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Product Loss During Retail Motor Fuel Dispenser Inspection
Product Loss During Retail Motor Fuel Dispenser Inspection
Product Loss During Retail Motor Fuel Dispenser Inspection
\
|
+
=
Where:
V
TM
= test equipment volume measurement of the liquid delivered by the pipe prover
corrected to prover temperature and pressure,
Vbase
TM
= to deliver volume (water) of test equipment at reference temperature corrected
for bias with pipe prover,
ctl
TM
/ ctl
Prover
= correction for liquid expansion due to temperature difference from the pipe
prover to the test equipment,
cts
TM
= correction for test equipment steel expansion due to thermal effects,
cpl
Prover
= correction for liquid expansion due to pressure drop from the pipe prover to the
test equipment.
The difference between the test equipment liquid volume measurement, with all corrections
applied, and the calculated liquid volume delivered by the pipe prover is obtained with:
Difference compared with pipe prover after all corrections = V
Prover
- V
TM
This value represents the combined effect of vapour loss and test equipment wetting error.
The difference between the test equipment liquid volume measurement, before any corrections,
and the calculated liquid volume delivered by the pipe prover is obtained with:
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 6 of 18
April 10, 2007
Difference compared with pipe prover before corrections = V
Prover
- (Vbase
TM
+ Reading)
This value represents the test equipment error when no corrections are applied to the test
equipment reading.
For the purposes of the analysis, the values for the individual corrections were calculated as:
Test equipment steel correction = (Vbase
TM
+ Reading) x cts
TM
Liquid thermal expansion correction = (Vbase
TM
+ Reading) x ctl
TM
/ ctl
Prover
Liquid expansion due to pressure drop = (Vbase
TM
+ Reading) / cpl
Prover
Since the correction values are small relative to the measurement value, an alternate and
approximate method of calculating the test equipment volume is as follows:
V
TM
(Vbase
TM
+ Reading) + test equipment steel correction + liquid thermal expansion
correction + liquid expansion due to pressure drop
Vapour Pressure
The fuel vapour pressure at proving conditions was calculated from the model provided in API
Manual Petroleum Measurement Standards, chapter 19.4, Appendix B using a value of s = 3 for
the slope of the ASTM distillation curve at 10% evaporated, in degrees F per percentage point.
The following graph provides the results of this model for the range of gasoline encountered
during the study. The product vapour pressure was lowest in the summer at 50 RVP and highest
in the winter at 110 RVP.
Figure 2. True Vapour Pressure of Refined Petroleum Stocks.
True Vapour Pressure of Refined Petroleum Stocks
0.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
-30 -20 -10 0 10 20 30 40
Temperature (C)
V
a
p
o
u
r
P
r
e
s
s
u
r
e
(
k
P
a
)
RVP = 50
RVP = 80
RVP = 110
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 7 of 18
April 10, 2007
Results
The Volume Difference before Corrections values represent the test equipment error when no
corrections are applied to the test equipment reading.
The Volume Difference after all Corrections values represent the combined effect of vapour loss
and test equipment wetting error.
The Equipment Steel Temp. Correction is the correction for test equipment steel expansion due
to thermal effects.
The Liquid Temperature Correction is the correction for liquid expansion due to the temperature
difference between the pipe prover and the test equipment.
The Liquid Pressure Correction is the correction for liquid expansion due to the pressure drop
from the pipe prover to the test equipment.
All values are the average of 5 runs of 20L test quantity.
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 8 of 18
April 10, 2007
Table 1. Results for the August 23, 2005 test.
Test
Equipment
Flow Pipe
Prover
Temp.
(C)
Pipe
Prover
Pressure
(kPa)
Volume
Difference
before
Corrections
(mL)
Equipment
Steel Temp.
Correction
(mL)
Liquid
Temp.
Correction
(mL)
Liquid
Pressure
Correction
(mL)
Volume
Difference
after all
Corrections
(mL)
Liquid
Vapour
Pressure
(kPa)
Test
Measure
high 29.2 257.8 -62.1 13.1 13.5 -6.6 -41.2 42.6
Calibration
Cart
high 29.3 261.3 -26.1 15.2 -8.7 -6.7 -26.1 40.9
VRP high 30.7 256.5 -30.0 16.6 -6.7 -6.7 -26.5 42.6
Test
Measure
low 27.3 95.8 -63.0 11.4 10.1 -2.4 -43.1 40.2
Calibration
Cart
low 25.8 94.4 -44.4 11.0 3.9 -2.4 -31.4 35.6
VRP low 25.3 114.4 -29.6 10.7 -0.3 -2.8 -21.8 35.3
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 9 of 18
April 10, 2007
Table 2. Results for the December 7, 2005 test.
Test
Equipment
Flow Pipe
Prover
Temp.
(C)
Pipe
Prover
Pressure
(kPa)
Volume
Difference
before
Corrections
(mL)
Equipment
Steel Temp.
Correction
(mL)
Liquid
Temp.
Correction
(mL)
Liquid
Pressure
Correction
(mL)
Volume
Difference
after all
Corrections
(mL)
Liquid
Vapour
Pressure
(kPa)
Test
Measure
high -5.0 259.2 -7.6 -19.6 12.3 -5.0 -20.7 26.8
Calibration
Cart
high -4.8 250.9 5.8 -20.7 4.1 -4.9 -16.2 27.9
VRP high -2.4 262.0 -9.8 -18.2 2.7 -5.2 -28.2 30.0
Test
Measure
low -6.0 99.3 -8.1 -20.7 16.9 -1.9 -14.6 25.6
Calibration
Cart
low -3.8 121.3 14.4 -19.4 -4.1 -2.4 -11.6 29.3
VRP low -3.0 126.8 4.8 -18.7 1.4 -2.5 -15.4 29.4
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 10 of 18
April 10, 2007
Table 3. Results for the February 15, 2006 test.
Test
Equipment
Flow Pipe
Prover
Temp.
(C)
Pipe
Prover
Pressure
(kPa)
Volume
Difference
before
Corrections
(mL)
Equipment
Steel Temp.
Correction
(mL)
Liquid
Temp.
Correction
(mL)
Liquid
Pressure
Correction
(mL)
Volume
Difference
after all
Corrections
(mL)
Liquid
Vapour
Pressure
(kPa)
Test
Measure
high 3.6 300.6 -35.0 -11.3 10.7 -6.3 -42.5 36.5
Calibration
Cart
high 4.0 303.3 -5.3 -11.6 5.0 -6.4 -18.6 37.4
VRP high 6.2 296.4 -7.2 -9.1 0.8 -6.3 -22.1 40.7
Test
Measure
low 2.6 137.9 -21.5 -12.1 6.3 -2.9 -30.7 35.4
Calibration
Cart
low 4.0 131.0 -12.9 -11.4 1.1 -2.7 -26.3 37.6
VRP low 5.2 137.9 -4.7 -10.1 -1.9 -2.9 -19.9 39.3
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 11 of 18
April 10, 2007
Table 4. Results for the January 11, 2006 test.
Test
Equipment
Flow Pipe
Prover
Temp.
(C)
Pipe
Prover
Pressure
(kPa)
Volume
Difference
before
Corrections
(mL)
Equipment
Steel Temp.
Correction
(mL)
Liquid
Temp.
Correction
(mL)
Liquid
Pressure
Correction
(mL)
Volume
Difference
after all
Corrections
(mL)
Liquid
Vapour
Pressure
(kPa)
Test
Measure
high 8.2 289.5 -40.1 -6.8 10.5 -6.3 -43.1 42.6
Calibration
Cart
high 8.4 292.3 -7.2 -7.2 7.5 -6.3 -13.4 43.0
VRP high 8.7 289.5 -10.4 -6.6 2.8 -6.3 -20.7 43.8
Test
Measure
low 5.7 124.1 -30.0 -9.0 3.6 -2.6 -38.6 39.3
Calibration
Cart
low 3.5 128.2 4.5 -11.8 -2.8 -2.7 -12.9 36.7
VRP low 3.9 136.5 4.7 -11.3 -4.7 -2.9 -14.3 37.3
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 12 of 18
April 10, 2007
Table 5. Results for the January 25, 2006 test.
Test
Equipment
Flow Pipe
Prover
Temp.
(C)
Pipe
Prover
Pressure
(kPa)
Volume
Difference
before
Corrections
(mL)
Equipment
Steel Temp.
Correction
(mL)
Liquid
Temp.
Correction
(mL)
Liquid
Pressure
Correction
(mL)
Volume
Difference
after all
Corrections
(mL)
Liquid
Vapour
Pressure
(kPa)
Test
Measure
high 1.2 295.1 -38.4 -13.6 12.4 -6.0 -46.7 32.7
Calibration
Cart
high -0.1 308.9 -6.5 -16.0 8.2 -6.3 -21.1 31.3
VRP high 0.1 297.8 -5.1 -15.6 4.4 -6.0 -22.9 31.7
Test
Measure
low 0.9 142.0 -44.8 -14.0 13.5 -2.9 -49.3 32.2
Calibration
Cart
low -0.3 140.6 -7.0 -16.3 11.0 -2.8 -15.7 30.9
VRP low -0.8 159.9 -6.8 -16.5 4.4 -3.2 -22.6 30.7
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 13 of 18
April 10, 2007
Table 6. Results for the May 25, 2005 test.
Test
Equipment
Flow Pipe
Prover
Temp.
(C)
Pipe
Prover
Pressure
(kPa)
Volume
Difference
before
Corrections
(mL)
Equipment
Steel Temp.
Correction
(mL)
Liquid
Temp.
Correction
(mL)
Liquid
Pressure
Correction
(mL)
Volume
Difference
after all
Corrections
(mL)
Liquid
Vapour
Pressure
(kPa)
Test
Measure
high 30.8 383.8 -62.9 16.2 3.3 -10.0 -52.3 42.2
Calibration
Cart
high 31.6 358.5 -46.6 15.7 5.3 -9.4 -34.3 43.3
VRP high 31.5 255.1 -25.8 17.1 -0.5 -6.7 -15.5 43.4
Test
Measure
low 23.1 146.5 -39.1 8.5 -1.7 -3.6 -35.6 32.8
Test
Measure
low 20.9 146.5 -22.0 6.7 -12.6 -3.5 -31.3 30.8
Calibration
Cart
low 24.7 159.9 -14.8 9.6 -7.3 -4.0 -16.4 34.9
Calibration
Cart
low 26.6 125.8 -31.5 11.1 -0.7 -3.2 -24.0 36.9
VRP low 26.3 164.6 -21.6 11.8 -2.8 -4.1 -16.6 36.6
VRP low 23.9 126.8 0.8 9.8 -14.6 -3.1 -7.2 34.3
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 14 of 18
April 10, 2007
Discussion
Product Temperature Range
The results show a very wide range of liquid temperatures, -5to 30C, which was due to the use
of an above-ground fuel storage tank. The temperature range is therefore more representative
of extreme field conditions as opposed to typical field conditions.
Product Vapour Pressure
The range of product RVP varied from 50 to 110 RVP and the product vapour pressure during
testing was between 25 and 45 kPa. Since fuel is normally formulated with low RVP in summer
and high RVP in winter, it is expected that low product vapour pressure will be encountered when
the fuel storage temperature will be low relative to ambient temperature. We also expect to see
the reverse high vapour pressure when the product storage temperature is high relative to
ambient temperature.
Steel Thermal Expansion Correction
The most significant correction in this study was the correction for equipment steel expansion.
This effect is approximately 1 mL per C when 304 stainless steel is used. It ranged from -20 mL
to 17 mL, and was due to the extreme product temperature range experienced in this study. We
would expect smaller variations in typical field conditions.
Liquid Temperature Correction
The correction for liquid temperature change between the pipe prover and the test equipment is
approximately 2.5 mL per 0.1C difference for gasoline. The two factors believed to influence the
temperature differential are ambient/product temperature differences and evaporative cooling.
It is estimated that the evaporation of 40 mL of fuel is equivalent to a temperature drop of 0.25C
on 20 L of fuel. In practice, however, the temperature drop will be less because not all cooling
heat is transferred to the liquid. For the majority of tests, the fuel temperature was very close to
the ambient temperature. As a result, the effects of ambient/fuel temperature differences could
not be analyzed.
The test measure liquid temperature correction averaged about 10 mL. The calibration cart and
VRP showed correction values averaging just above 0. This supports the assumption that higher
evaporation rates in the test measure will result in greater evaporative cooling of the product.
However, there was no significant correlation between the amount of temperature correction and
product VP. It should be noted that the accuracy of the temperature measurement is
approximately 0.2 C, which is equivalent to a 5 mL correction.
Liquid Pressure Effect Correction
The pressure inside the pipe prover was approximately 250 kPa (35 psi) at high flow and 125 kPa
(18 psi) at low flow, resulting in a small expansion of the liquid as it was transferred to the
ambient pressure in the test equipment. The expansion for 20 L was approximately 6 mL at high
flow and 2 mL at low flow. Similar expansion would occur during dispenser testing, depending on
the metering pressure.
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 15 of 18
April 10, 2007
Difference in Volume after all Corrections
This graph shows the results of the study in terms of volume measurement difference between
the pipe prover and the equipment used. Each point is the average of five runs.
Figure 3. Difference in Measured Volume After All Corrections.
Difference in Measured Volume After All Corrections
-60.0
-50.0
-40.0
-30.0
-20.0
-10.0
0.0
20.0 25.0 30.0 35.0 40.0 45.0
Product Vapour Pressure (kPa)
D
i
f
f
e
r
e
n
c
e
(
m
L
)
VRP high flow Test Measure high flow Calibration Cart high flow
VRP low flow Test Measure low flow Calibration Cart low flow
Vapour Pressure Effect, TM
The graph shows a close correlation between the measured volume difference for the test
measure and the product vapour pressure during testing. As expected, the difference increases
with product vapour pressure. This is consistent with the assumption that vapour loss is the
main contributor with a regular test measure, as higher product vapour pressure will induce
greater evaporation rates.
Vapour Pressure Effect, VRP and Calibration Cart
Both the calibration cart and the VRP showed a relatively consistent difference of about 20 mL in
volume measurement. As seen in the next graph, the average bias for the VRP based on the last
two runs is approximately 15 mL. This would seem to indicate that this prover is sensitive to any
air entrained when the reservoir is drained and perhaps some conditioning of the air in the prover.
Other than the liquid pressure expansion from the pipe prover to the test equipment (6 mL at high
flow), the cause of this bias is not known but is expected to be due to a combination of:
- a small amount of evaporation and perhaps some atomization during transfer,
- wetting effects,
- bias errors in the study.
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 16 of 18
April 10, 2007
Wetting effect is caused by the variance in the amount of residue left in the to deliver test
equipment when a product other than water is used.
Figure 4. Difference in Measured Volume vs Product VP (VRP values based on last two
runs only).
Difference in Measured Volume vs Product VP
(VRP values based on last two runs only)
-60.0
-50.0
-40.0
-30.0
-20.0
-10.0
0.0
20.0 25.0 30.0 35.0 40.0 45.0
Liquid Vapour Pressure (kPa)
D
i
f
f
e
r
e
n
c
e
(
m
L
)
VRP high flow TM high flow Calibration Cart high flow
VRP low fLow TM low flow Calibration Cart low flow
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 17 of 18
April 10, 2007
Volume Difference before Corrections
The following graph shows the results of the measured volume difference before corrections.
This is somewhat representative of the expected bias between closed-loop proving and proving
using the test equipment under evaluation.
Figure 5. Difference in Measured Volume Before Corrections.
Difference in Measured Volume Before Corrections
-70.0
-60.0
-50.0
-40.0
-30.0
-20.0
-10.0
0.0
10.0
20.0
20.0 25.0 30.0 35.0 40.0 45.0
Product Vapour Pressure (kPa)
D
i
f
f
e
r
e
n
c
e
(
m
L
)
VRP high flow TM high flow Calibration Cart high flow
VRP low flow TM low flow Calibration Cart low flow
As expected, the spread of results is wider, about 15 mL to -65 mL, compared with the range of -
10 mL to -50 mL for the corrected results. A smaller range of results would be expected in typical
field conditions, since the product temperature range and resultant steel expansion effects would
be lesser. This is demonstrated in the following graph, with only the steel thermal correction
added.
Measurement Canada
Product Loss During Retail Motor Fuel Dispenser Inspection page 18 of 18
April 10, 2007
Figure 6. Difference in Measured Volume vs. Product VP (Test Equipment Only Corrected
for Steel Thermla Expansion).
Difference in Measured Volume vs. Product VP
(Test Equipment Only Corrected for Steel Thermal
Expansion)
-70.0
-60.0
-50.0
-40.0
-30.0
-20.0
-10.0
0.0
10.0
20.0
20.0 25.0 30.0 35.0 40.0 45.0
Product Vapour Pressure (kPa)
D
i
f
f
e
r
e
n
c
e
(
m
L
)
VRP high flow TM high flow Calibration Cart high flow
VRP low flow TM low flow Calibration Cart low flow
Conclusion
This study provides an estimate of product loss combined with wetting effects during testing with
test measures. When care is not taken to minimize splashing during testing, the results indicate
that the combined vapour loss and wetting effect error correlates closely with product vapour
pressure. In this study, the error was found to increase from 10 mL to about 50 mL for a
corresponding increase in product vapour pressure from 25 kPa to 45 kPa. When other sources
of error are included, the differences between the volume measured by the test measure and the
volume delivered by the pipe prover ranged from 15 mL to -65 mL. But with the product
temperatures of -5to 30C observed in these tests, correcting for expansion of the test measure
steel reduced these differences to the 0 to -60 mL range.
The desired accuracy ratio of test equipment to device under test is 1:3. Unless vapour loss and
wetting effect are addressed during the use of a test measure, this accuracy target will not be
met.
The performance of the VRP and calibration cart indicates that vapour loss can be significantly
reduced with these designs. When test equipment steel corrections were applied, the measured
volumes were in agreement with the delivered volumes, assuming a tolerance equal to the
retail dispenser tolerance.