5.

5.1

,
.
.
, .
7%.
10.600 , 126
.


.

,
,

.

, , ,
, .
,

. [: 96/61/
, IPPC]


(.....) 2003 .... ,:

: ,

70

: , ,

:
5.2

.
(26) .

.
,
,
.
5.1:
/

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26

1
2
3
4
5
6
7
8
9
10
1
2
3
4
1
2
3
4
5
6
7
1
2
3
4
5

/ .
. / .
. / .
. / .
. / .
. / .
. / .
. / .
. / .
. / .
./.
./.
./.
./.
. / .
. / .
. / .
. / .
. / .
. / .
. / .

71


.
5.3


,
,
.
,
.
10

.
,
,
.

:

(), () 1 ..
.
.

, 1, 2, 3 4 ,

scrap, ,
()
.
,
, .
1

72


1
.
(65)
.

.
,
.
.
5.2

1:

(m/year)

36.000

/ (tn/year)
Scrap

27.000

8.000

115

scrap

K (m3/year)

21.500

(m3/day)

73

22

 (m3/day)

6,5

1
:

1
. 22m3/day,
.


.
:

scrap

.
.
[: , 1990]
:
,

.

74

 2

2 1.
(46)

.

2 .
1 (, , ,
) ,
.
.
5.3

1:

49.523

15.840

(tn/year)

/ (tn/year)

6.300

5.000

10.700

250

700 C

N2

-
-

75

K (m3/year)

8.160

(m3/day)

4,8

(m3/day)

4,6

2 :

( 4,8 m3/day).

,
,
.

2 :

(1.320tn/year)

(60tn/year)
(40tn/year)
(50tn/year)
(300 kg/day)
.

,
,
.
.

76

 3

3
. 1
2 850 .

,
:

1. :
. , ( )
,
,
. , ,
.

2. :

,
.
,
.

3. :
( )

.
foil .

4. foil:

3.
5.

6. HF H2SO4
7.

77

 5.1:

3.
5.4 3
.3:
(/year)

61.000

92.000
(foil )
40.000
tn/year
/ (tn/year)

100.000

12.000

6.000
/year 70.000


-

-

-

-

78

foil

HF H2SO4

-
-
-
K (m3/year)

610.000
-
-

-
-
707
(m3/day)
(m3/day)
85

15m /week, ,

.
3

,
, :

, 50tn/year

, 900tn/year

79

160tn/year
.

,
:

,
10.000tn/y
ear

,
300tn/year

,
250
/year

80

, 10tn/year

,
800tn/year

,
.
1.

(
)

, :

1.

10mm

81

2.

3.


4.

2.

COD, .
:
1.

pH=6

2.

pH=8

3.

4.

5.


6.

7.

500tn/year, .

.
/

.
5.5
3

pH

7,8

82

COD (mg/l)

118

BOD (mg/l)

35

TDS (mg/l)

1.400

TSS (mg/l)

31,4

Al (mg/l)

1,9

Cu (mg/l)

<0,2

Mn (mg/l)

<0,2

Fe (mg/l)

0,37

Cl- (mg/l)

179

3
, 4 3

.
4 foils

, , .
,
.
. ,
5, 6, A7, 8 9
,

.

5 .
5

5

. (250) ,

.

83

1.

:
(
) .

2. - :
:
(, )

( )


,
( )

3. :
(,
..).

4. :

.

5. :
:

.
, ,
( )
)

180 - 200 C
.
5.6 5
5:

(tn/year)
10.800
1.572
1.512
1.824

84

/
4.644

12.960

960

72
Styrfoam
912

120

144

(tn/year)
PDI

3,8
4,8
24
0,7
2,1
2,1

-
-
-
-
- ,
-
-
-
-

-
-

480 oC

&

3
K (m /year)
9.000

-

- .
-
-
(m3/day) 9,5
(m3/day)
25

9 m3/day (
, , )

85

0,5 m3/day (
,
)

( 9,5 m3/day)
,
.

5

:

528 tn/year,

16.800 kg/year,

Al 192 tn/year,

7.200 kg/year,

43.200 kg/year,

Al

48 tn/year,

4 tn/year

40 kg/day

,
, :

0,5 kg/day

0,33 kg/day

86

1780 kg/day,

5 .
,
.
.
:
1. pH=8 NaOH HCl
( )
2. pH>9
3.
4.
5.

6. pH=7
7.
8.

9.

10.



500tn/year, .


.

87

 5.7
4. (, 2009)

pH
COD (mg/l)
TDS[mg/l]
TSS[mg/l]
TVS[mg/l]
SO4 - [mg/l]
SO3 - [mg/l]
PO4 -P[mg/l]
Ptotal [mg/l]
CN-[mg/l]
Mg (mg/l)
Cr (mg/l)
Cu (mg/l)
Mn (mg/l)
Fe (mg/l)
Ni (mg/l)
Pb (mg/l)
Zn (mg/l)
Cl-[mg/l]

[mg/l]
3- -N (mg/l)
NH4+ -N(mg/l)

: 4

4,5
5,63
40,1
118
38.025
27.370
276
388,3
41,3
45
6400
3700
1,1
<1.0
4,55
0,04
21,2
2,56
0,055
0,024
130
80
1,463
0,912
0,771
0,384
0,714
0,903
0,897
1,977
1,630
1,139
0,38
0,470
20.000
10.800
0,113
13
1,49

0,63
16
1,06

5.7

, (Mn, TSS)
.

,
.
.


.
,
.

88

. 10, ,

,
.

.
.
10
10
10
.
, , ,
.
(35) ,
300tn .

10
Teflon
.
1. Teflon :

rolle machine

Teflon

Teflon

Teflon.

89

 5.2
Teflon .9, 2009
2. :

90

 5.8 10
10:
(tn/year)

300
/ (tn/year)

370
Teflon
20

rolle machine

- Teflon

Teflon

,

()

( )

-
K (m3/year)
1.000

Teflon



0,4
(m3/day)
(m3/day)
3,5
-

10

Teflon. T Teflon
, 0,4 m3/day,
.

91

 5.9
10 (, 2009)
:10

Ph
8,090
[mS]
1,079
COD (mg/l)
14400
TDS[mg/l]
10923
TSS[mg/l]
5200
TVS[mg/l]
4400
TFS[mg/l]
800
SO4 [mg/l]
400
S2 [mg/l]
0.08
PO4 -P[mg/l]
5,05
Ptotal [mg/l]
1,5
CN [mg/l]
<0.010
Cr (mg/l)
0
Cu (mg/l)
0
Mn (mg/l)
0
Fe (mg/l)
0
Ni (mg/l)
0
Cd (mg/l)
0,021
Pb (mg/l)
0,21
Zn (mg/l)
4,186
F [mg/l]
0,26
ClO2[mg/l]
>2
Cr[mg/l]
<0.010
[mg/l]
3,2
2 -N (mg/l)
0,34
3 -N (mg/l)
34
+
NH4 -N(mg/l)
5,7
org N (mg/l)
56,7

10 :

92

 10
. Teflon .

.
:

Teflon 80%
.

.
.
3tn/year,
.

93

5.4

,
,
,
.
.
, IPPC 17%
46%
.

, ,
, , ,
, - .
4
.

1, 2 ... ,
:

.
1

1
,
1.300.000 tn/year .
(90) 8.000m3/year

53.500 m3/year .


.

94


1
.
) :

1. :
, ,
.

2. :

. .

3.
4. : ,
-

( ,
,
). .

5. :
.
)

1.

:
8mm .

2.

:
-
60mm x 35mm.

3.

:
.

4.

:
800C
8mm .

5.

8mm 4-6%
.
.

95

6.

coils: coils

.

7.

: coils

1.

2.

1080mm 8mm.

3.

450C
.

4.

5.

:
coils,
.

.

. ,
.
5.10

10:

(tn/year)

8mm
975.269

74.790

26.656


24.990

4.760
/ (tn/year)

99.198

Scrap

19.206

198
Scrap
Scrap
19.206


29.106

96

4.356
18.414
8.118
1.98

 5.10 1 ()

-

-
-

-
-

-
-
-

- /
-

-
-

-
-
- /

800C



.
coils,

450C

coils,

- -
K (m3/year)

61.500
-

97

-
-

13,6
(m3/day)
(m3/day)
9
-

, 80 m3/

,
.

,
, :

, 4tn/year,

, 330
tn/year .

630.000kg/year,

, 630.000tn/year,

98

600.000kg/year,

, ,

111.500kg/year

,
, 44.000kg/year

, ,
, 230.000kg/year

,
, 110.000kg/year

40.000kg/year, 85.000kg/year,
25.000kg/year, 25.000kg/year,
1.000kg/year, ,
,

500.000kg/year

500kg/year

,
10.000kg/year

.
,
,
, .
:

,
,

, , .

99

, 45tn/year,
.

.
(3)
. , 2
, , 3
4 ,
.
, , ,
, ,
3 PVC,
4 , .
2


. ,

.
2

100


2 , ,
,
. (135)
70.000tn/year.

33.000 m3/year.

2

, , , ,
.
.
) -

1.

2.

700-800 C

3.

, -

4.

: - 4

, , ( )

5.

Schumag
6.

7.

8.

()

9.

10.

11.

101

1.

2.

700-800 C

3.

4.

: 3

5.

Schumag
6.

7.

8.

()

9.

10.

11.

1.

2.

700-800 C

3.

4.

5.

: 4

, , ( )

102

6.

Schumag
7.

8.

9.

()

10.

11.

12.

103

 5.11 2
2:

(tn/year)

, , , ,

42.000

()

23.800

()

7.800

/ (tn/year)

54.600

8.400

(, ,
.)

10.329

9.038

6.456

700-800
C

4 ,
(2)

K (m3/year)

33.000

(
)

104


(m3/day)

135

(m3/day)

7,5

2
:

(
, ,

1-2 )

(
)

(.. )

( 135
m /day)
.
3

.
:

630.000kg/year

, ,
630.000tn/year

1.100.000kg/year,

, , ,

105

, , , ,
81.000kg/year

,
, 110.000kg/year

30.000kg/year

5.000kg/year

.
:

, ,

, , ,
.

2
135 m3/day
15 m3/hr . 10
m3/hr
:

pH:
pH=7
.

:
,

106

 : ,

:
.
,

,
75tn/year .
.

.

3 /

,
.
5.12
2.
2009

pH
COD (mg/l)
BOD (mg/l)
TDS[mg/l]
TSS[mg/l]
Fe (mg/l)
/HC

: 2

8,4
21
6
518
1,5
0,2
4,2

107

5.5

IPPC ,

, -
. ,
. O
:

(CUPOLA)

7
.

1997 9
. 2
.
,


.

(), () 1 ..
.
1

1
PET PP. (200) ,
67.000 m3/year
.


.

108


. ,
PVC PP.
)
:

:
(coils)

:

. H2SO4
,
p, .
.

, , .

:
.

: (patenting)
.
900 C,
400-500 C.

) (PP)
:

109

PP

Extrusion

(50-180 C)

PP: PP
scrap
) (PET)
:

PET

Extrusion:

PET: PET
,
. ,

110

 5.3 ,
1

.

5.13 1
1:
(tn/year)

83.720
PET
6.500
PP
6.000
/ (tn/year)

92.000
PET
6.500
PP
6.000

-




H2SO4



900 C

450C

(coils)

PP
PP

extrusion


(50-180 C)

scrap
PP
PET

111

extrusion
& .
.

, , / scrap
K (m /year)
67.320

-

-

242
(m3/day)
(m3/day)
20
PET

1 :

pH

, 242m3/day,

.

1


.



.

:

pH Ca(OH)2

112

.

.
1.000tn/year .
1
.
.

5.14
1.
2009
:.5

pH
7,7
COD (mg/l)
14
BOD (mg/l)
18
TDS[mg/l]
1.375
Cr total [mg/l]
0,04
Fe
0,04
Zn(mg/l)
0,06
Mn (mg/l)
1,1
Pb (mg/l)
0,03

0,7

p<9,0,
COD<120 BOD <40
.
MBR,
6
98%.

113

 2

.
,
.

5%
H2SO4 20% CuSO4 35-40 C .

.
,

.
3 4
.

.
5 ,
,
.

( 40)

,
.
, , ,
, ,
, ,
. , 6
7
.


,

.
()
. ,

114

5.6

, (26)
.
..., 1997 (51)
.
(26)
1.607 m3/day.

, ,
5.1.

21,4 m3/d
1%

554,9 m 3/d
34%
829,7 m 3/d
52%

209,0 m 3/d
13%

5.1

(19)
, 1540 m3/day.
(8), , 67,1 m3/day.

95,8%.

, ,

115


,
5.2.

116

 5.14:

m3/d

m3/d

/ .

6,500

22,000

. / .

4,600

4,800

. / .

83,000

. / .

2,000

. / .

25,000

. / .

. / .

tn/y

0,000

0,000

707,000

500,000

25,000

0,000

9,500

5,000

10,000

26,000

0,000

42,000

12,500

60,000

. / .

2,500

20,000

1,200

. / .

17,000

2,500

50,000

10

1
0

. / .

3,500

0,400

3,000

11

./.

9,000

13,600

45,000

12

./.

7,500

135,000

75,000

13

./.

45,000

60,000

3,000

14

./.

2,500

0,400

7,200

1.000,00
0

15

. / .

20,000

242,000

16

. / .

5,400

17

. / .

1,000

4,000

5,200

0,010

0,000

18

. / .

10,000

19

. / .

257,000

2,200

80,000

300,000

72,000

20

. / .

5,000

6,600

0,000

21

22

. / .

0,300

0,048

0,000

0,500

5,000

1,500

23
24

0,900

7,160

2,000

8,400

0,100

1,200

0,100

0,000

25

22,000

1,500

26

6,000

7,600

1.911,
400

1.607,318

117

800,0
707,0

600,0

500,0

400,0
300,0

300,0
242,0
200,0
135,0
100,0

60,0

7,6

1,5

0,1

7,2

5,0

0,0

6,6

4,0 0,010 2,2

0,4

13,6

10

0,0

0,4

12,5 20,0 2,5

9,5

25,0

4,8

26,0

22,0

(m3/day)

700,0

5.2: (m3/day)

118

(7)

(3)
()

(6)

(3) (
)

(2) , ,

.

(5)
.

1.911tn/year. 4,
,
.

.

119

 5.15:

(m3/day)

A
1

A
2

A
3

A
4

A
5

A
6

A7

A8

A9

10

X1

X2

X
3

X4

22,0

4,8

707,
0

25,0

9,5

26,0

12,5

20,0

2,5

0,4

13,6

135,
0

60,0

0,4

pH

UV

H2O2

5.15:
()

120

121


(m3/day)

242,
0

4,0

0,01

2,2

300,
0

6,6

0,05

5,0

7,2

0,1

1,5

7,6

pH

UV

H2O2

: , : , : , : , : , :

122

123