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14.

The van der Waals equation of state is given as:

P=

RT
a
2
vb v

a) Drive an expression for change of entropy of a van der Waals gas

undergoing a constant temperature process.
b) Write the van der Waals equation of state in the form of virial
equation and show that the Boyles temperature is given by:
TB =

a
Rb

c) Using van der Waals equation prove that at low pressure

1 2a
T

b , plot the family of curve T=f(P)h.

P h C P R T

d) Obtain the inversion temperature in terms of a, b and R.

Hint: for section consider only the highest power of v.
Two un-insulated tanks of equal volume are connected by a valve.
One tank contains a real gas at relatively low pressure and other tank is
evacuated. The valve is open for a long time.
a) is the final pressure is greater than, equal to or less than one half of
initial pressure?
b) Solve the problem for the cases of medium pressure and high
pressure.
15.

16.
For
a

P + 2 (v b ) = RT , a = 3.592, b = 0.04262, P = 1 atm, T = 300 K , R = 0.082054 ,

v

find specific volume.

bm

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