NERACA MASSA INDUSTRI ETILEN DIKLORIDA

6 8% NaOH Solution Off-gases H2,CH4,C2H4,C2H6 HCl Scrubber

E-12

Refrig

Wash (NaCl dan H2O)

water

E-8 E-14

Chlorine

6-8% NaOH Acid Wash

E-7

Ethylene
E-1 E-4

Ethylene Dichloride

Reactor Heat Control Loop

V-1

NaCl dan sebagian H2O Crude C2H4Cl2

E-6

E-5

E-3

FeCl3 or C2H2Br2 catalyst

E-2

Heavy Ends (C3H6Cl2 dan H2O)

Gambar 7. Produksi Etilen Diklorida

CH4 C2H4 C2H6 H2 HCl CH4 = C2H4 = C2H6 = H2 = HCl = C3H6Cl2 = kg kg kg kg kg kg

= = = = =

kg kg kg kg kg

CH4 C2H4 C2H6 H2

= = = =

kg kg kg kg NaOH Solution = kg

HCl Scubber

CH4 = C2H4 = C2H6 = H2 = HCl = C2H4Cl2 = C3H6Cl2 =

kg kg kg kg kg kg kg

Refrigenerator

NaCl = kg H2O = kg

Cooler

HCl = kg C3H6Cl2 = kg

HCl = kg C2H4Cl2 = kg

Cl2 = C2H4 = H2 = CH4 = C2H6 =

kg kg kg kg kg

Reaktor
NaCl H2O C2H4Cl2 C3H6Cl = = = =

Acid Wash
kg kg kg kg NaCl = kg H2O = kg

NaOH solution

HCl = kg C2H4Cl2 = kg C3H6Cl = kg

Separator

H2O = C2H4Cl2 = C3H6Cl =

kg kg kg

C2H4Cl2 = kg

Destilator

C3H6Cl = H2O =

kg kg

Gambar 7. Diagram Blok Produksi Etilen Diklorida

DATA KUANTITATIF Bahan Baku : C2H4 = 0,3 ton x Cl2 = 0,75 ton x = 300 kg = 750 kg

Asumsi komposisi dari C2H4 yang mengandung H2, CH4, C2H6 C2H4 = H2 CH4 = = = = = = = 300 kg

C2H6 = Total

Bahan baku Cl2 =

C2H4 = CH4 =

C2H6 = H2 =

C2H4 =. C2H6 = H2 =. CH4 =.... C2H4Cl2=. HCl =..

Cl2 C2H4 H2 C2H6 CH4 Total

= 750 = 285 = 1,5 =9 = 4,5 =1050

kg kg kg kg kg + kg

R E A K T O R

C2H4Cl2=. HCl =....

Reaksi Utama 95 % Mula : Bereaksi : Sisa : BM : Massa : C2H4 + 10,178 9,669 0,509 28 14,252 Cl2 10,578 9,669 0,909 70,9 64,448 C2H4Cl2 9,669 9,669 98,9 956,264 kmole kmole kmole kg/kmole x kg

95%

Mula : Bereaksi : Sisa : BM : Massa :

2C2H4 + 0,509 0,458 0,051 28 1,425

2Cl2 0,909 0,458 0,451 70,9 31,969

(C2H4Cl2)2 0,458 0,458 98,9 40,549

kmole kmole kmole kg/kmole x kg

Reaksi Samping C2H6 + CH4 Mula : 0,3 0,281 Bereaksi : 0,150 0,150 Sisa : 0,150 0,131 BM : 30 16 Massa : 4,491 2,091

+ 3Cl2 0,451 0,451 70,9 -

C3H6Cl2 + 4HCl 0,150 0,601 0,150 0,601 112,99 36,45 16,982 21,914

kmole kmole kmole kg/kmole x kg

Asumsi : Produk berupa fase gas yang merupakan produk atas dengan komposisi C2H4Cl2, C3H6Cl2 , HCl sebanyak 5 % dan merupakan fase cair. Produk atas: C2H4Cl2 : 15% x 1000 kg = 150 kg C3H6Cl2 : 15% x 16,982 kg = 2,547 kg HCl : 5% x 21,914 kg = 3,287 kg Produk bawah : C2H4Cl2 : 85% x 1000 kg = 850 kg C3H6Cl2 : 85% x 16,982 kg = 14,435 kg HCl : 95% x 21,914 kg = 20,818 kg Komposisi produk atas C2H4 = H2 CH4 C2H6 HCl = = = =

= 0,33 kmole = = 0,75 kmole = = 0,19 kmole = = 0,20 kmole = = 0,17 kmole = = 0,36 kmole +=

= 23,08% = 12,59% = 13,28% = 13,98% = 11,89% = 25,18% +

C2H4Cl2 = Total

DATA KUANTITATIF C2H4 : 0,3 ton x Cl2 : 0,75 ton x

Asumsi komposisi dari C2H4 yang mengandung H2,CH4,C2H6