1.

a)

Name the apparatus shown below.

.. b) What error has been made in its manufacture? .. 2. a) Hydrogen can be prepared by the reaction between magnesium and dilute hydrochloric acid. Name another metal, which can be safely used instead of magnesium. .. Give a test for hydrogen. Test: . Observation: . c) Hydrogen is less dense than air. Which is the better of the two method shown below to collect the gas? Tick the correct answer.

b)

d)

Can hydrogen be collected over water? Explain you answer. Answer: . Reason: .

e)

An excess of hydrochloric acid was added to 0.20 g of magnesium. (A, of Mg =24) Calculate: (I) the number of moles of magnesium used in the experiment.

Madhrasathul Ahmadhiyya First Term Test - 2001 Chemistry-10 Paper 4 Page 1 of 6

(II) The volume of hydrogen which should be produced at room temperture and pressure (r.t.p.) when all the magnesium had reacted. (Molar volume is 24 dm3 at r.t.p.) . dm3 f) The student collected 180cm3 of percentage yield. hydrogen from the experiment. Calculate the

3. A student electrolysed molten zinc bromide and dilute sulphuric acid in the apparatus shown below.

a)

What was produced at the electrodes A, B, C and D? A: B: C: D:

b)

What happened to the brightness of the lamp when the following changes were made to the experiment? (I) Water wad added to the dilute sulphuric acid. . (II) The heating was stopped and the apparatus was left of cool. Explain your answer. Answer: . Explanation: ...

5. a)

A student recorded the results of four experiments with ethanol. Which result was not correct? a) On reaction with acidified potassium dichromate (VI), the colour of the solution changed from green to orange.
First Term Test - 2001 Chemistry-10 Paper 4 Page 2 of 6

Madhrasathul Ahmadhiyya

b) c) d) 6. a) b) c) 7.

On combustion a gas was produced which turned limewater milky. The ethanol dissolved in water On combustion a gas was produced which turned limewater milky. A student did four tests on the fertiliser ammonium sulphate; F. Which test did not produce ammonia? Aqueous sodium hydroxide was added to F followed by a piece of aluminium foil. The solution was warmed. Aqueous sodium hydroxide was added to F and the solution was warmed. Dilute hydrochloric acid was added to F and the solution was warmed. A student found that a hydrocarbon, P, contained 85.7% by mass of carbon. What was its empirical formula? ()

a) b) c) d) 8.

CH CH2 C2H CH3 This question is in two parts. A student was given a substance, M, and was asked to identify M and to determine its percentage purity. The following table shows the test on M and the conclusions made from the observations. Fill in the mission observations and identify M.

a)

test M was dissolved in dilute hydrochloric acid and the resulting solution divided into two parts for tests (b) and (c). Any gas produced was tested. (I) To the first part, aqueous sodium hydroxide was added until a change was seen. An excess of aqueous sodium hydroxide was added to the mixture from (I0. To the second part, aqueous ammonia was added.

observations

conlusions M is not a compound of a transition metal. M contains Ca32+ ions.

b)

(II)

M probably contains Ca2+ ions.

c)

The presence of Ca2+ ions is confirmed

d)

Conclusion: the formula of M is

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Madhrasathul Ahmadhiyya

The percentage purity of M was determined in the following experiment. e) A sample of M was added to a previously weighed container which was then reweighed. Mass of container + M = 12.28g Mass of container = 10.95 g Calculate the mass of M used in the experiment. Mass of M = 9 The sample was placed in a flask and 50.0 cm 3 of 1.00 mol/dm3 hydrochloric acid (an excess) was added. The mixture in the flask was allowed to react completely. On completion of the reaction, distilled water was added until 250 3 cm of solution was obtained. 25.0 cm3 of this solution was plpetted into a conical flask. A few drops of methyl orange indicator was added. From a burette, o.100mol/dm3 sodium hydroxide was added until an end point was reached. f) What was the colour change of the indicator? The colour changed from to g) Three titrations were done. Parts of the burette with the liquid levels before and after each titration are shown below.

Titration number Final reading/cm3 First reading/cm3 Volume of 0.100 mot/cm3 Best titration result () Summary:

Tick () the best titration results. Using these results the average volume of 0.100 mol/dm3 sodium hydroxide was cm3. h) i) Calculate the number of moles of sodium hydroxide in the average volume of 0.100mol/dm3 sodium hydroxide in (g) moles of sodium hydroxide. Hydrochloric acid reacts with aqueous sodium hydroxide as shown in the equation.
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Madhrasathul Ahmadhiyya

...

i)

Using you answer from (h) calculate the number of moles of hydrochloric acid present in 25.0 cm3 of the solution of M.

. Moles hydrochloric acid

ii) How many moles of hydrochloric acid were present in 250 cm3 of the
solution of M? k) How many moles of hydrochloric acid were present in the 50.cm3 of 1.00 mol/dm3 hydrochloric acid that reacted with M.

. Moles hydrochloric acid l) By subtracting the answer (j) (ii) from answer (k), calculate the number of moles of hydrochloric acid that reacted with M.

. Moles hydrochloric acid m) Using the formula of M, as determined in part (d) of the experiment, calculate the relative molecular mass of M. ( A: Ca = 40, C = 12, O = 16 ) The relative molecular mass of M is n. Calculate the percentage purity of M by using your answers in the following formula. answer (1)x answer ( m ) x 50 answer ( e )

percentage =

Percentage purity of M= .% 9Name the piece of apparatus shown.

Answer ..

Madhrasathul Ahmadhiyya

First Term Test - 2001

Chemistry-10

Paper 4

Page 5 of 6

10-

A student added 100 cm3 of 1.00 mol/dm barium nitrate to 100 cm3 of 2.00 mol/dm3 sodium sulphate. Barium sulphate was produced. a) i) ii) iii) Give the formula of barium sulphate. . Describe the appearance of barium sulphate in the resulting mixture. . How could the barium sulphate be removed from the mixture?

Madhrasathul Ahmadhiyya

First Term Test - 2001

Chemistry-10

Paper 4

Page 6 of 6