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Table1.

Some characteristics of employed dyes


Dyes

Chemical Formula

Weight
-1

MW(g.mol )

max(nm)

(L.cm-1.g-1)

Methylene blue (MB)

356

664,5

0,1856

Crocein Orange G (OG)

350,33

483

0,069

Alizarin Red S (AS)

360,28

265

0,0281

Table.2. the grain size of samples with different mol percentages of vanadium doped zinc oxide
ZnO-Vx%

G(nm)

28,58

28,75

23,45

22,44

25,17

19,87

d())002(

2,6016

2,6057

2,6124

2,6132

2,6089

2,610

c ()

5,2032

5,2115

5,2249

5,2264

5,2179

5,22

Table,3, Band gap energies of samples with different mol percentages of vanadium doped zinc
ZnO-Vx% x =

Eg(eV)

3,210

3,198

3,191

3,179

3,133

3,124

Table,4, Apparent kinetic values for the degradation of MB


Catalysts

Adsorption
Percentage
(%)

Adsorption
kinetic
constant ka
(10-3min-1)

Degradation
kinetic
constant kr
(10-3min-1)

t1/2
(min-1)

Correlation
coefficient
(R2 )

Pure ZnO

13,57

9,70

26,82

31,42

0,995

ZnO-V1%

9,34

12,02

32,81

26,01

0,997

ZnO-V2%

13,92

13,43

35,64

24,03

0,998

ZnO-V3%

10,35

13,79

45,00

19,04

0,996

ZnO-V4%

10,15

8,37

29,03

30,20

0,989

ZnO-V5%

5,21

9,04

14,45

56,19

0,999

TiO2DegussaP25

10,34

7,26

27,21

31,42

0,984

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