S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII TRNG THPT BN TRE NM HC 2005 - 2006 THI NGH

GH MN HA Khi 11 Thi gian: 180 pht Bi 1 : Cu 1 1) Hp cht Z to thnh t 3 nguyn t A,B,X c M2 < 120 . Tng s ht proton, ntron,electron trong cc phn t AB2 , XA2 , XB ln lt l 66,96,81 a. Xc nh trn cc nguyn t A,B,X v cng thc ha hc ca Z b. Nguyn t Y to vi A hp cht Z gm 7 nguyn t trong phn t v tng s ht mang in trong Z l 140 . Xc nh Y v Z c. Vit cng thc electron , cng thc cu to ca cc cht AB,AB2, XA2,XB,ZZ, YCl3 , Y2Cl6 ( Cl : Cl0 ) Cu 2 2) X l mt hidrocacbon mch h trong phn tch c lin kt n hoc lin kt i, phng trnh nhit ha hc ca phn ng chy ca X nh sau : 3n + 1 k Cn H 2n + 2 k + O 2 nCO 2 + (n + 1 k)O 2 H = 1852 KJ 2 Trong n l s nguyn t ccbon v K l s lin kt i C=C trong X Xc nh cng thc cu to ca X bit rng nng lng cc lin kt nh sau : Lin kt O=O H-O C-H C=O C=C C-C Nng lng lin kt (KJ/mol ) 498 467 413 799 611 414 Bi 2 : Cu 1 : 1a)Trn 10ml dung dch n axit yu HA nng mol Co ( hng s axit l KA) C pH= 3,0 vi 5ml dung dch NaOH c pH=13 thu c dung dch c pH= 5,661 . Hy xc nh KA v Co ca HA ( b qua s in li ca nc ) 1b)Hng s phn li ca axit benzoic C6H5COOH bng 6,3.10-5 v ca axit axetic CH3COOH bng 1,79.10 5 . Hy xc nh t s nng ion H+ trong dung dch ng phn t ca axit benzoic v axit axetic 1c)Mt dung dch cha 0,2 mol Fe2+ v 0,2 mol Fe3+ . Dung dch c iu chnh n pH = 1 . Xc nh th ca dung dch . Thm vo dung dch cc ion OH cho n khi pH = 5 ( b qua s thay i th tch dung dch ) . Th ca dung dch o c bng 0,152V . Cht no kt ta v khi lng bao nhiu ? Tnh tch s tan Fe(OH)3. Bit E0Fe3+/Fe2+ = +0,77V ; Fe = 56 ; O=16 ; H = 1 Cu 2 : Trong iu kin c th Al tc dng vi HNO3 to hn hp kh X gm NO v NO2 . Vit v cn bng phng trnh phn ng oxi ha kh cho mi trng hp sau : a) d x / C3 H4 = 1, 020 b) d x / C3 H4 = 1,122 Nu nhn xt v h s cn bng phn ng . Cho bit khong gii hn ca d x / C H4 3

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S GD&T BN TRE K THI HC SINH GII OLYMPIC 30-4 LN TH XII TRNG THPT BN TRE NM HC 2005 - 2006 THI NGH MN HA Khi 11 Thi gian: 180 pht Bi 3 : Ha v c phi kim Ha tan 115,3 (g) hn hp X gm MgCO3 v RCO3 bng 500ml dung dch H2SO4 long, thu c dung dch A, cht rn B v 4,48(l) CO2 ( ktc ) . C cn dung dch A th thu c 12(g) mui khan . Mt khc , em nung cht rn B n khi lng khng i th thu c 11,2 ( l ) CO2 ( ktc ) v cht rn B1 . a) Tnh nng CM ca dung dch H2SO4 dng . b) Tnh khi lng ca B v B1 . c) Tnh khi lng nguyn t ca R bit trong hn hp u s mol ca RCO3 gp 2,5 ln s mol ca MgCO3 . Bi 4 : 1) Vit cc phn ng theo dy chuyn ha sau : ( C gii thch c ch phn ng )

CH3

| CH3

CH3 |

CH = CH 2 A B C = C (1) (2) (3)

/ CH3

CH3 \

CH3 /

\ CH3

2) Theo kt qu phn tch nguyn t , phn khi lng ca cacbon trong hidrocacbon X l
96,43% .Hidrocacbon X c tnh axit yu v c th to nn mui Y vi phn khi lng ca kim loi l 46%.Xc nh cng thc cu to ca cc cht X v Y . Vit phn ng bin ha X Yv phn ng hidro ha hon ton X . Bit cng thc phn t trng vi cng thcn gin I . 1) Bi 5 : Vit cc phng trnh phn ng ( Cht hu c vit dng cu to thu gn ) .
(1) (2) (3) a) Etanol X1 X 2 Axit lactic ( axit2 - Hidroxipropionic)
(1) C H O 8 12 4 (2) C b) A(C 4H 4O 4) 4H 4Br 2O 4 (3) C4H6O

(B) (C) (D)

Chn 1cu to thch hp

ca A hon thnh s .
(1) (2) (3) c) C5H8 C5 H10 O C5 H8 O C5 H9 O4 SNa

2) Cho 2,76g cht hu c A ( Ch cha C,H,O v c cng thc phn t trng vi vi

cng thc n gin nht ) tc dng vi dung dch NaOH va , sau chng kh th phn bay hi ch c nc ,phn rn khan cn li cha 2 mui ca natri chim khi lng 4,44 g . Nung nng 2 mui ny trong oxi d , sau khi phn ng hon ton ta c 3,18 g Na 2CO3 ; 2,464 lt kh CO2 (KC) v 0,9 g H2O.Tm cng thc phn t , cng thc cu to A tha mn cc tnh cht trn .B l 1 ng phn ca A khi B tc dng vi lng d dung dch NaOH hoc vi lng d dung dch NaHCO3 to nn sn phm khc nhau : C7H4Na2O3 ,C7H5NaO3 . Vit cng thc cu to B v cc phn ng .

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