1. Wurtz reaction of methyl iodide yields an organic compound X.

Which one of the following reactions also yields X (a) (b) (c) (d) 2. (a) (c) 3. (a) (c)

Ethyl orthoformate is formed by heating with sodium ethoxide (b) (d) 1 , 2 di-bromo cyclohexane on dehydro halogenation gives (b) (d) None of these

4. In which one of the following conversions phosphorus pentachloride is us ed as a reagent (a) (b) (c) (d) 5. When but 3-en -2- ol reacts with aq. HBr, the product formed is (a) 3 - bromobut - 1- ene (b) 1 - bromobut - 2- ene (c) A mixture of both a and b (d) 2 - bromobut - 2 - ene 6. Which of these do not form Grignard reagent (a) (b) (c) (d) 7. An organic compound on reaction with Na/diethyl ether gives a hydrocar bon, which on monochlorination gives only one chloro derivative. A is (a) t-butyl chloride (b) s-butyl chloride (c) Isobutyl chloride (d) n-butyl chloride (e) None of these Among the following the most reactive towards alcoholic KOH is (a) (b) (c) (d) Which one of the following possess highest m.pt.

8. 9.

(a) Chlorobenzene (b) o-dichlorobenzene (c) m-dichlorobenzene (d) p-dichlorobenzene 10. Which chlorine atom is more electronegative in the following (a) (b) (c) (d) 11. What would be the product formed when 1-Bromo-3-chloro cyclobutane react s with two equivalents of metallic sodium in ether (a) (b)

(c) (d) Read the assertion and reason carefully to mark the correct option out of the op tions given below: (a) If both assertion and reason are true and the reason is the correct expl anation of the assertion. (b) If both assertion and reason are true but reason is not the correct expl

anation (c) (d) (e) 12. Reason Answers 1.

of If If If

the assertion. assertion is true but reason is false. the assertion and reason both are false. assertion is false but reason is true.

Assertion : is stored in transparent bottles. : is oxidised in dark. and solutions (b) Wurtz reaction gives ethane Similarly reduced by to give ethane

2. 3. 4. 5.

(a) (d) (b, c) So, both reaction carried out by (c)

6. (a) The C F bond energy is maximum in . Thus fluoride is the less react ive to form the grignard reagent with Mg. 7. (a) 8. (d) The polarity between C-X bond increase by increasing the +I effe ct which increase by increasing the alkyl group by which X of C-X easily elimina te. In the polarity is maximum due to 3 alkyl group while in rest polarity dec rease due to the presence of double bond, presence of CO group ( I) and less no. of alk yl group. 9. (d) p-dichlorobenzene molecule has symmetrical structure. It can fit well in its crystal lattice. The intermolecular forces of attraction are strong . Hence, it possesses highest melting point. 10. (d) Due to +I effect of 3 alkyl group in option (d), the chlorine at om occupy the maximum charge in it so it is more electronegative. 11. (d) It is the example of Wurtz reaction.

Assertion and Reason 12. (d) e of sunlight. is stored in dark bottles of prevent oxidation of in presenc