Problem Set: Given: PbO2(s) + 4H+ + 4e- Pb(s) + 2H2O E0red = 1.

.455 V 2+ 3+ Cr2O7 + 14H + 6e 2Cr + 7H2O Eored = 1.33V a. Write the balanced reaction when the two standard half cells above are combined. b. Calculate Eocell, G0 and Keq at 298K. c. Calculate the cell potential when the concentrations of Cr3+ and Cr2O72- are each 1.0M and the pH is 4.0. Given: Ka for HCOOH = 1.8x10-4 In a titration experiment, 0.170g of sodium formate (MW 68g/mol) was dissolved in 25mL ditilled water and titrated with 0.100M HCl. a. Fill up the missing information below (A, B, and C) during titration pH A 3.17 B 2.03 C Volume of 0.00 20.0 25.0 30.0 50.0 titrant, mL b. Which of the following indicators would be the best for the titration? Indicate the color change at the endpoint of the titration Indicator pH range Color of acid form Color of base form Thymol blue 1.2-2.8 Red Yellow Methyl orange 3.2-4.4 Red Yellow phenolphthalein 8.2-10.0 colorless Pink c. Determine the percent of ionization of formic acid at the equivalence point. A 2.000 gram sample of an industrial alkali is dissolved and diluted to 100.0 mL. A 25.00 mL aliquot is titrated with 35.48 mL of 0.1936 M HCl to the phenolphthalein endpoint. Another 25.00 mL aliquot is titrated with 49.93 mL of the same acid until the methyl orange end point. Given: NaOH (FW=40.00), Na2CO3 (FW=15.99) and NaHCO3 (FW=84.01) a. Identify the components of the sample. b. Calculate the % by mass of each component in the sample. The concentration of a commercial hydrogen peroxide, H2O2 (34.00 g/mol) was determined using the iodometry technique. The iodine liberated by the action of excess KI on the 25.00 mL sample solution consumed 26.52 mL of a 0.0478 sodium thiosulfate solution (Na2S2O3) in a titration to the starch end point. Calculate the molar concentration of the H2O2 solution. Following are the involved unbalanced redox equations. Sample reaction H2O2 H2O I - I2 Titration reaction I2 IS2O32- S4O62-