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110B - Chapter 13: Molecular Spectros
110B - Chapter 13: Molecular Spectros
110B - Chapter 13: Molecular Spectros
Chapter 13
Molecular Spectroscopy
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Chapter 13
Infrared Spectrum
Chapter 13
Symmetric stretch
Instructor Tng Th Thanh Hng
Asymmetric stretch
Bend
20
Chapter 13
Chapter 13
2Qss = Qss
vQss = Qss
vQss = Qss
Qas belongs to the totally asymmetric irrecducible representation B2 Qas = Q as; 2Qas = - Qas vQas = - Qas vQas = Qas
Chapter 13
irreducible representation.
In three dimensional, N atoms in molecule, so 3N x 3N reducible.
Chapter 13
Selection Rules
The spectroscopic selection rules determine which transitions from one state to another are possible. Schrdinger equation:
Chapter 13
Chapter 13