Bi tp chui phn ng Bi 1 : Hon thnh s phn ng : + E + K+ A B C F H P CH3 - C - CH2 - CH3 K D K + G O K Trong t A n G l hp cht hidrocacbon .

. Bi 2 : Hon thnh s phn ng sau: A + NaOH 0 B + C + 2 NaCl + H2O. t B + NaOH1:1 CH3OH + Na2CO3. C + HCl HCOOH + NaCl Bit A khng phn ng trng gng v t l mol gia A, B, C l 1 : 1 : 1. Bi 3 : Hon thnh s phn ng sau: C4H7ClO2 + NaOH A + B + NaCl + H2O. A + NaOH t0 CH4 + Na2CO3. CaO, B + CuO NH3 D + Cu + H2O D + Ag2O E + 4 Ag. Bi 4 : Hon thnh s phn ng . +B A1 +B Fe+ HCl NaOH +B Toluen A3 A4 A5 +B A2 Bi 5 : Hon thnh s phn ng.
H2SO4 Ni, t
0

t0

1,3,5-tri aminotoluen.

A + H2O C + O2 zm C
Men H2SO
4 1700 C

B+C B+D E+D

HgSO4 800C

G + H2

G + AgNO3 + NH3 + ... K +.... K + H2SO4 ( long) B + ...

F( hidrocacbon) + D

Bi 6 : Hon thnh s bin ho sau : Al4C3 + HCl E + X

15000C

E Y+ Z CH3 COOH + Y A nA
trng hp

B
Cu(OH)2

B + n NaOH C + D C + NaOH E + F F + X + ? + + ? A + NaOH ?

Bi 7 : Hon thnh s bin ho: a) CaC2 C2H2 A B C D +C B1 E( mch vng) p, t0 xt, b) C+E G C5H6O4 + NaOH A + B + C C + AgNO3 + NH3 + ... H + Ag + .. D + AgNO3 + NH3 + .. I + K + Ag A + H2SO4 D + Na2SO4 + ... 0 CaO, t H + NaOH L + ...+ ... A + NaOH E + F t0 L M+F Bi 8 : Hon thnh chui phn ng sau, bit A c cu to mch thng v i xng: C2H6O C4H6 NaOH C9H17O4N C5H7O4Nna2 +C2H6O
+ H2/Ni NaOH

Nguyn Minh Tun : HSP H Ni

( A) C5H7O4Nna2

HCl

C5H10O4NCl + ?

C4H6 F

etylcyclohexan

Bi 9 : Hy xc nh cc cht trong cc phn ng sau: A + NaOH B + C + 2 NaCl E G B + NaOH D + Na2CO3 G + H2 C D + O2 E+ H2O G + Ag2O M + 2 Ag E + Ag2O L + H2O + 4 Ag M + NaOH B + H2O Cho bit A c cu to mch h v khng i xng. T l mol gia A, B, C l 1: 2 : 1. Bi 10 : Hon thnh s bin ho: C ( etylenglycol diaxetat) + H2, xt trng ngng trng hp, xt 2HCHO A B D (poliete) + O2 , xt Ca(OH)2 d E F ( a chc) G Bi 11: Cho s bin ho sau: C4H6O2
X1 + O2 xt X2 H C4H6O4 2SO4 +Y1 X3 H SO C7H122O4 4 +Y2 X4 H SO4 C210H18O4 +H2O CaO, t0 Ni, t0

X2 + Y1 + Y2

a) Vit phng trnh phn ng bit X1 l mt andehit a chc, mch thng, Y2 l ru bc hai. b) Bng nhng phn ng no chng minh X1 va c tnh oxi ho va c tnh kh. c) Bng phng php ho hc no nhn bit c Y1 v Y2. Bi 12 : Hon thnh s phn ng sau. A A G R Bi 13 : Vit phng trnh phn ng theo s sau. A
+OH+ Cl2, as t0, xt

B1 C1 D1 E1
+ OH
-

+CuO+ Ag2O + H2SO4

G1 ( axit cacboxilic)

B2 C2 D2 E2 ( polime) Bit A l etyl benzen tc dng vi clo theo t l 1 : 1. Bi 14 : Hon thnh s phn ng sau: C6H8O4 (A) + NaOH X + Y + Z. X + H2SO4 E + Na2SO4. Y + H2SO4 F + Na2SO4. F
H2SO4. 1800C

R + H2O.

Bi 15: Hon thnh s phn ng di dng CTCT.

NaOH 1:1

A +NaOH BCaO,t0

CH4 D E C2H5OH.

Bi 16 : Hon thnh s bin ho sau: A

t0,p, xt (1)

+NaOH (2) +HCl (3)

+HCl D1 (4) +NaOH (5)

D2

Bit B l -(NH-CH-CO-)n CH3

Nguyn Minh Tun : HSP H Ni

D2 Bi 17 : Cho s phn ng sau

15000C CH4 lnh nhanh +HCl NaO H B1 NaO H

D1

+2HCl

B2

D E F HCHO

Nguyn Minh Tun : HSP H Ni