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  • Lecture Lever Rule

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    JenYerro
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    This document discusses binary systems and phase diagrams. It explains that two-component systems with one phase have three intensive variables, with two phases have two variables if temperature or pressure is fixed, and with three phases have one curve of triple points. It then discusses lever rule for calculating mass fractions in alloy solid solutions. Simple eutectic systems have one eutectic point, while eutectic systems can have regions of solubility of components in each other.

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    This document discusses binary systems and phase diagrams. It explains that two-component systems with one phase have three intensive variables, with two phases have two variables if temperature or pressure is fixed, and with three phases have one curve of triple points. It then discusses lever rule for calculating mass fractions in alloy solid solutions. Simple eutectic systems have one eutectic point, while eutectic systems can have regions of solubility of components in each other.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    51 views20 pages

    Lecture Lever Rule

    Uploaded by

    JenYerro
    This document discusses binary systems and phase diagrams. It explains that two-component systems with one phase have three intensive variables, with two phases have two variables if temperature or pressure is fixed, and with three phases have one curve of triple points. It then discusses lever rule for calculating mass fractions in alloy solid solutions. Simple eutectic systems have one eutectic point, while eutectic systems can have regions of solubility of components in each other.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
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    Lever Rule_Binary Systems

    Two Component Systems


    c=2: f=c-p+2=4-p 1 phase, f=3: three independent intensive variables P, T and X 2 phases, f=2: if we fix P, we have a graph of T vs. X if we fix T, we have a graph of P vs. X 3 phases, f=1: curve of triple points 4 phases, f=0: invariant point

    Constant P: f=c-p+1

    NOTE:Constant P & T: f=c-p

    Vapor A & B (p=1) f=2

    T
    p=2; f=1

    p=1; f=2

    Pressure 1

    Pressure 2

    Overall composition 1

    Overall composition 2

    Solid solution (Alloys)

    Lever Rule

    CO= 35 % CL= 31.5% C=42.5%

    Mass fractions:

    C CO WL 0.68 C C L W CO C L 0.32 C C L

    Constant P: f=c-p+1

    Simple Eutectic System

    T
    f=1

    f=2

    f=1

    f=0

    Simple Eutectic : Composition 1

    Simple Eutectic : Composition 2

    Eutectic System

    region of solubility of A in B

    region of solubility of A in B

    Eutectic System: Composition 1

    Eutectic System: Composition 2

    Eutectic System: Composition 3

    Eutectic System: Composition 4

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