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TABLE 13.4 Characteristic Infrared absorptions ot groups


FREQUENCY
GROUP
RANGE (em-I)
INTENSITYa
A. Alkyl
C- H (stretching)
Isopropyl, -CH(CH
3
)2
and
terl-Butyl, -C(CH
3
h
and
B. Alkenyl
C-H (stretching)
C=C (stretching)
R-CH=CH
z
and
1(ou'-of-p'an:
cis-RCH=CHR C-H bendmgs)
trans-RCH =CHR
C AlkynyJ
==C - H (stretching)
C==C (stretching)
D. Aromatic
Ar-H (stretching)
Aromatic substitution type
(C- H out-of-plane bendings)
Monosubstituted
and
o-Disubstituted
m-Disubstituted
and
p-Disubstituted
E. Alcohols, Phenols, and Carboxylic
Acids
O-H (stretching)
Alcohols, phenols (dilute solutions)
Alcohols, phenols (hydrogen bonded)
Carboxylic acids (hydrogen bonded)
F. Aldehydes, Ketones, Esters, and
Carboxylic Acids
C=O (stretching)
Aldebydes
Ketones
Esters
Carboxylic acids
Amides
G _ Amine.:
N-H
H. Nitriles
C=N
2853-2962 (m-s)
1380-1385 (s)
1365-1370 (s)
1385-1395
(m)
-1365 (5)
3010-3095 (m)
1620- 1680 (v)
985-1000 (s)
905-920 (s)
880-900 (s)
675-730 (s)
960-975 (s)
-3300 (s)
2100-2260 (v)
-3030 (v)
690-710 (very s)
730-770 (very 5)
735-770 (s)
680-725 (s)
750-810 (very s)
800-840 (very s)
3590-3650 (sharp, v)
3200-3550 {broad, s)
2500-3000 (broad, v)

1630-1780 v,
1690-1740 (s)
1680-1750 (s)
1735-1750 (s)
1710-1780 (s)

1630-1690 v i
3300-3500 (m)
2220-2260 (m)
aAbbreviations: s = strong, m = medium, w = weak, v = variable, - = approximately .
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