AZODYES

SALT C6H5O-Na+
Na(s) NaOH

2,4,6-TRIBROMO PHENOL
(White precipitate) Br2 (aq) Neutral FeCl3 (aq)

PHENOL complex
(Purple solution)

DIAZONIUM SALT C6H5N2+ClNaNO3/H2SO4 T<10oC

PHENOL C6H5OH

BENZOIC ACID C6H5COOH

MNO4-/H2SO4 (aq) Reflux

ARYLAMINE C6H5NH2
Sn/c.HCl Reflux

AMMONIUM SALT RNH3+Cl(POLY)AMIDE RCONH2

Acid chloride

ALCOHOL + CARBOXYLIC ACID

HCl (aq) Reflux

ALCOHOL + SALT
NaOH (aq) Reflux

ALKYLBENZENE C6H5R

NITROBENZENE C6H5NO2 RX/FeX3

c.HNO3/c.H2SO4 50-60oC Br2/FeBr3

HCl (aq)

(POLY)ESTER R COO - R
ROH/H2SO4 Cat. Reflux RO-Na+/H2SO4 Cat. Reflux PCl5(s)

BROMOBENZENE C6H5Br

ARENE C6H6

AMINE CnH2n+1NH2 R NH2

Alcoholic NH3 HCN/KCN

LiAlH4 NaBH4

CARBOXYLIC ACID CnH2n+1COOH H2O/HCl (aq) R - COOH

Reflux LiAlH4 NaBH4 H+/Cr2O72Reflux

ACID CHLORIDE RCOCl

Na(s) NaOH

CYCLOALKANE CnH2n

Pt/Ir cluster On Al2O3 400-600oC SiO2 or Al2O3

Pt/Ir cluster On Al2O3

NITRILE R-CN
HCN/KCN

SALT RCOO-Na+

ALKANE + ALKENE CnH2n+2 + CnH2n

ALKANE CnH2n+2
H2 / Ni(s)

Br2 /UV light X2 HX

Pt or Heat SiO2

HALOGENOALKANE CnH2n+1X H+/Cr2O72Alcoholic Warm R-X

NaOH
Aqueous NaOH Reflux

BRANCHED ALKANE CnH2n+2

ALKENE CnH2n C=C

H2O(g) (steam) H3PO4 / T>100oC XS Conc. H2SO4 Reflux

ALCOHOL CnH2n+1OH R - OH
Na(s) NaOH

PCl5(s) NaBr/H2SO4 I2/P y

ALDEHYDE CnH2n+1CHO LiAlH4 R - CHO

NaBH4

2,4-DNP

I IIy IIIy
+

H+/Cr2O72Warm LiAlH4 NaBH4 H /Cr2O7 Reflux

2-

KETONE R CO - R NO REACTION

2,4-DNP

2,4-DINITROPHENYL HYDRAZONE
(Yellow/orange crystalline solid)

ADDITION POLYMERS -[CH2-CH2]NPaul T-C 2006

SALT RO-Na+