S.No.

Time interval
t, (s)

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19

Vol. of 0.1 N HCl

used, (ml)
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5

Conc. of NaOH, C
in effluent, (mol/l)

4.2
2.8
2
0.8
0.4
0.8
0.2
1
0.6
0.8
1
0.2
0.4
0.2
0.4
0.8
0.2
0.2
0.2

Ct
(mol.s/l)

0.084
0.056
0.04
0.016
0.008
0.016
0.004
0.02
0.012
0.016
0.02
0.004
0.008
0.004
0.008
0.016
0.004
0.004
0.004

0.42
0.28
0.2
0.08
0.04
0.08
0.02
0.1
0.06
0.08
0.1
0.02
0.04
0.02
0.04
0.08
0.02
0.02
0.02
1.72

(C.t)

Column1

Column2

Column3

Variance, (s) =

Area under the Cpulse

curve = (C.t)

1.72

(tCt) =

97.96

/ t =

(tCt)/(Ct)
56.95348837

/2t =

6721.28

D/uL>0.01

Mean residence time

t (s) =
(tCt) =

E= C/(C.t)
(per second)
0.097674419
0.065116279
0.046511628
0.018604651
0.009302326
0.018604651
0.004651163
0.023255814
0.013953488
0.018604651
0.023255814
0.004651163
0.009302326
0.004651163
0.009302326
0.018604651
0.004651163
0.004651163
0.004651163

(tCt/Ct) - t
664.0210925

0.204711017
0.102355508

Large Dispersion Model

tCt
(mol.s/l)
13.86
10.64
8.6
3.84
2.12
4.64
1.26
6.8
4.38
6.24
8.3
1.76
3.72
1.96
4.12
8.64
2.26
2.36
2.46

tCt
(mol.s/l)
457.38
404.32
369.8
184.32
112.36
269.12
79.38
462.4
319.74
486.72
688.9
154.88
345.96
192.08
424.36
933.12
255.38
278.48
302.58

Time taken
t, (s)
33
38
43
48
53
58
63
68
73
78
83
88
93
98
103
108
113
118
123

Fitting the Large Dispersion Model:

t=56.95348837 s
L = 325.8 cm.
Dia = 1.2 cm.
t = L/u

u = L/t=5.72045733 cm/s
D = 273.036 cm/s.

D/ul=0.1465>0.01

S.No.

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19

Et
Time taken
t, (s)
(per second)

33
38
43
48
53
58
63
68
73
78
83
88
93
98
103
108
113
118
123

0.010099934
0.011937639
0.013006837
0.013411362
0.013299966
0.012819358
0.012094952
0.011225881
0.010286448
0.009329983
0.008393147
0.007499871
0.00666466
0.005895211
0.005194438
0.004561988
0.003995367
0.003490754
0.003043584

=t/t

0.57942
0.667211
0.755002
0.842793
0.930584
1.018375
1.106166
1.193957
1.281748
1.369539
1.45733
1.54512
1.632911
1.720702
1.808493
1.896284
1.984075
2.071866
2.159657

1.241187
0.978593
0.844319
0.775031
0.743745
0.737619
0.750132
0.777925
0.81938
0.873945
0.941778
1.02357
1.120452
1.233957
1.366015
1.518961
1.695574
1.899121
2.133413

0.12

E (per second)

0.1
0.08
0.06
0.04
Series2
0.02
0
0

20

40

60

80

Time,t(s)

100

120

140

0.09

Conc. of NaOH,C(mol/l)

0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
Series2

0
0

20

40

60

80

Time interval,t(s)

100

120

140

Series1

140

2.5

Etheta

2
1.5
Series1

1
0.5
0
0

0.5

1.5

theta=t/t

2.5

0.016
0.014

Et(per sec)

0.012
0.01
0.008
Series1
0.006
0.004
0.002
0
0

50

100

time,t(s)

150