ANALIZACILESOREEKATIONEVE

TRETESIRAI+II(A+B)+III(A+B)+IV+V+HNO3+HCl(2N)+CENTRIFUGIM[(Hg 2+ 2;Ag+;Pb 2+ )(Hg2+ ;Pb 2+ ;Bi 3+ ;Cu 2+ ;As 3+,5+ ;Sn 2+,4+ ;Cd 3+ )(Al3+ ;Cr 3+ ;Fe 3+ ;Co 2+ ;Ni 2+ ;Mn 2+ ;Zn 2+ )(Ba2+ ;Ca 2+ ;Sr 2+ )(K+;Na +;NH 4 ;Mg 2 )]

HetohetmereaktivinNELSENNH4+,ngjyrosetmeportokallitretsiraedhn(TRETESIRANELSENESHTEHgI 2+2I=[HgI 4]2)

AgCl;PbCl;Hg2Cl2;+H2Oidistiluar+

tretsirategrupeveII(A+B)+III(A+B)+IV+V+NH4OH+H2O2(3%)+H2Oidistiluar+derinvlim+H2S+Centrifugim

vlim+centrifugim

Bi2S3;CuS;As2S3;CdS;HgS;SnS2;Sb2S3+
2+

AgCl;Hg2Cl2+NH4OH

tretsirPb +

(Grignar)+Centrifugim

CrO42ngjyre

HgS
HgS ;CuS
CuS ;Bi
Bi2S3;CdS+
+HNO3

everdh
Ingjyree

(6N)+H2Oidistiluar+centr centrifugim

Hg2Cl2+

tretsir

H2Ombret Ag++HNO3

eror+SnCl2 fundrrese verdh

(NH4)2S2+H2Oidistiluar+Centrifugim
3+

atherka
joneHg2

2+

atherka
+

joneAg

atherka
2+
jone PB

4+

+HCl

Fe(OH)3;Al(OH)3;Cr(OH)3+

tretsiraIIIB+IV+V+(NH4)2S+ujidistiluar+pushimjocentrifugim

NaOH(6N)+ujidistiluar+H2O2(3%)

CoS;NiS;MnS;ZnS+

TretsirIV
IV +V+(NH
(NH4)2CO3+NH
NH4OH(6N)+NH
NH4Cl(ng) +Centrifug

HCl(2N)+centrifugim

CaCO3;BaCO3;SrCO3+

TretsiraqprmbanjonetNa +

CoS;NiS

CH3COOH(2N)+K2Cr2O7+uji

K+;Mg2+;HClO4+Centrifugim

HgS+H2O tretsiraBi ;Cd ;Cu +

AS2S5;Sb2S3;SnS2+HCl(6N)

Fe(OH)3+ Tretsiraprmban
HCl(2N) + [Cr(OH)4];[Al(OH)4]

mbretror+ NH4OH+Centrifugim

(+)H2Oidistiluar+Centrifugim

(NH4)SCN

prmbajtjaeprovzs

(+)ujmbr

Nngjyre

ndahetndypjesdhe

tror

kuqegjaku

procedohetprprovzn

formohet

3+

2+

2+

2+

ebardh

3+

tretesireAs ;Sb ;Sn

2
fundrres bardheAgCl SO4 ngjyr SnCl2fund Bi(OH)3 tretesiraCu ;

ezezHgCl

TretsiraIII(A+B)+IV+V+HNO3(hidhetmepika)+ujidistiluar+NH4OH(6N)+NH4Cl(ng)+centrifugim

rresebar
dhHg2Cl2

ebardh
turbullt

+Hg(Me) ather
fundrrese
zez
atherka
joneHg2+

kajone
Bi3+

3+

Cd

n.q.skangjyr

(6N)+H2Oidistiluar+Centrifug

AS2S5+
NH4OH+
H2O2+

tretsirSb3+;Sn4+
(+)Fe(Me)
o

Sb

distiluar+Centrifugim

+
2+
KClO4 Na ;Mg +KOH

permbajtjene

NaOH(6N)+
Centrifugim

2+
2+
BaCrO4 tretsiraCa ;Sr +
precipitat Na2CO3+ujt

fundrres (6N)+Centrifugim
ebardh Mg(OH)2 tretsirae

menumrperkats1)2)

provzse

1)Mn(OH)2+ Iverdh

sivijon:

ndajmendy

HNO3(2N)+

1)CrO24+Ba2+BaCrO4

pjesedhe

Na3BiO3

tretsir
4+
HNO3(6N)+ formohet Sn +
tkaltr
atherkajone NH4NO3 ngjyree HgCl
Cu2+
fundrres zeznga fundrres

atherka

shfaqngjyrtverdh

procedohet:

kjotretsir

joneFe3+

atherkajoneCr3+

1)+NH4OH+

(+)KCN
'ngjyroset
' j
(+)H2S
fundrrese

ebardhe reduktimi ebardh

iSb3+
As(OH)3
SnCl2
NH3AsO
A O3

ather
h

ather
h

Themiseka kajone
Sb3+
joneAs 2+

kajone
Sn4+

kompleksi
[Fe(CN)n]

3n

2)[Al(OH)4] +NH4Cl(ng)
Al(OH)3 trubullirebardh
t b lli b dh
Al(OH)3+CH3COOH(2N)+
alizarinngjyrekuqe

verdheCdS

siluleshege
atherkajoneAl3+

ateherkajone
Cd

grupiiIikationeve

tretsira
Mn2+ ;Zn2++

3+

ngjyrroz

atherka
2+
dimetildioksan joneMn

ngopur+Centrifugim
SrSO4precipitati

shf
hfaqet

b
dh h k
bardhatherka
joneSr2+

Grupii I

CO 3+HCldgjohenkrcitjegjatbashkveprimit
C2O24+KMnO4+H2SO4+ujidistiluarTretsira'ngjyroset
SO23+Sr(NO3)2+HNO3Precipitatibardh
PO34+MolibdatAmoniPrecipitativerdh
B4O7Flakajeshile
2

SO 4+BaCl2Precipitatibardh

2)tretsirae
i

ngjyreiklamin [Zn(OH)4]+
atherkajone CH3COOH+H2S
Ni2+
fundrrese
2)+NH4SCN+ zzengaZnS

grupii III ikationeve

A/

ANALIZACILESOREEANIONEVE[ grupiiI;II(A+B);III ]
2

GrupiiIIdheiIII

Tretsira(Cl;Br;I)+HNO3+AgNO3+NH4CO4+centrifugimCl+tretsir
jonetjoddhebromhetohenI;Br+H2SO4everdhnkafeshtI
everdhshtBr
Cl+NH4CO3Precipitatibardh
CH3COOH(kaereuthulle)+H2SO4ertherse

SCN +FeCl3ngjyrtkuqegjaku

atherka CaCO3;SrCO3+
joneBa2+ CH3COOH(2N)+uji
distiluar+(NH4)2SO4e

eter+alkol
atherka
amilikshfaq joneZn2+
ngjyrtkaltr
netretsir
atherka
joneCo2+

grupii IIikationeve
A/B

distiluar+centrifug

NO 3+Shaphekuri+H2SO4ccformohetunaza

ClO 3+AgNO3precipitonperzierja+AgNO3+KNO3turbullireverdh

tretsiraCa2++

Na++HCl
(2N)[hidhe

atherka mepika]+
joneMg2+ K2H2SbO7
Na2H2SbO7
fundrres
b dh
ebardhe
atehereka
joneNa+

(NH4)2CO3fundrres
tebardheCaC2O4
atherkajoneCa2+

grupii IVikationeve
B/

atherka trubullir
joneK+ ebardh

grupii Vikationeve