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    IRlecture

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    Kusum Ahlawat
    This document discusses infrared spectroscopy and provides information about molecular vibrations, typical IR spectra, and functional group stretches. It outlines the electromagnetic spectrum and energy of a photon in infrared light. Typical ranges of infrared absorption are given for common functional groups like OH, CH, CC, and CN. Example IR spectra are shown for octane, octene, heptyne, ethanol, butyraldehyde, ethyl acetate, and benzonitrile to illustrate the absorption peaks corresponding to different functional groups.

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    IRlecture

    Uploaded by

    Kusum Ahlawat
    25 views16 pages
    This document discusses infrared spectroscopy and provides information about molecular vibrations, typical IR spectra, and functional group stretches. It outlines the electromagnetic spectrum and energy of a photon in infrared light. Typical ranges of infrared absorption are given for common functional groups like OH, CH, CC, and CN. Example IR spectra are shown for octane, octene, heptyne, ethanol, butyraldehyde, ethyl acetate, and benzonitrile to illustrate the absorption peaks corresponding to different functional groups.

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    This document discusses infrared spectroscopy and provides information about molecular vibrations, typical IR spectra, and functional group stretches. It outlines the electromagnetic spectrum and energy of a photon in infrared light. Typical ranges of infrared absorption are given for common functional groups like OH, CH, CC, and CN. Example IR spectra are shown for octane, octene, heptyne, ethanol, butyraldehyde, ethyl acetate, and benzonitrile to illustrate the absorption peaks corresponding to different functional groups.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as RTF, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as rtf, pdf, or txt
    25 views16 pages

    IRlecture

    Uploaded by

    Kusum Ahlawat
    This document discusses infrared spectroscopy and provides information about molecular vibrations, typical IR spectra, and functional group stretches. It outlines the electromagnetic spectrum and energy of a photon in infrared light. Typical ranges of infrared absorption are given for common functional groups like OH, CH, CC, and CN. Example IR spectra are shown for octane, octene, heptyne, ethanol, butyraldehyde, ethyl acetate, and benzonitrile to illustrate the absorption peaks corresponding to different functional groups.

    Copyright:

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    of 16

    Infrared Spectroscopy

    Electromagnetic Spectrum

    Energy of a photon

    x
    E =

    =
    hc/

    Molecular Vibrations

    IR Spectrometer

    Typical IR Spectra

    1
    6

    Typical Ranges for common functional groups


    wavenumber, cm-1 25002000

    4000

    3500

    3000

    1500

    1000

    500

    Strong O H Broad C H C H

    C C

    C N Strong CO

    Octane IR Spectrum
    C H 2850 - 2960 cm-1

    Octene IR Spectrum
    C H 3020 - 3100 cm
    -1

    Heptyne IR Spectrum
    C H 3300 cm-1 (strong) C C 2100-2260 cm-1

    10

    Ethanol IR Spectrum
    OH 3400-3650
    -1

    cm

    (strong, broad)

    11

    Butyraldehyde IR Spectrum
    C O 1670-1780 cm-1 (strong)

    O H

    12

    Ethyl Acetate IR
    C O 1670-1780 cm-1 (strong)

    O O

    13

    Benzonitrile IR
    C N 2100-2260
    -1

    cm

    14

    Typical Ranges for common functional groups


    wavenumber, cm-1 25002000

    4000

    3500

    3000

    1500

    1000

    500

    Strong O H Broad C H C H

    C C

    C N Strong CO

    15

    Functional Group Stretches


    Infrared Stretching Absorptions Functional Group Wavenumber -1)Range (cm
    2850-2960

    Absorption Strength

    notes

    CH

    medium-strong

    below 3000

    CH CH OH CC CN

    3020-3100 3300 3400-3650 2100-2260

    medium strong broad-strong

    above 3000 above 3000

    medium

    CO

    1680-1750

    strong
    16

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