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EuPIA - Packaging Inks For Non-Food Contact Surface of Food Packaging
EuPIA - Packaging Inks For Non-Food Contact Surface of Food Packaging
(2008-04-18)
EuPIA Incomplete Public Inventory List Notes & Lists 1. Preliminary Statement
Printing inks and varnishes for food packaging are intended to be applied to a variety of substrates using different printing techniques, such as:
Rotogravure and flexographic printing on flexible films, Aluminium foil, paper and cardboard Offset printing on paper, cardboard, rigid plastics and metal Screen printing on rigid plastics, films, foil and metal Roller coating on metal Digital inks printed on paper, cardboard, flexible films and Aluminium foils Jet inks printed on paper, flexible films, Aluminium foils and rigid plastics
Depending on the field of application and their formulation, printing inks and varnishes have different drying mechanisms:
Evaporation through hot air drying for water and solvent based systems Penetration into substrate structures with or without oxidative polymerisation Radical or cationic polymerisation induced by UV or EB irradiation. High temperature drying by solvents evaporation and/or polymerisation using baking ovens.
In the light of these diversified application requirements the strong chemical distinctions between ink systems and their constituent parts must be stressed. It should also be noted that the composition of the dried applied ink in almost all cases is not identical to the delivered wet form. Furthermore it should also be noted that end-user and/or customer requirements may prevent the use of some of the materials below in certain applications.
Additives Colourants, (i.e. pigments and dyes) Polymeric Resins Solvents and Energy Curing Monomers
3. Additives
Additives are substances used normally in small quantities, which essentially impart specific technical properties to the printing ink, primer or overprint varnish.
In the current version of the Inventory, the list of additives is subdivided into chemical categories of the substances and preparations used. Future versions will include more chemical details as they become available.
1.6
Ketones 1-Hydroxycyclohexyl Phenylketone, other Alpha-Hydroxy Ketones, Ketosulphones Benzophenone and Derivatives 4-(2-Hydroxyethoxy)-phenyl(2-hydroxy-2-propyl)-ketones Other Aliphatic Ketones Other Aromatic Ketones 1.7 Phenolic Derivatives Alkylated Phenols Isononylphenol Derivatives Alkoxyphenols Alkylphenolalkoxylates Phenylphenols 1.8 Hydroquinone and Derivatives Hydroquinone Alkylated Hydroquinones and Derivatives Quinines 1.9 Inorganic Alkaline, Alkaline earth-, Zirconium, Zinc and Aluminium salts Carbonates Borates / Perborates Phosphates Polyphosphates Hydroxide gel, dried powder Hydroxy Ammonium Carbonates Hydroxides / Oxides Citrates 1.10 Organic Alkaline, Alkaline earth-, Tin, Zinc, Zirconium, Barium and Aluminium salts Stearates / Laurates Nitro compounds / Phenylhydroxylamine complexes Al-Alkoxylates / Chelates and preparations Zr-Alkoxylates/Chelates Citrates 1.11 Titanium Chelates Titanium Alkoxylates Titanium alkoxylated phosphates Titanium alcoholates 1.12 Amides Fatty Acid Amides Fatty Acid Amide Derivatives Sulphoneamides 1.13 Ammoniumsalts Inorganic Organic 1.14 Alkaline-, Ammonia Hydroxides, salts (undissolved and dissolved in water) Sodium Hydroxide Ammonium Hydroxide Potassium Hydroxide Potassium salts
1.15 Benzoxazine and Benzoxazole / Triazole derivatives Benzoxazines derivatives Benzoxazol Thiophenediyl derivatives Benzotriazoles and Derivatives 1.16 Cyclic Diazo Compounds 1.17 Phosphine Oxide Derivatives 1.18 Amines (optional preparations) Alkoxysilylated Amines Aminacrylates Amines (optional preparations) Fatty acid amines Alkoxylated amines 1.19 Substituted Aromatic / Polycyclic Aromatic Hydrocarbons 1.20 Oximes (Optional Preparations) (optional: Butoxy-2-propanol, refined paraffinics, fatty acid esters) 1.21 Triazines / Stilbenes 1.22 Silanes 1.23 Phosphites 1.24 Aldehydes 2. Polymeric Additives Polyaminoamides; optional salts dissolved in 2-Butoxyethanol Polyalkylene Polymers and Block Copolymers with pigment affinic groups Acetophenone- / Alkylamino- / Phenolic- / Urea- Formaldehyde resins Polyurethanes Polysiloxanes / Polydimethylsiloxanes / Cyclosiloxanes Polyether- / Aminosiloxanes Epoxides / Cycloaliphatic Derivatives Stabilisers Polyethers / Polyols Polyesters Polyacrylates Fluorinated acrylates Rosin (Abietic acid) based Fluoraliphatic Polymers Natural Polymeric Products Polymeric Aminobenzoates Polymeric Benzophenones Polymeric Thioxanthones Melamin-Formaldehyde resins 3. Polymeric Additives Preparations Polyurethane, water based Polyurethane, solvent based Acrylic Polymers and Copolymers, water based
Polyethers- / Polyvinylethers and Derivatives, water based Ethylene-Vinylacetate- / Polyvinyl based copolymers Polyfunctional aziridines, water based Acrylated Siloxanes / org. modified Siloxanes (water based included) Polyglycols and Derivatives Polyglycosides Polyoxyalkylenes, other Polymers, water based Imines Polyamides Hydrocarbons Chlorinated Polyolefinic preparations
Silicone- and Wax Preparations Silicone oil Emulsions, aqueous (silicone compound/s, optional: solvent, binder, glycol ethers, biocide) Silicone Preparation, non-aqueous (silicone compound/s, optional: solvent, binder) Organomodified Polysiloxanes, aqueous (silicone compound/s, optional: solvent, binder, biocide, solid silica) PE Wax Dispersions, aqueous (PE wax/es, water, optional: emulsifier, Silica, detergent, biocide) Oxidized PE wax/es, aqueous (wax/es, water, optional: emulsifier, detergent, biocide) Wax Preparations, non aqueous (wax, solvent/binder, optional: surfactant/dispersent) Blended Synthetic and Natural Waxes, aqueous (waxes, water; optional: emulsifiers, detergents, biocides) PP Wax Dispersions, aqueous (PP wax/es, water, optional: emulsifier, detergent, biocide) PTFE Wax Dispersions and Wax Blends, aqueous (wax/es, water, optional: emulsifier, detergent, biocide)
4.10 Natural Waxes, aqueous (wax/es, water, optional: emulsifier, detergent, biocide) 4.11 Fatty acid amides wax dispersions, aqueous (wax/es, water, optional: emulsifier, detergent, biocide) 4.12 Fatty acid amides, non aqueous (wax, solvent/binder, optional: surfactant/dispersent) 4.13 Paraffinic Wax Emulsion, aqueous (wax, water, optional: surfactant, biocides, ethoxylated products) 4.14 PTFE Wax and non aqueous preparations 4.15 Other Polyolefin waxes preparations 4.16 Hydrocarbon and other Wax Preparations 4.17 Polyamide wax and Blends (water based) 5. Solid Waxes (also powderized / micronized) Natural waxes PE wax and blends Oxidized PE wax and blends PP wax and blends PTFE wax and blends Paraffin wax and blends Fischer Tropsch Wax and Blends Hydrocarbon- / Vaseline / Polymethylene wax and blends Polyamide wax and Blends
6.
Metalcarboxylate Preparations Cobalt bis(2-ethylhexanoate) Cobalt Naphthenate Cobalt Dilinoleate (other Fatty Acids) Cobalt-neodecanoate Manganese bis(2-ethylhexanoate) Manganese Naphthenate Manganese Dilinoleate (other Fatty Acids) Manganese Borate (Mn-borate, water) Cobalt/Zirconium bis(2-ethylhexanoates) Cobalt/Manganese Naphthenate Cobalt/Manganese (other Fatty Acids salts)/petroleum distillate Calcium bis(2-ethylhexanoate) Zirconium bis(2-ethylhexanoate) Copper-Naphthenate Zinc and other Metal Carboxylate Preparations Cobalt/Manganese Octoates with Perborates
7.
Inorganic Solids and Solid Preparations Inorganic salts Calcium Carbonate Calcium Carbonate with surface treatment Barium Sulphate Silicon dioxide, amorphous, highly dispersed Silicon dioxide, amorphous, highly dispersed / surface treated Bentonite / Bentonite surface treated Bentonite surface treated, optional quaternary ammonium salts Hectorite/ Smectite / Zeolite Clay and organo-modified Clay / Kaolin Magnesium Silicate Aluminium and other Silicates Aluminium Oxide / Hydroxide
8. 9.
Liquid / Paste Silicon dioxides preparations (non aqueous) Succinates, Sulphosuccinates Sulphosuccinate-Sodium salt; solved optional: ethanol, water
10.
11.
Isothiazolinones Isothiazolinone aromatic derivatives Isothiazolinone aliphatic derivatives Methylchlorisothiazolinone 12. Arylsulphoniumhexafluoro phosphates / iodonium / antimonates, derivatives and preparations
Aryl sulphonium salts / sulphates / fluoro salts Perfluoralkylthioalkylates Cyano compounds / acrylates
Imidazoles Isocyanates Urea and Derivatives Thiocarboxamide- / oxamide compounds Piperidinium Compounds
4. List of Colourants
All colourants (pigments and dyes) used in the manufacture of packaging inks have to comply with the specifications given in the Council of Europe Resolution AP (89)1 on the use of colorants in plastic materials intended to come into contact with food. Please note, pigments are finely dispersed as solids in to the printing ink binders whilst dyes are dissolved, which is a significant distinction in terms of method of preparation and properties thereby imparted by either colorant type. It should also be noted that on a quantity basis dyes represent a minor proportion (< 1%) of the overall colorant volumes. It is planned in a subsequent version of the Inventory to provide a full list of pigment additives; these are additives introduced in to pigments by their manufacturers prior to dispatch to ink makers. The Ecological and Toxicological Association of Dyes and Pigments (ETAD) has been asked to update their inventory of additives. This will be included in a future version of this inventory.
4.1 Pigments
CAS No
001333-86-4 012227-89-3 NA NA 000482-89-3 002475-31-2 001325-87-7 000147-14-8 000147-14-8 000147-14-8 000147-14-8 000147-14-8 000574-93-6 014038-43-8 025869-00-5 057455-37-5 006417-46-5 000081-77-6 001324-76-1
C.I. No
77266 77499 NA NA 63000 NA 42595:2 74160 74160 74160 74160 74160 74100 77510 77510 77007 42800 69800 42765:1
C.I. Name
C.I. Pigment Black 7 C.I. Pigment Black 11 C.I. Pigment Black 31 C.I. Pigment Black 32 C.I. Vat Blue 1 C.I. Vat Blue 5 C.I. Pigment Blue 1 C.I. Pigment Blue 15:1 C.I. PIgment Blue 15:2 C.I. Pigment Blue 15:3 C.I. Pigment Blue 15:4 C.I. Pigment Blue 15:6 C.I. Pigment Blue 16 C.I. Pigment Blue 27 C.I. Pigment Blue 27 C.I. Pigment Blue 29 C.I. Pigment Blue 56 C.I. Pigment Blue 60 C.I. Pigment Blue 61
CAS No
082338-76-9 016521-38-3 014154-42-8 014302-13-7 001328-53-6 001330-37-6 068186-85-6 007429-90-5 007440-50-8 003520-72-7 006505-28-8 015793-73-4 012236-62-3 012236-64-5 004424-06-0 067801-01-8 003468-63-1 072102-84-2 074336-59-7 084632-50-8 NA 001309-37-1 006535-46-2 006410-32-8 016043-40-6 005280-78-4 005280-68-2 068227-78-1 003905-19-9 012237-63-7 006655-84-1 002786-76-7 012225-06-8 004051-63-2 003049-71-6 005521-31-3 099402-80-9 061951-98-2 059487-23-9 061847-48-1 006041-94-7 003089-17-6 031778-10-6 061932-63-6 060618-31-3 006448-95-9 006471-49-4 052238-92-3 074336-60-0 084632-65-5 NA 088949-33-1 036968-27-1 016403-84-2 067990-05-0 NA NA 002425-85-6 002814-77-9
C.I. No
42595:4 73015:1 741300 74265 74260 74255 77377 77000 77400 21110 21160 21115 11780 12367 71105 15602 12075 12760 12915 561200 NA 77491 12370 12385 73915 20735 12485 12433 20730 45160:2 12390 12475 12515 65300 71155 71130 12487 12516 12486 12467 12310 73907 12514 12477 NA 12315 12355 20067 12925 56110 NA 561300 12474 12316 12466 561150 NA 12120 12085
C.I. Name
C.I. Pigment Blue 62 C.I. Pigment Blue 63 C.I. Pigment Blue 79 C.I. Pigment Green 36 C.I. Pigment Green 7 C.I. Pigment Green 37 C.I. Pigment Green 50 C.I. Pigment Metal 1 C.I. Pigment Metal 2 C.I. Pigment Orange 13 C.I. Pigment Orange 16 C.I. Pigment Orange 34 C.I. Pigment Orange 36 C.I. Pigment Orange 38 C.I. Pigment Orange 43 C.I. Pigment Orange 46 C.I. Pigment Orange 5 C.I. Pigment Orange 64 C.I. Pigment Orange 67 C.I. Pigment Orange 71 C.I. Pigment Orange 74 C.I. Pigment Red 101 C.I. Pigment Red 112 C.I. Pigment Red 12 C.I. Pigment Red 122 C.I. Pigment Red 144 C.I. Pigment Red 146 C.I. Pigment Red 147 C.I. Pigment Red 166 C.I. Pigment Red 169 C.I. Pigment Red 17 C.I. Pigment Red 170 C.I. Pigment Red 176 C.I. Pigment Red 177 C.I. Pigment Red 178 C.I. Pigment Red 179 C.I. Pigment Red 184 C.I. Pigment Red 185 C.I. Pigment Red 187 C.I. Pigment Red 188 C.I. Pigment Red 2 C.I. Pigment Red 202 C.I. Pigment Red 208 C.I. Pigment Red 210 C.I. Pigment Red 214 C.I. Pigment Red 22 C.I. Pigment Red 23 C.I. Pigment Red 242 C.I. Pigment Red 251 C.I. Pigment Red 254 C.I. Pigment Red 255 C.I. Pigment Red 264 C.I. Pigment Red 266 C.I. Pigment Red 268 C.I. Pigment Red 269 C.I. Pigment Red 272 C.I. Pigment Red 282 C.I. Pigment Red 3 C.I. Pigment Red 4
10
CAS No
007585-41-3 007023-61-2 015782-05-5 005280-66-0 001103-38-4 001103-39-5 017852-99-2 002092-56-0 005160-02-1 005281-04-9 006417-83-0 012224-98-5 080083-40-5 075627-12-2 063022-06-0 063022-06-0 006410-38-4 039379-50-5 010101-66-3 001047-16-1 001326-04-1 006358-30-1 012237-62-6 NA 001325-82-2 012225-08-0 017741-63-8 057971-98-9 064070-98-0 000471-34-1 001318-74-7 012001-26-2 007727-43-7 007727-43-7 001332-73-6 010101-41-4 014807-96-6 007631-86-9 001314-13-2 001345-05-7 013463-67-7 001314-98-3 002512-29-0 053026-63-4 012769-01-6 005590-18-1 069771-45-5 008004-92-0 006358-85-6 090268-23-8 071872-67-8 057971-97-8 005102-83-0 030125-47-4 036888-99-0 005468-75-7 025157-64-6 031837-42-0 068134-22-5
C.I. No
15865:1 15865:2 15865:3 15865:4 15630:1 15630:2 15860:1 15585 15585:1 15850:1 15880:1 45160:1 45160:3 45161:1 45161:2 45160:4 NA 45170:2 77742 73900 45175:1 51319 42535:3 NA 42535:2 12517 51345 51345 42555:2 77220 77005 77019 77120 77120 77002 77231 77718 77811 77947 77115 77891 77975 11680 19140:1 56284 56280 11745 47005:1 21090 21101 21102 20037 21100 56300 56298 21095 12764 13980 11781
C.I. Name
C.I. Pigment Red 48:1 C.I. Pigment Red 48:2 C.I. Pigment Red 48:3 C.I. Pigment Red 48:4 C.I. Pigment Red 49:1 C.I. Pigment Red 49:2 C.I. Pigment Red 52:1 C.I. Pigment Red 53 C.I. Pigment Red 53:1 C.I. Pigment Red 57:1 C.I. Pigment Red 63:1 C.I. Pigment Red 81 C.I. Pigment Red 81:1 C.I. Pigment Red 81:2 C.I. Pigment Red 81:3 C.I. Pigment Red 81:5 C.I. Pigment Red 9 C.I. Pigment Violet 1 C.I. Pigment Violet 16 C.I. Pigment Violet 19 C.I. Pigment Violet 2 C.I. Pigment Violet 23 C.I. Pigment Violet 27 C.I. Pigment Violet 29 C.I. Pigment Violet 3 C.I. Pigment Violet 32 C.I. Pigment Violet 37 C.I. Pigment Violet 37 C.I. Pigment Violet 39 C.I. Pigment White 18 C.I. Pigment White 19 C.I. Pigment White 20 C.I. Pigment White 21 C.I. Pigment White 22 C.I. Pigment White 24 C.I. Pigment White 25 C.I. Pigment White 26 C.I. Pigment White 27 C.I. Pigment White 4 C.I. Pigment White 5 C.I. Pigment White 6 C.I. Pigment White 7 C.I. Pigment Yellow 1 C.I. Pigment Yellow 100 C.I. Pigment Yellow 109 C.I. Pigment Yellow 110 C.I. Pigment Yellow 111 C.I. Pigment Yellow 115 C.I. Pigment Yellow 12 C.I. Pigment Yellow 126 C.I. Pigment Yellow 127 C.I. Pigment Yellow 128 C.I. Pigment Yellow 13 C.I. Pigment Yellow 138 C.I. Pigment Yellow 139 C.I. Pigment Yellow 14 C.I. Pigment Yellow 150 C.I. Pigment Yellow 151 C.I. Pigment Yellow 154
11
CAS No
068516-73-4 005979-28-2 004531-49-1 078952-72-4 090268-24-9 077804-81-0 074441-05-7 014059-33-7 076199-85-4 076199-85-4 023792-68-9 023792-68-9 082199-12-0 006486-23-3 001657-16-5 051274-00-1 008007-18-9 006358-31-2 022094-93-5 005567-15-7 005580-57-4 005280-80-8 012225-18-2 NA: Not Available
C.I. No
20031 20040 21105 21098 21103 21290 11777 771740 56290 56290 21094 21094 11785 11710 11665 77492 77788 11741 21127 21108 20710 20034 11767
C.I. Name
C.I. Pigment Yellow 155 C.I. Pigment Yellow 16 C.I. Pigment Yellow 17 C.I. Pigment Yellow 174 C.I. Pigment Yellow 176 C.I. Pigment Yellow 180 C.I. Pigment Yellow 181 C.I. Pigment Yellow 184 C.I. Pigment Yellow 185 C.I. Pigment Yellow 185 C.I. Pigment Yellow 188 C.I. Pigment Yellow 188 C.I. Pigment Yellow 194 C.I. Pigment Yellow 3 C.I. Pigment Yellow 4 C.I. Pigment Yellow 42 C.I. Pigment Yellow 53 C.I. Pigment Yellow 74 C.I. Pigment Yellow 81 C.I. Pigment Yellow 83 C.I. Pigment Yellow 93 C.I. Pigment Yellow 95 C.I. Pigment Yellow 97
4.2 Dyes
C.I. Name Yellow Y 21 Y 29 Y 32 Y 56 Y 62 Y 79 Y 81 Y 82 Y 83 Y 83:1 Y 88 Y 89 Y 135 Y 146 Y 162 Orange O 11 O 41 O 54 O 56 18745:1 O 62 Red R 49 R 89 12714 21230 48045 11021 C.I. N Solvent Dyes 005601-29-6 006706-82-7 061931-84-8 002481-94-9 061901-95-9 012237-31-9 012227-56-4 012227-67-7 012239-75-7 061116-27-6 061931-55-3 061969-51-5 068427-35-0 109945-04-2 104244-10-2 061725-76-6 094279-65-9 061901-91-5 012237-30-8 012227-68-8 013463-42-8 052256-37-8 000509-34-2 061725-81-3 CAS N
12
C.I. Name R 91 R 92 R 119 R 122 R 124 R 125 R 127 R 130 R 160 R 229 Violet V2 V8 V9 V 13 Blue B4 B 25 B 44 B 45 B 64 B 67 B 70 B 136 Brown Black Br 43 Br 52 Bk 3 Bk 27 Bk 28 Bk 29 Bk 35 Bk 45 Bk 48 Acid Dyes Y3 Y9 Y 17 Yellow Y 23 Y 49 Y 250 Orange Red O7 R6 R 14 R 51 R 51:1 R 52 R 52 R 87 Blue B2 B3 B9 B104 Violet V 66
C.I. N
CAS N 061901-92-6 061901-93-7 012237-27-3 012227-55-3 012239-74-6 012271-00-0 061969-48-0 077496-01-6 061725-84-6 071839-77-5 069899-68-9 065138-66-1
061725-86-8 052080-58-7 000467-63-0 000081-48-1 006786-83-0 001328-54-7 072428-99-0 037229-23-5 061703-12-6 012226-78-7 081457-65-0 012237-24-0 069898-57-3 061116-28-7 091673-26-6
26150
12195 + 12197
47005
19140
45430 45430:1
13
C.I. Name Green Black Basic Dyes Yellow Blue Y 37 B1 B5 B 26 B 81 Red Violet Food Dyes Yellow Y3 Y4 Y 13 Red R3 R 3:1 R7 R9 R 14 R 14:1 R 17 lake B1 B 1:1 Blue B2 B 2:1 B5 Brown Black Br 3 Bk 1 Bk 2 Yellow Y 86 Y 86 Y 132 Y 170 Red Blue R 23 B 199 Bk 19 Black Yellow Bk 168 R1 V 10 G1 Bk 152 Bk 2
C.I. N
45160 45170
000989-38-8 000081-88-9
15985 19140 47005 14720 14720:1 16255 16185 45430 45430:1 16035 42090 73015:1 Na-salt 42090 42090:2 42051 20285 28440 27755 Direct Dyes
002783-94-0 001934-21-0 008004-92-0 003567-69-9 084238-07-3 002611-82-7 000915-67-3 016423-68-0 012227-78-0 068583-95-9 003844-45-9 016521-38-3 003844-45-9 068921-42-6 003536-49-0 004553-89-3 002519-30-4 002118-39-0 050925-42-3 131013-83-7 061968-26-1
Y 82 Y 54 Y 232
551200 47020 55165 60756 60756 60756 73300 61104 60725 61104 Reactive Dyes
027425-55-4 007576-65-0 035773-43-4 017418-58-5 017418-58-5 017418-58-5 000522-75-8 062570-50-7 012217-80-0 000081-48-1 012217-80-0 213328-78-0
Red
R 60 R 71 R 83 R 364
Blue
B 59 B 60 B 72 B 99 B 359
Red
R 24
18208
070210-20-7
14
C.I. Name
C.I. N Natural
Red Miscellaneous Dyes Black 400 Colour Former Red 3 Blue 63 Green DCF
R4
75470
5. Polymeric Resins
The polymeric resins are represented by their generic groups. They act as binders in the inks and coatings used on packaging. Binders are the filmforming components of inks and coatings in which the colorants may be finally dispersed or dissolved. Binders are also important for the transfer of the ink from the press to the substrate. After the drying of the print, binders serve to adhere the ink film to the printed surface and contribute to functional properties.
Polyester and Alkyd Resins Polyester epoxy modified Polyester alkyl-vinyltoluene modified Polyamide modified Alkyd Chlorinated polyesters Polyamide modified alkyds Polyurethane modified alkyds Cellulosics Nitrocellulose Hydroxyethylcellulose, Ethylcellulose
15
Resins Generic Groups Cellulose Ester Resins, Cellulose Acetobutyrate/-propionate, other Cellulosics Polymeric Acrylic Resins (solid resins, or water-based dispersions) Polymeric Acrylates Water based Acrylic Dispersion Polymeric Methacrylates Water based Methacrylic Dispersion Polystyrene Resins and Copolymers (solid resins, or water-based dispersions) Polystyrene/acrylic resins Water based Polystyrene/acrylic dispersion Polystyrene Maleic Resins Polystyrene/butadiene resins Poly(alpha-methylstyrene) resins Vinyl Polymers and Copolymers Polyvinyl butyral Polyvinyl acetate and propionate Polyvinyl chloride Polyvinylidene chloride Polyvinyl ether Polyvinyl alcohol Chlorinated Polyethylene- / Polyolefines Polyisoprene derivatives Cyclized rubber Chlorinated rubber Ketonic and aldehydic resins
Polyurethane Resins
Polyisocyanates
Polyamide Resins
Polysiloxanes
16
Amino Functional Resins Urea-Formaldehyde Resins Triazin (Melamine) -Formaldehyde Resins Polyamidoamine Resins Oligomeric UV curing synergists Polyalkyleneimines Benzoguanamine Resins Natural Resins (other than rosin) Shellac, Dammar, Kopal, Casein, ... Natural rubber latex Fatty Oils and Derivatives Polymerised vegetable oils
6.
6.1 Solvents
Except for some specific offset ink systems, solvents volatilise or evaporate directly after the ink or varnish is applied to the packaging substrate. It is common practice to use solvent combinations in order to control the speed of the drying process. In addition the concentration of residual solvents in the ink or coating being applied is managed to ensure that it is kept to a minimum in the final printed article.
Solvent Water Oxygenated Solvents: Alcohols 2-Ethylhexanol 2-Octanol Alcohols (C12-C16) branched Chemical name CAS N 007732-18-5 000104-76-7 000123-96-6 090604-38-9
Octan-2-ol
17
Solvent Alcohols (C12-C18) Alcohols (C13-C15) Alcohols (C16-C20) branched Benzylalcohol Butanol Cyclohexanol Ethanol Fatty alcohols (C8-C18) Glycerol Hexanol Isobutanol Iso-Octadecan-1-ol Isopropanol Iso-Stearyl alcohol Iso-Tridecanol Methyl iso-butyl carbinol n-Propanol Octanol Sec-Butanol Tert-Butanol Tridecanol Trimethyl hexanol Oleyl alcohol Oxygenated Solvents: Glycols/Ethers 1,2-Propylene glycol monoethyl ether (Ethoxypropanol) 1,3-Propylene glycol 1,4-Butylene glycol 2,2-bis(hydroxymethyl)-1,3-Propanediol 3-Ethyloxetane-3-methanol 3-Methoxybutanol Alcohols (C12-C14) ethoxylated Alcohols (C16-C18) ethoxylated Alcohols (C6-C12) ethoxylated Alcohols (C9-C11) ethoxylated Alcohols ethoxylated Alcohols ethoxylated propoxylated Butoxyl Butyl diglycol acetate Butyldiglycol Diethylene glycol monoethyl ether Diethylene glycol Dipropylene glycol Dipropylene glycol dimethyl ether (DPDM) Dipropylene glycol monomethyl ether (DPGME) Dipropylene glycol methyl ether (mixture of 4 isomers) Dipropylene glycol n-butyl ether Dipropylene glycol-n-propylether (DPnP) Propylene glycol-n-propyl ether 2-Ethylhexyl oxyethanol Ethoxypropanol (Ethyleneglycol monoethyl ether) Ethyl diglycol acetate Ethylene glycol butyl ether acetate Ethylene glycol diethyl ether Ethylene glycol mono isopropyl ether Ethylene glycol monoacetate Ethylene glycol monobutyl ether (Butylglycol)
Chemical name
CAS N 067762-25-8 090604-31-2 070963-04-8 000100-51-6 000071-36-3 000108-93-0 000064-17-5 068551-07-5 000056-81-5 000111-27-3 000078-83-1 027458-93-1 000067-63-0 045235-48-1 068526-86-3 000108-11-2 000071-23-8 000111-87-5 000078-92-2 000075-65-0 000112-70-9 003452-97-9 000143-28-2
Benzenemethanol 1-Butanol
1,2,3-Propanetriol Hexan-1-ol 2-Methylpropanol-1 2-Propanol 2-Octyldecan-1-ol Isotridecylalcohol 4-Methylpentan-2-ol 1-Propanol Butan-2-ol 2-Methylpropan-2-ol 3,5,5-Trimethyl-1-hexanol 9-Octadecen-1-ol
001569-02-4 000504-63-2 000110-63-4 000115-77-5 003047-32-3 002517-43-3 068439-50-9 068439-49-6 068439-45-2 068439-46-3 251553-55-6 068603-25-8 004435-53-4 000124-17-4 000112-34-5 000111-90-0 000111-46-6 025265-71-8 111109-77-4 020324-32-7 034590-94-8 029911-28-2 029911-27-1 001569-01-3 001559-35-9 000111-35-3 000112-15-2 000112-07-2 000629-14-1 000109-59-1 000542-59-6 000111-76-2
3-Methoxybutyl acetate 2-(2-butoxyethoxy)ethyl acetate 2-(2-butoxyethoxy)ethanol 2-(2-ethoxyethoxy)-ethanol Bis(2-hydroxyethyl)ether Oxybis(methoxy)propane 1-(2-methoxy-2-methylethoxy)-2-propanol 1-(2-methoxy isopropoxy)-2-propanol etc. 1-(2-Butoxy-1-methylethoxy)-2-propanol 1-(2-propoxy-1-methylethoxy)-2-propanol Ethylene glycol mono(ethylhexyl)ether 3-Ethoxy-1-propanol 2-(2-ethoxyethoxy)ethyl acetate 2-Butoxyethyl acetate 3,6-Dioxaoctane 2-Isopropoxyethanol 2-Hydroxyethyl acetate Butoxy-2-ethanol
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Solvent Ethylene glycol monopropyl ether Ethylene glycoldimethylether Ethylene glycol Hexanediol Hexylene glycol Isopropoxy ethyl acetate Methyldiglycol (Diethylene glycol monomethyl ether) N-Ethylmorpholine N-Ethylpyrrolidone Polyethylene glycol Polypropylene glycol Propylene glycol methyl ether acetate Propylene glycol Propylene glycol monobutyl ether (PnB) Propylene glycol monomethyl ether Tert. Butylmethyl ether (TBME) Texanol Triethylene glycol Triethylene glycol dimethyl ether (TRIGLYME) Triethylene glycol monobutyl ether Trimethyl hexanediol Tripropylene glycol Tripropylene glycol methyl ether Tripropylene glycol monomethyl ether (TPM) Tripropylene glycol monomethyl ether (TPM) Tripropyleneglycol n-butyl ether (TPnB) 1-Phenoxy 2-propanol Oxygenated Solvents: Esters Butanedioic acid dimethylester Butylacetate Cyclohexylacetate Ethylacetate Hexanoic acid dibutyl ester Hexanoic acid dimethyl ester (Adipic acid dimethyl ester) Isobutyl isobutyrate (IBIB) Isopropylacetate Pentanedioic acid dimethylester Propylacetate Propylene glycol monomethyl ether acetate (Methoxypropyl acetate) Texanol isobutyrate (TXIB) Hexyl acetate Ethyl lactate Ethyl lactate n-Propyl lactate Butyl lactate Butyrolactone Ethylene di(acetate) Ethylethoxypropionate Propylene glycol diacetate iso-Butyl acetate Triacetine 2-Ethylhexyl acetate Amyl propanoate
Chemical name 2-Propoxyethanol 1,2-Dimethoxyethane 1,2-Ethanediol Hexamethylene Glycol 2-Methyl-2,4-pentanediol 2-(1-methylethoxy)ethyl acetate 2-(2-methoxy-ethoxy)-ethanol 1-Ethylpyrrolidine-2-one
CAS N 002807-30-9 000110-71-4 000107-21-1 000629-11-8 000107-41-5 019234-20-9 000111-77-3 000100-74-3 002687-91-4 025322-68-3 025322-69-4 000108-65-6 000057-55-6 005131-66-8 000107-98-2 001634-04-4 000144-19-4 000676-18-6 000112-49-2 000143-22-6 003089-24-5 024800-44-0 025498-49-1 020324-33-8 025498-49-1 055934-93-5 000770-35-4
2-Methoxy-1-methylethyl acetate 1,2-Dihydroxypropane 1-Butoxy-2-propanol 1-Methoxy-2-propanol 2-Methoxy-2-methylpropane 2,2,4-Trimethyl-1,3-pentanediol 1,2-Bis(2-hydroxyethoxy)ethane 2,5,8,11-Tetraoxadodecane 2-(2-(2-butoxyethoxy)ethoxy)ethanol 2,2,4-Trimethyl-1,6-hexanediol 3-(3-(3-methoxypropoxy)propoxy)-propanol 1-(2-(2-methoxy-1-methylethoxy)-1methylethoxy)-2-propanol 2-(2Methoxymethylethoxy)methylethoxy]propano l 1-(2-butoxy-1-methylethoxy)-1methylethoxy)-2-propanol
Butanedioic acid dimethyl ester 1-Butyl ethanoate Cyclohexyl ethanoate Ethyl ethanoate Hexanedioic acid bis(2-methylpropyl) ester Hexanedioic acid dimethyl ester Isobytyl isobutyrate 2-Propyl ethanoate Pentanedioic acid dimethylester 1-Propyl ethanoate 1-Methoxy-2-acetoxy propane 2,2,4-Trimethyl-1,3-pentanediol diisobutyrate Ethyl (L)-2-hydroxypropionate Ethyl (S)-2-hydroxypropionate Butyl 2-hydroxypropionate
000106-65-0 000123-86-4 000622-45-7 000141-78-6 000141-04-8 000627-93-0 000097-85-8 000108-21-4 001119-40-0 000109-60-4 000108-65-6 006846-50-0 000149-92-7 000097-64-3 000687-47-8 000616-09-1 000138-22-7 000096-48-0 000111-55-7 000763-69-9 000623-84-7 000110-19-0 000102-76-1 000103-09-3 000624-54-4
Pentyl propionate
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Solvent Esters (C4-C13) of mono and di carboxylic acids 2-Ethoxy-1-methylethylacetate Hydroxyacetic acid butylester Bis- Diglyceryl-Polyacyladipate-2 TOTM (Trioctyltrimetillitate) Ethyl hexanoate Oxygenated Solvents: Ketones Cyclohexanone Diacetone alcohol Ethylacetoacetate Diethylketone (Pentanone) Diisobutylketone Methylethylketone (MEK) Methylisobutylketone (MIBK) Propylene carbonate N-Methylpyrrolidone N-Ethylpyrrolidone Acetone 2-Pyrrolidone Pentane-2-one Hydrocarbon Solvents Toluene Xylene Petroleum distillate, solvent refined, middle Petroleum distillate, hydrogenated, middle Petroleum distillate, hydrogenated, desulphurized, middle Aliphatic Petroleum solvent (Naphtha) Petroleum distillate, heavy alkylated Solvent naphtha (Petroleum), light aromatic Solvent naphtha, hydrogenated, heavy Mineral oil, highly refined (white oil) Ink oil (240-270C), aromatic content 20 % w/w Ink oil (240-270C), aromatic content 1 % w/w Ink oil (260-290C), aromatic content 20 % w/w Ink oil (260-290C), aromatic content 1 % w/w Ink oil (280-310C), aromatic content 20 % w/w Ink oil (280-310C), aromatic content 1 % w/w Petroleum distillate acid treated middle Light white mineral oil Paraffin oil Heptane Cyclohexane Methylcyclohexane Dodecylbenzene Limonene Octane Tetradecane Trimethylbenzene Alkanes C11-C15 iso Alkanes C9-C12 iso Petroleum distillate straight-run middle Petroleum distillate hydrodesulphurised Petroleum distillate hydrotreated light Petroleum distillate hydrotreated heavy Petroleum distillate hydrotreated light
Cyclohexanone 4-Hydroxy-4-methyl-2-pentanone Ethyl-3-oxobutanoate 3-Pentanone 2,6-Dimethylheptane-4-one 2-Butanone 4-Methyl-2-oxo-pentane 4-Methyl-2-oxo-1,3-dioxolane 1-Methylpyrrolidine-2-one 1-Ethylpyrrolidine-2-one
000108-94-1 000123-42-2 000141-97-9 000096-22-0 000108-83-8 000078-93-3 000108-10-1 000108-32-7 000872-50-4 002687-91-4 000067-64-1 000616-45-5 000107-87-9
000108-88-3 001330-20-7 064741-91-9 064742-46-7 064742-80-9 064742-88-7 064741-65-7 064742-95-6 064742-48-9 008042-47-5 064741-91-9 064741-91-9 064741-91-9 064741-91-9 064741-91-9 064741-91-9 064742-13-8 092062-35-6 008012-95-1 000142-82-5 000110-82-7 000108-87-2 000123-01-3 000138-86-3 065996-98-7 000111-65-9 000629-59-4 000095-63-6 090622-58-5 090622-57-4 064741-44-2 064742-81-0 064742-47-8 064742-48-9 064742-49-0
Hexahydro-Benzene
1,2,4-Trimethylbenzene
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Solvent Petroleum distillate hydrotreated heavy naphthenic Petroleum distillate hydrotreated light naphthenic Petroleum distillate solvent-dewaxed light paraffinic Petroleum distillate hydrodesulphurised heavy Petroleum distillate solvent refined heavy paraffinic Petroleum distillate solvent refined light paraffinic Petroleum distillate highly refined middle Petroleum distillate hydrotreated light naphthenic Petroleum distillate hydrodesulphurised light dearomatised Paraffins normal C5-C20 Alkylbenzenes Mesitylene iso-Propylbenzene Solvent Naphthas (low naphtha content) Aromatic petroleum distillate Alkylbenzene Petrolatum (vaseline) Fatty Acid Esters and Vegetable Oils Isopropyl palmitate Pentaerythritol-tetraoctoate Pentaerythritol-tetracaprate Isopropyl laurate Tallow fatty acid ester Synthetic fatty acid ester 256, 100% Methylester-CE-16/18 Methyl linoleate Methyl stearate Tung oil Alkali Refined Linseed Oil Safflower oil Soyabean oil Linseed stand oil 60 P Castor Oil Rapeseed oil RME (Rapeseed-methyl-ester) Tall oil fatty acid butyl ester, 100% Soy bean fatty acid 2-ethylhexyl ester (SJEH) Octyl Palmitate 2-Ethylhexyl laurate Lanoline
Chemical name
CAS N 064742-52-5 064742-53-6 064742-56-9 064742-82-1 064741-88-4 064741-89-5 090640-93-0 092062-15-2 092045-53-9
Benzene C4-C16 alkyl derivatives 1,3,5-Trimethylbenzene 1-Methylethylbenzene Solvent naphtha (petroleum) Aromatic hydrocarbons Tetrapropylenebenzene
000142-91-6 003008-50-2 068411-68-9 010233-13-3 067762-56-5 Synthetic fatty acid ester = 2-ethylhexyl-2ethyl-hexanoate Fatty acids, C16-18/C18 unsaturated, Methyl Esters = Methyl Palmitate/Methyl Stearate/Methyl Oleate Mixture 9,12-Octadecadienoic acid (9Z,12Z)-, methyl ester Octadecanoic acid, methyl ester Linseed oil Safflower oil Soybean oil Linseed oil Castor oil Methyl Oleate Butyl ester of select tall oil fatty acids Fatty acid-2-ethylhexylester Octyl Palmitate 2-Ethylhexyl laurate 007425-14-1 067762-38-3 000112-63-0 000112-61-8 008001-20-5 008001-26-1 008001-23-8 008001-22-7 008001-26-1 008001-79-4 008002-13-9 000112-62-9 Not available several 016958-85-3 020292-08-4 008006-54-0
Imp = not used directly but present in other materials as a significant component/impurity * Note can be present as processing solvents for some raw materials, and therefore could end up in food despite not being intentionally used within printing inks
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Abbreviated Name
Monofunctional Acrylates ACMO Aliphatic Urethane Acrylate IBOA ODA CTFA = TMPFA LA TDA IDA VC POA or PEA
Chemical Name
Acryloyl Morpholine 2-acrylic acid, 2-(((butylamino)carbonyl)oxy)ethylester Isobornylacrylate Octyl- and Decylacrylate Cyclic Trimethylolpropan-formal-acrylate Laurylacrylate Tridecylacrylate Isodecylacrylate Vinylcaprolactam 2-Phenoxyethylacrylate Monoacrylate of glycidylester of a branched-chain alkyl carboxylate with 10 C-atoms
CAS No.
005117-12-4 063225-53-6 005888-33-5 002499-59-4/ 002156-96-9 066492-51-1 002156-97-0 003076-04-8 001330-61-6 002235-00-9 048145-04-6 094624-09-6
Difunctional Acrylates HDDA HD (EO)DA NPG(PO) DA NPG(EO) DA TPGDA DPGDA BPA(E0)4DA (DDA) TTEGDA PEG200DA BADGE-DA BDDA MPDDA PODIA Hexanediol diacrylate Ethoxylated 1,6-Hexanediol diacrylate Propoxylated Neopentylglycol diacrylate Ethoxylated Neopentylglycol diacrylate Tripropylenglycol diacrylate Dipropyleneglycol diacrylate Ethoxylated Bisphenol-A- diacrylate Tetraethylene glycol diacrylate PEG (200) Diacrylate / PEG(400)Diacrylate Di-Acrylated Bisphenol-A-Diglycidylether Butandioldiacrylate 3-Methyl-1,5-Pentan-Diyl-Diacrylate propoxylated Diacrylate Difunctional aliphatic polyester urethane acrylate oligomer Difunctional urethane acrylate Trimethylolpropane triacrylate Ethoxylated Trimethylolpropane triacrylate Highly propoxylated glyceryl triacrylate Pentaerythritol tetraacrylate Propoxylated trimethylolpropane triacrylate Ethoxylated Pentaerythriol-Tetraacrylate Ethoxylated/propoxylated Pentaerythritol Tetraacrylate 013048-33-4 084170-27-4 084170-74-1 no CAS No. assigned 042978-66-5 057472-68-1 064401-02-1 017831-71-9 026570-48-9 055818-57-0 001070-70-8 064194-22-5 123813-18-3
Tri- and higher functional Acrylates TMPTA TMP(EO)TA GPTA / GPPOTA PETA TMP(PO)3TA PPT(T)A mod. PPT(T)A 015625-89-5 028961-43-5 052408-84-1 004986-89-4 053879-54-2 051728-26-8 no CAS No. assigned
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Abbreviated Name
Di-TMPTA PETIA PET(PO)TA DPHA Di-PEPA PETIA + PET(T)A
Chemical Name
Di-Trimethylol propane-tetraacrylate Pentaerythritol triacrylate Propoxylated pentyerythritol-tetraacrylate Dipentaerythritol-Hexaacrylate Dipentaerythritol-Pentaacrylate Pentaerythritol triacrylate / Pentaerythritol tetracrylate Polyolacrylate Tetrafunctional polyether acrylate based on TMP(EO)TA Amine-modified oligoether acrylate based on TMP(EO)TA
CAS No.
094108-97-1 003524-68-3 053879-55-3 029570-58-9 060506-81-2 no CAS No. assigned no CAS No. assigned Not available Not available
Epoxides for cationic systems Cycloaliphatic Epoxide Cycloaliphatic Epoxide Alkyl(C12-C14)glycidyl ether Oxetanes for cationic systems Trimethylolpropane oxetane Others Reactive Diluent (Tetraethylene glycol divinylether) Oligo[2-Hydroxy-2-methyl-1-[4(1methyl-vinyl)phenyl]propanone] HBVE 3-Ethyl-(hydroxymethyl)oxetane 003047-32-3 7-Oxabicyclo(4,1,0)heptane-3-carboxylic acid, 7oxabicyclo(4,1,0)hept-3-ylmethylester 3,4-Epoxycyclohexylmethyl-3,4epoxycyclohexylcarboxylate Oxiran, mono(C12-C14)alkyloxy methyl)derivative 068609-97-2 002386-87-0
3,6,9,12-Tetraoxa tetradeca-1,13-diene
000765-12-8 163702-01-0
017832-28-9
Contact Details:
If you have any questions or enquiries with respect to this Incomplete Inventory, please send a formal e-mail enquiry to the following address: eupia@cepe.org. These enquiries will be processed by the relevant experts within the EuPIA organisation and replies sent accordingly.
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