PRELIMINARY EXAMINATION PAPER CHEMISTRY XII

PREPEARED BY :SALEEM CHOHAN CHEMICAL ENGINEERING NEDUET ,PAKISTAN Chohan_msc@yahoo.com

SECTION A MULTIPLE CHOICE QUESTIONS I) What is the coordination number of Co in [Co(NO2)2(en)2] + 1 ? (a) 4 (b) 5 (c) 6 (d) 3 II) An isomer of ethanol is (a) Dimethyl ether (b) Ethylene glycol (c) Methanol (d) Diethyl ether iii) Boric Acid when heated at 140oC turns into : (a) Pyroboric acid (b) Metaboric Acid (c) orthoboric Acid (d) Tetraboric Acid iv) Which of the following gas has rotten egg like smell: (a) NH3 (b) Cl2 (c) C6H6 (d) H2S v) Enzyme is : (a) Protein (b) Amino acid (c) vitamins (d) lipids vi) long chain of carboxylic acids are: (a)soap (b) Ester (c) fatty acid (d) Enzyme

vii) Which of the following possess maximum

+ +

hydration power? (a) Na (b) K (c) Ca+2 viii) Ethanol containing some methanol is called

(d) Mg+2 (d)formalin

(a) Absolute spirit

(b) Rectified spirit

(c) Methylated spirit

xi) The chemical formula of carnalite is. (a) (b) KCI. MgCl2. 6H2O (c) MgCO3.CaCO3 (d) ) Na2B4O7. 10H2O (d) N2O4 (d) C2H4 (d) C2H4 (d) C2H4 (d)

X) Laughing gas is chemically : (a) NO (b) N2O (c) NO 2 OR Which gas gives smoky flame: (a) C2H2 (b) CH4 (c) C6H6 OR Which of them is used as general anesthetic? (a) C2H2 (b) CH4 (c) C6H6 Xi) Dehydration of Ethanol gives a) C2H2 (b) CH4 (c) C2H4 O xii) Which pair of groups contains both ortho & para directors? (a) OH , RCO (b) NR 3 , CN (c) OCH 3 , CHO xiii) (a) Methoxy butane (b) But 2 en-3-ol xiv) The water soluble vitamin is (a) A (b) D XV) The main protein of milk is (a) haemoglobin (b) Casein xvi) Detergents are sodium salts of (a) Calcium suphonates (b) Sodium carbonates xvii) Tincal is a mineral of__ (a) Al (b) B (c) But-2-en-1-al (c) K (d) C

(d) Propenaldehyde

(c) Insulin

(d) Vitelin

(c) Benzene sulphonates (d) ) Barium sulphonates (c) C (d) S

SECTION B SHORT ANSWER QUESTIONS

NOTE: Answer any FIVE questions from INORGANIC CHEMISTRY and any FIVE from ORGANIC CHEMISTRY . All questions carry equal marks.
INORGANIC CHEMISTRY Q.2 ( I ) a) Write the valence shell configuration of : VIIA and VII B IIIA and III B b) Give the Block, period and the group no. of the elements having : Z= 24 & Z= 35 (ii) How hydrogen gas is prepared on industrial scale? (any two methods) Give also the method of

separation of hydrogen from the water gas? OR Explain Ionic and Complex hydrides . (iii) a) Give the molecular formula of the following compound? Bi-dentate ligand Borax Plaster of Paris Hypo b) Write a short note on the Corrosion OR Boric Acid.
(iv) How is H2S produced in laboratory? Draw its structure.Also show how it is a strong reducing agent.

OR How Sodium metal is extracted by the molten sodium chloride using downs process?
(v) Give reasons:

Why hydration energy of Li+ ion is greater than CS+ ion Cu 2+ ion is colored while Zn 2+ ion is not. OR H2SO4 has high viscosity and b.p . Why NH3 and H2O act as ligands but H3O+ and NH+4 do not act as ligand Why Cl2 replace Bromine from KBr OR Li forms covalent bond but Na forms ionic bond
(vi) Give equations of the following:

Action of heat on AgNO3 / Gypsum / blue vitriol Cu is treated with conc. / dil HNO3 OR Al is treated with conc. / dil H2SO4 Action of Aqua regia on gold OR H2 is passed over hot tungsten oxide NaOH is added into NH4Cl OR Auto oxidation reduction reaction of Cl2. (vii) a) Give the following characteristics of d Block elements Color Formation Used as catalyst b) Define Allotropy? Name the allotropic forms of Sulfur and write two properties of each.
(viii) Give the I.U.P.A.C name of the following:

[Cu(NH3)4]2+

[Cr (NH3)5Br]SO4

K3[Fe(CN)6]

[Ni(CO)4]

ORGANIC CHEMISTRY xi) a) Draw and discuss the structure of methane OR ethyne? b) Distinguish between the following by a simple chemical test Alcohol and Phenol Alkane and alkyl halide x) Give the equations for the preparation of: Acetone from Acetic Acid Benzene from Phenol Ethyne from Calcium Carbide Ethane from methyl Chloride xi) What is Grignard reagent. Prepare following compounds from Grignard reagent Ethanoic acid, Ter-alcohol, Alkane xii) a) Give the mechanism of the reaction of the methane with chlorine in the presence of sunlight? b) What are oxonium ions? Discuss chemical behavior of diethyl ether.

xiii) Define the following : Peptide Bond / Reducing sugars Homologous series Metamerism Markownikoff s rule xiv) Write down three equations of the reaction when: Phenol reacts with Br2 Ethene reacts with S2Cl2 Sodium benzoate reacts with H2SO4 Ethyne reacts with HBr xv) Define and classify amino acids.? Discuss dipolar nature of amino acids. OR Write a short note any two of the following : Fertilizers Glass Carbohydrates xvi) a)Give reasons of the following: E2 reaction is of second order Ethene is acidic in nature b) How ethyl alcohol is prepared by the fermentation of starch?
SECTION C ( DETAIL ANSWER QUESTIONS ) NOTE: Attempt TWO questions ,one from inorganic section and other from organic section. INORGANIC CHEMISTRY Q.3 a) How is soda ash produced on a large scale? Explain why this compound is used as wate softener? b) Define Periodicity and state Modern Periodic law. What are outer and inner transition elements and also write their valence shell configuration

c) Complete the reaction: SO2 + Cl 2 H3BO3 + NaOH C6H12O6 + H2SO4 (conc.) Fe2O3 + Al
Q.4 a)What is matte? Give the extraction of copper from matte.Draw the diagram of a Bessemer converter. OR Write the names and formulae of important ores of Aluminum . Describe the purification of Aluminum by Hoope's electrolytic method? b) Give the structure and preparation of HNO3 by Ostwalds method? ORGANIC SECTION Q.5 a) Define Aromacity and orientation. Give the mechanism of the nitration in Benzene

OR Describe the kekule structure of benzene in detail.

b) Give equation for the reaction : i) Ethyl alcohol reacts with Na metal OR Polymerization of Ethene 0 ii) Phenol reacts with Conc.HNO3 at 100 C OR Cannizaro reaction iii) Methanal reacts with Phenyl Hydrazine OR Iodoform formation iv) Basic hydrolysis of Ethyl acetate c) Outline the stepwise mechanism of SN2 OR Unimolecular eliminaton reaction with example. Q.6 a) What are Activating and Deactivating groups? Starting from Benzene, how would you prepare : o-Nitrotoulene p-Nitro benzoic acid Phenol b) Define Isomerism? Discuss it types? c) Give the IUPAC name of the following: (from book)