This table provides characteristic infrared absorption ranges and intensities for various functional groups. It includes the following sections: (A) Alkyl groups such as isopropyl and tert-butyl, (B) Alkenyl groups including vinyl and cis/trans alkenes, (C) Alkynyl groups, (D) Aromatic groups and their substitution patterns, (E) Alcohols, phenols, and carboxylic acids, (F) Carbonyl groups such as aldehydes, ketones, esters, and carboxylic acids, (G) Amine groups, and (H) Nitrile groups. The table acts as a reference for identifying functional groups based on their
This table provides characteristic infrared absorption ranges and intensities for various functional groups. It includes the following sections: (A) Alkyl groups such as isopropyl and tert-butyl, (B) Alkenyl groups including vinyl and cis/trans alkenes, (C) Alkynyl groups, (D) Aromatic groups and their substitution patterns, (E) Alcohols, phenols, and carboxylic acids, (F) Carbonyl groups such as aldehydes, ketones, esters, and carboxylic acids, (G) Amine groups, and (H) Nitrile groups. The table acts as a reference for identifying functional groups based on their
This table provides characteristic infrared absorption ranges and intensities for various functional groups. It includes the following sections: (A) Alkyl groups such as isopropyl and tert-butyl, (B) Alkenyl groups including vinyl and cis/trans alkenes, (C) Alkynyl groups, (D) Aromatic groups and their substitution patterns, (E) Alcohols, phenols, and carboxylic acids, (F) Carbonyl groups such as aldehydes, ketones, esters, and carboxylic acids, (G) Amine groups, and (H) Nitrile groups. The table acts as a reference for identifying functional groups based on their
TABLE 13.4 Characteristic Infrared absorptions ot groups
FREQUENCY GROUP RANGE (em-I) INTENSITYa A. Alkyl C- H (stretching) Isopropyl, -CH(CH 3 )2 and terl-Butyl, -C(CH 3 h and B. Alkenyl C-H (stretching) C=C (stretching) R-CH=CH z and 1(ou'-of-p'an: cis-RCH=CHR C-H bendmgs) trans-RCH =CHR C AlkynyJ ==C - H (stretching) C==C (stretching) D. Aromatic Ar-H (stretching) Aromatic substitution type (C- H out-of-plane bendings) Monosubstituted and o-Disubstituted m-Disubstituted and p-Disubstituted E. Alcohols, Phenols, and Carboxylic Acids O-H (stretching) Alcohols, phenols (dilute solutions) Alcohols, phenols (hydrogen bonded) Carboxylic acids (hydrogen bonded) F. Aldehydes, Ketones, Esters, and Carboxylic Acids C=O (stretching) Aldebydes Ketones Esters Carboxylic acids Amides G _ Amine.: N-H H. Nitriles C=N 2853-2962 (m-s) 1380-1385 (s) 1365-1370 (s) 1385-1395 (m) -1365 (5) 3010-3095 (m) 1620- 1680 (v) 985-1000 (s) 905-920 (s) 880-900 (s) 675-730 (s) 960-975 (s) -3300 (s) 2100-2260 (v) -3030 (v) 690-710 (very s) 730-770 (very 5) 735-770 (s) 680-725 (s) 750-810 (very s) 800-840 (very s) 3590-3650 (sharp, v) 3200-3550 {broad, s) 2500-3000 (broad, v)
1630-1780 v, 1690-1740 (s) 1680-1750 (s) 1735-1750 (s) 1710-1780 (s)
1630-1690 v i 3300-3500 (m) 2220-2260 (m) aAbbreviations: s = strong, m = medium, w = weak, v = variable, - = approximately . --'--- " .. .