c)
(i)
(ii)
..
[1 mark]
Describe what happens when sodium hydroxide is added to zinc nitrate.
..
[1 mark]
Zinc nitrate can be converted to nitrogen dioxide and gas X. How can this
conversion be carried out?
..
[1 mark]
Name gas X
..
[ 1 mark]
(iii)
Page 81 / 96
(d)
When potassium iodide is added to zinc nitrate solution a precipitation takes place.
(i)
Name the substance Z
(ii)
(e)
..
[1 mark]
Write an ionic equation to show how Z is produced.
..
[1 mark]
Write the chemical formula of substance R
..
[1 mark]
PAPER 2: ESSAY
4. (a)
The following are three examples of sulphate salts that can be prepared in the laboratory.
Potassium sulphate
Lead (II) sulphate
Zinc sulphate
(i)
(ii)
State the reactants for the preparation of the insoluble salts in 4 (a) (i).
[2 marks]
(b)
With the aid of a labeled diagram, explain the crystallization method for preparing a soluble
salt from its saturated solution.
[6 marks]
(c)
You are given a solution that contains a mixture of iron (III) nitrate and iron (III) chloride.
Describe the confirmatory test to determine the presence of cation and anion in the solution. Your
description must include all the materials used, observation and conclusion.
[10 marks]
Page 82 / 96
5. (a)
(b)
Table 5 shows the observations from some tests carried out on salt X.
Test
Observation
Table 5
Based on the information in Table 5.
(i)
Identify anion that is present in Test I and describe a chemical test to verify the anion.
[4 marks]
(ii)
Identify two cations that are present in Test II and describe a chemical test to verify the
cations.
[6 marks]
PAPER 3: STRUCTURE
6.
Seven test tubes of the same size are labelled 1 to 7. A fixed volume of 5.0 cm3 of 1.0 moldm-3
potassium chromate (VI) solution is placed in each of the seven test tubes. Varying amounts of 1.0
moldm-3 of a nitrate salt of metal M is added to each test tube. For example, 1 cm3 to test tube 1, 2 cm3 of
test tube 2, and so on until 7 cm3 is added to test tube 7.
The height of the yellow precipitate formed in each test tube are recorded in the table 6.
Test tube
Height of precipitate (cm)
1
1.0
2
2.0
3
3.0
4
4.0
5
5.0
6
5.0
7
5.0
Table 6
(a)
Based on results from table 6 , plot a graph of precipitate heights against volumes of M nitrate
solution added.
Page 83 / 96
(b)
What is the volume of M nitrate solution that reacted completely with 5.0 cm3 of potassium
chromate (VI) solution? Explain your answer.
.
(c)
Calculate the number of moles of potassium chromate (VI) found in the test tube and the number
of moles of M ions that reacted completely with the 5.0 cm3 of potassium chromate (VI) solution.
(d)
(e)
Page 84 / 96
7.
You are told that the two colourless solutions are calcium nitrate and magnesium nitrate. You are
required to label correctly the name of each solution in the containers.
Design an experiment to identify which is calcium nitrate and which is magnesium nitrate solution by
using aqueous of ammonia solution as a reagent.
Your answer should include the following:
(a) Problem statement
(b) Hypothesis
(c) All variables
(d) List of materials and apparatus
(e) Procedure
(f)
Tabulation of data
[17 marks]
Page 85 / 96
SET 5
Manufactured Substances
in Industry
Page 86 / 96
PAPER 2 : SRUCTURE
1
Catalyst chamber
Ammonia gas
Hydrogen gas
Diagram 1
(a)
State the name of the process for the production of ammonia in industry.
(b)
...............................................................................................................................................................
[1 mark]
Write an equation for the process stated in (a)?
(c)
..............................................................................................................................................................
[1 mark]
State the catalyt used in this process?
(d)
...............................................................................................................................................................
[1 mark]
Other than the use of catalyst, state two conditions required for optimum production of ammonia.
(e)
...............................................................................................................................................................
[1 mark]
Ammonia react with sulphuric acid to form a fertilizer.Name the fertilizer.
(f)
...............................................................................................................................................................
[1 mark]
The reaction between ammonia and carbon dioxide produce urea, CO(NH2)2 and water.
(i)
(ii)
(g)
[2 marks]
Aqueous ammonia can be used as a reagent to identify cations. State the observation when aqueous
ammonia is slowly added until excess to a solution containing Cu2+ ion.
................................................................................................................................................................
...............................................................................................................................................................
[2 marks]
Page 87 / 96
2.
Diagram 2 shows a flow chart for the formation of Salt A through Process X and Process Y.
Sulphur
Sulphur dioxide
Process
X
Sulphur trioxide
Nitrogen
Hydrogen
Process
Y
Ammonia
Sulphuric Acid
Salt A
Diagram 2
(a)
Name
(i)
Process X : ....................................................................................................
(ii)
Process Y : ....................................................................................................
[2 marks ]
(b)
(i)
(ii)
(c)
(i)
(ii)
...................................................................................................................................................
[1 mark ]
State the optimum temperature and pressure for Process Y
Temperature:.................................... Pressure:...................................................
[1 mark ]
(d)
(i)
(ii)
Name salt A
.....................................................................................................................................................
[1 mark ]
Write the formula for salt A
.....................................................................................................................................................
[ 1 mark]
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(iii)
[2 mark ]
(e)
Polymer
Starch
Ethene
Chloroethene
Polychloroethene(PVC)
Natural rubber
Table 3
(a)
(b)
................................................................................................................................................................
[ 1 mark ]
Complete Table 2 by writing the correct polymer or monomer for the respective monomer or polymer.
(c)
Draw the structural formula for the polymer formed from the polymerization of ethene.
[4 marks]
[ 1 mark ]
(d)
Diagram 3 shows the structural formula for the polymer polychloroethene or PVC.
H
|
C
|
H
H
|
C
|
Cl
H
|
C
|
H
H
|
C
|
Cl
H
|
C
|
H
Diagram 3
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H
|
C
|
Cl
(i)
[ 1 mark ]
(ii)
(e)
In the system for water supply to homes, PVC pipes are widely used to replace metal pipes.
State one advantage of using PVC pipes compared to using metal pipes in terms of their
chemical properties.
.....................................................................................................................................................
[ 1 mark ]
Classify the polymers in Table 3 into natural polymers and synthetic polymers.
Natural polymer
Synthetic polymer
[ 2 marks ]
PAPER 2 : ESSAY
4.
(a)
Diagram 4 shows the arrangement of atoms in pure copper and an alloy of copper, brass.
Pure copper
brass
Diagram 4
(i)
(ii)
(iii)
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(b)
(i)
Explain why pure aluminium is not suitable for building bodies of planes.
[2 marks]
(ii)
State the alloy suitable for building bodies of planes and give reasons for your answer
[4 marks]
(c)
(i)
(ii) Besides hardness, state three advantages of the alloy pewter to its pure metal.
[ 3 marks]
5.
(a)
(i)
(ii)
(b)
(i)
(ii)
[ 7 marks ]
[ 5 marks ]
(c)
Diagram 5 shows the waste products from a factory which affect the quality
of the environment.
a. amples/uses
b. pollution
Sulphur
dioxide
gas
Factory
actory
Building
Toxic
waste
Diagram 5
Based on diagram 5, describe how the waste products affect the quality of the environment.
Your description should include the following aspects:
Source of pollutants
Process
Effect
[ 8 marks ]
Page 91 / 96
PAPER 3 : STRUCTURE
6.
Diagram 6 shows the set up of apparatus of an experiment to compare hardness of copper and brass. The
steps of carrying out the experiment are as follows.
1 kg
weight
Metre
ruler
Steel
ball
bearing
Copper block
Diagram 6
Table 6 shows the results of the experiment
Experiment
0.5
0.6
0.5
0.3
0.3
0.2
Average
diameter/ cm
Table 6
(a)
Based on Table 6, record the average diameter of dents in the space provided.
[3 marks]
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(b)
Give a statement to describe the operational definition of the hardness based on this
experiment.
.......
(c)
......
[3 marks]
Complete table below.
Name of variables
(i) Manipulated variable:
Action to be taken
(i) The way to manipulate variable:
[6 marks]
(d)
(e)
Page 93 / 96
7.
Concrete and reinforced concrete are two types of composite materials. Diagram 7 shows an
experiment to investigate the strength of concrete and reinforced concrete. The 10kg weight is dropped from
a fixed height.
10 kg weight
concrete
clamp
Diagram 7
(a)
What is concrete?
.
(b)
.....
[3 marks]
What is the material used to reinforce concrete?
Why is this material able to strengthen the concrete?
....
........
....
........
[6 marks]
(c ) State three uses of reinforced concrete.
...
.......
..
[6 marks]
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(e)
(f)
.....
[3 marks]
Based on the experiment above, state
(i)
the manipulated variable.
(ii)
.............
the responding variable.
(iii)
............
the fixed variable.
..........
[3 marks]
What is the operational definition of strength of the composite material in this experiment..
...
...
[3 marks]
(g) A commonly used composite material is photochromic glass which is made by embedding
glass with silver chloride.
(i)
.....................
[3 marks]
(ii) Describe how silver chloride can be prepared in the laboratory.
..................
..................
................
[3 marks]
Page 95 / 96
PAPER 3: ESSAY
Kitchen utensils such as pan, pots, spoons and forks rust easily if they
are made from iron. To overcome the problem of rusting, kitchen
utensils are made from steel.
8.
Referring to the explanation above, plan a laboratory experiment to compare the rusting of iron and steel.
Your experiment should cove the following items:
(a)
(b)
(c)
(d)
(e)
(f)
Statement of problem
Variables
Hypotheses
List of materials and apparatus
Experimental procedure
Tabulation of data
Page 96 / 96