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SCH4UEnergyChangesandRatesofReactionsMoreTestReview

1. a)Statethreefactorsthatwillaffecttherateofachemicalreaction.(2marksK/U)
b)Usethecollisiontheorytoexplainwhyoneoftheabovefactorsaffectstherateofareaction.

2. Achemistusesacoffeecupcalorimetertocompletelyneutralize75.0mLof6.67mol/LHClwith75mLof6.67
mol/NaOH.Thetemperaturechangeoftheresultingsolutionis+39.6C.Calculatetheheatofneutralization,in
kJ/molofHCl.

3. Usestandardheatsofformationtodeterminetheheatofcombustionpermoleofethanolforthefollowing
reaction.

2C2H5OH(l)+3O2(g)6H2O(l)+ 4CO2(g)

4.a)Writetheequationfortheformationofethyne(acetylene)gasfromitselementsintheirmoststandard
states.
b)Usingthefollowingthermochemicalequations,calculatetheenthalpychangefortheformationofethyne
gas:
(1)C(s)+O2(g)CO2(g)H=393.5kJ
(2)H2(g)+O2(g)H2O(l)H=285.8kJ
(3)2C2H2(g)+5O2(g)4CO2(g)+2H2O(l)H=2598.8kJ

5. Ammoniumnitrateisusedinacoldpack.
NH4NO3(s)NH4+(aq)+NO3-(aq)H=+26.2kJ/molNH4NO3

30.0gofammoniumnitrateisusedinacoldpackthatcontains100.0mLofwater.Iftheinitialtemperatureof
thewateris22.0C,whatisthefinaltemperatureofthewaterwhenthecoldpackisactivated?

6.Drawanenergyprofilediagram(Energyvs.ReactionPathway)fortheoxidationofNiSasgiveninthe
followingequation:

2NiS+3O2(g)2NiO+2SO2+936kJ(EA=220kJ)

Completelylabelyourdiagram,includingpositionsofthereactantsandproducts,theenthalpy
ofthereactionandtheactivationenergy,aswellasenthalpyofthereversereaction.

7. a)ManyhomesinCanadausenaturalgas(methane,CH4)asfurnacefuelandpropane(C3H8)asBBQfuel.If
theenthalpyofcombustionofmethaneis8.90x102kJ/molandtheenthalpyofcombustionofpropaneis
2.22x103kJ/mol,determinethemassofmethanethatmustbecombustedinordertogivethesameamountof
energyasthecombustionof1.0kgofpropane.

b)Assumethatthecombustionoftheabovefuelsoccursinexcessoxygengas.Discussthebyproductsformed
inthisreactionandanyimpacttheymayhaveontheenvironment.Aswell,discussonealternativesourceof
energyandstatewhetheryouwouldrecommenditovertheuseofhydrocarbonsmentionedabove.

8. Apieceofmetalofmass20.0gat100Cisplacedinacalorimetercontaining50.7gofwaterat22C.Thefinal
temperatureofthemixtureis25.7C.Whatisthespecificheatcapacityofthemetal?(2marksBONUS)

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