Cu 1: Cho 150ml dd Ba(OH)2 vo 250 ml dung dch Al2(SO4)3 xM thu c 42,75 gam kt ta.

Thm tip 200ml dd

Ba(OH)2 1M vo hn hp pw th lng thu c l 94,2375 gam. Gi tr ca x l: A. 0,1 B. 0,35. C. 0,45. D. 0,55
Bi 2: Cho 20 g hh X gm Fe, Fe2O3, FeO, Fe3O4 ha tan trong 300ml dd H2SO4 1M thu c 0,15mol H2 v dd D. Cho
dd D tc dng vi Ba(OH)2 d, lc kt ta v em nung ngoi khng kh n khi lng khng i thu c m gam
cht rn. Xc nh m. A. 92,1 gam B. 87.5 gam. C. 70,1 gam D. 93,9 gam
Cu 3: A l mt este c CTPT l: C16H14O4. 1 mol A tc dng vi 4mol NaOH. Mui natri ca axit cacboxylic thu c
sau pw x phng ha nu em t chy ch thu c CO2 v xa. A c cu to i xng. A l:
A. este ca axit sucxinic ( HOOC-CH2-CH2COOH). B. Este ca axit malonic vi phenol v cresol.
C. Este ca axit oxalic vi hai cresol.
Bi 4: C 100ml dd hh 2 axit H2SO4 v HCl c nng tng ng l 0,8M v 1,2M. Thm vo 10 gam bt hh Fe,
Mg, Zn. Sau pw xong, ly lng kh sinh ra cho i qua ng s ng a gam CuO nung nng. Sau pw xong hon ton,
trong ng cn li 14,08 gam cht rn. Khi lng a l: A. 12,0 gam B. 13,6gam. C. 16,8 gam C. 15,2 gam
Bi 5: Cho hp cht thm Cl-C6H4-CH2-Cl tc dng vi dung dch KOH ( long, d, t0) sp thu c l:
A. KO-C6H4-CH2-OH. B. HO-C6H4-CH2-OH.
C. HO-C6H4-CH2-Cl. D. Cl-C6H4-CH2-OH
Bi 6: Cho tt c ng phn mch h, c cng CTPT C2H4O2 ln lt tc dng vi Na, NaOH, CH3OH ( iu kin
thch hp). S phn ng xy ra l: A. 5
B. 3
C. 4.
D. 6.
Bi 7: Cho dy cht v ion: Zn, S, Fe3O4, SO2, N2, HCl, CH3CHO, Fe(NO3)3, Fe2+, Cu2+, Cl-, S cht v ion va c c
tnh oxi ha v tnh kh l: A. 6 B. 9. C. 7. D. 8.
Bi 8: Cho cc dd sau: Na2CO3 , NH3, NaAlO2, NaOH, FeCl3, Na2S. S lng dung dch c th dung d kt ta hon
ton Al3+ trong dung dch hn hp gm NaCl, KCl, AlCl3 di dng Al(OH)3 l: A. 3 B. 4. C. 6. D. 2
Bi 9 : X l mt tetrapeptit. Cho m gam X phn ng va vi 0,3 mol NaOH thu c 34,95 gam mui. Phn t khi
c X c gi tr l : A. 324. B. 432. C. 234. D. 342.
Bi 10: un nng hn hp gm 1 mol HCOOH, 1 mol CH3COOH v 2mol C2H5OH t0C ( trong bnh kn dung tch
khng i) n trng thi cn bng th thu c 0,6 mol HCOOC2H5 v 0,4 mol CHCOOC2H5. Nu un nng hn
hp gm 1 mol HCOOH, 3mol CH3COOH v a mol C2H5COH iu kin nh trn th n trng thi cn bng th thu
c 0,8 mol HCOOC2H5. Gi tr ca a l: A. 12,88 mol. B. 9,97 mol. C. 5,6 mol. D. 6,64 mol.
Bi 11: Cho 5,87 gam hn hp Ba v K c t l s mol nBa : nK = 4 : 1 vo 100ml dung dch Fe2(SO4)3 0,2 M thu c
kt ta A, kh B v dung dch C. em kt ta A nung trong khng kh n khi lng khng i thu c m gam cht
rn khan. m c gi tr l : A. 12,53g. B. 11,72g
C. 9,39g D. 13,32 gam
Bi 12 : Cho cc cht sau : C2H5OH, CH3COOH, C6H5OH, C2H5ONa, C6H5ONa, CH3COONa. Trong cccht , s cp
cht phn ng c vi nhau ( iu kin thch hp ) l : A. 4 B. 6 C. 5. D. 3
Cu 13 : Cht hu c X mch h, khng cha lin kt (-O-O-) v c cng thc phn t l C3H6On. Bit X ch cha mt
loi nhm chc. S ng phn cu to c th c ca X l : A. 4. B. 6 C. 7. D. 5
Cu 14 : Cho hn hp gm 25,6 gam Cu v 23,2 gam Fe3O tc dng vi 400ml dung dch HCl 2M n khi phn ng
hon ton thu c dung dch A v cht rn B. Cho dung dch A phn ng vi dung dch AgNO3 d to ra kt ta X.
Lng kt ta X l : A. 114,8 gam B. 32,4 gam C. 125,6 gam D. 147,2 gam
Bi 15 : t chy hon ton hn hp X gm 0,02 mol FeS2 v 0,01 mol FeS ri cho kh thu c hp th ht vo dung
dch KMnO4 va , thu c V lt dung dch c pH = 2. Gi tr ca V l : A. 4 B. 6. C. 2 D. 8
Bi 16 : ha tan 19,5 gam hn hp X gm Na2O v Al2O3 vo nc c 500ml dung dch Y. Dn t t kh CO2 vo
dung dch Y ng thi khuy u cho n khi bt u thy xut hin kt ta th dng li, thy th tch kh CO2 dng
( ltc) l 2,24 lt. Khi lng Na2O v Al2O3 trong hn hp X ln lt bng :
A. 6,2 gam v 13,3 gam B. 12,4 gam v 7,1 gam
C. 9,3 gam v 10,2 gam
D. 10,85 gam v 8,65 gam
Bi 17: t butan, cht v c v iu kin phn ng c . S phng trnh pw ti thiu iu ch glixerol l:
A. 5. B. 4. C. 7 v D. 6.
Bi18: phenol pw c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br2, (CH3CO)2O, CH3COOH, Na,
NaHCO3, CH3COCl: A. 4. B. 6. C. 5
D. 7.
Bi 19: th t tnh bazo ca dy: (I) Amoniac, (II) Anilin; (III) Metylamin;(IV)imetylamin; (V) iphenylamin; (VI)
nc: A. (VI) < (V) < (II) < (I) < (III) < (IV). C. (V) < (II) < (VI) < (I) < (III) < ( IV)

Bi 20: Ha tan ht 10,24 gam Cu bng 200ml dung dch HNO3 3M c dung dch A. Thm 400ml dd NaOH 1M vo
dd A. Lc b kt ta, c cn dung dch ri nung cht rn n khi lng khng i thu c 26,44 gam cht rn. S
mol HNO3 phn ng vi Cu l: A. 0,48 mol. B. 0,58 mol. C. 0,56 mol D. 0,4 mol
Bi 21: Ly 13,14 gam Cu vi 250 ml dd AgNO3 0,6M mt thi gian thu c 22,56 gam cht rn A v dd B. Nhng
thanh kim loi M nng 15,45gam vo dung dch B khuy u n khi pw hon ton thu c dd ch cha 1 mui duy
nht v 17,355 gam cht rn Z. Kim loi M l: A. Zn B. Mg. C. Pb
D. Fe.
Bi 22: Ha tan a gam Al vo 450ml dd NaOH 1M thu c 13,44 lt H2 (ktc) thu c dd A. Ha tan b gam Al vo
400ml dd HCl 1M thu c 3,36 lt H2 (ktc) v dd B. Trn dung dch A vi dung dch B n pw hon ton th thu
c m gam kt ta. Gi tr ca m l: A. 31,2 gam B. 3,9 gam. C. 35,1 gam. D. 7,8 gam
Bi 23: t a mol X l trieste ca glixerol v axit n chc, mch h thu c bmol CO2 v cmol H2O, bit bc = 4a.
hidro ha m gam X cn 6,72 lt H2 (ktc) thu c 39gam X. Nu un m gam X vi dd 0,7mol NaOH n pw sau y
c cn cn thn dung dch sau pw th thu c bao nhiu gam cht rn? A. 57,2g B. 52,6g C. 53,2g D. 61,48g
.Bi 24: Lu hunh si 4500C, nhit no lu hunh tn ti di dng phn t n nguyn t?
A. 4500 C. B. 14000C. C. 17000C. D. nhit phng.
Bi 25: Thy phn cc cht sau trong mi trng kim: 1. CH3CHCl2 2. CH3 COO CH = CH CH3
3. CH3 COO- CH2CH=CH2. 4. CH3 CH2CCl3. 5. (CH3COO)2 CH2. 6. CH3COO-CHCl-CH= CH2.
S cht thy phn trong mi trng kim cho sp c pw trng gng l: A. 4 B. 5 C. 3 D. 6
Bi 26: Cho 24 gam Cu vo 400ml dd NaNO3 0,5M, sau thm 500ml dung dch HCl 2M, thu c dd X v c khi
NO thot ra. Th tch kh NO thot ra ( ktc) v th tch dd NaOH 0,5M thi thiu cn kt ta ht Cu2+ trong dd X
l: A. 4,48 lt v 1,2 lt. B. 5,6 lt v 1,2 lt. C. 4,48 lt v 1,6 lt. D. 5,6 lt v 1,6 lt.
Bi 27: Hp cht Q ( cha C, H, O) c iu ch theo s :
+Cl2 ( 1:1)
dd Br2
+ NaOH
+KOH/ROH
+ CuO
propen
X
Y
Z
T
Q
- 2HBr
5000 C
t0
Nu ly ton b lng hp cht Q ( c iu ch t 0,2 mol propen) cho tc dng vi dd AgNO3/NH3 d th lng kt
ta thu c l: A. 82 gam. B. 75,4 gam C. 43,2 gam. D. 60,4 gam
Bi 28: t chy 1,6 gam mt este E n chc c 3,52 gam CO2 v 1,152 gam H2O. Nu cho 10 gam E tc dng vi
150ml dd NaOH 1M, c cn dung dch sau pw thu c 16 gam cht rn khan. Vy CT ca axit to nn este trn c th
l: A. CH2=CH-COOH. B. HOOC(CH2)3CH2OH C. HOOC-CH2-CH(OH)-CH3 D. CH2=C(CH3)-COOH.
Bi 29: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150ml dd Ba(OH)2 1M. C cn dd sau pw thu c
m gam cht rn. Gi tr ca m l: A. 18,95 B. 36,40 C. 26,05 D. 34,60
Bi 30: X l dung dch Al2(SO4)3 ; Y l dd Ba(OH)2 . Trn 200ml dd X vi 350ml dd Y thu c 8,55 gam . Trn
200ml dd X vi 500ml dd Y thu c 12,045 gam . Nng mol ca dung dch X v Y ln lt l:
A. 0,1M v 0,075M B. 0,1M v 0,2M C. 0,075M v 0,1M D. 0,05M v 0,075M
( THE END)

Bi 1:HD: ta thy nu lng kt ta sau cng nu cha xy ra hin tng kt ta tan th lng kt ta se4x l rt ln
( t cc bn c th tnh c theo s mol ca Ba(OH)2 ).
Vy c kt ta tan. t nAl2(SO4)3 = a th khi lng kt ta sau cng l:
nAL(OH)3 = 4nAl 3+ - nOH- = 8a 0,7 mol. nBaSO4 = 3a. mol. Vy tng kt ta:;
mkt ta = 3233a + 78(8a 0,7) = 94,2375 a = 0,1125 mol. x = 0,45 M.
Bi 2: HD1 : Quy i v hh Fe v Fe2O3 c m = 20g. u tin: Fe2O3 + axit Fe3+ + . Sau Fe + 2Fe3+ 3Fe2+.
(1). V pw c kh thot ra nn chc rng Fe cn d pw vs H+ to kh H2. C: nFe d = 0,15 mol. S mol H+ pw vi
oxit st III l: 0,32 0,152 = 0,3 mol nFe2O3 = 0,3 6 = 0,05 mol. nFe3+ = 0,1 mol nFe p (1) = 0,05 mol. Bo
ton nguyn t Fe c: nFe(OH)2 = 0,15 + 0,1 + 0,06 = 0,3 mol cht rn thu c gm: 0,3 mol BaSO4 v 0,15 mol
Fe2O3 m = 93,9 gam.! Chn!
HD2: trnh t pw: st III + axit mui st III (1). St II oxit + axit mui st II (2).
St + st III oxit mui st II. (3). St + axit mui st II + kh. (4).
Vy sau pw ch c mui st II vi s mol = s mol axit = 0 .3 mol. T tnh c khi lng kt ta sau khi nung!
Cu 3: HD: Ch cn da vo dng: t chy ch thu c CO2 v xa thy ch C tha mn, v cc p n khc u
to them nc.
Cu 4: HD: nH2SO4 = 0,08 mol, nHCl = 0,12 mol. => nH+ = 0,28 mol. Nguyn t trung bnh: M + 2H+ => M2+ + H2 .
G/s hh ton l Zn ( Mmax ) nn s mol ca 10g hh lun ln hn: 0,1538 mol nn pw u axit pw ht, s mol H2 tnh
theo H+ = 0,14 mol. Tip n ly mol kh = 0,07 mol kh n pw. C a = mhh rn + mO = 15,2 gam!
Cu 5: D
Cu 6: Gii: HO-CH2CHO + {Na, CH3OH}; CH3COOH + {Na, NaOH, CH3OH}, HCOOCH3 + {NaOH}
Cu 7: p n: D. 8
Bi 9: HD : (4A 3H2O) + 4NaOH = mui + 1H2O X = ((34,95 + (0.3/4)*18 0,3*40 ) / (0,3/4) = 324. Chn A.
Bi 10: Gii : Pw : axit + ru este + nc. Vi ru l 1 mol, nc l 1 mol v axit, este nh u bi. ng vi mi
axit-este ta c KHCOO... = 3/2. KCH3COO = 2/3. t x, y l s mol ru v nc cn li TH2. th ri vi HCOOH c :
THCB : axit ( 0,2 mol) + ru ( x mol) este ( 0,8 mol) + nc ( y mol). Suy ra : (0,8.y)/(0,2.x) = 1,5. tng t vi
CH3COOH. Ta tnh c x = 7,253 mol v y = 2,72. Vy a = x+y = 9,97 mol.
Bi 11: p n B, 11,72 gam !
Bi 12: HD : theo th t l : (1 ;2) ( 2 ;4), ( 2 ;5) v (3 ;4) Chn A.
Cu 13: HD : d thy n 3. TH n = 1 : C3H6O, ancol = 1, ete = 1, andehit = 1, xeton = 1. n = 2 th axit = 1, este = 1,
ancol = 1. TH n = 3 loi. Vy c 7 cht Chn C.
Cu 14: HD : ta cn cht rn B nn trong dung dch nFe2+ = 0,1 3 = 0,3 mol. nCu2+ = ? ( khng cn tnh ). Theo bo ton
th nCl- = 0,8 mol. Nh vy kt ta l : m = 0,8 143,5 + 0,3 108 = 147, 2 gam.
Cu 15 : p n A.
Cu 16 : HD : CO2 + NaOH NaHCO3 . Dng 0,1 mol CO2 pw vi NaOHd ta thy lng CO2 pw va vi
NaOH nn s khng to mui Na2CO3 . t : nNa2O = x, nAl2O3 = y th
62 x + 102 y = 19,5 x = 0,15 mNa2O = 9,3 gam

2 x 2 y = 0,1
y = 0,1
mAl2O3 = 10, 2 gam
0

+ Cl2 + H 2O
crackinh
500 C
+NaOH
CH2 Cl CH=CH2
CH2 Cl CHOH CH2 Cl
glixerol
Cau 17 : C 4 H10 C3 H6
+ Cl 2

Cu 18: HD: l: NaOH, Na, Br2, v 2 cht (CH3CO)2O, CH3COCl to este

Cu 19:: hnh nh A.
Cu 20: HD:Gi: nNaOH d = x, nNaNO2 = y. ( do nu NaOH khng d th kl cht rn ln hn 26,44 gam). Ta c:
x + y = 0, 4 ( = nNa )
nHNO 3du = 0, 4 0, 04 0,16 2 = 0, 04

40 x + 69 y = 26, 44
Cu 21: HD: dung bo ton e ta c: ne kl M = nekl Ag = 0,15. khi lng kl bm vo thanh M l:
13 14 + 0,15 108 22 56 = 6, 78 . Vy khi lng M pw l: 15, 45 ( 17,355 6, 78 ) = 4, 785 2 M = 65n .
Cu 22: HD: dd A gm : 0,4 mol NaAl(OH)4 v 0,05mol NaOHd . dd B gm: 0,1 mol AlCl3 v 0,1 mol HCl..
Trn 2 dd vo nhau xy ra cc pw: NaOH + HCl NaCl + H2O (1). NaAl(OH)4 + HCl Al(OH)3 + NaCl + H2O
3NaAl(OH)4 + AlCl3 4Al(OH)3 + NaCl (3). Nh vy tng kt ta: nAl(OH)3 = 0,45 gam mAl(OH)3 = 35,1 gam!.
Cch 2: c: nAl = 0,5 mol mAl(OH)3 ti a = 39 gam. M lng OH- d sau pw trung ha vi HCl cn 0,05 mol nn lng
kt ta b ha tan l 3,9 gam. T chn c C.!
Cu 23: HD: p n B
Cu 24: HD: nhit 1700 hi lu hunh l nhng nguyn t S. 1400 hi lu hunh l nhng phn t S2. 445 lu
hunh si, t0 ny cc phn t ln Sn b t gy thnh nhiu phn t nh. 187C lu hunh lng tr nn qunh nht,
c mu nu. nhit ny mch vng ca phn t S8 b t gy to thnh nhng chui c 8 nguyn t S
nhit 119C, lu hunh nng chy thnh cht rn mu vng, rt linh ng. Tm li chn C.! ( lm chuyn )

Cu 25: HD: gm: 1, 2, 5, 6. : (CH3COO)2 CH2 + 2NaOH 2CH3COONa + HCHO

Cu 26: HD: li b la! NaOH tc dng them vs axit d trong X na l ok!. Chn C.
Cu 27: HD: Chn A. Ch : Q l: CHC-CHO.
Cu 28: HD: Tnh: nCO2 = 0,08 mol; nH2O = 0,064 mol nE = 0,016 mol ME = 100. M este n chc CTPT:
C5H8O2. 10 gam este E tc dng 150ml NaOH 1M t l: 11,5 mui tnh theo este.
TH1: este khng phi mch vng, d thy khng tha mn.
TH2: Este E mch vng. Mui s l; HO-C4H8-COONa. Suy ra CT ca axit l HOOC(CH2)3CH2OH. Chn B!
Cu 29: HD: 2CH3CH(NH3Cl)COOH + Ba(OH)2 (CH3CH(NH2)-COO)2Ba + BaCl2 + 4H2O.
Dng bo ton khi lng l c kq: D. 36,4
Cu 30: HD: ta c pw: 3Ba(OH)2 + 2Al2(SO4)3 3BaSO4 + 2Al(OH)3 .
Nhn xt: nu pw ng theo t l kia hoc Ba(OH)2 d th khi thm Ba(OH)2 kt ta gim.
Nu sau pw ny Al2(SO4)3 d th khi thm Ba(OH)2 kt ta tng.
Vy nu theo bi ra th TH2 xy ra. Theo : Chn C!.
**** CH3CH2ONa > NaOH > . V pH