Sanyo 26th International Battery Seminar

Development of Sanyo Li/Ion Batteries
Akira Kinoshita SANYO Electric Co., Ltd.

Mobile Energy Company Lithium-Ion Battery Division Technology Management Department
Copyright(C) SANYO Electric Co.,Ltd. 2009
Growing of Rechargeable Battery Market

Billion pcs
4
For High-Power Vehicles
For Telecommunications
2
99 Polymer
For Portable Products
94 90
Li-Ion Ni-MH
64
Ni-Cd 1970 1980 1990 2000 SANYO Electric Co.,Ltd. 2009 2010 Copyright(C)
Applications of Lithium Ion Batteries

High capacity High power
Digital camera Notebook computer
Electric assisted bicycle
HEV
VCR
Robot Power tool Cellular phone Cordless equipment PDA

Features of SANYOs Lithium Ion Batteries [1]

1. We are leader to develop attractive batteries based on advanced technology.
2. We have confidence of providing high quality products because we have a lot of experience and know-how based on technology, quality control and manufacturing through actual results.
3. We have many kinds of cells, that is, various sizes and capacity.
Features of SANYOs Lithium Ion Battery [2]

4. We have No.1 production capability. * production capability : over 70 million cells per month.
5. We have about 30% share in the Li ion market with steady and proactive approach.
SANYO Li Ion Battery SANYO Li Ion Battery Development Trend Development Trend
SANYOs Lithium Ion Battery Development Concept

valuable battery development
High Capacity
High Power
Co Reduction Low Cost
High Safety
Differentiation of the technology

Development Trend of Cylindrical Cell (18650-size)

Previous Model Typ.2400mAh Current Model Typ.2600mAh
Typ.2800mAh Model
High capacity
Higher Capacity
More Capacity
High Power
Typ.2000mAh Model Typ.2250mAh Model
Typ.1200mAh Model Typ.1600mAh Model
Co Reduction
More Power
Development Trend of Prismatic Cell

Min.840mAh
More Capacity
Current model Min.800mAh Previous model Min.750mAh
Higher Capacity
600mAh
High capacity
*Robust model
with UF463443 size
Higher Cost Performance

Development Trend of Prismatic Cell [1]

We have various size lineup as satisfying customers needs.
Standard Model
UF383551 UF463450 UF553450 UF653450 UF103450 UF423643 UF463048 UF553048 UF653048 UF463446 UF503445 UF553446
Low Height Model

UF383543 UF463443 UF553443 UF603443 UF503436 UF553436 UF653436 UF583136
Large Foot Print Model

UF613756 UF453846 UF534042 UF634042
Small Model
UF752836
... and several models are under developing.

Development Trend of Development Trend of High Capacity Batteries High Capacity Batteries
Trend of Energy Density of cylindrical Li-ion battery

* Energy density is calculated with Min. capacity value
over 3000mAh
Gravimetric Energy Density (Wh/kg)
2008
new cathode material
225 200 175 150

Charging voltage: 4.10 to 4.20V
2005 2002 2004

Typ.2600mAh Typ.2400mAh Typ.2200mAh
Typ.2800mAh
New Generation :
Challenge by using new materials
2001 2000 1998
1996
1995 125 1994
100
Current Generation : LiCoO2-Graphite
250
300
350
400
450
500
550
600
650
700
Volumetric Energy Density (Wh/l)

Candidate of Cathode for High Voltage Charge

High voltage Charged Cathode Material LiCoO2 LiNiO2 LiMn2O4 Li(Ni-Mn-Co)O2 Capacity Safety

Concept of New Cathode Material [Neo-Hybrid Cathode)

Li(Ni-Mn-Co)O2
Higher Thermal Stability
Improved LiCoO2
High Capacity High Packing Density
Synergy Effect by mixing two material High Voltage Charge
Achieve high capacity keeping safety and operating voltage

Comparison of High Capacity Models (UR18650ZT)

UR18650F(Typ. 2.6Ah) Cell size Capacity(mAh) Capacity(Wh) Cathode active material Charge & discharge voltage Weight Safety 18 X 65mm Typ. 2600mAh Typ. 9.62Wh LiCoO2 Charge: 4.2V Discharge: 3.0V Typ. 45.5g Level UR18650ZT 18 X 65mm Typ. 2800mAh Typ. 10.36Wh LiCoO2 Li(Ni-Mn-Co)O2 Charge: 4.3V Discharge: 3.0V Typ. 46.0g Same
Discharge Rate Characteristics of UR18650ZT

4.5
Discharge:CC:Variable Current(E.V.:3.0V) at 20degC
4.0
Cell Voltage / V
3.5
Typ.2.8Ah Model Typ.2.6Ah Model
UR18650ZT (1It=2700)
3.0
2.5
0.2CA 0.2 ItA 0.5CA 0.5 ItA 1.0 ItA 1.0CA 2.0 ItA 2.0CA
CHG: CC-CV: 1.0A-4.30V (54mA cut) at 20deg.C DCH: CC: Variable Current (E.V.:3.0V) at 20deg.C UR18650F(Typ. 2.6Ah) (1It=2500) CHG: CC-CV: 1.75A-4.20V (50mA cut) at 20deg.C DCH: CC: Variable Current (E.V.:3.0V) at 20deg.C
2.0
400
800
1200
1600
2000
2400
2800
3200
Discharge Capacity / m Ah
Temperature discharge Characteristics of UR18650ZT

4.5
4.0
Cell Voltage / V
3.5
Typ.2.8Ahmodel Typ.2.6Ahmodel
UR18650ZT (1It=2700)
3.0
2.5
-10deg.C -10 0 0deg.C 20 20deg.C 40 40deg.C
CHG: CC-CV: 1.0A-4.30V (54mA cut) at 20deg.C DCH: CC: 0.5C(=1350)mA (E.V.:3.0V) at Variable Temp. UR18650F (Typ.2.6Ah) (1It=2500) CHG: CC-CV: 1.75A-4.20V (50mA cut) at 20deg.C DCH: CC: 0.5C(=1250mA) (E.V.:3.0V) at Variable Temp.
2.0
400
800
1200
1600
2000
2400
2800
3200
Discharge Capacity / mAh

Cycle Characteristics of UR18650ZT

3000 2500 Capacity / mAh 2000 1500 1000 500 0 0 100 200 Cycle Number / 300
CHG: CC-CV: 0.5C-4.30V (54mA cut) at various temp. DCH: CC: 2700mA (E.V.:3.0V) at various temp.
25 deg.C
Achieved 83% capacity after 500 cycles.
400
500
Storage Characteristics of UR18650ZT

Storage at SOC 100% for 20 days @ 60 deg.C 3000 Capacity / mAh 2500 2000 1500 1000 Initial Residual Recovery
UR18650ZT UR18650F(Typ.2.6Ah)
UR18650ZT (1It=2700) CHG: CC-CV: 1C(=2700mA)-4.30V (54mA cut) at 25deg.C DCH: CC: 1C (E.V.:3.0V) at 25deg.C UR18650F (Typ.2.6Ah) (1It=2500) CHG: CC-CV: 1C (=2500mA)- 4.20V (50mA cut) at 25deg.C DCH: CC: 1C (E.V.:2.75V) at 25deg.C
UR18650ZT has higher capacity than UR18650F after storage

Result of Safety Test for UR18650ZT

UL 1642Testresults UL approval JIS C8714
Crash Test External Short circuit test
(Condition: Charge Voltage 4.30V)
<Notes> Criteria: No explosion, no fire
Thermal abuse test at 130
Forced internal short circuit test
50deg.C
UR18650ZT
passed passed
passed passed
passed passed
passed passed
5deg.C
Condition: Charge Voltage 4.35V

Development of prismatic cell Development of prismatic cell with High Capacity with High Capacity
Comparison of High Capacity Models (UF463443GT]

UF463443G(Typ. 830mAh) Cell size Capacity(mAh) Capacity(Wh) Cathode active material Charge & discharge voltage Weight Safety UF463443GT (under development)
T4.35 X W33.7 X H42.5mm T4.32 X W33.7 X H42.5mm Typ. 830mAh Typ. 2.95Wh LiCoO2 Charge: 4.2V Discharge: 2.75V Typ. 15.3g Level Typ. 870mAh Typ. 3.12Wh LiCoO2 Li(Ni-Mn-Co)O2 Charge: 4.33V Discharge: 3.0V Typ. 15.1g Same
Discharge Rate Characteristics of UF463443GT (under development)

4.5
UF463443GT UF463443G(Typ.800mAh)
4.0
Cell Voltage / V
3.5
3.0
UF463443GT (1It=840mA) CHG: CC-CV: 1C-4.30V (16.8mA cut) at 25deg.C DCH: CC: Variable Current (E.V.:3.0V) at 25deg.C
2.5
UF463443G(Typ. 830mAh) (1It=800mA) CHG: CC-CV: 1C-4.20V (16mA cut) at 25deg.C DCH: CC: Variable Current (E.V.:2.75V) at 25deg.C
0.2 ItA 1.0 ItA 2.0 ItA
2.0 0 200 400 600 800 1000
Discharge Capacity / mAh

Cycle Characteristics of UF463443GT

45 deg.C 1000 Capacity 800 Capacity / mAh
UF463443GT UF463443G(Min.800mAh)
2.0
1.6 Swelling / mm
600
1.2
400 Swelling 200
0.8
0.4
0 0 100 200 300 400 500 Cycle number / -
Development Trend of Development Trend of High Power Batteries High Power Batteries
Comparison of High Power Models (UR18650WX) (under development)

UR18650SAX Cell size Capacity(mAh) Cathode active material Max. Current (Continuous) Max. Current (durable 350 cycles) AC Impedance(1kHz) 18 X 65mm Typ. 1350mAh UR18650WX 18 X 65mm Typ. 1550mAh UR18650W 18 X 65mm Typ. 1600mAh
LiMn2O4 LiMn 2O4 LiMn2O4 Li(Ni-Mn-Co)O2 Li(Ni-Mn-Co)O2 Li(Ni-Mn-Co)O2 25A 20A 15A
20A 14m
15A 14m
10A 25m
Discharge Characteristics at large current

4.5
20A
4.0 3.5
UR18650WX UR18650SAX UR18650W
Voltage / V
3.0
2.5
Charge: CC-CV:1C-4.2V(100mA cut) at 25 deg.C Discharge:CC:10A(E.V.:2.5V) at -10 deg.C
2.0 0 200 400 600 800 1000 1200 1400 1600 Discharge Capacity / mAh
UR18650WX shows high operating voltage with high capacity at large current.
Discharge Characteristics at low temperature

4.5
10A at -10 deg.C

4.0
UR18650WX UR18650SAX UR18650W
Voltage / V
3.5
3.0
2.5
Charge: CC-CV:1C-4.2V(100mA cut) at 25 deg.C Discharge:CC:10A(E.V.:2.5V) at -10 deg.C
2.0 0 200 400 600 800 1000 1200 1400 1600 Discharge Capacity / mAh
UR18650WX shows high operating voltage with high capacity at low temperature.
Future Development Trend of Future Development Trend of Lithium Ion Batteries Lithium Ion Batteries
Requirements for lithium ion batteries
Cost Capacity Power
Safety
Durability Reliability Availability
New Applications with Rechargeable Batteries

PDA Future Cellular-Phones Note-PCs
High Capacity
Robot
DSC
Mobile Applications
HEV
Cordless Applications
Power Tools
High Power
END
Thank you very much

Sanyo 26th International Battery Seminar

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Development of Sanyo Li/Ion Batteries

Akira Kinoshita SANYO Electric Co., Ltd.

Copyright(C) SANYO Electric Co.,Ltd. 2009

Growing of Rechargeable Battery Market

Applications of Lithium Ion Batteries

Digital camera Notebook computer

Electric assisted bicycle

Robot Power tool Cellular phone Cordless equipment PDA

Features of SANYOs Lithium Ion Batteries [1]

Copyright(C) SANYO Electric Co.,Ltd. 2009

Features of SANYOs Lithium Ion Battery [2]

Copyright(C) SANYO Electric Co.,Ltd. 2009

Copyright(C) SANYO Electric Co.,Ltd. 2009

SANYOs Lithium Ion Battery Development Concept

Co Reduction Low Cost

Differentiation of the technology

Development Trend of Cylindrical Cell (18650-size)

Development Trend of Prismatic Cell

Current model Min.800mAh Previous model Min.750mAh

with UF463443 size

Higher Cost Performance

Development Trend of Prismatic Cell [1]

Low Height Model

Large Foot Print Model

... and several models are under developing.

Copyright(C) SANYO Electric Co.,Ltd. 2009

Trend of Energy Density of cylindrical Li-ion battery

Gravimetric Energy Density (Wh/kg)

225 200 175 150

2005 2002 2004

2001 2000 1998

1995 125 1994

Typ.2000mAh Typ.1900mAh Typ.1700mAh

Typ.1420mAh Typ.1370mAh Typ.1260mAh

Current Generation : LiCoO2-Graphite

Volumetric Energy Density (Wh/l)

Candidate of Cathode for High Voltage Charge

Concept of New Cathode Material [Neo-Hybrid Cathode)

Synergy Effect by mixing two material High Voltage Charge

Achieve high capacity keeping safety and operating voltage

Comparison of High Capacity Models (UR18650ZT)

Discharge Rate Characteristics of UR18650ZT

Temperature discharge Characteristics of UR18650ZT

-10deg.C -10 0 0deg.C 20 20deg.C 40 40deg.C

Discharge Capacity / mAh

Cycle Characteristics of UR18650ZT

Achieved 83% capacity after 500 cycles.

Copyright(C) SANYO Electric Co.,Ltd. 2009

Storage Characteristics of UR18650ZT

UR18650ZT has higher capacity than UR18650F after storage

Result of Safety Test for UR18650ZT

<Notes> Criteria: No explosion, no fire

Thermal abuse test at 130

Forced internal short circuit test

Condition: Charge Voltage 4.35V

Copyright(C) SANYO Electric Co.,Ltd. 2009

Comparison of High Capacity Models (UF463443GT]

Discharge Rate Characteristics of UF463443GT (under development)

0.2 ItA 1.0 ItA 2.0 ItA

2.0 0 200 400 600 800 1000

Discharge Capacity / mAh

Cycle Characteristics of UF463443GT

400 Swelling 200