Professional Documents
Culture Documents
Bohr Atom Model
Bohr Atom Model
What is the structure of atom? How the electrons are arranged in the atom?
The question was first replied by J.J. Thomson by suggesting an atom model.
It states that all the matter are composed of a very small particle called atom which is indivisible.
THIS THEORY FAILS As he was unable to distinguish the different types of particles.
Electrons are embedded within spherically distributed, positive charge (so-called plums in the pudding model) Both the positive charge and the mass of the atom would be more or less uniformly distributed over its size.
The negative charges came from within the atom. A particle smaller than an atom had to exist. The atom was divisible!
SO, Thomson called the negatively charged corpuscles, today known as electrons. Since the gas was known to be neutral, having no charge, he reasoned that there must be positively charged particles in the atom.
In 1909, he with co-workers (Hans Geiger and Ernest Marsden) experimented with streams of alpha particles passing through a thin gold foil. The foil thickness was ~8.6 x 10-6 cm
The foil was so thin that it had to be supported on a glass plate
The plate without any foil was transparent to the alpha particles.
TRANSMITTED BEAMS (LITTLE OR NO DEFLECTION ) B SCATTERED BEAM (SMALL DEFLECTION) C SCATTERED BEAM ( LARGE DEFLECTION)
OVSERVATIONS :
As most of the alpha particles pass through the gold foil, without any deflection, most of the space within the atom is empty. As some of the alpha particles were deflected by large angles, they must have approached to some positive charge region called as nucleus. As very few of the alpha particles experience the deflection, it was concluded that the volume occupied by the nucleus is very small. Since alpha particles, which are comparatively denser, were deflected by the nucleus, it shows that almost the complete mass of the atom must be within the nucleus.
The nucleus is very small positively charged - with the electrons outside the nucleus.
Rutherford explained his experimental results. By considering the solar system - the planets are attracted by the sun under universal gravitation. Yet planets are not pulled into the sun. As they are in motion around the sun and this motion prevents them from being pulled into the sun.
And according to Earnshaw's theorem , a system of charge particle cannot remain at rest in stable equilibrium under the influence of purely electrostatic force.
ATOMIC SPECTRA
When an atomic gas or vapour at low pressure is excited usually by passing electric current through it, the gas/vapour emits radiations of certain specific wavelength only. A spectral of this kind is called line emission spectrum and it consists of a few bright lines on a dark background.
When white light is pass through the same gas/vapour, we observed a bright background crossed by few dark lines signifying missing wavelength or wavelength that are absorbed by gas . They form the line absorption spectrum.
HYDROGEN SPECTRUM
The spectrum of hydrogen atom consists of a numbers of lines which fall into the region of definite sets which are called series. The line in each series are such that their separation and intensity decrease regularly toward shorter wavelength converging to a limit called the series limit. The first such spectral series are reported by J.J.Balmer in1885 and is called the Balmer series of Hydrogen. And is to be discuss later in detail.
According to classical electromagnetic theory the frequency of the emitted electro magnetic wave must be equal to the frequency of the revolution of the electron . As the revolving electron spiral inward , the frequency of the emitted electromagnetic wave must change continuously . Therefore , atom should emit continuous spectrum . This is not so in actual
And
For ground state energy of hydrogen, n=1 Hence the ground state energy of hydrogen is -13.6eV
This eqn can be represented diagramatically and is called energy level diagram When n=1, E1 =-13.6eV When n=2, E1 =-3.4eV When n=3, E1 =-1.51eV When n=4, E1 =-0.85eV
Thus , the radiation is emitted as a single photon of light . Hence Bohrs model successfully explain the existence of line spectra.
,
=Rydbergs constant
BALMER SERIES
7 6 5 4 3
LYMAN SERIES
2 n=1
-3.4
ENERGY IN (ev)
Balmer series
n=2
-13.6
n=1
1) Lyman series
2)BALMER SERIES
line of hydrogen
line of hydrogen
line of hydrogen
line of hydrogen
3)Paschen series
4)Bracket series
5) Pfund
UPPER STATE
LOWER STATE
UPPER STATE
1)LYMAN SERIES
1216
18751
912
2)BALMER SERIES
3)PASCHEN SERIES 4)BRACKETT SERIES 5)PFUND SERIES
2
3 4 5
3
4 5 6
6563
18751 40515 74584
2
3 4 5
3696
8220 14585 22789
6563
8220
LYMAN
BALMER
PASCHEN
.
Therefore , the mass m in the earlier expression of energy is to be replaced by the reduced mass .
In this consideration of reduced mass, Bohrs postulate becomes and Similarly, and Therefore, the wave number is given by
And, i.e,
,
For doubly ionised lithium atom,
,with
This value is in excellent agreement with the value obtained by the other method.
DISCOVERY OF DEUTERIUM
Deuterium was first predicted by Berge and Menzel in 1931. But it was discovered by Harold Urey and his co-worker in 1932
,
The wavelength of the emitted radiation when electron undergoes transition from n=3 to n=2 of deuterium has a shorter wavelength 6561 that of the line of wavelength 6563.But the intensity is less.
The energy required to removed an electron completely free from the influence of the nucleus of the atom is called Ionization energy. So, when this energy is expressed in electron volt, it is term as IONIZATION POTENTIAL.