Pre-Laboratory 1.

Chemical formula, properties, and danger a) b) c) d) e) f) g) h) i) ammonia : NH3 nitric acid sodium hydroxide hydrochloride acid potassium thiocianate 1,10-phenanthroline Potassium ferrocianade Ethylendiamine tetra acetic acid Na2C2O4

2. Name of each complexes ion a) b) c) d) e) f) g) h) i) j) [Cu(Cl)4]2[Cu(OH)4]2[Cu(NH3)4]2+ [Ni(NH2CH2 NH2)3]2+ [Co(SCN)4]2[Fe(CN)6]4[Cr(H2O)6]3+ [Cr(C2O4)3]3Mn(SO4) Ni(C4H7N2O2)2

3. Structural formula of complexes ion a) b) c) d) e) f) g) h) i) j) [Cu(Cl)4]2[Cu(OH)4]2[Cu(NH3)4]2+ [Ni(NH2CH2 NH2)3]2+ [Co(SCN)4]2[Fe(CN)6]4[Cr(H2O)6]3+ [Cr(C2O4)3]3Mn(SO4) Ni(C4H7N2O2)2

4. a. salt solution of CrCl3 in the water will form stable complexes ion, that is (i) the color is (ii) with the name of complexes ion (iii) and the picture of is structure is b. if a base solution is added to its ionic solution (4a) will form (i) that have color (ii) and if added by base again will form(iii) with the reaction (iv) if in the results of 4b is added by acid will yield (v) with the reaction (vi) (viii) it means the properties of chromium (ix) 5. a. salt solution of Mn(II) in the stable water in the complexes ion form b. if added a base solution will form c. the color is d. if added a base solution again will form the color (vii)

e. solution of Iron(II) in the stable water in the complexes ion form f. if added a base solution will form g. the color is h. if added a base solution again will form the color

i. solution of Iron(III) in the stable water in the complexes ion form j. if added a base solution will form k. the color is l. if added a base solution again will form the color

m. solution of Cobalt(II) in the stable water in the complexes ion form n. if added a base solution will form o. the color is p. if added a base solution again will form the color

q. solution of Nikel(II) in the stable water in the complexes ion form r. if added a base solution will form s. the color is

t. if added a base solution again will form

the color

u. solution of Copper(II) in the stable water in the complexes ion form v. if added a base solution will form w. the color is x. if added a base solution again will form the color

7a. tuliskan deret spektrokimia urutan ligan-ligan dari yang menghasilkan splitting medan ligan paling kecil sampai yang menghasilkan splitting medan ligan paling besar b. berikan daftar pasangan warna komplementer dari warna larutan yang tampak dilihat oleh mata kita serta panjang gelombangnya