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4541 Chemistry Mac 2010 1 hours JABATAN PELAJARAN MELAKA ____________________________________________________________ UJIAN SELARAS 1 SIJIL PELAJARAN MALAYSIA 2010

CHEMISTRY One hour and fifteen minutes

DO NOT OPEN THE QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO 1. This paper consists of two sections. 2. Answer all questions. A 3. The diagrams in the questions are not drawn to scale unless stated. 4. You may use a non-programmable scientific calculator. 1 B 2 Total marks 1 - 30 For Examiners use only Section No. Marks

This paper consists of 21 printed pages

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SECTION A 1 Which one of the following processes most clearly suggests that matter is made up of particles in continuous motion?
Pernyataan yang manakah mencadangkan dengan jelas bahawa jirim terdiri daripada zarahzarah yang sentiasa bergerak?

A B C D 2

Combustion
Pembakaran

Diffusion
Resapan

Condensation Kondensasi Neutralisation

Peneutralan

Diagram 2.1 shows the change of the state of matter. Rajah 2.1 menunjukkan perubahan keadaan jirim.

Process Q Proses Q Diagram 2.1 Rajah 2.1 Which of the following is process Q? Antara berikut, yang manakah proses Q? A B C D Boiling Pendidihan Sublimation Pemejalwapan Freezing Pembekuan Melting Peleburan [Lihat sebelah SULIT]

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Which of the following is a molecule? Yang manakah antara berikut adalah molekul? A Neon Neon. B Ammonia Ammonia. C Sodium chloride Natrium klorida. D Potassium hexacyanoferate(III) Kalium heksasianoferat(III) The diagram shows the atomic symbol of element X Rajah menunjukkan simbol atom bagi unsur X
1 9 9

Which of the following represents 9? Antara berikut, apakah yang diwakili oleh angka 9? A B C D Proton number nombor proton Nucleon number nombor nukleon Number of neutrons bilangan neutron Number of electrons bilangan elektron

Which of the following chemical formulae is correct? Antara berikut, yang manakah formula kimia yang betul? A B C D Cu2Cl AlCl3 NaO2 BaOH [Lihat sebelah SULIT]

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The following is chemical equation for a reaction. Berikut ialah persamaan kimia bagi satu tindak balas. CaCO3 + 2HNO3 Ca(NO3)2 + H2O + CO2

Which of the following are reactants? Antara berikut, yang manakah bahan tindak balas? A B C D 7 H2O and CO2 HNO3 and CO2 CaCO3 and HNO3 Ca(NO3)2, H2O and CO2

Which of the following chemical equation is balanced? Yang manakah antara berikut persamaan kimia seimbang? A B C D 2NH4Cl + Ca(OH)2 CaCl2 + 2NH3 + H2O 2Cu(NO3)2 he at 2CuO + 4NO2 + O2 KI + Pb(NO3)2 PbI2 + KNO3 CuCO3 + HNO3 Cu(NO3)2 + CO2 + H2O

What can be deduced from the symbol 13 Al? Apakah yang dapat disimpulkan dari symbol Al? I II II IV A B C D

2 7

2 7 1 3

The electron arrangement of aluminium atom is 2.8.3 Susunan elektron bagi atom aluminium ialah 2.8.3. Aluminium atom has 13 protons and 27 neutrons. Atom aluminium mempunyai 13 proton dan 27 neutron. Aluminium atom has a proton number of 27 and 14 neutrons. Atom aluminium mempunyai nombor proton 27dan 14 neutron. The total number of proton and neutron of aluminium atom is 27. Jumlah bilangan proton dan neutron atom aluminium ialah 27. I and III II and IV II and III I and IV

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Which of the following statements is true for one mole of a substance? Antara pernyataan berikut yang manakah benar tentang satu mol suatu bahan? A B C D 1 mol of hydrogen gas contains 6.02 1023 atoms 1 mol gas hidrogen mengandungi 6.02 x 1023 atom 1mol of magnesium contains 6.02 1023 molecules 1mol magnesium mengandungi 6.02 1023 molekul 1 mol sodium chloride solution accupies 22.4 dm3 at s.t.p 1 mol larutan natrium klorida mengandungi isipadu 22.4 dm3 pada s.t.p 1 mol of water contains the same number of molecules as the number of atoms in 12 g karbon-12. 1 mol air mengandungi bilangan molekul yang sama dengan bilangan atom dalam 12 g karbon-12.

10

Diagram 10.1 shows the set up of apparatus to determine the empirical formula of a metal oxide. Rajah 10.1 menunjukkan susunan radas untuk menentukan formula empirik oksida logam.

Diagram 10.1 Rajah 10.1 Which of the following metals is most suitable to be used in the diagram? Logam yang manakah yang paling sesuai digunakan dalam rajah itu?
A B C D

Lead Silver Copper Magnesium

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SULIT 4541/1 6 11 If the formula for sulphate salt of M is MSO4, what is the formula for nitrate salt of M?
Jika formula garam sulfat bagi M adalah MSO4 , apakah formula garam nitrat bagi M?

A B

MNO3 M(NO3)2 M2NO3

C M(NO3)3 D 12 Which of the following chemist arranged the elements in the Periodic Table of Elements in order of increasing proton number Antara ahli kimia berikut, siapakah yang menyusun unsur-unsur di dalam Jadual Berkala Unsur mengikut susunan bilangan proton yang menaik A B C D Moseley Mendeleev Dobereiner Lothar Meyer

13

Diagram 13.1 shows a Periodic Table.

Rajah 13.1 menunjukkan Jabual Berkala

X Diagram 13.1
Rajah 13.1

What is the special characteristic for element X ?

Apakah ciri istimewa bagi unsur X ?

A B C D

Forms coloured compounds

Membentuk sebatian berwarna

Reacts vigorously with water

Bertindak balas cergas di dalam air

Not chemically reactive

Tidak reaktif secara kima

It is a semi metal
Bersifat separuh logam

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SULIT 4541/1 7 14 Table 14.1 shows the elements in Period 3 of the Periodic Table of elements. The elements can react with oxygen to form oxides. Jadual 2 menunjukkan unsur-unsur Kala 3 dalam Jadual Berkala Unsur. Unsurunsur tersebut bertindak balas dengan oksigen membentuk oksida. Element Unsur Na Mg Al Si P S Cl

TABLE 14.1 JADUAL 14.1 Which of the following element form oxide that can react with both hydrochloric acid and sodium hydroxide solution? Antara berikut unsur manakah membentuk oksida yang boleh bertindak balas dengan asid hidroklorik dan juga larutan natrium hidroksida? A B C D S P Si Al

1 Which noble gases given below is used to fill airships and weather balloons ? 5 Manakah antara gas adi berikut digunakan untuk mengisi kapal udara dan belon kaji cuaca? A B C D Helium Neon Argon Xenon

16 Which statement about chemical bonds is true? Pernyataan yang manakah benar mengenai ikatan kimia? A A covalent bond is formed when metal atoms share electrons to achieve a stable electron arrangement Ikatan kovalen terbentuk apabila atom logam berkongsi elektron untuk mencapai susunan elektron yang stabil A metal reacts with a non-metal to form particles which are bonded together by inter-molecular forces Satu logam bertndak balas dengan satu bukan logam untuk membentuk zarah yang diikat bersama oleh daya tarikan antara molekul An ionic bond is formed when a metal atom transfers electron to a non-metal atom Satu ikatan ionik terbentuk apabila satu atom logam memindahkan satu elektron kepada satu atom bukan logam. Covalent bonds are stronger than ionic bonds Ikatan kovalen adalah lebih kuat daripada ikatan ionik. [Lihat sebelah SULIT]

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17

Diagram 17.1 shows the electron arrangements of atom X and atom Y. Rajah 17.1 menunjukkan susunan elektron bagi atom X dan atom Y .

Diagram 17 Rajah 17 Which one of the following shows the electron arrangement of the compound formed from these two elements? Di antara berikut yang manakah menunjukkan susunan electron bagi sebatian yang terbentuk daripada unsur-unsur ini?

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Which of the following comparison is correct about ionic compounds and covalent compounds? Antara perbandingan berikut, yang manakah betul mengenai sebatian ionik dan sebatian kovalen?

19.

The proton number of magnesium is 12. When magnesium reacts to form an ionic compound, the electron arrangement of the magnesium ion formed is
Nombor atom bagi magnesium ialah 12. Apabila magnesium bertindakbalas membentuk sebatian ion, susunan elektron bagi ion magnesium ialah

A B 20

2. 8 2. 8. 1

C D

2. 8. 2 2. 8. 3

The diagram below shows the apparatus used to test the electrical conductivity of four subtances. Gambarajah di bawah menunjukkan radas yang digunakan untuk menguji kekonduksian elektrik bagi empat bahan.
Battery Bateri

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Bulb lights up Mentol menyala

Substance Y Bahan Y

What is substance Y? Apakah bahan Y? A Molten naphthalene Leburan naftalena B Molten lead(II) bromide Leburan plumbum(II) klorida C Glacial ethanoic acid Asid etanoik glasial D 1,1,1-trichloroethane 1,1,1- trikloroetana

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Diagram 21.1 shows the electrolysis of 1.0 mol dm-3 potassium iodide solution. Rajah 21.1 menunjukkan elektrolisis bagi larutan kalium iodida 1.0 mol dm-3.

Carbon electrode X Elektrod karbon X

Carbon electrode Y Elektrod karbon Y

1.0 mol dm-3 potassium iodide

solution

1.0 mol dm-3 larutan kalium

iodida Diagram 21.1 Rajah 21.1

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Which of the following are the products formed at the carbon electrodes X and Y? Antara berikut yang manakah hasil yang terbentuk pada elektrod karbon X dan Y? Carbon electrode X Elektrod karbon X Oxygen Oksigen Iodine Iodin Hydrogen Hidrogen Iodine Iodin Carbon electrode Y Elektrod karbon Y Hydrogen Hidrogen Hydrogen Hidrogen Oxygen Oksigen Potassium Kalium

A B C D

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The ions present in aqueous copper(II) chloride solution are Ion-ion yang hadir dalam larutan akueus kuprum (II) klorida ialah A B C D Cu2+ and ClCu2+, Cl-, H+ and O2Cu2+, Cl-, H+ and OHCu2+, Cl-, H3O+ and O2-

23

Impure silver can be purified by using electrolysis. Which of the following pair of electrodes is correct? Argentum tak tulen boleh ditulenkan dengan menggunakan elektrolisis. Pasangan elektrod manakah adalah betul? Anode
Anod

Cathode
Katod

A B C 4541

Carbon Karbon Carbon Karbon Pure silver Argentum tulen

Pure carbon Karbon tulen Carbon Karbon tak tulen Impure silver Argentum tak tulen [Lihat sebelah SULIT]

SULIT D Impure silver Argentum tak tulen

12 Pure silver Argentum tulen Impure

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The figure shows a simple chemical cell. Gambarajah menunjukkan sebuah sel kimia ringkas.

Which pair of metals will produce an electron flow, in the direction shown? Pasangan logam manakah akan menghasilkan arah pergerakan elektron yang ditunjukkan? Metal P Logam P Magnesium Magnesium Copper Kuprum Tin Timah Iron Ferum Metal Q Logam Q Copper Kuprum Lead Plumbum Iron Ferum Aluminium Aluminium

A B C D 25

The pH value of 0.1 mol dm-3 sodium hydroxide solution is higher than the pH value of 0.1 mol dm-3 ammonia solution. This is because Nilai pH bagi 0.1 mol dm-3 larutan natrium hidroksida lebih tinggi daripada nilai pH bagi 0.1 mol dm-3 larutan ammonia. Ini adalah kerana A sodium hydroxide is more soluble in water than ammonia. natrium hidroksida lebih larut dalam air daripada ammonia B the concentration of hydrogen ion in sodium hydroxide solution is higher than the concentration of hydrogen ion in ammonia solution. kepekatan ion hidrogen dalam larutan natrium hidroksida adalah lebih tinggi daripada kepekatan ion hidrogen dalam larutan ammonia

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SULIT 4541/1 13 C sodium hydroxide ionises partially in water whereas ammonia ionizes completely in water. natrium hidroksida mengion separa dalam air manakala ammonia mengion lengkap dalam air D the concentration of hydroxide ion in sodium hydroxide solution is higher than the concentration of hydroxide ion in ammonia solution. kepekatan ion hidroksida dalam larutan natrium hidroksida adalah lebih tinggi daripada kepekatan ion hidroksida dalam larutan ammonia 26 Which of the following is not a chemical property of an acid? Antara pernyataan berikut yang manakah bukan sifat kimia suatu asid? A Acid + alkali salt + water B C D Asid + alkali garam + air Acid + metal salt + water Asid + logam garam + air Acid + metal carbonate salt + water + carbon dioxide Asid + logam karbonat garam + air + karbon dioxide Acid + base salt + water Asid + Bes garam + air

27

Diagram 27.1 shows the set-up of apparatus for the titration of sodium hydroxide solution with sulphuric acid, H2SO4. Rajah 27.1 menunjukkan susunan radas bagi proses pentitratan larutan natrium hidroksida dengan asid sulfurik, H2 SO4.

H2SO4 acid Asid H2SO4 Sodium hydroxide solution and phenolphthalein Larutan natrium hidroksida dan penunjuk fenolftalein

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DIAGRAM 27.1 RAJAH 27.1 25.0 cm3 of H2SO4 acid neutralises 20.0 cm3 of sodium hydroxide solution, NaOH 1.0 mol dm-3. What is the molarity of the acid, H2SO4? 25.0 cm3 asid H2SO4 meneutralkan 20.0 cm3 larutan natrium hidroksida, NaOH, 1.0 mol dm-3. Berapakah kemolaran asid H2SO4? A B C D 0. 2 0. 4 0. 6 0. 8 mol dm-3 mol dm-3 mol dm-3 mol dm-3

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Which of the following salt is insoluble in water? Manakah di antara yang berikut merupakan garam tak terlarutkan di dalam air? A Silver nitrate B C D Argentum nitrat Calcium chloride Kalsium klorida Ammonium sulphate Ammonium sulfat Lead(II) carbonate Plumbum(II) karbonat

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SULIT 4541/1 15 29 Substance X + Sulphuric acid Salt Y + Water + Carbon dioxide Bahan X + asid sulfurik Garam Y + air + karbon dioksida Based on the the equation above, what could substance X be? Merujuk kepada persamaan di atas , apakah bahan X yang mungkin? A Copper(II) oxide Kuprum (II) oksida B Magnesium metal Logam magnesium C Zinc carbonate Zink karbonat D Sodium hydroxide Natrium hidroksida

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Diagram 30.1 shows the steps taken to prepare a standard solution. Rajah 30.1 menunjukkan langkah-langkah untuk menyediakan larutan piawai.

Step P Langkah P

Step Q Langkah Q

Step R Langkah R

Step S Langkah S

Diagram 30.1 Arrange the steps in the correct order of preparing a standard solution. Susunkan langkah-langkah mengikut urutan yang betul bagi menyediakan larutan piawai. 4541 [Lihat sebelah SULIT]

SULIT A B C D S, Q, R and P S, Q, R dan P S, R, P,and Q S, R, P dan Q Q, P, R and S Q, P, R dan S P, R, S and Q P, R, S dan Q

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SECTION B
1

Table 1.1 shows five substances and their respective formulae Jadual 1.1 menunjukkan lima bahan dengan formula kimia masing-masing. Substance Bahan Iodine Iodin Lithium Lithium Acetamide. Asetamida Magnesium oxide Magnesium oksida Copper oxide Kuprum oksida Chemical formula Formula kimia I2 Li CH3CONH2 MgO CuO Table 1.1

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17 Jadual 1.1 State one compound from Table 1 which exists as a molecule Nyatakan satu sebatian dari Jadual 1 yang wujud sebagai molekul.

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. [1 mark] (b) Name the process of change in state of matter when solid iodine is heated to form iodine gas. Namakan proses perubahan keadaan jirim apabila pepejal iodine menjadi gas apabila dipanaskan . [1 mark]

(c)

Graph 1.2 shows the temperature against time when liquid acetamide is cooled from 90oC to 30oC. Graf 1.2 menunjukkan graf suhu melawan masa apabila cecair acetamida disejukkan dari 90oC kepada 30oC. Temperature/oC 90

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SULIT Graph 1.2 (i)

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What is meant by freezing point ? Apakah yang dimaksudkan dengan takat beku ? ... [1 mark] Based on Graph 1.2, state the freezing point of acetamide. Berdasarkan Graf 1.2, nyatakan takat beku bagi acetamida.

(ii)

... [1 mark] (iii) Explain why there is no change in temperature from t1 to t2 . Terangkan mengapa tiada perubahan suhu dari t1 ke t2. ... ... [2 marks]

(d)

Diagram 1.3 represent an atomic structure of lithium atom. Rajah 1.3 mewakili struktur atom bagi atom litium.

(i)

Diagram 1.3 What do the symbols below represent ? Apakah yang diwakili oleh simbol-simbol di bawah.

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19 Calculate the nucleon number of lithium. Hitungkan nombor nukleon bagi litium.

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[1 mark] (e) Empirical formulae for magnesium oxide and copper oxide can be determine by two different method. Formula empirik bagi magnesium oksida dan kuprum oksida boleh ditentukan dengan dua kaedah yang berbeza. You are given combustion tube with a small hole at the end, glass tube, retort stand and clamp, stopper, copper oxide and dry hydrogen. Draw the set-up of apparatus for the experiment to determine empirical formula of copper oxide. Anda dibekalkan dengan tiub pembakaran berlubang kecil dihujungnya, tiub kaca, kaki retot dengan pemegang, gabus, kuprum oksida dan gas hidrogen kering. Lukiskan susunan radas bagi eksperimen menentukan formula empirik kuprum oksida.

[2 marks]

2. Figure 2.1 shows part of the Periodic Table of the elements. M, N, Q, R and T do not represent the actual symbol of the elements.
Rajah 2.1 menunjukkan sebahagian daripada Jadual Berkala Unsur. M, N, Q, R dan T tidak mewakili simbol sebenar unsur.

Figure 2.1
Rajah 2.1

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4541/1 20 Using the letters in the Periodic Table of the elements in Figure 2.1, answer the following questions.
Menggunakan huruf-huruf dalam Jadual Berkala unsur dalam Rajah 2.1, jawab soalan berikut

(i)

Choose an element that is alkali metal

Pilih unsur yang merupakan logam alkali

................................................................................................................................ [ 1 mark ] (ii) Which element is a halogen ?

Unsur yang manakah merupakan halogen ?

(iii)

................................................................................................................................ [ 1 mark ] Which element forms an amphoteric oxide ?

Unsur yang manakah membentuk oksida amfoterik ?

(b)

................................................................................................................................ [ 1 mark ] Arrange M, N, Q, R and T according to the increase in size of the atoms
Susun M, N, Q, R dan T berdasarkan kenaikan saiz atom

....................................................................................................................................... [ 1 mark ] (c) Write the electron arrangement for an atom of element T
Tuliskan susunan elektron bagi atom unsur T

(d)

....................................................................................................................................... [ 1 mark ] Write the formula for the ion formed from an atom of element Q
Tuliskan formula bagi ion yang terhasil daripada atom unsur Q

....................................................................................................................................... [ 1 mark ] (e) When a small piece of element Q is put into water, reaction occurs.
Apabila secebis kecil unsur Q diletakkan dalam air, tindak balas berlaku

(i)

State one observation for the reaction.

Nyatakan satu pemerhatian bagi tindak itu

(ii)

............................................................................................................................. [ 1 mark ] Write the chemical equation for the reaction in (e)(i)
Tuliskan persamaan kimia bagi tindak balas di

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KERTAS SOALAN TAMAT

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