I

Series SSO

Code N~.

(5)s

';f.

56/3
W- ~-~

Roll No.
W1

Candidates must write the Code on the title page of the answer-book.
tRTaw.IT

;t.

C!5ls em 3'rR -~~QJI

1:R~~

Please check that this question paper contains 12 printed pages. Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. Please check that this question paper contains 30 questions.

Please write down the Serial Number of the question before attempting it.
15 minutes time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the student will read the question paper only and will not write any answer on the answer script during this period.
~ ~-1:f;f ~
~

Cf){ ~

fcn

~
Chl

~-1:f;f

# ~
~ ~

~
~

12 ~
Cf?t ~

# ~
~
~

m~
fcn

3ffi ~
~-1:f;f

~-~f1chl

:rsr-~
WRi
ctlT ~

1R

fu&

Cf){ ~
CfiT ~

# 30 ~
~

f(,.~"'1 ~
~ ~

it ~,
ctlT ~

CfiT

~-1:f;f

Cf?t

15 fl:Rc:

m ~ ~I
ClCfi ~ ~ -;:r@

~ ~ ~m ~~-~
'"

10.15 ~

fcn<:rr

10.15 ~

~ 10.30 ~

~-1:f;f

~ Cf?t ~

#
am:

~-1:f;f

1R cnW ~

CHEMISTRY

(Theory)

~fa"m;J(~)
Time allowed : 3 hours Maximum Marks: 70

56/3

p.T.a.

General Instructions :
(i) (ii) (iii) (iv) (v) (vi) (vii) ~~: (i) (ii) (iii)
(iv) (v) (vi) (vii)

All questions are compulsory.

Marks for each question are indicated against it. Questions number 1 to 8 are very short-answer questions and mark each. carry Questions number 9 to 18 are short-answer questions and carry 2 marks each.

Questions number 19 to 27 are also short-answer carry 3 marks each. Questions number 28 to 30 5 marks each. are long-answer

questions

and

questions and carry is not allowed.

Use Log Tables, if necessary. Use of calculators

ff'ift ~
J[f'irq; ~

31f.:r"cff4

$'

3fcn ~

7JTJ:

$' I ~ ~. I J[f'irq; ~ ~ I J[f'irq; ~ ~ ~. I ~

~ ~
fC7r!:

~~~~-~

~
~ ~

1 it 8 (fCfi
9 it 18
(fCfi

3ffrr ~-3r7fp;r

1 3fcn
3 3fcn
$' I

~ I

(1f{-3r7fp;r ~ '"
'4T

fC7r!:

3fcn ~ I ~. I

19 it 27

(fCfi

~-3r7fp;r

~ I J[f'irq; ~
~ ~
fC7r!:

fC7r!:

28 it 30 cfJrf-3r7fp;r~
~ q:;r

'" 3WH4q,d/rf.f;-{/~"fifrr

5 3fcn

cR I

cJ,r::Pc1c:.~} ~

ctt 3R11frr '"

;rif

~ I

1.

What is the number of atoms in a unit cell of a face-centred cubic crystal?

fcnm ~-~ ~ ~ ~ ~

1 1

m-r

if ~

W1TUT ~ ..;)

2.

What is the 'coagulation' process? (coagulation)"5ffii11FIT mm ~ C

i~'

tal
~,

Why is red phosphorus less reactive than white phosphorus? ~ ~1~~*1 cnl ~ ~ ~1~~*1 cpr rs:h'1I~I1<.1 cp:ff mm ~ ? What is meant by the term 'pyrometallurgy' ?
inN_~'

1 1

6)
56/3

it

CFIT ~

mm ~?

I
5. Write the structural
1-~H(.14~<i-1-3TR
CfiT ~

formula of I-phenylpentan-l-one. m- ~ e-.

I

1 1

6.

Give the IUPAC name of the following compound:

H2C = CH - CH - CH2 - CH2 - CH3
1

OH
r ... r .r. .. ~
CfiT

IUPAC ~
1

H2C = CH - CH - CH2 - CH2 - CH3

OH
/, i7~)
',-

What does '6,6' indicate ~-6,6 ~

in the name nylon-6,6 ?

'Cp1T ~

if ~

'6,6'

Cfi\(IT

8.

D
.~

2
Complete the following chemical reaction equations (i) XeF2 + H20 --7 (ii)
r (i)

BH3 + HgC12 --7

r r. r ~
--7 ~J-;lcp\u~

ciT ~

XeF 2 + H20

(iD 10.

PH3 + HgC12 --7 :

Complete the following reaction equations

(i)

0 0(CH3

+ HI --7

56/3

p.T.a.

~---------------.

1
I

11.

Which one in the following pairs undergoes SN1 substitution faster and why ?
(i)

reaction 2

/I~
~
if

CI

rn

or
Cl.

~
Cl
~

(ii)
CFff?

or~
~-SNI

r r r: ~

it ~

~:m~"ffiwIT

it ~

31R

(i)

/I~
Cl
~ 3l~

Cl

(ii)

~Cl

~comPlete
, (i) (ii)

MnO~ (aq) + C2O~- (aq) + H+ (aq) ~ Cr2O~- (aq) + Fe2+ (aq) + H+ (aq) -7

the following chemical reaction equations:

.

r r r
(i) (ii)
13.
_

r:m~

~~iICPo(Y~

cit 1:[Uf

MnO~ (aq) + C20~- (aq) + H+ (aq) ~ Cr20~- (aq) + Fe2+ (aq) + H+ (aq) -7

..

Describe the Tole of the following : /' /- I

-,""

~ (ii)

NaCN in the extraction of silver from a silver ore. Cryolite in the extraction of aluminium from pure alumina.
ctT ~
CfiT

r rr
(i)
(ii)

quf;r

:
Hl>:h~UI ~

~
~

~
Q~I1Ir11

~ ~

if NaCN

ctT

it

Q~~H.!.l11

Hl>:h~UI if 9h1.!.l1<1ISc. ~

56/3

14.

Define the following: (i) Order of a reaction

-qft~ ~ :

(ii) ,Activation energy of a reaction

r (i) r.r._ .. ~ 31f~ 31f~

c8 W
c8 ~r~"jul
~

(ii) 15.

What type of cell is a lead storage battery ? Write the anode and the cathode reactions and the overall cell reaction occurring in the use of a lead storage battery.
OR

Two half cell reactions of an electrochemical cell are given below : MnO~ (aq) + 8 H+ (aq) + 5 e-7

Mn2+ (aq) + 4 H20 (l),

EO =

EO

= + 151 V

Sn2+ (aq) -7 Sn4+ (aq) + 2 e-,

+ 015 V

Construct the redox equation from the two half cell reactions and predict if this reaction favours formation of reactants or product shown in the equation.
mm
31R

~-ql"jcn ~
~~

fcR:r ~
Cf!ffi

m
~

CfiT "ffi1, ~
31R

mm

~-ql"jcn ~ r~<:1lcn\ ~

if

m~
"ffi1 ~

w:r:r ~
~

tR

"f

'Cf!ffi

~I

3l~
~ ~-\I~I"jHcn ~ ~ ~

3l~ irc1Tc8 ~
-7

f.:p:;r

~
EO

MnO~ (aq) + 8 H+ (aq) + 5 e-

Mn2+ (aq) + 4 H20 (l),

EO

= + 151 V

Sn2+ ,(aq) -7 Sn 4+ (aq) + 2 e-, ~

~

= + 015 V

itc1 31f~:m
fcfi ~

it 00cm
~~lcn\UI ~

(~414-q"j)~~lcn\UI

R~
~ ~

~
CfiT ~'"

3fR ~
~

31f~

31f~

3l~

16. Name the four bases present in DNA. Which one of these is not present in RNA ? 'qR ~ ~ ~ ~ ~ DNA if fc1'C.l~I..-j ~ I ~ it ~ ~ RNA if ~
~ ~ ?

56/3

p.T.a.

i/::;"~;

(.!_71 Differentiate between condensation and addition polymerisations.

Give 2
~

one example each of the resulting polymers.

~ q,(1cnlcn~ul

3fu:

<iljll\<-icn

q,(1cnlcn{UI

if ~
I

I ~

c:rr#r

?!g~ Name two fat soluble vitamins, their sources and the diseases caused
'-- due to their deficiency in diet. qm if :!c.1.p{ (1 G) fcR:1f~ it -;w:r,
11

~/--.

it ~

q:;r~-~

~c;.IQ{UI ~

2
~ ~
31R ~ ~

if

CfilTI

qTffi

:J, .. r.

.Ii

it

-;w:r

19.

Silver crystallises with face-centred cubic unit cells. Each side of the unit cell has a length of 409 pm. What is the radius of an atom of silver ? (Assume that each face atom is touching the four corner atoms.) ~ ~-~ er.:fm ~ iwr if r9h~r(1c1 ~ ~ I ~ iwr it ~ fcfnR cnl ~409pm~ I ~~cnl~CFIT~? (~~~fcn~ "Cf)\ill ~ I) ') ~:qRf ~ it ~3TI ~

20.

A first order reaction has a rate constant of 00051 min-I. If we begin with 010 M concentration of the reactant, what concentration of the reactant will be left after 3 hours ?
~ >f2p1

c8R:- cnl 31f~

q:;r

G\ ~

00051 min-1 ~ I ~ 3 ttZ ~

~ ~

~ ~

~
it1f

it
W

010 M ~ ~?
21.

it ~~ ~

~,

-ffi

A voltaic cell is set up at 25 C with the following half-cells: All A13+ (00010 M) and Ni I Ni2+ (050 M). Write the equation for the cell reaction that occurs when the cell generates an electric current and determine the cell potential. (Given: EO 2 +/ Ni = - 025 V, Ni EO 3 + / Al = - 166 V) AI Ni I Ni2+ (050 M)
~ I ~
~<-ilcn{ UI ~

r r r. ~_~
All
A13+

(0,0010 M)
cnw

31R

it ~~ ~
CfiIT ~

ClI<.'"GI~ ~

-ffi

iwr 25 C ~ ire cnl ~ iwr ~ it ft;m:

iwr ~
3fu:

~-mu ~ iwr fcrqq ~

~I
(~ TJ7.IT ~ : EO

Ni 2 +/ Ni

= - 025 V,

EO 3 + / AI = - 166 V) AI 6

56/3

22. What happens in the following activities and why?

(i) (ii) (iii) An electrolyte is added to a hydrated ferric oxide sol in water. A beam of light is passed through a colloidal solution. An electric current
,

is passed through a colloidal solution.

~

r..or or.,
(i) (ii) /Liii)
t.-- ..,::"'/" ..... ,/

M3TI if

CF1T

3lR ern ?

7j[B"

~ ~

if \J1c:1<.iif\J1<1 3-lTcffil~s if ~ ~-~ ~ ~ ct)c:1T~sl fcm<:Rif it wmr $1 ~ m-r ~ ~

ct)c:1T~sl fcm<:Rif it ~ mu ~
<tt ~

~ ~ I
~ I

~/

Explain the following : (i) Low spin octahedral (ii) (iii)

3
complexes of nickel are not known. elements only.

The n-complexes are known for transition CO is a stronger

ligand than NH3 for many metals.

OR
Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : (i) (ii) (iii) [Ni(CN)4J2[NiC14J2[CoF 6J3Co = 27J-1~
L1

[At. Nos. : Ni = 28;

r rr
(i) (ii) (iii) ~ ~

itCfiRUT~~: Lhc:1chl<.! cnT~cffi ~ it .awq ftl:R it 3-l~ ~ ~3TI

mq)

it ~

m n-cnT~q-~ \ifH ~
<tt ~

iI
<tt

i
~

~-m

it ~.

CO fuitug NH3 3l~

<tt "AT,

31f~ ~

f:ikff~f.(9<1 ~ (cnT~cffil) ~ ~ ~cnl~~'if ~ (i) (ii) (iii) [Ni(CN)4J2[NiC14J2[CoF 6J3:

00

3-l1~~<.!1,.. .'L
0

3-lT~C.C1I~ it

if ~

['WJTll] ~

Ni = 28; Co = 27J

56/3

p.T.a.

------,---.-------------

24.

How would you account for the following: (i) (ii) Many of the transition good catalysts. elements and their compounds can act as

The metallic radii of the third (5d) series of transition elements are virtually the same as those of the corresponding members of the second series. There is a greater range of oxidation states than among the lanthanoids. among the actinoids

(iii)

3:rrq H...,

r~r @(f
-B ~

Cf<IT qmur

(i) (ii)

~ ~

3W ~

~
cr ~

q)T ~

crut ~
~ cWt

cr

cmro (5d) ~

~ ~

mm ~

it ~ ~ ~ d~~4r
(iii) 25.
Q~rfl~-51

ctt mm ~ I I1m1 ~
cr .~

iT -::$l(-q<?jrf 3=fCW.IT3TI q)T

31f~

Explain the following observations

(i)

: ethanol is higher than that of

The boiling point methoxymethane.

of

(ii) (iii)

Phenol is more acidic than ethanol.

0-

and p-nitrophenols
cr ~ ~

are more acidic than phenol.

:

r r r. . a:tqc..iich ..i'i
(i) (ii) 11:m ~

q)Tqq~
11:~

it~~

~ qq~
.~ ~ ~ I

-B ~

it

31f~

(iii) 26.

0- 3W p-"'I~~It.h)",Ic1 ~

~.-B

31f~

Complete the following reaction

equations

(i) (ii) (iii)

56/3

II R - C - NH2
C6HsN2Cl

LiAlH4 H2

)
+ H20 --7

+ H3P02

C6HsNH2 + Br2 (aq) --7

8


r rr
(i)

II

~1-;lctl-tU~

it

Tf ~ i: ~
)

LiAlH4 . H20

R - C - NH2

(ii) (iii)
27.

C6HSN2Cl + H3P02

+ H20 ~

C6HSNH2 + Br2 (aq) ~

What are the following substances? them. (i) (ii) (iii)

r

Give one example of each of 3

Cationic detergents Enzymes Sweetening agents

'iC\I"1

rr~.\:

cp:rr

~;): (! .. ~ (!m ( >t\"1q')

CfiT ~-~

-:$<;IQ-tUI

~ <..,11\)1'-'

(i) (ii)

31\.j"I~ctl

l!,~I~.,
~GHII (r"dl~ctll-t) (~)

(iii)
28.

(a)

Define the foll{)wingterms: (i) Mole fraction (ii) Van't Hoff factor 100 mg of a protein is dissolved in enough water to make 100 mL of a solution. If this 'solution has an osmotic pressure of 133 mm Hg at 25 C, what is the molar mass of protein ? (R = ,00821 Latm mol-1 K-1 and 760 mm Hg = 1 atm.)
OR

(b)

(a)

What is meant by : (i) (ii) Colligative properties Molality of a solution

(b)

What concentration of nitrogen should be present in a glass of water at room temperature? Assume a temperature of 25 C, a total pressure of 1 atmosphere and mole fraction of nitrogen in air of 078. [KH for nitrogen = 842 x 10-7 M/mm Hg] 9

56/3

P.T.D.

(a)

Hkjrc1r~d ~ (i)
l1Wr

~ ~

am
~
~
Yo(.l<:-lo(.u~ ~

(ii)

CfR ~

(b)

~
'P1T

mif.:r

cn1

7ffi::
$\ CX-l111

100 mg 1WIT ~ ~ 25 C 1R ~ fcK;r:R CflT

rj
Cf<IT ~

if ~

100 mL fcK;r:R ~ 133 mm Hg m, "ffi mif.:r

CflT

l1Tffi

? 31R

(R = 00821 L atm mol-1 K-1

(a) HkjrC:1r~dit (i) (ii) (b) ~
~
CflT

760 mm Hg = 1 atm.)

3l?rcrr
Cf<IT ~ ~ :

3-lUJ~~

"TT~
.i1

fcK;r:R cn1 ~ ~
fcfi
Cf11l

1R ~

f1rc;mr

if ~
~ ~
KH

rjl~~I\!jrj

CflT ~

25 C ~ 31R ~
I

1 QCl1lr~~o(.

Cf<IT

? ~

31R ~

if .. ,) .. ~

l1Wr

am 078 ~

[rjl~~I\!jrj ~ ft;rQ:

= 842 x 10-'-:7M/mm Hg]

29. (a)

Write chemical equations to illustrate the following name bearing reactions: (i) Cannizzaro's reaction (ii) Hell-Volhard -Zelinsky reaction Give chemical tests to distinguish between the following pairs of compounds: (i) Prop anal and Propanone (ii) Acetophenone and Benzophenone (iii) Phenol and Benzoic acid

(b)

OR
(a) How will you bring about the following conversions : (i) Ethanol to 3-hydroxybutanal (ii) Benzaldehyde to Benzophenone An organic compound A has the molecular formula CSH1602' It gets hydrolysed with dilute sulphuric acid and gives a carboxylic acid B and an alcohol C. Oxidation of C with chromic acid also produced B. C on dehydration reaction gives but-l-ene. equations for the reactions involved.
56/3

(b)

Write 5

10

~~ I 1-

(a)

rrjkjrc1~d

~3TI

cit

'('1<:iI~HCP W-llcp'('UI

W~ ~

(i) (ii) (b)

rrjkjrc1r~d

~H~I~ ctt

~-~-~rC1h1
~ ~

# f~
>WAR
~ ~~sCP

cn1 ~

ft;m: ~-~

'('1<:iI~Hcp ~

~: (i) (ii) ~
31R

# # #
~

Q<:ilcllhlrjlrj

~o;J1llhlrjlrj

(iii)

3l~
(a)
rrjkjrc1r~d ~yid'('UI ~ ~ ~ :

(i) (ii)

cit

3-QI$~Tq+fl~~rjc1

# #
~

~~rc:-s()ls-s

cit

~o;J11lhl.flrj

(b)

men A
~ ~:m
1l'<1T ~

(31TfUq-q:;
~

CSH1602)
CPlafITCK1rC1CP ~

cit

C11

<:iC'.~Cp

~ Qc:cnIQlc1

-B

~-3-il.j~r2.d

B ~
-B 'lft

~ B

C
I

r
C

C ~ ~
~ 'R

~ ~
>rT({f

dY-q~rj

>rT({f mcrr ~ ~

CfiT H~c1lcp'('ul

~-l-B

mm ~

I <:ir?\fQd

3WmT3TI

fc;m:

<:il-\lcp'('UI CfiT I\'II~~

"

?""~

30.

(a)

Draw the structures of the following :

(i) XeF4 H2S207

(ii)

(b)

Explain the following observations: (i) (ii) (iii) Phosphorus nitrogen. has a greater tendency for catenation than

The negative value of electron gain enthalpy is less for fluorine than that for chlorine. Hydrogen fluoride has a much higher boiling point than hydrogen chloride. 5

OR
56/3
11 .

P.T.D.

~~-~1~--------~~-~------~---------------------J1
(a) Draw the structures of the following :
(i)

PCIs (s) 8023

(ii)

(b)

Explain the following observations: (i) (ii) (iii) Ammonia has a higher boiling point than phosphine. Helium does not form any chemical compound. Bi (V) is a stronger oxidising agent than 8b (V).
cfiT

(a)

H~r\1r~~

~,,:qrll~ ~

(i) (ii) (b)

XeF4 H28207
3-fC/ctlChrll cr
cr ~ cx:m'1T ~ : cr ~
31f'i::fCfiWffi ~

H~r~r~~

(i)

rll~~I'Jjrl ~~~Irl

~I~~I"'~ if ~ ~
I
~ cor

(ii)

;t~.uII("+iCh ~.

'Rj~
cor

~. ~
q:q~

~
~

~
31f'i::fCfi

~cp11mm~

(iii)

QI~~I'Jjrl cK1l"'I~S cr mm ~ I

Qj~~I'Jjrl 1:Rj~

31~
(a)

H~r\1r~~

cr

~",-qrll~ ~

(i)

PCIs (s)

(ii)
(b)

80;3-fC/\1IChrll ~
cr ~

H~r\1r~~

31f'iW: ~
~

~
cor

(i) (ii)

~1~lrl

q:q~
~ ~

~
~
>I'if0

mm ~

Qlr~~+i ~

"'1~I~HCh~
~

I
~Y-qI~Ch ~ I

(iii)

8b (V) cr

Bi (V) ~

31f'i::fCfi

56/3

12

97,100