Part A Part A Part A Parta - Chemistry Chemistry Chemistry Chemistry

CAREER POINT, CP Tower, Road No.1, IPIA, Kota (Raj.
), Ph: 0744-3040000
Website : www.careerpointgroup.com, Email: info@careerpointgroup.com
1

PART A PART A PART A PART A CHEMISTRY CHEMISTRY CHEMISTRY CHEMISTRY

Sol. [3]
Ozone absorbs UV rays from sun and not
infrared radiation.

Sol. [1]
r
d
p

M
p

B
A
r
r
=
2 / 1
A
B
B
A
M
M
P
P
|
|
\
|

Sol. [1]

RO
RS
size
B.S.
B.S.
N.S.
size
N.S.

(2) specific rotation

Sol. [3]
Fact

CAREER POINT, CP Tower, Road No.1, IPIA, Kota (Raj.), Ph: 0744-3040000
2

Sol. [1]
m =
30 . 0 60
01 . 0
=
30 60
1
= 5.55 10
4

d
water
= 1 kg/dm
3

Sol. [3]
V
mp
, V
rms
, V
av.

T

Sol. [1]

OH
0
OH

+H CH
3
+I

(A)

(B)

OH
+

NO
2
(C)

OH

M
I

(D)

I

D > C > A > B

at 27C is 1366.5 kJ mol
1
. The value of

Sol. [2]
H = E + n
g
RT
E = H n
g
RT
= 1366.5 (1) (8.3 10
3
) 300
= 1366.5 + 2.490
= 1364.01
_~ 1364 kJ

Sol. [2]

OH
+ HCH=O
Bakelite

3

Sol. [3]

CH
3 C

CH
3
O

CH
3 CH CH
2 O

CH
3 CH C

CH
3
CH
2 CH
3
2-methyl-2-pentene

Sol. [3]
4NO
2
+ O
2
2N
2
O
5
H = 111 (1)
(g)
4NO
2
+ O
2
2N
2
O
5
H = ? (2)
(s)

2N
2
O
5
2N
2
O
5
H = 54 2 ...(3)
(s) (g)

(1) (3)
H = 111 108 = 219 kJ

Sol. [4]
pH =
2
1
pk
a

2
1
log C
5 =
2
1
pk
a

2
1
log 1
pk
a
= 10
k
a
= 10
10

Sol. [2]
Cl > F > Br > I
Order of electron gain enthalpy.

4

Sol. [1]

H
=
+
He

H
2
2
2
1
2
n
1
n
1
RZ
(
(
|
|
\
|
=
+ (
(
|
|
\
|
He
2
2
2
1
2
n
1
n
1
RZ

2
2
2
1
n
1
n
1
=
(
\
|
16
1
4
1
4

2
2
2
1
n
1
n
1
=
4
1
1
1

n
1
= 1
n
2
= 2

Sol. [2]

1
=
2

c
1
= c
2

342
5
=
M
1

M =
5
342
= 68.4

Sol. [3]
G < 0 spontaneous reaction
so
2 4
Pb Pb
+ +

Pb
+2
> Pb
+4
(stability)
G > 0 non-spontaneous reaction

2 4
Sn Sn
+ +

Sn
+4
> Sn
+2
(stability)
Pb
+2
, Sn
+4

Sol. [2]
K
sp
= s(3s)
3
= 27s
4
= 1.6 10
30

27
10 6 . 1
4
s
30
=
5

Sol. [1]
LiNO
3

Li
2
O + NO
2
+ O
2

Sol. [1]
m
=
M
1000
( = 1.3 S m
1
= 1.3 10
2
S cm
1
)

M
1000
a
1

=
l

a R
1 l
=

a
l
= R = 1.3 10
2
50 = 65.0 10
2
cm
1

m
=
4 . 0
1000
10 65
260
1
2

= 6.25 S mol
1
cm
2

= 6.25
100
1
100
1
m
2

6.25 10
4
m
2
S mol
1

Sol. [1]
According to spectrochemical series increasing
order of strength of ligands is
NH
3
< en < CN
< CO

Sol. [2]

C
2
H
5
OH
H
2
SO
4
110C

C
2
H
5
OSO
3
H
C
2
H
5
OC
2
H
5
CH
2
= CH
2
140C

170C

6

Sol. [4]

There is no continuous resonance thus it is non-
aromatic.

Sol. [4]
Calcium carbide is a ionic carbide
Ca
2+
[CC]
2

It contains 1 and 2 bonds.

Sol. [3]
k
1
=
RT
Ea
1
1
e A

k
2
=
RT
Ea
2
2
e A

RT
Ea
RT
Ea
1
2
1
2
1 2
e
A
A
k
k
+
=

RT
Ea Ea
1
2
2 1
Ae
k
k
= (Ea
2
= 2Ea
1
)

RT
Ea
1
2
1
Ae
k
k
=
k
2
= Ak
1
RT
Ea
1
e

k
1
= Ak
2

RT
Ea
1
e
+

Sol. [2]
4r = a 2
r =
4
2
361
= 127.61
~
128 pm
7

Sol. [2]
gm eqv. = gm. Eqv.
of of
Mohr's K
2
Cr
2
O
7

salt

w . E
gm
1000
) ml ( NV
=

6
294
x
1000
) 750 1 6 . 0 (
=

x =
1000
294 75
6
294
1000
750 6 . 0
=

= 22.05 gm

Sol. [1]
Na
2
O + H
2
O 2NaOH

Sol. [3]
XeF
2
has maximum number of lone pairs
(3 lone pairs)

Sol. [1]
NH
2
NaNO
2
/HCl
N=NCl

CuCN
CN

Sand
mayer
reaction

Sol. [2]

Co
NH
3
NH
3
en
en
3+

cis
Co
NH
3
en
en
3+

trans
NH
3

It has geometrical isomers.
8

PART PART PART PART B BB B PHYSICS PHYSICS PHYSICS PHYSICS

Ans.[3]
Sol. K.E. t i.e., t mv
2
2
1

v t
a =
dt
dv

t 2
1
, F = ma
F
t
1

Ans.[1]
Sol. I =4I
0
cos
2
/2
I
P
= 4I
0
cos
2
0 = 4I
0
.(1)
I
Q
= 4I
0
cos
2
2
4
4
0
I
= |
\
|
= 2I
0
.(2)
2 =
Q
P
I
I

Ans.[1]
Sol.
2
2
) R 2 (
Gm
=
R
mv
2

v =
R 4
GM

R
m
m

9

Ans.[3]
Sol. F
1
= mg sin + mg cos ...(i)
F
2
= mgsin mgcos ...(ii)

m

2
1
F
F
=
1 tan
1 tan

+
=

+
2
2
=
1
3

Ans.[1]
Sol. R = R
1
+ R
2
+ R
3
+R
4
= 400
%
R
R
=
400
] R R R R [
4 3 2 1
+ + +
100
=
400
20
100 = 5 %

Ans.[1]
Sol. Magnetic force ) ( B V q F
r r r
= j q
10 =
and electric force in direction of y-axis j q F
=
r

F
Net
= 11q in direction of y-axis.

Ans.[3]
Sol.
A
i
L
V
AB

= = = 0.1 volt/meter
10

Ans.[3]
Sol.

= 30
r = H
v
v' = v cos 30

L = mvr
= m(vcos30)
|
|
\
|
g 2
30 sin v
2 2

=
g 2
mv
3

2
3

4
1

=
16
mv 3
3

Ans.[2]
Sol. Q = mC
p
dT
= (100 10
3
)
(
(
\
|
dT
T
.
400
32
4
20
3

= 0.002 KJ

W
Q
T T
T
2
2 1
2
=
= ; T
2
= 300 K, Q
2
= 0.002 KJ
If T
1
= 20 K, W = 0.148 KJ
T
2
= 4 K, W = 0.028 KJ
i.e., amount of work will be between 0.148 KJ
to 0.028 KJ.

11

Ans.[1]
Sol.

x
L
L

Restoring force F
R
= (L
2
x)g ... (1)
In case of SHM F
R
= m
2
x ...(2)
From equation (1) & (2)
m
2
x = L
2
xg
(d)L
3
2
= L
2
g
dL
2
= g
dL
g
=
g
dL
T
= 2

Ans.[4]
Sol. It is free expansion of Ideal gas which is both
adiabatic and isothermal process.
T constant, so for the isothermal process
P
1
V
1
= (P
2
V
2
)
P
1
V
1
= P
2
(2V
1
)
P
2
=
2
P
1

12

Ans.[1]
Sol. I
1
= 4I
0
cos
2
/2 = 4I
0
. (1)
I
2
= I
0
+ I
0
= 2I
0
. (2)
(for non coherent sources)

1
2
2
1
=
I
I

Ans.[2]

Sol.

OR gate
NOT gate
NOR gate

Ans.[4]
Sol. W = q (V) = KE

q q
q
B
q
A

a
Kq
a
Kq
a
Kq
a
Kq
V
A
2 2
+ =
V
B
= 0

|
|
\
|
=
5
1
1
2
a
Kq
W
13

Ans.[3]
Sol.
T
2
C
R 693 . 0
10 C 2 R 693 . 0
=
=

T
10
2 / 1
1 / 2
=

T
10
1
4
=
T = 2.5 sec

Ans.[2]
Sol. Actual depth = (h
1
+ h
2
)
Apparent depth =
2
2
1
1
h h

Shift
|
|
\
|
+
2
2
1
1
2 1
) (
h h
h h

|
|
\
|
+
|
|
\
|
2
2
1
1
1
1
1
1 h h
14

Ans.[2]
Sol. Y =
Strain
Stress

Strain =
L
L
=
L
t L
= t
Stress = Y t

Ans.[4]
Sol.

O
/4 /2
3/4

Y
1
= A sin (t kx)
Y
2
= A sin (t + kx)

R
Y
=
1
Y
+
2
Y
= 2A coskx sin t
So, nodes will be at .....
4
5
,
4
3
,
4

Ans.[3]
Sol.

x
dx

2
R
T
q
A i M = =
2
x
T
dq
dM =
=
2
x
T
dA

15

dM =

2
2
2
x dx x

= dx x M
3

4 4
4
0
4
R x
R

=
|
|
\
|
=

Ans.[4]
Sol. = 3 = 3 23 10
6
= 69 10
6
/C

Q V =
3
3
4
r =
3 2
) 10 10 (
3
4

=
3
10
3
4

Change in volume (V)
V' V = Vt
= ) 0 100 ( 10 69
3
4
6 3
|
\
|

R
= 28.9 cc

Ans.[3]
Sol. Volume of big drop = total volume of small
drops
R = 2
1/3
r
Surface energy of small drops U = 2T 4r
2

Surface energy of big drop
U' = T4R
2

= T 4(2
1/3
)
2
r
2

= T 4(2)
2/3
r
2

U' = T(2)
2
2
2/3
r
2

U' = T(2)
8/3
r
2

Ans.[1]

16

Sol. } {
9
2
2
l
d d g
r
V
b
=

)
`
=
2
1
1
2
2
1
d d
d d
V
V

)
`
2 . 1 8 . 7
1 8 . 7
10 5 . 8
2 . 13 10
4
V

V = 6.25 10
4
cm/s

Ans.[1]
Sol. e = B v l
= 0.30 10
4
5 20
= 3 millivolt

Ans.[3]
Sol. Acceleration to momentum conservation, linear
momentum of both point is same So
wavelength is also same.

Ans.[1]
Sol. Time is not dependent on modulation.

Ans.[4]
Sol.

l
A
l
B

l = l
A
+ l
B

3
2
=
B
A
l
l

l
1
K ... (1)

A
A
K
l
1
... (2)
From (2)/(1)
17

A
A
K
K
l
l
=

A
B A
A
K
K
l
l l } { +
=

)
`
+ =
A
B
A
K K
l
l
1

)
`
+ =
2
3
1 K K
A

2
5K
K
A
=

Ans.[2]
Sol. Maximum energy = End point energy
= E
1
E
2

Three particles at least required
v e p n + +
4 4 4 3 4 4 4 2 1
0
1
1
1
1
0

v e n p + +
+
4 4 4 3 4 4 4 2 1
0
1
1
0
1
1

Ans.[1]
Sol. ) )( 1 (
1
k
f
=
f
f
R
> f
V

so increases.

Ans.[2]

18

Sol. Statement-I Polarisation
Statement-II Raylegh's criteria
Scattering
4
1

So statement I and II both correct statement-II
is the correct explanation of statement-I.

Ans.[3]
Sol. a
1
= 2a, a
2
= a

1
= ,
2
= 2
I a
2
n
2
(for same medium)
So I
1
= I
2
statement-I (True)
Statement-II
n constant
I a
2

I = ka
2
(statement -II True )
But no correct explanation, because of
frequency.

19

PART PART PART PART C CC C MATHEMATICS MATHEMATICS MATHEMATICS MATHEMATICS

Sol. [2]
f(x) = (x 1)
2
+ 1 = y
(x 1)
2
= y 1
x 1 = 1 y
x = 1 1 y
f
1
(y) = 1 1 y
f
1
(y) = 1 + 1 y Q y 1
Statement 2 is true
f(x) = f
1
(x)
(x 1)
2
+ 1 = 1 + 1 x
(x 1)
2
= 1 x
Solving these we get x = 1, 2
Statement 1 is true.

Sol. [4]
If H is scalar matrix
H =
(
x 0
0 x

H
n
=
(
n
n
x 0
0 x

H
70
=
(
70
70
0
0
=
(
0
0
= H

Sol. [3]

+ + =
1
0
2
1
5 . 1
2
5 . 1
0
2
2 0 ] [ dx x dx x dx dx x x
20

= 0 + ( )
5 . 1
2
2
2
1
2
2
x
x
+
|
|
\
|

=
4
3
) 2 25 . 2 (
2
1
1 = + |
\
|

Sol. [2]

(x, y)
(a, 0)
(0, 3)

2
,
2
b
y
a
x = =
a = 2x b = 2y
&
a
b
dx
dy
=

x
dx
y
dy
x
y
dx
dy
=
=

=
x
dx
y
dy

log y = log x + log c xy = c
Q it passes through (2, 3)
c = 6
equation of curve is xy = 6

Sol. [1]
There is no change in mean deviation if each
observation increased by a constant number
while mean increased by that constant number
Hence
A.M. = 30 + 2 = 32
M.D. = 2

Sol. [2]
x + y = a x + y = | a |
ax y = 1 ax y = 1
(1 + a)x = |a| + 1 ax + ay = a|a|
x =
a
a
+
+
1
1 | |
(a + 1)y = a|a| 1
y =
a
a a
+
1
1 | |

21

0
1
1 | |
>
+
+
a
a
, 0
1
1 | |
>
+
a
a a

a > 1

Sol. [4]
0
1 1
1 1
1 1
=
r
q
p

p(qr 1) 1 (r 1) + 1 (1 q) = 0
pqr p r + 1 + 1 q = 0
pqr (p + q + r) + 2 = 0

Sol. [1]

Q
P(1,5, 9)

Equation of PQ
=
=
+
=
1
9
1
5
1
1 z y x

Q( + 1, 5, + 9)
lies on x y + z = 5
+ 1 + 5 + + 9 = 5
= 10
Q = (9, 15, 1)
PQ =
2 2 2
) 1 9 ( ) 15 5 ( ) 1 9 ( + + + +
= 3 10

+ b 3 a i s col l i near wi t h
c and

+ c 2 b

Sol. [3]
c b a
r
r
r
= + 3
a c b
r r
r
= + 2
) 3 ( 2 b c c b
r
r r
r
= +
b c c b
r
r r
r
= + 3 2
(1 3) b
r
+ (2 ) c
r
= 0
1 + 3 = 0 2 = 0
=
3
1
= 2
= 6
0 6 3 = + + c b a
r
r
r

22

Sol. [2]
A (2, 3) B(2, 1)
Centroid, (h, k)
Let third vertex is (, )
h =
+
3
2 2
, k =
+ +
3
1 3

= 3h
= 3k + 2
Q 2 +3 = 9
2(3h) + 3(3k + 2) = 9
6h + 9k + 6 = 9
6h + 9k = 3
2h + 3k = 1
locus 2x +3y = 1

Sol. [1]
Max. traingles =
10
C
3

6
C
3

= 120 20
= 100
N 100

f
2
(x) =
0 , 0
0 ,
1
sin
x if
x if
x

23

Sol. [3]
f
1
(x) = x is continuous every R
& f
2
(x) =
0 0
0 ;
1
sin
x
x
x
is discontinuous at x = 0
product of f
1
(x) and f
2
(x) is continuous
St. (1) is correct and (2) is false

Sol. [1]
By induction, to proof
S(n) = n
7
n is divisible by 7
Let n = 1
S(n = 1) = 1
7
1 = 0 7,
Hence it is true for n = 1
Let the statement is true for n = k
P(n = k) k
7
k is divisible by 7.
k
7
k = 7.
Now to proof the statement is true for n = k + 1
P(n = k + 1) (k + 1)
7
(k + 1) is
divisisble by 7
[1 +
7
C
1
k +
7
C
2
k
2
+ ..... +
7
C
6
k
6
+ k
7
] k 1
= 7. + (k
7
k)
= 7 + 7 = 7.( + )
which is divisible by 7.
Statement - 2 is true
Statement -1
n
7
n is divisible by 7
use it put n = n + 1
(n + 1)
7
(n + 1) = 7 True
[(n + 1)
7
n
7
1] + (n
7
n) = 7
= Stanement -1 + 7 = 7
statement-1 is true and statement-2 is also
correct explanation of Statement -1.

Sol. [2]
Points will be end of diameter
(x 1) (x 0) + (y 0) (y 1) = 0
x
2
+ y
2
x y = 0

Sol. [2]
ae = 2
e = 2
a = 1
24

e
2
= 1 +
2
2
a
b

4 = 1 + b
2

b
2
= 3
1
3 1
2 2
=
y x

Sol. [1]
0 for trivial solution.

1 1 3
k 3 k
1 k 1
0
k
2
+ k 6 0
k R {3, 2}

Sol. [1]
Let quadratic equation be
x
2
+ bx + c = 0
+ = 4 + 3 = 7 = b
b = 7
. = 3.2 = 6 = c
correct quadratic equation
x
2
7x + 6 = 0
(x 1) (x 6) = 0
x = 1, 6

25

Sol. [2]
=
=
100
1
2
r
r
a
= +
d a
r
r
100
1
1 2

= =
= +
100
1
100
1
1 2
r r
r
d a
+ 100d =

100

= d

Sol. [3]

y
x
y
dx
dy
1
2
=

2
1
y
y
x
dy
dx
=

3 2
1
y y
x
dy
dx
= +
I.F. =
y
dy
y
e e
1 1
2

dy e
y
e x
y y

=
/ 1
3
/ 1
.
1
.
=
dt e t
II
t
I

y
t
1
=
= { }
dt e te
t t
. 1

y
xe
/ 1
= c e te
t t
+ +
26

y
xe
/ 1
= + c e e
y
y y
+ +
/ 1 / 1
1

x = 1
1
+
y
+ ce
1/y

at x = 1, y = 1 1 = 2 + ce
1

c = 1/e
x =
y
e
e y
/ 1
1
1
1
+

Sol. [4]
0
| 5 |
9 )) ( (
lim
2
5
=
x
x f
x

Limit can be zero only when

5
lim
x
f(x) = 3

Sol. [4]
Statement-1 is true
Statement-2 is false
|A'| = |A| true
|A| = (1)
n
|A| false
Statement-2 is false

27

(1)
9
8
,
4
3
,
3
2
,
2
,
12
5
,
4

Sol. [4]
2 sin 4 cos 3 + sin 4 = 0
sin 4 (2 cos 3 + 1) = 0
sin 4 = 0 cos 3 =
2
1

=
4
n
3 = 2n
3
2

= (3n 1)
9
2

Put n I
=
9
4
,
9
8
,
9
2
,
4
3
,
2
,
4

Sol. [4]
y
2
= 4ax & x
2
= 4by
Area bounded by these curve is
3
16ab

here a = b = 1
A =
3
16

28

Sol. [2]
Since we know in neighbourhood of x = 0,
1
tan
>
x
x
& f(0) = 1
x = 0 is point of minima
&
a x
a f x f
a f
a x
) ( ) (
lim ) ( '

x
x
x
f x f
f
x x
1
tan
lim
0
) 0 ( ) (
lim ) 0 ( '
0 0
=

2
0
tan
lim
x
x x
x
= 0
St. (1) & (2) both correct but (2) is not
correct explanation of (1)

Sol. [3]
A B A B A B AB [A (AB)] SB
T T T T T T T
T F F T F F T
F T F T T F T
F F F F T F T
Hence [A (A B)] B is tautology

Sol. [4]
|
|
\
|
C
B A
P
=
) (
) (
C P
C B A P

=
) (
) ( ) ( ) ( ) (
C P
C B A P C B P C A P C P +

= 1 P(A) P(B)
= ) ( ) ( B P A P or ) ( ) ( A P B P

29

Sol. [4]
0 = (a a
1
) (b b
1
) + (c c
1
) (1)
2 = (a a
1
) 4 (b b
1
)2 + (c c
1
) (2)
p(0) = c c
1
= 2 Q (x = 1) is only root
D = 0 of p(x) = 0 p(2) = p(0) = c c
1

= ?
To find (a a
1
) 4 + 2 (b b
1
) + (c c
1
) = p(2)
Let a a
1
= x and b b
1
= y
2x 2y + 4 = 0 (1)
4x 2y + 2 = 2 (2)
x = 2, y = 4
= 8 + 8 + 2 = 18

Sol. [3]

P(3, 1, 11)
L
Q

=
=
4
3
3
2
2
z y x

Q = (2, 3 + 2, 4 + 3)
D.r
s
of PQ = 2 3, 3 + 3, 4 8
Q L PQ
2(2 3) + 3(3 + 3) + 4 (4 8) = 0
4 6 + 9 + 9 + 16 32 = 0
29 = 29 = 1
Q (2, 5, 7)
PQ =
2 2 2
) 7 11 ( ) 5 1 ( ) 2 3 ( + +
= 16 36 1 + +
= 53

30

Sol. [4]
Statement -1
A = P
1
B P
PA = BP
P = {(A, A) | PA AP in general not
reflexive. So not equivalence relation.
Statement-2
(MN)
1
= N
1
M
1
True
from defination.

Sol. [3]
|
\
|
form
a x
x f a a f x
a x
0
0 ) ( ) (
lim
2 2

Applying D.L.

a x
lim 2xf(a) a
2
f '(x)
= 2a f(a) a
2
f ' (a)

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