Cp Data

Component
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen

Stram 7
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Total

A
32.083
24.915
25.399
20.056
28.146
29.342

B
-0.014831
0.20648
0.020178
0.28153
0.04344
-0.0035395

C
0.0002477
0.000059829
-0.000038549
-0.000013143
0.00018946
0.000010076

(lb/hr)
1442
1301
8
82
147
55
3034

(Xi)1
0.47517167
0.42878296
0.00260006
0.02695538
0.04851968
0.01797025
1

(mol/hr)
51.48294089
23.22845516
3.943886598
1.409899889
4.906451613
3.894009217
88.86564337

D
-2.38E-07
-1.42E-07
3.19E-08
-9.46E-08
-1.91E-07
-4.31E-09

Cp (mix)
at

E
6.83E-11
4.71E-11
-8.76E-12
3.41E-11
5.33E-11
2.59E-13

Steam 10
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Total

Component
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Total
(lb/hr)
817734
331088
4540
48386
85386
31318
1318452

(Xi)4
0.62022281
0.25111874
0.00344343
0.0366991
0.06476231
0.02375361
1

For Mean temp. of E - 202

T (K)
342

Cp (mix)
at

For Mean temp. of E - 201

T (K)
346.5

Cp (J/mol-k)
47.41240747
97.50607224
28.94647008
111.4861805
58.25933214
29.14109704
-

Component
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Total

Cp (J/mol-k)
Cp (J/g-k)
47.78311076 1.7065397
98.42851236
1.757652
28.96240929 14.481205
112.5861207
1.94114
58.77569091 1.9591897
29.14967967
2.08212
-

(mol/hr)
29204.78571
5912.285714
2270
834.2413793
2846.2
2237
43304.51281

Cp (J/g-k) (Xi)1*Cp (J/g-K)

1.69330027
0.804608315
1.74117986
0.746588251
14.473235
0.037631297
1.92217553
0.051812968
1.94197774
0.09422414
2.08150693
0.037405204
1.772270176
Stream (7+10)
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Total

(lb/hr)
819176
332389
4548
48468
85533
31373
1321486

(Xi)2
(mol/hr)
0.619889818 29256.26866
0.251526594 5935.514169
0.003441496 2273.943887
0.03667673 835.6512792
0.064725025 2851.106452
0.023740337 2240.894009
1 43393.37845

Cp (mix)
at
(Xi)2*Cp (J/g-K)
1.057866566
0.442096222
0.049837009
0.071194669
0.126808601
0.049430231
1.797233297
Stream 11
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Total

For Inlet Stream (11) temp. of Reactor

T (K)
328

Component Cp (J/mol-k)
Ethylene
46.2728914
Butene-1
94.6228549
Hydrogen
28.8937277
C4
108.041936
Ethane
56.6612308
Nitrogen
29.1159164
Total
(lb/hr)
845622
334900
4563
48483
85560
31373
1350500

(Xi)3
(mol/hr)
0.62615424 30200.7717
0.24798219 5980.35834
0.003379
2281.6683
0.03589986
835.9099
0.06335443 2852.00645
0.02323029 2240.89401
1 44391.6087

Cp (J/g-k) (Xi)3*Cp (J/g-K)

1.652603263
1.034784536
1.689693837
0.419013974
14.44686384
0.048815904
1.862791996
0.066873966
1.888707694
0.119658006
2.079708312
0.048312224
1.737458609
Stream 5
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Polymer
Total

(lb/hr)
1706
1539
9
97
174
65
28458
32048

Cp (mix)
at

For outlet Stream (10) temp. of Reactor

T (K)
361

Component Cp (J/mol-k)
Ethylene
48.99095516
Butene-1
101.3858632
Hydrogen
29.01059441
C4
116.1063168
Ethane
60.44732648
Nitrogen
29.17891656
Total
(Xi)5
0.05323007
0.04803348
0.00029127
0.00301962
0.00543531
0.00201308
0.88797718
1

Cp (mix)
at

Cp (J/g-k) (Xi)4*Cp (J/g-K)

1.749677
1.085189561
1.8104618
0.45464089
14.505297
0.049948007
2.001833
0.073465468
2.0149109
0.130490288
2.0842083
0.04950748
1.843241694
Stream 4
Nitrogen
Catalyst
Total

(lb/hr)

(Xi)6
10 0.714286
4 0.285714
14
1

For Inlet Stream (4) temp. of Reactor

T (K)
328

Component Cp (J/mol-k) Cp (J/g-k)

Nitrogen
29.11591637 2.0797083
Catalyst
Total
-

m (4) temp. of Reactor

(Xi)6*Cp (J/g-K)
1.485505937
1.485505937

Cp (mix)
at

For outlet Stream (5) temp. of Reactor

T (K)
361

Component
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Polymer
Total

Cp (J/mol-k)
48.99095516
101.3858632
29.01059441
116.1063168
60.44732648
29.17891656
-

Cp (J/g-k) (Xi)5*Cp (J/g-K)

1.749677
0.09313543
1.8104618
0.086962777
14.505297
0.004224903
2.001833
0.00604477
2.0149109
0.010951668
2.0842083
0.004195675
1.7545398
1.557991266
1.763506488

ENERGY BALANCE FOR E - 202

Equipment Use:
For cooling the process stream 7
Duty Calculation :
Duty =

( m*Cp*T)

T =

(78-60)

m=

Mass Flow Rate of Stream 7 =

Cp =

1.7722702 (J/g-K)

Duty =

12.177804 (KJ/sec)

18 (C or K)
381.739 (gm/sec)

11045.51

ENERGY BALANCE FOR E - 201

Equipment use :
For cooling the process stream (7+10)
Duty Calculation :
Duty =

( m*Cp*T)

T =

(92-55)

m=

Mass Flow Rate of Stream (7+10) =

Cp =

1.797233 (J/g-K)

Duty =

11057.69 (KJ/sec)

37 (C or K)
166287 (gm/sec)

ENERGY BALANCE FOR COMPRESSOR K -202

Equipment use :
For compressing stream 7
inlet
temperature
pressure

outlet
333
65

366 (K)
275 (psia)

Work for this compressor

W=

m*(y/(y-1))*R*(T2-T1)
Where y = (Cp/Cv)=1.4
m=
Mole Flow Rate of Stream 7
R=
Gas constant = 8.314 J/mol-K

T2 =

366

T 1=

333
8.314

R=
W=

y=
m=

(gmol/sec)

1.4
24.6849

23.7041 kW
1426.7085
12472.219

ENERGY BALANCE FOR COMPRESSOR K -201

Equipment use :
For compressing stream (7+10)
inlet
temperature
pressure

outlet
361
275

365 (K)
300 (psia)

Work for this compressor

W=

m*(y/(y-1))*R*(T2-T1)
Where y = (Cp/Cv)=1.4
m=
Mole Flow Rate of Stream (7+10)
R=
Gas constant = 8.314 J/mol-K

T2 =

365

T 1=
R=

361
8.314

W=

1403.004 kW

y=
m=

1.4
12053.7162

(gmol/sec)

ENERGY BALANCE FOR REACTOR R - 201

361
Equipment use :
For polymerization reaction
Stream
4
5
11
10

Cp (mix)
2.0797083
1.7635065
1.7374586
1.8432417

m*Cp (mix)
3.66375281
7111.81394
295260.205
305803.4

m*Cp*T
1201.71092
2567364.83
96845347.2
110395028

Energy Balance :

Catalyst
Nitrogen
Total

4
10
14

4
Energy IN + Heat of Reaction = Energy OUT

328 K

96846549 112962392
16115.84
328

Reactor

10

11

Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Total

Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Total

817734
331088
4540
48386
85386
31318
1318452
361 K
Ethylene
Butene-1
Hydrogen
C4
Ethane
Nitrogen
Polymer
Total
845622
334900
4563
48483
85560
31373
1350500

1706
1539
9
97
174
65
28458
32048