Salt Analysis

CATIONS : Pb ANIONS
2+

,Hg
2-

2+

,Cu
2-

2+

,Cd
2-

2+

, Ag , Fe
2-

2+ -

, Fe

3+

, Al

3+ -

, Zn

2+

, Mn , Co
3-

2+

2+

, Sr

2+ -

, Ba

2+

, Mg

2+

, NH

4+

: CO3 , S , SO3 , SO4 , NO2 , NO , Cl , Br , PO4 , CH3COO

32-

Below we are providing a download link for Salt Analysis Chart which can be useful for Class 12 Chemistry students.The file is in PDF format and contains procedure for all tests.
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Cations
Group Zero Group I Group II Group III Group IV Group V Group VI Group Group Reagent O.S. + NaOH + Heat O.S. + HCl O.S. + HCI + H2S O.S. +NH4Cl + NH4OH O.S. + NH4CI + NH4OH +H2S O.S. + NH4CI + NH4OH +(NH4)2CO3 O.S + NH4CI + NH4OH + NaH2PO4 Radicals NH4+ Pb2+ Cu2+ AI2+ ,Fe3+ Ni2+ ,Mn2+ , Zn2+ ,Co2+ Ba2+, Ca3+, Sr2+ Mg2+

Anions
Group I Group II Group Group Reagent Salt + dil. H2SO4 Salt + conc. H2SO4 Add Cu piece and heat Add KMnO4 soln. III Group IV Group Test Physical Appearance Colour White NH4+, Pb2+, Al3+ , Zn2+, Ba2+, Ca2+ , Sr2+ and Mg2+ O.S. + BaC!2 O.S + Conc.HNO3 + Heat + (NH4)24 MoO Observation Radicals CO3 , SO3 , S , NO2Cl-, Br-, I-, CH3COONOc2o42so42PO43Inference
222-

Pre limi nar y Tes ts

Blue Green Brown Red Light pink Odour Smell of NH3 Smell of vinegar Smell of rotten eggs Dry Heating Colourless gas evolved Blown gas evolved Violet gas evolved Crackling sound Brown residue Flame Test Greenish blue Light green Brick red Crimson red

Cu2+ Ni2+ Fe3+ Co2+ Mn2+ NH4+ CH3COOS2CO32- , SO32-, S2- and ClBr-, NO3IPb(NO3)2 and Ba(NO3)2 Cu2+ Cu2+ Ba2+ Ca2+ Sr2+