INTRODUCTION

ISTILAH PENTING
BOLA KOORDINASI BILANGAN KOORDINASI MUATAN KOMPLEKS

Coordination sphere : Metal and ligands bound to it

Coordinated ligands

Solv
L

Central metal atom

+n
L

Solv
L L M L

Solv

L M L

[A -]n

Solv

Solv

L L

Inner coordination sphere Inner coordination sphere counteranion

Ligands
classified according to the number of donor atoms Examples
monodentate = 1 bidentate = 2 tetradentate = 4 hexadentate = 6 polydentate = 2

chelating agents

Monodentate
Examples:
H2O, CN-, NH3, NO2-, SCN-, OH-, X- (halides), CO, O2-

Example Complexes
[Co(NH3)6]3+ [Fe(SCN)6]3-

Bidentate
oxalate ion ethylenediamine

O C O C

O O

2-

CH2 CH2 H2N

*
CH CH CH C CH CH

NH2

ortho-phenanthroline
HC HC

*N
N C C CH C

TETRADENTATE LIGAND
Porphine, an important chelating agent found in nature
N NH N NH

N 2+ N Fe N N

Metalloporphyrin

HEXADENTATE LIGAND
O

EDTA
CH2 CH2 N

*O *O

C C O

CH2 CH2 N CH2 C O O*

CH2 C

O*

EDTA

FG24_014.JPG

Ferrichrome (Involved in Fe transport in bacteria)

Coordination number:
number of donor atoms bonded to the central metal atom or ion in the complex Most common = 4, 6

NOT NUMBER OF LIGAND !!!!!!!

EXAMPLES

molecular formula [Ag(NH3)2]+

Lewis donor coordination Lewis acid base/ligand atom number

[Zn(CN)4]2[Ni(CN)4]2[PtCl6]2[Ni(NH3)6]2+

NH3 CNCNClNH3

Ag+ Zn2+ Ni2+ Pt4+ Ni2+

N C C Cl N

2 4 4 6 6

TENTUKAN BILANGAN KOORDINASINYA !!!!!

Coordination Environment of Fe2+ in Oxymyoglobin and Oxyhemoglobin