Give the amine and the coupling compound needed to synthesize the following azo dyes.

Indicate the number of moles needed for each. 1. Para red

OH N

Amine:

Coupling agent:

NO2

2. Ponceau 2R
HO H3C CH3 N SO3H

Amine:

Coupling agent:

SO3H

3. Disperse Blue 2B
HO3 S SO3H HO 3S N N OH NH2 SO3 H

Amine:

Coupling agent:

N NH2 OH

STRUCTURE ELUCIDATION Resveratrol a polyphenol found in the skin of red grapes and is a constituent of red wine having the formula C14H12O3. Test/Reagent Ignition test concentrated H2SO 4 (3) KMnO4 (5) Observation/Visible Result (1) soluble Yellow solution, negative (4) Inference Aromatic ring is present (2) Saturated part is absent alkene part is present 3,5-disubstituted phenol is present Highly colored complex para-substituted phenol is also present (6) 2,4-DNPH 5% NaHCO3 (9) White to yellow/orange crystal Yellow solution, no ppt NVR negative Aromatic ring is present (7) (8) Ester group is absent