Af

ehemi

stry- Mol..rl ar Ce om etryY ructice

F

l_xam

Mr. Matthew I otaro

MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
1) Determine the electron geometry (eg), molecular geometry (mg), and polarity of so2.

A) eg:16gotlal planar, mg=bent, polar

B) eg=iinsa1, mg=linear, nonPolar C) eg-lsfthedral, mg:fent, Polar D) eg:19116hedral, mg=tstrahedral, nonpolar E) eg:16gotlal pyramidal, mg:16gst-tal pyramidal, polar 2) Determine the electron geometry (eg) and molecular geometry (mg) of CO32
.

A) eg=1s116hedral, mg=tligonal planar

B) eg=1911thedral, mg=tgtrahedra C) eg=1g11thedra1, mg=tigonal pyramidal
1

D) eg=111g6nal Planar, mg=bent E) eg=t6get-tal planar, m8=trigonal planar

3) Determine the electron geometry (eg) and molecular geometry (mg) of IC12
.

A) e9:16get al bipyramidal, mg=linear B) eg:e6135edral, mg:linear C) eg-1s11nliedra1, mg=11igonal pyramidal

D) eg=1sh3hedra1, mg=bent
E) eg:169ot-tal bipvramidal, mg:16gsna1 planar 4) The F-B-F bond angle in the BF2- ion is approximately

A)

120'

B)

60'

c)

109.5'

D)

90'

E) 180"

5) How many of the following moiecules are poiar?

BrC13 CSZ
A)4

SiF4
B)0

SOS

c)1

D)2

trJJ

6) Determine the electron geometry (eg) and molecular geometry (mg) of XeF4 A) eg:16g6t'tal bipyramidal, mg:1g116hedral B) eg:1s11nhedral, mg:lstrahedral C) eg:s61ahedral, mg:5quare Pianar

D) eg=lins3t, eg=linear
E) eg:1s113hedra1, mg:bent

7) Determine the electron geometry, molecular geometry and polarity of XeF6

A) eg:11get,ai bipyramidal, mg=16gsnal bipyramidal, nonpolar B) eg:e6161-tedral, mg:sctahedral, nonpolar C) eg:e6121-redral, mg:11igona1 bipyramidal, nonpolar D) eg=1shahedral, mg=tstrahedraf polar E) eg:1lgottal bipyramidal, mg=sss-saw, polar
8) Determine the electron geometry, molecular geometry and polarity of TeCl6.

A) eg:eqlahedral, mg:square planar, polar B) eg-t6gsrta1 bipyramidal, mg=5sg-5aw, polar C) eg=t6g6t"tal bipyramidal, mg=16g6nal bipyramidal, nonpolar D) eg:s613hedral, mg:ectahedral, nonpolar E) eg=1s112hedral, mg=11igonal pyramidal, poiar
9) Determine the electron geometry, molecular geometry and polarity of N2O (N central).

A) eg:ling3t, mg=linear, nonpolar B) eg:lghrhedral, mg=linear, nonpolar C) eg: linear, m8-linear, polar D) eg:t1g6na1 planar, mg:bent, polar E) eg=1shal-Iedral, mg=bent, polar
10) Determine the electron geometry, molecular geometry and

polarity of HBrO2

A) eg=1s116hedral, mg=bent, polar B) eg=1s11ahedral, mg=linear, nonpolar C) eg=lingat, mg:linear, polar D) eg=66136edral, mg=5quare pianar, nonpolar E) eg=1dgsnal bipyramidai, mg=16genal planar, nonpolar
11) Consider the molecule

below. Determine the molecular geometry at each of the 2 labeled carbons.

\/'

-Ci

//

L.-(.

0
trT

,/

\.._,t\,-t.,

-(lHr
F

A) C1
B) C1 C) C1

D) C1
E) C1

trigonal planar, C2= bent = trigonal pyramidal, C2 = see-saw - tetrahedral, C2 = linear : bent, C2 = trigonal planar = trigonal planar, C2: tetrahedral

i2) Consider the molecule below. Determine the hybridization at each of the 3 labeled atoms

,/0\

\'f / qCIt H
/ r
11

,/-"\

(:v

ll^
H

..lli

- Il'"'ll H
Tr

:=fl

A) 1:sp2,2:sp3,3=sp3
B)

1:sp,24p2,3=t

C) 1=sp3,2=sp3,34p2

D) 1-sP3, 2:5P3, 3:5P3 E) 1--sP2, Z4P3 , g:5P2

13)Thereare-oand-nbondsintheH2C:C:CH2molecuIe' B) 6,4 A) 4,2 C)2,6

14) Draw the Lewis structure for the molecuie

D) 6,2

E) 2,2

A) 7 sigma,2 pi
15) There is/are

B) 8 sigma,2

pi

C:HO. How many sigma and pi bonds does it contain? C) 9 sigma,0 pi D) 8 sigma, 1pi E)9sigma,1pi

n bond(s) in the molecule below.

H H H H-

lllll,.

:O:
t'

H-- C--H
I

t{
A)0
B)1

c)2

D)4

E) 16

16) The Lewis structure of carbon monoxide is given below. The hybridizations of the carbon and oxygen atoms in carbon monoxide are and . respectivelv.

:C=O:
A) sp3, sp2
B) sp2, sp2 C) sp2, sp3

D) sp, sp

E) sp, sp3

17)Amolecu1econtainingacentra1atomwithsp3hybridizationhasa(n)-e1ectrongeometry.
A) trigonal bipyramidal
B) bent C) tetrahedral

D) octahedral E) linear

18) Draw the Lewis structure for OF2. \Mhat is the hybridization on the O atom?

A)

rp3 sp

B)

sp34 tp3

C)

sp sp34

D)

sp342 tp2

E) rp2

19) Draw the Lewis structure for BrC13. \.44rat is the hybridization on the Br atom?

A)

B)

C)

D)

E) sp342

20) How many of the following molecules have sp2 hybridization on the central atom?

HCN
A)3

SOz

OCl2
B)4

XeCl2

c)2

D)0

E)

Answer Key Testname: AP CHEMISTRY - MOLECULAR GEOMETRY PRACTICE EXAM

1) A 2)E

3)A
4) A

s)

6)C 7)B
8) D e) c
10) 11) 12) 13)

A
E

A
D

14) D 15) C
16) D

77) C 18) A 19) C

20) E